Document zzwRd6558BK3L4n6LE2jDBGx7
LOUISIANA DIVISION INDUSTRIAL. HYGIENE REPORT AN OPERATING UNIT OP THE DOW CHEMICAL COUP'AN Y SOLVENT S/EDC1 INDUSTRIAL HYGIENE ACTIVITY REPORT -- 1907
DEPARTMENT
PILE NUMBER
DATE
SOLVENTS/EDCi
LAD - SOI..V/EDC - 07.01
6-03-00
AUIIIOR
S I' jITAT URL
MICHAEL 5. BROWN
REV I EWER'S
SIGNATURE
WILLIAM E. LEDFORD
BRUCE A. IIEJNZE
_________ ____________
SUMMARY OF 1907
PERSONNEL MONITORING WAS CONDUCTED ON 14 DOW OPERATIONS PERSONNEL AND ON 1 CONTRACT MAINTENANCE PERSONNEL. ALSO INCLUDED IN THE SURVEY ARE SAMPLES FROM 1> AREAS WIT IT POTENTIAL EXPOSURE PROBLEMS. SAMPLING IN 1907 COI ICEI-N RAT PL- ON POTENTIAL SHORT TERM EXPOSURES THAT OCCUR DURING PRODUCT LOADING PROCEDURE'S A!'D DUPING PROCESS SAMPLING ROUNDS.
THE SAMPLING CONSISTS OF TWO PH, ,5ES , PEL'S AND HEXES, AND THE APPROVED METHOD FOR EACH OF THESE WAS USED.,
ANALYSES ALSO CONFORMED TO APPROVED TECHMT VUES, SPECIFIC COMPOUNDS ANALYZED FOC -IN THE PEL SURVEY INCLUDE : CARBON TETRACHLORIDE, ETHYLENE BICHLORIDE, ETHYL.. CHLORIDE,, PEROHL. ORCTET IT YLF ! !E , PROPYLENE BICHLORIDE,, AND BETA-TRI (1,, .1,2 TT'.T Cl ILOROEl I lANE) . COMPOUNDS ANALYZED FOR IN THE HEX SURVL V WERE : HI' - ALT II i' ' ! 11 AT-IF , I IF XACI IL f iROBUT r .D11:: ME , Al ID HE XACHLROBi: U7EHE ..
ANALYSES I 'EPFORIIED SUPPORT HISTORICAL DATA THAT INDICATES THERE ARE WO UNIT'OWN EXPOSURE I 'I TUB LIZ MS . DATA DECO C0ME1RHS SOME ALREADY II 'oHi ' rWTLHTIAL EXPOSURE PROBLEMS.
ADDITIONALLY, AN ARE,-, noise SURVEY WAS CONDUCTED AND THE RESULTS WERE PRESENTED TO AL. I EMPLOYEES DURING THE SOLVENT S -'EDO 1 ANNUAL PE-NEW VF ME!. INDUCT I; I,-L Nr'.: II. I 'I. CONCERNS (TOXIC CHEMICAL REVIEW, CONSEQUENCES OF uVERE> POSURE, AND HEAR I NO CONSERVATION PROGIYAM ) .
GOALS FOR 1908 : 1, iNCOPPERAT1NO MORE EMPLOYEES INTO OUR PROGRAM. 0. A GREATER SAMPLING FREQUENCY.
0. PERSONNEL NOISE SURVEY. 4. FT SUITE HEX WIPE SAMPLING. 5. IMPROVING PERSONAL ANALYTICAL AND SAMPLING TECHM1HUES. 6. QUICKER RETURN TIME ON EXPOSURE ANALYSIS INFORMATION.
DIG[RIBUTION
LOUISIANA
J, W. SHIVELY -1601
RON GAST
-- 1601
CATHY BILELLO -1601
WAYNE MILLER -16V 1
*R. W. GALLANT --23V6
M. F. CURRIER -23' '6
stRAY GASKA
-3701
M. E. NEVIL.L --7 302- f_;
U-l, l-H BELL-
T -01 1
RES'TR1CTED r
MIDLAND
M. G. SWANK
-1E03
TL. W. RAtiPY
-1003
i O. W. ENGDAHL. -1003
SLR. D. OLdllN
-1803
>/ 0 . h. L..E [BEAU -JS-'C.
si: A. W. SCHAFFF.R -1003
slr. r. coqi-:
--1803
'T S . M. GO RCA CZ - 4 74
* COVER LETTER 01-11.Y FOR USE WITHIN THE DOW CHEMICAI.
FREEPORT *D. E. CRAGER
PITTSBURG 1F. D. AXE
STRONGSVILLE slG. L. liEIER
HvKTUA si A , F . POLLOCK COMPANY ONL'i'
DO 0 7 7 4 3 t>
CONFTDFNTTA
***1^^' LOUISIANA DIVISION INDUSTRIAL HYGIENE REPORT
*, 9
AN OPERATING UNIT OF THE DOW CHEMICAL COMPANY
i .sbi-VENTS/EDCl INDUSTRIAL HYGIENE ACTIVITY REPORT - 1987
DE PARTMENT
FILE NUMBER
DATE
| SOLVENTS/EDC 3.
|
i A LI !HUE
MICHAEL S. BROWN
LAD - SOLV/EDC - 87.01 SIGNATURE
6--03--88
| REVIEWER'S
SIGNATURE
WILLIAM E. LEDFORD j-iIruce a. heinze
4 SUMMARY OF 1987
PERSONNEL MONITORING WAS CONDUCTED ON 14 DOW OPERATIONS PERSONNEL AND ON 1
CONTRACT MAINTENANCE PERSONNEL.. ALSO INCLUDED IN THE SURVEY ARE SAMPLES FROM 10
AREAS WITH POTENTIAL EXPOSURE PROBLEMS. SAMPLING IN 1987 CONCENTRATED ON
POTENTIAL SHOE'! '"ERM EXPOSURES THAT OCCUR DURING PRODUCT." u-OADING PROCEDURE 8
AHP DUPING PROCESS SAMPLING ROUNDS. TUP S'-PPL ] MC-i CONSISTS OF TWO PHASES. PCX'S AND HEXES. AND THE APPROVED METHODS
rpr: each or these was used, ANALYSES ALSO CO'-FOEMED TO APPROVED TECHNIQUES. SPECIFIC COMPOUNDS ANALvZED
rfcP IN THE RCL SURVEY INCLUDE i CARBON T E T R. ft CHLORIDE, ETHYLENE DI CHLORIDE, cj~ HYL CHLCrUDF . FERiT'LGPC'ET lY-ER -!E . PROPYLENE DI CHLORIDE. AND BETA-TRI
;.? : .2 TPTCI !:..nrorU ' !v::T . COMPOUNDS analyzed for in the HEX SURVEY WERE :
HE X APH'. Of" SETHft Kir p s:',i . \i>
I IF X APT ILC'ROE'UT AD IENE . A! !E HEXACHLROBENZENE . 6ut:t:"T" hiruepical da'-a that indicates there are
HHNCW"'! - r_- -L, ; ; ::
T'-D'i"! V f
.i
''A1' s! ELENS . f ~ ; p1 r-; ;-
...
; i 0'EES
DATA ( '.GO COME I RMS SOME ALREADY KNOWN POTENT I ft
r1' n " .r
: CONDUCTED AND THE RESULTS HERE
DU"1 MG THE SOLVENTS/EDC 1 ANNUAL REVIEW OF ALL
T ATT"' T TOXIC CHE! J C.'... REVIEW;, CUhSEDUENEEE 0:"- IT.'ZF'E;
fiiO'XJRL, AND HEARING CONSERVATION PROGRAM). j
I l. ..NlORT:. ! TIC MOF:E EMPLOYEES into OUR PROGRAM. I r. GREATSR Stirling frequency.
I
F'F. 1R'J11
NOISE SUI'FL'Y.
! 4. RESUME XT >IF;: SAMPLING. I 3, ! 'TMKi -V) \'G -'E-.ADHAL ANALYTICAL AND SAMPLING TECHNIQUES.
I 6. QJIIOO-E RETURN TIME ON EXPOSURE ANALYSIS INFORMATION.
|
I LOUISIANA
Tf. W. SHIVELY -1601
IRON GAST
-1603
i'ZTH- BILELLC -C6L1
IWAYNE MILLER 16* >1
'if-:, W. GALLANT 0306
h. . CURRIER 23' -6
^PAY GP;SKA
3701
M. L. NEVILN 3S02-E
H. :-1. BE LI...
r;03-T
RESTRICT ED :
FDR
MIDLAND
m. g. swank
-ieo:
*L. W. RAMPY
-180:
W. ENGDAHL --IS 03
YE . D. OLSON
-1803
# J . E . LE BEAU -3 803
*A. W. SCHAFFER -1803
SR. R. COOK
-1803
S. M. GORCACZ - 4 74
&COVER LETTER OWLY USE WITHIN THE DOW CHEMICAL
FREEPORT *D. E. ERASER
PITTSBURG *F,, D. AXE
STRONGSVILLE i G . L . ME IE R
SARNIA iA F COMPANY ONLY
ri.-i"
00 077437 CONFIDENT!
SAMPLING AND ANALYTICAL PARAMETERS ^AMPL rNG PROCEDURE FOR RCL' S AND HEXES
CANS.. I!' !5 GAG PERFORMED USING THE ANATQLE J. SI PIN COMPANY PERMISSELE
ERCGIi GAM!"LING F'UMP, MODEL, # 5P-1. THESE PUMPS WERE CALIBRATED TO 100 CC'S
ER m. itl: r LGU USING THE
NIC ...E~ CYL.IN FT IF. . CALIBNAT
AKb C! 1
N i... i`
TC ct:
'Mw d: :
LIRE j ,y I!
ACCURACY. NIDL IDE l:,G
WERE
CONNECTED
TO.
THE
SAMPLER
BY
A
2'
(FOOT) SECTION
r i YGDN TUE INC. . FUR RCL SAMPLING, A A" (INCH) DUAL SECTION ACTIVATED CHARCOAL
LAS S TUBE ( SKC , LOT 120, 400 MG FRONT SECTION AND 200 MG BACK SECTION), WAS V;v: -- . FOR HE X AriFLlNG, A 3" (INCH) DUAL SECTION PQRAPACK GS GLASS TUBE i SKC
; `EC IAL LOT, i 0 0 MG FRONT TO INSURE F. lz [l- ESENTATIVE
Wear the tube holder on the collar of their shirt, this allowed the sample to
li"'A YEN IN "HE ACTUAL "BREATHING 2 ONE" OF EACH INDIVIDUAL.
A-U: PREPARATION
rc:.. la1 'Pel J I-"
RET APED BY DRY ICE CHILLING 10 ML'S OF CS2 IN A 2D ML. GLASS
IAl, WITH A MIN INERT VALVED TOP, AND THEN ADDING THE 600 MG OF CHARCOAL FROM
I II NAUR:~ "Mil?'--' , f-HE-SAMPLE WAS THEN ALLOWED TO-COME TO ROOM TEMPERATURE AND
" r> "cyA' f- "2 ml glass vial with a septum.top was their filled
;< . L ,1 .HI A1'.!:.' LOADED INTO A HEWLETT--PACKARD 7673f- AUTO-INJEC1 Ca! OUSEL.
IT. C A''-'ONCE I , INTER; AGED WITH A HEWLETT-PACKARD 76"'3A CONTROLLER. THEN ALLOWED
. II RCL I'' E": C.''.Mr',LE TO PE INJECTIN' INTR A HEWLETT- PACKARD 57"'.- S ,,.
-P .A:; WERE PREPARED RY PLACING THE
MG GF PUPA!'ASK PALLING INTO A 25
`"I: ..'V ", 'A, ".A A MI NINE FIT VAL.'-'ED TOP, AND THEN ADDING 10 ML' S OF- HExANE.
'' H LAY "'"'I. H !S "'HE!-; SHAKEN FOR- ONF HOUR f ~ A...I* GW FOR MAXIMUM EXTRACTION. A GNE
- ip-: samp;..:.: is in ri>-iawn and 'mi.'-j or is immediately injected into a
5790 gas chrcnatpsrait-n
-1i , s,t T (f-
l. VC`5::. 2 FI '!i' ,r;.r'- l/ |
DGi'iE MS If- A HEWLETT - -V 1 h ARD 3 SCO Si- T L HRCMA'-'CGRAPl -1, AME I ON7 ` F I .)! i DETECTOR, AND INTERFACED 70 A HEWLETT-PACKARD ! - L Y 1 Di-.' E PM'i NED F AN'- I...F CON! ENTRAT ] ONE; BASED ON THE to T'.e l-vF'L.e ^olc'tnthmTlor DATA RMS STORED ON FLOPPY DISC
LNEN. INETL'HENH CONDI'! IOi-iS ARE AS FOLLOWS ;
'"'1 `.'Mi !
ICON
40 Ml- T ERE:. IN TNG SECTIONS. - MODEL UV 1701, 25 METERS, .5 ML MEBABORE, 3 MIC-RCW
FILM, FUSED SILICA. COLUMN - MODEL DB-5, 15 METERS, .5 ML MEGABORE, 5 MICRON -I J!,
FUSED SILICA.
TEMPF.i MATURE PROGRAM
-:! LFCPL ('
-| r-r-/- v.p
DETECTOR TNTEGTOR
OVEN
ilTTENLIAT I ON
'llAMRLE SIZE eIluttqn time I" i lute: g .
3 NIC! GLITTFvS
FITCL
J1. C/3 Cj If
p CO 2 ,, 770
"r CT "T
6.32.1
EDS
6,998
PRC
0.37C
!: j A, 740
D..TFT 10. FT
200 DEGREES
250 DEGREES
INITIAL TEMPERATURE : 6 MINUTES A "I 50 DECREES
2.S3 MINUTE RAMP UP AT 30 DEGREES A MINUTE TO'
135 DEGREES
FINAL TEMPERATURE 1.17`MINUTES AT 135 DEGREE
CARRIER GAS r HELIUM
INJECTION SPLIT FLOW ; 150 CC/MINUTE
GAS FLOW
: HELIUM 12.5 CC/MINUTE t. COi-UMN)
GAS PRESSURE : HELIUM
1C.5 PS I
H'T-RUGLN 23 ..0 FBI
AIR
21.0 PSI
DO 077438 confidential.
A JALYTICAL CQMT. )
HEX ANALYSED WERE DOME USINS A HEWLETT-PACKARD MODEL 5790 HAS CHROMATOGRAPH EpUIPPED WITH hN ELECTRON CAPTURE DETECTOR. THIS CHROMATOGRAPH WAS INTERFACED ri-, sr.c(;'; p 0Pfv<2 ICG MODEL 4100 COMPUTER/INTEGRATOR WHICH DETERMINED C'bf ICE NT RAT IONE BASED ON THE INTEGRATED PEAK AREA. INSTRUMENT CONDITIONS ARE
; r ooldlg ;
.1 i r;:.riLL L O': , 3C METERS, .32 MILLIMETER I. D., 1 MICRON FILM, CAPILLARY.
EMPERATURE PROGRAM : .CUREES CENTIGRADE;
DETECTOR INJECTOR DUES!
