Document zo1gqVqxrQpwKeOn2w7kR9pJ0

Uriel* Precautionary Labeling of Hazardous Chemicals Wished b* MMitacturlK MM nwMrtinil Ihih II ffasbingtoa MONS 095678 IMPORTANT Mail th Record Card Now When you receive Monual 1-1, please All Out and moil (ho post cord provided below. A rocord of holders will moke potiiblo tho corroct distribution of supplements or notices, if any, which may bo issued boforo tho next edition ii printed. MANUFACTURING CHEMISTS' ASSOCIATION, INCT 825 Connecticut Avenue, N. W. WASHINGTON 9, 0. C. For your future reference, record here the name and address you have given below. Date............................................................................. MANUFACTURING CHEMISTS' ASSOCIATION, INC. 1825 Connecticut Avenue, N. W. WASHINGTON 9, D. C. Gentlemen: I have a copy of the MCA Manual L-1, "Guide to Precautionary Labeling of Hazordouc Chemical*"--Sixth Edition--1961. Please tend me any supple* mentt Or notice* relating thereto. I should like to be advised when o new edition is printed. Name................................................................................................... j Address................................................................................................ I I ................................................................................................ i Company.............................................................................................. 1 I MQNS 095679 PLEASE MAIL RECORD CARD NOW STAMP HIRE MANUFACTURING CHEMISTS' ASSOCIATION, INC. 1823 CONNECTICUT AVENUE, N. W. WASHINGTON 9, D. C. HONS 095680 GUIDE TO PRECAUTIONARY LABELING OF HAZARDOUS CHEMICALS MANUAL L-1 Sixth Edition - 1961 MICIj M.00 PwbMsfod by MANUFACTURING CHEMISTS' ASSOCIATION, INC. IMS CONNfCTICUT AVINUI, H. W,, WASHtNGTON 9, D. C. The information, recommendations, and illustrative labels contained in Manual L I have been compiled from sources believed to be reliable and to represent the best current opinion on the subject No warranty, guarantee, or representation is made by the Association as to the abao* lute correctness or sufficiency of any information, recommendation, or illustrative labels herein, and the Manufacturing Chemists' Association, Inc, assume* no responsibility in connection therewith; nor can it be assumed that all necessary warnings and precautionary measures are contained in this Guide, or that other or additional measures may not be required under particular or exceptional conditions or circumstances. Copyright 1545. 1946. 1949, 1953, 1956. 1961 by Manufacturing Chemists' Association. Inc. ADOPTED ...................... .......1945 REVISED 1946 SECONO REVISION 1949 THIRD REVISION 1953 FOURTH REVISION..... ......1956 FIFTH REVISION......... ... 1961 (SIXTH EDITION) 095682 MQNS Contents rA.ce MCA Precautionary Labeling Activity--A Review .............................. 5 introduction ............... 7 Definition* ......................................................... 9 PARTI Proportion of Proavtfonory Ubois General Principle* ................................................................................. 1 2 Preparation of label* ........................................................................... 13 Exomple of lobe! Preparation ............................................................. 16 Toble I Selection of Precautionary Statement* ................................20*21 label* for Small Commercial Package*................................................ 22 label* for Samples and for New Product* for Investigational Use. .. 23 Container Handling and Storag* ....................................................... 24 PART II lltaitntltr* UMi for Knirfoii Chtmiuls Preface .................................................................................................. 29 Product labels ........................................................................................ 30 MCA Chemical Safety Data Sheet* .................................................... 95 PART III IlhutrMira UMs for Ptstfddtf Preface ................................................................................................... 97 Product label* ......................................................................................... 100 3 HONS 095663 MCA PRECAUTIONARY LABELING ACTIVITY A Review Accidental experience and willful experiment led man early to recognize the hazards which typify some substances. In 1450. Scotland enacted one of the first statutes governing product hazard. The Court Apothecary then ruled "that all persons are forbidden under the pain of treason to bring home poisons for any use by which Christian man or woman can lake harm." From such beginnings came today's laws and regulations covering the identification of hazardous substances. One of the earliest United States statutes in the chemical field was the Federal Caustic Poison Act ll927i. It covered twelve caustic or corrosive substances in certain concentrations, in containers "suitable for household use." Interpretation and enforcement was by the Food and Drug Administration. In its simplest terms, packages of the speci fied materials were required by law to carry labels containing the word "POISON" in particular type size along with an "antidote" statement. The year 1932 saw the introduction into Congress of a Volatile Poisons Bill. A first draft contained a general definition of Hazardous materials. A subsequent one followed the earlier plan of listing specific chemicals. The second draft authorized the Surgeon General to enlarge the list after investigation. While these bills did not become law, they marked a sharp acceleration in the evolution of precautionary labeling and its recognition by statutory requirement in the United States. With this came renewed awareness of responsibility by producers and by industry groups such as the Manufacturing Chemists' Association, Inc. From such group activity came the Chemical Products Agreement Committee appointed by the S eon General. The work of this group evolved the voluntary "Surgeon General's Agreements" entered into by the U.S. chemical industry in 1934*35. The texts of the precautionary labels to be used on specific products were agreed upon and made a part of executed agreements. These continued in effect and were honored by industry until 1952. The Surgeon General then agreed to their replace ment by broader and more widely applicable practices formulated through the continued work of MCA and its Labels and Precautionary Information Committee. The Manufacturing Chemists' Association. Inc., and its members, had early recognised the place of precautionary labeling in relations both with its customers and with state and federal governments. There were 5 HONS 095684 numerous strong reasons {or taking the initiative in this phase of chemical marketing. The industry had an outstanding safety record in its manufacturing units. The Association believed this safety record could be projected to the plants and homes of its customers to their mutual benefit. There was always the shadow of litigation that faces any producer as the result of real or fancied injury by a product. Chemical manufacturer* had already seen the possible alternative of federal and state legislation which might or might not be wisely framed. MCA chose the path of self-correction. In 1944 it convened a confer ence on a chemical precautionary labeling code. Attended by over ninety member representatives, it resulted in the formation of the Labels and Precautionary Information Committee of the Association. This committee continues as the group longest setive in this endeavor. One of its earliest concerns was the compilation of a manual on precau tionary labeling practices for chemicals. First issued in March 1945. Manual L-l of the MCA LAP! Committee has become a widely recognised text on this subject. 6 MGNS 0956Q5 MANUAL L-I PRECAUTIONARY LABELING OF HAZARDOUS CHEMICALS Introduction Many products present no hazard in normal handling and storage. For these product, no precautionary statements are necessary on the label. The development of new chemical products, and the introduction of chemical processes into ever-widening fields, have accentuated the need for furnishing appropriate information in those cases where there are hazards requiring special precautions. Precautionary information should, so far as is practicable, reach every person using, handling, or storing hazardous substances. The most practical means of disseminating this information appears to he hy precautionary labels, affixed to containers of hazardous sub stances, bearing appropriate precautionary statements expressed as simply and briefly as possible. Such label information, however, cannot take the place of the education of personnel regarding product hazards and the use of safety clothing and equipment. This education is, and must remain, the direct responsibility of their employers. The wording on precautionary labels cannot be expected to cover complete information as to the properties of a material nor the complete details of its proper handling under all conditions. Such information may be found in the producers' technical bulletins or in the Manufacturing Chemists' Association's Chemical Safety Data Sheets. To achieve uniform and adequate labeling of hazardous substances, the Labels and Precautionary Information (LAPI) Committee of the Manufacturing Chemists' Association, Inc. (MCA) offers Manual LI MQNS 095686 7 as a guide in preparing precautionary label texta. Part I seta forth general principles. Part II presents precautionary texts selected to illustrate the application of these principles to the major types of hasards encountered. Part III presents precautionary texts illustrating the labeling of a group of substances used in the pesticide (economic poison) held. The labeling of radio-active materials is a complex problem outside the scope of this Guide. In preparing precautionary labels for such materials, it ia suggested that reference be made to the series of hand books published by the United States Department of Commerce, National Bureau of Standards, covering the safe handling of radio active materials. The Surgeon General of the United States Public Health Service has discontinued the labeling agreements entered into some years ago with the manufacturers of a few specific chemicals. This was done be cause today adequate precautionary labels are in general use by the producers. The United States Public Health Service has approved the principles of precautionary labeling developed by MCA and continues its interest in this field in cooperation with the Association. It ia felt that cooperation on the present broad basis will best serve the purpose intended when the earlier more specific agreements were made. This Guide will be found extremely useful in tho prepare* tion of precautionary text for any hazardous chemical oven though tho Genera/ Pr/nc/p/es and illustrative texts wore designed originally for hazardous chemicals Intended for industrial users. The precautionary texts at presented in this Guide should be used in addition to, or in combination with any specific wording re* quired by law. Since individual statutes, regulations, or ordi nances may require that particular information be included in a label, that certain information be displayed in a particular man ner, or that a specific label be affixed to a container, the use of the Genera/ Pr/nc/p/es or the illustrative texts in this Guide will net necessarily insure compliance with such laws. The specific re quirementi of each such law and regulations issued thereunder must be observed in order to insure compliance. Such laws include the Federal Hazardous Substances Labeling Act and similar state and municipal legislation; the Federal Insecticide, Fungicide, and Radenticide Act and similar stata legislation; Interstate Commerce Commission Regulations for Transportation of Explosives and Other Dangerous Articles; and others. 8 HONS 09568 7 DEFINITIONS Laws making precautionary labeling mandatory mark (he evolution of labeling from its earliest beginnings. Complementary to the develop ment of sueh codes has been the definition of terms used in specifying such labeling. This part of the development has received extensive study by the MCA Labels and Precautionary Information Committee. This has resulted in the following definitions encompassing the modes in which substances are hazardous and the types of materials which exhibit such behavior. Combustible liquid--Any liquid which gives off flammable vapors, above 80F. to and including 150F., as determined by flash point with Tagliabue's Open-Cup Method as used for testing of burning nils. Corrosive (Physiological)--A substance which in contact with living tissue causes destruction of the tissue by chemical action. This term shall not refer to action on inanimate surfaces. Dust--Solid particles generated by handling, crushing, grinding, rapid impact, detonation, or decrepitation of organic or inorganic materials such as rock, ore, metal, coal, wood, grain, etc. Dusts do not diffuse in air but settle under the influence of gravity. economic Poison (PosHcldo)--(1) Any substance or mixture of sub* stances intended for preventing, destroying, repelling, or mitigating any insects, rodents, nematodes, fungi, weeds, or other forms of plant or animal life or viruses, except viruses on or in living man or other animals, and 12 > any substance or mixture of substances intended for use as a plant regulator, defoliant or desiccant. Ixtromoly Flammable liquid--Any liquid which gives off flammable vapors, at or below a temperature of 20'3F., as determined by flash point with Tagliabue's Open-Cup Method as used for testing of burning oils. Plammobla liquid--Any liquid which gives off flammable vapors, above 20F. to and including 809F.. as determined by flash point with Tagliabue's Open-Cup Method as used for testing of burning oils. Puma--Solid particles generated by condensation from the gaseous state, generally after volatilization from molten metals, etc., and often accompanied by a chemical reaction such as oxidation. Fumes floccu late and sometimes coalesce. 9 HONS 095688 Oa*--A normally formless fluid which occupies the space of enclosure and which can be changed to the liquid or solid state by the effect of increased pressure or decreased temperature or both. A gas diffuses. Hazardous Substance--Any substance or mixture of substances which is (ll toxic: <2) corrosive: (3) an irritant: i4 a strong sensitizer; toi flammable, or which 161 generates pressure through decomposition, heat, or other means, if such substance or mixture of substances may cause substantial persona) injury or substantia) illness during or as a direct result of any customary or reasonably anticipated handling or use. Irritant (Physiological)--An\ substance which on immediate, prolonged, or repeated contact with normal living tissue will induce a local inflam matory reaction. Mist--Suspended liquid droplets generated bv condensation from the gaseous to the liquid state or by breaking up a liquid into a dispersed state, such as bv splashing, foaming, or atomizing, Mixture--A physical commingling of two or more substances which may or may not bear a fixed proportion to one another and which have not reacted chemically with one another. . Oxidizing Material--A substance that yields oxygen readily to stimu late the combustion of organic matter. Pesticide--Same as Economic Poison Poison--'Any substance or mixture of substances which falls within any of the following categories: (ll Produces death within 14 days in half or more than half of a group of 10 or more laboratory white rats each weighing between 200 and 300 grams, at a single dose of 50 milligrams or less per kilogram of body weight, when orally administered: or < 21 produces death within 14 days in half or more than half of a group of 10 or more laboratory white rats each weighing between 200 and 300 grams, when inhaled continuously for a period of one hour or less at an atmospheric con* rentration of 200 parts per million or less by volume of gas or vapor or 2 milligrams or less per liter of mist, fume or dust, provided such con* centration is likely to be encountered by man when the substances are used in any reaionabiy foreseeable manner: or <3i produces death within 14 days in half or more than half of a group of 10 or more 10 MONS 095689 rabbit* tested in a dosage of 200 milligrams or less per kilogram ot body weight, when administered by continuous contact with the hare skin for 24 hours or less. If available data on human experience with any substance in the above-named concentrations indicate results different from those obtainod on animals, the human data shall tofte precedence in any classification of a substance as poisonous. Sensititer--A *ubstan<r which will cause on normal living tissue through an allergic or photodynamic process a hyper-sensitivitv which becomes evident on reapplication of the same substance. Toxic Substonce--A substance which has the inherent rapacity to pro duce personal injury or illness to man through ingestion, inhalation, or absorption through any body surface. Vapor--The gaseous form of a substance which is normally in the solid or liquid state. A v apor diffuses. MQNS 095690 11 PART I Preparation of Precautionary Labels General Principles The following Generol Principle* serve as a guide in the prepara* lion of precautionary labels for hazardous substances. (1) Each hazardous substance presents s distinct problem and must be treated individually in the light of its own characteristics. Conclu sions regarding the hazards of a product cannot safely be drawn either from the properties of the materials from which it is formed or by analogies based upon chemical structure. Mixtures of two or more chemicals may have properties that vary in kind or degree from those of the individual components. Any precautionary label for mixtures should be based on the prop, erties of the finished product. Impurities may contribute hazardous properties and should not b overlooked. (2) All statements on precautionary labels should be brief, accurate, and expressed in simple, easily understood terms. (3) Precautionary labeling should be used only when and to the extent necessary. The language should be practical, not based alone upon the inherent properties of a product, but directed toward the avoid* ance of hazards resulting from such use, handling, and storage as may reasonably be anticipated. The uae of precautionary labels for relatively harmless products, or the use of unnecessary words, will develop a disregard for labels and defeat their purpose as surely as will failure to give adequate notice of hazards. (4) On labels for different products, uniformity in language to indicate the same hazards and same degree of hazard is most desirable in order to gain greater understanding through standardization. (5) The following subject matter should be considered for inclusion on a precautionary label: A. Name of Produet. B. Signal Word designating degree of hazard--DANGfRI, WARNINOI, or CAUTION) 12 MOWS 095691 C. Affirmative Statement of Hazard*. D. Precautionary Measure* covering actions to be followed or avoided. E. instructions in Case of Contact or exposure, where ad visable. (Note: Under tome law* antidote* or first aid procedures are required when the word "POISON" is used. 1 Instructions for the handling and storage of containers should also be considered for inclusion on the label. This is information relating to characteristics of the container as well as those of its contents, and is discussed separately under Container Handling and Storage on Page 24. (6) The inclusion of the word "POISON" and the skull and crossbones on a label should be limited to those cases where the product is a poison according to the definition appearing on Page 10, or where such use it prescribed by law. When used, this legend should be in addition to the other label warnings and should not take the place of the Signal Words DANGER!, WARNING!, and CAUTIONI which are designed to show the relative degree of hazard. (7) A non*dencriptive code designation or trade name should not be used as the only identification of a hazardous substance. If the complete chemical name is not shown, the label should clearly state the type of chemical, e.g., "corrosive add", "load compound". (8) Precautionary statements should be grouped together in a prominent location on the label and should be printed in easily legible type which is in contrast by typography, layout, or color with other printed mutter on the label. The label should be affixed firmly to and in a conspicuous place on the container. Preparation of Labels In the preparation of a precautionary label, the compilation of all available relevant information on the product is a necessary first step. An adequate knowledge of the toxicity of the material (obtained from the literature or through laboratory tests) and data on physical and chemical properties, packaging, and methods of handling and use of the product are needed to make possible a description of the hazards. In the case of an established product, advantage should be taken of the experience of people involved in manufacturing, shipping, and using HONS 095692 13 the materiel. All the General Principles should be kept in mind end the following information considered for inclusion on the label: A. Name el Product This is important information for the safety of handlers and users, it is preferable that the chemical name of the product be used. The recommendations of the American Chemical Society for nomenclature should be followed. Trade names may be used in addition to chemical names. A non-descriptive code designa tion or trade name should not be used as the only identification of a hasardous chemical. If the complete chemical name is not shown, the label should at least clearly state the type of chemical, e g., "corro sive oeld", "load compound". B. Signal Word This word is intended to draw attention to the pres ence of hazard, and to indicate the degree of severity. The Signal Words recommended are, in the order of diminishing severity of hazard: (1) DANGER) (2) WARNING! (3) CAUTION! Degree of severity can be expressed only in relative terms. "DANGER!" is the strongest of (he three words and should be used for those products presenting the most serious hazards. "CAUTION)" is recommended for those compounds presenting the least serious hazards. "WARNING!" is intermediate between "DANGER!" and "CAUTION!" Reference to the illustrative labels in Part I! of this Guide will help in the selection of the proper Signal Word. C. Statement of Hazards This statement should give notice of the hazards that are present in connection with the customary or reasonably anticipated handling or use of the product. Examples are: CAUSES RURNS VAPOR EXTREMELY HAZARDOUS Many chemical products will present more than one type of hazard, in which case, appropriate statements for each significant type should be included on the label. In general, the most serious hazard should be stated first. While any compound may be hazardous if improperly used, it is impractical to cover every possible contingency on a label. Efforts should be directed toward giving notice of the significant hazards. A minor hazard may frequently be covered clearly and briefly by an appropriate precautionary statement alone. In some cases, the totsl hazard of a product, while justifying one or more Precautionary Meas 14 HONS 095693 ures, may be of such order as to require no Statement of Hazard on the label. 