Document zxkYdnLGx2Q9qYrvO9mayLKz

Material Safety gpData Sheet (cqTM>>) Emergency Medical Telephone (800) 441-3637 SOUR CONDENSATE o^ 3/3] I. MATERIAL IDENTIFICATION Name Sour Condensate CAS Registry Number Mixture; See Section XI Synonyms Casinghead Gasoline, Natural Gasoline Product Code _ 0541 - 20-H Chemical Family Petroleum Hydrocarbons Transportation Emergency Phone l-(800) 424-9300 (Chemtrec) IL OSHA HAZARD DETERMINATION The material is hazardous as defined by OSHA's Hazard Communication Standard, 29 CFR 1910.1200. Refer to Section XI of this MSDS for federal and state regulatory information. Hazardous Ingredients Hydrocarbons (Aromatic & Paraffinic) Benzene Hydrogen Sulfide CAS Registry Number Mixture 71-43-2 7783-06-4 Concentration > 50% 0.1-1 wt. % 1-10% Hazardous Physical Properties Class IA Flammable Liquid - NFPA 30-1987. III. PHYSICAL DATA Appearance and Odor Dark liquid; Sulfur odor Specific Gravity (HaO = 1) 0.8 Bolling Point/Range 80* - 700F % Volatiles (by volume) Variable Vapor Pressure (mmHg), <8*F 200 - 500 Solubility In Water Insoluble Vapor Density (Air 1.0) >1 IV. REACTIVITY DATA Stable; X Unstable: Hazardous Decomposition Materials: Carbon monoxide and oxides of sulfur may be formed. Conditions to Avoid: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. GASC0066/March 1989 1 Conoco Inc., P.O. Box 2197, Houston, TX 77252 General Information No. (713) 293-5550 MCD 000023360 V. FIRE AND EXPLOSION HAZARD DATA IJELa X UELi 10 Flash Point (Method used): -S0F (PMCQ Handle and store in accordance with NFPA procedure for Class IA Flammable Liquid. Extinguishing Media: Use dry chemical, C02, foam. Special Fire Fighting Procedures: Water may be ineffective to extinguish, but water should be used to keep fire-exposed containers cool. If a leak or spill has not ignited, use water spray to disperse the vapors and to protect personnel attempting to stop a leak. Water spray may be used to flush spills away from areas of potential ignition. Unusual Fire and Explosion Hazards: Highly flammable. Products of combustion may contain carbon monoxide, carbon dioxide and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Association (NFPA) Classification Health 1 Fire 3 Reactivity Q VI. TRANSPORTATION AND STORAGE HAZARD RATING Least-0 Slight-1 Moderate-2 High-3 Extreme-4 Storage Conditions: Store in accordance with National Fire Protection Association regulations. Shipping Information: DOT: Proper Shipping Name: Gasoline Hazard Class: Flammable Liquid UN/NA No^ UN 1203 DOT Label(s): Flammable Liquid DOT Placard: Flammable lATA/IMCh Proper Shipping Name: Natural Gasoline Hazard Class: 3 (IMO 3.1) UN Noj UN 1257 IMO/ICAO Label: Flammable Liquid Packaging Group: II VII. HEALTH HAZARD INFORMATION Exposure Limits for Sour Condensate PEL: None Established TLV: None Established Exposure Limits for Petroleum Distillates PEL: 400 ppm: 1600 my/m3 TWA Exposure Limits foe Benzene PED 1 ppm - 8 Hr. TWA 5 ppm - (Short-Term Exposure Limits 0.S ppm - Action Level TLV: 10 ppm. 30 mg/m3 Du Pont AEL: 1 ppm - 8 & 12 Hr. TWA 5 ppm - 15 Min. TWA Exposure Limits for Hydrogen Sulfide PEL: 10 ppm. 14 mg/m3 STEL 15 ppm. 21 me/m3 Du Pont AEL: 10 ppm - 8 A 12 Hr. TWA TLV: 10 opm. 14 mg/m3 STEL 15 own. 21 me/m3 GASC0066/March 1989 2 MCD 000023361 VIII. Primary Routes of Exposure/Entry; Skin, Inhalation. Sign* and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: A few studies have indicated that workers exposed many years to high concentrations of benzene have a slightly higher incidence of leukemia. Benzene can also be toxic to the blood and blood-forming tissues. Studies with mice or rats have shown that some petroleum distillates have caused either damage or tumors of the kidneys or tumors of the liver. However, kidney effects were not seen in similar studies involving guinea pigs, dogs or monkeys. Also, the significance of the liver tumors in rodents is highly speculative. Mouse skin painting studies have shown that petroleum middle distillates (boiling range of 100-700F; naphtha, jet fuel, diesel fuel, kerosene, etc.) can cause skin cancer when repeatedly applied and never washed from the animal's skin. The relative significance of this to human health is uncertain since the petroleum distillates were not washed from the skin and resulting skin