Page 1 KION GROUP AG | Thea-Rasche-Str. 8 | 60549 Frankfurt am Main | Germany Consultation on the restriction of per- and polyfluoroalkyl substances (PFAS) 1.
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best regards, Dit bericht kan informatie bevatten die niet voor u is bestemd.
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Can you suggest someone we could discuss this with - someone in your organisation who is familiar with REACH and give us definitive guidance Best wishes
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CHEMICAL RESISTANCE AGAINST H2SO4 Chemical resistance Material properties Effects of chemical media Resistance against various media Case studies PVDF and ECTFE used for sulphuric acid Description of sulphuric acid slightly yellow viscous liquid (oil of triviol) soluble in water at all concentrations Diprotic acid Corrosive due to its - strong acidic nature, - strong dehydrating property - strong oxidizing property (concentrated acid) CHEMICAL RESISTANCE AGAINST H2SO4 Chemical resistance Material properties Effects of chemical media Resistance against various media Case studies Resistance of PVDF against sulphuric acid Temperature [C] Maximal admissible concentration of H2SO4 23 96,3 50 93 100 85 120 80 150 70 (no pressure) Information based on chemical resistance tests of the raw material supplier CHEMICAL RESISTANCE AGAINST H2SO4 Chemical Resistance of PVDF against sulphuric acid resistance Brown discoloration Permeation Material properties H2SO4 Concentration Temperature Hoop stress V max Time at rupture H2O V max without rupture Effects of % C MPa hours MPa 97 10 54700 chemical media 96 50 18 37650 23 93 18 > 54900 * Resistance 96 1 8600 93 100 4 7900 12.5 against various 9800 6 > 9200 11 54530 media 93 120 3 296 9.5 80 9 > 17500 * Case studies 90 2 1825 80 150 5 > 1700 5.5 70 fCR = H2SO4 / H2O 4 > 30000 fCR 0.43 0.78 0.78 < 0.1 < 0.3 0.48 < 0.88 < 0.1 0.94 < 0.1 (0.91) 0.72 CHEMICAL RESISTANCE AGAINST H2SO4 Chemical resistance Material properties Effects of chemical media Resistance against various media Case studies Sulphuric acid - brown discoloration Test criteria: 200 h at 95C V=11,5 N/mm Stopped after 240 hours Burst pressure 20C; 0,08 bar/sec 98 bar CHEMICAL RESISTANCE AGAINST H2SO4 Chemical resistance Material properties Effects of chemical media Resistance against various media Case studies High concentrated sulphuric acid (concentration: >96,3%) SO3(g) + H2O(l) H2SO4(l) -H2O Sulfur trioxide (SO3) CHEMICAL RESISTANCE AGAINST H2SO4 Chemical resistance Material properties Effects of chemical media Resistance against various media Case studies Resistance of PVDF against sulphur trioxide, which is formed by sulphuric acid >96,3% Deshydrofluorination Permeation Increase in weight (>5%) Stress cracking corrosion Typical phenomenon if SO3 only is present in very small amounts Physical and chemical degradation ECTFE is resistant against sulphuric acid with a concentration >96,3% without any restrictions CHEMICAL RESISTANCE AGAINST H2SO4 Chemical resistance Material properties Effects of chemical media Resistance against various media Case studies Medium: Temperature: Medium: Temperature: sulphuric acid 98% 20C sulphuric acid 96% 20C - 30C CHEMICAL RESISTANCE AGAINST H2SO4 Chemical resistance Material properties Effects of chemical media Resistance against various media Case studies Medium: Temperatrure: sulphuric acid 98% 20C The solution ETHYLENCHLORTRIFLUORETHYLEN - ECTFE
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High Heat Resistant Thermal Interface Material VMQ EPDM FKM Heat resistant Good Fair Excellent Fiiler additon Excellent Good Fair Volatility resistance Fair Fair Excellent
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ANNEX 2- Answer to question 7 from Europump Potential derogations marked for reconsideration - Analysis of alternatives and socio-economic analysis: Paragraphs 5 and 6 of the proposed restriction entry text (see table starting on page 4 of the summary of the Annex XV restriction report) include several potential derogations for reconsideration after the consultation (in [square brackets]).
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Lens cleanability and how to clean lenses: a review WHITE PAPER This technical paper summarises the results of the latest research on the topic of lens cleanability while also taking the wearer's perspective into account.
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Request for exemption - EBulb Markus Fiebig (Senior Business Development Manager, JOB Group) Summary of request for exemption - EBulb Why we believe an exemption for EBulb can be justified: Goal of this presentation: Request for exemption, unlimited Relevance for society: High because EBulb reduces the risk of fires caused by electricity and enables digitalization in sensitive areas Impact for environment: Low Expected emissions in the air by 2030: 92,50 mL(mililiters!)
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The exemption application of perfluorosulfonic acid(PFSA) resins and perfluorocarboxylic acid(PFCA) resins and ion exchange membranes for chlor-alkali industry Hangjin Jinxi Chlor Alkali Chemical Co., Ltd. has a production capacity of 450,000 tons of chloralkali, and has been committed to the healthy development of chlor-alkali industry, keeping up with industry requirements and constantly updating the production process.
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Vorlufige Technische Information Dy neo nTM PFA 6505T Z Fluorthermoplast M erk male Groer Temperatureinsatzbereich Nahezu universelle Chemikalienbestndigkeit Sehr hohe Witterungsbestndigkeit und UVStabilitt Sehr gute elektrische Isolationseigenschaften Sehr schwer entflammbar (hoher LOI) Glatte Oberflche Sehr gute Antihafteigenschaften Niedriger Reibungskoeffizient Breites TemperaturVerarbeitungsfenster verbesserte Entformungseigenschaften Verbesserte Spannungsribestndigkeit Hohe Transparenz T ypisc he Eigensc haf ten* Eigensc haf ten Dichte Schmelzpunkt MFI (372 C/5 kg) LOI T es tmetho d e DIN EN ISO 12086 DIN EN ISO 12086 DIN EN ISO 1133 ASTM D2863 Einheit g/cm3 C g/10 min % W ert 2,15 310 5 > 95 M ec hanisc he Eigensc haf ten an gesinterten Fo rmk rpern* Hrte ASTM D2240/ISO 868 60 Shore D Reifestigkeit DIN EN ISO 527-1 MPa 30 Reidehnung DIN EN ISO 527-1 % 410 Biege E-Modul ASTM D790 MPa 550 * Mittelwerte A llgemein DyneonTM PFA 6505T Z Fluorthermoplast, ein voll fluoriertes Copolymer aus Tetrafluorethylen und Perfluorvinylether, zeichnet sich durch exzellente Temperaturbestndigkeit, optimale Chemikalienund Witterungsbestndigkeit und sehr gute elektrische Eigenschaften aus.
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Page 1 KION GROUP AG | Thea-Rasche-Str. 8 | 60549 Frankfurt am Main | Germany Consultation on the restriction of per- and polyfluoroalkyl substances (PFAS) 1.
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Comments: I.
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rel i -- .CTAssociates, Inc.
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