0. Precautionary Measures These instructions are intended to sup plement the Statement of Hazards by setting forth briefly measures to be taken to avoid injury or damage from stated hazards. Examples are: Keep away from Heat, sparks, and open Pome. Avoid breathing dust. Precautionary Measures may be included for hazards not considered of sufficient importance to require mention in the Statement of Hazards. Statements similar to, "Do net take internally," deserve special attention. They are seldom necessary where the Precautionary Measure to be followed is obvious as, for example, when the product is labeled "POISON" or the Statement of Hazards contains the words, "MAY BE FATAL IP SWALLOWED". On the other hand, the instruction may be desirable if the name, appearance, use, or other attributes of the chemical arc likely to result in its being taken orally through accident or mistaken identity. E. Instructions in Cato of Contact or Expoturo The primary pur pose of precautionary labeling is to prevont injury or damage. How ever, Instructions in Case of Contact or Exposure may be included in those instances where the results of contact or exposure are severe and immediate treatment is highly desirable, and where simple remedial measures may be taken safely by non-professional persons before medical assistance is available. Instructions should be limited to recognized first aid procedures based on simple methods and commonly available materials. Instruc tions for strictly medical treatment should be omitted except when specifically required by law or indicated by special circumstances. Because of the serious and lasting effects that may result from eye injuries, a recommendation to get medical attention should accompany any specific instructions directed to treatment of the eyes. In certain instances, simple remedial measures such as washing, or removal of clothing, may be included where they will serve to avoid serious injury following contact or exposure. All precautionary information should appear on (he label as a unit and should be printed in the order given above. The labels in Parts If ami Ili illustrate suitable arrangements and indicate the relative promt- 15 MONS 095694 ncnce that should be given to the individual statements. Such relative prominence may be achieved in a number of ways such as by variation in type size, color, or layout of the printed material. Not*: Some state laws and regulations require, on labels, the use of special or strictly defined antidotes or prescribe special ways in which these must be shown for certain hazardous substances. The require* ments for any given poison may. therefore, vary greatly, and the impossi bility of showing, in the illustrative labels, antidotes which might be nationally acceptable has led to the practice of indicating only the need for an appropriate first aid or antidote statement where the "POISONskult and crossbonas" legend is used. Table I, on Pages 20 and 21. is intended as a guttle in the selection of precautionary statements for labels. Listed are classifications of mate rials according to the hazardous properties most frequently encountered. Opposite each classification are given Statements of Hazard, Precaution ary Measures and. in most cases. Instructions in Case of Contact or Exposure, it is important to recognize that hazardous substances can have inherent in them more than one of such hazardous properties, and that the label wording for such products should include an appropriate combination of the pertinent statements. As each hazardous substance must be treated individually in the light of its own characteristics and customary or reasonably anticipated handling or use, there will be many instances in which the illustrative statements in Table l will not be applicable, either because they do not accurately express the degree of hazard or because they fail to cover the particular characteristics. In such cases, suitable statements should be chosen to fit the situation. The illustrative labels in Part II of this Guide may be helpful in the choice of appropriate wording, EXAMPLE OF LABEL PREPARATION To give as complete an illustration as possible of the procedure to be used in writing a precautionary label. Ethylene Chlorohydrin has been selected. A study of available physical, chemical, and toxicological data shows that this chemical presents several hazards for consideration, it is a poison, as defined in this Guide, by skin absorption and is dangerously toxic by ora] ingestion and by vapor inhalation. On con tact It can cause serious damage to the eyes. There is a hazard of combustibility since the flashpoint of the liquid is 140 F., which is within th range of combustibility in Class of Hazard I C in Table 1. A special hazard of Ethylene Chlorohydrin is its ability to penetrate ordinary rubber. 16 HONS 095695 The selection of the Signal Word depends on the seriousness of the hazards and to a lesser extent on the number of hazards. In the case of Ethylene Chlorohydrin, both major hazards--its toxicity and its ac tion on the eyes--are serious and acute. Therefore, the Signal Word "DANOERI" is indicated. Since ethylene chlorohydrin is dangerous by any type of contact with the bod>, strong Statements of Hazard should be used. As far as possible, hazards should be listed in the order of decreasing importance. Thus, from Table 1. Classes of Hazard HI. IX. and X. appropriate State ments of Hazard are selected to describe the various hazards. From III: VAPOR EXTREMELY HAZARDOUS VAPOR MAY BE FATAL IP INHALED From IX: EXTREMELY HAZARDOUS LIQUID ABSORBED THROUOH SKIN From X: MAY BE FATAL IP SWALLOWED For brevity and better emphasis, the above statements are combined and rearranged: EXTREMELY HAZARDOUS LIQUID AND VAPOR MAY BE FATAL IF SWALLOWED, INHALED, OR ABSORBED THROUOH SKIN For the major hazard of eye damage, the appropriate Statement of Hazard as selected from Table 1, Class of Hazard VII, is modified to: CAUSES BURNS TO EYES The Statement of Hazard "COMBUSTIBLE" is not necessary (ex cept aa required by Jaw), since the Precautionary Measure. "Keep away from heat anal epen flams.'1 ia considered adequate. Since ordinary rubber protective clothing, including gloves, wilt not eliminate the haiard of skin absorption, a special Precautionary Statement to this effect should be prepared and included. 17 HONS 095696 Statement* of Precautionary Measure* are selected from Table 1, Column 3, Classes of Hazard 1, ill, VII, IX and X. From 1: Keep away from heot and open flame. From HI: Do not breathe vapor. Use only with adequate ventilation. From VII: Do not get in eyes, on skin, on clothing. From IX: Do not get in eyes, on skin, on clothing. From X: Do not take internally. Special Precautionary Statement prepared to cover special haiard of material: Ordinary rubber protective clothing, including gloves, will not pre vent skin absorption. Instructions in Case of Contact or Exposure are selected from Table i. Coluum'-i. Cta*s of Hazard |X: * From IX: In cost of contact, immediately remove all contaminated clothing and flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Wash clothing before re-use. Ethylene Chlorohydrin is a poison by absorption into the body by skin contact, therefore, the "POISON*kull and crosibones" legend is used, followed by first aid instructions: poison Call A Physician Pint Aid If swallowed: If conscious, moke potient vomit immediately by putting Anger down throat or by giving worm mustard wafer or salt water freely. General: Keep patient warm; if conscious, give block coffee. Net* to Physician: Do not give adrenalin. 1 MOMS 095697 Thus, the completed precautionary label, combining and rearrang ing selected material according to Genera/ Principle* as outlined in this Guide, will include the following components as shown below: Q Name of Product, Signal Word, ^ Statement of Hazards, Q Precautionary Measures, Q Instructions in Case of Contact or Ixpoiure, 0 Poison Legend and First Aid Statement O [iTHYLiNE~CHLOROHYORrN~(ANHYOgOUS OR 38%) ----- [BaNOIRI riYTREMitr'hazardous IIOUIO AND VAPOR |MAY II RATAL IP SWALIOWID, INHALID, OR 0------------------------j AISOMID through skin (CAUSIS BURNS TO IYIS Do not pet <n eyes, on ikin, on clothing. Ordinary rubber protec i tive clothing, including gloves, will not prevent skin absorption. { Do not breathe vapor. o-- { Use only with adequate ventilation. ) Do nut toke internally. | Keep away from heat end open flame. -- In case of contact, immediately remove all contaminated clothing and flush skin or eyes with plenty of water for at least 15 minutes; for eyes, got medical attention. Wash clothing before re-use. -- POISON Call A Physician r 7irlr Aid* I If swallowed: If conscious, make patient vomit immediately by putting finger down throat or by giving warm mustard water or salt water freely. i Oeneral: Keep patient warm; if conscious, give black coffee. ^ Not* to Physlclant Do not give adrenalin. MQNS 095698 19 TABLE 1 SELECTION OF PRECAUTIONARY STATEMENTS Prpdwctt will ba ancaunfarad that praiant haiard* varying In kind or dogroa from tkn llitod. Appropriate Metimtnt of Horordt, ^rocooflonory Mor*r and InurvctloniT Casa a/ Contact or Fxpaivr* ihovld bo proparod on tho botlt of Iho proportion of rho orad" net, fallowing ha pattarn and gonarol phroiooiogy of th following tab)*. o..T-^>tll>t` words In tha tabla oxprau variation* In kind or dogroa and or* to bt viod wfiaro___ cabin, ue EXAMPLE OF LABEL PREPARATION BEGINNING ON PACE 1*. " Clan *f Haiard I. liquid* Flashing at I50*F. or lalaw (Flash point* ora datarminad by th* Tagllabot Opan.Cup Mathad) A. Flash point 10*F. or balow________________ B. Hath paint obava S0*F. to IQ*F. Indusiv* C. Plath point obava 10*P. to IJO'F. indvsiv* II. Oildlting Metoiioli Stotantontt of Haiard IMPORTANT! Salad appiicabla itatamtntf*} only S*l*cti*n() fa ba basad on octual hoiord(i) nd dogroa of haiard. tn soma Ini'ancat, wh*r o mild caution I* Indicated, tho Slatamant of Haiard may bo omittad and adaqvata Information pravidad by tho itatamant of Fracawtlonary Mooiuroi, EXTREMELY FLAMMABLE FLAMMABLE COMBUSTIBLE* STRONG OXIOANT CONTACT WITH COMRUSTIItC (OTHER) MATERIAL MAY CAUSE FIRE III. MatarlaH Giving Vapor* Rapidly Toilc or Cntranialy Irritating an Inpatuta far a Short Tima or ta Law Cancantratian* IV. Metarlal* Olvlng Vapan Haiardau* from Prolangad or Ropaatad Cipatwras ar Ixpamira ta High Cancantratian* VAPOR (CXTRIMCLY) HAZARDOUS (IRRITATINO) HAZARDOUS LIQUID AND VAPOR (GAS UNDER PRESSURE) VAPOR POISONOUS IP INHALED VAPOR MAY IE FATAL IF INHALED (Sao NOTE appoilto paga) VAPOR HARMFUL CAUSES (MUTATION OF EYES, NOSE, AND THROAT V. Oatoi and Vapar* Fhytlalaglcally Inort Inholatlan ar Canfact VII. Cartadv** OAS (VAPOR) REDUCES OXYOCN AVAIUILE FOR IRIATHINO RELEASES HEAVY OAS (VAPOR) WHICH MAY CAUSE SUFFOCATION HAZARDOUS (HARMFUL) OUST HARMFUL IP INHALED CAUSES IRRITATION OP SKIN, EYES, NOSE, AND THROAT CAUSES SEVERE IURNS CAUSES BURNS MAY CAUSE BURNS V)H. Irritant*, SantiMkoro CAUSES SKIN IRRITATION MAY CAUSE SKIN IRRITATION IX. Matartafc Taak through Shin Absorption X. Metarlolo Tank If Swailowad 20 (EXTREMELY) HAZARDOUS (HARMFUL) SOLID (LIQUID) ABSORPTION THROUOH SKIN MAY IE FATAL ABSORPTION THROUOH SKIN HARMFUL (RAPIDLY) ABSORBED THROUOH SKIN |$aa NOTE appadto paga] ' POISONOUS IF SWAUOWfD MAY RI FATAL IF SWALLOWED HARMFUL IF SWALLOWED (Saa NOTE appasita pago) 'A* roquirod by law MUNS 095699 The Molemerm ihown Mow ore net intended 1 be complin. In (he preparation of 9j,,n label >#. mend applicable to the product may be found in thU Table. However. luitoble medtUn rhwreef, or U(*T*rtnt tlfltemenn entirely, may be iteeeuery. NOTEi "PO(IOM-fcwN and treMbanoc" rheuid be included if the preduet meet* any f the criteria ier "POISON" *t forth on Pape 10 er ii required by low. if "POISON'* it uted. odd flrtl aid er onlideie ttatemenl at repaired. Precautionary Maotoroc IMPOSTANT; Select applicable ifoteent() only. Selectlan(i) to be bated on octvol haiard(t) and degree el heterd. In tome Imtaneet the emtition of a Precautionary Statement may be iuitlAed where the meeiure to be fallowed it ebviowt from the Statement of Haioid. Inttrvcdana la Cote of Contact er lupoeuro IMPORTANT; Select applicable itatomentfr) only. Selection!*) te be bated on necetuty far prompt action in ardor te avoid terleui effect*. Keep away from heat (tparhi.) and epan Some. Keep container doted (and away tram heat}. Ute with adequate ventilation, Store leperoreiy (away! from and avoid contact with tembuttlbie (othet) material!. Avoid contamination of clothing o it become* dongeroutly flommoble when dry. Keep container dated (and away from heat). Avoid contact with Mn and eyet. Oo not breathe vapor. Oa not pet in eyet, on thin, on clothing. Ute only with adequate ventilation. Keep container elated (and away from heat). Have oirJine respirator or iel!<anta(nod aiypen rtp(ratar available for emergency. Ute only with adequate ventilation. Avoid (prolonged er repeated) breathing (at) -roper, Avoid contact with thin, eyet, and derhing. Keep container dated (and away from heat). Ute with adequate ventilation. Keep container doted. Oa not enter tforage area* unlew adequately ventilated. Da not breathe doit. Avoid breathing dud. Wath thoroughly before eating er tmehlng. Avoid contact with thin, eyet, and elothtng. Oo not got in tyei, on thin, on clothing. Avoid contact with thin, eyet, and clothing. Avoid enpoture t (concentrated) vapor. Avoid (prolonged or ropoalod) contact with (kin. Woth thoroughly alter handling. Avoid etpoturp ta (concentretod) vapor. Do net get in eyet, on thin, on clothing. Avoid contact with thin, oyet, and dathing. Woth thoroughly before eating or tmehlng. Woth thoroughly after handling. Do net breathe dart (vapor), Avoid broathlag dwtt (vapor). Oo not taka (PtarnaNy. [loo Precautionary Meoturot, Paga 11). In cat# of contact, immediately Suit* thin er eyet with plenty el water for (at leatt) IS minutet; far eyet, get medical attention. (Woth clothing thoroughly at once.) Sweep up tpiilape at once. Fluth or obtorb tpiliago with........... .......... . In cote of contact, immediately Such ikln or eyet with pionfy of water far (at leatt) 15 minutet; far eyet, pet medical attention. Semave and wath clothing before re-ute. (See MOTS aPove) If tpilled on clothing, remove and vroth before re.ute. In cat# of enpature to high cancentratlent, move to froth air. If affected by enpeture, move te froth air. If breathing hat Mapped, apply artificial retpfratfen. (n cate of contact, (immediately) ffuth thin er eyet with plenty ef water for (el leatt) IS minutet; for eyet, get medical attention. (Semeve end wath clothing before ro ute.) In cate ef contact, immediately Suth thin er eyet with plenty of water far (at leatt) 15 minutet* Her eyet,) pet medical attention. (Semave and woth clothing before re-utg.) in cat# of contact. Suih with (plenty of) water; (far eyet, pet medical attention.) In cote of contact, immediately (remove ell eontemi. noted clothing and) fluth thin er eyet with plenty of water for (at leatt) 15 minutet; (for eyet.) get medical attention. Waih clothing before re.vie. [See NOT8 above) (See NOTE above) HONS 095700 ti Labels for Small Commercial Packages The Genero/ Principle governing the preparation of precautionary labels discussed in Part I and the illustrative labels in Part II of this Guide have been developed primarily for bulk packages of chemicals intended for industrial use. The General Principles may be applied, however, to chemicals packaged in small containers. These may include, among others, hazardous substances in retail packages intended for the ultimate consumer; highly purified chemicals intended for research, testing, or control; and chemicals intended for professional use such a* in pharmacy. As stated in the General Principles on Page 12, each hazardous substance presents a distinct problem and must be treated individually in the light of its own characteristics. This same principle will apply to small containers. Small containers may present problem of less available space for labeling purposes. Careful and selective shortening of precautionary statements for such containers may be in order if necessary to permit legibility, or if the wording on labels for the chemical in industrial packages is not applicable. Consideration should always be given to (1) the intended or reasonably anticipated handling or use of the particular product. (2) the training and experience of the expected user, and i 3) the extent to which the hazard is modified by the size or type of container. The following principles are recommended for condensation of suggested label wording where necessary or advisable: (1) Retain the Signal Word; (2) Retain the Statement of Hazards, shortened if necessary to a practical equivalent; (3) Consider omission of Precautionary Measures if they are clearly indicated or implied from the Statement of Hazards or can be clearly indicated or implied by revising the Statement of Hazards; (4) Consider omission of wording relating to hazards that may be less serious because of the particular characteristics of the package, the nature of the use, and the training and experience of the user. Care must be taken to include Precautionary Measures for any additional haaard which may be present as a result of such characteristics, use. , or training and experience. Cara should ho taken thart labels prepared in accordance with fho above principles Include all information required by law. 2a MOMS 095701 Labols tor Samplos and for Now Products for Invostigational Uso Semples: In general, the label for samples of s product should bear the same precautionary information that is on the commercial label, with the exception of possible differences in container instructions, if the prod uct is not in commercial production, the label for samples should be prepared in accordance with the 0antral Principle stated on Page 12 in this Guide. New Products for Invostigotlonal Uso: Chemical, physical, and toxicological data should be obtained on any product before it is distributed, so that hazardous properties can be described on the label. However, it may occasionally be necessary to make delivery of a new product for investigational use before all of these data are obtained. For instance, the quantity available may be too small for necessary tests, or the product may have to be delivered to investigators for the purpose of obtaining the desired information. These deliveries should be made to qualified investigators only, and should be labeled as adequately as possible with the information avail able. To cover such cases (and such cases only I the following illustra tion is suggested for preparing labels to be used during the period of investigation. fWAMI o* ottcwrtoN Of MOOI/CTJ FOR INVESTIGATIONAL USB ONLY SIGNAL WORDI STATEMENT(S) OP KNOWN HAZARD(S) Appropriate precautionary measures. Appropriate instructions in cose of contact or exposure. IMPORTANTI The chemical, physical, and toxicological properties of this product hove not been fully investigated, and its handling or use may (be hazardous! (present additional hazards). Exercise due care. 23 MONS 095702 CONTAINER HANDLING AND STORAGE Care should alwaya be exercised in handling 1 storing containers of hazardous chemicals and in removing (he contents. The Chemical Packaging Committee of the Manufacturing Chemists' Association, Inc., has recommended the general precautions given below for handling and storing certain classes of containers. Applicable phrases may be selected from these statements. These may be used either as separate labels or in combination with the precautionary labels illustrated in Part !l. Where the properties of the substance require special or addi tional precautions, such instructions are indicated in some instances in conjunction with the individual label in Part II. Metal Drum Handling and Storage (fr liquids and eu-Uq*id Keep plug up 10 prevent leakage. Keep drum oul of sun and away from best. Relieve internal pressure when received and at least weekly (hereafter by slowly loosening plug. Reiighlen immediately. Drums should be grounded when being emptied. Do not drop or slide across sharp projection. Never use pressure to empty. Drum is not s pressure vessel. Keep lights, fire, and sparks away from drums. Drum musi not be washed oul or used (or other purposes. Replace plug after each withdrawal and return with *ty drum. In case of spillage, flush with plenty of water. G!a Carbay Handling and Storage Before moving carboy be sure closure is securely (a-t- ned. Avoid rough handling or dropping. Loosen closure carefully. Keep carboy out o( *un and away from heal. Never use pressure to empty. Carboy is not a pressure vessel. Completely drain carboy before returning. In case of spillage, flush with plenty of water. Woodnn Barrol Handling and Starago ttw liquids nd semMiquids) Keep barrel out of sun and away from heal. Stare with bilge bung up. Never um pressure to empty. Drain completely. Keep banel moiat--shrinkage may cause leaks. In case of spillage, flush with plenty of water. 