Document zzMVQkar2Q6QjZ3JMEDeGdENa

PAG e.'- 2C PPG INC0TRIES ckeXiical division LAKE CHARLES^ LOUISIANA ( CAPTIVE USAGE T/O 1973 AVG. i LIQUID PHASE EDC To TCE Mfq. & MC Mixes ! Perchlor Trlchlor Mfg. & Mixes 188.5 1.3 1.9 Vinyl Chloride P/T-TETRA UNIT ; 682.9 59.1 OHC EDC To Perchlor Trichlor____________________________ No. 2 EDC Plant 3.3 P/T-TETRA UNIT 258.4 JAM FEB. 190.5 0.0 0.0 429.9 125.8 199.1 0.0 0.0 237.6 108.6 0.0 3.0 285.9 189.6 MAR. APR. MAY JUNE 203.7 0.0 0.0 539.0 29.6 202.2 0.0 0.0 611.6 69.0 205.6 0.0 0.0 811.8 11.3 209.7 0.0 0.0 928.0 2.0 19.0 268.6 6.1 10.5 74.4 192.9 0.0 0.0 79.5 343.0 0.0 0.0 135.5 326.1 JULY AUG. SEP. 129.5 0.0 0.0 718.2 38.1 187.0 0.0 0.0 731.3 60.3 232.4 0.0 0.0 720.0 45.7 0.0 0.0 57.7 293.6 0.0 0.0 129.9 265.9 0.0 0.0 163.0 272.7 OCT. 216.6 0.0 0.0 668.9 16.2 0.0 0.0 112.9 251.2 NOV. DEC. 255.6 0.0 0.0 564.7 94.2 261.9 0.0 0.0 679.8 46.8 0.0 0.0 180.1 177.6 0.0 0.0 144.5 298.5 1974 AVG. 207.8 0.0 0.0 636.7 54.0 0.5 0.9 91.4 263.8 CO --cm FI DEW IAL: 1" Sub j iCt tC Protc ctive Order ------------ i > Judi -ial t istrit t Cou; t o -------- ET5 . &1-1 145 --* c*> CO CD ---* FORM Nf^A 201 - 4 EDC SHIPMENTS 1973 JAN Avg. FEB Pe.G IN TRIES CHEMICAL DIVISION IAKE CHARLES, LOUISIANA LABORATORY PRODUCT REPORT MAR APR MAY JUNE JULY 1974AUG SEP OCT NOV DEC Avg. Trans 1.2. Dl CHLOROETHYLENE PPM 1.1 Dichloroethane ppm Cts t.2 OlCHLOROETHYLENE PPM Chloroform ppm Ethylene Dichloride % Trichloroethylene Perchloroethylcne ppm ppm 1.1.2 Trichloroethane ppm 10 0 (1 0, 0 0 16 22 27 26 14 17 16 54 3 5 6: 5 4 24 66 43 26 2i 19 27 99.987 99.983 99.981 99.985 99.989 99.988 99.987 8 (1 0 00 0 0 (1 0 9 0 (1 14 0 7 (1 36 30 11 T3--------- 15 00 11 18 54 32 13 99.986 99.988 20 05 17 31 n0 13 16 44 23* 23 99.983 99.982 01 9 37 46 42 00 0 11 17 3 32 53 55 17 7 33 99.975 99.976 99.984 52 37 7 41 13 10 33 48 27 Ethylene Chlorobromide Ethyl Chlorioe ppm 11 ppm 4o 14 23 0 44 14 0 2 44 31 26 3 39 3 11 7 10 52 29 27 22 4 12 7 8 13 30 Color IAPhA) Appearance Acidity water ppm ppm Non-Volatiles Total Iron Specific Gravity 60/60uF ppm ppm fyr f-- <--> CO rov>> L ........................... 7 Clear (1 45 8 .... Clear (1. . 49 8 Clear 2 64 7 Clear (1 38 7Clear (1 39 5 Clear (1 51 6 Clear (1 89 76 CLEAR CLEAR Cl 1 50 27 5 Clear 1 50 6 CLEAR :i 41 68 CLEAR CLEAR (1 (1 38 38 7 OTjEAR (1 48 3 0.17 1.262 a. 0.24 1.263 (1 3.49 1.262 6 0.23 1.262 (1 0.10 1. '262 Cl 3.20 .. 261 (1 0.28 1.262 (1 (1 0.14 3.21 1.261 L.262 5 0.28 1.261 0.23* 1.260 Cl U 0.27. 0.24 1.263 1.263 1 0.24 1.262 - - Km Of 1 1 1- UNrjOf NT IA ij -Oi ro J c^ rrr id ] t&eti Uisti e Ord< f-ct C< >r 'art to. Jl PAGfc: 20: METHYLCHLOROFORM SHIPMENTS 1973 AVG. Type 314 Color Specific Gravity Distillation Range APHA 25/25 C C 6 1.330 Low 73.9 High 74.7 Moisture PPM 42 Acidity Non-Volatile Residue PPM asHCI (1 % .0005 Soluble Chlorides PPM (0.5 JAN. 6 i vie; 73.9 75.2 40 (1 (.0001 (0.5 PP INATR1ES C^tWlCALDfVlSION LAKE CHARLES,LOUISIANA LABORATORY PRODUCT REPORT FEB. MAR. APR. MAY JUNE JULY --- ----- -_- __ - --_ - _ --- M -- -- - -- "" -- -- " - -- -- Type 321 Assay Moisture Distillation Range Low High Specific Gravity Color Acidity N n-Volatile Residue Soluble Chlorides % PPM C 25/25 C APHA PPMasHCI % PPM AUG. SEP. _ -_ --- --- --- -- OCT. NOV. DEC. 1974 AVG; - (5 - -- - - - - 23 - -1- - --- (5 1 .33 5^ 73.9 75.2 32 (1 (.0001 (0.5 fr\ r- w Co w rr\ Co ---rrP OaDj li iat* --------CO ect ti Jud: tiC JFTDENj > Profc Dial 91- PIALi - c t i vp* )i3tri .145 - vd* ^ uur Wtl CL PACE: 2' 6 PPGJN STRIES CHEMICAL DIVISION LAKE CHARLES,LOUISIANA LABORATORY PRODUCT REPORT TRI-ETHANE SHIPMENTS 1973 AVG. Tvoe 324 Color APHA Soecific Gravity 25/25 C Distillation Range______________ C Low High 6 1.305 73.2 82.9 Moisture Acidity Soluble Chlorides PPM 50 PPM as HCI U PPM (0.5 Aluminum Scratch APHA Non-Volatile Residue *38 .O00l . Type 339___________________________ Color APHA 6 Specific Gravity 25/25 C 1.322 Distillation Range Low High Moisture C PPM 74.0 83.0 55 Acidity Non-Volatile Residua PPM as HCI (1 % .0001 Soluble Chlorides PPM (1.0 JAN. FEB. 68 1 .51 5 1.305 73.2 84.6 51 (1 (0.5 53 .0003 72.8 82.8 67 (1 (0.5 21 .0002 87 1.324 - 73.8 83.5 - 52 97 1 (1 (.0001 - (0.5 - MAR. 6 1.303 72.8 83.4 60 2 (0.5 .6002 7 1.332 73.8 83.2 68 (1 .0004 (0.5 APR. MAY JUNE 66 7 1 me; 1 .305 l -and 72.8 72.8 82.3 82.1 58 68 12 <0.5 (0.5 28 26 t.0001 (.0001 72.8 82.5 63 2 (0.5 34 .0003 66 1.323 1.323 - 72.5 81.5 49 (1 .0006 (0.1 72.5 81.5 44 1 .0006 - - - JULY AUG. 65 1.306 1.305 72.8 72.8 82.8 82.8 64 88 11 (0.5 (0.5 31 14 (.0001 .0006 --- ----------- SEP. OCT. NOV. DEC. 15 (5 (5 6 1.307 1.304 1.304 1.305 73.1 73.0 73.5 73.5 83.6 83.3 83.4 83.6 54 46 56 43 1 2 "I--------- 2 (0.5 (0.5 (0.5 ' (0.5 16 12 9 20 (.0001 .0662 .0002 .6002 - - -- - -- - - -- -- -- - -_ - - --- -- 1974 AVG. 5 1.306 73.0 83.1 60 1 (0.5 24 .0002 7 1.326 73.2 " 82.4 62 (1 .0004 (0.5 r(--J) cONr I )ENT1A a * irb je c t "to P 1 ottic t irtre--0T "tec------- o of 14tit : cal iui, nt--Dis Li xL CO -MB'.-- 7------------- CO OT -ft* FORM 5A 201- 7 PPG INWSTRIES CHEMICAL DIVISION LAKE CHARLES, LOUISIANA LABORATORY PRODUCT REPORT TRICHLOR SHIPMENTS 1973 Avg . JAN 122 & So )type (Degreasing Lvent f rade Color Specific Gravity 20/EO C apha 8 1.461 7 1.460 Distillation Range C Low 86.1 86.1 High water Content Cloud nonvolatile acid Acceptance Point % as C * NaOH pH Acidity/Alkalinity 87.6 (-10 .0013 0.14 7.7 .0003 87.7 (-10 .0014 .14 7.4 .0002 FEB 9 1.460 86.1 87.8 (-10 .0016 .14 7.7 .0003 MAR * 8 1.460 86.1 87.9 (-10 .0012 .15 9.0 .0017 APR 8 1.460 86.0 87.7 (MO .0006 .15 9.0 .0019 MAY 7 1.460 86.1 87.7 (-10 .0002 .16 9.0 .0020 JUNE JULY AUG 10 1 .469 97 1.462 1 .469 86.1 87.9 (-10 .0006 .16 9.0 .0019 86.0 87.8 (-10 .0012 .19 8.9 .0017 86.0 87.5 (-10 __ 9.1 .0026 SEP OCT NOV OEC 5 1 JKfl 7 (5 1.462 6 1.461 86.1 87.5 (-10 .0003 .19 9.1 .0026 86.2 87.4 (-10 .0005 .19 9.1 .0024 - 86.1 - (-io - 88.0 (-10 - .0005 .20 9.2 9.3 .0030 .0028 1974 Avg . 7 1.461 86.1 87.7 (-10 .0008 0.17 8.8 .0019 TYPE Ei110 Colon Specific gravity 20/20 C apha Distillation Range Low High water Content Cloud Point C C Non,Volatile acid Acceptance % %.as NaOH 8 (-10 * type 113 (Hieh Puritv Gr Color apha 7 ___ 7 Specific Gravity 20/20 C Distillation Range C - LOW HI GH (-10water Content Cloud Point C (-10 NONiVOLATILE % .0002 .0002 77 (-10 MO .0005 .0004 7 (-10 .0003 78 (-10 (-10 .0002 .0004 7 (-10 .0005 6 6 (5 (5 6 (-10 f-10 (-10 (-TO " (-10 .0004 .0006 .0005 .0003 .0003 6 (-10 .0004 SL 013365 CONF UEN'Fl 5*1 b jef * to 'rotec :ive c refer ---------Of 4 111 dTKtirr a I til strict Court --No: 91-11 15 *Type 122 is Type 132 subsequest to FeB FORM 45A20I - 8 TRICHLOR SHIPMENTS 1973 AVG. Type MS (Dual l^irpose Gr ade) Color apha Specific Gravity 20/0 C Distillation Range C 8 Low High water Content Cloud Point C Non.-Volatile Acio Acceptance % % as NaOH (-10 .0004 JAN "PPG USTRIES CHEMICAL DIVISION LAKE CHARLES, LOUISIANA LABORATORY PRODUCT REPORT FEB MAR APR MAY JUNE JULY AUG 1974SEP OCT NOV DEC AVG. r\njj r~ o CO CJ m . . .. o> :omfiu THTT/oj J _ --1----- St Trjorrtr tTTTT Ytect j ve Ore er --Of- ] ttrh" TTl f1 j c i a (list net L our L trt; t -1145 FORM N rA 201 - 9 PERCHLOR SHIPMENTS Iir-PE 207 Color APHA Specific Gravity 20/20 C Distillation Range C Lor High water Content Clouo Point C Hon - Volatile PH Wt. % acid Acceptance ft as NaOH Co'ter Corrosion Acidity Ml of O.Ot N NaOH Flask MG/30 CM2 SoxhLET MG/30 CM2 Condenser MG/30 CM2 Chlorides ppm 1973 Avg . 10- CO 8.2 JAN 11 (0 8.3 PPG' iNODSTtUES CHEMICAL DIVISION LAKE CHARLES, LOUISIANA laboratory product report FEB MAR APR MAY JUNE JULY 10 9 11 9 11 14 (0 (0 Co (0 8.1 8.3 8.3 8.3 CO 8.3 (0 8.3 AUG 10 (0 8.4 SEP OCT 15 15 (0 8.2 (0 8.4 NOV DEC 10 12 (0 8.5 (0 8.5 m ii (0 8,3 TYPE 208 Color Specific Gravity APHA 20/20 C Distillation Range C Low HI GH vatcr Content Clouo Point ucn-Volatile PH -wt.% cC Copper Corrosion Acidity ML of 0.01 N NaOH Flask MG/30 CM2 SoxhlET MG/30 CM2 CpnotnsER MG/30 CM2 Chlorides ppm 9 1.625 120.8 121.6 (0 .0003 6.6 1 2 6 7 0.13 - SL 013367 10 1.624 120.8 121.7 (0 .0003 6.5 2 1 7 3 0.11 10 1.624 120.9 121.6 (0 .0002 6.8 1 2 8 10 0.11 8 10 8 1.624 1.624 1.625 120.7 121.6 CO .0006 6.7 120.8 120.9 121.6 121.8 (0 (0 (.0001 .0006 6.5 6.5 1 1 9 10 (.06 2, (1 5. 5 .] 8 2 2 5 6 .10 10 12 9 1.626 1.627 11 10 7 1.626 1.625 -- 10 in 1.624 1.625 120.8 120.8 121.7 121.7 (0 (0 (.0001 .0006 6.5 6.4 CO 6.8 120.9 121.7 (0 .0005 6.8 120.9 121.7 (0 .0002 6.5 - (0 - 6.6 120.8 121.7 (0 .0005 6.6 120.8 121.7 (0 .0003 6.6 1 1 6 6 (0.06 1 (1 6 9 0.06 __ - 2 2 7 7 0.10 2 1 7 8 0.16 - - - - 2 1 7 7 0.08 2 1 7 8 0.09 conf; DENTL \L: Subiec t to 1 'rotec cive O :der Of 14th Judic al Di strict Court No. 91-11 15---------- FORM SA 201 - 10 PERCHLOR SHIPMENTS TYPE 203 CotOR APHA Specific Gravity 20/20 C Distillation Range Low C High Water Content Clouo Point C non-volatile wt.% PH Acto Acceptance % as NaOH Copper Corrosion Acidity ML of 0.01 N NaOH Flask MG/30 CM2 Soxhlet MG/30 CM2 Condenser MG/30 CM2 Chlorides PPM 1973 AVG. JAN NlG, II JSTRIES CHEMICAL DIVISION LAKE CHARLES, LOUISIANA LABORATORY PRODUCT REPORT FEB MAR APR MAY JUNE JULY AUG SEP OCT NOV OEC m TYPE 209 Color Specific Gravity APHA 20/20 C Distillation Range LOW HI GH Water Content Cloud Point C C Non-volatile wt.jS PH Acid Acceptancr % as NaOH Copper Corrosion Acidity ML of 0..01 N NaOH Flask MG/30 CM2 Soxhlet MG/30 CM2 Condenser MG/30 CMZ Chlorides ppm SL 013368 * ---------fcy >ict t nm TTTTTnr mnr * -------- DUD V V 31 rcoi 'Or--rt rh--uud LCinl fcrrSxri ----------- wki J % 9J, Hie ^PPG ftjSTRIES ETHYL CHLORIDE SHIPMENTS JAN CHEMICAl DIVISION LAKE CtlARlES, LOUISIANA LABORATORY PRQDUCT REPORT FEB MAR APR MAY JUNE JULY AUG SEP OCT NOV DEC m Color Moisture SPECIFIC GRAVITY apha ppm 0/4 C 6* 24 n.Q24 6 (5 14 29 0.923 0.924 (1 f 5 57 9 0.924 0.924 (5 4 0.923 (5 (5 d>s 75 n QO-a 0.923 15 30 0.924 4 37 n (5 :s 30 30 0.924 0.924 (5 14 0.923 (5 91 0.924 Acidity as HCl Non volatile Residue wt. % Wt. % o -ooF 1 * (.0001 (.0001 (.0001 (.0001 .0008 .0004 [.0010 ( .0001 {.ooo: (.0001 (.0001 (.0001 (.0001 .0002 (.0001 .0013 .0002 (.0001 .0008 .0010 .0005 .0005 .0010 (.0003 ;.oooi (.0001 . .0004 Ethyl Chloride Wt. % 99.96 Distillation Range C Low 12.3 _________________High_________ 12.6 99.97 - 99.95 - - 99.96 99198 99.97 99.97 99.97 99.97 --- - - --- - - 99.96 99.95 99.98 99.97 99.97 -- - - -- -- SL 013369 -- * - CONF DENTI *L: Ci i h jor t- t- o : 'rotec ;ive C rder 1 dTh .Tudic: al Di strict Court No. 91-11 15 FORM N A 201-12 VINYL CHLORIOE SHIPMENTS MCI TS7T" JAN PPM PPM AVG. 38 (1 48 (1 * PPM SULFUR PPM ACETYLENE PPM ALOEHYOES. AS ACETALOEHYOfi PPM PEROXIDES. AS Hj a PPM 0.06 (1 (1 (1 0.02 0.07 (1 (1 (1 (0.01 FEB 41 (1 0.09 (1 (1 (1 0.03 PP G JSTRIES CHtMICAl Division IAKE CIIARUS, tOUISlANA LABORATORY PRODUCT REPORT MAR 40 (1 APR IQ n MAY 36 (1 JUNE JULY 19 38 (1 1 (0.1 (1 (1 (1 (0.01 (0.1 (l (i (l 0.04 0.1 a (i a (1.00 0.24 a (i (i 0.05 0.13 (1 Cl . (1 0.01 N N-VOL ATIL E RESIDUE PPM 3 (1 4 6 (i 10 (1 10 . AUG 43 (1 0.10 (1 (1 0.01 4 SEP 59 (1 (0.1 (1 (1 (1 0.02 OCT 41 (1 (0.1 (1 (1 (1 0.02 NOV 37 1. 0.1 (1 (1 (1 0.01 DEC 974 AVG. 2a___ 21_____ _u___ _LL_____ (Q.i (i (i (i (1.00 (l (l (1 (l.ob 4 14 14 (i 5 * SL 0w I13v1J7/Un - .. - CON FT IFM'I' r n r . >ui)ier " fcr> P of 14 th r ud i r>; No . n -i i a i 'UUJl ^ - 1 rOflwi nO*2A 202*4 EDC PRODUCT #1 PPM* 1973 Avg. JAN res PPG IN iTRIES CHEMICAL DIVISION LAKE CHARLES, LOUISIANA LAflORATORY OPERATIONS REPORT MAR APR MAY JUNE JULY AUG SEP OCT NOV OEC 1974 Avg. Trans 1.2 Dichloroethylenc Dl1.1 chloroethrne Cis 1.2 Dichloroethylene Chloroform Ethylene Dichloride T1.1.2 richloroe thane (Wt. u fl i 15 18 22 235 29 56 35 99.989 99.989 99.979 6 2 15 - - - - ethylene Chlorobromioe :ihyl Chloride JH1OCNTIF1tO 13 2 27 7 (1 0 0 43 6 -- -- __ - _ - -1 1 -- 12 12 15 14 11 12 15 19 15 -8 3 4 7 13' 11 9 47 - 21 23 20 61 179 59 37 40 53 D. 99.98? 99.979 99.983 99.98] 99.963 99.968 99.976 99.98-; 99.979 - 17 19 27 28 28 21 29 21 -5 8 - 28 29 *- - 9 55 37 30 5 - 46 25 (1 14 T--------------- 0 6 6 5 5 19 3 (?o E ICL 22 0.04 0.45 24 0.04 0.76 25 0.03 1.61 - SL 013371 - . 30 30 - 0.07 0.04 - 0.45 0.67 42 0.02 0.61 * 44 0.06 0.70 42 0.05 1.77 46 0.06 1.12 26 0.24 1.56 34 0.10 0.89 34 0..07 1.01 ,* * jar e COwt LD nbieC^ LO * iv Ot -oteet 1ltt pftCtr 514 tb rncrre* 91-114 -- *UM.CSS OTHERWISE SPECIFIED F0Ri.i 202- 5 EDC PRODUCT #2 PPM* 1973 Avg . JAN FEB PPG Ih TRIES CHfMlCAl DIVISION IAKE CHARLES, LOUISIANA LAPORATORY OPERATIONS' REPORT MAR APR MAY JUNE JULY AUG SEP OCT NOV DEC 1974 Avg. ' TflNS 1.2 DrCHL0R0E1HYLENE 1 .1 Dl CHLOfiOETH*NC Cis 1.2 Drchloboethylene Chloroeorm Ethylene Dichloride (Wt. HI 1.1.2 TniCHLOBOETHANE 2 44 19 51 21 8 84 42 18 33 99.984 99 -.981 99.985 2 0 24 1 14 7 21 99.985 12 13 __ -- 15 17 . 416 12 3 39 12 4 32 99.906 99.988 99.985 15 8 28 5 12 3 14 99-99 2 15 . 1 8 6 899.994 9 - 13 11 6* 9 31 36 99.987 99.988 39 3 - 13 12 127 99.9?1 11 (1 11 10 90 99.979 13 4 16 7 72 99.978 15 Ethylene Cklorobromioe Ethyl Cmlobioe Uhioentimeo h2o fe HCt [ . . w 1 Ud/ 5 so 19 67 (1 40 31 11 58 13 23 8 73 51 20 18 4 3 1 1 0 5 6. 2 5 29 7 8 3 (1 12 - - -- " 10 0 0 6 4 - 23 0.04 0.45 35 0.06 1.71 23 0.01 2.42 .. 49 35 TT.TJB" 0.03 0.33 0.94 30 0.06 0.52 36 0.04 0.58 48 0.03 0.58 42 0.01 0.94 33 0.04 1.09 * 36 0.02 .80 28 0.03 1.98 27 0.03 0.66 35 0.04 1.05 . - - * Unless otherwise srcctFiEO . t` - * ----------- C 0NF1DI IHTIAL 3l b jfc! cl to 1 Pl( L oo'C'i: 'c Orti of li ttrti cli'cin. D j. sj L - Itrt C j Li Jl L. ttrr;--91 -1145 y ... FOhNt 202 | EDC REACTOR #1 ETHYLENE OlCHLORIDE Tp I CHLOPOE THYLE HE PeRCHLOROETHVLENE 1.1,2 Tfii(HLOBOCTHAN! U.TETRACHLOROCTHANE S-TE TRACHLOROCTHANE Pentachloroe thane 1973 Avc. WT. % 98.71 0.02 0.01 0.34 0.02 0.30 (0.01 JAN FEB 97.98 0.02 0 0.69 0 0.62 0 98.18 n.T 2 n 0.31 0 0.19 0 .PPG lWSTRIES CHEMICA^IVISION LAKE CHARLES, LOUISIANA LAPORATORY OPERATIONS REPORT . MAR APR MAY JUNE JULY 98.99 0.02 0 0.30 0 0.21 0 99.22 Q. 01 (1 0-26 0 0*16 0. 99.27 0.04 fl 0.38 0 0.13 0 99.34 0 n 0.24 0 0.09 0 98.90 0.08 0 0.30 0 0.18 0 Ethylene Chlorobromide Ethyl Chloride Uni OENTt rICO 0 0.05 0.56 0 0.34 0.35 0 0.12 1.07 0 0.14 0.34 0 0.11 0.23 0 0.03 0.18 0 0.11 0.24- 0 0.08 0.46 AUG SEP 98.94 fn.ni 0 0.44 0 0.18 0 98.45 0.03 0 0.67 0 0.25 0 0 0.06 0.38 0 0.03 0.55 OCT NOV OEC 1974 Avg . 