Document zdXq9zwdG68OkYYQd2r5NV8GB

TTOOXXIICCIITTYY TTEESSTT FFIINNAALL RREEPPOORRTT EEVVEENNTT 11 EE0044--00112200 FFeebbrruuaarryy 1122,, 22000044 CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 1937.0001 3M MN01538387 fra Leboratoriss, Inc. il EEcE k Faeriry 18, 2004 DuWiNSStB0hL20,17 (218) 7274380 [3 VMdei.mSeui os Biann cinhg we d Mantcting S5E3P5 DnAANvi33e1,06Buin 33.05 CoSs1MM0.~7,C4ToTitinna~agGOeaGalrt]lloioovowwenaaysRoad BuiCdnog 1m45pMeimtein550s16 10746 Inno~ atia~ Road Building 145 Cottage Grove, Minnesota 55016 TVeo.e Baeeacsh,blow summa the sheild- egal eal or the es onde wil Fhe tables bdow summarize {he chemical a~sd toxicological resuhs fl:,r ~be ~ests conducted witl, ie 1 oats rove ois samples ceived B Ere on Febray 13,2009 The sms wie th~ ~M C'oWmse G~os,e famnL,, s~ples rece,ved by Era on ~eoruar} I.L 2004 The {outs were Coded a ouimed tS GPO dred ebm 5.2004 snd te LIV mer FOA0120 conducted as outlined in the 3M GPO dated f:ebruau 9, 2004 and the LIMS number E04-0! 20. BBrriieeffllyy,, ceaacchh ssaammpollec wwaass tteesstteedd aatt 110000%% ccoonncceennttrraattiioonn wwiitthh ttsw~oo rrceppliiiccaattee tteesstt cchhaammbbeerrss ppeenr EE ae sample. Ten 13 day old fish were exposed per replicate and test temperature ',~as mmntained a~ TC 170: Sehatom ee rented ao 3 hp et rel og aE amp on 25:~C = 1 C~ SoIut~o~s were renexvsd at the 48 hour t~st in[~rval using ~t~e afigina~ samp~ tha~ Te a Ee Fon Ae nt Tn A had been stored in darkness a~ }-4C. Test d~travrm was 96 hours, and per your ~uidance, fine lb tests were conducted m darkness. npc | ening | W, i La ET 27t277004 [men Ef~Iue~st 4 [zon] 2! [ 2/2004 suing] ye I 1 OC !:45 nia ER EES arn | nt| A | Ariat [ci Ara nval Aa rrival Arrival Arrival ArrX:aI Temp. | Ammonia| TRC vom] ww | ._: 1 ._.:.... 10:~0 Ee 2/13/2004 t 18:~0 [amor] ono | tw | 20 an | am [Coitvien [rota] oon [ommee] ow [vo | 31 [om [roPomrta4A |oaoes| nao |owves] 2/12i2004 i 1:35 I 2!1312004 wom l {}:3{} l 0:30 [v0 | I0 1.0 ~ is | wer 1.5 <0,02 ~ 6 <0.62 one of the meng sons sol smd slats (TVCYemsensatons hs So bod None of the samples contained 1oral residual chlorine {TRC'} concentrations above the Gein imi oT0.02 mp. Amore ovecntaton othe samples ened om 1371 or detection limit of 0.02 mgq.. Ammonia concentrations ~br the samples ranged fl'om !.3 mgir f2,r he elatt V3 sats A 21 ma or Comedie wie, Te reat svn ~he Influcnt I72 sample to 2.1 mgL lbr the Combined Effluent sample. The measured mae ares al oss me sea abo Son Bae concentrations were not anucipated to cause acute adve-se elliot> !o ff~e fish and t?x'rc-{bre the os wre 2 a Fedo for ho oe es wn 1 ~es~s were not pH adjusmd. Amval Icmpcrature fi}r each ord> samples was I COENAFINDEEPNITICAOLUNSTUYBDIIESCTTRITCOTACPORUORTT.ECNTG.IV3E71OR0D2E8R8E6N3TEREDIN CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00000022 sw_morssssss 3M MN01538388 gfErit Result forthe too exposureres shown in th able below. Results for the Ioxicity exposures are shown in ,he table below Tom eoow [on [our [ows tneSnsTdeunepnneiion||| PN eSao0mcT e||7 PrA oeomma||TPTeior:wv|o|PmTebaerRatcnse|| Tpo Mantse || 00R|ange cRea-nogren" MNRW Mema Mea~ Mean I % |4our Mean P-~centa~ P~rccnmgc Pcrccnt~g~ : Percentage SSu~rrvvi/vvaall | SSuurrvviNvaall | SSu:ar~v,iivvaalI |' SSuurrvviivvaalt H ~O0 i00 10O | owty: | (robin) ere oe oo ws | ow 85 [no 70 [ess sere] mmm 8 ~8,4 f ~407~462 4.5~7,~ 1482-~4S8 Fort 4A Conoed Sr ee T sae] t on s 7755 E65R E 65SE E 8.084 | 45-77 |! I1442266o-~144881I | 4.4-7.8 : 1441-!486 J he moderately had seconstiuted wet (MHIRW) supported 1005 fh suralfo the duration The mc,deratelv hard reconstituted water {MHRW) suyported 100% fish sur~ch al fbr the duration ooff {thhee ~te.csst[ ~innddiiccaattihn~g tthhee lf]isshh man~dd ~teesst/ mmeetthhooddss wweerree aacccceeppttaabbllee ffoorr aasssseessssihn~g ttooxxiicciKtyv.. TThhee Tnfues 172 sample was observed Gas comple (100% fish morality wit 3 Rowrs of et Tnfluem 1/2 samp]e was observed to cause comN~ete {I00%) hsh mo~@Ky w]tmn 3 hours inion. The sample demliod 5 Efuent 4 wae ound 1 Support mean 56 hour fish survival initiation. The sample identified as Effluent 4 was %und to support mean 96 hour fSsh s~rviva] oF 755% ad she songs Henifiod5 East 1 was obser to suppor kan 56 hou fl of 75%, and the sample identi~ed as Eft]uent I was observed to support mean 96 hour fish SreeeieAepomfeee7a0e9e6en.layorteTeh4ernCsdomPominotneLtAPAsihrnsspslasllsupspsorotweePdfmwoteneasdh9moahgoBnuer9B6eWhpovRui.Sesolhmeorf 6s09sanodf sm'vivN of %%. Port 4A and Po~ IA sam pies supported mean 96 bout fis'h survh-a~ of 66% and ohensetoafrte samsoireshTorotoo ppaeroseesd?(pH iene ovens sandy) sessed di the i~t ~;cr abnermal ~2or rE1 ~ rypc of stud)-. Please call or mil mfeyou have any questions. Sincerely, EErraa LLaabboorm atfoorri[eess,. Inc. PfreoejDeitokMeasn,cger Bo-Toxicaogy Project Manager. CREONNNFEIRDCOEU-NNTSTYUIBDJIAESCLTTRITCOTACPORUORTT.ECNTO.IV2E7-O0R1-D1E0R.2E89N6T2ERED IN CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00000033 su_wmoresesss 3M MN01538389 6 Lobarstorn inc Era Laboratories, Inc. Cent BE Era Project # __017869 Ti'ecsst,:: FFaatthheeaadd MMiinannooww AAccuut{ee TTooxxiicci{t~y" TTeessttss TTecsst{ IInniittiiaattiioonn DDaat{ee:: FFeebbrruuaarryy 1133,. 22000044 Test Termination Date: February 17,2004 PPaaggee 1 of 6 `CHGEOONNNNFFEIIDPDEIENNNTTCIIAOALLUN-- TSSUYUBBDJJIEESCCTTTRITTCOOT AACOPPURRROOTTT.EECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR.2E6E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00000044 S3MW_-MMNNO011853388339900 EENNXVIIRROONNMMEENN'T~AALL SSAAMMPPLLEE TTEESSTT ~I[NNFFOORRMMAATT~IOO~N [Date February 13,2008 SEs T ] R Dat~: Feb~um~' t 3, E anin nan) | Era Project 5: 017869 1 EE a i ThebLesTTE || . g~2a prOj.5~ct #_{)1786~ Test Organism(sAge: Fathead Minnow' 13 day Jlomne. Li ,~--Tes~ Orga,~fism_(sii.A~~:~ Far,cad M~nnowe i . ! d re E e Emy er -- ------------------1 pyr 1 eT Bony -------------------- eed Fee EEE EE Prem erred Page 2 of6 GNONEFIDCEO-NTSTYUIBTJAERCLTITEO ASPoROaTrECNT37IVEuORrDeERzeEsNeTsEREDIN CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00000055 swmorssesen 3M MN01538391 to tooctoses ne TOX~I[CII~TgY TEST REENNEEWWAL FFOORRMM mer TEST.Aca TirBoies ORAM, PabedVion wamoncre ose iE TESTINTATIONDATE Flel blols TESTTERMNATION DATE. Fry 1200 TesTOAY le 2 !f= | or] aren |, uot [258 ! | | meorrenewaL | cos {ator | pygey | | ww | ne commovwatsn | ww | www | amw | a | | | | NITIALS Ae se. | S& A | st Pa3gofe6 `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITOCOT AACOPPURRROOTTT.EECNCTOT.IIVV2EE7-OOCRR\-DD1EE0RR-2E6E3NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00000066 _orsasase 3M MN01538392 IHIAL CHISTES ro Anan. meen: em a ()RGAhI~M~ ~) F:~thcad Tm TT i ET ES] EEE aT oi Tend |Tem|p EL DOL pi eT Cond. Temp. | TDYO Mikw| Spy wo3t34TI1Toreyo %FA a{aTon [23a5r|[awbrs[|wgeal| ewws |NE ou frie zie Ee E7 Co T een Bra | 2.332 | wer | awe 73: gag hover: pg vy [Fe BE Ee Rs, pas heii TRE a ene re YR TE rns fw BUC Sf | mh 0 age] ma] Pan | Gah ol omBl zd | 0 Bes hor ap? = oR soak fp yy nel Fe | dos | pu or 8 Troeccon|Ea R e Eda ES wes | poy | oyasy | avd Ee a SES Ta OR h ieT SH zo | gan | gus3 | avs 78 PPaaggee 440u1l"66 COR NFIDEE NTIALSSUBJES CTT0 AhPROTECTIVE GROER ENTERED HENNEPINCOUNTY CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 sumer 3M_MN01538393 11993377..00000077 FINAL CHEMISTRIES EH rere IEE EE ee te ati deed Hg 3iHe LT imi: Tmt: Sra Tre Eau Ai | TTeanmDO.e |p enH|rTeempo. |nDO.|fp w T |Tu empE | DO. Tams SE pi | Temp. | DO. mew bnlaofannlealae fais aus ana gi llg ofielpasiereace 58 BX acing seifisnjes BL El wwmn ebann bbeaorlsseleevenal fone1na 7 [saTvle loavTrhas oenrdal[55745 avisbeofeea fad 105 {15 La we Re oral yb Loleve 1lonr glennln T71lmbse rane cafe bban as ie Teme bh Lui Sime ph an EE Tn ec pee cei aes eg eer Bie Tonite| ions bo vn fide aie TORR pornLyiselrsiiileeionk win iain wave lena aangglurlptgys lenciina rare Ported ery bcagoifH or #2E1 3lRt eifaveS svaie o 17] 00 19.6n740i6 d0tlga|n liensa[5E47 13100.g104 E 9 iv |95 BE vera {iT | CR evap mer gptey | vay Ll wy boiehhitly a1 len palettefog de losin ntualsy fos bea Lalo aaa Page Sof SCONFRIDENCTIaAL SUBIECOT r0 A SPRoOTECTIVE ORDER ENTERED I HENNEPIN COUNTY CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 aw norsasss 3M_MN01538394 11993377..00000088 ACUTE TOXICITY DATA LOG a SselifrtampsgaigEnsiciataeTyLL: ARSrSE USE NTIATON DATE: shes 1= oe] Des Supe|pgepo ic rNowe ReLpt % aiRee sttsatee e r dagerpilei a Ek ackho--ooooohoiSiis iN = Azali aonns Jony lELo i0 JE She SRC LIRIl fel FLERE ER | et warrt l(ls r Ee hSaan a|sao diso seLEEAlE) l 6 I5g8E es we FEES ba EE ERAT: <0 - SHEP HEEEY 3 an Foes oy" BRERA ERE a ge err ven fon ER ue I ee Ete13 1 re a a BN BE natasha HEHE HH Bis iam a fig ay od fogs Poret1p [Fi Tae hung HEE <n FEE | ecw ER ERE Eee hee al a eran {0 IZ 0 io [THK] pani Pa6gofe6 S CONFIDER NCTaIAL SUBIECOT r0 A PSRoOTECTIVE ORDER ENTERED I HENNEPIN COUNTY CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 aw norsooss 3M_MN01538395 11993377..00000099 Ee Ee 3MEnvironmental Laboratory Chasscf Custody RequestforLaboratoryAnayteal 6038 |TBMEMEsl F Hme . sEET |EEE Sell Laman pee 1] I Ee es ryes || aa Ay aE ee le TET Ee ee vit) me HE Jaentg rFnudp LE | ! | { LeeyeYT ge te heoe = rsh [oi [meeee re hao ores YR[if 2) a oof HHH 4 EfLIoeF Hd _ (EF4) appr ee eee a 2 Foe b|EeE tRwEn EiEeantvo ow TOe-- =F R-- E re aalpeo |2 LLLLL] TCR A. 1 COfNFIrDENaTIALtSUSBJEeCTTpo AaPRO)TECTIVE ORORA ENTERED NEMNEP COUNTY CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 aw morsosse 3M_MN01538396 11993377..00001100 CCoonnvveennttiioonnaall PPoolllluuttaannttss FFIINNAALL RREEPPOORRTT EEVVEENNTT 11 EE0044--00112200 FFeebbrruuaarryy 1122,, 22000044 CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 1937.0011 3M MN01538397 aMEnvironmentalLaboratory ChainofCustodyRequest1fo0rLa8bo4ra6to0ry5Arayical pl Ee a a 5250_[WHER Taos = -- 1 =F moe 10% |mTE Erel rETep Ce Toreonsi[omeBoPande _-- ee LLL Ah ee =m limesGot es Gg reg] 1 [111 oCrsioer ila . reDrpi tabilihtiiessTa] 1218 fg dln te4 [ w"p [R2e 8 TTb TB S e e TTTh FH m E eeE t Fah PcererLA n B7 a [et Crkaery fasio TF t] EHs ee eT! = EE FE ry, -- TTT TTT HZ A Ti ah] Ree 12 orn QUIT in PACE 1219 Hi3hh EEE : STE ba Ror ETT S CONFIDER NCTaIAL SUBIECOT r0 A PSRoOTECTIVE ORDER ENTERED I HENNEPIN COUNTY CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 aw morsesae 3M_MN01538398 11993377..00001122 __conmmenrisamns conser COOL~N / CT PACE ANALYTICAL wRoEGoEoD BY PoRAwT NnAMEySOo N SO. RGGE_~ ar A meenGwe TT eso mare [moo SE |e [| REE en mn "SAMPLEDELIVERYGROUPS3 p er |a pr m ee J[" |vLO ofsanow, eve. [rors prom pr wor ; {rar---- rw San Sg 3CarCUSTODY.Eten mem_o. [|p oe ~ {ovwd4,7c | PmropaedyFieledOnut youne N-- . pr [me rr i 1I4=7c Loam suse | N besser = | = agg oN lLeEzE snd < | ;I | Foe Boers |LMEd g E |C I Y | T || E Br E pe pl T Le ENT NIT | sE k emeErmoReyi wnFT rX a]] | RisRRwE nt E Mi ver] 1 1 Ce T rr-- w ---- wmmes-------------- ERI COUNTY ISTRY COURT: NG, 57 ihae CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00001133 3M MN01538399 FaceAnraleytaicicarall" rt orsi ss P~ne: 9tS.25 L28~8 ge Fax: 91&25 L259~ [---- Februsry 25 2004 RovannePaterson Roanne Pattersor~ Face yeas Soros Pace Analytical Services ffi I700 E~m Street Suite 200 inveapeis, WN 5414 Minneapolis, MN 55414 Projet: Inter Labi 108555 Project: ~ater Labl [irae SDG: 53924 Dearie Patron Dear Ms. Patlerson: oso plage fe ur nda bar port or spl received by out Enclosed Nease fi~d o~r standard tabular repoA 1or sams~es received by our ora on Febary 14. 