Document zdr2zXn8dKXGGXkkKaGwqmEbR
bsgd Associated Lead Inc.
MATERIAL SAFETY DATA SHEET
. MA1N^-. 'JKRT NAMl ..... /
-................- ...
ASSOCIATED LEAD, INC.
REGULATORY AFFAIRS DEPARTMENT
DA1TE '. .1" ___ 4.14.80
SlitIT ADCItSi
2545 ARAMINGO AVENUE
CITY. STATE. IIW PHILADELPHIA, PA* 19125
flODUCT CLASS
AAANUFACTUKrS COM I D.
Stabilizer-Pigment
34006
TltADC NAMK
^
$yphos XL
EMEtGCNCV TELEPHONE NO. 215-427-4681
"1
INGREDIENT
-m
percent
BY WEIGHT
PPM
TLV m g/m*
i.. l , r -
*
LEL %
VAPOR pressure mm Hg @ 68*F
Dibasic Lead Phosphite
90.0
s 2(1) x - (Lead)
(1) OSHA Standard, 29 CFR 1910.1000 Table 1-2
IOlJnG VANCE N/A
| | HEAVIER
s%c3-Tie>?i m
iMija
VAPOR DENSITY
N/A
lighter than air
evaporation rate
| 1 FASTER
N/A
Q slower than ether
% VOLATILE BY VOLUME
-
WEIGHT PER GALLON
-
` 'r ^
SPECIFIC ORAVITY
4.5
>m & -.pm S? i5asfeg@)S5s
3?Tr
DOT CATfOOtY
Flammable Solid
FLASH POINT
N/A
Unknown
iXIiNCUiSHiNG *!DlA i'Al ER-FOG
FOAM
OTHER
CARBON DIOXIDE
& DRY CHEMICAL
UN.^VAl Mtf AND fxPlOi'ON HAZARDS
Isolate from heat, open flames, and all sources of sparks including static electricity. Use nonmetallic scoops. Equipment and hoppers must be properly grounded.
SPFClAl MU MGHTlNG FfcOCEDUItJ
Isolate and scatter material to cool. Cover with sand.
T7
f> NSTABLE [T] STABLE
CONDITIONS TO AVOID
Keep dust accumulations to a minim,urn.
vOiO)
None. 0KO*C5HiON ttfODVdi
On ignition, oxides of lead may be volatilized.
f OvT-Att':*tiON
LJ /'AY OCCUR ra WILL NOT OCCUR
COND TiCNS TO AVOID
Temperature greater than 400F.
N'A -NOT APPLICABLE
DO 086314 CONFIDENTIAL
THRESHOLD lt*n!T VALUE
3
___________0.2 mg/m based on lead.
tMfCTS & OVIRUPOSuW
Depending on individual susceptability and degree of over exposure., effects are generally ^een only after long-term exposure, although short-term high level, exposure may also be poisonous. Symptoms may include tiredness, decreased appetite, metallic taste, and stomach cramps resemb
ling colic (intermittent rather than continous pain). More severe symptoms could include true muscle weakness, intense headaches and on rare occasions convulsions and even more rarely death.
Kianey may occur without symptoms. Lead crosses the placenta. Fetal exposure should be kept wi thin guidelines of the Communicable Disease Center of the U.S. Department HEW-30ug/100g of blood
EMERGENCY AND flfiM AID PROCEDURES
Abnormal Ingestion-Induce vomitting by means of finger-in-throat, salt water or other means. Call a physician at once. External- The product may be removed by washing with soap and water.
sups io ftc taken in case material is released ot spilled
Wear gloves, goggles and respirator. Clean area returning all material possible to container. Do not use compressed air for cleaning floors and other surfaces. These surfaces should be cleaned by vacuuming, taking care that the material is not returned to the work area.
WASTE D SfOlAl method
Keep waste rags in labeled safety container-do not incinerate. with state, local or federal regulations.