- 200 DEGREES - 200 DEGREES
4 MINUTES AT 200 DEGREES 5 MINUTE RAMP UP AT 10 DEGREES A MINUTE
280 DEGREES ,5 MINUTES AT 280 DEGREES
TO
. AjT :'i NJATIUN ; CAMPLE. LITE i
MICRO:,..: TE'
CARRIER GAS : HELIUM INJECTION SPLIT : 10 TO 1
ELU'i ION TIMES ; mj nu res-)
3.00 HOE 3.65 HCBD
HCBT
GAS GAS
FLOWS : HELIUM
1
NITROGEN .60
RRESSUPE. r HELIUM
NI TALCS::.L
CC/MINUTE (COLUMN) CC/MINUTE (.MAKEUP)
50 PS I 10 FSI
!' '-"C *V 7 j; AL COLA'1' I `JNE
F.O'.JA ! IDP
PPM VOLUME OX ROLL IN A IF-: -
; WEIGH'; OF CC2 IP CRAMS j (.0021) ( L LGF.G S M) (pf'l'l FROM CHROMATOGRAM;
'ic-) l ;
CAR}?"!)! ' DICUIJ'IDE USED FOP ^ESGPFTIDM
O- COROT ANT (CALLS RTS GRAMS TO LITERS}
DECREES
--'IK (DEGREES CENTIGRADE + 273)
t--;: R'L T AIL AP WE I '""`I'T CF SPECIFIC COMPOUND
LITERS OP AIR SAMPLED
O' EO.JAi' I!
PPB VOLUME OF HEXES IN AIR (MG) (24.45) (1000)
(L) (MW) (RR)
MG MICROGRAMS FROM INTEGRATOR DATA 24.4S i-- LITERS OCCUPIED BY 1 MOLE OF GAS AT STANDARD CONDITIONS
- LITERS OF AIR SAMPLED 1 i!\' < MOLECULAR WEIGHT OF SPECIFIC COMPOUND
" RECOVERY RATE OF COMPONENT
DO 077439 CONFIDENTIAL.
SOLVENTS / EDC 1 1987 NOISE LEVEL SURVEY POTENTIAL NOISE EXPOSURE SOURCES
PI... A NT LULU PMr NT
PLANT AIP (3/4. " BLEED WIDE OPEN)
47D # STEAM TRAP r AR- 40 A & B)
K-4 0 A
AR-40 A & B (ON LINE)
!-:> D20 DECK
0 500 INLET CONTROL VALVE
AI-iCL TO C-TRAIN CONTROL VALVE
K--40 B DLL'-4 0 A & B
K-3 E HOT GAS BYPASS CONTROL VALVE
KS-40
BL--740
RIVER WATER PUMPS (SOLVENTS)'
D-2 C DUMP CONTROL VALVE (OPENING)
K- 3 E GROUND LEVEL' ' ' '
NORTH '! E BOTTOMS PUMPS
AR-- 4 0 A &
I. OFFLINE)
L 500'S n> r t 5 ' r
^
WCST C-U..T BOTTOMS PUMP
;< -3 E i. TQUID 1" PEON INJECT TON CONTROL
".Ti,""" WATER PtJMPS ' EDC M '
p- jo
E', KYLE!-!.-" " 0
E CONTROL k;;lve
p: c
c&c .............. " - - ... 1 e-. , 1 / c '
VYO'E
' : ' yl.l : :c to i i d control.. v. .lve ' LPr
0-2 !: BCTT 0! "0 .1 D OVERHEAD PUMPS
CDP-'K C~1 't- A BOTTOMS PUMP' 0 -IT A BOTTOMS CONTROL VAlVE P-201 A COUTH L'-DT A EAST P--1 E 014 D OVERHEAD PUMPS E-541'S WEST P-1 D p- i r ] NL.ET
C-01 NORTH
R-l C HO 40 f rr--4 r.
IRON DRUM TO C-l C
SOUND LEVEL (dba)
132 db 112 ` db
106 - 102 db 105 db 105 - 100 d b 104 db 104 db 102 - 100 db 102 db 102 db 101 d& a oo db
9S - 95 db 97 db 95 - 93 db 95 db O r- db 94 -- 90 db 92 db 92 db
db 92 db 9c - 38 db >.-1 - db Cji 2 db O. j.' d b ?1 - 35 db 90 db 90 db 90 o b 89 db 88 db 88 db se db 37 d b 87 DB 87 db 86 db 86 db 85 db 84 db 84 db 83 db 81 db 80 db 79 db
Ni -- HAUL 7 0.0! E '.IMPACT NOISE)
AMMEP AMMP"' C.HMEf1 AH' TCP
'ON MET A! \ (ON ETC EL.. CM] EEL) ' DR IV J M'f NAIL.) (ON WOOD CHISEL)
SOUND LEVEL (d ba)
116 db 106 db .103 db
95 dL
00 077440 CONFIDENTIAL
NOISE SURVEY (CONT.)
- ........ ----- ----- .... ---- ------------------------------------------------------------------ ---- -- --... --
power TUOL.S
SOUND LEVEL
t r p S!- J NDER
P T ? -E Or:; j NDER CIRCLJLAR SAW pire CUTTER,, PIPE CUTTER, PIPE CUTTER. PIPE CUTTER,
(RIDER DISC ON METAL)
(CUT TING WOOD) LG. (FAST SPEED) SM. LG. (MED. SPEED) LG. (SLOW SPEED)
110 db 108 db 107 db
9 b db 95 db
db 85 db
HEAVY equipment and machinery
ci:ep ! v pil; i::n (full ti!RCttle>
PGRTA3LE AIR COMPRESSOR (DOORS OPEN/
WELD INS MACHINE (FULL THROTTLE)
iij
r-1 J'f'tYjrR f jn; fMACHINE ! ID-E )
AIR COMPRESSOR (DOORS CLOSED)
SOUND LEVEL (dba)
IOC db 102 db 101 db
96 db 96 :sb 90 db 90 db 90 db
vp 1 1 ! r"t jc:;
! i L.
i |-i* > I J,iT
r; ; j f f'' 5 WOPURCOH , EDO 1)
: '! ! ! L 'APR s SOL VLK! j
.. i. 1 ' v',./1" - 1. \'r<
-M'jp ' O' JL IMF! ,"r)
L,-'0` IN;.:.
VU;-7 L-i(OC1 J
EON!" i. i'1 p PLUM ; SSL1 ''`-'NTS ;; O' >..:, . c 1 e > ^ esc * )
PA'-'LIMG LOT ( SO. . OE.L'TS ,,
.'EY'-R ROL ROOM ; I EC 1 )
SCUN
EL ( d b i
91 db 90 db T t_"\ r'- j 1
EE db BE db 92 db 90 db 75 db 72 db 66 db SE db
TL/iPC'
DO 077441
confidential
I
| CONTRACT ASBESTOS SAMPLE RESULTS
r SAHPLEI PERSONNEL DESCRIPTION
DUBININ) VOLUME(L) FIB/CO5N1CR0N 8-HR TNA F1B/CC PLANT
12/15/87 8681 *436-74-3503 INSUL-REMOVING TRANS ITE OFF BLDG; NET METHOD USED
355 781.000 '*'
0.020
0.0*15 SOLVENTS**"7!
11/23/87 8670 *439-98-0392 INSUL. REMOVING ASB. NET METHOD USED
325 654.875
0.022
0.015 SOLVENTS
11/21/87 8672 *436-74-3503 INSUL - STRIPPING ASB. FROM PIPE IN RACKiHET METHOD
33? 759.360
0.004
0.003 SOLVENTS
12/14/87 8680 *439-98-0392 INSUL-REH0V1HB TRANS1TE OFF BLDG:NET METHOD USED
355 807.625
0.015
0.011 SOLVENTS
11/12/87 8280 *437-05-3320 INSUL - REMOVING ASB. NET METHOD USED
373 B72.820
0.051 v 0.040 SOLVENTS
12/05/87 8678 AREA
DONNHIND; NORTH OF CONTROL RN.;NET METHOD USED
118 166.380
0.013
0.003 SOLVENTS
DO 0 7 7 4 4 2
CO NFIDENTIAL
L
DOW CHEMICAL LAD INDUSTRIAL HYGIENE SAMPLE CONCENTRATIONS
RCL DATA ENTRY FORM
NAME
: MIKE BROWN
PLANT
i SOLVENTS / EDC 1
PLANT # : 3.6 / 17
:; - r* l:.aa ur =:: tt Ik ss
r- " -- = sr = ~ ~ -- = ^;=.-ses==ESS2- E= = EES=s=SSSSK = = 3E8T = =E:SSSE=ESff EESSVSCSW SEE. ~E==:
SAMPLE DATE (MM/DD/YY) SAMPLE NUMBER
: 10/21/B7 1
TIME START- ! 9: OO AM TIME STOP ! 9:20 AM
SAMPLE TIME (MIN.) SAMPLE VOLUME (L) SAMPLE TYPE (A, S, P)
: 20 MIN. t 1.84 :S
PUMP START FLOW : 100 CC/MIN. PUMP STOP FLOW : IQo CC/MIN.
<A- AREA), S-SHORT TERM, P-PERSQNNEL)
IF AREA, DESCRIBE
H
RESPIRATOR USED (1-7) : 3
8 OR :2 HOUR SHIFT
:8
S1 IFT (DAY >MIGHT-, EDO) : DAY
EFpLCVEE I. D, #
; 434082
JOB OLSCR: FT ) ON
: LOADING A JO 00 GALLON PER T/TL
iRESPIRATOR TYPES
1=NONE, 2=M0UTHBIT, 3-COMFO II, 4=FULL FACE, 5=BREATHING AIR, 6-'DUST' MASK, 7*SCBA. ' '
ANALYTICAL RESULTS
! COMPOUND |etcl j^ET
D T! I
I; i m ANALy ilS DR = IHG ST EL e MDL : RESU
3701 , 1 :oo ; 0 . 01
<. c 1
3d, 34 ;
cr : 0
.01 : ::.0i
n *i o 0 /i
10 t 0 - .01 : < . 0 1 '75 : J10 : . 01 = ,, 2
36 I'D k:
.200 -
1 ; 3.999
"!' A,,,) OL) *t' - 10 2 0
.01 : ;. 01
6 HOUR TlV/TWA
STEL tlv/tw-
AR
NOTE
PPM
OTHERWISE NOTED.
RCL EQUATION
PM VOLUME OF RCL.S IN AIR -
(WEICUT OF 052 IN GRAMS) (.0821) (DEGREES K) (PPM FROM CHROMATOGRAM)
WHERE
CS2
. 0821 DEGREES MW
(MW) (L)
- CARBON DISULFIDE USED FOR DESORPTION = GAS CONSTANT (CONVERTS GRAMS TO LITERS) = DEGREES KELVIN (DEGREES CENTIGRADE + 273) = MOLECULAR WEIGHT OF SPECIFIC COMPOUND = LITERS OF AIR SAMPLED
MB ( .3/
DO 077443
confidential
DOW CHEMICAL LAD INDUSTRIAL HYGIENE SAMPLE CONCENTRATIONS
RCL DATA ENTRY FORM
PLANT
MIIX BROWN SOLVENTS / EDO 1
SAMPLE DATE (MM/DD/YY) : 10/21/37
TIME START :10s00 AM
SAMPLE NUMBER
:2
TIME STOP *10*40 AM
SAMPLE ""IME (MIN.)
: 40 MIN.
SAMPLE VOLUME (L)
: 3.69
PUMP START FLOW I 100 CC/MIN.
SAMPLE T'T-'E (a. S, P) ; S
PUMP STOP FLOW : 100 CC/MIN.
(A-AREA , S-SHORT TERM, P-PERSONNEL )
IF- AREA, DESCRIBE
:
RESPIRATOR USED (1-7) : 3
3 OR 12 HOUR SHIFT
:8
omrr (day,night, edo) : day
| EMPLOYEE I . D#
: 434213
i 70F rcocniP^ioN
: LOADING A 3470 GALLON TET T/T,
RESPIRATOR TYPES
1=N0NE, 2=M0UTHBIT, 3=C0MF0 II, 4=FULL FACE, ^BREATHING AIR, 6=DUST MASK, 7-SCBA.
ANALYTICAL RESULTS
COMFTUNB
nr,: ft
s IH5 iSTEu : MDL
ANALYSIS S HOUR RESULT TuV/TWA
ST El. TLV/TW4 : AREA
ETCL i.
r: rs r
0002-3701 :iOOC ~r >. '
0001 -- V''SO, i ; -ngj-
10
o ('
01 : <,01 OX ; 2.992 01 < .01 01 i 1.034
1.Q ,3
20'"'
O1
OOO2-3d,07
. 01
.01
ALL r;ECULTS IN PPM UNLESS OTHERWISE NOTED.
PPM VOLUME Or RCLB IN AIR (NE-OHT 'l>r CS2 IN GRAMS) (.0821) (DEGREES K) (PPM FROM CHROMATOGRAM)
i-.'HE i
032 . 0821
MW I..
(MW) (L)
- CARBON DISULFIDE USED FOR DESORPTION --- GAS CONSTANT (CONVERTS GRAMS TO LITERS) I-" =- DEGREES KELVIN (DEGREES CENTIGRADE + 273) ^ MOLECULAR WEIGHT OF SPECIFIC COMPOUND - I..I FEES OF AIR SAMPLED
m r~i i;
00 077444 confident rA,
DOW CHEMICAL LAD INDUSTRIAL HYGIENE SAMPLE CONCENTRATIONS
RCL DATA ENTRY FORM
NAM!" PLANT PLAN"'
: MIKE! BROWN : SOLVENTS / EDO 1 t: : 16 / 17
SAMPLE DATE (MM/DD/YY) : 10/23/87
TIME START
SAMPLE NUMBER
:3
TIME STOP .
SAMPLE IJML (MIN.) i SAMPLE VOLUME (L)
: 300 MIN. : 28.77
PUMP START FLOW
SAMPLE TYPE (A, S, P)
;P
PUMP STOP FLOW
(A-APIA, 8-SUORT TERM, PPERSOMNEL
i IF AREA, DESCRIBE:
RESPIRATOR USED (1 - 7)
i 8 OR 12 HOUR SHIFT S' ! 1 F"*T (HAY- NIGHT, FDD)
:8 : EDO
EMPLOUE I. D -i #
: 433555
70D Dr'SOR I X nw
; CHARGING PER FILTERS.
8:00 AM 1:00 PM
100 CC/M1N. 100 GO/MIN.
RESPIRATOR TYPER : 1N0NE, 2^M0UTHBIT, 3-CQMFQ II, 4--FULL FACE,
5-BREATHING-AIR,- 6=DUST MASK, -7=SCBA.
CCMRO'JNr i
DR t.
1NAL..YT I CAL RESULTS : IHG :STEL : MDL : RESU _!
C'-i f; : 7LV/TWA ; TLV/TWA : AREA :
: 0002-'3701 : 1000 : 0 ; .01 : <.01
:
:
*
!Wi r r* ," ' r tn r~
M,1
. -02-T-Lb'-: .
5
-1 ; ft X a < . 01
:
:l- ::s:u ^ 10 : o : a 0 1 I , 998 : .11 :
; OO'oi -9'/4 3 : 75 i 110 : . 0.1 : . 573
V
"*
:;
kJ
78 b 'j 200 01 :18.597
i . 19
TC rAi i IU
JLT!
0 01 01 N PPM UNLESS O'-'MERWiSF NOTED.
PPM VOLUME OP RCLS IN AIR = WE:GMT OF LS2 IN GRAMS) (.0821) (DEGREES K) (PPM FROM CHROMATOGRAM;
RE .0821 v r* ^ r;i
(MW) (L)
CARBON DISULFIDE USED FOR DESORPTION GAS CONSTANT (CONVERTS GRAMS TO LITERS) DEGREES KELVIN (DEGREES CENTIGRADE + 273) MOLECULAR WEIGMT OF SPECIFIC COMPOUND LITERS OP AIR SAMPLED
MB r OA/>:/ Be
ii i
00 077445
confidfnti
DOW CHEMICAL LAD INDUSTRIAL HYGIENE SAMPLE CONCENTRATIONS
ECL DATA ENTRY FORM
N.'-FlE
, ' : KE DROWN
RL.S.v"
SOLVENT'S ' EDC 1
PLANT F : A / .17
:: 'm, -- s 'j i. t..z ::r: ' rA- ::: u\ *
SAMPLE DATE (MM/DD/YY) : .10/27/87
SAMPLE NUMBER
t4
TIME START : 9s55 AM TIME STOP : .1 O t 1 5 AM
SAMPLE TIME (MIN.) EAMCLC l'Ol..lJHE (L) SAMPLE TYPE (A, C, P)
: 20 MIN. : 1.78 :3
PUMP START FLOW : 100 Ct/MIN. PUMP STOP FLOW : 100 CC/LIM.