3004 Poa 3 ns ancimds SG Naas for ~aboratory on February" 14, 2004 Please see the enclosec SDG Narrahves for ona moat gr napa of ro sams additiona~ nformation regarding analysis of these samples 1 nour review, you shold have any cueson offcr addtional formation, ~f0 in yu~r review, :you should have asy questioRs or require additiona~ information, Sicerbe,idaio 9~ease co not hesitate to tail varyspSoanpaseabacors ra~d sta.~qs@#acelabs.com roe Wamager Project Manager ers RESft EhC!OSUTeS eco eli report mes ied NLAC pein stnds "We celtiC} that the tbilow~g ~port meets aii required NELAC ~eport]ng st~dards as specified u~ NEIoAC oi 3 July 1~ ! 999. An5' deviation or va~im'~ce is u~ted in the case re, Eoin)seoria n TeTRnEE di ~n t~e Q~Nity {nelac: EANEPI COUNTY DISTRICT COURT. NG. 371028863 CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00001144 3M MN01538400 /_PaceAnawleystwicianall { SDG NARRATIVE rs" rotoeeroteE, sBEsa340s0 CCPLRLIOIEJENET~C,T: :PPIAANCTCEEE~RMMLNNAB PROJECT: INTER-LAB DATE: February 252000 DA'I~: February 25,2004 EPISODE NO: 53924 EPISODE NO.: 53924 ININOORRGGAANNIICCFFR~ACCTTIIOON N:: ring sls of ee ple. Th ses ys wre completed seri oh llving `SSeevveenn wwaatteerr ssaammp_plieess wweerree ssuubbmmiitttteedd ffoorr ddiissssoollvveedd ttoottaall oorrggeanniicc ccaarrbboornt aannaallyyssiiss.~ NNoo mmaN"j"~oxr~ pprroobbl|eemmss ooccccuurrrreedd during the a~ysls of ~ese ~ples. The ~npie's ~my~s were completed ~co~ding ~o the foftowing SSW WLL SSOOPP ## SGT SE To Organic Carbon g~-~i-310 MethodReference SM5310B PPaarraammeetteerr Total Org~c Carbon Pes feo Cooler Recep /Sample Log. Set fr dtl ofsample codonsat csp. Please re*?r to Coot~r Receipt !Sample Log-In SHeet ~br details af sample conditions at receipt. her ere 50 bold ime ition noid. Samples ce Fired in a fln fier pis to anys There were no hold time violatior~s noted. Samples we~:e filtered using a teflon filter prior to analysis repruion Blk: No target rls were eet nth ration bn ove the POL P~.p~adon Bla~k: No target ~[ytes were detected [n the prepm*ation btauk above the PQL. LF onal Sykes. AT sory sorrel spies were wits OC imi. Lab Control Spikes: &ll labor.Dry control spikes were within QC limits. Mise Spke, No mati shes ee ubewit is cpio Matrix Spikes: No matrix s~ik.s were submitted with ~s episode. Dulce: AlLCSandrte dlc ests wr wih OC fits. D~pticates: All LCS ~d matrix duplicate resuRs were witNn QC limits. No ih dt ably ian st fo sng Anyi Di Package. No #~rther data usability l{mRadons exist for this Inorganic A~,~alysis Dam Package Expansions ofthe forms ve te following Expirations ofthe forms are the following: Foam 1 Samplers Form I Sample res'dts Earn Dek. Provided the LB Quality Cont Dit Secs. Form 3 Blar~s - Provided by ~e LB Qualky Control Data Sheets. Fem Laboratory Comet Sample evil by he LCSLCSD Quality Cont Dat Secs Form "/Laboratory, Control Sample - Provided by the LCS!LCSD Qoality Control Data Sheets !1 cceerrttii~fy! tthaat tthhiiss ddaattaa iiss tteecchhnniiccaallllyy aaccccuurraattee,, ccoommpplelettee,, aanndd iinn ccoommppltiiman~ccee wwiitthh tthhee tteerrmmssaanndd ccocnnddiittiioonnssoofftthhee Cora for ler a contin dead ows, Relatof ho encod ths hrdepy oa contract, for other tha~ the conditions detailed above. Release of the data comained in this hardcopy data era ba bn hid vy the Larter Masago ihr esigcs as vid the oon packag~ ha~ been authorized by the Laborato~T M~ager, or his[her designee, as verified by the t%llowing Ginna ~i~nature. =2 > We Chemis Suprisor SSuusseann S8., TFuurrnneerr Wet Chemistry Superv,.sor oT REPe OeRTmOF e LABOo Ro ATOnRY A, NALYSIS -------------- hela:iia---- CCHOEONNNFNFIEIDDPEEINNNTTCIIAAOLLUN-- TSSUUYBBDJJIEESCCTTTR ITTCOOT AAGOPPURRROOTTT.EECNCTOTIIVV2EE7 -OO0RR1-DD1EE0RR.0E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 su_wmoressson 3M MN01538401 11993377..00001155 } _PaceAnalyticafle wwgaceiats.com I Sample Results ro etTssR rae avovenArrow,OF 74012 Fax: 518.251.2589 RwEPOTrtRT OFa--LAe --BOa RATOg RYS SeANlALbkYS0I:S ee fnelac: `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACOPPURRROOTT.TEECNCTGT.IIVV2EE7-OOGRRu-DD1EE0RR.2E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00001166 m_morsssece 3M MN01538402 Ce `aceAnamlyitsiceasl rsHsS , coa nE dogma7GE 5112855 sDSEeine saars-oaize-enn oSErEn Toneens evnern corneas mason TOTAL ORGANIC CARBOH sTeerrosBaums To mmqe]nl l,O wSSshiswomisi>zdn oo0ai2/342s//ya5a000n00s neoits owneerirgo>us murs reevreiren: Ta]7~3 easse in wan sion 0212410% 17:32 ~%L SM531OB CC~5OD5oM?7tO=2UoN5NbDnO17a==SDreERTTReEeEESCcSUTUrLELeSTDTDaSScAsoBRevoOeEEVrPuOEyONRIAGTQEZoUND9ToTS~IiA8KTS8oIAETRATTEoIICfOOENNIacVEELDILrMiIieTiss UNMiE!8nA?oZ0O=L=OsOS~ReoLOUcO7~Gti[YOAh.:GPecAPeTLiSSsEHIMi-CcnAoR=aBn[LiSCbSEasOTTbYAA,ENNRDDYAAaRRDDOaUTEcSTIHD1OZ9D6S5O,F Q1C9THLIME~D?ITSION, 952/19 SDETION, 1355 Ee EPA = #L~A60014-79-020~ }S%RCH 19~5 SW = SW 846 Rev 4 1996 Rr EPt ORT OiFoLe Ae eBORt r ATORa YS ANALYSIS ------------------------------------------------------------------------------------------------ `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NTSSTUYUBBIDJJIAEESCCTLTTRITTCOOT AACOPPURRROOTTT.EECNCTOT.IIVV2EE7-OOCRR\-DD1EE0RR-2E6E3NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00001177 au_Notsaseos 3M MN01538403 /_Pace Analsytoinciiacaloln" ress arnn rnmBTeE [ih weSSPeE#t~Ps1LE: s|: aaBfm0ua4cee-a0.i10s22e~--~e7n43e~ TESDS [I~TRIX : : N5T3o9s2s4ess SITB 1384@@5 srenanzs NAF~METZR or CRGANIC CARBON TOTAL CR~ANIC CARBON iresi REPONTZNG LIMIT UNITS iToo0 mmge/ni ap SSs~eIoPonLZcDamn +: g 00S22a/1n21a82//12220000008t4 SUBMITTED ; 02/l~f 200~~ RESULTS a3,22 oven DATE!T~M wenkon METHOD ANALYZED ANALYST REFERENCE D0a2r/a24a//0o4n 1177::4444 K~{LL SSMH5S3311O0B8 Cc$NIOD0oM22nO=UtNNbNDoOo~oTr a~=nD~erTRSn~EEms,SSaCUUrTLLaaETTnDcSSonAvsRBEeoOEEeVvPOrEeORREToQQEEUUTDDRASINIATTBOSSIIETTAARTTEOIICFOOENLNOVELLDIELMAIIIWTEERS * = SURROGATE RECOVERY OUTSID~ OF in Rn Sepia N/A = NOT APPLICABLE BBEEoStacohn.ica4-9-S03h0a, nVeAvRETH1O9D555, METHODLOG~: SN = STANDARD METHODS~ 10TH SALTON 992/197 QC LIMITS I$TH ZDITION~I992/~9TH EDITION, EDITION~ 1595 1995 Seeds ner. 4 1096 E>A = #EPA600i4-79-020~ DN 1996 M~RCH = SW 845 Rev~ 4 REoPnOReTvonOoFrLArA BeOnRATcORYtAirNAssL.YSbIe S wi~hO~l th~ wr~en `nneellaacc: `CONFIDE-NSTUBIJAECLT TO APROTECTIVE ORDER ENTERED IN CHHEOENNNNNFEIEDPPEIINNNTCCIAOOLUUN-NTSTUYYBDDJIIESSCTTTRRIITCCOTTACCOOPUURRROTTT,,ENNCOOT..IV22E77--OCCRVV-D-11E00R--2288E88N66T22ERED IN 11993377..00001188 S 3M M MN01s53z8440044 ~ ce Analytiscraall ovassiscom sn ew A152 nea gseostte cy o,r]se Pho~,~: 918.251.285z? LutSSAAhhBNeiPL:IsE~ s|:: a5gssw30aa94ean2-cee43d1oi02nd33e--5s7r4e3n9 SSSDoGon ' 53924 donsees ; i0846~5 ePxAuRaAsNegrTeRsq TTOoTAmL oORvGaAmNaIcC aon CARBOH sTReEosProOnsRtTnIiNbeGate I,THIT UNITS 11.00 mmga/nl RsSSSEatAwPraMiOowPmRRiLsTtEr.EeDiDoen ::: o0000u2253////z2211/s524///a/2222000000000000444 SUBMZTTE : 02/14/2004 mess RESUI,TS Te11,9 meoDAcrTeE;oaTnIMsE wis meMwErToeHOncDe ANALYZED ANALYST REFERENCE ower 02/24/04 1w8a~2r2 mLY~,L sSNe5s3i1o0s8 CC5N2ODo5MMPp2O-OUmNNCNDDOOO!~TtRO=S=DEEASTTRTEEEEESSCCUITTLLEERTTDDoSSCOAAVBBRREOOEERVVPFYEEOORRTQQGTEEDEODTADMSNTIATAISDISTETAARRTTOEEIIFCCGOEENNIGIVCVEELLDD~ILHHiIIMTTITS NMwUE~ E/iaETnnATHIO=-CDOAOVNSOBLoOULPOrTRORGRGGYaAOE:RePGLrAPTLLSS4EiIMh-cC7nA=R=9aBE-LtCSSEsO0~TVAA0E~N,RDGYAAHRRDODUaMTMESETTIHND1OOE5#D8SS5O,,[ QC LIMITS 10TH EDITION 1992/19TH ]STH EDITION, 1992/19TH EDITION, EDITION, 1995 1995 SHE Rev. 1956 SPA = ~EPA600/4-79-C20~ SN : SW $46 Revo 4 199~ [4ARCH 1985 Rt EP"OoRk T0A1o ORsFtcLrAopBOotf RAyTeOi RYrAAt NtALYSIS `nelac: `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACOPPURRROOTTT,EECNCTOT.IIVV2EE7-OOCVRR-DD1EE0RR28EE8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00001199 m3M_mMoNr0s1s5s38e4o0s5 ge SoeAnalyticaloe wepaceists.com ussi ot boBiSnts as mss Fax: 918.2512805 LhwseAeteBtl]itDo:|; sBS53oa9ew2da4,ie0e4-srus PSS~TERhIX ; Wfoes SITE 1084665 r sSsozmotrszeepg n | 00002222////) 2214852////2222000000084444 02/14/2004 PeAxPegmMSeTeEnR ssTraornrrice s wswrs LIMIT UNITS RESULTS moaxnsen mat saerriene ~ALYZED ANALYST REFERENCE TTOOT~AALL OORRGGAANNIICC CCAARRBBOOZN 1i..0O mgmg/./ll 1133,.77 0022//2244//0044 1!88:;3355 KEgAoLL SSKM553311008B " C5C0O"oMPnOUoNND0n*7 ND ~ NOT =D=GEeRTsrEEseSCscUuTrLiEHeTrDdsSAaaBdsReOoEVsvPEoeOnRtQqi TeUuEbdDm~vTIAaISIsTTARsRTEEeICCOoEcNNISrVBLLeDIhMueIITT wEHNMe/EaEnATHOO-~2=D0OSSNVGLUoORROnTELPGRXYAAG:):ePRGbPLAi/LSTSAiE~Eh-cC7Ah==R3BaE-LtSCS0EsTOT3VAA0EVN,RCOYAAPRRhOODAUCWTMHESETITHD1IO~3DO0S$O5,~F Q1C9THLISMDILTTSION, 1952/197 IET~ ZBITION 1992/19T~ EDITION, EDITION. 1955 199~ Bae Th EEA = #EPA{00/4-79-020, S~ = ~W 846 Rev. 4 1996 kZRCH 1985 RSETPkOiRrtToOnFakLoAmt wBOofRpAo TiObRnYct HASNtA1L,1YS5IS `nelac: `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NTSSTUYUBBIDJJIAEESCCTLTTRITTCOOT AACOPPURRROOTTT.EECNCTOT.IIVV2EE7-OOCRR\-DD1EE0RR-2E6E3NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00002200 au_Notsaseos 3M MN01538406 Le ace Analyteiitceaclon [s--ueb--tG--aE ERE DSpLAheEBerlIotO 5 sos ; 53924.05 Ssnine-c : ~04-0120-67~35 i ER :Sat oW5s3a92s4es [084665 enmnezn TPAoRmAsMEToERve Geen tOTAL ORGANIC CARBON weaning ~EPORTiNG en Wits LiMiT UNITS 1 mA loD m~/l RSSsSE~oahPdhrwOgwaeZLasiP~raoEDrzOeDn :::| 200002/3321//12211155324///1/222220000000000n0440 SUBMITTED : 02/14/2004 meswts 16 RESOLTS 16~7 moaDwAnnTeE//oeTnIvMeE moet saMvEreTreHiOeoDos ANALYZED owasor iAeNAsLYSTmLREFsEiReENoCnE 02/24/04 18148 ZAL SM53108 GCHFODoMoPO"nUNNRHooDO~rTo==SDt~eRTRenE~aSCasUTtoLZRLeTOesScaAosBRRvOoEEeVvRPErsOONRqGQTTuUEEuTADDRsNITE~ATSISoATsARRTToEEIIfCCOOEEnNIIGVVcEELLDDILIMiTIvTTre MTaSNEeEiATnmHaO'==DnyONRSosLoOUoeOtTRtGnRYcsOAS:aGPenAPeTLSLa5EIMi-CC3AaR=-BRE0LLCSSnEEOTE0VAA,ENNRDGYAgcRRDDOUhWTMEESTTIHHD1OOE9DD3SS5O~,F ~1C8HLIMSDIITTSION, 1952/1911 18TH ZDITION, 1992!19TH GONTION, EDITION~ i1999355 Sere ser, 1 199 Eg~ = ~EPA600i{-'79-020~ MA~C~ 1985 SN = SW 8~6 Rev, { i996 eee R-- EPOhR-- eT aOFl--LnApBi-- OeRAiTOaRYaoAkN,A,LYS5IS `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NTSSTUYUBBIDJJIAEESCCTLTTRITTCOOT AACOPPURRROOTTT.EECNCTOT.IIVV2EE7-OOCRR\-DD1EE0RR-2E6E3NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00002211 au_Notsaseor 3M MN01538407 / haceAnnalayltyiccaal," Peo ste on saernBES En Phone; 918 251o285~ esE R isn: :Lseohe s EE ees a eres eE sr,e TOTAL ORGA~{IC CARBO~i ]h~0 mg/~ roe saszsiaos REPORTED : 02/25/2004 om lm SAMPLED : 02/12/2004 pL Seen SUBH[TTED ; 02/&4/2004i srs wseee maurer swioe aa arma wes a wor ~o~ 02/~4/04 i9:OO KAL SM53i0B QED RESTS RERGRTCD 38 SESEEVD COMPOUND~ = RESt]LTS RE?OZTED AS RECEIVED nee, tor ND ~ NOT DETECTED ABOVE QUANTITATION LIMIT Ta or i pis * = SURROGATE RECOVERY OUTSICE OF QC LIMITS iPn EmeneA ------ NiA - NOT A~PLICABLE METHODOLOGY: SM = STANDARD METHODS, 18TH EDITiCN, 1992i19TH EDITION~ i995 a onan omy EPA = #EPA600/4-75-020 !