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E--06440 f\AS?6.A&-5 DjuJjiu! DJ. (3 , m-ri., r[ oaJu^wo t l--6 V - <^> \ #>8,50 facsd. n... ____ This book is the property of Ethyl Cor poration and is assigned as desk copy to: (A). fi._M.OeA/ Please return the book to the Chemical Development Library when no longer needed. E--06441 RESPIRATORY PROTECTIVE DEVICES MANUAL PUBLISHED BY AMERICAN INDUSTRIAL HYGIENE ASSOCIATION AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS 1963 E--06442 / Copyright, 1963 American Industrial Hygiene Association American Conference of Industrial Hygienists Copies Available from: BRAUN AND BRUMFIELD, Inc. Box 1203 Ann Arbor, Michigan Price: $8.50 --06443 PREFACE Respiratory protective devices are perhaps the oldest method of controlling occupational diseases; however, health and safety personnel are generally less informed about the applications and limitations of these devices than about any other particular control device. Many books and technical reports have been written on engineering control measures, but it should be noted that no text exists covering compre hensively the field of respiratory protective devices. Because of the limited published technical data in this field, the committee has drawnlieavily upon the experience of respirator manufacturers, representatives from the U.S. Bureau of Mines, and infor mation made available by the American Standards Association. Throughout the preparation of thermanual, close cooperation of all these agencies was achieved. The manual primarily involves commercial devices; hence, there are specific technical details that cannot be discussed. Obviously, the respirator manufacturers are reluctant to jeopardize their develop ment investment and possible patent rights by disclosing information until such rights are protected. Research and development laboratories are reluctant to give interim progress reports, preferring to make the completed research available in the form of a technical report or of a product. Government classification may also make it necessary to withhold some of the developments. This book has been prepared primarily to provide the industrial hygienist and other health and safety specialists with technical information pertaining to the principles of operation of the various types of respiratory protective devices and their selection, use, and maintenance. Safety and supervisory per sonnel will find many of the chapters especially useful. This committee will gratefully receive comments and suggestions for future consideration. The manual will be revised as needed to present new practices and developments. Edwin C. Hyatt, Chairman Joint AIHA-ACGIH Respiratory Protective Devices' Committee in E--06444 ACKNOWLEDGEMENTS The Committee wishes to acknowledge the assistance of the following men who reviewed and made valuable suggestions for several chapters in this Manual. They are all acknowledged specialists in the respiratory protective field: Mr. William H. Revoir, Chief Engineer Respirator Development Laboratory American Optical Company Mr. Allan L. West, Chief Respirator Branch Protective Development Division U.S. Army Chemical Warfare Laboratories William J. Wiswesser Industrial Hygiene Department Willson Products Division Ray-O-Vac Company We also wish to acknowledge the valuable assistance of Harry F. Schulte for his technical reviewing and editing of Chapters 2 through 5; Mrs. Helen M. Miller for editorial assistance to the Chairman, and Mrs. Mary C. Singer for her services in typing the chapters in this Manual. v E--06445 AUTHORS ADLEY, Frank E., Manager, Occupational Hygiene Operation, General Electric Company, Richland, Washington. BERRY, Clyde M., Ph.D., Associate Director, Institute of Agricultural Medicine, State University of Iowa, Iowa City, Iowa. GILLILAND, E. W., Technical Consultant, Mine Safety Appliances Company, Pittsburgh, Pa. GLIDDEN, G. M., President, Acme Protection Equipment Company, South Haven, Michigan. HYATT, Edwin C., Industrial Hygiene Group, Los Alamos Scientific Laboratory, Los Alamos, New Mexico. INGRAM, Fred R., Consulting Engineer, Walnut Creek, California. JORDAN, Harry S., Jr., Group Leader, Environmental Radiation Field Studies Group, Los Alamos Sci entific Laboratory, Los Alamos, New Mexico. PEARCE; S. J., Chief, Branch of Health Research, U.S. Bureau of Mines, Pittsburgh, Pennsylvania. SCHRENK, H. H., Ph.D., Managing Director, Industrial Hygiene Foundation of America, Inc., Pittsburgh, Pennsylvania. SILVERMAN, Leslie, Sc.D., Professor of Engineering in Environmental Hygiene and Head, Department of Industrial Hygiene, Harvard School of Public Health, Boston, Massachusetts. vii "06446 COMMITTEE MEMBERS April 1958 to May 1962 Frank E. Adley Clyde M. Berry, Ph.D. Henry M. Doyle Andrew D. Hosey Fred R. Ingram Carl R. Jensen Harry S. Jordan, Jr. S. J. Pearce H. H. Schrenk, Ph.D. Leslie Silverman, Sc.D. William P. Yant, Sc.D. Edwin C. Hyatt, Chairman May 1962 to May 1963 Frank E. Adley Clyde M. Berry, Ph.D. R. A. Fulton, Ph.D. E. W. Gilliland G. M. Glidden A. D. Hosey F. R. Ingram C. R. Jensen H. S. Jordan, Jr. S. J. Pearce H. H. Schrenk, Ph.D. Leslie Silverman, Sc.D. E. C. Hyatt, Chairman ix E--06447 CONTENTS INTRODUCTION I. History of Respiratory Protective Devices.............................................................. II. Definition and Classification of Respirators....................................... .................... 1 2 CHAPTER 1. A RESPIRATOR PROGRAM.................................................................................................. I. Selection and Use...........-............................................................................................ II. Instruction................................................................................................................... m. Supervision.................................................................................................................... IV. Program Essentials..................................................................................................... A. Selection.................................................................................................................. B. Instruction............................................................................................................... C. Supervision........................................................................ D. Centralized Cleaning Station................................................................................ E. Inspection and Maintenance................................................................................... F. Storage......................................................................................................... G. Medical Surveillance............................................................................................. V. U.S. Bureau of Mines Respirator Testing and Approval............................... i VI. U.S.D.A. Respirator Evaluation Program ................................................................. VH. Unapproved Respirators . ........................................................................................... Vm. Surplus Military and Civilian Masks........................................................................ 3 3 3 3 6 6 6 6 6 6 6 6 6 7 8 8 CHAPTER 2. PHYSIOLOGICAL FACTORS IN RESPIRATORY PROTECTION..................................... L Introduction .................................................................................................................. n. Physiological Factors of Importance in Respiration through Protective Devices......................... A. Minute Volume....................................................................................................... B. Mean Inspiratory Flow........................................................................................... C. Instantaneous Air Flow ........................................................................................ D. Expiratory Air Flow............................... E. Tidal Volume.......................................................................................................... F. Mean Inspiratory and Expiratory Air Flows....................................................... G. Effects of Resistance Versus Air Flow.............................................................. H. Effect of Work Rate on Physiological Response in Respirators..................... L Respiratory Work Rate and ItsSignificance................... in. Tabular Data............................................................... TV. Reference Sources.................................................................... 9 9 10 10 10 11 12 12 12 12 13 14 17 17 CHAPTER 3. FACEPIECES...................................... I. Introduction. . .............................................................................................................. II. Relation of Respirator Dimensionsto Face Fit....................................................... A. Half Masks Fitting Under Chin(Type A)..................................... B. Half Masks Fitting on Chin (Type B)................................................................... C. Full Face Masks..................................................................................................... IIL Relation of Mechanical Features to Respirator Effectiveness............................... A. Peripheries of Facepieces................................................................................... B. Face Fit and Respirator Suspension................................................................... C. Valves .......................................................................................... D. Air-purifying Elements........................................................................................ E. Eyepieces (Lenses)............................................................................... F. Eyeglasses ............................................................................................................. G. Limitation of Vision................................................................................................ H. Speech Transmission...................................................... L Skin Irritation.......................................................................................................... J. Worker Acceptance............................................................................................... xi 19 19 19 20 23 23 26 26 27 27 29 29 29 29 31 32 32 V E--06448 xii RESPIRATORY PROTECTIVE DEVICES MANUAL CHAPTER 4. PARTICULATE FILTERS.................................................................................................... I. Introduction......................................................................................................... II. Filter Materials and Construction..................................................................... A. Materials ............................................................................................................... B. Construction.............................................. ;...................... ................................... III. Mechanisms of Filtration............................................................................................. A. Direct Interception............................................................................................... B. Inertial Impaction.................................................................................................. C. Diffusion............................................................................. ............................... . _ D. Electrostatic Attraction........................................................................................ E. Gravity.................................................................................................................... F. Over-all Efficiency.................................................................................... IV. Filter Performance Characteristics........................................................................ A. Efficiency.............................. 1. Filtration Velocity.................... 2. Fiber Size................................................ 3. Loading............................................................................................................ 4. Particle Size..................................................................................................... B. Pressure Drop....................................................................................................... V. Permissible Filter Medium Penetration................................................................... VI. Filter Testing......................................................................................... A. Dioctyl Phthalate (DOP)........................................................................................ B. Methylene Blue....................................................................................................... C. Sodium Chloride..................................................................................................... D. Uranine.................................................................................................................... E. Other Test Aerosols............................................................................................. 35 35 35 35 35 35 37 37 38 38 39 40 40 40 40 41 42 42 42 45 46 46 47 47 47 47 CHAPTER 5. SORBENTS FOR GASES AND VAPORS................................................................................ I. Introduction.................................................................................................................... II. Sorbent Requirements........................................................................ A. Sorbent Properties.......................................................................... B. Bed Depth............................................................................................................... in. Adsorbents................................................................................................................... A. Activated Charcoal................................................................................................ B. Molecular Sieves .................................................................................................. C. Activated Alumina.................................................................................................. D. Silica Gel.................................................................................................................. E. Hopcalite......................................................................................................... IV. Absorbents......................... V. Mixtures and Layers in Canister Manufacture.................. A. Advantages of Different Arrangements.............................................................. B. Universal Canister................................................................._............................. VI. Discussion and Recommendations Concerning the Use of Sorbents in Canisters . A. Moisture.................................................................................................................. B. Maintenance............................................................................................................. C. Use......................................................................................................................... VTI. Sorbents for SpecificGases and Vapors........................................................... VIE. Reference Sources..................................1.................................................................... 49 49 49 49 49 50 50 52 52 52 52 53 54 54 54 55 55 55 55 56 59 CHAPTER 6. AIR-PURIFYING RESPIRATORS........................................................................................... I. Introduction..................................................................................... '.......................... IL Types of Air-purifying Respirators.......................................................................... A. Particulate-removing Respirators...................................................................... B. Gas- and Vapor-removing Respirators.............................................................. C. Combination Particulate-removing and Gas- and Vapor-removing Respirators............................................................................................................. TO. Description and Principles of Operation.................................................................. A. Particulate-removing Respirator.............................................. 61 61 61 61 61 61 61 61 E--06449 CONTENTS xiii B. Gas- and Vapor-removing Respirators.............................................................. 1. Gas Masks.......................................................................................................... 2. Chemical Cartridge Respirators......................... 3. Mouthpiece Respirators................................................................................... C. Combination Particulate-removing and Gas- and Vapor-removing Respirators............................................................................................................. 1. Gas Masks.............................................. 2. Combination Chemical Cartridge Respirators with Filters........................ IV. Limitations and Factors Affecting Use.......................................................... A. Oxygen-deficient Atmospheres.............................................................................. B. Specified Contaminants ................................... C. Limited Concentrations........................................................................................ D. Limited Service Lives........................................................................................... E. Resistance to Breathing........................................... F. Facepiece Fit.......................................................................................................... 62 62 65 65 65 65 66 66 66 66 66 66 66 67 CHAPTER 7. SUPPLIED AIR RESPIRATORS............................................................................................. 69 I. Hose Masks .................................................................................................................. 69 II. Air Line Respirators.......................................................................................... 70 m. Abrasive Blasting Respirators.................................................................................. 72 IV. Supplied Air Hoods........................................................................................................ 72 V. Supplied Air Suits ................................................ 73 VI. Compressed Air Supply..................................................................................................... 74 VII. Maintenance and Supervision...................................................................................... 74 CHAPTER 8. SELF-CONTAINED BREATHING APPARATUS................................................................. I. Introduction...................................................... IL Types of Self-contained Breathing Apparatus............................................................ m. Description and Principles of Operation.................................................................... A. Demand Self-contained Breathing Apparatus .................................................... B. Recirculating Compressed Oxygen Self-contained Breathing Apparatus .... C. Oxygen-generating Self-contained Breathing Apparatus.................................. IV. Advantages and Limitations of Self-contained Breathing Apparatus................... V. Factors Affecting the Use of Self-contained Breathing Apparatus ...................... 75 75 75 75 75 75 76 77 77 CHAPTER 9. U.S. BUREAU OF MINES APPROVAL SCHEDULES AND TESTS..................................... L Approval System for Respiratory Protective Devices........................ H Test Methods .............................................................................................................. A. Self-contained Breathing Apparatus.................................................................... B. Gas Masks................................................................................................................ C. Supplied Air Respirators............................................................'........................ D. Dispersoid Respirators........................................................................................ E. Chemical Cartridge Respirators............................................ - ....................... 79 79 80 80 81 84 88 89 CHAPTER 10. RESPIRATORY PROTECTIVE DEVICES APPROVED BY THE U.S. BUREAU OF MINES.................................................................................................................................... 95 L Types Approved............................................................................................................. 95 A. Self-contained Breathing Apparatus Approved under Schedules 13, 13A, 13B, 13C, and 13D................................................................................................... 95 B. Gas Masks Approved under Schedules 14, 14A, 14B, 14C, 14D, 14E, and 14F..................................................................................................................... 95 1. Type A: Acid Gas Masks.............................................................................. 95 2. Type AE: Acid Gas, Dust, Mist, and Fog Masks........................................ 96 3. Type B: Organic Vapor Masks . *.................................................................. 96 4. Type BE: Organic Vapor, Dust, Mist, and Fog Masks.............................. 96 5. Type BE: Organic Vapor, Toxic Dust, Fume, Mist, and Fog Masks . .86 6. Type AB: Acid Gas and Organic Vapor Masks........................................... 96 7. Type ABE: Acid Gas, Organic Vapor, Dust, Mist, and Fog Masks .... 96 H--06450 xiv RESPIRATORY PROTECTIVE DEVICES MANUAL 8. Type ABE: Acid Gas, Organic Vapor, Toxic Dust, Mist, and Fog Masks....................................................................................................... 97 9. Type C: Ammonia Gas Masks...................................................................... 97 10. Type CE: Ammonia, Dust, Mist, and Fog Masks ..................................... 97 11. Type D: Carbon Monoxide Gas Masks....................................................... 97 12. Type N: Universal Gas Masks....................................................................... 97 C. Supplied Air Respirators Approved under Schedules 19, 19A, the Amend- ! ment to Schedule 19A, and 19B .............................. 98 ; 1. Type A: Hose Masks with Blowers ............................................................. 98 2. Type B: Special Hose Masks without Blowers........................................... 98 3. Type C: Air Line Respirators .................................................................... 98 4. Type CE: Abrasive Blasting Helmets, Hoods, or Masks ........................ 99 D. Dispersoid (Dust, Fume, and Mist) Respirators Approved under Schedules 21 and 21A........................................................................................... 100 1. Pneumoconiosis-producing and Nuisance Dust Respirators ................... 100 2. Toxic Dust Respirators................................................................................ 100 3. Dust Respirators .......................................................................................... 101 | 4. Fume Respirators............................................................................................ 102 I 5. Mist Respirators ........................................................................................... 102 j E. Nonemergency Gas Respirators (Chemical Cartridge Respirators) i Approved under Schedules 23, 23A, and 23B....................................................... 102 1. Type B: Organic Vapor Respirators............................................................. 102 2. Type BE: Dispersoid and Organic Vapor Respirators............................. 103 IL Names and Addresses of Manufacturers................................................................... 104 CHAPTER 11. SPECIAL APPLICATIONS................................................................................................. L Introduction..................................................................................................................... II. Respiratory Protective Devices for Radioactive Aerosols and Gases.................. A. History ..................................................................................................................... B. Current AEC Activities......................................... C. Commercial Devices.................................... D. Scope of the Problem............................................................................................. E. Interim Recommendations for Respirators to Provide Protection against Radioactive Aerosols and Gases........................................................................... 1. Dusts and Fumes of Extreme Toxicity......................................................... 2. Dusts and Fumes of Moderate Toxicity....................................................... 3. Radioactive Gases........................................................................................... 4. Fission Products ........................................................................................... F. Information Service................................................................................................ IIL Respiratory Protective Devices for Beryllium........................................................ A. Background Information........................................................................................ B. Interim Recommendations for Respirators to Protect against Beryllium and Its Compounds . . -...................................................... 1. Half Mask Respirators (Air-purifying Type) ............................................ 2. Full Face Respirators (Air-purifying. Type)............................................... 3. Supplied Air (Air Line)Respirators............ ................................................ 4. Self-contained Breathing Apparatus............................................................ IV. Respirators for Protection During Fumigation....................................................... A. Defining the Problem........................................................ B. Current Practice ................................................................................................... C. Recommendations for Respiratory Protective Devices for Protection during Fumigation........................................................... V. Respirators for Protection Against Insecticides .................................................... A. Background Information........................................................................................ B. USDA Respirator Program................................................................................... 1. Test Methods.................................... 2. Test Apparatus................................................................................................ 3. Results of Tests.............................................................................................. 4. USDA Recommended Respirators .............................................................. 105 105 105 106 108 110 110 110 110 Ill Ill Ill 112 112 112 112 112 113 113 113 113 113 113 117 119 119 119 119 119 120 120 E--06451 CONTENTS xv C. Air-purifying Respirators for Insecticides ............................................ .. D. Protection Against Skin Absorption...................................................................... VI. Thermal Protective Respirator ................................................................................ A. Background Information........................................................................................ B. Operating Principle............................ C. Construction............................................................................................................ D. Applications............................................................................................................ VIL Household Items for Emergency Use in Civilian Defense.................................... .. 121 122 122 122 122 122 123 123 CHAPTER 12. MAINTENANCE, CARE, AND STORAGE........................................................................... L Inspection . . .. .............................................................................................................. IL Cleaning......................................................................................................................... m. Storage.......... ................................................................................ 127 127 127 128 CHAPTER 13. TRAINING............................................................................................................................... L Introduction.................................................................................................................... II. Specific Training for Various Types of Respirators . ........................................... A. Particulate-removing Respirators...................................................................... B. Gas- and Vapor-removing Respirators.............................................................. 1. Chemical Cartridge Respirators................................................................. 2. Gas Masks........................................................................................................ 3. Mouthpiece Respirator(Self Rescue Respirator)................. C. Supplied Air Respirators...................................... ................................... ". . . . 1. Hose Mask with Blower................................................................................ 2. Hose Mask without Blower........................................................................... 3. Air Line Respirator........................................................................................ 4. Supplied Air Hoods ........................................................................................ 5. Supplied Air Suits.................................... D. Self-contained Breathing Apparatus.................................... 129 129 129 129 130 130 131 132 132 132 133 133 134 134 135 APPENDIX A. Definitions......................................................................................................................................... L American Standards Association Definitions........................................................................ IL Supplementary Definitions............................................................................. B. Recommendations Regarding Respiratory Protection Against Highly Toxic Aerosols .... C. Protection Against Particulates Significantly More Toxic than Lead.................................. D. Respiratory Devices for Protection Against Certain Pesticides (Reproduction of USDA Release, Dated Sept., 1962)................................................................................................ 137 137 138 140 141 143 INDEX................................................................................................................................................................. 153 E--06452 TABLES Table No. Page 2.1 2.2 2.3 3.1 3.2 3.3 3.4 3.5 4.1 4.2 5.1 5.2 5.3 6.1 9.1 9.2 9.3 9.4 9.5 9.6 9.7 9.8 9.9 9.10 9.11 9.12 Mean Air Flow Measurements and Gas Analyses for Nine Levels of Activity....................... 11 Mean Air Flow Measurements and Gas Analyses with External Resistance................... 13 Comparison of Mean Air Flow Measurements, Gas Analyses, and Standard Devia tions for Athletes and Nonathletes....................................................................................... 16 Selected Sizes of Type A Half Masks...................................................................................... 21 Summary of Respirator Fit Tests for 500 Men................................................................... 23 Selected Sizes of Type B Half Masks...................................................................................... 24 Arbitrary Tabulation for Rating Resistance of Exhalation Valves..................................... 28 Classification of Dynamic Leakage and Opening Pressures for Exhalation Valves.... 28 Particle Size Range for Separating Mechanisms................................................................. 37 Efficiency of Approved Dispersoid-Removing Respirators.............................................. 46 Effect of Adsorbed Water Vapor on Capacity of Charcoal for Organic Vapors only Slightly Solubl'e in Water . ........................................................................................ ............... 51 Nominal Resistances of Canisters Only................................................................................ 55 Sorbents for Gases and Vapors Listed in ACGIH Threshold Limit Values (1961)........... 56 ASA Color Code for Gas Mask Canisters................................................ 64 Limits of Carbon Dioxide Content of Atmosphere within Self-Contained Breathing Apparatus-during Approval Tests........................................................................................... 81 Duration of Specific Activities for Tests 1 through 4 of Self-Contained Breathing Apparatus ................................................................................................................................. 81 Duration of Specific Activities for Tests 5 through 8 of Self-Contained Breathing Apparatus ................................................................................................................... 82 Duration of Specific Activities for Tests 9 through 11 of Self-Contained Breathing Apparatus.................................................................................................................................... 82 Duration of Specific Activities for Tests 12 through 14 of Self-Contained Breathing Apparatus ................................................................................................................................. 83 Duration of Specific Activities for Test 15 of Self-Contained Breathing Apparatus.... 83 Test Conditions and Performance Requirements for Machine Tests on Gas Mask Canisters at Low Concentration and Low Rates of Flow.................................................... 85 Test Conditions and Performance Requirements for Machine Tests on Gas Mask Canisters at High Concentrations and High Rates of Flow............................ 86 Schedule of Exercise for Man Tests of Gas Masks ............ 87 Test Conditions and Performance Requirements for Mechanical Tests of SuppliedAir Respirators............... 88 Test Conditions and Performance Requirements for Dispersoid Respirators................ 91 Test Conditions and Performance Requirements for Machine Tests of Cartridges of Organic Vapor Chemical Cartridge Respirators............................. 91 xvi E--06453 RESPIRATORY PROTECTIVE DEVICES MANUAL xvii Table No. Page 9.13 9.14 11.1 11.2 11.3 11.4 11.5 Test Conditions and Performance Requirements for Machine Tests of Dispersoid Filters for Paint SprayRespirators.......................................................................................... 92 Schedule of Exercise for Man Tests of Chemical Cartridge Respirators........................ 92 Activities of Individual Particles and Daily Tolerances for Various Insoluble Materials..................................................................................... Types and Colors of Gas Mask Canisters to be Used for Respiratory Protection Against Specific Fumigants........................................................................................................ 118 Particle^ Size Classification for Pesticides........................................................................... 120 Chemical Classification of Pesticides and Their Threshold Limit Values........................ 121 Respiratory Protection Provided by Common Household and Personal Items Against Aerosols of 1 to 5 Micron Particle Size ............................................................................. 124 e'-06454 FIGURES Figure No. Page 1.1 Outline for selecting respiratory protective devices ......................................................... 4 2.1 Effect of various amounts of resistance on several mean values of physiological and subjective measurements for 12 subjects performing Series I and IL Work rate 830 kg-m/min................................................................. .. ................................................................ 14 2.2 Mean respiratory changes, airflow measurements, gas exchange, pulse, and subjec tive reactions for 10 subjects performing Series HI, conditions AA through Al. Work rate 415 kg-m/min.......................................................................................................... 15 3.1 Types of half mask facepieces...................................................... ........................................ 19 3.2 Facial measurements of importance in fitting facepieces................................................. 20 3.3 Length and width of Type A half masks, actual and five selected sizes.......................... 22 3.4 Length and width of Type B half masks, actual and three selected sizes ........................ 24 3.5 Size circles for fitting civilian protective masks................................................................. 25 3.6 Comparison of mask length with sizing circles.......... ....................................................... 25 3.7 Gas mask peripheries............................................................................................................... 26 3.8 Full face mask illustrating center mounted prescription glasses inside facepiece and nosecup insert ......................................................................................................................... 30 3.9 Full face mask illustrating method of mounting prescription glasses inside facepiece by special mount on each side and nosecup insert.............................................................. 30 3.10 Full face mask illustrating method of mounting prescription glasses inside facepiece with center mounted suction cup and nosecup insert............................................................ 31 4.1 The sizes of airborne contaminants ..................................................................................... 36 4.2 Particle removal by fibrous filter through mechanisms of interception and impaction . 37 4.3 Filtration mechanisms............................................................................................................. 39 4.4 Filter media configurations for increasing surface area.................................................... 41 4.5 Experimental collection efficiencies of the IPC filter mat for special polystyrene particles of density 1.05 and DOP smoke at ambient pressure.......................................... 41 4.6 Comparison of efficiency-velocity relations for experimental and theoretical values . . 42 4.7 Effect of running time on efficiency of AEC filter paper at a flow rate of 5 linear feet per minute................ ...................................... ........................................................................... 43 4.8 Clogging of various types of filter material......................................................................... 44 4.9 Penetration of homogenous DOP aerosols through a fiber glass FG-50 filter mat . . . . 45 4.10 Efficiency of respirator filter cartridges.............................................................................. 46 5.1 Adsorption capacity of activated charcoal as related to boiling point of contaminant . . 51 5.2 Comparative adsorption capacities of activated charcoal for chlorine derivatives of methane....................................................................................................................................... 51 5.3 Adsorption capacity of four commercially available impregnated charcoals for different contaminants............................................................................................................. 52 5.4 Effect of moisture content on adsorption capacity of alkaline absorbents........................ 54 xviii E--06455 RESPIRATORY PROTECTIVE DEVICES MANUAL xix Figure No. Page 6.1 7.1 7.2 7.3 7.4 7.5 7.6 8.1 8.2 8.3 9.1 9.2 9.3 9.4 9.5 9.6 9.7 11.1 11.2 11.3 11.4 11.5 11.6 13.1 Universal gas mask canister.................................................................................................. 59 Type A hose mask with hand-operated blower...................................................................... 69 Typical use of hose mask with blower.................................................................................. 70 Air-line respirator of the demand flow type................................. 71 Abrasive-blasting respirator of the helmet type........................................................... .. . 72 One type of supplied air hood.................................................................................................. 73 Supplied air suit of continuous flow type................................................................................ 73 Self-contained breathing apparatus, demand type............................. 75 Self-contained breathing apparatus, recirculating typecompressed oxygen...................... 76 Self-contained breathing apparatus, oxygen-generating type............................................... 76 Dust respirator approval label........................................................................ 79 Organic vapor mask approval label........................................................................................ 80 Test equipment used to determine effectiveness of universal gas mask canisters against carbon monoxide-air mixtures...................................................................................... 84 One of the man tests for gas mask canisters........................................................................ 87 Use of DOP smoke to locate and quantitate leakage where aerosol respirator contacts face.................................................................................................................................. 89 Illustrating use of DOP smoke generator and penetrometer to quantitate over-all peripheral face seal..................................................................................................................... 90 Testchamber for paint spray respirators............................................................................ 92 U.S. Army Chemical Corps M-9 gas mask equipped withthe M-ll canister.................... 106 U.S. Army Chemical Corps M-14 mask aerosol filter ...................................................... 107 U.S. Army Chemical Corps M-3 impermeable protective outfit........................................ 108 Respirator tester.................... 109 Warning bulletin on dangers of using surplus military masks ..................................... 116 Thermal protective respirator. Cross section illustrating metallic screens (heat exchanger) mounted in foam plastic shell of cartridge. The exhalation valve is plugged................................................................................................................................ Testing face fit, isoamyl acetate..................... 130 123 E--06456 INTRODUCTION In the control of those occupational - diseases spraying until about 1919 or 1920. The Bureau of caused by breathing air contaminated with harm Mines highlighted the early development of res ful dusts, fumes, mists, gases, or vapors, the pri pirators in 1923 when it described approved hose mary objective should be to prevent the air from masks sold for protection against irrespirabl? becoming contaminated. This is accomplished as gases. far as possible by accepted engineering control measures; however, although one may wish to be IL DEFINITION AND CLASSIFICATION OF RES idealistic in applying these procedures, there will PIRATORS always be circumstances in which, for one reason or another, the procedures will be uneconomical, inapplicable, impractical, or ineffective. Protec tive respirators will be needed for these situa tions, either as a primary means or as an adjunct or supplement to other primary control measures. The terms "respiratory protective devices" and "respirators," as used throughout this Manual, include gas masks, self-contained breathing ap paratus, chemical cartridge respirators, hose masks, abrasive blasting respirators, air line respirators, mechanical filter respirators, and combination mechanical filter--chemical cartridge respirators. Although by definition a "respirator" is any device used for providing respirable air, the use and connotation of the word "respirator" has be come both more specialized and quite variable. Some interpret it as a device for protecting against atmospheric contaminants alone; some envisage specifically a device to fit over the nose and mouth to protect against the inhalation of dust and smokes. To others, the word signifies a small face-type device for either gases or dusts, in con tradistinction to a larger device, such as a gas mask of the type with a breathing tube and a canis ter worn on the chest. Frequently, the scope of the meaning includes canister gas masks and even I. HISTORY OF RESPIRATORY PROTECTIVE DEVICES masks supplied with fresh air through hose lines. It appears logical to expand the scope further and include all devices for personal respiratory pro Respiratory protective devices are probably tection. the oldest method of controlling occupational dis In order to promote greater uniformity in the ease, their first use dating back at least as far as naming of the various devices that appear on the the Christian Era. Pliny the elder* (23-79 A.D.) market and to provide a basis for a clearer under describes filter respirators of a sort, for use standing of the operating principles and uses of against vermilion dust, and Agricola2 mentions the device as implied by the name, the Bureau of the use of such devices in various mining opera Mines and the American Standards Association tions in the 16th Century. Katz etal.2 in 1926, and (ASA) have promulgated standard definitions and Drinker and Hatch^ in 1935, gave a review of the classifications for respiratory protective devices. history and development of respirators. Davies Appendix A lists the ASA definitions, as well as in England in 1949 presented a good review of the some additional terms that are used in the res- filters used in* combat gas masks and discussed -pirator field and sometimes found in the literature. their possible application in industry. Respiratory protective devices are grouped Significant contributions to the design and broadly according to their mode of functioning. testing of respirators date from about 1900, with The basic classifications are: the real development of these devices dating from World War I. Drinker and Hatch note that in the Air-purifying respirators United States apparently no technical papers on Particulate-removing (mechanical filter) type respirators or masks appeared until after that Gas- and vapor-removing (chemical filter) type war, when the U.S. Bureau of Mines first started Combination particulate-removing and gas- investigations of respirators for industrial uses and vapor-removing type based on their earlier work on military gas masks. Atmosphere-supplying respirators 2jc.' Drinker mentions advertisements, dated 1914, il lustrating air masks for sand blasters as part of Hose-type atmosphere-supplying respirators Hose mask the equipment sold by an American manufacturer, Air line respirator and notes that masks supplied with fresh air were Continuous flow type * not used industrially for operations like paint Demand type 1 E-06457 2 RESPIRATORY PROTECTIVE DEVICES MANUAL Self-contained breathing apparatus Recirculating type Demand type Design details and operating principles are discussed in the following chapters: air-purifying respirators, Chapter 6; hose-type supplied air respirators, Chapter 7; and self-contained breath ing apparatus, Chapter 8. REFERENCES 1. Plinius Secundus, C.: Historae Naturalis, Lib. 33, Sec. 11. 2. Agricola, G.: De Re Metallica. Translation from first Latin Edition of 1556, by H. C. and L. H. Hoover, The Mining Magazine, Book 6, p. 214, London, 1912. 3. Katz, S. H., Smith, G. W., and Meiter, E. G.: Dust Respirators, Their Construction and Fil ter Efficiency, U.S, Bureau of Mines Technical Paper No. 394, 1926. 4. Drinker, P. and Hatch, T.: Industrial Dust, 1st ed., McGraw-Hill Book Co., Inc., New York, 1936, 316 pp. 5. Davies, C. N.: Fibrous Filters for Dust and Smoke, Proc. 9th Intern. Congr. Ind. Med., 162-196, London, 1948. i E--06458 Chapter 1 A RESPIRATOR PROGRAM This chapter presents the essential informa tion for the intelligent selection and use of res pirators, and the fundamentals of a respirator program. The chapter also considers the Bureau of Mines Approval Program, unapproved respira tors, and the problems of outdated and surplus gas masks. L SELECTION AND USE A respiratory protective device is used to protect the wearer from the inhalation of harmful atmospheres. The protection required may range from conditions which are mainly a nuisance, as from odor or irritation, to those which are imme diately dangerous to life. The hazard may be due to one or more toxic contaminants or to an at mosphere significantly deficient in oxygen. The contaminants may be in the gaseous or particulate state or a combination of both. Protection may be needed for only minutes, as in rescue operations, or for hours, as in routine use. For adequate protection against the multi plicity of conditions which may be encountered in individual operations, many types of respiratory protective devices have been developed. Each has a particular field of application and limitations from the viewpoint of protection, as well as ad vantages and disadvantages from the viewpoint of operational procedures and maintenance. The use of a respiratory protective device is justified only after a consideration of the factors involved indicates that the device selected will provide satisfactory protection when properly used. It is clearly evident, therefore, that the use of a respirator requires a thorough knowledge of such factors as the following: 1. The chemical, physical, and toxicological properties of the substance against which protec tion is required (Chapter 5, Table 5.3). 2. The effect of the processes and conditions of use of the substances as they relate to the pos sible formation of significant secondary products. 3. The processes and conditions of their use as they relate to the dissemination of contami nants. 4. An evaluation of,actual and potential haz ards to determine whether conditions immediately dangerous to life or health might arise or whether injurious effects would be produced only after pro longed or repeated exposures. 5. The nature of the duties to be performed by the wearer of protective devices, particularly as they relate to restriction of movements (see Chapter 13). 6. An understanding of the principles, design, scope of use, limitations, advantages, and disad vantages of the respiratory protective equipment available (see Chapters 6, 7, and 8). Virtually all applications of respiratory pro tective devices are specific and require individual attention. However, a classification of principal kinds of exposures and the type of respiratory de vice considered effective is given in Fig. 1.1. Since the various types of respirators were out lined in the Introduction and are described in other chapters, they will not be discussed here. The following discussion will be confined mainly to the nature of exposures and conditions affecting the use of respiratory protective devices. As shown in Fig. 1.1, hazardous atmospheres have been classified into two major groups: (1) oxygen deficient, and (2) those containing sig nificant concentrations of toxic contaminants. The toxic contaminants are classified into three sub groups depending upon physical state, namely, gaseous, particulate, and a combination of gaseous and particulate contaminants. From the viewpoint of hazard, the atmospheres containing toxic con taminants are grouped into two subgroups: (1) those immediately dangerous to life and (2) those not immediately dangerous to life. Under each classification is the type or types of respi rator considered satisfactory. This selection chart follows the classification system in this Manual for the various types of devices. - For protection against atmospheres deficient in oxygen, only the self-contained type of respi rator or the hose mask with blower is considered satisfactory. The oxygen content of normal air is about 20.9 percent by volume. Atmospheres in confined spaces such as wells, mines, holds of ships, tanks, and burning buildings may contain a lower per centage of oxygen because of dilution or displace ment of the air by other gases or vapors, or be cause of the loss of oxygen by its reaction with, or absorption by, other substances. When the oxygen content of the air is about 16 percent, the flame of a safety lamp will be extinguished. Below this con centration, a person breathing the air exhibits symptoms ranging from increased volume of E--06459 4 RESPIRATORY PROTECTIVE DEVICES MANUAL --06460 Fig. 1.1. Outline for selecting respiratory protective devices. (After Bureau of Mines information circular 7792. Numbers in parentheses refer to Bureau of Mines Schedules and Revisions thereof). A RESPIRATORY PROGRAM 5 breathing and acceleration of pulse rate to un consciousness and death, depending on the oxygen content of the air and the degree of his physical activity. For protection against concentrations of gas eous contaminants which are immediately danger ous to life, the self-contained apparatus, hose mask with blower, or gas mask may be used. Gaseous contaminants immediately dangerous to life are gases present in concentrations that would endanger the life of a person breathing them for even a short period of time. For example, 400 to 500 parts of sulfur dioxide per million parts of air (0.04 to 0.05 per cent) by volume is considered to be dangerous for a short exposure. A gas mask should not be used if the concentration of the con taminant is above 3 per cent by volume of am monia, 1 per cent of chlorine, or 2 per cent of other gases and vapors, as stated on the label of the particular canister. When the gas mask is used, the proper canister should be selected for protection against specific contaminants. It also must be borne in mind that high concentrations of gaseous contaminants may be irritating to the skin and mucous membranes, and also that some substances, such as hydrocyanic acid, can be ab sorbed through the unbroken skin. In addition, they may be explosive hazards. These factors, as well as respiratory protection, must be considered in using respiratory protective devices. For protection against concentrations of gas eous contaminants which are not immediately dan gerous to life, the air line respirator, hose mask without blower, or chemical cartridge respirator may be used. Gaseous contaminants not immedi ately dangerous to life are gases present in con centrations that could be breathed for a short period without endangering the life of a person breathing them, but which might produce discom fort and possible injury after a prolonged single exposure or repeated short exposures. For in stance, the threshold limit value for sulfur dioxide has been set at 5 ppm, based primarily on the ir ritating effect of the gas on the nose, eyes, and throat. If the concentration of organic vapors is above 0.1 per cent by volume, the chemical car tridge respirator should not be used. For protection against concentrations of gas eous and particulate contaminants which are im mediately dangerous to life, the devices that were listed for gaseous contaminants may be used, with the addition that the gas mask should be provided with a special filter. For protection against particulate contami nants, the-dust, fume, or mist respirator, air line respirator, or abrasive blasting respirator may be used. The majority of particulate contaminants are not immediately dangerous to life; that is, days, weeks, or even years of exposure may transpire before harmful effects are noted. Nota ble exceptions are dusts and mists containing the organic phosphorus insecticides which, if present in high concentrations, may incapacitate or even kill a man in a very short time. Other exceptions to this generalization are certain radioactive par ticulates and beryllium. For protection against highly toxic contami nants such as radioactive aerosols, beryllium,'and pesticides (not shown in Fig. 1.1), see Chapter 11, Sections n through V. IL INSTRUCTION The selection of respiratory protective equip ment should be the responsibility of a person with adequate training and experience to decide if the respirator is a desirable control measure and to evaluate thoroughly the hazard, the limitations of the various types of devices, and the conditions of Usage. Of equal importance to proper selection is proper use and maintenance (see Chapter 12 for maintenance recommendations). The failure of a respirator to give adequate protection may result from improper use and maintenance as well as from improper selection; therefore these factors require particular emphasis. No one should be permitted to wear a respi rator as a control measure unless he has been in structed in its use (see Chapter 13 for training). The purpose for which the respirator is to be worn, its operating principles, its limitations, and the essential parts should be explained to the wearer. There should be both demonstration and practice in how the respirator should be worn, how to adjust it, and how to determine if it fits proper ly. The extent of instruction varies from a specific and detailed training program for the use of selfcontained breathing apparatus to brief instructions for the simpler devices, such as the dust respi rator. In general, the amount of training is directly related to the anticipated hazard. For example, " the training should be thorough- and complete for devices that will be used in atmospheres immedi ately dangerous to life. In the use of the gas mask, the wearer not only must be acquainted with all mechanical aspects of the apparatus but also should be trained in the detection of the odor and irritating effects of incipient concentrations so that he can immediately detect when the canister is exhausted. The use of devices in an emergency by unauthorized or untrained persons will only handicap a rescue operation. m. SUPERVISION After a wearer is instructed in the use of a selected respirator, he needs adequate supervision, ET--06461 6 RESPIRATORY PROTECTIVE DEVICES MANUAL as 'well as an explanation of the character and magnitude of the hazard. The respirator should be inspected to assure that it is in proper operating condition. The device should then be carefully ad justed in fresh air, paying particular attention to obtaining a gas-tight fit with the facepiece. The wearer should enter the contaminated air cautious ly, and if there is any evidence of improper func tioning of the device, he should return to fresh air to determine the cause. If the atmosphere is im mediately dangerous to life, the wearer should know the approximate length of time that the res pirator will allow him to remain in the contami nated area, and he should know his distance from fresh air. If the wearer is to enter a confined space, such as a tank, he should use a life line, and attendants with similar apparatus should stand by in fresh air in case of an emergency. The use of respirators under such dangerous conditions should always be under strict supervision, and the wearer should never be permitted to operate alone. When respirators are used for routine pro tection in atmospheres not immediately dangerous to life, supervision can be much less and the indi vidual wearer can be responsible for proper use of the device if he is adequately trained. Closer supervision is required if a respirator is worn for protection against toxic particulates which could produce chronic poisoning, or against dusts pro ducing fibrosis or other significant pulmonary im pairment, than is needed with so-called nuisance dusts whose effects are negligible. In general, however, some degree of supervision should be in effect at all times. IV. PROGRAM ESSENTIALS the device is complete and in proper operating condition. Provide such supplemental safety pre cautions as a life line and stand by rescue per sonnel where needed. D. Centralized Cleaning Station Use a centralized cleaning station to clean respirators after each use when they are used routinely; see Chapter 12 for cleaning methods. Assign each worker two respirators marked with his initials or number so that he retains the same respirators and has a clean one always available. E. Inspection and Maintenance Devices used routinely can be inspected dur ing cleaning, and worn or deteriorated parts re placed with parts specifically designed for the particular respirator. Filters or cartridges may be changed after each use or according to schedule. Emergency equipment should be thoroughly inspected at scheduled periodic intervals to as. sure first-class condition at all times. F. Storage Store equipment in dustproof containers (original cartons, cases, or plastic bags are suit able) away from sunlight, heat, extreme cold, and excessive moisture. G. Medical Surveillance Since respirators are a control measure, per sons using them should have the same medical supervision as persons protected by ventilation or other control measures. The effective use of respirators in industry requires a planned program with responsibility specifically assigned to an adequately trained, ex perienced person. The following are essential parts of the program: A. Selection Select a respirator that will protect ade quately, and one that can be worn with reasonable comfort under the conditions of use. B. Instruction Instruct the wearer in the need for using the device and the means by which protection is af forded. Demonstrate and have the wearer practice obtaining proper facepiece fit and adjusting for comfort and effective protection. C. Supervision Supervise to assure that the proper device is being used for each exposure condition and that V. U.S. BUREAU OF MINES RESPIRATOR TEST ING AND APPROVAL The U.S. Bureau of Mines, through its central experiment station in Pittsburgh, in 1919 began issuing schedules for testing respiratory protec tive equipment of specific types. Under the cur- rent Bureau of Mines approval schedules and tests the manufacturer of respiratory protective devices can for a reasonable fee have his products tested and approved by the Bureau, a now widely accepted procedure throughout the United States. The Bureau of Mines currently has five ap proval schedules (see Chapter 9) under which it tests and approves the following types of respira tory protective devices: (1) self-contained breath ing apparatus, (2) gas masks, (3) supplied air respirators, (4) nonemergency gas respirators (chemical cartridge respirators), and (5) dust, fume, and mist respirators. Several types of respirators that are cur rently available are not covered by existing Bureau A RESPIRATORY PROGRAM 7 of Mines approval schedules. These are (1) filter type respirators for protection against materials significantly more toxic than lead, such as radio active aerosols, beryllium, and pesticides; (2) chemical cartridge respirators for protection against gases and vapors other than organic va pors; (3) escape type self-contained breathing ap paratus; (4) combination air line and self-contained breathing apparatus; (5) supplied air suits; and (6) combination air supplying-purifying device us ing a facepiece, helmet or suit. The Bureau of Mines* is considering the feasibility of establishing performance require ments for types (2), (3), and (4) above, and work is in progress on a revision of the performance re quirements for supplied air respirators. The Bureau of Mines is currently engaged in establish ing test procedures and assembling information on which to base performance requirements for fil ter type respirators noted above in (1). The Bureau of Mines, at present, approves devices to be used only for protection against con taminants not significantly more toxic than lead. Since the end of World War. II many highly toxic materials, including radioactive aerosols, berylli um, and organic phosphates (insecticides and nerve gases), have been marketed. Before the in troduction of these extremely toxic contaminants, many users assumed that respirators approved for lead fume would protect adequately against other toxic fumes. Following World War II, however, the Bureau of Mines decided to limit the approval of dust and fume respirators to dusts and fumes that are not significantly more toxic than lead. Before selecting any respirator one must be aware of the limitations imposed by face fit and the limits of the Bureau of Mines schedules, as described in Chapter 9. Ignorance of these limita tions and improper use have resulted in overex posure to the workmen. Tentative approval requirements for materi als significantly more toxic than lead have been prepared. Obviously many respiratory protective devices must be selected and used for such con taminants. Chapter 11 (Sections II through V) deals specifically with this subject, and Appendix B contains interim recommendations for respira tory protective devices for protection against aerosols that are significantly more toxic than lead. These interim recommendations differ from those first published^ in that limitations of the half mask respirator are given. VL USDA RESPIRATOR EVALUATION PRO GRAM The U.S. Department of Agriculture (USDA) in 1949 initiated an. investigation of respiratory protective devices for operators handling pesti cides. Respirator manufacturers were invited to submit devices that might provide suitable protec tion against pesticides. Since 1950, the USDA has issued several lists of devices tested and found satisfactory against specific pesticides. Two types of devices are listed in the 1962 report (see Appendix D)--chem ical cartridge respirators and gas masks. This report includes other precautionary measures to be observed. The methods of testing these devices are described in Chapter 11, Section V. VIL UNAPPROVED RESPIRATORS Two main groups of unapproved respirators are of great concern: the "nuisance dust respira tors* sold by many of the respirator manufac turers, and the respiratory protective devices for protection against special materials significantly more toxic than lead. Unfortunately, if a device lacks approval, it is not readily apparent whether this is due to the lack of a suitable schedule, to failure of the device to meet approval under an existing schedule, or to not having been submitted to the Bureau of Mines for approval. If a qualified individual selects the respira tory protective devices for a particular situation (see Section I), some of the unapproved devices may be used safely. Since the inhalation and exhalation resistance is a large factor in U.S. Bureau of Mines approv als, anyone selecting unapproved devices should give these facts full consideration. High resist ances will increase the leakage due to poor fit as well as at connections of cartridges, canisters, valves, and other parts. Low resistances may in dicate open valves, very inefficient filters or even worn |punctured parts. An employee selecting a device will generally select one having a low re sistance, regardless of other important factors that must be considered. Many respirators are selected and bought by a purchasing department, which may be attracted by the cheapest price. Often the purchaser gives little thought to the type of problem and the degree of protection afforded. Obviously, an inexpensive respirator with a frame holding a piece of gauze or a sponge is ineffective against toxic dusts and should never be used for such a purpose.. Un questionably there are .nuisance dust problems, and some of the nuisance respirator filter media on the market may be 50 to 95 per cent efficient against 1 to 5 micron (jjt) in diameter dusts. Nuisance respirators may be effective for certain limited applications, as when 20m pollen particles must be filtered to protect hay fever sufferers. Nuisance respirators should only be used for dusts positively known to be non toxic. E-0&463 8 RESPIRATORY PROTECTIVE DEVICES MANUAL Vm. SURPLUS MILITARY AND CIVILIAN/ an employer may be subject to legal action if one MASKS of his employees should be injured while wearing a surplus military mask issued by the employer. Following World War I, thousands of surplus Surplus respiratory protective devices also masks were thrown on the market and used for originate from the U.S. government agencies us protection against substances for which they were ing them for the protection of civilian personnel. never intended. There were many nonfatal poison Civilian government agencies have no uniform in ings of workers^ in ammonia plants and of fire structions regarding the disposition of surplus men who used these devices when they were ex respirators. Surplus devices are not available posed to carbon monoxide. These poisonings re from manufacturers of respiratory devices, since sulted in widespread newspaper publicity which the industry polices itself through the Industrial emphasized the hazards of using such devices. Safety Equipment Association. After World War II the U.S. Army Chemical Corps It is strongly recommended that individuals policy45 was very conservative, as indicated in responsible for the disposal of surplus equipment the following instructions issued to all military follow this guide: personnel in September 1948: 1. If a respiratory protective device is judged "Surplus masks must be rendered useless for inadequate for the protection of your personnel, it further use as gas masks in the interest of mili should be completely destroyed and not placed on tary security and public health and safety by the a government surplus list to endanger the health of removal of the canister. The canister may be de anyone buying such a device through a surplus militarized by smashing it, punching several holes dealer. completely through it, or by disassembling it if 2. If an agency has large quantities of new but recovery and sale of the components is considered unneeded respiratory protective devices which economically feasible. However, disassembly currently are on the market and approved by the must be done so that the canister cannot be re Bureau of Mines, and if these respirators are of assembled.* the simple dust type (in new condition) they may To eliminate further the possible disposition be safely surplused. If they are of the air-purify by sale of Chemical Corps controlled surplus gas ing type, with chemical cartridges or canisters, masks, the following additional instructions were and have been stored three years or longer, they furnished to all military personnel: "Surplus should be destroyed. If the canister is attached to military type protective masks will be demili the facepiece (with bottom seal intact), the canis tarized as follows: the facepieces of surplus pro ter should be discarded after one year (see tective field masks will either be chopped or cut Chapter 12). up so that they cannot be repaired, or destroyed entirely by burning, depending upon the method of disposal. . . . Canisters for military type protec REFERENCES tive masks will be destroyed by burning. Under no circumstances will canisters be declared or sold 1. Pearce, S. J.: A Discussion of the Bureau of as scrap.* Mines Approval Schedules for Respiratory The above instructions notwithstanding, a lim Protective Devices, Am. bid. Hyg. Assoc. J., ited quantity of assorted gas masks periodically 19:126-129, Apr. 1958. are offered to the public, from stocks evidently 2. Respiratory Protective Equipment (Joint AIHA- purchased many years ago by surplus dealers, ACGIH) Committee: Recommendations Regard before -the disposition instructions were issued.