Document zzzqrQr0XxRJxLVxnZb8D2kzg
DEPARTMENT OF THE NAVY
BASE REALIGNMENT AND CLOSURE PROGRAM MANAGEMENT OFFICE EAST
4911 SOUTH BROAD STREET PHILADELPHIA, PA 19112-1303
5090 ser BPMOE/16-237 June 29, 2016
M s . Sarah Kloss Remedial Project Manager U.S. Environmental Protection Agency Region III (3HS11) 1650 Arch Street Philadelphia, PA 19103-2029
'
Mr. Colin Wade Project Officer Environmental Cleanup Program PA Department of Environmental Protection
2 East Main Street Norristown, PA 19401-4915
-'
Dear Ms. Kloss and Mr. Wade:
Enclosed are the final technical memorandums and compact disc for the 2015 Perfluorinated Compounds Groundwater Investigations at Naval Air Station Joint Reserve Base - Willow Grove Shenandoah Woods Housing Complex located in Warminster, PA. The documents address PADEP comments received on November 19, 2015. EPA concurrence was received on April 7, 2016.
Should you require any further information concerning this subject, please contact me at (215) 897-4904.
BRAC Environmental Coordinator By direction of BRAC PMO
Enclosure: Technical Memorandums - April 2016
Copy to: EPA Region III (L. Cunningham) Horsham Land Redevelopment Authority Warminster Township <G. Schuster) Horsham Township Library (L. Tynan) Aldie Foundation, Inc. Navy Caretaker Site Office (M. Schy) BRAC PMO East Files
(T. Ames)
US00008269
0)
RESOLUTION CONSULTANTS
Resolution Consultants A J o in t Venture ofAECOM & EnSafe
510 Carnegie Center Princeton, New Jersey 08540
Technical Memorandum Perfiuorinated Compounds Groundwater Investigation
Shenandoah Woods Housing Complex Naval Air Warfare Center, Warminster, Pennsylvania
4 June 2015 through 1 July 2015
1.0 INTRODUCTION
This Technical Memorandum summarizes the findings of the additional groundwater investigation performed by Resolution Consultants (Resolution) at the Shenandoah Woods Housing Complex, located at the former Naval Air Warfare Center (NAWC) Warminster between 4 June 2015 and 1 July 2015, under Naval Facilities Engineering Command (NAVFAC) Atlantic, Comprehensive Long-Term Environmental Action, Navy (CLEAN) Contract No. N62470-11-D-8013, Contract Task Order (CTO) WE 28.
The former NAWC Warminster is an 824-acre facility located in Warminster Township, Northampton Township, and Ivyland Borough, Bucks County, PA. As a result of the Defense Base Realignment and Closure Act (BRAC), NAWC Warminster was closed on 31 March 1997; the entire property, except for the Shenandoah Woods parcel, has been transferred to the private sector for redevelopment. Custody of the Shenandoah Woods Housing Complex on the NAWC Warminster property was transferred to NASJRB Willow Grove located in nearby Horsham Township, Montgomery County, Pennsylvania. Historic waste disposal locations were grouped within three general areas on the former NAWC property (see Figure 1): Area A (Sites 1, 2, and 3), Area B (Sites 5, 6, and 7), and Area C (Sites 4 and 8). A fourth general area (Area D) primarily includes the former main building complex at the former NAWC Warminster. This perfiuorinated compounds (PFCs) investigation focused on the former Navy housing area, consisting of approximately 55 acres, which includes a portion of Site 5 of Area B.
PFCs are persistent in the environment and are an emerging class of environmental contaminants. PFCs are used to make a wide range of products including oil-, stain-, heat-, and water-resistant materials such as clothing (i.e. GORE-TEX), carpeting (i.e. ScotchguardTM), furniture, food packaging (i.e. popcorn bags), flooring (i.e. StainmasterTM), non-stick cookware (i.e. Teflon), stain/water resistant paint, and roofing materials. They were also used as surfactants in metal plating baths, shampoos, moisturizers, shaving cream, oil well surfactants, aqueous film forming foam (AFFF), and semiconductor baths. Additional applications of PFCs include use in rust inhibitors, starting materials for herbicides/pesticides, acid mist suppressants, aviation hydraulic fluids, and adhesives. (Tetra Tech 2014).
Short-term Preliminary Health Advisories (PHA) were developed by the USEPA for perfluorooctanesulfonic acid (PFOS) (0.2 micrograms per liter (pg/L)) and perfluorooctanoic acid (PFOA) (0.4 pg/L) to reduce potential exposure through drinking water (EPA 2009 and 2014). Currently, there are not PHAs for the remaining four PFCs (perfluorononanoic acid [PFNA], perfluorohexanesulfonic acid [PFHxS], perfluoroheptanoic acid [PFHpA] and perfluorobutanesulfonic acid [PFBS]) evaluated during this sudy.
PFCs (PFOA and PFOS) were identified in on-site and off-site wells in the vicinity of NAWC Area C during the five year review (Tetra Tech 2011). Sampling for PFCs was initiated at Shenandoah Woods in 2015 in support of property transfer (Resolution, 2015). Monitoring wells HN-107, HN-108, and HN109 were installed and soil samples collected from 23 March through 27 March 2015. Soil sample results were below the laboratory detection limits except for SB7 (PFOS 6.040 J pg/kg). The monitoring wells were sampled on 16 April 2015. Concentrations of PFOS and PFOA in the groundwater samples were below their respective EPA PHA in all monitoring wells sampled except PFOS in HN-1081. PFOS
1 April 2016
US00008270
RESOLUTION CONSULTANTS
Resolution Consultants A Jo in t Venture ofAECOM & EnSafe
510 Carnegie Center Princeton, New Jersey, 08540
detected in the groundwater samples collected from HN-1Q8I (0.236 pg/L) exceeded the PHA for PFOS (0.2 pg/L). Detectable concentrations of PFOS and PFOA were reported in all groundwater samples collected except in those obtained from HN-108S.
This additional investigation was initiated to further characterize the occurrence and concentrations of six PFCs: PFOA, PFOS, PFNA, PFHxS, PFHpA and PFBS in groundwater at Shenandoah Woods. Installation of monitoring wells was requested by the Pennsylvania Department of Environmental Protection to determine if PFCs are present in shallow groundwater and might be discharged by basement sump pumps if the area is redeveloped. A maximum depth for each well of 25 feet below ground surface (bgs) was proposed to account for the possible future use of basement sump pumps. The six PFCs were analyzed to be consistent with previous investigations. During this investigation, groundwater samples were collected from six monitoring wells with one blind duplicate. Groundwater data for PFOS and PFOA were compared to the PHAs. PFC sample locations are shown on Figure 1. Note that three dual-nested monitoring well pairs were installed in Shenandoah Woods during previous investigation activities performed in April 2015. These wells are also shown on Figure 1; but were not sampled during the July 2015 groundwater sampling event.
2.0 FIELD ACTIVITIES
Between 4 June and 12 June 2015, six monitoring wells were installed and developed at Shenandoah Woods (Site 5) to identify potential PFC impacts to shallow groundwater. The wells were sarhpled approximately two weeks later on 30 June and 1 July 2015.