98.96 98.78 0.02 b 0.01 fO.Ol 0.39 0.68 00 0.26 0.32 u0 99,36_ 0 0 0.24 0 0.10 0 98.86 0.02 0 0.41 0 0.22 0 o 0.05 0.28 0 0.02 0.20 ' 0 (0.01 0.29 0 0.09 0.38 H?0 Total Fe as FeCLj Tars Specific Gravity PPM % % 60.60P TTE5 0.41 4.63 1.303 (126 0.58 4.71 1.287 (252 0.48 b. 37 1.298 , (126 0.29 2.83 1.280 (191 0.48 7.63 1.297 (124 0.31 2.95 1.273 (164 0.42 5.50 1.284 (165 0.47 6.23 1.289 (119 0.27 2.68 1.269 (165 0.39 4.67 1.299 (141 0.36 4.19 1.287 (182 0.41 5.51 1.291 (196 0.45 6.79 1.323 (163 0.41 5.00 1.290 . * * * ci 013373 oL u 1 ' oo.l t b jert L rtf % ONPi D JNTiai. to trt tecti ciiciaj Histi i'pP vo. 9 J -1145 n, FORM NC^mLA 202- 7 EDC REACTOR #2 ClVi(H[ Bichloride Tticmlohoethyltne PCRCHLOROETHVLCNE 1.1.2 Trilhlorocthane U-TE TRACHLOROE THANE S-TE tbachlorocthane Pen TACHLOROETHANE 1973 Avg. JAN WT. % 98.61 0,02 0.01 0.35 0.02 0.31 (0.01 97.48 0 0 0.71 0 0.67 0 FEB 98.86 o.ns n 0.32 0 0.21 0 Ethylene Chlorobromioe Ethyl Chloride Uni oenti r ied 0 0.03 0.65 0 0.13 1.01 0 0.11 0.42 PPG I PASTRIES CHEMICAl DIVISION LAKE CIIARIES, IOUIS1ANA LABORATORY OPERATIONS REPORT MAR APR MAY JUNE JULY AUO SEP OCT NOV DEC 1974 Avg . 98.82 0.04 0' 0.27 0.02 0.19 0 99,04 0*03 0. 0.32 0 0,12 0 99.24 0.02 0 0.39 0 0.13 0 99.44 0 0 0.27 0 0.15 0 98.71 0.14 0 0.33 0 0.26 0 98.96 0.02 0 0.42 0 0.20 0 98.60 0.01 0 0.59 0 0.97 0 98.70 0.01 0 0.35 0 0.39 0 99.14 0 0 0.32 0 0.23 0 99.27 0 0 0.19 0 0.15 0 98.86 0.02 0 0.32 0 0.26 0 0 0.14 0.51 00,05 0.41 0 TTTT5 00 0.08 0.09 7T.T5T" 0 0.08 0.32 0 0.04 0.38 (0.01 0 0 :vr 0.04 O'.W 0.26 0 0.02 0.37 0 0.07 0.43 HjO Total Fe as FECL3 Tars Specitic Gravity PPM * % 60-0F (207 0.51 5.83 1.299 (217 0.59 3.62 PL. 301 (236 0.46 4.43 1.288 (157 0.44 5.08 1.290 (214 0.45 8.58 1.306 (100 0.24 2.56 1.271 (148 0.38 3.98 1.280 (115 0.29 3.77 1.282 (127 0.28 4.54 1.283 (137 0.32 4.99 1.296 (150 0.34 4.23 1.279 (108 0.28 3.49 1.278 (130 0.30 4.34 1.294 (153 0.36 4.47 1.287 . * *_ -- SL 013374 t<.* 4 nh -Gf^i Of 1 4 t- h . 1 SETNTJTi ilit rrtmrv it is ve Or net ier :ourt J-'-rtT: FORM 202* EOC REACTOR #3 Ethylene Bichloride TRICHLOROETHYLENE PCRCHLOBOE TMYLENE 1.1.2 Trk.hloroethahe U. Tctrachloroethane S-TETRACHLOROETHANE PenTACHLOROETHANE 1973 Avc. WT. % 98.45 0.03 0.01 0.58 0.06 0.35 {0.01 JAN FEB 97.28 0.06 0 1.72 0 0.16 0 96.96 0.16 0 1.72 0 0.18 0 Ethylene Chlorobromide Ethyl Chloride rUn i denti IED 0 0.03 0.53 0 0.04 0.73 0 0.02 1.01 P.G IN TRIES CHEMICAL DIVISION LAKE CHARLES, LOUISIANA LABORATORY OPERATIONS REPORT MAR APR MAY JUNE JULY AUG SEP OCT NOV OEC 1974 Avg. 97.82 0.11 0.01 0.88 0 0.430 97j99 0.03 0 0.84 0^ 0.60 0- 9q .ofi (0.01 n 0.54 0 0.16 0 98.99 0.02 0 0.52 0 0.18 0 98.73 0.06 0 0.64 0 <3713 0 98.49 0.02 0 0.76 0 0.26 0 97.16 0.04 0 1.47 0 0.-78 0 98.26 0.04 0 1.03 0 0.50 0 97.88 0 0.02 1.34 (0.01 0.47 0.06 96.71 n (fi.m 1.80 (0.01 1.35 0.01 97.94 n n6 (n m i.11 (0.01 0.44 (0.01 0 0.22 0.53 0, Oi.04 0.34 0 0.03 0.16 0 0.10 0.20 0 0.04 0.35 0 0.03 0.43 0 (0.01 0.54 0 (0.01 0.24 0 0.05 0.14 0 (0.01 0.12 0 0.05 0.40 H?0 Total Ft as FECL3 Tars Specific Gravity ppm % % 60-0F {226 0.59 5.37 1.310 (324 0.82 4.63 1.295 (272 0.60 3.50 1.296 {157 0.44 5.08 1.290 (248 0.56 4.58 1.292 (192 0.46 3.19 1.283 (210 0.48 4.98 1.292 (205 0.52 5.28 1.294 (248 0.52 4.82 1.286 (235 0.60 5.31 1.295 (223 0.51 3.94 1.286 (159 0.37 1.59 1.271 (233 0.54 2.81 1.282 (226 0.54 4.14 1.289 . *_ * * " SL 013375 - - COMP Kub jet t to Of T 4 th Judin No. iLi ail o1. r i 01-11 -i ve "o > Ljl i ct r*ier Court J FORM N EDC STILL BOTTOMS HI ETHYLENE dichloride Tb1CHLOROETHVLENt Perchloroethylene 1.1.2 Trichioroethane U-TeTRACHLORETHANE S- Te TRACHLOROE THANE Pentachloroethane Ethylene Chlorobromide Ethyl Chloride Un|OENTIEl ED PPQ Ihi^STRIES 1973 Avg. W1 % 35.29 0.14 0 44.45 0.28 11.97 0.01 JAN 53.25 0 0 32.36 0 10.54 0 0 0 7.23 0 0 3.84 FEB _ -- - - - - CHEMICAl DIVISION LAKE CHARLES, LOUISIANA LABORATORY OPERATIONS REPORT MAR APR MAY JUNE JULY - ,-- - __ , - "_ - _ __ - --- - --- T- - - - -- f- -- - --- AUG SEP % OCT NOV OEC 1974 Avg. 89.17 - 0.23 9.11 - 1.14 0.05 71 .64 (0.01 0.08 22.53 0.05 3.84 0.01 71.35 <n.m 0.10 21.33 0.03 5.17 0.02 0.24 " b .06 0.42 1.32 0.22 0 1.74 HjO PPM 16 24 -- Fe ppm 50.67 35.04 - - - - HCL PPM 697 1308 - ** - Specific Gravity 60-60F 1.386 1.355 - -- - - 67 40.85 550 1.319 10 89.59 433 1.320 34 55.16 764 1.331 * * -- QL OL- 013376 w * COM P DE'ltTT z -hi!j j'jij t--tor--t t cnrc ive o 'TtTTT------- i. cj '.i 1 D J. itt lot --Nu 91 *-11 -5-------------- F 0 i* m N 20*. 10 EDC STILL BOTTOMS #2 Ethylene OtCHLORIDE T<;ICHLOROt THYLCNC Ft rchloroethylenc 1.1,2 TfllCHLOROETHANt U-TeTRACHLORCTKAHC S-Te tbachlohoe THANE PeNTACHLOBOETHANC 1973 Avg. WT% 15.88 0,03 0 62.79 0.20 14.67 (0.01 JAN FEB 25.67 n. o 69.37 0 2.55 0 50.67 0 0 45.16 0 2.61 0 PPG I STR1ES trFtfMlCAL DIVISION LAKE CHARLES, LOUISIANA LABORATORY OPERATIONS REPORT MAR APR MAY JUNE JULY AUC. 65.99 66.64 0.13 0.40 0& 21.43 25.63 0 0.28 9.90 5.82 0 "02 33.56 0.44 0 56.18 0 * 8.82 0 35.70 26.71 1.14 0.53 00 53.20 58.33 00 8.43 i0.34 00 17.25 0.15 n.na 64.45 1.06 12.94 0 SEP OCT MOV DEC 1974 Avg. 17.98 0.12 0 64.94 0 13*. 90 0 12.31 0.1-2 2.38 67.02 0.04 14.40 0.10 18.99 0.08 1.86 64.13 0.06 11.54 0.03 17.00 0.14 0.'85 66.60 0.62 13.43 0.06 32.35 0.27 0.43 54.70 0.17 9.56 0.05 Eihyl ChLOB1 DC LmJ DENIt n CO 0 6712 00 3.40 2.21 0 0. 1.89 0.81 0 1.30 00 1.52 2.35 0 4.12 0 3.09 0 3.52 0 0.64 00 1.19 2.17 4, HjO Fc HO. Specific Gravity 60-6QF PPM PPM PPM 9 74.82 932 1.429 189 _ 54.17 2702 1.388 22 40.15 1168 1.345 "50----------- 28 51S.S4 54.88 "573-- 812 17 353 1*330 32 42.48 1066 1.394 30 50.71 800 1.266 60 46.66 1427 1.407 127 40.71 1495 1.421 25 24.96 951 1.419 26 41.14 862 1.430 42 34.61 989 1.422 65 10.35 192 1.421 59 41.64 1112 1.383 - -- SL 0u 1lO1^J7/7/ r* * L-------------CO FJFTDEK 'FI A : ----- Strtr jrecft u "Prot errtrrvt Ttnrrfm of- I"4 rh Jud Lcial Distti c t Col It N ll'IS' FORM f "TR1-ETHANE* TCE REACTOR I.imvi Chloride 1973 AVGWT.% (O.Ol JAN 0 FEB 0 'PPG IWUSTRIES CHEMICAL DIVISION LAKE CIIARIES, LOUISIANA LABORATORY OPERATIONS REPORT MAR APR MAY JUNE JULY (0.01 (0.01 0 0 0 AUG 0 SEP OCT n0 NOV 0 DEC 0 1974 Avg. (0.01 CIS 1.2 DlCHLOROETHYLTNE 1.2 Dichloroethame Tfl 1 CHLUROE thylene 1.1.2 Tfl1CHLOBOETHANC U-Tetrachloroethane S.TETBACHLOBOETHANE PeNTACKLOAOETHANE (0.01 (0.01 (0.01 65.28 (0.01 31.06 1.59 1.90 0.06 63.40 (0.01 32.60 1.74 2.04 0.06 64.42 0.01 31.54 1.74 2.04 0.07 (0.01 62.69 0.01 32.88 1.96 2.29 0.08 (0.01 ; 62.43 (0.01 32.77 1.95 2.30 0.09 (0.01 62.63 (0.01 32.71 1.95 2.29 0.10 fn m 60.63 0.02 33.86 2.04 2.40 0.11 0 63.63 0.03 31.33 1.73 2.02 0.13 0 n0 63.82 0.03 30.35 1.59 1.89 0.20 61.16 (0.01 33.48 2.00 2.36 0.09 61.63 (0.01 33.67 TTol 2.39 0.08 0 57.24 0.01 36.64 2.72 3.07 0.13 0 59.16 (0.01 35.40 2.47 2.65 0.08 (0.01 61.90 0.02 33.11 1.99... 2.31 0.10 F E PPM 3 2 3 HEAVIES STILL REFLUX WT.% * 35 13 20 13 12 14 22 27 56 16 CIS 1.2 DlCHlOROETHYllNE 1.2 Dickloroethane TbiCHLOROETHYLCNE 1.1.2 Trichloroethane u.TETRACHLOROETHANE (0.01 (0.01 (0.01 0 0 (0.01 0 0 (OiOl 0 (0.01 (0.01 0 (0.01 (0.01 0 0 (0.01 0 0 0 0 (0.01 0.01 0 0 (0.01 (0.01 0 (0.01 (0.01 (0.01 (0.01 36 0 58 61 6 139 48** 3** 9.8** 99.97 99.99 99.98 0.01 (0.01 (0.01 99.97 99.96 99.98 99.98 99.78 99.91 99.95 99.74 99.95 99.89 99.92 0.02- (0.01 (0.01 (0.01 0.80 (0.01 (0.01 ,0.01 493 420 456** H.,0 PPM - -- - --- Fe ppm .. (1. . 3.4 (0.1 6". <38 (1 (1 (1 2 - - LIGHT STILL REFLUX HjO fe PPM 2 2 fit ^^78 RL 2 "3------ 3 6 45 64 c Subesquent to Nov. values will kg reported in PPM **' Average in PPM . -- TT----- (1 -- (1 (1 * 52 2 4 7I t- A 11 -----------vc Or 1IC. X-- \ n y r- - J a v* L w O U fe1 " f- ) 1A FORM 202 12 PPG IN^iTRIES "TRI .ETHANE" HEAVIES STILL FEEO 1,1,2 TrICHLOROETHANE UTEYBArHLOROETHANE S-TETBACHLOBOE THANE Pe.n..t.a..c..h..loboethane 1973 avg. WT% 89.56 4.98 5.59 0.19 JAN 88.58 5 09 6.13 0.20 FEB 88.58 5.1 s 6 f)S 0- 1R CHEMICAL OIVISIOM LAKE CHARLES, LOUISIANA LABORATORY OPERATIONS REPORT MAR APR MAY JUNE JULY AUG 87.42 5.51 6.65 0.37 87.20 5i64 6;85 0.29 87.10 5.68 6.94 0.24 87.13 5.67 6.86 0.34 86.98 5.53 7.10 0.39 87.10 5.62 6.65 0.62 5EP 87.09 5.79 6.87 0.25 OCT 86.89 5.84 6.95 0.29 NOV DEC 86.62 6.12 6.97 0.26 87.25 5.98 6.59 0.18 1974 Avg. 87.33 5.64 6.72 0.30 VDC REFLUX WT. % VtNYEIDENE CHLORIDE Trans. 1.2 Dichloroethylene CIS 1,2-OlCHLOROETHYtENE 99.70 0.13 (0.01 99.57 0.28 (0.01 99.53 0.33 0 99.55 0.32 0 99,. 35 0.24 0 99.57 0.28 0 99.38 0.39 0.02 99.34 99.38 0.40 0.36 0.03 0.11 99.42 0.43 (0.01 99.18 0.30 0.02 99.16 99.37 0.25 0.35 0.01 0.05 99.40 0.33 0.02 TQNME PPM 198 213 174 177 188 230 234 198 204 168 148 205 361 208 VOC PRODUCT PPM HjO 20 26 35 51 28 28 28 HCAWE . 257 289 224 190 265 294 318 46 59 220 243 34 194 46 178 35 . 34 214 297 38 244 * su I 1 --CU1 IF1UEN L'lAL: --smr ecit ti rrror iCtiVS crrdfTi or in frmTd cial itstrrl Tt Cere It ' " N< n-- .14 5-- FORM K 5A 202 - 13 *'TRI - ETHANE "<B> 1973 avg. MC REACTOR WT. % Ethyl Chlorioe (0.01 VINYLIPENC CHLOBIPF______________________ 3.68 TRANS 1-Z-DICHLOROETHYLENE 0.28 JAN FEe (0.01 (0.Q1 5.17 A fid 1.36 1.18 PPG \l STR1ES CHEMICAL division LAKE CHARLES, LOUISIANA LARORATORY OPERATIONS REPORT MAR APR MAY JUNE JULY 0.01 4.58 1.16 0.O1 Am n ac. (0.01 3.55 0.73 fn.ni 0.02 3.94 4.78 0.80 0.83 AUG SEP OCT NOV DEC 1974 Avg. (0.01 3.56 0.93 (0.01 3.61 1.27 (0.01 4.36 0.68 (0.01 3.92 0.53 (0.01 4.20 0.67 (0.01 4.19 0.90 CIS 1 ,2-DlCHLOROETHYLENE Methyl Chloroform (0.01 0 0 95.95 93.35 92.29 000 0 0.03 0.06 (0.01 (0.01 0 (0.01 (0.01 94.16 95.40 95.45 94.97 94.19 95.33 95.06 94.5$ 9^.35 94.95 94.62 trichloroethylene 1 ,1 ,2-TRICHLOROETHANE U-TETRACHLOROETHANE PENTACHLOROETHANE Unknown (0.01 0.06 (0.01 0 (0.01 0 0.11 (0.01 0 (0.01 0.01 0.12 (0.01 0 (0.01 (0.01 0.07 (0.01 0 (0.01 i.0.01 0.04 0. 0. (0.01 (0.01 0.08 0 0 (0.01 (0.01 0 0.14 0.13 0 ( 6.(51 00 (0.01 0.02 (0.01 0.11 (0.01 0 (0.01 0 0.05 0 0 (0.01 0 0.04 0 0 (0.01 0 0.04 0 0' 0 6 0.03 0 0 0 (0.01 0.08 (0.01 0 (0.01 Ft PPM 848 514 436 788 876 719 807 1380 1481 588 587 566 710 788 - TOPPING STILL PRODUCT WT5 vinylioene Chloride * 0.02 TRANS l,1-Dichloroethylene 0.07 1,1-DtCHLOROETHANE 0.01 CIS 1.2-D1CKL0R0ETHYLENE Methyl Chloroform (Q.01 99.80 I,2-Dichloroethane 0.03 Trichloroethylene (0.01 1.1,2-TRPCHLOpCETHANC 0.06 0.01 0.22 0.01 (0.01 99.66 0.03 (0.01 0.06 (0.01 0.160.01 (0.01 99.64 0.06 (0.01 0.11 (0.01 (0.01 0.21 0.20 (0.01 0.02 (0.01 (0.01 99.67 99.66 0.05 0.06 00 0.04 0.04 (0.01 0.15 (0.01 (0.01 99.75 9.04 9 9.05 (0.01 0.21 0.04 0.01 99.55 0.07 (0.01 0.09 0.02 0.23 0.06 0.05 99.42 0.07 0 0.12 0.02 0.17 0.04 0.09 99.56 0.03 0 0.08 9.01 9.23 0.08 (0.01 99.55 9.03 9 9.08 0.01 0.22 0.13 0.0J, 99.51 0.03 0 0.07 100 97 0.18 0.21 0.05 0.11 (0.01 0.03 99.64 99.50 0.02 0.03 00 0.07 oTo? 98 ** 0.20 0.05 0.02 99.59 0.04 (0.01 0.07 . - SL 013380 cown 9 EBITA fTT--------{TtTjTTC . TO' V TTtTrrrt i. vt! Or i i er r 1 6t ri I'M TrrtiTrr rt--rrrs tTTTTtr C* tv a L Nu. rr--arnt A* Subsequent tg^Nov. .values will be reported in PPM FORM i5A 202- 14 'TRI-ETHANE* TYPE 324 STABILIZATION WT. % vinlyidene Chloride BLM BTE 1973 Avg i 0.01 0.39 0.76 JAN FEB PPG INDUSTRIES CHEMICAL DIVISION LAKE CHARLES, LOUISIANA laboratory operations report MAR APR MAY JUNE JULY AUG (0.01 (0.01 (0.01 0.55 0.46 0.52 1.04 0.82 0.76 10.01 0.51 0.79 (0.01 (0.03 n an 0.43 n 7^ 0.79 (0.01 0.02 0.49 0.46 0.81 n_7fl SEP 0.01 0.48 0.77 MiOCT NOV DEC 0.02 0.49 0.73 0.01 0.46 0.81 0.02 _ n, 0.87 n.m n, 49 0.81 Methyl Chloroform OOL CIS 1,2-Dichloroethylehe trichloroethyl ene I .2-Dichloroethane IBL NRE N1TROCTHAHC -MEL_____________________________ TCE 1 ,1 ,2-TRICHLOROETHAME 94.02 1.00 0 (0.01 0.03 0.37 2.19 0.06 0.65 0.80 0.04 93.52 1.06 (0.01 (0.01 0.02 0.36 2.12 0.06 0.42 0.82 0.05 93.78 1.06 0 (0.01 0.02 0.06 2.05 0.10 0.75 0.75 0.10 93.86 93.68 1.07 1.05 00 00 0.04 0.03 0.02 , (0.01 2.05 2.25 0.11 0.08 0.79 0.79 0.76 0*78 0.07 0.06 - 94.07 1.00 0 0 0.03 0 2.06 0.10 0.78 0.72 0.06 93.89 0.98 (0.01 (0.01 0.04 0 2.10 0.11 0.78 0.77 0.11 94.11 0.88 0.03 (0.01 0.07 0 1.92 0.09 0.50 0.70 0.11 93.87 0.97 0.04 (0.01 0.02 0.11 2.10 0.03 0.72 0.80 0.08 94.03 0.93 0 (0.01 (0.01 0.73 2.07 0 0.08 0.80 0.07 93.85 1.01 0.01 (0.01 0.0 0.84 2.08 0 (0.01 0.89 0.06 93.77 1.03 0.01 (0.01 0.0 0.83 2.04 0 (0.01 0.85 0.08 93.48 1.04 0.04 (0.01 0.0 0.87 2.22 0 0.01 0.89 0.09 83.83 1.01 0.01 (0.01 0.02 0.32 2.09 0.06 0.47 0.79 U7o5 STABILIZING TANKS Moisture ppm PH HCL Acidity Non-Volatile Residue ppm * Color Specific gravity APHA Avg. Oh tillatiom Ramge Low Soluble Chlorides High C pf>m 46 7.0 (1 .0002 6 1.305 73.2 P2.7 (0.5 54 7.0 (1 .0002 5 1.306 73.0 82.7 (0.5 63 7.0 (1 .0002 6 1.306 72.8 82.8 (0.5 57 52 6.9 6*9 21 .0002 .0003 6 6. 1.305 1.304 72.8 82.2 (0.5 72*8 32.2 (0.5 62 6.9 1 .0002 6 1.305 50 6.8 1 .0002 7 1.305 44 66 6.8 6.9 21 .0002 .0004 95 1.305 1.304 61 6.8 2 .0002 (5 1.304 72.8 82.3 (0.5 72.8 82.5 (0.5 72. B 82.8 (0.5 7278 73.2 mTL-- 82.8 7975 (0.5 , 29 6.8 2 .0003 (5 1.304 47 44 6.8 6.7 22 .0002 .non? (5 6 1.304 1.304 52 6.9 1 . 0005 5 1.305 73.4 82.8 (o.'S 73.4 83.3 (0.5 73.4 83.3 (0.5 73.0 82.9 (0.5 cOiL 0w 13381 Sub ji < if 141 i TON 5*1 IlCH'l TAT.. Tri PrnFe r*fr f vo Judi t i -t 1 r iclrif P No . 9.1-1 1 4S r*<-> t f **- FORM 15A202. 15 PER - TRI HEAVIES STILL BOTTOMS Trichloroethylene 1,1,2TIHCHLOROETHANE Pfrchloroe thvlene U-TtTBACHLOROETHANE S-TETRACHLOROCthane Pentachloroethanc HeXACHLOROCthane % % ft ft ft ft ft PPG 'USTRIES CHEMICAL OiVISION LAKE CHARLES, LOUISIANA laboratory operations report 1973 AVG. (0.01 (0.01 13.84 2.16 34.38 22.33 1.67 JAN 0 0 7.50 3.88 42.96 28.30 1.83 FEB MAR 0.06 0.25 n.fii 6.54 28.83 30.00 2.30 0 0.03 17.51 4.09 26.20 26.85 3.23 APR MAY JUNE JULY D. 03 (0.01 30.85 3.56 27.90 20.84 2.81 0 0 23.50 4.43 28.69 22.72 3.71 0 0 17.18 5.25 39.66 22.80 2.57 0 0 18.30 4.34 26.49 24.49 4.42 AUG SEP OCT NOV 0 0 24.49 4.12 26.90 24.16 4.12 (0.01 (0.01 26.92 3.94 25.77 21.34 5.61 0 P 28.63 3.82 27.34 21.79 4.18 0 0 17.9S 4.62 31.03 27.45 2.94 Heavy Unknowns ft 5.27 5.13 7_ 55 9.81 4.52 4.24 3.99 6.51 4.81 5.37 T7SI 5.50 FtCL, Non-Volatile PPM 22 ft 2.64 14 2.33 22 31 3.87 6.10 54 4.07 10 2.40 46 3.68 34 - 52 69 84 41 -- - OEC (0.01 (0.01 20.81 4.19 22.48 29.88 4.94 1974 Avg. (0.01 0.03 20.63 4.40 29.52 25.05 3.56 6.27 47 - 5.71 42 3.74 -- 5oiL nUilo*aoufztoL i 4 "CON P D I'lN'J'J \L : SO l> jut "t--On-- 'TTrlrPm "TTC--ti LMU L" 14Ui JuOic TTT--uT "Irict "TJTUtlXt * n J X1 1111 a r. i FORM f A 202.16 TPG iWuSTRIES CHEMICAL DIVISION LAKE CHARIES, LOUISIANA LABORATORY OPERATIONS REPORT PERCHLOR STABILIZATION 1YPE 208 WT. Perchloboe thyleme 1.J-DlCHLOROBROMOETHYLEHE 1 . 2- DlCHLOROBROMOE THYLEHE U1.2-TR1CHLOBOETHANE UlTE TRACHIOROETHANE EPE % 1973 Avg . 99*89 {0.01 0.01 0.01 0.04 0.04 JAN FEB 99.77 (0.01 m.m 0.02 0.05 0.05 99.85 (n nl d.oi 0.02 0.05 0.05 MAR APR 99.88 0.01 0.02 0.01 0.04. 0.05 92.86 (0.01 0.01 0*02 6*05 0.05 MAY 99.87 (0.01 0.01 0.02 0.04 0.05 JUNE 99.87 (n.m n. m 0.04 0.03 0.04 JULY AUG SEP OCT NOV DEC 99.87 99.89 99.86 (0.01 (0.01 (0.01 0.01 (0.01 0.01 0.03 0.01 0.03 0.03 0.04 0.05 0.05 0.05 0.04 99.85 [0.01 0.02 0.04 0.05 0.04 99.87 (0.01 0.02 0.03 0.04 0.04 99.86 (0.01 0.01 0.03 0.06 0.04 1974 Avg. 99.86 (0.01 0.01 0.03 0.04 0.05 TYPE 207 PEBCHtOBOE THYLEHE WT 1,1-Dichlobobromoethylehc 1 . 