- ing Respiratory Protection-Against Highly Tox These sales cannot be legally restrained; however, ic Aerosols, Am. bid. Hyg. Assoc. J., 22:214, warnings to the public (for example, the warning June 1961. bulletirf'issued by the State of Kansas, as shown in 3. Patty, F. A.: Industrial Hygiene and Toxicology, Fig. 11.5) are encouraged by the military authori 2nd Ed., Vol. I, 343-355, Interscience Publi ties to eliminate the misuse of these masks. shers, Inc., New York, N.Y., 1958, 830 pp. ,The following three factors are involved in 4. U.S. Army Chemical Center: Disposition of (he use of surplus military masks. First, the Chemical Corps Items, dated 15 Sept. 1948, canisters will not protect against carbon monoxide superseded by Chemical Corps Materiel Com Or ammonia and are not designed for industrially- mand Regulation No. 755-2, Disposal of Sup occurring concentrations of other gases and va plies and Equipment, dated 26 Oct. 1960. pors. Second, the rubber in the facepieces, valves, 5. U.S. Army: Army Regulation No. 755-71, dated and head harness may have deteriorated. Third, 29 Sept. 1960. E--06464 Chapter 2 PHYSIOLOGICAL FACTORS IN RESPIRATORY PROTECTION L INTRODUCTION The purposes of -this chapter axe to describe the physiological factors which must be considered in respiratory protection and to discuss those physical factors in the protective respiratory equipment that must be considered in the design, testing, and use of respiratory devices. The types and applications for protective respiratory devices are discussed in detail in subsequent chapters. However, it should be mentioned that, in terms of physiological requirements, the distinction be tween the devices must be based primarily upon their inherent design characteristics. Physiological demands are the greatest for the widely used filter or canister respirator, in which the wearer breathes through the protective filter or sorbent, or combination thereof, and then exhales through a relief valve of some type. In supplied air units of the type utilizing de mand or diaphragm valves or utilizing a self generating canister, the respiratory resistance requirements are not severe since a forced draft or positive air supply exists, or there is supply which can be triggered by a slight negative pres sure. Exhalation from these devices would be comparable to that in the induced flow type of equipment, except for the self-generating unit, in which exhaled flow is through a canister and then into a bag or bellows under a slight positive pres sure. Supplied air respirators of the continuous flow type differ completely in that a continuous flow of air is provided to the wearer, and the only physi ological requirement is that total flow supplied should be' greater than the peak instantaneous value. Details of peak flows created during inhala tion are covered in this chapter so that the essen-. tial physiological requirements for all types will be included. This chapter does not describe respiratory physiology in detail nor cover the mechanism of oxygen transport through! the pulmonary mem brane. It is essential that the wearer of a particu lar respiratory device understand its purpose. Some devices provide flows of particulate- or gasfree air or air with minimal contamination by re moving contaminants from the existing atmos phere. In other cases, they may provide an inde pendent source of oxygen or air. In certain indus trial exposures, oxygen-deficient atmospheres can exist. Naturally they should never be entered without a device that will supply oxygen. For purposes of this chapter the lungs may be considered to be inflatable bags in which the infla tion is created by the downward movement of the diaphragm. Flow of air into the lungs must enter through the nose or mouth into the oral nasal cavity and thence through the trachea into its sub divisions, the large bronchi. Flow then proceeds into the small bronchi and into the smallest re ceptacles of the lungs, the alveoli. The important point to emphasize here is that inhalation or in spiration is an active movement created by a nervous impulse to th# phrenic nerve which in nervates the diaphragm and causes it to contract downward, which inflates the lungs. The motiva tion for this, which is both nervous and chemical in nature, is not of primary concern here and can be reviewed in detail by reference to a number of textsl-3 on human physiology. During inhalation, oxygen transport takes place through the epithelial membrane to the blood circulating through the lungs; while this is being achieved, there is simultaneous passage of carbon dioxide into the lungs. During exhalation, which is passive except under forced movement, the diaphragm relaxes. By means of this relaxation the lungs are deflated through elastic collapse, expelling the air through the same airway system. It should be pointed out that exhalation can be forced by a contracting action of accessory mus cles known as the external and internal intercostals. These muscles which surround the lungs and rib cage can, by their action, induce forced exhalation. However, the important distinction to "bear in mind in regard to breathing through res piratory impedance, such as filters and sorbent canisters, is that inhalation is an active action while exhalation is passive. For this reason it is possible for a subject or wearer of respiratory devices to inhale through a higher inspiratory re sistance than that through which he can exhale. This is the primary reason that inhalation re sistance values that can be tolerated by subjects are greater than those on exhalation. It should be mentioned, however, that subjects can be trained to exhale against resistance. Once muscle conditioning for this purpose has been achieved, performance of the individual is not Impaired and wearing such a respirator is not considered an abnormal physiological task. This E--06465 A' \ 10 RESPIRATORY PROTECTIVE DEVICES MANUAL is true for the wearers of self-contained under water breathing apparatus (SCUBA). It is es pecially so in the case of pressure demand oxygen equipment used by pilots at elevations about 40,000 feet (ft), where a small positive exhalation resistance increases the altitude capabilities of the wearer. Since the lungs are a device designed pri marily for gaseous exchange and involve a two phase system, namely, a gas phase on one side of the membranes and a liquid or blood phase on the other, it is necessary to consider the influence of the respiratory resistance and physical work of breathing on other factors. It should be remem bered that, anatomically speaking, the cardiac system--that is, the heart--is also in the lung > cage. Thus, if severe positive pressures are created within the cage because of forced breath ing in either phase, stress will be placed upon-the thin walls of certain heart vessels. Most of the disturbing effects will occur, fortunately, at re sistance values far higher than those which can be tolerated by a subject without almost immediate subjective complaints. The manner in which air enters and leaves the airways of the lung during breathing with differ ent amounts of inspiratory and expiratory resist ance can be represented by the shape of the air flow curves developed by measuring instantaneous flow on a time scale. There are certain factors to be considered when the lung is represented as a set of inflatable bags which are not of a complete ly collapsible structure. One, of course, is the socalled anatomical dead space beyond which volume the lung cannot contract. The other is the maxi mum volume which the lung can occupy in full ex pansion. This is considered the vital capacity, which can be determined by complete inhalation from a volume-measuring device or by complete exhalation from full distention of the lungs into a similar device. Actually, the vital capacity and anatomical dead space of the lungs are not of pri mary concern in evaluating ability of the wearer to tolerate the influence of resistance or respira tory impediments on breathing. However, the dead space and the tidal volume (the volume of air per breath) have a relation to the volume of the air included within the respira tor cavity, which is known as respirator dead space. This volume does become contaminated with various amounts of carbon dioxide from the previous exhalation, which is thus inspired on each subsequent inhalation. Carbon dioxide in sig nificant amounts can stimulate the respiratory center. It has been determined that the dead space of the respirator cavity is not of consequence if it does not exceed 150 to 200 milliliters (ml). It ob viously is of greater significance at rest with minimal air flow requirements. It should be borne in mind, however, that dead space of breathing ap paratus is an important consideration in their de sign and that minimal volumes should exist in respirators. In positive supply equipment this consideration is unnecessary. IL PHYSIOLOGICAL FACTORS OF IMPORTANCE IN RESPIRATION THROUGH PROTECTIVE DEVICES Physiological factors which are important in respiration under sedentary and working condi tions are the following; minute volume, mean in spiratory flow, instantaneous air flow, expiratory air flow, tidal volume, mean inspiratory and ex piratory air flows, inspiratory and expiratory re sistance to air flow, work rate, and respiratory work rate. They are discussed in detail below. A. Minute Volume The minute volume is the volume of_air_ breathed per minute by the subject'. Thismay"5e_ measured during inhalation or exhalation. There Tsvery llffle^ifference betweeiiTthese two values because the depletion of oxygen during inhalation is compensated for by a volume of carbon dioxide and water vapor from the metabolism of the body. Minute volumes for adults vary from a mini mum of 5 liters, corresponding to subjects under basal conditions or complete rest, to above 100 liters at heavy work. Table 2.1 indicates average values measured at 20C for a number of condi tions. Minute volumes, significantly higher than the 100 liters shown for maximum exertion will be required by certain individuals at maximum ef fort However, the values presented in Table 2.1 are primarily for purposes of general considera tion and are of concern to those interested in de signing masks or estimating and evaluating flows encountered in their use. B. Mean Inspiratory Flow. Since inspiration may i>e approximately 40 per cent of the total cycle during resting condi tions and 50 per cent during work, the average in spiratory flow rate is thus usually considered ar twice the numerical value of the minutp volume for working conditions. This concept , has been used as the basis for resistance and penetration measurements and for testing purposes. However, it should be pointed out that the maximum flow may attain values ranging to almost four times the minute volume. Early studies led to the assumption that 85 _ liters per minute (1/min) represented thp_masHmum_averageJttow rate for air into or out _pf_the_ lungs during, sustained work. This value was Based on measurements which corresponded to the E-06466 TT 21B 21A Silica Dust (0.4-0.6 micron) Test Concentration Max. Leakage -- 3 respirators Max. Leakage -- 1 respirator 50-60 mg/m3 4.5 mg 2.0 mg 40-60 mg/m3 9.0 mg 4.0 mg Lead Dust (0.4-0.6 micron) Test Concentration Max. Leakage per respirator 15-20 mg/m3 0.43 mg 10-20 mg/m3 0.43 mg Lead Fume Test Concentration Max. Leakage per respirator 15-20 mg/m3 1.5 mg Silica Mist (325 Mesh Si02) Test Concentration Max. Leakage per respirator 20-25 mg/m3 2.5 mg 10-20 mg/m3 1.5 mg 5-15 mg/m3 2.5 mg Chromic Acid Mist Test Concentration Max. Leakage per respirator 15-20 mg/m3 1.0 mg 10-20 mg/m3 1.0 mg In addition, Schedule 2IB requires the use of 0.3 micron DOP (dioctyl phthalate ) aerosols for evaluating respira tors for materials having a TLV less than 0.1 mg/m3. MSA RESPIRATORS CURRENTLY APPROVED UNDER SCHEDULE 21B Custom Comfo S Cat. No. Dusts, mists and fumes having a (BM21B-69) 10-86431 TLV not less than 0.1 mg/m3 or 2.4 mppcf. (Class 1,2,3) Custom Comfo H Cat. No. Dusts, mists and fumes having a (BM 21B-90) 10-86432 TLV less than 0.1 mg/m3 (Pro tection factor of 10). (Class 4) Dustfoe 77 (BM 21B-97) Cat. No. Dusts and mists having a TLV 10-96000 not less than 0.1 mg/m3 or 2.4 mppcf. (Class 1,3) /V\5A MINE SAFETY APPLIANCES COMPANY 201 NORTH BRAOOOCK AVE., PITTSBURGH. PA. 1S20B Printed in U.S.A. 6710 Pertinent Information Concerning i Bureau of Mines Approval Schedule 21B ET-06467 E--06469 -r-- -- < Ct exited M >* E-0&4"70 ** S55 fSg,o<So8SsySo: .1111:1; ^ ?r. 8' r*e'E%. gH gn._- oci.iJ,^SJ0srSw 25-g P 1? se Sl*| il:iagcp SB 5B g> E2 " Sol rt;i !m*i ill !1|" ail ?l?f?a E-06471 erg o cm pfMe f IPIPIPKM* gag s fli Sill? sref? In S|i| lifllllllIff nils _ O O cn w 55 52 ^ ft "* sia&^s "gels*0 | lsi|if ip PaSl ess li^gII8 &2agt& ais fSS'gS55^6- 5g S!2s.fiL*llssraa 5 J3C O* : & & 2 b p s aaE * SsfS& & S ^j? o IM!.-P|i fitftitli1ffi: HiF I s'llfg'i-Igll fiUni? I 'sslifs * S P. P 5 Ha aPsli1 -s: 8 ig.lkf* sg-s r e *% Eitnife^a8iw B&P' ?2 2. ** Saiga- gSig&5'Pg lllfilf? tail III! s Ilflf ess t(jBar8 SIfMa INOI iWfcB. E--06472 E--06473 .. u r t u i w rtiATiRt orrtcii im PHYSIOLOGICAL FACTORS nj RESPIRATORY PROTECTION TABLE 2.1 MEAN AIR FLOW MEASUREMENTS AND GAS ANALYSES FOR NINE LEVELS OF ACTIVITY4 11 Measurement Sedentary 0 Work Rate, Kg-M/min 208 415 622 830 1,107 Subjects Pulse rate per minute Respiration rate per minute Minute volume, liters Maximum inspiratoryHow, l/min Maximum expiratory flow, l/min (Maximum inspiratory flow)/(minute volume) (Maximum expiratory flow)/(minute volume) (Maximum inspiratory flow)/ (maximum expiratory flow) (Inspiratory cycle)/(total cycle), % (Expiratory cycle)/(total cycle), % (Rise)/(inspiratory cycle), % (Sustained flow)/(inspiratory cycle), % (Maximum flow occurrence)/ (expiratory cycle), % (Rise)/(expiratory cycle), % (Sustained flow)/(expiratory cycle), % Oxygen deficit, % Oxygen consumption, ml/min Carbon dioxide production, ml/min Respiratory quotient 29 73 14.6 10.3 40 32 3.9 3.1 1.3 39.2 57.6 17.7 58.7 27.7 11.8 49.3 3.56b 306 261 0.85 12 93 19.6 14.2 49 43 3.4 3.0 1.1 41.4 58.2 20.7 59.0 37.5 20.3 37.4 3.89 496 425 0.86 12 105 21.2 20.8 63 58 3.1 2.8 1.1 44.1 55.8 16.3 65.3 47.9 23.5 51.0 4.30 800 695 0.87 14 116 22.7 29.9 84 85 2.8 2.9 1.0 46.8 53.2 13.3 69.4 46.8 21.6 52.3 4.41 1176 1068 0.91 12 128 23.0 37.3 100 107 2.7 2.9 1.0 48.2 51.7 13.8 65.9 46.7 22.3 53.1 4.63 1545 1432 0.93 59 158 30.4 54.7 149 154 2.7 2.8 1.0 48.3 51.6 11.2 71.1 45.1 18.8 57.7 4.31 2075 2017 0.97 46 166 34.8 75.3 194 211 2.6 2.8 0.9 49.4 50.6 14.3 69.8 44.0 19.0 59.7 4.12 2723 2723 1.00 a. Resistances were 6 mm of water inspiratory and 3 mm expiratory. b. Values from 11 subjects are included in the mean values for gas analyses. 1,384 8 177 40.7 104.0 254 314 2.4 3.0 0.8 51.3 48.7 16.9 68.1 44.4 21.1 57.1 3.39 3114 3399 1.09 1,660 6 178 47.6 113.8 286 322 2.5 2.8 0.9 50.2 49.8 18.2 68.0 50.4 21.8 61.3 3.44 3413 3598 1.06 minute volume of air respired during a slow run, whichwas about 42.5 liters. Since for this condi tion inhalation represents one-half the cycle, the actual average inspiratory fiowJJ'tfSSld be twice this value or 85 l/min. Use of this value or of any average inspiratory flow rate as a maximum air flow through a filter or sorbent cartridge during inhalation, assumes a rectangular wave shape for flow rates versus time. Actual measurements made at the Harvard School of Public Health, which are described by Silverman et al.,4 show that the shape of the curve Is far from rectangular although it does approach an approximate rectan gular shape if a large respiratory resistance is present. Typical curves are presented later to in dicate the relation between minute volume and maximum flow conditions. C. Instantaneous Air Flow Instantaneous air flows are important in the design of respiratory protective equipment be cause they determine the velocity of air through the filter or sorbent material which occurs at the peak flow rate. It is on the basis of this streaming velocity that the effectiveness of the filter or sorbent must be assessed. Consequently, evalua tions or testing done at average flow rates will not necessarily correspond to the peak values en countered in use. Pulsation is also important and steady flow tests such as those specified by the Bureau of Mines Approval Schedules, at the present time, do not allow any relaxation period for sorbents. The Army Chemical Corps, prior to World War n, used constant flow tests. During World War II, on the basis of data developed at Harvard University, at the Chemical Warfare Service Development Laboratory at Massachusetts Institute of Tech nology, and at an Office of Scientific Research and Development project at Northwestern University, it was determined that for testing purposes a breather pump which simulated respiration was essential. It is of interest to point out here that the Chemical Corps breather pump values now used E-06474 12 RESPIRATORY PROTECTIVE DEVICES MANUAL represent a minute volume of 50 liters with a peak flow rate of 150 1/min. The mean inspiratory flow at steady state would be 100 1/min, but the peak flow is based on the respiratory curve shape, which in the case of the bell-crank type of Chemi cal Warfare Service pump is a sine wave. A flow of 150 1/min represents a ratio of 3 to 1 for peak flow to minute volume, or 1.5 to 1 for peak flow to average mean inspiratory flow. D. Expiratory Air Flow Instantaneous air flows during exhalation are not of much concern except for exhalation valve design. It has been determined that the effect of high inhalation resistances is to increase exhala tion flows because the subject tends to inhale over a longer period of time to ease the work of breath ing and thus exhales more rapidly. This indicates that the effect of inspiratory resistance is to in crease the peak velocity during exhalation. This is especially true should the value of inspiratory re sistance reach objectionable levels. Instantaneous inspiratory air flows under sedentary conditions attain values as high as 40 1/min, depending upon the minute volume and re sistance to breathing. At maximum effort, how ever, peak flows over 300 1/min have been ob tained in individual subjects with a mean value without resistance of 286 1/min for a group of three subjects. When air flow resistances cor respond to a respirator inhalation equivalent of 64 millimeters (mm) of water at 85 1/min, an ex halation resistance of 41 mm of water for peak values slightly less than 300 1/min is achieved. E. Tidal Volume A value of some importance in physiological response to resistance is the tidal volume. This is the volume of air per breath. It can readily be determined from minute volume and respiration rate. Minute volumes have already been indicated in Table 2.1, and respiration rates range from a mean of 15 respirations per minute under seden tary conditions to a value of 48 respirations per minute for maximum effort. Tidal volumes which correspond to these are obtained by dividing the minute volume by the respiration rate. F. Mean Inspiratory and Expiratory Air Mows Mean inspiratory and expiratory flows have already been mentioned. These are obtained by taking the shape of the breathing pattern on a cycle ratio basis, determining the percentage of the total cycle represented by inhalation or exhalation, and dividing the minute volume by this value. These values are useful only for determining an inte grated value of the respiratory curve shape. G. Effects of Resistance versus Air Flow The effect of adding external resistance to air flow to an individual's respiratory tract is to pro duce a compensatory adaptation response. In or der to reduce the effect of resistance, the sub ject's response is to reduce his peak flows. This is clearly shown by comparing the data of Table 2.2 with Table 2.1. The data of Table 2.1 were ob tained with minimal resistance to inhalation and exhalation. These values correspond to 6 and 3 mm of water at 85 1/min air flow. It should be noted that these low values are less than the dif ference between nose and mouth breathing as far as pulmonary effort is concerned. Data given in Table 2.2 correspond to measurements at 64 and 41 mm (at 85 1/min), respectively, comparable to typical Army or universal mask values. These values also correspond to Bureau of Mines limits (89 and 38 mm) for this type of mask although the exhalation resistance is somewhat high for ex halation valves now widely in use. The comparison of the data in these two tables shows that essentially the effect of resistance is to reduce minute volume, maximum inspiratory and expiratory flow, and respiration rate. The air flow curve shape becomes more rectangular and the subject makes his breathing more effective by increasing the oxygen deficit. That is, a greater percentage of oxygen is removed per breath than when the resistance is at minimal values. From the negligible changes in pulse rate, it can be seen that the amounts of resistance imposed are not of serious concern as to well-being of the individual. An over-all comparison of the effects of sev eral changes in resistance on all of the respiratory air flow values can be obtained from the data of several experiments performed at Harvard by Silverman and his co-workers.These data are shown in Figs. 2.1 and 2.2 for a number of experi mental series. Resistances ranged from the mini mal values of 6 and 3 mm expressed above to 106 mm of water on inhalation and 76 mm on exhala tion. Even these greater-limits had no serious ef fect on the capability of the wearer to perform hard work. A subjective resistance comparison was made to determine values which would not be considered objectionable. For this purpose, a simple arbi trary scale was adopted in which subjective re sponse to air flow resistance to inhalation and ex halation was placed in four discrete categories which called for some judgement on the part of the subject. By limiting the number to a small group, less arbitrary decisions could be made. These categories are as follows: 1. Not perceptible 2. Noticeable 3. Uncomfortable 4. Objectionable E-06475 PHYSIOLOGICAL FACTORS IN RESPIRATORY PROTECTION TABLE 2.2 MEAN AIR FLOW MEASUREMENTS AND GAS ANALYSES WITH EXTERNAL RESISTANCE3 13 Measurement Sedentary 0 208 Subjects Pulse rate per minute Respiration rate per minute Minute volume, liters Maximum inspiratory flow, 1/min Maximum expiratory flow, 1/min (Maximum inspiratory flow)/(minute volume) (Maximum expiratory flow)/(mlnute volume) (Maximum inspiratory flow)/ (maximum expiratory flow) (Inspiratory cycle)/(total cycle), % (Expiratory cycle)/(total cycle), % (Rise)/(inspiratory cycle), % (Sustained flow)/(inspiratory cycle), % (Maximum flow occurrence)/ (expiratory cycle), % (Rise)/(expiratory cycle), % (Sustained flow)/(expiratory cycle), % Inspiratory work rate. Kg Expiratory work rate, Kg Total respiratory work rate, Kg Oxygen deficit, % Oxygen consumption, ml/min Carbon dioxide production, ml/min Respiratory quotient 13 75c 14.8 9.1c 37 29 3.9 3.1 1.3 38.2 57.5 19.1 62.6 27.5 14.1 42.3 0.4 0.1 0.2 3.79 304 259 0.85 12 12 91 103 17.5 18.7 13.2 19.8 44 60 37 56 3.4 3.1 2.8 2.8 1.2 1.1 43.1 46.4 56.1 53.3 17.7 15.1 60.1 62.2 37.6 44.7 18.4 20.3 49.2 0.6 0.3 0.4 4.15 489 416 0.85 54.9 1.3 0.7 0.9 4.60 812 709 0.87 a. Resistances were 64 mm inspiratory and 41 mm expiratory. b. Resistances were 64 mm inspiratory and 27 mm expiratory. c. One less subject is included in mean. 415b 14 118 22.0 28.2 79 85c 2.8 3.0C 0.9C 48.7 50.9 13.3 66.5 39.9 15.7 57.2 2.5 1.1 1.8 4.75 1190 1052 0.89 Work Rate, Kg-M/min 415 622 830 1,107 12 12 115 131 20.7 22.5 27.0 36.2 78 101 77 105 48 22 155 169 27.4 32.5 48.9 64.4 128 160 144 195 2.9 2.8 2.9 2.9 2.6 2.5 2.9 3.0 1.0 1.0 0.9 0.9 47.9 49.0 51.2 51.9 52.0 50.9 14v5 12.6 48.6 47.8 11.6 11.5 65.2 66.6 71.7 73.0 45.0 45.8 19.1 20.3 45.1 46.9 17.7 19.4 57.8 2.3 1.3 1.8 4.85 1159 1039 0.90 60.1 4.1 2.5 3.3 4.98 1606 1482 0.92 61.4 7.2 5.2 6.1 4.70 2052 1976 0.96 62.1 12.7 9.5 11.1 4.54 2591 2621 1.01 1,384 6 176 34.2 81.3 192 252 2.4 3.1 0.8 53.9 46.2 10.2 74.3 43.6 18.7 65.8 19.3 16.5 18.0 4.14 3033 3231 1.07 1,660 3 184 42.0 90.3 240 274 2.7 3.0 0.9 51.4 47.1 11.8 71.9 45.6 19.5 62.8 27.8 19.2 23.3 3.98 3245 3450 1.07 A fifth category, intolerable, which repre sents the situation where the subject will not wear the mask, could be included. This scale is simple and covers a wide enough range of reactions for the subject to interpret. One other condition necessary in using such a scale is to be sure the subject is concentrating on some task or work effort; otherwise his response will be oriented to the fact that his attention was fo cused on his respiratory efforts. In the Harvard .study mentioned above, the resistances were changed without the subject's knowledge. The effect of increased inhalation resistance is to reduce peak inspiratory flows and to cause increased peak expiration flows. This effect takes place because the subject usually extends the period of inhalation and then must expel the same air volume over a shorter exhalation period. This . can be seen in Fig. 2.1, when one examines the curve corresponding to expiratory flow. For mini mal exhalation resistance, the peak flows are greatest. This points out the fact that it is de sirable that there should be a balance between the two resistances; otherwise a conscious effort be comes apparent on the part of the wearer. In practice, exhalation resistance has been half or less than half of inspiratory resistance, although changes of 25 per cent from this ratio are not significant from a comfort consideration. H. Effect of Work Rate on Physiological Re sponse in Respirators It has been mentioned in the preceding sec-tion that the effect of concentrating on the task minimizes subjective complaints, unless exces sive resistances are added to the airway path. Under these circumstances it is essential that the actual resistance to breathing should not interfere with normal oxygen transport to the lungs and E-Q6476 14 RESPIRATORY PROTECTIVE DEVICES MANUAL 2200 2100 2000 1900 1800 Z S RESISTANCE 6-3 64-3 6-41 64-41 6-3 i 82-3 SERIES I *** 106-3 82-41 6*3 6*76 44-76 6*53 64-53 82-53 6-3 106-41 SERIES n Fig. 2.1. Effect of various amounts of resistance on several mean values of physiological and subjective measurements for 12 subjects performing series I and n. Series I and II were a sequence of resistance changes produced by simulated canisters in which values conformed to existing respiratory protective devices. Work rate was 830 Kg-M/min. circulatory system. The data in Tables 2.1 and 2.2 and Fig. 2.1 confirm this fact. The work rates which have been studied using a bicycle ergometer and in some instances a treadmill, correspond to sedentary no load, 1,500, 3,000, 4,500, 6,000, and 8,000 foot-pounds per minute (ft-lb/min) or, in the metric system, 208, 415, 622, 830, and 1,107 kilo gram-meters per minute (Kg-M/min). The 4,500 ft-lb/min value represents medium work which can be continued for long periods (hours) by aver age individuals. The 6,000 and 8,000 ft-lb/min load cannot be sustained except for short periods of about fifteen minutes. A period of training is required to achieve the upper value for this time period. The condition of working while wearing a respirator, that involves breathing through some respiratory impediment does not present the wearer with a serious problem unless a great pul monary effort must be made to obtain enough air exchange to satisfy his oxygen demand for a given task or work rate. In some cases it has been found that if the resistance is intolerable, the subject will be forced to terminate or suspend his work effort. The intolerable situation can also be re lated to the subject's physical condition and de gree of training. Well-trained individuals or athletes with well-developed respiratory muscu lature and -physiological tone have presented far less difficulty in this regard. Athletes when com pared to non-athletes show a lower respiration rate, minute volume, and peak flow rates for the same amount of external work. This is shown clearly in Table 2.3 for these values and others. Studies at Harvard and in England by Cooper have confirmed the fact that there must be some relation between the output work rate or the task performed and the effort resulting from respira tory resistance that can be tolerated by the respiratory musculature and diaphragm. This re lation is discussed in the following section. The external effort of breathing through a resistance must be distinguished from the internal work of the lungs in breathing through the existing respi ratory system (normal airway resistance). L Respiratory Work Rate and Its Significance The respiratory work .rate is defined as the actual work done by the lungs in drawing air through the resistances of the valves, filter, and canister. It can be divided into inspiratory and expiratory values, but the total effort must be the sum of the two components. The values are ob tained by multiplying the mean inspiratory or ex piratory air flow by the total air flow resistance of the respirator or exhalation valve correspond ing to that flow. The time of inspiration or expira tion as a percentage of the total cycle must be considered in making respiratory work calcula tions. These values can be related to the output of work achieved by the subject. Based on a large number of subjects and a wide range of respiratory resistances which were -06477 PHYSIOLOGICAL FACTORS IN RESPIRATORY PROTECTION 3ivy gsnnd UIU'/IW ujui/ur&t| *xao/v\ Aaoivuidsaa o m -- t----- i----- 1----- 1------1 `NOIldWnSNOO N3DAX0 15 4 o z < 8S SS Sis o 4 8* u. < 8 UI 4 5 5" cr. cu</c>j o 5" < w w> m o < * W *> o 4 <0 *> 04 Sg 4 4 0z 2o inEo tu<ori zQo O rt bD bD CQ O' s H 01 E-06478 16 RESPIRATORY PROTECTIVE DEVICES MANUAL TABLE 2.3 COMPARISON OF MEAN AIR FLOW MEASUREMENTS, GAS ANALYSES, AND STANDARD DEVIATIONS FOR ATHLETES AND NONATHLETES3 Measurement Nonathletes Athletes Mean (First S.D. Mean (First (Second Mean S.D. Group) Group) Group) Age range, yr 17-22 17-22 Subjects 20 -- 14 Pulse rate per minute 164 14 167 Respiration rate per minute 32.6 6.7 36.0 Minute, volume, liters 67.7 11.2 74.2 Maximum inspiratory flow, 1/min 180 30 196 Maximum expiratory flow, 1/min 187 32 217 (Maximum inspiratory flow)/(minute vol ume) 2.7 0.2 2.7 (Maximum expiratory flow)/(minute vol ume) 2.8 0.3 3.0 (Maximum inspiratory flow)/(maximum expiratory flow) 1.0 0.1 0.9 (Inspiratory cycle)/ (total cycle), % 49.1 ,, 48.7 (Expiratory cycle)/ (total cycle), % 50.9 51.3 (Rise)/(inspiratory cycle), % 14.1 14.9 (Sustained flow)/(in spiratory cycle), % 69.7 .. 69.1 (Maximum flow oc currence)/(expir atory cycle), % 44.7 42.7 (Ris e)/(expiratory cycle), % 19.6 18.4 (Sustained flow)/ex piratory cycle), % 61.2 .. 56.0 Oxygen deficit, % 4.59 0.58 4.00 Oxygen consumption, ml/min 2766 252 2646 Carbon dioxide pro duction, ml/min 2662 339 2632 Respiratory quotient 0.97 0.04 1.00 -- -- 9 7.6 11.1 29 33 0.2 0.5 0.2 __ 0.51 223 243 0.04 17-37 26 169 36.5 81.1 205 229 2.6 2.9 0.9 49.6 50.4 14.4 69.9 43.4 18.5 58.4 3.76 2690 27711.03 a. Work rate was 1,107 Kg-M/min and resistance was mini mal. reported by Silverman and Billings and a limited series reported by Cooper, it has been found that respiratory work rates form only a small per centage of the total output work rate. This is true even when high resistances (over 100 mm) are en countered and there are a number of subjective complaints. The greatest percentage of complaints is evoked when total respiratory work rate ex ceeds 5 Kg-M/min. On a basis of inspiratory and expiratory work rates, the corresponding values . are 5 and 2.5 Kg-M/min, respectively. Based on the concept of a maximum allowable resistance to breathing, a large number of ex perimental results indicates that a limit of ex ternal work by the lungs of 0.6 per cent of the total output work rate seems to be a reasonable value. Recent work and analysis of the problem by Cooper indicate that the earlier value of 0.6 per cent is essentially correct, but he recommends a somewhat higher value of 0.74 per cent, based on the assumption that the shape of the respiratory air flow curve is a sine wave. The rationalization for converting 0.6 to 0.74 per cent is insignificant from a practical viewpoint !For greater tolerance and longer work peri ods with less discomfort, Cooper, on re-evaluating the results at Harvard with his own data, recom mends the use of 25 Kg-M/min respiratory work rate at 100 1/min for an apparatus rating value. He believes less than one half of this value should be used in practice in order to avoid subjective complaints. If his value of 25 Kg-M/min is con verted to resistance at 100 1/min, it corresponds to a rather high maximum total for inspiratory and expiratory resistances of 250 mm of water. In practice, therefore, he says to use one half of this value of 125 mm. For comparison.^ present U.S. Bureau of Mines values for filter respirators^ specifyjnaximum values of 50 mm inspiratory and 2g~mm expiratory or a..total .ofLjjiim.m.at _g5 1/min. Assuming linearity for resistance values, a nu merical total of 88 mm at 100 1/min is obtained. The Bureau's permissible values for gas masks are 89 and 38 mm, which total 127 mm at 85 1/min or 149 mm at 100 1/min. Since the Bureau of Mines values represent somewhat arbitrary stand ards which can be achieved by commercial de signs, it is important to recognize that they, are well_below maximum physiological limits_(dounot interfere with normal metabolic processes) and. would not induce any respiratory stress in the wearer. They should not be interpreted as comfort limits. Using the maximum of D.6 per cent respira tory work value obtained at Harvard from data analyses, the corresponding total resistance can be evaluated. For example, if an acceptable work rate for long periods is 4,500 ft-lb/min (622 KgM/min), then the respiratory work rate should not exceed 27 ft-lb/min or 3.7 Kg-M/min. In Table 2.2 it can be seen that a value of 3.3 Kg-M/min was actually obtained as a mean value for several subjects. Respiratory work can be calculated from the product of resistance and flow. If the presently accepted Bureau of Mines test flow rate of 85 1/min is used for resistance, then the calculated maxi mum total respiratory work should be based on a minute volume value of 42.5 1/min. E--06479 PHYSIOLOGICAL FACTORS IN RESPIRATORY PROTECTION 17 For filter respirators and gas masks, the Bureau of Mines allowable resistances correspond to the values calculated by the following formula for respiratory work rate: Respiratory work rate = (specific gravity of water) x (flow rate) x (resistance) Or, in terms of units, Kg-M/min = (Kg/M3)(M3/min)(M) Substitution of the Bureau of Mines equivalent val ues in the formula gives the following respiratory work rates: For filter masks Rate . (1.0 x 1,000)(^)(jJ88 42.5 ' 000 X 100 i = 1.6 Kg-M/min resistance--either inhalation or exhalation--can best be tolerated on a balanced basis; that is, if exhalation resistance is approximately one half of inspiration resistance, the subject will tolerate the total resistance more readily. Cooper summarizes his resistance and flow recommendations as follows: "1) Breathing apparatus should be tested in full working trim by ventilation by sine-wave flow at minute volumes of 20, 50, and 100 1/min (tidal volume of 1, 2, and 31 and frequencies of 20,25, and 33.3 cycles per minute, respectively). " 2) The rate of respiratory work done on the apparatus expressed in Kg-M/min should be not greater than one-fourth of the minute volume (1/min). "3) The rate of work should preferably be not greater than one-half of this standard. "4) The fraction of the work done in expiration should preferably be not more than 50 per cent at high minute volumes, but the lower the total rate of work the less important this becomes." _ For gas masks (14,00050\/ / 149 (1,000 42.5' 000 ~ 100 - = 2.7 Kg-M/min By dividing these values by 0.6 per cent, it is possible to calculate a desirable maximum work effort corresponding to Bureau of Mines Schedules. Thus for_filter masks a peak value should be 266 Kg-M/min or 1,920 ft-lb/min. and for gas masks a peak value should be 450 Kg-M/min or 3.260 ft^lb/min. Neitner of these work values can be considered as strenuous effort and both can be maintained for several hours without fatigue. Although these values represent tolerable re sistances which do not induce physiological stress, it should be recognized that the lowest total re sistance that can b.e achieved in practical and safe designs should be sought. It is apparent from con siderations of newer materials and designs that values equal to approximately one half of those presently recommended may be possible. A recent tentative specification of the U.S. Atomic Energy Commission (AEC) considers values as low as 32 mm inspiratory and 19 mm expiratory (at 85 1/min) as achievable (see Appendix C). From a practical standpoint, the factors of importance in respiratory resistance are based largely on comfort rather than physiological stress. Obviously, the effect of resistance is to increase the respiratory work rate and cause some physiological demand on the subject during work. It has been determined from a number of studies at Harvard that the maximum amount of III. TABULAR DATA Representative values of air flow and of respiratory gas measurements for subjects under various work and respirator conditions are shown in Tables 2.1 and 2.2. These data can be used for respirator design and for evaluation of needs of the subject at various work rates. The values pre sented are useful for estimating flows that may be encountered in practice and for determining allow able resistances. Also, they can be related to permissible concentrations for exposure in esti mating dose values. IV. REFERENCE SOURCES For a complete bibliography on physiological effects of breathing with respiratory devices, the assembled material listed in Refs. 9 and 10 should be consulted. Cooper's article will also be useful as his bibliography has some recent English ref erences. Two additional articles by Cooper*^*3 will be of interest to the scientific investigator. The bibliography of Ref. 5 will also be of interest. REFERENCES 1. Haldane, J. S.: Respiration, Yale University Press, New Haven, Conn., 1922. 2. Wright, S.: Applied Physiology, 6th Ed. or later, Oxford Press, New York, 1937. 3. Winton, F. R. and Bayliss, L. E.: Human Physiology, 2nd Ed., P. Blakiston's Son and Co., Inc., Philadelphia, Pa., 1937. 4. Silverman, L., Plotkin, T., Sawyers, L. A., and Yancey, A.: Air Plow Measurements on E--06480 18 RESPIRATORY PROTECTIVE DEVICES MANUAL Human Subjects With and Without Respiratory Resistance at Several Work Rates, Arch. Ind. Hyg. Occupational Med. 3:461, May 1951. 5. Silverman, L. and Billings, C. E.: Pattern of Air Flow in the Respiratory Tract, Inhaled Particles and Vapours, pp. 9-45, Pergamon Press, Oxford, 1961. 6. Cooper, E. A.: Suggested Methods of Testing and Standards of Resistance for Respiratory Protective Devices, J. App. Physiol. 15:1053, 1960. 7. Bureau of Mines: Respiratory Protective Ap paratus, Tests for Permissibility, Fees, Part 14, Filter-Type, Dust, Fume, and Mist Respirators, Schedule 21A, 7 pp., Apr. 19, 1955. (Code of Federal Regulations reference, 30 CFR, Part 14). 8. Bureau of Mines: Respiratory Protective Ap paratus, Tests for Permissibility, Fees, Part 13, Gas Masks, Schedule 14F, 9 pp., Apr. 23, 1955. (Code of Federal Regulations reference, 30 CFR, Part 13). 9. Silverman, L.: A Bibliography on Protective Respiratory Devices and the Physiology of Respiration Through Gas Masks, Am. Ind. Hyg. Assoc. Quart. 7:3, Sept. 1946. 10. Hyatt, E. C.: Current Problems in the Field of Respiratory Protection, Am. Ind. Hyg. As soc. J. 19:121, Apr. 1958. 11. Cooper, E. A.: Device for the Estimation of the Rate of Work on Passing Air by Sine Wave Flow, J. Sci. Instr. 36:436, 1959. 12. Cooper, E. A.: A Comparison of the Respira tory Work Done Against an External Re sistance by Man and by a Sine-wave Pump, Quart. J. Exp. Physiol. XLV: 179, 1960. E--06481 Chapter 3 FACEPIECES I. INTRODUCTION The configuration and mechanical appurte nances for facepieces of respiratory protective devices and their relation to wearer acceptability and device reliability are considered in this chapter. The point at which respiratory protection is most likely to fail is the seal between the facepiece and the wearer's face. The establishment and maintenance of the seal, with tolerable com fort, depends largely on the proper fit of the facepiece to the face, and, together with efficient func tioning of the device's component parts, controls the adequacy of the wearer's protection against irrespirable atmospheres. IL RELATION OF RESPIRATOR DIMENSIONS TO FACIAL FIT Three common types of facepiece are: 1. Half mask fitting under chin (Type A), which encloses the wearer's nose, mouth, and chin (see Fig. 3.1). 2. Half mask fitting on chin (Type B), which encloses the wearer's nose and mouth but rests on the chin (see Fig. 3.1). 3. Full face mask, which completely encloses the wearer's face, including eyes, nose, mouth, and chin. Anthropologists*" have established- certain measurements for accumulating and classifying data on human faces, and Fig. 3.2 indicates some INLET VALVE AND FILTER HERE TYPE B FITTING ON CHIN TYPE A FITTING UNDER CHIN Fig. 3.1. Types of half mask facepieces. 19 E--06482 20 RESPIRATORY PROTECTIVE DEVICES MANUAL I. NAS I ON-MENTON (FACE LENGTH) 2. LENGTH OF NASAL BONE 3. PRONASALE- SUBNASALE (NOSE PROTRUSION) (CHIN LENGTH ) 5. BIZYGOMATIC DIAMETER ( FACE WIDTH) 6. BICHELION DIAMETER (MOUTH WIDTH) Fig. 3.2. Facial measurements of importance in fitting facepieces. of the measurements of importance for fitting respiratory protective devices. Although other facial characteristics must be considered in designing and fitting a facepiece, by far the most important single measurement is the face length. Faces have been classified according to the general appearance of the full face as round, square, or triangular and then subclassified with in this system, e.g., variations of the round in clude vertical oval and horizontal oval. Attempts^ have also been made to identify faces according to profile as concave, convex, or straight. However, to date no study has been reported in which either of these classification systems was used in the fitting or design of respirator facepieces. Facepieces manufactured in the United States reported ly are triangular, round, or long and narrow. However, the configurations of the masks are not intended for any particular face type, but repre bent instead the manufacturer's concept of the facepiece which will best fit the largest number of people. Whatever the configuration of the facepiece, the wearer's face length must be within its range to obtain a proper fit. Due to variations in other measurements, some individuals may be fitted with one facepiece and not with another with the same face length range. It is often desirable, therefore, to have respirators from different manufacturers available for issue. However, even if a respirator is available in various sizes, or is exceptionally versatile, a few people still will be unable to obtain a leakproof fit. For example, the Army expects the three sizes of its assault mask to fit only about 98 per cent of its personnel. It is difficult to fit women who must wear per sonal respiratory protective equipment because no commercially available full face masks, and few half masks, are sized to fit them. Although the Bureau of Mines' approval does not specifically exclude women, they are not required to be fitted in the Bureau's evaluation of a respirator. A. Half Masks Fitting under Chin (Type A) During World War II the Aero Medical Lab oratory1* of the Army Air Force collected the fa cial measurements of 1,454 flying personnel (men and women), subsequently measured an additional 1,500 as a check on the original findings, and then E--06483 FACEPIECES 21 based the design of the oxygen mask for flying personnel on these data. Even though the person nel surveyed were a selected population, having passed rigid physical requirements, the param eters used for the Army Air Force oxygen mask are applicable to the industrial Type A half mask. The Army Air Force showed that the face length measurement (the nasion-menton dimension, No. 1, Fig. 3.2) is primary to the development of the half mask. The reported variations in this measure are: Negro male White male White female 112 to 152 millimeters (mm) 101 to 146 mm 96 to 136 mm Assuming that these findings apply to the adult population, an extreme difference of at least 56 mm may be expected (i.e., the longest face length minus the shortest face length, disregarding sex and race). The nose cup of the half mask must seal on the nasal bone because the slightest pressure on the nose below this bone compresses the nares and interferes with inhalation. For any individual, therefore, the tolerable variation in the length of a half mask fitting under the chin is determined by the length of the nasal bone (dimension No. 2, Fig. 3.2; according to the Army Air Force study, about 12 mm for most adults). Since the 12 mm varia tion should not be exceeded, it follows that con secutive sizes of half masks with chin cups should fit faces that differ in length by not more than 12 mm. Ideally, therefore, a minimum of five sizes would be required for an optimum fit of the adult population. The width of the mouth (dimension No. 6, Fig. 3.2) also is important in the sizing of half mask facepieces. This measurement not only establishes the necessary width for the facepiece, but also, to some degree, fixes the flexibility of any given size of half mask because, with a fixed perimeter, the length of a facepiece cannot be increased without decreasing the width. The extremes of this measurement for the adult industrial population have not been reported; however, on the seven head forms developed from the Army Air Force data on white males, the range is from 44 to 61 mm. A crude extrapolation, assuming a compara ble variation in the mouth width and face length, indicates that the expected range for the total adult population would be from 40 to 66 mm. A mask pressing the inner surface of the mouth against the teeth rapidly becomes very un comfortable; to avoid this distress the sealing edge of a half mask must clear the mouth by at least one-half inch (12.5 mm) on both sides. If the mouth width of the adult population ranges ap proximately from 40 to 66 mm, as extrapolated above, adding 25 mm to the total mouth width would indicate a desirable range in the minimum width of a half mask of from 65 to 91 mm. Al though the criterion for the maximum width of a half mask for any one individual is not established, the maximum width obviously could exceed the minimum width by 10 mm, i.e., ignoring other measurements, a half mask with a width of 75 mm would fit individuals with a mouth width in the range of 40 to 50 mm. Five selected half mask sizes, therefore, could accommodate the adult population's range of face length and mouth width with a reasonable overlap of sizes. Table 3.1 shows the range of facial measure ments corresponding to these five selected facepiece sizes and the percentage of the population in each of the five size ranges. This grouping as sumes a direct relationship between face length and mouth width, which may not be correct in all cases. The selected sizes are plotted in Fig. 3.3. The shaded rectangles indicate the range of face TABLE 3.1 SELECTED SIZES OF TYPE A HALF MASKS Facepiece 1 2 3 4 5 Observed Population in Size Range, % 1 21 69 27 1 Length of Facepiece, mm 102 113 124 135 146 Width of Facepiece, mm 75 80 85 90 95 Face Length of Individuals Fitted, mm 96-108 107-119 118-130 129-141 140-152 Mouth Width of Individuals Fitted, mm 40-50 45-55 50-60 55-65 60-70 E--06484 22 RESPIRATORY PROTECTIVE DEVICES MANUAL 160 150 140 S U. o 130 2 LU <fi 120 X H* O 2 UJ 1r AFL Air Force Mask Large Size AFM Air Force Mask Medium Size AFS Air Force Mask Small Size IN Manufacturer No, ,1 Normal "1L Manufacturer No, 1 Lengthen IS Manufacturer No. 1 Shorten 2N Manufacturer No .2 Normal 2L Manufacturer No, 2 Lengthen 2S Manufacturer No, 2 Shorten _3N Manufacturer No, 3 Normal 3L Manufacturer No, 3 Lengthen 3S Manufacturer No, 3 Shorten Selected Sizes 3L IL 2L S no S too 40 50 60 70 80 WIDTH OF MASK, MM -i---------------------- - ... * i___ 15 25 35 45 55 65 75 MOUTH WIDTH, MM 85 Fig. 3.3. Length and width of Type A half masks, actual size and five selected sizes. lengths and mouth widths, with the 12.5 mm clear ance on each side, which each size of facepiece should fit. Also plotted on Fig. 3.3 are the meas urements of three commercial respirators and the sizes of the Army Air Force oxygen mask. It is obvious that for practical reasons the Army Air Force decided not to manufacture and stock the extremely large or extremely small size mask required to fit the one per cent at the extremes of the surveyed population. It must be borne in mind that the Army Air Force could and would eliminate from flight duty individuals who could not be ac commodated by standard equipment. Three configurations--normal, maximum elongation, and maximum shortening--are plotted for each commercial respirator in Fig. 3.3. Since elongation of the facepiece decreases the width and shortening increases the width, this flexibility of the half mask obviously is contrary to actual needs in fitting an adult population. Ideally, the length and width should be in creased or decreased independently. Figure 3.3 implies that it would be impossible for a single size of half mask to fit a high percentage of the adult population. This is supported by data in Table 3.2, summarizing tests at the Los Alamos Scientific Laboratory? on 500 adult males, using three different commercially available half masks fitting under the chin. The following points should be noted in E--06485 f FACEPIECES 23 TABLE 3.2 SUMMARY OF RESPIRATOR FIT TESTS FOR 500 MENa Respirator Men Fitted,b % Respirator A First attempt Second attempt Respirator B First attempt Second attempt Respirator C First attempt Second attempt 47 60 60 80 42 50 a. Test medium was 100 ppm isoamyl acetate. b. Five per cent of the men were not fitted by any of the respirators tested. interpreting the figures in Table 3.2: 1. Each of the three respirators was equipped with two separate straps. 2. The first test for leakage was made after the individual had been instructed thoroughly in donning the respirator. Each facepiece was checked for fit before exposure by sealing the ex halation valve and pressurizing the mask. 3. The second leakage test disregarded com fort. Nasal respiration was severely restricted sometimes, or the straps were unduly tight. 4. The men did not exercise vigorously during the tests. 5. The test exposures were short. 6. Women were not included in the tests. Ninety-five per cent of the subjects could be fitted with at least one of the three respirators, indicating that, for any situation in which a number of respirators are in use, devices from different manufacturers should be available, even though this complicates purchasing, stocking, and issuing procedures. B. Half Masks Fitting on Chin (Type B) A chin cup molded into the facepiece of a half or full face mask is a major factor in stabilizing the respirator on the face and is demonstrably im portant in maintaining the seal if the wearer is talking. Originally Type B half masks were de signed to achieve light weight and compactness primarily for dust respirators. Many industrial users prefer half masks without chin cups, per haps believing that the half mask without chin cup is more comfortable and fits a higher percentage of workers. When the Type B half mask is worn, the bot tom edge of the facepiece bears on the chin and the vertical dimension of the chin permits a variation in the placement of the facepiece on the face. Al though the range of this vertical dimension for the adult population is not established, extrapolation from the Army Air Force data indicates that the extremes of the mandible height (dimension No. 4, Fig. 3.2) would be from 22 to 36 mm. The exact portion of this length suitable as a contact surface for a half mask is not known, but 10 to 12 mm ap pears to be a reasonable estimate. This allowable variation, together with the variation of 12 mm for the nasal bone, indicates a reasonable difference in the length of two con secutive sizes of Type B half masks of about 25 mm. Therefore, since the difference in the ex tremes of face lengths for adults is about 56 mm, the entire range of face lengths could be ac commodated with only two sizes, although ideally three different sizes would be indicated; Because of the way in which this type of facepiece contacts the face, the face length (dimension No. 1, Fig. 3.2) minus 10 mm could be a measure of the de sired mask length. Then the required total range of facepiece lengths would be from 96 minus 10 mm to 152 minus 10 mm, i.e., from 86 to 142 mm. The range of minimum facepiece widths dis cussed in the preceding section also applies to the half mask without chin cup. The range of maxi mum facepiece widths might well be increased be cause the permissible maximum width is deter mined, within reason, by the design of the facepiece, rather than by the range in face sizes. The three ideal sizes of Type B half masks and the face measurements of the adults who could be fitted by each size are given in Table 3.3. Figure 3.4 shows the dimensions of the three selected sizes of Type B half masks. The shaded rectangles indicate the variation in face lengths and mouth widths that the different selected sizes could be expected to fit. Also plotted on Fig. 3.4 are the dimensions of a number of Type B com mercial half masks. It should be emphasized again that the maximum width of a facepiece is pri marily a function of design. Facepieces wider than the theoretical sizes could be entirely suitable, whereas the effectiveness of facepieces narrower than the indicated size would be questionable in deed. C. Full Face Masks In sizing full face masks, the length of the face (nasion-menton measurement) and the width of the face (bizygomatic diameter, No. 5, Fig. 3.2) are the important measurements, with the face E--06486 24 RESPIRATORY PROTECTIVE DEVICES MANUAL TABLE 3.3 SELECTED SIZES OF TYPE B HALF MASKS Facepiece 1 2 3 Observed Population in Size Range, % 22 92 28 Length of Facepiece, mm 97 114 131 Width of Facepiece, mm 80 90 100 Face Length of Individuals Fitted, mm 96-118 113-135 130-152 Mouth Width of Individuals Fitted, mm 40-55 50-65 60-75 160 150 140 - 140 130 - s 2s s 130 * 120 W I- < 02 1o UJ120 X no 22 UJ IN Manufacturer No.l Normal JL Manufacturer No.l Lengthen 2N Manufacturer No. 2 Normal 2L Manufacturer No. 2 Lengthen SN Manufacturer No. 3 Normal 3L Manufacturer No. 3 Lengthen L4N Manufacturer No. 4 Lg. Size Normal M4N Manufacturer No. 4 Med. Size Normal S4N Manufacturer No. 4 Small Size Normal Manufacturer No. 5 Normal Manufacturer No. 6 Normal Selected Sizes no ioo 100 90 80 15 60 70 80 WIDTH OF MASK, MM 25 35 45 55 65 75 MOUTH WIDTH, MM Fig. 3.4. Length and width of Type B half masks, actual size and three selected sizes. 85 E-06487 FACEPIECES 25 length considered the more important of the two. The Army Chemical Corps,2,3 during research on gas masks for combat and civilian protection, de veloped a relationship between face sizes and sizing of full face masks. The size circles in Fig. 3.5 are from data obtained by the Forsythe Dental Infirmary for Children, Cambridge, Massachu setts, under a research contract from the Army Chemical Corps.^ About 1,200 persons, including children from age five and adults, were measured in this study. The circles were used subsequently with about 90 per cent accuracy in predicting gas mask sizes for about 2,000 persons.^ The data ob tained in this fitting trial substantiated the original data. Fig. 3.5 represent a civilian population that ap parently did not include the extremely large males. The limiting factor in sizing a reasonably comfortable full face mask has not been stated. However, judging from the sizing circles in Fig. 3.5, and the differences in the sizes of the Army M-9 mask, the difference between two consecutive sizes should be about 7 to 10 mm. In Fig. 3.6, the six sizing circles from Fig. 3.5 are reproduced without reference to the face width. A seventh circle representing the sizing circle for large adult males is approximated and is also shown in Fig. 3.6. 110. -120 ISO 140 FACE WIDTH, MM ISO 160 ir- Fig. 3.6. Comparison of mask length with Fig. 3.5. Size circles for fitting civilian sizing circles. protective masks. Sizing circles with a diameter equal to that of Each size circle has as its center an average size 6 in Fig. 3.5, for several different full face tE. face width and face length for the specific size in masks, are included also in the figure to indicate question. The radius of each circle is one stand the facial length that could be fitted with the vari ard deviation of measurement from the mean. Ob ous facepieces. The facepiece lengths were deter viously, the extreme range of face length in the mined by measuring the distance from the chin cup discussion on half masks was not used for this to a point on the facepiece that would be opposite sizing. Presumably this was because of a differ the wearer's nasion point if his eyes were in the ence in the populations surveyed, since data for ideal position relative to the eyepieces. This the half masks were obtained from flying person measurement cannot be established for some types nel in the Army Air Force, whereas the data for of full face mask because neither the area into E--06488 26 RESPIRATORY PROTECTIVE DEVICES MANUAL which the wearer's chin must fit nor the position ing of the eyes is fixed. In these cases the term "facepiece length" is meaningless; however, for those facepieces in which the face position is fixed by a molded chin cup and small viewing apertures, the facepiece length can be established with rea sonable accuracy and can be related to face length for prediction of fit. Obviously, a greater range of face length could be fitted with a given respirator if the wear er's chin and eye positions were not fixed by the features of the respirator. The U.S. Navy, with a single size of the MarkV full face mask, has fitted successfully an exceedingly high percentage of males. This mask has one large viewing aperture and no fixed chin position. In addition, the sealing periphery of the facepiece is a pneumatic tube which the Navy believes is responsible for the high percentage of fittings among the male population. The mask, however, fits only a small percentage of the Navy's female personnel. Two factors in the design of facepieces with a single large viewing port should be mentioned here, although they have no bearing on face fit. First, fogging of the large eyepiece must not be come a problem and, second, the shape of the facepiece accommodating the larger lens should not have a dead air space exceeding a volume of about 150 to 200 milliliters (ml) (see Chapter 2, Section I). in. RELATION OF MECHANICAL FEATURES TO RESPIRATOR EFFECTIVENESS Any respiratory protective device must have a number of mechanical features to maintain the separation between ambient and respirable at mospheres, yet permit proper respiration and adequate vision. Because most of these features require openings in the facepiece, they are, po tentially, points of penetration for the ambient at mosphere. The seal at these points should be ef fective for the life of the device and should with stand rough handling of the respirator without de-veloping a leak. A. Peripheries of Facepieces Figure 3.7 shows cross sections of the pe ripheries of several facepieces in current use. There is no general agreement on the superiority of any sealing edge. The U.S. Navy, after consid erable research, concludes that the pneumatic type of periphery achieves a superior seal with maxi mum comfort. The combat mask developed by the British also has a pneumatic tube periphery. The British8 believe it is important to provide such a periphery with a valve for re-inflating the tube, but the Navy has experienced little or no trouble EXTERNAL FLANGED FLAT PNEUMATIC INTERNAL ROLL T-STYLE CUSHION FLAT WITH INNER FLAP Fig. 3.7. Gas mask peripheries. with sealed tubes collapsing. The Army M-9 as sault mask has a flat peripheral surface because Army tests showed that such surfaces provide leaktight face seals. It is apparent that either ap proach can be used to achieve essentially a leakproof seal. Most commercial full face masks use a smooth, flat peripheral surface, although some of the newer facepieces have a flat surface with an inner flap as the sealing surface. All types of peripheral surfaces are used for half masks ex cept the pneumatic and the flat surface with inner flap; the internal roll and the cushioned types are the most usual. Lack of flexibility in the facepiece and pe riphery makes it difficult for the facepiece to con tact facial contours. Quite often, therefore, the tension needed to seal all points on the periphery results in excess pressure at certain spots, caus ing "pain spots." This is of major importance for, contrary to the belief of many individuals, a half mask must be adjusted firmly to the face to be ef fective--usually more tightly than the individual prefers for comfort. In the Bureau of Mines' test ing procedures half masks are fitted very tightly to most of the wearers, and the Bureau stressed that half masks must be secured firmly for proper protection of the user. E-0&469 FACEPIECES 27 B. Face Fit and Respirator Suspension Ideally, a respirator would be held against the face by an infinite number of adjustable supports, to direct tension where needed. Practically, a proper seal can be achieved with only a minimum number of supports. The Army's full face mask is supported by a head harness with six adjustable straps attached at six symmetrical points around the periphery of the facepiece. Adjustment of this number of straps is not too complicated, and the seal is tight if the facepiece is of the proper size. Five adjustable straps on a full face mask appears to be the minimum number to ensure a seal. The buckles on head harnesses should be easily adjustable by pulling on the individual straps and should retain that adjustment without slippage. Ideally, they should be attached without penetrating the facepiece, although commonly the buckle straps are fastened to the facepiece with metal rivets. The rivet head must be recessed to avoid touching the wearer's face which, of course, con siderably reduces the thickness of the material around the rivet available for clamping. Tension on the buckle strap may distort the rivet hole and, to offset this, rivet heads are made quite large and then, in turn, must be recessed still further. A compromise, in which the possibility of leakage is minimized, involves hard facial pressure from the metal rivet heads. When full face masks are worn for extended periods, pressure from the hard metal on a restricted area of the face or head creates " pain spots" and makes continued use of the respirator intolerable. The pain spots, or sensitized areas, recover slowly and may remain sensitive for several days. A respirator that is improperly sized for an individual increases the number and the severity of any consequent pain spots. Half masks generally are supported by one or two straps without a harness. The preferred two straps may be attached to the facepiece at four points or only at two points, with the four-point attachment approximating more nearly the ideal mechanism. Often the straps are attached to the canister or the filter holder. Tension on the straps so attached may fold the facepiece inward, as well as press it against the face, and in some instances the folding action may disrupt the seal at the bridge of the nose. Since half masks usually are available in only one size, the range of facial sizes and characteristics which a respirator with one strap can accommodate is severely limited. Also, the resultant of an ideal number of forces holding a half mask on the face probably would cross the ears; to avoid a strap across the ears, the strap must pass either above or below, with further adjustment generally required because a strap will remain anchored on the back of a work er's head only at certain points. It lias been pointed out by Tait^ that the use of a head harness with a half mask provides for an improved fit and increased stability. Several foreign half masks also utilize the head harness. C. Valves Both expiratory and inspiratory valves are used on respiratory protective equipment. Generally, a valve for such equipment con sists of two elements, an orifice for passage of air, which also provides a valve seat, and a moveable diaphragm (cover) for controlling the direc tion of air flow. The materials of construction can be hard rubber, soft rubber, plastic, mica, or metal, but in any case the material and construc tion specifications must be such as to ensure trouble-free operation in a pulsating flow of mois ture-saturated air. The operation of an expiratory valve for airpurifying respirators is more crucial than that of an inspiratory valve, which is merely a check valve to prevent the back flow of expired air through the air-purifying system. It is generally agreed, 10 however, that respirators should be provided with inspiratory valves, although they are not required by the Bureau of Mines for all types of respirators. An inspiratory valve should have a low re sistance to air flow and a low opening pressure, and should be well designed and protected to en sure proper operation. It is not necessary for the inspiratory valve to be extremely efficient, al though from a leakage standpoint, a poorly de signed inspiratory valve or the lack of such a valve will permit passage of moisture-laden ex pired air back through the filter or chemical cartridge. Condensation on certain types of filter media quickly causes an uncomfortable increase in the resistance to breathing; it also affects ad versely the performance and the resistance to breathing of certain chemical sorbents. In addi tion, an inefficient inspiratory valve allows re breathing of expired air, with the possible buildup of carbon dioxide in the facepiece cavity and, in the case of full face masks, can be responsible for additional fogging of eyepieces. Silverman, " in what is probably the most complete study of expiratory valves made to date, listed the following factors in the performance of the valves in order of their physiological impor tance: 1. Resistance to air flow. 2. Leakage. a. Dynamic. b. Static. 3. Opening pressure. 4. Location or orientation of valve in mask. P-06490 28 RESPIRATORY PROTECTIVE DEVICES MANUAL l 5. Protective mechanisms. moisture in expired air, which may actually im l a. Protection against damage. prove the seal of the valve. However, this mois b. Effect of atmospheric conditions, such ture is a detriment if it freezes or is responsible as Temperature and Wind. for distorting the valve diaphragm or seat The study by Silverman indicates that, for the By conserving the heat of the expired air and usual dimensional range of valve orifices and for by protecting the valve from the effects of high the physiologically possible flow rate, the air flow velocity winds, a protective shield of proper de may be under streamline, transitional, or turbu sign wUl allow the valve to operate satisfactorily lent conditions, and that the valve resistance to at lower temperatures than would otherwise be air flow will depend largely upon the conditions of possible. The protective shield or housing will flow. The location of the valve in the mask also also be instrumental in preventing leakage by pre has a considerable effect on the resistance. Ex venting distortion of the soft, light valve covers perimental data indicate that from the standpoint from wind and by providing a dead air space on the of resistance the most advantageous position for exit side of the valve. This protected volume of the valve is midway between the nose and mouth. air is swept clean and remains filled with expired It is important that the orientation of the valve al air. Any leakage past the valve during the initial lows for proper drainage. The protective shield or phase of the inspiratory process will consist of housing, generally provided for protection, leakage previously expired air and the very small amount control, and temperature control of the valve, will of ambient air that could diffuse into the dead air also be a factor in the over-all resistance. Us space between breathing cycles. ually the addition of a shield will increase the re In testing valves for leakage, it is important sistance, but in some cases it will actually de to determine the leakage under dynamic conditions, crease the total resistance. that is, under conditions that simulate actual An important point made by Silverman and breathing patterns for various work loads. A also by Smith*'2 is that the resistance of a valve leakage test under a single set of static conditions should be established for a complete range of is not indicative of the reliability of a valve. The physiologically possible flow rates. Tests con cold weather performance of the valve should also ducted at a fixed flow rate are suitable for pro be evaluated in any comprehensive study. An arbi duction control, but they are not satisfactory for a trary classification of dynamic leakage established complete evaluation of a valve. The tabulation in by Silverman** is shown in Table 3.5. Opening Table 3.4 was arbitrarily chosen by Silverman** pressures of expiratory valves were also classi for rating the resistance of expiratory valves. fied by Silverman on the arbitrary scale in Table The amount of leakage or back flow through 3.5. an expiratory valve--an important consideration-- depends upon the nature of the sealing surfaces. Surface irregularities or distortions will prevent TABLE 3.5 a proper sealing action of the valve. The actual leakage from a given source, how CLASSIFICATION OF DYNAMIC LEAKAGE ever, will not obey the laws of air flow--for an in AND OPENING PRESSURES FOR crease in negative pressure may increase the EXHALATION VALVES sealing action or may create additional sources of leakage. An important factor in valve leakage is the wetting of the valve from condensation of the Leakage per Opening Respiration,a Pressure,*1 TABLE 3.4 Classification cm* mm HjO ARBITRARY TABULATION FOR RATING RESISTANCE OF EXHALATION VALVES Low Medium <2 2 to 4 <4 4 to 10 High > 4 >10 Air Flow Rate, Resistance, mm H,Q Air Flow l/min Low Medium High Low Medium High 50 < 7 <12 >12 150 <21 <36 >36 250 <35 <60 >60 a. Test conditions were 600 ml per respiration and 50 mm water resistance at 85 l/min. b. With wet valve. A high opening pressure is undesirable for several reasons, of which comfort considerations are most apparent. A high opening pressure can _0649l FACEPIECES 29 cause a snapping or popping of the valve on each expiration that can become extremely annoying. Probably the most serious consequences of an ex cessively high opening pressure are the diffusion of moist expired air into the facepiece cavity, with resulting eyepiece fogging, and the breaking of the seal between the face and respirator periphery. It has been found by Glidden^ that an expiratory valve with high opening pressure will freeze sooner than one with a lower opening pressure. Experience has shown that the higher the opening pressure of expiratory valves, the poorer the ac ceptance of the respirator by wearers. The main protective feature provided for an expiratory valve is the protective shield or hous ing previously discussed in connection with re sistance and leakage. Physical protection of the generally fragile valve cover is provided by the shield when the respirator is in use or in storage. A reduction in possible leakage is provided by the valve shield in two ways; first, by creation of the dead air space and, second, by reducing aspira tion of the ambient atmosphere into the mask by decreasing turbulence at the valve. The shield also provides climatic protection for the valve in that it prevents distortion of the valve cover in high velocity winds and retards freezing of the valve. In addition to the main factors of an expira tory valve noted in the above discussion, Smith^ in his report listed the following characteristics of a good expiratory valve: 1. Ease of cleaning. 2. Dimensional and material stability. 3. Ease of production in large quantities. 4. Lightness in weight. 5. Minimum obtrusiveness. 6. Good voice transmission, if practicable. D.Air-purifying Elements The seal of the filter or cartridge to the facepiece usually is leakproof if the manufacturer's directions are followed, although users tend to fasten these elements carelessly, so that in prac tice loose connections are common. In some de vices the filter material itself serves as a gasket, and a tight seal without wrinkling or tearing the filter requires considerable care; leakage because of this difficulty has been reported. Research by the U.S. Navyl^ indicates that a leakproof connec tion between the facepiece and a canister can best be accomplished by covering the joint with a rub ber apron. When the canister or cartridge is connected to the mask by means of a hose, the outside di ameter of the nipple and the inside diameter of the hose must be nearly equal. Stretching the hose un*duly to go over a large nipple will cause the hose to deteriorate rapidly, and too small a nipple will make the hose wrinkle when the clamping band is applied. Obviously, the proper filter media or chemi cal sorbents must be selected for suitable proc essing of the contaminated ambient air. E. Eyepieces (Lenses) Three important considerations attend the at tachment of eyepieces to a full face mask. First, the eyepieces must be secured so as to ensure a leakproof connection which will withstand not only normal flexing but also considerable abuse. Sec ond, the method of securing the seal must not dis tort or stress the glass or plastic eyepieces, thus distorting the field of vision and increasing break age of the eyepieces. Third, excessive stretching of the facepiece material, which reduces appreci ably the serviceable life of the facepiece, must be avoided. F. Eyeglasses Providing respiratory protection for individ uals wearing corrective glasses is a serious problem. A proper seal cannot be established if the temple bars of the eyeglasses extend through the sealing edge of the full face mask. The U.S. Army furnishes each user of corrective glasses a corrective lens mounted in a wire bracket that snaps into place in the eyepiece socket of the facepiece, which preserves the seal but does not pro vide really satisfactory vision. At least three manufacturers of full face masks have developed systems for mounting cor rective lenses inside the facepiece. One mounts the lenses in a special frame attached to a centermounted adjustable mount inside the facepiece (see Fig. 3.8). Another provides corrective glasses with special short temple bars that are supported by a special mount on each side of the facepiece but inside the sealing surface (see Fig. 3.9). A third supports with a suction cup a frame which holds prescription glasses from which the ^temple bars have been detached- (see Fig. 3.10). An alternative used for many years, but which generally is not very satisfactory, is to remove temple bars or leave one-half inch of bar and tape the eyeglasses to the wearer's head. The ability to wear corrective glasses with a half mask depends on the face fit. It is possible to obtain a seal with a poorly fitting respirator, but quite often the device will rest so high on the face as to make it impossible to wear glasses. G. Limitation of Vision* 1 Any respirator affects the wearer's ability to see. The adverse effect may be due to: 1. Reduced total field of vision. 