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Classification: General Business Use SHPP's Inputs to the Public Consultation Comments to Annex XV PFAS Restriction Proposal Question number 6.

Eindverslag bestek: DGEM/DPPC/ADS/22045 Versie: 01 Datum: 04/2023 FOD VVVL - Galileelaan 5/2 - 1210 Brussel, Belgi Besteknummer DGEM/DPPC/ADS/22045 PFAS-gebruik in de Belgische Huishoudtextielindustrie Opgemaakt door CENTEXBEL Pagina 1 van 53 Eindverslag bestek: DGEM/DPPC/ADS/22045 Versie: 01 Datum: 04/2023 1 Inhoudstafel 1 Inhoudstafel _________________________________________________________________________ 2 2 Samenvatting ________________________________________________________________________ 4 3 Situering en doelstellingen van de opdracht _______________________________________________ 5 4 Kennis van de textielsector in Belgi______________________________________________________ 6 Centexbel ________________________________________________________________________________ 6 Textielfederatie ___________________________________________________________________________ 6 Federatie Belgische Textielverzorging (FBT) ____________________________________________________ 6 5 De Belgische textielindustrie, gericht op huishoudelijke toepassingen _________________________ 7 5.1 Interieurtextiel (Fedustria, 2023) ___________________________________ 7 6 Situering van PFAS-gebruik binnen de textielsector _________________________________________ 8 6.1 Indeling en toepassing van PFAS op textiel ___________________________ 8 6.1.1 Algemene informatie PFAS ____________________________________ 8 6.1.2 Fysische en chemische eigenschappen van niet-polymeren PFAS______ 10 6.1.3 Fysische en chemische eigenschappen van polymeren PFAS _________ 11 6.2 Toxiciteit van PFAS _____________________________________________ 11 6.3 Verspreiding van PFAS __________________________________________ 12 7 REACH- en POP-verordening: PFAS restricties relevant voor de textielsector ___________________ 13 7.1 Autorisaties___________________________________________________ 13 7.2 Restricties ____________________________________________________ 14 7.3 Beperkingen van textielrelevante PFAS-componenten __________________ 14 7.3.1 De aanwezigheid van PFAS-componenten op textiel dat gecertificeerd is volgens de "Oeko-Tex Standard 100" ________________________________ 15 8 Toepassing van water-, olie- of vuilafstotend finishes op textiel _____________________________ 16 8.1 formuleringen voor water- en olieafstotende finishes __________________ 16 8.1.1 afstotende finish op basis van wax (paraffine-metaalzoutformuleringen) 16 8.1.2 op hars gebaseerde afstotende finish ___________________________ 16 8.1.3 silicone gebaseerde middelen _________________________________ 16 8.1.4 fluor gebaseerde middelen ___________________________________ 17 8.2 Applicatiemethoden voor oppervlakte behandeling van textiel ___________ 17 8.3 Alternatieven voor PFAS _________________________________________ 18 8.3.1 Courante alternatieven voor waterafstotende behandeling van textiel __ 18 8.3.2 Onderzoek naar nieuwe alternatieven voor PFAS __________________ 19 Pagina 2 van 53 Eindverslag bestek: DGEM/DPPC/ADS/22045 Versie: 01 Datum: 04/2023 9 PFAS in de (textiel)afvalfase ___________________________________________________________ 20 10 Gebruik van PFAS bij huishoudtextiel op de Belgische en Europese markt ____________________ 21 10.1 Bevraging bij leveranciers van chemicalin __________________________ 22 10.1.1 Gebruik van PFAS bij chemicalinleveranciers ____________________ 23 10.1.2 Conclusie _________________________________________________ 25 10.2 Bevraging bij producenten en loonwerkers __________________________ 26 10.2.1 PFAS-gebruik binnen de tapijtsector ____________________________ 27 10.2.2 PFAS-gebruik bij productie van meubelstoffen ____________________ 28 10.2.3 PFAS-gebruik bij de productie van huishoudelijk linnen _____________ 28 10.2.4 PFAS-gebruik bij de productie van Passementerie _________________ 28 10.2.5 PFAS-gebruik bij productie van decoratieve stoffen ________________ 29 10.2.6 PFAS-gebruik bij de productie van Matrasbeschermers _____________ 30 10.3 Bevraging bij traders van textielmaterialen __________________________ 31 11 Besluitvorming ______________________________________________________________________ 33 11.1 PFAS-gebruik voor huishoudtextiel_________________________________ 33 11.2 Textiel voor professionele doeleinden ______________________________ 34 11.3 Textielverzorging ______________________________________________ 34 12 Bronvermelding _____________________________________________________________________ 35 13 Bijlagen ____________________________________________________________________________ 36 Bijlage 1 - PFAS-componenten die zijn opgenomen in de "Kandidaatslijst van zeer zorgwekkende stoffen voor autorisatie" _________________________________________________________________________ 37 Bijlage 2 - Vragenlijst Chemicalin leveranciers _______________________________________________ 38 Bijlage 3 - Vragenlijst Productiebedrijven ____________________________________________________ 41 Bijlage 4 - Vragenlijst Traders _______________________________________________________________ 47 Bijlage 5 - Factsheet Oeko-Tex Standard 100 _________________________________________________ 52 Pagina 3 van 53 Eindverslag bestek: DGEM/DPPC/ADS/22045 Versie: 01 Datum: 04/2023 2 Samenvatting Poly - en perfluoralkylverbindingen (PFAS) kenden in het verleden een ruime toepassing binnen de textielindustrie omwille van de water- en vuilafstotende eigenschappen die ze kunnen genereren.