24 MONS 095703 Cylinder Handling and Storage Keep cylinder out of sun and away from heat Never drop cylinders. Kerp cylinder* locked vertically to prevent falling and/or (iroppirg. Be sure connection* rr tight. ICC Regulation* prohibit refilling cylinder without permission of owner. Have air line respirator or self-contained oxygen respirator available for emergency. Aerosol Container* The term "aerosol container" is generally applied lo a container which holds its contents under pressure and is equipped with a dis pensing nozzle designed to release the container's contents through a very small orifice. While a (rue aerosol is a mist or spray of fine particl* * or droplets suspended in air. aerosol type containers are used for packaging and dispensing many products which do not form true aerosols on release Thus, there are aerosol products dispensed as depositing sprays fpaints or insecticides! or as semi-liquid froths (whipping cream or shaving lather). In all cases, aerosol containers require more care in handling and storage than similar unpressurized containers, and particularly require protection from elevated tempera tures. When the contents are released as an aerosol or fine spray, there may be greater flammability or inhalation hazard than would be pre sented by the same product in other types of packaging and use. The Chemical Specialties Manufacturers Association suggests the following precautionary text for the pressure hazard presented by a metal aerosol container: WARNING! Content* under pressure. Do not puncture. Exposure to heat or prolonged exposure to sun may cause bursting. Do not throw into lire or incinerator. NOTE'. Addition*) rtwiijic citation* tor itawmenr* *i to hitard* rn pertont ind propcity, the ( *<KMtn of contend, etc. will depend upon the particular product. Appropriate modification of the above text may be required for an aerosol container made of a non-metallic material. Also, additional precautionary labeling may be needed to warn against hazards presented by the contents of an aerosol container after release. Special lest pro cedures developed by the Chemical Specialties Manufacturers Associa tion are used in determining the flammability hazards of products in aerosol containers. HONS 25 095704 MANUAL l-l -- SIXTH EDITION 1961 In thia new edition oi Manual L-l, certain illustrative label texts have been added to illustrate specific new material types. Other texts which appeared in the Slh Edition have been revised in order to recog nise new information concerning the products' properties, or in con sideration of revised Container Handling and Storage precautions as set forth on Page 24. Finally, tome texts have been deleted since the labeling principles which they illustrated are adequately illustrated by other text* in this Guide. The fact that a label text formerly used in Manual L-l is deleted from this edition does not imply that the material no longer requires precautionary labeling. Furthermore, the omission of a label text for a particular product does not indicate that the product does not require precautionary labeling. Individual statues, regulations, or ordinances may require that particular information be included in a label or that a specific label be affixed to a container. In each case, the requirements of such laws should be studied. PART II Acrolein Bentidine Hydrochloride Bentidine Sulfste Bensoyl Peroxide Beryllium Oxide Powder BuiylUthium (normsl) Calcium Cyanide Decsborsne Oiborsne Dichierobensene (orthoj Ethyl Acrylue Isepropylamine i ADDED Lead Oxide (Red Lead) Methyl Acrylate Methylaminea, Anhydrous Methylsmines, Aqueous Solutions Pentaborsne Phosphorus PentteulAde Potassium Dichromate Titanium Trichloride, Anhydroua Tolylene Diiaocyanste Vanadium Tetrachloride V inyl Acetate Zirconium Metal Powder LAIILS REVISED Acetaldehyde Acetic Acid. Glacial Acetic Anhydride Acetyl Chloride Acrylonitrile Allyl Alcohol Aliyi Chloride Aluminum Chloride, Anhydroua Ammonium Hydroxide ieo-Amyi Acetate (now Amyl Acetal*. Mixed (miners) Aniline Antimony Trichloride Barium Chloride Bensyl Chloride Bromine Butadiene <now Butadiene, Inhibited) Butyl Alcohol 'normal or secondary) n-Butylamine 'now Butylamine, normal) Butyraldehydo Caustic Potash Caustic Soda Chlorine Chlorotuifonic Acid Chromic Acid [Chromium Trioxidel (now Chromium Trioxide [Chromic Acid)) Cresol (Cresylic Acid) Cyanides, Inorganic Cyclohexane Continued Ntxt Page 26 MONS 095705 PART ll--Continued UL$ fttviseo Dichloroethylene Dichloroethyl Ether Diethylaminr Dieihylenetriamine Dimethylamine, Anhydrous Dimethyl Sulfite Dioiane U.4.Dieihylene Dioxide* Ethyl Acetate Ethylene Chlorohydrin Anhydrous or 38%) Ethylene Dichloride ' Ethylene Oxide Formaldehyde Solution Hydrochloric Acid (..Muriatic Acid) Hydrocyanic Acid Hydrogen Chloride. Anhydrous Hydrogen Peroxide 7.4% Hydrogen Peroxide (Wronger then 7.4% hut not exceeding 32% * Hydrogen Sulfide Lead Monoxide (Litharge) Paraformaldehyde Phenol Phosphoric Acid Phosphoric Anhydride 'no" Phosphorus Pentoxide) Phosphorus Phosphorus Penlaohloride Phlhalic Anhydride Potassium Hydroxide iso-Propyl Ether (now Isopropyl Ether) Pyridine Siher Nitrate Sodium Cyanide Sodium Fluoride Sodium Hydrosulfite Sodium Hydroxide Sodium Orthosilicate Sodium Sesquisilicaie. Anhydrous Mercurtc Chloride ( Mercury Bichloride) Methanol Methyl Bromide Methyl Chloride Methyl Ethyl Ketone Methyl Methacrylate Monomer Methyl Morpholine Mixed Add (Sulfuric end Nitric) Morpholine Muriatic Acid Naphihylatnine (alpha) Sodium Sulflmlrate Sodium Sulfide Sc'fiir Chloride ' ir Dichloriile s ..iuryl Chloride Tar Acids Thiwnvl Chloride Toluene < Tnluoli Toluidine (ortho or meia* Toluidine < parai \ inyl Acetate Xylene i Xylol i Ammonia. Anhydrous Barium Nitrate Benzidine U-Dlch(oroethane Di iso Butyl Ketone Dlmethylenillne Dipropyl Ketone Ethyl Formate Ethylene Dibromide Ethylene Glycol Monomethyi Ether Mesityl Oxide Methyl Amyl Acetete Methyl Amyl Alcohol Methyl n>Amyt Ketone Methyl iso-Butyl Ketone MMIS DELETED Methyl Cyclohexenol Methyl Cyclohexanone Methyl ito-Propyl Ketone Methylene Chloride Nitrogen Dioxide Nitrophenol Pentachlorophenol Petroleum Naphthas and Solvents. Industrial Phenetidine 'ortho or para* iso Propyl Acetate Propylene Chlorohydrin Sodium Fluosilicate Teirachlorophrnol Trichlorophenol PART III LABELS ADOIO 3* (alpha-Acetonylfurfuryl) 4-hydroxycoumartn and Sodium Salt AllyI Alcohol 2-CarlMtmeihexy-l-methylvjnyl Dimethylphoophair and Beta Isomer 2-Chloroailyl Diethyldithiocarbamate alpha-Chloro-N.N-ditllylaceiamtde L.l'bis(CUlorophenyl)2,2.2-trichIorofthanol 1.2*DibromO'3*rliloropropane Continued Next Page HONS 095706 PART III--Continued LAlllS ADDIO DichioropToperie-DlchloropTopane Miituze Diethyl Diphenyl Dichloroethana C)odin* Hetaethyl Tetraphoaphata Maleic Hydraaide, Diethanolamine Salt 1-Naphthyl N-Methylcarbanate Pentachloronitrobensene Phoiut Ronnel N-Trichloremethyhhiophthatimide LAICLS REVISED Acrylonitrile Arsenical*. Liquid (Weed Killer** now Arsenical Weed Killer*, Organic Calcium Arsenate Calcium Cyanide Chloranil Cyanides, Inorganic Dichlone Dichloioethyl Ether Ethylene Dibromide Ethylene Dtchloride Formaldehyde Solutions ($% and overt Hydrocyanic Acid Lead Arsenate Malathion Methyl Bromide Nicotine Sulfate Parathion Paris Green Sodium Fluoride Sodium Fluosilicate Tetraethyl Pyrophosphate Thallium Sulfate Toaaphene Zinc Amnite Antu Aramite LAICLS DELETED Barium Fluoailicate Glyodin 2a MCNS 095707 PART II Illustrative Labels for Hazardous Chemicals The precautionary labels in this section have been prepared to demonstrate the practical application of the General Principles in Part I to a number of chemical products intended for industrial use. The user should familiarise himself with Part I before adapting any of the label statements contained in Part U to his products. The chemicals were selected to illustrate labeling for the major types of hazards com monly encountered. Consequently, the listing covers only relatively few of the hazardous chemicals for which precautionary labels are necessary. In many cases, these labels would be applicable to other products having the same hazards, and examples of this are listed by appropriate cross references. The labels are based on the properties of the named chemicals: the presence of other substances, including impurities, may alter these prop erties and necessitate additional or different precautionary information. General information regarding the handling and storage of con tainers is not included on these labels. This subject is discussed under the heading, "Container Handling and Storage", beginning on Page 24. First aid treatment is given for a few products only. Such informa tion may be durable on other products. Where "clothing'* is men tioned in first aid instructions, it should be understood to mean all articles of clothing, including shoes, garters, and other accessories. Shoes are specifically named in some instructions because of special hazards arising from absorption of the chemical by leather. The notation, "MCA Chemical Safety Data Sheet available", appear ing with certain labels in this section, refers to Data Sheets published by the Manufacturing Chemists' Association, Inc. These publications con tain detailed information on the chemical, physical, and toxicological properties of the product, as well as information on shipping containers, labeling, storage, handling, and protective equipment. Prices and a complete list of available Chemical Safety Data Sheets may be obtained directly from the Manufacturing Chemists' Association, Inc. (See Pages 95 and 96 for complete listing of Chemical Safety Data Sheet# now available.) The labeling of radio-active materials is a complex problem outside the scope of this Guide. In preparing precautionary labels for such 29 HONS 095708 material*, it is suggested that references be made to the series of hand books published by the U. S. Department of Commerce, National Bureau of Standards, covering the safe handling of radio-active materials. The illustrative precautionary labels suggested In Manual L-l should be used In addition to, or in combination with, any labol required by law. ACETALDEHYDE DANOERI EXTRIMUY FLAMMABLE MAY FORM EXPLOSIVE PEROXIDES UNDER AIR PRESSURE Koep away from heat, sparks, and open flam*. Keep container closed. Use with adequate ventilation. Avoid prolonged breathing of vapor. *Cool to below 68F. before opening. *Do not use air pressure to transfer. MCA Chemkei Sefety Date Sheet SOUS eveilebie ACETIC ACID, GLACIAL DANOIRI CAUSIS ilVIRI BURNS Do not get liquid or vapor (n eyes, on skin, on clothing. Keep away from heat and open flame. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. 'Glacial Acetic Acid freezes at 62F., forming hard lumps which may breok carboy when moved. 'Store in area maintained above 629F. 'If frocen, thaw by carefully moving carboy to warm area. MCA Cbemkel tefety Dete Sheet SEMI eveileble * Addition M `'Container Handling end Storage". Pago 24. 30 MGNS 095 709 ACETIC ACIO, 80% DANOBBI CAUSIS SEVIM BURNS Do not 0*f liquid or vapor in eyes, on skin, on clothing. In cat* of contact, immediately flush tkin or eye* with plenty of water for at least 15 minutes; for eyes, get medical attention. MCA Chemical Safety Data Sheaf ID-41 available ACETIC ACID, 56% - 70% WARWNOI MAY CAUSf BURNS Avoid contact with k(n, eyes, and clothing. In cose of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. MCA Chemical Safety Data Shaat SD<4t available ACETIC ACID, 28% CAUTIONI MAY CAUSI BURNS Avoid conroct with iktn, eyes, and clothing. In coco of contact, immediately Ruth ikin or oy.i with plenty of water for at leait IS minutoc; far eyer, got madicot attention. MCA Chemitef Sefety Oete thee! ItMt evetlehie 31 HONS 095710 ACETIC ANHYDRIDE DANOflU CAUS1S SEVERE BURNS VAPOR HARMFUL Do not got liquid or vapor in eyes, on fkin, on clothing. Do not breathe vapor. In cat* of contact, immediately remove contaminated clothing and flush skin or eyes with plenty of wotor for at least 15 mingles; for eyes, got medical ottontion. Wh clothing btforo re-yio. MCA Chtmkal loftty 0ot Ihtit SO-1S ACETONE OANOIRI EXTREMELY FLAMMABLE Keep awoy from hoot, sporks, and opon flamo. Keep containtr closed. Use with odoquato vontilation. Avoid prolonged or repeated contact with skin. ACETYL CHLORIDE DANOtftt HAMMABlf CAUSKS SEVERI BURNS Keep away from heat, sparks, and open flame. Keep container dosed. Do not get in eyes, on skin, on clothing. Avoid exposure to concentrated vapor. In case of contact, immediately Ruth skin or eyes with plenty of water for of least 15 minutes; for eyes, get medical attention. Do not allow water to get into container because of violent reaction. 32 MGNS 095711 ACROLEIN DANGER! EXTREMELY FLAMMABLE MAY EE FATAL IF INHALED LIQUID CAUSES SEVERE BURNS Keep away from hoot, sparks, and open flam*. Keep container closed. Do not breathe vapor. Do not got in oyoi, on skin, on clothing. Uio only with adaquate ventilation. In case of contact, immediately romovo contaminated clothing, includ ing shoes, and flush skin or oyoi with plenty of water for at leail *15 minutes; for eyes, get medical attention. Wash clothing thor oughly before re-use. poison . Call A Physician First Aid If inhaled: Move patient to froth air; if breathing becomes diffi cult, start oxygen inhalation through suitable equipment. If swallowed; If conscious, make patient vomit immediately (Anger down throat or give warm mustard water or salt water freely). General: Keep patient warm; if conscious, give coffee. ACRYLONITRILE DANGER! VAPOR HAZARDOUS FLAMMABLE Do not breathe vapor. Do not get in eyes, on skin, on clothing. Use only with adequate ventilation. Keep away from heat, sparks, and open flame. Keep container dosed. POISON .&> Finf Aid {In addition, INCLUDE tha ram* Pint Aid end Antideta at racemmendad far CYANIDES, INOROANIC ihawa n Pag* St.) 33 HONS 095712 AUYL ALCOHOL DANOERI EXTREMELY HAZARDOUS LIQUID AND VAPOR RAPIDLY ARSORBID THROUGH SKIN PLAMMABLI Do nor get In eyes, on skin, on clothing. Oo not breathe vapor. Oo not toko internally. Keep away from boat, sparks, and open flam*. Keep container, closed. In ease of contact, immediately remove ait contaminated clothing end flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Wash clothing before re-use. . poison A* Call A Physician first Aid ALLYL CHLORIDE DANOERI IXTRKMELY FLAMMABLE VAPOR HARMFUL Keep away from heat, sparks, and open Home. Keep container dosed. Use only with adequate ventilation. Da not get in eyes, on skin, on clothing. Do not breath# vapor. In case of contact, immediately remove all contominoted clothing and flush skin or eyes with plenty of wator for at loost 15 minutes; for eyes, got medical attention. Wash clothing before re-use. 34 MONS 095713 ALUMINUM CHLORIDE, ANHYDROUS WARNING! MAY CONTAIN GAS UNOKR PRtSSURI CONTACT WITH WATIR OR MOIST AM UBIRATH HYDROCHLORIC ACID GAS CAUSIS BURNS loosen closure cautiously before opening. Avoid contact with eye*, ikin, or clothing. Keep container tightly doted. tn co<e of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. MCA Chemket Safety Date Sheer t04t avertable AMMONIA, AQUASamm label at AMMONIUM HYDROXIDE MCA Chamkel Safety Data Sheet ID-IS avertable AMMONIUM DICHROMATE WARNINGI FLAMMABLE HARMFUL DUST MAY CAUSS RASH OR IXTIRNAl ULCCRS Keep awoy from heat, sparks, and open flame. Keep container closed. Avoid contact with skin and eye*. Avoid breathing dust or solution spray. In cose of contact, immediately flush skin or eyes with plenty of woter for of least 15 minutes; for eyes, get medical attention. Wash clothing before refuse. Use fresh clothing daily. Take hot shower after work using plenty of soap. MCA Chamkel.fefety Data Sheat SIMS available 33 MONS 095714 AMMONIUM HYDROXIDE WARNING! UQUID CAUSIS BURNS VAPOR EXTRCMILY IRRITATING , loosen closure coutiously before opening. Avoid breathing vopor. Avoid contact with eyes, skin, and clothing. In case of contact, immediately flush skin or eyes with plenty of watei for at loost 15 minutes; for ayes, gat modical attantion. MCA Safety Data SH SO-13 avalUfcl* far AQUA AMMONIA AMYL ACETATE (mixid isomrs) CAUTIONI Kaap away from haat and opan flam#. Avoid prolonged braathing of vapor. Us# with adequate v#ntilation. Avoid prolonged or r#p#ot#d contact with skin. ANILINE DANOIRI EXTRIMILY HAZARDOUS LIQUID AND VAPOR RAPIDLY ABSORRiO THROUGH SKIN Do not gat in #y#s, on skin, on clothing. Avoid br#othing vapor. Us# only with od#quat# ventilation. In cas# of contact, imm#diat#ly r#mov# all contaminated clothing, including $ho#s, and flush skin or #y#s with plenty of water for at least 15 minutes; get medical attention. Wash clothing before refuse. poison . Call A Physician First Aid MCA Chwefcel Safety Data llu*i SO-17 36 MONi 095715 ANISIDINE (ortho) WARNING) HAZARDOUS LIQUID AND VAPOR ABSORftID THROUGH SKIN Avoid contact with skin. eyes, and elothing. Avoid breothing vopor, Use only with odequate ventilation. In cost of contoct, flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Rempv* and wash clothing before re-use. ANISIDINE (para) WARNINOI HAZARDOUS SOLID AtSORHD THROUGH SKIN Avoid contoct with skin, eyes, and clothing. Avoid breathing dust. Use only with adequate ventilation. - In case of contact, flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Remove and wash clothing before re-use. ANTIMONY TRICHLORIDE DANOIRI CAUSIS SCVIRI IURNS VAfOR HAZARDOUS Do not get in eyes, on tkin, on clothing. Do not breathe vapor. Keep container closed. In case of contact, immediately remove all contaminated clothing and flush skin or eyes with plenty of water for at least 15 minutes,for eyes, get medical attention. Wash clothing before re-use. MCA Chsmkel Safety Data Sh*M SIM* vllW | ' I 37 MQNS 095716 ARSENIC TRIOXIDE DANGER! MAY U FATAL IF SWAUOWID Avoid breathing dust or iproy mist. Avoid contact with skin, eyes, and clothing. Wash thoroughly aftor handling. poison Call A Physician First Aid MCA Chemical Safety Data SHaat ID40 available BARIUM CHLORIDE DANGERI MAY BE FATAL IF SWALLOWED Do not take internally. Avoid breathing dust. Wosh thoroughly aftor handling. poison Call A Physician First Aid IF swallowed: Give Epsom solt or sodium sulfate in water. 38 MONS 095717 BENZENE (BENZOL) DANOERI EXTREMELY HAMMAME VAPOR HARMFUL Keep oway from heat, spark*, and open flam*. Keep container closed. Use only with adequate ventilation. Avoid prolonged or repeated breathing of vapor. Avoid prolonged or repeated contact with skin. *. poison Call A Physician First Aid MCA Cticmiret l*lly Out* llwil 10*2 r(IU BENZIDINE HYDROCHLORIDE DANDER! HAZARDOUS SOLID HARMFUL IF SWALLOWED, INHALED, OR ADSORBED THROUGH SKIN REPEATED ABSORPTION MAY RESULT IN BLADDER TUMORS Do not get in eyoi, on ikln, on clothing. In case of contact, immediately Rush skin or eyes with plenty of woter for at loose 15 minutes; for eyes, get medical attention. Wash clothing before re-use. Take hot shower after work, using plenty of soap. BENZIDINE SULFATE Sam* /ab*( at BENZIDINE HYDROCHLORIDE 39 MONS 095Ufl BENZOYL CHLORIDE WARNING! CAUSIS RURNS VAPOR IRRITATINO Avoid contact with iktn and eyes. Avoid breathing vapor. In cat# of contact, immediately Rush skin or eyes with plenty of water for at least 15 minute*; for eye*, get medical attention. BENZOYL PEROXIDE DANGER! PIAMMARLI SOLID OXIDIZING MATERIAL HEAT, SHOCK, OR CONTACT WITH OTHER MATERIALS MAY CAUSE HR! OR EXPLOSIVE DECOMPOSITION BEFORE USING, READ MCA CHEMICAL SAFETY DATA SHEET SD-81 Store in a cool place in original container and protect from direct sunlight. Keep away from heat, sparks, and open Rome. Do not add to hot materials; do not grind or subject to frictional heot or shock--explosive decomposition may result. Prevent contamination with readily oxidlxable materials ond poly* mediation accelerators. Avoid contact with skin, eyes, and clothing. Per Wet lenxeyt Peroxide change the heading to read: BENZOYL PEROXIDE (W*f) Use /obei appearing above For Benzoyl Peroxide inserting immediately above the iinei Store in o cool p/ace . . . the iine.- Keep container closed to prevent drying out. MCA Ct>*lal Safety Pete Stow* $041 evelleMs 40 HONS 095719 2. PHKNYl MSRCURY OilATI flew than 1 .OH and over O.l % * WARNIN01 POISONOUS IP SWAUOWfD MAY CAUSI SKIN IRRITATION OR DILAYSD CHIMICAL SURNS Avoid contact with thin, eyes and clothing. Avoid brtathing spray mist. in cos# of contact, immediately remove oil contaminated clothing and flush skin or eyes with plenty of water for at least 15 minutes/ for eyes, get medical attention. If burning or blistering of skin results, get medical attention. Wash clothing before refuse. A POISON JL (Antidotal 1 0.1% or Zee* CAUTIONI HARMFUL IP SWAUOWID MAY CAUSI SKIN IRRITATION OR DllAYID CHIMICAL SURNS Avoid contact with skin, eyas, and clothing. Avoid breathing spray mist. In ease of contact, flush skin or eyes with plenty of water; for eyes, get medicol attention. If burning or blistering of skin results, get medical attention. Netei far certain epplkeflens, Dlrestlen* ter Use may need e Include mar* detailed In. MrvctleM far sofa Handlist ef *hl# product and materials treated with it. 139 MOMS 0958 LB PHORATE (O.O-DIETHYL-S-ETHYLTHIOMETHYIPHOSPHORODtTHIOATE) (any effective concentration) danorri poisonous r skin contact, inhalation, or SWAUOWINO RAPIDLY ASSORSID THROUOH SKIN RIPIATIP INHALATION OR SKIN CONTACT MAY, WITHOUT SYMPTOMS, PROORISSIVILY INCRIASI SUSCIPTIRILITY TO PHORATI POISONING Do not sat an .tin, In gyg, on clothing. Wsar eieon heavy rubber gloves and goggles. Wear dean water proof or freshly-laundered protective clothing (coverall*, cop, etc.}. Destroy and replace glove* frequently. Wo*h thoroughly with toop and warm water before eating or smoking. Bathe immediately after work and change ail clothing. Wa*h clothing thoroughly with toop and hot woter before re-ute. In cote of contact, immediately remova contaminated clothing and wah kln thoroughly with oop and water; for eye*, flush with plenty of water for at least 15 minute* and get medical attention. Do not breathe duet or vapor. Wear moik or respirator of a type passed by the U. S. Depart ment of Agriculture for phorate protection. If handled indoors, provide mechanical exhaust ventilation. Do not store near food or feed products. Keep out of reach of children and domestic animals. Bury spillage; wash area thoroughly with o solution containing 1 lb. soda ash per gallon of woter, to which a water-soluble wetting agent has been added. Empty containers are to be destroyed by burning or burying; never re-use. Stay out of smoke when burning containers. . poison Pint AM (Sam* Pint AM at far Parathlan) Natat Par certain appikaflMR, Dlrectlani tar Ilia may naad la Include mare detailed InStructIans tar irfa hattdMnf at INIs praduct and material* treated with It. Labels should aha baar statements relatWa ta tha pratacriaa at partans and animals In treotad and 140 MONS 095819 POTASSIUM CYANATE CAUTIONI Avoid breathing dust or spray mist. Avoid prolonged or repeated contact with skin. Wash thoroughly aftor spraying. RONNEl (0,0-DIMETHYL 0-2,4,3-TR!CHlOROPHENYL PHOSPHOROTHIOATE) 1. Dry Formulations (10% to 30% Inel.Jt CAUTIONI HARMFUL IP SWALLOWED Avoid prolonged breathing o! dust or spray mist. Avoid prolonged or repeated contact with skin. Wash thoroughly with soap and water after handling and before eating or smoking. Avoid contamination of feed, foodstuffs, and water supplies. Keep out of the reach of children. 2. Solutions or Kmultiflablo Formulations: Since vertom letvenfi wtikh differ In tek prepcrtltt my be used, label* ittewld beer pracentlewery Iwtanwrlen e*erlnf the cemWned heierd* et renttel end telvenf. SODIUM CHLORATE WARNINOf STltONO OXIDANT CONTACT WITH OTHER MATERIAL MAY CAUSf Nil Clothing and vogatation contaminated with chlorate or its solutions ore DANGEROUSLY HAMMAIU. Remove clothing and wash thoroughly with water. Keep persons and onimels off treated areas. Spillage may causa fires. Do not get on floor. Sweep up ond . remove immediately' When not in usa keep tighHy dosed in original metal container. Keep away from fire. Store separately from flommoble moteriot. 141 MONS 095820 SODIUM FLUORIDE WARNINOI MAY IE FATAL IF SWALLOWED Avoid breathing dud. Wash thoroughly after handling. Cl*an up spillage. SODIUM FLUOSILICATE CAUTIONI HARMFUL IF SWALLOWED Avoid prolonged breathing of dust or spray mist. Avoid contamination of food and foodstuffs. Koop away from childron and domostic animals. Cloan up spillago. SODIUM TRICHLOROACETATE WARNING) IRRITATING TO SKIN AND EYES MAY CAUSE EURNS Do not got in eyes. Avoid contact with skin and clothing. Avoid broathing spray mist. In caso of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Remove contaminated clothing and wash before refuse. 