%ARCH 1985 Sst RW - SW 846 Rev~ ~ ]996 I A LaL REPORT OF LABORATORY ANALYSIS Pa GONFIDE-NSTUIBJAECLT TO APROTECTIVE ORDER ENTEREDIN HENNEPIN COUNTY DISTRICT COURT. NO, 27:CV-10-26862 CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00002222 aizes 3M MN01538408 ings /"_Pace Analywtilcalom feSorbTooIwSos0LA3y5 rge 31r8.251]268 FSwaieln svaaismesane eHRn D5ow3n92e4 s enmers PA?SHETER oTOrTaALoOwRagmavNiIcC CcAaRmBsOoNn SSwRSaEArPMhoOPtn~Let[EeEDnDe||:: ro00a002222r////ie1221s5324/7///a222zoo000o00004s44u SUBMITTED : 02/14/2004 HsREaEPrOTRoTnINWgGes LIMIT UNITS 1i.~00 mmegr/il manne RESULTS WNDo moaxienn aust seserzmnocne DATE/TIME METHOD Cron Toi10 KL SHOR ANALYZND ANAI~YST REFERENCE 02/24/04 19:10 ~L SMS319B CCSNELOOoMoPoO=oaUnNNcrDsO*Ta=D=sTBeRTtseEBaaSCcsTUnuEaLLREnTTaSScAosBvmAROsosEVnvrPEtsoOnRtQTqoUEEuuDDDtm_eiN4iAtT9SniIscTaRRAtEZo2iCCf1oSEONsIIcVcVEELLDDILoMiItvTre SwTNMEoEinnToAHbC==~6]NSNS0LoOUsOntTReGR.nYSAOi:e?GavBAuiLTSriIB~caCaAR+=-nBE-iLSCS0sZOTT3VAA0SNN,RDDYAARRwDDOUnWTMESETTIHHD(OOE3DD5SS50,,[ Q1C878LIMBISTITSIGN, 1952/19 18T~ E~[TZON, 1992~IgTH EDITION, 1355 1995 Saer. 1 ioe EBb = #Z?A600i4-79-020, [~RCH 1985 SW - ~W 846 R~v. ~ 1996 Ra EPTOoRoTnOF La rAe=B0rORp ieAeTaOeRn ncY A, tvNALmYSIS ee ------------------------------------------ `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NTSSTUYUBBIDJJIAEESCCTLTTRITTCOOT AACOPPURRROOTTT.EECNCTOT.IIVV2EE7-OOCRR\-DD1EE0RR-2E6E3NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00002233 aW_Notsase0s 3M MN01538409 PaceAnalytical" - A QQCC RReessuullttss ar] es To 0 01 REPORT OF LABORATORY ANALYSIS ItetnoueWitgyo,sctSi,. 7 This r~n snait no~ b~ r~rod~ce& ~xc~p~ ~n `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NTSSTUYUBBIDJJIEAESCCTLTTRITTCOOT AACOPPURRROOTT.TEECNCTGT.IIVV2EE7-OOGRRu-DD1EE0RR.2E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..000024 au_Notsaseto 3M MN01538410 oe ~ aceAnaelnyttiscaoln roon Arnon O"sr7ie2d ~tmk~ Arroi~; OK 74~2 moS5E5E4 F~x: 918.25t.2599 Da eetco: | nmoemzenzo Po?A~MNTEZ Tomi ovamic eon TOTAL QRGANIC CARBON 1s AMfsRNEeAaPsLOrYcaRZTmeEEreDD e~:+ 000o222o////222p854t////222s0u000n008k44 16:26 DILUTIO~ ; 1 serosa REPORTING Ihr Wits wars LIMIT UNITS 0mm !.0 mg/l RgSULTS ND noDoAnTiEs/nTIeME meus eMsETeiHOoD ~AGLYoZrBaD n tAeNrAsLeYSTRouREFsSwNsEi~cCnE 02/24/08 16:26 ~%L SMSZ]OB ciCN%nDO"oMPuO=2pUNoNSNDoOn*crT a==sDEerRTsrEEaaeSCscUTutLuEsSTtDooSsaaAosBRmusOEoepVPsnEoOnRQtTqSUeEuoAD>mrNvSTrAinsISEoTTeARsRTTEoeILrCcOoENNeIgVerErLeDLIviMIvITiTzs wUENM/iEEnAnTTHIO==0D0OSNSaLLoOOe0ORrTR6R~Y1aYRA)::he~GvPoAiLSTSriLMEH-cC7oAR=5nBE-iLSCSsETOT0AVA2ENN0RDDYAATNRAODDOUCMTMHEESTTIHHDTOOEoDDSbSQ.,F Q1C8THLIEMDIITTSION, 1982/1974 IBTH EOiTION.1992i19TN SDITION, EDTTION, 1955 i995 Sere fer. 3 13% EPA = ~EPA600i4-79-020, >1%~C~ 198~ $W = ~W 846 Eev. 4 1996 fnelats Rp EPOrReTiOa e F LABORt AT, ORoYotAe toNvAL,1Y,SIS `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NTSSTUYUBBIDJJIAEESCCTLTTRITTCOOT AACOPPURRROOTTT.EECNCTGT.IIVV2EE7-OOGRRu-DD1EE0RR.2E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00002255 aW_Norsssett 3M MN01538411 "Pace Analytic.al en sttecon ressocrtA eosisnStoST iArnes Broken Arrow,, OK 74012 SRE Fax," 918.251,2599 ww MATRIX : W LLAABBOORBAATTOOR~YY CCOONnTtRROOLL SSP?IIKKEE//SSPPIIKKZG DUPLICATE DUPLZCATE RECOVERY RECOVERY apeo+ 0R2/t25/e20o08 REPORTED ; 02/25/2004 us ze LAB i~ hits heW0402240451 ine LDW04~2240451 gSoQ0Ce4la0osB2isAa2Tliz4Cc0asHa1r$:ai 04C2240451 aA2SSNo0oAn0csuL4t--Yo0oZar2aE---Da2a4ts 1e166r::40e22 2004-02-24 I :5S h fastec r omsegrn wsoeno sGoeorwse sSemeees wGweGs. Aohweose Aroe-Ue0wRiEhbenetcs RIERPTCOhReT tOFleLtAtmlBOr rRwATeOo RYnmAn tNtA9LYSIS `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NTSSTUYUBBIDJJIAEESCCTLTTRITTCOOT AACOPPURRROOTTT.EECNCTGT.IIVV2EE7-OOGRRu-DD1EE0RR.2E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00002266 au_norsaserz 3M MN01538412 "_PaceAnaflcypteicvaill Chain of Custody / Cooler Receipt stnsis Sotoaepro eaO21dr2s REPTOoRyrTotOFacLorAoBtORoeAscTeOtRsYowASNnAeLYSIS `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACOPPURRROOTT.TEECNCTOT.IIVV2EE7-OOCRR\-DD1EE0RR-2E6E3NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..0000227 _Motsaser 3M MN01538413 iFE EL Tr31k ATR i [i Ry k HH | 1m a (|e ee ie ee | EehRl EE hry i SB roe r sae ts GIEE i{: SRE =| LN iE <N FoLE er l E e(e] r || RE ffiiVese i NENT REEER : = [TR FS HE A WEINNTTER = SirAEeN 1S B RuH ne cE onse ErEsR m HE Hy |2 TRE FEE -- HH SE CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 1937.0028 3M MN01538414 Mark Fue Saturddaayy Deluery- I(Prioriy po" Shipping Request { Ooo__2}m"2]isfus__wwmsnvaty 2/1 [44 seseniitos PPL exmsinte, 403 Tine AMPMocornn ows toes | SWTo PiekUpFom O Recipients Nome: Pio =Trusa, Company Name: Street addroes S~reet Address: [ico west Mary --BePeae noJoae lczd s _/ PPhhoonne8 NNuummbbeerr:: Sug251- 250 - Special nscions Oncctono Conteris --PSehd ipeone ce es -- Mobos oPacages Charge To [-- Ormtt "ons owes 00, CCooiierNSaemvaen DaveyTime. J---- 7[s ------ seve Come FedoraBrmss TT oieoramo _-- Nfareen --_-- OTWRITE WTSECST CCoosts,t wes Toe con em CCo~sstt HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV- 1028862 `COCNOFINDEFNITIDALE--NSSUTUBBIJJEEACCLTT TTOO AA PPRROOTTEECCTTIIVVEE OORRDDEERR EENNTTEERREEDD IINN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00002299 33MM_MMNNO105135834814155. PAacnealyti. cal.I.N.T.ER.R.E_GI5(O2NA0oL0W0bORKrsOrRarDEwsRg /57.7 f [sr o nace e serve] "JOG se eewvoaresen|7,0. -- seeaprwae | Ring lame eon2] FayaGea o] R 1- EE L J Se Se 7 7 SMSZIOR for ES I -- |257% Ml resass -- -- eeoe r J = _o Imrog ) A nd a Sloot 100 : Te resimmons 220fef % P"lbaeafosree faivbearliTpoico wiih TeflonFilter A Cnormeso Sn Ove oT upetaT sn ces e "sun Atom ts ora _ _~ comma mncrsens -- Reicreation LeH b R --ounces-- Le72U 2 rs man Pots svar Ove ------ `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACOPPURRROOTT.TEECNCTOT.IIVV2EE7-OOCRR\-DD1EE0RR-2E6E3NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00003300 _Mo1s3sets 3M MN01538416 aceAAnnaallyyttiiccaall esteon, Pace Analvtical Services, Inc. 1700 Elm Slreel, Sm'te 200 Frewne: 612a607170 Minneapolis, MN 55414 Phone: 612.607,1700 Fax: 612.507.6444 Fsbruary 26, 2004 ser i Mr. Jess Eldridgs 3M Environmental Laboratcry 935 Bush Ave. Bldg. 2-3E-09 wImTIon St. Paul, ~~ 55144 Lab Project N~mber: Cl~ent Project ID: rsce i0~4665 E04-0120 CG Carbon om System Test oSnot ai t riss nset t menh rSege moerme Dsar Mr. Eldridge: Enclossd are the analytical results for sample(s) received by the laboratory on February 13, 2004. Results rsportsd herein conform to the most current NELAC standards, where applicable, unless otherwise narrated in the body of the report. If you have any questions concerning this report please feel free to contact me. Sincerely, for Roxanne Patterson pRPoerxooajgneenccett. YMPaaasntaatggeeerrrson@pacelahs.} c~m Minnesota Certification @: 027 053 137 Wisconsin Certificaton ~: 9999407970 Enclosures ionhelAtaec,: momen RREEPPOORRTT OOFF LLAABBOORRAATTOORRYY AANNAALLYYSSIISS 'Thi~ r'epn~ shall no'( I~ r~pro~u~, eept i. f~ll, without the written consent of Pace Analytical Services, Inc. CSONFIEDENTIAL - SUBIECT T0 A PROTECTIVE OROER ENTERED CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00003311 aw orsseatr 3M MN01538417 iceAAnnaallyyttiiccaall eto Pace Analytical Services, Inc. en 1700 Elm Slreet, Sm'te 200 Minneapol& MN 55414 fri Id T Phone: 612.60Z 1700 Fax: 612.507.6444 oe Lab Sample No: 105333132 RW Client Sample ID: E04-0120-67432 iar Parameters Microbiology Mm mei 4 Biochemical Oxygen Demand, 5 d i BOD, 5 day EEE Date Prepared -- Wet Chemistry TL, re Phenolies Total. in Water Phenol SI GC/MS Semivolatiles OL 625 wastewater GC/MS SVOA eyPhenol Pr bis(2-Chloroethyl) ether So 2-Chlorophenol rm 1,3-Diehlorohenzene mee 1,4-Dichlorobenzene Filo 1,2-Dichlorobenzene nmr bls(2-Chloroisopropyl) ether fide N-Nitroso-di-n-propylamine Le Nitrobenzene ps Isophorone fe2-Nitrophenol 3 2,4-Dimethylphenol ile bis(2-Chloroethoxy)methane 2,4-Dichlorophenol jar. 1,2,4-Trichlorobenzene EANaphthalene Hexachloro-l,3-butadiene Dhogmde 4-Chloro-3-methylphenol me 2,4,6-Trichlorophenol a 2-Chloronaphthalene LoDimethylphthalate nim Acenaphthylene 2,6-Dinitrotoluene boAcenaphthene Et 2,4-Dinitrophenol Ty 4-Nitrophenol EL, 2,4-Dinitrotoluene an Diethylphthalate Lab Project Number: 1084665 II cn ir Client Project ID; E04-0120 CG Carbon System Test i er OE is Project Sample Number: 1084665-001 ll Matrix: Water Date Collected: 02/12/04 ii:00 Date Received: 02/13/04 12:10 mon 8SmSer ei ifm iE Results _ Uni_ ts Report Limit Analyzed By CAS No. Qual RegLmt regi Lattin Prep/Method: / SM 5210B iani s ull Hm i" 52 mg/l 6 02/18/04 JPHI 1,2 02/13/04 13:30 02/13/04 13:30 wig ing Method: EPA 420.4 75.0 ug/l 02/17/04 VAF 108-95-2 ima tin Prep/Method: EPA 625 / EPA 625 Dimitar Lie ws ~D ug/l ii. 3 ob Lime am ~D ug/l ii. P 2 Ema ND ug/l 11. 2: 2 Ummm ND ug/l ii. Doom on mmm ens ND ug/l ii. PE ZL fans ND ug/l ii. BL NTL Se ~D ug/l ii. 2 2 EF Bhan ~D ug/l ii. Doom on mmm a ND ug/l ii. BE a ND ug/l ii. Doom on mmm ND ug/l ii. 2 2 Daas ND ug/l ii. 2 3 LE usmle ~D ug/l ii. ND ug/l ii. I 3 & mma ND ug/l ii. EZ iE NB ug/l ii. NB ug/l ii. 3 IL mame ND ug/l ii. Doom on mmm ~D ug/l ii. 2 Zp Himman ~D ug/l ii. Doom mmm ~D ug/l ii. ERLE ~D ug/l ii. ~D ug/l ii. 2 2 hag ND ug/l ii. iP = Zmmein ~D ug/l 54. EI~D ug/l 54. 2 ZZ Dales ~D ug/l ii. 2 ZL ener ~D ug/l ii. 02/18/04 16:10 KSK 02/18/04 16:10 KSK 02/18/04 16:10 KgE 02/18/04 16:10 KSK 02/18/04 16:10 KSK 02/18/04 16:10 KSK 02/18/04 16:10 KSK 02/18/04 16:10 KSK 02/18/04 16:10 KSK 02/18/04 16:10 KSK 02/18/04 16:10 KSK 02/18/04 16:10 KSK 02/18/04 16:10 KSK 02/18/04 16;I0 KSK 02/18/04 16:10 KSK 02/18/04 16:10 KSK 02/18/04 16:10 KSK 02/18/04 16:10 KSK 02/18/04 16:10 KSK 02/18/04 16:10 KSK 02/18/04 16;I0 KSK 02/18/04 16;I0 KSK 02/18/04 16:10 KSK 02/18/04 16:10 KSK 02/18/04 16:10 KSK 02/18/04 16:10 KSK 02/18/04 16;I0 KSK 02/18/04 16;I0 KSK 108-95-2 ii1-44-4 95-57-8 541-73-1 106-46-7 95-50-1 39638-32-9 621-64-7 98-95-3 78-59-1 88-75-5 105-67-9 ii1-91-I 120-83-2 120-82-1 91-20-3 87-68-3 59-50-7 88-06-2 91-58-7 131-11-3 208-96-8 606-20-2 83-32-9 51-28-5 100-02-7 121-14-2 84-66-2 Date: 02/26/04 Page: i of 34 ionhelHaec: momen RREEPPOORRTTOOFFLLAABBOORRAATTOORRYY AANNAALLYYSSIISS 'This r'epn~ shall n~t I~ r~pro~u~, eept i. f~ll, without the written consent of Pace Analytical Services, Inc. EE -- en CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00003322 aw miseste 3M MN01538418 iceAAnnaallyyttiiccaall ee tn o Pace Analvtical Services, Inc. 1700 Elm Slreel, Sm'te 200 Minneapolis, MN 55414 fri Id T Phone: 612.607,1700 Fax: 612.607.6444 oe i Ier OIE icsn ir Lab Sample No: 105333132 RW ll Client Sample ID: E04-0120-67432 SR tearageie in O81 rteie EE Parameters rg pi 4 Chlorophenyiphenyl ether oe 5 ews Fluorene CEE gs & Th mim nn 4,6-Dinitro-2-methylphenol ims 3 2 5 Bannan 4-Bromophenylphenyl ether Lar Doom on aman Hexachlorobenzene bd : 2 uma Pentachlorophenol [oe 2 ZL fleas Phenanthrene fea, =D amin Anthracene Di-n-butylphthalate fr PZ dase Fluoranthene bo Doom on amu Pyrene En --_-- Doom on mmm me Butylbenzylphthalate Gpmewess EA mami wen 3,3'-Dichlorobenzidine Da : = zmmnid Benzo(a)anthraeene iis 2BTA2 0 Ummi mErmeEas Chrysene Results ND ND ~D ~D ~D ND ~D ND rD ~D ~D rD ND ND ~D Lab Project Number: 1084665 Client Project ID; E04-0120 CG Carbon System Test Project Sample Number: 1084665-001 Matrix: Water Date Collected: 02/12/04 ii:00 Date Received: 02/13/04 12:10 Units ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l Report Limit Analyzed By ii. 02/18/04 16:10 KSK ii. 02/18/04 16:10 KSK 54. 