Apr 25, 2023 Comment on Proposed Restriction of PFAS Conference of Fluoro-Chemical Product Japan (FCJ) On behalf of chemical manufacturers, we, Conference of Fluoro-Chemical Product Japan (FCJ), have been working tirelessly to comply with national chemical regulations.

Classification: General Business Use SHPP's Inputs to the Public Consultation Comments to Annex XV PFAS Restriction Proposal Question number 6: Missing uses: PTFE Used in Internally Lubricated Thermoplastic Compounds for Automotive Applications Previous ECHA submission Ref.

Attachment-3List of properties 1.Plastics Plastic type Formability Physical properties Mechanical properties Thermal properties Electrical properties Other chemical property Formability Compression molding temperature Injection molding temperature Mold shrinkage rate Specific gravity Water absorption rate (24 -3 .18mm thickness ) Tensile strength MPa Elongation Tensile modulus of elasticity MPa Compressive strength MPa Flexural strength MPa Impact strength(Izod/notch)J/m Hardness (Rockwell) Coefficient of thermal expansion 105/ Continuous heat resistance temperature Melting point Deflection temperature under load (1 .81MPa) Volume resistance (50% , RH23) Dielectric breakdown strength Short-time Permittivity 103Hz(106Hz) Arc resistance sec Burning rate mm/min Effects of weak acids Effect of strong acid Effects of weak alkali Effect of strong alkali - D792 D570 D638/651 D638 D638 D638 D638 D638 D785 D696 D2117 D648 D257 D149 D150 D495 D635 D543 D543 D543 D543 Organic solvent resistance D543 Polytetrafluoroethylene PTFE 2 .13 - 2 .20 0 .01 20 - 35 200 - 400 10-15 150 - 160 R20 10 260 327 55 1018 19 2 .1 300 V-0 Fluorinated-ethylenepropylene FEP 319 - 399 329 - 404 3 .0 - 6 .0 2 .12 - 2 .17 0 .01 20 - 35 300 - 350 15 - 20 didn't break R50 12 260 310 47 1018 20 2 .1 300 V-0 Perfluoroalkoxy alkane PFA 329 - 371 371 - 427 2-3 2 .15 - 2 .17 0 .01 20 - 30 200 - 400 14 - 19 didn't break R50 9 200 260 50 1018 22 2 .1 300 V-0 Regulated materials Polychlorotrifluoroethylene PCTFE Ethylene tetrafluoroethylene ETFE 238 - 254 227 - 316 1 .0 - 1 .5 2 .10 - 2 .20 1 .73 - 1 .74 0 .01 0 .03 31 - 41 80 - 250 31 - 51 135 - 145 R80 38 - 42 300 - 400 40 - 50 didn't break R50 6 6 120 220 90 1018 22 2 .6 300 V-0 150 270 74 1017 16 2 .6 75 V-0 Ethylenechlorotrifluoroethylene ECTFE 1 .68 - 1 .69 0 .01 41 - 48 200 - 300 35 - 40 didn't break R50 8 150 245 77 1015 20 2 .6 18 V-0 Polyvinylidene fluoride PVDF 204 - 288 232 - 288 3 1 .75 - 1 .78 0 .03 30 - 70 200 - 370 32 - 74 160 - 375 R93 - 116 16 150 151 - 178 100 1015 11 8 .4 60 V-0 Plastic type Formability Formability Compression molding temperature Injection molding temperature Mold shrinkage rate Physical properties Specific gravity Water absorption rate (24 -3 .18mm ) Tensile strength /2 Elongation Mechanical properties Tensile modulus of elasticity 104kg/ Compressive strength /2 Flexural strength /2 Impact strength(Izod/notch)J/m Hardness (Rockwell) Thermal properties Electrical properties Coefficient of thermal expansion 105/ Continuous heat resistance temperature Heat deformation temperature (18 .5Kg/2) Volume resistance (50% , RH23) Dielectric breakdown strength Short-time Permittivity 103 Arc resistance sec Other Burning rate (flame resistance) Effects of weak acids Effect of strong acid chemical property Effects of weak alkali Effect of strong alkali Organic solvent resistance ECHA alternative candidate Polyvinyl chloride PVC Hard PVC Soft High density polyethylene HDPE - - - 141 - 204 141 - 177 149 - 232 D792 D570 149 - 204 0 .1 - 0 .5 1 .35 - 1 .45 0 .07 - 0 .40 160 - 195 1-5 1 .16 - 1 .35 0 .15 - 0 .75 149 - 316 2-5 0 .94 - 0 .97 0 .01 D 638/651 D 638 D 638 350 - 630 2 - 40 2 .5 - 4 .2 105 - 630 200 - 450 - 220 - 390 15 - 100 0 .42 - 1 .1 D 695 D 790 D 256 D 785 D 696 560 - 910 700 - 1130 2 .2 - 109 70 - 90 ( Shore D) 5 - 18 .5 63 - 120 - 50 - 100 ( Shore A ) 7-25 230 70 8 .2 - 10 .9 60 - 70 ( Shore D) 11-13 - 66 - 79 66 - 79 121 D 648 D 257 D 149 54 - 74 1016 16 .7 - 51 .1 1011 - 1015 11 .8 - 39 .3 43 - 54 1016 17 .7 - 19 .7 D 150 D 495 3 - 3 .3 60 - 80 4-8 2 .3 - 2 .35 - - D 635 Self-extinguishing Slow self-extinguishing Very slow D 543 D 543 D 543 D 543 D 543 - Swelling or soluble in ketones, esters, swelling in aromatics

