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AR226-2340 Item 10: Monitoring - Fluoropolymers EPA Data Needs: (Draft 9-21-03) Data Need LOI Commitment Manufacturing Releases Data on releases to air, water, wastewater, landfill leachate Information on release of PFOA to air, water, wastewater, landfill leachate from manufacturing facilities Continued monitoring of releases Manufacturing Sites Concentration of PFOA in air, surface water, groundwater, soil, biota, wastewater, landfill leachate at manufacturing facilities Surface water, groundwater, wastewater, landfill leachate concentrations at manufacturing sites Limited biota data Modeling of PFOA in air Additional data needs beyond LOI .EPA Proposal to Address Data Needs Manufacturing none Monitored concentrations of PFOA in air, soil, additional biota Screening level monitoring of PFOA in air to quantif concentration and extent Screening level monitoring of PFOA in biota (eg. fish aquatic species, plants, herbivores, avian, terrestrial s manufacturing facilities Item. 10: Monitoring - Fluoropolymers EPA Data Needs: (Draft 9-21-03) Data Need Off Site from Manufacturing Concentration of PFOA in air, surface water, groundwater, soil, and biota down gradient from manufacturhg facilities LOI Commitment PFOA concentrations in surface water and groundwater from manufacturing sites Additional data needs beyond LOI Monitored concentrations of PFOA in air, soil, additional biota Limited biota data Modeling of air contamination EPA Proposal to Address Data Needs Monitoring of PFOA in air to quantify concentration and ex of off site contamination Additional groundwater monitoring, similar to Washington Works, to quantify PFOA in groundwater of&ite contamina at additional manufacturing sites, Groundwater samples s be collected to determine the extent and level of contamina away fro.rn.ttie ske Soil sampling for PFOA to quantify and determine axtent o site soil contamination Monitoring additional biota for PPOA (plants, herbivores, avian terrestrial species, fish and other aquatic species)nea manufacturing facilities Item 10: Monitoring - Fluoropolymers EPA Data Needs: (Draft 9-21-03) Data Need Use Releases Information on release ofPFOA to air, water, wastewater, sludge from use facilities LOI Commitment Composite information on process releases from user facilities representing different use industries Modeling of releases from user facilities (carpet initially) Additional data needs beyond LOI EPA Proposal to Address Data Needs Use Monitoring data on release of PFOA to air, water, wastewater, sludges from processing/use facilities Screening level monitoring studies to measure PPOA r to air, water, wastewater, and sludgesat representative sites. Number of sites should be sufficient to allow prelimina assessment of releases associated with different use ind Monitoring should be sufficient to provide baseline dat allow quantification reduction in environmental release time. For industries that are clustered fewer sites sho needed. -3- Data Need LOI Commitment Use Sites Concentration of PFOA in air, surface water, groundwater, soil, biota wastewater, landfill leachate at processing/use facilities Modeling of air, soil, groundwater concentrations Off Site from Use Concentration of PFOA in air, surface water, groundwater, soil, and biota down gradient from use facilities Modeling of air, soil, groundwater concentrations Item 10: Monitoring- Fluoropolymers EPAData Needs; (Draft 9-21-03) Additional data needs beyond LOI Measured concentrations of PFOA in air, surface water, groundwater, wastewater, soil, sludges biota at use facilities EPA Proposal to Address Data Needs Screening level monitoring studies at facilities representative different user industries. Initially 5-10 "Worse case" sites associated with each use industry should be selected for monitoring similar to that do at manufacturing facilities. Monitoring should be designed provide scoping baseline data to inform future site selection needed, and to allow qualification efforts to reduce releases. Number of sites and locations dependant on information abo number and location of user facilities Monitoring data should be collected sufficient for screening level characterization of PFOA concentrations in environme media at the site and released from the site. Screening level study design is site/industry dependant, but may include: 5-1 surface water samples upstream, at the site, and downstream 20 wells with quarterly groundwater sampling, 5-10 air sam monthly wastewater sampling, quarterly sludgesampling if discharges go to POTW, 20-50 soil samples, 20-50 biota samples Measured concentrations in air, surface water, groundwater, wastewater, soil, sludges, biota down gradient from use facilities Surface water, groundwater wastewater, air, soil, biota (plan herbivores, avian terrestrial species) monitoring studies arou use facilities Data to characterize environmental concentration away from site and to identify limit of environmental contamination Wastewater and sludges from POTWs receiving discharge user facilities should be included -4-