Disposal must be in accoradance
RESPIRATOR** PROTECTION
NIOSH approved respiratory protection must be used in accordance with existing standards. Medical Removal Protection (MRP) and biological surveillance are necessary. Respirator must be worn if TLV is exceeded. "See 29CFR 1910.1025(k) "1910.134;1910.1000 Table 1-2.
VENTILATION
All work areas where lead compounds are used must be ventilated to keep TLV below acceptable
limits. See 29 CFR 1910.94.
PROTECTIVE GLOVES
yGS
EY PROTECTION
yes-goggles
OTHER PROTECTIVE EQUIPMENT Use respirator. Use clean work clothes. Change work clothes daily.
DO 086315
............... ............. "
` ....
TfLr If O i't 1 >:<
i- 0 L r* r t' ' C 'iVty T
" CONFTDFNTTAL
precautions to be taken in handling ano storing
Take every precaution to avoid contamination of the atmosphere. ^Special care should be given
to removing lead from hair and under fingernails. *Working or c ontaminated clothes and shoes
must not be worn home. *Before entering eating areas, work clothing should be removed or loose
dust vacuumed off clothing surface. *Take every precaution to avoid ingestion and inhalat1-
*Use gloves and avoid spilling on hands, face, or body. *Do not smoke, eat, or apply cosmetics
in work area. *Wash hands and face thoroughly before entering into eating areas. While the in
formation and recommendations set forth are believed to be accurate as of the date hereof,
Associated Lead Inc. MAKES NO WARRANTY WITH RESPECT THERETO AND DISCLAIMS ALL LIABILITY FROM
RELIANCE OR ACTION BASED THEREON. Because of the nature of the product, user assumes allrisk
with respect to it.
___
I Anzon Inc. MATERIAL SAFETY DATA SHEET
rm
sassSECTION I . * i^
V,j4uFACTUHER S NAME
ANZON INC.
REGULATORY AFFAIRS DEPARTMENT
12-27-85
STREET ADDRESS
2545 ARAMINGO AVENUE
CITY. STATE, Z\P
PHILADELPHIA, PA 19125
PRODUCT CLASS
Stabilizer-Pigment
MANUFACTURERS CODE 1.0.
34032
TRADENAME
D yphos Envirostab
[EMERGENCY TELEPHONE NO.
| 215-427-3000
. INGREDIENT
L4lJMilj.lld
PPM
tlv
mg/m1
1 vapor pressure
LEL%
mm Hg <S> 68*F
Dibasic Lead Phosphite (1) OSHA Standard, 29 CFR 1910.1025
0.05D
N/A
N/A
m
BOILING RANGE
N/A
iM
VAPOR DENSITY
PI HEAVIER
N/A
D LIGHTER than air
EVAPORATION RATE
l~l FASTER
N/A SLOWER THAN ETHER
% VOLATILE BY VOLUME
N/A
WEIGHT PER GALLON
N/A
SPECIFIC GRAVITY
3.9
EXTINGUISHING MEDIA
IS WATER-FOG
El FOAM
DOTHER
El CARBON DIOXIDE
El DRY CHEMICAL
unusual fire and explosion hazards
Isolate from heat, open flames and all sources of sparks including static electricity. Use non-metallic scoops. Equipment and hoppers must be properly grounded.
SPECIAL fire fighting PROCEDURES
Isolate and scatter material to cool. Cover with sand.
m jgjp ECTION WT^EAt^VIT^p)ATA
stability
CONDITIONS TO AVOID
FIunstable
UPATABUJTY .ERIAIS TO AVOID)
None.
STABLE
Keep dust accumulation to a minimum.
haVardous decomposition products
On ignition, oxides of lead may be volatilized.
HAZARDOUS POLYMERIZATION
may occur
WILL NOT OCCUR
CONDITIONS TO AVOID
Temperatures greater than 400 F.