;A=- /TEA. S^SMDRT TERM, P=-=PERSONNEL)
| .1F AREA, DESCRIBE
:
| RESPIRATOR USED (1-7) : 3
' 8 UP 1.2 HOUR S'-! I FT
:G
!S!.'I"r (l. A. y , N10! !T , EDO) : DAY
'.
EMPLOYEE I. D,, #
t 434213
':E )'A .'Li'1 ON
i LOADING A 10C0 GALLON TET 7/T WITH A LEAKING
EXTERNAL LOAD VALVE.
RESPIRATOR TYPES : i-NONE,, 2"M0UTHBIT, 3=COMF0 11, 4=FULL FACE,
.... s'
5~BREATHING AIR, 6=DUST MASK', ` 7=SCBA'.
\p::: :*r:
- \ *;; 7 k: . -l :si: "z zr:Z": ::: _. :
rrjy, jit. :.a :.7 wz w..
r" :::: :.z. l. *
i; CO.'lPOUMD l
ANALYTICAL RESULTS :. :", ; :,7 v;: *. r" rr L." * :.7 ml 1 r ; " r.v 7- 7. r r::. ;:u 35 ;.7 :;r::.:r l;- - - \\r. z-^ rui zr te'
"
ANALYSIS : 8 HOUR l
; T ~: t ST EL i ML.- i !'ESU!...T . Tj_ V/TWA I
= = s?r:*=r^ " i:
STEL.
T LV/TWA ;
: sr?
: ARE A :
LTCL.
: 0( 02-3701 : 1000
0 1 .01 : L.Ol
:
:
* :
, r.. -- f.s
. o-' 02 O'i'-A 1
R 1 r> u
: * ., L 01
, " "R3i
10 1 0 - 01 : . 01
: r
; 5.1 7
: :
PER '
: V. I.; - 7 !3 i h '-'u- , "3 I... <i > :
3 i i i C . ci
. 203
L / 20C
. 0.1 ; 3.935
r i
t ** _ " 4.11
: :
:: TRI
. 0' 02- 3uG7 E 10 ; 0
. 01 ? <.01
t
;; :
MOTT AU. RESULTS IH PPM UNLESS OTHERWISE NOTED. . : %: -vrJ :::: t- r.- "
32L EfiUATION :
PPM VOLUME OF RCLS IN AIR =
(WEIGHT OF CS2 IN GRAMS) (.0021) (DEGREES K) (PPM FROM CHROMATOGRAM)
WHERE
032 . css;
decrees:
i ;w
s MW) (L)
= CARBON DISULFIDE USED FOR DESORPTION GAS CONSTANT (CONVERTS CRAMS TO LITERS) = DEGREES KELVIN (DEGREES CENTIGRADE 273; := MOLECULAR WEIGHT OF SPECIFIC COMPOUND - LITERS OF AIR SAMPLED
f -j j" fm)" / f , / r->'
DO 077446 CONFIDENTIAL
DOW CHEMICAL LAD INDUSTRIAL HYGIENE SAMPLE CONCENTRATIONS
RCL DATA ENTRY FORM
NAME
!i Ml'-'E. BROWN
PLANT i SDL. VENTS / EDO 1
PLAN' i: : :.L / 17
SAMPLE: DIRE (MM/DD/YY) : 10/27/87
TIME START
iAMF'LE MUMPER
:0
TIME STOP
SAMPLE TIME (MIN.)
; 30 MIN.
SAMPLE VOLUME L)
: 3.0"
PUMP START FLOW
SAMPLE TYPE (A, S, P) : B
PUMP STOP FLOW
A-ARCA, S "'SHORT TERM, P-F'ERSO.NNEL)
IF AREA, DESCRIBE
:
RESPIRATOR USED (1-7) P OR 12 HOUR SHIFT
3
SHIFT (OrY^NIBHT, EDO)
DAY
EMPLOYEE ), D. #
434213
JO);: DEOCRIF i'lON
"BUCKET TEST" ON TET T/T.
1:40 PM 2 10 FM
100 CO/MIN,, 100 CC/h'iN.
RESPIRATOR TYPES
I-NONE, 2=M0UTHBIT, 3-C0MF0 II, 4-FULL FACE, 5-BREATHI NO AIR, A^DUBT MASK,' 7=SCBfi.
ANALYTICAL RESUL'i
-ir;,-,. irjr
IHS TEL MD<
ANAL "F 1 F RESULT
b HOUR : STEL TLV/TWA : TLV/TWf
AREA
ETC!. ] ......-
TET
000.2--3701 :1000 : 0 : .01 : 0 4/
09, &&
00
1<
4c
5.094
TR1 0002-3337 : 10 :
01 01
NOTE.
L RESULTS IN PPM UNLESS OTHER ISE NOTED.
RCL EQUATION
PPM VOLUME OF RCLS IN AIR -
(WEIGHT OF CS2 IN GRAMS) (.0821) (DEGREES K) (PPM FROM CHROMATOGRAM)
WHERE L
(MW) (L)
CARBON DISULFIDE USED FOR DESORPTION CAS CONSTANT (CONVERTS GRAMS TO LITERS) P'S0REES KELVIN (DECREES CENTIGRADE -i 273) MOLECULAR WEIGHT OF SPECIFIC COMPOUND LITERS OF AIR SAMPLED
00 077447 CONFIDENTIAL
DOW CHEMICAL LAD INDUSTRIAL HYGIENE SAMPLE CONCENTRATIONS
RCL. DATA ENTRY FORM
! NAME ! FI. AMT
PLAN!
: MIKL P'KDWU : SOLvE NO S / EDC I
L .. 16 , 1"'
SAMPLE !>.Tr ' MU/DD/YV) SAM PL. C MUMPER
; 10/09/87
t6
TIME START sl0:00 AM TIME STOP :10i40 AN
sample time <;min.)
: -40 min.
SAMPLE VOLUME (L)
: 3.87
PUMP START FLOW : 100 CC/'MIN
SAMPLE. 1 P-L-
C , P;
:S
PUMP STOP FLOW : 100 CC/N.iP
' AVARS'A ,, S---SMORT TERM , P-PERSONNEL )
IP AREA, DESCRIBE
:
RESPIRATOR USED (1-7) ; 3
8 OF: 10 MOOR SMIE"!
:8
S i- .1. F f /DAY, NIGHT, EDO) t DAY
employe::- i. d,,
: 434213
'CP u: H.;R> 1` '! TON
; LOADING A 3470 GALLON TE.T T/T. THERE WAS A 3
GALLON BUCKET OF PER AT T 'T RACK.
RESPIRATOR TYPES : i-NONE, 2-MQUTHBIT, 3=C0MF0 II, 4=FULL FACE,
-5-BREATHING AIR,-6*DUST MASK, 7-SCBA.
ANAL'-"1'I CAL RE SUL"! S
i r'r']i ';;"i f't
J k c: T jV! * 1 " !
r'< y ,*"* /, rr a
s ANALYSIS : 8 HOUR ; STE:._
:
M)}L. it RESULT l TLV/TWA : TLV/1WA : AREA
,, o1 i
.01
4.717
2.4!
. 01
Al' W, YY
C
OL LALY
1V
c*'; m L. i...
-*.r
*|
J
f
!
Ppr*i
5.638 01 < . 01
NO I' ED.
': ci.".' t
PPM VOLUME OF RCLS IN AIR =
,W! I DMT OF CLP IN GRAMS) (.0821) (DEGREES K) (PPM FROM CHROMATOGRAM
; JHERE
CS2 .0021
DC ARRIS M1 ( l
(MW ) : L )
CARBON DISULFIDE USED FOR DESORPTION GAS CONSTANT (CONVERTS GRAMS TO LITERS) DEGREES KELVIN (DEGREES CENTIGRADE + 273) MOLECULAR WEIGHT OF SPECIFIC COMPOUND LITERS OF AIR SAMPLED
", /
DO 077448 CONFIDENTIAL
DOW CHEMICAL LAD INDUSTRIAL HYGIENE SAMPLE CONCENTRATIONS
RCL DATA ENTRY FORM
Mtr.' like shown SOLVENTS / EDC i */ / iy
SAMPLE Dr.TE (MM/DD/YY) : 11/05/87
TIME START : 6:30 AM
SAMPLE MUMPER
:7
TIME STOP
2:30 PM
SAMPLE TIME (MIN.)
: 430 MIN.
SAMPLE VOLUME (L)
: 64.86
PUMP START FLOW : 100 CC/MIN.
.SAMPLE TY!:;,E (A, 8, P)
:P
I (A"- AREA. S`-SHORT TERN, P"FERSDNNEL )
PUMP STOP FLOW ; 100 CC/NIK.,
|IF AREA, DESCRIBE
:
!RESPIRATOR USED (1-7) : 3
is oi:
hour shift
:8
'SHIFT (DAY.NIGHT, EDO) t DAY
EMPLOYEE I. D. #
434037
FOP DEE FT::. FT ION
: LOADING COORDINATOR PERFORMING NORMAL DAILr
DUTIES INCLUDING CATCHING PRELOAD SAMPLES.
RESPIRATOR TYRES 1"N0NE, 2~HQUTHBIT, 3-C0MF0 II, 4=-FULL FACE,
S^BREATHJNG Air, 6=DUST MASK, 7'=SCBA'.'
hNAlY>ICAL RESULTS
r-rjiv pr.i
.
DP If
: ANALYSIS : S HOUR
ST EL
: IHG :STEL : MDL l RESULT : TLV/TWA : TLV/TWA : AREA
; 00.1.7 3/01 l!000 i 0 l . 01
< .01
. 1)002- 305^ :
! 0 t .01
4 4.032
1.40
. -1 TO! -8 531 : , , , ; ,, c ro/j 7 ,
: TO02 3698 r
3 0 :: 0 : . '01 7*", I 11 0 ; . 01. 50 : 300 i ri
1.275 . 652 .42
. 06 . 03 1.90
; 0003-7637 : 10 : 0 i . 01
<.. 01
; ALL RESULTS IN PPM UNLESS OTHERWISE NOTED,
RCL COURT T ON!
PPM VOLUME OF RCLS IN AIR =
(WEIGHT OF CS2 IN GRAMS) (.0821) (DEGREES K) (PPM FROM CHROMATOGRAM)
WHERE
CS2
. 0821 DZO'-'L
ME i
(MW) (L)
a CARBON DISULFIDE USED FOR DESORPTION - GAB CONSTANT (CONVERTS GRAMS TO LITERS) K == DEGREES KELVIN (DEGREES CENTIGRADE + 273) = MOLECULAR WEIGHT OF SPECIFIC COMPOUND = LITERS OF AIR SAMPLED
Mr* `i/.
00 077449 CONFIDENTIAL
DOW CHEMICAL LAD INDUSTRIAL HYGIENE SAMPLE CONCENTRATIONS
RCL DATA ENTRY FORM
NAME
i MILL BROWN
PLANT i SOLVENTS / EDC 1
PL. A N't' : ; 16 / 17
SAMPLE DATE (MM/DD/YY) : 11/25/87
TIME START 7:00 AM
SAMPLE NSJMEER
tB
TIME STOP
7:20 AM
SAMPLE TINE (MILL)
: 20 MIN.
SAMPLE VOLUME (L)
: 1.91
SIMPLE TYPE (A, S, P) : S
PUMP START FLOW PUMP STOP FLOW
100 CC/MIN. 100 CC/MIN.
(A-AREA, S=SHORT TERM, P=PERSONNEL]
IF AREA, DESCRIBE
s
RESPIRATOR USED (1-7) ; 3
I S OP 12 HOUR SHIFT
:3
SHIFT (DAY,NIGHT, EDO) l DAY
EMPLOYEE I. D. tt
: 433923
JOB DESCRIPTION
: MONITORING THE DRAINING OF ORGANICS FROM V-201
INTO V-201 SUMP.
RESPIRATOR TYPES : 1-NONE, 2=MGUTHBIT, 3=C0MF0 II, 4=FULL FACE,
- 5=?BREATHIN0- AIR, 6=DUST MASK, 7=SCBA-.
...
ANALYTICAL RESULTS
COMPOUND
DP ii
; : : ; ANALYSIS : S HOUR : STEL : IHG eSTEL : MDL : RESULT
'), T'"7C J ^
A tr
: .01 : *='.01
AREA
^ r-o..3^5^ :
3 r 0 : .01 :
2."V
oo-u-scr: * ; '0.J -^043 l
ir> 0 : .Cl-i 75 r 110 1 ,, Q J.
:]. 01 t 332
C;
i "'ER
OOOO- 3-69C : 50 : 00r; . .01 :
3.976
;`,'w/K
/ r>"/7
p *
i
J.
\f
;
0
i .01 i
<.01
RESULTS IN PPM UNL.EBC OTKERWTSE NOTED
'CL COUNT ION
PPM VOLUME OF RCLS IN AIR =
(WEIGHT OF CS2 IN GRAMS) (.0821) (DEGREES K) (PPM FROM CHROMATOGRAM) i
.0321 DEGREES MW L.
(MW) (L)
CARBON DISULFIDE USED FOR DESORPTION = GAS CONSTANT (CONVERTS GRAMS TO LITERS) = DEGREES KELVIN (DEGREES CENTIGRADE + 273) - MOLECULAR WEIGHT OF SPECIFIC COMPOUND " LITERS OF AIR SAMPLED
MB r 07/02
DO 077450 CNF TDFNTrAL.
[0
DOW OHFMTrai 1 AD INDUSTRIAL HYGIENE SAMPLE CONCENTRATIONS
RCL DATA ENTRY FORM
NAME
: MIKE BROWN
PL A1' 'T
i SDL VENTS / EDC 1
PLANT L ; 16 17
SAMPLE DATE (MM/DD/YY) SAMPLE MUMMER
: 11/23/87 i9
TIME START : 7:00 AM TIME STOP 111 00 AM
AMPLE TIME (MIN.) AMPLE VOLUME (L) CAMPLE. TYPE (A, 3,
P;
s 240 MIN. t 27.16 ;A
PUMP START FLOW 100 CC/MIN. PUMP STOP FLOW i 100 CC/MIN.
(A-AREA. S"S!TORT TERM, P- PERSONMEL )
IF AREA, DESCRIBE
: V-201 SUMP
REST'I RAT OR USED (1 - 7) t
8 OR 12 HOUR SI! I FT
i
SHIFT ( DAY , N1 Cl !`i" s EDO ) : DAY
EMPLOYEE! I . D. #
:
US PUS2K ? p" j ON
MONITORING THE DRAINING OF ORGANICS FROM V-201
INTO V-201 SUMP.
RESPIRATOR TYPES 1-NONE, 2--MOUTHBIT, 3=CQMF0 II, 4=FULL FACE,
3"BREATHING AIR, 6-DUST MASK, 7=5CBA.
