ARTICLE pubs.acs.org/JPCA Atmospheric Chemistry of (Z)-CF3CHdCHCF3: OH Radical Reaction Rate Coefficient and Global Warming Potential Munkhbayar Baasandorj,, A.R.

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TURI TOXICS USE REDUCTION INSTITUTE UMASS LOWELL TOXICS USE REDUCTION INSTITUTE The Offices at Boott Mills West 126 John Street, Suite 14 (2nd Floor) Lowell, MA 01852-1152 www.turi.org The Toxics Use Reduction Institute (TURI) respectfully submits the following comments to the European Chemicals Agency as input on their PFAS restriction proposal regarding fluorinated gases (F-gases).

389 20109 NEW C HE MIC AL M AT ERI ALS Vol 38 No9 75 710065 Progress in synthesis and applications of trifluoropropanoic acid Zeng JijunDu YongmeiZhang WeiKang Jianpin Hao ZhijunWang BoMa YangboLv Jian Xi'an Modern Chemist ry Research InstiuteXi'an 710065 AbstractPhysical and chemical properties of trifluoropropanoic acid w ere introducedDifferent preparation meth- ods and application progress in some fields such as synthesis of fluorinated compoundscatalysts and specific solvent w ere s um m ariz ed Key wordstrifluoropropanoic acidpropertypreparationapplication Oxone2K HS O5K2S O4K HS O4 5 1 1 CF3 1 RhC 2 CF3 3 4 2 CF3S O2ClCF3CdBr 333- -1- HCFC-1233zd 21 CF3SO2Cl AIBN CF3S O2Cl 333--1- 1984 ODS 76 38 25 HCFC-1233zd HCFC-1233zd 1 HCFC-1233zd 9 5 2HCFC-1233zd 10 6 3HCFC-1233zd Oxone 11 7 26 111333- CF3C H2CCl3 CF3C H2CCl2F CF3C H2CClF2 OleumS O3 H2S O4 12 8 3 31 CF3 311 2-13 2- 312 B1 B1 14 3 N- B1 B1 B1 313 U S5100751 15 32 16 17 33 18 19 4 20 HCFC- 115 9 115 15 6 T gT d 1 Cassidy P ET hermally stable polymers M New YorkDekker 1980 2 Yang H H Aromatic high-st rengt h fibers M New York Wiley 1989 3 Sheng-Huei HsiaoYu-Hui ChangNew soluble aromatic polyamides containing et her linkages and laterally attached p-terphenyls J European Polymer Journal2004401749-1757 4 M 1988 5 Lora JSoriaro BComposite membranes of aromatic polyamidemembrane peaparation and characterization J Deaolinut io n 198764375-386 6 Biw are M V Ghatge N DSt udies in piperazine containing poly sulphone-amides for use in w ater desalination J Desalinat io n 199510193-100 7 Iborra M LLora JEffect of oxidation agent s on reverse osmosis membrane performance to brackish w ater desalination J Desalination199610883-89 8 Wing-Hong ChanSuei YeeSynt hesis and characterization of random polyamide-sulfonamides3Copolymers f rom t w o diamino monomers J Polymer199533234503-4508 2010-06-12 2010-07-18 76 1233zd HCFC-1233zd 1 Henne A L Fox C J Ionization constant s of fluorinated acids J J Am Chem Soc1951732323-2325 2 Buyle O Lorent K Mat hieu V Process for t he manufact ure of fluorinated alcohols P EP1820789A12007-8-22 3 How ard M PLeonard O RRobert L SMarion E HImproved synt heses of et hyl 333-t rifluoropropionate and 333t rifluoropropionic acid J J Chem Eng Data197116 3 376-377 4 Ling XiaoT omoya Kitaz umeSynt hesis of some fluorinated acidsketones and alcohols derived f rom333-t rifluoropropionic acid J J Fluorine Chem19978699-104 5 Wakselman CT ordeux MSynt hesis of 333-t rifluoropropionic and 444-t rifluoro-2-ketobutyric acids J J Fluorine C hem 19922199-106 6 Bouillon J PMaliverney CMernyi RT rifluoromet hylation of aliphatic halogen compounds J J Chem Soc Perkin T rans199192147-2149 7 Munavalli E SLewis OMuller A JNovel reactions of perfluoro-2-t rifluoromet hyl-propene J J Fluorine Chem1993 63253-64 8 Yamanaka H T T akekaw a KMorita T IPreparation of novel -t rifluoromet hyl vinamidinium salt and it s synt hetic application to t rifluoromet hylated heterocycles J T et rahedron Lett 1996371829-1832 9 Komata T Akiba SHosoi KOgura KConvenient synt hesis of 333-t rifluoropropanoic acid by hydrolytic oxidation of 33 3-t rifluoropropanal dimet hyl acetal J J Fluorine Chem 200812935-39 10Komata T Akiba SHosoi KOgura KProcess for producing 333-t rifluoropropanoic acid P WO 2007052492A1200705-10 11 Van Der Puy MT henappan APreparation of fluoroalkyl compounds and t heir derivatives P U S 57771841998-06-07 12Veronique MOlivier BF rancine JPreparation of carboxylic acids P EP 1754697A12007-02-21 13Jimenze J MBemis GWang T ianshengKinase Inhibitors P WO 2008094992 A22008-08-07 14Wood M RAnt hony N JBock M GN-Biphenylmet hyl aminocycloalkanecarboxamide dernatives wit h a substit uent on t he met hyl usef ul as brad ykinin antagonist s P WO 2003066577 2003-08-14 15Kato EIshii KIshibashi HLiquid developing agent for elect rostatic photography P U S 51007511992-04-31 16 P C N 1012742262008-10-01 17 F P C N 17576392006-04-12 18 Yamamoto EIshihama Y Asakaw a N LC-MS analytical met hod and it s mobile phase P JP 20040772762004-03-11 19 Spaugh A T Vinyl ends measuring met hod P WO 20080974162008-04-16 20 J 200432944-46 2010-04-19 2010-06-03