N/A-NOT APPLICABLE
00 0B&31.6 CONFTDFNTTAL
THRESHOLD limit value
0.050mg/m3
EFFECTS OF OVEREXPOSURE
VI-2HEALTH ^HAZARD *DATA
Depending on individual susceptability and degree of overexposure, effects are generally seen only after long-term exposure, although short-term high-level exposure may also be poisonous. Symptoms may include tiredness, decreased appetite, metallic taste and stomach cramps resembling colic (intermittent rather than continuous pain). More severe symptoms could include true muscle weakness, intense headaches and on rare occasions convulsions and even more rarely death. Kidney damage may occur without symptoms. Lead crosses the placenta. Fetal exposure should be kept within guidelines of the Communicable Disease Center of the U.S. Department HEW-30ug/100g of blood.
EMERGENCY AND FIRST AID PROCEDURES
Abnormal Ingestion - Induce vomiting. Use syrup of ipecac-one ounce followed by eight ounces of water. Call a physician at once. Ext rnal - The product may be removed by washing with soap and water.
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Wear gloves, goggles and respirator. Clean area returning all material possible to container. Do not use compressed air for cleaning floors and other surfaces. These surfaces should be cleaned by vacuuming, taking care that the material is not returned to the work area.
WASTE DISPOSAL METHOD
Keep waste rags in a labeled safety container-do not incinerate. Disposal must be in accordance with state, local or federal regulations.
Kl
RESPIRATORY PROTECTION
NIOSH approved respiratory protection must be used in accordance with existing standards.
VENTILATION
All work areas where lead compounds are used must be ventilated to keep TLV below acceptable limits. See 29CFR
1910.94.
PROTECTIVE GLOVES
YS
eye protection
Yes - goggles
OTHER PROTECTIVE EQUIPMENT Use respirator. Use clean workclothes. Change workclothes daily.
DO 086317 CONFIDENTIAL
MMJMMMkWMAm jlX-^SPECIAL^RECAUTJONS I
PRECAUTIONS to BE TAKEN IN HANDLING and STORING
Take every precaution to avoid contamination of the atmosphere. 'Special care should be given to removing lead from hair and under fingernails. `Working or contaminated clothes and shoes must not be worn home. 'Before entering eating areas, work clothing should be removed or loose dust vacuumed off clothing surface. 'Take every precaution to avoid ingestion and inhalation. 'Use gloves and avoid spilling on hands, face or body. 'Do not smoke, eat or apply cosmetics in work area. 'Wash hands and face thoroughly before entering into eating areas. While the information and recommendations set forth are believed to be accurate as of the date hereof, Anzon Inc. MAKES NO WARRANTY WITH RESPECT THERETO AND DISCLAIMS ALL LIABILITY FROM RELIANCE OR ACTION BASED THEREON. Because of the nature of the product, user assumes all risk with respect to it.
N/A--NOT APPLICABLE
MATERIAL SAFETY DATA SHEET
(Approved by U.8. Department of Labor "Issantlslly Similar*' to Form Ui-OOM)
.TURlA'i MAUI
Section I
N L Industries, Inc,; Pigments and Chemicals Division '""VSSrgfflc. Box 420
i|Tv ,T|fff;cw jersey 08520
I emerqiTOW3M& EXT. 473 - Manager, Quality Control
CHEMICAL name AND SYNONYMS
Dibasic Lead Phosphite
TRADE NAME
"MIMICAL FAMILY
Lead Chemical
FORMULA
Dyphos
Sect: jn II - HAZARDOUS INGREDIENTS
PAINTS, PRESERVATIVES, & SOLVENTS
PIGMENTS
%
tlv
(Unite)
SOLVENTS
NPVLA 6-70
%
n.v
(Unit*)
CATALYST VEt^ -
ADDITIVES
OTHERS
HAZARDOUS MIXTURES OF OTHER UOUIOS. SOLIDS. OR OASES
Lead, Pb Phosphorous, P
%
TVV (Unit*)
84 0.2mg/l
4.0
1 SOILING POINT l*F )
VAPOR PRESSURE (mm Hq.) VAPOR DENSITY (AlRx=1) fOLUSILITY IN WATER
' APPEARANCE and odor
I
!