ANALYTICAL RESULTS
Wr^.JMI liri'vr-LiUJ-' iLnU
DR
IMG iSTEL
MEL
ANALYSIS RESULT
3 HOUR : STEL TLV/TWA s TLV/TWA
AREA
ILT-- " w'"Mi--
; C) 0 0 .7 ' " 7 1 0 - , 1 f_1('
: .01 l
<.0i
:
;
;
NIT
Uj *
11 :
31,70:
,
cef:! .
i:
t
>'
: .''1
19.938
:
p
. 2.34:
"ir.r
, /wn-'v-i f"~< >";
r: , -i ^ p, i .`.1 : 91,860 i
>' ".41:
.
;
3- ****C_ i,
1 * 201'1 : .01 ; 185.073 s
i .1 2,93:
** V
l 0002-SSG7 : 10 : 0 i .01 :
<.01
:
kt *
i <. .M r~ , ALL RESULTS IN P^'M UNLESS OTHERWISE NOTED.
OUATIOr
PPM VOLUME OF RCL5 IN AIR -
fWEIGHT OF CS2 IN GRAMS (.0821) (DEGREES K) (PPM FROM CHROMATOGRAM)
WHERE
CS2
. 0821
DEGREES
(MW ) (L.)
CARBON DISULFIDE USED FOR DESORPTION - GAS CONSTANT (CONVERTS GRAMS TO LITERS) - DEGREES KELVIN (DEGREES CENTIGRADE + 273) - MOLECULAR WEIGHT OF SPECIFIC COMPOUND = LITERS OF AIR SAMPLED
ML". 6 '0 / i:) r:
Do 0774S1 CONFIDENT!A
DOW CHEMICAL. LAD INDUSTRIAL HYGIENE SAMPLE CONCENTRATIONS
RCL DATA ENTRY FORM
! NAME
j PLANT
. NIKE BROWN . SOLVENTS / EDO I
' PL A Hi L , ifc / l"7 :v; , ..:; r. :: m ;
` r- Lr.: :t L.,, el- Li r": z
V z;: =z Zi Si, k St ur r.z s::- l; ss: =s* " :l. vz
. z,,=r rr -- rz sz z.. z: r.:: r
SAMPLE DATE (NM/DD/YY) SAMP LE NUMBER CAMPLE TIME (MIN.)
SAM'-'LF VOLUME fL) Si' YPE (A, S, R) ( A AREA S--SHORT TERM,
12/03/S7 10 ID MIN.
1 . D7 S P "PERSONNEL
TIME START :12*45 PM Tl'ME STOP : 1:00 PM
PUMP START FLOW : 100 CC/MIN. PUMP STOP FLOW : 100 CC/MIN.
I!" AREA s DESCRIBE REST'J RAT OP USED (1-7)
OR 12 HOUR SHIFT :u.::pt (bay ,night, edd) EMPLOYEE I. D. #
12 DAY 434213
; : '/ G M- PT1QN
CATCHINC P/T PROCESS SAMPLES.
RESPIRATOR TYPES : 1N0NE, 2<*M0UTHBIT, 3-COMFO II, 4=FULL FACE, D-BREATHING AIR, 6-DUST MASK,' 7=SCBA.
......a*
,:,J mi * ,
, ozsks :rrt iz:..:,,,-, .:i zs z: sz == =z luz
iszszs zr zv : ::z z=.z:zr. ztiz--. *:rrz iz :;:izi:,"i
ll i".- -- -------- zr. :=-_ -
ANALYTICAL RESULTS
c*
c.i r. s::u-s::: zr jz z:: zi zszr z; sz " zv y-xz 2= tz iz aa Sit
`"H 2Z St I.-: z.- r~ r_- az szzs zs :sr " sz izz: z: z=i= =: -z ~ z: szaz zz Z= s
:
S
r
:
: ANALYSIS i S HOUR : ST El.
f
COMI-'OL)!'!!: :
DR t
j I HO :STE. : MOL : RESULT : TLV/TWA : TLV/TNA : AREA
PT CL Tf
: 0002- T'-'O.' ;i0<: d:
.01 : : .l... :
. 01 : 7.OSS :
: 9.21
; 000! C5ZI
10 . 0 : .,01 :
; 1.10
. o:. :
< 0.1 ; .. 3?1 :
.6
,:0 : 200 i ,, 0 1 :
a,,60S :
TR1
: 0002-3607
10 " 0 : .01 :
<.01
;
KC--E ` AL..L RESUL'iS IN PPM UNLESS OTHERWISE NOTED.
it' ::/
:::: :r : :::::r, :*m
'. ' '.: l `l:- . z 5" rr. n. zr zi rz; zr sl. z:. zl zi sz :z: z." '
RCL EQUA1 ION ;
PPM VOLUME OF RCLS IN AIR =-
(WZIOI-IT OF CS2 IN GRAMS) (,0B21) (DEGREES K) (PPM PROM CHROMATOGRAMS
(MW) (L)
WHERE : CS2
- CARBON DISULFIDE USED FOR DESORPTION
.0821
~ GAG CONS'! ANT (CONVERTS GRAMS TO LITERS)
DEGREES K ^ DEGREES KELVIN (DEGREES CENTIGRADE + 273)
MW - MOLECULAR WEIGHT OF SPECIFIC COMPOUND
- L1 1 ERG OP AIR SAMPLED
DO 077452 CONFIDENT! A'
COW CHEMICAL LAD INDUSTRIAL HYGIENE SAMPLE CONCENTRATIONS
RCL DATA ENTRY FORM
name:
: Mice drown
PLANT t SOLVENTS / ETC; i
FLA!'!';' I! : is / 17
= E=
=r= sr a* =_ =-; Ft* au K: 5T as es sass -- s towr .ra = = s=:=r=. =;:= = = !==::::
SAMPLE DATE (MM/DD/YY) s 12/03/87
TIME START : 6:00 AM
SAMPLE NUMBER
h 11
TIME STOP s 6:15 AM
SAMPL.E TIME (MIN.) SAMPLE VOLUME (L) SAN'~'LE T'/PE (A. S, F) .
h 15 MIN.
J 1.63 :S
PUMP START FLOW ; 100 CC/MIN PUMP STOP FLO'/ : 100 CC/MIN
(A-AREA, S-SHORT TERM, F PERSONNEL)
IF AREA, DESCRIBE
s
RESPIRATOR USED (1 - 7)
8 DR 12 LOUR SHIFT
i 12
L'P.I'f (DAY ..NIGHT, EDO) t CAY
EMPLOYEE I. D. #
/34213
FUL RLSCR p!"!.CM
CATCHING P /T PROCESS SAMPLES.
RESPIRATOR TYPES : i*NONE. 2-MOUTHBIT, 3=C0MF0 II, 4=FULL FACE, ' 5`-BREATHING' AI FT, 6-DLJST MASK, 7-SCBA.
ANALYTICAL RESULTS
:C'1F'uLJi\!D
>P I;
IhS :TEL MDL
RESULT
8 HOUR1 TLA/TWA
i TEL
Mt-H
r 'T T
: CO -
, oco
; jl
t::( n
U
LI 1/786
ii i | r-
K QTjTT
O1' r t~-t
474
2C <; :u
/ ijT . I I, .
10 01 . 01
RESULTS IN PPM UNLESS OTHERWISE NOTED,
. G2
EQUATION t
PPM VOLUME OF RCLS IN AIR =
PLIGHT OF CSL IN GRAMS) (.0821) (DEGREES K) (PPM FROM CHROMATCGPA
WHERE
CS2 0821 DE GREFS ri: ` L
lMW) {L)
CARBON DISULFIDE USED FOR DESORPTION GAS CONSTANT (CONVERTS GRAMS TO LITERS) DEGREES KELVIN (DEGREES CENTIGRADE + 273) MOLECULAR WEIGHT 0^ SPECIFIC COMPOUND LITERS OF AIR SAMPLED
ML:06/03/88
DO 077483 CONFIDENTIAL
KJ/v rJj!
PLAN! pi 0.1-1
DOW CHEMICAL LAD INDUSTRIAL HY8IENE SAMPLE CONCENTRATIONS
RCL DATA ENTRY FORM
H ;i ;7'ni PRC^N jOLT'DRS / EDO 1
1.1 / 17
SAMPLE DATE (MM/DD/YY) RAMPLE NUHDFE
12/03/87
12
TIME STAR"! TIME STOP
6:40 AM 7:00 AM
SAMPLE TIME (MIN.)
20 MIN.
SAMPLE VOLUME (!...) pA.iPu:;; tvpe (a, s, r)
2.16
c;
PUMP START FLOW : 100 CC/MIN.
""uMP STOP FLOW
100 COM Ur-.:.
(A"AREM, S-'SHON'! TERN, P^PLROONNEL)
'} F AREA s DESCRIBE
:
r AT EUP USED N - 7) : ,S
0 Llr j2 HOUR SHIFT
12
^HIF! (I; AY, NIGHT, EDO) EMPLOYEE I. D. v!
DAY /| tto A**=
Y\f T? !"<1 i ,*V J ^
CATCHINO EDC PROCESS SAMPLES,
RESPIRATOR TYPES
1-NONE, 2-MOUTHBIT, 3-C0MF0 II, 4=FULL FACE., 5=BREATHING AIR , 6-DUST MASK, 7=SCBA. `
ANAL. YTI GAL RESULTS
F..! C
fJOO 1
I HG 10
EL : N.DL.
ANALYSIS : 8 PJO'JF' i STD.
t
RESULT : TLV/TWA : TLV/TWA : AREA
< .01
. 01
0.995
., o :i
4 . 07'!'
.0,
AL.L. RE.SUL"! 3 IN PPM UNLESS OTHERWISE NOTED.
1 ON
WE 101
PPM VO,...Li ME Of RGLS IN AI
'N
(.0321;
ES K) (PPM FROM CHROMA!01
CPE
tMW) (L)
CARBON DISULFIDE USED FOR DESORPTION GAS CONSTANT (CONVERTS GRAMS TO LITERS) DECREE4* KELVIN (DEGREES CENT I BE ADR + 273) NOlECUlAN WEIGHT OF SPECIFIC COMPOUND L.ITERS Or' AIK SAMPLED
s
DO 077454 CONFTDENTTAL
DOW CHEMICAL LAD INDUSTRIAL HYGIENE SAMPLE CONCENTRATIONS
i RCL.. DATA ENTRY FORM
NAME. PLANT Pl.AIM!
NIKE BROWN ; SOLVENTS / EDC 1 :K ; .1.6 / 1,7
i SAMPLE DATE (MN/DD/YY) ; 12/03/87
TIME START r 1:25 PM
! SAMPLE NUMBER
: 13
TIME STOP : 1:30 PM
I SAMPLE TIME (MIN.)
: 05 MIN.
SAMPLE VOLUME (L.)
: .58
PUMP START FLOW : 100 CC/MIN.
SAMPuE TYPE (A, E, P)
:S
PUMP STOP FLOW : 100 CC/MIN..
(A*-AREA, S~ SHORT TERM, P-PERSONNEL ;
IF AREA, DESCRIBE
:
RESPIRATOR USED (1 - 7) ; 3
S OR 12 HOUR SHIFT
12
SHIFT (DAY ..NIGHT, EDO)
DAY
EMPLOYEE 1. D,, L
-r f \v, r. f *i * ;`*t
433945 CATCHING EDC PROCESS SAMPLES.i &
I RESPIRATOR TYPES : 1-NONE, 2-MQlJTHBIT, 3-COMFO II , 4=FULL FACE, 5-BREATHING AIR, 6-DUST MASK, 7-SCEA. '
ANALYTICAL. RESULTS
' FTC! . rrT
nr r"v [-,f~ r"-
I'-TP I
*
: ANALYSIS a 8 HOUR * STEL
.
.
DP L
; I HP * qtj:! MDL RESULT = TLV/tWA : TLV/TL'A : AREA
O'X'2 -3701 s 1 000 : 0
.01
< .01
2 "'002 - 3jJ lZ A, to ' . _ A r r- '' ! :
VXU -9--+3 - -999
; 0002'--3 687
5 0 .01 :
\0 :
.01
/y
rf
:
11)' ;
. 01
50 2 2v>0 ' B o 1 : 10 0 fftt . 01
< . 01
1 ,, 25
m
"7
Q.*n>
O
W
4.951 C.Oi
:
6.85 1 1O
NOTE : ALL RESULTS IN PPM UNLESS OTHERWISE NOTED.
<'
RCL EQUATION ?
PPM VOLUME OF RCLS IN AIR =
(WEIGHT OF CS2 IN GRAMS) (.0821) (DEGREES K) (F'RM FROM CHROMATOGRAM)
WHFF.
tW"v W --
,0821
iy.z GRcr
(MW) (L)
CARBON DISULFIDE USED FOR DESORPTION GAB CONSTANT (CONVERTS GRAMS TO LITERS) DEGREES KELVIN (DEGREES CENTIGRADE + 273) MOLECU-MR WEIGHT OF SPECIFIC CONFOUND LITERS OF AIR SAMPLED
HP:06/C3/0G
CO0t0slpj 7?4S* ~oe/vrr AC
DOW CHEMICAL LAD INDUSTRIAL HYGIENE SAMPLE CONCENTRATIONS
HEX DATA ENTRY FORM
NAME
: MIKE BROWN
PLANT
: SOLVENTS / EDO 1
PLANT $i : IS / 17
" -s- : - ~ -
- -= -- -- -- -- =- TM =-
..i w. :,===:= ii.=s SB sa as B: si .=.s=s= ct sseas ss, s= =; = = SS
=-==-= = --==-=!==Sis:a:==--==
SAMPLE DATE (MM/DD/YY) CAMPLE: NUMBER
12/22/87 hk 14
TIME START : 9:00 Al! TIME STOP : 2:00 PM
SAMPLE TIME (MIN.) SAMPLE VOLUME (L)
300 kk 34.99
PUMP START FLOW s 100 CC/MIN.
SAMPLE T/PE (A, S, P)
P
PUMP STOP FLOW : 100 CC/MIN.
(A--AREA, S-SHORT TERM, P -rHIRSONNEL.)
IF AREA,, DESCRIBE
4
RESPIRATOR USED (1 - 7) t 5
?? OF, J.2 HOUR SMl'-T
3
SHIFT (DATRNIGHT, EDO) 1 DAY
EMPLOYEE 1 .. D. ft
LABORER
cd decefm''7' ion
k CLEANING UP HEX SPILL AT D--13.
RESPIRATOR TYPES. i.l-IMONE, 2=MPUTHBIT,, 3=C0MF0 II, 4=FULL FACE, 5-BREATHING AIR, 6DUST MASK, 7=SCBA.
ANALYTICAL RESULTS
iCOMPOUND :
DR 4
I HQ s MDl t ANALYSIS t S HOUR TL.V
ir'CE 1 '..if-v;''
: 0002-13643 t 10@: .02*: . .')(.r.--q. . r:-~ ....................... . 02T:
90.7 40.9
I : .275.97 r 123.13
i
i AML
0007" 531.0 : 150$: .02*: 2.34
; t " PPM2 PPI . & PR .! IT F:,,LOD RESULTS IN ~'FS UNLESS ON ISRWIGE NOTED
:
6.38
NET r P'JAT - f.3 1
ORB VOLUME OF HEXES IN AIR (MR, (24.43) (3 000)
( L ) (MW ) (RF:)
WHERE : MG
- MICROGRAMS FROM SAMPLE DATA
24,43 - LITERS OCCUPIED BY 1 MOLE OF GAS AT STANDARD CONDITIONS
L = LITERS OF AIR SAMPLED
M: - I j L ,,L',,AR WEIGHT OF SPECIFIC COMPOUND
PR = RECOVERY RATE OF COMPONENT
MB:06/03/80
DO 0774S6 CONFIDENTIAL
DOW CHEMICAL LAD INDUSTRIAL HYGIENE SAMPLE CONCENTRATIONS
HE X DATA ENTRY FORM
i NAME | PLANT
i AN"!