2-DlCHLOROBROMOE THYLEHE t.J,ZiTfllCHLOROETHANE U-.TETHACHLOROE THANE EPE % 99.80 {0.01 {0.01 0.01 0.04 0.05 99.81 0 0 0.01 0.05 0.05 99.80 (0.01 0 0.02 0.04 0.05 99.81 0.01 oTol 0.02 o7o3 0.05 99.80 00 0.02 0.03 0.05 99.76 {0.01 0 0.02 0.05 0.05 99.80 (0.01 0 0.02 0.04 0.04 99.79 {0.01 0 0.04 0.03 0.04 99.80 (0.01 0 0.02 0.03 0.05 99.79 (0.01 0 0.04 0.05 0.05 99.79 (0.01 0 0.03 0.05 0.04 99.81 (0.01 0 0.02 0.04 0.04 99.82 (0.01 (0.01 0.02 0.05 0.05 99.80 (0.01 (0.01 0.02 0.04 0.05 ' ' SL 013383 CO *FIDEft TTAf.. Sub ect t J Prot i vc n r:_rl ^ | of 141 h Jud LCial 'll Bl-ri r>fN< >, 91- t 145 zu _____ 1 FORM i^^5A 202-17 TRICHLOR STABILIZATION 1973 AVG. TYPE 115 WT.% JAN USTRIES CHEMICAL DIVISION LAKE CHARLES, LOUISIANA LABORATORY OPERATIONS REPORT FEB MAR * APR MAY JUNE JULY AUG SEP OCT NOV OEC 1974 AVG. Carbon Tetrachloride ADH NPL T R1CHLOROtTHYLEHE Perchlohoethylene 1. l.2-Trichloroethane Unidentified. Total (0.01 0.03 (0.01 99.46 (0.01 0.02 (0.01 TYPE 122 WT. % Cabbon Tetrachloride ADH NPL TR1CHLOROE THYLEHE Perchloroethylene 1, 1,2-Trichloroethahe GDL Unidentified, Total . NMP NRE DPE (0.01 0.03 0.16 99.52 (0.01 0.02 0.06 (0.01 0.02 0 ;03 0.16 99.46 n 0.01 0.06 fO.Ol 0.01 0.04 0.16 99.48 (0.01 0.02 0.06 (0.01 (0.01 0 0.13 99.59 0.01 0 (0.01 0.027 0.05 .0093 0.16 99.47 (0.01 0.02 --. (0.01 0.03 0.06 .0150 (0.01 (0.01 0.14 99.40 '0 0.01 0.14 99.38 0 0.01 0.01 0.03 0.06 .0110 0.01 0.03 0.06 .0110 (0.01 - 0.14 99.39 0 0.01 - 0.01 0.03 0.06 0.014 (0.01 0.14 99.46 0 0.02 -- (0.01 0.026 0.06 0.010 (0.01 - 0.13 99.39 0 0.02 - (0.01 0.028 0.06 0.013 (0.01 [0.01 -- (0.01 - 0.13 0.14 99.37 99.35 00 0.03 0.02 "- 0.14 99.38 0 0.02 -- (0.01 (0.01 (0.01 0.028 0.031 0.030 0.05 0.05 0.05 0.009 0.010 0.009 (0.01 0.04 0.14 99.43 (0.01 0.02 0.06 (0.01 0.029 0.06 0.011 -- __ SL 013384 C OlJFIDI NT1A Lj Su of 1 aiect 4th 3u to Prtj diciaJ , t C c L i1 : Dist 1 AT No- 9: * Type 122 is Type 132 Subseauent to Fob. ar iiir t FORM N A 202. 10 P^G INDUSTRIES CHEMICAL DIVISION UKE CHARLES, LOUISIANA LABORATORY OPERATIONS REPORT TRICHLOR STABILIZATION 1973 Avg. JAN FEB MAR APR MAY JUNE JULY AUG SEP OCT NOV OEC 1974 Avg. TYPE I IOE WT.. % Cab bon Tetrachloride ADH NPL Trichloroethylene PERCHLOROE thylene 1.1.2-trichloroethane GOL Unidentified.) Total 0.01 0.08 0.32 98.88 0 0.03 0.12 CO.01 TYPE 113 WT. % Carbon Tetrachloride NPL Trichloroethylene Perchloroethylene i.l. 2-Trichloroethane Unidentified. Total (0.01 (0.01 0.01 (0.01 n (0.01 (0.01 (0.01 0 (0.01 (0.01 (0.01 0 (0.01 (0.01 99.97 (0.01 0.02 0 qq.qn 0 0.01 0 9q.q7 0 0.01 0 99.98 (0.01 0 99.99 0 (0.01 0 99.99 o (0.01 00 99.98 99.98 00 0.01 (0.01 0 99.98 (0.01 (0.01 0 99.96 (0.01 0.01 00 99.98 99.98 00 0.02 0.01 0 99.98 (0.01 0.02 0 99.98 (0.01 0.01 (0.01 (0.01 0(0.01 00 0 0.01 (0.01 (0.01 (0.01 (0.01- 0 (0.01 i L_ SL 013385 !-- i 1 ' CONF lDENTI AL; Sutrjei . L L u L x v tr c! Trim-- -------- roc >j url i" c Ldl Dj y t z i crt Coxa (f'crr ~9x''xl TO--------- FORM * ' 45A 202 19 ETHYL CHLORIDE 1973 Avg. JAN FEB - PPG USTRIES CIIEMICAl DIVISION * IAKE CHARIES. LOUISIANA LABORATORY OPERATIONS REPORT MAR APR MAY JUNE' JULY AUG SEP OCT NOV DEC 1974 - Avq, C2H4 Feed % PRIMARY STRIPPER Bottoms PPM HCl FeCl3 H2O 99.92 99.87 99.92 99.91 99.94 99.97 99.95 99.93 99.95 99.91 99.86 99.94 99.88 99.92 242.9 10.3 122 43.7 2.1 117 117.5 60.9 64 99.8 4.3 89 _ 6.2 68 99.7 -- -- - - 90.2 3.4 11.4 6.93 0.81 4.40 1.68 1.37 2.18 56 56 66 112 126 66 36 78 Still Overhead C2h5ci HCl Wt. % 99.96 99.95 - 99.97 - -- -- - -- -- 99.96 PPM 294 _ 55 . - --- - --- -- 55 H?0 PPM 161 256 46 - --- - -- -- 151 , _ 4>L 013366 - ' 1' tdent: TfET n u; 1 sri --txr~ Jtrqic -----nor Protec 131 Us tivo strici T5------- >rder Cour FOI SO 1 VINYL CHLORIDE 1S73- JAN FEED TO UNIT * EOc VAPORIZING FURNACE FEED AVG. 99.98 99.97 vinylidene chl moe 1,1-DICMLOnOETHANC CHLOHOF nw wt. it (0.01 WT. % 0.04 WT.* 0.05 (0.01 0.04 0.02 1.1* WCHLOWOETMAME OTHER* wt. % 99.78 99.88 WT.% o.oi 0.01 MI' PPM 41 56 MCI ytt.% ^ PPM Clj PPM ABSORBER-STRIPPER COLUMNS QU ENCH LIQUOR 0.03 0.20 (1 0.03 0.24 (1 VINYL CHLORIDE vinylidene chl aide l- 1.1 DICHtOflOCTHYLCNC f 1- Of CHL R ETHANE CHton phene CHL EORM nT.% wt.* NT, WT.S wt.* WT.\ 9.86 (0.01 0.07 0.02 U . Ub 10 .-68 b.02 0.04 3.02 3.03 I.J- OICHLORQETKANC THEM MjO MCI WT.* wt.* PPM WT.* PPM 89.41 0.08 191 0.85 ii.o5 39.16 3.04 213 3.93 17.46 FEB 99.98 (0,01 0.04 0.04 99.86 (0.01 29 0.04 0.89 (1 3.39 0.01 0.06 0.01 0.05 96.44 0.03150 0.98 61.28 . PPG)USTRIES ' ' ; CHCMICTaDIVISION tAKC CHARLES, LOUISIANA LABORATORY OPERATIONS REPORT MAR APR 99.98 99.98 MAY 99.99 JUNE 99.99 JULY AUG SEP OCT 99.99 _99.99__ 99.99 99.97 NOV 99.96 DEC 99.99 .1974 AVG. 99.98 (0.01 0.04 0.03 99.87 (0.01 76 0.02 0.24 (1 iO.Ol 0.04 0.39 29.13 Q.01 65 0.02 0.35 (1 (0.01 0.04 0.14 99.62 (0.01 (0.01 0.04 0.03 99.82 {0.01 76 0.04 0.35 89 0.08 0.48 71--------- (1 0.01 0.04 0.02 sgrsr (CL 01 87 0.02 0.33 a (0.01 0.04 0.03 99.84 (0.01 96 0.03 0.18 (1 (0.01 (0.01 0.05 0.05 0.23 0.14 ~WT5T 99. 0.03 67 0.04 0.23 0.01 76 0.02 0.22 (1 a (0.01 0.04 07217" 97TUET 0.01 33 0.01 0.51 1 (0.01 0.05 0.27 99.31 0.01 51 0.01 0.46 (1 (0.01 0.04 0.13 99.68 0.01 67 0.03 0.37 (1 -- _. -- _ - - --- 7.04 - - - -- 0.02 - - --_ - ---- -. "- - - -w --- --- - 0.05 - - -- - 0.02 - -- -- 0.04 " - - - 92.80 -- 6.o4 -- 134 101 79 146 179 219 44 ------- 155-------- -- - - - -- 3.96 - 13.70 14.99 3l5 15731 2.60 12.27 19.33 4.4(J 23.23 16.64 FI1 Hi ACE FEED % CC1(| JLfli- ,(2^1 (0.01 (0.01 0.34 0.09 (0.01 {0.01 0.01 0.08 0.02 0.01 0.04 0.05 Si- 0J3387 -- i fLTTTT A J: >n!.' jec 1 '(XI 1' TTtxrrr "W-DT lr 1 O A. 11"! ITTi rr-ttttt T tv L txjxmr~ FOf. m 202- VINYL CHLORIDE ABSORBER-STRIPPER COLUMNS LEAN It VIMYL CHLORIDE WT.H VtNVLIDENE CHLORIDE WT.S 1973 AVG. (0.01 JAN 0.03 FEB PPG fMJSTRIES CIlfMIC^^OIVIStON LAKE CIIAfllES, LOUISIANA LABORATORY OPERATIONS REPORT MAR APR MAY JUNE JULY 0.02 0.01 __ _ - AUG 1.1* DICML ROCTHANC CHLOROPREME chloroform (,l* OICHL ROCtHANE OTHER! MjO, MCI P* UPPER INTERC LER VINYL CHL WIDE Ml H Cl re LOWER INTERC OLCR VINYL CHLORIDE he MCI re WT,% 0.06 wt.% 0.04 0.05 0.04 0.07 0.06 0.07 0.03 ftr.% WT.X V1T.X PPM PPM PPM 0.06 99.47 0.05 51 1.57 0.43 0.03 99.82 0.02 51 5.68 0.47 0.06 99.59 0.04 25 15.57 0.80 to7o3 99.83 o.o2 82 6.18 0.42 r - -* " -* - - - - -- -- "- --, ---- WT.X PPM WT.* ppm 1.93 396 1.57 31.01 2.64 275 1.68 11.70 0.76 180 ` 1.30 22.49 - WT.X ppm WT.fc ppm 6.11 215 1.54 18.37 3.20 163 2.02 4.44 1.23 65 5.50 2.75 -- -- 233 15.81 - 287 31.00 --- 226 215 -- 29.62 29.65 - 221 8.27 - 364 - 27.28 - 283 - 23.51 _- 198 _ 212 - 26.50 30.87 - 306 _ 19.04 -\ SEP OCT NOV 0EC 1974 AVG. --- ------ - - -- 107 3.56 _ - , M, 105 4.86 -- - * - '335 11.48 187 8.70 - - 0.02 - 0.06 - 0.94 or - 99.75 -- 0.03 T3-------9.14 0.56 116 11.00 1.70 197 1.49 16.80 -_ 108 - 8.56 2.22 221 3.76 16.31 \ i \i t t Li~ SL 013388 J * --Sub j &r--14L 3 i Cup eft Ec JUdi No FIDEN'j Prot cial t . 91-1 IAL: ct i ve istric TT5 Order t Cou] t FORM#** PPG l,msTRIES ', CHEMICAL DIVISION : LAKE CHARLES, LOUISIANA LABORATORY OPERATIONS REPORT VINYL CHLORIDE 1973 AVG JAN FEB MAR APR MAY VC________________ PRODUCT STILL FEED VINYL CHL RIDE VINYUOENE CHLORIDE 1.1-OTCHL.On ETHANE CHL ROPREHC WT-.% Wt.% WT.% WT.t 15.98 0.01 0.06 0.04 chlorof rm 1.3- OICHL ROETHANC wt.% 0.07 WT.t 83.89 OTHERS Hj WT. % 0.03 PPM 48 H Cl PPM 3.83 re ppm 0.83 PRODUCT MONOMER (OAV TANK]) VINYL CHL, RIOC butadiene methyl chloride ETHYL CHLOmOE WT.% 99.990 5ppm - ppm 12 PPM 37 12.58 0.02 0.05 0.04 0.03 87.23 0.02 67 7.38 0.99 -- _ _ - 20 6.08 0.63 99.995 99.990 69 21 23 21 64 -- - 0.07 - 0.07 --- - 0.10 _ -- 99.34 - -- - 45 75 -- 1.63 . T785 s 99.97 99.986 99.977 87 8 31- 33 32 124 90 12 JUNE JULY AUG _ __ -- - -' - 69 1.45 - --- -- -- -- -- 53 60 --- 0.39 . 1.90 99.98f 99.984 99.991 10 6 5 33 26 22 56 52 34 SEP OCT NOV DEC 1974 AVG - - - -- -- 87 2.08 - - - - - - 95 0.86 - - - -- -- - 66 - 0.32 - - -- - 32 0.28 l2.58 "6765 0.06 0.04 0.07 93.29 0.02 61 6.73 1.13 99.995 99.994 99.995 3 42 25 ' 29 26 17 16 17 99.994 2 30 21 99.989 6 28 23 OTHERS HjO Re PH HC1 Vinyl Acetylene 1,1 - Dichloroethane 1,2 - Dichloroethane PPM 0.2 PPM 41' ppm. 7.4 U PPM 4 PPM (1 PPM 0 (0.1 45 0.12 7.0 0.2 5 U (1 (0.1 40 0.20 7.2 (1 5 0 0 0.1 49 0.16 7.1 (1 4 - - 0.1 (1 37 39 0.13 0.11 7.2 7.2 (0.1 . (1 3 8------------------- i-----------; - -- (0.1 30 0.08 7.3 (0.1 9 - - 0.5 37 0.04 7.3 :o.i 5 - - 0.3 45 ` 0.06 7.5 0.2 5 - 0.3 57 0.12 7.6 0.2 4 - - 6.2 46'1' 0.04 7.5 (0.1 4 - - 0.2 34 0.09 7.5 (0.1 2 - - 0.3 45 0.04 7.3 . (0.1. 6 - - 0.2 42 0.10 7.3 0.2 5 1.2 (i - - - SL 013389 * f-! 11 h i ru r' of 1 4 t ti f'f iMM r LM5N 111 L i ro tec t Tvn cn tier 11 J 1 U1 b trlc't court T1 1 * FORM 15A 202 / 23 - I `*PPj3 WUSTRIES CHEMICAL DIVISION LAKE CIIARIES, tOUISIANA LABORATORY OPERATIONS REPORT VINYL CHLORIOE FECD HEAVIES STILL 1973 JAN FEB MAR APR MAY JUNE JULY AUG SEP OCT NOV OEC 1974 AVG. AyG_. _ VINYUOENE CHLORIDE * 1.1- OICHLOROETH AN E c- i.a- dichloroethyLENC CHLOROrOAM l .I- D1CHL BO C TM AN E 1.1,2' trickloroeth ahe OTHER* M,0 H Cl re - Cl, WT.% (0.01 WT.% 0.06 WT.% WT.% 0.07 VfT.11 99.31 WT.% 0.19 WT. % 0.06 PPM 38 VfT.% 0.13 PPM PPM 1.30 2; BOTTOM* CHLOROP rm l.a* OICHL R ETHANE Trichloroethylene W T.% W T.% Wt.% (0.01 73.47 (0.01 0.02 0.05 0.03 99.68 0.15 0.03 73 _ 0.03 2.49 (1 (0.01 61.92 0 * 0.02 (0.01 0.06 99.58 0.18 0.02 30 0.04 1.51 (1 0 66.22 0 (0.01 0.06 -0.05 99.82 0.02 0.04 iol 0.01 TT33 1 0 86.11 0 0.02 (0.01 0.07 0.07 (0.01 0 0.84 0.20 98.07 qq.fiq 0.12 0.10 0.02 0.04 71 55 0.03 0.06 8.63 6.17 71--~ (1 00 86.88 85.18 00 fn m (0.01 (0.01 0.08 0 0.05 99.48 0.18 0.06 102 1.44 9.36 1 n net 0 0.03 99.65 0.11 0.04 77 0.03 3.12 (1 0.07 0 0.04 99.63 0.15 0.02 7b cJ703 2.29 1 0 82.07 0 0 86.74 0 0 82.85 0 . 0.02 0.08 0 0.44 98.65 0.18 0.02 55 0.02 2.89 (1 0 82.15 0 (0.01 0.02 0.08 0 0.20 0.08 0 6.2i 98.90 99.32 0.27 0.05 0.08 0.03 96 si - 0.02 0.02 3.25 2.18 (1 1 ' 00 69.36 91.87 O0 0.02 cToT 0.10 0 o.5o 98.03 0.05 0.13 44 0.01 2.68 (1 0.07 !o7iI 0773 99'. 2i 0.13 0.05 69 0.15 4.01 a 0 87.34 0 CO. 01 80.73 0 1.1.2* TRICHLOROETH AHE - VfT.X 18.61 25.95 22.90 8.04 7.45 7.93 . 7.95 OTHER* MCI %WT. 7.83 XWT. 0.08 re PPM 39.76 V.ASTE-DOPP KFTTI F BOTTOMS t J- OTCHLOROETH ane ** ECH LORO ETHYLENE %WT. *WT. 11.79 0.02 97.38 10.88 3.03 109.28 1.1.2* TR1CHLOROE THANE u*tetracmloroethane * T E T R ach lo r e th an e WT.1l %WT. WT.% PEN TACHLOROETHANE WT.% * TMERS nT\ re PPM TAR* KCSIDUK WT.% WT.% SL 01339U 5.47 0.02 87.55 5.67 0.05 99.02 5.89 8.56 3.03 0.03 136.82 73.43 8.14 11.32 V 5.12 5.83 0.02 3.01 71.55 58.74 11.62 6.22 0.02 77.89 20.32 2744 4.17 . 11.52 10.32 5.70 0.02 0.02 49.41 51.20 8.49 0.04 51.95 7.58 0.03 80.34 * COf* FI DENI I ALt . Sub- 5Ct tc Prot ctive Orrtor 141 i Judi cial t istrif t Cnn Nc . 91-1 145 PAGE: 202- 27 PPG INTODUl STRIES CHEMICAL DIVISION LAKE CHARLES,LOUISIANA OHC-EDC CONDENSED ORGANIC REACTOR NO. 1 Methyl Chloride % Vinyl Chlorido Ethvl Chloride Vinylidine Chloride 1.1-Oichtoroethvlene cis-t, 2-Dichloroethylene Chloroform EDC Carbontetrachloride Tr ichtoroe thvlene Chlorel L 1,2- Trichioroethane Perch loroethylene U-Tetrachloroethane S-Tetrachloroethane Pentschloroethane Unknown* 1973 AVG. JAN. FEB. MAR. APR. MAY JUNE JULY AUG. SEP. OCT. NOV. DEC. 1974 AVG. 0.04 0.08 0.74 0.05 0.05 0.10 0.62 0.05 0.03 0.07 0.24 0.05 0.04 0.08 0.49 0.06 0.04 0.08 0.88 0.04 0.08 0.08 0.79 0.06 0.05 n 07 n Aa 0.05 0.06 0.04 0.29 0.06 0.03 0.05 0.32 0.03 0.04 0.05 0.38 0.04 . 0.04 0.05 0.52 0.04 0.06 0.06 0.32 0.06 0.05 0.06 0.31 0.06 0.05 0.07 0.45 0.05 0.18 0.21 0.64 94.61 0.79 0.13 0.56 1.74 0.02 0.01 0.18 (0.01 0.19 0.26 0.62 94.43 0.88 0.09 0.63 1.92 0.02 (0.01 0.16 0 0.12 0.17 0.46 96.09 0.64 0.08 0.37 1.54 (0.01 (0.01 0.15 0 0.16 0.20 0.80 94.93 07T7 T57IG 0.58 T763 0.02 0.01 0.13 0 0.18 0.17 0.37 96.16 0i 41 0.08 0.41 1.30 0.02 , (0.01 0.16 0 0.26 0.23 0.60 95.09 0.46 0.19 0.33 1.70 0.03 (0.01 0.25 0 0.26 0.29 0.39 95.54 0.39 0.13 0.31 1.69 0.05 (0.01 0.30 0 0.20 0.23 0.59 94.31 0.56 0.13 0.21 2.48 0.03 0.01 0.82 0 0.23 0.27 0.36 96.11 0.29 0.13 0.16 1.64 0.03 (0.01 0.39 0 0.22 0.28 0.85 93.88 0.93 0.12 0.43 2.24 0.02 0.01 0.49 0 0.15 0.17 0.71 94.89 0.83 0.10 0.34 1.74 0.03 0.01 0.37 0 0.18 0.13 0.36 0.16 0.73 1.08 94.26 93.42 i:or 1.65 U7T2 0.11 6727 ~ 0.24 2.TT9- 2.24 o:o3 0.03 0.02 0.02 0.51 0.39 00 0.19 0.23 0.63 94.93 0.74 0.12 0.36 1.85 0.03 (0.01 0.34 0 (0.01 (0.01 D 00 00 0.01 (0.01 (0.01 (0.01 0.01 ~5---------- (0.51'" SL u ioo3i 'Unless Otherwise Indicated CONF . DENTl \L: Sublet t to ' rotee rTve d rdet of 14 th Jud ic .-t ] 1) i strict court No. 91-11 ID PAGE: 02- 28 OHC-EDC CONDENSED ORGANIC REACTOR NO. 2 Methyl Chloride % Vinyl Chlorirfo Ethyl Chloride Vinylidine Chloride 1. 1-Dichloroethylone cis-1. 2-Oichtoroethylene Chloroform pc Carbontctrochloride Trichloroethylene Chloral L 2 Trichlorae; thane Perch loroethy lene U-Totrechlorcethane S-Tetrachloroothane Pen tachl o roethane Unknown! 1973 AVG. JAN. FEB. PP& INTOSTR1ES CHEMICAL DIVISION LAKE CHARLES,LOUISIANA LABORATORY OPERATIONS REPORT MAR. APR. MAY JUNE JULY AUG. SEP. OCT. NOV. DEC. 1974 AVG. 0.03 0.06 0.57 0.05 0.03 0.08 0.51 0.05 0.04 0.09 0.36 0.05 0.04 o.nfi 0 - 37 0.06 0.04 0.07 0.84 0.04 _ 0.03 0.04 0.03 0.03 0.04 0.05 0.07 0.04 _ 0.06 0.05 0.04 0.05 0.06 0.06 0.05 0.06 0.53 0.43 0.21 0.39 0.42 0.34 0.32 0.43 0.03 0.05 0.03 0.04 0.06 0.05 0.07 0.05 0.15 0.14 0.15 0.18 0.18 0.20 0.13 0.16 0.18 0.21 -- 0.22 0.17 0.16 0.13 0.16 0.15 0.14 0.16 - 0.11 0.14 0.14 0.10 0.16 0.16 oTTS 0.16 0.69 0.66 0.50 0.82 0.50 - 0.35 0.63 0.49 0.97 0.98 0.98 0.97 0.71 94.89 94.81 95.15 95.23 95.46 - 96.23 95.33 96.44 94.72 94.79 94.21 93.46 95.08 1.02 1.15 0.79 0.87 0ii37 - 0.58 0.97 0.49 1.60 1.18 1.43 1.69 1.01 0.12 0.09 0.11 0.09 0.10 - 0.08 0.11 0.09 0.12 0.12 0.11 0.13 0.10 0.41 0.38 0.53 0.37 0..44 - 0.36 0.30 0.25 0.26 0.23 0.28 0.32 0.34 1.55 1.77 1.80 1.63 1.56 - 1.25 1.55 1.40 1.39 1.58 1.87 2.11 1.63 0.02 0.02 0.02 0.01 0.03 - 0.02 0.04 0.03 0.03 0.03 0.02 "0*2-- 0.02 0.02 o.oi (0.01 0.01 (6.01 - 0.01 0.01 (0.01 evar'i ttjti-- 7J7U2-- 0.02 0.01 0.14 (o.oi 0.11 0 0.17 0 oTT5 EJ" 0.16 0- - 0.14 0.19 0.21 "0".T5"' 0.20 WT2S-- 035-- 0.20 -0 0 0 00 0 0 0 (0.01 0 0 0 0 -0 (0.61 (0.01 (0.01 0.01 "oToI (0.01 (u.ur eOiL 0w 11 3392 * Unless Otherwise Indicated * cc NFlbfep TIALi SliLr o Prot ectivf Ordei or 14 -It JUd iciai Distri ct Cot rt N J. 9l* 1145 PACE? 202- OHC-EDC CONDENSED ORGANIC REACTOR NO. 3 Methyl Chloride %* Vinyl Chloride Ethyl Chloride Vinylidine Chloride 1.1-Dichloroathvlone eli-1,2-Dlchloroethvlene Chloroform EDC Carbontetrachloride Trichloroe thylana Chloral 1,1,2-iTrichloroethanp Perehloroethylene U-Tatrachloroethana S-Tetrachloroethane Pen tachlo roethane Unknown! 1973 AVG. _ -- -- -- - - JAN. - - - - " " " _- FEB. RPG )USTR1ES CHEMICAL DIVISION LAKE CHARLES,LOUISIANA LABORATORY OPERATIONS REPORT MAR. APR. MAY JUNE JULY AUC. SEP. OCT. NOV. DEC. 1974 AVG. - 0.02 0.03 0.07 0.06 0.06 0.05 0.04 . 