2. Reduced binocular field of vision. <-ay>3 " E-06492 30 RESPIRATORY PROTECTIVE DEVICES MANUAL Fig. 3.8. Full face mask illustrating center mounted prescription glasses in side facepiece and nose cup insert. Fig. 3.9. Full face mask illustrating method of mounting prescription glasses inside facepiece by special mount on each side and nosecup insert. 3. Distorted field of vision. 4. Fogged eyepiece. The degree of visual impairment from these factors depends not only on the design of the respirator but also on the fit of the particular facepiece. Either the half or the full face mask can reduce the total field of vision. The half mask and the attached elements can restrict normal downward vision appreciably, an objectionable-in terference to individuals wearing the mask while walking or working at benches or desks. Upward and downward vision, as well as side ward vision, is of utmost importance in emer gencies. Ability to see the safest pathway or stairs, to see and avoid low hanging pipes and sup ports, and to recognize without delay any motion or situation at the extreme sideward limit of nor mal vision is often the key to satisfactory handling of critical situations. In selecting masks, this should be carefully weighed, together with the other factors outlined in the Manual. Diminished vision in the full face mask may be caused not only by the facepiece and attached canisters, but also by the design and placement of the eyepieces. Here the total field of vision de- pends on the size of the lens and its distance in front of the eye, i.e., a small lens close to the eye gives the individual essentially the same total field of vision as a large lens farther from the eye. However, the smaller the lenses or eye pieces, the more critical the face fit of the respi rator, because the position of the eye for proper viewing is restricted to small variations. For this reason, vision data from shadow graphs of lights placed at the center of the eye pieces reflect only the maximum field of vision of that particular respirator without showing the field of vision of an individual whose eyes are not centered at the optimum position. Also, the small er the eyepieces, usually the more the binocular field of vision is reduced. The importance of lessened binocular vision too frequently is overlooked. Quite often respira tory protective equipment is used in actual or po tential emergencies, in which a worker's ability to see determines his response, so that diminution of the normal binocular field of vision, with im paired depth perception, could have serious con sequences. Although a person could learn to com pensate for lack of depth perception, normally he E-06493 FACEPIECES 31 fogged on the inside when the worker is in a cold environment because of condensation of water produced by exhalation and by facial perspiration. It is impossible and impractical to try to pre vent fogging of the eyepieces merely by sealing off exhaled air from the cavity behind the lens, thus creating a sealed goggle physically attached to a half mask respirator. It is possible to pre vent fogging successfully for a limited period in a full face mask with a nose cup (see Figs. 3.8 through 3.10) to lead the exhaled air directly to the exhalation valve and an air inlet system which directs the incoming air across the inside of the eyepieces. In the Army assault mask, a nose cup with proper valves prevents exhaled air from con tacting the lenses. With nose cup and deflector tubes (see Fig. 11.1), the Army mask can be used at low temperatures with reduced fogging or frosting of the lenses, for limited periods. Antifogging compounds, an effective adjunct in efforts to reduce eyepiece fogging, should be used routinely. If such a practice is not followed regularly, a situation will inevitably develop in which dangerous fogging of the eyepiece will occur that could have been prevented or alleviated by the use of an antifogging compound. Fig. 3.10. Full face mask illustrating method of mounting prescription glasses inside facepiece with center mounted suction cup and nose cup insert. would not wear a respirator often enough to gain this facility. This lack of depth perception may very well be responsible for the sense of uneasi ness experienced by many individuals when wear ing a respirator; certainly most workers react favorably to a facepiece allowing greater binocu lar vision even though the total field of vision is somewhat reduced. Although minor scratches and opacities on an eyepiece are annoying, usually the annoyance is not extreme, and workers endure scratched eye pieces much as spectacle wearers tolerate dirty corrective lenses. Impaired vision from fogged eyepieces, however, is intolerable. When water in warm humid air condenses on cold eyepieces, it fogs them. Thus a worker wearing a respirator under cold temperature conditions finds the eye pieces immediately fogged on the outside when he enters a warm room with relatively high humidity. On the other hand, the eyepieces may become H. Speech Transmission The ability to communicate while wearing a respirator affects both the wearer's comfort and the effectiveness of the respirator. Communica tion may make the difference between a safe, ef ficient operation and confusion and panic, especial ly in difficult and dangerous jobs, when it is im perative to maintain constant control over a situa tion. Speech transmission through a respirator is extremely difficult, and irritating as well as fa tiguing, so workers may insert a finger and pull the facepiece away from the face in order to com municate. Even if they do not, mere movement of the jaws in speaking may cause leakage between the facepiece and the face, especially with the half -mask respirator. The Army Chemical Corps*^ has established criteria for evaluating speech transmission through a respirator. Factors con sidered are the volume of air in the facepiece cavity, the composition and placement of the ex halation valve and the diaphragm, the character istics of the nose cup and facepiece, and the free dom of jaw movements within the facepiece. A properly designed diaphragm in the facepiece helps materially in speech transmission, al though the diaphragm adds a maintenance problem to the routine cleaning program. The condition of the diaphragm should be checked carefully after each cleaning of the respirator. Several manu facturers market a combination voice transmitter diaphragm and outlet valve for use in full face E--06494 32 RESPIRATORY PROTECTIVE DEVICES MANUAL masks (see Fig. 3.9, and Fig. 3.10). Some others are offering battery-operated transistor amplifiers with speaker, and with the microphone mounted in the facepiece of a full face mask. Several sell, a self-contained breathing apparatus approved by the Bureau of Mines that has a facepiece micro phone, either a sound-powered or transistor-type telephone system, and earphones for receiving. L Skin Irritation The elastomers for facepieces should contain no additives that could be skin sensitizers. Gen erally, only additives proved harmless are used, but occasionally an individual may be unduly sensi tive to one of the ingredients used in compounding the rubber. Respirators worn in direct sunlight during hot weather often irritate and blister the wearer's skin beneath the facepiece, causing much distress and even disrupting work schedules. It is not clear whether the heat inside the facepiece, or reaction to the composition of the facepiece, causes the blisters. The Bureau of Mines approves some half mask respirators with cotton "facelets" for pro tection against some dusts. The facelets help pre vent facial irritation and are considered more comfortable than rubber contacting the face in hot and sweat-producing work. When respirators are worn during work with an irritant dust, many in dustries report that the cotton facelets must be used to prevent dermatitis. The Bureau of Mines does not approve fume, gas, or vapor respirators with cotton facelets. In fact, the Bureau empha sizes that it is impossible to obtain a gas-tight face seal with a cotton facelet. In general, skin irritation can be eliminated or minimized if the respirators are cleaned daily. J. Worker Acceptance The wearer's comfort, and his acceptance of the distress caused by wearing a respirator, are no less important than the devices' effectiveness. " Comfort," although perhaps not the most appro priate term to apply to a respirator which re stricts vision, breathing, and ventilation to the face, nevertheless expresses all the considerations involved in an individual's acceptance of the res pirator and is synonymous with "wearability." There is no necessary relation between effective ness and discomfort: the degree of discomfort caused by a respirator in no way indicates its ef ficiency! Although an individual probably always will experience some discomfort when wearing a personal respiratory protective device, for most people respirators are available that do not cause undue distress, yet effectively separate an irrespirable atmosphere from a respirable one. The number of complaints about the wearing of a respirator often varies inversely with the dirtiness and the physical exertion associated with a job, i.e., an office or a laboratory worker us ually finds more fault with a respirator than does a laborer on dirty, heavy work. Complaints also increase rapidly if the worker must wear the respirator while doing heavier work than he is accustomed to performing routinely. Some individuals cannot tolerate the sense of confinement of a full face mask. Called by the Army "psychological leakers," they rarely admit this but find unlimited fault with the respirator, and often retire from a job in a contaminated at mosphere "because the mask leaks." These peo ple, a real hazard to themselves and to others in an emergency, cannot be identified beforehand. Therefore, those who may have to enter an at mosphere immediately dangerous to life should be trained in the actual use of a respirator in a test atmosphere. As discussed in preceding sections, other factors also influence a worker's acceptance of a respiratory protective device. An improperly fitted mask may create intolerable pain spots. Poorly designed or malfunctioning valves may cause uncomfortable resistance to breathing or an irritating flicking and popping. Limitation of vision and of speech transmission is unpleasant. All these factors contribute to the sum of physical discomfort which affects a worker's willingness to wear a personal respiratory protective de vice. REFERENCES 1. Hertzberg, H. T. E., Daniels, G. S., and Churchill, E.: Anthropometry of Flying Per sonnel-1950, Wright Air Development Center Technical Report, WADC-TR-52-321, Sept. 1954. 2. Martin, Robert E.: Fitting Trials of E52R23 and E52R24 Civilian. Protective Masks, In terim Report, Chemical Corps, Chemical and Radiological Laboratories, Army Chemical Center, Maryland, CRLR 249, 10 Sept. 1953. 3. Garn, Stanley M., Hunt, Edward E., Jr., and Maranjian, Forsythe: Rapid Reading Faceometer and Data for Headform Design, Final Report on Part n of Contract No. DA 18-108CML-2829, 31 July 1952. 4. Army Air Forces, Materiel Center, Memo randum Report No. EXP.-M-49-695-15, Sept. 9, 1942. 5. -Randall, Francis E.: Facial Types Among Aviation Cadets, Army Air Forces Materiel Center, Memorandum Report PB 6951, Sept. 9, 1942. 6. Cosentino, John A.: Faces and Heads, U.S. E--06495 FACEPIECES 33 Army, MIT Memorandum Report No. 135 (PB 7939), 2 June 1945. 7. Industrial Hygiene Group, Los Alamos Sci entific Laboratory, Los Alamos, New Mexi co: Memorandum Report, 1960. Unpublished. 8. Dorman, R. G.: (British Army Chemical De fence Experimental Establishment, Porton, England), personal communication, Apr. 1960. 9. Tait, G. W. C. and Byington, E. E.: Respira tor Problems in Atomic Energy Practice: Am. Ind. Hyg. Assoc. J., 19:123-125, Apr. 1958. 10. American Standards Association: American Standard Safety Code for Head, Eye, and Respiratory Protection, Z2.1 1959, Amer. Stand. Assoc., 10 East 40 St., N.Y. 16, N.Y. 11. Silverman, L., Lee, R. C. and Lee, George: Fundamental Factors in the Design of Pro tective Respiratory Equipment--The Charac teristics of Inspiratory and Expiratory Valves: Office of Scientific Research and De velopment, Report No. 1864, Aug. 1, 1943. 12. Smith, Donald P.: Considerations in the De sign of Gas Mask Outlet Valves, M.I.T.--M.R. No. 212, Project E7a-3MIT> Job 27 (No date-- approximately 1945). 13. Glidden, G. M.: A New Development in Gas Masks, Armed Forces Chem. J., 51-52, Apr. 1952. 14. Bogardus, H. F.: The Development of the NDMK-V Gas Mask, NRL Report 5038 (Confi dential), Nov. 19, 1957. 15. Siegel, Bernard and Shanty, Frank: Design Considerations in the Development of Protec tive Masks: Respiratory Protective Devices and Civil Defense, OTS Report, PB 121162, 4 April 1955. E-0&496 Chapter 4 PARTICULATE FILTERS L INTRODUCTION One method for removal of airborne particu late contamination is filtration by mechanical fil ters. Since filter media vary widely in construc tion and design, an understanding of the various separation mechanisms that influence filter per formance is important in choosing the proper fil ter for a specific situation. The effectiveness of all separation mechanisms is primarily related to particle size. Some idea of the variety and size of airborne contaminants, and therefore of the va riety of the problems that may be encountered, can be seen in Fig. 4.1. In early industry major health problems re sulted from the inhalation of production materials such as siliceous dusts, lead, and asbestos. Re cently more complex hazards have come from synthetic chemicals, new metals, radioactive sub stances, etc., and exposures to highly hazardous substances such as beryllium, lithium hydride, in secticides, and radioactive aerosols. Inhalation of even microscopic quantities of certain of these highly toxic substances may be serious. One as pect of correcting this problem has been the stim ulation of development of more highly efficient filter media for use in respiratory protective de vices. n. FILTER MATERIALS AND CONSTRUCTION A. Materials added strength contain a binding agent; and other materials are often used to improve water re sistance. In some cases the filter medium is ar tificially loaded with materials such as asbestos floe to provide high initial efficiencies. B. Construction The majority of filter media are manufactured on standard paper-making equipment in which the fibers are dispersed in a water slurry and de posited in a sheet form on a felt or screen by fil tration means. Subsequently, the mat is dried and rolled into reels for later use. Another method, having limited use, is the air-laying method, in which the fibers are deposited or suspended in air and laid down in a flat sheet on a moving felt or screen. A third method uses fibers of prede termined length and diameter that are formed by spraying through orifices and then deposited on a moving screen. Where felt media are desired, a selected commercial felt is impregnated with resins to provide electrostatic properties. In most instances the final air-purifying ele ment or cartridge consists of a filter medium con tained in a suitable casing to permit attachment to the respirator facepiece. The filter media are normally cemented or crimped into the casing to ensure satisfactory sealing and suspension. In this manner the media are also protected from damage during use. Early respirator filters usually were com posed of cellulose materials. In recent years, de velopments' in filter manufacturing have brought forth a number of materials that have improved filtering efficiency and resistance, including glass, asbestos, wool, ceramic, and a variety of cellulose and plastic fibers. These are used indi vidually or in combinations. Because a decrease in fiber diameter (usually accompanied by higher fiber packing) results in greater efficiency, considerable effort has been made to produce fiber diameters as small as pos sible. Many filter materials are available down to and including submicron sizes. Supplementary materials may be added for various purposes. Filter media designed to .possess electrostatic properties are impregnated with resinous substances; those requiring some m. MECHANISMS OF FILTRATION Numerous considerations are required in the initial design and development of a filter medium for any particular respiratory protective device. Some of the considerations are: 1. Particle size distribution of contaminant. 2. Toxicity of contaminant. 3. Concentration of contaminant. 4. Type of use (emergency or routine). The development and production of high ef ficiency filter media received considerable atten tion during World War II for use in gas masks and other military applications.! Further improve ment in high efficiency media resulted from the stringent demands on air-cleaning facilities for atomic energy installations. The filtering param eters of such filter media are analogous in most 35 E--06497 COURTESY MINE SAFETY APPLIANCES CO. RESPIRATORY PROTECTIVE DEVICES MANUAL 5 6 OOCL J(oUuaDV o .*wWQN-> J<CD H fcxD -06498 PARTICULATE FILTERS 37 respects to those used for respiratory protection. Respirator filter media do not behave merely as screens or sieves which remove particles larger than the pore size with extremely high plugging rates. They achieve their air-cleaning ability from a number of mechanisms which con tribute to the over-all filter performance. The primary filtration mechanisms that act upon a particle when it encounters a fibrous bed are: di rect interception, inertial impaction, and diffusion. Under certain conditions with various types of fil ter media, electrostatic attraction and gravity may also be of significance. The relation between these separation mechanisms and particle size is given in Table 4.1. TABLE 4.1 PARTICLE SIZE RANGE FOR SEPARATING MECHANISMS Force Particle Size Range, p Direct Interception Impaction (inertial contact) Diffusion (Brownian motion) Electrostatic Attraction Gravity >1 >1 <0.1 - 0.2 >0.01 >1 A. Direct Interception Direct interception of a particle occurs when a particle of radius " r" approaches a fiber along a streamline which passes closer to the fiber than the distance " r," and thus the particle makes con tact with the fiber and is collected (see Fig. 4.2). VISCOUS FLOW STREAMLINES Thus the direct interception parameter for par ticles which do not deviate from the streamline is: where R = r_ rf df R = direct interception parameter r = particle radius Tf = fiber radius dp = particle diameter df = fiber diameter The target efficiency of the interception mech anism is a function of R and the Reynold's number of the system. While, strictly speaking, direct in terception is a collecting mechanism only for par ticles which do not deviate from streamlines (small particles or particles of low density), the mechanism does increase the effectiveness of other forces. Hence R is a significant parameter of filtration. B. Inertial Impaction Inertial impaction occurs when a particle has sufficient mass to deviate by inertia from the line of flow as the air stream passes around the fiber and when the center of the particle passes within the distance r', contacting the surface of the fiber (see Fig. 4.2). Inertial forces are a function of a number of factors which influence the amount of deviation of a particle from the path of streamline flow. This can be seen from the classical inertial parameter: 2 where Cpvdg 18 pdf ip = inertial parameter C = Cunningham correction factor p = density of aerosol particle v = velocity of air flow p = viscosity of gas (air) dp = particle diameter df = fiber diameter Fig. 4.2. Particle removal by fibrous filter through mechanisms of intercep tion and impaction. The inertial parameter is related to the target efficiency in a complex maimer which cannot be stated in a simple equation. The relationship has been presented graphically and confirmed by ex periment by several writers.34 The efficiency in creases as the value of the parameter increases. The inertial parameter is one of the most in fluential forces in the filtration of particulates, especially with particles over 1 p in size. The --06499 38 RESPIRATORY PROTECTIVE DEVICES MANUAL effect due to an increase in particle size is readily apparent. The viscous drag of the air attempts to limit deviation from the streamline, but the larger or more dense the particle the more pronounced is the deviation and hence the efficiency. Effi ciency is also enhanced by an increase in par ticle velocity or a decrease in filter fiber size. Submicron particles are relatively unaffected by inertial forces. C. Diffusion Diffusion (Brownian motion) has been es tablished as another of the major separation mechanisms in the filtration of particulates, with increasing effect for particles from less than 0.1 ijl to 0.2 m in diameter. When particles are so small that they are comparable in size with the free mean path of gas molecules (about 0.06 ii), their motion is violent and collisions with filter fibers are therefore increased.5 The diffusion parameter may be expressed as follows: 2 D 1 v df CkT M dp where D = diffusion parameter -3-tC-t--km--T-d--p = diffusion coefficient k = Boltzmann constant T = absolute temperature of gas (air) v = velocity of air flow df = fiber diameter dp = particle diameter Ii = viscosity of gas (air) The target efficiency of the diffusion mech anism is related to the parameter D and the Reynolds number of the system and is approxi-. mately proportional to VD. The importance of diffusion for removing fine- particulates increases considerably as the velocity of the air passing through the filter decreases, such as at the beginning and end of an inhalation cycle. This is due to the extended time the parti cle remains within the filter medium, with a cor respondingly greater opportunity for contact with the fibers during its erratic motion from impacts with air molecules. The importance of the diffusion mechanism is evidenced by the small particles such as metal fumes, powders, and dusts liberated in many pres ent day industrial operations. The removal of such fine particulates by respirator filters depends largely on this mechanism. Ramskill and Anderson6 have presented graphically, for a given aerosol and a given filter, how the effectiveness of direct interception, in ertial impaction, and diffusion vary with velocity. This is shown in Fig. 4.3. The relative positions indicated for the vari ous mechanisms were chosen arbitrarily by Ramskill and Anderson and do not represent ex perimental data. The general manner in which the diffusion mechanism varies with velocity is shown schematically in Curve I of Fig.'4.3. The slope of this curve is dependent on the radius of the aero sol particle, the fiber diameter, and the inter fiber distance. The effect of the direct interception mech anism is shown in Curve II of Fig. 4.3. As might be expected, this mechanism is independent of velocity, except as the flow line pattern may be changed by velocity, and is dependent on particle radius, fiber diameter, and interfiber distance. The effect of inertia is shown in Curve III of Fig. 4.3. This mechanism is dependent on the mass of the particle, the fiber diameter, and the interfiber distance. It is expected that the inertial mechanism should become measurable at some velocity (Vg) and should exert no additional effect above some velocity (vm) where the collection ef ficiency reaches 100%. The net effect of the three mechanisms will be a curve similar to the dotted curve of Fig. 4.3 with a maximum penetration at a velocity Vp. D. Electrostatic Attraction The electrostatic attraction which may be present due to certain characteristics of the par ticles and of the filter medium is also a separa tion mechanism in some types of respirator fil ters. An electrostatic charge on a fibrous filter bed may be produced in a number of ways, such as by carding the fibers or by' the application of a resin to the fibers. Certain dielectric waxes, resins, and plastics have the property of gen erating an electrostatic charge and will attract and hold particulate matter.1* Hansen,8 in 1930, de veloped a resin-wool filter having an electrostatic charge; it is used in many present day respira tors. Filters treated with resin develop their electrostatic charge when the filter medium is carded or flexed. The particulate contamination that enters the filter medium during respirator use may have a slight residual charge, either positive or negative. Particulate matter receives an electrostatic charge in various ways. Some of the ways in which charges are formed are friction of the particles with each other and with the air, ionization by ultraviolet radiation, chemical reaction, collision of particles with electrons and gaseous ions, and E-06500 PARTICULATE FILTERS 39 INTERCEPTION AS RADIUS INCREASES CURVE MOVES I AS FIBER DIAMETER INCREASES CURVE MOVESt AS INTER FIBER DISTANCE INCREASES CURVE MOVES f DIRECT INTERCEPTION INERTIAL 0s AS RADIUS INCREASES CURVE MOVES *- AS DENSITY INCREASES CURVE MOVES - AS FIBER DIA. INCREASES CURVE MOVES -*> or h \txJ Z liJ /AS RADIUS INCREASES Q_ / AS FIBER DIAMETER INCREASES j CURVE MOVES ----------> AS INTER FIBER DISTANCE INCREASES CURVE MOVES ---------- LINEAR VELOCITY, CM/SEC Fig. 4.3. Filtration mechanisms (after Ramskill and Anderson). Copyright, Journal of Colloid Science. absorption by particles of such ions and elec trons.^ Uncharged nonconducting particles can be collected by electrostatic forces as a result of polarization. It has been shown that oil mists, high humidity, and wet smoke^ may dissipate the electrostatic .charge from filter fibers. Another force that adversely affects electrostatic charge is the presence of radioactive substances in the filter bed. The resultant ionization from the radi ation fields causes the fiber charge to be dis sipated. E. Gravity Gravity as a force in the removal of particu lates by a fibrous bed is a function of the terminal settling velocity of the particles, and the impor tant parameter is: _ u P dpS v 18 /i v where G = settling parameter u = terminal settling velocity of the par ticle v = velocity of air flow M = viscosity of gas (air) p = density of aerosol particle dp = particle diameter g = acceleration of gravity The target efficiency due to gravity is direct ly proportional to G and is approximately equal to G/tt for unoriented fibers. Since u is very small compared to v for airborne dust, gravitational force is of minor importance in respirator filtra tion. Since the velocity of air passing through a respirator filter medium is proportional to the air movement produced during inhalation, it can vary from a negligible value to one that is relatively high in a fraction of a second during the inhalation and exhalation cycle. 40 RESPIRATORY PROTECTIVE DEVICES MANUAL F. Over-all Efficiency The over-all target efficiency of a filter fiber cannot be accurately calculated by adding the ef ficiencies due to interception, impaction, diffusion, electrostatic forces, and gravity. The following equation, which is based on the work of Davies,3 expresses the total target efficiency of an isolated fiber for interception, impaction, and diffusion. Davies did not consider the effects of gravitational and electrostatic mechanisms. *7o = 0.16 [R + (0.5 + 0.8 R) (ip + D) - 0.1052 R {ip + D)2] where V 0 = total target efficiency R = direct interception parameter ip = inertial parameter D = diffusion parameter The over-all efficiency of a mass of fibers com prising a filter mat can be calculated from tj 0, the packing density of the mat and the filter thickness using the method of Davies. Modifications of this last step have been proposed by Chen,^^ and a somewhat different method has been used by Stairmand.14 The application of Stairmand's method to a filter composed of slag wool has been detailed by Silverman.^ IV. FILTER PERFORMANCE CHARACTERISTICS The filtration forces discussed in the pre ceding section, when associated with the physical characteristics of the filter bed and the aerosol, permit an appraisal of the two major performance characteristics of filter media used in respira tory protective devices--efficiency and pressure drop. A. Efficiency Air.-clea-ning efficiency is probably the mostimportant performance characteristic of a filter medium in a respiratory protective device. If this quality is impaired, a serious inhalation risk may occur. The degree of removal of contamination from the air, or the efficiency of a filter, is de pendent on the characteristics of the medium and of the particulate matter. Respirator filters de signed for use against substances of low toxicity may demonstrate relatively low efficiencies, in the range of 20 to 90 per cent. Filters designed for use against material of high toxicity must have high efficiencies--above 99.95 per cent. Some of the factors which influence efficiency are filtering velocity, fiber diameter, loading, and particle size. 1. Filtration Velocity The velocity of air passing through a filter is normally kept as low as possible to increase the efficiency of small particle removal and to de crease the resistance to air flow. Reduced ve locity has been achieved largely by increasing the area of the filter media by folding, pleating, or convoluting or by joining the edges of properly spaced flat filter sheets. These methods achieve compactness and provide a greater surface area, with associated low pressure drop and improved loading characteristics. Examples of configura tions that increase surface area are shown in Fig. 4.4. Filter efficiency for small particles is nor mally increased with reduced velocities since the filtration forces of diffusion and, in certain in stances, electrostatic attraction are enhanced, al though the inertial force is less effective. For a given filter medium there is a velocity at which any given particulate of a definite size will show a maximum penetration. In general, the smaller particles penetrate most readily at higher velocities, indicating the reduced opportunity for diffusion. Stern et al.2 have demonstrated this for spherical polystyrene particles of density 1.05 and for dioctyl phthlate (DOP) smoke, using Institute of Paper Chemistry filter mat (see Fig. 4.5). Of particular interest in the filtration of par ticulate contamination is the effect of pulsating air flow on efficiency because velocity has been shown to strongly influence the filtration parameters (see Section III). It can be seen in Chapter 2, Sec tion IIC, that the inhalation phase of the respira tion cycle produces air flow rates ranging from zero at the beginning of inspiration to levels of almost 300 liters per minute (1/min) at the point of maximum inspiratory air flow under a work rate of 1,660 kilogram-meters per minute (Kg-M/min). This effect of pulsating air flow on efficiency has been studied by Jordan and Silver man,and a comparison of pulsating flow effi ciency with that from steady flow is shown in Fig. 4.6. The following conclusions were made by these investigators: 1. The efficiency of collection for a filter sub jected to pulsating flow is not equal to the effi ciency obtained under conditions of steady flow with a velocity equal to the mean velocity of the pulsating flow. 2. Under conditions of pulsating flow, the character of stream flow is altered in such a man ner as to increase the effective range of velocities for the inertial diffusion and settling mechanisms. At low mean velocities, the effect of this change is to increase the efficiency of collection for pul sating flow over the efficiency obtained under F-06502 PARTICULATE FILTERS 41 MAT EFFICIENCY, PERCENT Fig. 4.4. Filter media configurations for increasing surface area. VELOCITY, FT./MIN Fig. 4.5. Experimental collection efficiencies of the IPC filter mat for special polystyrene particles of density 1.05 and DOP smoke at ambient pressure (after Stern, Zeller, and Schekman). Copyright, Journal of Colloid Science. conditions of steady flow at a velocity equal to the mean velocity. 3. At high velocities the collection efficiency obtained under pulsating flow conditions is less than the efficiency obtained under conditions of steady flow at a velocity equal to the mean pul sating velocity. 4. For the range of velocities to which a filter for a respiratory protective device would be sub jected, the effect of pulsating flow would be to in crease the efficiency of collection. 2. Fiber Size The technology of fine fiber production has made outstanding advances in recent years. It is now possible to produce on a commercial scale fine fibers of materials such as glass, plastics, and ceramics. Some of these are available in fiber diameters of less than 1 p. Fine fibers, in many instances, do not pos sess sufficient strength to withstand the required air flows and have to be supported by the inclusion of fibers of larger diameter or by a backing with greater strength. Fine fibers predispose to higher E--0f>503 42 RESPIRATORY PROTECTIVE DEVICES MANUAL VELOCITY, CM/SEC Fig. 4.6. Comparison of efficiency-velocity relations for experimental and theoretical values (after Jordan and Silverman). efficiencies because of the favorable effect on the filtration mechanisms, and they are normally em ployed whenever possible. This is evident from the impaction and diffusion equations in Section III, which demonstrate that a filter bed composed of fine fibers provides a greater opportunity for im paction to occur, as well as a greater surface for particles to contact when under the influence of Brownian motion. 3. Loading In addition to the increase in resistance caused by the presence of a filter loading, there is an accompanying increase in efficiency due to the filtering action of the dust or fume deposit The effect of loading on the efficiency of a filter me dium has been shown by Smith and Stafford* (see Fig. 4.7). As mentioned in Section II, various types of filter medium construction are possible. Those for use in respiratory protective devices, how ever, are normally designed with loading charac teristics to provide long life. Davies^ has pre sented the relative loading characteristics of three typical filter media, from which the difference in the rate of pressure drop increase due to loading is evident. This can be seen in Fig. 4.8. Because of high pressure drop due to loading, cotton sheet is not practical as a filter medium for respirator cartridges. 4. Particle Size The parameters related to the particulate matter involved have an important influence on the performance of a filter medium as noted in Sec tion m. It has been demonstrated by Thomas and Yoder*17 that for any given filtration velocity there is a particle size that penetrates a filter most readily (see Fig. 4.9). With fibers of approximate ly 1.5 ix diameter and a face velocity of about 1.8 ft/min (0.94 em/sec), penetration increases with a decrease in particle size below 0.5 (i and reaches a maximum at about 0.25 ix. Numerous investigations have shown this peak in penetration to be within the range of 0.1 to 0.4 ix, which means that particulates smaller and larger than this range are normally removed with greater effi ciency. Those of larger size are affected to a greater degree by the forces of interception, im paction, and gravity. Those below this size are primarily removed by diffusion. B. Pressure Drop The efficiency of a filter medium is at its lowest when it is new, since its effectiveness re lies entirely on the characteristics of the medium itself. As a respirator is-used, the medium grad ually loads with particulates removed from the air. A portion of these particles, especially the smallest size fraction, penetrates into the filter bed, although most remain on or near the sur face. *8 As the loading increases, it supplements the filtering ability of the medium, thereby in creasing the over-all efficiency as well as the re sistance. Since the filtration afforded by deposited dust or fume supplements that provided by the medium itself, it is apparent that the over-all resistance will be increased as loading progresses. The im portant factors which influence filter resistance as a function of loading are: 1. Particle size. E--06504 PARTICULATE FILTERS 43 a. w 5 u. O (A U1 Xo z I 0. o O UJ " E <A (A Ui aa:. HOURS OF RUNNING TIME AT 5.25 LIN.FT/MIN. Fig. 4.7. Effect of running time on efficiency of AEC filter paper at a flow rate of 5 linear feet per minute (after Smith and Stafford). 2. Particle shape. 3. Particle density. 4. Particle surface characteristics. 5. Packing characteristics of deposited ma terial. 6. Amount of dust or fume on filter. 7. Gas'density. 8. Gas viscosity. The resistance to gas flow through a filter medium containing a deposit of dust or fume will normally be influenced by each of these factors. For practical consideration, the resistance due to the presence of its loading has been expressed by Silverman*-** as: KiLTV2 Rf - Ri R = 7000 where Rf = final resistance, inches of water Rf = initial resistance, inches of water = K0 V R = net resistance due to dust K0 = resistance coefficient for clean fil ter V = filtering velocity, ft/min L = dust load in air to filter,,gr/cu. ft. T = time, in minutes, for filter resist ance to increase R inches of water Kf = specific resistance of the dust in inches of water per pound of dust per square foot of cloth area per foot per min. filtering velocity The above relationship between resistance and use time prevails until the interstices are greatly re duced in size. After this the resistance increases exponentially with time. High initial efficiency is an essential quality when a device is used as protection against a high ly hazardous substance. This is particularly true where radioactive particulates are involved, for E--06505 44 RESPIRATORY PROTECTIVE DEVICES MANUAL 0 250 500 750 1000 DUST LOAD,G/M3 COTTON SHEET NAP FELT Fig. 4.8. Clogging of various types of filter material (after Davies). Copyright, .British Institution of Mechanical Engineers Journal. in such instances dust levels encountered are sel dom high enough for loadings to increase effi*clencies significantly. Some respirator filter media are purposely preloaded with asbestos fi bers or floe at the time of manufacture to ensure that initial filtering efficiencies will be relatively high. Although the efficiency of a filter medium will increase with an increase in loading, it should be emphasized that a filter should not be used in a respirator beyond the point where the pressure drop causes the resistance to inhalation to be ob jectionable. When the resistance attains this mag nitude, it not only fatigues the wearer, but, more important, it will probably result in an increase in the leakage around the facepiece which will mark edly increase the over-all penetration of the de vice. Respiratory protective devices approved by the U.S. Bureau of Mines meet limitations on the maximum resistance to inhalation. Such limits are based partly on the physiological requirements for inhalation as described in Chapter 2, Section n. When a person wearing a respirator is engaged in E--06506 PARTICULATE FILTERS 45 Fig. 4.9. Penetration of homogeneous DOP aerosols through a fiberglass FG-50 filter mat (after Thomas and Yoder). Copyright, A.M.A. Archives of Environmental Health. active exereise, the increase in respiration pro duces relatively high air flows and an accompany ing increase in resistance of the device. Accord ing to current approval schedules of the Bureau of Mines, the limiting pressure drop for a complete particulate respirator is 50 mm of water at an air flow rate of 85 1/min. Tests on a series of eleven currently available filter cartridges of various types showed pressure drops ranging from 15 to 50 millimeters (mm) of water at a flow rate of 85 1/min. Pressure drop is also a function of several properties of the filter medium itself. It varies directly as the filter density, which is related to the filter thickness or the degree of calendering. 'It is also affected directly as the loading and the air velocity, which is determined by the filter sur face area. Normally, a decrease in fiber, diameter is accompanied by an increase in resistance. V. PERMISSIBLE FILTER MEDIUM PENETRA TION It has been described elsewhere in this man ual that penetration of contamination into a respi rator facepiece may originate from several sources. With respect to air-purifyingrespirators using particulate-removing filters, there is always a certain inherent penetration through the filter medium itself since no medium is 100 per cent efficient. In view of this and because modern filter manufacturing techniques enable filters with rela tively high efficiencies to be produced, the Bureau "06507 46 RESPIRATORY PROTECTIVE DEVICES MANUAL of Mines has established permissible penetration values for the various air-purifying respirators. The approval schedule requirements can be seen in Table 9.11 (Chapter 9). These data are pre sented in Table 4.2 as calculated in terms of the minimum filter media efficiencies that will meet the approval requirements of the Bureau of Mines test schedules. The test schedules outlined in Tables 9.11 and 4.2 apply only to contaminants not significantly more toxic than lead. As discussed in Chapter 1, Section V, the Bureau has prepared tentative ap proval requirements for dusts and fumes more toxic than lead. Protection against highly toxic and radioactive materials requires, among other things, filter media which furnish dependably high efficiencies. Respirator filter media that are presently available provide efficiencies as high as 99.99 per cent, as tested with DOP smoke of 0.3 n diameter. Recent performance tests* on a representative group of 100 commercially available respirator filter cartridges demonstrated efficiencies as shown in Fig. 4.10. Ninety-five per cent of the filters tested had efficiencies > 99.97 per cent. Since this test was made, manufacturers have ob tained greater quality control by routine testing of all filters with dioctyl phthlate. VL FILTER TESTING Several methods are currently used to evalu ate efficiencies of particulate-removing filter media. These include the use of liquid aerosols such as DOP; solid aerosols such as methylene blue, uranine, sodium chloride, silica dust, and Fig. 4.10. Efficiency of respirator filter cartridges. lead fumes; insecticide aerosols; and bacteriologi cal aerosols. TABLE 4.2 EFFICIENCY OF APPROVED DISPERSOID-REMOVING RESPIRATORS Dispersoids Covered by Respirator Pnetimoconiosis-producing and nuisance dusts Toxic dusts (not significantly more toxic than lead) Metal fumes (not significantly more toxic than lead) Chromic acid mists Pneumoconiosis-producing and nuisance mists Test Dispersoid Silica dust Litharge 75%; free metallic lead 25% Lead fume Chromic acid mist Silica mist (atomized silica dust-water mist) Minimum Efficiency for Approval Performance, % 97.4 98.5 98.5 99 90 E--06508 PARTICULATE FILTERS 47 A brief summary of each of the more common test methods is given below. Not included are the National Bureau of Standards dust spot method and other recognized standard methods commonly used for space filters, since these are not appli cable to respirator filter testing. Details of filter tests carried out under the several U.S. Bureau of Mines approval schedules are discussed in Chapter 9. Test aerosols used include silica dust, lead fumes, chromic acid mist, and a mixture of litharge and free metallic lead. The U.S. Department of Agriculture carries out tests to evaluate the efficiency of respirator filters for various insecticides. In each case, the test aerosol is the insecticide in question. Details are included in Chapter 11, Section V. A. Dioctyl Phthlate (POP) The DOP test aerosol^'^O generated by passing air through concentrated vapor produced by heating dioctyl phthlate to 170C. The resulting aerosol is mixed with clean air at 25C and ad justed to produce a concentration of approximately 100 milligrams per cubic meter (mg/M^) of air. This produces a homogeneous liquid aerosol, with a median size of 0.3 /*, through condensation from the vapor state. Test efficiencies are similar to those obtained by atmospheric dust counting. Pen etration down to 0.001 per cent can be achieved by light-scattering measurements before and after the filter. Details of the DOP smoke penetration test are available in the literature.21 B. Methylene Blue A solid aerosol is produced by the atomiza tion of a one per cent aqueous solution of methy lene blue.^>22 The resulting aerosol is mixed with larger quantities of dry air to evaporate water vapor present and adjusted to a concentra tion of approximately 25 mg/M^ of air. The heterogeneous solid aerosol produced has a me dian size in the submicron range. Filter effi ciencies are determined by discoloration compari sons with a filter standard after exposure to steam. The lower limit sensitivity is approximately 0.005 per cent penetration. Additional details are avail able in the literature.23,24 C.. Sodium Chloride A solid aerosol is produced by atomizing a 2 per cent aqueous salt solution, which is then di luted with dry air to produce solid sodium chloride particles.^ Analysis is carried out with a com parison spectroscope, which is used to measure . the intensity of a sodium light from a hydrogen flame in the test aerosol before and after the fil ter. This method produces relative efficiencies and must be calibrated by some other method such as methylene blue. Details of this test procedure are available in the literature.25 D. Uranine A solid aerosol is produced by atomizing a 2.35 per cent aqueous solution of uranine.26 The resulting aerosol is mixed with large quantities of dry air to evaporate water vapor present. Using impinger cutoffs, a heterogeneous aerosol having a median diameter of 0.20 fi and a geometric standard deviation of 2.4 can be produced. Fluorometric analysis is carried out by light excitation at 4400 to 5000 angstroms (A), with a resulting light emission at 5700 to 5900 A. Fluorometric measurements can be made for as little as 10"9 g of uranine, permitting great sensitivity. E. Other Test Aerosols Of some interest is the use of bacterial spores, such as B. globiggi, as a test aerosol. 2? Other aerosols used include uranium, copper sul fate, and various radioactive materials. REFERENCES 1. Smith, W. J. and Stafford, E.: Dry Fibrous Filters for Dust-Free Air, presented at the U.S. Technical Conference on Air Pollution, Washington,D.C., May3-5,1950 (unpublished). 2. Stern, S. C., Zeller, H. W., and Schekman, A. L: The Aerosol Efficiency and Pressure Drop of a Fibrous Filter at Reduced Pressures, J. Colloid Sci. 15:546-562, Dec. 1960. 3. Davies, C. N.: The Separation of Airborne Dust and Particles, Inst Mech. Engrs., Proc. B, 1, 185-213, 1952-1953. 4. Friedlander, S. K., Silverman, L., Drinker, P., and First, M.W.: Handbook on Air Clean ing, Dept, of Ind. Hyg., School of Public Health, Harvard Univ., USAEC, Washington, D.C., Sept. 1952, 89 pp. 5. Davies, C. N.: Fibrous Filters for Dust and Smoke, Proc. 9th Intern. Congr. Ind. Med., London, Sept 1948, 162-196, John Wright and Sons, Ltd., Bristol, England, 1949, 1090 pp. 6. Ramskill, E. A. and Anderson, W. L.: The Inertial Mechanism in the Mechanical Filtra tion of Aerosols, J. Colloid Set 6:416-428, Oct. 1951. 7. U.S. Atomic Energy Commission: Handbook on Aerosols, Chapters from the Summary Tech. Rept. of Div. 10, Natl. Defense Re search Comm., Filtration of Aerosols, by Rodebush, W. H., p. 117-122, USAEC, Wash ington, D.C., 1950. 8. Hansen, Nicolai L.: Gas Masks, Brit. Pat. No. "06509 48 RESPIRATORY PROTECTIVE DEVICES MANUAL 384,052, Dec. 1, 1932. 9. Rodebush, W. H., Langmuir, I., and LaMer, V. K.: Filtration of Aerosols and the Develop ment of Filter Materials, OSRD No. 865, Part I, by Rodebush, W. H., p. l-8a, Office of Sci entific Research and Development, Natl. De fense Research Comm., Div. B., Washington, D.C., Sept 4, 1942, 408 pp. 10. Silverman, L.: Filtration through Porous Ma terials, Am. Ind. Hyg. Assoc. Quart. 11:11-20, Mar. 1950; Heating and Ventilating (Ref. Sec.) 68-74, July 1950. 11. Thomas, D. J.: Fibrous Filters for Fine Par ticle Filtration, J. Inst. Heating Ventilating Engrs. (London) 20:35-55, May 1952. 12. Rodebush, W. H., Langmuir, I., and LaMer, V. K.: Filtration of Aerosols and the Develop ment of Filter Materials, OSRD No. 865, Part V, by LaMer, V. K., p. 1-12, Office of Sci entific Research and Development, Natl. De fense Research Comm., Div. B, Washington, D.C., Sept. 4, 1942, 408 pp. 13. Chen, C. Y.: Filtration of Aerosols by Fibrous Media, Chem. Rev. 55:595-623, June 1955. 14. Stairmand, C. J.: Dust Collection by Impinge ment and Diffusion, Trans. List. Chem. Engrs. (London) 28:130-136, 1950. 15. Silverman, L., Small, W. D., Beauchamp, I. L., and Billings, C. E.: Open Hearth Stack Gas Cleaning Studies, Semi-Annual Rept. SA2 for May 1, 1954 to Oct. 31, 1954, School of Public Health, Harvard Univ., Boston, Mass., Dec. 1, 1955. 16. Jordan, H. S. and Silverman, L.: Effect of Pulsating Airflow on Fiber Filter Efficiency, Rept. NYO 4814, Air Cleaning Lab., School of Public Health, Harvard Univ., Boston, Mass., Dec. 15, 1961. 17. Thomas, J. W. and Yoder, R. E;: Aerosol Size for Maximum Penetration through Fiberglass and Sand Filters, A.M.A. Arch. Ind. Health 13:545-549, 1956. 18. Stafford, E. and Smith, W. J.: Performance Characteristics of Dry Fibrous Air Filter Media, presented at the Symposium on Dispersons in Gases, Am. Chem. Soc., Balti more, Md., Dec. 1950 (unpublished). 19. Adley, F. E.: Penetration and Pressure Drop Tests on Respirator Cartridges, personal communication, Jan. 30, 1962. 20. Smith, W. J. and Surprenant, N. F.: Proper ties of Various Filtering Media for Atmos pheric Dust Sampling, presented to Am. Soc. Testing Material, Philadelphia, Pa., July 1, 1953, published as Appendix D of Media for Air Cleaning and Air-Assay Purposes, Rept. AECU 3119, USAEC, Div. of Engineering, Washington, D.C., Oct. 3, 1955. 21. Dinius, J. H. and Plummer, A. W.: Develop ment of the D.O.P. Smoke Penetration Test for Filter Materials, M.I.T.-M.R. No. 52, Mass. Inst. Technology, Cambridge, Mass., Jan. 8, 1944, 94 pp. 22. Anon.: Protective Equipment Evaluation Pro gram, Quarterly Progress Rept., Oct. 1, 1949 to Dec. 31, 1949 (declassified Mar. 1, 1956), Rept. Y-532, Carbide and Carbon Chems. Corp., Oak Ridge, Tenn., 35 pp. 23. Plummer, A. W.: Methylene Blue Penetration Tester, M.I.T.-E2, M.I.T.-M.R.-5, May 6, 1942. 24. Ellison, H. J., Jr. and Long, E. R.: TD-MR440, Sept. 23, 1942. 25. Rinehard, C. A. and Dinius, J. H.: Evaluation of the British Sodium Flame Apparatus as a Filter Tester, TD-MR-578, Feb. 26, 1943. 26. Silverman, L., Fitzgerald, J. J., Burgess, W. A., Corn, M., and Stein, F.: Respiratory Pro tective Equipment, Progress Rept. for June 1959 to April 1960, Rept. NYO 9322, Dept, of Ind. Hyg., School of Public Health, Harvard Univ., Boston, Mass., June 27, 1960, 52 pp. 27. Guyton, H. G. and Lense, F. T.: Methods for Evaluating Respiratory Protective Masks and Their Component Parts, A.M.A. Arch. Ind. Health 14:246-249, Sept. 1956. E--0651O Chapter 5 SORBENTS FOR GASES AND VAPORS L INTRODUCTION Molecules of gases and vapors, when in con tact with a solid surface at ordinary temperatures, are attracted and held to some degree to the sur face of the solid. This phenomenon is termed sorption. The solid substance is the sorbent and the gas or vapor being sorbed is the sorbate. If the molecules of the sorbate are held to the sur face by physical forces, similar to that occurring in condensation, the process is termed adsorption. If strong interaction, such as electron transfer, takes place between the sorbate and the surface of the sorbent, the phenomenon is chemisorption. However, if the sorbate does not remain on the surface, but enters into the solid and reacts chemically with it, changing the chemical nature of each, the process is called absorption. The rate at which sorption takes place varies with the sorption phenomena, hi physical adsorp tion the molecules of the sorbate are adsorbed as fast as they contact a free surface. In chemi sorption and in absorption phenomena, the rate of sorption is measurably slower than in adsorption, being controlled by the rate of chemical reaction or solution of the sorbate with the sorbent. The amount of gas or vapor sorbed may be small or large; it is a function of the physical and chemical nature of both the sorbent and the sor bate. Since sorption is primarily a surface phe nomenon, porous solids having a tremendously large surface area are potentially the most effec tive sorbents. - In air-purifying respirators, porous granular sorbents are utilized to remove the gas and vapor contaminants from the inspired air. The sorbents are dispersed in layers of varying depths in can isters and cartridges and must function under varying conditions of concentration of contaminant, flow rate, temperature, and humidity. The con taminant concentration may vary from a few parts per million (ppm) to a maximum of 2 per cent (20,000 ppm) or more. The maximum inspiratory flow may vary from 60 liters per minute (l/min), for a person performing light work, to over 200 l/min for heavy work. Under these extreme con ditions, the sorbent layer must reduce the ambient concentration of contaminant to less than 1 ppm in a period of less than 0.1 second (sec). IL SORBENT REQUIREMENTS A. Sorbent Properties Sorbents for air-purifying respirators should exhibit the following properties: (1) activity or ability to sorb the contaminant at a high rate; (2) capacity or ability to sorb appreciable quanti ties of tiie contaminant; (3) retentivity or ability to retain the sorbate once it has been sorbed; (4) hardness or ability of granules to retain their size and shape when subjected to crushing and abrasion; (5) stability or ability to retain these properties under normal conditions of storage and use. B. Bed Depth The effective utilization of the sorbent in a canister or cartridge is largely influenced by the depth of layer through which the air stream is drawn. As the initial portion of'the air stream contacts the initial layer of sorbent granules, the contaminants are partially sorbed and the concen tration is greatly reduced. This process is re peated .at each succeeding layer of granules until at some specified layer the concentration of con taminant approaches zero. Each succeeding por tion of the air stream will continue to be free of contaminant at this point, until the capacity of the initial layer is exceeded. At this time, the depth of the sorption bed is advanced slightly and traces of contaminant appear in the air stream at the _exit of the initial sorption bed. - This initial sorption bed is referred to as the ` critical bed depth' and is defined as the minimum depth of sorbent required to remove the contami nants from the air stream under specified test conditions. As the sorption bed is extended beyond the critical bed depth, the upper layers of the bed are exposed to very low concentration of the con taminant, which considerably increases the time a unit layer of sorbent remains effective. Major factors contributing to the critical bed depth are: 1. Concentration of contaminant. As the con centration is increased, a larger percentage of the molecules escape the initial layer of sorbent and penetrate to the next layers. 2. Rate of flow. At higher rates of flow, the contact or dwell time of the contaminant with the 49 E--06511 50 RESPIRATORY PROTECTIVE DEVICES MANUAL sorbent is significantly reduced, permitting some of the molecules to escape being sorbed by the initial layer of sorbent. 3. Size of granules. In a specified volume of sorbent composed of small granules, the external surface area is greater than a similar volume of large granules, which facilitates the sorption process. 4. Activity of sorbent. 5. Capacity of sorbent. m. ADSORBENTS Granular adsorbents are characterized by an extraordinarily large internal surface area which, in some materials, may approximate 1500 square meters per gram (M^/g). This massive internal area is due to a system of pores, whose diameter may vary from a few angstroms to 1,000 angstroms (A) or more. The pore size distribution (number of large pores versus small pores) may also vary widely, depending on the material and the treat ment it has been given. Many theories have been advanced regarding the nature of adsorption. For a detailed discussion of these theories, a few references are presented for review. It is generally accepted that adsorption is a surface phenomenon in which the molecules of the sorbate and the molecules of the sorbent are at tracted to each other by either physical or chemi cal forces. These forces may vary in intensity and are influenced to some extent by the electron con figuration of the molecules. Polar substances have strong attraction for each other; - hence polar gas molecules, such as ammonia, are strongly at tracted to the surface of polar sorbents, such as silica gel. Nonpolar gas or vapor molecules, such as carbon tetrachloride, may become polarized when they reach the field of force exerted by the surface of the sorbent, and the induced polariza tion attracts them to the surface. With some compounds, these attractive forces may permit adsorption to occur in thin layers only, one or several molecules thick--indicative of low capacity of the sorbent for that compound. With other compounds, whose vapors are more easily liquefied, these forces are sufficient to coalesce the molecules and condense them--indica tive of high capacity. As additional molecules are adsorbed, the strength of the forces are altered and the molecules tend to rebound or evaporate from the surface. At this threshold point, a decrease in the ac tivity and retentivity of the sorbent is initiated. In air-purifying respirators, the granules in the ef fluent zone of the sorbent layer must operate be low this threshold point; otherwise contaminant'' would appear in the effluent air stream. A. Activated Charcoal Granular activated charcoal is the most ver satile of the sorbents utilized in air-purifying respirators. Its millions of pores create an in ternal surface area ranging from 600 to 1,200 M^/g, depending on the type of carbon and the conditions of activation. Because of its wide pore size distribution, both large and small size mole cules can diffuse through the pores to its active surfaces. It is utilized primarily as an adsorbent for organic vapors, but it also exhibits significant capacity for some acid gases and vapors. More over, it can be successfully impregnated with se lected materials which enhance its capacity for certain gases or vapors, without seriously im pairing its original capacity for others. The adsorption of organic vapors by activated charcoal is primarily physical adsorption or con densation. Hence, the critical temperature and the boiling point of organic compounds serve as broad criteria for the relative capacity of activated charcoal for specific organic gases or vapors. Compounds with low boiling points are adsorbed only slightly, whereas compounds which are liquid at or near ordinary temperatures and pressure are adsorbed more readily. This is specifically applicable in a homologous series of organic com pounds, where the next higher member of the series is adsorbed more readily than the lower member. Figure 5.1 illustrates the increase in adsorption capacity of activated charcoal for a homologous series of paraffin hydrocarbons.^ The introduction of halogen atoms into an or ganic molecule usually increases the adsorbability of the resulting compound. This is illustrated in Fig. 5.2 by the comparative adsorbability of chlorine derivatives of methane. Methane is ad sorbed only very slightly, but as substituent chlorine atoms are introduced into the molecule, greater adsorption occurs. Since the adsorbability of a vapor is also a function of the nature of the molecule and its .elec tron configuration, the boiling point criterion does not apply for many organic compounds. Methyl bromide, whose boiling point is considerably low er than ethyl mercaptan, is adsorbed to a greater extent than ethyl mercaptan. The capacity for pentane is considerably higher than for ethyl mercaptan, although their boiling points are near ly the same. The retentive capacity of activated charcoal is important during long service of charcoal canisters. The retentive capacity of a sorbent is the ratio of the weight of the retained substance to the weight of the carbon. It is measured by passing clean, dry air at constant pressure and tempera ture continuously through a bed of granular carbon previously saturated with a specific gas or vapor E--06512 SORBENTS FOR GASES AND VAPORS 51 Fig. 5.1. Adsorption capacity of activated charcoal as related to boiling point of contaminant. Test con ditions: charcoal layer measur ing 65 cm2 by 11 cm; contami nant concentration of 5,000 ppm; and flow rate of 500 cm/min. Fig. 5.2. Comparative adsorption capacities of activated charcoal for chlorine derivatives of methane. Test con ditions: charcoal layer 65 cm2 by 11 cm; contaminant concentration of 5,000 ppm; flow rate of 500 cm/min; relative humidity, 50%. and continuing the air flow until the carbon ceases to decrease in weight. Water vapor, a component of inspired air, is also adsorbed by activated charcoal. However, since charcoal is a nonpolar substance, it does not have great affinity for water vapor. At relative humidities of 25 per cent or less, water vapor is adsorbed to a very limited extent. At 40 per cent or higher; the adsorption increases sharply and those portions of the surface which attract water molecules become covered with condensed water. This affects the sorption of organic vapors be cause these portions of the surface are unavailable to the organic molecules. Table 5.1 indicates the loss in adsorptive capacity of humidified charcoal for organic vapors which are only slightly soluble in water. Although charcoal adsorbs water vapor at higher humidities, its retentivity is very low, the water being readily desorbed by a stream of dry air. Charcoal also exhibits significant capacity for gases such as chlorine, bromine, and iodine. Chlorine is adsorbed to a greater extent than its boiling point would indicate. Sulfur dioxide, when TABLE 5.1 EFFECT OF ADSORBED WATER VAPOR ON CAPACITY OF CHARCOAL FOR ORGANIC VAPORS ONLY SLIGHTLY SOLUBLE IN WATERa Charcoal Equilibrated Conditions Contaminant Adsorbed, e Carbon Methyl Tetrachloride Bromide Not equilibrated 25% relative humidity 85% relative humidity 125.0 125.0 93.5 25.3 24.3 19.5 a. Test Conditions: sorbent layer measuring 65 cm2 by 11 cm; contaminant concentration of 5,000 ppm; flow rate of 500 cm/min; relative humidity 50%. -0651? 52 RESPIRATORY PROTECTIVE DEVICES MANUAL present in concentrations not exceeding 1,000 ppm, is also adsorbed satisfactorily although the capacity is not large. Activated charcoal is also effective as a catalyst or a catalyst support for certain reac tions, which results in an apparent increase in its capacity for certain sorbates. Many substances, when sorbed, become highly reactive. When chlorine and water vapor are sorbed simultane ously in charcoal, hydrochloric acid is formed. Phosgene reacts with sorbed water vapor to form hydrochloric acid and carbon dioxide. Charcoal exhibits limited capacity for many highly toxic gases and vapors, such as mercury, arsine, phosgene, ozone, ammonia, hydrogen sul fide, and cyanogen chloride. When charcoal is impregnated with selected compounds, its effec tiveness as a sorbent for these substances is greatly augmented. When impregnated with iodine, for example, its capacity for mercury vapor and hydrogen sulfide is increased tremendously. Salts of copper or cobalt improve the capacity for am monia and ozone. Copper or copper oxide are ef fective agents for phosgene. Figure 5.3 illustrates the improvement in capacity for hydrogen cyanide and hydrogen sulfide with four different impregnated charcoals. It also indicates that the capacity for chlorine is only slightly reduced, whereas the capacity for chloropicrin is reduced significantly in only two of the four impregnated charcoals. Although the preceding discussion demon strates the versatility of activated charcoal and its impregnations, it also indicates that the actual capacity for a specific contaminant is dependent upon many factors and that even broad generaliza tions must be interpreted only as guides to spe cific problems. B. Molecular Sieves Most molecular sieves are synthetic crystal line zeolites, which in this discussion are treated as adsorbents. They are prepared by dehydrating crystalline alkali aluminosilicates to obtain a net work of empty pores and cavities, which develop an internal surface area of 700 to 800 M^/g3. However, the cavities and pores are relatively uniform in size; that is, there is limited pore size distribution. This is in contrast to activated-char coal, which has an internal surface area of 600 to 1,200 M^/g and whose pore size varies greatly. Molecular' sieves have a high affinity for polar molecules; hence, they are excellent adsorbents for water vapor, particularly at low relative hu midities. However, at 40 per cent relative hu midity and above, the capacity of molecular sieves is less than that of silica gel. The pores of molecular sieves, which are of molecular dimension and uniform size, adsorb small molecules but not large molecules. Because of the controlled pore size, the adsorbability of organic vapors will vary with the specific type of sieve, as well as with the specific compound. As a generalization, molecular sieves exhibit less ca pacity for most organic vapors than activated charcoal, but greater capacity than silica gel. Molecular sieves exhibit a capacity for ammonia comparable to silica gel. Sulfur dioxide and hy drogen sulfide are also adsorbed to some degree. Because of their capacity for ammonia and af finity for water vapor at low partial pressures, molecular sieves have been successfully used in a universal gas mask canister. Their general use in respirators has been limited because of economic factors. HYDROGEN CYANIDE HYDROGEN SULFIDE CHLORINE CHLOROPICRIN Fig. 5.3. Adsorption capacity of four com mercially available impregnated charcoals for different contami nants. Test conditions: sorbent layer measuring 65 cm^ by 11 cm; contaminant concentration of 5,000 ppm; and flow rate of 500 cm/min. C. Activated Alumina Activated alumina is a porous aluminum oxide prepared by dehydrating alumina trihydrate. It exhibits an affinity for polar molecules and has good capacity for water vapor. However, its ca pacity for acid gases and organic vapors is lim ited. When it is impregnated with metal salts which hydrate readily, its capacity for ammonia is greatly enhanced. In contrast to other adsorbents, the hardness of the impregnated granules is low E--06514 JT I f SORBENTS FOR GASES AND VAPORS 53 & and extra precautions are required to preserve their size and shape. In air-purifying respirators, activated alumina has been utilized as a water va por adsorbent and, when impregnated with metal approved by the Bureau of Mines, in which hop calite is used as a carbon monoxide adsorbent. During the oxidation of carbon monoxide by hopcalite, heat is generated in proportion to the salts, as an ammonia adsorbent. amount of carbon monoxide being oxidized. When a mixture of 1% of carbon monoxide in air is D. Silica Gel oxidized, the temperature of the air is increased (theoretically) about 96C (205F). However, un A Silica gel is a partially dehydrated colloidal silica. In common with other adsorbents, it has a fine pore structure which develops a comparative ly large internal surface area. However, this area is considerably less than that in activated char coal. Silica gel exhibits an affinity for polar molecules and has good capacity for water vapor der practical conditions of use in canisters, the actual temperatures attained are somewhat lower. Breathing a mixture of 1% carbon monoxide in air at a rate comparable to conditions of vigorous work (32 1/min continuous flow), the effluent air temperature at the top of the canister reaches ap proximately 100C (212F), an increase of about and ammonia. Its capacity for most organic va 75C (167F) above ambient temperature. The #; pors is considerably less than that of activated charcoal, and it does not possess the versatility of activated charcoal. When it is impregnated with metal salts, the capacity for ammonia is in creased. Its use has been largely as a water vapor and ammonia adsorbent. heat has been known to "bum the paint off canis ters* and even to "unsolder the canister necks." Practically, however, the effluent air in such a condition is so hot that a wearer will not be able to stay in the atmosphere (2% or higher of carbon monoxide) and wiU retreat before either combus E. Hopcalite tion or deterioration of the canister "Sets in, as temperatures of 100C are readily obtained. Hopcalite is a porous granular mixture of manganese and copper oxides. The pore structure in the granules creates a large surface area, and IV. ABSORBENTS it exhibits the properties of an adsorbent. Hop Granular absorbents differ from adsorbents it calite has a high affinity for water vapor, organic in that the granules, although porous, do not con vapors, acid gases, and ammonia, and it exhibits tain the myriad of fine microscopic pores nor the strong oxidizing properties for some of the ad large internal surface area characteristic of ad sorbates. However, it is primarily an oxidizing sorbents. The gases and vapors diffuse from the agent, being designed to catalyze the oxidation of air stream onto the external surfaces and into the carbon monoxide to carbon dioxide at ambient pores of absorbents in a manner comparable to 3 temperatures. This is accomplished by chemi that occurring with adsorbents, but the contami sorption and catalysis. nants combine chemically with the absorbent. The It is generally accepted that hopcalite, by vir capacity and activity of the absorbent are depend tue of its chemical and physical nature, chemi ent upon the rate of reaction at the surfaces and sorbs carbon monoxide and holds it in an `acti the diffusion of the ions from the surface to the vated' condition on the surface. Oxygen molecules, interior of the mass. chemisorbed on the surface and held in an `acti Granular alkaline absorbents are generally vated' condition, react with the carbon monoxide composed of mixtures of sodium, or potassium hy to form carbon dioxide, which is immediately de droxide with lime and/or caustic silicate. They sorbed to the air stream. The `active' sites on the " are primarily utilized as acid gas absorbents. surface which are depleted in oxygen and carbon Alkaline granules are prepared either with a low monoxide immediately adsorb the required stoi caustic content (5 to 10 per cent) or a high caustic chiometric quantity of oxygen and carbon monoxide content (> 50 per cent). These granules require a from the air stream, and the carbon monoxide particular range of moisture content to attain oxidation process is repeated. In this process reasonable capacity for acid gases. hopcalite is the catalyst. Low caustic granules require a high moisture Since this process is highly selective in na content (10 to 20 per cent)- for greatest capacity ture, the surface of the hopcalite is very suscepti and, conversely, high caustic granules exhibit ble to poisoning by any adsorbates- which would greatest capacity with low moisture content (0 to occlude the active sites or react with the hop 5 per cent). In general, high caustic granules ex calite. It is therefore essential to remove all con taminants except carbon monoxide from the air hibit equal or better capacity for the more toxic acid gases and vapors. The low moisture--high stream prior to its contact with the hopcalite, if caustic absorbents are hygroscopic, while the high this activity is to be maintained. This is effective moisture--low caustic absorbents effloresce in nor ly accomplished in the Type N universal canisters mal air. These properties are used advantageously E-06515 54 RESPIRATORY PROTECTIVE DEVICES MANUAL In their respective fields of application. Figure 5.4 illustrates the influence of moisture on the capacity of each type of alkaline absorbent when exposed to representative acid gases. However, even in the simplest two-component case, no generalizations can be made regarding the service life difference between mixtures and layers of the same total quantities of ingredients. Fig. 5.4. Effect of moisture content on absorption capacity of alkaline absorbents. Test conditions: sorbent layer measuring 65 cm^ by ii cm; contaminant concen tration of 5,000 ppm; and flow rate of 500 cm/min. In addition to absorbing acid gases effectively, the high caustic absorbents also serve as water vapor absorbents. This absorbent is utilized in gas mask canisters, where highest capacity is re quired for both acid gases and water vapor. When high humidity air is encountered, the initial layers of the absorbent retain most of the moisture, thereby ensuring high capacity in the upper layers of the absorbent. V. MIXTURES AND LAYERS IN CANISTER MANUFACTURE Canister - performance depends on the ability of the sorbents to remove all or all but a few parts per million of contaminants from a rapidly moving airstream. The dynamic test conditions estab lished to evaluate performance generally make it impossible to predict performance data from static equilibrium data. Different arrangements of two or more sorbents (layers versus mixtures) in a given canister may give significantly different' service lives against a specific contaminant. A. Advantages of Different Arrangements The advantages of layers versus mixtures de pend upon specific reacting systems. For exam ple, chlorine gas is absorbed better when it passes respectively through soda lime and charcoal layers than when these layers are reversed or mixed. However, when chlorine is adsorbed by charcoal, some of the chlorine is reduced to hy drochloric acid, which is not well retained. Thus, when charcoal is the last or " exit" layer, the hy drochloric acid escapes unless absorbed by an ad ditional layer of soda lime. Phosgene, although similar to chlorine in other respects, is absorbed better by a mixture of the two component parts than by either of the layer sequences. Similar behavior is shown when ammonia is absorbed by two different kinds of chemicals: the mixture is superior to either ar rangement of layers. In the case of sulfur dioxide, there is no absorption difference between layers of soda lime and carbon or the mixture. The improvement in service life due to a pre ferred arrangement of several sorbents is not very large, typically around 15 to 30 per cent bet ter than the poorest arrangement. This magnitude of difference also is affected by normal variations in test conditions for canisters, as from low con centration and low rate of flow (5,000 ppm concen tration at 32 l/m) to high concentration and high rate of flow (20,000 ppm concentration at 64 1/m). B. Universal Canister The Type N universal gas mask is designed to provide respiratory protection against all com monly occurring gases and vapors and against dusts, mists, fogs, and smoke, provided the con taminated air contains enough oxygen to support life. The sorbents are required to be in layers and their relative position is controlled by their re activity to various contaminants (see Chapter 6, Figure 6.1). Hopcalite is the only sorbent com mercially used which is capable of oxidizing car bon monoxide to carbon dioxide.. However, it also reacts with moisture, acid gases, ammonia, and many organic vapors, each of which can poison its catalytic action toward carbon monoxide. Locating the hopcalite near the "exit" end of the canister protects it from these contaminants, since the air stream must first pass through all the other puri fying sorbents. A small layer of dryer tops the hopcalite, to protect it from moisture that may diffuse in from the top. Similar reasoning dictates E-06516 * SORBENTS FOR GASES AND VAPORS 55 * f that a highly efficient moisture sorbent must be 2. Mechanical damage may distort the body, located immediately below the hopcalite. Acid gas resulting in (a) leaks; (b) crushing granules into sorbents, which also have capacity for moisture, finer particles, which can result in higher re are generally located near the inlet end of the sistance to air flow; or (c) channeling, an area of canister. Particulate filters are located so that decreased resistance and reduced sorptive ca the incoming air stream must first penetrate them. pacity. 