142 HONS 095821 STRYCHNINE and STRYCHNINE SALTS (any H*ctiv* concentration) DANOMI POISONOUS IF SWAUOWID Do not braotho dust. Wash thoroughly after handling and bafora ooting or smoking. Sloro away from and do not contaminate food ond foodstuffs, Kap children, pats, and domutic animals away; aspacially from boitad araos. POISON (Antldol*) 2,4,5-T (2,4,5>TRICHLOROPHENOXYACETIC ACID and D*rivativ*t) -- Sam* labels as 2,4*D TETRACHLOROPHENOLSam* fob*/* as PENTACHLOROPHENOL 143 MONS 095828 TETRAETHYL PYROPHOSPHATE (any tttactiv concintration) DANOIRI POISONOUS Y SKIN CONTACT, INHALATION, OR SWALIOWINO RAPIDLY ASSORRID THROUOH SKIN RIPIATSD IXPOSURI MAY, WITHOUT SYMPTOMS, I INCRIASINOIY HAZARDOUS 0 not gil In ayit, on skin, on clothing. Wear dean heavy rubber gloves and goggles, Wear clean water* proof or freshly*laundered protective clothing (coveralls, cop. etc.). Replace gloves frequently and destroy used gloves. Wash thoroughly with soap and worm water before toting or smoking. Bathe immediately after work and chonge all clothing. Wash clothing thoroughly with soap and hot water before re-use. In case of contact, immediately remove contaminated clothing and wash skin thoroughly with soap and water; for eyes, Rush with plenty of water for at least 15 minutes end get medical attention. . Da not breathe duet, vaper, or spray miet. Wear mask or respirator of a type passed by the U. $. Depart ment of Agriculture for tetraethyl pyrophosphate protection. Airplane pilots should wear full-face canister-type mask. if handled Indoors provide mechanical exhaust ventilation. Oe not store near food or feed products. Keep out of reach of children end domestic animals. Bury spillage; clean up area with strong lye solution. Burn or bury containers; never re-use. Stay out of smoke when burning containers. poison First Aid (Same First Aid as far Parathien) MWi USili rKvmM kw tTMtsd and d|Mnt irtfi. rUtiv th p*Dltcfton *1 pdyrmr *nd nimnl* in 144 MOWS 095823 THALLIUM SULFATE (any affaetiva concan(rafion) DANOIRI CUMUUTIVI POISON ABSORRRD THROUOH SKIN Do not got In eyes. on skin, on clothing. Wosh thoroughly after hondllng ond before eating or smoking. Store ctwoy from and do not contaminoto food and foodstuffs. Keep childron, pots ond domoslic onimols away, especially from baited areas, burn all pests killed. JL poison JL> (Anlld.l.) THIOCYANATES lmN of rtie dlfferente* in pr*yerfle at members at rtil* %*np, *e*H product eentelninf ffcem must be reviewed Individually In llM el in vwn RheretlerliMc*. THIRAM (any atfactiva concantration) CAUTIONI MAY CAUSI IMITATION OP IYU, NOM, THROAT, AND SKIN HARMPU1 IP INHAIID OR SWAUOWSD Avoid breathing dust or spray mist. Avoid contact with skin, ayes, and clothing. In cose of contact, flush skin or eyes with plenty of water; for eyes, get medical attention. Netci Per senate eepPcertee*. OirecMem for Um mey need re Include mere deteiled In. itrwcrteM ter Ike *efe heedHeg ef this product end materiel* treated with It. 145 MONS 09582<t TOXAPHENE 1. Dry Formulations (25% and ovor): WARNING! MAY II FATAL IF SWALLOWED MAY BE HARMFUL BY SKIN ABSORPTION Avoid breathing dust or spray mitt. Avoid contact with skin, oyei, and clothing. Wash thoroughly aftor handling. . 2. Dry Formulations (lass than 23%): CAUTION! HARMFUL IF SWALLOWED Avoid prolongad braothing el duit or tproy mill. Avoid contact with skin, eyes, and clothing. Woth thoroughly altar handling. 3. Solutions or Emuisiftablo Formulations: Sine* varievs sehrenti which differ in toxic propcrtloi moy bo vied, label* should boor the precautionary information covering tho combined hoiordi at texophono and solvent. N*TRICHLOROMETHYLTHIOPHTHALIMIDE Sam* labal at CAPTAN TRICHLOROPHENOL (all isomors) CAUTtONI MAT CAUSI SKIN IRRITATION Avoid prolongad or rapaatad contact with skin. Do not toko Intarnolly. 14* MQNS 0958x25 WARFARINSam* labels at 3-(alpha-ACETONYLFURFURYl)-4> HYDROXYCOUMARIN and SODIUM SALT ZINC ARSENITE - Sam* lab*/ at CALCIUM ARSENATE ZINC PHOSPHIDE FORMULATIONS (10% and ov*r) WARNING! POISONOUS IF SWAUOWID Oo not breathe butt or vopor. Woih thoroughly after handling and bafora eating or smoking. Store away from and do not contaminate feed and foodstuffs. Keep children, pets, and domestic animals away; especially from baited areas. A. poison JL (Antidot.) ZINEB (any ffectiva concmntration) CAUTION1 MAY CAUSI IRRITATION OP 1Y1S, NOSR, THROAT, AND SKIN MAY 1 HARMPUl IP INHALED OR SWALLOWED Avoid breathing dust or spray mist. Avoid contact with skin, eyes, and clothing. In cose of contact, flush skin or eyes with plenty of water; for eyes, get medical attention. `Keep away from Are or sparks. *Fqr dust mtxtwqt 40% n4 %v*r, nd lot Ipwpqr caMantrations it di)u*A> Is combutHW*. Z1RAM (any *ff*cfiv* conc*n(ration) -- Sam* label at ZINEB 147 HONS 095826 Not** PRINTED IN THE UNITED STATES OF AMERICA MQNS 0958<>7 BENZYL CHLORIDE (Stabilized) WARNINOl CAUSES BURNS Avoid contqcf with skin, eyes, and clothing. Avoid breathing vapor. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minute*; for eyes, get medical attention. MCA Chemttel Safety Oete Sheet lB4t available BENZYL CHLORIDE (Unstabilized) WARNINOl CAUSES BURNS CONTAMINATION MAY RESUIT IN DANGEROUS PRESSURE Keep dry and handle only In suitable equipment to prevent metallic contamination. Consult manufacturer. Avoid contact with skin, eyes, and clothing. Avoid breathing vapor. In case of contact, immediately flush skin or eyes with plenty of water for ot least 15 minutes; for eyes, get medical attention. MCA Chemtset lefety Pete $h*t 10-49 available BERYLLIUM OXIDE POWDER OANOIRI HAZARDOUS DUST Oonot breathe dust. Use with adequate ventilation. Avoid contact with skin, eyes, and clothing. Wash thoroughly after handling. Wash clothing before refuse. Keep container tightly dosed. Flush container dean before discarding. Avoid spillage. If any occurs, carefully wet down and remove. poison Call A Phytlclan PlrM Aid 41 HONS 095720 BROMINE DANOIRI CAUSES SEVERS BURNS VAPOR HAZARDOUS . Do not got in eyes, on skin, on clothing. Do not brootho vapor. Uio only with adoquoto vontilotlon. Woor goggles, neoprene rubber gloves, ond rubber protective doth* ing when handling. In cose of contact, immediately remove oil contaminated clothing, including shoes, and flush skin with plenty of water for ot least 15 minutes. Plush eyes for at least 30 minutes. Get medical attention In ail coses. Wash clothing before re-use. If inhaled, move patient to fresh air, keep him warm and quiet until physician arrives. MCA Chemical Safety Pete Sheet SCM9 evailehle BUTADIENE (Inhibited) DANOIRI IXTRIMKIY FLAMMABLE MAY FORM EXPLOSIVE PEROXIDES ON EXPOSURE TO AIR Keep away from heat, sparks, and open flame. Keep container closed. Use with adequate ventilation. MCA Chemical Safety Pete Sheet SO>SS eveilehle BUTYL ACETATE (normal) Same lab*/ as AMYL ACETATE (mixed isomer*) BUTYL ALCOHOL (normal or secondary) WARNINOI LIQUID CAUSIS IYI BURNS Keep away from heat and open flame. Avoid contact with the eyes. Avoid prolonged breathing of vapor. Use with adequate ventilation. Avoid prolonged or repeated contact with skin, in case of contact with eyes, immediately flush with plenty of water for at leost 15 minutes. 42 MGNS 095721 BUTYL ALCOHOL (tortiory)Som* fabml at ETHYL ACETATE BUTYLAMINE (normal) WARNINOI NAMMABLI CAUSIS BURNS Keep away from hoar, sparks, ond opon flame. Koop container closed. U*o with adequate vontilation. Avoid broothing vapor. Avoid contact with skin, eyos, and clothing. In caio of contact, immodiatoly flush skin or oyo with plonty of wator for at least 15 minutes; for eyes, got medical ottontion. Remove and wash clothing before re*use. BUTYLCATECHOL (para-Urtiary) WARNINOI CAUSIS SKIN IRRITATION CAUSIS BURNS WHIN MOIST Do not got In oyoi, on ikin, on clothing. In cot# of contact, immodiatoly wash ikln with soap and plonty of wator; flush oyos with wator for at loait 15 minutes ond got medical ottontion. BUTYL CHLORIDE (normal) DANOIKI KXTMMHY KAMMAUI Koop away from hoot, sparks, and opon flame. Koop container closed. Use with adequate ventilation. Avoid prolonged breathing of vapor. Avoid prolonged or ropoafod contact with skin. 43 HONS 09572e BUTYL ETHER (normal) CAUTIONI TINDS TO FORM EXPLOSIVE PEROXIDES ESPECIALLY WHEN ANHYDROUS Keep away from hoot and optn flam*. Ute with adequate ventilation. Avoid prolonged breathing of vapor. Avoid prolonged or ropoatod contocf with skin. Do not allow to ovoporato to noar drynett, Addition of wator or appropriate reducing agents will losson peroxide formation. BUTYLLITHIUM (normal) (25% or lot* in hydrocarbon solvents) DANSERI EXTREMELY FLAMMABLE IONITES ON CONTACT WITH MOIST AIR CAUSES BURNS DO NOT HANDLE OR USE UNTIL SAfETY PRECAUTIONS RECOM MENDED BY MANUFACTURER HAVE BEEN READ AND UNDERSTOOD. Handle under inorf got atmosphere in DRY equipment. Keep away from hoot, tparkt, and opon Romo. Avoid spillage and contact with moisture or combustibles. Do not got in eyet, on tkin, on clothing. Wear goggles and protoctiv# clothing whtn handling. In caio of Are, uio CO* Are extinguisher. In cat# of contact, immediately Ruth ikln with plenty of water; for eyes, Ruth with plenty of water for at least 15 minutes ond get prompt medical attention. Remove and wath clothing before refute. BUTYRAIDEHYDE (iso or normal) OANOiM EXTREMELY FLAMMABLE VAPOR HARMFUL Keep away from heat, tparkt, and open flame. Keep container doted. Ute with adequate ventilation. Avoid contact with eyet, skin, or clothing. In caee of contact, immediately remove contaminated clothing, in* eluding thoei, and Ruth tkln or eyet with plenty of wottr for at leotf 15 minutot; for eyet, get medical attention. Wath clothing thoroughly before re-uie. MCA Cktiwkel foMy Ihoot S0*7t eveilebl* 44 HONS 095 723 CALCIUM CYANIDE DANOIM POISONOUS SOUD UIIRATIS POISONOUS OAS Do not take internally. Do not breathe got or dust. Do not got in eyes, on skin, on clothing. Wash thoroughly after handling. Keep container tightly closed and away from water or acids. Clean up spillage immediately. Keep away from feed or food products. In case of contoct, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Wash contaminated clothing before refute. POISON First Aid Carry patient to fresh oir. Have him lie down. Remove contaminated clothing but keep patient warm. Start treatment immediately. Call a physician. Antidote If Cyanide Oas Is Inhaled: Break an amyl nitrite pearl in a cloth and hold lightly under nose for 15 seconds. Repeat 5 times at about 15-second intervals. Use artificial respiration if breathing has stopped. If Cyanide is swallowedt Break on amyl nitrite pearl In o cloth and hold lightly under nose for 15 seconds. If patient is con scious, or when consciousness returns, give emetic (1 tablespoonful of salt to each glass of warm water) ond repeat until vomit fluid is clear. Repeat inhalation of amyl nitrite 5 times at about 15-second intervals. Use artifleiol respiration if breathing has stopped. Never give anything by tneuth to on unconscious porton. MONS 095724 45 CARBON DIOXIDE, SOLID ("DRY ICE") WARNINOI IXTRIMIIY COLO <KF. bolow zero) CAUSIS SSVIRI BURNS LIBIRATtS HCAVY OAS WHICH MAY CAUSI SUFFOCATION Do not got on skin or bonds. Do not taito. Oo not put in stopporod or dotad contoinor*. Do not ontor placos where utod or storod until adequately ventilated. CARBON DISULFIDE DANGKRI IXTRIMIIY FUMMABLI VAPOR HARMFUL HIOHLY VOLATILI Koop away from fire, sparks, or hootod surfacos. Sloro in eooi placo and koop contoinor dosod. Uso only with adequate vontilotion. Avoid breathing vapor. Avoid contact with skin and oyos. J|* POISON 4k Call A Physician First Aid MCA Cksmlcel feisty Dot* Sksst MM2 sveileMe 46 MONS 095725 CARBON TETRACHLORIDE DANOERI HAZARDOUS VAPOR AND LIQUID MAY M RATAL IP INHALED OR SWALLOWED Use only with odequote ventilation. Do not breathe vapor. Avoid prolonged or repeated contact with skin. Do not take internally. 4k poison 4k Coll A Physician Pint Aid MCA Cfiemkel Safety Qete Skeel |p*3 eveliebU CAUSTIC POTASHSam label as SODIUM HYDROXIDE MCA Chemical Set*y 0 Sheet 10*10 available CAUSTIC SODASome label as SODIUM HYDROXIDE MCA CHemkel hlttf Dot* Sheet 10>t iiwIMI* CHLORAL DANOCRI IXTRIMEIY HAZARDOUS LIQUID AMO VAPOR INHALATION MAY CAUSi DILAYKD FATAL LUNO INJURY Do not got in eyes, on skin, on clothing. Do not broarho vapor. Ubo only with adequate ventilation. . In coso of contact, immediately Rush skin or oyos with plenty of wator for at toast IS minutes; for eyes, got medical attention. In cose of inhalation or suspicion of inhalation, move patient at once to fresh atr and call a physician. Keep patient absolutely quiet and start oxygen inhalation through suitable equipment. WGNS 095726 47 CHLORINATED DIPHENYL (MONO, Dl, or TRI) Sam* label at CHLORINATED NAPHTHALENE CHLORINATED DIPHENYL OXIDE (MONO, Dl, or TRI) Sam* label as CHLORINATED NAPHTHALENE CHLORINATED NAPHTHALENE (For TRI and HIGHER CHLORINATED NAPHTHALENES) CAUTIONI Avoid repeated contact with skin. Avoid repeated inhalation of fumes and dust. CHLORINE DANGER! HAZARDOUS LIQUID AND GAS UNDER PRESSURE DO NOT HANDLE OR USE UNTIL SAFETY PRECAUTIONS RECOM MENDED BY MANUFACTURER HAVE BEEN READ AND UNDERSTOOD. Do not breathe air containing this gas. Do not got in eyes or on skin. Do not heat cylinders. Hovo available emergency gas masks approved by U.S. Bureau of Mines for Chlorine service. In case of exposure, move patient to fresh air, keep him warm and quiet, and call a physician. MCA CKmnIcbI tahfy D*K Sh**t SO-SO Rvallafct* 4S mons 0957^7 CHLOROBENZENE (MONO) WARNINOI VAPOR HARMFUL Keep away from heat and open flomt. Use only wirh adequate ventilation. Avoid contoct with ikin ond clothing. Avoid prolonged breathing of vapor. CHLOROFORM WARNINOI VAPOR HARMFUL Ult only with adequate ventilation. Avoid breathing vapor. Avoid prolonged or repeated contact with skin. Do not take internally. CHLOROPHENOL (MONOCHLOROPHENOL) (ortho, mota, or para) -- Same label as CRESOL CHLOROSULFONIC ACID DANOIRI CAUSU SiVIRf (URNS Do not get in eyei, on ikin, on clothing. Avoid breathing vapor. In cate of contact, immediately fluih ikin or eyes with plenty of water for at leait 15 minute*; for eye, get medical attention. Do not allow water to get into container became of violent reaction. MCA ChBfRkel lefety Pete thee* tP49 evelleble CHLOROTOLUENE (MONO) CAUTION! VAPOR HARMFUL Keep away from heat and open Acme. Use with adequate ventilation. Avoid prolonged breathing of vapor. HONS 49 095728 CHROMIUM TRIOXIDE (CHROMIC ACID) OANOERI STRONG OXIDANT CONTACT WITH OTHKR MATERIAL MAY CAUSE FIRE MAY CAUSE BURNS OR EXTERNAL ULCERS . Keep container dosed. Do not got in eyes, on skin, on clothing. Do not breathe dust or mist from solutions. In cos* of contact, immediately flush skin or eyes with plenty of wotor for at least 15 minutes; for eyes, got modicoi attontion. Wash clothing before re-use. List fresh clothing doily. Take hot shower after work, using plenty of soap. MCA Chemical Safety Data Sheet 10*44 available CREOSOTE OIL (COAL TAR CREOSOTE) CAUTIONI MAY CAUSE SKIN IRRITATION1 Avoid prolonged or repeoted contact with skin. Avoid prolonged breathing of vapor. Use with adequate ventilation. CRESOL (CRESYLIC ACID) DANOERI HAZARDOUS LIQUID RAPIDLY ABSORBED THROUGH SKIN CAUSES SEVERE BURNS Do not get in eyes, on skin, on clothing. Avoid breathing vapor. Do not take internally. In case of contact, immediately remove all contaminated clothing, including shoes, and flush skin or eyes with plenty of wotor for ot least 15 minutes; for eyes, get medical attention. Wash clothing before re-use. MCA OweliU Safety Oata Sheet S0-4S available so MONS 095 72 9 CYANIDES, INORGANIC {excluding HYDROCYANIC ACID and CALCIUM CYANIDE) INAMI Of CrANIM) DANOIRt POISONOUS SOLID CONTACT WITH ACID UBSRATB POISONOUS OAS Do nor breathe got or dust. Do nor rako internally. Avoid contact wirh eyes and skin. Wash thoroughly after handling. Keep container doled and away from acldi. Store in o dry place. Keep away from feed ond foodstuffs. In cose of contoct with eyes, flush with plenty of water for at least ) 5 minutes and get medico! attention. * poison A* Piref Aid Carry patient to fresh air. Have him lie down. flemove contaminated clothing but keep patient warm. Start treatment immediately. Call a physician. Antidote if Gas is inhaledt Break an amyl nitrite pearl in a doth and hold lightly under nose for 15 seconds. Repeat 5 times at about \ 5**econd Intervals. Use artificial respiration if breathing has stopped. If swallowed: Break an amyl nitrite pearl In a doth and hold lightly under nose for 15 seconds. If patient is conscious, or when consdousness returns, give emetic (1 tablespoonful of salt to each glass of warm water) and repeat until vomit fluid is clear. Repeat Inhalation of amyl nitrite 5 times at about 15-second intervals. Use artificial respiration if breathing has stopped. Never give anything by mouth fa an unconscious person. MCA ehsmhd Safer Stow ISM eveileM* to SOOIUM CYANIM 5t HONS 095730 CYCLOHEXANE DANGER) EXTREMELY FLAMMABLE Keep away from heat, iparki, and pen flam*. Keep container dosed. Uia with adaauata ventilation. Avoid prolonged breathing of vapor. MCA Chtnltii Safety Oata fhtat S0*4l available CYCLOHEXANOL CAUTIONI VAPOR HARMFUL Use only with adequate ventilation. Avoid prolonged breathing of vapor. Avoid prolonged or repeated contact with skin. CYCLOHEXANONE CAUTIONI VAPOR HARMFUL Keep away from heat and open flame, llte only with adequate ventilation. Avoid prolonged breathing of vapor. Avoid prolonged or repeated contact with skin. 52 HONS 095731 DECABORANE OANQIRI HAZARDOUS SOilD AND VAPOR POISONOUS IP INHALED, 5WAUOW1D, OR AftSORfttD THROUGH SKIN FORMS SHOCK-SENSITIVE MIXTURIS WITH CIRTAIN OTHCR MATIRIAIS DO NOT HANDLE OR USE UNTIL SAFETY PRECAUTIONS RECOM. MENDED BY MANUFACTURER HAVE BEEN READ AND UNDERSTOOD. Always wear a self-contained breofhing apparatus or full-fact airlint rttpiratar whtn using this chtmicol. Do not get in tyts, on skin, on clothing. Do not brtatht vapor. Kttp from contact with oxidizing mattrials, highly oxygenated or halogenaftd solvents, organic compounds containing rtduciblt functional groups, or aqueous ammonia. In cast of contact, immtdiottly wash skin with soap ond pltnty of wattr. Flush tyts with wattr for at itast 15 minutts and gtt medical atftntion. Rtmovt and wash clothing btfor# rt-ust. poison Call A Physician First Aid Movt patitnt to frtih air; kttp him warm and quit!. If swallowed* If conscious, givt a tabltspoonful of salt in a glass of warm wattr and rtptat until vomit fluid is cltar. Nat# It physician; Treat symptomatically. Symptoms may bt delayed up to 48 hours after suspected exposure. Allow rest; keep under observation. Administration of methocarbamol or other muscle rekixants may be helpful immediately following exposure and in absence of symptoms. 53 MONS 095732 DIBORANE DANOIRI EXTREMELY FLAMMABLE GAS UNDIR PIIUUKK EXTREMELY IRRITATING IF INHALBO . RIACTS VIOLENTLY WITH OXIDIZING MATERIALS DO NOT HANDLE OR USE UNTIL SAFETY PRECAUTIONS RECOM MENDED BY MANUFACTURER HAVE BEEN READ AND UNDERSTOOD. Kp away from hoot, sparks, and open flome. Do not breathe gas. Use only with odopuoto ventilation. Have available emergency self-contained breathing apparatus, or full-face air-line respirator when using this chemical. Keep from contact with oxidizing materials. Note: This gas deadens the sense el smell. Do net depend on odor to detect presence of gas. POISON .& Call A Physician First Aid Move patient to fresh air; keep him warm and quiet. Note te physician: Treot as irritant gas. Administration of oxygen and bronchodilators may be helpful. DICHLOROBENZENE (ortho) CAUTIONI VAPOR IRRITATING Avoid prolonged breathing of vapor. Avoid prolonged or repeated contact with skin. If liquid gets in eyes, immediately flush thoroughly with plenty of water. MCA ChwMsnt fefoty Sfcwt SO-SS gvgUgWo 54 MONS 095 733 DICHIOROETHYLENE WARNINOI FLAMMABLE Keep owoy from hoof, sporki, and open flam*. Keep container closed. Us* with adequate ventilation. Avoid prolonged or r*p*ot*d breathing of vapor. Avoid prolonged or repeated contact with skin. Do not take internally. DICHLOROETHYL ETHER DANGER! MAY II FATAL IF SWALLOWED, INHALED, OR ABSORBED THROUGH SKIN Do not get on (kin or clothing. Do not breath* vopor. Us# only with adequate ventilation. Do not take internally. In ceie of contact, immediately remove contaminated clothing and flush skin or eyes with plenty of water for at least 15 minut*. Wash clothing before re-ute. POISON Call A Physician First Aid 2.4.0ICHLOROPHENOI WARNINOI CAUSES BURNS Avoid contact with eyes, skin, and clothing. Avoid breathing vapor. Do not take internally. In cost of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Remove and wash clothing before re-use. 55 MGN5 095734 DIETHYLAMINE -- Sam* labsl as METHYLAMINES, AQUEOUS SOLUTIONS MCA ChaMiMl hM) O-M. kM W-.r In MlmTUMINII DIETHYLENETRIAMINE DANQIRI CAUSIS KVHtl IYI AND SKIN BURNS Do no* got in oyos, on skin, on clothing. Avoid prolongod or ropoatod broathing of vapor. In caso of contact, immodiatoly flush oyos or skin with plonty of wator for cit (tost 15 minutos; for eyot, got prompt modicai attention. Romovo contaminotod clothing, including shoos. Wash clothing boforo rouso/ discord contaminotod shoos. MCA Chemlcol Safety Por* Sheet ID-7* ovotfehle - DIMETHYLAMINE, ANHYDROUS DANGIRI IXTRIMCLY FLAMMAILI HAZARDOUS LIQUID AND VAPOR UNDIR PRRSSURI LIQUID CAUSIS SURNS VAPOR 1XTRKMILY IRRITATING Koop away from hoot, sparks, and opon flamt. Uio only with adequate vontiiation. Do not brootho vopor. Do not got In oyos, on skin, on clothing. In coso of contact, immadlatoiy Rush skin or oyos with plonty of wator for at toast 15 minutos. Wash dothiog boforo ro-uso. Call physician at onco in cato of burnt, ospociolly to oyos, noso, and throat, or If paHont Is unconscious. Havo aMino rospirotor or loif-containod oxygon rotpirator ovailablo for owargoncy. hrMCA CtimHri lofety Dot* Sheet IM7 evottehJe MfTttYLAMlMtS 36 MGNS 095 DIMETHYL SULFATE DANGER! EXTREMELY HAZARDOUS LIQUID AND VAPOR CAUSES SCVCRR BURNS Do not got in oyos, on skin, on clothing. Do not brootho vapor. Usa only with adoquata vontilation, Woar gogglas and rubbor giovo* whan handling. In caia of tpiilaga, covar immadiotaly with dry soda ash. POISON sj|< Call A Physician Pint Aid Start traotmant immadiotaly. Eyas-. flush with wotar for at loosf 15 minutas. Skint Romovo oil contominatad clothing ond Rush skin with wotar for of loast IS minutas. Inhalation: if braothing bacotnas difficult, start oxygan inhalation through suitobla oqvipmant. MCA Chamf**! UfWy Bt) Sham WMt avaUoM* DIOXANE {1,4-DIETHYLENE DIOXIDE) WARNINOI FLAMMABLE VAPOR HARMPUi TENDS TO FORM EXPLOSIVE PEROXIDES ESPECIALLY WHEN ANHYDROUS Kaap away from hoot, sparks, ond opan Roma. Kaap contolnar cioiad. Usa only with adoquata vantilotlon. Avoid prolongod braothing of vapor. Avoid prolongod or rapaatad contact with skin. Do not allow to avoporoto to noar drynoss. Addition of wotar or oppropriata reducing ogant will lassan poroxido formation. 