02/18/04 16:10 KSK ii. 02/18/04 16:10 KSK ii. 02/18/04 16:10 KSK 25. 02/18/04 16:10 KSK ii. 02/18/04 16:10 KSK ii. 02/18/04 16:10 KSK ii. 02/18/04 16:10 KSK ii. 02/18/04 16:10 KSK ii. 02/18/04 16:10 KSK ii. 02/18/04 16:10 KSK 22. 02/18/04 16:10 KSK 11. 02/]8/04 16:~0 KgE ii. 02/18/04 16:10 KSK CAS No. 7005 72 3 86 73 7 534-52-1 101-55-3 118-74-1 87-86-5 85-01-8 120-12-7 84-74-2 206-44-0 129-00-0 85-68-7 91-94-1 56-55-3 218-01-9 Qual RegLmt bis(2-Ethylhexyl)phthalate Di-n-octylphthalate [a Benzo(h)fluoranthene re Benzo(k)fluoranthene es Benzo(a)pyrene Solow Indeno(l,2,3-cd)pyrene biDibenz(a,h)anthracene a Benzo(g,h,i)perylene feres Hexachloroethane ND ug/l ii. ND ug/l ii. Doom on ND ug/l ii. PZ ND ug/l ii. Doom on ND ug/l ii. Lf ob MD ug/l ii. Doom on ~D ug/l ii. 2 2 ~D ug/l ii. I=BL ~D ug/l ii. 02/18/04 16:10 KSK 02/18/04 16:10 KSK mmm wa 02/18/04 16:10 KSK hmm 02/18/04 16:10 KSK mmm we 02/18/04 16:10 KSK mmm 02/18/04 16:10 KSK mmm 02/18/04 16:10 KSK Deus 02/18/04 16:10 KSK pumbrai ia 02/18/04 16:10 KSK 117-81-7 117-84-0 205-99-2 207-08-9 50-32-8 193-39-5 53-70-3 191-24-2 67-72-1 Nitrobenzene-d5 (S) 79 % 02/18/04 16:10 KSK 4165-60-0 2-Fluorobiphenyl (S) 83 % 02/18/04 16:10 KSK 321-60-8 ~erphenyl-dl4 (s) Phenol-d6 (S) amet 2-Fluorophenol (S) 2,4,6-Tri~romophenol (S) a Date Extracted A GC/MS Volatiles EIS Volatile GC/MS by 624 rs Chloromethane ShVinyl chloride on es Bromomethane a Se e Chloroethane 82 % 0 % Co2 % 44 % wid02/16/04 02/18/04 16:10 KSK 1718-51-0 02/18/04 16:10 KSK 13127-88-3 3,4 SEALE 02/18/04 16:10 KSK 367-12-4 3,4 02/18/04 16:10 KSK 3,4 wn 02/16/04 wage Method: EPA es WE 5.4 Fil Eve Bn ~D Tom nn mmenem ones 19. P 2 Z3B4 mHmamaabannd ND 624 ug/l ug/l ug/l ug/l 1.0 02/17/04 19:04 PNI 74-87-3 1.0 02/17/04 19:04 PN1 75-01-4 1.0 02/17/04 19:04 PNI 74-83-9 1.0 02/17/04 19:04 PNI 75-00-3 Trichlorofluoromethane ~D ug/l 1.0 02/17/04 19~04 PNI 75-69-4 Date: 02/26/04 Page: 2 of 34 iS nelE ac: momen RREEPPOORRTT OOFF LLAABBOORRAATTOORRYY AANNAALLYYSSIISS 'Thi~ r'epn~ shall n~t I~ r~pro~u~, eept i. f~ll, without the written consent of Pace Analytical Services, Inc. EE -- en CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00003333 aw miseats 3M MN01538419 iceAAnnaallyyttiiccaall eto Pace Analytical Services, Inc. en 1700 Elm Slreet, Sm'te 200 Minneapolis, MN 55414 fri Id T Phone: 612.607,1700 Fax: 612.507.6444 oe i Ier OIE icsn ir Lab Sample No: 105333132 RW ll Client Sample ID: E04-0120-67432 Sa ein ion Og 81 erte lfm Parameters Co , tcp te Sue Jak or 83 Methylene chloride re Pn Le I,i Dichloroethene Dame EZ um mmmnem on trans-l,2-Dichloroethene Sn 2 Zi mae l,l-Dichloroethane Le oom amano Chloroform ri : 2 4 awanmam l,l,l-Trichloroethane Fn 2 ZB meee Carbon tetrachloride = Doom amu Benzene er : ZB anal 1,2-Diehloroethane fn 2 Zi dmmsenue Trichloroethene Fer Doom amu one 1,2-Dichloropropane se EI I aioe Bromodichloromethane mete Dm ny mmmuem on trans-l,3-Dichloropropene Results ND ND ~D ~D ~D ND ~D ND ND ~D ~D ~D ~D Lab Project Number: 1084665 Client Project ID; E04-0120 CG Carbon System Test Project Sample Number: 1084665-001 Matrix: Water Date Collected: 02/12/04 ii:00 Date Received: 02/13/04 12:10 Units ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l Report Limit Analyzed By 1.0 02/17/04 19:04 PNI 1.0 02/17/04 19:04 PNI 1.0 02/17/04 19:04 PNI 1.0 02/17/04 19:04 PNI 1.0 02/17/04 19:04 PNI 1.0 02/17/04 19:04 PNI 1.0 02/17/04 19:04 PNI 1.0 02/17/04 19:04 PNI 1.0 02/17/04 19:04 PNI 1.0 02/17/04 19:04 PNI 1.0 02/17/04 19:04 PNI 1.0 02/17/04 19:04 PNI 1.0 02/17/04 19:04 PNI CAS No. 75 09 2 75 35 4 156-60-5 75-34-3 67-66-3 71-55-6 56-23-5 71-43-2 107-06-2 79-01-6 78-87-5 75-27-4 10061-02-6 Qual RegLmt Toluene cls-l,3-Diehloropropene Sra 1,1,2-Trlchloroethane TiTetrachloroethene fe Dibromochloromethane in Chlorohenzene a Ethylbenzene Xylene (Total) neBromoform m Le ps l,l,2,2-Tetrachloroethane 20. ug/l ND ug/l Doom mma wen ND ug/l PZ i manana ND ug/l Doom maemo ND ug/l 2 Zi mamas ND ug/l Doom maemo ND ug/l 3.6 ug/l Sm mmm ne ND ug/l 3I B 2 OBaHmamaana ND ug/l 1.0 02/17/04 19:04 PNI i09-9~-3 1.0 02/17/04 19:04 PNI 10061-01-5 1.0 02/17/04 19:04 PNI 79-00-5 1.0 02/17/04 19:04 PN1 127-18-4 1.0 02/17/04 19:04 PN1 124-48-1 1.0 02/17/04 19:04 PN1 108-90-7 1.0 02/17/04 19:04 PNI 100-41-4 3.0 02/17/04 19:04 PNI 1330-20-7 1.0 02/17/04 19:04 PNI 75-25-2 1.0 02/17/04 19:04 PNI 79-34-5 1,3-Dichlorobenzene 1,4-Dichlorobenzene ho1,2-Dichlorobenzene are 2-chloroethylvinyl ether oar Dibromofluoromethane (S) Toluene-d8 (S) We ew 4-Bromofluorobenzene (S) Patten 1,2-Dichloroethane-d4 (S! ND ug/l 1.0 ND ug/l 1.0 2 Zi ~D ug/l 1.0 2 2B ~D ug/l 5.0 fj 96 % 89 % 597 % 292 % 02/17/04 19:04 PNI 02/17/04 19:04 PNI manag 02/17/04 19:04 PNI maaan, 02/17/04 19:04 PNI Srna 02/17/04 19:04 PNI 02/17/04 19:04 PNI a em 02/17/04 19:04 PNI TAARaT va, 02/17/04 19:04 PNI 541-73-I 106-46-7 95-50-1 110-75-8 1868-53-7 2037-26-5 460-00-4 17060-07-0 Date: 02/26/04 ionhelHaec: momen RR EPOE RTOP OFFLLAO ABBOORR RAATTOT ORRYY AANNAALLYYSSIISS 'This r'epn~ shall n~'( I~ r~ro~u~, eept i. full, without the written consent of Pace Analytical Services, Inc. EE -- en CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00003344 Page: 3 of 34 [pT 3M MN01538420 iceAAnnaallyyttiiccaall ee ton Pace Analldical Services, Inc. 1700 Elm Slreet, Sm'te 200 Minneapolis, MN 55414 fri Id T Phone: 612.60/1700 Fax: 612.507.6444 oe Lab Sample No: 105333140 RW Client Sample ID: E04-0120-67434 iar Parameters Microbiology mm 4 Biochemical Oxygen Demand, 5 d vein BOD, 5 day EEE Date Prepared -- Wet Chemistry SL, re Phenolies Total. in Water enPhenol SI GC/MS Semivolatiles OL 625 wastewater GC/MS SVOA eyPhenol Pr bis(2-Chloroethyl) ether So 2-Chlorophenol rm 1,3-Diehlorohenzene mee 1,4-Dichlorobenzene Filo 1,2-Dichlorobenzene nmr bls(2-Chloroisopropyl) ether fide N-Nitroso-di-n-propylamine Le Nitrobenzene ps Isophorone fe2-Nitrophenol 3 2,4-Dimethylphenol ile bis(2-Chloroethoxy)methane 2,4-Dichlorophenol jar. 1,2,4-Trichlorobenzene EANaphthalene Hexachloro-l,3-butadiene Dhogmde 4-Chloro-3-methylphenol 2,4,6-Trichlorophenol a 2-Chloronaphthalene LoDimethylphthalate nim Acenaphthylene 2,6-Dinitrotoluene boAcenaphthene Et 2,4-Dinitrophenol Ty 4-Nitrophenol EL, 2,4-Dinitrotoluene an Diethylphthalate Lab Project Number: 1084665 II cn ir Client Project ID; E04-0120 CG Carbon System Test Ee Project Sample Number: 1084665-002 ll Matrix: Water Date Collected: 02/12/04 11:45 Date Received: 02/13/04 12:10 eee mon 85SmSer ei ifm Results _ Uni_ ts Report Limit Analyzed By CAS No. Qual RegLmt epi Lattin Prep/Method: / SM 5210B cgors s ogi S rHtsm oe i" 15 mg/l 6 02/18/04 JPHI 1,2 02/13/04 13:30 02/13/04 13:30 wigsimeisngWE Method: EPA 420.4 ND ug/l 02/17/04 VAF 108-95-2 ima tin Prep/Method: EPA 625 / EPA 625 Din imat iin ws ND ug/l i0. 3 5 5 Luma ~D ug/l i0. PZ I ama ND ug/l ]0. 2: 2 OF Ummm ND ug/l i0. Doom ame ens ND ug/l i0. EZ 5 lanes ND ug/l i0. BL NL ~D ug/l i0. 2 2 OF Haan ~D ug/l i0. Doom on mmm a ND ug/l i0. [EE ND ug/l i0. Doom on mumps ND ug/l 10. 2 2 Dmbaus ND ug/l 10. 2 3 saan len ND ug/l 10. ND ug/l 10. I 3 5 maaan ND ug/l 10. EZ EE NB ug/l 10. NB ug/l i0. 3 IL mapas ND ug/l i0. ~D ug/l i0. EE Eo ND ug/l i0. 2Doo2 m B Gmmeanny ~D ug/l i0. 02/18/04 17:04 KSK 02/18/04 17:04 KSK 02/18/04 17:04 ~E 02/18/04 17:04 KSK 02/18/04 17:04 KSK 02/18/04 17:04 KSK 02/18/04 17:04 KSK 02/18/04 17:04 KSK 02/18/04 17:04 KSK 02/18/04 17:04 KSK 02/18/04 17:04 KSK 02/18/04 17:04 KSK 02/18/04 17:04 KSK 02/18/04 17:04 KSK 02/18/04 17:04 KSK 02/18/04 17:04 KSK 02/18/04 17:04 KSK 02/18/04 17:04 KSK 02/18/04 17:04 KSK 02/18/04 17:04 KSK 02/18/04 17:04 KSK 108-95-2 ii1-44-4 95-57-8 541-73-1 106-46-7 95-50-1 39638-32-9 621-64-7 98-95-3 78-59-1 88-75-5 105-67-9 111-91-1 120-83-2 120-82-1 91-20-3 87-68-3 59-50-7 88-06-2 91-58-7 131-11-3 ~D ug/l ~D ug/l 2 2 Shade ND ug/l P = Zien ~D ug/l En ND ug/l 2 ZZ Dunia ~D ug/l 2 Zk dame ~D ug/l i0. 02/18/04 17:04 KSK 208-96-8 i0. 02/18/04 17:04 KSK 606-20-2 10. 02/18/04 17:04 KSK 83-32-9 51. 02/18/04 17:04 KSK 51-28-5 51. 02/18/04 17:04 KSK 100-02-7 i0. 02/18/04 17:04 KSK 121-14-2 i0. 02/18/04 17:04 KSK 84-66-2 Date: 02/26/04 Page: 4 of 34 ionhelHaec: momen RREEPPOORRTTOOFFLLAABBOORRAATTOORRYY AANNAALLYYSSIISS This report shall not I;e reproduced, except in full, without the written consent of Pace ,~,nalytieal Services, Inc. EE -- en CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00003355 pr 3M MN01538421 iceAAnnaallyyttiiccaall eto Pace Analytical Services, Inc. en 1700 Elm Slreet, Sm'te 200 Minneapolis, MN 55414 fri Id T Phone: 612.607,1700 Fax: 612.507.6444 oe E II e cn ir Lab Sample No: 105333140 RW ll Client Sample ID: E04-0120-67434 SR aterageie in 8188 rteie EE Parameters ra pr 4 Chlorophenyiphenyl ether oe 5 oes Fluorene CEE gs & TAM mumemnn 4,6-Dinitro-2-methylphenol ims 3 2 F Bannan 4-Bromophenylphenyl ether Lar Doom on amas Hexachlorobenzene bd : 2 amass Pentachlorophenol [oe 2 2b apes Phenanthrene fea, } = Bangin Anthracene Di-n-butylphthalate fr 2 ZI & Hades Fluoranthene bo Doom mma Pyrene En --_-- Doom on mma me Butylbenzylphthalate Gpmewess EAM mans wen 3,3'-Dichlorobenzidine Da P 2 EB ZapEnad Benzo(a)anthraeene i 2: 2 PF UmmErE Chrysene is BTA Mmmm meas hls(2-Ethylhexyl)phthalate se PZ b&b Haneewa Di-n-octylphthalate [a Doom mma wa Benzo(h)fluoranthene re PZ bE Hansa Benzo(k)fluoranthene es Doom on mmm we Benzo(a)pyrene Solow Lo mmoama Indeno(l,2,3-cd)pyrene bi Doom on mumps Dibenz(a,h)anthracene a 2 2 Bmpans Benzo(g,h,i)perylene feres I5 Latnn se ia Hexachloroethane Results ND ND ~D ~D ~D ND ND ~D ~D ~D ~D ND ~D ND ND ND ~D ~D ND ~D ~D ~D ND ~D Lab Project Number: 1084665 Client Project ID; E04-0120 CG Carbon System Test Project Sample Number: 1084665-002 Matrix: Water Date Collected: 02/12/04 11:45 Date Received: 02/13/04 12:10 Units ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l Report Limit Analyzed By i0. 02/18/04 17:04 KSK i0. 02/18/04 17:04 KSK 51. 02/18/04 17:04 KSK i0. 02/18/04 17:04 KSK i0. 02/18/04 17:04 KSK 24. 02/18/04 17:04 KSK i0. 02/18/04 17:04 KSK i0. 02/18/04 17:04 KSK i0. 