LULL FROWN SOLVENTS / EDC 1 ,\6 / .17
SAMPLE DATE (MM/DD/YY)
12/22/87
SAMPLE NUMBER
: 15
SAMPLE TIME (MIN,)
s 300
SAIL'LL VOLUME (L)
76.73
SAMPLE 1YPE (A, S, P)
A
r.A" AREA, S:~ SHORT TERM, p: 'PERSONNEL)
IF AREA, DESCRIBE
D--13
RESPIRATOR USED (1 - 7)
S OR 12 HOUR SHIFT
St! I FT (DAY, MIGHT.. EDO)
DAY
EMPLOYEE .i D. #
;QB DESCRIPTION
10 FEET FROM
TIME START TIME STOP PUMP START FLOW PUMP STOP FLOW
CLEAN UP OF HEX SPILL
Vs00 AM 2:00 PM 100 CC/MIN 100 CO/MIN
AT D-13
RESPIRATOR TYPES
1.--NQNE j 2=M0UTHEIT, 3=C0MF0 II, 4=FULL FACE,"ET,:.F AT H 3. NG AIR.. 6;- -DUST MASK, 7^-SCBA.
ANALYTICAL RESULTS
IHB
MDL
ANALYSIS : S HOUR TL..V : AREA :
: 0002-36T3 : 100: .02*: : 0''C V-2375 : 20*: .02*:
y c.
: 64.64: 21.54:
: 0002- 3310 : ISO*: ,02)i:
r 06
.16:
I'M * ^ PPB, it = PPR IN BLOOD IN PPB UNLESS OTHERWISE NOTED.
-B VOLUME OF HEXES
AIR
(MG) (2^.45) (.1000)
(L) (MW) (RR)
WHERE : MG
== MICROGRAMS FROM SAMPLE DATA
74.40 - LITER: OCCUPIED BY 1 MOLE OF GAS AT STANDARD CONDITIONS
I. - LITERS OF AIR SAMPLED
MW = MOLECULAR WEIGHT OF SPECIFIC COMPOUND
P.R = RECOVERY RATE OF COMPONENT
MD:06/03/S8
DO 077457 CONFIDENTIAL
DOW CHEMICAL LAD INDUSTRIAL HYGIENE SAMPLE CONCENTRATIONS
RCL DATA ENTRY FORM
N PL r'.MT '.AN'
: MIKE DROWN : SOL VEN1 S EDC 1 ; 1.6 / 3.7
BAMfLE DATE (MM/DD/YY) : 12/30/87
CAMPLE NUMBER
: 16
SAMPLE TIME (MIM.)
: 240 MIN.
SAMPLE VOLUME (L)
: 31.86
| SAMPu.7 TYPE (A, 8, F`)
:P
j (A,-" AREA, Sr~ SHORT TERM , F-PERSDNNEL )
i IF AREA, DESCRIBE
:
TIME STAR`1 : 6:00 AM TIME STOP :10:00 AM
PUMP START FLOW : 100 CC/MIN. PUMP STOP FLOW : 100 CC/MIN.
j RESPIRATOR USED fl - 7) i 1
S U OR 32 HOUR SHIFT
: 12
| CH.I!" 1 ( DAV , NIGHT , P.Dui
EMPLOYEE I . D. +3
/ OB DECOR I!" !' ION
s DAY : 433914 : P/T OUTSIDE B.Q.T. PERFORMING NORMAL DAILY TOP
DUTIES INCLUDING ROUNDS.
RESPIRATOR TYPES
1=N0NE, 2-MOUTHBIT, 3C0MF0 II, 4=FULL FACE,
5~nREATHING AIR, 6--DUST MASH, 7-SCBA.
.-
ANALYTICAL RESULTS
LHE iSTEI.. M !
ANALYSIS : 3 HOUR RESULT : TLV/TWA
STE'L TLV/TUA : AREA
ETOL -r r
O2100 2-
, 03 I .01
< .01
0001 2 I
;(>(-! -j r . . ..i
lio i .01 :
< . 01
.38
. U-
200
.01 :
4.128
B-TRI
1 0 .01 ; <. 01
3| ,. -| TIN PPM UNLESS OTHERWISE NOTED,
RCL EQUATION :
PPM VOLUME OF RCLS IN AIR
(WEIGHT OF 082 IN GRAMS) (.0821) (DEGREES K) (PPM FROM CHROMATOGRAM 3
WHERE
CS2 f-\ C", ^
DE G'-'EE MW
(MW) (L)
= CARBON DISULFIDE USED FOR DESORPTION GAS CONSTANT (CONVERTS CRAMS TO LITERS) = DEGREES KELVIN (DEGREES CENTIGRADE + 273) = MOLECULAR WEIGHT OF SFECIFIC COMPOUND =- LITERS OF AIR SAMPLED
MB 2
00 0774K& confidentTAL
DOW CHEMICAL LAD INDUSTRIAL HYGIENE SAMPLE CONCENTRATIONS
RCI. DATA ENTRY FORM
NAME PLANT PL AN"'
KE DROWN 9 / EDC 1
/ 17
SA cr DATE (MM/DD/YY) : 12/30/87
TIME START i 6:00 AM
SAMPLE MUMPER
t 17
TIME STOP 10:00 AM
SAMPLE I ME (HIN.)
: 240 MIN.
SAMPLE VOLUME (L)
; 26.17
PUMP START FLOW 100 CC/MIN.
SAMPLE TYPE (A, .S, P >
:P
PUMP STOP FLOW : 100 CC/MIN.
(A*AREA, B-SHORT TERM, P-PERSONNEL)
IF AREA, DESCRIBE
RESPIRATOR USED (1 - 7)
1
E OR 12 HOUR SHIFT
12
SHIFT (DAY,MIGHT, EDO)
DAY
EMPLOYEE I. D. # * f^ p. r* | *** f"| pr "< ^ C"} J"!
s 431530 : P/T INSIDE O.S. PERFORMING NORMAL DAILY JOB
DUTIES INCLUDING OUTSIDE ROUNDS.
RESPIRATOR TYPES
l-NONE, 2-MOUTHBIT, 3=C0MF0 II, 4=FULL FACE,
5-BREATHING AIR, 6==DUST MASK,-7-SCBA.
ANALYTICAL RESULTS
CSMPQ. IMP
DR I!-
i ct-i
MOL
ANALYSIE RESULT
S HOUR TLV/TWA
TL7/ '
AREA
(.h.'OIl-
-j
i.)
< .01
`rE '002' 3354
< .01
P"- T',
''DP
1 0001- 3531 1
1 , i 1 `/ .A. 73
;
10 t 0 : >- 02 7 0 110 : . 01 I
<.01 .412
r
. 04
*a a *
|,
MMr- , -I" p- *p
r 0^02" 3698 * ; 0002" 3687 :
50 : 200 : .01
10 :
0
:
.01
3.453 :
< . 01
.24 _
ra :
a
NOTE : ALL. RESULTS IN PPM UNLESS OTHERWISE NOTED.
,-\,rw L EGUATI ON
PPM VOLUME OF RCLS IN AIR =
(WEICUT OF CS2 IN GRAMS) (.0821 (DEGREES K) (PPM FROM CHROMATOGRAM)
(MW) (L.)
WHERE : CS2
= CARBON DISULFIDE USED FOR DESORPTION
.0821
* GAS CONSTANT (CONVERTS GRAMS TO LITERS)
DEGREES K = DEGREES KELVIN (DEGREES CENTIGRADE + 273)
MW = MOLECULAR WEIGHT OF SPECIFIC COMPOUND
L - LITERS OF AIR SAMPLED
00 O77450 CONFTDNTial
DDW CHEMICAL. LAD INDUSTRIAL HYGIENE SAMPLE CONCENTRATIONS
HEX DATA ENTRY FORM
NAME
i MIL'S ElRUl-IN
PLANT
: SOLVENTS / EDG .1
PLAN'1 L : 16 / 1.7
SAMPLE
D
TE
(
MM/DD/'Y
i
s
/
CAMPLE NUMBER
12/30/87 *b IS
TIME START : 6:00 AM TIME STOP :10:00 AM
SAMPLE TIME (MIN.) SAMPLE Upl IS-i!"' (1^ )
*
240
b 24.4
PUMP START FLOW : 100 CC/M1N.
SAMPLE TYPE (A, S, P)
>P
PUMP STOP FLOW : 100 CC/MIN.
(A"AREA , S-SIIORT TERM , p =P ERSONNEL)
IF AREA , DESCRIBE
at
RESPIRA TOR USED CL _ 7)
b *i
<t
8 OR 12 HOUR SHIP"''
: 12
SWIFT (DAY.NIGHT, EDO) : DAY
EMPLOYEE I,. 0.. #
433625
JOD LLCCRYPTION
: INSIDE AHCL O.S. PERFORMING NORMAL DAILY JDS
DUTIES.
RESPIRATOR TYPES' :-1*N0NE, -2"M0UTHBIT-, 3*C0MF0 II, 4=FULL FACE,
5-DREATHI NS AIR, 6-DUST MAP'", 7-SCBA,
ANALYTI CAL. RESULTS
;
DR It
: IMG : MDL : ANALYSIS ; 8 HOUR TLV : AREA :
MCE
s 0002-3643 : 10: .0?f,
.22
:
.96
:
:
i-irro
- 0002- -r 310
20*'
150$
T' *
17
4.84
,56
LEY ; (;
"PM,
= PI'U, $ == PRB IN FLOOD
Y..L RESULTS IN PPF UNLESS D"''HERWI5E NOTED.
HEC
I ON
PPP VOLUME OF HEXES IN AIR ^ (MG) (24.45) (1000)
(L) (MW) (RR)
WHERE t MO
- MI GROGRAMS FROM SAMPLE DATA
24.45 - LITERS OCCUPIED BY 1 MOLE OF BAS AT STANDARD CONDITIONS:
L = LITERS OF AIR SAMPLED
r,W ^ MOLECULAR WEIGHT OF SPECIFIC COMPOUND
RR * REQOVFRY RATE OF COMPONENT
MD;06/03/88
00 077460 CONFIDENTIAL
DOW CHEMICAL LAD INDUSTRIAL HYGIENE SAMPLE CONCENTRATIONS
RCL DATA ENTRY FORM
NAME:
; M'! Ki: BROWN
PLANT
l SOLVENTS / EDC 1
PLAN"; # : 16 / ` 7
r,rz;:rrzr...-r = ::: ts=ss1= SB B= = = = SE ss sbss c.- ssss a as = =:S5 = !=: ss =;:= = = = srssss = = --.z=:tz. = zt.7=
SAMPLE DATE (MM/DD/YY) SAM,::,LE NUMBER
: 12/30/87 : 19
TIME START ; 6:00 AM TIME STOP :10r00 AM
SAMPLE TIME (MIN.)
SAMPLE VOLUME (L) SAMPLE TYPE (A, S, P) (A--AREA .. 3--SHORT TERM,
: 240 MIN. e 26.04 :A RaPERSONNEL)
PUMP START FLOW ! 100 CC/MIN PUMP STOP FLOW : 100 CC/MIN
i
IF AREA, DESCRIBE
: C-2
RESPIRATOR USED f1 - 7) G OR 12 HOUR SHIFT
SHIFT (DAY.NIGHT, EDO) : DAY
EMPLOYEE I, D. #
*
3OB DESCRIPTION
p
RESPIRATOR TYPES s 1-NONE, 2=M0UTHBIT, 3=C0MF0 II, 4>=FULL FACE, 5-BREATHJNO AIR, 6=DUST MAS!::, 7-SCBA.
ANALYTICAL RESULTS
r r"' t
!FL
J) V.
! : A NALYS1S : IMG EX: TEL : MEL : RESULT
3 HOUR : STEL TL'VTWA l. TLV/TWf-i
AREA)
E`( CL
r 0 002
oi e w..OO * 0 e .01 ;
< s 01
"rET
- 7002 365/ :
0 n C> 1 ; 26.259
1.97
!
*-
*.
rW`
irf"
0 TP I
. -oi 0371 : 9 V A3 :
: `POO 1 ""0 i . 00C2 -3607 s
10 E 0 e .01 : 75 e 110 e ,01 : tr*0 .. 200 e .03 ; i ri r 0 t . 01 ;
3 .175 . 158
9,48S < .01
. 14
. 02 . AA
MC'Y^ e ALL RES'J L TS 114 PPM UNL ESS OTHERWISE NOTED.
RCL EQUATION :
PPM VOLUME OF RCLS IN AIR
(WEIGHT OF CSE IN GRAMS) (.0821) (DEGREES K)
fj`
(MW) (L)
WHERE : CS2
CARBON DISULFIDE USED FOR DESORRT1ON
.0821
* GAS CONSTANT (CONVERTS GRAMS TO LITERS)
DEGREES K =* DEGREES KELVIN (DEGREES CENTIGRADE + 273)
MK * MOLECULAR WEIGHT OF SPECIFIC COMPOUND
L = LITERS OF AIR SAMPLED
MR: o6/o?` /r?C
00 077461 CONFIDENT! Al
DOW CHEMICAL LAD
INDUSTRIAL HYGIENE SAMPLE CONCENTRATIONS i RCL DATA ENTRY FORM
NAME
: MIKE BROWN
FI_ANT : SOLVENTS / EDC i
PLAN'; T
16 / 3.7
SAMPLE DATE (MM/DD/YY)
12/30/87
TIME START : 6:00 AM
SAMPLE NUMBER
20
TIME STOP :10:00 AM
SAMPLE TIME (MIN.)
240 MIN.
SAMPLE VOLUME (L.)
28.52
PUMP START FLOW 100 CC/MI N.
SAMPLE TYPE (A, S: P)
P
PUMP STOP FLOW
iOO CC/MI N.
(M:-APEA j, 5"SHORT TERM, F'--=PERSONNEL
IF AREA,, DESCRIBE
:
RESPIRATOR USED (i - 7)
1
0 OR 12 HOUR SHIFT
: 12
CM in (DAY, NIGHT.. EDO) r DAY
EMPLOYEE I. D. #
i5
,7OB DESCRIPTION
: INSIDE AHCL O.S. PERFORMING NORMAL DAILY JOB
DUTIES WITH NO OUTSIDE ROUND.
RESPIRATOR TYRES : l--NONE, 2=M0UTHBIT, 3=-C0MF0 II, 4=FULL FACE,
-5-BREATHING AIR, 6=DUST MASK, 7=SCBA,
ANALYTICAL RESULTS
ANALYSIS 8 HOUR
STEL
OF
DP 0
IMG
TEL
MDL
RESULT
TLV/TWA TLV/TWA AREA
: 0002-3701: .1000
.<.01
, /002-L6 5-: : 5
n
< . 01
EDC
r OOOi-8531 10 : 0 : .01
. 935
. 3 (!) :
TR
r. 000.1--9943 : 75 : 110
.03 :
r 0002--3698 : 50 : 200 : .01 :
.4 75 T O /,, 0
* p rfU W vO
. 04 :
r 'J4l-
.
D TRI
0002-3687 : 30 : 0 : .01 :
< . 01
RESULTS IK PPM UNLESS OTHERWISE NOTED.
RCL POLY
PPM VOLUME OF RCLS IN AIR =
'WEIGHT OF CS2 IN GRAMS) (.0821 (DEGREES K) (PPM FROM CHROMATOGRAM)
WHERE
i
! !
