MATERIAL SAFTY DATA SHEET Sigma-Aldrich Corporation 1001 Vest Saint Paul Ave, Hilvak.ee, VI 53233 USA This information valid through May 01, 1993 For Emergency Contact USA/Canada Sigma 800-325-5832 314-771-5765 Aldrich 800-321-8327 414-273-3850 --------------------------------------- IDENTIFICATION ------------------------------------------ PRODUCT #: 84711 NAME: '.CARBON DISULFIDE CAS #; 75-15-0 " SYNONYMS CARBON BISULFIDE * CARBON BISULFIDE (DOT) * CARBON BISULPHIDE * CARBON DISULFIDE (ACGIH,DOT,OSHA) * CARBON DISULPHIDE * CARBONE (SUFURE DE) (FRENCH) * CARBONIO (SOLFURO DI) (ITALIAN) * CARBON SULFIDE * DITHIOCARBONIC ANHYDRIDE * KOHLENDISULFID (SCHVEFELKOHLENSTOFF) (GERMAN) * K00LST0FDISULFIDE (ZVAVELKOOLSTOF) (DUTCH) * NCI-C04591 * RCRA VASTE NUMBER P022 * SCHVEFELKOHLENSTOFF (GERMAN) * SOLFURO DI CARBONIO (ITALIAN) * SULPHOCARBONIC ANHYDRIDE * UN 1131 (DOT) * VEEVILTOX * VEGLA DVUSIARCZEK (POLISH) * -------------------------------------- TOXICITY HAZARDS ------------------------------------------ RTECS NO: FF6650000 CARBON DISULFIDE TOXICITY DATA IHL-HMN LCLO:4000 PPM/30M 29ZVAE -,118,68 IHL-HMN LCLO:2000 PPM/5M TABIA2 3,231,33 UNR-MAN LDLO:186 MG/KG 85DCAI 2,73,70 ORL-RAT LD50:3188 MG/KG GISAAA 31(1),13,66 IHL-RAT LC50:25 GM/M3/2H 85GMAT -,32,82 ORL-MUS LD50:2780 HG/RG GISAAA 31(1),13,66 IHL-MUS LC50:10 GM/M3/2H 85GMAT -,32,82 ORL-RBT LD50:2550 MG/KG GISAAA 31(1),13,66 ORL-GPG LD50:2125 MG/KG GISAAA 31(1),13,66 REVIEVS, STANDARDS, AND REGULATIONS ACGIH TLV-TVA 10 PPM (SKIN) 85INA8 5,104,86 MSHA STANDARD-AIR:TWA 20 PPM (60 MG/M3) (SKIN) DTLVS* 3,39,71 OSHA PEL:8H TVA 20 PPM;CL 30 PPM;PK 100 PPM/30M/8H FEREAC 54,2923,89 OSHA PEL FINAL:8H TVA 4 PPM (12 MG/M3);STEL 12 PPM (36 MG/M3)(SKIN) FEREAC 54,2923,89 OEL-ARAB REPUBLIC OF EGYPT:TVA 10 PPM (30 MG/M3);SKIN JANUARY 1993 OEL-AUSTRALIA:TVA 10 PPM (30 MG/H3);SKIN JANUARY 1993 OEL-BELGIUM:TVA 10 PPM (31 HG/M3);SKIN JANUARY 1993 OEL-CZECHOSLOVAKIA: TVA 10 MG/M3; STEL 20 MG/M3 JANUARY 1993 OEL-DENMARK:TVA 5 PPM (15 MG/M3);SKIN JANUARY 1993 OEL-FINLAND:TVA 10 PPM (30 MG/M3);STEL 20 PPM (60 MG/M3);SKIN JANUARY OEL-FRANCE:TVA 10 PPM (30 MG/M3) ;STEL 25 PPM (75 MG/M3) JANUARY 1993 OEL-GERMANY:TVA 10 PPM (30 MG/M3);SKIN JANUARY 1993 OEL-HUNGARY:TVA 5 MG/M3;STEL 10 MG/M3;SKIN JANUARY 1993 OEL-INDIA:TVA 10 PPM (30 MG/M3);SKIN JANUARY 1993 OEL-JAPAN:TVA 10 PPM (31 MG/M3);SKIN JANUARY 1993 OEL-POLAND: TVA 25 MG/M3 JANUARY 1993 OEL-RUSSIA:TVA 10 PPM;STEL 1 MG/M3 JANUARY 1993 OEL-SVEDEN:TVA 5 PPM (16 MG/H3); STEL 8 PPM (25 HG/M3);SKIN JANUARY 1993 OEL-SVITZERLAND:TVA 10 PPM (30 MG/M3); STEL 20 PPM (60 HG/H3);SKIN JANUARY 1993 OEL-THAILAND:TVA 20 PPM (60 MG/M3); STEL 30 PPM (90 MG/M3) JANUARY 1993 OEL-THE NETHERLANDS:TVA 20 PPM (60 MG/M3);SKIN JANUARY 1993 OEL-THE PHILIPPINES:TVA 20 PPM (60 MG/M3);SKIN JANUARY 1993 OEL-TURKEY:TVA 10 PPM (65 MG/M3);SKIN JANUARY 1993 D0 A CONFIDFNTTAl OEL-UNITED KINGDOM:TVA 10 PPM (30 MG/M3);SKIN JANUARY 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA, NEV ZEALAND, SINGAPORE, VIETNAM CHECK ACGIH TLV NIOSH REL TO CARBON DISULFIDE-AIR: 10B TVA 1 PPM (SK);STEL 10 PPM (SK) NIOSH* DHHS #92-100,92 NOBS 1974: HZD 17370; NIS 24; TNF 1074; NOS 27; TNE 24200 NOES 1983: HZD 17370; NIS 20; TNF 751; NOS 44; TNE 45760; TFE 5834 EPA GENETOX PROGRAM 1988, POSITIVE: SPERM MORPHOLOGY-HUMAN EPA TSCA CHEMICAL INVENTORY, JUNE 1990 ON EPA IRIS DATABASE EPA TSCA TEST SUBMISSION (TSCATS) DATA BASE, JANUARY 1993 NIOSH ANALYTICAL METHODS: SEE CARBON DISULFIDE, 1600 NTP CARCINOGENESIS STUDIES;SELECTED, OCTOBER 1992 TARGET ORGAN DATA LIVER (FATTY LIVER DEGENERATION) PATERNAL EFFECTS (SPERMATOGENESIS) PATERNAL EFFECTS (PROSTATE, SEMINAL VESICLE, COVPER'S, ACCESSORY GLANDS BFFECTS ON FERTILITY (POST-IMPLANTATION MORTALITY) EFFECTS ON EMBRYO OR FETUS (PBTOTOXICm) EFFECTS ON NEWBORN (BEHAVIORAL) ONLY SELECTED REGISTRY OF TOXIC EFFECTS OF CHEMICAL SUBSTANCES (RTECS) DATA IS PRESENTED HERE.