Monitoring Well Installation
Monitoring well locations were selected in accessible areas within the residential portions of Shenandoah Woods. Well installation details are summarized below.
On 4 June 2015, a geophysical survey was performed by PULS, Inc. of Bethlehem, PA under Resolution oversight for utility clearance purposes in each of the six proposed well locations. On 8 June and 9 June 2015, the initial boreholes were advanced at the HN-110 to HN-115 locations (Figure 1). The boreholes were advanced by Raab Drilling of Perkasie, PA, a Pennsylvania licensed driller, using an air rotary drill rig, under oversight of a Resolution geologist. Based on previous investigations at the Site and discussions with the US EPA, the target depth for the monitoring wells was a maximum of 25 feet bgs. At each location, a 10-inch carbide hammer was used to advance borings to 25 feet bgs. Six flush mounted, two-inch diameter monitoring wells were completed at each location. Monitoring wells were constructed with two-inch polyvinyl chloride (PVC) 0.01-inch well screen and riser. The annular space was filled with Number 1 sand to two feet above the well screen. The monitoring well was sealed above the screen using bentonite slurry via pressure grout injection to 1-foot bgs. The well seal cured for 24 hours prior to surface completion of the well pad.
Monitoring wells were developed on 11 June and 12 June 2015. Soil cuttings and groundwater generated during drilling and well development purge water were containerized in drums. The drums were transported to the NAWC groundwater treatment plant where they were staged pending characterization and off-site disposal. Off site disposal was completed on 23 July 2015
Completed monitoring wells were surveyed in Pennsylvania South State Plane, UTM Zones 17 and 18, by R.L. Showalter & Associates of Chalfont, PA. A well construction table is provided as Table 1. Well locations are shown on Figure 1. Boring logs and well construction diagrams are included in Attachment 1.
2 April 2016
US00008271
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RESOLUTION CONSULTANTS
Resolution Consultants A Jo in t Venture ofAECOM & EnSafe
510 Carnegie Center Princeton, New Jersey, 08540
Groundwater Sampling
On 30 June and 1 July 2015, monitoring wells were gauged and sampled in accordance with US EPA
Region 1 Low-Stress Sampling Guidance (EPA 2010). Precautions were taken to avoid sample
contamination and/or bias during collection per the draft Sampling and Analysis Plan (SAP) (Battelle,
2015). Products containing Teflon were not used during sample collection, handling, or transportation.
Sampling personnel did not use any waterproof items, wore only well-laundered clothing, and attempted
to identify and isolate any potential PFC-containing materials that might cross-contaminate groundwater
samples.
.
During gauging, depth to groundwater was measured above the well screens in three of the six monitoring wells (HN-111, HN-114, and HN-115). Groundwater was encountered during drilling at 21 feet bgs in HN-110, 24.5 feet bgs in HN-111, 22 feet bgs in HN-112, 18 feet bgs in HN-114, and 22 feet bgs in HN-115. Water was not encountered in HN-113 during drilling. Well screen intervals were proposed from 15 to 25 feet bgs to coincide with the depths of sump pumps that may be installed in basements if/when the land is redeveloped. Monitoring well screens were set from 15 to 25 feet based on the depths of water encountered during drilling; however, water levels rose after well installation. During drilling, weathered bedrock was noted through the entire boring column to 25 feet bgs. The depth of weathered bedrock is consistent with a geophysical investigation designed to investigate bedrock water-bearing fractures beneath the site at Area C (U.S. Geological Survey 2008). Area C was divided by the U.S. Geological Survey into shallow and deep hydrogeologic units. The shallow unit is comprised of sandstone. The deep hydrogeologic unit is defined as water-bearing bedrock beneath the shallow hydrogeologic unit, and typically exhibits artesian conditions (Batelle 2015). Consistent with shallow hydrogeologic conditions at Area C, boring data from monitoring wells HN-110 through 115 does not suggest confined or semi confined conditions.
Groundwater was purged using dedicated, high-density, polyethylene tubing that was discarded after each sample was collected. Groundwater was extracted using a stainless steel submersible pump that was decontaminated before each use with distilled water and Alconox detergent. Monitoring wells were purged continuously until water quality parameters (pH, conductivity, dissolved oxygen, and turbidity) stabilized. Once parameters stabilized, groundwater samples were collected for analysis in clean, laboratory-supplied, PFC-free, high-density polyethylene bottles. A blind duplicate and a field blank were collected using laboratory-certified, PFC-free, deionized water. Matrix spike and matrix spike duplicate samples were collected and analyzed at a rate of one per 20 samples. Samples were packaged with ice in a cooler, and shipped via laboratory courier under chain-of-custody to Accutest Laboratories of Orlando, Florida (Attachment 2). Samples were analyzed for PFCs using EPA Method 537 modified for environmental media. Data validation was completed by the Resolution Project Chemist. The data were found to be valid as reported and suitable for decision-making purposes. The data validation report is provided in this document as Attachment 3.
3.0 RESULTS
Detectable concentrations of PFOS were reported in all groundwater samples collected on 30 June and 1 July 2015 and PFOA was detected in all samples except HN-112 and HN-113. However, concentrations of PFOS and PFOA in the groundwater samples were below their respective EPA PHA's in all monitoring wells sampled.
Where they were detected, concentrations of PFOS were higher than PFOA in all samples. The highest concentration of PFOS was detected in monitoring well HN-110 (0.127 jjg/L). The most common detection of the four additional analyzed PFCs without PHAs was PFHxS, which was reported in all of the groundwater samples. The highest concentration of PFHxS was detected in monitoring well HN-110
3 April 2016
US00008272
RESOLUTION CONSULTANTS
Resolution Consultants A J o in t Venture ofAECOM & EnSafe
510 Carnegie Center Princeton, New Jersey, 08540
(0.0475 |jg/L). The concentrations of all analytes were below their respective detection limits in the field blank collected during the monitoring well sampling. Analytical results from the groundwater investigation are summarized in Table 2.
4 April 2016
US00008273
RESOLUTION CONSULTANTS
Resolution Consultants A J o in t Venture ofAECOM & EnSafe
510 Carnegie Center Princeton, New Jersey, 08540
4.0 REFERENCES
Battelle. 2015. Final Sampling and Analysis (SAP) Plan. October.
Department of Defense (DOD). 2011. Internal Navy Correspondence on Perfluorinated Compounds Clarification.
Naval Facilities Engineering Command (NFEC). 2000. Record of Decision for OU-10 (Site 5 Soil and Area B Surface Water/Sediment) at NAWC Warminster.
Resolution. 2015. Technical Memorandum Perfluorinated Compounds Soil and Groundwater Investigation, Shenandoah Woods Housing Complex, Naval Air Warfare Center, Warminster, Pennsylvania.
Tetra Tech. 2014. Evaluation of Potential Sources of Perfluorinated Compounds, Former Naval Warfare Center Warminster, Pennsylvania.
-- 2011. Third Five-Year Report, Former Naval Air Warfare Center, Warminster, Pennsylvania.
