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AR2 2 t>- SRPTT-6295.8, T-6316.4, T-6868.2, T-707U, T-7132.1 DT15-B 3M MEDICAL DEPARTMENT, CORPORATE TOXICOLOGY Title: Comparative Molecular Biology of PerfluorooctanesoIfonate (PEGS, 1-6295), N-ethyl peril tiorooctanesuIfonamido ethanol (N-EtFOSE, T-6316), N-Ethy!

il RESEARCH Precise Research.

AR226-3173 TRADESECRET Study Title H-24616: Bacterial Reverse M utation Test Authors Valentine O.

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FirstChemical Corporation A DuPont Company PASCAGOULA BASELINE STUDY/REPORT FOR FIRST CHEMICAL CORPORATION PASCAGOULA, MISSISSIPPI Date: October 2006 Project No.: 18984786.06051 508800 Pascagoula Baseline Study/Report Table of Contents TABLE OF CONTENTS Executive Summary............................................................................................................1 1.0 Introduction.................................................................................................................1 1.1 Background on PFOA and PFOS......................................................................1 1.2 Report Content.................................................................................................. 2 2.0 Pascagoula Region Water and Solids Sampling........................................................ 3 2.1 Introduction and Background........................................................................... 3 2.2 Water and Solids Field Sampling..................................................................... 3 2.2.1 Surface Water and Wastewater Sampling........................................... 3 2.2.2 Potable and Industrial Water Sampling............................................... 5 2.2.3 Groundwater Sampling........................................................................ 5 2.2.4 Pascagoula POTW Sludge Sampling.................................................. 6 2.3 Laboratory Analysis and Data Review - Water and Solid Samples.................6 2.4 Discussion of Analytical Results...................................................................... 8 2.4.1 Surface Water...................................................................................... 8 2.4.2 Groundwater........................................................................................ 9 2.4.3 Pascagoula POTW Sludge..................................................................10 2.5 General Occurrence of PFOA in the Water and Solids...................................10 2.5.1 Discussion of PFOA Concentrations in Fresh Water.........................10 2.5.2 Discussion of PFOA Concentrations in Salt Water............................11 2.5.3 Discussion of PFOA in Waste Water Treatment Facilities................11 2.6 Summary of Water and Solids Field Sampling...............................................11 3.0 Pascagoula Region Fish and Invertebrate Sampling.................................................13 3.1 Introduction and Background..........................................................................13 3.2 Fish and Invertebrate Field Sampling..............................................................13 3.2.1 Selected Fish Sampling......................................................................13 3.2.2 Selected Invertebrate Sampling..........................................................14 3.3 Laboratory Analysis and Data Review - Fish and Invertebrate Samples.......14 3.4 Discussion of Analytical Results for Fish and Invertebrates..........................15 3.4.1 Fish.....................................................................................................15 3.4.2 Invertebrates.......................................................................................16 3.5 General Occurrence of PFOA in Fish and Invertebrates.................................16 3.5.1 Discussion of PFOA Concentrations in Saltwater Fish......................16 3.5.2 Discussion of PFOA Concentrations in Marine Invertebrates...........17 3.5.3 Bioaccumulation Discussion..............................................................17 3.6 Summary of Invertebrates and Fish Field Sampling.......................................18 4.0 References.................................................................................................................19 S:\Groups\URS\WP\Pascagoula\508800 Baseline Study\Report\FCC BaselineStudyRpt.doc October 2006 i Pascagoula Baseline Study/Report Table of Contents Table 1a Table 1b Table 2 Table 3a Table 3b Table 4 Table 5 TABLES PFOA Summary Water Samples PFOS Summary Water Samples PFOA and PFOS Summary of Solids Sample PFOA Summary Biological Samples PFOS Summary Biological Samples Summary of Background Information on PFOA from the Literature Cited in This Report Biological Sample Sizes Figure 1 Figure 2 FIG URES Baseline Study Sampling Locations Groundwater and Storm Water Sample Locations Appendix A Analytical Data APPEN DICES S:\Groups\URS\WP\Pascagoula\508800 Baseline Study\Report\FCC BaselineStudyRpt.doc October 2006 ii Pascagoula Baseline Study/Report Acronyms ACRONYMS Acronym APFO BCF BAF COC DuPont FCC LC/MS/MS LOD LOQ MDEQ MDL MDMR MS ND NQ Pg/Kg Pg/L ng/g NERR PBS PFOA PFOS POTW Ppb PQL QAPP QC RPD SNUR SOP STL SWPPP WWTP Definition / Description Ammonium perfluorooctanoate Bioconcentration Factor Bioaccumulation Factor Chain of Custody E.

l3^l-ll07-39f 3>o( November 20, 2007 DuPont Haskell Global Centers for Health and Environmental Sciences Elkton Road, P.O.

TSCA SANITIZED A22&3B3/ M B Research Laboratories , VOLUME I P.

INTERIM REPORT # 21 - Analysis of Soil Samples STUDY TITLE Analysis of Perfluorobutanesulfonate (PFBS), Perfluorohexanesulfonate (PFHS), and Perfluorooctanesulfonate (PFOS) in Water, Soil, Sediment, Fish, Clams, Vegetation, Small Mammal Liver and Small Mammal Serum Using LC/MS/MS for the 3M Decatur Monitoring Program DATA REQUIREMENTS EPA TSCA Good Laboratory Practice Standards 40 CFR 792 STUDY DIRECTOR Jaisimha Kesari P.E., DEE Weston Solutions, Inc. 1400 Weston Way West Chester, PA 19380 Phone: 610-701-3761 INTERIM REPORT COMPLETION DATE November 6,2006 PERFORMING LABORATORY Exygen Research 3058 Research Drive State College, PA 16801 Phone: 814-272-1039 STUDY SPONSOR 3M Company 3M Building 0236-01-B-10 St.

SEVERN TRENT LABORATORIES ANALYTICAL REPORT JOB NUMBER: 244963 Prepared For: Weston Solutions, Inc. 1400 Weston Way Building 5-2 West Chester, PA 19380-1499 Project: Confidential Decatur - FC Investigation Attention: Sue Stefanosky Date: 03/23/2006 Signature Name: Richard C.

310 Bank Street Decatur, Alabama 35601 256.353.2910 tele 256.353.3944 fax www.TTyNC.com geotechnical analytical * materials * en v ir o n m e n t a l Decatur.

M zz If January 30, 2002 MEDOW12nfirar0fv.eis0icCchretoPihonnoeargmn,rftlnoCPeesnsonhy,lteMllaDmvul.at.PiiCnAcoria.noualte2PAeCr0crvo4etienv6onte0nrunoeAtli,oDgNnei.nvWacinsy.dio(Tn7o4x0i5cMs ) Fire Fighting Foam Coalition Thomas A.

Andrea V.

Naval Research Laboratory Washington, DC 20375-5320 N R L /M R /6 1 8 0 --00-8474 Evaluation of the Effects of AFFF Inputs on the VIP Biological Nutrient Removal Process and Pass-Through Toxicity M .

PUBLIC COPY 06 APR i i f g: o Yo-/cy3 ^ April 7, 2006 Via Federal Express Document Processing Center (Mail Code 7407M) Room 6428 Attention: 8(e) Coordinator Office of Pollution Prevention and Toxics U.S.