02/18/04 17:04 KSK i0. 02/18/04 17:04 KSK i0. 02/18/04 17:04 KSK i0. 02/18/04 17:04 KSK 21. 02/18/04 17:04 KSK 10. 02/]S/04 17:04 KSK i0. 02/18/04 17:04 KSK i0. 02/18/04 17:04 KSK i0. 02/18/04 17:04 KSK i0. 02/18/04 17:04 KSK i0. 02/18/04 17:04 KSK i0. 02/18/04 17:04 KSK i0. 02/18/04 17:04 KSK 10. 02/18/04 17:04 KSK 10. 02/18/04 17:04 KSK 10. 02/18/04 17:04 KSK CAS No. 7005 72 3 86 73 7 534-52-1 101-55-3 118-74-1 87-86-5 85-01-8 120-12-7 84-74-2 206-44-0 129-00-0 85-68-7 91-94-1 56-55-3 218-01-9 117-81-7 117-84-0 205-99-2 207-08-9 50-32-8 193-39-5 53-70-3 191-24-2 67-72-1 Qual RegLmt Nitrobenzene-d5 (S) 67 % 02/18/04 17:04 KSK 4165-60-0 2-Fluorobiphenyl (S) 71 % 02/18/04 17:04 KSK 321-60-8 ~erphenyl-dl4 (S) Phenol-d6 (S) amet 2-Fluorophenol (S) 2,4,6-Tribromophenol (S) a Date Extracted A GC/MS Volatiles EAI Volatile GC/MS by 624 rs Chloromethane ShVinyl chloride on es Bromomethane r Se e Chloroethane 80 % 32 % FR43 % 71 % san 02/16/04 wap Method: EPA 624 per ~D ug/l 1.0 3 3 ~D ug/l 1.0 SR RL 6.7 ug/l 1.0 2 32 B4 ~D ug/l 1.0 02/18/04 17:04 KSK 1718-51-0 02/18/04 17:04 KSK 13127-88-3 3,4 SAT Ra 02/18/04 17:04 KSK 367-12-4 3,4 02/18/04 17:04 KSK wn 02/16/04 mm 02/17/04 20:00 PNI Ummm 02/17/04 20:00 PN1 WTAE fats 02/17/04 20:00 PNI mmmandsahsd 02/17/04 20:00 PNI 74-87-3 75-01-4 74-83-9 75-00-3 Trichlorofluoromethane ~D ug/l 1.0 02/17/04 20~00 PNI 75-69-4 Date: 02/26/04 Page: 5 of 34 iS nelE ac: momen RREEPPOORRTT OOFF LLAABBOORRAATTOORRYY AANNAALLYYSSIISS 'Thi~ r'epn~ shall n~t I~ r~pro~u~, eept i. f~ll, without the written consent of Pace Analytical Services, Inc. EE -- en CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00003366 [pr 3M MN01538422 iceAAnnaallyyttiiccaall eto Pace Analytical Services, Inc. en 1700 Elm Slreet, Sm'te 200 Minneapolis, MN 55414 fri Id T Phone: 612.607,1700 Fax: 612.507.6444 oe E II e cn ir Lab Sample No: 105333140 RW ll Client Sample ID: E04-0120-67434 So ee ion Og 81 rtn lfm Parameters Co , tcp te Sue Jak ag 83 Methylene chloride re 5 Lr I,i Dichloroethene Dame EZ um mmmnem on trans-l,2-Dichloroethene Sn 2 Zi mane l,l-Dichloroethane Le Doom mmmnemonn Chloroform ri : 2 4 faanam l,l,l-Trichloroethane Fn EZ i fanange Carbon tetrachloride = oom mmmnemoa Benzene er : ZB mame 1,2-Dichloroethane fn 2 Zi dmmsanue Trichloroethene Fer Doom amnem one 1,2-Dichloropropane se EI ios Bromodichloromethane mete Dm ny mmmnem on trans-l,3-Dichloropropene Results ND ND ~D ~D ~D ND ND ND ~D ~D ~D ~D ND Lab Project Number: 1084665 Client Project ID; E04-0120 CG Carbon System Test Project Sample Number: 1084665-002 Matrix: Water Date Collected: 02/12/04 11:45 Date Received: 02/13/04 12:10 Units ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l us/l ug/l ug/l Report Limit Analyzed By 1.0 02/17/04 20:00 PNI 1.0 02/17/04 20:00 PNI 1.0 02/17/04 PNI 1.0 02/17/04 20:00 PNI 1.0 02/17/04 20:00 PNI 1.0 02/17/04 20:00 PNI 1.0 02/17/04 20:00 PNI 1.0 02/17/04 20:00 PNI 1.0 02/17/04 20:00 PNI 1.0 02/17/04 20:00 PNI 1.0 02/17/04 20:00 PNI 1.0 02/17/04 20:00 PNI 1.0 02/17/04 20:00 PNI CAS No. 75 09 2 75 35 4 156-60-5 75-34-3 67-66-3 71-55-6 56-23-5 71-43-2 107-06-2 79-01-6 78-87-5 75-27-4 10061-02-6 Qual RegLmt Toluene cls-l,3-Diehloropropene Sra Doom mma wen l,l,2-Trlchloroethane Ti PZ i maemo Tetrachloroethene fe Doom mmmnem oma Dibromochloromethane in 2 Zi mamma Chlorobenzene a oom mmmnemoaen Ethylbenzene Sa PS aan Xylene (Total) ne Doom mpmuem ne Bromoform mes 3 BO mame l,l,2,2-Tetrachloroethane Lp I 2 Bamana 1,3-Dichlorobenzene 1,4-Dichlorobenzene ho 22 fanaa 1,2-Dichlorobenzene are 2 2B amma 2-chloroethylvinyl ether mid Sratam a Dibromofluoromethane (S) Toluene-d8 (S) We wh a em 4-Bromofluorobenzene (S) Prtian 2 SAAnaE va, 1,2-Dichloroethane-d4 (S! ND ug/l ND ug/l ND ug/l ~D ug/l ~D ug/l ~D ug/l ~D ug/l ~D ug/l ~D ug/l ~D ug/l ND ug/l ~D ug/l ~D ug/l ~D ug/l 90 % 78 % 85 % 88 % 1.0 02/17/04 20:00 PNI 1.0 02/17/04 20:00 PNI 10061-01-5 1.0 02/17/04 20:00 PNI 79-00-5 1.0 02/17/04 20:00 PNI 127-18-4 1.0 02/17/04 20:00 PNI 124-48-I 1.0 02/17/04 20:00 PNI 108-90-7 1.0 02/17/04 20:00 PNI 100-41-4 3.0 02/17/04 20:00 PNI 1330-20-7 1.0 02/17/04 20:00 PNI 75-25-2 1.0 02/17/04 20:00 PNI 79-34-5 1.0 02/17/04 20:00 PNI 541-73-I 1.0 02/17/04 20:00 PNI 106-46-7 1.0 02/17/04 20:00 PNI 95-50-1 5.0 02/17/04 20:00 PNI 110-75-8 02/17/04 20:00 PNI 1868-53-7 02/17/04 20:00 PNI 2037-26-5 02/17/04 20:00 PNI 460-00-4 02/17/04 20:00 PNI 17060-07-0 Date: 02/26/04 ionhelHaec: momen RR EPOE RTOP OFFLLAO ABBOORR RAATTOT ORRYY AANNAALLYYSSIISS 'Thi~ r'epn~ shall n~t I~ r~pro~u~, eept i. f~ll, without the written consent of Pace Analytical Services, Inc. EE -- en CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00003377 Page: 6 of 34 awmises 3M MN01538423 iceAAnnaallyyttiiccaall eto Pace Analytical Services, Inc. en 1700 Elm Slreet, Sm'te 200 Minneapolis, MN 55414 fri Id T Phone: 612.607,1700 Fax: 612.507.6444 oe Lab Sample No: 105333157 I ew Client Sample ID: E04-0120-67439 iar Parameters Microbiology mom 4 Biochemical Oxygen Demand, 5 d i BOD, 5 day EEE Date Prepared -- Wet Chemistry SL, re Phenolies Total. in Water enPhenol SI GC/MS Semivolatiles OL 625 wastewater GC/MS SVOA eyPhenol VR bis(2-Chloroethyl) ether So 2-Chlorophenol rm 1,3-Diehlorohenzene mee 1,4-Dichlorobenzene Filo 1,2-Dichlorobenzene mr bls(2-Chloroisopropyl) ether fide N-Nitroso-di-n-propylamine Le Nitrobenzene ps Isophorone fe2-Nitrophenol 3 2,4-Dimethylphenol ile bis(2-Chloroethoxy)methane 2,4-Dichlorophenol jar. 1,2,4-Trichlorobenzene EANaphthalene Hexachloro-l,3-butadiene Dhogmde 4-Chloro-3-methylphenol me 2,4,6-Trichlorophenol a 2-Chloronaphthalene LoDimethylphthalate nim Acenaphthylene 2,6-Dinitrotoluene boAcenaphthene Et 2,4-Dinitrophenol Ty 4-Nitrophenol EL, 2,4-Dinitrotoluene an Diethylphthalate Lab Project Number: 1084665 II cn ir Client Project ID; E04-0120 CG Carbon System Test i er OE xi is Project Sample Number: 1084665-003 ll A Matrix: Water Date Collected: 02/12/04 11:20 Date Received: 02/13/04 12:10 mon 85SmSer ei ifm iE Results _ Uni_ ts Report Limit Analyzed By CAS No. Qual RegLmt regi Lattin Prep/Method: / SM 5210B casnss ogi St Hm om i" 42 mg/l 6 02/18/04 JPHI 1,2 02/13/04 13:30 02/13/04 13:30 wigsimeisngWE Method: EPA 420.4 ND ug/l 02/17/04 VAF 108-95-2 ima tin Prep/Method: EPA 625 / EPA 625 Bin tmat Lie ws ND ug/l i0. CE doin ~D ug/l i0. P= I mn ND ug/l ]0. 2: 2 OF mE ND ug/l i0. Doom mma ens ND ug/l i0. EZ 5 fiance ND ug/l i0. BL RL ee ~D ug/l i0. 2 2 OF Haan ~D ug/l i0. Doom on mma a ND ug/l i0. [EE ND ug/l i0. Doom on mma ND ug/l 10. 2 2 Dmbesue ND ug/l 10. 2 3 saaiien ~D ug/l 10. ND ug/l 10. I 3 5 mamas ND ug/l 10. EZ EE NB ug/l 10. NB ug/l i0. 3 IL mana ND ug/l i0. Doom on mma ND ug/l i0. 2 Zk Haasan ~D ug/l i0. Doom mma ~D ug/l i0. a ~D ug/l i0. ~D ug/l i0. 2 2 Shade ND ug/l 10. iP = Zmmein ND ug/l 51. EI~D ug/l 51. 2 ZZ Dmuemies ~D ug/l i0. 2 Zk anes ~D ug/l i0. 02/18/04 17:57 KSK 02/18/04 17:57 KSK 02/18/04 17:57 K~E 02/18/04 17:57 KSK 02/18/04 17:57 KSK 02/18/04 17:57 KSK 02/18/04 17:57 KSK 02/18/04 17:57 KSK 02/18/04 17:57 KSK 02/18/04 17:57 KSK 02/18/04 17:57 KSK 02/18/04 17:57 KSK 02/18/04 17:57 KSK 02/18/04 17:57 KSK 02/18/04 17:57 KSK 02/18/04 17:57 KSK 02/18/04 17:57 KSK 02/18/04 17:57 KSK 02/18/04 17:57 KSK 02/18/04 17:57 KSK 02/18/04 17:57 KSK 02/18/04 17:57 KSK 02/18/04 17:57 KSK 02/18/04 17:57 KSK 02/18/04 17:57 KSK 02/18/04 17:57 KSK 02/18/04 17:57 KSK 02/18/04 17:57 KSK 108-95-2 ii1-44-4 95-57-8 541-73-1 106-46-7 95-50-1 39638-32-9 621-64-7 98-95-3 78-59-1 88-75-5 105-67-9 111-91-1 120-83-2 120-82-1 91-20-3 87-68-3 59-50-7 88-06-2 91-58-7 131-11-3 208-96-8 606-20-2 83-32-9 51-28-5 100-02-7 121-14-2 84-66-2 Date: 02/26/04 Page: 7 of 34 ionhelHaec: momen RREEPPOORRTTOOFFLLAABBOORRAATTOORRYY AANNAALLYYSSIISS 'This r'epn~ shall n~t I~ r~pro~u~, eept i. f~ll, without the written consent of Pace Analytical Services, Inc. EE -- en CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00003388 pr 3M MN01538424 iceAAnnaallyyttiiccaall eto Pace Analytical Services, Inc. en 1700 Elm Slreet, Sm'te 200 Minneapolis, MN 55414 fri Id T Phone: 612.607,1700 Fax: 612.507.6444 oe i Ier OIE xiicnsir Lab Sample No: 105333157 I ew ll A Client Sample ID: E04-0120-67439 SR aterageie in 8188 peiE Parameters ra pi 4 Chlorophenyiphenyl other oe 5 mrEEs Fluorene CEE gs & TAM muna 4,6-Dinitro-2-methylphenol ims 3 2 F Bannan 4-Bromophenylphenyl ether Lar Doom on amano Hexachlorobenzene bd PZ ness Pentachlorophenol [oe 2 ZB lures Phenanthrene fea, } = PB amma Anthracene Di-n-butylphthalate fr PZ & Hades Fluoranthene bo Doom on amano Pyrene En --_-- Doom on aman ae Butylbenzylphthalate Spmewess EA mano wen 3,3'-Dichlorobenzidine Da : = zammnad Benzo(a)anthraeene i 2 2 EF UmmEiE Chrysene is BTA mmo nes hls(2-Ethylhexyl)phthalate se PZ b&b Hamewa Di-n-octylphthalate [a Doom mwmanm na Benzo(b)fluoranthene re PZ bE Hansa Benzo(k)fluoranthene es Doom on mma oe Benzo(a)pyrene Solow fo mmoeman Indeno(l,2,3-cd)pyrene bi Doom on mma Dibenz(a,h)anthracene a 2 2 Dmbaas Benzo(g,h,i)perylene feres I5BL Duane irar Hexachloroethane Results ND ND ~D ~D ~D ND ~D ND ~D ~D ~D rD ND ND ND ND ~D ND ~D ND ~D ~D ~D ~D Lab Project Number: 1084665 Client Project ID; E04-0120 CG Carbon System Test Project Sample Number: 1084665-003 Matrix: Water Date Collected: 02/12/04 11:20 Date Received: 02/13/04 12:10 Units ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l Report Limit Analyzed By i0. 02/18/04 17:57 KSK i0. 02/18/04 17:57 KSK 51. 02/18/04 17:57 KSK i0. 02/18/04 17:57 KSK i0. 02/18/04 17:57 KSK 23. 02/18/04 17:57 KSK i0. 02/18/04 17:57 KSK i0. 02/18/04 17:57 KSK i0. 02/18/04 17:57 KSK i0. 02/18/04 17:57 KSK i0. 02/18/04 17:57 KSK i0. 02/18/04 17:57 KSK 20. 02/18/04 17:57 KSK 10. 02/]S/04 17:57 KSK i0. 02/18/04 17:57 KSK i0. 02/18/04 17:57 KSK i0. 02/18/04 17:57 KSK i0. 02/18/04 17:57 KSK i0. 02/18/04 17:57 KSK i0. 02/18/04 17:57 KSK i0. 02/18/04 17:57 KSK 10. 02/18/04 17:57 KSK 10. 02/18/04 17:57 KSK 10. 02/18/04 17:57 KSK CAS No. 7005 72 3 86 73 7 534-52-1 101-55-3 118-74-1 87-86-5 85-01-8 120-12-7 84-74-2 206-44-0 129-00-0 85-68-7 91-94-1 ~6-55-3 218-01-9 117-81-7 117-84-0 205-99-2 207-08-9 50-32-8 193-39-5 53-70-3 191-24-2 67-72-1 Qual RegLmt Nitrobenzene-d5 (S) 71 % 02/18/04 17:57 KSK 4165-60-0 2-Fluorobiphenyl (S) 79 % 02/18/04 17:57 KSK 321-60-8 Terphenyl-dl4 (s) Phenol-d6 (S) amet 2-Fluorophenol (S) 2,4,6-Tribromophenol (S) a Date Extracted A GC/MS Volatiles EAI Volatile GC/MS by 624 rs Chloromethane ShVinyl chloride on es Bromomethane Se Chloroethane ae Trichlorofluoromethane 81 % 21 % FI32 % 62 % sien 02/16/04 02/18/04 17:57 KSK 1718-51-0 02/18/04 17:57 KSK 13127-88-3 3,4 SAL ea 02/18/04 17:57 KSK 367-12-4 3,4 02/18/04 17:57 KSK wn 02/16/04 wap Method: EPA per mmm ND 3 3 Ummm ~D Sr EE Fs 7.5 2 2 4 aan ND 2 3B Dmuabai ~D 624 ug/l ug/l ug/l ug/l ug/l 1.0 02/17/04 20:28 PNI 74-87-3 1.0 02/17/04 20:28 PN1 75-01-4 1.0 02/17/04 20:28 PNI 74-83-9 1.0 02/17/04 20:28 PNI 75-00-3 1.0 02/17/04 20~28 PNI 75-69-4 Date: 02/26/04 Page: 8 of 34 iS nelE ac: momen RREEPPOORRTT OOFF LLAABBOORRAATTOORRYY AANNAALLYYSSIISS 'Thi~ r'epn~ shall n~t I~ r~pro~u~, eept i. f~ll, without the written consent of Pace Analytical Services, Inc. EE -- en CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00003399 [pr 3M MN01538425 iceAAnnaallyyttiiccaall eto Pace Analytical Services, Inc. en 1700 Elm Slreet, Sm'te 200 Minneapolis, MN 55414 fri Id T Phone: 612.607,1700 Fax: 612.507.6444 oe i Ier OIE xiicnsir Lab Sample No: 105333157 I ew ll A Client Sample ID: E04-0120-67439 So ie ion Og 81 rto lfm EE Parameters Co , EE a Methylene chloride re 5 aere I,i Dichloroethene Dame EZ um mmmnam on trans-l,2-Dichloroethene Sn 2 Zi mand l,l-Dichloroethane Le oom mmmnam on Chloroform ri ? 