United States Environmental Protection Agency (US EPA). 2009. Provisional Health Advisories for Periluorooctanoic Acid (PFOA) and Perfluorooctane Sulfonate (PFOS).
-- 2010. Region I. Low Stress (low flow) Purging and Sampling Procedure for the Collection of Groundwater Samples from Monitoring Wells. i
-- 2014. Emerging Contaminants - Perfluorooctane Sulfonate (PFOS) and Perfluorooctanoic Acid (PFOA) Fact Sheet.
United States Geological Survey (USGS). 2008. Interpretation of Borehole Geophysical Logs at Area C, Former Naval Air Warfare Center, Warminster Township, Bucks County, Pennsylvania, 2007. Open-File Report 2008-1207.
5 April 2016 US00008274
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Notes: PFOS/PFOA results reported in micrograms per liter (pg/L) PFOS - Perfluorooctanesulfonic acid. PFOA - Perfluorooctanoic acid J - Estimated Concentration U - Indicates not detected above reporting detection limit ft-F ee t
USE PA Preliminary Health Advisory le v e ls PFOS - 0.2 pg/L. PFOA - 0.4 pg/L
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FIGURE 1 GROUNDWATER RESULTS
JULY 2015
SHENANDOAH WOODS NAWC WARMINSTER
BUCKS COUNTY, PENNSYLVANIA
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Table 1 Well Construction Summary
NAWC Warminster
Well
HN-110 HN-111 HN-112 HN-113 HN-114 HN-115
Total Depth (ft bgs) 25 .25 25 25 25 25
Screened interval (ft bgs) 15-25 15-25 15-25 15-25 15-25 15-25
Elevation (ft amsl)
361.74 355.38 364.34 367.13 348.46 352.43
ft bgs feet below ground surface ft amsl feet above mean sea level Survey completed by Showalter and Associates Coordinate System: PA State Plane Southeast, US Feet
Well Type Flush Flush Flush Flush Flush Flush
Installed 6/8/2015 6/8/2015 6/9/2015 6/9/2015 6/9/2015 6/9/2015
Table 2 PFC Investigation - July 2015 Validated Results Summary NAWC Warminster - Shenandoah Woods
Chemical Name
Perfluorobutanesulfonic Acid (PFBS) Perfluoroheptanoic Acid (PFHpA) Perfluorohexanesulfonic Acid (PFHxS) Perfluorononanoic Acid (PFNA) Perfluorooctanesulfonic Acid (PFOS) Perfluorooctanoic Acid (PFOA)
CAS
375-73-5 375-85-9 355-46-4 375-95-1 1763-23-1 335-67-1
Sample ID HN-110_06302015 HN-111_07012015 HN-112_07012015 HN-113_07012015 HN-114_07012015 DUP-070115 HN-115_07012015 FB-07012015
Location
HN-110
HN-111
HN-112
HN-113
HN-114
HN-115
HN-115
Screen Interval
15-25
15-25
15-25
15-25
15-25
15-25
15-25
15-25
Sample Date 6/30/2015
7/1/2015
7/1/2015
7/1/2015
7/1/2015
7/1/2015
7/1/2015
7/1/2015
Sampled Delivery Group FA25785
FA25785
FA25785
FA25785
FA25785
FA25785
FA25785
FA25785
EPA Health
Units
Advisory Level
Ud/L
NA
< 0.015 U
< 0.015 U
< 0.017 U
< 0.016 U
< 0.016 U
< 0.015 U
< 0.016 U
< 0.015 U
pq/L
NA
0.0293
< 0.015 U
< 0.017 U
< 0.016 U
< 0.016 U
< 0.015 U
< 0.016 U
< 0.015 U
pg/L
NA
0.0475
0.0254
0.0291
0.0165 J
0.0282
0.0401
0.0416
< 0.015 U
pq/L
pg/L pq/L
NA
i 0.2
! = 0 .4
0.0132 J 0.127
0.0210 J
< 0.015 U 0.0508 0.0245 J
< 0.017 U 0.0449
< 0.033 U
< 0,016 U 0.0619
< 0.032 U
< 0.016 U 0.0745 0.0231 J
< 0.015 U 0.104
0.0194 J
< 0.016 U 0.110
0.0199 J
< 0.015 U < 0.015 U < 0.031 U
Notes: CAS Chemical Abstracts Service Number U indicates not detected above reporting detection limit J indicates estimate value EPA Environmental Protection Agency Gray shading indicate exceedance of EPA Health Advisory Level pg/L micrograms per liter Screen Interval is expressed in feet below ground surface
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Prepared in accordance with:
Engineering Geology Field Manual. 2nd Edition. D2487 Practice for Classification of Soils (USCS). D2488 Practice for Description and Identification of Soils (Visual Manual Procedure). CalTrans Soil and Rock Logging, Classification, and Presentation Manual 2010 Edition
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6 in. Screen:
6/8/2015 Depth of Borinq:
6/12/2015 Water Level:
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Description Cleared to 5 ft, bgs. via vacuum truck and air knife. Unimproved surface. 0 to 5 ft. bgs.: CLAYEY SILT (ML); variegated brown, light brown, strong brown; some gravel, angular; dense; stiff; nonplastic to slightly plastic; dry. FILL to
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6/12/2015 W ater Level:
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= <5
0.01 in. slotted screen-
Sitt 22 ft. bgs.: Same as above; cuttings return as nonplastic fines with some evidence of
stone water. Yield = 3 to 5 gallons removed at 22 ft. bgs. after 10 minutes.
-Sr
#1 Sand
25 ft. bgs.: SILTSTONE (Stockton Fm.j; strong red; soft drilling; fractured; weathered; micaceous; dry.________________________________________________________
TO: 25 ft. bgs.
PID Photoionization detector
USCS Unified soil classification system ppm Parts per million ft. Feet bgs. Below ground surface PVC Polyvinyl chloride in. Inches TD Total depth_____ ;_____________
ML Sift
gpm Gallons per minute Fm. Formation SS Sandstone TOC Top of casing GS Ground surface
Prepared in accordance with:
Engineering Geology Field Manual, 2nd Edition. D248T Practice for Classification of Soils (USCS). D2488 Practice for Description and Identification of Soils (VisualManual Procedure). CalTrans Soil and Rock Logging, Classification, and Presentation Manual 2010 Edition
US00008290
o
D O D O O O O O D O O O Q O O O
O
US00008291
0 0
0 0
D
0 0 0 0 0
D D
0
G
0 0
a
D
Location Sketch
Client: Department of the Navy
North
^H N-113
unit 592 | Weather:
/ * Project Number:
60276503
a
Site Location;
NAW C Warminster, Pennsylvania
M
s
Coordinates;
326399.288
275638.680
TO C Elevation:
I 0 Drilling Method; Sample Type(s):
Air Rotary/Percussion none
Boring Diameter:
Clear 80's F
Logged By: G. Richards Start Date:
Drilling Contractor
RAAB (Rick Raab)
GS Elevation: 367.51 Date Complete:
Borin9: HN-113
367.13
Sheet:
Well Installed:
6 in. Screen:
6/8/2015 Depth of Boring:
6/12/2015 W ater Level:
2 of 2 Single riser
15-25 25
Not observed
e
Q.