0.05 0.05 0.06 0.05 - n.nfi 0.07 0.08 0.08 0.06 0.09 0.08 0.07 0.06 0.05 0.07 - 0.28 0.59 0.64 0.35 0.31 0.29 0.31 0.59 0.36 0.28 0.40. - 0.03 0.03 0.09 0.06 0.07 0.04 0.06 0.05 0.05 0.07 0.06 - 0.12 ... 0.18 0.25 0.34 0 0.29 0.29 0.23 0.16 0.16 0.22 - 0.14 0.15 0.34 0.48 0.26 0.46 0.44 6.30 0.21 0.23 0.30 - 0.44 0. 35 0.67 0.46 0.63 0.54 1.04 0.64 0.81 0.99 0.66 - 96.38 96.25 94.09 94.02 94.04 94.60 93.49 94.55 94.80 93.61 94.58 - 0.44 Q. 45 0.49 0.47 'o;?5' 0.43 1.23 0^.52 0.92 1.51 0.72 - 0.06 0.09 0.55 ' 0.17 TOT 0.13 0.16 0.69 0.07 0.13 0.13 - 0.27 Q. 39 0.43 0.52 0.25 0.48 0.21 0.54 0.28 0.28 0.37 - 1.64 1. 30 2.26 2.37 2.48 2.11 2.11 1.96 1.90 2.10 2.02 - 6.01 0.03 0.03 0.06 0.05 0.06 0.07 0.04 0.04 0.03 0.04 - (0.01 (0.01 (0.01 (0.01 (0.01 (0.01 (0.01 (0.01 (0.61 7J7UI (0.01 - 0.08 0. 10 0.37 0.59 -0 0 00 0.56 0.42 00 0.46 0 0.38 0 0.30 0.40 60 0.37 0 0 --- _ - 0.02 0 (0.01 0 0 (0.01 SL 013393 "Unteu Otharwiaa Indicated CONF .D ENT 1 \L: Sub jec t to 'rotec :ive O rder -o^ 14 th J ud i c cl] l)i ; trict Court No. 91-11 5 PAGE: 202- 29 OHC-EDC DH STILL BOTTOM Methyl Chloride Vinyl Chloride Ethvl Chloride Vinylidirte Chloride %* 1973 avq. JAM PEB. PPG INDUSTRIES CHEMICAL DIVISION LAKE CHARLES,LOUISIANA LABORATORY OPERATIONS REPORT MAR. APR. MAY JUNE JULY (0.01 (0.01 0.16 0.04 (0.01 (0.01 0.14 0.04 0 (0.01 0.06 0.03 0 (n.m 0.10 0.04 0 (0.01 0.06 0.03 0 (0.01 0.09 0.05 0 n n .m 0.04 [0.01 (0.01 0.09 0.04 AUG. SEP. OCT. (0.01 ffl.Ol n. n 0.04 0 (0.01 0.07 0.04 0 0 0.10 0.04 NOV. DEC. 0 0 0.18 0.06 [0.01 0.01 0.14 0.07 ;o.oi (0.01 0.10 0.04 1, 1-Dichloroethyfene cis-1. 2-Dichloroethvlene Chtorof rtn EDC Carbon tetrachloride Trichloroethylene Chloral 1,1.2-' Trichloroethane Perch loroethy lene U-Tetrachloroethane S-Tetrachloroethane Pentachloroethane 0.15 0.19 0.18 0.20 1.23 1.03 95.29 95.05 0.92 1.05 0.13 0.10 0.06 0.18 1.68 1.90 0.02 0.02 0.01 0.01 0.17 0.11 (0.01 0 0.12 0.17 0.84 95.59 0.78 0.12 0.15 1.84 0.02 0.01 0.21 0 0.14 0.15 0.17 0.16 1.09 0.91 95.70 96.46 0.66 a. 39 0.10 0.10 0.12 JO.10 1.72 1.50 0.01 0.02 (0.01 (0.01 0.13 0.12 00 0.22 0.28 0.98 95.26 0.42 0.14 0.12 2.01 0.03 (0.01 0.32 0 0.23 0.33 0.8195.37 0.52 0.14 0.16 1.92 0.04 (0.01 0.39 0 0.18 0.27 1.17 94.44 0.79 0.14 0.12 2.23 0.04 0.01 0.48 0 0.27 0.36 1.33 94.92 0.36 0.12 0.16 2.41 0.05 (0.01 0.37 0 0.20 0.31 1.72 93.62 174V 0.17 0.06 1.95 0.04 (0.01 0.39 0 0.18 0.23 1.56 94.52 0.78 0.15 0.36 1.96 0.04 0.01 0.38 0 0.15 0.17 1.94 93.65 1.25 0.12 0.02 2.06 0.03 0.61 0.38 0 0.16 0.24 1.86 93.05 1.65 0.16 0.05 2.17 0.03 0.02 0.44 0 0.18 0.24 1.27. . 94.80 0.84 0.13 0.13 1.97 . .0.03 (0.01 0.31 0 Unknown* (0.01 (0.01 0 0.14 0 0 (0.01 0.01 0 "0--------- (0.01 0.02 (0.01 0.03 Water Fe PPM 36 67 37 PPM 0 0 0 73 64 62 93 85 70 000 0 0 0 59 71 00 28 34 00 62 0 0l1 3v 3sJ jnj `Unless Otherwise Indicated CONF DENtI Vb: o( Sub je< 14th t to Judic 'rotec Lai Di Live 0 refer stcictj CoUT"l No. 91-11 46 PAGE: 02- 29 A OHC-EDC DH STILL BOTTOM #2 Methyl Chloride %m Vinyl Chloride Ethyl Chloride Vinylidine Chloride 1973 avg. 1,1-Dichloroethylene cis-1, 2-Dichloroethylene Chloroform EOC Carbontetrachloride Trichloroethylene Chloral 1.1.2-Trichloroe thane_________ Perchloroe thy lent U-Tetrachloroethane S-Tetrachloroethane Pe ntach 1 o roe thane JAN. Unknown! Water Fe PPM PPM FEB. PPG INTOSfRlES CHEMICAL DIVISION LAKE CHARLES,LOUISIANA LABORATORY OPERATIONS REPORT MAR, APR. MAY JUNE JULY * AUG. SEP. OCT. NOV. DEC. 1974 avg. 0 n in m 6.01 (0.01 (0.01 0.08 0.04 0 (0.01 0.06 0.03 0 0 0.06 0.04 (0.01 0 0.05 0.05 (0701 (0.01 0.05 0.03 0.10 0.29 1.07 95.50 0.41 0.13 0.09 2.04 0.05 (0.01 0.35 0 0.21 0.15 0.32 0.23 2.05 1.71 93.26 94.39 1.62 0.78 0.19 0.17 0.05 0.19 1.88 1.97 0.05 0.05 0.01 o.ol 0.36 0.40 0 TJ 0.16 0.22 1.81 93.62 1.29 0.18 0.02 2.13 0.08 0.02 0.39 0 0.12 0.21 1.74 93.44 1.43 0.15 0.05 2'. 32 0.15 T5723 1.68 94.04 1.11 0.16 0.08 2.07' ' 0.04 0.02 0.42 0 0.05 0.01 0.38 0 (0.01 (0.01 (0.01 0.01 0 (0.01 79 72 67 29 36 57 0 00 0 0 0 oQLi nU m1 v Jocv 'Unless Otherwise Indicated --------- Ci )MT T IJENT. A L: ret- to Prop fit rtive 1 )rder C 1 A t- 1, . 1 ii rl i f i 1 l) stric ; Cour , Ho 91-1 ArJ PAGE: 30 t 1973 OHC-EDC ava. LIGHTS STILL BOTTOMS (Product! Methyl Chloride % (0.01 Vinyl Chloride (0.01 Ethvl Chlorido 0.06 Vinylidino Chlorido 0.03 trans-1, 2 Dichloroethylent 0 1, 1-Dichloroothylene 0.04 cis-1, 2-D i chloroethylone 0.07 Chloroform 0.06 EDC Cn rbontotrnchlorlde 98.75 0.56 T richtoroethvlcno Chloral 1.1,2- Tricaloroethane Per c h lo roo thy1 one U- Totraeh loroethane 0.20 0.03 0.51 0.04 (0.01 S-Tetrachtoroothane 0.04 Pentach loroethane 0.01 JAN. 0 n 0 (0.01 0 0.02 0.02 (0.01 99.02 0.90 0.12 0.01 (0.01 0,02 0 0 0.02 FEB. 0 n rv Q- 02 0 0.09 0.15 0.03 99.24 0.57 0.20 (0.01 0 0.03 0 0 0 PPG,1.N5TRIES CHEMICAL division LAKE CHARLES,LGUISIANA LABORATORY OPERATIONS REPORT MAR. APR. MAY JUNE JULY AUG. SEP. OCT. 0 0 0 0 0 0 (0.01 (o.oi 99.58 0.08 0.32 0.01 0.03 0.03 0 0 0 0 ri 0 a 0 0: 0i03 0.14 99.04 0*f84 0.30 0.01 0.03 0.17 (0.01 (0.01 0 0 0 n (0.01 0 0.01 0.01 0.01 99.72 0.02 0.21 0.01 0.04 0.0 4 (U.TI1 0.10 0 0 0 0 (0.01 O' 0.02 0.01 0.04 99.12 0.20 0.16 0.12 1.94 0.04 0.04 0.42 0 00 00 00 00 (0.01 n 00 0.02 0 0.08 0.03 0.02 (0.01 0 (0.01 0.07 0.12 0 0.01 0 lerjrrr 0 0 (0.01 0.01 0.04 0.03 99.55 98.20 96.84 97.24 0.08 0.23 0.04 0.03 0.27 0.89 0.12 0.18 (0.01 0.06 0.06 0.06 0.34 1.72 2.43 2.18 0.02 0.05 0.07 0.15 0.07 W01" U.01 0.02 0.24 0.62 00 0.43 0.50 0 0757 NOV. DEC. 1974 avq. 0 0 0 0 0 0.03 o.oi "0.07 0 0 0 0 0 0.02 (0.01 0.07 0 0 (0,01_ (0.01 0 0.03 0.03 o.oS 96.46 0.11 0.10 0.03 2.73 0.08 o.Oi 0.51 0 92.60 0.06 0.09 0.08 5.51 0.15 0.04 1.54 0 98.05 0.26 0.25 0.04 1.54 0.07 0.03 0.37 0.05 Unknown! Water (0.01 0 0 (0.01 0 0.02 0 0.01 (0.01 (0.01 0.01 o.ol 0.01 tot PPM 4 0 0 0' o- 0 (0.01 0 0 119 0 0 0 ~T0----- -- SL un^w Unless Otherwise Indicated : - CONF IDENTJ \L: ------oi Sub jet tttTi :t to TTutTTc ?rotee ial Di live o 5tricf reto r --TTo7 91-11 15 PACE: 31 VINYLIDENE CHLORIDE MONOMER VDCM REACTOR CRUDE Acetylene Monochloroacetylene PPM PPM Dichtoroacetylene PPM Vinytidene Chloride Wt. % trans-1,2 DichloroethylenePPM cis-1,2 Dichloroethylene PPM T richloroethylene t ,2-0ichloroethane PPM PPM Unknowns (Total) PPM Toluene PPM 1973 AVG. JAN. .Jfc PPC INff&STRIES CHEMICAL DIVISION LAKE CHARLES,LOUISIANA LABORATORY OPERATIONS REPORT FEB. MAR. APR. MAY JUNE JULY AUG. SEP. OCT. NOV. DEC. 1974 AVG. DAY TANK * Monochloroacetylene Dichtoroacetylene PPM PPM Vinylidene Chloride Wt. % trans-1,2 DichloroethylenePPM cis-1,2 Dichloroethylene PPM Trichloroethylene PPM 1,2-Dichloroethane Unknowns (Total) PPM PPM Toluene PPM H,0 Acidity, As HCI Color Peroxide, As H?0? HQMME Phenol Appearance PPM PPM APHA PPM PPM Wt. % 5 52 99.97 211 (1 (1 U 3 (1 1 64 99.85 1458 1 0 U 2 (1 1 56 99.81 1216 6 (1 16 1 (1 11 28 138 73 99.77 99.70 2145 2736 48 01 35 23 0 (1 50 63 99.83 1672 3 1 1 1 - 16 60 99.78 1968 2 0 0 2 (1 27 40 84 98 99.76 99.80 2249 1779 (1 5 01 0 T------ 0 2 0 (1 43 100 99.77 2191 2 0 0 1 (1 75 80 99.80 1827 2 0 1 2 2 27 68 99.77 2192 25 92 99.89 1035 57 00 (1 (1 12 (1 1 29 81 99.79 1872 4 (1 2 2 U------ 21 (1 5 (1 191 0 CLEAR 20 (1 5 u. 204 0 - 16 (1 (5 (1 205 0 CLEAR 38 24 (1 (1 (5 (5 (1 (1 204 210 0Q CLEAR CLEAR 18 (1 (5 (1 189 0 CLEAR 19 0.05 (5 (1 187 0 Clear 24 38 (1 0.31 rs--------- (5 u------ (0.01 194 189 00 CLEAR CLEAR 24 (1 (5 a 193 0 - 26 16 (1 (1 (5 (5 (1 (1 200 185 TJ--------- 0 CLEAR - 23 2 (5 (1 215 0 CLEAR 24 3 (5 (1 198 0 CLEAR quLL 0w 13397 _________________________ l________ * Storage Tank Subsequent to Jan -------- trt N FrnE* \ l,mi A ll: "'UUfJ ) (? c r--t tr--I1 r ol eeti v V" ^ C T A Lli JU( 1. V- i, LI 1 iM Hit * U1 H'*? PACE: -32 WASTE RECOVERY UNIT Ethyl Chloride Wt. Vinylidene Chloride t-1,2-Dichloroethylene 1,1-Dichloroethane % c-1,2-Dichloroethvlene Chloroform 1,2-Dichloroethane Carbon Tetrachloride Trichloroethylene 1,1,2-Trichloroethane Perchloroethylene U-Tetrachloroethane S-Tetrachloroethane Pentachloroethane Hexachloroethane Pentachloro Butadiene Hexachloro Butadiene Unknowns 1973 AVG. -- -- - - - " Specific Gravity - ppq II^fesTRlES CHEMICAL DIVISION LAKE CHARLES*LOUISIANA LABORATORY OPERATIONS REPORT JAM FEB. - 0.16 - 0.02 -n - n.m - 0.16 - 0.42 " 13.22 - 0.26 -- 0.08 -- 28.41 6.09 -- 6.93 - 24.52 - 12.56 - 0.71 - 0.71 - 4.62 1.509 MAR. APR. MAY 0.38 0.03 0 0.31 0.33 1.30 0.40 0.01 0.01 0.08 0.18 0.34 - - 23.90 13.26 - 0.50 0.18 0.22 0.07 '- 27.84 28.35 ' - 8.11 12.28 -- 3.42 5.74 * " 17.26 23.52 -- 9.56 10.49 0.48 0.43 -- 0.86 ." TTT7 6.33 2.52 * " 1.458 1.488 - JUNE JULY AUG. 0.96 (0; 01 0 O.OR 0.22 0.13 11.88 0.14 0.11 27.69 14.84 5.39 23.90 10.33 0.58 0.64 1.08 2.59 0.11 0.01 0 0.06 0.11 0.22 7.67 0.14 0.11 43.20 "5735 "7753 21.04 8.57 0.49 0.91 1.29 1.40 0.14 0.01 o 0 17 0.54 0.69 18.13 0.20 0.17 33.67 9.54 5.38 18.30 9.66 0.41 0.55 0.59 2.34 SEP. 0.19 (0.01 0 0.12 0.29 0.49 17.05 0.11 0.11 30.23 ''17.43 4.44 16.84 8.77 0.44 0.59 0.66 2.24 OCT. 0.47 0.11 0 0.24 0.40 0.47 14.49 0.04 0.10 28.52 23.62 4.56 14.57 8.37 0.57 0.39 0.33 2.26 NOV. 0.22 0.01 0 0.14 0.22 0.64 15.19 0.12 0.17 21.14 10.21 6.42 23.08 11.39 0.60 0.75 0.77 2.30 DEC. 1974 AVG. 0.27 0.01 0 0.10 0.32 0.66 17.14 0.11 0.15 28.36 10.81 7.13 21.18 11.19 0.34 0.48 0.48 1.25 0.26 0.02 O 0.14 0.26 0.54 15.19 0.18 0.13 30.40 11.93 5.74 20.42 10.09 0.51 1.-9-70.80 2.78 1.481 1.482 1.452 1.480 1.466 1.475 1.461 1.475 R| 013398 ____________________________________1________ 1 rnwFt 7ENT1A I.: nh jor* trt P rnfrert i ve O* der - n f 1 4 f. h , hid 4 n i =* 1 Hi n trict Court No. 31-114 11 PACE: -33 INCINERATOR 1973 AVG. WASTE GAS FEED c2h4 HC1 EC VDC EDC Wt. % Perchlor Trichlor Trans Cis Other No. 1 INCINERATOR HC1 in Stack Clp in Stack HC1 in Effluent PPM PPM GPL Stack HCB Aqueous HCB PPM PPM JAN. PPG INSTRIES chemical DIVISION lake Charles,Louisiana LABORATORY OPERATIONS REPORT FEB. MAR. APR. MAY JUNE JULY ,, CONFIDENTIAL; Subject to Protective Order i4th Judicial District Court No. 91-1145 AUG. SEP. OCT. NOV. DEC. 1974 AVG. 5.33 36.42 _ 0.71 L " -- 2.12 , - - 2.01 - - 0.13 ( - - - 1.04 -' - 1.88 - s _ -- - 1.14 -- -- 0.08 - 9.94 ifl.nfi n ni 2.11 2.01 0.12 1.03 1.86 1.34 0.20 5.80 13.56 21.21 16.00 0.33 1.45 1.46 1.13 1.14 2.65 0.06 0.07 2.24 1.36 1.97 1.42 1.57 1.08 0.09 0.27 16.18 11.68 8.11 23.03 1.66 0.51 1.82 1.92 2.88 2.28 0.10 0.17 T.n 1.28 1.92 2703 1.24 1.39 - 0.05 4.51 18.23 0 2.71 0.46 0.18 2.28 3.07 2.08 0.10 6.17 18.48 0.33 1.23 2.32 0.43 0.71 1.26 0.58 0.00 9.15 19.94 0.83 1.81 1.97 0.16 1.26 1.93 1.30 0.13 320 440 21.1 - -- 18.8 116 164 8.6 - 121 95 14.2 - 144 122 9.5 - 195 111 13.9 164 197 16.9 --- -- 159 220 19.5 151 269 17.5 - 183 191 16.8 - 101 99 11.8 - 165 191 15.3 - No. 2 INCINERATOR HC1 in Stack Cl2 in Stack HC1 in Effluent PPM PPM GPL Stack HCB Aqueous HCB PPM PPM STACK GAS ANALYSES PPM CO NOX Orqanics CHd HCl Cl SL 013399 147 355 L9.4 -- _ 168 242 18.4 164 300 23.0 - 109 95 23.1 -- - 155 137 20.3 - -- -- - _- -- - --- - -- - - - ---- - - - 220 152 18.0 161 150 17.4 -- 167 203 18.5 166 237 17.6 -- 154 181 15.7 - 94 54 10.1 - 155 191 18.3 - - - - - -- - -- - - - Ft * - - Snl, i`-< t - r n - - of i`1 Lh .1 -' - -- it ) 1 1 |. rtf- -N< 1 r U 1 .. n * J- J. -------------------- -- PACE: 1 Pf?G IN^STRIES CHEMICAL DIVISION LAKE CHARLES^ LOUISIANA CON F .1 DENT 1 hL Subject: to Protecti v^P>rdor : 14 tb Judici' al Distract Cour: No* 91-1145 GENERAL DEPARTMENT EDC Production --` T/D EOC Area Production ---^ T/D EDC Shipments T/D Purchased Ethylene to EDC T/D % CjH* Purchased Ethylene Cl2 to EDC T/D 1973 JAM AVG. 1082.3 628.1 1081.3 648.4 145.0 53.3 312.6 185.5 99.92 99.87 785.4 469.4 FEB. MAR. 941.6 967.4 110-0 279 - 3 99.92 704.1 964.4 956.0 64.0 279.3 99.91 693.8 APR. MAY JUNE JULY AUG. 896.4 903.4 11.3 260.7 99.94 657.0 978.9 987.1 14.5 288.4 99.97 726.1 996.7 880.2 987.7 895.2 421.1 14.2 287.4 255.5 99.95 99.93 726.8 657.1 882.8 889.2 20.2 260.5 99.95 661.6 SEP. OCT. 811.2 811.0 14.9 234.6 99.91 592.6 765-5 758.1 QA 221.4 99.86 560.4 NOV. DEC. 860.7 875.7 862.9 878.0 16.4 53.1 253.8 252.5 99.94 99.88 626.5 639.6 1974 AVG. 873.5 878.7 66. 9 95A.9 99.92 642.9 YIELDS Area Prod. + Trans. Credits Basts Clj C Records Prod. + Trans. Credits Basis CI2 C 99.0 99.9 98.3 99.8 99.1 98.4 96.8 96.7 99.0 98.6 96.4 96.0 99.8 97.9 ----- F------ 99.2 98.0 98.8 97.5 100.6 98.8 98.4 97.2 98.0 96.7 1 97.8 98.0 97.7 99.6 98.6 96.4 98.6 98.0 96.7 97.0 96.0 96.3 99.0 97.7 98.7 97.6 95.0 98.6 96.7 98.5 99.3 99.2 96.8 99.2 '99.0 99.0 96.6 99.0 98.6 98.3 98.0 97.7 Excess C5Hj Excess C2H4 Stiflbottoms To W.Rec. Total Losses Loading Losses EDC Inventory % T/Mo. T/D T/D T/D Tons 2.0 0.9 187.5 51.8 3.4 5.5 1.8 143.6 5*1 3.0 258.6 3.5 -1.0 20.4 25.9 -8.4 -1.0 20.4 25.9 -8.4 6927.8 2709.6 11704.7 L6261.4 1.8 3.0 139.2 267.4 2.6 0.6 222.9 63.9 3.3 262.4 2.0 3.0 141.7 201.6 5.8 5.6 7.0 8.2 7.0 8.2 3.4 -9.0 -9.0 3.3 15.0 15.0 3.0 1T75 6.5 7.2 -0.1 -0.1 5.3 -7.4 -7.4 1855a] 19030.7 617i 8 7346.5 7774.1 6610 Jj 5593.1 3.7 1.4 2.3 276.7 110.8 177.6 4.7 7.0 5.4 2.2 2.3 T72------- 2.2 2.3 5.2 12963 JE 13632 A 16695'.! EDC REACTOR NO. 1 Pressure Bott m PSIG Temp. F Bottom Top EDC REACTOR NO. 2 Pressure Bottom PSIG Temp. F Bottom Top EDC REACTOR NO. 3 Pressure Bottom Temp. F Bottom Top 18.6 227 216 L6.7 224 214 17.5 222 213 L7.0 221 212 21.5 224 213 21.6 224 216 18.5 227 215 18.5 223 215 22.3 225 223 18.0 224 214 17.9 223 213 22.6 228 218 17.8 224 214 18.1 225 214 17.9 222 213 18.0 221 213 22.3 227 ~SW 24.2 227 219 18.9 227 216 19.0 229 219 18.6 224 215 19.1 226 219 23.4 226 216 23.9 228 218 19.2 227 219 19.6 226 219 23.5 220 211 19.4 228 218 20.8 230 221 19.3 226 218 19.9 229 220 23.2 218 209 22.7 217 208 20.3 230 220 21.0 231 220 20.0 227 220 20.0 228 220 23.5 217 209 23.8 218 209 19.0 227 217 18.8 225 217 23.1 223 214 SL 013400 FORM f A 208-2 GENERAL DEPARTMENT EOC STRIPPER NO. 1 PRESSURE TOP TEMP. *F BOTTOM FEED RATE TP PSIG G PM 1973 -AV6. 9.3 214 209 67.2 JAN 8.9 213 199 42.9 ETHYLENE PPG INDUSTRIES CHEMICAL DIVISION LAKE CHARLES, LOUISIANA DICHLORIDE DEPARTMENT OPERATIONS CONFIDENTIAL Subiect to Protect ' of 14tii Judicial District REPORT No. 91-1145 or Court FES MAR APR MAY JUNE JULY AUG SEP OCT NOV OEC 1974 AVG. 9.3 215 201 64.9 9.1 214 206 57.6 9.0 213 206 54.8 9.2 214 209 71.6 10.0 216 210 77.3 10.8 11.1 7T5------ 219 211 213 47.7 46.3 10.5 218 213 44.8 11.2 221 91 A 55.4 11.2 <220 214 50.0 11.2 220 216 58.9 10.1 217 209 ... 56.0 EDO STRIPPER NO. 2 PRESSURE TOP TEMP. *F BOTTOM TP FEED PATE PSIG GPM 11.4 217 213 82.5 11.8 220 217 67.0 11.2 218 213 73.8 13.0 222 217 77.2 ii.e 221 217 61.3 13.7 224 220 7173-- 3.9 222 220 66.4 16.2 227 224 81.5 16.4 226 223 82.9 15.3 224 222 8971 11:8 217 214 72.3 11.7 216 214 96.8 11.3 216 214 33.3 13.2 221 218 79.5 EDC STILL NO. 1 FEED PATE REFLUX PATE PRODUCTION EOC STILL NO. 2 Temp. ? BOTTOM . TOP FEED PATS beflux patc PB OUCTION GPM 44.7 32.5 52.0 GPM 24.3 25.0 25.2 GPM 45.9 33.7 53.0 -- - ---. - - * -- - _--- - - GPM opm CPM 255 195 101.6 77.3 96.9 248 194 65.2 79.6 61.4 242 201 129.4 100.4 123.0 245 202 130.2 105.4 124.0 . 