57 HONS 095736 ETHYL ACETATE WARNINOI FIAMMABLR Kp away from hoof, sparks, and opn flam#. Keep container closed. Use with adaquota ventilation. Avoid prolonged breathing of vapor. Avoid prolonged or repeated contact with skin. MCA Chemical lately Pete Sheet ID>I1 avertable ETHYL ACRYLATE (Inhibit9<i with.................. ) WARNINOI FLAMMABLI VAPOR HARMFUL MAY IRRITAU SKIN AND IYIS Keep away from heat, sparks, and open flame. Keep container closed. Use only with adequate ventilation. Avoid breathing vapor. Avoid contact with skin, eyes, and clothing. In ease of contact, immediately flush skin or eyes with plenty of water for ot least 15 minutes; for eyes, get medical attention. Remove and wash contaminated clothing before refuse. MCA Chamtcal Safety Pens Sham MMS avartaW* ETHYL BROMIDE WARNINOI VAPOR HARMFUL Uio only with odeqvate ventilation. Avoid prolonged breathing of vapor. Keep container closed, out of run, and away from heat. ss MQNS 09b 73 7 ETHYL CHLORIDE DANOIRI IXTMMIIY FLAMMASLi Keep away from heat, iparki, and opto ftame. Use with adequate ventilation. Keep container closed, out of sun, and away from hoot. MCA Chemical Safety Data Sheet SMQ available ETHYL ETHER DANQIRl IXTRiMIlY KAMMAftll HIGHLY VOLATtll TINGS TO FORM IXPLOSIVt PIROXIDCS 6SPCC1ALLY WHIN ANHYDROUS Keep away from heat, sparks, and open-flame. Keep container tightly dottd. Do not allow to evaporate to noar dryness. Addition of wafor or appropriato reducing agent will lessen peroxide formation. MCA Chemical Safety Pate Sheet tD>2t avallahie 59 HONS 095738 ETHYLENE CHLOROHYDRIN (ANHYDROUS or 38%) DANOERI EXTREMELY HAZARDOUS LIQUID AND VAPOR MAY If FATAL IP SWALLOWED, INHALID OR AISORUD THROUGH SKIN ' CAUSIS BURNS TO IYKS Do not got in eyes, on skin, on clothing. Ordinary rubber protee> five clothing, including gJovos, will not prevent ikin abiorptlon. Do not breathe vapor. Use only with odequate ventilation. Do not toke internally. Keep away from heot and open flame. In caie of contact, immediately remove all contaminated clothing and fluih skin or eyes with plenty of water for at least 13 minutes; for eyes, get medical attention. Wash clothing before reuse. poison ^ Call A Phyticlan First Aid If swallowed: If conscious, make patient 'vomit immediately by putting finger down throat or by giving warm mustard water or salt water freely. General: Keep patient warm; if conscious, give black coffee. Note to Physician: Do not give adrenalin. ETHYLENEDIAMINE DANOERI CAUSIS SEVERE EYE AND SKIN BURNS Do not get in eyes, on skin, on clothing. Avoid breathing vapor. Keep away from heat and open flome. In case of contact, immediately flush eyes or skin with plenty of water for at least IS minutes; for eyes, get prompt medical attention. Remove contaminated clothing, including shoes. Wash clothing before refuse; discard contaminated shoes. This product freeies at approximately 50F.* * Addlttee te "Ceetetaer Handling end Staraga", Page 24. 60 MQNS 095739 ETHYLENE DICHLORIDE WARNING) FLAMMABII VAPOR HARMFUL Keep away from heot, sparks, ond open flam*. Keep container closed. Use only with adequate ventilation. Avoid prolonged or repeated breathing of vapor. Avoid prolonged or repeated contact with ikin. Do not toke Internally. MCA ChenlreJ Safety date Shew 10-tl available ETHYLENE OXIDE DANOIRI KXTREMILY FLAMMABLK VAPOR HARMFUL MAY CAUSI BURNS Keep owoy from heot, sporks, and open flame. Keep container doted. Avoid breathing vapor. Avoid contact with skin, eyes, and clothing. In case of contact, immediately remove all contaminated clothing, including shoe*, ond flush skin or eyes with plenty of water for at least 13 minutes; for eyesr get medical attention. Wash clothing before re-use. Discard contaminated shoes. MCA Cknlul Safety D Sheet tOJt evellaW* 61 MGNS 095740 FORMALDEHYDE SOLUTION WARNING! CAUSIS IMITATION OF SKIN, CYKS, NOSt, AND THROAT Avoid prolonged or repeated contact. Avoid prolonged breathing of vapor. Use with adequate ventilation. In caie of contact, immediately flush thin or eyes with plenty of water for at leost 15 minutes; for eyes, get medical attention. 4^ POISON Call A Physician First Aid If swallowed; Give a tableipoonful of soft in a glass of warm water and repeat until vomit fluid It clear. Give milk or white of egg beaten with water. MCA Chemical Safety Pete Sheet SfH available FORMIC ACID Soma label as HYDROCHLORIC ACID HYDROCHLORIC ACID WARNINOl CAUSIS IURNS Avoid contact with skin and ayes. Avoid breathing vapor. In cose of contact, Immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. MCA Chemical Safety Pate Sheet IPO* available 62 MQNS 095741 HYDROCYANIC ACID DANOCRI IXTRKMUY HAZARDOUS LIQUID AND GAS IXTRIMiLT FLAMMABLE MAY Iff FATAL IF SWAllOWCD, INHALED, OR ABSORBED THROUGH SKIN USE ONLY IN A CLOSED SYSTEM. Keep awoy from heat, sparks, and open flam*. Do not take internally. Do not breathe got. Do not got In eyes, on skin, on clothing. In cat# of contact, immediately flush skin or oyot with plonty of wator for at loott 15 minutes? for oyot, got modical attontion. Wash contaminated clothing boforo re-use. vR. POISON First Aid Carry patlont to froth air. Havo him llo down. Remove contaminated clothing but keep pationt warm. Start treatment Immodiotoly. Coll a physician. Anridoto If Cyonldo Oas It inhaled: Broak on amyl nitrite pearl in a cloth and hold lightly undor noto for IS seconds. Repeot 5 timoi at about 15-second intervals. Uio arriflelol respiration if breathing has stopped. If Cyonldo It swallowed: Break an amyl nitrite pearl in a cloth and hold lightly under nose for 15 seconds, if patient Is conscious, or when consciousness returns, give emetic U toblespoenful of sob to each glass of warm water! and repeat until vomit fluid is clear. Repeat Inhalation of amyl nitrite 5 times at about 15-iecond intervals. Use artificial respiration if breathing has stopped. Hover give anything by mouth to on unconscious porson. 63 HONS Q95742 HYDROFLUORIC ACID, ANHYDROUS DANGER! IXTRIMBLY HAZARDOUS LIQUID AND VAPOR CAUSIS SKVCRI BURNS WHICH MAY NOT M IMMKDIATBIY PAINFUL OR VISIBLE ' Do not got in eyes, on skin, on clothing. Do not brootho vapor. Storo out of sun and away from diroct hoat. UNLOAD ONLY IN ACCORDANCE WITH PRACTICE RECOMMENDED IN MANUFACTURING CHEMISTS' ASSOCIATION, INC. MANUAL H-10. Road alio MCA Chemical Safety Data Shoot SO-25. First Aid, In Cate of Contact or Suspicion of Contact. Always have on hond a supply of Magnesia past# (magnesium oxide and glycerin). Skin: Immediately flush with large quantities of cold water until oil add Is removed (up to 3-4 hours or until medicol attention is obtained), paying particular attention to skin under nails. In case medical attention is delayed, apply a mixture of glycerin with either magnesium oxide or milk of magnesia. Oet medical often* tion. Remove and wash clothing before re-use. lyet: Immediately flush with cool water for 15-30 minutes; Prompt medical attention is absolutely necessary. MCA Chemkei Safety Pete Sheet SD-35 evellehle HYDROFLUORIC ACID, AQUEOUS DANOIRI HAZARDOUS LIQUID AND VAPOR CAUSES SEVERE BURNS WHICH MAY NOT BE IMMEDIATELY PAINFUL OR VISIBLE (In eddIHen te ebe*e Stetemenft, alt* intlud* helene* ter HYDROAUORIC ACID, ANHYDROUS) MCA Cheadtel Sefety Pete Sheet SP-3S evelleble jt,*teuUen*ry label r***nn**nd*d 64 MONS 095743 HYDROGEN CHLORIDE, ANHYDROUS DANOERt HAZARDOUS LIQUID AND OAS UNDER PRESSURE CAUSES SURNS EXTREMELY IRRITATING Do not breothe got. Do not got in oyos or on skin. In cose of contact, immediately flush tkin or syst with plonty of water for ot loott IS minutes; for eyes, got medical ottontion. *NOTEi Suck-back Into Cylinder May Couio Explosion. Under no circumstance* should the cylinder delivery tube be inserted in a liquid or gas without a vacuum break or other protective apparatus in the line to prevent tuck-back. MCA (hieksl fefty bote IHmi IMS eveflefcU HYDROGEN PEROXIDE 7.4% CAUTIONI STRONG OXIDANT Avoid contact with skin and eyes---wear rubber gloves and goggles. Avoid contamination from any source, including metals, dust, and organic materials. Such contamination may cause rapid decom position, generation of large quantities of oxygen gas, and high pressures. 'Store in original dosed container. 'Be sure thot the container vent Is working satisfactorily. * Do not add any other product to this container. 'When empty, rinse thoroughly with dean woter. MCA Ctmntsat Safety Data thaat NPH fwpplemeftt* A A I eveileltla * AddtHen te "Centalnet Headline and ftarofaM, Faya >4. 65 HONS 0957V* HYDROGEN PEROXIDE (strongmr than 7.4% but not xcaading 52%) CAUTION! STRONO OXIDANT Avoid contact with shin and eyes---wear rubber gloves and goggles. Avoid contact with combustible materials. Drying of this concentrated product on clothing or combustible material* may eause fire. In caio of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Remove and wash clothing at once. Avoid contamination from any source, including metals, dust, and organic materials. Such contamination may cause rapid decom* position, generation of large quantities of oxygen gas, and high pressures. 'Store in original closed container. *6e sure that the container vent is working satisfactorily. *Do not add any other product to this container. 'When empty, rinse thoroughly with clean water. MCA Chemical Safety Data Sheet 10-SI Supplement* At! available * AMMen *e "Centnlne? ManiHne and Starafa**, Pepe 24. 66 MONS 095745 HYDROGEN PEROXIDE, HIGH STRENGTH (ov#r 52%) DANOIRI POWIRPUL OXIDANT CAUSIS SSVIRI BURNS Do not got in eyes, on skin, on clothing. Wear goggles, rubber gloves, protective outer clothing, and heavy rubber shoes. Keep from contact with combuitible material*. Spill* on clothing or combustible material* will cause Are. Plush spillage with water. Keep from contamination from any source, including metals, dust, and organic materials. Such contamination ean cause rapid decomposition, generation of high pressure* or formation of explosive matures. in cos# of contact, immediately remove oil contaminated clothing and flush skin or ayes with plenty of water for at least IS minutes. OfT MfDICAL ATTfNTION. Wash clothing promptly and thoroughly. `HANDLING INSTRUCTIONS Do Not Open Unlese You Have Bean Properly Instructed, Store In original closed container. Store container in a cool, clean place. Keep drum in upright position. ' 0 not roll drum on side. Wash leakage with water. Put nothing else in this container. When Imply, Drain And Plush Container Thoroughly With Ctoan Water. . . Reploce Bunge Securely. MCA Chsmkel leftty Pete Ihsst ID-SJ tepehmswH A ft I aveiloMa 67 MQNS 095746 HYDROGEN SULFIDE DANGERI POISONOUS LIQUID AND GAS UNDER PRSSSURi FLAMMABLE BEFORE USING, READ MCA CHEMICAL SAFETY DATA SHEET SD-36 Do not breothe got. Keep away from heat, tparkt, and pen flam*--may form explosive mixture with air. NOTE: This got deadens tho sense of tmoll. Do not dopond on odor to dotoct presence of gat. POISON Coll A Phyticlan Pint Aid Carry potiont to froth air. If potiont hoi itoppod breathing, apply artificial respiration imme diately. Keep patient warm. MCA ChemUel lefety Date IHt $D4f *v*lt*tV* . ISOPROPYLAMINE DANGBRI EXTREMELY FLAMMABLE VAPOR EXTREMELY HAZARDOUS LIQUID CAUSES BURNS Keep away from heat, sparks, and open flame. Keep container closed. Do not breathe vapor. Use only with adequate ventilation. Do not got in eyas, on skin, on clothing. In coto of contact, immediately remove contaminated clothing, in cluding shoes, and flush skin or eyes with plenty of water for ot least IS minutes; for eyes, get medico! attention. Wash clothing before re-use. MCA dwHOcd Safety Date Sheet SD-7J available ISOPROPYL ETHER - Sams labal as ETHYL ETHER LEAD ACETATE WAKNINOI HARMFUL DUST Avoid breathing dust. Wash thoroughly before eating or smoking. Keep away from food or food products. LEAD MONOXIDE (LITHARGE) Same labal as LEAD ACETATE MCA Clwmleal fahly Data Dual 10-M avallaMa far IIAD OXIDII LEAD OXIDE (RED LEAD)Sama labal as LEAD ACETATE MCA Chamtiat Safety Oata Shear IP-44 availabfa MALEIC ANHYDRIDE WAKNINOI CAUSIS KUHNS Avoid contact with skin, oyos, and clothing. Avoid exposure to concentrated vapor. In case of contact, immediately Kush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. MERCURIC CHLORIDE (MERCURY BICHLORIDE) DANOIRI HARMFUL DUST MAY Bl FATAL IF SWAUOWSD Do not breathe dust or vapor. Avoid contact with eyes or prolonged contact with skin. Keep away from feed or food products. Wash thoroughly before eating or smoking. Usa fresh clothing dolly. Taka hot shower after work, using plenty of soap. . POISON Call A Phyaldan Tint Aid 69 MONS 095748 METHANOL DANOIRI FLAMMABLE VAPOR HARMFUL MAY ftl FATAL OR CAUSI BUNDNISS IF SWAUOWCD CANNOT II MADI NONPOISONOUS Koop away from hoot, sparks, end opon Romo. Koop contoinor closod. Avoid prolonged or ropoatod breathing of vapor. Uso only with adoquato vontilallon. poison Call A Physician First Aid If lwallowod: Givo a tablospoonful of salt in a glass of warm wator and ropoat until vomit fluid is cloar. Givo two toaspoonfuls of baking soda in a glass of wator. Havo pationt Uo down and koop warm. Covor oyos to oxdudo light. METHANOL MIXTURES ' Far pradvets cattaining mathanal In prapartla* swMUlanl la raata kaiard bacaata at mafhanal caatant, usa applkabls sHrtamanN abava, wHti add)Kan afi CONTAINS OVER........................% OF METHANOL Ttia ward "HAMMASLI" mar ha amlftad tram ha Statanwt af Natardt If tfca pradvet hoi flash paint abava 10*f. MCA Chandcsri lofaty Data Shaat SD*I2 avallabia 70 HONS 095749 METHYL ACRYLATE (Inhibited with.................. ) WARNINQI FLAMMAILI VAPOR HARMFUL MAY IRRITATI SKIN AND (Y(S Keep away from hoot, sparks, and open flame. Keep containor closed. Use or>fy with adequate ventilation. Avoid breathing vapor. Avoid contact with thin, eyes, and clothing. In cate of contact, immediately flush skin or eyes with plenty of water for ot lean 15 minutes) for eyeir get medical attention. Remove and woth contaminated clothing before re-uie. MCA Chemical Safety Pete Sheet Ihtt evettehte METHYLAMINES, ANHYDROUSSam# /a6#/ as DIMETHYLAMINE, ANHYDROUS MCA Chemitel Safety Deta Sheet SMS eveilaMe fer ITMTl ACITATI METHYLAMINES, AQUEOUS SOLUTIONS DANOIRI IXTRIMIIY MAMMABIC MAY CAUSI SKIN IRRITATION Keep away from heat, spark*, and open flame. Keep container closed. Use with adequate ventilation. Avoid exposure to vapor. Avoid contact with skin and eyes. In case of contact, flush skin or eyes with plenty of water for at ieost 15 minute*) far eyes, get medical attention. 71 MUNS 095750 METHYL BROMIDE DANOIR1 VAPOR IXTRCMIIY HAZARDOUS HIGHLY VOlATIll CAUSIS RURNS ' Do not breathe vopor. Do not got in eyes, on skin, on clothing. Keep away from hoot. In coso of contact, immediately romovo oil contaminated clothing, including shoos, ond wash skin thoroughly with soop and water; for eyes, flush with plenty of water for at least 15 minutes; get medical attention. Do not re-use shoes or clothing until free from all contamination. POISON . Call A Physician First Aid Remove patient to fresh air. Keep lying down and warm. Use artificial respiration if breathing has stopped. Get IMMIDIATI medico! attention. Use oxygen inhalator only at the direction of a physician. On Can label Add; IMPORTANT! The contents of this eon are under pressure. Do not use ordinary con opener. Special handling equipment is ovailable. Contact................ <"** <. equipment ond proper use. MCA Chemitel Safety Pate Sheet ID4) available .................. for information on MONS 095751 72 METHYL CHLORIDE WARN1NOI FLAMMAftll LIQUID AND OAS UNOIR PRKSSURI VAPOR HARMFUL Keep away from hoot, sparks, and open flam*. U> only with adequate ventilation. Avoid breathing vapor. Avoid contact with skin. MCA Chemical Safely Pete Sheet SIMO available METHYL ETHYL KETONESam* lafa.l as ETHYL ACETATE MCA Chemical Safety Data Shear ID-M available METHYL METHACRYLATE MONOMER WARNING! FIAMMARLI MAY CAUSI SKIN IRRITATION Keep away from hoot, sparks, and pen Rome. Keep containar dosed. Use with adequate ventilation. Avoid prolonged breathing of vapor. Avoid contact with skin, eyes, and clothing. METHYL MORPHOLINE WARNINGI HAZARDOUS LIQUID AND VAPOR MAY CAUSI SKIN IRRITATION PLAMMAILI Use with adequate ventilation. Avoid exposure to vapor. Avoid contact with skin and eyes. Keep away from heat, sparks, and open flame. Keep container dosed. 73 MOMS 09575^ MIXED ACID (SULFURIC and NITRIC) DANOCR1 CAUSIS SIVIRI BURNS VAPOR IXTRIMILY HAZARDOUS MAY CAUSI NITROUS OAS POISONING SPILLAOI MAY CAUSI FIRI OR UBIRATI DANOCROUS OAS . Do not breathe vapor. Do not got in eyes, on skin, on clothing. In cose of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; got medical attention. MCA Safety Data Shaat SD>iS available MONO-COMPOUNDS alternative chemical name, e.g., CHLOROPHENOL for MONOCHLOROPHENOL MORPHOLINE WARNINOl CAUSIS IYI BURNS MAY CAUSI SKIN IRRITATION ABSORPTION THROUGH SKIN HARMFUL Do not get in eyes. Avoid contact with skin or clothing. Keep away from heat and open flame. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Remove contaminated clothing and wash before re-use. MURIATIC ACID -- Sam* fab*/ as HYDROCHLORIC ACID MCA Ch.mk.1 MM, m HtMt KM. hr HYODOCHIOAIC ACID 74 MONS 095753 NAPHTHYLAMINE (alpha) (containing b.taNAPHTHYLAMINE)Samo /afar/ as NAPHTHYLAMINE (bta) MCA Chemicel UU*y Mm Shaet SO-41 avallaM* far tETANAPHTHYLAMINI NAPHTHYLAMINE (b*ta) WARNING! HARMFUL OUST ANO VAPOR REPEATIO ARSORPTION MAY RESULT IN ftLADDER TUMORS Ui< only with adequate ventilation, Avoid breathing dust or vapor. Avoid contact with skin. Wear freth clothing daily. Take hot thower after work, using plenty of soap. MCA Chamkal Safety Data Sheet S0*32 availed# NITRIC ACID DANOERI CAUSES SEVERE EURNS VAPOR EXTREMELY HAZARDOUS MAY CAUSE NITROUS GAS POISONING SPIUAOE MAY CAUSE PIRI OR LlftlRATI DANGEROUS GAS Do not breathe vapor. Do not get in eyes, on skin, on clothing. In cose of conloct, immediately hush skin or eyes with plenty of water for at least 15 minutes; get medical attention. MCA Chemise! Safety Date Sheet SD$ evelteMe 73 MONS 09575*. NITROANILINE (ortho, mota, or para) DANGERI HAZARDOUS SOLID AND VAPOR RAPIDLY ABSORBED THROUGH SKIN . Do not got in eyes, on skin, on clothing. Avoid broathing duit or vopor. Use only with adequate ventilation. In cos* of contact, immediately romov* oil contaminated clothing, including ihoes, and flush skin or *y*s with plenty of wator for at least 15 minutes; got medical attention. Woih clothing b*for* re-use. NITROBENZENE - Sam* label as ANILINE MCA Chtmfcoi Softty Dot* Shoot SD<31 eveileble OLEUM (FUMING SULFURIC ACID) DANGIRI CAUSIS SIVIRI BURNS Do not get in *y*s, on skin, on elothing. Avoid breathing vapor. In case of contoct, immediately flush skin or *y*s with plenty of water for at least 15 minutes; for eyes, get medico! attention. Do not add water to contents while in o container because of violent reaction. MCA Chemlsel Sefety Pete Shear SP> evellebfe fer SUtSUIIC ACIP OXAUC ACID WARNINOI HARMFUL IF SWAUOWID CAUSCS SKIN IRRITATION Avoid breathing dust. Avoid contact with skin and eyes. Do not take internally. Keep away from feed or food products. In case of contoct, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. 76 HONS 095755 PARAFORMALDEHYDE WARNING! CAUSIS IRRITATION OP SKIN, KYIS, NOSI, AND THROAT Avoid prolonged or repeated contact. Avoid breathing dust or proiongod breathing of vapor. Use with adequate ventilation. In coie of contact, immediately flush skin or eye* with plenty of water for at least 19 minutes; for eyes, get medical attention. 4k POISON 4k Call a Physician Immediately First Aid if swallowed: Give a tablespoonful of salt in a gloss of worm water and repeat until vomit fluid is dear. Give milk, or white of egg beaten with water. MCA Chemical Sefety Oefe Sheet 10*4 eveiteWe PARALDEHYDE CAUTIONI VAPOR HARMFUL Use only with adequate ventilation. Avoid prolonged or repeated breathing of vapor. Keep away from heof and open flame. Do not take Internally. * Solidifies ot obout S4P. {12C.) and may break container. * Store in a moderately warm place. MGNS 095756 77 PENTABORANE DANOIRI POISONOUS IF INHALIO, SWALLOWED, Oil ABSORBED THROUGH SKIN . EXTREMELY FLAMMABLE LIQUID UNDER PRESSURE FORMS SHOCK.SENSITIVI MIXTURES WITH CERTAIN OTHER MATERIALS DO NOT HANDLE OR USE UNTIL SAFETY PRECAUTIONS RECOM MENDED BY MANUFACTURER HAVE BEEN READ AND UNDERSTOOD. Always wear self-contained breathing apparatus or fuil-faee air-line respirator when using this chemical. Do not get in eyes, on skin, on clothing. Do not breathe vapor. Keep away from heat, sparks, and open flame. Keep from contact with oxidizing materials, highly oxygenated or halogenated solvents, and organic compounds containing reducible functional groups. in ease of contact, immediately wash skin with soap and plenty of water. Flush eyes with plenty of water for at least 15 minutes and get medical attention. Remove and wash clothing before re-use. vjR. POISON Call A Physician First Aid Move patient to fresh air; keep him worm and quiet. Note to physician* Treat symptomatically. Symptoms may be delayed up to 48 hours after suspected exposure. Allow rest; keep under observation. Administration of methocarbamol or other muscle relaxants may be helpful immediately following exposure and in absence of symptoms. MGNS 095757 78 PERCHLORIC ACID DANOIRI STRONG OXIDANT CONTACT WITH OTHIR MATSRIAl MAY CAUSK PIRK OR IXPIOSION, ESPECIALLY IP HKAT1D CAUSES 5EVCRR RURNS Keep container dosed and away from boat. Store separately from, and avoid contact with, dehydrating agents and other material*. Do not got in eye*, on skin, on clothing. In cose of spillage, Ruth with plenty of wafer and remove contom- mated article*. In cate of contact, immediately remove all contaminated clothing and fiu*h skin or eye* with plenty of water for at least \ 5 minutes; for eyes, get medical attention. Waih clothing before refuse. MCA CKemket lihly DM* Sheet MM I ewefleWe PERCHLOROETHYLENE (TETRACHLOROETHYLENE) Sam* labtl at TRICHLOROETHYLENE MCA Chemlcet Sefety IHNe Sheet SD-14 evelteWe PHENOL OANOERI HAZARDOUS LIQUID OR SOLID RAPIDLY ARSORBID THROUGH SKIN CAUSES SEVERE RURNS Oo not get in eyes, on skin, on clothing. Avoid breathing vapor. Do not take internally. In case of contact, immediately remove all contaminated clothing, including shoes, and Rush skin or eyes with plenty of woter for at least l $ minutes; for eyes, get medical attention. Wash clothing before reu*e, poison Call A Phyaiclan Pint Aid MCA Chmlul Mu, am Muu SOU ..ulakk 79 MU NS 095758 PHENYLENEDIAMINE (m*ta or para) CAUTION! MAY CAUSE SKIN IRRITATION Avoid contact with skin and eyes. Avoid breathing dust. PHOSPHORIC ACID CAUTIONI CAUSES SKIN IMITATION Avoid contact with skin and ayes. In cast of contact, flush skin or eyas with plenty of water for at least 15 minutes; for eyes, get medical attention. MCA Chamical Safely Oata (hie SB*TO (vrIIrU* PHOSPHORUS, Whit* or Y*llow (For Wot Shipments) OANOIRI CAUSES SEVERE (URNS Contents packed under water and will ignite if water is removed. Do not get on skin or in eyes. Wear heavy rubber gloves and goggles or face shield. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; keep skin area wet until medical attention is obtained. POISON . Call A Physician First Aid MCA Ctumkat t*tMy beta Stiaar SD1* avail*1st* SO MGNS 095759 PHOSPHORUS OXYCHLORIDE DANOIRI CAUSIS SfVtRI BURNS VAPOR IXTREMKIY IRRITATING Oo not breathe vopor. Do not got in eyes, on skin, on clothing. In cot# of contact, Immediately remove all contaminated clothing and flush skin or eyes with plenty of wotor for at loait 1J minutes; for eyes, got medical attention. Wash clothing boforo re-use. In cost of spillage, Rood carefully with LARGE VOLUME of wotor and provido adequate ventilation. Do not odd wotor to content* while in a container because of violent reaction. *Do not open unless you hove been properly instructed. Do not use this container for any other product. MCA Chsmlcel feisty Pete Sheet ID-ti available PHOSPHORUS PENTACHLORIDE WARNING! HAZARDOUS DUST CAUSCS BURNS Do not breathe dust. Do not get on skin or in eyes* Wear rubber gloves and goggles. In case of contact, immediately flush skin or eyes with plenty of water for ot least IS minutes; for eyes, get medico! attention. Open container carefully. Do not odd water to contents while in a container because of violent reaction. * AddMea te "Ceetetaer Hudllwf and Iterate". Feet 24. 