Q. E
O
s
o
& CD
21. 22 . 23 _
24. 25. 26 .
27
28 . 29 . 30 . 31 .
32. 33.
Q
O w
CL 3
Siltstone
Description
I <= o
i'l
il
(D CO
oO
0.01 in.
slotted
O~ -- <o
is
# 1 Sand
25 It. bgs.: SILTSTONE (Stockton Fm.); strong red; easy drilling; soft to medium hard;
0.0 weathered; micaceous; trace quartz; oxidized iron; dry._________________________
TD: 25 ft. bgs.
34 . 35. 36 . 37
38.
39 .
40 Legend:
Air rotary/ percussion V 7 First observed Y groundwater
PID Pbotoionization detector
USCS Unified soil classification system ppm Parts per million ft. Feet bgs. Below ground surface PVC Polyvinyl chloride in. inches TD Total depth__________________
CL Clay
ML S ilt Fm. Formation TOC Top of GS Ground surface
Prepared In accordance with:
Engineering Geology Field Manual, 2nd Edition. D2487 Practice for Classification of Soils (USCS). D2488 Practice for Description and Identification of Soils (Visual Manual Procedure). CalTrans Soil and Rock Logging, Classification, and Presentation Manual 2010 Edition
US00008292
o o
D
O
0
D
O
Locdtion Sketch
North
Unit 624
Client: Department of the Navy
Project Number:
60276503
Boring: HN-114
<S> HN-114
Unit 621 Unit 623 Unit 625
Site Location:
NAWC Warminster, Pennsylvania
1 Coordinates: 325936.005 2752652.069
Q
C Drilling Method:
Air Rotary/Percussion
o8 Sample Type(s):
none
TOC Elevation: 348.46 Boring Diameter:
Sheet: Well Installed: 6 in. Screen:
1 of 2 Single riser
15-25
Weather:
Clear 80's F
Logged By: G. Richards Start Date:
6/8/2015 Depth of Boring:
25
Drilling Contractor: RAAB (Rick Raab)
GS Elevation: 348.77 Date Complete:
6/9/2015 Water Level:
18
Description
Cleared to 5 ft. bgs. via vacuum truck and air knife. Unimproved surface.
C '3
3 ?y
to .h (0 O2 CO
Concrete
0)
Q.
E
8--*aj
O
0 to 5 ft. bgs: SANDY SILT (ML); light brown and brown; silt (70%); very fine sand (25%); trace clays; trace cobbles (up to 6 in.), sandstone, weathered, hard, micaceous; nonplastic; grading to silty very fine sand; dry.
u
r=f
D
O
D O
Q
O
O
O O O
8 ft. bgs.: SILTSTONE (STOCKTON Fm.); red; hard; micaceous; dry.
=t
r=r
2 in. PVC riser
?r PR
11 ft. bgs.: SANDSTONE (Stockton Fm.); yellowish-tan; hard; moderately weathered; fractured; wet.
r=r T 5 s
13 ft.
15 ft. bgs.: SILTSTONE/MUDSTONE (Stockton Fm.); red; micaceous; dry.
0.01 in. slottascreen
#1 Sand
17.5 ft. bgs.:SANDSTONE (STOCKTON Fm,); yellowish-tan-brown; micaceous; medium soft.
19 ft. bgs.: SILTSTONE (Stockton Fm.); red to strong brown; wet.
- -
US00008293
0
0
0
D
0
D
0 0 0
D D
0 0
D
0 0 0 0
Location Sketch
Client: Department of the Navy
North
I Unit 624
Project Number:
60276503
Site Location:
NAW C Warminster, Pennsylvania
MN-114 Unit $21 I Unit 6231 Unit 625
S Coordinates; 325936.005
2752652.069
D g
Drilling Method;
c O
Sample Type(s):
Air Rotary/Percussion none
Weather:
Clear 80's F
Logged By: G. Richards
TO C Elevation:
Boring Diameter: Start Date:
Drilling Contractor
RAAB (Rick Raab)
GS Elevation: 348.77 Date Complete:
Boring: HN-114
348.46
Sheet:
Well Installed:
6 in.
Screen:
6/8/2015 Depth of Boring:
6/12/2015 W ater Level:
2 of 2 Single riser
15-25 25 18
0 1
21
22 23 <
o 24,
25.
26
27
28 . 29
Description
$ oc
otS
g o. 3
Si IIW(0OO
om
20 ft. bgs.: SILTY SANDSTONE (Stockton Fm.); reddish to strong brown; micaceous; 0.01 in.
heavily oxidized; wet.
slotted
screen"
SS
#1 Sand
25 ft. bgs.: Same as above; wet. TD: 25 ft. bgs.
TD=25
30 .
31 . 32 .
33. 34. 35. 36.
37_
38.
39 _
40 Legend:
0 Air rotary/ percussion V 7 First observed Y groundwater
PiD Photoionization detector
USCS Unified soil classification system ppm Parts per million ft. Feet bgs. Below ground surface P V C Polyvinyl chloride in. inches TD Total depth__________________
ML Silt Fm. Formation TOC Top of GS Ground surface SS Sandstone
Prepared in accordance with:
Engineering Geology Field Manual, 2ndEdition. D2487 Practice for Classification of Soils (USCS). D2488 Practice for Description and Identification of Soils (VisualManual Procedure). CalTrans Soil and Rock Logging, Classification, and Presentation Manual 2010 Edition
US00008294
o
o iJsaaiLSki
Client: Department of the Navy
North
' Project Number:
60276503
B-g: HN-115
o &HN-115
Site Location:
NAWC Warminster, Pennsylvania
Coordinates: 326269.128
2752203.529
TOC Elevation: 352.43
Sheet:
1 of 2
Drilling Method:
Air Rotary/Percussion
Well Installed:
Single riser
Unit 595 Unit 597
Sample Type(s):
none
Boring Diameter
6 in. Screen:
o Weather:
Clear 80's F
Drilling Contractor: RAAB (Rick Raab)
Logged By: G. Richards Start Date: GS Elevation: 352.28 Date Complete:
6/8/2015 Depth of Boring: 6/12/2015 Water Level:
15-25 25 22
o Description
0) 5c
"ioS5 So3
03 Q.
Eo
o Cleared to 5 ft. bgs. via vacuum truck and air knife.
(0 3
^ 5 Concrete
O^ = 'ro o 'S 5Q
Unimproved surface.
o 0 to 5 ft. bgs: SANDY SILT (ML): light brown to strong brown; very fine sand; dense; well sorted; fragments of siltstone, dark red, hard; nonplastic; moist below 4 ft.
1 ft. H
r=f
D hydrated bentonite 3/8 in.
O
D 6 ft. bgs.: SILTSTONE (Stockton Fm.); red; soft; weathered; dry. 2 in. PVC riser
O
O 10 ft. bgs.: SILTSTONE (Stockton Fm.); red; medium hard; weathered; dry.
O Possibly thin interbeds of very fine, micaceous sandstone.
s a n ic i
O 13ft
15 ft.
O #1 Sand
O 0.01 in. slotted screen 20 ft. bgs.: Same as above; dry.