,ULSH POINT (METHOD USED)
Section III - PHYSICAL DATA
N/A
SPECIFIC GRAVITY
=
N/A N/A
PBYERVCOELNUTMVEO<L%AT) ILE
EVAPORATION RATE
( =t>
Slight
Fluffy White Crystal! ine Powder
Section IV - FIRE AND EXPLOSION HAZARD DATA
,,
N/A
flammable limits
,
N/A
6.1 N/A N/A
OO 086318
C0Nl" '"
k!_____________ _____y
('SPECIAL FIRE FIOHTINO"pROCEDURE
Isolate, scatter to cool and use sand to contain smoldering material,
productunusual fire and explosion hazards will auco Ignite and smolder Wheri excised to temperatures 400* rT
Reference Section II
Section V - HEALTH HAZARD DATA
thmsmolo UMIT v*i.wiprolonged excessive absorption of Inorganic lead by ingestion or Inhalation of
t'McTt mouth,
or ovcftiiposuftfdust Iobb of weight,
and fume pains in
ismucshcalersacatnedrizmeudscbuylaardwoemalknnael sps.ainTh(leead<mcnolircif)cymnettatllic taste in
wuithn tnhoase ogfi ovtt-hueert Illnesses require tnheat exxcceessisive absorption of lead be verified by medical
examination and analysis of biological specimens.
emergency ano host *10 procedures consult a physician If you have symptoms of illness. Abnormal Ingest!
/C'eal l1l aa phyns4ic4iaOnn aAtt* aomnacae. AA sa ff4irsetf aa 4idft , 4inwd<4uc*ea v,Aomm4 i^t4ingr>, g>4ive m* 4 i1lkla andJ ^m*aaganaes4iutumt* stut1lfCaa teea /(PEapsaoa Halt;. ExternaH normal work day accumulations can be effectively cleansed with soap and wat "Eyes: Use tlrst aid procedure tor dust.
stability
UNSTABLE
STABLE INCOMPATABILITV (Maurialt to avoid;
Section VI - REACTIVITY DATA
CONDITIONS TO AVOIO
X Temperatures > 400F.
NAIAR00US DECOMPOSITION PRODUCTS At high temperatures toxic fumes are emitted
hazardous
P0LVMERI2ATION
MAY OCCUR WIU not occur
X CONDITIONS to AVOID Auto ignites at 400F.
1W TO
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--.
Section VII - SPILL OR LEAK PROCEDURES
takENIN CASE MATERIAL is RELEASED Oft SPILLED Sweep carefully, wear gloves, goggles, and respirato
keep spark or flame sources away.
waste disposal mithod Landfill or smelter. Disposal must be done in accordance with local. state, and federal regulations.
Section VIII - SPECIAL PROTECTION INFORMATION
Rt ^iratort protection ^Speei/y
ancj/or fume respirator (Bureau of Mines Approved)
ventilation
local exhaustVinenSteilcatitoionnTIIprpBveildoewd aacscerpetgabulieredli,mbyit_sjo.b condition to keepr TLV liste
MECHANICAL (General)
OTHER
protective gloves
ygs
other protective eou.pment
Change of work clothes
EYE PROTECTION
goggles
Do n
Section IX - SPECIAL PRECAUTIONS
m
AUTIONS to BE TAKEN IN HANDLING AND STORING Handle carefully to avoid dusting.
Personnel must wear
OTHER PRECAUTIONS
dust respirator, gloves and goggles. Use non-metallic scoops. Equipment and hoppers used for Dyphos must be gr unded
July 18, 1973