3. Resistance changes may indicate undue VI. DISCUSSION AND RECOMMENDATIONS CON CERNING THE USE OF SORBENTS IN CANIS TERS water adsorption, excessive gas absorption, dam age of granular structure, or a combination of these factors that result in decreased life and/or efficiency. Resistances for typical canisters as A. Moisture manufactured and upper limits at the end of effec tive life specified by the Bureau of Mines are As discussed in Sections m and IV, a change shown in Table 5.2. in the moisture content of the sorbents may im prove or adversely influence their performance. Gas mask canisters have very satisfactory shelf TABLE 5.2 life when sealed and reasonable life when attached % to a facepiece in readiness to give protection in an NOMINAL RESISTANCES OF CANISTERS ONLY emergency or in routine use. The shelf life has arbitrarily been limited to three years for canis ters completely sealed, except for the window- Upper Limit indicator universal gas mask canister. There is no definite time limit that sealed window-indicator at End of As Effective canisters may be stored. Such canisters should be inspected periodically and should be discarded Canister Manufactured, in. of HjO Life, in. of HjO when the indicator shows that moisture has pene trated the hopcalite. If the facepiece is attached to Supersize the canister with bottom seal intact, the canister Universal 1.7 3.00 must be discarded after one year of such storage. The change in canister moisture content oc curs in the following ways: Universal with filter 2.5 3.25 1. Changes in temperature and barometric pressure. Increased temperatures or decreased pressures expand the atmosphere within the can ister, and the pressure generated is relieved by Intermediate size Industrial (chest canister) 2.6 3.00 escaping through tapes, corks, or inlet and outlet ports. If sorbents are moist, a loss of moisture occurs. Conversely, lowered temperatures or in C. Use creased pressures cause ambient air (with its 1. Scheduling of replacement of canisters is moisture) to leak into the canister. If sorbents are dry, the moisture is sorbed. 2. Migration. If, through use or by design, the advisable to assure maximum usability and maxi mum protection. The factors involved are: a. Observation of recommended dates humidity of the atmosphere surrounding the gran printed on labels of canisters. ules of the sorbent in one position is higher than b. Setting up advisable limits of canister that surrounding other granules, a migration of use for each operation based on: moisture occurs in proportion to their respective abilities to sorb moisture. (1) time, (2) moisture of air, (3) concen tration of toxic gases, and (4) degree of effort used by wearer. B. Maintenance 2. Several factors affect the choice of canis ter size. They include: Maintenance of canisters is largely a matter of - moisture control, prevention of mechanical a. Where nuisance concentrations of rela tively nontoxic gases, or concentrations damage, observation of resistance changes, and scheduling of replacement. Experience has shown that: only slightly exceeding maximum allow able concentration limits of toxic gases exist, use chemical cartridges (50 to I. Moisture control is attained through storage 200 cm^). in areas which are nominally dry and in which b. Where high concentrations for short temperature variations are at a minimum. duration or emergencies are to be i E-06517 56 RESPIRATORY PROTECTIVE DEVICES MANUAL encountered, use chin style canisters (250 to 500 cm3). c. For higher concentrations up to the max imum recommended or for longer dura tion, use 1,000 to 2,000 cm3 canisters as the situation may indicate. VH. SORBENTS FOR SPECIFIC GASES AND VA PORS The earlier sections of this chapter have em phasized that the actual capacity of a sorbent for any specific contaminant is dependent upon many varied factors. Any list of sorbents for specific gases and vapors must be interpreted only as a guide to specific problems. Such a guide is the list of sorbents for the gases and vapors listed in Table 5.3. They are the gases and vapors for which threshold limit values were listed by the American Conference of Governmental Industrial Hygienists in 1961. An examination of this table shows that acti vated charcoal is the best sorbent for the majority of the gases and vapors listed. Obviously, it is TABLE 5.3 SORBENTS FOR GASES AND VAPORS INCLUDED IN ACGIH THRESHOLD LIMIT VALUES FOR 1961 This sorbent information is not necessarily based on actual tests but in many cases is .based on "educated guesses." Sorbent Code 1. Activated charcoal. 2. Soda lime. 3. Combination charcoal and soda lime. 4. Silica gel. 5. Hopcalite. 6. Treated carbon for specific chemical; example, carbon treated to absorb ammonia. 7. Special sorbents or mixtures (different manu- facturers may have different sorbents for same chemical); example, ammonia sorbent is indicated as 7a. 8. Universal canister. Substance3, Sorbent'3 Substance3 Sorbent'3 Acetaldehyde Acetic acid Acetic anhydride Acetone Acetylene tetrabromide: gas mask Acrolein: gas mask Acrylonitrile: skin, gas mask Allyl alcohol: skin Allyl chloride Allyl propyl'disulfide Ammonia Amyl acetate Amyl alcohol (isoamyl -alcohol) Aniline: skin, gas mask Arsine: gas mask Benzene (benzol) Benzyl chloride: gas mask Boron trifluoride: gas mask Bromine: gas mask Butadiene (1,3-butadiene) 2-Butanone (methyl ethyl ketone) Butyl acetate (n-butyl acetate) Butyl alcohol (n-butanol) tert. butyl alcohol Butylamine 1 1 (3) 3 (1) 1 1 1 1,3 1 1 (3) 3 7a (6) 1 1 1,7 6 (8) 1 3 (1): filter 8 3 1 1 1 1 1 1+7 Butyl cellosolve (2-butoxyethanol) p-tert. butyltoluene Carbon dioxide Carbon disulfide: skin, gas mask Carbon monoxide: gas mask Carbon tetrachloride: skin Cellosolve (2-ethoxy-ethanol) Cellosolve acetate (2-ethoxyethyl acetate) Chlorine: gas mask Chlorine dioxide: gas mask Chlorine trifluoride: gas mask, no organic sorbent Chlorobenzene (monochloro- benzene) Chloroform (trichloromethane) 1-Chloro-l-nitropropane Chloropicrin: gas mask Chloroprene (2-chloro-l,3- butadiene) Cresol (all Isomers): skin, gas mask Cyclohexane Cyclohexanol Cyclohexanone 1 1 2 1 5, 8 1 1 1 1.3, 7 1,7 `2 1 1 1 1 1 1 1 1 1 --06518 -ttaw- > -1 'f * *,**&..* ----------'-'ty; -- i iifi 1VTtiyi irr--' t-ir |~n^M-| I|*I| ni ' Til I miTfT^-------* ------------------------ .. ,. y-~.tvi 3 .J American Industrial . Table of Sorbents for Contaminants Listed in ACGIH Substance 1970 Threshold Limit Values 2-Aminoethanol, see E>. 2-Amir.opvridine Ammonia r Ammonium sulfamate American Industrial Hygiene Association and the American Conference of Governmental Industrial Hygienists Joint Committee on Respirators n-Amyl acetate jec-Amyl acetate Aniline - Skin 3 3 Introductory Statement 7. Special sorbent (manufacturers proprie Anbidine (o.g-isomers Antimony & compound ANTU (Alpha naphtht '"THE AIHA-ACGIH RESPIRATOR COMMITTEE has prepared this table of sorbents for airborne contaminants in re tary mix) 8.' Filter, for highly toxic dusts 9. Filter, for toxic dusts . Arsenic & compounds \ Arsine Azinphos-methyl -- Skin J sponse to questions from users of respirators. Notes: Barium (soluble compo; a There is an apparent mystery' about what is in a gas mask or chemical cartridge respirator (1) Where two or more sorbent code num Benzene (benzol) *- Ski Benzidine -- Skin .1i S >j a that magically purifies the inspired air. There fore, the primary purpose of this table is to serve as an educational aid to respirator users by eliminating some of the mystery about res piratory protection. The table may also be used in the laboratory to aid in selecting sor bents for gases and vapors. This printing updates the first list of sor bents that appears on pages 56 to 58 in Res piratory Protective Devices Mpnual, published by AIHA-ACGIH in 1963. yhe manual lists gases and vapors for which ACGIH assigned TLV values in 1961. This now table includes bers are listed after a substance, the sor bents are in decreasing order of prefer ence. Where a plus ( + ) sign is used, both are required. (2) Very strong oxidizing substances in low concentrations may be sorbed by acti vated or impregnated carbon; however, carbon should not be used because of a possible explosion hazard with these combinations. For respirator)' protec tion against very strong oxidizers, a selfcontained breathing apparatus should be used. p-Benzoquinone, see Qu Benzoyl peroxide Benzyl chloride Bcrvliium Biphenyl, see Diphenyl Boron oxide { Boron tribromide Boron Trifluoride Bromine Bromine pentafluoride Brornoform -- Skin Butadiene (1,3-butadien Butanethiol, see Butyl mt all contaminants in the 197Q TLV list. As emphasized in the Manual, the actual capac List of Contaminants with Sorbent Code 2-Bufanone 2-Butoxy ethanol (Butyl ity of a sorbent for any specific contaminant Substance Sorbent Butyl acetate (rr-Butyl in is dependent upon many factors. Any list of sorbents must therefore be interpreted only as a guide. Users should refer to respirator man ufacturers for information on specific respi rators for specific contaminants. \ Sorbent Code. Abate Acetaldehyde Acetic acid Acetic anhydride Acetone Acetonitrile Acetylene dichloride, see 1,2- 9 1 1,2 3,2 1 .'3,1 n-Butyl acetate '. -~ r-Butyl acetate " terl-Butyl acetate ,| Butyl alcohol o rec-Butyl alcohol . - y.'Nl fcrt-Butyl alcohol . Butylamine -- Skin ' % 1." Activated carbon Dicloroethylene '1 terf-Butvl chromate (as-1 2. Soda lime 3. Combination of activated.carbon and so da lime 4. Silica gel 5. Hopcalite (with drier) , Acetylene tetrabromide Acrolein Acrylamide - Skin Acrylonitrile - Skin Aldrin - Skin Allyl alcohol - Skin 1 1 ' 1,6 3,1 84-1 1 n-Butyl glycidyl ether-;(E Butyl mercaptan p-fert-Butyltoluene Cadmium (metal dust an Cadmium oxide fume . Calcium arsenate ' 6. Impregnated carbon; example, carbon Allyl chloride - 1,3 Calcium oxide treated with metalic salt to absorb am Allyl glycidyl ether (AGE) . 1 Camphor monia Allyl propyl disulfide 3 Carbaryl (Sevin) 404 E-0651*: American Industrial Hygiene Association Journal 405 d in ACGIH Substance Sorbent Substance Sorbent 2*Aminoethanol, see Ethanolainine Carbon black 9 2-Aininopyridine 1,7 Carbon dioxide 2 Ammonia 7.6,4 Carbon disulfide - Skin 1 Ammonium sulfamate (Ammate) 9 Carbon monoxide 5 e of Governmental n-Amyl acetate 1 Carbon tetrachloride - Skin I j* jec-Amvl acetate Aniline - Skin Anisidine (o,p-isomers) - Skin Antimony & compounds (as Sb) 1 1,7 9+1 9 Chlordane -- Skin Chlorinated camphene - Skin Chlorinated diphenyl oxide Chlorine 9+1 1 1 3,6 nanufacturers proprie- ANTU (Alpha naphthyl thiourea) Arsenic & compounds (as As) 9+1 Chlorine dioxide 6+9 Chlorine trifluoride 2,7 2,7 jxic dusts sts ;ore sorbent code num* ter a substance, the sorreasing order of prefer* plus ( + ) sign is used, J. iizing substances in low nay be sorbed by actinated carbon; however, .ot be used because of a on hazard with these For respiratory protec ts strong oxidizers, a selfthing apparatus should with-Sorbemi Code.........- Arsine 6,7' Chloroacetaldehyde 1 Azinphos-methyl - Skin 9+4--Ghloracetophenone -(phenacylchloride) 1 Barium (soluble compounds) 9-P6 Chlorobenzene (monochlorobenzene) 1 Benzene (benzol) -- Skin 1 O-Chlorobenzylidene malononitrilc Benzidine -- Skin 8+1 (OCBM) 3,1 p-Benzoquinone, see Quinone Chlorobromomcthane 1 Benzoyl peroxide 9+1 2-Chloro-l ,3-butadiene, see Chloroprene Benzyl chloride 1,3 Chlorodiphenyl (42% chlorine Y~ Skin 1,3 Beryllium 8 Chlorodiphenyl (54% chlorine) - Skin 1,3 Biphenyl, see Diphenyl l-Chloro-2,3-epoxvpropanc, see Boron oxide 9 Epichlorohydrin Boron tribromide 5+3 2-Chloroethanol, see Ethylene chlorohydrin Boron Trifiuoride Bromine _ 5+-3 Chloroethylene, see Vinyl chloride 3 Chloroform (trichloromethane) 1 Bromine pcn'tatluoride " --2,7 _l-Chloro-l-nitropropane 1 Bromoform - Skin 1 Chloropicrin ~1 Butadiene (1,3-butadiene) 1 Chloroprene (2-chloro-l, 3-butadiene) Butanethiol, see Butyl mercaptan -- Skin l 2-Butanone 1 Chromic acid and chromates (as Cr03) 8+2 -2-Butoxy ethanol- (But)*! cellosolve) -Skin-1 .....CiTMn!ium> s?*ible ^romj.c or chromous ,-see 1,2tide (AGE) le Sorbent 9 1 1,2 3,2 1 3,1 1 1 1 1,6 3,1 8+1 1 1,3 1 3 -Buty-l acetate (n-B- utyl acetate) H-Butyl acetate sec-Butyl acetate fcrt-Butyl acetate Butyl alcohol rer-Butyl alcohol ferf-Butyl alcohol Butylamine -- Skin - tert-Butyl chromate (as CrOs) -- Skin n-Butyl glycidyl ether (BGE) Butyl mercaptan p-tcrf-Butyltoluene 1 1 1 1 1 1 1 7,6,4 8 1 1 1 Cadmium (metal dust and soluble salts) 9,6 Cadmium oxide fume 8 Calcium arsenate ` 9 Calcium oxide 9 Camphor 9+1 Carbaryl (Sevin) 9+1 salts as Cr ......................---9- Metal & insol. salts ~----- 9 Coal tar pitch volatiles (benzene soluble fraction) anthracene, BaP, phenanthrene, acridine, chrysene, pyridine) 9+1 Cobalt, metal fume &dust 8 Copper fume 8 Dusts and mists - _ 9 Cotton dust (raw) 9 Crag herbicide Cresol (all isomers) -- Skin Crotonaldehydc Cumene - Skin Cyanide (as CN) -- Skin 9+1 1 1. 1 9+2 Cyanogen 3 Cyclohexane * 1 Cycloliexanol 1 Cyclohexanone - 1 E-06520 ^titter 406 June, 1971 Substance Sorbent Substance Sorbent Cv**clohexene Cyclopentadiene 1 1 2,4-D 9+1 DDT-Skin 9+ 1 DDVP - Skin 9+1 Decarborane - Skin 9+7 Demeton -- Skin 8+1 Diaceton alcohol (4-methyl-2-pentanone) 1 1.2-Diaminoethane (Diazomethane), see Ethylenediamine Diborane 1.2-Dibromoethane (ethylene dibromide) - Skin Dibutyl phosphate Dibu tylphthalate Dichloroacetylene" ' 1 8+1 1 3,7 o-Dichlorobenzene ': 1 Dimelhylformamide - Skin 1 2,6-Dimethylheptanone, see Diisobutyl ketone 1.1-Dimethylhydrazine -- Skin 7,6,4 Dimethylphthalate 1 Dimethylsulfate - Skin 1,3 Dinitrobenzene (all isomers) - Skin 9+3 Dini tro-o-cresol -- Skin 9+3 Dinitrotoluene - Skin 9+3 Dioxane (diethylene dioxide) - Skin 1 Diphenyl 1 Diphenyl amine 9+1,7 Diphenylmethane diisocyanate, see methylene bisphenyl isocyanate (MDI) Dipropylene glycol methylether - Skin 1 Di-rec-octyl phthalate (Di-2ethylhexylphthalate) 1+8,9 p-Dichlorobenzene Dichlorodifluoromethane 1.3-Dichloro-5-dirnethyl hydantoin 1.1-Dichloroethane 1.2-Dichloroethanc ' 1 -2-Dichloroethylene Dichloroethyl ether - Skin Dichloromethane, see Methylene chloride Dichloromonofluoromethane 1.1-Dichloro-l-nitroe thane 1.2-Dichloropropane, see Propylenedich- loride Dichlorotetrafluoroethane | 1 Dieldrin -- Skin 9+1 Diethylamine 7,6,4 Diethylamino ethanol - Skin 7 Diethylene triamine - Skin 7,6,4 Diethylether, see Ethyl ether Diflurodibromomethane ( Diglycidyl ether (DGE) Dihydroxybenzene, see Hydroquinone Diisobutyl ketone 11 Diisopropylamine - Skin 7,6,4. Diphenyl amine 9+7 Dimethoxymethane, see Methylal Dimethyl acetamide -- Skin 1 Dimethylamine 7,6,4 Dimethylaminobenzene, see Xylidene Dimethylaniline (N-dimethylaniline) - Skin 7 Endosulfan (Thiodan) Endrin - Skin Epichlorohydrin - Skin EPN - Skin 8+1 8+1 1 9+1 1.2-Expoxypropanc, see Propylene-oxide 2.3-Epoxy-1-propanol, sec Glycidol Ethanethiol, see Ethylmercaptan Ethanolamine 2-Ethoxycthanol - Skin 7,6,4 1 2-Ethoxyethylacetatc (Cellosolve acetate) - Skin 1 Ethyl acetate Ethyl acrylate -- Skin 1 1 Ethyl alcohol (Ethanol) 1 Ethylamine 7,6,4 Ethyl iec-amyl ketone (5-methyl-3- heptanone) 1 Ethyl benzene Ethyl bromide f 1 Ethyl butyl ketone (3-Heptanone) 1 Ethyl chloride 1 Ethyl ether Ethyl formate Ethyl mercaptan 1. : - i' -l Ethyl silicate Ethylene chlorohydrin -- Skin :i " i" Ethylenediamine 7,6,4 Ethylene dibromide, see 1,2-Dibromoethane Dimethylbenzene, see Xylene 1 Ethylene dichloride, see 1,2-Dichloroethane Dimethyl-1,2-dibromo-2, 2-dichloroethyl phosphate, (Dibrom) 9+1 Ethylene glycol dinitrate and/or Nitroglycerin - Skin 1 American Industrial 1 : Substance Ethylene glycol monon see Methyl cellosolve Ethylene imine -- Skin Ethylene oxide Ethylidine chloride, sec N-Ethylmorpholine - S Ferbam Ferrovanadium dust ' Fluoride (as F) Fluorine Fiuorotrichloromethan Formaldehyde Formic acid Furfural-Skin J Furfuryl alcohol Gasoline Glycidol (2,3-Epoxy-l Glycol monoethylether. Guthion, see Azinphosi Hafnium Heptachlor-- Skin - Heptane (n-heptane) Hexachloroethane - Si Hexachloronapthalene Hexane (n-hexane) 2-Hexanone Hexone rcc-Hexyl acetate Hydrazine -- Skin Hydrogen bromide Hydrogen chloride Hydrogen cyanide - SI Hydrogen fluoride Hydrogen peroxide, 9< Hydrogen selenide Hydrogen sulfide - Hydroquinone Indene Indium and compoun . ^Iodine ,Tron oxide fume Iron salts, soluble, as F Isoamyl acetate ^Isoamyl ^alcohol - Isobutyl acetate - Isobutyl' alcohol Isophorone Isopropyl acetate Isopropyl alcohol. Isopropylamine "06521 > 4. \ June, 1971 Sorbent Skin e, see Diisobutyl 1 - Skin 7,6,4 1 1,3 somers) - Skin 9+3 1 9+3 9+3 dioxide) - Skin .1 1 9+1, 7 socyanatc, see methylene .e (MDI) lethylether - Skin 1 a (Di-2- e) 1+8,9 n) ' 8+1 8+1 tin 1 9+1 see Propylene-oxide >1, see Glycidol vlmercaptan 7,6,4 kin 1 : (Cellosolve acetate) 1 1 n1 anol) 1 7,6,4 ne*(5-methyl-3- 1 1 1 (3-Heptanone) 1 1 1 drin - Skin 1 7,6,4 e, see 1,2-Dibromoethane 2, see 1,2-Dichloroethane titrate and/or Skin - 1 American Industrial Hygiene Association Journal I 407 Substance Sorbent Substance Sorbent Ethylene glycol monomethylether acetate, Isopropylether 1 see Methyl cellosolve acetate Isopropyl glycidyl ether (IGE) 1 Ethylene imine -- Skin 7,6,4 Ketene '1 Ethylene oxide 1 Ethylidine chloride, see 1,1-Dichloroethanc N-Etbylmorpholine - Skin 1 Ferbani 9+3 Ferrovanadium dust 9 Fluoride (as F) 9+3 Lead Lead arsenate , Lindane - Skin Lithium hydride L. P. G. (Liquifiedpetroleum gas) 9 8 9 8 1 Fluorine 3,2 Magnesium oxide fume 9 Fluorotrichloromethane 1 Malathion -- Skin 9+1 Formaldehyde 1 Maleic anhydride 9+3 Formic acid 1 Manganese 9 Furfural --Skin 1 Mercury - Skin 6,7 Furfuryl alcohol 1 Mercury (organic compounds) Skin 8+6,7 Gasoline 1 Mesityl oxide 1 Glycidol (2,3-Epoxy-1-propanol) 1 Methanethiol, see Merhyl mercaptan Glycol monoethylether, see 2-Ethoxyethanol Mcthoxychlo| 9+1 Guthion, see Azinphosmcthyl 2-Methoxyeti^anol, see Methyl cellosolve Hafnium 9 Methyl acetate 1 Heptachlor--Skin 9 Methyl acetylene (propyne) 1 Heptane (n-heptane) 1 Methyl acet/lenc-propadiene mixture Hexachloroethane - Skin 1 (MAPP) 1 Hexachloronapthalene - Skin 9+1 Methyl acrylate-Skin 1 Hexane (n-hexanc) 1 Methylal (dimethoxymethane) 1 2-Hexanone 1 Methyl alcohol (methanol) 1 Hexone 1 Methylamine 7,6,4 j<?c-Hexyl acetate 1 Methyl amyl alcohol, see Methyl isobutyl Hydrazine - Skin 7,6,4 carbinol Hydrogen bromide 2,3+9 Methyl isoamyl ketone 1 Hydrogen chloride 2,3+9 Methyl n-amyl ketone (2-Heptanone) 1 Hydrogen cyanide - Skin 2,7 Methyl bromide --Skin 1 Hydrogen fluoride 2,3,7 Methyl butyl ketone, see 2-Hexanone Hydrogen peroxide, 90% 2,7 Methyl cellosolve - Skin .1 Hydrogen selenide 6 Methyl cellosolve acetate - Skin 1 Hydrogen sulfide 3,6 Methyl chloride 1 Hydroquinone 9 + 1 Methyl chloroform 1 Indene 1 Methylcyclohexane 1 Indium and compounds, as In - 8 Methylcyclohexanol 1 Iodine 9+1 o-Methylcyclohexanone - Skin 1 Iron oxide fume 9 Methyl ethyl ketone (MEK), Iron salts, soluble, as Fe 9 see 2-Butanone 1 Isoamyl acetate 1 Methyl formate - lv Isoamyl ^alcohol 1 Methyl iodide --Skin .1 Isobutyl acetate 1 Methyl isobutyl carbinol --Skin ` 1,. Isobutyl alcohol 1 Methyl isobutyl ketone, see Hexone Isophorone 1 Methyl isocyanate--Skin ,1 Isopropyl acetate 1 Methyl mercaptan 1 Isopropyl alcohol 1 Methyl methacrylate 1 Isopropylamine 7,6,4 Methyl propyl ketone, see 2-Pentanone --06522 W*irri liflBiriiiiHV> 11, 408 June, 1971 American Inc ,1 Substance Sorbent Substance Sorbent Substance A Methyl silicate 1 Phenol -- Skin I Methyl styrene I p-Phenylenediamine - Skin 7 Methylene bisphenyl isocyanate (MDI) 8+1 Phenylether (vapor) 1 Methylene chloride (Dichloromethane) 1 . Phenylether-biphenyl mixture (vapor) 1 Molybdenum (soluble compounds) (insoluble compounds) 9 Phenylethylene, see Styrene 9 Phenyl glycidyl ether (PGE) 1 Sulfur hexaflu Sulfuric acid Sulfur monoch Sulfur pentafli: Sulfuryl fluorid Systox, see Den Monomethyl aniline - Skin Monomethyl hydrazine - Skin 1.7 Phenylhydrazine - Skin 7,6,4 Phosdrin (Mevinphos) - Skin 7,6,4 8+1 2,4,5-T Tantalum Morpholine - Skin 1 Phosgene (Carbonyl chloride) 3,6 TEDP-Skin Naphtha (coal tar) . 1 Phosphine 6 Teflon deconqx Naphthalene /S-Naphthylamine 1 Phosphoric acid 7,6,4 Phosphorus (yellow) 9+1 8+2 Tellurium Tellurium hexa Nickel carbonyl 3+5 Phosphorus pentachloride 9+3 TEPP - Skin ' Nickel, metal and soluble compounds 9 Phosphorus pentasufide 9+3 Terphenyls Nicotine - Skin 1 Phosphorus trichloride 9+3 1.1.1.2-Tetrachl- Nitric acid-.__ 2,3 Phthalic anhydride 3 i,l,2^.-Xetmchli Nitric oxide ________________ _____---------^^3 ---Picric- acid--Skin -- /-Nitroaniline - Skin 1 Pival (2-Pivalyl-l,3-indandione) Nitrobenzene - Skin 1 Plattnuin (soluble salts) "8+3' 8 8 1.1.2.2-Tetrachl Tetrachloroethy Tetrachlorometl p-Nitro-chlorobenzene - Skin 1 Polytetrafluoroethylene. decomposition Tetrachloronapl Nitroethane Nitrogen dioxide Nitrogen' trifluoride Nitroglycerin - Skin Nitromethane 1-Nitropropane __ 1 products _ 2,7 - Propane .. ... - ---2.7 /3-Propiolactone i- Propargyl alcohol - Skin 1 n-Propyl acetate 1 Propyl alcohol ,, 8+3 Tetraethyl lead 1 1 Tetrahydrofuran 1 Tctramethyl lea< 1j -- Skin '1 j Tetrainethyl suci 1 Tetranitromethai 2-Nitropropane 1 ?i-Propyl nitrate 1,7 ; Tetryl (2,4,6-Tri. N-Nitrosodimethylamine (Dimethyl- Propylene dichloride 1 methylnitramir nitrosoamine) -- Skin Nitrotoluene -- Skin 7,6,4 Propylene imine-Skin 1 Propylene oxide 1 Thallium (solubl. 1 Thiram Nitrotrichloromethane, sec Ghloropicrin Propyne, see Methylacetylene Tin (inorganic ct '--1 J Octachloronaphthalene - Skin Octane Oil mist (mineral) Osmium tetroxide Oxallic acid------------------; ' Oxygen difluoride Ozone Paraquat - Skin j Pyrethrum 9 SnH, and SnO. j Pyridme *- 1 j Tin (organic emp 9+1 Quinone 1 Titanium dioxide \ \ 8 9+3 3.6 7 9-j-7 _RDXjt Skin------------ i------------- ---------Rhodium, metal fume and dusts, Soluble salts Ronnel ------ ft------ ----- Toluene (toluol) 8 Toluene-2,4-diisoc 8 o-Toluidine -- Skin 9+1 1 Toxaphene, see C Rotenone (commercial) 9+1 -*I.i**tv Parathion-Skin Pentaborane 8+1 ' Selenium compounds (as Se) 7,1 Selenium hexafluoride 8 3 Pentachloronaphthalene - Skin 9+1 Silver, metal and soluble compounds 8 Pentachlorophenol - Skin 9+1 Sodium fluroacetate (1080)-Skin 8 Pentane --3 2-Pentanone 1 Sodium hydroxide 1 Stibine 9 6 Perchloroethylene 1 Stoddard solvent 1 Perchloromethyl mercaptan 1 Strychnine 8 Perchloryl fluoride 2.7 Styrene monomer (Phenylethylene) 1 Petroleum- distillates (Naphtha) 1 Sulfur dioxide 2 i E-06523 '3 .* - . a. June, 1971 Sorbent : (vapor) 1 7 1 1 1 ) ae) ^position 1 7,6,4 8+1 3.6 6 9+1 8+2 9+3 9+3 9+3 3 8+3 8 8 8+3' 1 1 1 1 1 1.7 1 1 1 tSy ounds ikin me) 9 1 1 8 8 8 9+1 9+1 8 3 8 8 9 6 ,,1 8 1 2 American Industrial Hygiene Association Journal 409 Substance Sorbent Substance Sorbent Sulfur hexafluoride Sulfuric acid Sulfur monochloride Sulfur pentafluoride Sulfuryl fluoride Systox, see Demeton 3 2 9+3 3 7,3 2,4,5-T 9 Tantalum 9 TEDP-Skin 8+1 Teflon decomposition products 8+3 Tellurium .8 Tellurium hexafluoride 3 TEPP-Skin 8 Terphenyls 1- 1.1.1.2-Tetrachloro-2,2-difluoroethane 1 1.1.2.2-Tetrachloro-l ,2-difluoroethane 1 1.1.2.2-Tetrachloroethane-Skin 1 Tetrachloroethylene, see Perchloroethylene Tetrachloromethane, see Carbon tetrachloride Tetrachloronaphthalene - Skin 9+1 Tetraethyl lead (as Pb) -- Skin 8+1 Tetrahydnofuran 1 Tetramethyl lead (TML) (as Pb) -- Skin 8+1 Tetramethyl succinonitrile - Skin 1 Tetranitromethane 3 Tetryl (2,4,6-Trinitrophenyl- methylnitramine) - Skin 9+3 Thallium (soluble compounds) - Skin 8 Thiram 9 +1 Tin (inorganic compounds, except SnH< and Sn02) 9 Tin (organic empds) 8+1 Titanium dioxide 9 Toluene (toluol) 1 Toluene-2,4-diisocyanate (TD1) .9+1 o-Toluidine -- Skin 1 Toxaphene, see Chlorinated camphene Tributyl phosphate 9+3 1,1,1-Trichloroethane, see Methyl chloroform 1.1.2-Trichloroethane - Skin Trichloroethylene Trichloromethaney see Chloroform 1 1 Trichloronaphthalene - Skin 9+1 1.2.3-Trichloropropane 1 1,1,2-Trichloro-1,2,2-trifluoroethane Triethylamine Trifluoromonobromomethane 1 7,6,4 1 Trimethyl benzene 1 2.4.6-Trinitrophenol, see picric acid 2.4.6-Trinitrophenylmethylnitramine, see Tetryl Trinitrotoluene - Skin Triorthocresyl phosphate 9+1 8+3 Triphenyl phosphate 9+3 Tungsten & compoiihds, as IV Soluble Insoluble ). 9 9 Turpentine (i 1 Uranium (natural) ^soluble & insoluble compounds as U ' 8 Vanadium (VtOs dust) (VgOs fume) Vinyl benzene, see Styrene 8 8 Vinyl chloride * Vinylcyanide, see Acrylonitrile Vinyl toluene Warfarin Xylene (Xylol) Xylidine - Skin Yttrium _, ___ Zinc chloride fume Zinc oxide fume Zirconium compounds (as Zr) .1 I 9 9 9 9 Received February 15, 1971 p u f ; U' j -- ' SORBENTS FOR GASES AND VAPORS TABLE 5.3--continued 57 Substance^ Cyclohexene Decaborane: skin, gas mask Diacetone alcohol (4-hydroxy-4- methyl -2 -pentanon e) Diborane: gas mask o-Dichlorobenzene p-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane (ethylene dichloride) 1,2-Dichloroethylene Dichloroethyl ether Dichloromonofluoromethane 1,1-Dichloro-1 -nitroethane Dichlorotetrafluoroethane Diethylamine: gas mask Difluorodibromom ethane Diisobutyl ketone Dimethylaniline (N,N-dimethyl- aniline): skin Dimethylformam ide l,l-Dimethylhydrazinec: skin, gas mask, special fill Dimethylsulfate: skin, gas mask Dipropylene glycol methyl ether Dioxane (diethylene dioxide) Ethyl acetate Ethyl acrylate: skin Ethyl alcohol (ethanol) Ethylamine: gas mask Ethyl benzene Ethyl bromide Ethyl chloride Ethyl ether Ethyl formate Ethyl silicate Ethylene chlorohydrin: skin, gas mask Ethylenediamine: gas mask Ethylene dibromide (1,2-dibromo- ethane) Ethylene imine: skin, gas mask Ethylene oxidec Fluorine0: gas mask Sorbent'3 1 4: filter 1 5, 8 1 1 1 1 1 1 1 1 3 1 1,7 1 1 1 3, 8 4+6 1,3 1 1 1 1 1 1,7 1 1 1 1 1 1 1 1,7 1 1,7 1 3, 8 Substancea Fluorotrichloromethane Formaldehyde: gas mask Furfural: gas mask Furfuryl alcohol Gasoline Heptane (n-heptane) Hexane (n-hexane) Hexanone (methyl butyl ketone) Hexone (methyl isobutyl ketone) Hydrazine0: skin, gas mask Hydrogen bromide: gas mask Hydrogen chloride: gas mask Hydrogen cyanide: skin, gas mask Hydrogen fluoride: gas mask Hydrogen peroxide, 90 per cent: gas mask Hydrogen selenide: gas mask Hydrogen sulfide: gas mask Iodine: gas mask Isophorane Isopropylamine: gas mask Mesityl oxide Methyl acetate Methyl acetylene Methyl acrylate: skin Methylal (dimethoxymethane) Methyl alcohol (methanol) Methyl bromide: skin, gas mask Methyl cellosolve (2-methoxy- ethanol) Methyl cellosolve acetate Methyl chloride: gas mask Methyl chloroform (1,1,1-tri- chloroethane) Methylcyclohexane Methylcyclohexanol Methylcyclohexanone Methyl formate Methyl isobutyl carbinol (methyl amyl alcohol) a-Methyl styrene Methylene chloride (dichloro- methane) Monomethyl aniline: skin, gas mask Sorbent'3 1 1 1 1 1 1 1 1 1 4, 7a 2, 3: filter 2, 3: filter 7 2,7 3: filter for mist 6, 8 3, 6 1: filter 1 1+7 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1+7 a. The notation " gas mask* after an entry means that a gas mask only should be used and that a chemical cartridge respirator should not be used regardless of concentration or length of exposure. The nota tion " skin" indicates that the liquid compound can penetrate the skin to cause systemic effects. b. Sorbents listed in parentheses are second choices; where parentheses are not used, sorbents are equally good. The notation "filter" indicates that filter is needed with the sorbent. c. The sorbent recommended is for low to medium concentrations of the substance. For respiratory pro tection against high concentrations such as would occur after a spill, a self-contained breathing ap paratus should be used. E--06525 58 RESPIRATORY PROTECTIVE DEVICES MANUAL TABLE 5.3--continued Substance4 . Sorbent*3 Substance4 Naphtha (coal tar) Naphtha (petroleum) Nickel carbonyl: gas mask Nitric acidc: gas mask p-Nitroaniline: skin, gas mask Nitrobenzene: skin, gas mask Nitroethane Nitrogen dioxide: gas mask Nitroglycerin: gas mask Nitromethane: gas mask 2-Nitropropane Nitrotoluene: skin Octane: gas mask Ozone Pentane Pentanone (methyl propyl ketone) Perchloroethylene (tetrachloro- ethylene) Phenol: skin, gas mask Phenylhydrazine: skin, gas mask Phosgene (carbonyl chloride): gas mask Phosphine: gas mask Phosphorus trichloride: gas mask Propyl acetate Propyl alcohol (isopropyl alcohol) Propyl ether (isopropyl ether) Propylene dichloride (1,2- dichloropropane) Propylene imine: skin Propylene oxide Pyridine Quinone: gas mask Stibine: gas mask Stoddard solvent Styrene monomer (phenylethylene) Sulfur dioxide Sulfur, hexafluoride: gas mask Sulfur monochloride: gas mask Sulfur pentafluoride: gas mask 1,1,2,2-Tetrachloroethane: skin, gas mask Tetrahydrofuran Tetranitromethane: gas mask 1 1 5: filter 3, 8 1 1 1 8 1 1 1 1 1 6 1 1 1 1 1,7 3, 6 6(8) 3: filter 1 1 1 1 1 1 1 1: filter 6(8) 1 1 2 3 3: filter 8, 3 1 1 3 Toluene (toluol) o-Toluidine: skin, gas mask Tolylene-2,4-diisocyanate: gas mask Trichloroethylene Triethylamine Trifluoromonobromomethane Turpentine Vinyl chloride (chloroethylene) Vinyl toluene Xylene (xylol) Xylidine: skin, gas mask Tentative Values Acetonitrile: gas mask Allyl glycidyl ether (AGE) tert. butyl chromate (as CrOj) n-Butyl glycidyl ether (BGE) Butyl mercaptan Chloroacetaldehyde: gas mask Chlorobromomethane Diglycidyl ether (DGE) Dimethyl acetamide Ethanol amine: gas mask Ethyl mercaptan Glycidol sec-Hexyl acetate Isopropyl glycidyl ether (IGE) Ketene: gas mask Methyl mercaptan 1-Nitropropane Pentaborane: gas mask Perchloromethyl mercaptan: gas mask Phenyl glycidyl ether (PGE) n-Propyl nitrate0 Teflon decomposition products (as F): gas mask 1,2,3-Trichloropropane l,l,2-Trichloro-l,2,2-trifluoro- ethane Triorthocresyl phosphate Triphenyl phosphate Sorbent*3 1 1 1 1 1 1 1 1 1 1 1 1,3 1 6(3) 1 1 1 1,3 1 1 1+7 1 1 1 1 1 1 1,3 1 1 1 1 3: filter 1 1 3: filter 3: filter a. The notation " gas mask" after an entry means that a gas mask only should be used and that a chemical cartridge respirator should not be used regardless of concentration or length of exposure. The nota tion "skin" indicates that the liquid compound can penetrate the skin to cause systemic effects. b. Sorbents listed in parentheses are second choices; where parentheses are not used, sorbents are equally good. The notation "filter" indicates that filter is needed with the sorbent. c. The sorbent recommended is for low to medium concentrations of the substance. For respiratory pro tection against high concentrations such as would occur after a spill, a self-contained breathing ap paratus should be used. H-0652A SORBENTS FOR GASES AND VAPORS 59 beyond the scope of this manual to identify the many types of impregnants used on charcoal by the manufacturer or their special sorbents. These are closely guarded trade secrets. Where these are the indicated sorbents, consult the respirator manufacturers. To prevent the misuse of the sorbents listed in Table 5.3, gases and vapors for which chemical cartridge respirators (half mask facepiece device with one or two small cartridges attached) should not be used for respiratory protection regardless of concentration or time of exposure are indicated. It has been stated in Chapter 6, Section II, B, that the organic vapor cartridge is satisfactory for exposure to organic vapors in concentrations up to 0.1 per cent (1,000 ppm). It is well known, al though not always practiced, that chemical car tridge respirators are nonemergency respiratory protective devices and should never be used in immediately dangerous atmospheres. The sorbents listed in Table 5.3 are general ly available in chemical cartridge respirators, as well as in full face masks with chin and chest canisters. Because of the small volume of sorbent used in half mask cartridges and the difficulty of obtaining a reliable gas-tight seal on the face, it is emphasized that there are many gases and va pors whose toxicity is entirely too great to chance the minimum protection afforded by chemical car tridge respirators. The following cautions apply to the chemical cartridge respirators: 1. They should not be used for exposure to toxic vapors or gases which cannot clearly be de tected by odor. Methyl bromide is an example of an odorless gas. Hydrogen sulfide, although foul smelling, paralyzes the olfactory nerves so quick ly that detection by odor is unreliable. 2. They should not be used against any gases or vapors in concentrations which are highly ir ritating to the eyes. For example, although an acid gas cartridge will afford protection against sulfur dioxide in concentrations up to 500 ppm, serious eye' irritation begins in the range of be tween 20 and 30 ppm. It is impossible to remain in an atmosphere containing 200 ppm for more than one minute without satisfactory eye protec tion. VIIL REFERENCE SOURCES The references listed have been selected as a guide for those who may desire to stady in more detail. the phenomenon of sorption of gases and vapors by solid substances, and are by no means a complete bibliography of the subject. For a discussion of the theory of sorption, .references 1 to 6, 8 and 13 are recommended. Specific sorption data on some selected systems can be found in references 3,7, and 14. The theory and application of sorbents to air purifying respi rators are briefly covered in references 11, 12, and 15. A broad and detailed coverage of the published information on solid sorbent systems is available in references 9 and 10. REFERENCES 1. Trapnell, B. M. W.: Chemisorption, Academic Press, New York, 1955. 2. Brunauer, S.: The Adsorption of Gases and Vapors, Vol. I, Physical Adsorption, Prince ton University Press, Princeton, N.J., 1943. 3. Hersh, Charles K.: Molecular Sieves, Rein hold Publishing Corp., New York, 1961. 4. Bickerman, J. J.: Surface Chemistry, Theory and Application, 2nd ed., Academic Press, New York, 1958. 5. Gregg, S. J.: Surface Chemistry of Solids, Reinhold Publishing Corp., New York, 1951. 6. Garner, W. E.: Chemisorption, Academic Press, New York, 1957. 7. Sleik, H. and Turk, A.: Air Conservation Engineering, 2nd ed., Connor Engineering Corp., Danbury, Conn., 1953. 8. Mantell, C. L.: Adsorption, McGraw-Hill Book Co., New York, 1951. 9. Deitz, V. R.: Bibliography of Solid Adsorbents, 1900-1942, Chap. I, Adsorption of Gases and Vapors on Solid Adsorbents, U.S. Dept, of Commerce, Natl. Bur. Standards, Washington, D.C. 10. Deitz, V. R.: Bibliography of Solid Adsorbents, 1943-1953, Chap. I, Adsorption of Gases and Vapors on Solid Adsorbents, U.S. Dept, of Commerce, Natl. Bur. Standards, Washington. D.C., 1956. 11. Mecklenburg, W.: Layer Filtration, A Con tribution to the Theory of Gas Masks, Kolloid-Z. 52, 88-103, 1930. 12. Klotz, Irving M.: Factors in Canister Design and Tube Testing: Critical Bed Depth and the Nature of Gas Flow Through Charcoal, OSRD Rept. No. 3774, Office of Scientific Research and Development, Natl. Defense Research Comm., June 13, 1944 (PB 15616). 13. Lewis, W. K., Squires, L, and Broughton, G.: Industrial Chemistry of Colloidal and Amor phous Materials, Chap. V, 69-95, The Mac millan Co., New York, 1942. 14. Emmett, P. H.: Adsorption and Pore Size Measurements on Charcoal and Whetlerites, Chem. Rev. 43 (l):69-202, Aug. 1948. 15: York, J. Louis: Gas and Vapor Adsorption, Am. Ind. Hyg. Assoc. Quart. 11:86-92, Mar. 1950. E-06527 Chapter 6 AIR-PURIFYING RESPIRATORS I. INTRODUCTION An air-purifying respirator is, as its name implies, a respirator that removes contaminants from air inhaled by the wearer. n. TYPES OF AIR-PURIFYING RESPIRATORS Air-purifying respirators may be divided into the following types: particulate-removing (me chanical filter), gas- and vapor-removing (chemi cal filter), and a combination particulate-removing and gas- and vapor-removing. C. Combination Particulate-removing and Gasand Vapor-removing Respirators Combination particulate-removing and gasand vapor-removing respirators are designed to protect against particulates, gases, and vapors in various combinations. They may be either gas masks or chemical cartridge respirators. m. DESCRIPTION AND PRINCIPLES OF OPERA TION A. Particulate-removing Respirator A. Particulate-removing Respirators Particulate-removing respirators are de signed to protect the wearer against the inhalation of particulate matter in the ambient atmosphere. They may be designed to protect against a single type of particulate, such as pneumoconiosis-pro ducing and nuisance dusts, toxic dusts, metal fumes, or mists, or against various combinations of these types. B. Gas- and Vapor-removing Respirators Gas- and vapor-removing respirators are de signed to protect the wearer against the inhalation of gases or vapors in the ambient atmosphere. They are designated as gas masks, chemical cartridge respirators (nonemergency gas respi rators), and self-rescue respirators. They may be designed to protect against a single gas such as chlorine; a single type of gas, such as acid gases; or a combination of types of gases, such as acid gases and organic vapors. Gas masks are for protection against relative ly high concentrations (up to 1 to 3 per cent) of gases and vapors (1 per cent for chlorine, 3 per cent for ammonia, and 2 per cent for all other gases and vapors). Chemical cartridge respirators are for pro tection against low concentrations (up to 0.1 per cent) of gases and vapors. Self-rescue respirators (mouthpiece type) are, as the name implies, for assisting escape from, but not entry into, intermediate concentra tions of gases and vapors on the order of 1 per cent. The carbon monoxide self-rescuer is the only one of these devices approved by the Bureau of Mines at this time. A particulate-removing respirator consists of a facepiece (either full or half mask) and a me chanical filter. The facepiece has an exhalation valve through which the air exhaled by the wearer passes to the ambient atmosphere. It is desirable that it be equipped with an inhalation valve that closes during exhalation and prevents the expired air from en tering the filter. The facepiece is held securely on the wearer's face by a head harness, in the case of a full facepiece, or by headbands, in the case of a half mask. A knitted cloth cover ("facelet") is sometimes used on the face-contacting edge of a half mask to absorb perspiration and to prevent irritation of the skin when the respirator is worn in hot places or in air containing substances such as lime. Covers should not be used on respirators for protection against fumes because these fine particles will pass through the covers and into the facepiece cavity. The filter portion of the respirator consists of a single unit, or two units in parallel, designed to remove dispersoids from air inhaled through them. The size and shape of the units depend upon the materials of which they are made and upon the type or types of particulates against which they are designed to give protection. For a complete discussion of the factors affecting filtration of particulates, see Chapter 4. At present, most filters for particulate-re moving respirators are designed to be used only once; that is, they are to be discarded after the wearer of the respirator notices an increase in the inhalation resistance. Filters for some of the older types of dispersoid respirators that are still in use are designed to be cleaned and re used. These reusable filters should be cleaned 61 --06528 62 RESPIRATORY PROTECTIVE DEVICES MANUAL mechanically according to the manufacturer's in structions, but never washed or treated with solvents. The performance requirements for particu late respirators that are approved by the Bureau of Mines are given in Chapter 9, Section II, D. B. Gas- and Vapor-removing Respirators A gas- and vapor-removing respirator con sists basically of a granule-filled container con nected to a full facepiece for the gas mask, to a half mask for the chemical cartridge respirator, or to a mouthpiece for the self-rescue respirator. The performance requirements for gas- and vapor-removing respirators that are approved by the Bureau of Mines are given in Chapter 9, Sec tion II, B and E. 1. Gas Masks The facepiece of the gas mask is the full facepiece type that covers the eyes, nose, and mouth. It should be designed so that all of the air inhaled by the wearer is drawn in over the inner surface of the eyepiece or eyepieces to minimize the formation of droplets of moisture on this surface. It has an exhalation valve through which the air exhaled by the wearer passes to the ambient at mosphere. Most gas mask facepieces have a flex ible, kink-resisting breathing tube which connects the facepiece to the gas mask canister. Some gas masks have the canister attached directly to the facepiece. The facepiece is held securely on the wearer's face by means of an adjustable head harness. The gas mask canister is a container filled with granular sorbent of the type and amount necessary to remove the gas or vapor contaminant from the inhaled air. The canister may contain a single type of granular material, a mixture of two materials, or successive layers of two or more materials, depending on the type or types of gases and vapors to be removed. A complete discussion of gas sorbents and factors concerned with their use in gas mask canister design is given in Chap ter 5. The arrangement of the granular sorbent is different for each type and make of canister. Fig ure 6.1 shows a composite cross section of a uni versal gas mask canister and indicates the func tion of the various components. It is customary to use screens to separate the adjacent layers of granules to keep them from mixing and to maintain the integrity of the layers when the canister is in use. The corrugations in the outer shell of the canister serve to prevent "channeling" of the gas along the walls of the shell. In canisters without corrugations in the outer shell, baffles are usually inserted at the periphery of the screens to prevent channeling. The granular fill of the canister is supported by a screen or perforated metal plate so arranged as to allow even distribution of the incoming gasair or vapor-air mixture. The fill is held firmly in place by a spring. The various parts within the canister, as well as the coating of the interior of the shell, should be made of materials that are not affected by either the granular sorbent or the gases that might be expected to enter the canister. A check valve or valves should be incorporated in the gas mask to allow air to pass through the canister toward the facepiece and to prevent air from the facepiece from entering the canister dur ing exhalation. Some universal gas mask canisters have built-in indicators that enable the user to deter mine the effectiveness of the canister for protec tion against carbon monoxide and give a positive indication when the canister is no longer effective against this gas. The indicators, visible through small circular windows in the front of the canis ters, contain dark blue indicating panels and light blue reference panels with which the indicating panels are compared. The indicating panels, which are sensitive to moisture, change color progres sively to that of the reference panel, as moisture is absorbed by the canister contents, and turn pink with continued use of the canister. When the color of the indicating panel approaches or matches that of the reference panel, the canister is no longer effective for protection against carbon monoxide, and should not be used, even though it has never been used or used only in fresh air. The colors of the indicator and reference panels should be com pared, when practicable, in daylight or under day light-type lamps. Light from incandescent light bulbs or battery-operated cap lamps may accen tuate the blue color of the indicator panel; there fore, canisters observed under these types of lights should be discarded when the color of the indicator panel is still somewhat darker than that of the reference panel. Window indicators in uni versal canisters do not show their service life against other gases. An auxiliary external check valve is . required for universal window-indicator gas mask canisters which have no check valves in them. All gas mask canisters have some filter ma terial above the top layer of granular fill, pri marily to keep small particles (* fines") of the fill from entering the breathing zone of the wearer. Some gas mask canisters, particularly the univer sal gas mask canisters, have special filters to re move particulates from the air entering the canis ters. This is discussed in Section m, C. The primary means of identifying a gas mask canister is a properly worded label. Canisters of E--06529 AIR-PURIFYING RESPIRATORS Anhydrous calcium chloride for protecting the hopcalite from moisture. Anhydrous calcium chloric molecular sieve ,or some the ammonia absorbents for protecting the hopcalite^ from moisture. Silica gel or porous granules impregnated with certain metallic salts. Spring Filter pad for removing smokes from ordinary fires. JL/ ; ****D?yina ^ agent `/.'.`.'i <-'J'6fylhg' og'erit' Hopcalite, an activated mixture of oxides of manganese and coppei; for promoting the conversion of carbon monoxide (CO) to carbon dioxide (C02). S' ' Filter pad for removing smokes from ordinary fires, ji/ ///ach gas absorbent/ /-rr *'/// /// / /,'// ///yk Y//(//{//((// //A w Activated charcoai._/J\\ Organic^vapor adsorbent^ n \\\\ \.'\ \ \ \ V\ \N \\ i\ 'Alkaline hydroxides with a suitable supporting medium. JSJ .Check valve. _a/For the removal of toxic smokes, a special filter is located at the bottom of some canisters, b /The acid gas and the organic vapor sorbents may be present as single or multiple layers or as a mixture. 63 Fig. 6.1. Universal gas mask canister. gas masks that have been approved by the Bureau of Mines bear a label, as discussed in Chapter 9, Section L The secondary means of identifying a gas mask canister is a color code. The Bureau of Mines and the American Standards Association (ASA) are the two recognized authorities for color coding of gas' mask canisters. The color coding specified by the Bureau of Mines is given in Schedule 14, and revisions thereto. * The ASA^ Code is listed in.Table 6.1. The gas mask canister is held securely to the wearer's body in a convenient position by means of a canister harness. Conventionally, the canister is held in front of the wearer's chest or abdomen. However, many gas masks are supplied with can ister harnesses that hold the canister on the wearer's back. The back position is preferred if the wearer must lean over the opening of a rert* Va< & *=-06530 64 RESPIRATORY PROTECTIVE DEVICES MANUAL TABLE 6.1 ASA COLOR CODE FOR GAS MASK CANISTERS Contaminants Color Assigned1 Acid gases Hydrocyanic acid gas Chlorine gas Organic vapors Cyanogen chloride gas Ammonia gas Carbon monoxide Acid gases and organic vapors Hydrocyanic acid gas and chloro- picrin vapor Hydrocyanic acid gas and cyanogen chloride gas Acid gases, organic vapors, and ammonia gas Acid gases and ammonia gas Dusts, fumes, mists, and fogs in combination with any of the above gases or vapors All of the above atmospheric con taminants White White with 1/2 in. green stripe completely around the canister near the bottom White with 1/2 in. yellow stripe completely around the canister near the bottom Black Black with 1/2 in. white stripe completely around the canister near the bottom Green Blue Yellow Yellow with 1/2 in. blue stripe completely around the canister near the bottom Yellow with 1/2 in. black stripe completely around the canister near the bottom Brown Green with 1/2 in. white stripe completely around the canister near the bottom 1/2 in. gray stripe completely around the canister near the top Red with 1/2 in. gray stripe completely around the canister near the top a. The following requirements apply to color assignment: (1) Gray shall not be assigned as the main color for a gas mask canister. (2) Canisters other than those listed in this table shall be painted orange in color. This will require the user to refer to the canister label to determine the type of protection that the canister will afford. (3) Canisters having a special filter for dusts, fumes,'mists, and fogs shall have a statement of the type and degree of protection afforded by the filter imprinted on either a label affixed to the neck end of the canister or the gray stripe which is around the canister near the top. The degree of protection shall be marked as the per cent penetration of the canister by 0.3 micron (/z) diameter DOP smoke at a flow rate of 85 l/min. [Editor's Note Re Part (3): Filter penetration stand ards based on the penetration of 0.3 m DOP have not been published. The generally acceptable limit of DOP penetration for a high efficiency filter is less than 0.05% at 85 l/min.] container, such as at the top of a grain bin under fumigation or an oil storage tank during a tank gauging operation. When the canister is worn in the front position, the bottom or inlet end of the canister could be in a high concentration of gas or vapor present in or near the container opening. If, however, the canister is worn in the back position. it is farther removed from the area of high con centration. Both types of canister harness have some provision for attaching the facepiece to a shoulder strap of the harness when the facepiece is not being worn. Each gas mask should be stored and trans ported in a sturdy case designed to protect it from E--06531 AIR-PURIFYING RESPIRATORS 65 damage and to prevent the facepiece from becom ing distorted. A properly worded label should be prominently displayed on the exterior of the case; it should state the gaseous contaminant or con taminants against which the gas mask is designed to give protection. Adequate instructions regard ing the safe use of the gas mask should be inside the case. 2. Chemical Cartridge Respirators that of a gas mask canister. Usually, the cartridge has neither a check valve for controlling the di rection of air flow nor a spring to compress the fill. The fill is contained between two screens or perforated metal plates which exert sufficient pressure on the fill to hold it in place. Suitable baffles in the cartridge prevent channeling of con taminated air. A filter pad on the effluent end of the cartridge prevents "fines* from entering the breathing zone of the wearer. The facepiece of the chemical cartridge res pirator is limited to the half mask type. This lim itation has been applied because of the possibility of a chemical cartridge respirator with a full facepiece being used as a "junior" gas mask in a high ly contaminated atmosphere, which could result in disastrous consequences to the wearer. Since this is a nonemergency respirator with a rather lim ited volume of sorbent in the gas- and vaporremoving unit, it would not be able to cope with a high concentration of contaminant. The half mask facepiece is similar to the facepiece for the par ticulate-removing respirator. In fact, several respirator manufacturers use the same facepiece for both types of respirators. For reliable chem- ~ ical cartridge respirator performance, it is es sential to have an inhalation valve to prevent the expired air from entering the sorbent. The Bureau of Mines considers an inhalation valve desirable but optional on the facepiece for the particulateremoving respirator; however, it is mandatory on the facepiece for Bureau of Mines approved chem ical cartridge respirators. A knitted cloth cover or facelet must not be used on the face-contacting edge of the facepiece of a chemical cartridge respirator because it may allow contaminated air to enter the facepiece. Some chemical cartridge respirators use only a single cartridge; others use two cartridges in parallel. For comparable performance, the total volume of sorbent in the cartridges is essentially the same in both cases. If two cartridges are to be used in parallel, their resistances to air flow should be essentially equal. If this were not so, more air would be drawn through the cartridge with the lower resistance and it would be exhausted before the other cartridge was exhausted. Thus, the- over-all life of the unmatched pair of car tridges would be less than that of a matched pair. The cartridges usually are attached directly to the facepiece assembly, and the gas-tightness of the assembly is maintained by means of suitable gas kets. In some chemical cartridge respirators the cartridges are attached to a holder carried on the wearer's back and are connected to the facepiece by a flexible breathing tube. The construction of the cartridge for a chem ical cartridge respirator is much simpler than 3. Mouthpiece Respirators Mouthpiece respirators are usually designed to be carried on the user's person whenever he is in a situation where the atmosphere may be con taminated suddenly. They are used primarily to escape from a contaminated atmosphere, not to enter one. In certain industries where low levels of contamination are encountered intentionally, they are used under careful supervision. Mouthpiece respirators, as the name implies, are equipped with a mouthpiece, which-can be placed in the wearer's mouth and gripped firmly by his teeth. An exhalation valve is incorporated in the device through which exhaled air passes to the ambient atmosphere. To prevent inhalation through the nose, a rubber-padded spring clip is furnished to close off the wearer's nostrils. There is no protection for the eyes. In some mouthpiece respirators the mouth piece is attached directly to a cartridge or small canister filled with appropriate sorption media. A neck strap may be furnished to prevent loss of the respirator in case it is accidentally knocked from the wearer's mouth. In other self-rescue respira tors the mouthpiece is connected by a flexible breathing tube to a regular gas mask canister which is held on the wearer's person by a carry ing harness. In some instances, the canister is merely carried inside the wearer's shirt with the mouthpiece hanging outside in a readily accessible position. C. Combination Particulate-removing and Gasand Vapor-removing Respirator1 1. Gas Masks Some gasmask canisters,especially universal gas mask canisters, are provided with special fil ters to remove particulate matter from the air drawn through them. These filters are usually lo cated at the inlet end of the canisters and are in addition to the aforementioned filter material at the top of each gas mask canister. These special filters may be designed to protect against the in halation of one or more types of particulate mat ter. For instance, the filter for universal gas E--06532 66 RESPIRATORY PROTECTIVE DEVICES MANUAL mask canisters must protect against the inhalation of dusts, fumes, mists, fogs, and smokes. Some canisters having filters of rather limited filtering efficiency are approved by the Bureau of Mines for "respiratory protection against the smokes from ordinary fires and limited protection against dusts, fumes, mists, and smokes." Other canis ters, with filters of much greater efficiency, are approved for "respiratory protection against toxic dusts, fumes, mists, fogs, and smokes." 2. Combination Chemical Cartridge Respira tors with Filters Some chemical cartridges are provided with filters to remove particulate matter from the air drawn through them. The filter may be an integral part of the cartridge at the inlet end, or it may be attached to the inlet end of the cartridge by means of a suitable adaptor. Filters for dusts, fumes, or mists--or combinations thereof--are tested in a manner similar to that for dispersoid respirators (see Table 9.11). Filters for paint spray respira tors are tested against particulates formed by spraying lead paint, enamel, or lacquer. The com bination of a cartridge &nd a detachable filter al lows the filter to be discarded and replaced by a fresh filter if its inhalation resistance should in crease unduly before the cartridge is exhausted against the contaminant gas or vapor. IV. LIMITATIONS AND FACTORS AFFECTING USE Several limitations that apply to air-purifying respirators must be considered as factors affect ing their use. A. Oxygen-deficient Atmospheres Air-purifying respirators offer no protection against oxygen deficient atmospheres. B. Specified Contaminants Air-purifying respirators protect only against certain specified contaminants. Gas masks will protect against only those types of gases and vapors for which they are de signed. For instance, an ammonia gas mask will protect against ammonia, but not against carbon monoxide, acid gases, or organic vapors. Unless it has a special mechanical filter, it will not pro tect against particulates. The universal gas mask is designed to protect against all gases and vapors, and at least certain types and concentrations of particulates. The same comments apply to particulate respirators, i.e., they will protect against only those types of particulates for which they are de signed. In addition, they will not protect against gases or vapors. C. Limited Concentrations Air-purifying respirators protect only against limited concentrations of contaminants. The reasons for limiting the concentrations of gas against which a gasmask canister and a chem ical cartridge should be used are discussed in Chapter 5. An important limitation in regard to the con centration of the usual industrial particulates against which a particulate respirator will give protection is the plugging action of the dispersoid as it is removed by the filter. If the concentration is excessively high, the resistance of the filter to inhalation becomes very high in a short time. Another limitation regarding concentration applies, more particularly, to extremely toxic particulates, such as beryllium dusts and radioactive dusts. Because of their high toxicity, the penetration of small quantities may be a hazard. For half mask dust respirators equipped with high efficiency fil ters, a maximum concentration of 10 times the threshold limit value (TLV) of such aerosols has been suggested in the Los Alamos Scientific Lab oratory Handbook of Radiation Monitoring. 3 D. Limited Service Lives Both gas masks and particulate respirators have limited service lives. The length of time that a gas mask canister will protect against a gas or vapor depends on several factors, namely, the nature and amount of sorbent in the canister, the concentration of the gas or vapor in the air breathed, the activity of the wearer, and his breathing characteristics. The service life of a canister for protection against carbon monoxide depends on the capacity of the sorbents in the canister to remove water vapor from air before it reaches the the hopcalite catalyst, as well as on the water vapor and other contaminant contents of the inhaled air. Hopcalite does not promote the oxidation of carbon monoxide efficiently in the presence of moisture. The service life of the filter for a particulate respirator is limited by the amount of particulate that can be retained by the filter before the re sistance to inhalation increases significantly. As explained in Chapter 4, Section IV, the filtering ef ficiency of the filter increases as it becomes loaded with particulate. E. Resistance to Breathing Both gas masks and particulate respirators offer appreciable resistance to breathing. With no limitations as to size and weight, it would be it It ' V . ft m E--06533 AIR-PURIFYING RESPIRATORS 67 possible to make gas masks and particulate res pirators that would have practically no resistance to air drawn through them. However, they would be impractically bulky and, in the case of the gas mask, heavy. The present inhalation resistance of these devices is a compromise between inhalation resistance on the one hand and bulk and weight on the other. It appears that there is more likelihood of reducing the resistance of particulate respira tors as new filter materials or methods of filter construction are developed than there is of re ducing the resistance of gas mask canisters. F. Facepiece Fit In all air-purifying respirators a negative pressure occurs inside the facepiece throughout the inhalation phase of the breathing cycle. This requires a very tight seal between the face and the face-contacting portion of the facepiece to prevent inward leakage of contaminated air. Facepiece fit is discussed in detail in Chapter 3, Section II. In spite of these limitations, air-purifying respirators have been widely accepted and, when used within their limitations, have been the main stays of respiratory protection. Readers who are interested in further infor mation on air-purifying respirators, concerning either general usage or specialized applications in particular industries, can find a number of good discussions in the literature. REFERENCES 1. Bureau of Mines: Respirator Protective Ap paratus, Tests for Permissibility, Fees, Part 13, Gas Masks, Schedule 14F, 9 pp, Apr. 23, 1955 (Code of Federal Regulations reference, 30 CFR, Part 13). 2. American Standards Association: American Standard Safety Code for Identification of Gas Mask Canisters, K13.1-1961, American Stand ards Assoc., 10 East 40th St., New York 16, N.Y. 3. Los Alamos Scientific Laboratory: General Handbook for Radiation Monitoring, LA-1835, 3d ed., compiled and edited by Dummer, Jerome E., Jr., Los Alamos Scientific Laboratory of the University of California, Los Alamos, N.M., Nov. 1958, 180 pp. 4. Pearce, S. J.: Do's and Don'ts in Using Gas Masks, Safety Maintenance, 121:10-14, Mar. 1961. 5. Pearce, S. J.: The Use of Dust Respirators in Coal Mines, Bureau of Mines Information Cir cular 7561, 1950, 6 pp. 6. Walker, W. D., Jr., Pearce, S. J., Morrow, A. E., and Berger, L. B.: Protection Against Mine Gases, Bureau of Mines Miners' Circular 35, 1954, 58 pp. 7. American Standards Association: American Standards Safety Code for Head, Eye, and Res piratory Protection, Z2.1-1959, American Standards Assoc., 10 East 40th St., New York 16, N.Y. r E--06534 Chapter 7 SUPPLIED AIR RESPIRATORS The important advantages of air-supplying respirators are simplicity of design, broad appli cation, and good protection when properly se lected, adequately supplied with respirable air, and used in the manner or for the purposes for which they are designed and approved. They are applicable without regard to the kind or physical state of contaminant. Resistance to inhalation and service life are not dependent upon plugging of particulate filters or capacity of chemical sor bents. Hose-type atmosphere-supplying respirators (supplied air respirators) make air available to the wearer through a hose connected to a supply of respirable air. They may be divided into six main subgroups: 1. Hose mask with blower 2. Hose mask without blower 3. Air line respirator 4. Abrasive blasting respirator 5. Supplied air hood 6. Supplied air suit The first four subgroups are standard term inology for protectors used by the U.S. Bureau of Mines in approval schedules* and by the American Standards Association in its code.^ Items 5 and 6 are included because of the wide usage of these devices in industry and laboratories. For addition al information on the performance requirements of the various types of supplied air respirators, see Chapter 9. I. HOSE MASKS There are two types of hose mask: the hose mask with 'blower (Type A) and the hose mask without blower (Type B). These designations con form with the classification system used by the Bureau of Mines (see Chapter 10). The Type A hose mask with blower (see Fig. 7.1) is approved by the Bureau of Mines for res piratory protection in any atmosphere, regardless of the type or concentration of the contaminant, provided that enough respirable air is supplied to the wearer by means of the blower. It consists of a full facepiece connected by a flexible breathing tube, or tubes, and a large di ameter (approximately 1 in. inside diameter) hose to a hand- or motor-operated blower, which must be operated in respirable air. Two hose lines, 'each up to 150 ft in length, may be served by the Fig. 7.1. Type A hose mask with handoperated blower. hand-operated blower, and more by a motoroperated blower. The hose is -attached to the wearer by a sturdy body harness to which a life line may be secured. The respirator is designed for use with the blower in continuous operation, and with a man in constant attendance at the blow er (see Fig. 7.2 for an example of typical use). In the event that the blower should cease to operate, the wearer can still inhale respirable air through the hose with no more effort than when wearing a gas mask. Check valves in the facepiece and breathing tube assembly prevent exhaled air from entering the hose and cause it to leave the facepiece through the exhalation valve. Each hose mask has a serviceable trunk for storage and transportation. The Type B hose mask without blower is E--06535 70 RESPIRATORY PROTECTIVE DEVICES MANUAL Fig. 7.2. Typical use of hose mask with blower. approved by the Bureau of Mines for respiratory protection in any atmosphere from which the wearer can escape without the aid of the respira^ tor. It consists of a full facepiece connected by a flexible breathing tube, or tubes, to a large di ameter (approximately 1 in. inside diameter) hose, on the inlet end of which is a filter screen and a means of anchoring it in respirable air. The wear er obtains respirable air by means of his own in spiratory effort. Check valves in the facepiece and breathing tube assembly prevent exhaled air from entering the hose and cause it to leave the facepiece through the exhalation valve. The hose is attached to the wearer by a body harness. A max imum of 75 ft of hose may be used with this respirator. Only hose masks without blowers (Type B) and those with hand-operated blowers (Type A) are approved by the U.S. Bureau of Mines. Hose masks with power-operated blowers are not included in current Bureau of Mines schedules (see Chapter 9). The choice of the proper respirator for any situation requires consideration and integration of pertinent factors, which include contamination of the air, the place, and the kind of work to be done. n. AIR LINE RESPIRATORS The air line respirator (Type C) may be used for protection in any atmosphere that is not immediately hazardous to life. It is particularly adapted to some types of jobs because it is light and may be worn for a long period of time without appreciable discomfort. For example, it is often used for spray painting, insecticide applications, welding, metalizing, and prolonged production work in hazardous areas. The air line respirator consists of a VVi** s % } 4 4 E--06536 SUPPLIED AIR RESPIRATORS 71 compressed air supply, a pressure release valve, a small diameter (approximately 3/8 to 1/2 in. diameter) compressed air hose, a quick discon nect coupling, an air flow control device designed to permit regulation of the air-flow, and either a half or full facepiece. Like the hose masks, the air line respirator is provided with a low re sistance exhalation valve. The pressure release valve setting is stated for each Bureau of Mines approval and depends upon supply system pres sures, length of hose used, and the required air flows. To a large extent these requirements are closely related to performance and safety of the respirator. There are two basic types of flow for air line respirators--the continuous flow and the demand flow. In the first type, a set amount of air is fed continuously to the facepiece. The amount is regu lated by an air control valve or special air inlet design which is not susceptible to accidental changes of the setting even when jarred. This valve and a small filter may be placed in the air line between the short length of flexible tubing leading to the facepiece and the small diameter pressure hose from th'e air source. It can be clipped to the wearer's belt or mounted on a belt j ' permanently. A slight positive pressure on the in side of the mask is always maintained to prevent inward leakage of the contaminated outside at mosphere. The continuous flow respirator, with either the half or full facepiece, is the most com Fig. 7.3. Air line respirator of the demand mon type. It is'best suited for use with air com flow type. pressor systems. When the air must be conserved, as could be the case when the supply is from a cylinder of provided or an existing one of determined safe compressed air, the demand flow respirator is quantity and quality is available. Since an air line preferred (see Fig. 7.3). The demand flow type respirator is not to be used in lethal atmos contains a demand regulator at the lower end of pheres, no life line is needed. If something does the breathing tube. A demand regulator has a go wrong with the air supply, the mask can simply i" diaphragm-actuated valve which opens upon inha- be removed and the wearer can move out of the lation, permitting air to be supplied, and closes contaminated air. Because of the trailing hose, p- upon exhalation. This permits air to flow to the the travel of the user is limited to a specified facepiece only when the wearer inhales. Such con area. servation of air'allows one man about five hours A variation of both the continuous flow and the of service from one standard high pressure demand types of air line respirator is a device cylinder of compressed air containing about 220 which has a regular and an emergency source of cubic feet of air at 1800 psi. Such service life is, air supply. The emergency source may consist of of course, related to the physical activity required a small bottle of compressed air or oxygen, or a to do the job and may vary widely. canister, attached so that in case either the sup It should be emphasized at this point that the ply of higher pressure air to the small supply hose demand flow types must always be used with a is cut off or the hose is disconnected, the change tight fitting facepiece, whereas the continuous flow over to the bottle or canister is automatic and the type may be assembled with a half mask, full face- wearer can take his time getting out of the atmos piece, or hood. Also, the demand type usually re phere. Even though air line respirators are quires a pressure regulator when a high pressure equipped with emergency bottles or canisters, air supply is used. they are not approved by the U.S. Bureau of Mines The cost of an air line respirator may be for atmospheres that are immediately hazardous more than that of a hose mask or it may be less, to life. `depending on whether or not an air supply must be Air line equipment which does not include a E-06537 72 RESPIRATORY PROTECTIVE DEVICES MANUAL manual control valve worn on the wearer's belt is also available. It can be used where there is a reason to set up a given air supply for the individ ual and not leave it to his discretion, with a possi ble waste of air. This type depends upon a setting of the regulator for a given pressure or upon the design of the equipment. The wearer cannot change the supply of air within the facepiece. in. ABRASIVE BLASTING RESPIRATORS Abrasive blasting respirators fall into two general designs: (l),a full mask, tight fitting facepiece connected to a supply of air (continuous or possibly demand flow), assembled with a hood and cape of flexible material for protecting the head and shoulders from abrasive rebound; and (2), a rigid, loose fitting helmet covering the head and neck with a loose fitting collar around the neck, the helmet being connected through a hose line to a continuous flow air supply (see Fig. 7.4). The helmet is fitted with a flexible collar or short cape for protection from abrasive rebound. Abrasive blasting respirators are essentially modifications of air line respirators of the continuous flow type. When the letter E is added to type designation of supplied air respirators, such as Type AE and Type CE, it indicates that Type A or Type C respirators were modified for use as abrasive blasting respirators. The quantity of air supplied to an abrasive blasting respirator should be such that a slight positive pressure is maintained at all leakage points so that no contaminant can enter from the outside. Approximately 6 cubic feet per minute (ft^/min) of free air (ambient pressure) is the minimum requirement by the Bureau of Mines for a well designed, continuous flow, helmet-type, abrasive blasting respirator. The minimum re quirement for a demand (Type CE) respirator is 4 ft^/min of free air. The manner in which the air enters the helmet is very important and much care must be taken to avoid injection effects that will cause localized low pressure areas inside the helmet, with result ing inflow of external contaminated atmosphere. Within certain ranges, increase in air flow may increase contamination, the reasons being evident from the behavior of nozzles. Considerable atten tion is being directed to the noise caused by air rushing through the air supply line and the sound being amplified in the helmet. The Bureau of Mines has recently taken this problem under con sideration, and each helmet now approved is ex amined subjectively for discomfort due to noise. Where excessive noise is found, the manufacturer of the helmet is asked to provide muffling or other means for reducing the noise level. Fig. 7.4. Abrasive blasting respirator of the helmet type. IV. SUPPLIED AIR HOODS The supplied air hood is similar to the abra sive blasting respirator except that the hood is generally constructed of lighter material, such as duck, other sturdy cloth, or plastic, with a large transparent area for viewing the work. In many instances, such as for paint spraying and use with radioactive materials, these hoods are made of in expensive materials and are disposable. Many variations in design and materials are available for specific uses. Figure 7.5 illustrates one of the many types that are commercially available. Various methods of air entry into the hoods are employed. These range from the splash of air on a diffusion plate near the back or top of the hood to the downward and upward flow of air from a number of small streams of air from orifices evenly distributed in the bottom and top of a cir cular plenum attached to the head frame. One type consists of a flexible vinyl hood without headgear or frame. Air from the supply source inflates the hood like a balloon, causing it to float around the wearer's head. Drawstrings under the chin hold it in place to ensure a snug fit, and there is a large window for viewing the work. This type could be % M*-A --06538 SUPPLIED AIR RESPIRATORS 73 ii '-s v n iv & frr Fig. 7.5. One type of supplied air hood. Fig. 7.6. Supplied air suit of continuous flow type. used for paint spraying operations. The hood acts as a positive pressure chamber which is being continuously purged with fresh air at low velocity. The Bureau of Mines requirement is 6 ft^/min of free air (ambient pressure). Only well designed hoods will meet this requirement. Others may re quire more free air. The control valve is general ly supported on the wearer's belt at the lower end of the breathing tube in a position where the user is free to regulate the supply to his own require ments within certain limits. As in other types of supplied air respirators, it is desirable to include a device in the supplied air line to remove odors, mists, and particulates which may arise from the compressor. V. SUPPLIED AIR SUITS Supplied air or air-inflated suits are forms of supplied air respiratory protective equipment which provide purified air not only for breathing purposes but also for insulating the whole body from the surrounding atmosphere (see Fig. 7.6). Although these suits are not covered by Bureau of Mines schedules, they are finding increasing use industrially. This type of protection is needed only in the most extreme conditions where there is an exposure to substances that are irritating or cor rosive to the skin and mucous membranes and are also toxic or hazardous to life. Examples of such conditions would be the escape of toxic and corro sive gases, like chlorine, beta propiolactone hydrocyanic acid gas, and tritium (H3). One very specific use of a supplied air suit is in biological laboratories, where the worker is isolated from large scale, dangerous cultures. .The isolation of the man from the work rather than the isolation of the work from the man seems to be much more ef ficient in this instance. In any event, a complete suit of protective clothing plus some arrangement for supplied air must be used. Another type of supplied air suit is one de signed to protect workers from high temperature environments. Suits for fire use should be both in sulating and reflective to mitigate the radiant energy of the flames. Various combinations of wool, asbestos, glass fiber, and aluminized cloth with synthetic rubber as a vapor barrier have been offered on the market. Such a suit should be water resistant not only because of its primary use, but also so that it can be worn under a hose stream for cooling without becoming soaked. The wearing i f E-06539 TWBS*n- '`M W W W .t 74 RESPIRATORY PROTECTIVE DEVICES MANUAL of respiratory equipment under or with fire suits will depend on whether they are used for disaster control or for industrial use. If for industrial use, such as repair of a conveyor in a process oven, the conditions may indicate canister gas masks, sup plied air respirators, or self-contained breathing apparatus. Disaster fire control usually requires the use of self-contained breathing equipment. There is more hazard to life in the use of sup plied air suits than is ordinarily apparent, par ticularly if they are used in atmospheres that are immediately hazardous to life. Loss of continuous air supply and deficiency of oxygen caused by re breathing can cause very rapid onset of uncon sciousness and death without significant warning. The need for an adequate continuous supply of clean air to such suits is more important than with other types of supplied air respirators, owing to the small inside diameter of the hose line and the in ability of the wearer to get air by his own inspi ratory effort. In selecting such suits, attention must also be given to impermeability of the suit material by the harmful agent against which pro tection is needed. Some materials may be sorbents for a harmful constituent and in that manner en hance permeability. VI. COMPRESSED AIR SUPPLY The compressed air supply, whether it is ob tained from a compressor directly or from a cylinder of compressed air, can be a source of contamination unless adequate precautions are taken. It is preferable to use equipment which does not need internal lubrication, rather than high pressure compressors as sources of respirable air. Water-lubricated compressors offered by several distributors are safe so far as production of carbon monoxide and oil mists or vapors is concerned. Diaphragm, graphite-ring, and graphite-vane nonlubricated types of compressors are available. It is necessary to provide a trap and filter on the line side of the compressor to remove oil,' water, scale or other extraneous matter before it comes to the regulator or mask. The compressor intake must be kept away from all sources of con tamination, including engine exhausts. If an in ternally lubricated compressor is used, it should be well maintained so as to keep it from overheat ing to the point of forming dangerous amounts of carbon monoxide. As an extra safeguard, the com pressor should be equipped with a temperatureactuated alarm which also can be made to shut off the compressor if it starts to overheat. Any positive detectable amount of carbon monoxide in air supplies for respiratory protec tion is a definite sign of some source of contami nation. In the absence of valid information to the contrary, such contamination cannot be considered to be a constant value but instead may be consider ably higher or lower at other times, depending on a number of factors, such as leaky compression valves, excessive overheating of compressors, pyrolysis or combustion of lubricating oil, and contamination of the compressor intake. The posi tive finding of as much as 0.005 per cent or 50 parts per million (ppm) of carbon monoxide in air should condemn it for respiratory purposes for three reasons: (1) it can be a possible uncontrolled source of danger; (2) long periods of exposure can produce up to 12 per cent carboxyhemoglobin, which alone is not dangerous but undesirable par ticularly if there are additional sources of carbon monoxide at the work place, on the streets, or through smoking; and (3) there is no reason for not providing clean air. The finding of 0.001 per cent (10 ppm) could be tolerated, if the source is posi tively identified and determined to be relatively constant, or if measures are instituted to achieve such control. For safety practices and precautions recom mended for air supplies to air line respirators used in natural gas processing plants, see Bureau of Mines Bulletin 588.3 Vn. MAINTENANCE AND SUPERVISION Maintenance and supervision of equipment are very important phases of any protection program, and they are no less important for respiratory protective devices and appurtenances. Rubber and someplastic parts can and do deteriorate rapidly if exposed to oxidizing materials, air pollution, and sunlight. Strain points are usually the first areas to give way. Inhalation and exhalation ports may corrode and cease to operate. Air lines that have not been used for some time, as well as control valves, may tend to clog. Deterioration of rubber parts may occur because of prolonged contact with grease or oil. Filters need periodic replacement; blowers should be regularly inspected and over hauled as required; harnesses should be checked for strength; and all components of the facepiece should be cleaned and disinfected regularly. REFERENCES 1. Bureau of Mines: Respiratory Protective Ap paratus, Tests for Permissibility, Fees, Part 12, Supplied-Air Respirators, Schedule 19B, April 19, 1955 (Code of Federal Regulations reference, 30 CFR, Part 12). 