Ethanolamines/Glycol Ethers In Plant Training (IPT) Section Number Issue Number Origination Date Revision Date Section Test :4 :1.2 :08-14-91 :02-22-96 :8 Author: L.C.

Ethanolamines/Glycol Ethers In Plant Training (IPT) Section Number Issue Number Origination Date Revision Date Section Test :6A : 1.2 :10-04-91 :02-22-96 :8 Author: Bryan Abadie Lab Familiarization Area Hazards Answers: 1.

Section Number Issue Number Origination Date Revision Date Section Test Ethanolamines/Glycol Ethers In Plant Training (IPT) :15 :1.3 :09-01-91 : 12-23-97 :15 Author: Mike Viator Ethanolamines/Glycol Ethers Control Module Line-O-Logic Answers: 1.

Section Number Issue Number Origination Date Revision Date Ethanolamines/Glycol Ethers In Plant Training (IPT) :5 :1.3 :09-29-91 : 12-11-95 Section Test 4B Ammonia System Objectives/Answers: 1.

Ethanolamines/Glycol Ethers In Plant Training (IPT) Section Number issue Number Origination Date Revision Date Section Test 4B 1.2 08-05-91 12-09-94 :4B Author: Keith Bonanno Ethanolamines - Ammonia System D-210 -E-210- P-210 A/B Answers: 1.

Ethanolamines/Glycol Ethers In Plant Training (IPT) Section Number Issue Number Origination Date Revision Date Section Test 4B 1.3 09-29-91 12-23-97 :4B Author: Keith Bonanno Ethanolamines - Ammonia System P-212 A/B Answers: 1.

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California Environmental Protection Agency OFFICE OF ENVIRONMENTAL HEALTH HAZARD ASSESSMENT January 27,1995 State of California Pete Wilson, Governor F) Has Shah, Ph.D, Chemical Manufacturers Association 2501 M Street NW Washington D.C., 20037 Dear Dr.

DEC--2B-1994 12= 42 FROM DRAYDEN UYOE & UOQD LLP TO ^2129062021-02030005 P.02 No. 94-1103 DORIS EIRVEN, INDIVIDUALLY AND AS REPRESENTATIVE OF THE ESTATE OF ROBERT H.