D
O
US00008295
o
o
0
o
o
o
o
O
O
O
o o
o o o o o
Location Sketch
Client: Department of the Navy
North
Project Number:
60276503
Site Location:
NAW C Warminster, Pennsylvania
&HN-115
Coordinates: 326269.128
2752203.529
TOC Elevation:
Drilling Method:
Air Rotary/Percussion
Unit 595 Unit 597 |
W eather
Clear 80's F
Sample Type(s):
none
Boring Diameter:
Logged By: G. Richards Start Date:
Drilling Contractor
RAAB (Rick Raab)
GS Elevation: 352.28 Date Complete:
B-g: HN-115
352.43
Sheet:
Well Installed:
6 in.
Screen:
6/8/2015 Depth of Boring:
6/12/2015 W ater Level:
2 of 2 Single riser
15-25 25 22
c
O
21 22 23 . 24 25. 26 27 . 28
Description
I
m
g Q. '
w13
<CzT>JoO
0.01 in. slotted screen"
O = 'ra
Silt-
22 ft. bgs: Same as above; cuttings return aggregated indicating water. Used air to
stone blow out boring. Slow infiltration.
-Sr
#1 Sand
25 ft. bgs.: SILTSTONE (Stockton Fm.); red; moderately bard; weathered; micaceous; dry.__________________________________________________________________
ID : 25 ft. bgs.
M a tt
TD=25
29 . 30 . 31 . 32 . 33.
34. 35. 36.
37
38 .
39 .
40 Legend:
^><Q Air rotary/ percussion
-3=First observed groundwater
PID Photoionization detector
USCS Unified soil classification system ppm Parts per million ft. Feet bgs. Below ground surface PVC Polyvinyl chloride in. inches TD Total depth___________________
ML Sift Fm. Formation TOC Top of GS Ground surface
Prepared in accordance with:
Engineering Geology Field Manual, 2nd Edition. D2487 Practice for Classification of Soils (USCS). D2488 Practice for Description and Identification of Soils (VisualManual Procedure). CalTrans Soil and Rock Logging, Classification, and Presentation Manual 2010 Edition
US00008296
US00008297
.0
o
D
0 0
D
0 ATTACHMENT 2
0 0
o
D D O O O O. O D O
US00008298
GROUNDWATER LOW-STRESS PURGE AND SAMPLING DATA
o Project Name: Project Location:
NAWC Warminster - Area B Warminster PA
Well Number:
/ D.
G PURGING AND SAMPLING DEVICE Pump Type and Model: SS monsoon
Project No.: Weather: Sampler
60276503
__ Date: 6/30/2015
Pedro Lopes and Geoff Richards
Decontamination Procedure: Alconox and clean water
O Tubing Diameter and Material: 3/8"x lA" poly WELL INFORMATION
Well1Previously Sampled:
Well Diameter (in.): 2"___________________
D Initial Depth to Water (ft., TOC): INDICATOR PARAMETER MONITORING
Depth to Bottom (ft., TOC): S S , f t ) Screened Interval (ft, bgs): 15-25 ft
Pump Set at Depth (ft., TOC):
jy .
D Time: e*Ptl Purge Rate (mL/min)^ 3 t f
f e o O clcC
O X 1
n a s * aS*
tfj't '
(OSS -tro n
iocsH
O Depth to W ater (ft.): Volume Purged (liters) 9
1*0% ^ 9 CH
H IG 1>
/S .*r
I t . lk 2C
Parameter and
is a s A L __
Stabilization Range*
D Temp. (C) pH '
3%
0 .l
HdQ .V -k
W
t%o<* H H H h Y 6 >
i^ .H c il- S o U w
ft. T *
tV -L u m 5
q . v i k m ... U . "H l H . 1 0 U til
SC (m mhos)
O sDO* (mg/L)
3%
10% if >l
. n o O 'M S B A \U G ,lt >t\$ -W S *
a .tf* 6.10= , n
U . u t 0 111 * n i o . t U 5 .^ 1 5 .V V 5 . IT
D /65ORP (mv) Turbidity (NTU)
I0 mv / 5
10%
jfc o o
*io c o
3H cl
)OO S f r
tn
Ic iS
1 -n
5 i.o i ib # m 3 T 2 . 4 iS .o
TST |i.o
O TDS $ / L Color/odor
none none
.O T T c .c T 'l CxeHe b-SH j. t
0 . 0 f< : o , m f 3 o .e T 3 .- T 'L . t A V Q o T ?
5 4 f V <6k\gf
c y < d i& s &&>.< Cr<x/
l
Time:
.>
O Purge Rate (mL/mln): Depth to W ater (ft.):
Parameter and
D Stabilization Range* pH (std units) 0 .l
O Conductivity (m mhos) Turbidity
3% 10%
(NTU)
O DO* (mg/L) Temp. (C)
10% N/A
ORP (mv)
IO mv
O * Stabilization requires three consecutive readings within the range indicated. Once the well is stabilized, the sample may be collected. DO is the key indicator parameter for VOC analyses; turbidity is the key indicator parameter for all other analyses.
Sample:
If/LHfQ Sample time:
O Comments/Analytes: y-c'1 kI i /Sbi 0f l
O
O
US00008299
0 0 0
D
0 0
D D
0 0 0
0
G
0
GROUNDWATER LOW-STRESS PURGE AND SAMPLING DATA
Project Name:
Project No,:
Date:
Project Location:
Weather:
Well Number:
jt f r l .
PURGING AND SAMPLING DEVICE
Sampler:
Pump Type and Model: _____________
Decontamination Procedure:
Tubing Diameter and Material: ________________________ Well Previously Sampled: _
WELL INFORMATION
Well Diameter (in.): _________________________________ Depth to Bottom (ft., TOC):
Initial Depth to Water (ft., TOC): ______________________ Screened Interval (ft., bgs):
INDICATOR PARAMETER MONITORING
Pump Set at Depth (ft, TOC):
Time: 1 * * 9 fcQ -
10^6
Purge Rate (mL/min): ? d J c
te s o 7:x4a
Depth to W ater (ft.):
Volume Purged (liters) 'U < > Parameter and
Stabilization Range*
(te * * l f a . s
tt '
Temp. (C) pH SC (m mhos)
DO* (mg/L)
3%
0.1 3% 10 % if >1
2 *3 * w S './
x liC * M
/W .H n /tf
M f,*1 C t a .U S
W ,\S
ORP (mv) Turbidity (NTU)
TDS ^ L Color/odor
10 mv 10%
none none
Time:
^ is r O .efH
on W C ie xc
2>l 2 S
tr a
Purge Rate (mL/min):
Depth to W ater (ft.):
Param eter and Stabilization Range*
pH (std units) 0.1
Conductivity (m mhos)
3%
Turbidity (NTU)
10%
DO* (mg/L) 10 %
Temp. (C) N/A
ORP (mv)
10 mv
* Stabilization requires three consecutive readings within the range indicated. Once the well is stabilized, the sample may be collected. DO is the key indicator parameter for VOC analyses; turbidity is the key indicator parameter for all other analyses.