81 MONS 095760 PHOSPHORUS PENTASULFIDE WARNING) HARMFUL DUST CONTACT WITH WATIR OR ACID SLOWLY , 11MRATKS POISONOUS AND FlAMMAftll HYDROGKN SULPIOS GAS Avoid breathing dust or evolved gat. Avoid contact with ikin, eyes, and clothing. Use only with adequate ventilation. Keep container tightly doted. Avoid friction or rough handling become of fire hazard. fire* with Carbon Dioxide or Sand. Smother MCA Chunk*! l*S*ry 0r lhl ID'TI ntihUi PHOSPHORUS PENTOXIDE (PHOSPHORIC ANHYDRIDE) WARNING! CAUSES BURNS Avoid contact with skin and eyes. ( Wear rubber glovet and goggles. In case of contact, immediately Rush skin or eye* with plenty of water for at least IS minute*; for eyes, get medical attention. Open container carefully. Do not add water to content* while in a container because of violent reaction. MCA Chunk*! UifeSy Du* UiiH ID-}I **ttM* 82 MOMS 095761 PHOSPHORUS TRICHLORIDE DANOIRI CAUSES SEVERS SURNS VAPOR RXTRCMIiY IRRITATING CONTACT WITH WATIR MAT CAUSt PUSH PIRI Do not got in eyes, on skin, on clothing. Do not breothe vapor. In cat* of contact, immediately romovo oil contaminated clothing and flush skin or eyes with plonty of wator for at least IS minute*, for eyes, got medical attention. Wash clothing before re-use. In case of spillage, flood carefully with LARGE VOLUME of water and provide adequate ventilation. Do not add water to contents while In a container because of violent reaction and possible flash fire. *Do not open unless you have been properly instructed. *Do not dean or re-use this container. MCA Ctitmlnl Safety Data Ihtil SP-97 available PHTHALIC ANHYDRIDE (SOLID) CAUTIONI MAY CAUH SKIN IRRITATION Avoid prolonged or repeated contact with skin. Avoid breathing dust. MCA Chemical Safety Data Sheet ID4I available POTASSIUM DICHROMATE Soma label as SODIUM DICHROMATE MCA Chemical Safety Date Sheet SP-44 available AddMe* te "Ceeteteer Haadttof and Starefe", Pafa 24. 83 MONS 09576i POTASSIUM HYDROXIDE Sam* labal as SODIUM HYDROXIDE MCA CImmUmiI tmtaty Om*m |U* SEMO v*U.bl* Iff CAUSTIC POTASH PROPYLENE Sam* labal as ETHYL CHLORIDE MCA QimiIiiI Mdy D*t JIimI SMt welUIHe PYRIDINE WARNING! FLAMMABli VAPOR HARMFUL Keep away from hoot, sparks, and open ftatne. Kotp container closed. Use only with adequate ventilation. Avoid prolonged or repeated breathing of vapor. Avoid prolonged or ropootod contact with skin. SILVER NITRATE WARNING! MAY CAUSI BURNS Avoid contact with skin and oyoi. in coso of contort. Rush skin or oyos with wator for at least 15 minutest for oyos, got medical attention. poison Call A Phyolctan Pint Aid HONS 095763 84 SODIUM METAL DANOER1 REACTS VIOLENTLY WITH WATER LIBERATING AND IGNITING HYDROGEN MAY CAUSE BURNS Keep from any possible contact with water. Keep container tightly cioead. Do not get in eyes or on ikin. Wear goggles and DRY gloves when handling. In case of fire, smother with ORY SOOA ASH--NEVER USE WATER OR CHEMICAL FIRE EXTINGUISHERS. Dispose of SOOIUM by burning eorefvlly in an open fire. First Aid Skin: Remove SODIUM and fiush affected area with water. Eyet: IMMEDIATELY flush eyes with plenty of water for 15 minutes. Get medical attention. MCA Chemical Safety Oete Sheet SO-4? available SODIUM CHLORATE WARNINOI STRONO OXIDANT CONTACT WITH OTHIR MATERIAL MAY CAUSC FIRI Clothing and vegetation contaminated with chlorate or its solutions are DANGEROUSLY FLAMMABLE. Remove clothing and wash thor oughly with water. Keep persons and animals off treated areas. Spillage may cause fires. Do not get on floor. Sweep up and remove immediately. When not in use, keep tightly closed in original metal container. Keep away from fire. Store separately from flammable material. MCA Chemical Safety Oata Sheet SO-42 avaMahte SODIUM CYANIDE Sam* fob*/ as CYANIDES, INORGANIC 85 HONS 095764 SODIUM DICHROMATE WAANINO! HARMFUL DUST MAY CAUSI RASH OR EXTERNAL ULCERS . Keep container cloud. Avoid contacr with tkin and eyes. Avoid breathing dust or solution spray. In cat* of contact, immediately flu*h skin or eyes with plenty of water for et least T5 minutes; for eyes, get medical attention. Wash clothing before r**u#> Use fresh clothing daily. Take hot shower after work, using plenty of soap. MCA ChemUet Safety 0te Sheet 10*44 evetteWe SODIUM FLUORIDE WARNING! MAY BE FATAL IF SWALLOWED Avoid breathing dust. Wash thoroughly after hondflng. Clean up spillage. SODIUM HYDROSULFITE CAUTIONI MAY IONITI IF ALLOWED TO BECOME DAMF Keep container tightly closed. Us* only dry, dean utensils in handling. Store in a cool, dry pioce. In case of fire, smother with SODA ASH, DRY SAND, or CARSON DIOXIDE. Dispose of by Rushing away with a LARGE VOLUME of water under adequate ventilation. 86 MONS 095 765 SODIUM HYDROXIDE DANOERI CAUSIS SIViH BURNS TO SKIN AND CYSS Do not got irteyes, on skin, on clothing. Oo not toko intornoiiy. When hondiing, woor goggles or foco shield. While making olu- lions, add slowly to surface of solution to avoid violent spattering. In ease of contoct, immediately flush skin with plenty of water; for eyes, flush with plenty of water for at least 15 minutes and get medical attention. ImfttyMCA ChsmJ'al Data Shtat SB-V avallaWta far CAUSTIC SODA SODIUM ORTHOSILICATE WARNINOI CAUSES SEVERE BURNS TO SKIN AND EYES Avoid contoct with skin, eyes, and clothing. Oo not toko intornoiiy. Whon handling, woar gogglos or foco ihitld. Whilo making solu tions, odd slowly to surfaco of solution to avoid vioiont spottoring. In coso of contact, immodiatoly flush skin with pionty of water; for oyos, flush with pionty of wator for at least I 5 minutes ond got medical attention. SODIUM SESQUISIIICATE, ANHYDROUS Sam* label as SODIUM ORTHOSILICATE SODIUM SULFHYDRATESame label as SODIUM SULFIDE 87 MONS 095766 SODIUM SULFIDE (Containing 35% or mors combined watw) DANOIRI CONTACT WITH ACID LIMRATK POISONOUS. OAS BURNS SKIN AND IYIS Do not breathe dust or gas. Do not get in eyes, on skin, on clothing. Koop container eieiod and owoy from acid and hoot. Swoop up spillage. Do not flush to sowor which may contain acid. In cast of contact, immediately flush skin or oyos with plenty of water for at leost 15 minutes; for eyes, get medical attention. Remove and wash clothing before refuse. STYRENE MONOMER CAUTIONI VAPOR HARMFUL Keep away from heat and open flame. Use only with adequate ventilation. Avoid prolonged breathing of vapor. t Avoid prolonged or repeated contact with skin. MCA Chnil Safety Oat* Sheet SD*37 evaMebU SULFUR CHLORIDE WARNING! CAUSIS BURNS VAPOR IRRITATING Avoid contoct with eyes, skin, and clothing. In case of contact, immediately flush skin or eyes with plenty of water for at least IS minutes; for eyes, get medical attention. Oo not allow woter to get into container because of violent reaction. MCA Chamfeel S*f*ty D< llwt SO-77 <ritbU SULFUR CMLORSOtl SULFUR DICHLORIDESam# labtl as SULFUR CHLORIDE MCA ClnakM l.I.iy O.U ...! >0.,, ...M.l. SUIFU, CHIO.IDII MQNS 09S767 SULFURIC ACID DANGER! CAUSES SEVERE BURNS Do not got in eyes, on skirt, on clothing. In cot* of contact, immadiotaly flush skin or aye* with plenty of water for at least \ 5 minute*; for eyes, get medical attention. Do not add wqtar to contents while in a container because of violent reaction. MCA Chemical Safety Data Sheet SD>20 available SULFURYL CHLORIDE Sam* label as SULFUR CHLORIDE TAR ACIDS "-Same label as CRESOL TETRACHLOROETHANE DANGIRI VAPOR EXTREMELY HAZARDOUS Use only in completely enclosed system. Do not breathe vapor. Oo not get in eyes, on skin, on clothing. Do not take internally. 4k poison 4k Call A Physician First Aid MCA Chemical Safely Data Sheet 10*34 available TETRACHLOROETHYLENE (PERCHIOROETHYLENE) Sam* lab*/ as TRICHLOROETHYLENE MCA CtlkMinl Ufily Dm (km SD-34 MKHlOAOITHTliNI 89 MONS 095768 TETRAETHYLENEPENTAMINE Same label as DIETHYLENETRIAM1NE THIONYL CHLORIDE -- Same label as SULFUR CHLORIDE TITANIUM TRICHLORIDE, ANHYDROUS DANOERf SOLID MAY IONITE SPONTANEOUSLY IN AIR VAPOR CAUSES IRRITATION OP SKIN, EYES, NOSE, AND THROAT DO NOT HANDLE OR USE UNTIL SAFETY PRECAUTIONS RECOM MENDED BY MANUFACTURER HAVE BEEN READ AND UNDERSTOOD. Keep away from hoot, sparks, and open Romo. Do not got in eyes, on skin, on clothing. Do not broatho vapor or dust. Keep container closed; opon contoinor caroMly and only in dry oxygon froo or inert atmosphoro. Woar rubbor glovos and faco shield or safety goggles. In case of contact, immediately remove from skin with dry doth fol lowed by flushing with plenty of water for at least 15 minutes/ for eyes, Rush with plenty of water for ot least 15 minutes,- get medical attention. Remove contaminated clothing and wash before re-use. TOLUENE (TOLUOL) WARNING! FIAMMAILE VAPOR HARMPUL Keep away from heat, sparks, and open flame. Keep container closed. Use only with adequate ventilation. Avoid prolonged breathing of vapor. Avoid prolonged or repeated contact with skin. MCA Clmniul Sefsty Pets tSnt SO-U available 90 MONS 095769 TOIUIDINE (ortho or mota) DANOIRI HAZARDOUS LIQUID AND VAPOR RAPIDLY ABSORBED THROUGH SKIN Do not get In eyes, on skin, on clothing. Avoid breothing vapor. Use only with adequate vontilation. In cose of contact, immediately remove at) contaminated clothing, including shoe*, and flush skin or eyet with plenty of water for at least 15 minutes; get medical attention. Wash clothing before refuse. MCA Chemical Ms'y Date Sheet iD*ll available TOIUIDINE (para) -- Samo label as NITROANILINE MCA Chemise! Safety Dele Sheet SD>t3 available TOLYLENE DIISOCYANATE DANOKRI HAZARDOUS LIQUID AND VAPOR CAUSIS BURNS Keep container closed. Do not get in eyes, on skin, on clothing. Do not breathe vapor. Use only with adequate ventilation. In case of contact, Immediately flush eyet or skin with plenty of water for at least 15 minutes; for eyes, get medical attention. Remove and wash clothing before re-use. MCA Chamlcal Safaty Data Shoot |0>?3 available TRICHLOROETHYLENE WARNING! VAPOR HARMFUL Use only with adequate ventilation. Avoid prolonged or repeated breathing of vapor. Avoid prolonged or repeated contact with skin. Do not take intemolly. MCA Chamkai Safaty bote thaat ID>!4 avakabk 91 MONS Q9577G TRIETHYLENETETRAMINE Sama labtl as DIETHYLENETRIAMINE TRIMETHYLAMINE, ANHYDROUSSams label as DIMETHYLAMINE, ANHYDROUS MCA Chemical SaUry DaMi Shea* SD-S7 available Ur MCtHYlAMINII TRIMETHYLCYCLOHEXANOL Sam* label as CYCLOHEXANOl VANADIUM TETRACHLORIDE DANGER! EXTREMELY HAZARDOUS LIQUID AND VAPOR ABSORPTION THROUGH SKIN MAY BE FATAL CAUSES SEVERE BURNS MAY CONTAIN GAS UNDER PRESSURE DO NOT HANDLE OR USE UNTIL SAFETY PRECAUTIONS RECOM MENDED BY MANUFACTURER HAVE BEEN READ AND UNDERSTOOD. Open container carefully and only in dry oxygen>free or inert atmosphere. Do not get in eyes, on thin, on clothing. Do not brootho vapor. Do not toko internally. Wear rubber gloves and face shield or safety goggle*. In case of contact, immediately remove from skin with dry doth fol* lowed by flushing with plenty of water for at least IS minutes; for eyes, flush with plenty of water for at least IS minutes; get medical attention. Remove contaminated clothing and wash before re-use. POISON + Call A Physician First Aid 93 MOMS 095771 VINYL ACHATE DANQMI IXTMMIIY FLAMMAIll Keep away front heat, sparks, and open flam*. Kp container dotedUte with odequote ventilation. Avoid prolonged or repeated breathing of vapor. Avoid prolonged or repeated contact with ikin, MCA Chwnkai Safety Dali lhaat SD.7J awailakl# VINYL CHLORIDE OANOIM (XTMMtLY FLAMMAUI LIQUID AND OAS UNDU NtlSSUM Keep away from heat, sparks, ond open flame. Keep container closed. Use with adequate ventilation. Avoid prolonged breathing of vapor. MCA CtwmUal Safety Data lhaat SD*M avaitakla XYLENE (XYLOL) WARNINOI FLAMMAUI Keep away from heat, sparks, and open ftome. Keep container closed. Use with adequate ventilation. Avoid prolonged breathing of vapor. Avoid prolonged or repeated contact with skin. XYIIDINES -- Sam* labml as TOLUIDINE (ortho or mota) 93 MONS 095772 ZINC CHLORIDE (Granular, FumcJ, or Solution) WARNING! MAY CAUSI SIVIRI SKIN IRRITATION Avoid contact with skin or eyes. , in caso of contact, flush skin or eyes with plenty of water for ot least 7 5 minutes,- for eyes, got modical attention. ZIRCONIUM METAL POWDER (Mmirm/m 25% Wafer; DANQIRI FLAMMABLE SOUD MAY EXPLODE IF WATER CONTENT IS 10% OR BELOW Keep wt in storage--dry powder may be ignited by friction, static electricity, or heat. DO NOT ATTEMPT TO LOOSEN OR REMOVE MATERIAL FROM CON TAINER WITH ANY TOOL. Keep away from heat, sparks, and open flame. Keep from freezing. In case of spillage, keep wet and remove carefully. In case ot Are, smother with foam-type fire extinguisher or sand. Da oat use carbon tetrachloride, CO} extinguishers or water. Wear goggles or face shield and fire-retardant clothing when handling. 94 MONS 095773 CHIMICAL SAnnr DATA SHOTS Acetaldehyda -----------------................... -...... Acotie Acid -------------------- ------------- -........... Acetic Anhydride.......................................... Acetylene ............ -- -- Acrylonitrile ... Aluminum Chloride, Anhydroue ........... .. Ammonia. Anhydroue ................................... Ammonia. Aqua ........................................... Ammonium Dichromeie ................................. Ammonium Hydroxide .............................. Aniline ....................................... Antimony Trichloride. Anhydroue .............. Arienic Trioxide ..................... Banieno ....................................... Bentoyl Peroxide .......................................... Bemyl Chloride .............................................. Betantphlhyltmine ......................................... Bromine ......................................................... Buudienc ..................................................... Butyraldehyde .............................................. Calcium Carbide ........................................... Carbon Dieuiftdo .............. ............................ Carbon Tetrachloride ................................... Cauetlc Potaeh (Potaeiium Hydroxide) .... Couetic Soda (Sodium Hydroxide) .......... Chlorine .......................................................... Chloroeulionic Acid ....................................... Chromium Trioxide (Chromic Acid) .......... Creaoi .............................................................. Cyclohexane .................................................. Dkhloroboiuene (Ortho) ............................. Oiethylenetriemine .... -.......................... -..... Dimethyl Sulfaio............................................. Ethyl Acetate................................................... Ethyl AcryJate ............................................... Ethyl Chloride .............................................. Ethyl Ether .................................................... Ethylene Dichloride ............... Ethylene Oxide .............................................. Formeidehyde ............................ Hydrochloric Acid ............... . Hydrocyanic Acid .................................. .... Hydrofluoric Acid, Anhydrous, Aqutoua .... Hydroion Chloride, Anhydroue ......... .......... Hydrogon Peroxide............:..................... ....... Hydroien Sulfldo .............................. -...... leopropyiemino .................................. ........... .....................--.S043 ..........................SD41 .......................... SD-1S SD-7 .................. so-n SD42 ........................ SD >D-13 ..........................SD-4S ..........................SD-13 SO-17 ......... SD-66 ..........SD-60 ...........SD-2 ..........................SD-81 ..........................SD49 ......................... SD32 ..........................SD49 ......................... SD-53 ..........................SD78 ....................... SD-23 ..........................SD-12 ....................... SD-3 ..........................SDlO ......................... SD-9 ..........................SD40 ..........................SD33 ......................... SD44 ......................... SD48 ..........................SD-68 ................ _ SD-5* ......................... SD.76 .........................SD19 .........................SD-S1 .........................SD-79 .........................SD-50 ..........................SD-29 ....................... SD-18 ......................... SD-38 ........................ SD-1 ..........................5D-39 ..........................SD47 ......................... SD-25 ................... SD-39 SD-53 Sup. A and B ................. SD-36 ........................SO-72 Continued Next Page 95 i i MGNS 095774 CHIMICAl SAF1TY DATA SHEETS (Continued from Pago 95) lead Oxide* .............................. ................. Methanol .......................... --........ Methylamines ............................................ Methyl Acrylate ......... Methyl Bromide . Methyl Chloride ... ................ Mflhyl Ethyl Ketone .................................... Mixed Acid .................. :..................................... Naphthalene .................................................. Nitric Add ............................... Nitrobeniene ........................................................ Paraformaldehyde . ............... Perchloric Add Solution ......................... Perchloroethylene ............................................. Phenol ................................................... Phosphoric Acid .............................................. Phosphorus. Elemenial ................................... Phosphorus Oxychloride .................................. Phosphorus Pentesulfide .................................... Phoiplioru* Penloxide (Phosphoric Anhydride Phofphoru* Trichloride ................................... Phihelic Anhydride ............................... . Potassium Dichromete ..................................... Potassium Hydroxide 'Caustic Potath) ... . Propylene .............. ......................................... Sodium Chlorate .................................................. Sodium Cyanide ................................................. Sodium Dichromale ................................ . Sodium. Metallic .................................................. Sodium Hydroxide (Caustic Sods) ... Styrene Monomer ................................................. Sulfur .................................................................... Sulfur Chloridea ............. .......... . Sulfur Dioxide ................................... .. Sulfuric Acid .................................. Tetrachloroethane .......................... . Toluene ................................................................. Tolylene Dilaocyinete ......................................... Toluidine ...................................... . . . ........ Trichloroethylene .............................................. Vinyl Acetate ............................................ Vinyl Chloride ..................................................... SD-64 SD 22 SDS7 SD-79 SD-35 SD 40 SD-83 . SD-6S SR-SB SD-5 SD-2I SDll SD-24 SD-4 SD-70 SD-16 ........ SD 26 SD-71 . SD-28 ........ SD 27 ... SD-61 . SD-46 . SD-10 SD-59 SD-42 ........SD-30 ........ SD-46 ........SD-47 ....... sn-9 ...... SD-37 ...... SD-74 SD-77 ...... SD-52 .... SD-20 .... SD-34 ........ SD-63 SD-73 ......... SD-82 SD-14 .......SD-75 ...... SD-56 MONS 095775 96 PART III Illustrative Labels for Pesticides This section contains suggested precautionary texts for a group of hazardous chemicals commonly used as, or in the formulation of, in secticides, fungicides, rodenticides, Herbicides, nematocides, plant regu lators, defoliants, and desiccants. The term "Pesticide" is used in this Guide to indicate these products but the term "leonomlc Poison" is synonymous. Wording is based on the Genero/ Pr/nc/pfes set forth in Part I. Careful study should be given to Part l and the special con sideration* discussed below before any suggested wording is used for a pesticide. These labels have been selected for illustrative purposes only, and the listings do not purport to cover ail pesticides for which precautionary labeling is necessary. Omission of a label for any par* tlcvlar product should not bo intorprotod to moan that tueh product requires no procautlonary labol. The principles in Part I apply primarily to the labeling of hazardous chemicals intended for industrial consumption, some of which are also used as. or fot processing into forms of, pesticides intended for home, farm, or other ultimate consumer use. Label* for such packages of pesticides require consideration of additional factors since they will be handled, stored, and used differently from those intended for indus trial consumption. Pesticide labels should include warnings not only of hatards to man, but also of hazards to domestic animals, useful inverte brates, and desirable vegetation. The usual legally-required ingredient statement may make unnecessary a separate showing of chemical identi fication of hazardous components on labels using code or nondescriptive names. A producer or distributor of s pesticide should be familiar with all pertinent laws, regulations, and interpretations affecting these products, including those of the federal government, states, territories, and other political subdivisions; and with any applicable statutes, ordinances, or regulations affecting labeling in general. Statements suggested In Part III should be usad In addition to, or In combination with, any othor wording roquirod by law. Each suggested precautionary text in thi* section applies to a commercial chemical or to an indicated concentration range of a chemi cal. Many pesticides are marketed in a variety of formulations contain ing different concentrations or combinations of their ingredients. Formulations of two or moro constituents may hove properties that 97 MONS 095776 vary in kind or degree from than f the constituents. In all cases, the precautionary sfatomonft should b# bosed on th# properties of tht finished formulation. It has not been practical to propose statements (or all special pack ages, extraordinary uses, or other unusual circumstances surrounding individual products. Each statement is designed for the normal and customary use of a particular product when packaged for sale as a pesticide, Each lobolor of a pesticide should recognize that his product mutt bo troatod Individually, in tho light of its own charactsristics, including, among others, concentration and grado, packago sitos and typos, channois of distribution, normal stprago and transportation conditions, Intondod consumers, and Intended uses. The label statements in Part III are confined mainly to measures necessary to prevent injury to man and domestic animals arising out of the ordinary handling, storage, or use of a pesticide. Additional state ments may be indicated by the particular form or manner in which a product is sold or the circumstances surrounding its use. There also may be other hazards to man or animals which can arise only from specific uses for which directions are given in the labeling. Frequently a pesticide may also be hazardous to useful invertebrates or useful vegetation, or by reason of residues on edible vegetation. The omission of reference to any of these hazards from any text in Part 111 does not imply that they may be disregarded. As a rule, such statements are properly incorporated in directions (or use. By way of illustration, note# directed to the foregoing appear in connectioa