effects (irritation, cell damage, etc.) may play a role in the tumorigenic response. A few studies have shown that washing the animal's skin with soap and water between treatments greatly reduces the carcinogenic effect of some petroleum oils. The product contains petroleum hydrocarbons which may cause irritation to the eyes, lungs and skin after prolonged or repeated exposure. Extreme exposure or aspiration into the lungs may cause pneumonia. Overexposure may cause weakness, headache, nausea, confusion, blurred vision, drowsiness and other nervous system effects; greater exposure may cause dizziness, slurred speech, flushed face, unconsciousness or convulsions. Hydrogen sulfide can be irritating at low concentrations to the eyes, skin and lunjp. At higher concentrations, loss of ability to smell hydrogen sulfide, respiratory paralysis and death may occur. Listed as Carcinogen or Potential Carcinogen by: NTP Benzene Yes IARC Category 1 OSHA Yes EMERGENCY AND FIRST AID INFORMATION Eyes: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Call a physician. Skin: In case of contact, immediately wash skin with soap and plenty of water. If irritation develops, consult a physician. Inhalation: Because hydrogen sulfide can cause death, rescuers must wear positive pressure full facepiece, self-contained or supplied-air NIOSH-approved respirators before attempting the rescue, if hydrogen sulfide is present Remove victim to fresh air immediately. If breathing stops, begin artificial resuscitation. Keep victim warm and at rest Seek medical attention. Ingestion: If swallowed, do not induce vomiting. Give large quantities of water. Never give anything by mouth to an unconscious person. Call a physician. Notes to Physician: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. GASC0066/March 1989 3 MCD 000023362 IX. SPILL, LEAK AND DISPOSAL INFORMATION In Case of SpUl or Leak: All sparks, flames and ignition sources must be restricted from the area. Contain spill immediately in smallest possible area. Recover as much of the product as possible by such methods as vacuuming, followed by recovering residual fluids by using absorbent materials. Nonrecoverable product, contaminated soil, debris and other materials should be placed in proper containers for ultimate disposal Avoid washing, draining or directing material to storm or sanitary sewers. NOTE: Review FIRE AND EXPLOSION HAZARDS before proceeding with clean up. Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clean up. Waste Disposal Method: Recycle as much of the recoverable product as possible. Treatment, storage, transportation and disposal must be in accordance with applicable Federal, State/Provincial, and Local regulations. X. PRECAUTIONARY MEASURES Respiratory Protection: Select appropriate NIOSH-approved respiratory protection where necessary to maintain exposures below the acceptable limits in Section VIL Proper respirator selection should be determined by adequately trained personnel and based on the contaminants), the degree of potential exposure and published respiratory protection factors. Ventilation: General mechanical ventilation normally adequate but use local exhaust where necessary to maintain exposures below acceptable limits. Protective Gloves: Should be worn when any potential exists for sldn contact NBR or neoprene recommended. Eye Protection: Goggles or face shield for spray/mists or if splashing is probable. Other Protective Equipment: Coveralls with long sleeves if splashing is probable. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. Safety Precautions: Do not breathe vapor or mist Avoid contact with eyes, skin, or clothing. XI. REGULATORY INFORMATION FEDERAL REGULATIONS CERCLA, 40 CFR 261 and 302 The material contains the following hazardous substance which, when released in quantities equal to or exceeding the Reportable Quantity, triggers National Response Center notification requirements. Hazardous Substance Not Applicable Reportable Quantity SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986, TITLE in SECTIONS 302, 304, 311, 312, 313 SECTION 302/304 - Extremely Hazardous Substances (40 CFR 355) The material contains extremely hazardous substances at greater than 1.0% concentration as listed below; it Is possible that this material may contain other