2 4 faanam l,l,l-Trichloroethane Fn 2 ZB fmaiange Carbon tetrachloride = Doom mmmnam Benzene er : ZB amma 1,2-Diehloroethane fn 2 ZW means Trichloroethene Fer Doom amnam oe 1,2-Dichloropropane se EI io Bromodichloromethane mete Dm ny mmmnam on trans-l,3-Dichloropropene Results ND ND ~D ~D ~D ND ~D ND ND ~D ~D ~D ~D Lab Project Number: 1084665 Client Project ID; E04-0120 CG Carbon System Test Project Sample Number: 1084665-003 Matrix: Water Date Collected: 02/12/04 11:20 Date Received: 02/13/04 12:10 Units ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l us/l ug/l ug/l Report Limit Analyzed By 1.0 02/17/04 20:28 PNI 1.0 02/17/04 20:28 PNI 1.0 02/17/04 20;28 PNI 1.0 02/17/04 20:28 PNI 1.0 02/17/04 20:28 PNI 1.0 02/17/04 20:28 PNI 1.0 02/17/04 20:28 PNI 1.0 02/17/04 20:28 PNI 1.0 02/17/04 20:28 PNI 1.0 02/17/04 20:28 PNI 1.0 02/17/04 20:28 PNI 1.0 02/17/04 20:28 PNI 1.0 02/17/04 20:28 PNI CAS No. 75 09 2 75 35 4 156-60-5 75-34-3 67-66-3 71-55-6 56-23-5 71-43-2 107-06-2 79-01-6 78-87-5 75-27-4 10061-02-6 Qual RegLmt Toluene cls-l,3-Diehloropropene Sra l,l,2-Trlchloroethane TiTetrachloroethene fe Dibromochloromethane in Chlorobenzene a Ethylbenzene SaXylene (Total) neBromoform mes l,l,2,2-Tetrachloroethane Lp 1,3-Dichlorobenzene 1,4-Dichlorobenzene ho1,2-Dichlorobenzene are 2-chloroethylvinyl ether oar Dibromofluoromethane (S) Toluene-d8 (S) We en 4-Bromofluorobenzene (S) mE 1,2-Dichloroethane-d4 (S! ND ug/l 1.0 ND ug/l 1.0 Doom ND ug/l 1.0 PZ i ~D ug/l 1.0 Doom ~D ug/l 1.0 2 Zi ~D ug/l 1.0 oom ND ug/l 1.0 PS ~D ug/l 3.0 Doom ~D ug/l 1.0 3 BO ~D ug/l 1.0 I 2 B ND ug/l 1.0 ~D ug/l 1.0 22 1 ND ug/l 1.0 2 2B ~D ug/l 5.0 Ij 97 80 587 SE 91 02/17/04 20:28 PNI 02/17/04 20:28 PNI mmmnam wen 02/17/04 20:28 PN1 maemo 02/17/04 20:28 PN1 manawa 02/17/04 20:28 PNI mammnas 02/17/04 20:28 PNI maaan 02/17/04 20:28 PNI Beem 02/17/04 20:28 PNI aman one 02/17/04 20:28 PNI Hmmm ie 02/17/04 20:28 PNI gmeuaniay 02/17/04 20:28 PNI 02/17/04 20:28 PNI imams 02/17/04 20:28 PNI EEEaL 02/17/04 20:28 PNI Srntam a 02/17/04 20:28 PNI 02/17/04 20:28 PNI nm 02/17/04 20:28 PNI AAT Sa, 02/17/04 20:28 PNI i09-9~-3 10061-01-5 79-00-5 127-18-4 124-48-I 108-90-7 100-41-4 1330-20-7 75-25-2 79-34-5 541-73-1 106-46-7 95-50-1 110-75-8 1868-53-7 2037-26-5 460-00-4 17060-07-0 Date: 02/26/04 ionhelHaec: momen RR EPOE RTOP OFFLLAO ABBOORR RAATTOT ORRYY AANNAALLYYSSIISS 'Thi~ r'epn~ shall n~t I~ r~pro~u~, eept i. f~ll, without the written consent of Pace Analytical Services, Inc. EE -- en CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00004400 Page: 9 of 34 [pr 3M MN01538426 iceAAnnaallyyttiiccaall eto Pace Analytical Services, Inc. en 1700 Elm Slreet, Sm'te 200 Minneapolis, MN 55414 fri Id T Phone: 612.607,1700 Fax: 612.507.6444 oe Lab Sample No: 105333165 RW Client Sample ID: E04-0120-67438 iar Parameters Microbiology Tm ome 14 Biochemical Oxygen Demand, 5 d i BOD, 5 day EEE Date Prepared -- Wet Chemistry SL, re Phenolies Total. in Water enPhenol SI GC/MS Semivolatiles OL 625 wastewater GC/MS SVOA eyPhenol Pr bis(2-Chloroethyl) ether So 2-Chlorophenol rm 1,3-Diehlorohenzene mee 1,4-Dichlorobenzene Filo 1,2-Dichlorobenzene mr bls(2-Chloroisopropyl) ether fide N-Nitroso-di-n-propylamine Le Nitrobenzene ps Isophorone fe2-Nitrophenol 3 2,4-Dimethylphenol ile bis(2-Chloroethoxy)methane 2,4-Dichlorophenol jar. 1,2,4-Trichlorobenzene EANaphthalene Hexachloro-l,3-butadiene Dhogmde 4-Chloro-3-methylphenol me 2,4,6-Trichlorophenol a 2-Chloronaphthalene LoDimethylphthalate nim Acenaphthylene 2,6-Dinitrotoluene boAcenaphthene Et 2,4-Dinitrophenol Ty 4-Nitrophenol EL, 2,4-Dinitrotoluene an Diethylphthalate Lab Project Number: 1084665 II cn ir Client Project ID; E04-0120 CG Carbon System Test i er OEE is 5 Project Sample Number: 1084665-004 ll Matrix: Water Date Collected: 02/12/04 11:35 Date Received: 02/13/04 12:10 mon 8SmSer ei ifm Results _ Uni_ ts Report Limit Analyzed By CAS No. Qual RegLmt regis Lattin Prep/Method: / SM 5210B casnss ogi aHtm om i" 43 mg/l 6 02/18/04 JPHI 1,2 02/13/04 13:30 02/13/04 13:30 wigsimeisngWE Method: EPA 420.4 ND ug/l 02/17/04 VAF 108-95-2 ima tin Prep/Method: EPA 625 / EPA 625 Bin tmat Lie ws ND ug/l i0. 3 ob 5 Limam ~D ug/l i0. : 2 I mma ND ug/l 10. 2: ZF Jammu ND ug/l i0. Doom mane ND ug/l i0. EZ 5 Danes ND ug/l i0. BL RL ee ~D ug/l i0. 2 ZF Haan ~D ug/l i0. Doom on mma a ND ug/l i0. BT a ND ug/l i0. Doom on mma ND ug/l 10. 2 2 Deus ND ug/l 10. 2 3 Susndilen ~D ug/l 10. ND ug/l 10. I 3 5 mama ND ug/l 10. EZ ERE NB ug/l 10. NB ug/l i0. 3 IL mee ND ug/l i0. Doom on mma ND ug/l i0. EE Eo ~D ug/l i0. Doom amano ~D ug/l i0. Ea ~D ug/l i0. ~D ug/l i0. 2 2 Shade ND ug/l 10. iP = Zmmein ND ug/l 52. EI~D ug/l 52. 2 ZZ 5 Dummies ~D ug/l i0. 2 Zi ands ~D ug/l i0. 02/18/04 18:50 KSK 02/18/04 18:50 KSK 02/]8/04 18:50 KgE 02/18/04 18:50 KSK 02/18/04 18:50 KSK 02/18/04 18:50 KSK 02/18/04 18:50 KSK 02/18/04 18:50 KSK 02/18/04 18:50 KSK 02/18/04 18:50 KSK 02/18/04 18:50 KSK 02/18/04 18:50 KSK 02/18/04 18:50 KSK 02/18/04 18:50 KSK 02/18/04 18:50 KSK 02/18/04 18:50 KSK 02/18/04 18:50 KSK 02/18/04 18:50 KSK 02/18/04 18:50 KSK 02/18/04 18:50 KSK 02/18/04 18:50 KSK 02/18/04 18:50 KSK 02/18/04 18:50 KSK 02/18/04 18:50 KSK 02/18/04 18:50 KSK 02/18/04 18:50 KSK 02/18/04 18:50 KSK 02/18/04 18:50 KSK 108-95-2 ii1-44-4 95-57-8 541-73-1 106-46-7 95-50-1 39638-32-9 621-64-7 98-95-3 78-59-1 88-75-5 105-67-9 111-91-1 120-83-2 120-82-1 91-20-3 87-68-3 59-50-7 88-06-2 91-58-7 131-11-3 208-96-8 606-20-2 83-32-9 51-28-5 100-02-7 121-14-2 84-66-2 Date: 02/26/04 Page: i0 of 34 ionhelHaec: momen RREEPPOORRTTOOFFLLAABBOORRAATTOORRYY AANNAALLYYSSIISS 'This r'epn~ shall n~t I~ r~pro~u~, eept i. f~ll, without the written consent of Pace Analytical Services, Inc. EE -- en CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00004411 awissn 3M MN01538427 iceAAnnaallyyttiiccaall eto Pace Analytical Services, Inc. en 1700 Elm Slreet, Sm'te 200 Minneapolis, MN 55414 fri Id T Phone: 612.607,1700 Fax: 612.507.6444 oe Lab Sample No: 105333165 RW Client Sample ID: E04-0120-67438 SR aterapne Parameters ra 4 Chlorophenyiphenyl other oe Fluorene CEE gs 4,6-Dinitro-2-methylphenol fms 4-Bromophenylphenyl ether LarHexachlorobenzene bd Pentachlorophenol [oe Phenanthrene fea, Anthracene Di-n-butylphthalate frFluoranthene boPyrene En --_-- Butylbenzylphthalate Gpmewess 3,3'-Dichlorobenzidine DaBenzo(a)anthraeene i Chrysene is bls(2-Ethylhexyl)phthalate seDi-n-octylphthalate [a Benzo(h)fluoranthene re Benzo(k)fluoranthene es Benzo(a)pyrene Solow Indeno(l,2,3-cd)pyrene biDibenz(a,h)anthracene a Benzo(g,h,i)perylene feres Hexachloroethane ie in 818i8 Ier OrI EeEliliecsn i5 ErE Results pi ND 5 omen ND & TAM muna ~D 3 2 Bannan ~D Doom on aman ~D : 2 naa ND 2 2 br desde ~D 2B aang ND ~D 2 ZI & Handed ~D Doom no mma ~D Doom on aman ae rD EAM mame wen ND : 2 BE Zmmmnid ND 2: 2 PF UamEEE ~D BTA Mme meas ND PZ & Hawise ~D Doom mma wa ND PZ bE Fhwmmas ~D Doom on mma we ND fo mmimea ~D Doom on mmm ~D 2 2 Deus ~D IEo 2 Lui men ia ~D Lab Project Number: 1084665 Client Project ID; E04-0120 CG Carbon System Test Project Sample Number: 1084665-004 Matrix: Water Date Collected: 02/12/04 11:35 Date Received: 02/13/04 12:10 Units ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l Report Limit Analyzed By i0. 02/18/04 18:50 KSK i0. 02/18/04 18:50 KSK 52. 02/18/04 18:50 KSK i0. 02/18/04 18:50 KSK i0. 02/18/04 18:50 KSK 24. 02/18/04 18:50 KSK i0. 02/18/04 18:50 KSK i0. 02/18/04 18:50 KSK i0. 02/18/04 18:50 KSK i0. 02/18/04 18:50 KSK 10. 02/18/04 18:50 KSK i0. 02/18/04 18:50 KSK 21. 02/18/04 18:50 KSK 10. 02/]8/04 18:50 KgE i0. 02/18/04 18:50 KSK i0. 02/18/04 18:50 KSK i0. 02/18/04 18:50 KSK i0. 02/18/04 18:50 KSK i0. 02/18/04 18:50 KSK i0. 02/18/04 18:50 KSK i0. 02/18/04 18:50 KSK 10. 02/18/04 18:50 KSK 10. 02/18/04 18:50 KSK 10. 02/18/04 18:50 KSK CAS No. 7005 72 3 86 73 7 534-52-1 101-55-3 118-74-1 87-86-5 85-01-8 120-12-7 84-74-2 206-44-0 129-00-0 85-68-7 91-94-1 56-55-3 218-01-9 117-81-7 117-84-0 205-99-2 207-08-9 50-32-8 193-39-5 53-70-3 191-24-2 67-72-1 Qual RegLmt Nitrobenzene-d5 (S) 80 % 02/18/04 18:50 KSK 4165-60-0 2-Fluorobiphenyl (S) 86 % 02/18/04 18:50 KSK 321-60-8 ~erphenyl-dl4 (s) Phenol-d6 (S) amet 2-Fluorophenol (S) 2,4,6-Tribromophenol (S) a Date Extracted A GC/MS Volatiles EAI Volatile GC/MS by 624 rs Chloromethane ShVinyl chloride on es Bromomethane Sre e Chloroethane 82 % 0 % Co0 % 2 % a 02/16/04 wap Method: EPA 624 per ND ug/l 1.0 3 3 ~D ug/l 1.0 SA RL 4.8 ug/l 1.0 22 23B4 ND ug/l 1.0 02/18/04 18:50 KSK 1718-51-0 02/18/04 18:50 KSK 13127-88-3 3,4 SEALa eR 02/18/04 18:50 KSK 367-12-4 3,4 02/18/04 18:50 KSK 3,4 wn 02/16/04 mm fn 02/17/04 20:56 PNI unm 02/17/04 20:56 PN1 i TE pts 02/17/04 20:56 PNI mDmaimmabai 02/17/04 20:56 PNI 74-87-3 75-01-4 74-83-9 75-00-3 Trichlorofluoromethane ~D ug/l 1.0 02/17/04 20~56 PNI 75-69-4 Date: 02/26/04 Page: ii of 34 iS nelE ac: momen RREEPPOORRTT OOFF LLAABBOORRAATTOORRYY AANNAALLYYSSIISS 'Thi~ r'epn~ shall n~t I~ r~pro~u~, eept i. f~ll, without the written consent of Pace Analytical Services, Inc. EE -- en CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00004422 [pT 3M MN01538428 iceAAnnaallyyttiiccaall eto Pace Analytical Services, Inc. en 1700 Elm Slreet, Sm'te 200 Minneapolis, MN 55414 fri Id T Phone: 612.607,1700 Fax: 612.507.6444 oe i Ier OI EE icsn i5 r Lab Sample No: 105333165 RW ll Client Sample ID: E04-0120-67438 Sa erieg ion 858e pti lm fm Parameters Methylene chloride re FT amare I,i Dichloroethene Dame E Zn mmmnem ne trans-l,2-Dichloroethene Sn 2 Zi mma l,l-Dichloroethane Le Doom amano Chloroform ri ? 