Sample:
Sample time:
________________________________________________ .________
Comments/Analytes:
_____________
fa irs *#
X/tsl
y jty f
<r
h L ir -
US00008300
GROUNDWATER LOW-STRESS PURGE AND SAMPLING DATA
Project Name: Project Location: Well Number:
NAWC Warminster --Area B Warminster PA___________
/ / V ? / - ) l j __________
Project No,: Weather: Sampler:
60276503
Date:
fZ ^
----------
Pedro Lopes and Geoff Richards____________
PURGING AND SAMPLING DEVICE Pump Type and Model: SS monsoon__________________ Decontamination Procedure: Tubing Diameter and Material: 3/8"x 14" poly___________ Well Previously Sampled:
Alconox and clean water
Imj
WELL INFORMATION
Well Diameter (in.): 2"______________________________ Depth to Bottom (ft,, TOC):
Initial Depth to Water (ft., TOC): j$ M Q ______ , Screened Interval (ft., bgs): 15-25 ft
INDICATOR PARAMETER MONITORING
Pump Set at Depth (ft., TOC): ^
Time: /Jk |T
Purge Rate (mL/min):
fo cf &\\Q o l i r CMlC
Q??Q-
mx
Tfo
>^ts
^in>'
Depth to W ater (ft.): Volume Purged (liters)
Parameter and
(HM*
HM} 14,4} \H 4 } im m * i W
iH-1? m i
t.o 3.
\ktO_
TL0 7/Y& .l _ 1
Stabilization Range*
Mv
_....
Temp. ("C)
3% i i s i m
I t H \1 -&
iH-Xf IM,M a ji \iS k .
pH 0.1
SC (m mhos) 3%
w `f
44*
H.Vj 4*H ,
1 , n $ . l e i . lite .140 A A^L
4 e>\ A H 4) m i-
DO* (mg/L)
10% if >1
>
III
l?> l , 61
ORP (mv)
10 mv \
2o% !>\% 3 )4 77.4 m s ,?t/
Turbidity (NTU)
10% ^ lo )
t o f t m x n * n-'b
x r CM
TDS
' Color/odor
none none
l J
0.1%\
W
m
. UD . ids .\Ol .OI . 1 0 0 tb^ . 0 ^
tPcOaV CWiXf4
cM tj Cktr
Time:
Purge Rate (mL/min):
Depth to W ater (ft):
Parameter and Stabilization Range*
pH (std units) 0.1
Conductivity (m mhos)
3%
Turbidity (NTU)
10%
DO* (mg/L) 10 %
Temp. (C) N/A
ORP (mv)
10 mv
* Stabilization requires three consecutive readings within the range indicated. Once the well is stabilized, the sample may be collected. DO is the key indicator parameter for VOC analyses; turbidity is the key indicator parameter for all other analyses.
Sample:
* ^ n p l e time: H 'V 'i i l
Comments/Analytes:
____________
US00008301
GROUNDWATER LOW-STRESS PURGE AND SAMPLING DATA
Project Name:
NAWC Warminster - Area B
Project No.: 60276503
Date: -6/30/20te-
Project Location: Warminster PA
Well Number:
. h i S z J Ix k -
PURGING AND SAMPLING DEVICE
Weather: Sampler:
.` ^ 1 Pedro Lopes and Geoff Richards
Pump Type and Model: SS monsoon
Decontamination Procedure: Alconox and clean water
Tubing Diameter and Material:: 3/8"x f% poly
Well Previously Sampled:
WELL INFORMATION
Well Diameter (in.): 2"
Depth to Bottom (ft., TOC):
Initial Depth to Water (ft,, TOC):
Screened Interval (ft., bgs): 15-25 ft
INDICATOR PARAMETER MONITORING
Pump Set at Depth (ft., TOC):
4~ -IH ", Iti. M ftU l n *
Time:
^5
U* 61bo
Purge Rate (mL/min): S%j) /50 tfO 9H HvU
oWO JaO
oiG
i&c-e
toK /4c>
4<
'<tyo
Depth to Water (fL): Volume Purged (liters)^
/;.4t n>r nv> 1 fn
L4-* fluiti /f.45 i^fi tl.V . A i . a* i 2 1 * as.5
Parameter and
Stabilization Range*
Temp. (C)
3% ,
/M3 /* IH.io f1x&tf.ds) H.'H* li-io /.A .<>4
JIM
pH SC (m mhos)
0.1
3%
sv A*?/7
Sit* Xai &rWl
.si s.a) 5.AO .10
.& <?.3o i . s u
H&T 6{&t OUT-~W6.17% o-MY 5,7(ML .T tfr
DO* (mg/L)
10 % if >1
to.&
6 .)1 &>& U S
iW| $.af SJ?-
fi
ORP (mv) Turbidity (NTU)
TDS Color/odor
10 mv /o3
m rtf rti m
m 3_ 1W ~
m Itr5
10% rfooD ^fooO\d<k t f itr ?ds
m l U l.5
I A . C .%
none Oot, 2O <sa/H atVT- o,m &ft a. o.3a*
.-Wf
.SUff-
none -c-d-w--K7
Time:
4Jt < Ue*i I
clctf <^r ie-r
Purge Rate (mL/min):
Depth to Water (ft.):
Parameter and Stabilization Range*
pH (std units) 0.1
Conductivity 3%
(m mhos)
Turbidity (NTU)
10%
<.
i
DO* (mg/L) 10 %
Temp. (C) N/A
ORP (mv)
10 mv
* Stabilization requires three consecutive readings within the range indicated. Once the well is stabilized, the sample may be
collected. DO is the key indicator parameter for VOC analyses; turbidity is the key indicator parameter for all other analyses.
Sample: : M H f i L Comments/Analytes:
`P fW:A^rr Z)
Sample time: TkuXV.
vrrlf fa r
a z~ ^ U v fU r\u > f r
.Mejyh&ifa 4:, uu LailjJviMha. ai&hdL, } .aLaothtj.
,v>M \ l
US00008302
GROUNDWATER LOW-STRESS PURGE AND SAMPLING DATA
Project Name: NAWC Warminster--Area B
Project Location: Warminster PA___________
Well Number:
f - j m - _________
PURGING AND SAMPLING DEVICE
Pump Type and Model: SS monsoon_______ _
. Tubing Diameter and Material: 3/8"x `/T* poly
Project No.: Weather: Sampler:
60276503________ Date:
|
f _______________ Pedro Lopes and Geoff Richards__________
Decontamination Procedure: Alconox and clean water
Well Previously Sampled:
4m- in____
WELL INFORMATION Well Diameter (in.): /F___________________ Initial Depth to Water (ft., TOC):
Depth to Bottom (ft., TOC): _______2 5 * Screened Interval (ft., bgs): 15-25 ft_____
INDICATOR PARAMETER MONITORING
Pump Set at Depth (ft., TOC):
*2.3 '
Time: 106 0 IAo S" loto 1Ni3T Ib Z c ibLT
Purge Rate (mL/min):
~ -\bo
Depth to Water (ft.): TjO.^o
2 l 7,1JTt l\& >
Volume Purged (liters) GO
Parameter and Stabilization Range*
5 . 0 |. L&
to 3o
ib*io io wi' IPSO.. i o s r
6 A-30* ''ion ^ 3 6 0 *?oo
<u A u A U A k j<\ M A
14.0
7 N .a >1 4 .0
Temp. CC) pH SC (mmhos)
DO* (mg/L)
ORP (mv) Turbidity (NTU) TDS Color/odor
3% lL Jb\ 0.1 3%
1^ IN.tit i .^ t
iH .W
j m [Lj& 1U I _ 11.Aft.