REV F1 American Pacific Corp (2-BTP Clean Fire Extinguishant) Exhibit A - Additional Background on the Effort to Replace Severe Ozone Depleting Halons with 2-BTP A.

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BRITISH ADHESIVES & SEALANTS ASSOCIATION About BASA BASA are a Trade Association set up to act as the voice for the adhesives & sealants sector in the United Kingdom and Ireland.

TURI TOXICS USE REDUCTION INSTITUTE UMASS LOWELL TOXICS USE REDUCTION INSTITUTE The Offices at Boott Mills West 126 John Street, Suite 14 (2nd Floor) Lowell, MA 01852-1152 www.turi.org The Toxics Use Reduction Institute (TURI) respectfully submits the following comments to the European Chemicals Agency as input on their PFAS restriction proposal regarding fluorinated gases (F-gases).

Extract from the reference list of FRIOTHERM heat pumps with numbers of operating hours Installation Vrtan Ropsten Sandvika 1 Kista Akalla Lysaker Nimrod Fornebue Fornebue 05 Sandvika 2 Skoyen 05 Skoyen 07 Katri Vala Turku I Type d'UNITOP 50FFE 28/28CPY 33/28CY-8129U 28/22BY-8107U 33/28CPY-10149U 28/22CY-8117U 33/28CPY-10149U 33/28CPY-816118U 50FY-101711U 34FY-81411U 50FY-81912U 50FY-81912U N of HPs 6 2 2 1 4 1 1 1 1 1 5 1 Year of delivery 1984 (4) 1986 (2) 1988 1998 1998 2000-01 2000 2005 2008 2006 2008 2005 2009 City / Country Stockholm / SE Sandvika / NO Stockholm / SE Lysaker / NO Stockholm / SE Fornebue /NO Fornebue /NO Sandvika/NO Oslo / NO Oslo / NO Helsinki / FI Turku / FI Evap. regime 2.5/0.5 10/6C 14/4C 5/2C 8.5/6C 5/2C 5/2C 8.7 / 4 C 10/5.8C 10/6.3C 10 / 4C 9 / 2.8C Cooling capacity 6 x 20'000 kW 6 x13'500kW* 2 x 4'750 kW 2 x 6'000 kW 1 x 3'000 kW 4 x 9'000 kW 1 x 3'600 kW 1 x 5'600 kW 5'200 kW 11'840 kW 6'000 kW 5 x 12'000kW 11'900 kW Source froide Sea water Sewage water District cooling Sea water ind.

Reference: 1.

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