243 247 * 204 203 130.4 132.2 111.1 114.3 124.6 128.0 v ~2!>3 ~TD5-- 250 204 nrrs 132.5 114.6 105.5 123.4 123.0 256 194 130.9 109.5 123.4 257 196 134.5 116.9 126.4 259 194 122.7 100.7 115.5 27'.0 21.8 27.7 40.4 24.7 40.4 38.0 24.2 38.7 261 199 133.7 122.8 126.2 263 195 107.7 124.1 134.1 252 200 123.4 108.7 119.4 STEAM IHO# BASIS) KWH/T EDC WELL WATEH CAS NITROGEN LBS./T EOC M OALS./T EDCl MC F/T EDC TONS/T EDC 772 .831 13.4 23.2 0.57 0.98 0.06 0.06 0.005 0.008 - 15.5 3.75 3.05 3.006 310 15.8 0.74 0.05 3.005 OPEBATIMC TIME lANY Rx)_______ !_ 99.5 [33.2 LOO.O LOO.O 1 L SL 013401 194 583 15.3 14.7 0.78 0.72 0.05 0.07 0.005 0.005 iob.o 100.0 658 636 14.8 15.2 0.70 0.78 0.06 0.06 0.006 0.005 839 16.2 . 0.82 0.07 0.005 974 17.1 0.89 0.14 0.006 887 18.1 0.94 0.12 0.006 100.0 91.3 100.0 100.0 100.0 935 14.0 0.74 0.11 0.005 914 16.3 0.69 0.09 0.006 706 16.4 0.79 0.08 0.006 100. C 100.0 97.9 FORM 0> .208*3 GENERAL DEPARTMENT EQUIPMENT HOURS* A) Ft COMPRESSORS #1 z *3 #4 #s 1973 AVG. JAN PR6.|ISTRIES CHEMICAL DIVISION LAKE CHARLES, LOUISIANA ETHYLENE DICHLORIDE DEPARTMENT OPERATIONS REPORT FEB MAR APR MAY JUNE JULY AUG 6001 621 544 480 720 6108 744 672 664 272 5080 1 J-i 128 344 448 690 126 4 246 714 696 700 654 696 0 712 712 SEP OCT 00 720 744 720 74 A NOV 642 77 720 OEC 744 220 520 1974 avg; 4571 6481 6509 MAN HOURS PER TON EDC PRODUC TION 0.035 MAlNTtN ANCC 0.023 JSAUAB1S__________________________ 0.012 TQTAI_______ 0.070 COW-TRACT M AIN T. IWCLUPSO tN ABOVE 0.001 0.056 0.080 0.020 0.156 0.000 0.041 0.024 0.013 0.078 0.004 olC-Ol o 0.048 0.013 0.079 0.000 0.040 0 8 023 b*0l5 0.078 OiOOO MAN HOURS/TON SHIPPED** BULK 0.024 0.073- 0.038 0.063 0.328 0.042 0.040 0.040 0.023 0.022 0.026 0.513 0.012 0.014 0.078 0.074 0.080 0.000 0.006 ---- ,--------------- 0.002 0.043 0.053 0.014 0.110 .0.035 0.045 0.047 0.031 0.D28 0.015 0.018 0.091 0.093 0.011 0.000 0.399 0.015 0.143 0.127 0.161 0.220 0.040 0.017 0.013 0.070 0.000 0.042 0.019 0.014 0.075 0.001 0.044 0.030 0.014 0.088 0.00S 0.284 0.083 0.161 IAUANI ED -------------- 0.002 0.008 0.004 0.005 0.028 0.032 0.001 0.014 0.013 0.015 0.020 0.023 0.008 0.014 * CONI I DENT * AL*i C 11 r> j e r- h t"o Prote :tive >rder - f 141-1 .1 ucli< : i a 1 0 Lst ric L" CoQL t-----------No 91-1 T5------- __ : SL 013402 TOTALS ** OPERATIONS * MAINTENANCE PAGE: 2 GENERAL DEPARTMENT MC Production MC Area Production "Tri-Ethane" Production "Tri-Ethane" Shipment* T/D T/D T/D T/D Chlorine Consumed EDC Consumed C2H4 Consumed T/D T/D T/D PPG IN^STRIES CHtMlCAL DIVISION LAKE CHARLES,LOUISIANA "TRI-ETHANE" DEPARTMENT OPERATIONS REPORT CONFIDENTIAL Subject to Protective Order of 14th Judicial District Court No. 91-1145 1973 AVG. 153.4 158.0 162.4 162.8 JAN. 137.7 146.5 144.9 126.5 FEB. MAR. I49.n 152.0 1 57 R i no 0 149.7 154.7 160.6 157.6 APR. 159.0 163.9 165.1 211.5 MAY 137.3 138.0 147.3 122.6 JUNE JULY AUG. SEP. 130.2 136.9 138.0 131.0 75.4 87.9 76.5 112.3 149.6 146.6 164.1 152.1 163.6 164.0 160.5 168.0 OCT. NOV. DEC. 172.3 180.1 195.5 149.9 173.6 178.0 183.9 211.8 211.0 219.4 226.8 135.1 1974 AVG. 150.7 155.7 l80.1 155.1 146.6 146.2 153.6 152.7 156.9 154.4 186.6 190.5 199.1 203:7 202.2 205.6 165.1 103.5 142.7 182.3 173.9 191.8 195.6 159.9 209.7 129.5 187.0 232.4 216.6 255.6 261.9 207.8 ---- f----- YIELDS Area Prod. * Trans. Credits Basis CI2 C Records Prod. + Tran*. Credits Basis Cl3 TCE TO FER-TRI C t7d HCI to HCI Pros*. T/D VDC to VDCM T/D Tons Cl?/T TCE Tons EDC/T TCE Tons C2H4/T MC Tons N,/T MC Steam (HO# Basis) Lbs./T MC Well Water M Gals/T MC Tons Cell Liquor/T MC Catalyst Lbs./T MC (FeCl3) TPP Lbs./T MC HQMME Lbs./T VDC AIBN LbsJT TCE "Tri-Ethane" Inventory Tons Operating Time % - 93.2 91.8 94.6 91.9 89.8 89.0 97.6 92.1 97.5 92.2 90.7 85.5 91.5 89.4 56.0 19.1 18.2 0.598 0.763 91.3 86.4 66.9 23.1 22.3 0.569 0.741 90.8 87.9 77.9 23.4 19.3 0.567 0.735 95.8 90.3 83.8 26.9 22.1 0.535 0.714 95.8 90.4 73.9 26.7 23.5 0.547 0~.705 90.4 85.3 70.9 30.3 25.5 0.582 0:775 oToTT" 0.085 T2S2 2352 7.6 3.1 0.478 0.515 3.9 1.9 6.6 7.6 1.6 2.2 0.279 0.689 0.082 L614 0.4 0.501 4.7 7.2 1.2 0.330 0.110 1213 3.8 0.501 4.1 7.3 L.O 0.356 0.072 1665 10.1 0.504 3.0 6.9 1.2 0.312 0.098 1261 8.7 0.572 1.8 8.0 1.5 0.383 2449 96 2671 96 L986 07 2077 97 679 38 T443 TOO 94.6 90.5 90.7 89.2 * 93.8 91.4 93.1 89.0 93.0 90.2 91.1 89.0 9375 91.4 93.5 90.0 92.3 83.8 88.3 82.1 77.6 47.7 35.1 22.1 39.4 15.7 0.589 0.672 0.748 0.842 95.0 92.6 74.2 26.9 11.5 0.549 0.719 93.0 90.5 89.8 88.8 87.6 87.8 61.1 61.0 73.5 34.3 36.2 4275 21.7 38.6 0.585 0.606 0.585 O'. 74b" 07756" 0.780 91.3 89.1 b4.1 33.6 30.2 0.568 0.760 3175 tiU J. WT5 29.6 26.0 0.58(3 0.752 0.089 0.092 1204 1087 8.7 17.3 0.623 0.605 2.0 4.6 7.5 7.4 1.5 1.1 0.422 0.723 0.093 1292 9.7 0.528 1.8 7.8 0.9 0.756 U.U83" 0.073 1264 1213 8.1 8.0 0.570 0.502 2.4 1.2 5.4 2.4 1.0 1.5 0.316 0.439 0.074 1235 8.2 0.556 1.4 7.2 1.5 0.468 0.061 1218 7.7 0.486 5.3 11.0 1.1 0.183 0.084 1385 9.5 0.539 3.1 7.1 1.3 0.448 1653 542 97 62 910 676 2087 1247 4088 1672 92 100 95 98 100 94 SL 013403 PACE: 2 PPG Its^STRlES chemical division LAKE CHARLES,LOUISIANA "TRI-ETHANE" DEPARTMENT OPERATIONS REPORT GENERAL DEPARTMENT MAN HOURS/T MC PRODUCED Production Maintenance _______ Salaried_____________________ Total Contract Maint. Included In Above 1973 AVG. 0.337 0.231 0.105 0.673 0.008 JAN. 0.438 0.245 O.llfi 0.799 0.004 FES. MAR. 0.390 0.189 0.113 0.692 0.000 0.315 0.1 52 0.105 0.572 0.000 APR. MAY 0.306 0.127 0.107 0.540 0.000 0.359 0.347 0.123 0.829 0.000 JUNE JULY AUG. 0.367 0.627 0.227 1.881 0.117 0.194 0.711 2.702 0.005 0.030 0.361 0.580 0.116 1.057 0.216 SEP. OCT. HOV. DEC. 1974 AVG. 0.333 0.548 0.098 0.979 0.312 0.31R n aol 0.099 0.838 0.117 0.288 0.223 0.085 0.596 0.021 0.234 0.246 0.078 0.558 0.075 0.361 0.432 0.113 0.906 0.065 MAN HOURS/T "TRI-ETHANE" SHIPPED Bulk. Drum Salaried 0.038 0.043 0.725 0.880 0.007 0.010 0.036 0.038 0.928 0.747 0.007 0.007 0.031 0.046 0.999 0.841 0.006 0.008 0.038 0.041 0.710 0.778 0.007 0.010 0.037 0.767 0.009 0.033 0.042 0.733 0.918 0.006 0.007 0.026 0.792 0.004 0.023 0.036 01815" 0.826 0.006 0.007 SL 013404 c Subjc r~rm ---- CSTtn 7TC trr J ud i ------- fit? rrucfe;xor , " Ai? i ---1 > VO j ci l- r ic )45 Order t Cour L FORM NCA' 209- 3 PPG It fcTRIES CHEMICAL DIVISION LAKE CHARLES, LOUISIANA .. CONFIDENTIAL: Subject to Protective Order of l'4th Judicial District Court No. 91-1145 MATERIAL BALANCE CARBON - TONS Total Carbon in Fcco Carbon in Production Carbon Loss in Process Lossacct. in Still Bottoms Misc. Acct. Losses unaccountable Carbon Loss in Process Carbon Loading Loss Total Carbon Loss CHLORINE - TONS Total Chlorine in Feed Chlorine in Production Chlorine Loss in Process Acct. Loss in Still Bottoms misc. Acct. Losses Loss from vex: Reaction Plus other Unaccountable Losses Chlorine Loading Loss Total Chlorine Loss 1973 JAN AVG. FEB MAR APR MAY JUNE JULY AUG SEP OCT NOV DEC TO. 1373.0 1433.4 1353.1 1532.4 1295.3 1313.7 1 JAR C ldfi3 A , 82.7 8.9 119.7 ind. o 69.0 0.0 0.0 0.0 1472.3 1546.8 1392.2 1363.6 86.1 183.2 0.0 0.0 1527:1 975.6 1386.1 886.0 141.0 89.6 0.0 27.7 1407.0 1691.6 1630.0 1861.6 1970.6 1533.5 1235.9 1496.C 1 AfC7 7 1592.0 1769.1 1384.6 171.1 0.0 195.8 162.3 0.0 0.0 % 269.6 201.5 6.0 0.0 148.9 2.8 73.8 25.3 119.7 104.2 69.0 49.0 15.1 28.0 106.6 168.7 * 119.3 97.0 80.1. 183.2 26.1 3.7 106.2 186.9 141.6 6175 36.4 69.5 171.1 195.8 162.3 -16.6 2.0 43.6 177.4 159.1 154.5 197.6 205.9 263.6 201.3 146.1 24.1 46.8 27.3 363.7 3 176.2 8532.6 8765.6 8296.9 9258.5 6260.9 6721.8 6182.5 7341.1 0 2271.7 2043.8 2114.4 1917.4 45.6 0.0 0.0 0.0 9054.0 9352.5 9462.3 6086.9 7003.4 5724.9 7113.3 4612.5 2050.6 2627.6 2349.C 1474.4 0.0 0.0 0 95.0 8579.0 10464.3 10203 11248.4 HR7C).i BTR7.6 6385.0 7566.9 7336.8 7964.4| 8315.C 6939.0 2194.0 2897.4 2866.8 3284.0 3564.1 2448.6 0.0 0.0 0.0 26.8 0.0 10.2 1976.2 2043 .-e 2114.4 1917.4 118.8 229.7 71.0 131.3 2390.5 2273.5 2185.4 2048.7 2050.6 2627.6 122.5 17.4 2173.1 2645.0 2349.C 1379.4 2194.0 2897.4 2866.8 170.9 326.2 -77.9 9.3 204.6 2519 .S] 1800.7 2116.1 2906.7 3071.4 3257.2 3564.1 2438.4 106.7 207.9 126.6 3390.V 3772.0 2575.2 TCE REACTOR SYSTEM Temr. Press. Bottom Tor EDC ABSORBER F rsig temr. Chilled HCL F rEED Flor gpm 193 50 11 12.0 cmr. LIGHTS STILL Bottom Varor cco Flo* F 291 F 203 gpm 39 209 50 18 25.8 292 204 100 203 48 26 10.5 291 303 LOO 212 49 18 9.6 292 205 100 223 209 208 206 52 Ttt----- 48.9 47.9 23 24 ltJlO 12.0 40 39 12.0 L2.0 295 297 208 210 100 99 297 294 211 208 104 L01 202 48.1 27 13.0 215 216 50.1 48.0 23 22 12.0 OTo 287 289 286 199 201 200 103 119 116 203 196 49.1 50.0 49.4 31 24 12.6 9.5 25 12.4 * 282 283 290 192 193 110 ll5 TITS SL 013405 FORM I A209-4 HEAVIES STILL Temp. Fcto Flow Steam Tor . W Avg. JAN F 274 F 236 gpm 31.1 265 237 32.8 Pl*G IJ^UStRIES CHEMICAL DIVISION LAKE CHARLES. LOUISIANA CONFIDENTIAL.: Subject to Protective OLcier of 14th Judicial- district Court **TRI ETHANE** DEPARTMENT OPERATIONS REPORT No. 91 FES MAR 26S 238 31 _q 265 237 32.7 APR 268 238 34.0 MAY 268 237 33.2. JUNE JULY 267 237 35.6 268 237 34.1 AUG SEP OCT 273 236 5T:7` 275 236 3^.0 277 238 34.8 NOV OEC 279 27Q 241 2dl 37 .IT" 1974 Avg. 571 238 Id 3 VDC REACTOR SYSTEM Flows tce Feed C.L. FeEo gpm gpm 22.2 72.7 22.1 77.3 Bottom Column Press. Temp. Bottom Vapor psig. F F 22.2 224 130 21.3 228 129 MC REACTOR SYSTEM clos VOC Feed gpm Temp. HCL Feed VOC Vap. Bottom Bottom SCFm jF op Top F [7775 613 134 94 89 18.7 587 128 95 89 21.9 22.2 78.1 79.4 20.6 227 128 21.1 226 128 18.2 630 133 91 87 L8.2 ^87 t131 32 35 fLASHER SYSTEM Temp. Dopp Kettle Terr.o, Of 178 F 173 STRIPPER SYSTEM Feed Flow gpm 25.8 Temp. Bottom uF 229 179 171- 26.9 230 181 170 27.6 230 188 174 27.8 229 Top Press. psig 2TJT5 TOPPING STILL SVS['EM Top Temp. op 167 Flow ` MC PRODUCT gpm 18.9 22,0 167 21.6 . 167 17.2 17 C7 21.3 L67 L7.5 23.3 22.2 64.5 80.9 24.1 22.9 87.3 84.4 22.3 226 131 24.3 226 132 24.3 23.5 "J35----- 228 133 133 21.0 79.2 22.6 229 131 24.6 24.4 95.6 95.7 23.7 226 131 22.7 225 133 28.3 30.6 24.0 101.5 109.2 87.8 22.7 224 134 21.4 224 133 22.5 226 131 19.7 617 134 93 86 15.9 557 134 94 87 16.9 17.7 563 602 "775 137 T5I-- 101 89 88 I 191 191 185 184 172 173 "179 174 28.8 229 24.7 227 24. b 25.6 228 229 20.9 20.6 167 167 21.0 20.9 * 167 167 18.0 620 135 99 89 17.9 623 135 96 87 20.0 732 138 98 91 20.2 683 145 88 87 23.3 853 149 80 83 18.7 777-- 136 "53--------------- 87 182 174 184 185 175 175 188 187 189 192 185 176 26.8 inr u.i; 32.6 41.2 228 229 229 228 232 2975 229 20.1 20.4 20.6 20.2 22". I" TTTD-- 167 167 168 166 172 167 18.6 15.9 16.0 18.0 .19.2 19.8 22.0 18.3 22.5 18.6 - SL 013406 q I 1 PACE: GENERAL DEPARTMENT Records Per Prod. Shipments Inventory Rec rds Tri Prod. T/O T/D Tons T/D __________ Shipments______ t;d Inventory Tons Area Per Prod. T/D EDC T/T Cl, T/T PERCHLORETHYLENE PPG INDUSTRIES CHEMICAL DIVISION SL 01340^ LAKE CHARLES,LOUISIANA TRlCHLORETHYLENE DEPARTMENT OPERATIONS REPOK. 1973 JAN. FEB. MAR. APR. AVG. 213.3 246.4 233.8 234.7 180.6 208.9 190.9 285.8 263.9 264.1 4732.3 7421.2 6016.2 5112.1 2610.3 264.6 313.6 260.8 270.3 228.3 265.7 162.4 254.9 425.1 262.3 3525.2 7190.3 7353.9 2545.5 1524.8 215.4 250.9 235.9 247.2 175.3 MAY JUNE 224.2 203.1 244.2 172.8 1992.0 2896.4 298.7 250.7 274.9 237.8 2263.1 2649.2 234.9 196.7 JULY AUG. SEP. 197.2 188.2 202.8 228.8 153.6 259.6 1916.0 2985.9 1282.6 260.2 217.8 281.7 232.6 233.0 274.0 3506.6 3035.6 3268.4 213.0 175.9 211.2 OCT. NOV. DEC. 1974 AVG. 179.7 195.4 247.6 21171" 98.9 246.4 196.5 217.1 9791.R 2259.4 3841.7 751075" 180.2 239.8 245.9 254.0 209.5 193.8 237.4 249.8 2359.8 3741.1 4o05.8 3620.3 183.2 221.6 242.9 215.7 JT7U7U~ 0.093 0.071 0.086 0.116 0.082 6.107 0.084 0.078 0.067 0.085 0.036 0.046 0.079 NH-, Lbs./T __ Area Tri Prod.___________ T/D EDC T/T Cl, T/T 6.4 8.2 7.2 265.9 316.3 261.4 0.044 0.058 0.045 NH3 Lbs./T Total Area Prod. O2 T/T . N, T/T Catalyst Lbs./T 400 # Stm.(actual) Lbs./T KWH/T Total Stillbottoms T/T 6.4 0.160 0.086 2.87 4859 56.3 0.272 8.3 0.149 0.072 2.09 4548 62.0 0.251 7.3 0.163 0.091 3.04 4883 58.8 3.305 3.3 265.4 0.054 3.3 0.155 0.098 1.73 4561 69.0 0.239 9.5 9.0 WP5------ 8.2 8.2 7.6 239.6 301.9 258 4 253.5 239.4 255.4 0.073 , 9.6 0.165 0.115 3.76 5203 8573 0.392 0.052 0.068 9.3 8.6 0.169 0.197 0.072 0.109 1.63 . 4.21 4374 5231 64.3 8273 0.243 0735T 0.053 8.4 0.167 0.119 3.11 5286 81.5 0.383 0.049 8.7 0.190 0.144 3.10 3873 99.8 0.365 0.042 7.4 0.161 0.112 4.02 3531 83.5 0.265 7.4 209.1 0.054 7.6 0.184 0.149 7.21 5694 94.9 0.346 372------ 6.9 ""7715-- 248.4 249.1 258.7 " 0.022 0.029 0.030" 379------ --77T3-- "779----- 0.150 0.184 0.170 0.172 0.116 0.110' 5.09 5.21 3.68 "3819 4605 5UT0 7377" 83.9 79.2 " 0.237 0.256 0.305 MAN HRS./T RECORDS PROD. Production Maintenance Salaried Total Contract Man Hrs. Included 0.186 0.318 0.060 0.564 0.003 0.171 0.208 0.052 0.431 0.000 0.196 0.292 0.060 0.548 0.000 0.212 0.313 3.056 0.581 0.047 0.278 0.468 0.074 0.820 0.004 0.192 0.293 0.055 0.540 0.000 0.239 0.384 0.062 0.685 0.013 0.218 0.353 0.064 0.635 0.6S2 0.285 0.496 0.071 0.852 0.003 0.242 0.500 0.060 0.802 0.018 0.306 0.655 0.079 1.040 0.000 0.246 0.440 0.056 0.742 0.000 0:233 "07275" "07352 0.404" 0.060 0.745 0.032 0.062 0.701 0.016 MAN HRS./T SHIPPED Bulk Drum Salaried TCE T/T PER AREA PROD. TCE T/T TKI AREA PROD. 0.028 0.699 0.005 0.044 3.863 0.008 0.029 0.862 3.005 0.025 0.748 0.003 0.022 0.729 0.004 0.032 0.760 0.005 0.032 0.660 0.005 0.036 0.749 0.006 0.041 0.920 0.007 0.027 0.045 0.757 0.725 0.004 0.007 0.919 0.938 0.877 0.871 0.850 0.897 0.814 0.919 0.943 0.842 0.906 jl. 165 L.185 L. 107 1.099 1.073 1.133 1.028 1.160 1.190 1.063 1.144 0.036 0.857 0.005 0.845 1.067 0.035 0.034 0.977 0.801 n.nofi 0.005 0.938 0.887 1.185 1.120 PA<_ _ _ij Pf?G \b STRIPS CHEMICAL division LAKE CHARLES, LOUISIANA YIELDS 1973 AVG. Area Production Basis + Trans. Cl2 88.1 C 88.7 Records Production Basis + Trvinc; Cl2 87.6 c 88.4 JAN. FEB. 88.5 87.5 91. 7 89.5 87.8 87.3 90.4 89.2 MAR. 84.7 Rfl Q 83.9 88.1 APR. MAY 83.4 86.2 86.6 89.4 82.8 84.8 85.4 87.7 JUNE JULY 84.8 84.8 85.8 85.6 AUG. * 82.1 83.0 SEP. OCT. 86.4 8.3.7 85.5 83.1 84.7 83.8 85.4 84.8 81.1 81.1 88.3 79.7 88.5 77.6 NOV. DEC. 1974 AVG. 93.3 90.3 90.2 86.3 86.3 87.1 89.1 90.5 85.3 . 