CS2 .0821 DEGREE l'1W
(MW) (L)
CARBON DISULFIDE USED FOR DESORPTION GAS CONSTANT (CONVERTS GRAMS TO LITERS) DEGREES KELVIN (DEGREES CENTIGRADE + 273) MOLECULAR WEIGHT OF SPECIFIC- COMPOUND LITERS OF AIR SAMPLED
MB / .>3/GO
00 077462 CONFIDENTIAL
DOW CHEMICAL LAD INDUSTRIAL HYGIENE SAMPLE CONCENTRATIONS
RCL DATA ENTRY FORM
NAME
: .MIKE BROWN
PLANT
: SOLVENTS / EDO 1
PLANT ti : 1.6 / 17
SAMPLE DATE (MM/DD/YY) : 12/30/87
TIME START : 6:00 AM
SAMPLE NUMBER
: 21
TIME STOP :10:00 AM
SAMPLE TIME (MIN.)
: 240 MIN.
SAMPLE VOLUME (L)
t 26.05
PUMP START FLOW : 100 CC/MIN.
SAMPLE TYPE (A, S, P)
:P
PUMP STOP FLOW : 100 CC/MIN.
(''."AREAS:-SHORT TERM, P-PER30NNEL)
IF AREA, DESCRIBE
RESPIRATOR USED (1-7) : 1
8 OR 12 HOUR SHIFT
: 12
SHIFT (DAY 5 NIGHT, EDO) : DAY
EMPLOYEE I. D. #
: 431633
BOB DESCRIPTION
; INSIDE EDC O.S. PERFORMING NORMAL DAILY ,?QB
DUTIES WITH NO OUTSIDE ROUND.
RESPIRATOR TYPES 1=N0NE^ 2--MDUTHBIT, 3-C0MF0 II, 4-FULL FACE,. . .
5"BREATHING AIR, 6=DUST MASK, 7=SCBA.
ANALYTICAL RESULTS
r :ji i. i ETC!.. 'I r-f SBC
rcr'' --. n-r- y
= )P 4
T*. i*Jir-a3
f.e c.tI tj-,ii, ,
.
p
iMi irt
ANALYSIS : 8 HOUR RESULT : TlV/TWA
' V 0 0 2 3701 : .1000 s 0
; 00 / . , 3654 0 0 01- n i " "7 H :
5 10 r
0 0
: 0 0 t's ,iA. , 9943
75 ; 110
, 01 . 01 .01 s . 01
< . 01
<.01 . 534
. 06
O'' 02- 3690 ; 30
uO 02-
; j. n
200 p p 0 2 0 p .01 r
3 ,S?4 < . 01
STEL
;
TLV/TWA : AREA
N3TC : ALL RESULTS IN PPM UNLESS OTHERWISE NOTED.
POL EQUATION :
PPM VOLUME OF RCLS IN AIR =
(WEIGHT OF CS2 IN GRAMS) (.0321) (DEGREES K) (PPM FROM CHROMATOGRAM)
(MW) (L)
WHERE : 052
= CARBON DISULFIDE USED FOR DESORPTION
.0G21
- GAS CONSTANT (CONVERTS GRAMS TO LITERS)
DEGREES I- : DEGREES KELVIN (DEGREES CENTIGRADE + 273)
11W == MOLECULAR WEIGHT OF SPECIFIC COMPOUND
' L LITERS OF AIR CAMPLED
hip . t / c / rj ~>
DO 077463 CONFTDENTIA!
DOW CHEMICAL LAD INDUSTRIAL HYGIENE SAMPLE CONCENTRATIONS
RCL DATA ENTRY FORM
NAME
: LIKE DROWN
p; sr;
^ SC!..VENTS / EDC 1
p! f.'OO F ; j v, / 17
SAMPLE DATE (MM'DD.'YY) : 12/30/87
TIME START s 6s00 AM
RPMPL E NUMBER:
: 22
TIME STOP :10:00 AM
SAMPLE TIME. (MIN.)
: 240 MIN.
SAMPLE VOLUME (L)
: 24.86
RUMP START FLOW : 100 CC/MIN.
SAMPLE TYPE (A, S, P) s P
PUMP STOP FLOW : 100 CC/MIN.
(A"AREA,, B"SHORT TERM, P--PERSONNEL )
IF AREA, DESCRIBE
RESPIRATOR USED (1-7) : 1
8 OR 17 HOUR SHIFT
: .12
DRIFT (DAY j, NIGHT, EDO) j DAY
EMPLOYEE I D, -
: 433366
.SB D23CR? nION
s INSIDE EDO O.S. PERFORMING NORMAL DAILY JOB
DUTIES INCLUDING AN OUTSIDE ROUND.
RESPIRATOR TYPES : 1=N0NE, 2-MQUTHBIT, 3-COMFO II, 4=FULL FACE,
""BREATHING AIR, 6=DUST MASK,' 7-SCBA.
ANALYTICAL RESULTS
ANALYSIS ; 8 HOUR : STEL
:
D MiOL RESULT ; TLV/TWA : TLV/TWA : AREA
".>002- 7701 slOOO
01
IT 0002-3634
.01 , 01
003) ; 10
<_>
.01
200 ;
, 06 34
1.0 > 0
I ,01
RESULTS IN! `PM UNLESS OTHERWISE NOTED.
02L EOU.MVON
PPM VOLUME OF RCLS IN AIR ~
OF CS2 IN GRAMS) (.0821) (DEGREES K) (PPM FROM CHROMATOGRAM;
WHERE
CS2 .0021 degree: MW
(MW) (L)
CARBON DISULFIDE USED FOR DESORPTION GAS CONSTANT (CONVERTS GRAMS TO LITERS) DEGREES KELVIN (DEGREES CENTIGRADE + 273) MOLECULAR WEIGHT OF SPECIFIC COMPOUND LITERS OF AIR SAMPLED
MB ' 0:nO; / ' if'
DO 077464 CONFTDFNTIAI
DOW CHEMICAL LAD INDUSTRIAL HYGIENE SAMPLE CONCENTRATIONS
HEX DATA ENTRY FORM
NAME
. MILE BROWN
PLAN"! i SOLVENTS / EDC 1
PLANT 1' ; .1,6 / 17
SAMPLE DATE (MM/L'D/YV) : 12/30/87
TIME START : 6:00 AM
SAMPLE MUMPER
: 23
TIME STOP : 10:00 AM
SAMPLE TIME (MIN.)
: 240
S/T-PLE VOLUME (L)
t 21 P-16
PUMP START FLOW : 100 CC/MIN,.
SAMPLE TYPE (A, S, P)
:P
PUMP STOP FLOW : 100 CC/MIN.
A-AREA, Sr:;SHORT TERM , P-PERSONNEL)
IP AREA, DESCRIBE
:
RESPIRATOR USED (1-7) i 1
'JR 12 HOUR SHIFT
: 12
SHIFT (DAY,NIGHT, EDO) i DAY
EMP... I YES l .. D . 4.;:
; 431530
I 03 DESCRIPTION
: P/T INSIDE O.S. PERFORMING NORMAL DAILY JOB
DUTIES.
REST IPATOR ~YFE5 1"NONE-, 2-MOUTHBI-T, 3--C0MFQ I I, 4-FULL FACE,-
5'-ERF ATM).NG AIR, 6-DUST MASK, 7"SCBA.
ANALYTICAL RESULTS
COMPOUND
DF
IHG : MDL ANALYSIS: 8 HOUR TLV
AREA
hoe
.102: .02#
. 3 : 1.49
-If P"'
2 O1# : . 1ZOT: .02#
1.1 i .13
1 5,,45 t .67
'PM,
PPE, t = PPB IN EL ODD
ALL RESULTS IN FT'D UNLESS OTHERWISE NOTED.
F'F 3 VOLUME OF HEXES IN AIR (MS) (24.45) (1000)
(L) (MW) (RR)
U-iERE
MG - MICROGRAMS FROM SAMPLE DATA 24.45 - LITERS OCCUPIED BY 1 MOLE OF GAS AT STANDARD CONDITIONS L - LITERS OF AIR SAMPLED MW - MOLECULAR WEIGHT OF SPECIFIC COMPOUND RR = RECOVERY RATE OF COMPONENT
MB:06/03/SB
DO 077465 CONFIDENTIAL
y't cm
DOW CHEMICAL LAD INDUSTRIAL HYGIENE SAMPLE CONCENTRATIONS
HEX DATA ENTRY FORM
NAME PLANT PLANT
: MIKE BROWN t SOLVENTS / EDO 1 : 3- 0 / 1.7
SAMPLE DATE fMM/DD/YY) : 12/30/87
TIME START : 6:00 AM
SAMPLE NUMBER
: 24
TIME STOP : 10:00' AM
SAMPLE TIME (MIN.)
: 240
AMPLE VOLUME (L)
r 29.42
PUMP START FLOW : 1.00 CC/MIN,
AMPLE TYPE (A, S, P)
sP
PUMP STOP FLOW : 100 CC/MIN,
; A:- AREA, S-SHORT TERM, P=PERSONNEL )
IF AREA, DESCRIBE
:
RESPIRATOR USED (1-7) : 1
0 OK 12 HOUR SHIFT
: 12
SH3FT (DAY,NIG!-IT , EDO) : DAY
EM"1' C-VEE I. D. *
: 433914
3OR Dl,-UUH7rTJ'0N
: P/T OUTSIDE S.O.T. PERFORMING NORMAL DAILY JOB
DUTIES INCLUDING ROUNDS.
RESPIRATOR TYPES 1 -i"NONE, -2M0UTHBIT, 3=C0MF0 II, 4=FULL FACE,
5 "-BREATH I NO AIR, 6=DUST MASK. 7==SCBA.
-ANALYTICAL RESULTS
COMPOUND ;
DR +1
: I HE : MDL : ANALYSIS : B HOUR TLV : AREA
HOE
: 0O02-3643 : 100: .02#:
.29
:
1.05
:
:
1-nSD
. 0009--237E : 20*.: ,02*:
i.Oj
HE 03
0002-3310 : !30S; .02?:
14
:T3' - o - - jp:*,
, !. : rs. _ I > -j|"c..: vii
- ppi-, $ p*| I 11 I_, Lp.- c-'.C.j" unj Ti gr ,,1- RW1SE NOTED,
; .
u
5.84 Are
h *T
:
*
;
r!F \ E' 3 U riTIn N :
PPB VOLUME OF HEXES IN AIR (MG; (24.45) (1000)
(LI (MW; (RR)
WHERE
MG ^ MICROGRAMS FROM SAMPLE DATA 24.4 5 LITERS OCCUPIED BY 1 MOLE OF GAS AT STANDARD CONDITIONS
- LITERS OF AIR SAMPLED =- MOLECULAR WEIGHT OF SPECIFIC COMPOUND ---RR RECOVERY RATE OF COMPONENT
MB;06/03/SB
DO 077466 CONFIDENTS
DOW CHEMICAL LAD
industrial hygiene sample concentrations
HEX DATA ENTRY FORM
NAN'i.
; NIKE DROWN
PLANT
r SOLVENTS / EDO 1
plait h is / 17
:.n :r : =. =:: a : sx sr r*t rs. :22 ar lfj *: -a -- :sr r? r=: rz\ " rr sr rzisr: "#.ws rr-s::'^!^"=:ar:srax;:^r:-:rr:ss=sssi srat 2=: = "TM:
= r= =: r" :=-s=sar===:
sz as sa* as tsr sr; as: sr
SR: 1FL-L DATE (MM/DD/YY) SAMPLE NUMBER
12/30/97
t. dH Ik*
TIME START * 6:00 AM TIME STOP 8:00 AM
SAMPLE TIME (MIN.) SAMPLE VOLUME (L) SAMPLE TYPE (A, S, P)
# 120
t 12. AS :A
PUMP START FLOW * 100 CC/MIk PUMP STOP FLOW t 100 CC/MIN
(A^AREA, S ""SHORT TERN, P-F'ERSONNEL)
IF AREA, DESCRIBE
: D-13
F;ESD JR'AT OR USED (I - 7 ) : 9 OR 12 HOUR SHIFT
SHIFT (DAY,NIGHT, EDO) : DAY
L! T lC YLE I, D. #
:
JOB DESCRIPTION
: MONITORING FROM SAME PLACE AS ON 12/22/87,
SAMPLE #15.
RE Pi'-'1'PAT OF, TYRES : 1-NONE. 2=M0UTHBIT', 3="C0MFQ II, 4-FULL FACE,
5 - BRLAT! 11 NO AIR, 6-DUST MAST., 7*5CBA.
AUALYTICAL RESULTS
l jf
!ih::DD
A
00/ ?- 2
s 1IHG : MDL s ANALYSIS : S HOUR TLY :, AREA :
i AQ 02't
At:
P!
20 :v . 02* : 2,, L
21.6
1 ' r' y 0
ALL r*i.r
fJ U v j. \ 1504; 02 v
FT'' 1, * - PPL', $ - FTT IN BLOOD 2 IN ITT: UNLESS OTFOTWISE NOTED
't )N
PPL VOLUME OF HEXES IN AIR ,, MO) 1.24.45) (1000)
(L) (MW) < RR)
WHERE ; MG
= MICROGRAMS FROM SAMPLE DATA
24.45 LITERS OCCUPIED BY 1 MOLE OF GAS AT STANDARD CONDITIONS
1. - LITERS OF AIR SAMPLED
MV = MOLECULAR WEIGHT OF SPECIFIC COMPOUND
RR - RECOVERY RATE OF COMPONENT
*'1B: 06-'03/38
00 077467 CNFTOE/VTrAL
DOW CHEMICAL LAD INDUSTRIAL HYGIENE SAMPLE CONCENTRATIONS
HEX DATA ENTRY FORM
NR Mil.
r MIKE BROWN
f-LAM'i
r SOLVENTS / EDC 1
p:Ti.` i ; L / J 7
SAMPLE'. DATE (MM/DD/YV ) : 12/TO/87
SAMPLE NUMBER
: 26
SAMPLE TIME (MIN.)
: 240
SAMPLE VOLUME (L..) ! SAMPLE TYPE (A, S, P)
: 22.33 :A
j (A-RREft, S^SHORT TERM, R=PERSONNEL)
j IF AREA, DESCRIBE
t TQX
PEEP 1PATOR USED (JL - 7) s
j S CR 12 HOUR SMIFI
:
SHIFT (DAY .NIGHT., EDO) : DAY
CMPLQ\YE 3. D #
:
JOE DESCRIPTION
:
TIME START : 6:00 AM TIME STOP :10:00 AM
PUMP START FLOW : 100 CO/MIN. PUMP STOP FLOW : 100 CC/MIN.
RE`": IRATMR TYPES-; -l^NONE, 2"::MGUTHEIT, V^COMFD II, 4-FULL FACE,. 0-"BREATH 11 :G A J R , 6 = DUCT MASK . 7-5CBA
ANALYTICAL RESULTS
! r.0Mr--0.:-!D t
DP
: IHB ; MDL : ANALYSIS : B HOUR TLV : AREA
iI &
'j2%
29
1.38;
r 11 os 2375 ; 20*': .02?
i 1 3"*
"ID"
^ i:,, T1-.
; . T'2'i'l
LTD' ; e ~ "PM, * ~ FT'S. $ = PPB IN BLOOD ALL RZCL'i-TC IK Pr'T UNLESS C TT !L: <W ISE NOTED.
PPB VOLUME OF HEXES IN AIR (MG) (24.45) (1000)
(L) (MW) (RR)
WHERE : MG
== MICROGRAMS FROM SAMPLE DATA
24.45 LITERS OCCUPIED BY 1 MOLE OF GAS AT STANDARD CONDITIONS
L " LITERS OF AIR SAMPLED
MW MOLECULAR WEIGHT OF SPECIFIC COMPOUND
RR = RECOVERY RATE OF COMPONENT
MB s06/03/8S
DO 077468 CONFIDENTIAL
DOW CHEMICAL LAD INDUSTRIAL HYGIENE SAMPLE CONCENTRATIONS
RCL DATA ENTRY FORM
NAME:
: MIKE BROWN
PLANT ; SOLVENTS / EDO 1
PLAI-P E ; , id, / 17
SAMPuE DATE (MM/DD/YY) ! 12/31/87
SAMPLE NUMBER
i 27
SAMPi-E TIME (MIN.)