extremely hazardous substances at a lover concentration. Extremely Hazardous Substances: Hydrogen Sulfide Threshold Planning Quantity: 500 lbs of H2S Reportable Quantity: 100 lbs of HjS Concentration: 140% GASC0066/March 1989 4 000023363 MCD SECTION 311/312 - MSDS and Chemical Inventory Reporting Requirements (40 CFR 370) The materia] should be reported under the following EPA hazard categories: x Immediate (Acute) Health Hazard x Delayed (Chronic) Health Hazard x Fire __ Sudden Release of Pressure __ Reactive __ Not Applicable NOTE: See Section II for the concentration of any ingredients classified as hazardous by OSHA SECTION 313 - Ust of Toxic Chemicals (40 CFR 372) The material contains the following chemical(s) at a level of 1.0% or greater (0.1% for carcinogens) on the list of Toxic Chemicals and is subject to toxic chemical release reporting requirements. Toxic Chemical Benzene CAS Registry Number 71-43-2 Approx. Concentration (Upper Bound) 1% TOXIC SUBSTANCES CONTROL ACT (TSCA), 40 CFR 710 This material is a mixture as defined by TSCA The chemical ingredients in this material are in Section 8(b) Chemical Substance Inventory and/or are otherwise in compliance with TSCA In the case of ingredients obtained from other manufacturers, Conoco relies on the assurance of responsible third parties in providing this statement RESOURCE CONSERVATION AND RECOVERY ACT (RCRA), 40 CFR 261, SUBPART C AND D The material, when discarded or disposed of, is not specifically listed as a hazardous waste in Federal regulations; however, it could be considered hazardous if it meets criteria for being toxic, coitosive, ignitable or reactive according to U.S. EPA definitions (40 CFR 261). Additionally, it could be designated as hazardous according to state regulations. This material could also become a hazardous waste if it is mixed with or comes in contact with a listed hazardous waste. If such contact or mixing occurs, check 40 CFR 261 to determine whether it is a hazardous waste. If it is a hazardous waste, Regulations 40 CFR 262, 263, 264 and 268 may apply. FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 401.15, 40 CFR 116 The material contains the following ingredients) which is considered hazardous if spilled in navigable waters. Ingredient Petroleum Hydrocarbon Reportable Quantity Film or sheen upon or discoloration of the water surface or adjoining shoreline HAZARDOUS MATERIALS TRANSPORTATION ACT, 49 CFR 172 The material contains the following ingredients) which is considered hazardous if spilled while being transported in commerce. Ingredient Not Applicable Reportable Quantity FOREIGN REGULATIONS CANADIAN HAZARDOUS PRODUCTS ACT (WHMIS) The material is a WHMIS Controlled Product and a Canadian MSDS is available. GASC0066/March 1989 5 MCD 000023364 STATE REGULATIONS CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986 ("PROPOSITION 65") The material contains ingredients) known to the State of California to cause cancer, birth defects or other reproductive harm. Read and follow label directions and use care when handling or using all petroleum products. Ingredient Benzene PENNSYLVANIA WORKER AND COMMUNITY RIGHT TO KNOW ACT To the best of our knowledge the material is not sold or produced in Pennsylvania. Please notify us at the telephone number noted below if the material results in Pennsylvania commerce. MSDS Code: GASC0066 DATE OF LATEST REVISION/REVIEW: DEPARTMENT RESPONSIBLE FOR MSDS: PRODUCT INFORMATION CONTACT: 3/89 - Replaces MSDS dated 12/88 Environmental and Occupational Health Services MSDS Analyst Conoco Inc. (713) 293-5550 The above data are based on tests, experience, and other information which Conoco believes reliable and are supplied for informational purposes only. However, some ingredients may have been purchased or obtained from third-party manufacturers. In these instances, Conoco, in good faith relies on information provided by those third parties. Since conditions of use are outside our control, CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA. NOTHING CONTAINED HEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF NffiRCHANTABIUTY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE MATERIAL DESCRIBED, OR ITS USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. GASC0066/March 1989 6 Cconoco) MCD 000023365