86.4 85.3 85.8 A//<-'/ Tb goaZBt 3________________________________________________________________ SI 0u1 '"JiAhnUoo ' V rn apiDepi TTAL: CfiiH jnrt t I Pfot ectiv Order 1*4m -H .tud icidl Distril ct Coi rt N o. 91- 1145 * Corrected Values FORM MATERIAL BALANCE CARBON IONS Total Carbon in Feed Carbon in Unstab.'Product Process Loss by Difference Accountable Process Losses Reactor Mt SCELLANEOUS Sue Total Carbon Loading Loss Total Carbon Losses CHLORINE-TONS Total Chlorine in Feed Chlorine in Unstab. Product Process Loss by Difference accountable Process Losses Reactor MlSCELLANEOUS Sub Total Chlorine Loading Loss Total Chlorine Loss Rt 013409 " : PPG >USTRIES CHEMICAL DIVISION LAKE CHARLES, LOUISIANA PERCHLORETHYLENETRICHLORETHYLEME DEPARTMENT OPERATIONS REPORT 1973 JAM Avg^ FEB MAR APR MAY JUNE JULY AUG SEP OCT NOV OEC 1974 A. 3444.8 4141.1 3347.2 3748.8 3374.0 3882.6 3660.8 3927.3 3503.0 3562.0 3251.4 3317.7 3752.2 3622.3 3Q59.9 3778.8 2Q88-A 3332.8 2921.3 3471.5 3140.4 3361.9 3046.7 3044.3 2702.6 2993.1 3238.0 3169.0 384.9 362.3 Tin 418 . n 452.7 411.1 520.4 565.4 456.3 517.7 548.8 324.6 514.2 453.3 364.9 20.0 384.9 J 342.3 20. n 362.3 330.8 20.0 350.8 ; 394.0 20.0' 416.0 432.7 20.0 452.7 391.1 20.0 411.1 500.4 20.0 520.4 545.4 20.0 565.4 436.2 20.0 456.3 * 497.7 20.0 517.7 528.8 20.0 548.8 304.6 20.0 324.6 494.2 20.0 514.2 433.3 20.0 453.3 16.6 26.1 22.6 28.2 20.7 -2.9 19.0 22.9 82.0 -50.3 22.3 170.6 10.3 30.9 401.5 388.5 373.4 444.2 473.4 408.2 539.4 588.3 538.3 467.4 571.1 495.2 b'24.b" 484.2 . . 22489.E 27621.3 216410 24272.4 21390.E 25528.2 22717 A 24815 3 21636.9 22017.91 20635.2 21081.2 23861.51 23101.7 19786.5 24433.7 18947.8 20568.4 17844.6 22019.9 19274.7 21035 JD 18227 .4 19033.9 17269.0 L9660.2 21547.S 19988.6 2703.3 3187.4 2695.2 3704.0 3546.0 3508.3 3442.5 3780.3 3409.5 2984.0 3366.2 L421.0 2313.6 3113.1 * 2603.4 3087.3 2595.2 100.0 100.0 100.0 2703.4 3187.4 2695.2 ! 3604.0 100.0 3704.0 3446.0 100.0 3546.0 3408.3 100.0 3506.3 3342.5 3680.3 3309.5 100.0 100.0 100.0 3H2'.3 3780.3 3409.5 2884.0 3266.2 100.0 LOO .0 2984.0 3366.2 1321.a LOO .0 1421.0 2213.6 100.0 2313.6 3013.2 100.0 3113.2 86.2 .^ 141.0 120.9 207.5 48.7 21.1 86.6 186.5 309.3 -259.2 135.8 321.5 26.2 162.7 2789.5 3328.3 2816.1 3911.5 3594.7 3536.0 3529.1 3966.8 3718.8 2724.8 3502.1 2342.5 2339.8 3275.8 CUN1 1 HUNT. AL: Sub je cL to Protoi rtive > r d o r o f 14 th Jud i.L i a 1 1) s t r i c -rX'ouT - >. u I J * 4 b FORM N^A 210- 4X0** At" T*0 ' tct PPG I t .' STRIES CHEMICAL DIVISION Si. LAKE CHARLES, LOUISIANA PERCHLORETHYLENE.trICHUORETHYLENE DEPARTMENT OPERATIONS REPORT 0 13410 REACTOR NO. 1 On Stream Time *Hrs 1973 Avg. 8272 JAN 744 FEB 646 MAR 714 APR MAY 616 730 JUNE JULY 682 736 AUG 740 SEP 641 OCT 674 NOV 672 Temp, <*f Vapor her Ltouor Dortheru Out 3.36 380 377 390 460 450 455 5fi9 351 386 359 383 372 370 377 363 552 578 500 468 470 447 522 503 DEC 606 384 515 1974 Avg. 8201 374 502 Sec. Cono. Oisch Catalyst Charged Catalyst From Centrifix Fed* GPM Groanic sew Cl2 * Lbs. *Lbs. 33 32 111537 4698 111537 4698 18.0 21.9 1419 3100 27 4292 4292 20.9 3600 30 23S9 51 HQ 20.4 3 TOO 13100 13800 16200 12600 34 12512 12512 19.3 3600 50 5082 5082 22.8 3100 35 13892 13892 20.6 3140 36 13784 13784 21.7 2780 41 5472 5472 20.3 1700 39' 20823 20823 19.1 1700 40 29305 29305 19.3 1100 27 10026 10026 17.6 5soo 11400 13200 12500 14090 13400 12000 14600 14600 24 34 14118 136393 14118 136393 17.1 20.1 1900 2626 13000 13449 Per-Tri Ratio Per i Tri tn Crude ft REACTOR NO. 2 Ch Stream Time * Hrs. Temp, op vaporizer Liouor Oortherm Out 0.92 D.85 1.04 85.83 83.69 77.23 7963 680 650 356 376. 394 526 520 " 485 1.15 88.67 684 381 537 1.15 0.98 82.29 80.65 698 155 607 710 384 580 0.94 76.60 . 662 362 520 0.89 82.10 742 379 604 1.02 82.60 524 _ 364 571 0.93 1.60 82.00 84.40 570 360 541 * 690 374 609 1.43 84.36 569 375 576 1.49 1.12 Bl.io 82.64 676 7855 376 519 ~374 Sec. Cono. Disch, Catalyst Charged (Catalyst from Centrifix * lbs. * LBS. Flo* GPM SCFH Organic! Cl 38 33 136569 10648 136569 10648 T7TT5 19.4 2'5CIT" 4300 32 6392 6392 19.0 1800 37 9914 9914 if; . n 3500 * 15901)' 17100 20900 15900 35 51 12862 6132 12862 6132 15.6 17.7 3600 3200 42 18092 18092 18.5 3571 41 10284 10284 16.5 2912 48 7572 7572 1373 3000 43 6123 6123 15.2 2350 35 L3905 L3905 L6.9 2000 29 16676 16676 15.9 2700 12500 15500 16400 16480 14900 15100 L5500 17100 28 38 11468 130068 11468 130066 14.4 16.6 1900 2903 18400 16315 Per.Tri Ratio Per 1 Tri in Crude 0.90 1.69 L. 27 1.06 1.21 " 0.95 0.94 0,,70 0.81 0.90 ft 87.79 81-80 9Q.22 a6,.85. 80.61 BQQ1- 78-9.0 33.IQ fifi.80 86.00 1.26 0.88 80.00 8Q.1Q, 1.52 1.10 89.00 83.71 Totals FORM t*A 2 tO* 5 t CQui Ttfei"sttiC 'to &xTo3^ 3 vV13-' vct-a \\*b N.PPGWDUS TRIES CHCMICAl DIVISION SL 01341 l$o TAKE CHASIES, LOUISIANA o- PERCHLORETHYLENE-TRICHLORETMYLENE DEPARTMENT OPERATIONS REPOk REACTOR NO. 3 Os STncAn Tun # Hits. m 82 2 3 JAN 742 EEB (AAR 532 734 APR 692 MAY 682 JUNE 667 JULY 714 AUG 702 SEP 686 OCT NOV 584 639 Ttup,F v**>oiee* Liouon DOTHtM Out 338 495 367 456 366 356 464 525 342 ~75S-- ~35I----- 347 356 3bl 347 773 560 499 479 576 582 541 602 567 DEC 663 379 520 1974 AVG. 8037 359 531 Sec. Como. Disch. C*IALT*T Ch**5C0 1Catalyst tag* CfNTmrix tos. * Lex. A -1^^-PganifiL SCFH Ct7 31 88216 88216 18.4 1944 25 6448 6448 18.2 3000 24 11992 11992 16.8 3500 28 7289 7289 16.2 3700 OJ 16400 16700 13500 16200 29 9362 9362 15.6 3300 49 5082 5082 16.4 3400 32 13892 I 3RQ5 15.1 3700 34 6434 6434 15.8 2200 31 6872 6872 15.2 2180 32* 11198 11198 13.7 2270 30 7255 7255 11.9 2900 23 10026 10026 13.7 800 27 20218 20218 13.7 800 30 L16068 L16068 15.2 2646 13900 16800 15000 16500 16400 TW 13000 19500 T7600 1600b * P*h.Tim Ratio Pc* 1 Tm ih Ceuot 0.94 0.87 1.03 1.48 % 85.89 85.25 81.78 91.49 REACTOR NO. 4 On Stmam Tmi *Hrs. 8325 tL iTCMP. op V*ORI tt* Liquor ' 352 Dothcb Out 490 726 354. 451 616 362 475 744 361 585 i.16 1.05 1.17 0.90 86.19 '85.38 77 .-40 87.6 1 692 734 690 672 . 328 358 338 348 588 .508 536 517 1.02 86.2 715 350 541 1.30 86.9 1.02 85.4 720 362 521' 655 349 603 1.00 86.0 634 362 562 0.96 86.4 1.08 85.5 670 370 485 8268 354 531 Stc. Como. Disch. CATAtYJT Ouncto cos.* jct*V.Y*T f0l CtMTHIFI* . IRS,* Flo CH4 SCFM Orcranic Cl* 41 77320 77320 18.0. 1952 55 10298 10298 19.5 2900 55 10942 10942 18.7 3200 52 4489 4489 L8.6 3000 53 7262 7262 T5T7 13600 i 1 5082 5082 L9.4 3600 60 5142 5142 18.4 2760 53 52 10284 10372 10284 10372 16.6 ~ 16.8 2700 2400 47 6648 6648 17.0 1260 50 14955 14955 14.3 2500 29 17726 17726 15.4 1400 :________ :_______ ?i________________ 13700 16700 16400 16600 1 13600 18300 1 i 16100 1460Q 16800 16500 12600 13600 44 6l 12668 116066 12668 116068 18.4 600 17.4 2400 16700 15700 * |*t.Tm Ratio jPtft 1 Tm ih Cruoc 1.01 L. 00 L. 15 3.22 1.26 (L.44 1.41 1.05 1.02 1.13 0.86 1.18 1.14 1.16 . % 88.37 j&J&j B7.81 1.56 $9.88 J90.95 J87.00 89.0 86.9 87.7 85.0 |87.8 89.3 88.19 f C..... NO. 2L HPGg^USiKltS f DIVISION IAKE CHARI ES, IOUISIANA PERCHLORETHYLENE-TRICHLORETHYLENE DEPARTMENT OPERATIONS REPORT REACTOR NO. 5 ON STREAM TIME 1973 AVG. * HRS. 8346 JAN .728 pee MAR 650 728 APR 700 MAY 729 JUNE JULY 714 716. AUG 583 SEP 660 TEMP. F VAPORIZER LIQUOR OOWTH EflM ur 350 3.20 520 462 320 324 469 509 294 302 624 607 "255-- 320 506 490 326 379 521 500 OCT 686 NOV 662 DEC 664 1974 AVG. 08220 368 370 380 333 523 495 500 517 SEC* COND. OfSCH. CATALYST CHARCCO CATALYST FROM CENTRIFIX fl * cpm oraanic CFH Ctj * LOS. * LOS. 49 - 89333 89333 16.4 2785 43 4698 4698 18.6 3800 Z 11700 15400 42 8842 8842 18.7 2700 15800 4? .3439 3439 16.2 3500 13300 47 4612 14.7 3700 60 54 5752-- 6542 5752-- 6542 19.8 3700 18.3 3720 55 4334 4334 16.5 2200 10600 13000 14300 13900 Por-Tri Ratio Per + Tri in Crude 0.92 0.89 1.11 1.43 1.32 0.91 90.11 89.48 88.47 91.73 86.92 85.16 1.30 3.80 82.90 33.9 58 9672 9672 15.2 1700 51 11545 11543 19.2 23711" 53 22306 22306 15.0 1600 43 17376 17376 17.3 305 40 20918 20918 19.4 " 49 120269 120269 17.4 2663 13600 16700 13300 13800 12500 13850 1.32 86.3 1.21 84.5 1.32 85.2 1.09 5075 0.98 . 1.14 5172 B5.5 * ' r. ' .4 . 4 \ * ___ -________ __ __ C JNFTHE MTf Atr. Su >ject .o Pro terrt i v F> OffJ? of 1 Ith Ju Ucial Digfcr ict-Co lo. 91 -1145 `Totals F0mm N 210- 7 9u Ol *'0'tpfUvi!,i!'--r`tVet *^WtV'jevCotv cUt V C'F* P?;G t^JSTRIES tjl' -Vy! *5 NO ' CHEMICAI OIVISIOM IAKE CMARUS, LOUISIANA PERCHLORETHYLENE - TRICHtORETHYLENE.DEPARTMENT OPERATIONS f34?3 REPORT REFRIGERATED BRINE Temp. F #1 Warm (in) #1 Cold (out) 1973 AVO. JAN FEB MAR APR MAY JUNE JULY AUG SEP OCT NOV DEC 1974 AVG. ____!_________ #2 Warm fin) 6 *2 Cold (out)____ 2 PER STILL #1 Feed Reflux GPM GPM 7.6 13.7 Recycle Pot Temp GPM Op 0.21 287 Overhead Temp _____ F___ ~2?T 55 -4 -5 7.9 13.3 (0.1 288 258 8.4 14.3 0.4 289 262 4 3 9.0 14.1 0.1 290 264. 4, -6 - 7,5 13.7 0.5 23 21 8.6 14.0 0.6 285 248 5 -3 8.5 14.1 0.7 285 236 6 4 1 4 71--------- to-- ~5-----------3 -3 -4 -4 -6 -5 -2 7.1 14.2 0.4 288 247 ~T71-- 8.0 ~n:T nr. 5' 0.6 0.8 ---- 291 --251-- 243 9.8 11.2 0.7 284 242 7.8 8.9 Tf72 15.0 tvnz-- l3.b 1.0 0.5 0.5 280 238 " 245 287 249 PER STILL #2 'Feed Reflux Recycle Rot Temp Overhead Temp TRI STILL #1 Feed Reflux Recycle Bottoms Pot Temp Dverhead Temp TRI STILL #2 Feed Reflux Recycle bottoms Jot Temp >verhead Temp______ DH STILL #1 emp, F Pot Overhead ot Pressure GPM GPM GPM Op Op GPM GPM GPM GPM F F GPM GPM GPM GPM OF OF PSIG 16.2 24.8 1.5 293 248 19.3 22.7 1.8 294 253 18.0 23.5 2.9 296 260 14.8 66.0 2.76 17.1 234 160 17.5 63.7 3.4 18.2 233 158 17.0 62.6 4.4 15.3 233 160 23.2 101.2 4.7 18.2 226 147 28.4 98.8 5.6 23.0 237 147 26.5 93.9 7.0 18.7 236 154 181 148 1.70 179 144 1.68 180 141 1.68 i9.6 19.6 3.8 294 261 * 14.6 18.6 3.0 290 252 17.3 16.5 3.9 283 255 14.8 54.3 3.1 14.9 229 170 13.6 53.2 3.1 13.1 230 166 16.5 52.2 4.2 15.6 229 172 24.0 82.5 5.0 18.6 234 162 22.8 82.9 5.1 18.6 235 1!j8 29.0 84.3 6*. 2 23.6 235 159 184 147 1.70 ~Wl 142 1.66 185 147 1.68 18.0 17.9 4.5 290 251 15.5 56.8 3.9 13.8 232 169 27.3 92.9 6.3 21.0 237 157 181 142 1.70 18.2 17.9 3.9 290 252 17.7 18.4 4.3 292 254 20.3 18.7 5.6 302 253 20.1 17.8 5.2 301 246 17.0 55.0 4.6 15.8 230 172 16.8 61.4 4.4 "is; 5 231 173 51.5 58.6 3.2 15.1 229 166 14.6 54.3 2.8 13.8 228 162 28.6 95.2 6.7 21.2 234 162 187 150 1.68 28.1 25.6 100.2 100.4 6.0 6.1 22.4 20.1 236 237 163 162 24.3 93.9 4.7 20.6 235 158 185 151 1.78 185 T38 1.66 184 148 1-48 19.6 18.6 5.1 299 252 22.0 17.4 4.7 294 251 18.7 19.0 4.1 294 253 15.6 56.2 2.8 14.2 227 162 15.1 57.5 2.6 14.8 228 163 15.6 58.0 3.5 l6.1 229 if>6 25.2 87.6 5.0 19.5 227 160 26.1 95.6 4.5 20.6 234 160 26.3 92.3 5.7 20.7 235 158 177 182 143 1*52 . 1.49 183 ~Wo 1.64 v FORM ^45rt 210- a . PPGWjUSTRIES ClttMICAl DIVISION IAKE CHARIES, tOUlSIANA -Continued DH STILL #2 Temp. F Pol- Overhead Pot Pressure psig 1973 AVG. 202 143 1.64 JAN 201 135 1.66 FEB MAR 203 133 1 .61 207 140 1.66 PER-TRI STILL Feed Reflux Pot Temp.. Overhead Temo. GPM GPM Op F 67.6 54.8 292 190 81.3 64.3 283 189 77.5 61.6 298 187 73.0 61.1 294 189 APR MAY 202 136 1.60 195 142 1.67 64.5 56.7. 292 189 82.5 69.0 301 196 JUNE JULY AUG 198 142 1 .67 202 147 1.65 199 145 1.77 76.2 66.0 295 193 75.2 66.9 298 194 76.6 68.3 291 193 SEP OCT NOV DEC 1974 AVG. 202 141 1.72 290 13$ 1.57 208 142 1.43 207 139 1.30 202 T3o 1.61 78.1 66.8 295 192 74.3 59.4 290 192 74.1 63.2 289 193 76.9 60.0 "255 197 75.6 63.6 rm "155 HEAVIES STILL Feed Reflux Temp op Top Pot- GPM GPM 29.4 309.2 261 323 NEUTRALIZATION & #1 PER NH-* Product to Sta. Na3 #2 PER Product to Sta. DRYING PSIG GPM PSIG GPM 3.7 11.7 5.9 21.4 33.5 362.7 265 333 4.0 9.1 6.1 26.2 32.5 360.6 265 328 3.9 6.3 6.2 24.3 36.5 330.8 264 318 4.0 7.3 6.9 28.4 31.4 265.5 252 ~35I 35.3 288.5 255 306 3.7 4.8 8.6 10.3 7.4 5.8 25.9 27.2 34.0 30.8 342.3 318.9 259 258 321 315 30.7 326.1 256 303 5.0 9.6 3.7 5.6 2.7 6.4 4.9 5.1 24.2 25.1 5.5 22.3 34.9 299.4 254 306 34.4 305.6 256 307 32.1 34.7 303.5 319.1 261 260 316 m 33.4 318.6 259 314 2.4 10.5 3.2 26.1 2.4 2.9 20.7 10.7 3.9 3.1 27.4 24.5 4.0 12.4 3.7 27.4 3.6 9.8 5.2 25.8 -TRI- nh3 Product to Stq. V PSIG 3.37 GPM 5!To 2.9 32.0 2.6 26.2 1.9 5575 1.9 2.55 27.5 33.1 3.10 3. l6 30.5 34.6 2.33 31.8 1.85 27.3 2.20 2.3 26.0 28.2 2.3 36.4 2.4 29.6 SL 013414 CONF DKUTIj iL: Subjec t to rotec :ivs O :der of 14th Judic al DiJ strict Court No. 91-11 5 FORM ^45A 2 11-1 GENERAL DEPARTMENT 62A DRY HCl HCl Solo - Chlorine to 62A Hydrogen to 62A T/O T/O MCF/O Cl? Eeeiciency % Avg. PPG INDUSTRIES CHEM1CAI DIVISION LAKE CHARLES, LOUISIANA HYDROGEN CHLORIDE DEPARTMENT OPERATIONS REPORT JAN FEB MAR APR MAY JUNE JULY AUG SEP OCT NOV DEC Avg, Excess H; Tons Cl,/*Ton HCl Solo MCE H,/Ton HCl SOLO KWH/Ton Well Water m gal/lton HjSOjL bs/Ton ft MAN HOURS/TON HCl Production Ma 1N TENANCE SALARIED Total Contract Maint. included in Above SL 013415 (`ON P T L A f, - . Subi ?cL t-H P co 1- c. * )f 14 t i .Tiifli r' i ^ l r -L JJ No . R1 ~ i .1, Ik ift- LUU, .Cl FUKM >ijA 21a-a GENERAL DEPARTMENT PRESSURE Comp. Disch. Comp. Suction PSIG "H->0 1973 AVG. TEMPERATURE F No. 1 Burner Gas from Primary Gas from Secondary No. 2 Burner Gas from Primary Gas from Secondary No. 5 Burner Gas from Primary Gas from Secondary No. 5 Comp. Disch. Op Cell Liquor #/Ton HC1 Well Water to HC1 GPM OPERATING TIME * No. 1 Burner No. 2 Burner No. 5 Burner JAN PPG -USTRIES CHEMICAL DIVISION LAKE CHARLES, LOUISIANA FEB WAR APR MAY JUNE JULY SL 013416 JAUG SEP OCT NOV 0EC 1974 AVG. -- -----** -------- e VPIUISN lilUi! y--PTOt rWrlAS* of "IV h Jud L c i d 1 N 3istn CC tuil r 11i 4i 7e ` COMPRESSORS #1 #2 #3 #4 #5 #6 #7 #8 No. 1 Stripper No. 2 Stripper * 6741 * 7669 * 3180 * 7188 * 2543 * 7826 7895 * 59 730 664 35 0 35 709 * 7404 * 6927 35 0 345 76 345 0 0 0 626 0 0 632 497 333 363 0 0 689 375 0 338 469 452 108 0 0 628 684 308 438 0 0 0 744 146 683 578 0 0 370 356 475 744 231 0 0 15 654 145 0 0 0 0 000 707 488 358 595 634 720 744 315 0 232 352 305 0 00 0 0 0 57 659 0 0 121 0 597 .696 579 487 594 214 588 0 744 0 744 5421 6134 4518 506 1460 541 7509 0 000 0 555 0 0 6 0 0 0 Totals FOAM ^ 211-3 ?PG IIWISTRIES CHEMICAL DIVISION ,IAK CHAItlES, LOUISIANA HYDROGEN CHLORIDE DEPARTMENT OPERATIONS REPORT GENERAL DEPARTMENT 1973 AVG. 62B - WET HC1 Wet HC1 Produced T/D 97.9 JAN 39.3 FEB 37.0 MAR 53.6 APR 45.3 MAY JUNE JULY AUG SEP 47.5 19.4 32.5 17.6 5.2 OCT 2.8 NOV 10.7 n7 Steam (Actual) Well Water H7S0d KWH/Ton T/T 0.046 0.158 M lbs./T 2831 225 M Gals/T 4.2 -- lbs./T 0.3 0.6 "10.4 24.6 0.169 0 0.4 28.9 0.105 1293 - n. a lfl.n 0.147 592 0.4 22.0 0.119 0 0.7 20.4 0.258 0 - 1.0 51.5 0.199 0 - 0.9 29.8 0.640 0 1.4 54.8 1.272 0 - 6.7 190". 7 2.579 0 - 0.0 343.9 0.547 476 0.0 93.8 DEC 1974 AVG. 8.9 26.6 0.908 0 - 0.0 109.0 0.592 646 - 1.0 82.3 HC1 ACID (as Muriatic Acid) Captive Use T/D Shipped T/D 46.2 36.5 1.2 0.0 51.7 0.0 Strong Weak Wt. % 31.95 32.79 31.30 wi-. & 46.3 0.0 54.3 0.0 * 32.24 31.57 47.2 0.0 41.2 0.0 37.3 0.0 28.6 0.0 (J.U 34.7 0.0 38.7 30.6 0.0 "TO 40.5 o.u 30.04 30.78 30.47 30.96 30.95 32.52 32.39 ' '30 .