ABD00027762 CONDEA VISTA COMPANY CORPORATE SAFETY, HEALTH & ENVIRONMENT STANDARDS Subject: Issue Date: Supersedes: Approved By: Process Safetv Manaaement - Trainma March 22. 1996 Auaust 18. 1995 (Final Draft) Harrv D Garrison Manager Safety, Health & Environment 1 0 SCOPE This standard applies to CONDEA Vista Company facilities covered by OSHA Process Safety Management It addresses the training requirements specified in the OSHA Process Safety Management regulation 29 CFR 1910 119(g) which is specific to employee and contract operator training Training specified by 1910 119(j), Mechanical Integrity, 1910 119(1), Management of Change and 1910 119(h), Contractors are not addressed by this standard unless the facility uses contract operators in which case, this standard applies 2 0 PURPOSE This standard specifies the minimum requirements that each covered facility must incorporate into their local training standard for Process Safety Management The training required by this standard can be performed as part of training to meet other regulatory requirements, but the facility's training program documentation should specifically make note of that fact 3 0 PSM REQUIREMENTS SPECIFIC TO OPERATOR TRAINING 3 1 Initial Training Prior to beginning work or prior to assuming the duties of a new assignment in a covered process in a solo capacity (without direct supervision or assistance from a fully qualified and competent trainer or supervisor), operators must be initially trained and successfully complete the minimum training requirements specified by the operating procedures requirements of 1910 119(f) for their position Training must include emphasis on the specific safety and health hazards, emergency operations including shutdown, and safe work practices applicable to the employee's job task PSM-006 Page 1 of 4 This Document is UNCONTROLLED unless one of the following appears Red Stamp stating "Controlled Document" or Blue "CONDEA Vista Controlled Copy" on the right of the page ABD00027763 CONDEA VISTA COMPANY CORPORATE SAFETY, HEALTH & ENVIRONMENT STANDARDS Subject: PSM-Training Issue Date: March 22, 1996 3 2 Refresher Training 321 Each facility must ensure that employees (CONDEA Vista and contractor) involved in operating a covered process understands and adheres to the current operating procedures of the process and must provide refresher training at least every three years, or more frequently if necessary 3 2 2 The appropriate frequency and scope of refresher training shall be determined through consultation between the facility management and the employees (CONDEA Vista and contractor) involved in operating the process Such determinations should be based on observed or reported deviations from standard operating procedures, recent incidents, incident investigation recommendations, apparent deficiencies in training, audits, etc A record of this consultation and the resulting determination shall be maintained indefinitely or until subsequent consultation/ determinations occur Each facility shall specify in their standard the job title(s) of the person(s) who will be responsible for maintaining this documentation 3 2 3 The time period for refresher training of an employee involved in operating a covered process is to be measured from the date of the employee's last training required by this standard or May 26, 1992 if "grandfathered" as permitted by 1910 119 (g)(1)(n), whichever is later 3 2 4 The content of the refresher training shall parallel that required for initial training such that it includes the following applicable to the employee's job task a specific safety and health hazards, b emergency operations including shutdown, PSM-006 Page 2 of 4 This Document is UNCONTROLLED unless one of the following appears Red Stamp stating "Controlled Document" or Blue "CONDEA Vista Controlled Copy" on the nght of the page ABD00027764 CONDEA VISTA COMPANY CORPORATE SAFETY, HEALTH & ENVIRONMENT STANDARDS Subject: PSM-Training Issue Date: March 22, 1996 c safe work practices, and d special emphasis on additions or changes to information or procedures made since the last initial or refresher training Note Refresher training is considered an independent training requirement in addition to other training requirements of the OSHA PSM standard, therefore, training under "Management of Change" does not normally satisfy the refresher training requirement of this standard unless the refresher training covers the entire procedure -- not just the change An example might be training provided following a new expansion or or process change where the training provided for the change parallels that one would receive for initial training When this occurs, it is strongly recommended that the training be documented as both - MOCA and Refresher or Initial training 4 0 DOCUMENTATION AND RECORDKEEPING 4 1 Each facility shall, through some affirmative means ascertain that each employee (CONDEA Vista and contractor) involved in operating a covered process has received and understood the training required under this standard This could include the administration of written tests, but may also include on-the-job demonstrations, or other methods as long as they are adequately documented 42 Documentation shall include 4 2 1 The identity of the employee (or contractor), 4 2 2 The date of training, 4 2 3 The means used to verify the employee understood training, 4 2 4 The identity of the person(s) conducting the training and/or administering the verification of understanding, 4 2 5 Results of testing, field demonstrations, etc PSM-006 Page 3 of 4 This Document is UNCONTROLLED unless one of the following appears Red Stamp stating "Controlled Document" or Blue "CONDEA Vista Controlled Copy" on the right of the page ABD00027765 CONDEA VISTA COMPANY CORPORATE SAFETY, HEALTH & ENVIRONMENT STANDARDS Subject: PSM-Training Issue Date: March 22, 1996 4 2 6 Copies of course outlines, field demonstration requirements, blank tests or checklists, etc as appropriate to evidence the content of the training and verification, and 4 2 7 Any other documentation deemed pertinent by the facility 4 3 Training records for items 4 2 1 through 4 2 5 above as a minimum shall be maintained in a data base for the term of the person's employment 4 4 Documents in items 4 2 6 and 4 2 7 above shall be retained not more than five years 4 4 Each facility shall develop a Training compliance document that a Defines the job positions of employees involved in the operation of the process that are subject to the training requirements of this standard b Describes the process that will be used to ensure that all training required by this standard occurs in the time frame(s) specified c Specifies who (by job title) will be responsible for various aspects of the training requirements including but not limited to maintenance of training records, advance notification that training is required, preparation of training materials, actual training, and verification of comprehension d Specifies where training records are located for inspection PSM-006 Page 4 of 4 This Document is UNCONTROLLED unless one of the following appears Red Stamp stating "Controlled Document" or Blue "CONDEA Vista Controlled Copy" on the right of the page