with some of the illustrative labels. Even though they may bo separated from tho principal warnings, thoy should, novortholoss, bo prominently displayed. Examples: Do not apply within..................... days of harvest. Avoid us* during flowering and pollination periods. Do not consume or market fruits or vegetables until residue is removed. Do not use this powder on drainboards, shelves or other places where contact with food is likely. Do not allow spray to come in contact with garden plants. For protection of fish and wildlife, avoid contamination of streams, lakes, or ponds. The Federal Insecticide, Fungicide, and Rodenticide Act and most state acts require the "POISON skull and crossbones" legend and 98 MONS 095777 an antidote on all "Economic Poisons" deemed "highly toxic to man". The definition of "Poison" in Part I of thia Guide is similar to the definition of "highly toxic to man" in the regulations under the fed* eral act. The products in this section have been classified according to the "highly loxic to man" definition. Other state*, while not following the federal act on the definition of "highly toxic to man", require the "POISON* skull and erossbonas" legend and antidote on ail substances which are defined as "Poisons" in their poison laws. The term "Poison" has been commonly understood by the layman to mean toxic by oral intake only. The controlling criteria should con sider oral intake, inhalation, and skin absorption. To clarify the use of the term, labels on packages of pesticides "highly toxic to man" should specify the modes of entry into the body by which the product is poisonous. Examples: POISONOUS IP SWALLOWED POISONOUS BY SKIN CONTACT MAY BE POISONOUS IP INHALED POISONOUS IP SWALLOWED OK ABSORBED THROUGH SKIN It is not intended that the word "POISON", should take the place of a signal word. One of the signal words "DANGIKI" or "WARNING!" will be applicable when a product is a "Ptisan". The selection of the appropriate word will depend not only on the degree of toxicity of the product, but more particularly on tho risk of Injury presented under normal condition* of handling or use. The word "POISON" (or its derivatives) should be reserved exclusively for those products coming within the definitions of the federal act as "highly toxic to man" except where it may be required by other laws or regulations. For products that are lets toxic, statements like the following are preferred; MAY BE PATAL IP SWALLOWED HARMPUl IP INHALED OR SWALLOWED First aid in case of contact ia given for a few products only. The Federal Insecticide, Fungicide, end Rodenticide Act and most state acts require a statement of an antidote on all "Economic Poisons" deemed "highly toxic to man". The term "antidote" is defined in the federal act as "a practical immediate treatment in case of poisoning and includes first aid treatment" and the regulations state that "the antidote statement shall include direction to call a physician immedi ately". Some state laws and regulations require, on labels, the use of special or strictly defined antidotes or prescribe special ways in which these must be ihowwjpr certain chemicals. The requirements for any 99 MUNS 09577U given pesticide may, therefore, vary greatly and the impossibility of showing, in the illustrative labels, antidotes which might be nationally acceptable has led to the practice of indicating only the need for an appropriate antidote statement where the "POISON*skull and crass, banes" legend is used. Such information may be desirable on other products. Where "clothing'* is mentioned in first aid instructions, it should be understood to mean all articles of clothing, including shoes, garters, and other accessories. Shoes are specifically named in some instructions because of special hazards arising from absorption of the chemical by leather. An important principle of good labeling ia to avoid the indis criminate use of precautionary statements since this tends to detract from the importance which should be given to the vital warnings. Common sense indicates certain fundamental precautions in the handling of nearly all household and farm supplies and a label statement cannot substitute for it. Phrases such as "Avoid contamination of feed and foodstuffs." and "Oo not toko internally." should be necessary only where the inherently high toxicity of the product, special use of the material, size of the package, likelihood of mistaken identity, or actual use experience strongly indicates their need. 3-(alpho-ACETONYLFURFURYL)4-HYDROXYCOUMARIN and SODIUM SALT 1. Over 3.0%: WARNING! If swallowed by humons, domestic animals, or pets, this material may reduce the clotting ability of the blood and causa bleeding. In such case, intravenous and oral administration of Vitamin K combined with blood transfusions ora indicated at in the case of hemorrhoge touted by overdoses of biihydroxycoumarin. Keep away from humans, domestic animals, and pets. POISON . (Antidote) Motet Olrrctiofli for UM kovld include a iteftmcnt directing placement of bolt* m m It protect children, pot*, ond deme*H animal*. (continued on met pogc) 100 MONS 095779 2. 3*(alphACETONYlPURFURYl)-4-HYDROXYCOUMARIN and SODIUM SAIT (0.1% to 3.0% incl.): CAUTIONI If swallowed by humans, domestic animals, or pats, this malarial may rtduca fha dolling ability of tha blood and cause bleeding. In such case, intravenous and oral administration of Vitamin K combined with blood transfusions are indicated as in the case of hemorrhage caused by overdoses of bishydroxycoumarin. Keep away from humans, domestic animals, and pets. Mete: Directions tor Use should Include statement directing placement ai baits to as la protect children, pets, and domestic animals. 3. Finished Balts: Directions lor Use should Include a statement directing placement of baits so at to protect children, pets, and domestic animals. ACRYLONITRILE DANOCRI POISONOUS IF INHALED FLAMMABLE Do nol breathe vapor. Do nol get in eyes, on skin, on clothing. Keep away from heat, sparks, and open flame. Keep container closed. POISON (Antidote) Noloi OUottlens far Use should Indudo Instructions for appropriate respiratory protection. 101 MONS 095780 ALDRIN 1. ALDRIN Technical and Formulation* (60% ond ov#r): WARNING! POISONOUS BY SKIN CONTACT, INHALATION, OR SWALLOWING ABSORBED THROUGH SKIN Avoid contact with shin, eyes, and clothing. Avoid brtathing spray mist or powdor. Wash thoroughly with soap and water after hondling and before eating or smoking. Do not uto indoors without adequate ventilation. Us* dan clothing daily. In cos* of contact, immediately r*mov* all contaminated clothing and flush skin or *y*s with p(nty of wator for at least IS minutes; for eyes, get medical attention. Wash clothing before re-use. POISON (Antidote) 2. Formulations (10% to 60%): WARNING! HAZARDOUS BY SKIN CONTACT, INHALATION, OR SWALLOWING Avoid contact with skin, eyes, and clothing. Avoid breathing spray mist or dust. Wash thoroughly with soap and water after handling and before . eating or smoking. Use clean clothing daily. In case of contact, immediately remove oil contaminated clothing ond flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Wash clothing before refuse. Nets: Direction! for Uto should inctvdo instructions for appropriate respiratory protection and the use of clean synthetic rubber gloves during commercial or prolonged eeposure In spray-mining and loading operation!, labels should bear a statement relative to pro tection of persam and animate in treated and ad|aceat aress. (continued on next page) 102 MOWS 095 781 3. ALDRIN Formulations (/om than 10H): CAUTION! HARMFUL SY SKIN CONTACT, INHALATION, OR SWAILOWINO Avoid eontoct with thin and ayas. Avoid braafhing iproy mist or dust. Wosh with soap and watar after handling and bafora eating or smoking. Avoid contamination of faad and foodstuffs. Netei Directions ter Use thould include Instructions for appropriate respiratory protection, labels should bear a statement relative * protection of portent end animals in treated and ad|oont areas. AUYL ALCOHOL DANOIRI IXTRIMILY HAZARDOUS LIQUID AND VAFOR RAPIDLY ABSORMD THROUGH SKIN Do not gat in ayos, on skin, on clothing. Do not braatha vapor. Do not taka intarnally. Kaap away from hoot and opan ftama. Kaap containar dosad. In casa of contact, immadiataly ramova all contaminatad clothing and flush skin or ayos with plonty of wator for at laast 15 minutos,for ayas, gat madscal attantion. Wash clothing bafora ra-uta. JL* poison {Antidata) Netei Directions ter Use should include Instructions ler adequate ventiletien or respiratory protection, et well as the vie el neoprene gloves end geagles, when product is being handled. It product eahiblts Tag. Open.Cup flesh point el 80*P. or less, epprepriate ANTIMONY POTASSIUM TARTRATE (TARTAR EMETIC) WARNINOt MAY SI FATAL IF SWALLOWID Avoid braathing dust. Wash thoroughly aftor handling. 103 MONS 095762 ARSENICAL WEED KILLERS, INORGANIC 1. 2% and ovar a Metallic Arsenic: WARNING! POISONOUS IP SWALLOWED Avoid contact with skin, gyes, and clothing. Do not breathe spray mist; wear respirator. In cose of contact, wash thoroughly. * poison (Antidote) 2. Lou than 2% at Metallic Arsenic: WARNING! MAY BE PATAL IP SWALLOWED Avoid contact with skin, eyes, and clothing. Avoid breathing spray mist. Keep away from food and out of reach of children and domestic animals. In eose of contact, wash thoroughly. Nete: Directions tor Use should Include reference to the avoidance ol ipray drift to valu able plants and roMrtctian af parsons and animals from treated arsas. BENZENE HEXACHLORIDE (See LINDANE also) I. BENZENE HEXACHLORIDE Ttchnical and Dry Formulation* (2SH and ovor)i WARNING! HARMFUL IP SWALLOWED MAY CAUSE IRRITATION OP SKIN AND EYES MAY BE ABSORBED THROUGH SKIN Avoid breathing dust, vapor, or sproy mist. Avoid contact with skin and eyes. Avoid contamination of feed and foodstuffs. In cose of contact, wash skin with plenty of joop and water; for eyes, flush with water and get medical attention. Netoi If tht product Is to Iso applied to plonts that or* used as food, a warning should he Included In the Directions for Use to the effect that the material should not Iso applied where there is danger of residual odor or taste remaining in foodstuffs or edible portions of treated crops. (continued on next page) 104 HONS 095783 1. IINIINI HIXACHlOJtIDI Dry Formulations //* than 25%). CAUTION! Avoid breathing dust, vapor, or spray mitt. Avoid contact with skin and y. Avoid contamination of food and foodstuffs. Wash thoroughly aftor handling. 3. Solutions or ImulslAabU Formulations: Sine* various telvenh whkh differ in leek properties may be used, labels thould hear the precautionary infermollen covering the combined heierds of bencene hexechloride and sehrtnt. Netei It the product it to bo applied la plent* that are vted o food, a warning should bo included in the Directions far Uta ta the effeet that the material theuld not bo applied whtro thoro I* danger of residual odor or teito remaining in feodifufft or ediblo portion* ot fronted crap*. CADMIUM SALTS Toxicity varies with the different product*! hence, each product muit be camidarod en It* own properties. CALCIUM ARSENATE WARNINOI rOISONOUS IF SWALIOWID Avoid breathing dust or spray mist. Avoid contact with skin, oyos, and clothing. Wash thoroughly oftor handling. Cloan up spillago. JL POISON A. (AlHIdoM) 105 HOHS 09578* CALCIUM CYANIDE DANOHI POISONOUS SOLID IIBIRATIS POISONOUS OAS Do no> toke internally. Do not breathe gat or dust. Do not got in eyes, on skin, on clothing. Wash thoroughly after handling. Keep container tightly doted ond away from water or acids. Clean up spillage.immediately. Keep away from feed or food products. In cose of contact, immediately flush skin or eyes with pionty of water for at least 15 minutes; for eyes, get medical attention. Wash contaminated clothing before refuse. POISON (Antidote) Nat*: Directions for Indoor Uso should indvdo instructions for appropriate respiratory protection. CAPTAN CAUTIONI Avoid breathing dust or spray mist. Avoid prolonged or repeated contact with skin. Avoid contamination of feed and foodstuffs. 106 MOMS 095785 2-CARBOMETHOXY-l METHYLVINYL DIMETHYLPHOSPHATE and BETA ISOMER 1. Technical Material and formulations (over 2%): DANOBRI POISONOUS BY SWALLOWING, INHALATION, OR SKIN CONTACT RAPIDLY ABSORDID THROUGH SKIN REPBATBD IXPOSURI MAY, WITHOUT SYMPTOMS, PROGRESSIVBIY INCRIAJ1 SUSCIPTIBIUTY TO POISONING BY THIS PRODUCT Do not swallow or get (n eyee, on skin, on clothing. Wear clean heavy rubber gloves and goggles. Wear dean water proof or freshly-laundered protective clothing (coveralls, caps, etc.). Replace gloves frequently and destroy used gloves. Wash thoroughly with soap and water after handling and before toting or smoking. Bathe immediately after work and change all clothing. In case of contact, immediately remove oil contaminated clothing ond wash skin with soap and water; for eyes, flush with plenty of water for at least 15 minutes and get medical attention. Wash clothing before re-use. Do not breatha dust, vapor, or spray mist. Wear a mask or respirator of a type passed by U. S. Department of Agriculture for protection against this product. Do. not contaminate food ar feed products. Keep out of the reach of children and domestic animals. In case of spillage, wash down with large amounts of water. Decontaminate areas and equipment by washing with a strong lye solution. Empty containers are to be destroyed by burning or burying; never re-use. Stay out of smoke when burning containers. POISON first Aid Netei Per lochnicei malarial and manufacturing w**rair. add ofl *iolam*ntt at hasardi IttON USINO, CONSULT MANUFACTURES FO* SAFE HANMINO INSTRUC TIONS. (csnllnvad an na*l page) 107 MONS 095786 2. 2-CARBOMETHOXY*1-METHYLVINYL DIMETHYLPHOSPHATC and BITA ISOMER Formulations (2% of /): WARNINOl POISONOUS BY SWAUOWtNQ, INHALATION, OR SKIN CONTACT RAPIDLY ABSORBED THROUGH SKIN Do no* iwallow or got in eyos or on skin. Wor dean rubber gloves, protective clothing, and goggles. Replace glove* frequently and destroy used gloves. Wash thoroughly with loop and water after handling and before ating or smoking. In cat of contact, immediately remove all contaminated clothing and wash skin with soap and wafer; for eyes, flush with plenty of wator for at least 15 minutes and get medical attention. Do not breathe duel, vapor or spray mist. Wear a mask or respirator of a type passed by U. S. Deportment of Agriculture for protection against this product. Do not contaminate food or food products. Keep out of reach of children ond domestic animals. Empty containers are to be destroyed by burning or burying. Slay out of smoke when burning containers. POISON First Aid Netsi laboll ihavld boor o Matomont rolativt to tho protection of ponom and animoli in treated ond adfocent oreai. (coatinuod on next pqg) 10S mgns 2-CAMOMSTHOXY.1 MI7HLYV1NYL DIMETHYLPHOSPHATR end BITA IfOMM FIRST AID ATROPINE 15 THE EMERGENCY ANTIDOTE FOR POISONING BY THIS PRODUCT Consult physician about obtaining an adequate supply of 1/100 grain atropine tablets for emergency use. CALI A PHYSICIAN IN ALL CASES OP SUSPECTED POISONING Internal*' If swallowed, indue* vomiting by introducing finger down throat or by giving 1 tablespoonful of tab in a glass of warm water. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON Externals If spilled on skin, immediately movo pationt from vicinity of tho insecticide, remove all contaminattd clothing, and wash skin with soap and running wator. If material gets into eyes, wash immodlotoly with running wator for at loast 15 minutoi. If warning symptom* appoor: Admlnlstor two V 100 grain atropino tablets immodlotoly. NEVER ADMINISTER ATROPINE UNLESS WARNING SYMPTOMS APPEAR Koop pationt prono and quiot. Start artiflelai rospirotion immodiatoly if pationt Is not broothing. Transport tho pationt immodiatoly to tho noarost physician. Nate to Physician: This product is a cholinostoroso inhibitor. Warn* ing symptoms includo weakness, headache, tightness in chest, blurrod vision, un-reaetlv* pinpoint pupils, lolivotion, sweating, nausea, vomiting, diarrhea, and abdominal cramps. Troatmostf: Atropine is tho specific therapeutic antagonist of choice against tho parasympathetic nervous stimulation. If there are signs of parasympathetic stimulation, atropino suifoto should bo infected at 10 minute intervals, in doses of 1 to 2 milligrams, until complete atropinlsation has occurred. Morphine is contraindi cated. Clear chest by postural drainage. Oxygen administration may be necessary. Observe patient continuously for 48 hours. Repeoted exposure to cholinesterase inhibitors moy, without warn ing, cause prolonged susceptibility to very smelt doses of any cholinesterase Inhibitor. Allow no further exposure until time for cholinesterase regeneration has been allowed os determined by blood test. 109 HONS 095784 CARBON DISULFIDE DANOIRI EXTREMELY FLAMMABLE VAPOR HARMFUL HIGHLY VOLATILE Keep away from fire, sparks, or heated surfaces. Store in cool place and keep container closed. Avoid br*othing vapor. Avoid contact with ikin and eyes. , JL- poison . (Antidote) . Notoi Directions tor UiO should Include instructions tor odoquat# vontilotion or respiratory protection when product i being handled, CARBON TETRACHLORIDE DANGIRl HAZARDOUS VAPOR AND LIQUID MAY SI FATAL IF INHALED OR SWALLOWED Do not breath* vapor. Avoid prolonged or repeated contact with skin. Do not toke internally. . POISON (Antidote) Nofoi Oiroctlons tpr Use should Include initruetiom tor odoquato vonlilation or rosplratory protoctlon when product is being handled. CHLORANIL CAUTION) Avoid breathing duit. Avoid contact with skin. 110 HONS 095709 CHIORDANE 1. CHLORDANI Tochnicol ond Dry Formulations (25% and ovar): CAUTION! HARMFUL IF SWAUOWIO ABSORRCD THROUGH SKIN Avoid contact with thin, ay**, and clothing. Avoid braathing dull or spray milt. Avoid contamination of faad and foodstuffs. In cas# of contact, wash with soap and watar. 2. Dry Formulation, (lai, than 2t%k CAUTIONI Avoid braathing dust. Avoid contamination of food and foodstuffs. 3. Solution* or Emulsifiablo Formulation*: Staca ?* taivonro wWxh drllor In tonic proporflot may bo y#d, labofi ihould boor prosouHanarr infarmmlan covptUig rhp combined hoiordi of tWotdano ond *alont. Nti Diroctfoni for Uio thogld Intlvdp appropriate additional indfuctiom for aorotol pradvcti or that* intondod to bo uiod on animal*. Spatial labeling for yaffoac hovw hold proporetfoni It required fodorolly ond in ion*# itatoi. 2-CHLOROAUYL DIETHYLDITHIOCARBAMATE 1. Dry Formulations (granular): WARNING) MAY CAUSI IYI INJURY AND SKIN IRRITATION Do not got in ayot, on skin, on clothing. Avoid breathing dust. Do not tak* intarnally. Avoid contamination of food ond foodstuffs. In cat* of contact with dust, immediately flush skin or oyos with plonty of wotor for at (oast 15 minutes; for *yas, gat madicoi attantion. 2. Imuliiflablo Formulation*! Sine* vorlavt iplvpntt wMch differ In ImI pfopcrflei may ba vied, labali ibovld boar precautionary Informal)** cavarlnp the combined haiardc of this product and tafvent. in MUMS 095790 alpha-CHLORO-N,N-DIALLYlACETAMIDESam labels at 2-CHLOROALLYL OIETHYIOITHIOCARBAMATE CHLOROFORM WARNINOI VAFOR HARMFUL MAY SI FATAL IF SWAUOWID Avoid breathing vapor. Avoid prolonged or ropoatod contact with skin. Noloi Olrteliom l>f Uio ifeould intlvdo instruction* tor odoquoto ventilation or rospirotary proltilion wKsn product it feting handled. CHLORO-IPC (i$o-PROPYL-N-[3*CHLOROPHENYL] CARBAMATE) CAUTIONI HARMFUL IF SWAUOWID CHLOROPHENOL (MONOCHLOROPHENOL) Sam* label as CRESOL 112 HONS 095791 1,1 -bi(CHLOROPHENYl)-2,2,2-TRICHLOROETHANOl 1. Ory Formulations (over 10S): CAUTION! Avoid repealed skin contact. Avoid breathing dust or spray mist. Do nor fake internally. Avoid contamination of food and foodstuffs. Wash thoroughly oftor handling. 2. Dry Formulations (10% or loss): CAUTIONI Avoid breathing dust. Avoid contamination of food and foodstuffs. 3. EmvUiflobU Formulations! Sine* vorlavi talvtntc which differ In tonic prop*rtf*i may bo uiod, loboli ihould boar precautionary Information oovorinp combined hacardt at thli product and loivsnt. CHIOROPICRIN DANOIFI POISONOUS IF INHALED Do not broatho vapor. Do not got in eyes, on skin, on clothing. In caso of contact, immediately flush skin or oyos with plenty of water for at least 15 minutes; for eyes, got medical attention. Remove and wash clothing before re-use. POISON (Antidote) Netai Directions far Ui* hWd Indwda Inctrvrtlani far appr*prit* r*piratary pratvctlan. 113 MONS 095792 COAL TAR CREOSOTE CAUTIONI MAY CAUSi SKIN IRRITATION Avoid prolonged or repeated contact with skin. Avoid prolonged breathing of vapor. Use with adequate ventilation. COPPER COMPOUNDS (10% and over as Metallic Coppsr) CAUTIONI HARMFUL IF SWAUOWID CRESOL (CRESYLIC ACID) DANOIRI MAY Rt FATAL SY SKIN CONTACT OR SWAUOWINO RAFIOLY ARSORBKO THROUGH SKIN CAUSIS SIVIRI (URNS Do not got in oyos, on skin, on clothing. Avoid breathing vapor. in case of contact, immediately remove ail contaminated clothing, in. eluding shoes, and flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Wash clothing before refuse. 114 HONS 095 793 CYANIDES, INORGANIC (Excluding HYDROCYANIC ACID and CALCIUM CYANIDE) Of(NAMI MOOUCT) DANGER! POISONOUS SOLID CONTACT WITH ACID LItIRATIS POISONOUS GAS Do no! breothe gas or dust. Do not take internally. Avoid contact with eyes and skin. Wash thoroughly after handling. Keep container closed and away from acids. Store in a dry place. Keep away from feed and foodstuffs. In case of contact with eyes, flush with plenty of water for at least 15 minutes and get medical attention. .. poison .. (Antidote) N*fo< Directions for Indoer use should include insttuciioni fo> appicp'lalt respiratory protection. CYANO(METHYLMERCURI)GUANIDINE (METHYL MERCURY DICYANDIAMIDE) -- Same labels as ETHYL MERCURY CHLORIDE US MONS 095799 2,4-D (2,4-DICHLOROPHENOXYACETIC ACID and Derivatives) 1. 2,4-D ACID end Dry Formulations (10% and over); , WARNINOI IRRITATING TO EYES, NOSE, AND THROAT Do not got in aye*. Avoid contact with ikin. Avoid breathing duit. In cae of contoct with eye*, fluih with plonty of water for at loan 15 minute* and got medical attention. 2. SODIUM SALT (2,4-D Acid Equivalent 20% and over): CAUTION! IRRITATING DUST Avoid breathing dust. Avoid contact with skin and eyes. 3. liquid Formulations of 2,4-D ESTERS; CAUTIONI MAY CAUSE SKIN IRRITATION Avoid contact with oyos, ikin, and clothing.' 4. Liquid Formulations of 2,4-D AMINES: WARNING! CAUSES IRRITATION OF EYES AND SKIN Do not got in eye*. Avoid contact with thin and clothing. In ca*e of contact, Ruth eye* with plonty of wator for at least 1 5 minute* and get medical attention; wash skin with plenty of oap and water. Netei All weed hitter preparations centoining 2,4-0 or Its derivatives should, when appro priate, carry adequate warning statements regarding dangers of vapor, spray ar dust drift to dosirattlo plants, the necessity of using other equipment for handling and apply ing other agricultural themieoli, and avoiding contamination of domestic or irrigation water supply. 