M .n
A J i - S . I L U X . aq,,!.&7j<JS>L5MrV S.3H.. 2L
1 *7
,t^W
.1 ./
`V s h - .15 %a~. i s H -
10%
if >1 H > S t
S,hl
jT.f
5JH-
4 Nb
10mv 10%
I" t t y l t5 \ I T O
m V l>3
^ l i 3 5 U*t>
34,i f r i
I ti. L ^ i_ _
none .I}*, - Y f r . 17,$* t\V L s i l l
- l i t J l f e tfl?
. \ D > .160
none TA10 '
TfSfO
Clfjv/ (A<** cl&r
MlX- tltv CletKf
Time:
Purge Rate (mL/min):
Depth to Water (ft):
Parameter and Stabilization Range*
pH (std units) 0.1
Conductivity (m mhos)
3%
Turbidity
10%
(NTU)
DO* (mg/L) 10%
Temp. (C) N/A
ORP (mv) 10mv
* Stabilization requires three consecutive readings within the range indicated. Once the well is stabilized, the sample may be collected. DO is the key indicator parameter for VOC analyses; turbidityis the key indicator parameter for all other analyses.
Sample:
D & - U 3 Sample time: tt GO
Comments/Analytes:
_________
US00008303
GROUNDWATER LOW-STRESS PURGE AND SAMPLING DATA
Project Name;
f/A w c
Project No.:
_____ Date: y j j J j
Project Location:
Weather:
a r ^ ______________________
VVell Number:
M i\ J - ) i *~f...................... I JI Mi.............. ..il l
.....................
PURGING AND SAMPLING DEVICE
Sampler:
<gr; ____________________________
Pump Type and Model: < T ^ t^ ^ e - c vn_____________ Decontamination Procedure:
t^ U r-
Tubing Diameter and Material:
'< %/t$ * rT W _______ Well Previously Sampled: h ft^J - 11 <K_____________
WELL INFORMATION
Well Diameter (in.): ___________ 3 (_________________ Depth to Bottom (ft., TOC):
Initial Depth to Water (ft., TOC): * 9 . ^ 3 I r 4 " _______ Screened Interval (ft., bgs):
N-
INDICATOR PARAMETER MONITORING
Pump Set at Depth (ft., TOC): _ t Q
Time:
5 r------
to n s /*( > W S / t o o / / / O f t Sto h 3o
ItS o
/ . V o Ai/>
Purge Rate (mL/min):
3S n o
o S i O& a^-6 Stf'C' /c>o 4&e> # o O
Depth to W ater (ft.):
Volume Purged (liters) Parameter and
Stabilization Range*
`i . y t a
.43L 3. if
'h s ft>
cl'4 C 5 ^ . /*
* i (S
M L
3 Ci 3 L 3 (,
Temp. (UC) pH SC (m mhos)
DO* (mg/L)
3%
0.1 3% 10% if >1
/ y
/
V i t e r i f . Jo ti.T C l - Pc
C .oi / I 3 4 , 4 a fr i ve
o .M
H .V i H 3 T - ^ .3 4 H 3 W .ff
ik 2 L ff. ll
<.^3
4 .4 /
/*?<? -J M . f t j j j g .
H. Fi
OR? (mv)
10 mv
/la
Sc* 3 9 c
* * lf
3*37
Turbidity (NTU)
10%
/
3 HS-
i f
fe d /
-3*3.3 3 ^ . ?
TDS Color/odor
none none
Time:
/
O 'W k.AsS
t*M3i A P C c ie e C ^uC
o . 3 , {/* M /S o, liS. c m i* e u 3
J ti.r /za-T tS **" - 4 / f *
MiQ--
Purge Rate (mL/min):
Depth to W ater (ft.):
Parameter and Stabilization Range*
pH (std units) 0.1
Conductivity (m mhos)
3%
Turbidity (NTU)
10%
DO* (mg/L) 10%
Temp. (C) N/A
ORP (mv)
10 mv
* Stabilization requires three consecutive readings within the range indicated. Once the well is stabilized, the sample may be collected. DO is the key indicator parameter for VOC analyses; turbidity is the key indicator parameter for all other analyses.
Sample:
y y - t Sample time:
j 'p j__________
Comments/Analytes:
^ `jU )W .kk. r w . L . j v
U /iW
iiA r ) .
iM G - 7 Cs^c-vet) k'bSrTj *r.P l^ k S ^ -iA/y^U Csif
y I_________________________
US00008304
GROUNDWATER LOW-STRESS PURGE AND SAMPLING DATA
Project Name:
NAWC Warminster - Area B
Project Location: Warminster PA_____________
W ell Number:
f-{A3-- 1IS _______
PURGING AND SAMPLING DEVICE
'
Pump Type and Model: SS monsoon__________
Tubing Diameter and Material: 3/8"x 'A" poly
Project No.: Weather: Sampler:
60276503
Date: 6/30/30*6 1 - 1 |< T
Pedro Lopes and G eoff Richards
Decontamination Procedure: Alconox and clean water
Well Previously Sampled:
14 A3 -- ( 1* \
WELL INFORMATION Well Diameter (in.): 2"_______________________
Depth to Bottom (ft., TOC): ______*2-S-
Initial Depth to Water (ft., TOC): _____( 0 , * M
Screened Interval (ft., bgs); 15-25 ft_________
INDICATOR PARAMETER MONITORING
Pump Set at Depth (ft., TOC):
2 .0 '
Time:
- f/ m n o i f l f O /7 .l5 * \ T l O i n i I l 3 d | 2 3 i i7Mo m i \l% o. i i s r
Purge R ate (mL/min): ' o
''tylA ^ \o n --
h-ko*
+>\6o
Depth to W ater (ft.): I .G 0
Volum e Purged (liters)
Parameter and Stabilization Range*
J
'L
lo .S H
(s? .n i6 .r z . *
/9.SX i * s \ \o X l
|o \ 3 AL
'
ma lo
I0SL J S Z lA iS a. V _ T-C. 0 . 3 ...
to . Vk
Temp. (C) pH SC (m mhos)
DO* (mg/L)
ORP (mv) Turbidity (NTU) TDS Color/odor
. 3% 0.1 3% 10% if >1 10 mv 10%
none none
Y i,U ,
r.i i 11, K f U t l It.H S H ..23 ji-L |0 n . n \a ,o o i j i M -
.q n
<-5C fi f i l S M O <TMH S M V S s o
.L M
.1 * 3 - \~V> .y v i .9-0 H .* f
- Hat _ |l| h .-(tn lg
s.1.3
? .% %H1
? ? 4 . o l N .4 >0 H d i h a
H `*1 i . B o
H l 2-\B 2 0 % - U > \ l u t a u 1AS 0 3
Z l l Z -lft Z \ % H *\
-or
1 *>> U O \ O o o I I ? ' 17-H . a i
TAU
8& S .u l TAA3 T** v A w
1 c i\ .|o 0
w h a \o > .I S
23A L 2 5 - 3 2fc.l .le*V o .\ 3
TVMU T * 0 CitA( CA**\< C itA C l * r
T im e:
Purge R ate (mL/min):
Depth to W ater (ft.):
Parameter and Stabilization Range*
pH (std units) 0. 1
Conductivity (m mhos)
3%
Turbidity (NTU)
10%
DO* (mg/L) 10%
Temp. (C)
N/A
ORP (mv)
10 mv
* Stabilization requires three consecutive readings within the range indicated. Once the w ell is stabilized, the sample may be collected. DO is the key indicator parameter for VOC analyses; turbidity is the key indicator parameter for all other analyses.