2. American Standards Association: American Standard Safety Code for Head, Eye, and Respi ratory Protection, Z2.1 -1959, American Stand ards Assoc., 10 E. 40th St., New York 16, N.Y. 3. Kintz, G. M. and Hill, Frances C.: Safety at Gas-Producing Plants, U.S. Bureau of Mines, Bulletin 588, Washington, D.C., 1960, 98 pp. --06540 Chapter 8 SELF-CONTAINED BREATHING APPARATUS I. INTRODUCTION A self-contained breathing apparatus may be defined as a respirator in which the supply of air, oxygen,, or oxygen-generating material is carried by the wearer. Self-contained oxygen breathing apparatus was first developed and used in this country about 1921, primarily for mine rescue purposes.* At present, the various types of selfcontained breathing apparatus are widely used by fire departments, utility companies, and the chem ical industries. n. TYPES OF SELF-CONTAINED BREATHING APPARATUS Self-contained breathing apparatus falls into the following two general types: demand and re circulating. The demand flow type may supply air or it may supply oxygen. These compressed gases may not be used interchangeably in the same ap paratus for reasons of safety. The recirculating type of self-contained breathing apparatus falls into the following two classes: (1) apparatus in which the oxygen supply is contained as a com pressed gas in a gas cylinder and (2) apparatus in which the oxygen is generated from the action of the moisture in the wearer's exhaled breath on a solid chemical. m. DESCRIPTION AND PRINCIPLES OF OPERA TION Fig. 8.1. Demand flow type of self-contained breathing apparatus. A. Demand Self-contained Breathing Apparatus The demand 'flow type of self-contained breathing apparatus^ (see Fig. 8.1) consists of a full facepiece connected to a demand valve, which is connected, through a pressure-reducing valve, to a cylinder of compressed air or oxygen. A pressure gauge is located near the demand valve to indicate the pressure of the gas in the gas cylinder. When the wearer inhales, a slight negative pressure is created in the facepiece, breathing tube, and demand valve. This negative pressure depresses a diaphragm in the demand valve and causes the gas inlet valve to open and remain open until the wearer exhales and a positive pressure is created in the above parts. The gas flows from the compressed gas cylinder only when the wearer inhales, and the rate of flow is automatically ad justed by the wearer's breathing characteristics. Exhaled breath is not recirculated," but passes to the exterior of the facepiece through an exhalation valve. A bypass valve is provided, by means of which an adjustable flow of gas can be delivered to the facepiece in the event of failure of any part of the pressure-reducing valve or the demand valve. The apparatus is attached to the wearer's body by means of a suitable harness. B. Recirculating Compressed Oxygen Self-con tained Breathing Apparatus In the recirculating compressed oxygen ap paratus^ (see Fig. 8.2), compressed oxygen from the oxygen cylinder passes through a high-pres sure reducing valve and a low-pressure admission 75 E--06541 76 RESPIRATORY PROTECTIVE DEVICES MANUAL position to indicate the pressure in the oxygen cylinder. A manually adjusted bypass valve is provided, by means of which an adjustable flow of oxygen can be delivered to the cooler in the event of failure of the main cylinder valve, the pressure-reducing valve, or the admission valve. A saliva trap and release valve are provided so that the wearer can eliminate accumulated saliva and nitrogen when necessary. (Supplied oxygen may contain as much as 2 per cent of nitrogen, which would build up in the closed system as the oxygen is consumed.) The apparatus is attached to the wearer's body by means of a suitable harness. C. Oxygen-generating Self-contained Breathing Apparatus In the oxygen-generating apparatus2 (see Fig. 8.3), water vapor from the wearer's exhaled breath reacts with a chemical (potassium tetroxide) in a canister to form oxygen, which passes to a breathing bag. When the wearer inhales, oxygen passes from the bag to a full facepiece through a flexible inhalation tube which has a check valve to allow oxygen to flow only to the facepiece. The wearer's exhaled breath passes to the canister through a flexible exhalation tube which has a Fig. 8.2. Recirculating compressed oxygen self-contained breathing apparatus. valve to a breathing bag from which the wearer in hales through a flexible inhalation tube connected either to a mouthpiece or a full facepiece. A check valve allows the oxygen to flow to the facepiece only through the inhalation tube. The wearer's ex haled breath passes through a flexible exhalation tube to a container of chemical that removes the exhaled carbon dioxide. A check valve allows the exhaled, breath to flow only from the wearer's breathing zone through the exhalation tube. After the carbon dioxide has been removed, the exhaled breath passes to a cooler and thence to the-breathing bag. Oxygen from the .compressed oxygen 'cylinder enters the breathing bag only when the bag has collapsed sufficiently to cause a pressure plate to press on the stem of the admis sion valve and open it. The valve closes when the bag is expanded enough so that the pressure plate no longer presses on the stem of the admission valve. Thus, oxygen is recirculated in the appara tus by the wearer's breathing, and oxygen is added to this closed system only as needed. If a mouth piece is used, the nostrils are closed with a nose clip. A pressure gauge is located in a convenient Fig. 8.3. Oxygen-generating self-contained breathing apparatus. $ E-06542 SELF-CONTAINED BREATHING APPARATUS 77 check valve to allow the exhaled breath to flow only to the canister. The chemical in the canister removes the carbon dioxide from the exhaled breath and reacts with the moisture to form oxy gen, which then passes to the breathing bag. The rate of evolution of oxygen is governed by the vol ume rate of breathing of the wearer. The formulae for the basic chemical reactions involved in generating oxygen in a typical canister are as follows: 2KOa + C02 C+HjO) - K2COj + 3/2 02 (+1^0) 2KOa + 2COs + HjO - KHCOg + 3/2 02 A timer, which is actuated by clockwork and not by the wearer's breathing, gives an audible signal after a preset time. A pressure release valve is provided to release excess pressure and saliva, as well as to purge the apparatus to pre vent the accumulation of nitrogen. The apparatus is attached to the wearer's body by means of a suitable harness. A quick start cartridge has been developed for use with a 30 min oxygen-generating selfcontained breathing apparatus to provide quick starting at temperatures as low as -20F and to enable the wearer to start the apparatus in toxic atmospheres without drawing in outside air. The cartridge, which is filled principally with sodium chlorate and iron, is inserted in a retainer in the apparatus and fired by striking. Burning of the cartridge fill liberates more oxygen than is re quired to fully inflate the breathing bag so that some oxygen is vented automatically to the at mosphere. This enables the wearer of the appara tus to begin work immediately. The heat from the cartridge further aids the initial canister oxygen production caused by the wearer's exhaled breath. IV. ADVANTAGES AND LIMITATIONS OF SELFCONTAINED BREATHING APPARATUS The self-contained breathing apparatus has no limitation as to the concentration of gaseous or particulate contaminants in which it may be worn. Since the wearer of a self-contained breathing ap paratus carries his own supply of respirable at mosphere with him, he may leave the work area through any available exit. The chief limitations of this type of apparatus are weight and bulkiness, limited service life, and the training required for its maintenance and safe use. The self-contained breathing apparatus pro vides only respiratory protection. If used in gases that may be absorbed through the intact skin, such as hydrocyanic acid gas, or in gases that burn or blister the skin, adequate body protection must be afforded by other means. V. FACTORS AFFECTING THE USE OF SELFCONTAINED BREATHING APPARATUS The weights of the various types of self-con tained breathing apparatus range from 13.5 to 40 lb. Some models of approved self-contained breathing apparatus have the breathing bag and oxygen supply located on the chest and abdomen of the wearer, and other models have them located on his back. In choosing apparatus for a particular job, consideration should be given to the effect of the location of the bulky parts of the apparatus and of the size and weight of the apparatus on the wearer's ability to perform the job efficiently and safely. Each self-contained breathing apparatus that has been approved by the Bureau of Mines is rated according to the length of time that it will afford respiratory protection while the user is perform ing strenuous manual labor. The length of time that the various types may be safely used without replenishing the source of respirable air or oxygen ranges from 30 min for the demand type to 2 hr for one model of the recirculating type. Severe emotional strain or extreme exertion might cause the wearer to use up the available air or oxygen in less than the rated time. On the other hand, the apparatus will afford respiratory protection for much longer than the rated time if the wearer is calm and his activity is only moderate. Practical weight and bulk restrictions limit the quantity of air or oxygen that can be carried by the wearer and, hence, limit the safe operating period for self-contained breathing apparatus. When used in the conventional manner, selfcontained breathing apparatus that supplies oxygen from a cylinder cannot be used with safety for a practicable period in situations where the pressure of the ambient atmosphere is more than 2 atmos pheres absolute because of the danger of oxygen poisoning.3 However, the Bureau of Mines has de veloped a modified technique by means of which the 2 hr self-contained oxygen breathing apparatus can be worn safely for 1 hr or more where the pressure of the ambient atmosphere is as high as 4 atmospheres absolute.4 The modified technique is based on flushing the apparatus with air at atmospheric pressure and donning the facepiece, or mouthpiece and nose clip, in the pressure lock at the working pressure before entering the pressurized contaminated at mosphere. The air contained in the lungs and breathing tubes of the apparatus serves to dilute and reduce the partial pressure of the oxygen in the closed breathing system below that which would cause oxygen poisoning. It is essential that the di luting air thus trapped in the closed system be maintained throughout the period at elevated pressure, and that the apparatus at no time during 78 RESPIRATORY PROTECTIVE DEVICES MANUAL this period be purged with oxygen. Under high ambient pressures, the period of use of demand type of self-contained breathing apparatus that supplies air is restricted because the rate at which the air is used from the com pressed air cylinder is directly proportional to the absolute pressure of the ambient atmosphere. Thus, the air supply in a conventional demand ap paratus, which would be adequate for 30 min at sea level pressure, would be used up in 15 min under the same working conditions at 2 atmos pheres absolute or 14.7 pounds per square inch gauge (psig) and in 10 min at 3 atmospheres abso lute or 29.4 psig. The use of a larger air cylinder or of multiple air cylinders would prolong the period of use of the apparatus, but the added weight and bulk would hamper the wearer. Self-contained breathing apparatus are much more complex and complicated than the other types of respiratory protective devices. Further more, they are designed for use in highly danger ous atmospheres. Hence, no one can safely use these apparatus unless he is physically fit and well trained in the care, use, and limitations of the ap paratus. In almost all cases where men have en countered serious difficulties while wearing selfcontained breathing apparatus, the difficulties could be traced to one or more of the following factors: poor physical condition of the wearer, poorly assembled or otherwise defective appara tus, lack of or improper training, or improper procedure. Self-contained underwater breathing appara tus (SCUBA) should not be used as a substitute for approved self-contained breathing apparatus, since SCUBA is not designed for respiratory protection against atmospheric contaminants. REFERENCES 1. Forbes, J. J. and Grove, G. W., Revised by Walker, W. D., Pearce, S. J., Morrow, A. E., and Berger, L. B.: Protection Against Mine Gases, Bureau of Mines Miners' Circ. 35, 1954, 58 pp. 2. Morrow, A. E., Demkowicz, W. M., and Chas tain, G. W.: Mine Rescue Apparatus and Auxil iary Equipment, A Handbook for Miners, U.S. Bureau of Mines, 1961, 287 pp. 3. Griffith, F. E. and Schrenk, H. H.: Use of Res piratory Protective Devices Under Abnormal Air Pressure, Bureau of Mines Rept. of In vestigations 3488, 1940, 9 pp. 4. A Bureau of Mines Information Circular, Ten tative title - Problems in the Use of Respira tory Protective Devices Under Air Pressures Greater than Atmospheric, in preparation. 5. Morrow, A. E.: Loss of Life Among Wearers of Oxygen Breathing Apparatus, Bureau of Mines Information Circular 7943, 1959, 28 pp. ">: >?- 4 Chapter 9 U. S. BUREAU OF MINES APPROVAL SCHEDULES AND TESTS I. APPROVAL SYSTEM FOR RESPIRATORY PROTECTIVE DEVICES The Bureau of Mines has in operation five schedules under which specific types of respira tory protective devices are tested and approved. These schedules cover self-contained breathing apparatus,* gas masks,2 supplied air respira tors,^ dispersoid (particulate) respirators,4 and chemical cartridge respirators, including paint spray respirators.^ The Bureau has no regulatory power requiring that all respirators must be sub mitted to it for approval testing. Submitting res piratory protective devices to the Bureau of Mines for approval is entirely voluntary on the part of the manufacturer. The Bureau acts as an impar tial testing agency that serves by making available to the public a list of respiratory protective de vices that have met definite published perform ance requirements. These performance requirements are based on the field of use of the respirator and on the three following fundamental requirements for a satisfactory device: (1) it must provide adequate protection for a suitable period, (2) it must be reasonably comfortable and convenient to wear, and (3) it must be constructed of durable ma terials. The performance requirements are set forth in the pertinent schedules. The Bureau of Mines offers free consulting service to manufacturers contemplating the de velopment and manufacture of respiratory protec tive devices which are later to be submitted for testing and approval. A fee is charged for the ap proval testing. After all the pretest requirements of a res pirator have been met, the Bureau tests the res pirator according to the requirements of the per tinent schedule. If the respirator meets these re quirements, the manufacturer is notified that the respirator has been approved, and copies of the official approval plate or plates are sent to the manufacturer. These approval plates give the limitations of the approval, such as the type and maximum con centration of gas in which a gas mask may be worn, or a statement such as that on the approval label of a Type C supplied air respirator: "Ap proved for respiratory protection in any atmos phere not immediately harmful or from which the wearer can escape unharmed without the aid of the respirator." The label lists the approval marking on the parts that make up the approved assembly, and it lists any special precautions that should be taken when using the respirator (see Figs. 9.1 and 9.2 for typical labels). If a respirator is used under conditions other than those covered by the approved label, the approval of that individual respirator is invalidated. The Bureau of Mines approval applies only to a respiratory protective device as a unit and not to its integral parts. For instance, if approvals were granted to four respirator manufacturers A, B, C, and D on four entirely different universal gas masks, an assembly of A's canister harness,. B's canister, C's timer or external check valve, and D's facepiece would not constitute an approved as sembly, even though the individual items were parts of approved gas masks. To maintain the approval status of a respira tor, the manufacturer must make the respirator PERMISSIBLE RESPIRATOR FOR DUSTS APPROVAL NO. 2100 ISSUED TO THE MANUFACTURER'S NAME Address Approved for protection against the inhalation of dusts that are not significantly more toxic than lead (dispersoids or particulate matter formed by the disintegration of solid materials by such processes as crushing, grinding and abrading). The approved assembly consists of: BM-2100 facepiece and BM-2100 filter. In making renewals or repairs, parts identical with those furnished by the manufacturer under the pertinent approval shall be maintained. CAUTION This respirator removes only dispersoids from the air. It gives no protection against gases, vapors, or an insufficiency of oxygen. Followthe manufacturer's instructions forfittingthe respirator to the face, for changing the filter, for cleaning the respirator, and for caring for it while not in use. Fig. 9.1. Dust respirator approval label. (Courtesy U.S. Bureau of Mines) 79 E--06544 80 RESPIRATORY PROTECTIVE DEVICES MANUAL PERMISSIBLE GAS MASK FOR ORGANIC VAPORS APPROVAL NO. 1400 MANUFACTURER'S NAME Address Approved for respiratory protection in atmospheres con taining not more than 2 percent by volume of organic vapors. The approved assembly consists of: BM-1400 canister, BM-1400facepiece, and BM-1400 canister harness. CAUTION 1. This mask protects against organic vapors only. 2. This mask must not be used where the oxygen content of the air is less than 16 percent 3. Renew exhausted canisters immediately. 4. Read cautions on the canister label, and instructions in the lid of the mask case. H-89320-P Fig. 9.2. Organic vapor mask label. (Courtesy U.S. Bureau of Mines) according to the drawings, design, and model that were submitted to the Bureau and that were con sidered and included in the original approval or subsequent extensions of approval. If the manu facturer desires to make any change in the design of an approved respirator, prior approval of the change must be obtained. From time to time, ap proved respirators are purchased on the open market. They are tested and inspected to ascer tain whether or not they conform to the approved respirator in physical make-up and performance. n. TEST METHODS As stated at the beginning of this chapter, the performance requirements for the various types of respiratory protective devices that may be ap proved by the Bureau of Mines are set forth in the pertinent Bureau of Mines schedules.*These schedules should be consulted for full details of the performance requirements. The remainder of this chapter discusses the main points that are considered during the approval testing of the vari ous types of respiratory protective devices. Tables list the more significant test conditions and performance requirements. A. Self-contained Breathing Apparatus Most of the approval tests made on self-con tained breathing apparatus are man tests; that is, they are made while the apparatus is being worn by men. The tests are designed to provide answers to the following questions regarding the perform ance of the apparatus: 1. Will the apparatus supply air or oxygen fast enough to meet the needs of the wearer? 2. Can the wearer breathe freely at all times? 3. Does the temperature of the inspired air remain within prescribed limits? (The tempera ture of the inspired atmosphere shall not exceed 110F when the temperature of the ambient at mosphere does not exceed 85F.) 4. Are vital parts of the apparatus protected so as to prevent damage or excessive wear? 5. Is the concentration of carbon dioxide in the inspired air within prescribed limits? (See Table 9.1) 6. Does the harness hold the apparatus on the wearer's body without undue discomfort to him? 7. For what period of time will the apparatus provide adequate respiratory protection for the wearer under the test conditions? The men who wear the apparatus during the man tests must first pass a physical examination by a qualified physician. They then put on the ap paratus and perform definite timed schedules of exercise that include walking, running, carrying and lifting weights, sawing wood, crawling, and lying in various positions. This is done in a test space containing an irrespirable formaldehydeair atmosphere. The specific activities of the test subject and the duration of each activity for the 15 tests are given in Tables 9.2 through 9.6. During the 2 min ute (min) periods for "sampling and readings* samples of the atmosphere within the apparatus are taken, and readings are made of the tempera ture of the inspired air, as well as the pulse and frequency of respiration of the wearer. The at mosphere within the apparatus is sampled as near to the point of inspiration as practicable, only while the wearer is inhaling and over a period covering several inhalations. The limits for the carbon dioxide content of these samples are given in Table 9.1. Each self-contained breathing apparatus, ex cept the oxygenrgenerating type, must be equipped with a bypass valve that will permit an adjustable flow of compressed oxygen or air from the gas cylinder to the circulatory system of the appara tus independent of the pressure reducing valve. The maximum acceptable weight of a fully charged self-contained breathing apparatus is 40 pounds (lb). * '5t E--06545 U.S. BUREAU OF MINES APPROVAL SCHEDULES AND TESTS TABLE 9.1 LIMITS FOR CARBON DIOXIDE CONTENT OF ATMOSPHERE WITHIN SELF-CONTAINED BREATHING APPARATUS DURING APPROVAL TESTS 81 Type of Apparatus Inhalation Tube Maximum3 Carbon Dioxide, % Inhalation Tube Facepiece Average3 Maximum*5 Recirculating with mouthpiece 2.5 1.0 Recirculating with facepiece 2.5 1.0 2.5 Demand with mouthpiece 2.5 1.0 -- Demand with facepiece -- -- 2.5 a. From inhalation tube near point of inspiration. b. From interior of facepiece near nose and mouth of wearer. Facepiece Average*5 -- 2.0 -2.0 B. Gas Masks The approval tests of gas masks may be di vided into two groups: machine tests of the can isters and man tests of the facepiece and the com plete gas mask. The continuous flow -machine tests on gas mask canisters are of two types: tests with low TABLE 9.2 DURATION OF SPECIFIC ACTIVITIES FOR TESTS 1 THROUGH 4 OF SELF-CONTAINED BREATHING APPARATUS Wearer Activity Duration, min Type Type Type Type A B CD Sampling and readings 2 2 2 2 Walks at 3 miles/hr 8 13 18 28 Sampling and readings 2 2 2 2 Walks at 3 miles/hr 8 12 17 28 Sampling and readings 2 2 2 2 Walks at 3 miles/hr 6 12 17 28 Sampling and readings 2 2 2 2 Walks at 3 miles/hr -- -- -- 26 Sampling and readings zz ZZ 2 Total 30 45 60 120 Type A is 1/2 hr apparatus. Type B is 3/4 hr apparatus. Type C is 1 hr apparatus. Type D is 2 hr apparatus. concentrations and low rates of flow and tests with high concentrations and high rates of flow. - The low concentration, low rate of flow tests are pri marily to determine the capacity and retentivity of the sorbents. The high concentration, high rate of flow tests are primarily to determine the activity of the sorbents (see Chapter 5). Some tests are made to determine the effect of passing either dry air (25 per cent relative humidity) or moist air (85 per cent relative hu midity) through the canisters for several hours. Canisters tested by machine must not allow more than 5 parts per million (ppm) of the test gas (100 ppm for ammonia) to penetrate them before the end of a specified minimum test period. The in halation resistances of the canisters to an air flow of 85 liters per minute (1/min) must not exceed 3 inches (in.) of water (3.25 in. of water for univer sal gas mask canisters or canisters with special mechanical filters) at any time during the machine test. Special machine tests are made on universal gas -mask canisters to determine the protection afforded to the catalyst (hopcalite) against water vapor, which adversely affects its ability to pro mote the conversion of carbon monoxide to carbon dioxide (see Fig. 9.3). A summary of the test conditions and per formance requirements for machine tests of gas mask canisters is given in Tables 9.7 and 9.8. To detect any gross leakage, the facepiece is attached to an ammonia gas mask canister and is worn by 15 to 20 men (with widely varying facial shapes and sizes) in a mixture of 1 per cent am monia gas in air. Each of the 15 to 20 men must obtain a gas-tight fit; otherwise, the device is not approved. The complete gas mask is then as sembled with an appropriate canister and canister carrying harness and is worn by the same group 82 RESPIRATORY PROTECTIVE DEVICES MANUAL TABLE 9.3 DURATION OF SPECIFIC ACTIVITIES FOR TESTS 5 THROUGH 8 OF SELF-CONTAINED BREATHING APPARATUS Wearer Activity Type A Durationl, min Type B Type C Type D Sampling and readings Walks at 3 miles/hr Carries 50 lb weight over overcast Walks at 3 miles/hr Sampling and readings Carries 45 lb weight and walks at 3 miles/hr Raises 45 lb weight 5 ft vertically Saws wood as indicated Sampling and readings Carries 50 lb weight over overcasta Walks at 3 miles/hr Sampling and readings Walks at 3 miles/hr Sampling and readings Total 2 2 2 times in 4 2 2 2 30 times in 2 2 2 3 times in 6 2 2 -- --- 30 2 3 3 times in 6 4 2 3 45 times in 3 6 2 4 times in 8 4 2 -- zz. 45 2 6 4 times in 8 4 2 2 10 5 times in 10 10 2 4 60 times in 4 10 2 5 times in 10 6 2 -- zz. 60 8 75 times in 5 15 2 10 times in 20 8 2 24 2 120 a. A passage through which the ventilating current is conveyed over an entry or air course in a mine. This overcast is 6 ft high and 24 ft long. TABLE 9.4 DURATION OF SPECIFIC ACTIVITIES FOR TESTS 8 THROUGH 11 OF SELF-CONTAINED BREATHING APPARATUS Wearer Activity Sampling and readings Walks at 3 miles/hr Crawls as indicated Lies on his side Lies on-his back Sampling and readings Walks at 3 miles/hr Runs at 6 to 8 miles/hr Walks at 3 miles/hr Sampling and readings Walks at 3 miles/hr Carries 50 lb weight over overcast1 Walks at 3 miles/hr Sampling and readings Walks at 3 miles/hr Sampling and readings Total Type A 2 2 25 ft in 3 2 1 2 2 300 ft in 1 3 2 2 2 times in 4 2 2 -- 30 Duration, min Type B Type C 2 3 40 ft in 4 4 2 2 6 400 ft in 2 4 2 3 3 times in 6 3 2 -- 45 2 4 60 ft in 6 5 3 2 6 600 ft in 3 7 2 6 4 times in 8 4 2 -- -- 60 Type D 2 5 100 ft in 10 10 5 2 10 600 ft in 3 15 2 10 5 times in 10 8 2 24 2 120 a. A passage through which the ventilating current is conveyed over an entry or air course in a mine. This overcast is 6 ft high and 24 ft long. E-06547 U.S. BUREAU OF MINES APPROVAL SCHEDULES AND TESTS TABLE 9.5 DURATION OF SPECIFIC ACTIVITIES FOR TESTS 12 THROUGH 14 OF SELF-CONTAINED BREATHING APPARATUS 83 Wearer Activity Type A Duration, min Type B Type C Type D Sampling and readings Walks at 3 miles/hr Runs at 6 to 8 miles/hr Raises 45 lb weight 5 ft vertically Carries 45 lb weight as indicated Carries 50 lb weight over overcast Sampling and readings Walks at 3 miles/hr Carries 50 lb weight over overcast1 Raises 45 lb weight 5 ft vertically Sampling and readings Walks at 3 miles/hr Raises 45 lb weight 5 ft vertically Walks at 3 miles/hr Sampling and readings Walks at 3 miles/hr Sampling and readings Total 2 1 300 ft in 1 30 times in 2 200 ft in 1 2 times in 4 2 2 2 times in 3 30 times in 2 2 2 30 times in 2 2 2 - _ 30 2 2 300 ft in 1 45 times in 3 400 ft in 2 2 times in 4 2 2 6 times in 9 45 times in 3 2 3 45 times in 3 5 2 -- 45 2 2 600 ft in 2 60 times in 4 400 ft in 2 4 times in 8 2 4 8 times in 12 60 times in 4 2 4 60 times in 4 6 2 -- 60 2 8 600 ft in 2 75 times in 5 1,000 ft in 5 5 times in 10 28 10 times in 15 75 times in 5 2 8 75 times in 5 15 2 24 2 120 a. A passage through which the ventilating current is conveyed over an entry or air course in a mine. This overcast is 6 ft high and 24 ft long. TABLE 9.6 DURATION OF SPECIFIC ACTIVITIES FOR TEST 15 OF SELF-CONTAINED BREATHING APPARATUS Wearer Activity Duration, min Type A Type B Type C Type D Sampling and readings 2 2 2 2 Sits quietly 8 12 18 28 Sampling and readings 2 2 2 2 Sits quietly 8 13 18 28 Sampling and readings1 2 2 2 2 a. Wearer continues sitting quietly. Samples and readings are taken at the same listed intervals until the supply of compressed oxygen or com pressed air is exhausted. of men in a 2 per cent phosgene gas--air mixture for a more severe test of the gas-tightness of the facepiece and of its ability to fit various types of faces. The gas mask is worn for 2 min in the maximum concentration of each type of gas to be covered by the approval. As a final test, the inlets of two canisters are attached to the chamber con taining the same gas--air mixture, facepieces with long breathing tubes are attached, and two men wear the facepieces while performing the schedule of exercise listed in Table 9.9 (see Fig. 9.4). To meet the requirements of this test, the gas masks must give complete respiratory protection to the wearers for 30 min for all types except the universal gas mask, which shall give complete respiratory protection against carbon monoxide for 30 min, organic vapors for 25 min, acid gases for 15 min, and ammonia for 15 min. Complete respiratory protection means that the wearers of the gas masks shall not detect the test gas or va por by odor, taste, or eye or throat irritation, and that they shall experience no subjective or objec tive effects attributable to carbon monoxide when testing the gas masks against this gas. Excessive fogging of the eyepieces must not occur, and undue discomfort must not be experienced because of the 84 RESPIRATORY PROTECTIVE DEVICES MANUAL Fig. 9.3. Test equipment used to determine effectiveness of universal gas mask canisters against carbon monoxide--air mixtures. (Courtesy U.S. Bureau of Mines) fit or other physical or mechanical features of the gas mask. C. Supplied Air Respirators* 1 2 The mechanical tests of supplied air respira tors are designed to provide the following infor mation regarding the performance characteristics of supplied air respirators: 1. The air flow characteristics; that is, the rates of flow of air to the breathing zone of the wearer with various lengths of air supply line and with either the hand-operated blower for the hose mask operated at several different crank speeds or with various air pressures applied to the inlet of the air supply line for air line or abrasive blasting respirators. 2. The strength and noncollapsibility of the air supply line and its resistance to permeation by liquid gasoline. 3. The strength of the'body harness of the hose mask. Some of the more significant test conditions and performance requirements for mechanical tests of supplied air respirators are listed in Table 9.10. Man tests provide information regarding the fit of facepiece, helmet, or hood; the distribution of air in the facepiece, helmet or hood; the avail able clarity and field of vision; other factors that might influence the safety and convenience of the wearer; and, primarily, the degree of respiratory protection afforded the wearer. Man tests in a 1 per cent ammonia--air at mosphere and in a silica dust--air atmosphere are made on all types of supplied air respirators. E-06549 U.S. BUREAU OF MINES APPROVAL SCHEDULES AND TESTS 85 TABLE 9.7 TEST CONDITIONS AND PERFORMANCE REQUIREMENTS FOR MACHINE TESTS ON GAS MASK CANISTERS AT LOW CONCENTRATIONS AND LOW RATES OF FLOWa Type of Canister and Gas or Vapor Con centra tion, % Maximum Leakage Allowed Minimum Life, min Regular Test After Equili bration*3 A: Acid gas Chlorine Hydrogen cyanide Sulfur dioxide 0.5 5 ppm 0.5 5 ppm 0.5 5 ppm 88c 44 88 44 88c 44 B: Organic vapor Carbon tetrachloride 0.5 5 ppm 96 48 C: Ammonia 2.0 100 ppm 36 1.8 D: Carbon monoxide Regular service Self-rescue 1.0 . 0.5 1.0 0.5 . 770 cm3" 770 cm3d,e 770 cm3d 770 cm3de 240 60 60 30 -- -- -- -- AB,AC,BC,ABC -- -- f Half of regular test N: Universal Chlorine 0.5 5 ppm 44 -- Hydrogen cyanide 0.5 5 ppm 44 -- Sulfur dioxide 0.5 5 ppm 44 -- Carbon tetrachloride 0.5 5 ppm 48 -- Ammonia 2.0 100 ppm 18 -- Carbon monoxide 1.0 770 cm3d 240 __ 0.5 770 cm3d>e 60 -- a. Relative humidity of test atmosphere, 50 + 5 per centj- temperature, room temperatur'e_(approximately 25C); rate of air flow, 32 1/min continuous flow; number of canisters, three for each test atmosphere. b. Canister was equilibrated with air of 25 or 85 per cent relative humidity. c. This value is for canisters on which approval for the maximum permissible concentration is desired. It should be reduced proportionately for canisters on which approval for a lower concentration is de sired. For example, the minimum life would be 44 min for canisters on which approval for a concen tration of 1 per cent is desired. d. This represents total carbon monoxide leakage for entire minimum life period shown in next column. In terms of concentration, it is equivalent to a uniform flow of 0.04 per cent carbon monoxide for 1 hr at 32 1/min. Maximum leakage shall not exceed 1,000 ppm. e. This test is made to determine the activity of the catalyst, which effects the oxidation of carbon mo noxide to carbon dioxide, under the adverse condition of a low temperature. The canister and precool ing coil for the entering test atmosphere are immersed in an ice-water bath. The relative humidity of the test atmosphere is 100 per cent at 0C. f. These combination gas canisters must meet the life requirements for each type of contaminant against which they are designed to give protection. 86 RESPIRATORY PROTECTIVE DEVICES MANUAL TABLE 9.8 TEST CONDITIONS AND PERFORMANCE REQUIREMENTS FOR MACHINE TESTS ON GAS MASK CANISTERS AT HIGH CONCENTRATIONS AND HIGH RATES OF FLOWa Type of Canister and Gas or Vapor A: Acid gas Chlorine Hydrogen cyanide Phosgene Sulfur dioxide B: Organic vapor Carbon tetrachloride C: Ammonia D: Carbon monoxide Regular service Self-rescue AB,AC,BC,ABC N: Universal Chlorine Hydrogen cyanide Phosgene Sulfur dioxide Carbon tetrachloride Ammonia Carbon monoxide Maximum Approval Concentration, % 2.0 2.0 2.0 2.0 2.0 3.0 2.0 -- 2.0 2.0 2.0 2.0 2.0 3.0 2.0 Maximum Leakage Allowed 5 ppm 5 ppm 5 ppm 5 ppm 5 ppm 100 ppm 770cm3 -- 5 ppm 5 ppm 5 ppm 5 ppm 5 ppm 100 ppm 770 cm3b Minimum Life, min 11 11 11 11 12 12 15 No test c 5.5 5.5 5.5 5.5 6 6 15 a. Relative humidity of test atmosphere, 50 5 per cent; temperature, room temperature (approximately 25C); concentration of gas or vapor: concentration for which approval is requested; rate of air flow, 64 l/min continuous flow; number of canisters, two for each test atmosphere. b. This represents total carbon monoxide leakage for entire minimum life period shown in next column. Maximum leakage shall not exceed 1,000 ppm. c. These combination gas canisters must meet the life requirements for each type of contaminant against which they are designed to give protection. In addition, man tests involving a sandblasting op eration are made on the abrasive blasting (Type CE) respirators. For the first test, the air flow of tight fitting facepieces is maintained at 4 cubic feet per minute (ft3/min) and for helmets or hoods at 6 ft3/min. Each test is repeated with the maxi mum air pressure applied to the minimum length of air supply hose. The protection afforded by the respirator dur ing the man tests against the 1 per cent ammonia- air atmosphere is evaluated by the wearer's sub jective observations. The respiratory protection afforded during the man tests against a silica dust aerosol and during a sandblasting operation is evaluated by sampling the air within the facepiece, helmet, or hood, at 32 l/min, as close as pos sible to the breathing zone of the wearer. The net amount of particulate matter in the air so sampled for 30 min must not exceed 0.5 milli gram (mg). '*06553 U.S. BUREAU OF MINES APPROVAL SCHEDULES AND TESTS TABLE 9.9 SCHEDULE OF EXERCISE FOR MAN TESTS OF GAS MASKS Activity Universal (Against Carbon Monoxide) Duration, min Universal Universal (Against (Against Acid Organic Gases and Vapors) Ammonia) Walking vigorously Sitting at rest Stationary running and calisthenic arm movements Sitting at rest Pumping air with a hand-operated tire pump into a 1 ft^ cylinder to a pressure of 25 psig or equivalent work Total 5 5 10 5 _5 30 5 5 5 5 _5 25 5 5 5 -- 15 a. Whether for a single contaminant or a specified combination of contaminants. 87 All Other Gas Masksa 5 5 10 5 _5 30 E-06552 88 RESPIRATORY PROTECTIVE DEVICES MANUAL TABLE 9.10 TEST CONDITIONS AND PERFORMANCE REQUIREMENTS FOR MECHANICAL TESTS OF SUPPLIED AIR RESPIRATORS3 Respirator Maximum Hose Length, ft Maximum Air Pressure at Hose Inlet, psig Air Flow to Breathing Zone, ft^/min Pull Strength of Hose and Couplings, lb Resistance, in. of HjO Inhalation Exhalation Type A: Hose mask with blower 150 0.18 At least 1.8 with blower hand-op erated at < 50 rpm 250 2.5 at 1 at 85 1/min 85 1/ min Type B: Hose mask without blower 75 Atmospheric Regulated by 250 1.5 at 1 at wearer's 85 1/min 85 1/min breathing Type C: Air line respirator Continuous flow class Demand class 250 25b 250 125 4 (facepiece) 100 -6 (helmet or hood) 1 at 1701/min Regulated by 100 2 at 1 at wearer's 1151/min 85 1/ min breathing Type CE: Abrasive blasting respirator Continuous flow class 250 25b 4 (facepiece) 100 -6 (helmet or hood) 1 at 85 1/min Demand class 250 125 Regulated by 100 2 at 1 at wearer's breathing 115 1/ min 85 1/ min a. The permeation of the hose by gasoline is tested by immersing 25 ft of hose and a coupling in liquid gasoline and.passing air through the hose at 8 1/min for 6 hr for Types A and B and for 1 hr for Types C and CE. The air from the hose must now show more than 0.1 per cent gasolinevapor by volume at the end of this period. b. For the majority of approved continuous flow respirators, the maximum inlet pressure is 25 psig. D. Dispersoid. Respirators The approval tests on dispersoid respirators are set up as follows: The face-contacting edges of the respirator are sealed to a test fixture so that all air drawn through the respirator will pass through an elec trostatic precipitator which will collect any un retained dispersoid in this air and allow it to be quantitated. The physical characteristics of the test aerosols (dispersoids suspended in air) simu late those that might be encountered in the use of the respirator. The aerosol is drawn to the res pirator at a steady rate of 32 1/min for set peri ods. The amount of unretained dispersoid, and the exhalation and inhalation resistance of the respi-' rator before and after the above test, are deter mined. The respirator is worn by 15 to 20 men with widely varying facial shapes and sizes as a check on its face fitting qualities (see Figs. 9.5 and 9.6). Some respirators are tested and approved for E--06553 Fig. 9.5. Use of dioctyl phthalate (DOP) smoke to locate and quantitate leakage where aerosol respirator contacts face. The penetrometer gives an instaneous reading of DOP leakage. (Courtesy U.S. Bureau of Mines) protection against only one type of dispersoid, whereas others are approved for protection against two or more types. The test aerosols used, and the types of dis persoid covered by the approval granted on res pirators which are tested against these aerosols, are listed in Table 9.11. E. Chemical Cartridge Respirators The approval tests on chemical cartridge respirators for organic vapors, which are the only type approved at present, are similar, in general, to those described for gas masks except that the test concentrations are lower. Some chemical cartridge respirators are approved for respira tory protection against dispersoids in addition to gases or vapors after having been tested by meth ods described for dispersoid respirators. Still other respirators are approved for protection against paint spray after having been tested against carbon tetrachloride vapor and against aerosols made by atomizing lead paint, enamel, and lacquer (see Fig. 9.7). The inhalation resistance of the respirator to an air flow of 85 1/min must not exceed 2 in. of water for those without dispersoid filters or 3 in. of water for those with dispersoid filters. The ex halation resistance of both types of respirator must not exceed 1 in. of water at the same air flow rate. -06554 90 RESPIRATORY PROTECTIVE DEVICES MANUAL The test conditions and performance require ments for machine tests of chemical cartridge respirators for organic vapors are listed in Table 9.12. The test conditions and performance require ments for machine tests of dispersoid filters for paint spray respirators are listed in Table 9.13. The respirator is worn by 15 to 20 men with widely varying facial shapes and sizes to test the suitability of the fit of the respirator to their faces. Eight of these men then wear the respira tor in an atmosphere containing 0.01 per cent (100 ppm) isoamyl acetate vapor for 10 min while walking, moving their heads from side to side, nodding, bending the body at the waist, and pumpair with a hand-operated tire pump. To meet the requirements of this test, no isoamyl acetate shall be detected by odor in the air breathed, and undue encumbrance and discomfort shall not be experi enced because of the fit or other features of the respirator. The respirator, with fresh cartridges, is then worn by two men in an atmosphere con taining 0.5 per cent (5,000 ppm) carbon tetra chloride vapors while the men perform the schedule of exercise listed in Table 9.14. To meet the requirements of this test, the respirators shall give complete respiratory pro tection to the wearers for 30 min. Undue discom fort must not be experienced because of fit or other physical or mechanical features of the res pirator. E--06555 U.S. BUREAU OF MINES APPROVAL SCHEDULES AND TESTS TABLE 9.11 TEST CONDITIONS AND PERFORMANCE REQUIREMENTS FOR DISPERSOID RESPIRATORS 91 Dispersoids Covered by Respirator for Protec tion against Test Dispersoid Concentration of Dispersoid, mg/M^ Duration of test, hr Maximum Allowable Leakage, mg Maximum Final Resistance to Air Flow, mm of HjO Pneumoconiosisproducing and nuisance dusts Silica dust; geometric mean not more than 0.6 n; Og = 1.9 50 10 1.5 3.0 50 Toxic dusts (not significantly more toxic than lead) Litharge,--75%; free metallic lead, --25%; geometric mean not more than 0.6 /i; Og = 1.9 15 + 5 1.5 0.43 (Pb) 50 Metal fumes (not significantly more toxic than lead) Freshly generated lead fume 15 5 5.2 1.50 (Pb) 50 Chromic acid mist Electrolytically generated dhromic acid mist 15 5 5.2 1.0 50 Pneumoconiosisproducing and nuisance mists Mist formed by atomizing a silica dust--water suspension 10 5 5.2 5.0 50 Various combina tions of above types of dis persoids Respirator must meet requirements for each type.a a. For example, the protection against dusts not significantly more toxic than lead, the respirator must meet the requirements for the first two items in this table, that is, for pneumoconiosis-producing and nuisance dusts and for toxic dusts not significantly more toxic than lead. TABLE 9.12 TEST CONDITIONS AND PERFORMANCE REQUIREMENTS FOR MACHINE TESTS OF CARTRIDGES OF ORGANIC VAPOR CHEMICAL CARTRIDGE RESPIRATORS21 Test Low rate of flow High rate of flow Chemical stability^ Number of Cartridges*3 3 2 4 Rate of Flow, 1/min 32 64 32 Maximum Allowable leakage, ppm 5 5 5 Minimum Life, minc 100 50 45 a. Relative humidity of test atmosphere, 50 5 per cent; temperature, room temperature (approximately 25C); test atmosphere, carbon tetrachloride vapor, 0.1 per cent by volume (1,000 ppm). b. This number refers to pairs of cartridges if two are used in parallel on the respirator. c. The values given for minimum life apply to each cartridge or to each pair of cartridges if they are used in parallel. Tests are continued until the maximum allowable leakage occurs. d. Two cartridges or two pairs of cartridges are treated at room temperature by passing carbon dioxide* free air of 25 per cent relative humidity through them at a rate of 25 1/min for 6 hr. Two cartridges of two pairs of cartridges are treated similarly with air of 85 per cent relative humidity. -06556 U.S. BUREAU OF MINES APPROVAL SCHEDULES AND TESTS 93 REFERENCES 1. Bureau of Mines: Respiratory Protective Ap paratus, Tests for Permissibility, Fees, Part 11, Self-Contained Breathing Apparatus, Schedule 13D, Sept. 22, 1956, 12 pp. (Code of Federal Regulations reference, 30 CFR, Part 11). 2. Bureau of Mines: Respiratory Protective Ap paratus, Tests for Permissibility, Fees, Part 13, Gas Masks, Schedule 14F, Apr. 23, 1955, 9 pp. (Code of Federal Regulations reference, 30 CFR, Part 13). 3. Bureau of Mines: Respiratory Protective Ap paratus, Tests for Permissibility, Fees, Part 12, Supplied-Air Respirators, Schedule 19B, Apr. 19, 1955, 14 pp. (Code of Federal Regula tions reference, 30 CFR, Part 12). 4. Bureau of Mines: Respiratory Protective Ap paratus, Tests for Permissibility, Fees, Part 14, Filter-Type, Dust, Fume, and Mist Respi rators, Schedule 21A, Apr. 19, 1955, 7 pp. (Code of Federal Regulations reference, 30 CFR, Part 14). 5. Bureau of Mines: Respiratory Protective Ap paratus, Tests for Permissibility, Fees, Part 14a, Nonemergency Gas Respirators (Chemical Cartridge Respirators, Including Paint Spray Respirators), Schedule 23B, Aug. 8, 1959, 8 pp. (Code of Federal Regulations reference, 30 CFR, Part 14a). -06557 Chapter 10 RESPIRATORY PROTECTIVE DEVICES APPROVED BY THE U. S. BUREAU OF MINES As stated in Chapter 9, The Bureau of Mines Appliances Company, November 26, 1946, under tests and approves various types of respiratory Schedule 13C. protective devices submitted to it by respirator 7. McCaa 2 hr oxygen breathing apparatus manufacturers. The Bureau publishes a list of ap with life line telephone (full) facepiece. Supple proved respiratory protective devices. From time mental approval BM-1303S, issued to Mine Safety to time, this list is revised to show currently Appliances Company, November 20, 1956, under available devices that have been approved. 1 Schedule 13D. Information on the approval status of respi 8. Globe Air Guardsman demand-type air ap rators that may have been put on the market since paratus (1/2 hr self-contained compressed air the most recently published listing may be ob breathing apparatus). Approval BM-13D-11, is tained by communicating with the Branch of Health sued to Globe Industries, Lie., June 30, 1959, un I Research, U.S. Bureau of Mines, 4800 Forbes Avenue, Pittsburgh 13, Pennsylvania. der Schedule 13D. _ 9. Fyr-Fyter Guardsman demand-type air ap hh*. paratus (1/2 hr self-contained compressed air I. TYPES APPROVED breathing apparatus). Extension of approval BM- i > ft The following is a list of the various types of currently available respiratory protective devices that have been approved by the Bureau of Mines to July 1, 1962. Section n lists the names and ad dresses of manufacturers of approved devices. 13D-11, issued to The Fyr-Fyter Company, August 6, 1959, under Schedule 13D. 10. U.S. Divers SurviAir demand-type air ap paratus (1/2 hr self-contained compressed air breathing apparatus). Approval BM-13D-12, is sued to U.S. Divers Company, September 11, 1961, A. Self-contained Breathing Apparatus Approved under Schedules 13, 13A, 13B, 13C, and 13D* 13 under Schedule 13D. 11. MSA One Hour Chemox oxygen breathing apparatus (self-contained oxygen-generating I 1. McCaa 2 hr oxygen breathing apparatus. Approval BM-1303, issued to Mine Safety Appli breathing apparatus). Extension of approval BM1307, issued to Mine Safety Appliances Company, ances Company, August 31, 1925, under Schedule January 25, 1962, under Schedule 13C. 13. 12. MSA One-Half Hour Chemox oxygen 2. MSA 1 hr oxygen breathing apparatus. Ap breathing apparatus (self-contained oxygen proval BM-1306, issued to Mine Safety Appliances generating breathing apparatus). Approval BM- Company, July 28, 1937, under Schedule 13B. 13D-13, issued to Mine Safety Appliances Com 3. Chemox oxygen breathing apparatus (3/4 hr pany, May 2, 1962, under Schedule 13D. self-contained oxygen-generating breathing ap paratus). Approval BM-1307, issued to Mine Safety Appliances Company, October 3, 1946, under Schedule 13C. B. Gas Masks Approved under Schedules 14, 14A, 14B, 14C, 14D, 14E, and 14F 4. Scott Air-Pak demand-type apparatus (1/2 hr self-contained compressed air breathing ap 1. Type A: Acid Gas Masks paratus). Approval BM-1308, issued to Scott Avia 1. MSA hydrocyanic acid gas mask. Approvals tion Corporation, October 3, 1946, under Schedule BM-1413 (regular size canister) and BM-1414 13C. (supersize canister), issued to Mine Safety Appli 5. MSA demand-type oxygen apparatus (1/2 hr ances Company, December 9,1933, under Schedule self-contained compressed oxygen breathing ap 14B. paratus). Approval BM-1309, issued to Mine 2. Acme chlorine gas mask. Approval BM- Safety Appliances Company, October 3, 1946, un 1421, issued to Acme Protection Equipment Com der Schedule 13C. pany, Inc., April 21, 1939, under Schedule 14D. 6. MSA demand-type air apparatus (1/2 hr 3. MSA chlorine gas mask. Approval BM- self-contained compressed air breathing appara 1422, issued to Mine Safety Appliances Company, tus). Approval BM-1310, issued to Mine Safety May 26, 1939, under Schedule 14D. 95 ^"06558 96 RESPIRATORY PROTECTIVE DEVICES MANUAL 4. Davis hydrocyanic acid gasmask. Approval BM-1424, issued to Davis Emergency Equipment Company, Inc., December 11, 1939, under Schedule 14D. 5. Davis chlorine gas mask. Approval BM1427, issued to Davis Emergency Equipment Com pany, Inc., June 26, 1940, under Schedule 14D. 6. Willson hydrocyanic acid gas mask. Ap proval BM-1428, issued to Willson Products, Inc., August 30, 1940, under Schedule 14D. 7. Bullard hydrocyanic acid gas mask. Exten sion of approval BM-1428, issued to E. D. Bullard Company, May 20, 1947, under Schedule 14D. 8. Willson chlorine gas mask. Approval BM1453, issued to Willson Products, Inc., January 20, 1953, under Schedule 14E. 9. Bullard chlorine gas mask. Extension of approval BM-1453, issued to E. D. Bullard Com pany, June 28, 1957, under Schedule 14E. 2. Type AE: Acid Gas, Dust, Mist, and Fog Masks 1. MSA industrial gas mask for chlorine, and dusts, mists, and fogs. Approval BM-14F-60, is sued to Mine Safety Appliances Company, March 29, 1961, under Schedule 14F. 2. MSA industrial gas mask for hydrocyanic acid gas, and dusts, mists, and fogs. Approval BM-14F-62, issued to Mine Safety Appliances Company, April 7, 1961, under Schedule 14F. 3. MSA gas mask with supersize canister for hydrocyanic acid gas, and dusts, mists, and fogs. Approval BM-14F-63, issued to Mine Safety Ap pliances Company, April 18, 1961, under Schedule 14F. 3. Type B: Organic Vapor Masks 1. MSA organic vapor mask. Approval BM1415, issued to Mine Safety Appliances Company, July 28, 1936, under Schedule 14D. 2. Davis organic vapor mask. Approval BM1417, issued to Davis.Emergency Equipment Com pany, Inc., May 3, 1938, under Schedule 14D. 3. Acme organic vapor mask. Approval BM1418, issued to Acme Protection Equipment Com pany, Inc., May 13, 1938, under Schedule 14D. 4. Willson organic vapor mask. Approval BM1423, issued to Willson Products, Inc., October 6, 1939, under Schedule 14D. 5. Willson organic vapor mask with large canister. Approval BM-1437, issued to Willson Products, Inc., August 5,1944, under Schedule 14E. 6. MSA organic vapor mask with supersize GMA canister. Approval BM-1441, issued to Mine Safety Appliances Company, August 2, 1946, under Schedule 14E. 7. Bullard organic vapor mask. Extension of approval BM-1423, issued to E. D. Bullard Com pany, May 20, 1947, under Schedule 14D. 8. Bullard organic vapor mask with large canister. Extension of approval BM-1437, issued to E. D. Bullard Company, May 20, 1947, under Schedule 14E. 4. Type BE: Organic Vapor, Dust, Mist and Fog Masks 1. MSA industrial gas mask for organic va pors, and dusts, mists, and fogs. Approval BM14F-56, issued to Mine Safety Appliances Com pany, February 24, 1961, under Schedule 14F. 2. MSA gas mask with supersize canister for organic vapors, and dusts, mists, and fogs. Ap proval BM-14F-57, issued to Mine Safety Appli ances Company, March 10, 1961, under Schedule 14F. 5. Type BE: Organic Vapor, Toxic Dust, Fume, Mist, and Fog Masks 1. Willson WIG-LG1-G mask for organic va pors, toxic dusts, fumes, mists, and fogs. Ap proval BM-1446, issued to Willson Products, Inc., April 17, 1950, under Schedule 14E. 6. Type AB; Acid Gas and Organic Vapor Masks 1. Davis acid gas and organic vapor mask. Approval BM-1411, issued to Davis Emergency Equipment Company, Inc., January 19, 1931, under Schedule 14B. 2. MSA hydrogen sulfide and petroleum vapor mask. Approvals BM-1416 and BM-1416A, issued to Mine Safety Appliances Company, June 16, 1937, and July 1,1937, respectively, under Schedule 14D. 3. Willson hydrogen sulfide and petroleum vapor mask. Approval BM-1444, issued to Willson Products, Inc., April 18, 1949, under Schedule 14E. 4. Willson WIG-LG3 acid gas and organic va por mask. Approval BM-1450, issued to Willson Products, Inc., March 22, 1951, under Schedule 14E. 5. Bullard hydrogen sulfide and petroleum vapor mask. Extension of approval BM-1444, is sued to E. D. Bullard Company, April 15, 1954, under Schedule 14E. 6. Bullard acid gas and organic vapor mask. Extension of approval BM-1450, issued to E. D. Bullard Company, April 15, 1954, under Schedule 14E. 7. Type ABE: Acid Gas, Organic Vapor, Dust, Mist, and Fog Masks 1. MSA gas mask for hydrogen sulfide gas, petroleum vapors, and dusts, mists, and fogs. Ap proval BM-14F-61, issued to Mine Safety :% E--06559 RESPIRATORY PROTECTIVE DEVICES 97 Appliances Company, March 29, 1961, under Schedule 14F. 2. MSA gas mask for'acid gases, organic va pors, and dusts, mists, and fogs. Approval BM14F-64, issued to Mine Safety Appliances Company April 18, 1961, under Schedule 14F. 2. MSA gas mask with supersize canister for ammonia, and dusts, mists, and fogs. Approval BM-14F-59, issued to Mine Safety Appliances Company, March 16, 1961, under Schedule 14F. 11. Type D: Carbon Monoxide Gas Masks 8. Type ABE: Acid Gas, Organic Vapor, Toxic Dust, Fume, Mist, and Fog Masks 1. Willson WIG-LG3-G acid gas, organic va por, toxic dust, fume, mist, and fog mask. Ap proval BM-1451, issued to Willson Products, Inc., March 22, 1951, under Schedule 14E. 2. Bullard acid gas, organic vapor, toxic dust, fume, mist, and fog mask. Extension of approval BM-1451, issued to E. D. Bullard Company, May 29, 1951, under Schedule 14E. 1. MSA self-rescuer. Approval BM-1447, is sued to Mine Safety Appliances Company, April 17, 1950, under Schedule 14E. 12. Type N: Universal Gas Masks a. Universal Gas Masks with Filters that Af ford Respiratory Protection against Smokes from Ordinary Fires and Limited Respi ratory Protection against Dusts, Fumes, Mists, and Fogs 9. Type C: Ammonia Gas Masks 1. MSA All-Service gas mask. Approval BM1405, issued to Mine Safety Appliances Company, 1. Acme ammonia gas mask. Approval BM- August 24, 1928, under Schedule 14A. 1420, issued to Acme Protection Equipment Com 2. McDonald All-Service gas mask. Extension pany, Inc., March 25, 1939, under Schedule 14D. of approval BM-1405, issued to B. F. McDonald 2. Willson ammonia gas mask with large Company, October 2, 1937, under Schedule 14A. canister. Approval BM-1438, issued to Willson 3. Acme All-Purpose gas mask. . Approval Products, Inc., September 22,1944, under Schedule BM-1435, issued September 30,1942, and approval 14E. BM-1435A with window indicator canister, issued 3. MSA ammonia gas mask with supersize March 30, 1960, to Acme Protection Equipment GMD canister. Approval BM-1442, issued to Mine Company, Inc., under Schedule 14E. Safety Appliances Company, August 29, 1946, un 4. Willson WUG-N1 universal gas mask. Ap der Schedule 14E. proval BM-1443, issued May 25, 1948, and ap 4. Bullard ammonia gas mask with large can proval BM-1443A with window indicator canister, ister. Extension of approval BM-1438, issued to issued June 9, 1958, to Willson Products, Inc., E. D. Bullard Company, May 20, 1947, under under Schedule 14E. Schedule 14E. 5. Bullard Multigas universal gas mask. Ex 5. MSA ammonia gas mask. Approval BM- tension of approval BM-1443, issued January 12, 1449, issued to Mine Safety Appliances Company, 1949, and extension of approval BM-1443A with December 19, 1950, under Schedule 14E. window indicator canister, issued September 3, 6. LaFrance ammonia gas mask. Extension of 1959, to E. D. Bullard Company, under Schedule approval BM-1449, issued to American-LaFrance- 14E. Foamite Corporation, March 9,1951, under Sched ule 14E. b. Universal Gas Masks with Filters that 7. Davis ammonia gas. mask. Approval BM- Afford Respiratory Protection against 1452, issued to Davis Emergency Equipment Com Toxic Dusts, Fumes, Mists" Fogs, and pany, Inc., March 29, 1951, under Schedule 14E. Smokes 8. Willson ammonia gas mask. Approval BM1454, issued to Willson Products, Inc., November 29, 1955, under Schedule 14F. 9. Acme ammonia gas mask. Approval BM14F-55, issued to Acme Protection Equipment Company, Inc., May 4, 1959, under Schedule 14F. 1. MSA All-Service Model S gas mask. Ap proval BM-1434, issued September 30, 1942, and approval BM-1434A with window indicator canis ter, issued June 9, 1958, to Mine Safety Appli ances Company, under Schedule 14E. 2. LaFrance Protexall gas mask. Extension of approval BM-1434, issued to American- 10. Type CE: Ammonia, Dust, Mist, and Fog* 10 LaFrance & Foamite Industries, Inc., March 2, Masks 1943, and extension of approval BM-1434A with 1. MSA industrial gas mask for ammonia, and dusts, mists, and fogs. Approval BM-14F-58, is sued to Mine Safety Appliances Company, March 10, 1961, under Schedule 14F. window indicator canister, issued July 28, 1958, under Schedule 14E. 3. Acme Model FD universal gas mask. Ap proval BM-1436, issued October 27, 1943, and V --06560 98 RESPIRATORY PROTECTIVE DEVICES MANUAL approval BM-1436A with window indicator canis ter, issued June 9, 1958, to Acme Protection Equipment Company, Inc., under Schedule 14E. 4. Willson WUG-N2 universal gas mask. Ap proval BM-1445, issued June 29, 1949, and ap proval BM-1445A with window indicator canister, issued October 16, 1958, to Willson Products, Inc., under Schedule 14E. 5. Bullard Smokeater universal gas mask. Ex tension of approval BM-1445, issued December 7, 1949, and extension of approval BM-1445A with window indicator canister, issued September 3, 1959, to E. D. Bullard Company, under Schedule 14E. 6. Davis universal gas mask. Approval BM1448, issued August 16, 1950, and approval BM1448A with window canister, issued October 16, 1958, to Davis Emergency Equipment Company, Inc., under Schedule 14E. 7. MSA All-Service Model S gas mask. Ap proval BM-14F-66, issued November 13, 1961, and approval BM-14F-66A with window indicator canister, issued November 16, 1961, to Mine Safety Appliances Company under Schedule 14F. c. Universal Gas Masks with Filters that Af ford Respiratory Protection against Dusts, Mists, Fogs, and Smokes 1. MSA All-Service gas mask. Approval BM14F-65, issued to Mine Safety Appliances Com pany, May 11, 1961, under Schedule 14F. C. Supplied-Air Respirators Approved Under Schedules 19, 19A, the Amendment to Schedule 19A, and 19B 1. Type A: Hose Masks with Blowers The Type A supplied air respirator (hose mask with hand-operated blower) is approved for respiratory protection in any atmosphere provided that enough respirable air is supplied to the wear er by means of the blower. 1. Davis hose mask. Approval BM-1902, is sued to Davis Emergency Equipment Company, Inc., March 30, 1931, under Schedule 19. 2. Bullard hose mask. Approval BM-1903, is sued to E. D. Bullard Company, April 14, 1933, under Schedule 19. 3. Davis hose mask. Approval BM-1904, is sued to Davis Emergency Equipment Company, Inc., October 29, 1934, under Schedule 19. 4. MSA combination hose mask. Approval BM1905A, issued to Mine Safety Appliances Company, July 2, 1935, under Schedule 19. 5. Davis hose mask. Approval BM-1906, is sued to Davis Emergency Equipment Company, Inc., August 2, 1935, under Schedule 19. 6. LaFrance Fresh-Air mask. Extension of approval BM-1905A, issued toAmerican-LaFrance & Foamite Industries, Inc., September 20, 1937, under Schedule 19. 2. Type B: Special Hose Masks without Blow ers The Type B supplied air respirator (special hose mask without blower) is approved for res piratory protection in any atmosphere from which the wearer can escape unharmed without the aid of the respirator. 1. Davis air line mask. Approval BM-1913, issued to Davis Emergency Equipment Company, Inc., March 10, 1939, under Schedule 19A. 2. Bullard Simplex hose mask. Approval BM1916, issued to E. D. Bullard Company, October 14, 1939, under Schedule 19A. 3. Type C: Air Line Respirators The Type C supplied air respirator (air line respirator) is approved for respiratory protection in any atmosphere not immediately harmful or from which the wearer can escape without the aid of the respirator. . Continuous Flow Air Line Respirators that Supply Air to Interior of Facepiece Con tinuously at a Set Rate 1. MSA air line respirator. Approval BM1909, issued to Mine Safety Appliances Company, July 15, 1938, under Schedule 19A. 2. Willson air line respirator, Models GA, GAF, GA2, GB, and GC. Approval BM-1912, is sued to Willson Products, Inc., October 7, 1938, under Schedule 19A. 3. Cesco No. 602 Healthguard direct air mask. Approval BM-1917, issued to Chicago Eye Shield Company, August 17, 1940, under Schedule 19A. 4. METCO air line respirator. Extension of approval BM-1920, issued to Metallizing Engi neering Company, Inc., December 8,-1948, under Schedule 19A. 5. Cesco No. 600 Healthguard hood. Approval BM-1925, issued to Chicago Eye Shield Company, August 16, 1950, under Schedule 19A. . MSA lead hood. Approval BM-1926, issued to Mine Safety Appliances Company, May 9, 1951, under Schedule 19A. 7. McDonald lead hood. Extension of approval BM-1926, issued to B. F. McDonald Company, September 4, 1951, under Schedule 19A. 8. McDonald lead dust helmets Nos. 177A100 and 177A100-1. Approval BM-1927, issued to B. F. McDonald Company, October 3, 1951, under Schedule 19A. 9. McDonald Dustfoe air line respirator. --06561 RESPIRATORY PROTECTIVE DEVICES 99 Approval BM-1928, issued to F. M. McDonald Com pany, August 9, 1954, under Schedule 19A. 10. MSA Dustfoe air line respirator. Exten sion of approval 6M-1928, issued to Mine Safety Appliances Company, October 4, 1954, under Schedule 19A. 11. Bullard Lite-Weight helmet, Type C sup plied air respirator. Approval BM-1929, issued to E. D.. Bullard Company, July 29, 1955, under Schedule 19 B. 12. Willson GA28 and GAHS air line respira tors. Approval BM-19B-30, issued to Willson Products Division, Ray-O-Vac Company, May 29, 1959, under Schedule 19B. 13. Acme CA mask. Approval BM-19B-31, is sued' to Acme Protection Equipment Company, October 13, 1959, under Schedule 19B. 14. MSA Lead-Foe air line respirator. Ap proval BM-19B-32, issued to Mine Safety Appli ances Company, June 28,1960, under Schedule 19B. 15. MSA Hyperflo air line respirator. Ap proval BM-19B-33, issued to Mine Safety Appli ances Company, July 18,1960, under Schedule 19B. 16. MSA Flexi-Flo air line respirator. Approv al BM-19B-34, issued to Mine Safety Appliances Company, August 30, 1961, under Schedule 19B. 17. MSA Flexi-Flo air line respiratory with Custom. Comfo facepiece for use with a welding helmet. Approval BM-19B-37, issued to Mine Safety Appliances Company, March 12,1962, under Schedule 19B. 18. MSA Flexi-Flo abrasive mask with full facepiece. Approval BM-19B-38, issued to Mine Safety Appliances Company, May 7, 1962, under Schedule 19B. 19. MSA Hyperflo air line respirator with Custom Comfo facepiece for use with a welding helmet. Approval BM-19B-37A, issued to Mine Safety Appliances Company, May 23, 1962, under Schedule 19B. 20. MSA Hyperflo air line respirator. Ap proval BM-19B-34A, issued to Mine Safety Appli ances Company, June 13,1962, under Schedule 19B. 21. MSA Hyperflo abrasive mask with full facepiece. Approval BM-19B-38A, issued to Mine Safety Appliances Company, June 14, 1962, under Schedule 19B. 22. Bullard Lite-Weight helmet, Type C sup plied air respirator. Approval BM-19B-40, issued to E. D. Bullard Company, April 30, 1962, under Schedule 19B. b. Demand Air Line Respirators that Supply Air to Interior of Facepiece Only When Wearer Inhales and at a Rate Governed by His Breathing 1. MSA demand-type air line respirator. Ap proval BM-1922, issued to Mine Safety Appliances Company,-May 27, 1949, under Schedule 19A. 2. Scott demand respirator. Approval BM- 1924, issued to Scott Aviation Corporation, Sep tember 28, 1949, under Schedule 19A. 3. Scott Model 2600 demand respirator. Ap proval BM-19B-36, issued to Scott Aviation Cor poration, February 23, 1962, under Schedule 19B. 4. Type CE: Abrasive Blasting Helmets, Hoods, or Masks The Type CE supplied air respirator (abra sive blasting helmet, hood, or mask) is approved for respiratory protection during abrasive blast ing in any atmosphere not immediately harmful or from which the wearer can escape without the aid of the respirator. 