: 240 MIN.
SAMPLE VOLUME (L)
: 27.36
SAMPLE TYPE (A, S, P) : A
(A-AREA, S-SHORT TERM, PPERSONNEL)
IF AREA. DESCRIBE
: D~2C
RESPIRATOR USED (1-7) :
Q OP 12 HOUR SHIFT
:
-21! I fi ( DPY ,, NIGHT , EDO ) : DAY
EMPLOYEE: I . D. L
:
CP DESCRIPTION
i
TIME START : 6:00 AM TIME STOP :10:00 AM
PUMP START FLOW : 100 CC/MIN. PUMP STOP FLOW : 100 CC/MIN.
RESPIRATOR TYPES : i=NONE, 2M0UTHBIT, 3-COMFO II, 4-FULL FACE, ' 5==BREATHING AIR, 6 -DUST MASK, 7=^SCBA.
ANALYTICAL RESULTS
; SSrPCCHD t
DR H
: : : : ANALYSIS : IMG : STEL : HDL : RESULT
S HOUR TLV/TWA
STEL TLV/TWA
AREA
TET
0002- 301 [1000 : 0
<.01 < . 01
OOO 'I -"'.'VI-- .
1*
110 : .01 i
< . 01 . 474
. 10
'Ll';
OLD2- 31 CD r
200 : .01 :
3.303
.44
0 : .01 :
< . 01
F ;ESUL,' IN PPM UNLESS OTHERWISE NOTED.
"CL EQUATION
PPM VOLUME OF RCLS IN AIR =
(WEIGHT OK' CS2 IN GRAMS)
0821) (DEGREES K) (PPM FROM CHROMATOGRAM;
(MW) (L)
JHERE : CS2
* CARBON DISULFIDE USED FOR DESORPTION
. 0021
= GAS CONSTANT (CONVERTS GRAMS TO LITERS)
DEGREES K * DEGREES KELVIN (DEGREES CENTIGRADE + ,273)
MW - MOLECULAR WEIGHT OF SPECIFIC COMPOUND
L * LITERS OF AIR SAMPLED
-0? : 06 - 03 / PC
DO 077469 CONFIDENTIAL
DOW CHEMICAL LAD INDUSTRIAL HYGIENE SAMPLE CONCENTRATIONS
RCL DATA ENTRY FORM
I NAME
: MIKE BROWN
Plant
: solvents / edc i
PLANT M i IS / 17
sample: date (mm/dlvyy)
12/31/87
SAMPLE NUMBER
28
SAMPLE TIME (MIN.)
240 MIN.
SAMPLE VOLUME (L)
26.36
SAMPLE TYPE (A. S, P)
:A
( A:" AREA , S-8HQR7 TER. 1, P^PERSCNNEL)
IF AREA, DESCRIBE
: C-1C
RESPIRATOR USED (1-7) t
0 OR 12 HOUR SHIFT
:
SHIFT (DAY ...NIGHT, EDO) : DAY
EMPLOYEE I D. L
:
LOB DESCRIPTION
:
TIME START t 6:00 AM TIME STOP i10:00 AM
PUMP START FLOW PUMP STOP FLOW
100 CC/MIN. 100 CC/MIN.
RESPIRATOR TYPES
1~N0NE, 2=MDUTHBIT, 3-COMFG . I, I , 4-FULL FACE,, 5-"BREATHING AIR, 6-DUST MASK, 7=SCBA.
wONPO',, N L: ;
r>K; ;
ANALYTICAL RESULTS
*a aa * ANALYSIS : 8 HOUR : STEL aa : IHG . cvy pi u MDL k RESULT : TLV/TWA : TLV/TWA a AREA i
ETCL
* 0002-3701 : 1000 : 0 : . 01 <.01 :
*k
TET
0002-3634 i*
:IV, 0 : .01
< . 01 :
'
EDC ! 0001-8331 : 10 i 0 s .01 <.01 : m :
PDC
0001-9943 : 75 : 110 : . 01
. 3 So :
ft rC*"."'*1 0002- 3690 : 50 : 200 : .01 a 4.175 :
km
a
. 08: .58:
E- TRI
r 0002-3687
10 :
0
s
. 01
k
< .01
:
*
*
NOTE : ALL RESULTS IN PPM UNLESS OTHERWISE NOTED.
POL EQUATION :
PPM VOLUME OF RCLS IN AIR =
(WEIGHT OF CS2 IN GRAMS) (.0821) (DEGREES K) (PPM FROM CHROMATOGRAM)
(MW) (L)
WHERE : CS2
= CARBON DISULFIDE USED FOR DESORPTION
.0821
= GAS CONSTANT (CONVERTS GRAMS TO LITERS)
DEGREES K = DEGREES KELVIN (DEGREES CENTIGRADE + 273)
MW - MOLECULAR WEIGHT OF SPECIFIC COMPOUND
L = LITERS OF AIR SAMPLED
- m, / C
DO 077470 CONFIDENTIAL
DOW CHEMICAL LAD INDUSTRIAL HYGIENE SAMPLE CONCENTRATIONS' *
RCL DATA ENTRY FORM
NAME
: NIKE BROWN
- L ANT
: SOI..VEN TS / E DC 1
plant n : 16 / ? '7
SAMPLE DATE (MM/ DD/YY)
SMLK'LE NUMIER
SAMPLE TIME (MIN . )
SAMPLE VOLUME (L )
SAMPLE TYPE (A, s. P)
A': AREA , S-SHORT TE RM,,
IF AREA , DESCRIBE
RESPIRATOR USED (1
/
9 OR 12 HOUR SHI FT
SHIFT ( DAY,N1GMT , EDO)
EMPLOYE E I D. #
'OB DESCRIPTION
: 12/ 31/87 * 3Q
s 24: MIN. : 26. 16 :A F =PERS CNNEL) : R-iC 2 2
: DAY ;
:
TIME START i 6:00 AM TIME STOP 10:00 AN
PUMP START FLOW : 100 CC/M1N. PUMP STOP FLOW : 100 CC/MIN.
PEEP IRATOP .TYPES .
lTM NONE., 2C3. t - T7 RE AT!-'JR
MOUTHBI fbn rI .i *1j rK** ^
T 6
5 =
ANALYT IC
r "`i; '[ ; I.' i
I>F.
* ft : ANALYSIS ! S HOUR 3TEL
I MS : S 7FL ; !v 7L
RESULT : TLV/TWA : TLV/TWA : AREA
ETCL
i 0C02- 370 H t 10 00 : 0 *' 0 'i
1.0.1
:
t:
;
TET
; 0002 7i <, 4 :
5 r 0 ; . o.t
<.01:
:
:
EDC
r 7 C1 11 W . u 4i- *.
0 i 01
<, 01
t
:
:
RDC :'ER
0001 994 3 : s 0" 02- CIS r^"` i
70 : 110 : . 01 710 : 200 : . C) ^
.801. : 6.01''! :
:
: .16 i .94
r TP I
: 000.0" 360 ~7 i ?'> : c : ,, 01
'.inTr h ILL PESUi... T : 1 ,! pr* N UNL ESS OTHER
<.01
E
l NOTED.
:
:
RCL EQU ^ T j n i j
PPM VOLUME OF
(WEIGHT OF CS2 IN GRAMS) (.0321 )
WHERE
. OCR? DCOREC S
< MW) (L)
CARBON DISULFIDE USED FOR DESORPTION GAS CONSTANT (CONVERTS GRAMS TO LITERS) DEGREES KELVIN (DEGREES CENTIGRADE + 273) MOLECULAR WEIGHT OF SPECIFIC COMPOUND LITERS OF AIR SAMPLED
00 077471 CONFIDENTIAL
DOW CHEMICAL LAD INDUSTRIAL HYBIENE SAMPLE CONCENTRATIONS
RCL DATA ENTRY FORM
NAME
: MIKE BROWN
PLANT : SOLVENTS / EDO 1
PLAN"'" li s J 6 / 17
SAMPLE.' DATE (MM/DD/YY) : 12/31/87
SAMPLE NUMBER
: 30
SAMPLE TIME (MIN.)
: 240 MIN.
SAMPLE VOLUME (L)
: 24.lO
SAMPLE TYPE (A, S, F) : A
(A--AREA. S~SHORT TERM, R = PERS0NNEL )
IF AREA. DESCRIBE
: C-S9
RESPIRATOR USED (1-7) :
S OR 12 HOUR SHIFT
SHIFT (DAY.NIBHT, EDO) : DAY
EMPLOYEE I, D. :
:
TDD DESCRIPTION
:
TIME START : 6:00. AM TIME STOP i10*00 AM
PUMP START FLOW : 100 CC/l'ilN. PUMP STOP FLOW : 100 CC/MIN.
RESPIRATOR TYPES ' i' l-NOMEI, `2-MOUTHBI T, 3=C0MF0 II, 4-FULL FACE,' 5-BREATHING AIR, 6-DUST MASK, 7-SCBA.
' ANALYTICAL RESULTS
ji ::
ITTPI
rv B T AI
s : ; : ANALYSIS ; 8 HOUR : STEL i IHG : STEL... : MDL : RESULT s TLV/TWA : TlV/TWA
: 0002-r70) si 000 : 0 . 03.
-A
36 L 4 ;
5 [ f'l 5 . 01 :
<.03 <.01
, ` C ?1 0231 i ,, ;>001 7743 ;
30 : 0 75 ; 110
. 03. e . 01 i
< . 03. .817
i 0002- 367 S : . 0:;:. 3607
50 : 200 : 01 : 10 * 0 * b lJ J. i
2.907 <.01
AREA
. 18 .44
NOTE . ALL RESULTS IN PPM UNLESS OTHERWISE NOTED.
PCL COMAT I ON s
PPM VOLUME OF RCLS IN AIR =
(WEIGHT OF CS2 IN GRAMS) (.0821) (DEGREES K) (PPM FROM CHROMATOGRAM)
WHERF
: CSC .0921 DOT" PL, HW
(MW) (L)
CARBON DISULFIDE USED FOR DESORPTION CAST CONSTANT (CONVERTS GRAMS TO LITERS) DEGREES KELVIN (DEGREES CENTIGRADE + 273) MOLECULAR WEIGHT OF SPECIFIC COMPOUND LITERS OF AIR SAMPLED
DO 077472 CONFIDENTS
DOW CHEMICAL LAD INDUSTRIAL. HYGIENE SAMPLE CONCENTRATIONS
RCL DATA ENTRY FORM
NAME PLANT PLAN"
: MIKE BROWN i SOLVENTS / i -- / 17
EDC 1
SAMPLE DATE (MM/DD/YY) : 12/31/87
SAM? 'LE NUMBER
: 31
SAMPLE TIME (MIN.)
: 180 MIN.
SAMPLE VOLUME (L)
; 20.02
SAMPLE TYPE (A, S, P)
:A
( A-- AREA , S--SHORT TERM, P^PERSONNEL)
IF AREA, DESCRIBE
: TOX
RESPIRATOR USED (1-7 ) :
h OR 1? HOUR SHIFT
s
SHIRT (DAY,NIGHT, EDO) : DAY
EM-'t..C\T:E ? - D, L ;UB DCSLPiPTION
: j
TIME START t 6:00 AM TIME STOP : 9:00 AM
PUMP START FLOW PUMP STOP FLOW
100 CC/MIN. 100 CC/MIN.
RECTOR/'TOR TYPE!
i~NONE, 2--MDUTHBIT, 3-COMFO 11 , 4-FULL FACE S"BREATHING AIR, 6-DUST MASK, 7-SCBA.
ANAI..YTICAL RESULTS
OF- '!:
: : : ANALYSIS : 8 HOUR : I HO : ST EL : MDL t RESULT : TLV/TWA
0002- 3701 ilOOO
r.
. 01
STEL XV/TWA
.. X
(
u.
01 :
. oi < .. Oi
i ;L 1 =
; 110 : .01 :
2-
DO ; 200 : .01 :
4.34 4
o
i
-IS IN F*FM UNLESS OTHERWISE NOTED.
PEL EQUATION :
PPM VOLUME OF RCLS IN AIR =
(WEIGHT OF CS2 IN GRAMS) (.0021) (DEGREES K) (PPM FROM CHROMATOGRAM)
WHEE : CSC . x DEGRFEES K
(MW) (L)
CARBON DISULFIDE USED FOR DESORPTION DAE CONSTANT (CONVERTS GRAMS TO LITERS) DEGREES KELVIN (DEGREES CENTIGRADE + 273) MOLECULAR WEIGHT OF SPECIFIC COMPOUND LITERS OF AIR SAMPLED
00 077473 CONFIDENTIAL
DOW CHEMICAL LAD INDUSTRIAL HYGIENE SAMPLE CONCENTRATIONS
RCL DATA ENTRY FORM
f'A, <c:
s mime brown
: SOLVENTS / EDO 3
PL. AN': f : L / 17
SAMFLE DATE (MM/DD/YY) SAMPLE NUMBER
: 12/31/87 h ~T O
SAMPLE TIME (MIN.)
t 240 MIN.
SAMPLE VOLUME (L;
* vJ l m.' -"*
SAMPLE TYPE (A, S. P)
sA
(A-ARE- , S:-SHORT TERM,. F^PERSONNEL
IF AFI'EA, DESCRIBE
: 0*13
":CT :'H-V7 PR USED (l - 7) k
S (JR 12 HOUR SHIFT
p
SHIFT (DAY,NIGHT, EDO) : DAY
EMPLOYEE I. D. L YGP; DlG'CR] FTIDN
:
tsa: TIME START : 6;00 AM TIME STOP :10i00 AM
PUMP START FLOW PUMP STOP FLOW
100 CC/MIN. 100 CC/MIN.
i.FLi C'JRATDR T VpF: v
L-NDNE,
-MDUTHBIT, 3=C0lir0 II* 4-FULL FACE j MO AIR, L-OUST MASK, 7-SCBA.
ANALYTI CAL RESULTS
ANALYSIS
KG
;
r--
w
-ri
fL:-1.l.
:
MSI.
i
RESULT
S HOUR : STEL : TLV/TWA r TLV/TWA ; AREA
PEP
-v1 " ' c" /> 1 - r?'r,/3
CO . p L * 0 1 r
CL ,
c
') L
v . f" i * ' L
7 5 ;
110
m
( m4
i
50 , 200 ; b Q 1 :
10 ;
t ** \ * L
..03 <.01 5.27l <.01 1.97-7 <.C1
2. . JL
' tt: M UN LESS DIMERL1 I EE NOTED
PCI lT.
PPM VOLUME CP RCLS IN AIR =
(WEIGHT OF CSC IN GRAMS)
0021) (DEGREES K) (PPM FROM CHROMATOGRAM)
(HERE
CSC s 0021 DEGREES MU
(MW) (L)
CARBON DISULFIDE USED FOR DESORPTION - GAS CONSTANT (CONVERTS GRAMS TO LITERS)
DEGREES KELVIN (DEGREES CENTIGRADE + 273) - MOLECULAR WEIGHT OF SPECIFIC COMPOUND = LI I ERG OF AIR CAMPLED
DO 077474 CONFIDENTIAL
DOW CHEMICAL LAD INDUSTRIAL HYGIENE SAMPLE CONCENTRATIONS
RCL DATA ENTRY FORM
uni-::::
: mike brown
RL.'.R'!