Sample:
U tn is
Comments/Analytes:
Sample time: ^ o o _____ ( ) / f SM S 4-
__ f iu Z - o W lt S " & / 2 o _____________________________________
US00008305
0
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Cd CID CD dD Cd Cd Cd Cd Cd Cd
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US00008307
US00008308
o.
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g ATTACHMENT 3
0
o o
o.
o o
G D D O G G
US00008309
LO]
RESOLUTION
CONSULTANTS
Resolution Consultants 250 Apollo Drive
Chelmsford, MA 01824
978.905.2100 978.905.2101
tel fax
D ata V alidation R ep ort
Project:
NAWC Warminster, PA
Laboratory:
Accutest Laboratories
Job Numbers:
FA25785
Analyses/Method:
PFCs by Liquid Chromatography/Mass Spectrometry/Mass Spectrometry (LC/MS/MS)/ EPA Method 537 modified
Validation Level:
Limited
Resolution Consultants 60276503, Shenandoah task Project Number:_____________________________
Prepared by:
Paula DiMattei/Resolution Consultants
Completed on:7/22/2015
Reviewed by:
Lori Herberich /Resolution Consultants
File Name: Warminster FA25785_PFCs
SUMMARY
The samples listed below were collected by Resolution Consultants from the NAWC Warminster, PA site on June 30 and July 1, 2015.
SDG
Sam ple ID`
Matrix/Sample Type
HN-110 _06302Q15
Groundwater
HN-111 _07012015
Groundwater
HN-112 J37012015
Groundwater
FA25785
HN-113 _07012Q15 HN-114 _Q7012015
Groundwater Groundwater
HN-115 _07012015
Groundwater
Dup-070115
Field duplicate of HN-115
FB-071215
Field Blank
` The date of sample collection was appended to the sample ID in the project database in order to maintain unique sample IDs.
Data validation activities were conducted with reference to:
Accutest Laboratories SOP: Analysis of Perfluorinated Alkyl Acids by LC/MS/MS; MS 014.1, Rev. Date: 05/14
USEPA Contract Laboratory Program National Functional Guidelines for Chlorinated Dioxin/Furan Data review (USEPA, September 2011);
USEPA Contract Laboratory Program National Functional Guidelines for Superfund Organic Methods Data Review (June 2008); and
Quality Systems Manual (QSM) for Environmental Laboratories, Version 4.2 (DoD, October 2010)
Resolution Consultants
2
In the absence of method-specific information, laboratory quality control (QC) limits, project-specific requirements and/or professional judgment were used as appropriate.
REVIEW ELEMENTS
The data were evaluated based on the following review elements (where applicable to the method):
/ Data completeness (chain-of-custody (CQC)/sample integrity / Holding times/sample preservation / Initial calibration/initial and continuing calibration verification / Laboratory method blanks/equipment blanks / Surrogate recoveries / Matrix spike (MS) and/or matrix spike duplicate (MSD) results / Laboratory control sample (LCS) results / Field duplicate results / Internal standard results / Sample results/reporting issues
The symbol ( / ) indicates that no validation qualifiers were applied based on this parameter. An NA indicates that the parameter was not included as part of this data set or was not applicable to this validation and therefore not reviewed. The symbol ( X ) indicates that a QC nonconformance resulted in the qualification of data. Any QC nonconformance that resulted in the qualification of data is discussed below. In addition, nonconformances or other issues that were noted during validation, but did not result in qualification of data, may be discussed for informational purposes only.
The data appear valid as reported and may be used for decision making purposes. Qualification of the data was not required.
RESULTS
Data Completeness/Sample Integrity
The data package was reviewed and found to meet acceptance criteria for completeness:
The COCs were reviewed for completeness of information relevant to the samples and requested analyses, and for signatures indicating transfer of sample custody.
The laboratory sample login sheet(s) were reviewed for issues potentially affecting sample integrity, including the condition of sample containers upon receipt at the laboratory.
Completeness of analyses was verified by comparing the reported results to the COC requests.
US00008311
Resolution Consultants
3
Holding Tiroes/Sample Preservation
Sample preservation and preparation/analysis holding times were reviewed for conformance with the QC acceptance criteria. All QC acceptance criteria were met or qualification of the data was not required.
Initial Calibration/lnitial and Continuing Calibration Verification
Calibration data were reviewed for conformance with the QC acceptance criteria to ensure that:
the initial calibration (ICAL) percent relative standard deviation (%RSD) or correlation coefficient (r)/coefficient of determination (r2) method acceptance criteria were met;
the initial calibration verification standard (ICV) percent recovery acceptance criteria were met; and
the continuing calibration verification standard (CCV) frequency and method percent recovery criteria were met.
The QC acceptance criteria were met.
Laboratory Method Blanks/Eguipment Blanks
Laboratory method blanks and field blanks are evaluated as to whether there are contaminants detected above the detection limit (DL). Target compounds were not detected in the laboratory method'blank or field blank [FB-07012015] associated with the samples in this data set.
Surrogate Recoveries
The surrogate recoveries (%Rs) were reviewed for conformance with the QC acceptance criteria. All QC acceptance criteria were met or qualification of the data was not required.
MS/MSD Results
The MS/MSD %Rs and relative percent differences (RPDs) were reviewed for conformance with the QC acceptance criteria. All QC acceptance criteria were met.
LCS Results
The LCS %Rs were reviewed for conformance. All QC acceptance criteria were met.
Field Duplicate Results
Field duplicate RPDs were reviewed for conformance with th Resolution Consultants QC criteria of <30% for aqueous matrices. These criteria apply if both results were greater than five times the limit of quantitation (LOQ). All field duplicate precision criteria were met.
Internal Standard Results
The internal standard (IS) results were reviewed for conformance with the QC acceptance criteria. All QC acceptance criteria were met.
US00008312
Resolution Consultants
4
Sample Results/Reportinq Issues
.
If applicable, compounds detected at concentrations less than the limit of quantitation (LOQ) but greater than the detection limit (DL) were qualified by the laboratory as estimated (J). This "J" qualifier was retained during data validation,
QUALIFICATION ACTIONS Qualification of the sample data was not required.
US00008313