2 4 Haaenmam l,l,l-Trichloroethane Fn 2 ZB fanaa Carbon tetrachloride = Doom mmmnum Benzene er : ZB Hanah 1,2-Diehloroethane fn 2 ZW mmsenue Trichloroethene Fer Doom ama onen 1,2-Dichloropropane s meete EDI m ny mmmnumeloon Bromodichloromethane Results 4.4 ND ND ~D ~D ND ~D ND ~D ND ~D ~D Lab Project Number: 1084665 Client Project ID; E04-0120 CG Carbon System Test Project Sample Number: 1084665-004 Matrix: Water Date Collected: 02/12/04 11:35 Date Received: 02/13/04 12:10 Units ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l Report Limit Analyzed By 1.0 02/17/04 20:56 PNI 1.0 02/17/04 20:56 PNI 1.0 02/17/04 20:56 PNI 1.0 02/17/04 20:56 PNI 1.0 02/17/04 20:56 PNI 1.0 02/17/04 20:56 PNI 1.0 02/17/04 20:56 PNI 1.0 02/17/04 20:56 PNI 1.0 02/17/04 20:56 PNI 1.0 02/17/04 20:56 PNI 1.0 02/17/04 20:56 PNI 1.0 02/17/04 20:56 PNI CAS No. 75 09 2 75 35 4 156-60-5 75-34-3 67-66-3 71-55-6 56-23-5 71-43-2 107-06-2 79-01-6 78-87-5 75-27-4 Qual RegLmt trans-l,3-Dichloropropene ~D ug/l 1.0 02/17/04 20:56 PNI 10061-02-6 Toluene ND ug/l 1.0 cls-l,3-Diehloropropene ND ug/l 1.0 Sra Doom l,l,2-Trlchloroethane ND ug/l 1.0 Ti PZ i Tetrachloroethene ~D ug/l 1.0 fe Doom Dibromochloromethane ~D ug/l 1.0 in 2 Zi Chlorobenzene ~D ug/l 1.0 a oom Ethylbenzene ND ug/l 1.0 Sa PS Xylene (Total) ~D ug/l 3.0 ne Doom Bromoform ~D ug/l 1.0 mes 3 BO l,l,2,2-Tetrachloroethane ~D ug/l 1.0 Lp I 2 OB 1,3-Dichlorobenzene ~D ug/l 1.0 1,4-Dichlorobenzene ~D ug/l 1.0 ho 22 1,2-Dichlorobenzene ND ug/l 1.0 are 2 2B 2-chloroethylvinyl ether ~D ug/l 5.0 Soar 3 Dibromofluoromethane (S) 98 % Toluene-d8 (S) 83 % We wh 4-Bromofluorobenzene (S) 89 % Prtian 4 1,2-Dichloroethane-d4 (S! 88 % 02/17/04 20:56 PNI 02/17/04 20:56 PNI amma wen 02/17/04 20:56 PNI fmamenas 02/17/04 20:56 PNI mamma 02/17/04 20:56 PNI amen 02/17/04 20:56 PNI mum 02/17/04 20:56 PNI maaan 02/17/04 20:56 PNI mau ne 02/17/04 20:56 PNI pmmpie 02/17/04 20:56 PNI meena 02/17/04 20:56 PNI 02/17/04 20:56 PNI imams 02/17/04 20:56 PNI Iams 02/17/04 20:56 PNI Srata 02/17/04 20:56 PNI 02/17/04 20:56 PNI am 02/17/04 20:56 PNI SAAT va, 02/17/04 20:56 PNI i09-9~-3 10061-01-5 79-00-5 127-18-4 124-48-I 108-90-7 100-41-4 1330-20-7 75-25-2 79-34-5 541-73-I 106-46-7 95-50-1 110-75-8 1868-53-7 2037-26-5 460-00-4 17060-07-0 Date: 02/26/04 ionhelHaec: momen RR EPOE RTOP OFFLLAO ABBOORR RAATTOT ORRYY AANNAALLYYSSIISS 'Thi~ r'epn~ shall n~t I~ r~pro~u~, eept i. f~ll, without the written consent of Pace Analytical Services, Inc. EE -- en CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00004433 Page: 12 of 34 [pT 3M MN01538429 iceAAnnaallyyttiiccaall eto Pace Analytical Services, Inc. en 1700 Elm Slreet, Sm'te 200 Minneapolis, MN 55414 fri Id T Phone: 612.607,1700 Fax: 612.507.6444 oe Lab Sample No: 105333173 RW Client Sample ID: E04-0120-67435 iar Parameters Microbiology Tm ome 14 Biochemical Oxygen Demand, 5 d vein BOD, 5 day EEE Date Prepared -- Wet Chemistry SL, re Phenolies Total. in Water enPhenol SI GC/MS Semivolatiles OL 625 wastewater GC/MS SVOA eyPhenol Pr bis(2-Chloroethyl) ether So 2-Chlorophenol rm 1,3-Diehlorohenzene mee 1,4-Dichlorobenzene Filo 1,2-Dichlorobenzene nmr bls(2-Chloroisopropyl) ether fide N-Nitroso-di-n-propylamine Le Nitrobenzene ps Isophorone fe2-Nitrophenol 3 2,4-Dimethylphenol ile bis(2-Chloroethoxy)methane 2,4-Dichlorophenol jar. 1,2,4-Trichlorobenzene EANaphthalene Hexachloro-l,3-butadiene Dhogmde 4-Chloro-3-methylphenol 2,4,6-Trichlorophenol a 2-Chloronaphthalene LoDimethylphthalate nim Acenaphthylene 2,6-Dinitrotoluene boAcenaphthene Et 2,4-Dinitrophenol Ty 4-Nitrophenol EL, 2,4-Dinitrotoluene an Diethylphthalate Lab Project Number: 1084665 II cn ir Client Project ID; E04-0120 CG Carbon System Test i er OEE i is Project Sample Number: 1084665-005 al A Matrix: Water Date Collected: 02/12/04 ii:I0 Date Received: 02/13/04 12:10 mon 8SmSer ei ifm Results _ Uni_ ts Report Limit Analyzed By CAS No. Qual RegLmt regis Lattin Prep/Method: / SM 5210B casnss ogi aHtm om i" 43 mg/l 6 02/18/04 JPHI 1,2 02/13/04 13:30 02/13/04 13:30 wigsimeisngWE Method: EPA 420.4 ND ug/l 02/17/04 VAF 108-95-2 ima tin Prep/Method: EPA 625 / EPA 625 Binet mie ws ND ug/l i0. 3 ob 5 Luma ~D ug/l i0. PZ amie gh ND ug/l ]0. 2: 2 F Jammu ND ug/l i0. Doom mma ens ND ug/l i0. EZ 5 fiapes gs ND ug/l i0. BL EL ~D ug/l i0. 2 2 OF Dhani ~D ug/l i0. Doom on mmm a ND ug/l i0. PZ Ob Emmmagan ND ug/l i0. Doom on mma ND ug/l 10. 2 2 Dmpumus ND ug/l 10. 2 3 saan len ~D ug/l 10. ND ug/l 10. I 3 5 mmm ND ug/l 10. EZ EE NB ug/l 10. NB ug/l i0. 3 IL mages ND ug/l i0. ND ug/l i0. 2 Zk Haman ~D ug/l i0. Doom mwmawmoe ~D ug/l i0. 2 2B Sinan ~D ug/l i0. ~D ug/l i0. 2 2 F Shaadi ND ug/l 10. P = Zein ND ug/l 52. 22 FE ~D ug/l 52. 2 2 5 Dmmamies ~D ug/l i0. 2 Zi ee ~D ug/l i0. 02/18/04 19:44 KSK 02/18/04 19:44 KSK 02/18/04 19:44 K~E 02/18/04 19:44 KSK 02/18/04 19:44 KSK 02/18/04 19:44 KSK 02/18/04 19:44 KSK 02/18/04 19:44 KSK 02/18/04 19:44 KSK 02/18/04 19:44 KSK 02/18/04 19:44 KSK 02/18/04 19:44 KSK 02/18/04 19:44 KSK 02/18/04 19:44 KSK 02/18/04 19:44 KSK 02/18/04 19:44 KSK 02/18/04 19:44 KSK 02/18/04 19:44 KSK 02/18/04 19:44 KSK 02/18/04 19:44 KSK 02/18/04 19:44 KSK 02/18/04 19:44 KSK 02/18/04 19:44 KSK 02/18/04 19:44 KSK 02/18/04 19:44 KSK 02/18/04 19:44 KSK 02/18/04 19:44 KSK 02/18/04 19:44 KSK 108-95-2 ii1-44-4 95-57-8 541-73-1 106-46-7 95-50-1 39638-32-9 621-64-7 98-95-3 78-59-1 88-75-5 105-67-9 111-91-1 120-83-2 120-82-1 91-20-3 87-68-3 59-50-7 88-06-2 91-58-7 131-11-3 208-96-8 606-20-2 83-32-9 51-28-5 100-02-7 121-14-2 84-66-2 Date: 02/26/04 Page: 13 of 34 ionhelHaec: momen RREEPPOORRTTOOFFLLAABBOORRAATTOORRYY AANNAALLYYSSIISS 'Thi~ r'epn~ shall n~t I~ r~pro~u~, eept i. f~ll, without the written consent of Pace Analytical Services, Inc. EE -- en CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00004444 [pT 3M MN01538430 iceAAnnaallyyttiiccaall eto Pace Analytical Services, Inc. en 1700 Elm Slreet, Sm'te 200 Minneapolis, MN 55414 fri Id T Phone: 612.60Z 1700 Fax: 612.507.6444 oe i Ier OI EE icinsir Lab Sample No: 105333173 RW al A Client Sample ID: E04-0120-67435 SR tearageie in 8188 reie EE Parameters rag pr 4 Chlorophenyiphenyl other oe 5 oes Fluorene CEE gs & TAM muni ans 4,6-Dinitro-2-methylphenol ims 3 2 Bannan 4-Bromophenylphenyl ether Lar Doom on amuse Hexachlorobenzene bd ? 2 Danas Pentachlorophenol [oe 2 Zk eee Phenanthrene fea, 2B agin Anthracene Di-n-butylphthalate fr 2 2 & Hague Fluoranthene bo Doom no mumbo Pyrene En --_-- Doom on aman me Butylbenzylphthalate Gpmewess EAM mans wen 3,3'-Dichlorobenzidine Da P= EB Zaminad Benzo(a)anthraeene i 2: 2 PF UmmELE Chrysene is BTA Mmm meas hls(2-Ethylhexyl)phthalate se PZ b&b Haase Di-n-octylphthalate [a Doom mma wa Benzo(b)fluoranthene re 2: ZZ bE Hwan Benzo(k)fluoranthene es Doom on mmm we Benzo(a)pyrene Solow fo mamas Indeno(l,2,3-cd)pyrene bi Doom on mmm Dibenz(a,h)anthracene a 2 2 Dmpeael Benzo(g,h,i)perylene feres I=BL Duanbeel ia Hexachloroethane Results ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ~D ND ~D ND ND ~D ~D ~D Lab Project Number: 1084665 Client Project ID; E04-0120 CG Carbon System Test Project Sample Number: 1084665-005 Matrix: Water Date Collected: 02/12/04 ii:I0 Date Received: 02/13/04 12:10 Units ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l Report Limit Analyzed By i0. 02/18/04 19:44 KSK i0. 02/18/04 19:44 KSK 52. 02/18/04 19~44 KSK i0. 02/18/04 19:44 KSK i0. 02/18/04 19:44 KSK 24. 02/18/04 19:44 KSK i0. 02/18/04 19:44 KSK i0. 02/18/04 19:44 KSK i0. 02/18/04 19:44 KSK i0. 02/18/04 19:44 KSK i0. 02/18/04 19:44 KSK i0. 02/18/04 19:44 KSK 21. 02/18/04 19:44 KSK ]0. 02/]8/04 19:44 KgE i0. 02/18/04 19:44 KSK i0. 02/18/04 19:44 KSK i0. 02/18/04 19:44 KSK i0. 02/18/04 19:44 KSK i0. 02/18/04 19:44 KSK i0. 02/18/04 19:44 KSK i0. 02/18/04 19:44 KSK 10. 02/18/04 19:44 KSK 10. 02/18/04 19:44 KSK 10. 02/18/04 19:44 KSK CAS No. 7005 72 3 86 73 7 534-52-1 101-55-3 118-74-1 87-86-5 8~-01-8 120-12-7 84-74-2 206-44-0 129-00-0 85-68-7 91-94-1 56-55-3 218-01-9 117-81-7 117-84-0 205-99-2 207-08-9 50-32-8 193-39-5 53-70-3 191-24-2 67-72-1 Qual RegLmt Nitrobenzene-d5 (S) 78 % 02/18/04 19:44 KSK 4165-60-0 2-Fluorobiphenyl (S) 83 % 02/18/04 19:44 KSK 321-60-8 Terphenyl-dl4 (s) Phenol-d6 (S) amet 2-Fluorophenol (S) 2,4,6-Tribromophenol (S) a Date Extracted A GC/MS Volatiles EAI Volatile GC/MS by 624 rs Chloromethane ShVinyl chloride on es Bromomethane Sre e Chloroethane 81 % 1 % FE12 % 54 % san 02/16/04 wap Method: EPA 624 per ~D ug/l 1.0 3 3 ~D ug/l 1.0 SC BT 3.2 ug/l 1.0 e2 23B3 ND ug/l 1.0 02/18/04 19:44 KSK 1718-51-0 02/18/04 19:44 KSK 13127-88-3 3,4 SA ea 02/18/04 19:44 KSK 367-12-4 3,4 02/18/04 19:44 KSK wn 02/16/04 mmm 02/17/04 21:23 PNI Ummm 02/17/04 21:23 PN1 IR Ets 02/17/04 21:23 PNI Tmmiasahnay 02/17/04 21:23 PNI 74-87-3 75-01-4 74-83-9 75-00-3 Trichlorofluoromethane ~D ug/l 1.0 02/17/04 21~23 PNI 75-69-4 Date: 02/26/04 Page: 14 of 34 iS nelE ac: momen RREEPPOORRTT OOFF LLAABBOORRAATTOORRYY AANNAALLYYSSIISS 'This r'epn~ shall rio'( I~ r~pro~u~, eept i. f~ll, without the written consent of Pace Analytical Services, Inc. EE -- en CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00004455 pr 3M MN01538431 iceAAnnaallyyttiiccaall eto Pace Analytical Services, Inc. en 1700 Elm Slreet, Sm'te 200 Minneapolis, MN 55414 fri Id T Phone: 612.607,1700 Fax: 612.507.6444 oe i Ier OI EE icinsir Lab Sample No: 105333173 RW al A Client Sample ID: E04-0120-67435 Sag ion O81 e ti ls fm Parameters Methylene chloride re Fn are I,i Dichloroethene Dame E Zn mamma trans-l,2-Dichloroethene Sn 2 Zi mane l,l-Dichloroethane Le Doom mmmanmonn Chloroform ri : 2 4 fmaanmam l,l,l-Trichloroethane Fn 2 ZB dmeiange Carbon tetrachloride = oom amano Benzene er : ZB ama 1,2-Diehloroethane fn 2 ZW immianue Trichloroethene Fer Doom mamma 1,2-Dichloropropane s meete EDI m ny mmmnisms on Bromodichloromethane Results 4.6 ND ND ~D ~D ND ~D ND ~D ND ~D ~D Lab Project Number: 1084665 Client Project ID; E04-0120 CG Carbon System Test Project Sample Number: 1084665-005 Matrix: Water Date Collected: 02/12/04 ii:I0 Date Received: 02/13/04 12:10 Units ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l Report Limit Analyzed By 1.0 02/17/04 21:23 PNI 1.0 02/17/04 21:23 PNI 1.0 02/17/04 21:23 PNI 1.0 02/17/04 21:23 PNI 1.0 02/17/04 21:23 PNI 1.0 02/17/04 21:23 PNI 1.0 02/17/04 21:23 PNI 1.0 02/17/04 21:23 PNI 1.0 02/17/04 21:23 PNI 1.0 02/17/04 21:23 PNI 1.0 02/17/04 21:23 PNI 1.0 02/17/04 21:23 PNI CAS No. 75 09 2 75 35 4 156-60-5 75-34-3 67-66-3 71-55-6 56-23-5 71-43-2 107-06-2 79-01-6 78-87-5 75-27-4 Qual RegLmt trans-l,3-Dichloropropene ~D ug/l 1.0 02/17/04 21:23 PNI 10061-02-6 Toluene 4.0 ug/l 1.0 cls-l,3-Diehloropropene ND ug/l 1.0 Sra oom 1,1,2-Trlchloroethane ND ug/l 1.0 Ti PZ i Tetrachloroethene ~D ug/l 1.0 fe Doom Dibromochloromethane ~D ug/l 1.0 in 2 Zi Chlorohenzene ~D ug/l 1.0 a oom EthylSenzene ND ug/l 1.0 Sa PZ Bh Xylene (Total) ~D ug/l 3.0 ne Doom Bromoform ~D ug/l 1.0 mes 3 BO l,l,2,2-Tetrachloroethane ~D ug/l 1.0 Lp I 2 B 1,3-Dichlorobenzene ~D ug/l 1.0 1,4-Dichlorobenzene ~D ug/l 1.0 ho 22 1,2-Dichlorobenzene ND ug/l 1.0 are 2 2B 2-chloroethylvinyl ether ~D ug/l 5.0 oar 2} Dibromofluoromethane (S) i00 % Toluene-d8 (S) 90 % We nh 4-Bromofluorobenzene (S) 95 % mE SE 1,2-Dichloroethane-d4 (S! 93 % 02/17/04 21:23 PNI 02/17/04 21:23 PNI mane owen 02/17/04 21:23 PNI mamma 02/17/04 21:23 PNI mamma 02/17/04 21:23 PNI mamas 02/17/04 21:23 PNI mma 02/17/04 21:23 PNI aan 02/17/04 21:23 PNI mpmanm one 02/17/04 21:23 PNI mani 02/17/04 21:23 PNI gmeaania 02/17/04 21:23 PNI 02/17/04 21:23 PNI fanaa 02/17/04 21:23 PNI Zaman 02/17/04 21:23 PNI Seat 02/17/04 21:23 RNI 02/17/04 21:23 PNI pan m 02/17/04 21:23 PNI TAARAL Sa, 02/17/04 21:23 PNI 10061-01-5 79-00-5 127-18-4 124-48-I 108-90-7 100-41-4 1330-20-7 75-25-2 79-34-5 541-73-I 106-46-7 95-50-1 110-75-8 1868-53-7 2037-26-5 460-00-4 17060-07-0 Date: 02/26/04 ionhelHaec: momen RR EPOE RTOP OFFLLAO ABBOORR RAATTOT ORRYY AANNAALLYYSSIISS 'This