: SOLVENTS: / EDO 1
!". nr.: 0 i 1.6 / 1.7
SAMPLE DATE (KM/DD/YY)
12/31/07
TIME START : 6:00 AM
SAMPLE NUMBER
TIME STOP :10:00 AM
SAMPLE TIME (MIN.I
: 240 MIN.
| SAMPLE VOL.'JME (L)
t 25.50
PUMP START FLOW : 100 CC/MIN.
! SAMPLE TYPE (A, S, F)
rP
PUMP STOP FLOW : 100 CC/MIN.
(A-'ARE.A, S-SHORT TERM, P-PERSONNEL)
IF AREA, DESCRIBE
RESPIRATOR USED (1-7)
9 OP 12 HOUR SHIFT
12
SHIFT (DAY,MIGHT, EDO)
DAY
EMPLTYLE 1. D. 8
434213
JOB DESCRIPTION
SAMPLE O.T. FOR P/T AND EDC INCLUDING ANALYSIS
AND OUTSIDE ROUNDS.
"'IPATCH TYPE
1 "NONE h 2~-M OUT MBIT 3-CDMFO II, 4*-FULL FACE 5
5BREATHING AIR, 6=DUST MASK, 7=SCBA.
ANALYTICAL RESULTS
IMPOUND
D.R 4
IHG :STEL
MDL
ni
ANALYSIS RESULT
< . 01
S HOUR * STEL
:
TLV/TWA s TLV/Twn : AREA
; OCvi 35; 1 -e 10 e 0 ; .01 e 1.954 :
: O-yU'9943 : 75 i 110 : .01 s 1.303 :
: 0002-3690 e 50 ; 200 : .01 e 5.138 :
e 0 e .01 e <.01
E
ILL OIL IS IN TT'M UNLESS QTHERWISE NOTED.
14 .37
T 10
PPM VOLUME OF RCLS IN AIR
(WEIGHT Oc CS2 IN GRAMS) (.0821) (DEGREES K) (PPM FROM CHROMATOGRAM)
WHERE . OS2 . L.J 2 i DECREES MW
(MW) (L.)
~ CARBON DISULFIDE USED FOR DESORPTION OLE CONSTANT (CONVERTS GRAMS TO LITERS) = DECREES KELVIN (DECREES CENTIGRADE + 273) ^ MOLECULAR WEIGHT OF SPECIFIC COMPOUND
LITERS OF AIR SAMPLED
00 077475 CONFIDENTIAL
NAME F,,A!-T
DOW CHEMICAL LAD INDUSTRIAL HYGIENE SAMPLE CONCENTRATIONS
RCL.' DATA ENTRY FORM
i MIKE BROWN : SOLVENTS / EDC I
SAMPLE DATE (MM/DDlYY)
12/31/87
SAMPLE NUMBER
34
SAMPLE TIME (MIN-)
240 MIN.
SAMPLE VOLUME (L)
23.99
SAMPLE TYPE (A, S, P)
A
:a^-area, s-short term, P-PERSONNEL
IF AREA, DESCRIBE
: R-1E
RESPIRATOR USED (1-7) !
3 OR 12 HOUR SHIFT
:
SHIFT (DAY,NIGHT. EDO) ; DAY
EMPLOYEE I. D. ;
:
SOB DECOR POTION
:
TIME START : 6s00 AM TIME STOP :10:00 AM
PUMP STAR! FLOW : 100 CC/MIN. PUMP STOP FLOW : 100 CC/MIN.
I RAT OR TAPES'
1>N ONE5 2-MOUTHBIT. 3-COMFO'II. 4-FULL FACE, 5"BREATHING AIR, 6-DUST MASK, 7~SCBA.
ANALYTICAL RESULTS
U COMPOUND :
DR $!
u
:
i ANALYSIS ; S HOUR : STEL
i
: IFIG i 3TEL MDL. : RESULT : TLV/TWA : TLV/TW A i AREA
I E7CL
. ' " 3`:' ->1 r 1000 r
. fV*\ H *t
<.01
:
it
j
i
`r, Cfc_"t,`
1 `* 1 m` 2.1 -,f L/J 4^* 1.
w : 0 .01 L
<.01
:
*
!
0001 OP 31 : 10 ` c-': ; .0.1 :
1.564 :
r . 40
|
i 1i
:'DO
PER
: 0001 994 3 : . 0002- 3698 l
75 ; 110
.. 01 :
50 : 200 - .01 :
<.01 < .01
: :
':
.1 '"'PI
; V 2- 3<-T : 10 ,, 0 .01 :
<.01
:
e : all result in ppm JNLESS OT HERWIB E NOTED.
:
RCL EQUATION :
PPM VOLUME OF RCLS IN AIR =
(WEIGHT OF CS2 IN GRAMS) (.0821) (DEGREES K) (PPM FROM CHROMATOGRAM'
(MW) (L)
WHERE : CS2
r- CARBON DISULFIDE USED FOR DESORPTION
.0C21
- GAS CONSTANT (CONVERTS GRAMS TO LITERS)
DEGREES K = DEGREES KELVIN (DEGREES CENTIGRADE -I- 273)
MW MOLECULAR WEIGHT OF SPECIFIC COMPOUND
" L'TERS OH AIR SAMPLED
DO 077476 CONFTDENTTAI
DOW CHEMICAL LAD INDUSTRIAL HYGIENE SAMPLE CONCENTRATIONS
RCL DATA ENTRY FORM
NAME
PLANT `"'LAN"!
t MIKE DROWN r SOLVENTS / EDO 1
SAMP! ..E D, O T (MM/DD/VY ) SAMPLE NUMBER
; 12/31/87 : 35
TIME START &:00 AM TIME STOP 10:00 AM
SAMPLE TIME (MIN }
; 24 0 MIN.
SAl'T'LE VOLUME (L)
: 30.39
PUMP START FLOW : 100 CC/KIN.
SAMPLE TYPE (A, S, P)
:P
PUMP STOP FLOW s 100 CC/M1N.
' A- AREA , S-SHORT TEEM , P--PERSDNNEL )
IF AREA, DESCRIBE
:
''ES^IRATOR USED (1-7) : 3
8 OP 1.2 HOUR SHIFT
. 12
SHIFT (DAY,NIGHT, EDO) EMPLOYEE ) . D, tt`
: DAY : -133624
JOB DLSCRIF' i'IDN
: TOX S.C.T. WORKED ON D-700 FEED TO TOX PLUGGING
. ...PROBLEM,
'"F'l'PIRRTOr; TVPGS : i-NONE, 2-MOUTHBIT, 3-COMFO II, 4-FULL FACE,
5-BREATH1NG AIR, 6-DUST MASK, 7-SCBA.
ANALYTICAL RESULTS
COMPOUND -
DP 11
m km. ANALYSIS : STEL : MDL RESULT
!X G)
1 i
: 1000 : 0 : . 01 :
< .,01
8 HOUR TLV/TWA
TET 70S
prsr-
PER
0002-3654 : - 0001-8531 :
000.1 - 9943 0002-3693 :
5 : 0 : .01 : 10 ; 0 : . 01 : "7 c, : 110 : .01 : 50 : 200 ; . /) 1 ;
5.984 2.12 5.827 7.725
.21 ,, 56 .46
r. r
l 002 36S7 : 10 : 0 : .01 :
< . 01
vnTr t : i L.. i
a ri
t.L
RESULTS IN PPM UNLESS OTHERWISE NOTED.
r. r..- .z:5fts;=
jrs :rz -- ss sssssaBSsissuarsassss;
RCL. EQUATION
PPM VOLUME OF RCLS IN AIR -
(WEIGHT OF CSC IN GRAMS) (.0821) (DEGREES K) (PPM FROM CHROMATOGRAM)
WHERE
(MW) (L)
CS2
CARBON DISULFIDE USED FOR DESORPTION
.0821
GAS CONSTANT (CONVERTS GRAMS TO LITERS)
DEGREES K - DEGREES KELVIN (DEGREES CENTIGRADE + 273)
MW MOLECULAR WEIGHT OF SPECIFIC COMROUND
LITERS OF AIR SAMPLED
ME : :&/02 ''GS
DO 077477 CONFIDENTIAL
DOW CHEMICAL LAD INDUSTRIAL HYGIENE SAMPLE CONCENTRATIONS
HEX DATA ENTRY FORM
NAML
; MIKE BROWN
PLANT
r SOLVENTS l EDO 1
PLANT # : 16 / 17
SAMPLE DATE >. MM/DD/YY) : 12/31/87
TIME START : 6:00 AM
SAMPLE NUMBER
t 36
TIME STOP :10:00 AM
SAMPLE TIME (MIN.)
: 240
SAMPLE VOLUME (L)
; 23.37
PUMP START FLOW : 100 CE/UIN.
AMPLE TYPE (A, S, P)
:P
PUMP STOP FLOW ! 100 CC/MIN.
(A-APEA.
SHORT TERM, P;" PERSONNEL )
IF AREA, DESCRIBE
i
RES!-'I RAT Cl!': USED <1 ~ 7) : 1
B OR 12 HOUR S!4TF"r
: 12
SHIFT (DAY,NIGHT, EDO) : DAY
EMPLOYEE I . D. *!
: 433624
JOB I;2 SCR 3 i-'T ION
: TOX S.O.T. WORKED ON D-700 FEED TO TOX PLUGGING
PROBLEM.
'"'ESPI RAT OP TYPES 1 NONE , 2-MOUTHBIT , 3"='C0MF0 II, 4=FULL FACE,
5=BREATHING AIR, 6^DUST MASK,, 7=SCBA.
cor POUND
dp L
ANALY11CAL RESULTS :H3 : MOL ; '".NLL. VSIS : S HOUR TLV : AREA :
0002-3643
100: .02*:
.31 :
1.16
s
:
9-2370
201: .021: 1.73 : 6.42
i
s
.50$. .02-::
, 1.S :
.61
:
s
, : r:,PB. T - PPD IN D....COD rZOULTS N f 'PL UNLESS OIKERWIBE NOTED.
PPB VOLUME OF HEXES IN AIR = (MG) (24.45) (1000)
(L) (MW) (RR)
WHERE : MG
== MICROGRAMS FROM SAMPLE DATA
24.4 5 LITERS OCCUPIED BY 1 MOLE OF GAS AT STANDARD CONDITIONS
L => LITERS OF AIR SAMPLED
MW MOL ECU!.. AR WEIGHT OF SPECIFIC COMPOUND
RR ~ RECOVERY RATE OF COMPONENT
MB:06 'O3/0E
DO 077478 CONFTDENTIAI
*. fc.
J
DOW CHEMICAL LAD INDUSTRIAL HYGIENE SAMPLE CONCENTRATIONS
HEX DATA ENTRY FORM
NAME
s MIKE BROWN
PLANT
s SOLVENTS / EDC 1
PLANT +! : 16 / 17
SAMPLE DATE (MM/DD/YY) : 12/31/87
TIME START : 6:00 AM
SAMPLE NUMBER
: 37
TIME STOP :10:00 AM
SAMPLE TIME (MIN.)
: 240
SAMPLE VOLUME (L)
: 23.90
PUMP START FLOW : 100 CC/M1N.
SAMPLE TYPE (A, S, P)
:P
PUMP STOP FLOW : 100 CC/MIN
(A^AREA, S-SHORT TERM, R~PERSONNEL)
IF AREA, DESCRIBE
:
RESPIRATOR USED (1-7) : 1
8 OR 12 HOUR SHIFT
: 12
-- > *
, '
V. - I,
DAY
EMPLOYEE I. D,,-#
434213
JOB DESCRIPTION
SAMPLE O.T. FOR P/T AND EDC INCLUDING ANALYSIS
AND.OUTSIDE ROUNDS. .
YE OR TYPES i:: NONE , 2--M0UT HBI7 , 3=C0MFQ II, 4=FULL PACE,
3=BREATHING AIR, 6==DUST MASK, 7=SCBA.
ANALYTICAL RESULTS
CO.'!POUND :
DF:
: IHG : MDL : ANALYSIS S HOUR TLV : AREA *
r! CE
t 0002- 364 3 : 100; .. 2 Y : , f COT -23'. 3 : 20S. : . 02 Sc:
.74
*
3.04
.41 j B 67
a at a
. voos- C3io- . loot-: . 02# :
* .81
t-
@ = PPM, * = P'f:'D, $ - PPB IN E'LOCD ."i'ULTS IN Pr~B UNLESS OTHERWISE NOTED.
jtrv EG!` J " T I O' 1
PPB VO-UME OF HEXES IN AIR (MG) (24.43) (1000)
WHERE : MG 2/ . 4 3
MW RR
MB;06'03/83
; L) (MW) (RR)
MICROGRAMS FROM SAMPLE DATA LITERS OCCUPIED BY 1 MOLE OF BAS AT STANDARD CONDITIONS LITERS OF AIR SAMPLED MOLECULAR WEIGHT OF SPECIFIC COMPOUND RECOVERY RATE OF COMPONENT
00 077479
confidential
m
\l
DOW CHEMICAL LAD INDUSTRIAL HYGIENE SAMPLE CONCENTRATIONS
RCL DATA ENTRY FORM
NAME PLANT PLANT
: MIKE BROWN SOLVENTS / EDO 1 .16 / 17
SAMPLE DATE (MM/DD/YY) s 12/31/87
SAMPLE NUMBER
! 38
SAMPLE TIME (MIN.)
: 60 MIN.
SAMPLE VOLUME (L)
! 7.94
SAMPLE TYPE (A, S, P)
:S
(A-AREA, S-SHORT TERM, P=PER5QNNEL)
IP AREA, DESCRIBE
:
RESPIRATOR USED (1 - 7) : 3
8 OR 12 HOUR SHIFT
:S
SHIFT (DAY,NIGHT, EDO) : DAY
EMPuCVEE I. D. #
; 433928
JOB DESCRIPTION
: WORKING WITH
LAB
TIME START TIME STOP
1:00 PM 2:00 PM
PUMP START FLOW : 100 CCVMIN. PUMP STOP FLOW : 100 CC/MIN,
LOADER ON 3385 GALLON TET T/T.
RESPIRATOR TYPES'
1=NQNE, 2=M0UTHBIT, 3-C0MF0 II, 4-FULL FACE, 5=BREATH1NG AIR, 6-DUST MASK, 7-SCBAt
ANALYTICAL RESULTS
COMPOUND
DR ft
s IMG :STEL : MDL
ANALYSIS : 8 HOUR : STEL RESULT : TLV/TWA : TLV/TWw
AREA
ETC!...
0002-3701 : 00O' : 0 : .01
<.01
:
0002-3654 : 5 : 0 : .01
33.651
8.26
EDC
: COOi- 8531 : 10 : 0 : .01
<.01
PDC
: 0001*9943 : 75 j iio : .01
.481
. 16
PEP Yj TP I
: 0002 - 369S : . 0002-3607 ;
50 : 200 : .01 10 . (") : . 01
1.553 <.01
NOTE : ALL RESULTS IN PPM UNLESS OTHERWISE
RCL EG LJATIOM .*
PPM VOLUME OF RCL
[WEIGHT OF CS2 IN GRAMS) (.0821) (DEGREES K) (PPM FROM CHROMATOGRAM)
WHERE
i CS51? .0821 DEGREES'K MW
. L.
(MW) (L)
CARBON DISULFIDE USED FOR DESORPTION GAS CONSTANT (CONVERTS GRAMS TO LITERS) DEGREES KELVIN (DEGREES CENTIGRADE + 273) MOLECULAR WEIGHT OF SPECIFIC COMPOUND LITERS OF AIR SAMPLED
! KB; 06/!" 3S
DO 077480 CONFIDENTIAL.