1. MSA abrasive mask. Approval BM-1907, issued to Mine Safety Appliances Company, July 15, 1938, under Schedule 19A. 2. Pangborn blast helmet, Type DD-4. Ap proval BM-1908, issued to Pangborn Corporation, July 15, 1938, under Schedule 19A. 3. Sly Purair helmet. Approval BM-1911, is sued to W. W. Sly Manufacturing Company, July 16, 1938, under Schedule 19A, and July 11, 1957, under Schedule 19B. 4. Willson No. 31 abrasive blasting helmet. Approval BM-1914, issued to Willson Products, Inc., March 10, 1939, under Schedule 19A. 5. Pangborn blast helmet, Type DF-2. Ap proval BM-1915, issued to Pangborn Corporation, March 23, 1939, under Schedule 19A. 6. Cesco No. 602 Healthguard mask. Approval BM-1918, issued to Chicago Eye Shield Company, January 4, 1941, under Schedule 19A.. 7. MSA abrasive mask. Approval BM-1920, issued to Mine Safety Appliances Company, April 30, 1948, under Schedule 19A. 8. METCO abrasive mask. Extension of ap proval BM-1920, issued to Metallizing Engineering Company, Inc., April 30,1948, under Schedule 19A. 9. Bullard No. V abrasive blasting helmet. Approval BM-1921, issued to E. D. Bullard Com pany, September 9, 1948, under Schedule 19A. 10. WiUscrn No. 51 lightweight abrasive blast ing helmet. Approval BM-1923, Issued to Willson Products, Inc., July 19, 1949, under Schedule 19A. 11. MSA Blastfoe abrasive helmet. Approval BM-1926, issued to Mine Safety Appliances Com pany, May 9, 1951, under Schedule 19A. 12. McDonald Blastfoe abrasive helmet. Ex tension of approval BM-1926, issued to B. F. McDonald Company, September 4, 1951, under Schedule 19A. 13. McDonald sandblast helmet No. 177A200 and shotblast helmet No. 177A300. Approval BM1927, issued to B. F. McDonald Company, October 3, 1951, under Schedule 19A. 100 RESPIRATORY PROTECTIVE DEVICES MANUAL 14. Bullard Lite-Weight helmet, TypeCE sup plied air respirator. Extension of approval BM1929, issued to E. D. Bullard Company, April 24, 1956, under Schedule 19B. 15. Cesco No. 603-RH, RS, RG abrasive blast ing hood. Approval BM-19B-35, issued to Chicago Eye Shield Company, January 9, 1962, under Schedule 19B. 16. MSA Flexi-Flo abrasive mask with lightor heavy-weight hood. Approval BM-19B-38, is sued to Mine Safety Appliances Company, May 7, 1962, under Schedule 19B. 17. MSA Hyperflo abrasive mask with lightor heavy-weight hood. Approval BM-19B-38A, is sued to Mine Safety Appliances Company, June 14, 1962, under Schedule 19B. 18. Bullard Model 37-V abrasive blasting helmet. Approval BM-19B-39, issued to E. D. Bullard Company, April 24, 1962, under Schedule 19B. 19. Bullard Lite-Weight helmet, TypeCE supplied-air respirator. Approval BM-19B-40, issued to E. D. Bullard Company, April 30, 1962, under Schedule 19B. D. Dispersoid (Dust, Fume, and Mist) Respirators Approved under Schedules 21 and 21A For the purpose of these approvals, the fol lowing definitions of terms are used: Dust. Dispersoids or particulate matter, smaller than 0.1 millimeter (mm) or 100 microns (ii), formedwhen solid materials are disintegrated by such processes as crushing, grinding, and abrading. Fume. Solid dispersoids formed when vapors are condensed from heated metals and other sub stances. Mist. Liquid dispersoids formed when liquid is disintegrated, as in spray coating and atomiz ing. 1. Pneumoconiosis-producing and Nuisance Dust Respirators These respirators are approved only for pro tection against the inhalation of pneumoconiosisproducing dusts and nuisance dusts, such as free silica, asbestos, aluminum, cellulose, cement, charcoal, coal, coke, flour, gypsum, iron ore, limestone, and wood. All respirators listed under Section 3 (dust respirators) and some listed under Section 4 (fume respirators) are also approved for protection against inhalation of pneumoconiosis-producing and nuisance dusts. 1. Willson bag respirator No. 400. Approval No. BM-2103, issued to Willson Products, Inc., January 21, 1935, under Schedule 21. 2. Cover No. 24 Dupor respirator. Approval BM-2111, issued to H. S. Cover, September 15, 1936, under Schedule 21. 3. Willson Rotiform respirator No. 200. Ap proval BM-2118, issued to Willson Products, Inc., December 30, 1937, under Schedule 21. 4. AO R1015 and R2015 respirators. Approval BM-2121, issued to American Optical Company, February 3, 1938, under Schedule 21. 5. Cover Dupor Skin-A-Cat respirator No. 40. Approval BM-2129, issued to H. S. Cover, July 5, 1939, under Schedule 21. 6. McDonald Dustfoe respirator. Approval BM-2132, issued to B. F. McDonald Company, August 23, 1939, under Schedule 21. (Also ap proved for protection against inhalation of pneu moconiosis-producing, chromic acid, and nuisance mists.) 7. MSA Dustfoe respirator. Extension of ap proval BM-2132, issued to Mine Safety Appliances Company, August 23, 1939, under Schedule 21. (Also approved for protection against inhalation of pneumoconiosis-producing, chromic acid, and nui sance mists.) 8. AO R9100 respirator. Approval BM-2137, issued to American Optical Company, March 6, 1940, under Schedule 21. 9. McDonald Clear-Vue Dustfoe respirator. Approval BM-2147, issued to B. F. McDonald Company, July 16, 1942, under Schedule 21. (Also approved for protection against inhalation of pneumoconiosis-producing, chromic acid, and nuisance mists.) 10. MSA Clear-Vue Dustfoe respirator. Ex tension of approval BM-2147, issued to Mine Safety Appliances Company, July 16, 1942, under Schedule 21. (Also approved for protection against inhalation of pneumoconiosis-producing, chromic acid, and nuisance mists.) 11. Cesco respirator No. 94. Approval BM2153, issued to Chicago Eye Shield Company, March 23, 1945, under Schedule 21. 12. Pulmosan S-600" respirator. Approval BM-2158, issued to Pulmosan Safety Equipment Corporation, March 1, 1949, under Schedule 21. 13. Pulmosan Mn 500 respirator. Approval BM-2159, issued to Pulmosan Safety Equipment Corporation, April 26, 1949, under Schedule 21. 2. Toxic Dust Respirators These respirators are approved only for pro tection against the inhalation of toxic dusts that are not significantly more toxic than lead, such as arsenic, cadmium, chromium, lead, manganese, selenium, vanadium, and their compounds. All respirators listed under Section 3 (dust respirators) and some listed under Section 4 -06563 RESPIRATORY PROTECTIVE DEVICES 101 (fume respirators) are also approved for protec tion against inhalation of toxic dusts. 1. Willson Rotiform respirator No. 200 L. Ap proval BM-2123, issued to Willson Products, Inc., April 18, 1938, under Schedule 21. 2. AO R1016 and R2016 respirators. Approval BM-2138, issued to American Optical Company, March 16, 1940, under Schedule 21. 3. AO R9100T respirator. Approval BM-2144, issued to American Optical Company, May 19, 1941, under Schedule 21. 3. Dust Respirators These respirators are approved only for pro tection against the inhalation of dusts that are not significantly more toxic than lead, such as arsenic, cadmium, chromium, lead, manganese, selenium, vanadium, and their compounds, and pneumo coniosis-producing and nuisance dusts. Some of the respirators listed under Section 4 (fume respirators) are approved for protection against inhalation of dusts that are not significant ly more toxic than lead. 1. Cover Dupor No. 46 respirator. Approval BM-2124, issued to H. S. Cover, October 3, 1938, under Schedule 21. 2. AO R1017 and R2017 respirators (formerly R1000AD). Extension of approval BM-2138, issued to American Optical Company, February 4, 1941, under Schedule 21. 3. Cesco Healthguard No. 94 respirator. Ap proval BM-2142, issued to Chicago Eye Shield Company, October 3, 1940, under Schedule 21. 4. McDonald Clear-Vue Dustfoe respirator. Approval BM-2148, issued to B. F. McDonald Company, July 21, 1942, under Schedule 21. 5. MSA Clear-Vue Dustfoe respirator. Ex tension of approval BM-2148, issued to Mine Safety Appliances Company, July 21, 1942, under Schedule 21. 6. Willson respirator No. 750DA. Approval BM-2151, issued to Willson Products, Inc., Octo ber 5, 1944, under Schedule 21. (Also approved for protection against inhalation of pneumoconiosisproducing, chromic acid, and nuisance mists.) 7. Willson respirators Nos. 5D and 45D. Ap proval BM-2152, issued to Willson Products, Inc., October 19, 1944, under Schedule 21. (Also ap proved for protection against inhalation of pneu moconiosis-producing, chromic acid, and nuisance mists.) 8. AO R2000 respirator. Approval BM-2154, issued to American Optical Company, January 2, 1947, under Schedule 21. 9. AO R5050 and R5050A respirators. Ap proval BM-2156, issued to American Optical Com pany, June 23,1948, under Schedule 21, and August 20, 1957, under Schedule 21A. (Also approved for protection against inhalation of pneumoconiosisproducing, chromic acid, and nuisance mists.) 10. Pulmosan L-800 respirator. Extension of approval BM-2160, issued to Pulmosan Safety Equipment Corporation, February 13, 1953, under Schedule 21. (Also approved for protection against inhalation of chromic acid mist.) 11. Willson respirators Nos. 6 and 460. Ap proval BM-2161, issued to Willson Products, Inc., June 30, 1950, under Schedule 21. (Also ap proved for protection against inhalation of pneu moconiosis-producing, chromic acid, and nuisance mists.) 12. Willson respirator No. 860. Approval BM2162, issued to Willson Products, Inc., June 30, 1950, under Schedule 21. (Also approved for pro tection against inhalation of pneumoconiosisproducing, chromic acid, and nuisance mists.) 13. DeVilbiss MSD-505 respirator. Extension of approval BM-2154, issued to The DeVilbiss Company, November 3, 1950, under Schedule 21. 14. DeVilbiss MSE-501 respirator. Extension of approval BM-2156, issued to The DeVilbiss Company, November 20, 1950, under Schedule 21, and September 18, 1957, under Schedule 21A. (Also approved for protection against inhalation of pneumoconiosis-producing, chromic acid, and nuisance mists.) 15. Pulmosan L-3100 pouch-type respirator. Approval BM-2165, issued to Pulmosan Safety Equipment Corporation, December 11, 1950, under Schedule 21. 16. Cesco No. 96 respirator. Approval BM2167, issued to Chicago Eye Shield Company, Octo ber 17, 1952, under Schedule 21. 17. MSA Dustfoe #66 respirator. Extension of approval BM-2166, issued to Mine Safety Appli ances Company, October 25, 1955, under Schedule 21. (Also approved for protection against inhala tion of pneumoconiosis-producing, chromic acid, and nuisance mists.) 18. McDonald Dustfoe #66 respirator. Exten sion of approval BM-2166, issued to B. F. McDonald Company, October 25" 1955, under Schedule 21. (Also approved for protection against inhalation of pneumoconiosis-producing, chromic acid, and nuisance mists.) 19. MSAComfo respirator with Type F filters. Approval BM-2168, issued to Mine Safety Appli ances Company, October 13, 1955, under Schedule 21A. (Also approved for protection against inhala tion of pneumoconiosis-producing, chromic acid, and nuisance mists.) 20. Willson Monomask respirator No. 600. Approval BM-2170, issued to Willson Products, Inc., January 18, 1956, under Schedule 21A. (Also approved for protection against inhalation of pneumoconiosis-producing, chromic acid, and nuisance mists.) E--06564 102 RESPIRATORY PROTECTIVE DEVICES MANUAL 21. MSA (Ltd.) Dustfoe #55 respirator. Ex tension of approval BM-2166, issued to Mine Safety Appliances Company, Ltd., Glasgow, Scot land, March 28, 1956, under Schedule 21. (Also approved for protection against inhalation of pneumoconiosis-producing, chromic acid, and nuisance mists.) 22. AO R2090 respirator. Approval BM-2172, issued to American Optical Company, July 11, 1958, under Schedule 21A. (Also approved, August 18, 1958, for protection against inhalation of pneumoconiosis-producing, chromic acid, and nuisance mists.) 23. Pulmosan C-264 respirator. Approval BM-2173, issued to Pulmosan Safety Equipment Corporation, August 26, 1958, under Schedule 21A. (Also approved for protection against inhalation of chromic acid mist.) 24. AO R5090 respirator. Approval BM-2174, issued to American Optical Company, August 18, 1958, under Schedule 21A. (Also approved for pro tection against inhalation of pneumoconiosisproducing, chromic acid, and nuisance mists.) 25. Welsh No. 7100 respirator. Approval BM2175, issued to Welsh Manufacturing Company, August 29, 1958, under Schedule 21A. (Also ap proved for protection against inhalation of pneumoconiosis-producing, chromic acid, and nuisance mists.) 26. Pulmosan L801 respirator. Approval BM21A-76, issued to Pulmosan Safety Equipment Corporation, December 11, 1958, under Schedule 21A. (Also approved for protection against chromic acid mist.) 27. Cesco No. 90-F respirator. Extension of approval BM-21A-77, issued to Chicago Eye Shield Company, January 11, 1962, under Schedule 21A. (Also approved for protection against pneu moconiosis-producing, nuisance mists, and chromic acid mist.) 4. Fume Respirators These respirators are approved for protec tion against the inhalation of fumes that are not - significantly more toxic than lead. 1. Willson respirators Nos. 780A and 880A. Extension of approval BM-2149, issued to Willson Products, Inc., August 7, 1942, under Schedule 21. (Also approved for protection against inhalation of dusts that are not significantly more toxic than lead, and pneumoconiosis-producing, chromic acid, and nuisance mists.) 2. Willson WHG-DFM respirator. Approval BM-2155, issued to Willson Products, Inc., March 1, 1948, under Schedule 21. (Also approved for protection against inhalation of dusts that are not significantly more toxic than lead, and pneumo coniosis-producing, chromic acid, and nuisance mists.) 3. MSA Comfo respirator with Type S filters. Approval BM-2169, issued to Mine Safety Appli ances Company, December 8,1955, under Schedule 21A. (Also approved for protection against inhala tion of dusts that are not significantly more toxic than lead, and pneumoconiosis-producing, chromic acid, and nuisance mists.) 4. AO R5056 and R5056F respirators. Exten sion of approval BM-2163, to cover the use of new filters, issued to American. Optical Company, February 28, 1957, under Schedule 21A. (Also ap proved for protection against inhalation of dusts that are not significantly more toxic than lead, and pneumoconiosis-producing, chromic acid, and nuisance mists.) 5. Pulmosan C-261 respirator. Approval BM2171, issued to Pulmosan Safety Equipment Cor poration, February 28, 1957, under Schedule 21A. (Also approved for protection against inhalation of dusts that are not significantly more toxic than lead, and chromic acid mist.) 5. Mist Respirators No respirators have been approved for pro tection against mists only, but several respirators have been approved for mists in combination with other dispersoids. Respirators that have been approved for pro tection against inhalation of pneumoconiosisproducing, chromic acid, and nuisance mists are listed as follows: under Section 1 (pneumoconiosisproducing and nuisance dust respirators), items 6, 7, 9, and 10; under Section 3 (dust respirators), items 6, 7, 9, 11, 12, 14, 17-22, 24, and 25; and under Section 4 (fume respirators), items 1-4. Respirators that have been approved for pro tection against inhalation of chromic acid mist are listed as follows: under Section 3 (dust respira tors), items 10, 23, and 26; and under Section 4 (fume respirators), item 5. E. Nonemergency Gas Respirators (Chemical Cartridge Respirators) _ Approved under Schedules 23, 23A, and 23B 1. Type B: Organic Vapor Respirators These respirators are approved for respira tory protection in atmospheres not immediately dangerous to life or containing not more than 0.1 per cent by volume, of organic vapors. 1. MSA twin cartridge GMA respirator, Ap proval BM-2301, issued to Mine Safety Appliances Company, June 4, 1945, under Schedule 23. 2. Willson No. 731A chemical cartridge res pirator. Approval BM-2303, issued to Willson Products, Inc., July 30, 1946, under Schedule 23. 3. Binks twin cartridge respirator, Type 8. Extension of approval BM-2301, issued to Binks E-06565 RESPIRATORY PROTECTIVE DEVICES 103 Manufacturing Company, June 18, 1948, under Schedule 23. 4. Willson No. 801 chemical cartridge res pirator. Approval BM-2302, issued to Willson Products, Inc., April 19, 1951, under Schedule 23. 5. AO R5051 chemical cartridge respirator. Approval BM-2304, issued to American Optical Company, July 19, 1949, under Schedule 23, and September 18, 1957, under Schedule 23A. 6. DeVilbiss MSE-502 chemical cartridge respirator. Extension of approval BM-2304, is sued to The DeVilbiss Company, October 19, 1950, under Schedule 23, and September 18, 1957, under Schedule 23A. 7. Cesco No. 99 chemical cartridge respi rator. Approval BM-2307, issued to Chicago Eye Shield Company, October 16, 1952, under Schedule 23. 8. Pulmosan No. C-256 chemical cartridge respirator. Approval BM-2309, issued to Pul mosan Safety Equipment Corporation, September 3, 1953, under Schedule 23. 9. Willson Nos. 741A and 841 chemical cart ridge respirators. Extension of approval BM2308, issued to Willson Products, Inc., September 3, 1954, under Schedule 23. 10. MSA Gasfoe chemical cartridge respira tor. Approval BM-2310, issued to Mine Safety Ap pliances Company, October 14, 1955, under Schedule 23A. 11. McDonald Gasfoe chemical cartridge respirator. Extension of approval BM-2310, is sued to B. F. McDonald Company, December 29, 1955, under Schedule 23A. 2. Type BE: Dispersoid and Organic Vapor Respirators These respirators are approved for respira tory protection in atmospheres that are not imme diately dangerous to life and that contain either jdispersoids (type of dispersoid stated for each respirator listed below) not significantly more toxic than lead,'or not more than 0.1 per cent, by volume, of organic vapors, or both. 1. AO R5055 chemical cartridge respirator. Approval BM-2305 for dusts and organic vapors, issued to American Optical Company, February 3, 1950, under Schedule 23, and September 18, 1957, under Schedule 23A. 2. MSA Gas-Fume respirator. Approval BM2306 for fumes and organic vapors, issued to Mine Safety Appliances Company, October 17, 1951, under Schedule 23. 3. Willson Nos. 741AD and 841D chemical cartridge respirators. Approval BM-2308 for dusts and organic vapors, issued to Willson Products,Inc., November 24, 1952, under Schedule 23.' 4. MSA Comfo chemical cartridge respirator with Static-Web filter. Extension of approval BM2301 for toxic dusts and organic vapors, issued to Mine Safety Appliances Company, June 24, 1953, under Schedule 23. 5. Cesco No. 99DF chemical cartridge res pirator. Extension of approval BM-2307 for toxic dusts and organic vapors, issued to Chicago Eye Shield Company, April 29, 1955, under Schedule 23. 6. MSA Gasfoe chemical cartridge respirator with Static-Web filter. Extension of approval BM2310 for toxic dusts and organic vapors, issued to Mine Safety Appliances Company, January 21, 1957, under Schedule 23A. 7. AO R5561 chemical cartridge respirator. Approval BM-2311 for dusts, fumes, mists, and organic vapors, issued to American Optical Com pany, October 2, 1957, under Schedule 23A. 8. Pulmosan No. C-259 chemical cartridge respirator. Extension of approval BM-2309 for dusts and organic vapors, issued to Pulmosan Safety Equipment Corporation, August 26, 4958, under Schedule 23A 9. MSA Comfo paint spray respirator. Ap proval BM-23B-12 for organic Vapors and paint, lacquer, and enamel mists, issued to Mine Safety Appliances Company, December 23, 1960, under Schedule 23B. 10. Binks paint spray respirator. Extension of approval BM-23B-12 (see item 9), issued to Binks Manufacturing Company, December 23, 1960, un der Schedule 23B. 11. AO R5051P respirator. Approval BM23B-13, for organic vapors, dusts, pneumoconiosisproducing and chromic acid mists, and paint, lacquer, and enamel mists, issued to American Optical Company, December 23, 1960, under Schedule 23B. 12. DeVilbiss MSP-503 respirator. Extension of approval BM-23B-13 (see item 11), issued to The DeVilbiss Company, January 4, 1961, under Schedule 23B. 43. Willson No. 941P paint spray, respirator. Approval BM-23B-14, for organic vapors and paint, lacquer, and enamel mists, issued to Willson Products Division, Ray-O-Vac Company, De cember 23, 1960, under Schedule 23B. 14. AO R5091P respirator. Approval BM23B-15, for organic vapors, dusts, pneumoconiosisproducing and chromic acid mists, and paint, lacquer, and enamel mists, issued to American Optical Company, December 23, 1960, under Schedule 23B. 15. DeVilbiss MSP-502 respirator. Extension of approval BM-23B-15 (see item 14), issued to The DeVilbiss Company, January 4, 1961, under Schedule 23B. 16. Pulmosan C-251 respirator. Approval 104 RESPIRATORY PROTECTIVE DEVICES MANUAL BM-23B-16, for organic vapors, and paint, lac quer, and enamel mists, issued to Pulmosan Safe ty Equipment Corporation, April 7, 1961, under Schedule 23B. II. NAMES AND ADDRESSES OF MANUFAC TURERS TO WHICH APPROVALS ON CUR RENTLY AVAILABLE RESPIRATORY PRO TECTIVE DEVICES HAVE BEEN GRANTED Acme Protection Equipment Company, 1201 Kala mazoo Street, South Haven, Michigan. American-LaFrance Corporation (formerly Am erican-LaFrance-Foamite Corporation), Elmira, New York. American Optical Company, Southbridge, Massa chusetts. Binks Manufacturing Company, 3114 Carroll Ave nue, Chicago 12, Illinois. E. D. Bullard Company, 2680 Bridgeway, Sausalito, California. Chicago Eye Shield Company, 2727 West Roscoe Street, Chicago 18, Illinois. H. S. Cover, Station A, South Bend, Indiana. Davis Emergency Equipment Company, Inc., 45 Halleck Street, Newark 4, New Jersey. The DeVilbiss Company, Toledo, Ohio. The Fyr-Fyter Company, 221 Crane Street, Day- ton 1, Ohio. Globe Industries, Inc., 125 Sunrise Place, Dayton 7, Ohio. B. F. McDonald Company, 5721 West 96th Street, Los Angeles 45, California. MetaUizing Engineering Company, Inc., 1101 Prospect Avenue, Westbury, New York. Mine Safety Appliances Company, Braddock, Thomas, and Meade Streets, Pittsburgh 8, Pennsylvania. Mine Safety Appliances Company, Ltd., Queenslie Industrial Estate, Glasgow E. 3, Scotland. Pangborn Corporation, Hagerstown, Maryland. Pulmosan Safety Equipment Corporation, 644 Pacific Street, Brooklyn 17, New York. Scott Aviation Corporation, Lancaster, New York. W. W. Sly Manufacturing Company, 4735 Train Avenue, Cleveland 2, Ohio. U.S. Divers Company, 3323 West Warner Avenue, Santa Ana, California. Welsh Manufacturing Company, 9 Magnolia Street, Providence, Rhode Island. Willson Products Division, Ray-O-Vac Company (formerly Willson Products, Inc.), Reading, Pennsylvania. REFERENCES 1. Kloos, E. J. and Pearce, S. J.: Respiratory Protective Devices Approved by the Bureau of Mines as of Oct. 16, 1958, Bur. of Mines Info. Circ. 7885, U.S. Bureau of Mines, Washington, D.C., 1959, 25 pp. -06567 Chapter 11 SPECIAL APPLICATIONS I. INTRODUCTION There are many highly toxic airborne con taminants which require a high degree of reli ability in respiratory protective devices. It must be emphasized that the U.S. Bureau of Mines does not approve filter-type respirators for protection against aerosols significantly more toxic than lead, such as (1) radioactive aerosols, (2) beryl lium dusts and fumes, and (3) pesticides such as Phosdrin. It is the purpose of this chapter to dis cuss the problems and developments relating to respiratory protective devices for such highly toxic contaminants. In addition, a unique thermal respirator and household items for emergency respiratory protection are discussed. Sections II and m discuss respirators for protection against radioactive materials and beryllium. There are many types of respirators currently available that claim to provide protec tion against these contaminants, but there is no official government agency which evaluates or ap proves such devices. Although industrial hygien ists and health physicists acknowledge the need for a high degree of protection when respirators are used, there is practically no uniformity among the devices recommended and used by these men at different locations. The recommendations made in Sections n and III are intended as interim recommendations until the Bureau of Mines or another government agency tests and approves de vices for protection against these contaminants. Sections IV and V both discuss respirators for protection against pesticides, although these two sections cover different chemicals that are applied for different purposes in different ways. The application of fumigants such as hydrocyanic acid or phosphine (aluminum phosphide) in a closed space creates inhalation hazards that prob ably are greater than those discussed in Sections II and III or elsewhere in this Manual, since the concentrations are often in the lethal range. Section V discusses the U.S. Department of Agriculture (USDA) testing program for certain pesticides and its relation to other government agency testing methods. A comparison of the Bureau of Mines test methods discussed in Chap ter 9 and the USDA test methods discussed in Sec tion V indicates the need for standardized meth ods to test respiratory protective devices. IL RESPIRATORY PROTECTIVE DEVICES FOR RADIOACTIVE AEROSOLS AND GASES The types of respiratory protective devices that will provide adequate protection against radi oactive aerosols have never been delineated, partly because of the broad scope of the problem. Radioactive aerosols include all of the elements in the periodic chart and their compounds. For ex ample, when only 1190 particles of plutonium dioxide, 1 micron (/x) tn diameter, constitute a daily tolerance level (see Table 11.1), it obviously is important to determine the exact degree of pro tection provided by a given respirator. The Bureau of Mines currently is studying this problem, but TABLE 11.1 ACTIVITIES OF INDIVIDUAL PARTICLES AND DAILY TOLERANCES FOR VARIOUS INSOLUBLE MATERIALS Isotope Natural uranium u* uass PuS9 Po Na*4 Sr80 Ra** Beryllium Lead Form UOj UO, up, PuO, Po NaCl SrO RaBr, BeO PbO Number of In Particles for Daily Tolerancea 3.49 x 10s 9.35 x 107 2.10 x 104 1.19 x 10* 0.09 2.53 10.0 173 3.54 x 10T 4.35 x 10* a. Based on the International Committee on Radia tion Protection values in Health Physics, V. 3, pp. 41-84, June 1960. Calculation based on daily air intake of 10 M3 and volume of 1m particle equal to 5.22 x 10"^ cnA 105 E-0656>8 106 RESPIRATORY PROTECTIVE DEVICES MANUAL approval of commercial respirators for such ma terials cannot be expected for some time. No official government agency evaluates or approves--for civilian use--respiratory devices for protection against aerosols significantly more toxic than lead, which include most radioactive aerosols. Commercially available devices, how ever, will protect adequately if they are carefully selected, fitted, used, and maintained. The highest degree of protection against radioactive aerosols and gases is provided by a continuous flow air line respirator or self-contained breathing apparatus that provides a positive pressure in the facepiece. Similar devices, when equipped with a demand value that operates on a reduced pressure in the facepiece, give good protection when the facepiece is properly fitted. Air-purifying respirators that function with a negative pressure in the facepiece and depend on filters and chemical canisters tc remove the radioactive contaminants provide good protection under many conditions, when their lim itations are understood (see Chapter 6, Section IV). A. History A review of the research and development work that has taken place in this field since the advent of atomic energy is interesting. During the period of the Manhattan District Project, it was recognized that respiratory pro tective devices would have to be used for uranium compounds and its many highly toxic isotopes. A contract was awarded to the University of Roches ter, where commercially available half masks, full face masks, and other devices were tested to de termine the degree of protection offered against several uranium compounds. The filters and/or cartridges were tested, the respirators were rated for wearing comfort, and commercially available devices were classified according to the degree of protection provided against uranium and its compounds. This work, conducted in 1942 to 1944, is reported by Dygert.l The information on commercial respirators reported by Dygert provided health and safety personnel with good data to choose the best avail able respirators for protection against uranium and its compounds during the early'years of the Manhattan District Project. When the U.S. Atomic Energy Commission began producing relatively large quantities of plutonium, many realized that a higher degree of respiratory protection was needed; therefore the U.S. Army Chemical Corps was asked to assist. Respiratory protective devices for protection against radioactive aerosols were provided during the Manhattan District Project by the U.S. Army Chemical Warfare Laboratories. According to Fig. 11.1. Army Chemical Corps M-9 combat gas mask equipped with the M-ll canister. (Courtesy U.S. Army Chemical War fare Laboratories, Protective Develop ment Div.) West,^ extensive tests conducted with the M-9 gas mask (Fig. 11.1) showed it to be capable of pro viding protection against radioactive dust. For protection against radioactive aerosols only, the M-ll canister, which contained activated charcoal for gases plus a filter, was replaced by the M-14 gas mask aerosol canister, which contained only a filter (see Fig. 11.2). Since 1946, the Chemical Corps has manu factured and shipped thousands of the M-14 aero sol canisters to the AEC and its contracting lab oratories. Many of the AEC laboratories use the M-9 facepiece with the M-14 aerosol canister or the M-.ll canister, which protects against aero sols and gases. Extensive efforts were made by the Chemical Corps to design the mask as -a whole, including facepiece, valves, and filters, to give a high de gree of protection. Each aerosol canister is indi vidually tested against dioctyl phthalate (DOP) to meet the Army specifications,^ which require that it allow no more than 1 in 100,000 parts of DOP particles to pass. The M-9 gas mask facepiece is provided in three sizes in an attempt to give E--06569 SPECIAL APPLICATIONS 107 Fig. 11.2. U.S. Army Chemical Corps M-14 mask aerosol filter. (Courtesy U.S. Army Chemical Warfare Laboratories, Protective.Development Div.) proper fit on the faces of adult males. For work in areas containing an appreciable quantity of highly toxic radioactive particles, per sonnel can be provided with a hood that is an ac cessory to the M-9 field protective mask. The M-3 toxicological agents gas mask hood4 is made of impermeable fabric and prevents the deposition of particulates in the hair and in the head harness of the mask, where they could be disturbed and shaken off to become a secondary respiratory hazard when the mask is removed. As described by West,2 the hood covers the entire mask except the eye lenses and canister inlet. It serves as a reservoir to hold the purified air which is exhaled through the outlet valve of the mask. Thus, the en tire face-fitting surface of the mask is enveloped in a curtain of uncontaminated air, and should minor leaks in the face seal result from facial ir regularities, only uncontaminated air would enter the mask. Such a hood is generally used as a com ponent of the M-3 impermeable protective outfit shown in Fig. 11.3. When the worker emerges from the contaminated area, he may be showered down with water before removing the hood and mask to remove any contaminated materials. When the Hanford Works started producing plutonium, they realized that they needed superior respiratory protection against this radionuclide. The M-9 mask was one of the early respirators used at this site. Before commercial respirators were used by General Electric in the Hanford Works, extensive tests of filter media efficiency were made by Adley et al. with uranium aerosols. In 1958, Adley6 described a "respirator test er" (Fig. 11.4) that measured filter efficiencies and leakage caused by the fit of the facepiece and that indicated some of the characteristics of the individual respirators. In Fig. 11.4, the respira tor tester has the panels removed to show' the mechanism. The breather pump system (A and B) was designed to simulate human respiration. A respirator is tested by mounting it on a manikin head (C) built up of latex that *has the resiliency and texture of human tissue." An inhalation tube passes from the mouth through the head and out the rear, where a high efficiency sampling filter (D) is located. A synthetic test aerosol can be in troduced into the chamber inlet (E), or the appara tus can be moved to the site of a questionable at mosphere, which may be radioactive or inert. The 108 RESPIRATORY PROTECTIVE DEVICES MANUAL Fig. 11.3. U.S. Army Chemical Corps M-3 im permeable protective outfit. (Courtesy U.S. Army Chemical War fare Laboratories, Protective De velopment Div.) results obtained with this apparatus have proven useful in providing data for the establishment of mask limits so that each type of respiratory de vice can be used with greater understanding of its characteristics and limitations. It is recognized that there is a limitation on testing face fit when only one head size of manikin is used. Additional tests made by General Electric at the Hanford Works include those by Gill7 on the penetration of respiratory protective devices by ruthenium. Morgan and Buchanan of the AEC Isotopes Division in Oak Ridge in 1952 prepared a booklet on air contamination and respiratory protection in radioisotope work. Although it contained many good recommendations, it emphasized filter effi ciency primarily. The safety and health physics personnel at the Union Carbide Nuclear Corp. purchased commercial respirators and performed their own tests to determine the degree of protec tion provided against several uranium compounds, fluorine, hydrogen fluoride, and certain other con taminants. After extensive testing, they developed what they called the ORGDP universal respirator. Canada's atomic energy project at Chalk River, because of the NRX reactor accident of De cember 1952, was uniquely dependent on respira tors to protect large crews of men dismantling and rebuilding the damaged reactor. Tait and Byington10 have reported the development of an excellent respirator program, resulting in' new, improved respirators and full face masks, conse quent on the lessons they learned. Interestingly, they found that the best respirator alone was not the answer. Since then, the authors report, they have had a "respirator officer" whose sole duty is to make certain that each worker has the right respirator and knows how to wear it and that the respirator is maintained properly. In 1958, a second accident at Chalk River, in volving the NRU reactor, provided additional in formation on the effectiveness of respirators for protection against radioactive aerosols and gases. The Canadian Army antigas respirator, which was worn in the reactor hall during decontamination, is described by White.^ This respirator was be lieved to give adequate protection against all ra dioactive aerosols and to be effective against many gases, such as radioactive iodine. A modified commercial half mask respirator, previously de scribed by Tait and Byington1 as the "modified oro-nasal respirator," was worn when workers entered the area outside the reactor hall. White reports that internal contamination of personnel occurred. He also reports that a careful study showed that many individuals who had received in ternal contamination had not worn their masks properly. Some men under the stress of the mo ment lifted the respirators from their faces in or der to speak to fellow workers. Others held them away from their faces in order to relieve respir atory distress after rapidly climbing stairs. B. Current AEC Activities In 1955, several of the -AEC contractors realized that a cooperative and uniform respira tory protective development project for the AEC was needed. The AEC organized a meeting of plutonium-using AEC contractors, at the Bureau of Mines, Pittsburgh, in February 1956. As a re sult of this meeting, the Division of Biology and Medicine of the AEC appointed a Respirator Com mittee from the various contractors, with instruc tions to investigate and recommend respiratory protective devices. In 1960, this committee pre pared and distributed design specifications for air-purifying respirators (full face and half mask) for protection against radioactive aerosols (see Appendix C). In 1959, the Division of Biology and Medicine ^-06571 SPECIAL APPLICATIONS 109 contracted with the Harvard School of Public Health to study and evaluate existing devices and to modify them or develop new devices for res piratory protection against highly toxic radioactive aerosols encountered in the nuclear industry. In the first progress_report on this respiratory eval uation project, Silverman^ lists the following items of principal concern in the achievement of the major objective: 1. A study should be made of the factors in fluencing the performance of respirators or pro tective breathing devices. These factors include pulsating air flow, facial seal, valve leakage and sealing, comfort, filter media factors, resistance, visual field, and interference with performance. 2. Initially, there should be developed an evaluation procedure for rating and qualifying per sonal protective equipment on wearers in order to determine the performance of such devices under conditions comparable to exposure to highly toxic radioactive materials such as plutonium and non radioactive materials such as beryllium. 3. An evaluation of existing types of respira tory protective equipment must be conducted in the light of AEC requirements. 4. The development and evaluation of a satis factory maximum comfort, minimum effort res piratory protective device for 8 hour (hr) daily use must be considered. In the first progress report, Silverman dis cusses: (1) development of a test method to evalu ate respiratory protective equipment; (2) evalua tion of the effectiveness of some examples of existing equipment; (3) development of devices for respiratory protection, and (4) coordination of re search efforts with other interested and responsi ble agencies. A new technique for evaluating res pirator performance, developed during the project, has been reported by Silverman.^ The technique described by Silverman is based on a comparison of coincidental air samples taken in the exposure environment and in the res pirator dead space during the inhalation phase of a test subject's respiratory cycle. Uranine was used E--06572 110 RESPIRATORY PROTECTIVE DEVICES MANUAL as the test aerosol because it has low toxicity and is detectable in micro quantities. The following procedure was used: A uranine aerosol with a geometric mean size (by count) of 0.20#x and a geometric standard de viation of 2 was continuously generated into an ex posure helmet chamber of unique design which permits djTiamic exposure of the subject in any location to aerosol concentrations of less than 4 milligrams per cubic meter (mg/M^). The cham ber design permits complete mobility of the sub ject. The uranine aerosol was collected inside and outside the respirator by sampling with membrane filters, using a lightweight miniature filter holder. A respirator sampling director, which directs con tinuous sampling outside the respirator, as well as sampling during either inhalation or exhalation inside the respirator, was developed. Uranine analysis was conducted with com mercially available equipment having a minimum detection sensitivity of 0.1 microgram per milli liter (/xg/ml). This sensitivity permits the evalu ation of respirator penetration as low as 0.05 per cent in a 10 minute (min) study with an exposure concentration of 3 mg/M^ of uranine. Total pene tration can be determined from the concentration of the aerosol inside the respirator and the res piratory minute volume of the subject. The res piratory minute volume is determined with a soap film spirometer technique. C. Commercial Devices Many respirator manufacturers meet the need for protection against radioactive and highly toxic aerosols by manufacturing high efficiency filters. The development of respirator filters has ad vanced so that adequate filters are now available for most specific uses. Most manufacturers indi vidually test each high efficiency filter against a DOP aerosol with a geometric mean size (by count) of 0.3fi, with an allowable penetration of less than 0.05 per cent. The possibility of leakage around the face piece is the main disadvantage of the half mask respirator and, to some extent, of the full face mask. One solution to such leakage is a positive pressure mask. Steps have been taken to help solve the prob lems often related to leakage: speech transmis sion and the wearing of corrective eyeglasses with a full facepiece. Voice transmission diaphragms, as well as facepiece microphones used in conjunction with battery-operated amplifiers, are now available for certain types of facepieces (see Chapter 3, Sec tion in). At least three methods of mounting cor rective eyeglass lenses inside full face masks have been developed, eliminating the need for temple bars, which cause leakage (see Chapter 3, Section m). Current development projects give promise of devices that will afford a higher degree of protec tion against radioactive aerosols under various conditions and that will be more comfortable for the wearer. Some AEC contractors currently are fitting in a gas chamber all men who must work with radio active aerosols. The mask providing the best face fit with maximum comfort is chosen from several commercial half and full face masks, thereby as suring acceptance by the workmen. D. Scope of the Problem As emphasized throughout this Manual, res pirators should never be substituted for adequate engineering and ventilation control measures. However, there will always be unusual, temporary, or emergency situations in which the other control measures will be inapplicable, impractical, or in effective, and in which respirators must therefore be used. Industrial and laboratory operations em ploying radioisotopes encompass practically every conventional industrial operation. In addition there are unusual problems related to reactor work, bomb tests, operation and servicing of marine nuclear engines, nuclear rocket engines, and many other specialized applications. Exposures to radioactive aerosols range from routine maintenance work to emergency situations, such as fires or explosions with pyrophoric radio active metals, ruptured reactor fuel elements, reactor explosions, and radioactive source leaks. Radioactive contaminants may be in the air as dusts, fumes, mists, or gases, often in conjunction with nonradioactive toxic chemicals. It is logical to consider respirators for radioactive airborne contamination by classification according to the type of contaminant and the degree of toxicity, as > in the following section. E. Interim Recommendations for Respirators to Provide Protection Against Radioactive Aero sols and Gases 1. Dusts and Fumes of Extreme Toxicity For dusts and fumes of such extreme toxicity as plutonium-239, polonium-210, and strontium90, the minimum protection is a well designed full face mask with high efficiency filter. The men wearing these devices must be carefully trained id their use after they have been fitted and the need for the respirator has been explained to them. Health and safety personnel of AEC contractors have adopted a full face maskwith a high efficiency filter as minimum protection against plutonium E-06573 SPECIAL APPLICATIONS 111 aerosols. A full face respirator with high effi ciency filter is recommended as the minimum pro tection that should be used for extremely toxic ra dioactive aerosols in air concentrations up to 50 times the threshold limit value (TLV). Above 50 times TLV, supplied air masks and suits, or selfcontained breathing apparatus that provide a posi tive pressure in the facepiece, should be used. (Fifty times TLV has been calculated as the best interim recommendation. The upper limit for a full face mask currently used by AEC contractors varies from 20 to 100 times TLV). 2. Dusts and Fumes of Moderate Toxicity For dusts and fumes that are significantly more toxic than lead but several orders of magni tude less toxic than plutonium--such as enriched uranium and fission products--the following in terim recommendations are made. They are con sistent with those made by an AEC contractor^ in 1958. 1. The upper limit of airborne contamination against which the half mask respirator offers suit able protection should be five times TLV. Because any given model of a half mask respirator is made in one size only, certain individuals with extreme or unusual facial contours obviously cannot be fitted perfectly with a half mask respirator. Al though a perfectly fitted respirator with tight straps and a high efficiency filter or cartridge has a moderately low penetration of contaminant (gen erally less than 5 percent and possibly 1 percent), it is impossible to give one figure defining the ef fectiveness of a half mask respirator for all work men under varying conditions. Therefore, an upper limit of the contaminant concentration in which half mask respirators may be worn should be estab lished. Before a qualified individual issues half mask respirators, he should assure himself that the possibility of the level of airborne contamina tion exceeding five times TLV is extremely re mote. If there is any doubt about this level, full face masks or supplied air equipment should be provided. 2. Full face masks should be used only when the concentration of the atmospheric contaminant is under 50 times TLV, although full facepieces may be worn safely in higher concentrations if they are expertly fitted (by individual leakage test) and if the wearer cares more for his safety than for his comfort. 3. For air concentrations of radioactive con taminants above 50 times TLV, supplied air res pirators or self-contained breathing apparatus should be worn. For maximum protection, a type providing a positive pressure in the facepiece should be used. 3. Radioactive Gases Tritium or hydrogen-3 as a gas cannot be re moved by any of the air-purifying devices on the market. For adequate protection against tritium, only supplied air respirators or suits, and/or selfcontained breathing apparatus, should be used. Because tritium water vapor in high concentra tions can be absorbed readily through intact skin, only a supplied air plastic suit gives adequate protection. The integrity of vinyl plastic suits in tritium atmospheres has been discussed by Butler and Van Wyck.^ One of the more common radioactive gases is radioactive iodine. Adams and Browning^ have shown that iodine can be absorbed or removed by an activated charcoal filter with an efficiency up to 99.99 per cent. The life expectancy of the ac tivated charcoal cartridge, related to quantity of sorbent and concentration of iodine, must be con sidered. The maximum permissible concentrations of the noble gases argon, krypton, and xenon- are based on the dose delivered to the whole body when submerged in air containing this concentration. Hence, respiratory protection against these gases is of no value. Such gases dissipate rapidly and are unlikely to be present in excessive quantities in an atmosphere containing mixed fission prod ucts. 4. Fission Products Fission products include dusts, fumes, and gases and are usually associated with nuclear ac cidents or with bomb tests. They may be present, of course, during routine reactor operations such as removing spent fuel elements and chemical processing of spent fuel elements. It is recognized that no air-purifying device will completely re move mixed fission products including gases; how ever, supplied air respirators or the Army M-9 masks with the M-ll canister (or equivalent) are considered satisfactory protection for routine ex posures. For emergency situations," only selfcontained breathing apparatus should be used. During many recovery operations following bomb detonations, a full face mask with a high ef ficiency filter has proven effective because the gaseous fission products have dissipated with the bomb cloud. No internal contamination has been detected for personnel involved. Minimum personal respiratory protection during the handling and processing of spent fuel elements should be a full face mask equipped with a combination high efficiency filter and activated charcoal canister to remove particulates and iodine. This type of device is satisfactory for de contamination following a reactor accident, pro vided the personnel have been properly fitted and 112 RESPIRATORY PROTECTIVE DEVICES MANUAL instructed in use of the respirator. To be worn properly under stress, the respirator must have moderately low resistance to inhalation and it should be equipped with a speaking diaphragm. F. Information Service If any questions about the selection, use, or care of respiratory devices for protection against radioactive aerosols are not covered in the Man ual, they should be referred to the Division of Op erational Safety of the AEC in Washington, D.C. m. RESPIRATORY PROTECTIVE DEVICES FOR BERYLLIUM Breslin and Harris describe some unusual problems encountered in a beryllium processing plant. Some soluble beryllium salts, such as beryllium fluoride and ammonium beryllium fluoride, are recognized skin irritants, and dust deposited on the skin from a heavy suspension in the air provokes a skin reaction. Material ac cumulated where the respirator contacts the face also causes dermatitis, and respirators worn in irritant dust atmospheres must be washed daily. Some. manufacturers supply respirator coverlets, cotton cloths that fit around the facial contact sur face of the respirator, but they are not recom mended because they prevent an airtight seal at the periphery of the facepiece. A. Background Information Respiratory protective devices for beryllium are especially important because of beryllium's high toxicity. The Bureau of Mines has not ap proved any device for respiratory protection against any particulate contaminants significantly more toxic than lead, and beryllium and its com pounds are many times more toxic than lead. Commercially available devices, however, provide reliable respiratory protection if they are care fully selected, fitted, used, and maintained. The control necessary for beryllium and its compounds is best emphasized by the permissible level of beryllium concentration in air. In 1949, the AEC Advisory Committee on Beryllium Intoxi cation proposed the following concentration limits for beryllium: 1. The in-plant daily weighted average expo sure to atmospheric beryllium should not exceed 2 ' micrograms per cubic meter (/ig/M^) average concentration throughout an 8 hr day. 2. Even when the daily weighted average is within the above limit, no person should be ex posed to a concentration greater than 25 ng/M^ for any period of time, however short. The permissible level of 2 was adopted as a threshold limit value in 1956 by the ACGIH" but the short term tolerance was not. The AEC Advisory Committee's setting of a short term tolerance level is unique in industrial hygiene practice and has caused considerable misunder standing regarding the type of respiratory protec tive device to use. Breslin and Harris* note that occupational disease at facilities operated under contract to the AEC has been avoided by adhering to the exposure criteria set in 1949. A few mild acute occupational respiratory cases (chemical tracheitis) have occurred where the limits were exceeded temporarily. The limitations and pitfalls of respirators for protection against beryllium are discussed by Breslin and Harris, who recom mend that their use be held to a minimum and carefully regulated. B. Interim Recommendations for Respirators to Protect against Beryllium and Its Compounds The following interim recommendations for the selection of respiratory devices for protection against beryllium and its compounds are made un til the Bureau of Mines tests and approves such devices and the devices become available com mercially. 1. Half Mask Respirators (Air-purifying Type) A maximum air concentration should be set, which should not be exceeded when a half mask respirator is worn, because such a mask provides only limited protection. A half mask respirator with high efficiency filter can be used safely when the atmospheric concentration of beryllium does not exceed 25 ng/h/fi, provided the facepiece is fitted to give an airtight seal. The original recom mendation (see Appendix B) that use of a half mask respirator be restricted to a concentration of 10 times TLV places the upper limit at 20 ng/M?. For beryllium, it is more practical to use 25 /ig/M , because this is the short time tolerance level recommended by the AEC Advisory Com-\ mittee and is a convenient guide line. Estimating this tolerance level each time a worker enters a beryUium processing area is dif ficult; therefore the following selection guide is suggested. A half mask respirator equipped with a high efficiency filter may be used during short ex posures (less than 4 hr) for protection in unven tilated operations if high concentrations of air borne particulates (greater than 25 iig/Mp) are judged improbable. Note: Some manufacturers assert, in writing, that certain commercial half mask respirators with high efficiency filters protect against beryl lium. The manufacturers make this claim for the complete respirator when actually the degree of efficiency for removing particulates applies only to the filter itself. Because of leakages around the "06575 SPECIAL APPLICATIONS 113 facepiece and other factors, the efficiency of a respirator in actual use may be far less than the efficiency of its filter under test conditions. Half mask respirators should be used with the understanding that they are not currently approved by the Bureau of Mines for protection against beryllium and should be selected only by quali fied industrial hygienists experienced in this field. 2. Full Face Respirators (Air-purifying Type) Although leakage around the face is possible with the full face mask, a good fit can be achieved in a higher per cent of cases than with the half mask respirator because the full face type is fitted to a portion of the face where there is less indi vidual variation. Less than 0.1 per cent over-all penetration may be obtained with a properly fitted full face respirator. However, because of the dif ficulty in fitting all types of faces with commercial masks in a single size, full face masks should be restricted to atmospheric concentrations where the contaminant does not exceed 100 iig/M^. If the individual selecting the device does not have a high degree of confidence that a level of 100 lig/wfi will not be exceeded, he should select a supplied air respirator rather than a full face mask. 3. Supplied Air (Air Line) Respirators Two types of supplied air respirators are available commercially: demand and continuous flow. The constant flow air line respirator ap proved by the Bureau of Mines (for all atmos pheres except oxygen deficiency) gives greater protection, although similar devices of the demand type may be worn safely if the workmen are prop erly trained in their use and expertly fitted so that there is a gas-tight seal. A competent individual should supervise both the selection and the use of air line respirators and periodically should re train workers who use such respirators. A posi tive supply of pure air through the respirator is vital (this problem is discussed in more detail in Chapter 7). IV. RESPIRATORS FOR PROTECTION DURING FUMIGATION A. Defining the Problem Fumigation is the process of disinfesting by dispersing a pesticide (in the form of a vapor, gas or solid) into a closed space, as opposed to the spraying of pesticide aerosols in open areas. Hy drogen cyanide, the most widely used fumigant in the past, is the standard to which all other fumi gant gases are compared. Respirators for protection against fumigants are now (1962) included in the U.S. Department of Agriculture's project of testing and recommending respiratory protective devices for protection against pesticides (see Section V). The USDA tests respirators only against such pesticides as Systox, Parathion, TEPP, Phosdrin, Aldrin, Chlordane, and Dieldrin--chemicals which usually are pre pared with carrier substances no more toxic than xylene. The Bureau of Mines is the only govern ment agency which tests and approves respiratory equipment for protection against hydrogen cyanide, methyl bromide, carbon disulfide, and carbon tetrachloride, which are commonly used as fumi gants. This difference is emphasized because ill nesses and even fatalities have resulted from mis understanding by some fumigant manufacturers and fumigators about the selection and use of res pirators for protection against this type of pesti cide. The confusion in the term * pesticide" obvi ously accounts for some of the trouble. According to deOng,^ all chemicals used as pest control agents are officially termed "pesti cides," including insecticides, repeUents, fungi cides, seed protectants, herbicides (weed killers), and rodenticides. Obviously, then, one cannot se lect and use a respirator for protection against " pesticides" in general; one must know the chem ical name, the method of dispersing, and the phy sical and toxicological properties of the individual pesticide. The respiratory devices-for protection against pesticide fumigants, used for fumigating buildings and stored grain, are discussed in this section. 4. Self-contained Breathing Apparatus Respirators for normal or nonemergency use are discussed in general above. In emergencies, or when a brief exposure to a high concentration may be hazardous or even potentially lethal, only self-contained breathing apparatus approved by the Bureau of Mines should be used, and thorough training should be given to the expected users of these devices (see Chapter 13 for a discussion of this-training). B. Current Practice A typical fumigant (Fumigant No.'3, used in the fumigation of stored, shelled corn) is de scribed by Paulus.l It consists of 80 per cent carbon tetrachloride and 20 per cent carbon di sulfide. He reports that the total vapor concentra tion in the breathing zone of the fumigator while fumigating 18 ft cylindrical bins of corn during an industrial hygiene survey., was over 20,000 parts per million (ppm) for carbon disulfide and carbon tetrachloride. The respiratory protective 114 RESPIRATORY PROTECTIVE DEVICES MANUAL equipment used during the fumigation with this mixture was a full face mask with organic vapor canister. Paulus notes that such a canister as ap proved by the Bureau of Mines is effective in at mosphere containing up to 2 per cent (20,000 ppm) organic solvent vapor for a period of 30 min at this concentration, or for an equivalent time-- concentration value. When fumigating a storage bin, a man stands on a ladder at the top of the bin and sprays with liquid fumigant through an open hatch. Paulus re ports that for corn about 18 gal of fumigant is sprayed into the 18 ft diameter bin at a rate of from 3 to 4-1/2 gallons per minute (gal/min). At these concentrations the vapor stream often is concentrated enough to impart a cooling sensation to parts of the body which it contacts. Paulus makes a series of recommendations for the safe fumigation of shelled com, which in clude the following for the selection and use of respiratory devices: 1. Each member of the fumigation crew should be provided with a Bureau of Mines approved full face gas mask and organic vapor canister. The mask should be donned and checked for leaks be fore fumigation starts and should not be removed until the crew member leaves the area of high va por concentration. If the crew member detects the odor of solvent while wearing the mask, he should leave the area immediately. 2. Bureau of Mines approved devices with the gas mask canister worn on the fumigator's back rather than on his chest are preferable, because they keep the canister out of the heaviest vapor concentration and increase its useful life. 3. After fumigation the bins should not be en tered without a mask for at least seven days. 4. Under no circumstances should a half mask, chemical cartridge respirator be used during fumigation. Although these recommendations are made for the fumigation of shelled com with a mixture of carbon disulfide and carbon tetrachloride, they are applicable to the fumigation of any grain with' any chlorinated hydrocarbon. There should be a stand-by man when the operator is fumigating. McCoHister* reports on the comparative in halation toxicity of fumigant mixtures known as Dowfume 75, EB-5, and EB-15, which contain ethylene dichloride, carbon tetrachloride, and ethylene dibromide in varying percentages. He recommends that exposures to Dowfume 75 should not exceed 100 ppm for a 7 hr exposure. Adams,2 during an industrial hygiene survey of flour mills and bakeries, found concentrations of the fumigant mixture EB-15 up to 200 ppm 30 min to 12 hr after application of the fumigant; however, all the values were below 75 ppm when work was resumed the next day. Certainly, very high concentrations of fumigant exist during fumigation, and adequate respiratory protective devices should be used. Phosphine is used in grain fumigation under the name of Phostoxin. It is introduced (in pellet form as aluminum phosphide) through probes forced into the grain. Phostoxin releases poison ous gas when moist. The claim is made that no mask equipment is needed because the evolution of phosphine is within the stored grain and because phosphine is heavier than air and should settle to the bottom. However, due to the high toxicity of phosphine, anyone entering into an area which has had the gas in it and which has not been thoroughly ventilated should wear a universal canister. In a U.S. Department of Labor bulletin, John son2* describes the mass attack on grain fumiga tion deaths by the Kansas State Board of Health and the Kansas State Department of Labor, after six deaths and 17 cases of illness in five years from fumigants. The program was sparked by the death of a 26 year old grain worker on his wedding eve. Johnson emphasizes the cooperation of the many state agencies, the federal agencies, and the grain handlers themselves toward achieving a good health and safety program for the protection of workmen handling fumigants. At a Kansas State University conference22 to encourage safe use of fumigants, Dr. W. F. von Oettingen (consultant, U.S. Public Health Service) warned that some persons lose awareness of an odor after smelling it for a short while. He also emphasized that some fumigants are virtually odorless, and some are absorbed through the skin, paralleling inhalation as a mode of poisoning. At the same conference S. J. Pearce (Bureau of Mines) discussed common errors in the use of gas masks, including the wearing of a dust mask dur ing fumigation, the use of a mask which either is no longer effective or is the wrong kind for a par ticular fumigant, and the wearing of an old mask which leaks or does not fit. Pearce warned also against the danger of entering a gas concentration ^ higher than the protective limits of any ^s mask. These limits are discussed in* Chapters 5 and 6. A similar conference was held in Texas in 1961. Mayes22 comments on the death of a fumigator who was wearing a commercial respirator which had been tested and accepted by the USDA for protection against pesticides. The USDA re leases on respiratory devices specifically state: * Respirators [chemical cartridge respirators] do not provide needed protection from inhalation of pesticide dust, mist, and vapors for use by (1) Those formulating or mixing pesticides in closed or inadequately ventilated spaces. (2) Those applying pesticides, including aerosols, in green houses. Fullface gas masks equipped with tested canisters should be worn under these conditions." The important safety fact in this case is that, j E-06577 J SPECIAL APPLICATIONS 115 although the respirator was approved by a govern ment agency, the user did not know that the fumi gant he was using (containing more than 70 per cent carbon tetrachloride) was not among those pesticides for which the respirator was approved or accepted. Moreover, the supplier of the fumi gant also had supplied this type of respirator--a very sorry situation, indeed. Mayes states that the problem of protecting fumigators is aggravated further by the reported distribution in Kansas of inadequate World War n surplus gas masks. A warning bulletin (Fig. 11.5) was distributed throughout the state, with an ap propriate news release for all newspapers in the state, cautioning against the use of the surplus masks. Even after one near fatality at a grain storage house, involving one of the war surplus masks illustrated in that bulletin, a chemical com pany still advertised a sales package, aimed pri marily at the farm market, in which one of the war surplus masks was given free with each pur chase of liquid fumigant. In March, 1960, the Kansas State Department of Labor issued a bulletin 24 establishing stand ards of safety and health protection procedures in fumigation operations. The standards for the use of respiratory protective devices state: "Approved personal protective equipment shall be furnished by the employer, that will provide adequate pro tection against the specific hazards involved in the particular fumigation operation. Approved per-: sonal protective equipment shall be only that equipment approved (and marked as approved) by the U.S. Bureau of Mines for the particular chem ical or hazard for which it is to be used." The standards of the Kansas Department of Labor also include a section on training which re quires that each employer shall conduct training and education programs sufficient to provide suit able instruction to all employees who will be handling and using fumigating chemicals. When ever possible, employees shall have on-the-job instruction and training with the actual chemical and with the protective devices and personal pro tective equipment which they will use in their fumigating operations. A California occupational health bulletin^ recommends that employees who dispense or test methyl bromide be equipped with approved (Bureau of Mines) respiratory protection, either supplied air respirators or canister masks specifically ap proved for methyl bromide. (The Bureau of Mines has not approved any gas masks specifically for methyl bromide.) If gas masks with canisters are used,' the bulletin notes the following precautions: (1) no canister will protect against concentrations of methyl bromide over 5 lb per 1,000 ft^ (2 per cent); and (2) a regular size, organic vapor can ister used in a methyl bromide concentration of 3 lb per 1,000 ft^ (1.2 per cent) affords protection for only 15 min. The capacity of activated char coal for methyl bromide is much less than for CC1, which is the reason for the suggested time limit precaution. In his book,*1* deOng recognizes the impor tance of proper respiratory protective equipment during fumigation and recommends that only Bureau of Mines approved devices be used. In his discussion of gas masks, he states that carefully fitted masks should be insisted upon'for anyone exposed to even moderate concentrations of hydro gen cyanide, chloropicrin, cyanogen chloride, and other quick-acting fumigants. He also advises the wearing of masks when subjected to higher con centrations or long exposure to nicotine fumes, ethylene oxide, methyl bromide, methyl formate, ethylene dichloride, carbon disulfide, carbon tetra chloride, and other organic fumigants. Determining when a canister is no longer ef fective against a gas is a most serious problem, especially when a gas or vapor has few or no warning properties. Many gases warn of impending failure of a canister by their odor, taste, or irri tating effect on eyes, nose, or throat. For exam ple, a person who has been wearing a gas mask for some time in an ammonia gas--air atmosphere knows, when he detects the odor of the gas, that the canister is exhausted and he should return to fresh air immediately to replace the canister. However, gases like methyl bromide and hydrogen cyanide give no such warning. There have been several instances in which workers wore gas masks while fumigating with methyl bromide, and yet, unaware that any gas was coming through the exhausted canister, breathed enough methyl bro mide to affect them seriously or fatally. There are available on the market mixtures of methyl bromide with chloropicrin. It has been found that chloropicrin is absorbed by organic materials at a greater rate than is methyl bromide, making it entirely possible to lose the warning properties from these mixtures during use. -A second problem is the use of -canisters in vapors and gases which cannot clearly be detected by odor. An example is hydrocyanic acid. This material may be easily detected by odor at low concentrations by some individuals, but the odor is not reliable to warn the user that the canister is exhausted because of olfactory fatigue. Most men become used to the odor, and the odor thres hold will effectively move up the scale by some unknown factor as the exposure continues. It is likely that the user will fail to detect concentra tions which may be harmful even in a short period of time. Many of the fumigants, such as hydrocyanic acid and acrylonitrile, may be absorbed through the skin in toxic quantities. Also, many of the i 5 i i: j h ?I f S' S I i;> E-06578 116 RESPIRATORY PROTECTIVE DEVICES MANUAL WARNING BEWARE OF THESE GAS MASKS The gas masks pictured above are reportedly being distributed in Kansas. Beware of them! They can be potential killers! NOT SAFE FOR USE WHILE FUMIGATING GRAIN IN CONFINED AREAS SMALL CANISTER EFFECTIVE ONLY A FEW MINUTES USE MASKS, BUT ONLY THOSE APPROVED BY THE U. S. BUREAU OF MINES AND IN GOOD CONDITION IF IN DOUBT AS TO THE SAFETY OF A MASK CONTACT ANY OF THE AGENCIES LISTED BELOW: K.uis.in Mate Board of Agriculture .n.i. '.it,- '-..`.-ti Coimcil Kansas State Board of Health Kansas Slate Department of Labor Fig. 11.5. Warning bulletin on dangers of using surplus military masks. -06579 SPECIAL APPLICATIONS 117 fumigants are skin irritants, especially in high concentrations. These irritants also are severely hazardous to the eye, and eye protection should always be provided during fumigation. Several of the fumigants are potential fire and explosive hazards. Benzene and carbon disulfide are well-known fire hazards. Fumigant manu facturers have used chlorinated hydrocarbons to reduce this type of hazard. Many fumigators insist that fresh canisters be used when either methyl bromide or hydrogen cyanide is being applied. Then these canisters must be discarded and fresh canisters attached to the masks before workmen re-enter a fumigated area to air it out. Tn this enlightened attitude no attempt is made to squeeze the last bit of life out of a canister, with resultant possible injury or even death to the wearer. The problems and hazards encountered dur ing fumigation are summarized here for clarity. It is emphasized that highly toxic and volatile chemicals are used to fumigate closed spaces such as buildings and grain storage bins. The concern in regard to these chemicals is due to the fact that they (1) are encountered in exceedingly high concentrations, (2) may be odorless or cause ol factory fatigue, (3) may be absorbed through the skin, (4) may affect the eyes and require eye pro tection, and (5) could create fire and explosive hazards. There has been confusion regarding the term "pesticide," especially in the selection and use of respiratory protective devices. It is very impor tant to identify the chemical or chemicals used as fumigants to permit the proper selection of a gas mask canister. The Bureau of Mines tests and ap proves gas masks specifically for respiratory protection against hydrocyanic acid gas and am monia gas and generally for respiratory protection against gases or vapors classed as organic vapors or acid gases. See Table 11.2 for type of gas mask to be used for respiratory protection against spe cific fumigants. The U.S. 