`05 31.34 * 1 SL 013417 CON S'lDEN'T I AT. I Subi< !Ct to Prote r?fc i vo Cirrt^fr C f m 1 Judi :ial D lRt rin t Trtiir t No , 9i-l L4S FORM N jA 211-4 GENERAL DEPARTMENT 620 WET! HCL REFRIGERATION UNIT Pressure PSIG Sue T1 ON D1SCHARGE Seal TEMPERATURES Op Brine In Brine Out Awrs "1973" Avg F^'GJNTCSTRIES CHEMICAL DIVISION LAKE CHARLES, LOUISIANA HYDROGEN CHLOR(DE DEPARTMENT OPERATIONS REPORT JAN FEB MAR APR MAY JUNE JULY AUG -20.5 11.4 30.1 -18.6 8.4 30.0 - 32 38 33 38 158 144 - 21.2 10.0 30.0 -21.6 8.8 30.0 - TS------------- 153 25 21 143 - ------ -- - ---- -- NO- 1 STRIPPER F LO5 Strong Acid Feed Steam qpm Los/Hn Temperatures Op Top Gas from Cooler 46.8 43.8 8881 9131 230 226 44 40 - 38.0 6674 226 42 36.3 6469 230 38 --- -- - --- SEP OCT NOV DEC 1974 Avg - -2 3.0 -21.8 -22.0 -21.4 - 8.8 8.2 8.5 8.8 - 29.9 30.5 30.3 30.1 - 19 - 15 - 146 28 31 24 27 144 145 28 25 146 -_ - -- -- ----- 39.4 7425 227 40 NO- 2 STRIPPER Flot. s Strong Acid Feed Steam GPM Los/Hb Temperatures Top Op Gas from Cooler 43.4 0 6793 0 244 44 - Sub ji CON >rt to t Judi 'I DENT Prote jiat E lAL: ctive istric Order t tour No . 91-1 145 man HOIIRS/TON RCL Production Maintenance Salari f d Total Contract Maint. Included in Above 0.135 0.090 0.034 0.259 0.000 0.346 0.016 0.087 0.449 0.000 0.365 0.069 0.092 0.526 0.000 0.242 0.289 0.060 0.591 0.000 Q. 314 0.038 0.078 0.430 0.000 0.291 0.066 0.072 0.429 0.000 0.690 0.022 0.165 0.877 0.000 0.372 0.191 0.105 0.668 0.000 0.519 0.190 0.193 0.902 0.000 1.990 1.272 0.610 3.872 0.000 3.233 0.756 1.266 5.255 0.000 0.917 0.219 0.285 1.421 0.000 1.079 0.406 0.384 1.869 0.000 0.863 0.294 0.283 1.440 0.000 SL 013418 FORM N SL 013419 PPG INDUSTRIES CHEMICAL DIVISION LAKE CHARLES, LOUISIANA ETHYL CHLORIDE DEPARTMENT OPERATIONS REPORT CONFIDENT!* Subject to Protective Order rtf 14th Judicial District Court GENERAL DEPARTMENT Ethyl Chloride Production EC arc* Production EC Shipments T/D T/D T/D 1973 Avg 168.2 168.6 169-3 JAN 175.4 175.7 139.7 FEB MAR 89.7 148.4 80.6 148.3 136.4 123.8 APR 141.2 142.0 153.0 MAY 172.3 172.7 176.4 JUNE JULY 183.8 165.7 184.5 167.1 158.7 152.4 AUG 139.1 144.8 171.0 SEP OCT 160.0 152.3 154.7 152.1 157.5 17370 NOV DEC 140.7 140.9 120.5 183.5 183.6 170.3 W4 154.3 153.9 152.8 __ HCl To EC T/D 105.2 110.9 50.9 92.5 87.8 112.5 114.2 104.7 84.9 93.8 98.2 91.8 114.6 96.4 Ethylene to EC Pur i ty T/D 76.0 79.0 36.3 67.0 64.3 79.8 85.0 79.2 69.5 73.0 73.0 66.3 84.7 71.4 * 99.92 99.87 99.92 99.91 99.94 99.97 99.95 99.93 99.95 99.91 99.86 99.94 99.88 99.92 HCl Efficiency Carbon Efficiency S 91.0 89.8 90.1 90.9 91.8 87.4 91.8 90.0 96.8 93.6 88.0 87.4 91.1 90.7 % 96.8 97.0 97.0 96.5 96.2 94.6 94.7 91.3 90.9 92.4 91.0 92.8 94.6 94.1 Excess HCl Excess HCl f/o 6.5 * 6.6 8.3 8.1 3.7 12.0 5.4 6.2 4.1 4.9 8.7 8.4 3.6 3.3 1.7 1.6 -5.4 -6.0 -1.1 -1.2 3.4 3.6 5.6 6.4 4.4 4.0 3.5 4.3 HCl to EC Tons/Ton EC Pnoo C;H4 to EC Tons/Ton EC Nj to EC Tons/Ton EC FrCL3 Sic AM Lds/Ton EC Los/Ton EC 'Airll Water Kw/tun EC M Gals/Ton EC 0.624 0.450 0.040 0.631 0.449 0.052 0.632 0.450 0.157 0.623 0.451 0.058 0.617 0.452 0.055 0.651 0.619 0.631 0.462 0.461 0.478 0.042 . 0.039 0.046 0.586 0.479 0.073 8.4 1102 1.529 93.0 9.5 1120 1.358 79.2 8.8 1182 1.816 95.3 7.7 1182 1.957 95.9 9.9 1139 2.041 90.6 7.9 1074 1.680 70.1 9.3 9.8 1052 1242 1.553 1.616 72.6 81.2 10.2 1116 1.692 88.1 0.606 0.645 0.472 0.479 0.067 0.069 0.651 0.470 0.064 0.623 0.461 0.045 0.626 0.464 0.064 9.6 11.1 1622 1703 1.723 1.759 87.0 95.5 9.8 1728 1.702 89.2 7.2 1567 1.457 90.3 9.2 1311 1.696 86.2 MAN HOURS/TON EC Product!on 0.212 Ma intfnance Salaried______________________________________ Total___________________________________________ Contract Maint. Included *n Arotc 0.197 0.076 0.485 0.035 0.238 0.154 0.074 0.466 0.000 0.508 0.841 0.163 1.512 0.000 0.266 0.151 0.084 0.501 0.000 0.300 0.221 0.095 0.616 0.007 0.244 0.134 0.076 0.454 0.000 0.226 0.096 0.066 0.388 0.000 0.188 0.115 0.079 0.382 0.000 0.199 0.316 0.090 0.605 0.000 0.195 0.180 0.183 0.132 0.079 0.090 0.457 0.402 0.020 0.000 0.196 0.167 0.083 0.446 0.000 0.146 0.069 0.071 0.286 0.000 0.240 0.215 0.088 0.543 0.002 an Hours/T EC Shipped > Bulk Salaried D.025 0.030 0.025 0.034 0.025 0.027 3.002 D.003 t).002 | 0.OO3 0.002 0.002 0.051 jO.041 0.025 0.004 0.004 0.003 0.038 0.020 0.030 0.004 0.002 0.002 0.022 0.031 n.nn? fi n_nn3.i FORM '^K5A 212-2 PPG r "JSTRIE5 CHEMICAL DIVISION LAKE CHARLES. LOUISIANA ETHYL CHLORIDE DEPARTNENT OPERATIONS REPORT MATERIAL BALANCE 1973 JAN Avg CHLORINE - TONS Total Chlorine in Feed 3112.0 3343.2 -t fChlihii he in Production .-.. 2832.8 3003.6 FEB MAR 1386.6 2788.7 1249.2 2535.9 APR MAY 2560.3 3390.3 2350.0 .2964.9 JUNE 3331.E 3058.5 JULY 3155Z 2839.4 AUG 2560.2 2479.2 SEP 2737.C 2563.3 OCT NOV DEC '4 2961.2 2676.9 3453.1 2862.0 2605.0 2340.4 3144.5 2594.5 Chlorine Loss in Process Bloadown From Heavies Still 279.2 339.6 137.4 252.8 210.3 425.4 273.0 315.9 81.0 15.3 11.4 8.9 9.6 8.7 22.9 17.8 17.6 12.6 173.7 356.2 336.5 308.6 267.5 12.9 13.9 17.0 15.9 14.1 -UNA CCOtlN TABLE PROCESS LOSS Chlorine Loading Loss Total Chlorine Loss 263.9 328.2 128.6 243.2 201.6 40775 255.2 298.3 ~58;4~ 160.8 342.3 139.5 292.7 253.4 7.2 5.1 5.6 -075 13.4 7.2 10.7 -24.9 93.9 -7375'' -3.6 3.9 3.0 3.3 286.4 344.7 143.1 252.2 223.7 432.6 283.7 291.0 174.9 100.2 352.6 340.4 311.6 270.8 CARBON -- TONS Total Carbon in Feed Carbon in Production T , LossCarbon in process Ploapown From heavies Still -- 1979.0 2095.8 870.7 T775T3 1653.0 2118.9 2184. 2102. 1844.3 1876.: 1937.4 1704.1 2249.1 1868.0 1916.4 2032.9 844.6 1716.4 1590.6 2004.2 2068.7 1920.: 1677.3 1734.2 1762.2 1582.2 2127.2 62.6 7.1 62.9 5.3 26.1 4.1 61.9 4.4 62.4 4.0 114.7 10.6 116.2 182.6 167.0 8.2 8.1 5.8 142.0 175.2 121.9 6.0 6.4 7.8 121.9 7.3. 112.5" 6b Unaccountable Process Loss Carbon Loading Loss Total Carbon Loss 55.5 4.9 67.5 57.6 22.0 3.5 3.8 66.4 29.9 5715 58.3 -=UT3-- 9.0 61.5 71.4 104.1 4.9 119.6 108.0 17375 161.2 136.0 168.7 114.0 114.6 106.4 7.2 -16.8 63.6 -52.5 -2.5 2.6 2.0 TZJ 123.4 165.8 230.6 89.5 172.7 124.6 T23.9 114.9" Z SL 013420 1 ' i1 ' CONF ID ENT. AL>: Subie crt to Prote< :tive i Jrder O : 14th J u elic i it 1 in stric ; Court Mo, 91-1. T5-------- PPG If^^STRIES REACTOR PRC SSURE TCMPCRATURE FLASHER Temperature BOTTOM op Top PS 1G Op PRIMARY STRIPPER Pressure ps i g Temperature op Top Bottom HEAVIES STILL .Feed Rate gpm Reflux Steam (actual) gpm Lbs/Hr Temperature op- Top Bottom SECONDARY STRIPPER pressure psig Tempera tore of Top Bottom 1973 A VG 125 136 JAN 128 133 CHEMICAL DIVISION LAKE CHARLES, LOUISIANA ETHYL CHLORIDE DEPARTMENT OPERATIONS REPORT FEB 106 120 MAR 106 126 APR 101 123 MAY 116 125 JUNE JULY 119 122 131 133 AUG 112 126 159 159 154 141 151 136 138 135 126 133 158 159 162 160 137 138 142 136 86 109 150 86 112 152 83 116 148 74 103 138 81 1G6 144 85 87 90 84 114 113 115 111 149 150 152 147 43.5 19.6 395$ 43.1 17.4 4186 146 147 191 187 36.2 18.1 3354 146 184 42.6 19.9 "3B3T' 45.0 19.0 3952 147 339 183 181 43.0 20.6 3818 43.1 20.0 4022 145 146 ' 154""1 188 20.0 4793 145 184 43.8 20.0 3631 146 187 73 74 153 154 154 154 73 153 153 71 74 152 149 151 154 73 74 73 73 152 153 152 154 152 153 153 154 SEP 113 127 OCT 113 131 163 160 136 139 84 87 113 107 148 150 38.8 20.0 3504 38.2 20.1 3605 145 144 190 184 74 73 154 153 154 152 NOV 96 122 DEC 103 128 1974 A VG 111 127 165 160 137 135 158 136 85 83 108 108 149 146 84 111 148 37.0 20.5 3552 42.2 20.0 3001 3176 19.6 3556 146 184 146 185 146 185 72 73 150 150 151 151 73 152 153 ol Subje< Utb CONS ifto Juui^ ------H-r nCNTl jfnFeC irI ni al -11 VL: :ive 0 strict 45 j oL U 1 0*r 1 PA__- 4 213-1 GENERAL DEPARTMENT VC Records Production VC Area Production VC Shipments T/D T/D T/D 1973 AVG. 416.5 421.9 427.6 PS*G IS^STRIcS CHEMICAL DIVISION LAKE CHARLES,LOUISIANA VINYL CHLORIDE DEPARTMENT OPERATIONS REPORT JAN. FEB. MAR. APR. MAY JUNE JULY AUG. 266.9 269.4 173.P 135.4 138.4 PR3 7 335. fl 337.8 PTfi.4 371.0 374.9 418.2 496.9 489.9 559.2 568.2 566.3 469.6 437.0 435.7 423.4 446.4 449.0 470.6 SEP. OCT. 438.0 409.2 441.5 410.8 332.0 480.2 NOV. DEC. 343.8 417.0 342.3 417,6 313.5 574.4 1974 AVG. 388.8 389.5 392.9 ___________ YIELDS________________ Area Prod. + Trans. Credits Basis CI2 C Records Prod. + Trans. Credits Basis Cl3 C 99.7 99.3 98.9 98.1 99.9 95.9 99.9 95.2 99.5 94.9 99.0 93.1 101.0 99.8 100.6 99.3 99.2 98.7 100.6 99.3 100.0 98.3 98.5 97.4 98.5 98.1 98.7 98.4 98.6 98.1 99.3 98.9 98.4 97.8 99.1 98.4 99.2 99.1 98.8 98.7 98.8 98.0 98.9 98.3 98.1 98.8 97.7 98.5 99.0 98.5 98.3 98.7 98.1 98.4 98.6 97.9 HCI By-Product Prod. HCI By-Prod. Utilized HCI By-Prod. Utilization T/D 246.2 T/D 241.0 % 97.9 156.6 80.7 153.6 82.1 98.1 101.7 197.0 188.5 95.6 218.5 216.5 99.0 289.7 281.9 97.3 330.1 321.0 97.2 254.8 246.8 96.9 261.8 256.4 98.0 257.3 260.7 101.3 239.5 232.4 97.0 199.5 243.4 192.2 246.4 96.4 101.2 227.4 223.2 98.3 Heavies Still Bottoms Prod, T/D 9.7 Dopp Kettle Waste Lbs./T VC 6.87 3.5 7.9 9.13 11.8 8.4 7.3 15.7 4.0 17.0 8.7 16.2 5.1 14.6 7.6 14.5 5.3 14.3 6.2 11.4 7.2 11.0 6.1 9.7 6.6 12.0 7.1 EDC Consumption EDC Consumption Cl2 Consumption T/D 682.9 T/T VC 1.62 Lbs./T VC TT33 429.9 237.6 1.60 1.72 6.93 5737 539.0 611.6 811.8 1760 1.63 1.63 4718 " 5.88 3.73 928.0 1.64 5.46 718.2 1.64 5.35 731.3 1.63 5.73 720.0 1.63 6.45 668.9 1.63 8.06 564.7 679.9 1.65 1.63 2.87 2.61 636.7 1.64 5,32 Steam Consumption Gas Consumption Well Water Used Nitrogen Used Power Consumption Lbs./T MCF/T M Gals./T Lbs./T KWH/T 3664 4.66 0.93 41.1 71.2 4384 4.67 2.78 75.2 108.4 1594 5.35 5.61 311.6 31U 3761 5.15 2.09 61.1 74.8 SL 013422 3867 5.50 1.80 75.9 70.5 3462 4.89 1.31 66.1 69.2 3154 1 4.60 1.29 58.2 67.4 3932 5.46 1.86 59.6 80.5 3886 5.38 1.76 48.4 72.5 3362 5.35 l.ll 89.4 70.5 4099 5.47 2.02 56.2 77.0 3024 4.35 1.81 87.6 58.4 3812' 5.32 1.50 67.8 73.0 3778 5.12 1.96 88.1 71.1 JlJU Or 1 a*-H r.ONFI ' to F JEWTH cotecit ) i VH tudici |a 1 I'M No- glTT* 5 I't rmitt . PAGE: 213- 2 PPG INl) TRIES CHEMICAL DIVISION LAKE CHARLES,LOUISIANA VINYL CHLORIDE DEPARTMENT OPERATIONS REPORT GENERAL DEPARTMENT MAN HOURS/TON VC PROD. 1973 AVG. Production 0.144 Maintenance 0.102 Salaried 0.039 Total 0.285 Contract Man Hours include do.029 MAN HOURS/T VC SHIPPED Bulk Salaried 0.021 0.002 JAN. 0.236 0.155 0.063 0.454 0.000 0.040 0.004 FEB. MAR. 0.515 1.256 0.124 1.895 0.000 0.195 0.098 0.048 0.341 0.013 0.023 0.028 0.002 0.002 APR. MAY 0.175 0.136 0.047 0.358 0.J015 0.127 n. i 38 n.n34 0.299 0.041 0.024 0.019 0.002 0.002 JUNE JULY 0.116 0.154 0.081 0.062 0.028 0.039 0.225 0.255 0.000 0.000 0.027 0.023 0.002 0.002 AUG. 0.143 0.046 0.038 0.227 0.000 0.025 0.003 SEP. OCT. NOV. 0.146 0.090 0.036 0.272 0.006 0.165 0.110 0.043 0.318 0.000 0.187 0.273 0.044 0.504 0.002 0.020 0.028 0.028 0.002 0.002 0.002 DEC. 0.146 0.070 0.041 0.257 0.009 0.021 0.002 1974 AVG. 0.192 0.210 0.049 0.451 0.007 0.026 0.002 oOiL U011 3o4*t 2i-3w i c ---------So !) jUv <5f 1 4J fc- V* ,lv tnfide StTKE! ho Prc tecti' dicia Disti No. 9: .-1145 u UtlH: ret r VIF *- FORM NOwi 213-3 PROCESS CONDITIONS VAPORIZING FURNACE EOC FEED TEMP. rURNACE fiRIOGCWAUL TEMP. apavc..passes#i Ac # i 1973 Avq. F *r psi 329 1308 193 CRACKING FURNACE FEED TEMP. *F 401 JAN 326 1932 209 450 PPG STRIES CHEMICAL DIVISION LAKE CHARLES, LOUISIANA VINYL CHLORIDE DEPARTMENT OPERATIONS REPORT FEB MAR APR MAY JUNE JULY AUG 322 1 241 211 450 308 1244 170 376 316 l?6l 182 ~36 307 l 9;3 198 287 1320 206 398 404 324 1289 205 392 322 1288 202 396 SEP 313 1306 214 401 OCT 315 1281 217 398 NOV 315 1369 205 388 CRACKING FURNACE#! FURNACE BRIDGE WALL temp. *f 1290 P AVC, PASSES Fl. #1, # 3 Ac # 4 PSI 126 1357 137 1255 141 1258 113 1285 122 1266 141 T37I 146 1340 140 1341 141 1281 150 1217 150 1284 130 A VC PASS OUTLET TEMP., PASSES #1, #2. #3. Ac #4 *P 904 936 920 913 886 870 926 912 904 844 842 878 CRACKING FURNACE #2 FURNACE bridgewall temp. 4 P AVC . PASSES #t, #3, #3 Ac #4 *f PSI J. 125 - - 1201 112 TTZ5 1261 Tt5------- 134 1308 143 1273 142 1263 134 1265 135 1272 140 * 1250 123 AVC- PASSQIJTLFT TFMP PASSES #1. #3, #sAc#4 *r 877 J - * 873 870 893 922 908 908 . 882 876 - 874 DEC 314 1344 202 392 1242 128 842 1210 120 837 1974 Avo. 314 1286 202 403 1297 137 889 1253 130 884 OUENCH TOWER TOP TEMP tor PPESS, ' *f 275 269 267 275 272 274 278 285 281 281 278 275 274 276 PSIC 91 84 86 88 91 97 102 98 95 96 93 91 . 89 93 , SL 013424 ~ r CONFIL BNTIAI : a jbject to Pt otect ve Ort er of .4 th j Jdicia 1 Dial rict C ourt, No. 9 1-1145 FORM 213-4 PROCESS CONDITIONS ABSORBER COLUMN 1973 Aver. SEC. QUENCH COND. GAS PEED TEMP. F BOTTOM I'Q TEMP.*F. TR fcY *7 TEMP. *F Tll *\2 TEMP. TRU *35 TEMP. T -F 159 123 66 55 19 L1Q. PROM UPPER INTERCOOLER TEMP. *r 45 L l O PROM LOWER INTERCOOLER TEMP. *P (0 LEAN OIL TO ABSORBER TEMP. *F -2 6 LEAN OIL PLOW AVG. GPM 166 ABSORBER top PRESSURE _ P St G 78 JIRIPPER.GOLUMN QUENCH HQ. PEED TEMP. BOTTOM HO- TEMP. STRIPPER TOP TEMP. BOTTOM PRESS PRODUCT STILL COLUMN LIQUID PE EO TEMP, BOTTOM LIQ TEMP. rmr temp. TOP TEMP. STILL TOP PRESSURE *F *F F PSIC 133 218 125 94 *P 222 *F 326 *f 240 *P 109 PSIG 85 JAN 142 127 55 53 39 52 -1 -26 150 77 118 225 133 B6 229 319 247 106 81 MjSUKS CHEMICAL DIVISION LAKE CHARLES, LOUISIANA VINYL CHLORIDE DEPARTMENT OPERATIONS REPORT FEB MAR APR MAY ' JUNE JULY AUG SEP 145 166 128 110 65 80 56 59 40 27 53 44 -1 (0 -26 [-25 150 |162 77 79 119 125 220 209 132 125 90 93 224 321 248 107 84 214 319 229 102 77 151 ii9 76 Si 24 49 (1 -25 173 79 126 210 123 94 216 318 239 106 81 140 123 81 61 19 49 0 -25 184 79 133 211. 122 97 218 323 244 109 37 148 168 181 127 136 136 95 81 76 65 58 59 23 19 20 ------- 43 45 0 -22 195 80 (0 -26 173 75 (0 |-22 180 80 178 137 70 57 18 44 -1 -24 180 80 142 208 1.23 100 151------ 139 219 219 129 129 95 96 139 219 129 97 215 227 232 229 324 321 322 322 243 244 241 241 110 10*9 111 111 88 -55-------- -05-------- 88 OCT 183 138 76 56 18 41 (0 -21 180 80 136 221 131 94 226 320 241 TTJ9 86 NOV OEC 1974 Avg. 159 160 160 124 126 128 71 64 74 56 55 58 20 24 24` 44 44 46 2 2 (0 -26 -27 -25 175 163 172 80 80 79 123 123 131 215 217 216 119 122 126 96 94 94 773------- 224 321 319 240 242 . 109 106 86 82 223 321 242 108 85 SL n01'l3'li4lOZOfi I. 1 1 __ cm (At,* Subl !Ct to Profrp rt f y'g rica_ ( if 141 i Jutli ' i .i 1 M * * t r i C . No _SLLtl U5____[ : ----------- FORM N< 213-5 PROCESS CONDITIONS 1973 Avq. HEAVIES STILL COLUMN HO PECO temp. BOTTOM LIO- temp. TOP TEMP. TOO PRESSURE REFRIGERATION PIRST STAGE SUCTION TEMP. SECOND STAGE SUCTION TEMP. third stage suction temp. POURTM STAGE SUCTION PRESS. COMPRESSOR #1 AMPsS IAOO V OISCH ARGE PRESS DISCHARGE TEMP. COMPRESSOR^; '-AMPS % 2A00V F F *F PSIG F F F PSIG PSI G *F 174 239 _ 201 1.28 -29 -4 34 57 213 124 183 228 DISCHARGE PRESS DISCHARGE TEMP. PSIG 130 *F 180 PRODUCT STORAGE OAV TANKS - AVC TEMP, AVG. PRESS. SPHERES- AVG. TEMP, AVG. PRESS * F 69 PSIG 36 r 68 PSt G 44 MISCELLANEOUS MCI BY-PRODUCT TO DISTRIBUTION. temp. *F -18 JAN 177 235 196 . 