116 HONS 095795 DAIAPON, SODIUM SALT CAUTIONI CAUSK SKIN IRRITATION Avoid contact with skin, eyes, ond clothing. In cost of contact, remove contaminated clothing and wash skin with plenty of soap and water; for eyes, flush with water for 15 minutes and gat medieot attention. Wash clothing before re-uie. DDD (DICHLORODIPHENYL DICHLOROETHANE) Sam* labels as DDT DDT (DICHLORODIPHENYL TRICHLOROETHANE) 1. DDT Technical! CAUTIONI HARMFUL IF SWAUOWKD ARSORMD THROUGH SKIN WHEN IN SOLUTION Avoid breathing dust or spray mist. Avoid contamination of feed and foodstuffs. 2. Dry Formulations (over 2S%): CAUTIONI HARMFUL IF SWALLOWED Avoid breathing dust or spray mist. Avoid contamination of feed ond foodstuffs. 3. Dry Formulations (29% or fee*): CAUTIONI Avoid breathing dust. Avoid contamination of feed and foodstuffs. 4. Solution* or ImulelRable Formulation*: Sine* varievi lelvenfi whkh differ In talk propertlei nay be used, labak iheuld bear precautionary tnfermetfe* eeretlnp *be combined heiords of DOT and solvent. Natai If the prepared** caatafni other beterdovi Ingredient*. opproprialo additional taw ' tlaai must be added to the ferae*!**. DlrecHeiw far Usa ihould include appropriate add!* tlenel Instructions tar aaraoal prodwtt* at far products Intended # bo used on onimolt. 117 MONS 095796 1,2-DIBROMO-3-CHLOROPROPANE 1. Technical frwlvct: WARNING! HARMFUL LIQUID AND VAPOR MAY BURN SKIN AND EYES * CAUSIS IRRITATION OP NOSI AND THROAT MAY B ABSORBED THROUGH SKIN Oo not breathe vapor. Avoid contact with eyes, skin, and clothing. Use only with adequate ventilation. Oo not taka Internally. In case of contact, immediately remove contaminated clothing, in* eluding ihoei, and wash ikin with soap and water} flush eyes with plenty of water for at least 15 minutes and get medical attention. Wash clothing and air shoes thoroughly before refuse. Store away from domestic animals and dwellings ond out of the reach of children. 2. Dry Formulation* (20% and over): WARNINOI HARMFUL DUST AND VAPOR MAY 1URN SKIN AND EYIS CAUSIS IRRITATION OF NOSI AND THROAT MAY Bl ABSORBED THROUGH SKIN In edditlen to ebove Statement*, alto include belonce of precautionary labol rcommanded for Technical Product. 3. Dry Formulation* (foi* than 20%): CAUTIONI MAY CAUSI IRRITATION OF SKIN, EYES, NOSI, AND THROAT Avoid contact with skin, eyes, ond clothing. Avoid prolonged breathing of vapors or dust. Do not toke internolly. Wash thoroughly with soap and water after handling and before eating or smoking. Keep out of the reach of children and domestic animals. 4. Solution* and Imulsiflablo Formulations: Since rarious oiventt which differ in taxic prepertiet mey he vied. lebeW iheuld beer precautionary Infarmatian covering the combined hasardi of thU preduct end IIS MONS 095 79 7 DICHIONE CAUTIONI MAY CAUil SKIN IRRITATION Avoid contact with ikln, oyot, and clothing. Woih hands ond faeo thoroughly with loop and wotor aftor handling. Storo away from food and foodituffi. WCHlOROETHYl ETHER 6ANOIRI MAY II FATAL IF SWAUOWID, INHALID, OR AISORilD THROUGH SKIN Do not got on ikln or clothing. Do not broetho vapor. Do not toko intornally. In cato of contact, [mmodiatoly romovo contaminated clothing ond Auih ikin or oyoi with plonty of wator for at loait 13 minutoi. Woih clothing boforo ro-uto. poison ^ {Antidoto) NMw Dlreetiem fer It*# th#vid indwd* instruct!#*! t#r #d#qvt# v#nHt#tf#n #r r*splrt#ry pr#t#<tl#Fi when predvet li baing handled. 119 MONS 09579B DICHLOROPROPENE - DICHLOROPROPANE MIXTURE WARNING! HAZARDOUS LIQUID AND VAPOR MAY SI FATAL IF SWALLOWID, INHALED, OR ABSORSID THROUGH SKIN ' CAUSIS BURNS TO SKIN AND EYES Do not got in eyes, on skin, on clothing. Woor goggloi and poly, othylono glovos whon handling. Do not broatho vapor. Uso only with adequate ventilation. Keep oway from heat and open flame. Keep container dosed. Keep out of reach of children. Da not contaminate feed and foodstuffs. In case of contact, immediately remove all contaminated clothing, including shoes, and wash skin thoroughly with soap and water; for eyes, flush with water for at least IS minutes and get medical attention. Wash clothing and air shoes thoroughly before re-use. Net( Direction* for Ue thowld Include Imirwctfont far retpiratery protection when the predict li being bundled in endeted ereei. DIELDRIN -- Sam labels at ALDRIN 120 MONS 095 799 DIETHYL DIPHENYL DICHLOROETHANE (1,1 -DICHlORO-2,2-b! [ p-ETHYLPHENYt] ETHANE) 1. Technical Product: CAUTION! ABSORBED THROUGH SKIN WHEN IN SOLUTION In cal* of skin contact, waih with loop and waf#r. Avoid brearhing dust. 2. Ducts and Wetfabl* Powders: CAUTIONI Avoid prolonged breathing of dust or spray mist. 3. Solutions and Imuttiflsblc Formulations: Sine* verlewi Iplventi which dlPer In taxlc propvrtUi my b gi*d, labeli ihogtd beer prpcnwHpRory informoHen to*er!ft| th# combined heiardi of dlothyt diphenyl dlcMereethen* and wtvoM. DINITRO-ortho-CRESOL DANOERI POISONOUS BY SWALLOWING OR SKIN CONTACT ABSORBED THROUGH SKIN Do not g*t in *y*s, on skin, on clothing. Avoid broothlng vapor, dust, or spray mist. In cot* of contact, immodlatoly remove contaminated clothing and wash skin thoroughly with pl*nty of toop and watr; for eyes, Rush with wator for at ioost 15 minutos and g*t medical attention. Wash clothing b*for* re-us*. poison (Antldoto) DODINE (DODECYLGUANIDINE ACETATE) Technical Product and Dry Pormulattans (over 50%): CAUTIONI CAUSIS EYE IRRITATION In caio of contact with eyes, flush with plenty of wot*r for at i*ost 15 minutes and get medical attention. Ill MQNS 095300 ENDRIN 1. INOWN Thnlcal and Formulation* (2.5% and over): DANOCRI POISONOUS BY SKIN CONTACT, INHALATION, OR SWALLOWINO RAPIDLY ABSORBID THROUGH SKIN Do not get In eyes, on skin, on clothing. Do not breothe spray mist or powder. Wash thoroughly with soop and water attar handling and before ating or smoking. Cleon up spillaga. Do not use indoors without adequate ventilation. Us# cl#an clothing daily. In cot# of contact, immediately remove all contaminated clothing and flush skin or ty#s with planty of wat#r for at last 15 minutes; for eyes, g#t m#dical attention. Wash clothing b#for# re-use. -A. POISON A, (Antidotal 2. Formulation# (lev# than 2.3%); , WARNING! HAZARDOUS Y SKIN CONTACT, INHALATION, OR SWALLOWING Avoid contact with skin, tyos, and clothing. Avoid breathing spray mist or dust. Wash thoroughly with soap and watr after handling and b#for# eat ing or smoking. Us# ci#on clothing daily. In cas# of contact, immediately remov# all contaminated clothing and flush skin or eyes with plenty of water for at least \ 5 minutes; for ey#s, get medicol attention. Wash clothing before refuse. Natsi Dlracfiani far Ui itiavid inaluda initrvcHant far apprapriata ratpiratary protection and the um at daen synthetic rvbbar gleves dwrln# commercial ar prolonged tapaiwra In preT`>#l>ln# and leading aparatlam. lobsli theuld b#ar a statement rolorivt to the pratactlaa at persons and animals in traetad and odjacant araat. 122 HONS 095801 ETHYL BROMIDE WARNINOI VAPOR HARMFUL Avoid prolonged breothtng of vapor. Keep container doled, out of sun, end owoy from heat. Nerei Direction* ter Uie thogld Include iniFructlone for adequate ventilation er retpiretaty protection when the product it being handled. ETHYL MERCURY ACETATE Sam* labels as ETHYL MERCURY CHLORIDE ETHYL MERCURY CHLORIDE 1. Dry Formulations (any effect/ve concenfrerf/on): OANOIftl POISONOUS SY INHALATION OR SWALLOWING MAY CAUSI SKIN IRRITATION OR DILAYID CHIMICAL BURNS Do not get in eyes, on ikin, on clothing. Do not breathe vapor, dust, or spray mitt. In cate of contact, immediately wash skin with plenty of soap ond water; for tyei, flush with water for at leott 15 minutes and get medical attention. If burning or blistering of skin results, get medical attention. Use deon clothing daily. POISON (Antidote) 2. Solutions: The star* label may require additions) Statement* el Hetardi lor leMleni tince In tMt term the themital may ba abeerbed tkreuqh the thin end thui be pelieneui by ifcln contact. Metai Per certain epplketianc, Otractiam far Uea may need t include mere detailed In. ttruetlane far cafe hoedllnf af tkti product and materiel* treated with It. 123 MONS 095B02 ETHYL MERCURY PHOSPHATESama labtls as ETHYL MERCURY CHLORIDE ETHYL MERCURY para-TOLUENE SULFONANILIDE Samm labmls as ETHYL MERCURY CHLORIDE ETHYLENE DIBROMIDE WARNINQI HARMFUL LIQUID AND VAFOR CAUSIS SKIN IRRITATION, AND IURNS ON FROLONOID CONTACT AftSOMID THROUGH SKIN Avoid breathing vapor. Avoid contact with skin, eyes, and clothing, Do not toko internally. In caio of contact, immodietoly remove oil contaminatod clothing, including shoot, and wash skin with soap and plenty of water; for eyes, hush with plenty of water for at least 15 minutes and get medical attention. Wash clothing and air shoot thoroughly before re*ute. New Dl'MiNm te Um K#mI4 InUrucMen* Itr atRSMta hrHIwIrr er rnplrewy preterite* wKdh The preHwt Is bebif bendled. SIhcq mlaturos HHt kpHrecerfee** er hetejtneteH hpdrecerbe*tpee selvenls eep be mi* keterHevi, ms "hlfhlp tdrI*", IsWt iheeM beer srewMewni IrIshmIIsr tewlR| Hid heserHi sf Hie ettatvre. ETHYLENE DICHLORIDE WAKNINOI PLAMMAUI VAPOK HAKMPUl Keep away from heat, iparkt, and open flame. Keep container doted. Avoid breathing vapor. . Avoid prolonged or repeated contact with skin. Oo not take internally. New PlreElw ter Use skeeld leriuHe InitrwcHeni ter edequele venHIetfen er rDspiretery 124 HONS 095303 FERBAM (any effective concentration) CAUTIONI MAY CAUS1 IMITATION Of IYIS, NOSf, THROAT, AND SKIN Avoid breothing dull 01 iproy mi it. Avoid contact with thin, eyes, and clothing. In cat* of contact, flush skin or eyes with plenty of wator,- for eyes, got medicol attontion. 'Keep away from Are or sparks. *fr But* mislotm $0% and vr, and tar tw*r concnrafioni it dllutnt is eambuttibla. FORMALDEHYDE SOLUTIONS (5% and over) WARNINOI CAUSIS IRRITATION Of SKIN. IYIS, NOSI, AND THROAT Avoid prolonged or repeated contact. Avoid prolonged breathing of vapor. Use with adequate ventilation. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. A. POISON JL (Antidote) HEPTACHIOR WARNINOI MAY M FATAL IF SWALLOWED Avoid breathing vapor, dust, or spray mist. Avoid contact with skin, eyes, and clothing. In case of contact, wash promptly with plenty of soap and water. Avoid contamination of feed and foodstuffs. 125 HONS 095604 HEXAETHYl TETRAPHOSPHATE Sam* /ab*/ as TETRAETHYL PYROPHOSPHATE HYDROCYANIC ACID DANOIRI IXTRIMILY HAZARDOUS LIQUID AND OAS IXTRIMILY PLAMMABLI MAY Bl FATAL IF SWAUOWID, INHALID OR ABSORBID THROUGH SKIN USE ONLY IN A CLOSED SYSTEM. Keep owoy from hoot, sparks, and opon flomo. Do not toko internally. Do not broatho 901. Do not got in eyas, on skin, on clothing. In eaio of contoet, immodiatoly flush skin or oyos with plonty of wator for at loast 15 minutos; for oyos, got modicai attention. Wash contominalod clothing boforo ro-uo. JL POISON A. (Amidol.) M*Ni OlrMtlMi tor Us* lhauld inclwd* inilrwt(A* f*r approp'lat* rt>p>'al*r)r pr*tcti*n. HYDROXYMERCURICHLOROPHENOL (any effective concentration) WARNINQI POISONOUS IP INHALIO Oil SWAUOWSD MAY CAUSI SKIN IRRITATION Avoid broathing dust. Avoid contact with skin, oyos, and clothing. In coso of contact, immodiatoly wash skin with plonty of soap and wator; for oyos, flush with wator for at loast 13 minutos and got modicai attention. A. poison JL (Amidst.) 0 01N S for <*rtein oppiUoNoni, Dtroctiom far Us* moy n**d I* 1kIw4* m*r# d*t*ll*d In. strucHont l*r sot* haitdHnf si this pradwal and malarials traatad with II. 12* NONS 095805 HYDROXYMERCURICRESOl Sam* label as HYDROXYMERCURICHIOROPHENOL HYDROXYMERCURINITROPHENOL Sam* label as HYDROXYMERCURICHIOROPHENOL HYPOCHLORITES Imouip of the differences properties ol members of thi* group, each product containing thorn mvit bo reviewed individually in light o* ils own chorocterisikt. IPC (Iso-PROPYLPHENYICARBAMATE) Sam* label as CHLORO-IPC LEAD ARSENATE WARNINOI POISONOUS IF SWAUOWSD Avoid braothing duit or spray mist. Avoid contact with skin, gyoi, and clothing. Wash thoroughly altar handling. Claan up spillaga. poison . (Antidotal 127 MQNS 095806 UNDANE (S-- BENZENE MEXACHLORJDE also) 1. LINDANE and Dry Formulations (25% and aver): WARNING) MAY M FATAL IF SWALLOWED MAY BE ABSORBED THROUGH SKIN Avoid breathing duit, vapor, or >pray mist. Avoid contact with skin and oyos. Avoid contamination of food and foodstuffs. In caso of contact, wash skin with plenty of soap and water; for eyes, flush with water and got medical attention. 2. Dry Formulations (less than 25%); Some lobe/ at BENZENE HEXACHLORIDE--Dry Formulations (less than 25%). 3. Solutions or Emultifloble Formulations: See BENZENE HEXACHLORIDE MAGNESIUM ARSENATE Sam* label as CALCIUM ARSENATE I2S hons 95807 MALATHION 1. MALATHION Technical and Dry Formulation* (over 50%); CAUTIONI HARMFUL IF SWALLOWED OR INHALED Avoid breathing vapor or dust. Avoid r*poofd or prolonged contact with skin. Wash thoroughly after handling. Wash contaminated ciothing before re-use. 2. Dry Formulation* (over 10% to 50% /nc/.)i CAUTIONI MAY Rl HARMFUL IF SWALLOWED Avoid prolonged breathing of spray mist or dust. Avoid repeated or prolonged contact with skin. Wash thoroughly after handling. Avoid contamination of feed and foodstuffs. Keep out of reach of children. 3. Imuilflable Formulation*: Sines verlswi islvsnto whkh differ In rank preparties may bs used, emultlffable liquid lebeis ksld bear prscevHsnery infermaHen covering the esmbinsd becordt t moletblen and islvent. 4. Du*t* (10% or feu): CAUTION! Avoid prolonged breathing of dust. Avoid repealed or prolonged contact with skin. Wash thoroughly after handling. Avoid contamination of feed ond foodstuffs. Keep out of reach of children. MALEIC HYDRAZIDE, DIETHANOLAMINE SALT CAUTIONI MAY >( HARMFUL IP SWALLOWED Avoid breathing spray mist. Avoid contact with skin, eyes, and clothing. 129 MQNS 095808 MANEB (any effective concentration) -- Same label at ZINEB MCP (2-METHYI-4-CHLOROPHENOXYACETIC ACID and Derivatives) -- Same labels as 2,4-D METHYL BROMIDE DANOERI VAPOR EXTREMELY HAZARDOUS HIOHIY VOLATILE CAUSES BURNS Do not breath* vapor. Do not get in eyes, on skin, on clothing. Keep away from heat, - In cot# of contact, immediately remove all contaminated clothing, including shoes, and wash skin thoroughly with soap and water; for eyes, flush with plenty of water for at least 15 minutes and get medical attention. Do not refuse shoes or clothing until free from all contamination. POISON (Antidote) IMPORTANT! The contents of this can are under pressure. Do not use ordinary can opener. Special handling equipment is available. Contact../!!!*.!!?. proper use. information on equipment and fer er respiratoryNetoi DlrMtiwti fe> Us* ihowld Includa inifruellan* adaquar* v*nlloHa" protection whan iha product it being handlad. 130 MQNS 095809 METHYL PARATHION - Som# labels as PARATHION METHYLENE CHLORIDE CAUTION! Use with adequate ventilation. Avoid prolonged or repeated breathing of vapor. Avoid prolonged or repeated contact with skin. Do not take internally. MONOCHLOROPHENOL - Sam* tab*) as CRESOL NABAM SOLUTIONS (19% and ov*r) CAUTIONI MAY CAUSI SKIN IRRITATION MAY >( HARMFUL IF SWALLOWID Avoid contact with ikln and oyti. tn caia of contact. Rush tkin or eye* with plenty of water; for eyes, get medical attention. 1-NAPHTHYL N-METHYLCARBAMATE CAUTIONI HARMFUL IF SWALIOWRO OR INHALID Do not take internally. Avoid breathing dost. Avoid prolonged or repeated contact with skin, Woih thoroughly alter handling. Wash contaminated clothing before rt-ue. Avoid contamination of feed and foodstuffs. 191 MOMS 095810 NICOTINE SULFATE SOLUTION (40% NICOTINE) DANGERI POISONOUS IP SWALLOWED ABSORPTION THROUGH SKIN HARMPUl Do not got in oyos, on skin, on clothing. Wear protective clothing and goggles when handling. Do not breothe spray mist; weor respirotor. Store away from food and out of roach of childron and domoitic animals. In easa of contact, immediately flush skin or oyos with pionty of war for at toast 15 minutos; for oyos, got modicol attontion. Remove and wash clothing boforo r*uso. *. POISON (Antidote) NICOTINE DUSTS (5% or loss) CAUTIONI HARMPUl IP INHALED OR SWAUOWID Avoid exposure to dust. Avoid contact with skin and oyos. Wash thoroughly after handling. Store awoy from food and foodstuffs. MeMi The percentage end t*rm *f nicotine prutnl may call ter poison labeling under the requirement! of vorlowi itotc low*. OVEX (p-CHLOROPHENYL p-CHLOROBENZENESULFONATE) CAUTIONI MAY CAUSE SKIN IRRITATION Avoid contacr with ikln. Avoid brvathing dvt or spray mi$1. 132 HONS Q958li PARATHION 1. PARATHION Technical: OANOIRI POISONOUS BY SKIN CONTACT, INHALATION, OR SWAILOWINO RAPIDLY ABSORBID THROUGH SKIN RIPIATID IXPOSURI MAY, WITHOUT SYMPTOMS, 51 INCRKASINGIY HAZARDOUS BEFORE USING, CONSULT MANUFACTURER FOR SAFE HANDLING INSTRUCTIONS. Do not got on skin, in eyet, on clothing. Wear dean heavy rubber gloves and goggles. Wear clean water* proof or frehly-laund*r#d protective clothing (coveralls, rubber booti, cop, etc.). Destroy and replace gloves frequently. Bathe immediately after work and change ail clothing. Wash clothing thoroughly with soap and hot water before refuse. In case of contact, immediately remove contaminated clothing and wash skin thoroughly with soap and water; for eyes, flush with water for I 5 minutes. Do not breathe vapor or duet. Wear respirator or mask effective for parathion protection. In case of spillage, cover with an absorbent such as soda ash, lime, day or sawdust. Sweep up and bury. Wash area thoroughly with strong lye solution. poison rim am (centlnved on next pap*) 133 HONS 095812 2. PARATHION Wettable Powders and Dusts (2S% or hit); OANOBRI POISONOUS Y SKIN CONTACT, INHALATION, OR SWALLOWING . RAPIDLY ABSORBED THROUGH SKIN RBPIATtD CXPOSURI MAY, WITHOUT SYMPTOMS, Bl INCREASINGLY HAZARDOUS Do not got on skin, on clothing. Wear clean heavy rubber gloves and clean woterproof or freshly, laundered protective clothing (coveralls, cap, etc.). Destroy and replace gloves frequently. Wash thoroughly with soap and warm water before eating or smoking. Bathe immediately after work and change all clothing. Wash clothing thoroughly with soap and hot water before re>use. In case of contact, immediately remove contaminated clothing and wash skin thoroughly with toap and water. Do not broatho dust, vapor, or spray mist. Wear mask or respirator of a type passed* by the U. S. Deport* ment of Agriculture for parathion protection. Airplane pilots should wear fulMaco canister*type mask. If handled indoors, provide mechanical exhaust ventilation. Do not storo near food or feed products. Keep out of reach of children and domestic animals. Bury spillage; clean up area with strong lye solution. Burn or bury containers; never refuse. Stay out of smoke when burning containers. poison .&> First Aid 2. Solutions or Imwlsiflable Formulations! Sine* various lelvonti which differ in fOKK prepertie* may be vied, iebeli iheuld bear precautionary intormerten covering the combined herordi el parethien end iplvtnt. Netei lebeb ihovid beer e Hetoment reietlv* to the protection at poneni and enimeli in treeted end ed(ecent area*. 134 (continued on n**t page) MONS 095813 PARATHION FIRST AID atropine 1$ an antidote--consult physician for EMERGENCY SUPPLY CALL A PHYSICIAN AT ONCt IN All CASES OF SUSPECTED PARATHION POISONING If symptoms or signs of poisoning include blurred vision, abdominal cramps, and tightness in the chest, do not wait for a doctor but give two atropine tablets (each 1/100 gr.) at once. Move patient immediately from the area where porothion is present. Remove contaminated clothing and wash the skin clean with plenty of soap and water to remove all traces of porothion. If swallowed, induce vomiting by giving salty or soapy worm water. NEVER GIVI ANYTHING RY MOUTH TO AN UNCONSCIOUS PERSON Physician's Note: This product Is a cholinesterase inhibitor. Warn ing symptoms inciudo weakness, heodache, tightness in the chest, blurred vision, non-reoetlve pin-point pupils, salivation, sweating, nausea, vomiting, diarrhea, and abdominal cramps. Treatment: Give atropine, preferably by injection, grains 1/100 three or more tablets at once and parenterolly or orally every hour until pupils dilate. Thirty or more tablets may be required in 24 hours. Never give morphine. Clear chest by postural drainage. Artificial respiration or oxygon administration may be necessary. Observe patient continuously 48 hours. Repeated exposure to cholinesterase inhibitors may, without warning, causa prolonged susceptibility to very small doses of any cholinesteroie inhibitor. Ailow no further exposure until time for eholinesterose regenera tion has bean ollowed os determined by blood tests. PARIS GREEN Sam* labl as CALCIUM ARSENATE MONS 095814 PENTACHLORONITROBENZENE 1. PfNTACHlOftONITROSKNZKNK Technicol and Dust Formulations: CAUTION! MAY CAUSt SKIN IMITATION Avoid prolonged or repeated contact with skin. Avoid prolonged breathing of dust. Wash thoroughly oftor handling. 2. Wettable Powders: CAUTIONI MAY CAUSf SKIN IMITATION Avoid prolonged or repeated contact with skin. Avoid prolonged breathing of dust or ipray mist. Wash thoroughly after handling. 3. Liquid Formulations: Since veriew* solvent* wkktv dWter In teak properties *ey be used. lobel* should beer precovtienery information revering the combined hesordi ef pentedileronitreben. tent end solvent, PENTACHLOROPHENOL 1. FINTACHIOROFHINOI Technical: WARNINOI HARMFUL DUST Avoid breathing dust. Avoid contact with shin, eye, ond clothing. Do not take internally. In caio of contact with dry material or its solution, immediately wash skin with soap and plenty of water; for eyes. Hush with plenty of water for at (oast 15. minutes and got medical attention. (continued on neat page) 136 HOMS 095815 2. PINTACHLOROPHENOl OK Solutions: WARNINOI CAUSES SKIN IRRITATION ABSORPTION THROUGH SKIN HARMFUL Avoid breathing vapor. Avoid contact with skin, eyes, and clothing. Oo not take internally. In cast of contact, immediately wash skin with soap and plenty of warm water; for eyes, flush with plenty of water for at least 15 minutes and get medical attention. Remove and wash clothing before re*uie. PHENOL (CARBOLIC ACID) DANGERI MAY Bi FATAL BY SKIN CONTACT OR SWALLOWING RAPIDLY ABSORBED THROUGH SKIN CAUSES SEVERE BURNS Do not get in eyes, on skin, on clothing. Avoid breathing vapor. In cose of contact, immediately remove all contaminated clothing, including shoes, and flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Wash clothing before re-use. JL POISON JL (Antidot.) PHENOTHIAZINE CAUTION! MAY CAUSI SKIN IRRITATION Avoid contact with skin and eyes. Avoid breathing dust. In cose of contact, wash skin with soap and plenty of water; for eyes, flush with water and get medical attention. 137 MQNS 095816 PHENYL MERCURY ACETATE 1. Dry Formulation* Sam* Jab*/ as HYDROXYMERCURICHLOROPHENOl 2. Soiutioni! Sam* /obe/s ax PHENYL MERCURY OLEATE PHENYL MERCURY OLEATE (Oil Solutions or Oil-Wator Emulsions) I. 1.0% and a**t: OANOIRI POISONOUS SY SWALLOWING OR SKIN CONTACT MAY CAUSI SKIN IRRITATION OR DILAYIO CHIMICAl SURNS ASSORSiO THROUGH SKIN Do not got in *y*i, on skin, on clothing. Do not br*ath* ipray mist. in cas* of contact, imm*diot*ly rmov* all contaminated clothing and Rush skin or *y*s with plenty of water for at l*ast 15 minutes; for y*s, g*t medical attention. If burning or blistering of skin r*. suits, get medical attention. Wash clothing before re-use. poison (Antidote) Nti Per certain applications, Directions ter Um may need to include more detailed in. trwttisn* for salt handling at this product and Material* treated with it. (continued on neat page) 138 MOWS 095817