'Department of Agriculture tests canisters only against specific organic compounds used as insecticides for open field spraying and aerosols for use in greenhouses and non-ventilated areas. New chemicals that present special problems are being introduced as fumigants before there has been time to test and approve canisters to protect against them. An example is Vikane (sulfuryl fluoride), a new fumigant recently released by Dow. It was first thought that an acid gas--or ganic vapor canister might have an adequate ab sorptive capacity, but this was not the case. The Dow Chemical Company has tested various can isters submitted by manufacturers and found only specific ones to be effective. In order to be sure that fumigators could be provided with adequate gas mask canisters to protect against Vikane, Dow has listed on the fumigant label those canisters found effective. For advice on respiratory protective devices for new or unusual fumigants, consult a responsi ble respirator manufacturer, the basic supplier of the chemical, or the Bureau of Mines and the USDA. A vital factor in respiratory protection is the length of time that a canister can be safely used. There are many varying factors that determine the life of a canister, including concentration of the contaminant, quantity and type of sorbent, humidi ty, and breathing rate. These factors are dis cussed in detail in Chapters 5, 6 and 9. The Bureau of Mines tests organic vapor canisters against vapors and requires a minimum 30 min life when canisters are worn by men performing a prescribed schedule of exercises. An increase in relative humidity may decrease the life of the sorbent (see Chapter 5, Section III). Surplus military gas masks should not be used for protection during fumigation (see discussion of surplus respirators in Chapter 1). C. Recommendations for Respiratory Protective Devices for Protection during Fumigation It is strongly recommended that only ap proved Bureau of Mines personal protective de vices of the full face type be used for protection during fumigation. Each device should be spe cifically approved by the Bureau of Mines for the particular chemical or hazard for which it is to be used, noting, first, that the Bureau of Mines tests and approval restrict the organic vapor canisters to use in a maximum gas concentration of 2 per cent (20,000 ppm), and, second, that at this maxi mum concentration, the canister life is approxi mately thirty minutes. If the air concentration of fumigant is known or estimated to exceed 2 per cent, a self-contained breathing, apparatus is recommended. A fresh canister should be used when hydro gen cyanide, methyl bromide, or ethylene dichlor ide is applied. Before workmen re-enter a fumi gated area to air it out, the canister used to fumi gate should be discarded and a fresh canister at tached to the mask. It is good practice to check the air concentration to see if it is safe to enter, especially when using hydrogen cyanide. Reliable chemical detectors are available from several safety equipment manufacturers. Because of the complex nature of the hazards involved in fumigation, all fumigators should con sult the USDA, or their State Industrial Hygiene Department, and follow their advice on application and hazards involved. For information on the E--06580 118 RESPIRATORY PROTECTIVE DEVICES MANUAL TABLE 11.2 TYPES AND COLORS OF GAS MASK CANISTERS TO BE USED FOR RESPIRATORY PROTECTION AGAINST SPECIFIC FUMIGANTSa Fumigant Odor*5 Type of Canister^ Color of Canister** Acrylonitrile Ammonia Benzene Carbon dioxide Carbon disulfide Carbon monoxide Carbon tetrachloride Chloroform Chloropicrin Ethylene bromide Ethylene dichloride Ethylene oxide Hydrocyanic acid Methyl bromide Methylene chloride Phosgen'e Phosphine Sulfur dioxide Sulfuryl fluoride Trichloroethylene NR Good NR None NR None NR NR Good NR NR NR NR None NR Good NR Good None NR Organic vapor Acid gas and organic vapor Ammonia Organic vapor Acid gas and organic vapor None Organic vapor Acid gas and organic vapor Universal Organic vapor Acid gas and organic vapor Organic vapor Acid gas and organic vapor Organic vapor Acid gas and organic vapor Organic vapor Acid gas and organic vapor Organic vapor Acid gas and organic vapor Organic vapor Acid gas and organic vapor Hydrocyanic acid Acid gas and organic vapor Organic vapor Acid gas and organic vapor Organic vapor Acid gas and organic vapor Acid gas and organic vapor Universal Acid gas and organic vapor Specific canistere Organic vapor Acid gas and organic vapor Black Yellow Green Black YeUow -- Black Yellow Red Black YeUow Black YeUow Black YeUow Black YeUow Black YeUow Black YeUow White with green stripe YeUow Black YeUow Black YeUow YeUow Red YeUow -- Black YeUow a. The universal gas mask canister will remove all of these fumigants (except sulfuryl fluoride) but would not be the canister of choice except in the two instances indicated. b. *NR" indicates odor not reliable to determine when canister is exhausted. c. Standard canister volume for organic vapors is 1,000 cm3; super canister contains 2,000 cm3. Stand ard canister for acid gas and organic vapors contains 1,500 cm3. d. The primary method of identifying canisters is to read the label. A secondary method is the color code. e. Use only canisters specifically recommended against sulfuryl fluoride. E--06581 SPECIAL APPLICATIONS 119 correct selection, use, and care of respiratory protective devices, fumigators should contact the Branch of Health Research of the U.S. Bureau of Mines, the USDA, or a responsible respirator manufacturer. The proper canisters for respiratory protec tion against specific fumigants are listed in Table 11.2. It should be noted that several of the fumi gants listed may cause eye irritation and require eye protection. Such protection is provided by full facepiece devices. Also, some of the fumigants are fire and explosive hazards. The volume of sorbent used for some canisters is noted. The standard organic vapor canister (1000 cm3) provide protection the same length of time as the super size acid gas--organic vapor canister (2000 cm) against the same concentration of carbon tetra chloride. V. RESPIRATORS FOR PROTECTION AGAINST INSECTICIDES B. USDA Respirator Program The USDA respirator filter and cartridge test ing program has been described by Fulton.>8 The USDA tests the filter and sorbent and in 1962 the complete respirator. The Bureau of Mines tests and approvals also (see Chapter 9) take cognizance of the performance of a completely as sembled device. The USDA began respirator testing to meet an immediate need, and their efforts have protected many workers against specific pesticides. Since Chapter 9 contains a detailed discussion of the Bureau of Mines test procedures, it is obviously necessary to acquaint the industrial hygienist with the USDA test procedures also. It should be noted that the manufacturers or packagers of pesticides are required by law (1956 Federal Pesticides Act) to have an adequate precautionary label on the package, including a direction on the label such as "use a mask or respirator passed by the USDA for (parathion, endrin, etc.) protection.* A. Background Information The U.S. Department of Agriculture is the only government agency that has tested and found satisfactory commercially available respirators and gas masks as being effective for protection against the following classes of pesticides: in secticides, fungicides, and nematocides. Fulton and Smith note that in 1947, when the first organic phosphorus insecticides were tested, none of the respiratory protective devices com mercially available had been proved to afford pro tection to the operator. In 1946, Schulte? reported on the misuse of "dust" type respirators for pro tection against the volatile organic mercury com pounds used in seed treating. In 1949, several government agencies that were concerned over the inhalation hazard to op erators applying dusts, sprays, and aerosols of parathion called a conference which resulted in a co-operative program for the development of respirators and gas masks. Manufacturers of in secticides and respirators worked with the former Bureau of Entomology and Plant Quarantine of the USDA, which developed tests for determining the effectiveness of experimental filters and sorbents against insecticides. In 1950, Fulton listed com mercially available respirators and canisters for protection against dusts, mists, and low vapor concentrations of parathion. As new insecticides were introduced, the USDA continued to release lists of commercial respirators tested and found effective against spe cific insecticides, fungicides, and nematocides. A current release3 (ARS-33-76) from the USDA Agricultural Research Service (Sept. 1962) is re produced in Appendix D. 1. Test Methods The chemical analytical procedures for in secticide aerosols which pass a filter or sorbent are rather involved, except those for malathion and parathion. These are the only organic phos phates tested by chemical analysis. The chlori nated hydrocarbon insecticides are analyzed by published methods of the Association of Official Agricultural Chemists. Filters and sorbents against fungicides and nematocides which are dis cussed by Fulton and McClelland31 and classified as (1) carbamates, (2) mercury compounds, (3) halogenated hydrocarbons, (4) copper com pounds, and (5) phenoxy compounds are tested by published chemical analytical procedures. Except for parathion, which may be tested either by a chemical or a bioassay method, and malathion, most organic phosphates are checked only by bioassay, because there are no satisfactory_ chemical procedures for determining the amount of organic phosphate insecticides in the air passing through a filter. Aphids and mites re act rapidly to most organic phosphorus compounds; therefore, the insects are used to detect these compounds in the air within a few minutes after the aerosol has passed through the filter. The fil ter's effectiveness is determined by counting the live and dead aphids and spider mites from colonies of known susceptibility in the insect exposure chamber after a 30 to 60 min exposure. Fulton discusses the bioassay method in detail. 2. Test Apparatus The apparatus used for biological or chemical testing of respirator cartridges consists of the ! f i I E--06582 120 RESPIRATORY PROTECTIVE DEVICES MANUAL following; (1) dusting or spraying chamber, (2) a cartridge or canister holder, (3) a chamber for exposing the test insects, (4) a flowmeter to de termine air flow through the unit, (5) a manometer to determine the resistance to the air flow, and (6) a sampling unit for withdrawing air for chemi cal analysis. Air is drawn through the apparatus by a vacuum pump at a rate of 16, 32, or 64 liters per minute (1/min). This apparatus is described in detail in Fulton's article,26 and several drawings of the equipment are given. An apparatus to produce concentrated vapors for testing the efficiency of gas mask canisters also is described in Fulton's article and illus trated in detail. Its sampling unit and insect expo sure chamber are the same as' for the cartridge tests. To control the vapor pressure of the in secticide, the entire unit is placed in a large con stant temperature box maintained at 85F. All the tests are made with the insecticide concentration recommended by the chemical manufacturer and the concentration of the insecticide in the air ahead of the filter is determined. The same type of apparatus is used to test against fungicides and nematocides. 3. Results of Tests The USDA has based their bioassay tests on known strains of insects. Fulton notes that the filters must remove all the particles in the wide range of sizes of insecticide formulations, which are classified according to particle size in Table 11.3. TABLE 11.3 PARTICLE SIZE CLASSIFICATION FOR PESTICIDES Classification Coarse sprays Fine sprays Mists Aerosols and fogs Coarse dusts Medium dusts Fine dusts Size, fi 400 and larger 100 to 400 50 to 100 50 and smaller 175 and larger 45 to 175 44 and smaller For adequate protection against organic phos phorus compounds, Fulton ultimately had to use high efficiency filters, with a sorbent to remove odors from impurities. The first tests made in 1949 were with parathion, in which "dust filters* reduced the amount of parathion passing the filter to less than 0.5 ppm. When HETP and TEPP were tested, a high percentage passed through dust fil ters persumably satisfactory for parathion. " Fume filters* were effective in removing HETP and TEPP. When Demeton was tested, it was neces sary to use the best fume filter available, plus a sorbent to remove nuisance odors from impuri ties. The filter--cartridge combinations developed for demeton were effective against all the previ ously tested organic phosphorus compounds, and against all the newer ones except Phosdrin. To remove Phosdrin, a high efficiency filter (99.95 per cent efficient for 0.3^ DOP) was re quired. Fulton's work in 1949 indicated that the halogenated insecticides were removed quantitatively by activated charcoal, but not by filtration, since they produced vapors. The most satisfactory ar rangement for chlorinated insecticides is a com bination of a filter to remove the particles and a chemical cartridge to remove vapor. The filter also prolongs the life of the cartridge. According to Fulton's data,28 the concentrations of dieldrin and aldrin passing through the combination of a sorbent and a filter were in excess (TLV to two times TLV) of the ACGIH threshold limit value for these pesticides. The TLV for several pesticides are given in Table 11.4. This table groups all the pesticides listed in the USDA release by chemical class. 4. USDA Recommended Respirators The 1962 USDA release concerning recom mended respiratory devices for protection against inhalation hazards of dusts, mists, and low vapor concentrations of certain pesticides is in Appendix D. This release contains a table listing certain pesticides with " respirators* and " gas mask can isters" that have been tested and found acceptable. The USDA classifies respiratory protective de vices according to the size of the sorbent contain er. Therefore, the respirators tested may have a half mask facepiece (respirator A, for example) or a full facepiece (respirator G) with a small sorbent cartridge (50 to 200 cm3 volume). Larger sorbent containers (> 350 cm3) are classified as gas mask canisters. Canisters tested range in vol ume from 350 to 1,000 cm3 0f sorbent. It should be noted that the USDA classification of respira tory protective devices differs from the sys tem used by this Manual and the Bureau of Mines. The USDA release contains several good recommendations for the field use and care of respirators. E-06583 SPECIAL APPLICATIONS 121 TABLE 11.4 CHEMICAL CLASSIFICATION OF PESTICIDES51 AND THEIR THRESHOLD LIMIT VALUES Class Insecticide TLV,b mg/ m3 Halogenated hydrocarbons Organic phosphates Aldrin0 Chlordane D-D Dieldrin0 Endrin Ethylene dibromide Terrachlor Thiodan DDVP Delnav Demeton (Systox) Diazinon Dibrom (emulsion) Dibrom (xylene solution) Dimethoate Di-syston EPN Ethion Malathion0 Methyl parathion Methyl trithion Parathion0 Phorate Phosdrin Phostex Ronnel Schradan TEPP0 Trithion Dicapton Shell SD-3562 0.25 2.0 -- 0.25 0.25d 190.0 -- -- 1.0d -- 0.2d -- -- -- -- -- 0.5 15.0 -- -- 0.1 -- 0.1d -- -- -- 0.05 -- -- -- Carbamates Ferbam Sevin Vapam Zineb 15.0 -- -- -- Copper compounds Calcium copper chloride , -- Mercury compounds Ceresan Panogen 0.01e 0.01e Miscellaneous ' Nicotine0 0.5 - a. See 1962 release in Appendix D. b. All threshold limit values based on ACGIH values for 1961. c. The liquid compound can penetrate the skin to cause systemic effects. d. Tentative e. As mercury. C. Air-purifying Respirators for Insecticides Air-purifying respirators depend on the use of efficient filters in combination with activated charcoal for adequate protection against agricul tural pesticides. The only effective way to remove organic phosphates is by the use of an efficient filter. The phosphates are not removed with com mon absorbing agents such as activated charcoal or soda lime. The chlorinated hydrocarbon in secticides show the properties of a true vapor, and they are removed quantitatively by activated char coal. The life of the unit is prolonged by the use of an efficient filter. The toxicity of the organic phosphate insecti cides is entirely too great to chance the minimum protection afforded by chemical cartridge respi rators. Malathion is the only known exception. The limitation of chemical cartridge respirators (half mask facepiece with sorbent cartridge) is dis cussed in Chapter 5, Section VL Because of the small sorbent volume used in half mask cartridges and the difficulty of obtaining a reliable gas-tight seal on the face, it is emphasized that there are several insecticide vapors (for example, dieldrin and Ceresan) too toxic to chance the minimum protection afforded by chemical cartridge res pirators. In Table 5.3, Chapter 5, sorbents for specific gases and vapors in the 1961 ACGIH thres hold limit values are given. Sorbents for insecti cide vapors were not listed, but activated charcoal or impregnated activated charcoal is generally the sorbent of choice. For mercury compounds, a mercury vapor sorbent plus filter is necessary. For maximum protection against the highly toxic insecticides, it is recommended that only a well-fitting full facepiece gas mask equipped with an organic vapor canister (standard or extra large size) plus a high efficiency filter be selected. Befor the individual is permitted to apply insecti cides, he should be properly trained in the use of the device (see Chapter 13). The gas mask de scribed above is commerciaUy available and will provide protection against organic, phosphates, halogenated hydrocarbons, carbamates and nicotine (see Table 11.4). For mercury compounds, the Type N universal gas mask contains hopcalite, which is effective against mercury vapors. Minimum protection is provided by half mask facepieces equipped with an organic vapor car tridge plus high efficiency filters. The Bureau of Mines approves chemical cartridge respirators for protection against a maximum concentration of organic vapors of 0.1 per cent (1,000 ppm). The insecticide concentration recommended by the manufacturer may exceed this limit. Chemical cartridge respirators plus a filter wUl provide adequate protection only when the wearer obtains a gas-tight face seal, when the insecticide aerosol concentration is low (< 0.1 per cent), and when the exposure time is short. 5 i j I i E--06584 122 RESPIRATORY PROTECTIVE DEVICES MANUAL Warning; Chemical cartridge respirators should never be used for protection during fumi gation with any pesticide. The USDA release in Appendix D warns that respirators are advised for protection only against the pesticides listed by them. It also warns that only full facepiece gas masks give adequate protection to those formu lating or mixing pesticides in closed or inadequate ly ventilated spaces and to those applying pesti cides, including aerosols, in greenhouses. D. Protection against Skin Absorption Many of the pesticides listed in Table 11.4 are known to produce toxic systemic effects when absorbed through the intact skin and are so desig nated. It should be noted that several other pesti cides listed in Table 11.4 may produce the same effect; they are not so designated because of the lack of specific toxicological data. In the USDA release in Appendix D, it is emphasized that the use of respirators is not a substitute'for essential precautions. This refers to personal protective clothing and personal cleanliness, to prevent skin absorption of the pesticide. The USDA notes that the gas mask should be worn with proper protec tive clothing when a workman is applying pesti cides in greenhouses or other enclosed spaces. In addition to using proper respiratory pro tective devicesand proper protective clothing (im pervious gloves, etc.), the workmen must be pro vided with adequate washing facilities and in structed to wash themselves and their respirators at frequent intervals. The USDA respirator main tenance and washing instructions are similar to those given in this Manual (see Chapter 12) and should be followed diligently. ble air is supplied through an insulated hose, or by use of a mask connected to a tank of compressed air carried on the body and insulated from the hot environmental air. These two solutions to the respiratory problem have the disadvantage that they severely limit the freedom of motion of per sonnel. Frederik32 and associates have developed a respirator, now obtainable commercially, which protects the respiratory system against hot at mospheres up to about 300F. This compact, light weight, self-contained thermal respirator consists of a half mask facepiece to which a simple heat exchange cartridge is attached. The respirator may be used alone for conditions of low thermal stress, or it may be worn with an aluminized as bestos hood and suit for full body protection against environments producing high thermal stress. B. Operating Principle The respirator described by Frederik is based on the principle of heat exchange. Because the heat capacity of a solid is much greater than that of a gas, a small mass of solid in a heat exchange car tridge can absorb and retain the heat from a rela tively large volume of air. Metallic fibers in the respirator cartridge act as the heat exchanger and remove heat from the incoming air so the wearer inhales cool air. The heat, stored temporarily in the fibers, then is forced out of the cartridge when the user exhales, thus returning the cartridge to its original temperature. The heat exchange cycle is repeated each time the user breathes. C. Construction VI. THERMAL PROTECTIVE RESPIRATOR A. Background Information Industrial situations frequently require the exposure' of personnel to inordinately high atmos- pheric temperatures for a short time, as during repair, inspection, and cleaning inside dryers, ovens, furnaces, and kilns. Excessive tempera tures may affect personnel psychologically, physi ologically, or psycho-physiologically. The effects, in order of increasing severity, are discomfort, irritation, reduced work capacity, increased er rors, increased accidents, imbalance of water and salt in the body, heart and circulatory system strain, acute exhaustion, and death. Clothing which protects the head (including the eyes) and the body against excessive tempera tures is used extensively in industry, with respi ratory protection against hot environmental air obtained by use of a mask to which cool, respira The cartridge is constructed so that it can be attached easily to a half mask respirator by screwing it into a holder mounted in the lightweight facepiece of the respirator. The complete respi rator weighs only 6 ounces (oz) and offers a breathing resistance of only' 0.2 inches (in.) of water for 85 l/min of air flow. See Fig. 11.6. The cartridge, 3 in. in diameter and 2-3/8 in. long, consists of a number of metallic screens isolated from hot environmental air by a thermal insulating shell (molded of a low density, closed cell polyurethane foam plastic which has a very small coefficient of thermal conductivity and can withstand very high temperatures). The metallic screens which are the actual heat exchange me dium are of aluminum, which is relatively corro sion resistant and has a large heat capacity com pared to that of air. In addition to a high density of heat-absorbing medium per unit volume of car tridge, the metal screens have a very low re sistance to the inflow of air. j ! 4 *4 E-06585 SPECIAL APPLICATIONS 123 Fig. 11.6. Thermal Protective Respirator. Cross section illustrating Metallic screens (Heat exchanger) mounted in foam plastic shell of cartridge. The exhalation valve is plugged. D. Applications Laboratory investigation showed that the heat exchange cartridge maintained a temperature dif ference of 198F after an 8 hr exposure to an en vironmental temperature of 300F, for a pulsating air flow with an average flow rate of 85 1/min and 35 pulses per minute, approximately the respira tion conditions of a person working at the rate of 8,000 foot-pounds per minute (ft-lb/min). Some typical applications of the thermal pro tective respirator include use by technicians who must periodically inspect materials in drying ovens in the plant of a building materials manu facturer; employment in a glass manufacturing plant by maintenance men who must repair fur naces in an environment of 150F; and use by power house workers in a factory in which boilers are repaired at 250F. When the respirator is used in dusty opera tions, a dust filter attached to the heat exchange cartridge provides respiratory protection against both dust and hot environmental air. The respirator also is effective in low tem peratures, as in walk-in freezer lockers. The temperature of the incoming frigid air is raised almost to body temperature. In this application the heat exchange cartridge usually is warmed before use. VIL HOUSEHOLD ITEMS FOR EMERGENCY USE IN CIVILIAN DEFENSE In case the civilian population of all ages should ever need emergency respiratory protection against aerosols resulting from radiological, bio logical, or chemical attack, it is worthwhile to in clude a discussion of an evaluation of eight com mon household and personal items for emergency use as respiratory protective expedients. This evaluation, reported by Guyton and Anton, was made by personnel from the biological warfare laboratories of the U.S. Army Chemical Corps at Fort Detrick, Maryland, at the request of the Di vision of Biology and Medicine of the AEC. Eighteen variations of eight household and personal items were evaluated to determine their potential utilization as emergency respiratory protection expedients in the event of a radiological or biological attack. Military enlisted men used these materials as respiratory protective devices in an atmosphere containing spores of a nonpathogenic bacteria. The mass median diameter of particles in the aerosol was 2.1m# 'with 95 per cent of the particulates between 1.0 and 5.0 n. The respiratory protective expedients tested possessed no mechanical means such as a strap or harness to maintain an effective peripheral seal. It was realized that a limitation of the test would be the reliability of the seal, which would depend solely upon the care taken by the subjects them selves to ensure a good peripheral seal. Experi ence in designing tests utilizing human subjects indicated that a minimum of 30 replicate observa tions would be necessary for each item evaluated. The results of these tests are given in Table 11.5. It will be noted that five variations of these items had a filtration efficiency greater than 85 per cent. They are: man's cotton handkerchief, folded to a thickness of 16 layers, also when folded to a thickness of eight layers, and when placed over the mouth and nose in a crumpled state; a commercially available toilet paper when used in the thickness of three sheets; and a turkish bath towel when folded in two layers. An important factor to consider in deciding which of these items would be superior for use as a respiratory protective expedient is the resistance to breathing offered by each. The evaluation of the respiratory protective items included asking the subjects if the item exhibited too great a resist ance for normal breathing. Based on the unani mous agreement of the subjects and the recom mendations of the Chemical Warfare Laboratory personnel, it was concluded that those items with a resistance of 36 millimeters (mm) of water or greater would be limited in their use as respira tory protective expedients. Although no data were available, the Chemical Warfare Laboratory per sonnel expressed doubt that women and children could tolerate any resistance greater than about 20 mm of water for an indefinite period. In considering the resistance criteria, a 36 mm resistance of the man's handkerchief (16 fold) E--06586 124 RESPIRATORY PROTECTIVE DEVICES MANUAL TABLE 11.5 RESPIRATORY PROTECTION PROVIDED BY COMMON HOUSEHOLD AND PERSONAL ITEMS AGAINST AEROSOLS OF 1 TO 5/x PARTICLE SIZE Item Handkerchief, man's cotton Toilet paper Handkerchief, man's cotton Handkerchief, man's cotton Bath towel, turkish Bath towel, turkish Bed sheet, muslin Bath towel, turkish Shirt, cotton Shirt, cotton Handkerchief, woman's cotton Handkerchief, man's cotton Dress material, cotton Handkerchief, woman's cotton Slip, rayon . Dress material, cotton Shirt, cotton Handkerchief man's cotton Number of Thicknesses Resist ance, mm of HgO 16 3 8 Crumpled 2 1 1 1 (wet) 1 (wet) 2 4 (wet) 1 (wet) 1 (wet) 4 i \ i i i 36 13 18 11 5 22 3 >150a 7 84a 98a 180a 2 6 5 3 2 Number of Observations 32 32 32 32 32 30 32 * 31 15 30 32 30 31 32 32 31 32 32 Geometric Mean Efficiency, % 94.2 91.4 88.9 88.1 85.1 73.9 72.0 70.2 65.9 65.5 63.0 62.6 56.3 55.5 50.0 . 47.6 34.6 27.5 95% Confidence Limits for Mean,"% Lower Upper 92.6 89.8 95.5 92.8 85.5 91.6 85.1 90.5 83.3 86.8 70.7 68.8 76.8 74.9 68.0 57.9 60.8 72.3 72.3 69.6 57.3 67.9 57.0 67.5 49.6 62.0 52.2 46.2 58.7 53.6 41.4 29.0 53.2 39.9 22.0 32.5 a. Resistance obtained when checked immediately after hand wringing. This resistance began to decrease after about one minute when the material started to dry. would limit the use of this item as an expedient. Because of its obvious variability, no resistance data were obtained for the man's handkerchief in a crumpled state. However, it can be assumed that the resistance approximates that of the 16-fold handkerchief. There were divided opinions concerning the muslin bed sheet, which had a resistance of 22 mm. -:v % 5. 5 E-06587 SPECIAL APPLICATIONS 125 A three-layer thickness of toilet paper exhibited the highest efficiency of the items whose resist ance is less than 20 mm. However, accumulated moisture from the breath could cause this ma terial to tear easily, which would preclude its use for any long period of time. The two remaining items, bath towel in two layers and man's handker chief in eight layers, do not appear to have any serious limitations. Prior to these tests, there was considerable discussion concerning the aerosol filtration effi ciency of wet versus dry materials. Consequently, it was decided to evaluate all the cloth items after they had been saturated with water and then hand wrung. However, two of these items, the muslin bed sheet and rayon slip, could not be evaluated since they exhibited intolerable resistance to hu man breathing. Two of the remaining five wet items, woman's handkerchief (four layers) and cotton dress material (one layer), showed a slight increase in filtration efficiency. Efficiencies of the cotton shirt material (one layer) and the man's handkerchief (one layer) increased about twofold. The other item tested after wetting, the bath towel (one layer), gave slightly less protection when wet than when dry. This difference, however, is not statistically significant. The results demonstrate that the protection of 70.2 per cent provided by the best of the five wet items, the bath towel, is still inferior to that of seven dry items. The resistance to breathing produced by these wet items, with the exception of the bath towel, was extremely high. In general, therefore, the use of such wet items as respiratory protective expedients is not practical. Caution; The reader should be cautioned, if considering the use of two layers of a common household bath towel or of eight layers of a man's handkerchief, that the indicated efficiencies were obtained by trained military personnel who were conscientiously making every effort to obtain a good fit on the face. It must be assumed that a small child could not be counted upon to obtain a reliable seal while holding one of these items over the nose and mouth. Also, it should be stressed that these items were tested against aerosols and under no circumstances will they provide protec tion against gases or vapors. REFERENCES 1. Dygert, H. P.: Pharmacology and Toxicology of Uranium Compounds, Vol. 1, edited by Carl Voegtlin and Harold C. Hodge, Div. VT, Tests of Respiratory Protective Devices in Atmos pheres Containing Uranium Dust, McGrawHill Book Co., Inc., New York, 1949. 2, West, A. L.: Respiratory Protection Equip ment Developments by the U.S. Army Chemi cal Corps, Am. Ind. Hyg. Assoc. J. 19: WO WS, Apr. 1958. 3. Military Specification MIL-C-10082A (CmlC), Canister, Gas Mask, Aerosol, M-14, 9 Apr. 1956. 4. Dept, of the Army: Protective Clothing and Accessories, Dept, of Army Tech. Manual TM-3-204, 25 Jan. 1957. 5. Adley, F. E., Scott, R. H., and GUI, W. E.: A Study of Efficiencies and Pressure Drop Char acteristics of Air-FUtering Media, Hanford Laboratory Report HW-28065, Hanford Atomic Products Operation, Richland, Wash., Aug. 10, 1953. 6. Adley, F. E.: Instrument Developments in Health Physics, Am. Ind. Hyg. Assoc. J. 19: 75-79, Apr. 1958. 7. GUI, W. E.: Penetration of Respiratory Pro tective Equipment by Ruthenium at Bldg. 202S, Hanford Laboratory Report HW-35043, Hanford Atomic Products Operation, Richland, Wash., Feb. 21, 1955. 8. Morgan, G. W. and Buchanan, C. R.: Air Con tamination and Respiratory Protection in Radioisotope Work, AECU-2821, Oak Ridge Operation Office, Oak Ridge, Tenn., Jan. 19, 1953. 9. Becher, A. F.: (Union Carbide Nuclear Co., Oak Ridge, Tenn.), personal communication, Nov. 1957. 10. Tait, G. W. C. and Byington, T. H.: Respira tor Problems in Atomic Energy Practice, Am. Ind. Hyg. Assoc. J. 19:123-125, Apr. 1958. 11. White, J. M.: Health Physics Problems Fol lowing a Reactor Accident, Am. Ind. Hyg. Assoc. J. 20:478-481, Dec. 1959. 12. SUverman, L., Fitzgerald, J. J., Burgess, W. A., Corn, M., and Stein, F.: Respiratory Pro tective Equipment Progress Report for June 1959 to April 1960, Report NYO-9322, Harvard School of Public Health, Boston, Mass., June 27, 1960, 59 pp. 13. Los Alamos Scientific Laboratory: General Handbook for Radiation Monitoring, LA-1835, 3rd ed., compUed and edited by.Dummer, J. E., Jr., p. 111-117, Nov. 1958. 14. Butler, H. L. and Van Wyck, R. W.: Integrity of Vinyl Elastic Suits in Tritium Atmos pheres, Health Physics 2:195-198, July 1959. 15. Adams, R. E. and Browning, W. E., Jr.: Re moval of Radioiodine from Air Streams by Activated Charcoal, ORNL-2872, Oak Ridge National Laboratory, Oak Ridge, Tenn., Apr. 1960. 16. Breslin, A. J. and Harris, W. B.: Health Pro tection in Beryllium Faculties--Summary of Ten Years of Experience, HASL-36, Health and Safety Laboratory, U.S. Atomic Energy Com mission, N.Y. Operations Office, May 1,1958. 17. deOng, E. R.: Chemistry and Uses of Pesti cides, 2nd ed., Reinhold Publishing Corp., New York, 1956, 334 pp. 126 RESPIRATORY PROTECTIVE DEVICES MANUAL 18. Paulus, H. J., Lippmann, M., and Cohen, A. E.: Fumigation of Shelled Corn with a Mixture of Carbon Disulfide and Carbon Tetrachloride, Am. Ind. Hyg. Assoc. Quart. 18:345-350, Dec. 1957. 19. McCollister, D. D., Hollingsworth, R. L., Oyen, F., and Rowe, V. K.: Comparative In halation Toxicity of Fumigant Mixtures, A. M. A. Arch. Ind. Health 13:1-7, Jan. 1956. 20. Adams, E. M., Hoyle, H. R., Schneider, E. J., and Maxwell, J. L.: Health Hazards Present in the Use of a Spot Fumigant, Modern Sanit. 4:61-67, Aug. 1952. 21. Johnson, N. A.: Cooperation is Kansas Key note, Safety Standards, U.S. Dept of Labor, X, No. 1, 21-23, Jan.-Feb. 1961. 22. Anon.: Unique Conference on Fumigants Held at Kansas State, The Manhattan (Kansas) Mercury (newspaper report), June 13, 1960. 23. Mayes, J. L.: (Kansas State Board of Health), personal communication, Aug. 1961. 24. Anon.: Safety Recommendations for Fumigat ing Operations in the Grain and Grain Proc essing Industries, State of Kansas, Dept of Labor, Mar. 21, 1960. 25. Anon.: Methyl Bromide Poisoning, Occupa tional Health Bull., California Dept, of Public Health, Bull. G, rev. Mar. 1956. 26. Fulton, R. A. and Smith, F. F.: Respiratory Protective Devices--Methods for Testing Them Against Pesticides, Agr. Chem. 13 (8): 30-32, 13 (9):22-24, 1958. 27. Schulte, H. F.: Mercury Hazards in Seed Treating, J. Ind. Hyg. Toxicol. 28:159-161, July 1946. 28. Fulton, R. A., Konecky, M. S., and Smith, F. F.: Determining the Efficiency of Respiratory Cartridges and Gas-mask Canisters Against Dusts and Sprays, U.S. Dept. Agr. Bur. Entomol. and Plant Quarantine, E-830, 1951, 6 pp. 29. Fulton, R. A.: How to Select and Use a Res pirator, Am. Fruit Grower 70 (6):17, 29, 1950. 30. Fulton, R. A., Smith, Floyd F., and Busbey, Ruth L.: Respiratory Devices for Protection Against Certain Pesticides, ARS-33-76, U.S. Dept. Agr., Agr. Research Service, Sept. 1962. 31. Fulton, R. A. and McClelland, W. D.: Respi ratory Protective Devices for Agricultural Pesticides, J. Phytopathology 47 (l):56-57, .Jan. 1957. 32. Frederik, Willem S.: The Development of a Respirator for Abnormal Temperatures, Safety Maintenance 117:14-17, Mar. 1959. 33. Guyton, H. G., Decker, H. M., and Anton, G. T.: Emergency Respiratory Protection Against Radiological and Biological Aerosols, A. M. A. Arch. Ind. Health 20:91-95, Aug. 1959. E--06589 Chapter 12 MAINTENANCE, CARE, AND STORAGE Maintenance is an important phase of any con trol procedure, and this is as true for respirators as it is for ventilation equipment. No matter how well a respirator is designed or how good its per formance, it cannot give satisfactory protection unless it is maintained in good condition. This, one of the most important factors in the use of these devices, is yet the most frequently neglected, particularly with nonemergency respirators in which the results of such neglect are not so readily evident. In addition to providing adequate protection, proper attention to maintenance of respirators in use has a definite economic value. Well-maintained equipment lasts longer and re quires less frequent replacement. The operations of a maintenance programfrequent and periodic inspections, cleaning, re placing or repairing worn or deteriorated parts, and storage--should be centralized wherever pos sible. They should also be supervised carefully by a responsible and capable person, because proper care and maintenance require a thorough knowl edge of the device. I. INSPECTION All routinely used respirators should be in spected frequently. Emergency respirators should be inspected at least every 30 days because, though they may stand unused for a considerable time, they must be available in first-class condition at a moment's notice. The tightness of connections should be checked, as well as the condition of the facepiece, headbands, exhalation and inhalation valves, con necting tube, and canister. The rubber parts of emergency equipment should receive particular attention to assure that they show no signs of de terioration. Unused rubber parts should be kept pliable and flexible, and prevented from taking a set during periods of disuse by working, stretch ing, and manipulating with a massaging action dur ing the inspection. If the sides of the exhalation valve gap even slightly, a new valve should re place the old. Emergency devices should be cleaned after each use. After the device is dry, an antifogging compound should be placed on the inside of the lens. Damaged lenses in some masks can be re placed by maintenance personnel, whereas others must be replaced by the manufacturer. The carry ing cases for emergency devices are designed to protect facepieces but the device must be properly placed to prevent crimping or pinching. The stor age place should be cool and dry, because high temperatures shorten the useful life of rubber parts. Self-contained breathing apparatus, either de mand- or recirculating-type, must be inspected monthly. The air or oxygen cylinder must be fully charged to 1,980 pounds per square inch (1,800 psi plus 10 per cent at 70F, as allowed by the Inter state Commerce Commission), and the regulator must function properly. No attempt should be made to repair or adjust either the reducing or admis sion valve mechanism or the safety valve of the regulator. If the regulator is not operatingproperly, it should be returned to the manufacturer for adjustment or repair. It is extremely dangerous for anyone other than a highly trained mechanic, who thoroughly understands the construction, op eration, and adjustment of a regulator to attempt to repair or adjust the regulator. IL CLEANING Routinely used respirators also should be cleaned after each use, and they should be collected at a central point at the end of each shift for cleaningand inspection. Each person's respirator should bear some sort of identification, such as his in itials or employment number. When a worker recevies a respirator, he should be briefed on the cleaning procedure and assured that he will always get the same device. If the respirators are serv iced between shifts, only one respirator per work man is needed. If the cleaning is done during a work shift, each worker requires two respirators. When not in use (for example, during the lunch period), the respirators should be stored in clean cabinets at convenient locations in the work area. It is generally accepted that washing with a good detergent in warm water, by hand brushing or agitation in a washing machine, is a sound basic cleaning procedure. According to Drinker and Hatch,* "there is no reason to require special sterilizing .... Scrubbing with warm water and soap, rinsing, and air drying in a clean place is entirely adequate." There are a number of procedures currently in use for cleaning respirators. When a respira tor is used by only one individual, a practical E-06590 128 RESPIRATORY PROTECTIVE DEVICES MANUAL method of cleaning is as follows: 1. Remove the filter or cartridge and discard. 2. Wash in good detergent or soap in warm water (120F). 3. Rinse completely in clean, warm water. 4. Air dry the device in a clean area. 5. Inspect the valves, headstraps, and other parts; replace with new parts if defective. 6. Insert new filters or cartridges; make sure the seal is tight. 7. Place in a plastic bag for storage. For complete decontamination against phos phate pesticides on respirators, following washing with alkaline soap, it should be rinsed with 50% alcohol (ethyl or iso propyl). Several respirator manufacturers currently sell a cleaner sanitizer that effectively cleans the respirator and contains a bactercidal agent. This bactercidal agent is generally a quaternary am monia compound. One manufacturer marketing a combination detergent and quarternary ammonia salt recommends immersing the respirator in the solution, rinsing in clean, warm (120F) water, and air drying. When the same respirators are used by dif ferent individuals, a good public health policy is to disinfect them before they are re-issued. The literature2-5 lists a variety of chemicals and methods for disinfecting respirators. A number of the procedures are unsatisfactory. For example, formaldehyde not only is a poor disinfectant, but it is absorbed on the rubber and may cause derma titis. Soaking a respirator in a 70 per cent solu tion of ethyl alcohol for 1 hr may be partially ef fective. Live steam or very hot water (170F), organic solvents, and ultraviolet light should not be used because of their injurious effects, par ticularly on the rubber parts. The compounds generally considered to be the most reliable for disinfecting respirators are: (1) a hypochlorite solution (50 parts per million (ppm) of chlorine; immersion time, 2 min), or (2) an alcoholic solution of iodine (50 ppm iodine;_ 2 min immersion). A concentration of 200 ppm of quaternary ammonia compounds in water with less than 500 ppm total hardness is generally an effec tive disinfecting solution. The disadvantages of the quaternary ammonia compounds are: (1) different concentrations of salts are required to achieve a disinfecting solution with waters of varying com position, and (2) the possibility of dermatitis if the quarternary ammonia salts are not completely rinsed from the respirator. If cleaning and inspection reveal parts which should be replaced or repaired, this should be done only by experienced personnel with parts specifically designed for the particular device. Filters or chemical cartridges also can be re placed at this time. Whether such replacements are made after each use or after some definite period of time will depend upon the conditions un der which the device is used and upon past experi ence. In general, if the conditions are not rela tively constant and well-known, replacement after each use is recommended, particularly for car tridges and canisters using sorbents. IIL STORAGE After cleaning, inspection, and necessary re pair, the equipment should be stored properly, in essentially dustproof containers, away from sun light, heat (not near radiators or steam pipes), extreme cold, and excessive moisture. Most de vices come in cartons or cases which are suitable for storage; however, if devices are placed at sta tions and work areas for emergency use, special compartments may be necessary to protect the de vices even in their original containers. Routinely used devices, such as dust respirators, may be placed in plastic bags. The devices should never be stored in such places as clothes lockers or tool boxes unless they are in their carrying cases or cartons. Respirators should be packed or stored so that the rubber facepiece and exhalation valve will rest in a normal position and function will not be impaired by the rubber setting in a bent or twisted position. Instructions for the proper storage of emer gency devices, such as universal gas masks and self-contained breathing apparatus, are on the "in structions for use and care* bulletin mounted on the inside of their carrying case lid. REFERENCES 1. Drinker, P. and Hatch, T.: Industrial Dust, 2nd Ed., McGraw-Hill Book Company, Inc., New York, 1954, 401 pp. 2. Industrial Safety Equipment Association, Inc.: Care and Maintenance of Safety Equipment, Safety Maintenance, 115:14-16, 30, Apr. 1958. 3. National Safety Council: Respiratory Protective Equipment, Data Sheet D-444, National Safety Council, 425 N. Michigan Ave., Chicago 11, HI., 1957. 4. American Standards Association: American Standard Safety Code for Head, Eye, and Res piratory Protection, Z2.1-1959, American Standards Assoc., 10 East 40 St, New York 16, N.Y. 5. Michigan Department of Health: Respirators-- Selection, Use and Care, Occup. Health Bull., 4:1-6, Winter 1958. ii' i' 4*TV.V. P-06591 Chapter 13 TRAINING I. INTRODUCTION A very important, but often neglected, phase of respiratory protection is adequate training of those who are expected to use such protection. It is a common misconception that training is needed only for the self-contained breathing apparatus. Training is necessary for supervisors, such as foremen who are to supervise the use of any type of respiratory protective device, as well as for those who are to wear it, if a device is to be used intelligently, confidently, and safely. Obviously, the more complicated the apparatus or the more hazardous the atmosphere in which it is to be used, the more extensive and intensive the training must be. Such training should be given by a quali fied person, such as an industrial hygienist, a safety engineer, or respirator manufacturer's representative. Training in the use of any respirator should cover the following: 1. Discussion of the airborne contaminants against which the wearer is to be protected, in cluding information on their physical properties, possible concentrations or changes thereof, mode of physiological action, toxicity, and means of de tection. 2. Discussion of the reasons for using the respirator. 3. Description of its construction, operating principles, and limitations. 4. Instruction in procedures for assuring that it is in proper working condition. 5. Instruction in fitting the respirator prop erly and checking for the adequacy of fit. 6. Instruction in the proper use and mainte nance of the respirator. 7. Discussion of the importance of careful reading of labels on the respirator and on its con tainer and of the manufacturer's instructions for its use and care. An important by-product of training is the sense of confidence that the trainee should develop in his ability to use the respirator properly. If something suspicious should happen to the res pirator, or to the atmospheric conditions, he would act rationally rather than panic. To conserve space and avoid repetition, only those items of the foregoing list that require spe cial emphasis will be included in the discussion of specific training for the various types of respira tors. However, all of the items should be covered adequately in the training program. n. SPECIFIC TRAINING FOR VARIOUS TYPES OF RESPIRATORS Supervisory personnel should be trained to select the proper type of respirator for the job. A choice from several makes of the proper type and design of respirator might be left up to those who are to wear them. Such a procedure tends to less en the workers' apparent inborn resistance to wearing a respirator. Since the maintenance of respirators is dis cussed in Chapter 12, no specific instructions on this matter will be given here. However, instruc tion in proper maintenance of respirators is a very important part of any training program. A. Particulate-removing Respirators The particulate-removing (mechanical filter) respirator is the simplest type, yet there have been many instances of misuse because of inade quate training. These misuses have included such practices as wearing the respirator upside down, wearing it without filters or without exhalation valve, and discarding the entire respirator be cause the filter "plugged up." Trained persons would not have committed these blunders. Since the main field of use of particulateremoving respirators is for respiratory protec tion against contaminants that have no immediate unpleasant effects, the worker usually must be conyinced that it is necessary for him to wear the respirator. This can be accomplished in a factual manner without undue "scare* tactics. Instruct the trainee how to check the. respira tor to be sure that it is in good wearing condition. Then allow him to actually check a respirator as follows: 1. Check the exhalation and inhalation valves to see that they are in place and not misshapen, and that no dirt or lint is on the valve or valve seating surfaces. 2. Check the body of the facepiece to see that the face-contacting periphery is clean and has not been unduly softened by body-oils, distorted, or hardened. 3. Check for the presence and condition of gaskets and special spacers, if any. 129 E--06592 130 RESPIRATORY PROTECTIVE DEVICES MANUAL 4. Check to see that the filter seating surface is not damaged. 5. Check to see that the filter designated for the intended use is present and is properly as sembled with the respirator. 6. Replace missing parts, and repair or re place damaged or defective parts. Instruct the trainee how to wear the respira tor properly. Since the most important part of this phase of training is to fit the respirator to his face, show him how to test for proper face fit, then remove the respirator from his face, and have him go through the procedure several times by himself until he is confident that he can do it prop erly. Stress the importance of maintaining a prop er face fit. A convenient means for testing the face fit is to close off the exhalation valve and ex hale gently into the facepiece. The face fit is satis factory if a slight positive pressure can be built up in the facepiece without any evidence of out ward leakage of air at the periphery. Instruct in the need to change the filter and the procedure for changing it. Train in the proper maintenance of the respirator, particularly if a centralized system for respirator maintenance is not used. . ume. Isoamyl acetate can be detected by odor in very low vapor concentrations. If the person wear ing the respirator can enter and remain in the test atmosphere for a minute or two without detecting the odor of isoamyl acetate, the respirator is properly fitted. If he detects the odor of isoamyl acetate, he should retreat to fresh air, readjust the facepiece, and then repeat the test. If leakage is still noted, he should retreat to fresh air and recheck the respirator, as previously. If the res pirator is to be worn in air containing contami nants other than organic vapors, replace the or ganic vapor cartridges with cartridges of the ap propriate type, after a satisfactory face fit test. There are many occasions when it is neces sary to conduct fitting tests in the field. A field check is illustrated in Fig. 13.1. The reliability of the face fit is checked by pouring a few drops of isoamyl acetate onto a piece of cotton and waving it gently near the periphery of the facepiece while the wearer breathes normally. The concentration is likely to be above 100 ppm, but it does serve to check the face fit and is commonly used in the field. B. Gas- and Vapor-removing Respirators 1. Chemical Cartridge Respirator Discuss the following limitations of the chem ical cartridge respirator: It is for use only against the type of contaminant listed on the cartridge label, in -concentrations not exceeding the maxi mum given on the cartridge label. It will not af ford respiratory protection against particulates unless a particulate-removing filter is indicated and present. Instruction and training in checking and fitting the respirator should be the same as described for particulate respirators except that the trainee should check the cartridge (and particulateremoving filter, if used) to see that it is of the proper type, is in good physical condition, and is seated securely against its gasket. It is desirable that the trainee check the fit of the facepiece by actually wearing the respirator, equipped with or ganic vapor cartridges, in an atmosphere contain ing approximately 100 parts per million (ppm) of isoamyl acetate vapor (banana oil). Before this test is made, an organic vapor cartridge should be affixed to the respirator in lieu of any other type of cartridge. A special test chamber is not needed for this training since such a concentration can be built up in any room, without damage to its contents, by evaporating 17.3 milliliters (ml) of isoamyl ace tate for each 1,000 cubic feet (ft) of room vol- Fig. 13.1. Field test of face fit of respirators using isoamyl acetate. E-06593 TRAINING 131 2. Gas Mask Explain the operating principle of the gas mask and its limitations (see Chapter 6, Section m). Instruct the trainee how to check the gas mask to be sure that it is in good wearing condition. Then allow him to check a gas mask as follows: a. Check the canister to see that it is in the proper type for its intended use and that its expi ration date has not passed. b. Check the canister for dents and signs of external corrosion, for the presence of closures on the inlet and outlet openings if a new canister is to be installed (all canisters should be stored sealed), and for malformations of the canister neck. c. If the canister has a window-indicator, check to see that there is good contrast between the indicator and reference portions of the indica tor and that either the external or internal check valve is present and in good operating condition. d. Check the canister harness to see that it is in proper condition to hold the canister securely in place on the wearer's body. e. Check the facepiece for cracked or dis colored eyepieces, dirty or misshapen exhalation valves, lack of elasticity of rubber or elastomer and missing tabs, or checked appearance of head harness. Check the face-contacting periphery of the facepiece to see that it is clean and has not been unduly softened by body oils or distorted. Apply antifogging material to interior of eyepieces. f. Check the corrugated breathing tube to see that it is flexible, that it has no visible holes in it, that it is securely fastened to the facepiece, and that the inlet end is not distorted. If a threaded canister adaptor is to be used, be sure that the in let end of corrugated tube is securely attached and that the adaptor gasket is in place. Instruct the trainee how to don and adjust the mask properly. The adjustment of the neck or shoulder strap of the canister controls the "repose" position of the breathing tube. Adjust this strap so that, when the mask is being worn, there is a slight bow in the breathing tube when the wearer's head is in the normal forward position. Adjust the belt strap of the canister harness so that the canister is held securely against the wearer's body, but not tight enough to interfere with his breathing or other body movements. The most important part of this phase of training is to fit the facepiece to his face, show him how to test for proper face fit, and have him go through the procedure several times by himself until he is confident that he can do it properly. Stress the importance of maintaining a proper face fit. There are two means for testing for the -gas-tightness of fit of the complete gas mask, as follows: 1. Negative pressure test. Close off the inlet opening of the canister by covering it with the palm of the hand or by replacing the tape seal, in hale so that the facepiece collapses slightly, and hold the breath for 10 sec. If the facepiece re mains in its slightly collapsed condition and no in ward leakage of air is detected, the gas-tightness of the gas mask--as worn--is satisfactory. 2. Positive pressure test. Close off the exha lation valve and exhale gently so that a slight positive pressure is built up in the facepiece. If no outward leakage of air is detected at the pe riphery of the facepiece, the face fit is satis factory. If leakage that is not attributable to a poor face fit is detected, check for unsoldered joints in the canister, recheck for the presence of and con dition of the gasket in the threaded breathing tube connector, tighten the breathing tube clamp, and repeat the negative pressure test If leakage is still detected, recheck the facepiece and breathing tube as described previously, and repeat the pres sure test. It is desirable for the trainee to check the fit of the facepiece by actually wearing the gas mask, equipped with a canister that will remove organic vapors, in an atmosphere containing approximate ly 1,000 ppm of isoamyl acetate vapor. Informa tion regarding the test atmosphere is given in the preceding section on the chemical cartridge res pirator. Warn the trainee to enter a contaminated at mosphere wearing a gas mask only (1) if he is certain that there is sufficient oxygen to support life, (2) if he has knowledge that the canister is of the proper type, and (3) if he has thoroughly checked the gas mask and the face fit thereof. Instruct the trainee to enter the contaminated area cautiously, and if the odor of the contaminant is noted, to return to fresh air immediately and ascertain the cause of the leakage. Encourage the trainee to attach a fresh, properly dated, canister before entering an ex tremely hazardous atmosphere, particularly one containing agas orvapor (such as methyl bromide) which cannot be detected by odor even in harmful concentrations. Instruct the trainee to assemble the complete gas mask, to replace missing or damaged parts and to repair defective parts. Information and instruction to develop confi dence should supplement a trainee's practice in the use of masks. The following factors are im portant and should be explained to the user. a. Heat felt on a canister, or in the effluent air which is breathed in, indicates that the canis ter is giving protection. The lower part of a single layer canister will feel hot shortly after the wear er enters the toxic atmosphere, and the heat will E-06594 132 RESPIRATORY PROTECTIVE DEVICES MANUAL progress upward until it is almost entirely in the 3. Mouthpiece Respirator (Self-rescue Res upper one or two inches of the canister, at which pirator) time the break point may be expected. The amount of heat varies with each gas and its concentration. In general, the effluent air temperature will reach the limit the person can be expected to tolerate only after several minutes' use at the upper recommended concentration. This is an indication of impending exhaustion of the canister. b. In pits or confined spaces with no ventila tion, contaminants of high vapor density will re main in the lower portion of the space. Extremely high concentrations may prevail if the heavy con taminant is being released at or near the floor. c. Contaminants with low boiling point and high vapor pressure are usually released most rapidly, producing high concentrations. d. Air movement is the most important factor in spreading a contaminant throughout an area, producing a rise in contaminant concentration in areas downwind and a decrease near the source. If fresh air is brought into the area, the total con centration will be reduced. The mask user should be trained to recognize any change from the ex pected conditions so that appropriate action may be taken. e. Every canister has some initial resistance Since the use of the mouthpiece respirator is primarily for escape from a suddenly contaminated atmosphere, instruct the trainee to carry the res pirator with him at all times when in an area where it might be needed. (In coal mining operations, carbon monoxide self-rescuers are carried on the belt by those required to move from location to location in the mine. A sufficient number of these self-rescuers for those men working in one place are stored in caches near the working place. These caches are moved forward as the working place advances.) Instruct the trainee how to check the respira tor to be sure that it is in good wearing condition, then allow him to check the respirator. Follow ap propriate instructions in Sections B, 1 and B, 2. Instruct the trainee as to how to wear the respirator. Stress the importance of using the nose clip to prevent accidental inhalation of the contaminated atmosphere through the nose. In struct* him to remove any gum, tobacco, or food from his mouth. Such solid material could lodge in the exhalation valve'and cause the valve to stick in the open position and thus leak. to breathing which increases with increased ex ertion. As a result, those who have not been prop C. Supplied Air Respirators erly trained are tempted to take off their masks, As explained in Chapter 7, there are two de calling them "no good." Instruction in the me grees of protection afforded by supplied air res chanics of the mask and the reasons for the an pirators. The hose mask with blower will afford ticipated resistance will bolster the user's confi respiratory protection in any atmosphere, whereas dence and help assure proper use of the equipment. the hose mask without blower, the air line res f. Fogged lenses, which interfere with vision, pirator, and the abrasive blasting respirator af may be caused by any of several conditions, in ford respiratory protection only in atmospheres cluding canister storage or previous use, exces that are not immediately hazardous to life and sive atmospheric humidity, and improper mask from which the wearer can escape unharmed with design. out the aid of the respirator. Hence, more training An old canister which lias been exposed to is needed for the use of the hose mask with blower high humidity atmospheres or excessive use may than for the other types. cause fogging (see Chapter 5, Section VI, a). The absorption of'certain gases produces moisture; if - 1. Hose Mask with Blower the canister contents are saturated with moisture the excess will come through with the effluent air and fog the mask facepiece lenses. Such a canister should be replaced. Excessively high atmospheric humidity, com bined with the water produced by absorption of a high concentration of certain gases, can cause fog ging even with a new canister. A larger canister is needed to correct this condition. An improperly designed mask which does not circulate incoming air over the eyepieces will also produce fogging. Since an operator is required at the blower at all times when the hose mask with blower is used, the man who is to operate the blower and the man who is to use the respirator must be trained as a team. Explain the operating principle of the hose mask with blower (see Chapter 7, Section I). In struct the trainees as to how to check the respi rator to be sure that it is in good wearing condi tion. Then allow them to actually check the res pirator as follows: a. Check the blower to see that it-operates properly. Cap any unused blower outlets. b. Check the hose to see that all gaskets are in place and in good condition. E--06595 TRAINING 133 c. Check the gasket seating surface of each hose coupling to see that it is smooth. d. Check the hose for worn covering and for resiliency. The resiliency may be determined as follows: Grasp the hose with the hands, palms down, about six inches apart and bend it by bring ing the knuckles of the hands together and holding for 30 sec. If visible cracking of the covering oc curs, the hose is definitely unsatisfactory. If audi ble crackling is noted, the hose fabric is deteri orating and the hose should be subjected to the fol lowing additional test: attach one end of the hose section to a stationary object, such as the blower in the trunk, make a single tight loop in the hose and attach a spring scale to the free end. The trunk should be anchored securely. Apply a slow steady pull of 90 lb to the spring scale while the loop is kept from unwinding by having another man place his hand on it. The hose should not deform or break at the kink so formed. e. Check the body harness for cracks or tears and for "pulled'' belt buckle holes. Attach a section of the hose to the body harness and check the security of the attachment. f. Check the facepiece for cracked eyepieces, dirty or misshapen exhalation valves, lack of elasticity of the rubber or elastomer and missing tabs, or checked appearance of head harness. Also, check the face-contacting periphery of the facepiece to see that it is clean and has not been unduly softened by body oils or distorted. g. Check the interior of the trunk for loose dirt, and remove any that may be present. h. Check for foreign material in the blower and hose by attaching the hose to the blower and operating the blower at high speed for 2 or 3 min. i. Check the life line to see that it is in good condition and is fastened securely to the D-ring on the body harness. j. Replace missing parts, and repair or re place damaged or defective parts. Show the trainees how to don the body harness and facepiece and how to test for proper fit of the facepiece. There are two means for testing for the gas-tightness of fit of the facepiece, as follows: a. Negative pressure test. Close off the inlet tube or tubes by hand pressure, inhale so that the facepiece collapses slightly, hold the breath for 10 sec. If the facepiece remains in its slightly col lapsed condition and no inward leakage of air is detected, the face fit is satisfactory. b. Positive pressure test. Close off the exha lation valve (the inlet tubes will be closed by the inhalation valve) and exhale gently so that a slight positive pressure is built up in the facepiece. If no outward leakage of air is detected at the pe riphery of the facepiece, the face fit is satisfac tory. A set of signals based on the number of pulls on the life line should be prearranged and prac ticed by the blower operator and the user of the respirator. Instruct the blower operator to locate the blower in respirable air, to operate the blower at a steady rate, to be alert to signals from the wearer of the respirator, and to warn the wearer to return to fresh air if the intake air of the blow er becomes contaminated. Instruct the wearer of the respirator to avoid fouling or exerting extreme pull upon the hose, to be alert to signals from the blower operator, to return to fresh air immediately if the forced flow of air to the facepiece stops or if he detects con taminated air in the facepiece, and to be certaitain that he is in respirable air before he removes the facepiece. Stress proper maintenance of the respirator. 2. Hose Mask without Blower Explain the operating principles and limita tions of the hose mask without blower (see Chap ter 7, Section I). Instruct the trainee as to how to check the respirator to be sure that it is in good wearing condition. Then allow him to actually check a respirator as follows: a. Follow instructions for items 2, 3, 4, 5, 6, 7, and 10 as given in the preceding section on the hose mask with blower. b. Check for foreign material in the hose by blowing compressed air through it. The com pressed air should be clean, that is, free from oil, water, and solid matter. Show the trainee how to don the body harness and facepiece, and how to test for proper fit of the facepiece using either the negative or positive pressure test as described in the preceding sec tion on hose mask with blower. Instruct the trainee to anchor the inlet end of the hose, with screen attached, securely in an as sured source of respirable air, to avoid fouling or exerting extreme pull on the hose, and to return to fresh air immediately if he detects-contaminant odor. 3. Air Line Respirator Explain the operating principles and limita tions of the air line respirator (see Chapter 7, Section II). Explain the necessity for a supply of respirable air and the means for obtaining it (see Chapter 7, Section VI). Emphasize the feet thatthe air pressure applied to the inlet end of the air supply hose must be within the pressure range given on the approval plate of the respirator to maintain the proper rate of flow of air to the breathing zone of the wearer. Stress the impor tance of using the proper length of the air supply hose specified by the respirator manufacturer. 134 RESPIRATORY PROTECTIVE DEVICES MANUAL The rate of flow of air through two hoses which are outwardly similar in appearance may be markedly different. Instruct the trainee as to how to check the respirator to be sure that it is in good wearing condition. Then allow him to actually check a res pirator as follows: a. Check the air issuing from the air supply line for droplets of water, particulate matter, and objectionable odors. These should be removed by a properly maintained air line filter. If in doubt concerning the presence of carbon monoxide, check the air issuing from the air supply line by means of a colorimetric tube type carbon monoxide detector or other method of equivalent sensitivity and specificity (see Chapter 7, Section VT). b. Check the air supply line to see that it is of the proper type, that it is not twisted or kinked, and that it has not been worn through to the fabric. c. Check the detachable coupling at the res pirator end of the hose to see that it can be de tached quickly and easily, and that it does not leak. d. Check for the presence of and condition of the filter cartridge which is used on many air line respirators as a secondary filter for the removal of odors and large particles from the air flowing to the wearer. e. Check the facepiece, helmet, or hood for obvious defects, such as missing or dirty exhala tion valves, cracked or dirty eyepieces, broken or inelastic head harnesses, and defective flexible breathing tubes. f. Check the helmets or hoods of abrasive blasting respirators for the general condition of their exteriors, for the presence of the safety glass or plastic eyepiece, and for the protective screen or perforated metal cover for the eyepiece. g. Replace missing parts, and repair or re place damaged or defective parts. If the air line respirator is of the continuous flow class, instruct the user in the proper method of donning the complete respirator and if of the flow control type, of adjusting the rate of flow of air to the interior of the facepiece, helmet, or hood. Allow him to practice uncoupling the de tachable coupling so that he could free himself of the encumbrance of the air supply hose quickly in an emergency. If the air line respirator is of the demand flow class, instruct the user in the proper method of donning the complete respirator, including a test for facepiece fit. This test may be made by either the positive pressure or the negative pres sure method, as described in the section on the hose mask with blower. Instruct him to set the pressure at the inlet to the air supply hose within the range shown on the approval label. 4. Supplied Air Hoods The supplied air hood (see Chapter 7, Section IV) is an air line respirator of the continuous flow class. However, the supplied air device described in Chapter 7, Section IV, has a flexible, clear plastic hood which distinguishes it from the abra sive blasting respirator. Instruct the user in the proper method of don ning the hood, which is generally mounted on an adjustable head band. Demonstrate how the flexi ble plastic hood may be closed at the bottom with a drawstring or may be tucked inside protective clothing, such as coveralls, when the hood is used for protection against airborne radioactive con taminants or irritant chemicals. Follow appropriate instructions for air line respirator listed in the preceding section. Caution the user that contamination on the outside of the hood may be transferred to the wearer or create an inhalation hazard when re moved. For example, when the device has been worn in high concentrations of radioactive con taminants, an assistant (wearing a respirator) should remove the hood and Immediately fit the wearer with an air purifying respirator. Explain that the plastic hood is relatively cheap and may be disposed of after use. 5. Supplied Air Suits It is imperative that the individuals being trained learn the operating principles and the limitations of supplied air suits (see Chapter 7, Section V). One cannot obtain performance stand ards from the usual source, the U.S. Bureau of Mines, because the Bureau has not set up a sched ule yet for testing and approving supplied air suits. A supplied air suit never should be worn in an environment which is immediately hazardous to life. The wearer of the suit is dependent solely upon the attached air hose for his supply of breath ing air, so that his activity is_ limited to a prede termined area. Moreover, should his air supply fail, he would have only two to three minutes to escape from the suit. Consequently, the environ ment in which the wearer is working must have both enough oxygen to support life and an immedi ate means of egress. A supplied air suit, in fact, always should be used with a team of two men--one to wear the suit and the second to act as a safety man, governing the air supply and continuously observing the main in the suit. The following fundamentals should be demon strated and explained to trainees: a. How air is distributed to the helmet for breathing and to the legs and arms for dissipating heat and perspiration. b. How the exhaust valves function, their lo cation, any position or situation which may close E-06597 TRAINING 135 them, and the importance of each in ensuring com fortable working conditions. c. How and why the suits are examined and checked for leaks, cracks, and excessive wear, and how the line which supplies air to the suit is tested for safe working condition. d. How the suits are donned without creating leaks which would permit contamination to enter and lessen the efficiency of the suit. e. How the suit is partly decontaminated be fore removal, and how the wearer should be helped. If contaminated by radioactivity, or by such things as beryllium or hydrogen fluoride, the wearer should, if possible, pass from the work area into a shower before removing the suit, to wash off gross contamination. An assistant (wear ing a respirator) should remove the suit because it is both difficult and impractical for the wearer to remove the suit himself, unassisted. With ra dioactive contamination, care must be taken to prevent contamination on the outside of the suit from being transferred to the wearer or to his clothing. f. How the suit is cleaned, and decontaminated if necessary, after use and before storage. These procedures will vary with the type and amount of contamination; see Chapter 12. The pressure in, and air flow to, the suit are most important. Too great air flow creates ex cessive pressure within the suit, ballooning the suit and hampering the operator's dexterity, as well as impairing his comfort while he performs his duties. Conversely, an inadequate air supply makes the suit difficult to wear because then the suit clings to the body and does not properly dis sipate body heat and perspiration. In an extreme case, inadequate air supply could create a safety hazard for the wearer by causing an oxygen de ficiency and carbon dioxide build-up. The air flow will vary between 6 and 15 cubic feet per minute (ft^/min), depending on the individual's personal comfort preference, the duties to be performed, and the size and number of exhaust valves in the suit, but the air flow never should be less than 6 ftVmin. Regulating this air flow and constantly ob serving the wearer of the suit are the primary duties of the wearer's partner. The wearer and his partner must establish a set of hand signals as a means of communication, because the air sup plied to the suit creates a nuisance noise which prevents hearing even very loud conversation. Other communication systems are discussed in Chapter 3, Section UL D. Self-contained Breathing Apparatus The self-contained breathing apparatus is the most complicated respiratory protective device and is worn in the most hazardous atmospheres, often under trying physical conditions. Hence, training should be most thorough, and the trainee should be physically fit. The Bureau of Mines has a formal training course for users or selfcontained breathing apparatus and issues certifi cates to the trainees upon completion of the course. Refresher courses are given from time to time. Space limitations of this Manual do not permit a complete discussion of the training procedures for self-contained breathing apparatus. They are described in a Bureau of Mines handbook.