Apr 25, 2023 Comment on Proposed Restriction of PFAS Conference of Fluoro-Chemical Product Japan (FCJ) On behalf of chemical manufacturers, we, Conference of Fluoro-Chemical Product Japan (FCJ), have been working tirelessly to comply with national chemical regulations.

Leveraging innovation to develop sustainable solutions Solvay's roadmap to phase out fluorosurfactants At Solvay, we have a long record of innovation, and since our founding 160 years ago we have used science to help invent more sustainable, high-performing solutions to address the challenges of today and tomorrow.

REVIEW Review of essential use of fluorochemicals in lithographic patterning and semiconductor processing Christopher K.

9.6Chemical Recycling of PTFE (as a Model for Other Polymers) 577 9.6Chemical Recycling of PTFE (as a Model for Other Polymers) Achim Schmidt-Rodenkirchen, Klaus Hintzer, Thorsten Gerdes 9.6.1Introduction PTFE (polytetrafluoroethylene) and other perfluorinated polymers like FEP (copoly mers of tetrafluoroethylene (TFE) and hexafluoropropylene (HFP)) or PFA (a copolymer of TFE and perfluorovinylether) are niche polymers, with a total production in 2015 of 160 kt, compared to polymers overall of 322 Mt [1].

PFAS additive consumption during battery life ref.

Old PTFE membrane Projects list Region Project Japan USA Europe Other Tokyo Dome Intex Osaka Nagai athletics Field University of La Verne Asheboro Zoo Walden Galleria mall Tropicana Field Denver International Airport Schlumberger Cambridge Research Center UK O2 ArenaUK Rome Olympic StadiumItaly The Hajj TerminalSaudi Arabia Completion year (years) 198835years 198538years 199627years 197350years 198340years 198835years 198934years 199430years 198439years 199825years 199033years 198142years

TeflonTM FEP 9494 Fluoroplastic Resin Product Information For inventory control purposes, product name may be followed by an X.

1 _____________________________________________________________________________________________ International Association of Fire and Rescue Services Asociacin Internacional de Servicios de Fuego y Rescate Internationale Vereinigung des Feuerwehr- und Rettungswesens CTIF WWW.CTIF.ORG Center for Fire Statistics World Fire Statistics Estadsticas Mundiales de Bomberos Die Feuerwehrstatistik der Welt Report / Informe/ Bericht 28 _____________________________________________________________________________________________ Copyright by Center for Fire Statistics of CTIF 2023 2 _____________________________________________________________________________________________ All statistical data presented in this report were obtained from responses to the requests of the Fire Statistics Center of CTIF (CFS CTIF) and published previously in official statistical information of various countries.