2.41 -28 -5 34 46 191 115 184 212 121 186 56 26 55 36 -21 PPG.INRiSTRIES CHEMICAL DIVISION LAKE CHARLES, LOUISIANA VINYL CHLORIDE DEPARTMENT OPERATIONS REPORT FEB MAR APR MAY JUNE JULY AUG 175 234 196 2.26 157 235 199 1.80 173 238 199 1.05 176 239 201 1.01 178 239 199 1.63 179 238 201 .82 190 240 202 1.11 -29 -5 42 47 197 121 190 215 126 183 -33 -5 33 54 201 115 TS2 771 124 176 -31 -33 -5 1-5 42 57 60 63 200 252 ITS------ 132 "155 191 218 231 124 136 182 191 -35 1-36 -34 -7 - 8 -7 55 63 40 64 62 62 ~241-- in-- 222 ~TT7-- 132 132 200 256 240 ~T32---- 136 ~TB9---- 196 190 222 "TT7 186 56 70 73 77 27 36 36 39 60 62 69 77 40 42 45' 50 82 82 40 51 80 82 56 56 87 50 79 ` 53 -21 -21 -23 -24 -24 -24 -22 SEP 207 241 201 0.97 -33 -7 50 61 214 128 195 220 m 193 76 44 75 52 -23 OCT 212 242 200 0.84 1-33 k 45 63 240 126 186 229 130 189 69 40 70 " 53 -20 NOV 143 236 201 1.00 1-33 i-4 39 57 224 124 180 222 128 186 60 33 58 41 -19 DEC 1974 Avg. 149 238 200 0.99 176 238 200 1.32 -36 -33 -6 -6 40 45 56 58 229 220 132 126 188 189 233 227 136 131 190 187 54 70 30 38 54 68 38 47 * -20 -22 COOLING TOWER WATER TO PLANT. TEMP. F 87 35 B7 85 84 88 89 90 91 38 85 83 34 87 -- bciL nUl1u*1QilZDOR l L'ONFTU RNTlAt S ib jec b to Pr oteeti vo Ore Or or -4th J j ci i. c jL ci 1 bust riot L ou r t No. 9 1-1145 PACE: 216-1 PPGJWTJSTRIES CHEMICAL DIVISION LAKE CHARLES^LOUISIANA CONFIDENTIAL: Subject to Protective Order of 14th Judicial District Court GENERAL DEPARTMENT OHC-EDC Production T/D 1973 Avg. 262.1 JAN. 294.5 FEB. 210.3 MAR. 274.1 APR. 293.9 MAY JUNE JULY 412.9 465.4 357.8 AUG. 390.8 SEP. OCT. 438.6 366.0 NOV. DEC. 362.0 436.0 1974 Avg. 358.5 HCL toOHC-EDC HCL Consumed T/D 197.6 224.6 157.2 205.9 227.7 312.5 351.3 275.3 T/T EDO 0.754 0.762 0.747 0.751 0.756 0.756 0.754 0.769 303.9 338.3 283.3 279.9 331.7 274.3 0.777 0.771 0.774 0.773 0.760 0.763 Purchased C2H4 to OHC-EDC % C2H4 Purity VIELD Cl2 Basis C?H& Basis T/D % 75.6 85.4 61.6 80.7 87.7 120.3 142.4 104.4 99.92 99.87 99.92 99.91 99.94 99.97 99.95 99.93 97.6 96.6 98.2 92.5 98.6 "9571 91.8 92.5 98.2 95.0 97.4 94.2 97.6 95.7 90.7 94.0 117.8 127.1 107.0 104.0 125.3 105.3 99.95 99.91 99.66 99.94 99.88 99.92 94.7 91.7 95.5 95.2 95.3 94.5 9513 96.9 95.3 95.4 96.6 93.6 Excess C7H4 Excess C^Hd Excess C9H4 % 1.9 T/M 41.2 Lbs/T ED .10.7 2.4 60.9 13.3 3.4 56.2 19.1 3.9 93.5 22.0 2.8 70.6 15.6 2.8 102.4 16.0 8.0 2.9 315.1 92.6 45.1 16.7 ~&73----- 217.4 35.9 2.2 82.2 12.5 3.2 ~T75----- 1.4 101.3 42.7 53.4 17.9 7.8 7.9 3.4 107.4 19.2 Oxygen to OHC-EDC Oxygen to OHC-EDC Excess O2 Excess 0? Excess O3 T/D 50.1 T/T EDC 0.191 % 15.6 T/M 205.4 Lbs/T ED ;51.8 57.5 0.195 16.7 255.3 57.8 39.5 0.187 12.6 124.0 42.1 52.4 0.191 15.9 222.8 52.4 55.1 0.183 10.4 155.3 34.4 75.8 0.183 10.5 223.4 34.9 85.1 75.8 0.182 0.211 10.4 25.4 241.6 476.4 34.6 86.8 79.4 0.203 19.1 395.5 65.3 74.7 0.170 0.7 15.2 2.3 72.7 0.198 17.0 327.3 57.7 69.9 0.193 13.8 254.4 46.9 81.1 0.186 11.5 258.8 38.3 68.3 0.190 13.7 245.8 46.1 CRUDE EDC INVENTORY TONS For Per-Tri Feed TONS For EDC Still No. 2 Feed TONS For Tetra Feed Tons Transferred to Per-Tri TONS Transferred to EDC Still No. 2 TONS .Transferred to Tetra TONS 228.4 46.7 183.7 - 240.6 89.7 150.9 - 531.8 200.8 331.0 - 82.7 3.0 0.0 7854.0 3863.9 5309.2 'tofTT 679.T 27.0 0.0 40.3 381.9 3^1 "357-5 STITT "31(5.7" "320.5 0.0 0.0 0.0 6.6 0.0 52.3 62.4 24.4 13.8 54.9 400.9 474.7 0.0 . 0.0 54.9 36.8 240.3 0.0 0.0 433.1 26.5 100.3 340.1 297.4 309.6 395.1 546.9 499.0 0.0 0.0 0.0 588.4 2231.5 2463.3 4064.2 1788.6 8327.8 5786.5 106325 9782.6 9100.3 396.9 0.0 4027.2 8242.1 365.6 0.0 4888 8180 346.0 0.0 3498.8 7786 2 437.9 240.3 306.3 0.0 0.0 41.6 5403.1 4479.1 2786.1 5329.E 9252.2 8049.5 MAN HOURS/TON EDC PRODUCED Production Maintenance Salaried Total Contract Man Hours Included -- 0.177 0.199 0.250 { 0.105 0.086 _Li 077 0.513 0.381 0.001 0.000 3.334 0.404 0.109 3.847 0.000 0.205 0.207 0.079 0.491 0.000 0.199 0.236 0.078 0.513 0.022 0.144 0.135 0.055 0.334 0.000 0.108 0.152 0.135 0.261 0.046 0.063 0.289 0.476 0.000 0.043 0.134 0.216 0.058 0.408 0.010 0.114 0.160 0.049 0.323 0.000 0.144 0.266 0.065 0.475 0.000 0.152 0.240 0.056 0.448 0.000 0.121 0.248 0.052 0.421 0.020 0.167 0. 218 0.065 0.450 0.008 . SL 013427 PACE: 216-2 ot lAt* tO \ V)^5^ HO 9i- Or aer Go \jt1 jSj < PPG INDUSTRIES CHEMICAL DIVISION LAKE CHARLES, LOUISIANA CHC-EDC REACTCR //I 1973 JAN. AVG. FEB. On-Stream Time * Mrs. 5249 688 522 Top Pressure pcig 23 25 20 Dcvstherm Temp. (Front) of 346 348 367 (Into) ~~W 313 303 335 Reactor Temp. Catalyst Bottom Middle OF 596 op 539 589 543 586 529 Top F 521 526 513 Vapor Space F 520 526 513 Refrig. Cond. Outlet F 55 43 43 FEEDS Cp schf 47384 48400 41500 Op schf 27546 29200 24700 HC1 schf 97390 101700 88600 RECYCLE AKiLY5IS(Vol. i) COo CpHL 02 Catalyst Charged % 28.6 32.8 iT" 54.2 51.2 i 2.7 1.8 Lbs. TL0725" 11669 30.9 51.7 2.0 0 MAR. 384 24 342 314 590 539 514 ST2-----m-------- 47100 28700 100600 31.5 51.4 2.0 17522 APR. 532 21 617 534 504 505 43100 25200 85700 27.2 48.0 1.6 106 MAY 696 22 -- 624 535 510 511 - 41900 25300 88600 27.7 47.5 1.6 15839 JUNE 676 21 - 580 526 514 sis 40600 24700 89000 32.6 50.0 2.0 15891 JULY 296 21 348 314 563 546 516 528 63 38200 27600 55800 35.2 39.1 2.9 4268 AUG. 404 20 366 337 591 538 511 515 61 34800 23800 86100 32.8 40.0 2.7 7493 SL SEP. 682 16 480 351 577 542 525 41 33700 23300 83700 30.3 50.5 3.0 6348 013428 OCT. NOV. 704 668 13 16 398 388 372 362 583 534 519 521 56 29600 20400 70400 586 541 525 526 44 31700 23500 78700 43.3 38.7 2.8 22110 38.5 47.1 2.7 18910 DEC. 288 15 3Q7 a7A 1974 AVG. 6540___ [2Q_____ 340____ 580 539 521 523 60 31400 22700 76100 589 537 516 519 51 38500 24900 87100 40.7 48.2 3.1 3260 33.6 47.0 2.4 7714 REACTOR #2 On-Stream Time * Hrs. 5269 736 Top Pressure psig 23 24 Dowtherm Temp.(From) F 352 356 (Into) F 315 316 Reactor Temp. Catalyst Bottom F 580 571 Middle Top Vapor Space OF 529 op 518 oF 520 534 527 528 Refrig. Cond. Cutlet F 55 43 FEEDS C?Hl schf 47249 16500 Op schf 25808 26400 HC1 schf 99500 97700 RECYCLE ANALYSIS(Vol. w~ COp CpHi, % 29.5 % 54.5 31.9 53.5 02 Catalyst Charged % 2.8 2.3 Lbs. 10907. [12641 Totals* 512 19 364 117 v 596 525 509 513 45 11700 23100 37200 28.8 53.3 0.0 0 708 19 377 346 576 521 508 513 45 38400 22300 84000 35.7 3277 3.2 32308 72 14 - 596 520 505 509 0 - - - - - " - * 32300 19400 72800 -- -- 35.7 52.7 -- 3.1 14 - 676 604 648 608 464 536 690 6254 21 20 12 16 15 13 18 17 - 326 383 379 381 396 375 371 - 302 356 350 352 366 339 340 580 526 514 518 -- 40600 24700 89000 593 522 507 511 65 38600 23600 86900 598 529 511 512 62 31100 18300 65300 580 594 TT3------ 532 3IS 518 513 520 43 52 34700 34900 21000 20300 79000 72500 589 532 520 522 45 33800 20100 70700 586 545 533 535 49 40200 25000 82500 587 529 518 518 50 37500 22200 80700 32.6 50.0 2.0 15891 39.8 42.4 2.0 8537 41.0 43.7 2.4 7493 43.3 43.3 3.1 5660 40.9 46.9 2.8 4950 40.4 46.0 2.7 8680 43.5 38.4 2.3 5580 37.6 47.5 2.6 9250 PACE: 1*3^216-2 A CHC-EDC REACTCR #3 1973 AVG. On-Stream Time * Top Pressure Dcv.'therm Temp.(From) Hrs. pcig F (Into) Reactor Temp. Catalyst Bottom Middle F F OF TEp F Vapor Space ^ Refrig. Cond. Outlet F FEEDS CcH^ Oo HC1 schf schf schf RECYCLE AK.UYSIS(Vol. %) _ <" CoHZt 02 Catalyst Charged % Lbs. JAM PPG'INDUSTRIES CHEMICAL DIVISION LAKE CHARLES*LOUISIANA FEB. MAR. APR. MAY 584 17.8 - 744 25.1 - -- JUNE 632 20.1 -- JULY 600 19.1 383 364 AUC. SEP. 690 20.8 389 369 720 15.8 395 374 OCT. 608 16.7 412 395 NOV. 480 21.3 385 363 1974 DEC. AVG. 712 20.4 381 361 5870 19.7 391 371 525 520 539 542 532 530 534 530 537 532 519 512 527 527 529 512 527 527 532 524 1 509 "513 498 487 ~5SS------ 3o5-- "52o 522 520 509 503 502 491 480 502 500 515 518 512 503 - - - 62 61 42 60 46 46 53 71500 92500 82200 81000 83400 73300 76100 6'95DT 88100 82000 41700 56300 52000 49900 50800 43100 43400 48400 50100 48400 153300 19550C 16790C 165300 170200 142900 15530C 165400 188000 167100 37.2 35.2 2.0 ll8 39.9 31.7 2.0 16531' 51.4 39.3 2.7 14818 47.6 "35"; 7 3.0. 8537 44.6 "3575 1.3 14985 48.2 38.8 3.0 6702 48.4 35.3 2.8 22560 50.2 32.0 2.7 30530 57.2 28.9 2.4 31620 47.2 34.7 2.4 15978 ' ' . ------ SL 013429 Tot.o ^ ofc Si ----------- f. ibject . 4fh 3 i.KnJllftirJI n a. .. Or nO *-- i'HTTAL it-pcti 1 ni fit 1-1145 . ve Ord rict C er ourt PAGE: i 216-3 OKC-EDC PLANT DATA 1973 AVG. Refrigerated Brine Temp. .'/a rm 0F Cold UF Chloral Treatment Feeds 51 50 Organic (gpm 30.5 Cell Liquor(gpm 3.6 Drying Still No. 1 Temp. Bottom F 183 Vacor Outlet UF 163 Press. Bottom psig 2.0 lights Still Feed (gpm 10.6 Reflux (gem 24.7 Temp. Bottom F 201 Overhead CF 164 JAN. 40 39 30.2 - 184 165 2.2 9.7 26.2 206 169 PPG INDUSTRIES CHEMICAL DIVISION LAKE CHARLES^ LOUISIANA OXYHYPROCHDCRINATION OPERATIONS FEB. MAR. APR. MAY JUNE JULY 39 42 38 38 - - 21.8 3.48 183 165 2.0 11.3 26.5 206 168 32.3 ` 4.41 185 - 2.5 11.4 26.6 204 167 31.2 4.97 , - - 13.5 25.5 - - ---- 48.5 55.1 5.38 , 5.18 - - 16.4 24.5 - - - 2.0 21.5 25.0 - - 59 58 35.6 4.96 102 97 2.6 12.2 18.6 204 178 AUG. SEP. OCT. NOV. DEC. 1974 AVG. 58 57 40.1 5.15 178 160 2.5 19.5 18.1 208 186 37 53 34 53 42 46 40 45 46 45 48.0 47.3 5.18 5.9 46.9 52.0 6.0 6.0 40.8 5.2 187 170 3.4 29.4 1W.T 209 184 185 184 165 162 2.9 1.1 2072-- 29.5 21.3 22.8 205 207 182 183 182 174 158 155 1.8 2.3 2570-- T577----2279-- 2T7I----2X2------ 267------T05------ 277------- 30? Steam Produced Lbs. 1164 1901 1048 1493 0 "o-------- 2855 1078 1239 2230 1667 2607 1427 1465 Electric rower (KNH/T EDCJ 108.2 .-.ell Via ter (N Gal/T EDC) 0.544 Natural Gas (KCF/T EDC) 0.000 Nitrogen (T/T EDC) 0.108 Catalyst (Lb./T EDC) 2.03 93.3 0.142 0.000 0.092 2.61 119.0 0.305 0.000 0.143 - 114.3 0.235 0.000 0.122 6.22 108.9 0.243 O'. 000 0.106 - 85.0 79.5 100.6 0.070 0.021 0.054 0.000 0.000 0.000 0.062 0.071 0.104 2.56 TIT 1.94 85.5 0.090 0.000 0.102 T.47" ' 82.2 0.060 0.000 0.080 1.42 95.3 0.070 0.066 0.107 4.41 81.8 0.046 0.000 0.106 5.35 73.1 86.8 0.066 0.117 0.000 0.000 0.086 0.098 2729-- 2731 Drying Still No. 2 Temp. Bottom Vapor Outlet Press. Bottom F F PSIG - '_-- 1.3 2.4 --2.9 2.8 - 190 188 183 - 173 166 168 2.3 3.07 3.1 1.9 189 189 170 169 1.8 1.7 188 169 2.3 _ SL 013430 r'nMP * nj?wr t l r * *- 4-, . ! fn i d * f. : f ir i i- Tnitrl- Mn r> ) 1 1 i r} PAGE'. 4 217-1 GENERAL DEPARTMENT No. of Catches Highest Reactor Temp. Avq. Avg. Time of Reaction F 1973 AVG. PPG IN!l,TR!ES CHEMICAL DIVISION LAKE CHARLES, LOUISIANA V1NYLIDENE CHLORIDE DEPARTMENT OPERATIONS REPORT JAN. FEB. MAR. APR. MAY JUNE JULY AUG. SEP. OCT. NOV. DEC. 1974 Avrv Reactor Feed Still Pressure Still Top Temp. Reboiter Steam Flow Reboiler Temp. Bottoms to VDC GPM PSIG 16.9 F 111 16.3 97 #/Hr, 704 F 136 560 132 Roto. % 40 36 15.8 15.9 94 98 20.7 19.6 104 114 20.0 122 21.3 117 16.1 17.5 134 120 470 480 ~63o 900 TTUT5-- 970 T35 1000 131 130 140 137 141 138 T3S-- 136 25 "25--------- 32 "35-------- 33 29 32 28 16.4 120 16.8 109 836 995 134 129 12-------- 26 18.4 105 822 127 27 17.9 111 792 134 30 MAN HOURS/TON Production Maintenance Supervision Total Contract Man Hours/T inc. Cl. 747 0.681 0.725 0.587 0.200 0.102 o.nnn 0.041 0.502 0.480 0.327 0.951 0.105 0.008 0.000 0.809 1.154 0.316 0.650 0.320 0.434 0.582 0.008 1.144 0.202 0.132 0.129 0.010 0.236 Production Shipped Tons/Day 18.2 22.1 19.3 22.1 Tons/Day 18.0 20.0 23.7 20.3 23.5 - 30.4 25.5 26.7 39.4 30.7 15.7 11.5 42.6 24.5 7.1 40.2 21.7 27.1 38.6 30.2 t 26.6 33.2 26.0 25.9 -I3FM____________________g,/Tnn VDCM ________________ #/Ton VDCM 2.2 2.9 6.8 -2.7 1.1 1.1 1.3 0.0 1.8 0.0 -0.2 O.'O 0.0 3.2 1.1 0.0 1.6 0.0 0.0 0.9 0.6 0.1 1.5 . SL 013431 _ _ _ _ _ _ _ _ _ _ L_ CON 7IDENT lAt.i Subjt tct to Prote ;t i vp Brdof C 14tl t Judi :ial D L s t rir f* [ *- No 9i-i .45 PrttiE- -x PPG INWSTRiES CHEMICAL DIVISION LAKE CHARLES,LOUISIANA GENERAL DEPARTMENT Total Received from: T/D EDC TCE EC VC P/T CONOCO Puerto Rican Tank TOTAL A^3 -- _ _ -- - - - JAN. 5.5 0.0 0.5 3.5 142.7 23.4 0.0 175.6 FEB. MAR. 5.1 0.0 0.5 7.9 152.0 22.1 2.8 190.4 9.5 0.0 0.5 8.4 122.6 20.5 52.4 213.9 APR. MAY 5.8 0.0 0.4 15.7 163.0 $5.2 14. a 224.9 5.6 0.0 1.1 17.0 130.7 21.0 10.9 186.3 JUNE 3.4 0.0 0.9 16.3 160.7 22.1 0.0 2(3.4 JULY 3.3 4.0 0.8 14.6 179.1 21.5 11.9 251.6 AUG. 3.0 0.0 0.6 14.5 151.9 24.0 6.1 211.2 SEP. OCT. 7.2 5.3 0.0 0.0 0.6 0.7 14.3 11.5 124.1 133.6 24.6 18.0 25.1' 35.0 224.1 227.9 NOV. 4.7 1.1 0.8 11.1 125.9 18.2 49.3 211.1 DEC. 1974 AVG. 7.0 no n Ft 9.7 126.2 16.5 6.9 195.6 5.4 nA n7 12.0 142.7 21.4 18.0 209.7 Transferred to P/T T/D - 137.0 202.5 190.3 193.1 156.9 174.6 218.2 128.3 179.4 L76.7 180.8 147.9 173.8 LOSS Tons - 322.2 659.0 731.5 805.0 99 7.. 7 701.8 695.1 1732.4 618.2 791.2 816.2 590.3 788.4 POT TEMPERATURES No. 1 Kettle No. 2 Kettle F _ OVERHEAD TEMPERATURES F No. 1 Kettle No. 2 Kettle - 329 319 325 323 326 325 330 307 324 322 320 312 328 313 321 280 305 297 297 291 300 294 301 279 308 302 298 292 296 296 304 290 YEILDS Cl 88.0 94.6 86.5 89.1 87.9 82.0 88.4 90.5 34.4 C 86.9 91.6 93.6 88.4 88.7 86.1 88.9 90.1 81.9 294 287 - 267 268 288 231 206 310 29 3 277 270 299 296 1 89.6 37.6 89.0 37.1 269 295 87.0 87.4 271 293 88.1 91.0 288 297 88.0 88.7 _ u13432 Sub7 J f 141 1 fVlk! r-i b*nrn iftt,:-- .Turl[ Mjr \ rf'6 -1 CJ`X--r >--- ------- i-'fi ve j stri r4~5------- Order" t C'OUJ t * Corrected Values PAGE: 9-1 GENERAL DEPARTMENT VENT FLOWS No. 1 EDC No. 2 EDC P/T OHC MCF/Day AVG. LIQUID FLOWS Cl LBS./Day EDC Waste Recovery MC EC VC NO. 1 INCINERATOR Waste Gas MCF/Day Natural Gas MCF/Dav Lake Water GPM Temperature Operating Hours* 0f HCl in Aqueous Sol. Tons JAM PPG\h STRIES chemical division LAKE CHARLES^ LOUISIANA INCINERATOR OPERATIONS REPORT FEB. MAR. APR. MAY JUNE JULY AUG. SEP. OCT. NOV. DEC. /// V AVG. 41.5 45.9 31.? 196-.2 178.2 172.2 1191.4 1455.0 1418.5 188.5 191.0 241.6 129.3 170.1 175.7 197.0 1256.8 1496.3 321.0 395.1 25.9 153.3 1257.5 288.5 15.4 241.0 1335.5 416.8 0.0 -o.o 167.0 236.7 1336.5 1178.4 451.2 307.8 0.0 4.2 212.2 221.8 1058.4 1260.1 279.2 357.1 42.2 195.6 1294.9 312.5 -- -- - - -_- 64689 -- - 53356 -- - - 84064 - 686G7 - - - 79750 - - 91144 - " '66573 I'75'32T -- --- - 97751 - - - 75705 - 194.2 922.0 235.1 213.0 702.9 685.4 0.0 266.9 574.9 772.9 266.0 646.8 18.0 317.0 433.1 75.2 229.8 453.0 0.0 323.0 481.2 o.o 0.0 223.0 247.1 402.8 501.4 584.9 1160.8 338.9 224.7 184.1 248.2 423.6 377.1 516.6 2045 2199 1083 2500 2461 554----- ^ 1058 2457 695 2508 1050 2470 2576 I ~nwr~ 1365 2507 736 1041 2490 2468 653 673 1162 801 2426 - 1003 NO. 2 INCINERATOR Waste Gas Natural Gas MCF/Dav MCF/Day Lake Water GPM Temperature Operating Hours* F HCl in Aqueous Sol. Tons _ SL 013433 Totals 1832.9 2090.7 2149.0 1308.4 2407.7 1985.6 2316.7 23194 1886.3 1160.0 960.4 178.8 225.4 109.2 131.6 192.3 229.9 225.9 221.0 229.0 215.6 315.6 569.7 595.3 601.6 543.0 516.8 411.9 511.8 525.7 700.1 453.5 395.1 1856.1 214.0 547.7 2469 2431 2518 2388 2500 2465 2490 2549 2509 - 734 2427 570 2458 744 2473 _ 2186 1763 2240 1270 1827 1296 1545 1750 1654 1080 704 1574 COI IF1DEN F1AL: --bUD_ --ti t Prot' ;ct ive order W--v it n--direr Cldl 1 listri It l'ou ------- u* 8 4-. 4-W----