* In general, the training consists of instructing the prospective user in the construction, testing, use, care, and limitations of the apparatus. The follow ing points are stressed: Make certain that the apparatus is in good operating condition with fully charged oxygen or air cylinder, or fresh oxygen-generating canister. Adjust the apparatus securely to the wearer's body and test for gas-tightness. Attach a life line to the wearer's body if he is to enter a confined space containing a highly toxic atmosphere. Two men should tend this life line, which serves as a means of transmitting prear ranged signals between the wearer and the safety men. At least one of these men should wear a similar apparatus. The life line also serves as a means of guiding the apparatus wearer to the exit and as an aid in rescue operations in case he gets into trouble. Enter the contaminated area cautiously and return to fresh air immediately if the contaminant is detected by odor, taste, or nose and throat ir ritation, or if the apparatus is not functioning properly. If entry is successful, remember the time limitations of the apparatus and allow sufficient time to return to fresh air. Do not remove the facepiece, or mouthpiece and nose clip, until after return to respirable air. REFERENCE 1. Morrow, A. E., Demkowicz, W. M., and Chas tain, G. W.: Mine Rescue Apparatus and Auxil iary Equipment, A Handbook for Miners, U.S. Bureau of Mines, Washington, D.C., 1961, 287 pp. -06598 Appendix A DEFINITIONS To standardize the terms used in the respira tory protective field, Section I of Appendix A lists the American Standards Association (ASA) defini tions. Because many other terms, not listed by ASA, are used in the manual and should be de fined, Section II contains supplementary definitions prepared specifically for this manual. Some of these definitions .are common to many scientific fields, but others are used only in respiratory protective work, and their definition is formulated from common usage. L AMERICAN STANDARDS ASSOCIATION DEFI NITIONS* Abrasive-Blasting Respirator: See Respira tor. Aerosol; A suspension of fine, solid, or liquid particles in air as dust, fume, mist, smoke, or fog. Air-Line Respirator; See Respirator. Air-Regulating Valve; An adjustable valve be tween the air-supply line and the breathing tube of an air-line respirator or an abrasive-blasting respirator whereby the flow of air to the facepiece, helmet, or hood may be regulated. Air-Supply Device; A hand- or motor-op erated blower for the hose mask or a source of respirable compressed air for the air-line res pirator and for the abrasive-blasting respirator. Air-Supply Line: A hose to conduct respira ble air from the air-supply device to that portion of a supplied-air respirator carried on the wear er's person. Breathing Tube; A flexible tube through which air or oxygen flows to the facepiece of a respira tor. Canister A detachable container filled with granular materials that remove gases or vapors from the air that is drawn through the unit; it may also contain mechanical filters to remove dust, mist, and smoke particles. Cartridge: A small canister. Cartridge-Type Respirator: See Respirator. Contaminant: A harmful material that is foreign to the normal atmosphere. Demand Respirator; See Respirator. Detachable Coupling; A device by means of which the wearer of an air-line respirator* may quickly detach the air-supply line from that part of the respirator worn on the person. Disinfection; The act or process of destroying organisms that cause disease. Dispersoid: A colloidal or finely divided sub stance. Dust; Finely divided solid particles generated by processing (including handling, crushing, grind ing, or pulverizing) materials such as rock, ore, metal, coal, wood, and grain. Eyepiece: A gastight transparent window in a gas-mask facepiece through which the wearer may see. Exhalation Valve: A device that allows exhaled air to leave a respirator and prevents outside air from entering it. Facepiece: That portion of a respirator that covers the wearer's nose and mouth and makes a gastight or dust-tight fit with his face; the head harness or headbands and the breathing tube are usually included in the facepiece assembly. Filter: A device that removes contaminants from air drawn through it or that converts those contaminants into less harmful compounds. Filter Respirator: See Respirator. Fog: Small liquid particles, condensed from the vapor phase, suspended in a gas such as air. Full Facepiece: A facepiece that covers the wearer's nose, mouth, eyes, and face and makes a gastight or dust-tight fit with his face. It includes eyepieces, the head harness, and breathing tube. Fume: Solid dispersoids formed by condensa tion of vapors, such as those from -heated metals. Gas Mask: See Respirator. Half-Mask Facepiece: A facepiece that covers the wearer's nose and mouth but not his eyes, and makes a gastight or dust-tight fit with his face; the headbands are included in the half-mask assembly. Head Harness (of Gas Mask): A device for holding the facepiece securely in place on the wearer's face. Hood: A device that completely covers the head, neck, and portions of the shoulders. Hose Mask with Blower: See Respirator. Hose Mask without Blower: See Respirator. Inhalation Valve: A device that allows *This material is reproduced from the American Standard Safety Code for Head, Eye, and Respiratory Protection, Z2.1-1959, copyrighted 1960 by American Standards Association, Inc. Copies of the code may be purchased from American Standards Association, 10 East 40th Street, New York 16, New York. 137 E-06599 138 RESPIRATORY PROTECTIVE DEVICES MANUAL respirable air to enter the facepiece and prevents exhaled air from leaving the facepiece through the intake opening. Irrespirable: Unfit for breathing. Mist: Suspended liquid droplets generated by breaking up a liquid into a dispersed state. Particulate Matter: Matter occurring in the form of minute separate particles, such as dust, fume, mist, and fog: a dispersoid. Prefilter: A low-resistance filter pad placed in front of and in series with a regular dispersoid filter to lessen the dust load on the latter byremoving the larger dispersoids from the air drawn through it. Resistance: Opposition to the passage of air, as through a filter or orifice. Respirable: Fit to be breathed. Respirator: A device to protect the wearer from the inhalation of irrespirable atmospheres. Abrasive-Blasting Respirator: A supplied-air respirator, similar in principle to the air-line respirator, providing respiratory protection for the head and neck of the wearer against impact and abrasion by rebounding material during abrasive blasting operations. Air-Line Respirator: A supplied-air respira tor designed to be connected by a smalldiameter hose to a supply of respirable air under positive pressure sufficient to deliver an adequate flow of air to a half-mask facepiece, full facepiece, helmet, or hood. Chemical-Cartridge Respirator: A non emergency chemical-filter respirator usually having a half-mask facepiece and one or more cartridges to remove contaminants from the air drawn through them; it is designed for respiratory protection against low concentra tions of gases and vapors or a combination of dispersoids, gases, and vapors. Demand Respirator: An atmosphere-supplying respirator in which air or oxygen is admitted to the facepiece only when the wearer inhales, and in quantities governed automatically by his breathing. Filter Respirator: A device designed for the wearer to inhale the surrounding atmosphere after it has passed through a filtering medium to remove contaminants. The filtering medium may chemically absorb or mechanically re tain or obstruct the impurities. Gas Mask: A filter respirator having a full facepiece, a canister containing the suitable granular material with or without dispersoid filter, and a canister-carrying harness; it is designed for respiratory protection against gases or vapors or a combination of disper soids and gases and vapors. Helmet, Respirator: A rigid device that com pletely covers the head, neck, and portions of the shoulders of the wearer, and is provided with an air inlet and eyepiece. Hood, Respirator: A loose-fitting device that covers the head and neck of the wearer. It may be a nonrigid or a combination of a rigid head covering and a nonrigid skirt for the head covering. Hose Mask with Blower: A supplied-air res pirator having a full facepiece to which res pirable air is forced through a large diameter hose by a hand- or motor-operated blower, and through which the wearer can inhale whether or not the blower is operated. Hose Mask without Blower: A supplied-air respirator having a full facepiece to which the supply of air is drawn from an inlet in res pirable air through a large diameter hose by the wearer's breathing effort Self-Contained Breathing Apparatus: A res pirator in which the supply of air, oxygen, or oxygen-generating material is carried by the wearer. Supplied-Air Respirator: A respirator that makes respirable air available to the wearer through a hose connected to a source of res pirable air. Self-Contained Breathing Apparatus: See Res pirator. Supplied-Air Respirator: See Respirator. Timer: A device, operated by the wearer's respirations, that indicates the approximate length of time that a universal gas mask has been worn. Toxic Dust: Dust that may be harmful to the respiratory tract or to other parts of the body through passing from the respiratory tract into the blood stream. Valve: A device that permits the passage of air through it in one direction only. n. SUPPLEMENTARY DEFINITIONS Absorption: The incorporation of a gas or va por by chemical action within the pores of a solid. Activity: The capacity of a sorbent to sorb a particular gas or vapor under specified condi tions. Adsorption: The adhesion of a gas or vapor to a solid surface due to molecular attraction. Air-Purifying Respirator: A respirator to remove gaseous and/or particulate contaminants. All Service Canister: Trade name for univer sal canister. Anthropometric: Pertaining to measurements of the human body. Bizygomatic Diameter: Greatest breadth across zygomatic arches (bone between cheek and ear). E-06600 * APPENDIX A 139 Break Concentration: Concentration of con taminant which will saturate canister sorbent within a specified time period. Canister Sizes: Supersize: trade name for large canister (approximately 2000 cc. sorbent). Industrial: fill volume (750 to 100 cc.) affording good protection for a single gas or vapor. Facepiece Attached: (280 to 500 cc.) for limited use in low concentration. Capacity: The total amount of gas or vapor which can be removed from an air stream by the sorbent under specified conditions. This is ex pressed as the ratio of the weight of sorbed sub stance to the weight of sorbent. Catalysis: Acceleration of a chemical reac tion produced by a substance (catalyst), which is unchanged at the end of the reaction. Chemical Filter Respirator: Same as gas and vapor removing respirator. Critical Bed Depth: Minimum depth of a sor bent required to remove a specific gas or vapor concentration from an air stream under specified test conditions. Desorption: The evolution of gases or vapors that have been adsorbed within a sorbent. The re verse of adsorption. Diffusion: The intermixing movement of ex tremely small particles due to molecular motion. Direct Interception: The deposition of a par ticle from a streamline onto a filter fibre due to the streamline's passing the fibre within a distance equal to or less than the radius of the particle. Dispersoid-Removing Respirator: A filter respirator that removes particulate contaminants such as dusts, fumes, and mists. Electrostatic Attraction: Force tending to move charged particles towards an oppositely charged surface while passing through an electric field. Charge may be carried or induced. Eyepiece: A gas tight transparent window in a respirator facepiece through which the wearer may see. Gas- and Vapor-Removing Respirator: A res pirator designed for the removal of gases and va pors. GMA Canister: Trade name. GMD Canister: Trade name. Inertial Impaction: Deposition of particles on a filter due to inertial effects produced by particle mass and velocity. Loading (of filter): Deposition of particles on the filter, thereby reducing pore size and increas ing efficiency and resistance. Mandible Height: Distance from midpoint of inferior border of mandible to the superior point of .the gum between the two central lower incisors. Mechanical Filter Respirator: Same as Dispersoid removing respirator. Nares: The external openings of the nose. Nasion-Menton: Face height; distance between Nasion (the middle of the naso-frontal suture) to the midpoint of the inferior border of the mandi ble. Nonemergency Respirator: A device designed to provide protection against atmospheres which are not immediately dangerous to life and from which the wearer can escape without the aid of the respirator. Nuisance Dust: Nontoxic and nonfibrosisproducing particles that dissolve and pass directly into the blood stream or remain in the lungs pro ducing neither local nor systemic effects. Pneumoconiosis-Producing Dust: Particles which remain in the lungs and may cause signifi cant pulmonary impairment. Recirculating Self-Contained Breathing Apparatus: A self-contained breathing apparatus that removes carbon dioxide and moisture from the ex haled air and adds oxygen to the exhaled air for rebreathing by the wearer. Retentivity: The total amount of gas or vapor which once sorbed will be retained by the sorbent under specified conditions. This is expressed as the ratio of the weight of sorbed substance to the weight of sorbent. It is always less than the ca pacity. Reynolds Number: A dimensionless number describing flow conditions. Below a Reynolds Number of 2000, laminar or viscous flow exists. Above a Reynolds Number of 3000, turbulent flow exists. SCUBA: Self-contained underwater breathing apparatus. Sorbate: That which is adsorbed or absorbed. Sorbent: A substance which has the capability of retaining gases or vapors by the adsorption or absorption mechanism. Standard Deviation (og): A statistical measure of spread of a mathematical distribution. ~ Threshold Limit Value: The time average atmospheric concentration of a contaminant to which workers can be repeatedly exposed, for an eight hour work day without adverse effect. Universal Canister: U. S. B. M. type N can ister, designed to remove acid gases, organic va pors, ammonia, carbon monoxide, and dispersoids. Viscous Flow: Laminar or streamline flow; flow at low Reynolds Number. Window-Indicator Universal Canister: A uni versal canister with a small window on one side which gives a visual indication of the canister's ability to remove carbon monoxide and indicates the end of useful service life of the universal can ister against carbon monoxide. i H E--06601 Appendix B RECOMMENDATIONS REGARDING RESPIRATORY PROTECTION AGAINST HIGHLY TOXIC AEROSOLS* The U.S. Bureau of Mines is carrying out a program that will eventually lead to the prepara tion of performance requirements for respiratory protective equipment designed to protect the wearer against the inhalation of highly toxic aero sols. The Joint AIHA-ACGIH Committee on Res piratory Protective Equipment believes that some performance criteria are necessary to cover the interim before the advent of formal approval pro cedures. For the interim, the Joint Committee recom mends the following approach to the protection of personnel against the inhalation of highly toxic aerosols: A. Highly Toxic Aerosols of Unknown Concentra tion Use respirators that provide a positive pres sure at all times in the breathing zone of the wearer. Such respirators include certain types of supplied-air respirators and self-contained breath ing apparatus. B. Highly Toxic Aerosols in Known Concentra tion** 1 For exposures to concentrations that are less than 10 times the threshold limit value '(TLV), use a half mask with "high efficiency* filter. For exposures to concentrations that are less than 100 times TLV, use a full facepiece with "high efficiency* filter. The wearers should be instructed in the proper method of fitting and using the respira tory protective equipment, and the equipment should be maintained in good operating condi tion. Prepared by the Joint AIHA-ACGIH Committee on Respiratory Protective Equipment. A footnote to the title of the recommendations reads: "For the purpose of this recommendation, `highly toxic aerosols' are defined as solid or liquid particles of materials which are significantly more toxic than lead but which present no inhalation hazard due to vapors of the materials at temperatures less than 100F.* **The term "known concentration," as used in this statement, implies a knowledge of the concentration based on actual measurements prior to exposure, sufficient previous evaluation of the operation, or the careful evaluation of the operation and a conservative estimate of the concentration by a trained ob server. 140 E-06602 Appendix C PROTECTIVE AGAINST PARTICULATES SIGNIFICANTLY MORE TOXIC THAN LEAD AD HOC AEC COMMITTEE ON RESPIRATORY PROTECTIVE EQUIPMENT REPORT OF THE SUB-COMMITTEE ON REQUIREMENTS SUGGESTED REQUIREMENTS FOR RESPIRATORY PROTECTIVE EQUIPMENT FOR USE AS PROTECTION AGAINST ATMOSPHERES CONTAINING PARTICULATES SIGNIFICANTLY MORE TOXIC THAN LEAD* The AEC Ad Hoc Committee on Respiratory Protective Equipment has herein synthesized cer tain objective requirements for respiratory pro tective devices to assist users, vendors, and manu facturers in understanding what characteristics and features are desired in such equipment to meet customer requirements for safe, comfortable, and functional equipment. The specifications that fol low do not set forth the complete requirements but are intended to accentuate certain features that warrant special consideration. In compiling these specifications, the opinions and experience of in dustrial health personnel of 23 AEC contractors were weighed. It is possible that subsequent ex perience in the development and use of devices in corporating the features outlined herein will indi cate modifications to these requirements that may be desirable in the future. L MASKS AND RESPIRATORS - MECHANICAL FILTER A. FULL-FACE MASKS 1. Performance (1): Overall penetration (2) of. the device shall be less than 0.1% averaged over the inhalation and exhala tion cycle. Any specific device (or a size series thereof) shall provide a fit that will assure no greater than the stated penetration for at least 95% of the normal adult population (3). The 5% not* 1 2 3 achieving the stated protection shall be identifiable by some criterion. 2. Comfort; a. Maximum initial resistance to air flow, at 85 liters per minute; inhala tion = 1.25M HjO, exhalation = 0.75" HjO. b. Maximum weight of complete face- piece, including cartridges, etc. = 1.25 lbs. Center of gravity should be as close to the face as possible to minimize neck fatigue. c. Device should be capable of being worn for two 4-hour periods daily without objectionable discomfort, such as * pain spots," etc. d. Cartridges, canisters, and other pro jections should be so located that un restricted freedom of head move ment is provided. e. The facepiece should incorporate features to minimize movement of the mask relative to the face. f. The device should incorporate fea tures that will permit utilization of corrective spectacles' .without in creasing penetration beyond the per missible maximum or adversely af fecting the other stated criteria. 3. Vision; a. Use of the device shall not restrict normal binocular vision more than The following specifications pertain to the components of the respiratory equipment that actually provide respiratory protection; viz., mask and respirator facepieces, etc., but do not include the requirements for supplementary components such as bottled gas supplies, air-supply piping systems, pumps, etc. (1) Based on tests performed with a gas and/or a standardized homogeneous particulate aerosol in the size range 0.1 /i - 0.5 m diameter and with pulsating airflows. (2) Overall penetration implies the combined penetration from all sources such as the filter medium, face seal leakage, leakage by valves, speaking diaphragms, etc. (3) Based on the definition of normal U.S. adult population as reported by the U.S. Army Chemical Corps and the Federal Civil Defense Agency as a result of a study to determine the fit of gas masks. 141 E 142 RESPIRATORY PROTECTIVE DEVICES MANUAL 3. Vision (cont.) 30%. Evaluation of this requirement shall be based on actual vision tests performed on individuals that repre sent the extreme facial characteris tics of the group that the device is supposed to fit. b. Where the use requires beta radia tion protection, the lens should have a minimum thickness of 2 mm. c. The lens should meet approved stand ards for safety lens material issued by the American Standards Associa tion. d. Air inlets should reduce lens fogging. 4. Exhalation and Inhalation Valves: a. Check valve(s) shall be present for inhalation and exhalation airflow con trol. b. All check valves should be adequate ly guarded. 5. Decontamination: a. Device must be capable of being de contaminated 50 times by being washed in mild soap for 15 minutes at 120F. without functional impair ment. b. The device should be capable of being disassembled and assembled using a minimum of common hand tools or special tools provided by the manu facturer. c. The device should have a smooth in terior and exterior finish, incor porating design features which elim inate cracks, wrinkles, pits, and overlapping parts. Canvas or other absorbent materials should not be used. 6. Standardization: Where possible, facepiece components . for-any manufacturer's device should be. standardized to permit interchangeable use of filters, cartridges, canisters or supplied air. B. RESPIRATORS AND HALF-MASKS 1. Performance: (1) Overall penetration (2) of the device shall be less than 1.0%. Any specific device (or a size series thereof) shall provide a fit that will as sure no greater than the stated penetra tion for at least 95% of the normal adult population (3). The 5% not achieving the stated protection shall be identified by some criterion. 2. Comfort: a. Maximum initial resistance to air flow, at 85 liters per minute; inhala tion = 1.25" HjO, exhalation = 0.75" HjO. b. Device should be capable of being worn for two 4-hour periods daily without objectionable discomfort, such as "pain spots," etc. c. Cartridges, canisters, and other pro jections should be so located that un restricted freedom of head movement is provided. d. The device should incorporate fea tures that will permit utilization of corrective spectacles without in creasing penetration beyond the per missible maximum or adversely af fecting the other stated criteria. e. The facepiece should incorporate features to minimize movement of the mask. 3. Exhalation and Inhalation Valves: a. Check valve(s) shall be present for inhalation and exhalation airflow con trol. b. All check valves should be adequate ly guarded. 4. Decontamination: a. Device must be capable of being de contaminated 50 times by being washed in mild soap for 15 minutes at 120F. without functional impair ment. b. The device should be capable of be ing disassembled and assembled us ing a minimum of common hand tools or special tools provided by the man ufacturer. c. The device should have a smooth in terior and exterior finish, incor porating design features which elim inate cracks, wrinkles, pits, and overlapping parts. Canvas or other absorbent materials should not be used. 5. Standardization: Where possible, facepiece components for any manufacturer's device should be standardized to permit interchangeable use of filters, cartridges, or canisters. (1) Ibid. (2) Ibid. (3) Ibid. E--06604 Appendix D This U.S. Department of Agriculture release became available after the text of the Manual was com pleted and therefore is included as an Appendix. September 1962 ARS-33-76 United States Department of Agriculture Agricultural Research Service RESPIRATORY DEVICES FOR PROTECTION AGAINST CERTAIN PESTICIDES1 2 by R. A. Fulton, Floyd F. Smith, and Ruth L. Busbey Entomology Research Division Increased interest in respiratory protective devices for operators handling pesticides began in 1947 and 1948, when parathion and other extreme ly dangerous phosphorus compounds were found highly effective in controlling insects in green houses and on agricultural crops. The former U.S. Bureau of Entomology and Plant Quarantine ini tiated an investigation of such devices. On June 22, 1949, it issued a statement on minimum safe guards to be observed in filling greenhouse aero sols containing parathion, other organic phosphor us chemicals, and methyl chloride produced under license agreements issued under U.S. Patent 2,321,023 (a public-service patent assigned to the Secretary of Agriculture). In this statement were mentioned three commercially available gas-mask canisters that had been found to give adequate pro tection against these insecticides. Also included were other precautionary measures to be ob served. No suitable, fully effective respirators were found to be available for protecting operators in the field from inhalation of dusts or mists of parathion andrelatedphosphorus insecticides. The Interdepartmental Committee on Pest Control sponsored an informal meeting on September 30, 1949. Representatives of the government agencies concerned with the use of pesticides or with res piratory protection met to consider the need for such protective devices against the many new pesticides that were coming into use. As a result of this meeting, two conferences were held by representatives of these agencies and manufac turers of respiratory protective equipment. The manufacturers were invited to submit devices that might provide suitable protection. These were evaluated by the Bureau of Entomology and Plant Quarantine. On May 4,1950, the Interdepartmental Committee issued a list of five respirators that had been found to give a high degree of protection from dusts, mists, and low vapor concentrations of parathion in field use. Subsequently, lists of respirators and gas-mask canisters found to give adequate protection against other pesticides were issued by the Bureau on August 24, 1951, and May 1, 1952; and by the Agricultural Research Service on July 12, 1954 (revised August 9, 1954); June 27, 1955; April 29, 1957; July 22, 1957; and March 20, 1961. In November 1951, Fulton and coworkers in the Bureau (1)2 described test methods for de termining the protective efficiency.of respirator cartridges and gas-mask canisters. In Augustl955, Fulton et al. (4) reported on testing methods used and respiratory protective devices for insecticides in agricultural use. In January 1957, Fulton and McClellan (2) reported on respirators and gas mask canisters found effective against several representative fungicides and nematocides. In August and September 1958, Fulton and Smith (3) described in detail the methods used in testing respiratory devices against pesticides, and they tabulated all the information obtained up to that time. In brief, the methods usually comprised 1._This publication contains all information available as of August 31, 1962 and supersedes all releases and publications on this subject by the Department. 2. Numbers in parentheses after the authors' names refer to Literature Cited at the end of this report. 143 E--06605 144 RESPIRATORY PROTECTIVE DEVICES MANUAL drawing pesticide-laden air through the cartridge or canister into a chamber containing insects (aphids and spider mites) of known age on plants. By observing the rate of fall of the insects from the plants, for most insecticides, the effectiveness of the device under test in removing the pesticides from the air stream could be determined in a few minutes. In the case of fungicides, the air after passage through the cartridge or canister was analyzed by methods cited by Fulton and McClel lan (2). TYPES OF RESPIRATORY DEVICES Two kinds of respiratory protective devices are in general use--chemical cartridge respira tors (hereinafter referred to as respirators) and gas masks. Most respirators are designed as half face masks that cover the nose and mouth but do not protect the eyes (Figs. 1, 2). They have one or two cartridges attached to the facepiece by a clamp or secured in a holder. The respirator facepieces are equipped with one-way valves, which allow the inhaled air to pass through the cartridges but pre vent the exhaled moist breath from passing through the cartridges. Gas masks usually are made to cover the entire face (Fig. 3). Their facepieces are made to hold a canister directly or to connect to the canister by means of a flexible hose. The canister of the hose type is carried on the chest or back by means of straps. Fig. 2. Wearing respirator during power spraying. Fig. 1. Commercially available respirator adequate for protection against pesticides. E-0660 APPENDIX D 145 Respirator cartridges usually contain an ab sorbing material such as activated charcoal. All the respirators listed in this report also have very efficient filters, which remove dust and spray particles and thus prolong the life of the absorbing material. Gas-mask canisters always contain more absorbing material and longer life filters than respirator cartridges. The volume of chemi cal absorbing cartridges and gas-mask canisters varies from 50 to 100 ml. (usually the latter) for cartridges, 180 to 500 ml. for chin-style canisters, and 750 to 1,800 ml. for chest-type canisters. Cartridges and chin-style canisters have a shorter useful life than regular canisters because of the smaller volume of sorbent material in them. U.S. Bureau of Mines requirements stipulate a gas-mask canister life of one-half hour when the device is worn by men performing moderate ex ercise in gas concentrations up to 2 percent. The life of the canister will vary according to the con centrations encountered, e.g., 1 hour for 1 percent. The life of chemical absorbing cartridges or can isters will also be affected by humidity, tempera ture, and volume of breathing. High humidity shortens the life of cartridges and canisters in use and in storage. Mist, sprays of water, and rain re duce the effective period of the units. Our tests have shown that cartridges and canisters in stor age will gradually lose their effectiveness because of the exchange of air within the unit due to changes in temperature and atmospheric pressure. An interesting supplied-air respirator (Fig. 4) has a combination blower-filter with a breathing hose leading to a hood worn by the operator. It incorporates both a safety helmet and a face shield. The unit supplies purified air which has passed through filters for removing dust or spray particles and insecticide vapors. Units for mount ing on tractors or application equipment (Fig. 5) are obtainable for operation on 6- to 24-volt di rect or 115-volt alternating current. Because of the difference in their protective capacity, gas masks, not respirators, must be worn when pesticides are formulated or mixed in close or inadequately ventilated spaces or when operators are exposed directly to concentrated Fig. 4. Supplied-air respirator with blower-filter and hood. 146 RESPIRATORY PROTECTIVE DEVICES MANUAL Fig. 5. Supplied-air respirator mounted on sprayer. dusts, sprays, or aerosols, as in greenhouses, in doors, or at the rear of a power-drawn rig. For special operations, such as dusting or spraying under tobacco shade cloth or in citrus groves on hot days, a half-mask facepiece with a regular gas-mask canister is available. To protect the eyes under these conditions nonfogging goggles are desirable. Thesecan be purchased wherever weld ing supplies or underwater and diving equipmentis sold. For fumigation workers in ship holds and be low the surface in grain elevators, where low oxygen content may be encountered, a hose mask with blower or a self-contained air-supply unit must be used. The hose mask is connected to an air source free of the toxic material. Demandtype masks connected to a compressed-air cylinder also can be used for short periods. These cylin ders are available in various sizes--the most com mon size contains 22 cubic feet of air, enough for 15 to 20 minutes' service. The use of an oxygen mask is not favored by some authorities where heavy work is involved, because this type of mask requires a period for the lungs to adjust to normal breathing. USE AND CARE OF RESPIRATORS The use of respirators is advised for protec tion from dusts or mists during field handling of the pesticides listed in Table 1. Instructions given on pesticide labels concerning respiratory protec tion should be carefully observed. The use of res pirators is not a substitute for essential precau tions. Protective equipment herein discussed is indicated for use when mixing or handling all pesticides in poorly ventilated areas or at high temperatures. Under open field conditions, pro tective equipment may not be required while ap plying dilute dusts or water sprays of naled, Sevin, malathion, and ronnel.^ It is necessary that respirators be used in handling pesticides during the loading of distribu tion equipment (Fig. 6), when containers are being disposed of, and whenever operators are exposed 3. The mention of proprietary products does not constitute their endorsement by the U.S. Department of Agriculture. (=-06608 APPENDIX D 147 (3) Remove filters and cartridges and wash the facepiece with soap and warm water after use. After washing, rinse it thoroughly to remove all traces of soap. Dry the facepiece with a clean cloth that is not con taminated with the pesticide. Place the facepiece in a well-ventilated area to dry. (4) Store the respirator, filters, and car tridges in a clean, dry place--preferably in a tightly closed paper or plastic bag. The respirator should be fitted properly on the face, not too high on the nose, with the narrow part over the bridge of the nose, and the chin cup contacting the underside of the chin. Headbands should be adjusted just tightly enough to insure a good seal (Fig. 3). Manufacturers can supply spe cial facepieces if the standard one does not fit. Fig. 6. Wearing respirator while loading spraying equipment with insecti cide concentrate. to obvious amounts of dusts or mists of the more dangerous pesticides. Field operators who may be exposed continuously during the day or for suc cessive days to'small amounts of toxic pesticides-- even those not readily detectable--should faithfully use respirators as a precaution. Respirators will give adequate protection to airplane pilots during normal dusting or spraying operations, but gas masks are necessary when there is exposure to high concentrations of the more toxic pesticides. Pilots should take care to select and wear goggles that give a tight seal with the respirator around the nosepiece. When respirators are used, the following practices are necessary: (1) Change filters twice a day or oftener if breathing becomes difficult. . (2) Change cartridges after 8 hours of actual use or oftener if any odor of the pesticide is detected. CONDITIONS REQUIRING GAS MASKS Respirators do not provide needed protection from inhalation of pesticide dusts, mists, and va pors for operators formulating or mixing pesti cides in closed or inadequately ventilated spaces. Full-face gas masks equipped with tested canis ters are worn under these conditions. In addition, proper protective clothing as specified on the pesticide-container label should be worn when ap plying pesticides in greenhouses or other en closed spaces (Fig. 7). When applying grain fumigants, recommenda tions of the fumigant manufacturer should be fol lowed closely. In some situations, as when pouring concentrated fumigating material directly on the surface of grains, there may be very high concen trations of gas close to the air inlet of the gas mask canister. The concentration of the gas in the intake air may be reduced by mounting the canister on the back (Fig. 8). OTHER ESSENTIAL PRECAUTIONS The use of respiratory protective devices does not eliminate the need for other precautions in handling toxic pesticides. Provide for adequate ventilation of the area where pesticides are loaded or mixed. Always wear well-constructed naturalrubber latex gloves when handling concentrated materials. Check the condition of the gloves fre quently and discard them if they develop pinholes or breaks. If any of the organic phosphorus in secticides are spilled on the skin or clothing, wash immediately with laundry soap. Never wear clothes that have been contaminated with pesti cides until they have been washed. If at any time the concentrated pesticide is spilled, cover it 148 RESPIRATORY PROTECTIVE DEVICES MANUAL Fig. 8. Gas mask with canister mounted on back of operator to reduce concentration of gas in intake air while applying grain fumigant. Fig. 7. Gas mask and protective clothing used during aerosol treatment in green house. immediately with dirt, clay, or sand. Then cover the contaminated area with washing soda or lime. If an operator shows any sign of dizziness or nausea, he should immediately be removed from the area and placed in the care of a physician before he returns to work. LIST OF RESPIRATORS AND GAS-MASK CANISTERS The commercially available respirators and gas-mask canisters that have been tested and found to give adequate protection against dusts, mists, and low vapor concentrations of certain pesticides are listed below. In developing and testing new designs for respiratory protective equipment, we have tested each device against the pesticides for which it actually will be used. Fol lowing the list is a table showing the particular pesticides against which each respirator or can ister will give protection. It should be noted that some of the devices are limited in their range of effectiveness. Cartridges and canisters that pro tect against individual pesticides do not always give adequate protection against mixtures of the same pesticides. Before a facepiece, cartridge, or canister is purchased, its range of usefulness should be checked. Respirators with Face-Mounted Cartridges A. Respirator No. 5055, equipped with R-55 filter and cartridge unit. Two units attached to facepiece. (American Optical Co., Safety Divi sion) B. Healthguard Respirator style 95, equipped with Code B cartridge and filter 1000 or 1001. One unit attached to facepiece. (Chicago Eye Shield Co.) C. DCA 6100 Respirator, with Para-A cartridge and DC 6100-7 felt filter. (Pulmosan Safety Equipment Corp.) D. Agrisol Dust and Vapor Respirator, equipped with R-414 filter and 11-A cartridge. Two E--0661O APPENDIX D 149 units attached to facepiece. (Ray-O-Vac Co., Willson Products Division) E. Respirator No. 5561, equipped with filter car tridge combination R-561. (American Optical Co., Safety Division) F. Farm Spray Respirator No. CR-72183, equipped with cartridge No. CR-49293 and filter No. 73488. (Mine Safety Appliances Co.) G. All Vision Chemical Cartridge Respirator No. CR-74910, equipped with inner cartridge No. CR-73841 and outer cartridge No. 73927. (Mine Safety Appliances Co.) H. Agritox Respirator, equipped with cartridge No. 11A (new type) and filter No. R490. (RayO-Vac Co., Willson Products Division) I. Respirator No. 5058, with filter-cartridge com bination R-58. (American Optical Co., Safety Division) J. C-241 Respirator, with CMP cartridge and C-241-7 .filter. (Pulmosan Safety Equipment Corp.) K. Gasfoe Respirator No. CM-86007, equipped with cartridge No. CM-76883 and mineral-wool filter No. CM-79786. (Mine Safety Appliances Co.) Supplied-Air Respirators able for field use. (Ray-O-Vac Co., Willson Products Division) 7. Canister No. 3235 TypeC-40. (Davis Emergency Equipment Co.) ********** The addresses of the companies supplying these respirators and gasmasks are given below.' Respirators are also available from pesticide dis tributors and mail-order houses. Acme Protection Equipment Co., 1201 Kalamazoo St., South Haven, Mich. American Optical Co., Safety Division, Southbridge, Mass. Chicago Eye Shield Co., 2300 Warren Blvd., Chicago, HI. Davis Emergency Equipment Co., 45-57 Halleck St., Newark 4, N.J. Jamieson Laboratories, Inc., 7900 Haskell Ave., Van Nuys, Calif. Mine Safety Appliances Co., 201 North Braddock Ave., Pittsburgh 8, Pa. Pulmosan Safety Equipment Corp., 644 Pacific St., Brooklyn 17, N.Y. Ray-O-Vac Co., Willson Products Division, Read ing, Pa. a. Whitecap Model SU-1 with No. 901 rubberized shroud, No. 301 cartridge, and No. 101 filter element. (Jamieson Laboratories, Inc.) b. Same as L, except with extra fine No. 102 filter element. (Jamieson Laboratories, Inc.) Gas-Mask Canisters 1. Chin Style (282-OVAG-F) Insecticide Canister. (Acme Protection Equipment Co.) 2. Canister GMC-1. (Mine Safety Appliances Co.) 3. Canister G3FD. (Ray-O-Vac Co., Willson Products Division) 4. Universal-type canister of any manufacturer. Type N, bearing Bureau of Mines approval. 5. Military Canister No. 084-Military. (Acme Pro tection Equipment Co.) 6. Canister No. H-3, equipped with facepiece filter holder and throwaway filter No. R361 or R393. Can be obtained with either a full-face gas mask or a half-mask facepiece. The half-mask facepiece should not be used when mixing or handling insecticides in enclosed spaces or applying aerosols in greenhouses, but is suit LITERATURE CITED (1) Fulton, R. A., Konecky, M. S., and Smith, F. F. 1951. Determining the efficiency of respira tory cartridges and gas mask can isters against dust and sprays. U.S. Bur. Ent. and Plant Quar. E-830, 8 pp. (2) 1957. and McClellan, W. D. Respiratory protective devices for agricultural pesticides. . Phyto pathology 47:56-57. (3) and Smith, F. F. 1958. Respiratory protective devices. Meth ods for testing them against pesti cides. Agr. Chem. 13(8):30-32; 13 (9):22-24. (4) Smith, F. F., and Gelardo, R. P. 1955. Respiratory protective devices for agricultural use. Jour. Econ. Ent. 48:457-459. 4. No discrimination is intended against any company not mentioned, nor is any guarantee implied-for the products of the listed companies. 150 RESPIRATORY PROTECTIVE DEVICES MANUAL 303Q Q* a i a 5 uc g g 2a o a t +a 3o a a a atc 3aH a aa a TJ 3a3 Q, au T3 1 is & t H I ++ + ++ + ++ + ++ + ++ + ++ + ++ +++++ + + + ++ +++++ +++++ +++++ +++++ + + + f + ++ ++ ++ ++ ++ ++ + +++++ + + + + +++++ +++++ +++++ +++++ +++++ + + + + + 4- + + + + + + + + + + + i- + + + + + + ++++++++ ++++ +++ ++++++++ ++ + + + +++ + + ++ ++ + ++++++ + +++++ + + +++++ + + ++++ + ++++ + ++++++ + ++ + +++ + + + ++ + + + ++ + + + + ++ + + + + + ++ + ++ + + +++ + + ++++ ++++++++ + +++++ + ++ + + ++ + + + ++ ++ ++ + + + + + + + ++ + + + + ++ + ++++ ++ ++++ ++++++++ + + ++ + ++ + ++ + +++ + + ++ +++ +++ +++ + + + +++ +++ + + + + + + + + + + + + + + + + + + + + + f + + ++++ + + + + + + + + '+ + + + + + + + + + + + + + + + ++++ + + +. + + + + + + ++&++ ++++ +++ + ++++ + + + + + + + + + + + + + + + f + + + + + + + + ++++ ++ + ++ ++ ++ ++ + ++ ++ ++ ++ + ++ ++ +t ++ + _. + ++ j- __ + + + + + + + + + + + + + + + + g s |! "s S?s - . . S.H & I1-R-R5 St u a 5 5v a ?5fiS2 E-06612 APPENDIX D a &aos *o a T & *5 0o>) a > 0) COQ a . 0> CD .O c 'O 1 CD 3 -M 151 I I --06613 INDEX -A- Abrasive blasting helmets, hoods, masks, ap proved, 99 Abrasive blasting respirators definition of, 137 types of, 72 Absorbents composition of, 53 definition of, 50 effect of moisture content on, 54 Acid gas canister, test conditions for, 85-86 Acid gas masks, approved, 95-97 Acme Protection Equipment Company products gas masks, approved, 95-97 gas mask canisters, 149 supplied air respirators, approved, 99 Acrylonitrile, proper canister needed for respira tory protection against, 118 Activated alumina, 52 Activated charcoal adsorption capacities of, 50-52 as a catalyst, 52 impregnation with selected compounds, 52 in relation to boiling point of contaminant, 51 Adsorbents definition of, 49 granular, characteristics of, 50 Advantages of self-contained breathing apparatus, 77 Airborne contaminants, sizes of, 36 Air flow to lungs comparison for athletes and non-athletes, 16 effect of work rate on, 13-17 effects of resistance to, 12-14 expiratory flow, 12 instantaneous flow, 11 mean inspiratory flow, 10 measurements of, with external resistance, 13 measurements of, with minimal resistance, 11 minute volume of, 10 subjective response to resistance of, 12-14 tests to determine, 84-86 tidal volume of, 12 Air inflated suits, 73 Air line respirators approved, 98 definition of, 137 description of, 71 training in use of, 133 types of, 71 uses of, 70; in protection against beryllium, 113 Air purifying respirators definition of, 138 description of, 61 for insecticides, 121-122 limitations of, 66-68 principles of operation of, 61 protection against radioactive aerosols and gases, 106 sorbents for, 49 types of, 61 Air supply, compressed, 74 Air supply line definition of, 137 tests to determine strength of, 84-86Alumina, activated, 52 Aluminum oxide, porous, 52 American LaFrance Corporation products gas masks, approved, 97 supplied air respirators, approved, 98 American Optical Company products chemical cartridge respirators, approved, 103 dispersoid respirators, approved, 100-102 respirators with face mounted cartridges, 148 American Standards Association color code for gas masks, 63-64 definition of terms used in respiratory pro tective field, 137-139 Ammonia adsorption by activated charcoal, molecular sieves, activated alumina, silica gel, 52-53 proper canister needed for protection against, 118 Ammonia canister, test conditions for, 85-86 Ammonia gas masks, approved, 97 Antifogging compounds, 31 Antigas respirator, of Canadian Army, 108 Approval label, illustration of, 79 Approval plates, Bureau of Mines, 79 Approval programs, respirator U-S. Bureau of Mines, 6-7; 79-89 U.S. Department of Agriculture, 7; 119-121 Approved respiratory protective devices, lists of chemical cartridge respirators, 102-103 dispersoid, 100-102 gas masks, 95-98 self-contained breathing apparatus, 95 supplied air respirators, 98-99 153 ^"06614 154 RESPIRATORY PROTECTIVE DEVICES MANUAL Approval schedules, U.S. Bureau of Mines system for, 79-80 test methods, 80-92 Army Chemical Corps (see U.S. Army Chemical Corps) Arsine, adsorption by activated charcoal, 52 -B- Bath towels, respiratory protection provided by, 124 Bed depth of sorbents, 49 Benzene, proper canister for protection against, 118 Beryllium concentration limits, proposed by AEC, 112 problems encountered in processing plants, 112 protection against, interim recommendations for respirators, 112-113 Binks Manufacturing Company products chemical cartridge respirators, approved, 102-103 Biological laboratories, use of supplied air suits in, 73 Blowers, hand and power operated, 70 Breathing apparatus, self contained (see self-con tained breathing apparatus) Bromine, adsorption by activated charcoal, 51 Bullard, E. D., Company products gas masks, approved, 96-98 supplied air respirators, approved, 98-100 Bureau of Mines (see U.S. Bureau of Mines) -C- Canadian Army antigas Respirator, 108 Canisters arrangements of layers in, 54 color code for, 64 conditions for testing, 85-86 definition of, 137 diagram of, 63 layers of sorbents in, 54; 62 life of, 117 maintenance of, 55 moisture effect on, 55 performance requirements, 85-86 tests, machine, continuous flow, 81 types and colors needed for protection against specific fumigants, 118 universal, 54 use of, factors involved, 55 use of sorbents in, 55 warning of impending failure of, 115 wearing of, 63-64 Carbonates, chemical classification and TLVof, 121 Carbon dioxide, proper canister for protection against, 118 Carbon disulfide, proper canister for protection against, 118 Carbon monoxide adsorption of by hopcalite, 53 approved gas masks, 97 canister, for protection against specific fumigants, 118 canisters, test conditions for, 85-86 Carbon tetrachloride, proper canister for protec tion against, 118 Cartridge, construction of, 65 Chalk River reactor accidents, 108 Charcoal (see activated charcoal) Check points in respirator instruction for air line respirators, 134 for gas masks, 130 for hose masks, 132-133 for particulate-removing respirators, 129 Chemical cartridge respirators approved devices, list of, 102-103 Bureau of Mines, approval system for, 79 cautions applicable to, 59 construction and uses of, 65 definition of, 138 man tests of, exercise schedule for, 87 manufacturers of, 102 organic vapor, performance requirements of, 91 test methods for, 89 training in use of, 130 warning against use of during fumigation with pesticides, 122 Chemical filter respirator (see gas and vapor- removing respirator) Chemisorption, definition of, 49 Chicago Eye Shield Co. products chemical cartridge respirators, approved, 103 dispersoid respirators, approved, 100-102 respirators with face mounted-cartridges, 148 supplied air respirators, approved, 98-100 Chlorine, adsorption by activated charcoal, 51 Chloroform, proper canister for protection against, 118 Chloropicrin, proper canister for protection against, 118 Cleaning of respirators, 127-128 Colloidal silica, dehydrated (see silica gel) Color code for gas mask canisters, 64 Combination chemical cartridge respirators with filters, 66 Combination particulate removing and gas-remov ing respirators, 61; 65 Comfort of respirator, effect on performance, 109 Compressed air supply, 74 Construction of particulate filters, 35 E--06615 INDEX 155 Copper compounds, chemical classification and TLV of, 121 Corn, shelled, recommendations for safe fumiga tion of, 113 Consulting service to manufacturers, Bureau of Mines, 79 Continuous flow supplied air respirators description of, 71 protection against radioactive aerosols and gases, 106 Cover, H. S., products dispersoid respirators, approved, 100-101 Critical bed depth of sorbents, 49 Crystalline zeolites, synthetic (see molecular sieves) Cyanide chloride, adsorption by activated char coal, 52 -DDaily tolerances for various insoluble materials, 105 Davis Emergency Equipment Co. products gas masks, approved, 96-98 gas mask canister, 149 supplied air respirators, approved, 98 Definitions of terms used in respiratory protec tive field, 137-139 Demand flow supplied air respirators, 71 Demand self-contained breathing apparatus, 75 DeVilbiss Company products chemical cartridge respirators, approved, 103 dispersoid respirators, approved, 101 Diaphragm compressors, 74 Diffusion, filtration by, 38 Dioctyl phthalate (DOP) filter test, 47 Dioctyl phthalate smoke, use of in testing aerosol respirators, 89-90 Direct interception, filtration by, 37 Disinfecting (see fumigation) Dispersoid-removing respirators definition of, 139 efficiency of, 46 manufacturers of, 100-101 Dispersoid respirators approved devices, list of, 100-102 Bureau of Mines approval system for, 79 filters for older types, 61 performance requirements of, 91 test methods for, 88 Disposable supplied air hoods, 72 DOP (see dioctyl phthalate) Dowfume 75 fumigant mixture, 114 Dress material, respiratory protection provided by, 124 Dusting operations, 147 Dusts and fumes extremely toxic, minimum protection against, 110-111 moderately toxic, minimum protection against, 111 Dust respirators, approved, 101 -E- Efficiency of filter fiber, calculation of, 40 Efficiency of filter media, factors affecting, 40-42 Electrostatic attraction, filtration by, 38-39 Emergency respirators cleaning of, 127-128 inspection of, 127 use of household items as, 123 Ethylene bromide, proper canister for protection against, 118 Ethylene dichloride, proper canister for protection against, 118 Ethylene oxide, proper canister for protection against, 118 Evaluation of respirator performance, technique for, 109-110 Exercise, schedules for, during man tests of chemical cartridge respirators, 92. of gas masks, 87 Eye protection, need of during fumigation, 117 Eyeglasses, provisions for, in full face masks, 29, 110 Eyepieces (lenses), consideration in attachment to full face masks, 29 -F- Facelets, 61 Facepieces air purifying elements of, 29 definition of, 137 field test for fit of respirators using isoamyl acetate, 130 fit of, as a limitation of use for air purifying respirators, 67 fit of, in relation to respirator dimensions, 19-25 fit of, in respirator protection against radio active aerosols and gases, 107 fit of, tests at Los Alamos Scientific Labora tory, 22-23 for abrasive blasting respirators, 72 for air line respirators, 71 for hose masks, 69 for self-contained breathing apparatus, 75-76 full face, description of, 23 half masks, fitting on chin, 23 half masks, fitting under chin, 20 mechanical features of, in relation to res pirator effectiveness, 26-34 peripheries of, 26 suspension of, 27 tests to determine fit of, 84-86 vision impairment caused by, 29 E--06616 156 RESPIRATORY PROTECTIVE DEVICES MANUAL Facial configurations Army Air Force statistics on, 20-21 classification of, 19 measurement of, 19-20 Facial seal, effect of on respirator performance, 109 Fiber size of filter media, 42 Filter fiber, calculation of efficiency, 40 Filter media configurations of, 41 factors affecting efficiency of, 40-42 factors affecting respirator performance, 109 Filter resistance as a function of loading calculation of, 43 influencing factors, 42-43 Filter respirators calculation of values, 16-17 definition of, 138 Filter testing methods, description of dioctyl phthlate, 47 methylene blue, 47 sodium chloride, 47 uranine, 47 Filter testing, USDA program recommended respirators, 120-121 results of tests, 120 test apparatus, 119-120 test methods, 119 Filters, combined with chemical cartridges, 66 Filters, particulate (See Particulate Filters) Filtration, mechanisms of diffusion, 38 direct interception, 37 electrostatic attraction, 38-39 gravity, 39 inertial impaction, 37-38 Fission products, interim recommendations for protection against, 111 Fit of facepieces Army Chemical Corp. research on, 25 as limitation of use of air purifying respi rators, 67 facelets, effect on, 61 field test for respirators using isoamyl acetate, 130 full face masks, 23-25 half masks on chin, 23 half masks under chin, 20 in respirator protection against radioactive aerosols and gases, 107 tests on, at Los Alamos Scientific Labora tory, 22-23 tests to determine, 84-86 U.S. Navy success with, 26 Full face respirators eyeglasses, provisions for attachment, 29; 110 eyepieces (lenses), considerations in attach ment of, 29 fogging problems of, 31 limitation of vision caused by, 29-30 recommended, for fumigation, 114; 117; 121 skin irritation due to wear of, 32 speech transmission problems of, 31 use of, against particulates significantly more toxic than lead, 141 use of, in protection against beryllium, 113 Fume respirators, approved, 102 Fumigants, specific, respiratory protection needed, 118 Fumigation California recommendations for methyl bromide, 115 Canister failure during, warning of, 115 canisters needed for protection against spe cific fumigants, 118 eye protection, need of during, 117 grain, deaths caused by, 114 hazards of, 117 Kansas standards for safe operations, 115 of shelled corn, recommendations for, 114 problems associated with, 113-117 respirators for use during, 146 warning against use of chemical cartridge respirators, 122 Fungicides, test methods for, 119 Fyr-Fyter Company self contained breathing apparatus, approved, 95 -G- Gas masks approved devices, list of, 95-98 approval tests for, 81 canisters color code for, 64 canisters, types and colors needed for pro tection against specific fumigants, 118 canisters, warning of impending failure, 115 combination particulate-removing and gasand vapor-removing type, 65 conditions for testing, 85-86 definition of, 138 factors important in operation of, 131-132 gas and vapor removing type, 62 illustration of, 144 life service of, 66 limitations of, 66 man tests of, exercise schedule for, 87 manufacturers of, 95-98 military surplus, hazards of, 8 pesticide operations requiring use of, 147 resistance to breathing, 67 training in use of, 131-132 transportation of, 64 Gas and vapor removing respirators (See also chemical cartridge respirators and gas masks) --06617 INDEX 157 protection designed for, 61-62 training in use of, 130-132 Gases and vapors detection by odor of, 115 guide for sorbent use, ACGIH list, 56-58 sorbents for, 49-60 Globe Industries products self-contained breathing apparatus, approved, 95 Grain fumigation, 113-114 Granular adsorbents, characteristics of, 50 Graphite ring compressors, 74 Graphite vane-compressors, 74 Gravity, filtration by, 39 -11- Half mash respirators fitting on chin, 23-24 fitting under chin, 20-23 sizes of, 21-22; 24 use of against particulates significantly more toxic than lead, 141 use of, for protection against beryllium, 112 Halogenated hydrocarbons, chemical classification and TLV of, 121 Handkerchiefs, respirator protection provided by, 124 Hand operated blowers, 70 Harness for gas mask canister, 63-64 tests to determine strength of, 84-86 Harvard School of Public Health study of respira tory protection against highly toxic radio active aerosols, 109 Hazardous atmospheres, classification of, 3-5 Heat, protection against with thermal protective respirator, 122 Helmets, for abrasive blasting, 99 History of respiratory protective devices, 1 Hood respirators abrasive blasting type, 99 definition of, 138 for toxicological agents, 107 supplied air type, 72 Hopcalite, 52 Hose masks classification of, 69-70 definition of, 138 list of, 98 training in use of, 132 use of, by fumigation workers, 146 Household items, use of, as emergency respira tory protection, 123 Hydrocyanic acid, proper canister for protection against, 118 Hydrogen - 3, protection against, 111 Hydrogen cyanide, use of, as fumigant, 113 Hydrogen sulfide adsorption by activated charcoal, 52 adsorption by molecular sieves, 52 -I- Impermeable protective outfit, illustration of, 108 Impregnation of activated charcoal, 52 Indicators, to determine effectiveness of canisters against carbon monoxide, 62 Inertial impaction, filtration by, 37-38 Insecticides air line respirators for protection against, 70 air purifying respirators for protection against, 121-122 chlorinated, removal arrangements for, 120 halogenated, removal of, by activated char coal, 120 respirators for protection against, 119-122 spraying of, 147 Inspection of respirators, 6; 127 Instantaneous air flow, 11 Instruction in use of respirator (see training) Interim recommendations for respiratory protec tion against beryllium, 112-113 against dusts and fumes of extreme toxicity, 110-111 against dusts and fumes of moderate toxicity, 111 against fission products, 111 against radioactive gases, 111 Interference, effect on respirator performance, 109 Iodine, adsorption by activated charcoal, 51 Isoamyl acetate, testing face fit of respirators using, 130 -J- Jamieson Laboratories products supplied air respirators, 149 -K- Kansas attack on grain fumigation deaths, 114 Kansas standards for safe fumigation operations, 115 -L- Label, approval, illustration of, 79 Limitations of self-contained breathing apparatus, 77 Loading characteristics of filter media, 42 Los Alamos Scientific Laboratory, tests on fit of facepieces, 22-23 -06618 158 RESPIRATORY PROTECTIVE DEVICES MANUAL -M- Machine testing of chemical cartridge respirators, 91 of dispersoid filters, 92 of gas mask canisters, 81; 85-86 of supplied air respirators, 88 Maintenance methods of, 127-128; 146 of canisters, 55 of supplied air respirators, 74 Malathion, test methods for, 119 Man tests exercise schedule during, 87 for gas masks, 81 for self-contained breathing apparatus, 80 for supplied air respirators, 84-86 Manufacturers of respirators and gas mask canisters, list of, 149 Manufacturers of respiratory devices, list of, 104 Masks, gas (see gas masks) Masks, hose (see hose masks) Materials used'in filter construction, 35 McDonald, B. F:, Company products chemical cartridge respirators, approved, 103 dispersoid respirators, approved, 100-101 gas masks, approved, 97 supplied air respirators, approved, 98-99 Mean inspiratory air flow, 10 Mechanical filter air purifying respirator definition of, 139 description of, 61 manufacturers of, 100-101 training in use of, 129 use of, against particulates significantly more toxic than lead, 141 Medical surveillance of respirator users, 6 Mercury, adsorption by activated charcoal, 51 Mercury compounds, chemical classification and TLV of, 121 Metallizing Engineering Company products supplied air respirators, approved, 98-99 Metallizing, use of air line respirators for, 70 Methyl bromide, proper canister for protection against, 118 Methylene blue filter test, 47 Methylene chloride, proper canister for protection against, 118 Mine Safety Appliances Company products chemical cartridge respirators, approved, 102 dispersoid respirators, approved, 100-102 gas masks, approved, 95-98; 149 respirators with face mounted cartridges, 149 self-contained breathing apparatus, ap proved, 95 supplied air respirators, approved, 98-100 Minute volume, air flow to breathing zone, 10 Mist respirators, approved, 102 Molecular sieves, 52 Mouthpiece respirators description and uses of, 65 training in use of, 132 -N- Nematocides, test methods for, 119 Noise problem in abrasive blasting respirators, 72 Nonfogging goggles, 146 Nuisance dust respirators definition of, 139 unapproved types, 7 use of, 61 -O- Odor, detection of gases and vapors by, 115 Organic phosphates, chemical classification and TLV of, 121 'Organic vapor adsorption by activated charcoal, 50 adsorption by molecular sieves, 52 mask, approval label, 80 Organic vapor canister recommended for fumigation, 114 test conditions for, 85-86 Organic vapor chemical cartridge respirators, performance requirements of, 92 Organic vapor, dust, mist and fog masks, approved, 96 Organic vapor masks, approved, 96 Organic vapor, toxic dust, fume, mist, and fog masks, approved, 96 ORGDP universal respirator, 108 Oro-nasal respirator, modified, 108 Outline for selection of respirators, 4 Oxygen-deficient atmospheres, 66 -Oxygen-generating self-contained breathing appa ratus, 76 Ozone, adsorption by activated charcoal, 52 -P- Paint spray respirators performance requirements of, 92 test chamber, illustration of, 92 test conditions for, 92 use of air line type, 70 use of supplied hood type, 73 Pangborn Corporation products supplied air respirators, approved, 99 Parathion, test methods for, 119 Particulate filters materials and construction of, 35 INDEX 159 performance characteristics of, 40-42 permissible filter medium penetration, 45 testing of, by dioctyl phthalate (DOP) method, 46 testing of, by methylene blue method, 47 testing of, by sodium chloride method, 47 testing of, by uranine method, 47 Particulate removing respirators construction of, 61 inhalation valve, need for, 65 life service of, 66 limitations of, 66 manufacturers of, 100-101 resistance to breathing, 67 training in use of, 129-130 Particulates significantly more toxic than lead, recommendations for protection against, 141 Performance characteristics of supplied air respirators, 84 Performance of respirators factors influencing, 109 technique for evaluation of, 110 Performance requirements for chemical cartridge respirators, 91 for dispersoid respirators, 91 for machine tests on gas mask canisters, 85-86 for paint spray respirators, 92 for supplied air respirators, 88 recommended, for respiratory protective equipment, 140 Peripheries of facepieces, 26 Permissible filter medium penetration, 45-46 Pesticides chemical classification of, and TLV, 121 particle size classification of, 120 precautions in handling, 147 respiratory devices for protection against, 143-144 skin absorption of, 122 types of, 113 Phosgene, adsorption by activated charcoal, 52 Phosgene, proper canister for protection against, 118 Phosphine proper canister for protection against, 118 use in grain fumigation, 114 Phostoxin, grain fumigant, 114 Physiological factors in respiratory protection (see air flow to lungs) Plates, approval, Bureau of Mines, 79 Plutonium aerosols, minimum protection against, 110-111 Polar sorbents, 50 Polonium - 210, minimum protection against, 110 Potassium tetroxide, use of in oxygen-generating self-contained breathing apparatus, 76 Power operated blowers, 70 Precautionary labelling, requirements of U.S. De partment of Agriculture, 119 Pressure drop, as a filtration performance char acteristic, 42 Pulmosan Safety Equipment Corp. products chemical cartridge respirators, approved, 103-104 dispersoid respirators, approved, 100-102 respirators with face-mounted cartridges, 148 Pulsating air flow, effect on filtration efficiency, 40 Pulsating air flow, effect on respirator perform ance, 109 -R- Radioactive aerosols and gases activities and daily tolerances for various insoluble materials, 105 protection against, interim recommendations for, 110-112 respiratory protective devices for, 105-112 Radioactive gases, protection against, 111 Radioactive iodine, removal of, by activated char coal, 111 Recirculating compressed oxygen self-contained breathing apparatus, 75 Recommendations for respiratory protective de vices against radioactive aerosols and gases, 110- 112 during fumigation, 117-122 of USDA, 120 Resistance, effect on respirator performance, 109 Resistance, effects of, versus air flow, 12 Resistance to breathing, air purifying respirators, 67 Respirator program cleaning of equipment, 5 inspection and maintenance of equipment, 6 instruction in use of equipment, 5 - medical surveillance of respirator users, 6 selection and use of equipment, 3-5 storage of equipment, 6 supervision of respirator users, 6 Respirator tester, 107; 109 Respirators (see respiratory protective devices) Respiratory protection physiological factors of, 9-18 recommendations for, against highly toxic aerosols, 140 Respiratory protection afforded by household items, 123 Respiratory protective devices abrasive blasting types, 72 against radioactive aerosols and gases, interim recommendations, 110-112 Respiratory work rates, 13-17 "06620 160 RESPIRATORY PROTECTIVE DEVICES MANUAL air line, 70-71; 98; 113; 133; 137 air purifying, 49; 61; 66-68; 106; 121-122; 138 approval program, Bureau of Mines, 6-7; 79-89 approval program, USDA, 7; 119-121 approved devices, list of, 95-104 chemical cartridge respirators, 59; 65; 79; 87; 89; 91; 102-103; 122; 130; 138 classification of, 1-2; 20-25; 144 cleaning of, 127-128 combination particulate-removing and gas- removing respiration, 61; 65 comfort of, effect on performance, 109 continuous flow supplied air, 71; 106 demand flow air line, 71 emergency, cleaning and inspection of, 127- 128 face pieces, 19-34 factors affecting performance of, 109 for fumigation protection, 113-119 for radioactive aerosols and gases, 105-112 fume, approved, 102: gas masks, 62; 65 gas removing, 61-62 half mask respirators, 20-24; 112; 141 history and definition of, 1 hood type, 72; 99; 107; 138 hose masks, 69-70; 98; 132; 138; 146 inspection of, 6 instruction in use of, 5; 129-135 maintenance of, 6; 74; 127-128; 146 military surplus, 8 mouthpiece respirators, 65 nuisance dust type, 7; 61; 100;-139 particulate removing, 61; 65-67; 100-101; 129-130 performance, evaluation technique, 109-110 performance requirements for, 79 personal identification of, 127 protection against certain pesticides, 143- 149 protection against insecticides, 70; 119-122; 147 protection against paint spray, 70; 73; 92 recommendations against specific fumigants, 118 recommended for protection against par ticulates significantly more toxic than lead, 141 selection of, 3-4 self rescue, 65; 132 storage of, 6; 127-128 supervision of use, 5-6 supplied air, 69-74; 79; 84; 98-100; 132-135; 138; 145 testing of, 6-7; 89-90 thermal protective type, 122-123 unapproved, 7 wearer acceptability of, 32 -S- Schedules, approval, U.S. Bureau of Mines (see approval schedules) Scott Aviation Corporation products self-contained breathing apparatus, ap proved, 95 supplied air respirators, approved, 99 SCUBA breathing practices for wearers of, 10 definition of, 139 precautions against use for protection against atmospheric contaminants, 78 Selection of respirators, basis for, 3 Self-contained breathing apparatus advantages and limitations of, 77 approved devices, list of, 95 Bureau of Mines approval system for, 79 definition of, 138 description and operation of, 75 factors affecting use of, 77 inspection of, 127 limits for carbon dioxide content in, 81 man tests of, 80 manufacturers of, 9.5 protection against radioactive aerosols and gases, 106 storage of, 128 testing of, duration for specific activities, 82-83 training in use of, 135 types of, 75 use of, by fumigation workers, 146 use of, in protection against beryllium, 113 weight of, 77; 80 Self-rescue respirators description and uses of, 65 training in use of, 132 Shirts, cotton, respiratory protection provided by, 124 Shelled corn, recommendations for safe fumiga tion of, 114 Sieves, molecular, 52 Silica gel, 52 Skin absorption of pesticides, protection against, 122 Skin irritating effects of facepieces, 32 Sly, W. W., Manufacturing Company products supplied air respirators, approved, 99 Sodium chloride filter test, 47 Sorbate, definition of, 49 Sorbents activated alumina, 52 activated charcoal, 50-52 bed depth of, 49 for gases and vapors in ACGIH threshold limit list, 56 e~066? INDEX 161 hopcolite, 53 moisture effect on, 55 molecular sieves, 52 polar, 50 properties of, 49 silica gel, 53 use of, for specific gases and vapors, 56 Speech transmission, effect on, by use of - respirators, 31; 110 Spray painting respirators, test conditions for, 72 use of air line respirators for, 70 use of supplied air hoods for, 73 Storage of respirators, 6; 128 Strontium-90, minimum protection against, 110 Sulfur dioxide adsorption by activated charcoal, 51 adsorption by molecular sieves, 52 proper canister for protection against, 118 Sulfuryl fluoride, proper canister for protection against, 118 Supervision in use of respirators, 5 Supplied air hoods description of, 72 training in use of, 134 Supplied air respirators advantages of, 69 approved devices, list of, 98-99 Bureau of Mines approval system for, 79 continuous flow, 71 definition of, 138 demand flow, 71 illustration of, 145 manufacturers of, 98-100 performance requirements of, 84 test methods for, 84 Supplied air suits materials used for; 73 training in use of, 134 types of, 73-74 Surplus military masks disposal of, 8 hazards of, 8 warning bulletin on, 116 -T- Technique for evaluating, respirator performance, 109 Test equipment for universal gas mask canisters, 84 Test methods for respirator evaluation for chemical cartridge respirators, 89 for dispersoid respirators, 88 for gas masks, 81-84; 131 for self-contained breathing apparatus, 80 for supplied air respirators, 84; 88 respirator tester, 109 USDA programs, 119-122 Thermal protective respirator application of, 123 construction of, 122-123 operating principle of, 122 Threshold limit values definition of, 139 for carbamates, 121 for copper compounds, 121 for extremely toxic particulates, 66 for pesticides, 121 Tidal volume, air flow to breathing zone, 12 Toxic aerosols, recommendations for respiratory protection against, 140 Toxic dust respirators, 100 Training in use of respirators gas and vapor removing respirators, 130-132 need for, 5 particulate-removing respirators, 129 points to be covered, 129 self-contained breathing apparatus, 135 supplied air respirators, 132-134 Trichloroethylene, proper canister for protection against, 118 Tritium, protection against. 111 -U- Unapproved respirators, 7 U.S. Army Chemical Corps. combat gas mask, illustration of, 106 development of respirators for protection against radioactive aerosols, 106 research on fit of facepiece, 25 U.S. Atomic Energy Commission proposed concentration limits for beryllium, 112 suggested requirements for respiratory pro tective equipment against atmospheres containing particulates considerably more toxic than lead, 141 U.S. Bureau of Mines approved devices, list of, 95-104 color code for gas masks, 63 consulting service to manufacturers, 79 minimum requirement for abrasive-blasting respirators, 72 permissible penetration values for air purifying respirators, 46 requirement for supplied air hoods, 73 schedules, approval, 79-92 testing and approval of respiratory protec tive devices, 6-7 values for filter respirators, 16-17 U.S. Department of Agriculture precautionary labeling, 119 -0662? 162 RESPIRATORY PROTECTIVE DEVICES MANUAL publication on respiratory devices for pro tection against certain pesticides, 143-149 recommended respirators, 120-121 respirator evaluation program, 7; 119 respirator test apparatus, 119-120 respirator test methods, 119 U.S. Divers Company products self-containing breathing apparatus, ap proved, 95 U.S. Navy, success with fit of facepieces, 26 Universial canisters definition of, 139 diagram of, 63 exercise schedule during testing of, 87 granular sorbent, arrangement of, 62-63 indicators to determine effectiveness against carbon monoxide, 62 storage of, 128 test conditions for, 85-86 use of sorbents in, 54-55 wearing of, 63-64 Uranine filter test, 47 Uranine, use of, in respirator performance evalu ation, 109 Uranium, enriched, interim recommendations for protection against, 111 -V- Valve leakage, effect on respirator performance, 109 Valves, respirator definition of, 138 diaphragm - activated type, 71 factors in performance of, 27-28 for hose masks, 69 for self-contained breathing apparatus, 75 leakage, testing for, 28 operation of, 27-28 types of, 27 Vapor removing respirators (see gas and vapor removing respirators) Vision impairment from use of full face mask, 29-30 Visual field, effect on respirator performance, 109 -W- Warning bulletin on use of surplus military masks, 116 Warning of impending canister failure, 115 Water lubricated compressors, 74 Welding, use of air line respirators for, 70 Welsh Manufacturing Company products dispersoid respirators, approved? 102 Willson Products Division, Ray-O-Vac Co. products chemical cartridge respirators, approved, 102-103 dispersoid respirators, approved, 100-102 gas masks, approved, 96-98 gas mask canister, 149 respirators with face mounted cartridges, 148 supplied air respirators, approved, 98-99 Women, fit of facepieces on, 20; 26 Worker acceptance of respirators, 32 Work rate, respiratory, effect on physiological response in respirators, 13-17 E-06623