r'epn~ shall n~'( I~ r~ro~u~, eept i. full, without the written consent of Pace Analytical Services, Inc. EE -- en CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00004466 Page: 15 of 34 aw isessz 3M MN01538432 iceAAnnaallyyttiiccaall eto Pace Analytical Services, Inc. en 1700 Elm Slreet, Sm'te 200 Minneapolis, MN 55414 fri Id T Phone: 612.607,1700 Fax: 612,507.6444 oe Lab Sample No: 105333181 Te Client Sample ID: E04-0120-67442 iar Parameters Microbiology mm 4 Biochemical Oxygen Demand, 5 d i BOD, 5 day EEE Date Prepared -- Wet Chemistry SL, re Phenolies Total. in Water enPhenol SI GC/MS Semivolatiles OL 625 wastewater GC/MS SVOA eyPhenol Pr bis(2-Chloroethyl) ether So 2-Chlorophenol rm 1,3-Diehlorohenzene mee 1,4-Dichlorobenzene Filo 1,2-Dichlorobenzene nmr bls(2-Chloroisopropyl) ether fide N-Nitroso-di-n-propylamine Le Nitrobenzene ps Isophorone fe2-Nitrophenol 3 2,4-Dimethylphenol ile bis(2-Chloroethoxy)methane 2,4-Dichlorophenol jar. 1,2,4-Trichlorobenzene EANaphthalene Hexachloro-l,3-butadiene Dhogmde 4-Chloro-3-methylphenol me 2,4,6-Trichlorophenol a 2-Chloronaphthalene LoDimethylphthalate nim Acenaphthylene 2,6-Dinitrotoluene boAcenaphthene Et 2,4-Dinitrophenol Ty 4-Nitrophenol EL, 2,4-Dinitrotoluene an Diethylphthalate Lab Project Number: 1084665 II cn ir Client Project ID; E04-0120 CG Carbon System Test i er OEE is Project Sample Number: 1084665-006 al Matrix: Water Date Collected: 02/12/04 12:00 Date Received: 02/13/04 12:10 mon 8SmSer ei ifm iE Results _ Uni_ ts Report Limit Analyzed By CAS No. Qual RegLmt epi Lattin Prep/Method: / SM 5210B cgs n ogi S rHtm om i" 24 mg/l 6 02/18/04 JPHI 1,2 02/13/04 13:30 02/13/04 13:30 wigsimeisngWE Method: EPA 420.4 ND ug/l 02/17/04 VAF 108-95-2 ima tin Prep/Method: EPA 625 / EPA 625 Dinas mie ws ND ug/l i0. 3 5 5 Limam ~D ug/l i0. P 2 I mag ND ug/l ]0. 2 2 OF Ummm ND ug/l i0. Doom mma ens ND ug/l i0. EZ 5 lanes ND ug/l i0. BL RL Se ~D ug/l i0. 2 2 OF Haan ~D ug/l i0. Doom on mma a ND ug/l i0. BE ar ND ug/l i0. Doom on mma ND ug/l 10. 2 2 Gmasus ND ug/l 10. 2 3 HEsugi len ~D ug/l 10. ND ug/l 10. I 3 5 mien ND ug/l 10. [OEEL NB ug/l 10. NB ug/l i0. 3 IL mamas ND ug/l i0. Doom on mma ND ug/l i0. 2: ZZ bk Umma ~D ug/l i0. Doom mma ~D ug/l i0. Ea ~D ug/l i0. ~D ug/l i0. 2 2 Shade ND ug/l 10. iP = Zmmein ND ug/l 51. EI lr ~D ug/l 51. 2 ZZ Ummm: ~D ug/l i0. 2 Zk ane ~D ug/l i0. 02/18/04 20:37 KSK 02/18/04 20:37 KSK 02/IS/04 20:37 KSK 02/IS/04 20:37 KSK 02/IS/04 20:37 KSK 02/18/04 20:37 KSK 02/18/04 20:37 KSK 02/18/04 20:37 KSK 02/18/04 20:37 KSK 02/18/04 20:37 KSK 02/18/04 20:37 KSK 02/18/04 20:37 KSK 02/18/04 20:37 KSK 02/18/04 20:37 KSK 02/18/04 20:37 KSK 02/18/04 20:37 KSK 02/18/04 20:37 KSK 02/18/04 20:37 KSK 02/18/04 20:37 KSK 02/18/04 20:37 KSK 02/18/04 20:37 KSK 02/18/04 20:37 KSK 02/18/04 20:37 KSK 02/18/04 20:37 KSK 02/18/04 20:37 KSK 02/18/04 20:37 KSK 02/18/04 20:37 KSK 02/18/04 20:37 KSK 108-95-2 ii1-44-4 95-57-~ 541-73-1 106-46-7 95-50-1 39638-32-9 621-64-7 98-95-3 78-59-1 88-75-5 105-67-9 111-91-1 120-83-2 120-82-1 91-20-3 87-68-3 59-50-7 88-06-2 91-58-7 131-11-3 208-96-8 606-20-2 83-32-9 51-28-5 100-02-7 121-14-2 84-66-2 Date: 02/26/04 Page: i~ of 34 ionhelHaec: momen RREEPPOORRTTOOFFLLAABBOORRAATTOORRYY AANNAALLYYSSIISS 'Thi~ r'ep(:,~ shall n~t I~ r~pro~u~. ~ept i. f~ll, without the written consent ~f Pac~ ,~naly'dcal Servi~e~, Inc. EE -- en CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00004477 aw isessa 3M MN01538433 iceAAnnaallyyttiiccaall eto Pace Analytical Services, Inc. en 1700 Elm Slreet, Sm'te 200 Minneapolis, MN 55414 fri Id T Phone: 612.607,1700 Fax: 612,507.6444 oe i Ier OI EE icsn ir Lab Sample No: 105333181 Te al Client Sample ID: E04-0120-67442 SR tearapeie in 8188 peie EE Parameters ra i 4 Chlorophenyiphenyl ether oe 5 mews Fluorene CEE gs & TAM muET nD 4,6-Dinitro-2-methylphenol ims 3 2 EF Bannan 4-Bromophenylphenyl ether Lar Doom on amu Hexachlorobenzene bd ? 2 Daan Pentachlorophenol [oe 2 ZB islam Phenanthrene fea, 2B amen Anthracene Di-n-butylphthalate fr 2 IZ & Hasamud Fluoranthene bo Doom no mwmnom ou Pyrene En --_-- Doom on mma ae Butylbenzylphthalate Spmewess EA mano wen 3,3'-Dichlorobenzidine Da : = I zmmnad Benzo(a)anthraeene i : 2 EF UmmEIE Chrysene is BTA mn nes bis(2-Ethylhexyl)phthalate se PZ b&b Hamme Di-n-octylphthalate [a Doom mma na Benzo(h)fluoranthene re PZ bE Hamma Benzo(k)fluoranthene es Doom on mma we Benzo(a)pyrene Solow fo mmatea Indeno(l,2,3-cd)pyrene bi Doom on mma Dibenz(a,h)anthracene a 2 2 Gnaeus Benzo(g,h,i)perylene feres I5 LansIe irias Hexachloroethane Results ND ND ~D ~D ~D ND ~D ND ~D ~D ~D rD ND ND ND ND ~D ND ~D ND ~D ~D ~D ~D Lab Project Number: 1084665 Client Project ID; E04-0120 CG Carbon System Test Project Sample Number: 1084665-006 Matrix: Water Date Collected: 02/12/04 12:00 Date Received: 02/13/04 12:10 Units ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l Report Limit Analyzed By i0. 02/18/04 20:37 KSK i0. 02/18/04 20:37 KSK 51. 02/18/04 20:37 KSK i0. 02/18/04 20:37 KSK i0. 02/18/04 20:37 KSK 23. 02/18/04 20:37 KSK i0. 02/18/04 20:37 KSK i0. 02/18/04 20:37 KSK i0. 02/18/04 20:37 KSK i0. 02/18/04 20:37 KSK i0. 02/18/04 20:37 KSK i0. 02/18/04 20:37 KSK 20. 02/18/04 20:37 KSK 10. 02/18/04 20:37 K~K i0. 02/18/04 20:37 KSK i0. 02/18/04 20:37 KSK i0. 02/18/04 20:37 KSK i0. 02/18/04 20:37 KSK i0. 02/18/04 20:37 KSK i0. 02/18/04 20:37 KSK i0. 02/18/04 20:37 KSK 10. 02/18/04 20:37 KSK 10. 02/18/04 20:37 KSK 10. 02/18/04 20:37 KSK CAS No. 7005 72 3 86 73 7 534-52-1 101-55-3 118-74-1 87-86-5 85-01-8 120-12-7 84-74-2 206-44-0 129-00-0 85-68-7 91-94-1 56-55-3 218-01-9 117-81-7 117-84-0 205-99-2 207-08-9 50-32-8 193-39-5 53-70-3 191-24-2 67-72-1 Qual RegLmt Nitrobenzene-d5 (S) 72 % 02/18/04 20:37 KSK 4165-60-0 2-Fluorobiphenyl (S) 76 % 02/18/04 20:37 KSK 321-60-8 ~erphenyl-dl4 (s) Phenol-d6 (S) amet 2-Fluorophenol (S) 2,4,6-Tribromophenol (S) a Date Extracted A GC/MS Volatiles EAI Volatile GC/MS by 624 rs Chloromethane ShVinyl chloride on es Bromomethane Se Chloroethane CAE Trichlorofluoromethane 82 % 30 % Lo40 % 64 % in 02/16/04 wap Method: EPA 624 per ND ug/l 1.0 EZ 3 ~D ug/l 1.0 Doom ~D ug/l 1.0 2: 2 4 ~D ug/l 1.0 SESEA ~D ug/l 1.0 02/18/04 20:37 KSK 1718-51-0 02/18/04 20:37 KSK 13127-88-3 3,4 SEAR 02/18/04 20:37 KSK 367-12-4 3,4 02/18/04 20:37 KSK wn 02/16/04 mn fn 02/17/04 21:51 PNI ummm 02/17/04 21:51 PNI amma one 02/17/04 21:51 PNI mana 02/17/04 21:51 PNI EL] 02/17/04 21~51 PNI 74-87-3 75-01-4 74-83-9 75-00-3 75-69-4 Date: 02/26/04 Page: 17 of 34 iS nelE ac: momen RREEPPOORRTT OOFF LLAABBOORRAATTOORRYY AANNAALLYYSSIISS 'Thi~ r'ep(:,~ shall n~t I~ r~pro~u~. ~ept i. f~ll, without th~ written consent ~f Pac~ ,~naly'dcal Servi~e~, Inc. EE -- en CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00004488 aw isesae 3M MN01538434 iceAAnnaallyyttiiccaall eto Pace Analytical Services, Inc. en 1700 Elm Slreet, Sm'te 200 Minneapolis, MN 55414 fri Id T Phone: 612.607,1700 Fax: 612.507.6444 oe i Ier OI EE icsn ir Lab Sample No: 105333181 Te al Client Sample ID: E04-0120-67442 Sa ieg ion O81 e pti lm fm Parameters me tcp te Sue Jak a 83 Methylene chloride re Pn ere I,i Dichloroethene Dame EZ um mamma trans-l,2-Dichloroethene Sn 2 Zi maaan l,l-Dichloroethane Le Doom mmmaam on Chloroform ri : 2 4 fmaanam l,l,l-Trichloroethane Fn 2 ZB fmeialge Carbon tetrachloride = Doom aman Benzene er : ZB amma 1,2-Diehloroethane fn 2 ZW mmnanue Trichloroethene Fer Doom amanm oe 1,2-Dichloropropane se EI is Bromodichloromethane mete Dm ny mmmnam on trans-l,3-Dichloropropene Results ND ND ~D ~D ~D ND ~D ND ND ~D ~D ~D ~D Lab Project Number: 1084665 Client Project ID; E04-0120 CG Carbon System Test Project Sample Number: 1084665-006 Matrix: Water Date Collected: 02/12/04 12:00 Date Received: 02/13/04 12:10 Units ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l us/l ug/l ug/l Report Limit Analyzed By 1.0 02/17/04 21:51 PNI 1.0 02/17/04 21:51 PNI 1.0 02/17/04 21:51 PNI 1.0 02/17/04 21:51 PNI 1.0 02/17/04 21:51 PNI 1.0 02/17/04 21:51 PNI 1.0 02/17/04 21:51 DNI 1.0 02/17/04 21:51 PNI 1.0 02/17/04 21:51 PNI 1.0 02/17/04 21:51 PNI 1.0 02/17/04 21:51 PNI 1.0 02/17/04 21:51 PNI 1.0 02/17/04 21:51 PNI CAS No. 75 09 2 75 35 4 156-60-5 75-34-3 67-66-3 71-55-6 56-23-5 71-43-2 107-06-2 79-01-6 78-87-5 75-27-4 10061-02-6 Qual RegLmt Toluene ND ug/l ~.0 cls-l,3-Diehloropropene ND ug/l 1.0 Sra Doom l,l,2-Trlchloroethane ND ug/l 1.0 Ti PZ i Tetrachloroethene ~D ug/l 1.0 fe Doom Dibromochloromethane ~D ug/l 1.0 in 2 Zi Chlorobenzene ~D ug/l 1.0 a oom Ethylbenzene ND ug/l 1.0 Sa PZ Bh Xylene (Total) ~D ug/l 3.0 ne Doom Bromoform ~D ug/l 1.0 mes 3 BO l,l,2,2-Tetrachloroethane ~D ug/l 1.0 Lp I 2 1,3-Dichlorobenzene ND ug/l 1.0 1,4-Dichlorobenzene ~D ug/l 1.0 ho 2 Zi 1,2-Dichlorobenzene ND ug/l 1.0 are 2 2B 2-chloroethylvinyl ether ~D ug/l 5.0 mid Dibromofluoromethane (S) 95 Toluene-d8 (S) 81 We nh 4-Bromofluorobenzene (S) 85 Prtian 2 1,2-Dichloroethane-d4 (S! 92 02/17/04 21:51 PNI 02/17/04 21:51 PNI aman wen 02/17/04 21:51 PN1 fmawmnas 02/17/04 21:51 PN1 mane oman 02/17/04 21:51 PNI mamas 02/17/04 21:51 PNI mma 02/17/04 21:51 PNI aaa 82/17/04 21:51 PNI mpmanm one 02/17/04 21:51 PNI mane 02/17/04 21:51 PNI gman 02/17/04 21:51 PNI 02/17/04 21:51 PNI maaan 02/17/04 21:51 PNI Jamas 02/17/04 21:51 PNI Sratam 02/17/04 21:51 PNI 02/17/04 21:51 PN1 nm 02/17/04 21:51 PNI SaAnAL Sa, 02/17/04 21:51 PNI i09-9~-3 10061-01-5 79-00-5 127-18-4 124-48-I 108-90-7 100-41-4 1330-20-7 75-25-2 79-34-5 541-73-1 106-46-7 95-50-1 110-75-8 1868-53-7 2037-26-5 460-00-4 17060-07-0 Date: 02/26/04 ionhelHaec: momen RR EPOE RTOP OFFLLAO ABBOORR RAATTOT ORRYY AANNAALLYYSSIISS 'Thi~ r'epn~ shall n~t I~ r~pro~u~, eept i. f~ll, without the written consent of Pace Analytical Services, Inc. EE -- en CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00004499 Page: 18 of 34 [pr 3M MN01538435 iceAAnnaallyyttiiccaall eto Pace Analytical Services, Inc. en 1700 Elm Slreet, Sm'te 200 Minneapolis, MN 55414 fri Id T Phone: 612.607,1700 Fax: 612.507.6444 Lab Project Number: 1084665 II cn ir Client Project ID; E04-0120 CG Carbon System Test oe i er OE i is 5 Lab Sample No: 105333199 TE en dl Client Sample ID: E04-0120-67487 Field Blank Project Sample Number: 1084665-007 Matrix: Water Date Collected: 02/12/04 00:00 Date Received: 02/13/04 12:10 iamon n 85Smer o Sei w n Parameters Microbiology Results _ Uni_ ts Report Limit Analyzed By CAS No. mm 4 ero Lattin Biochemical Oxygen Demand, 5 d Prep/Method: / SM 5210B EiEE cI r Hm em . BeD, 5 day 7 m9/l 6 02/18/04 JPHI Qual RegLmt 1 Date Prepared -- Wet Chemistry SL, re wigs ming Phenolics Total. in Water en iesWE Phenol -- GC/MS Volatiles tu SON Volatile GC/MS by 624 ry Ris Chloromethane Gn own mmm Vinyl chloride Soe PZ 3 mia Bromomethane Chloroethane SE Bm mmm ne Trichlerofluoromethane e isie E DoZ om i fmamamsnsuemn oe: Methylene chloride 02/13/04 13:30 Method: EPA 420.4 ND ug/l Method: EPA 624 ND ug/l ~D ug/l ND ug/l ND ug/l ND ug/l ND ug/l 02/13/04 13:30 25.0 02/17/04 VAF 108-95-2 1.0 02/17/04 17:56 PNI 74-87-3 1.0 02/17/04 17:56 PNI 75-01-4 1.0 02/17/04 17:56 PNI 74-~3-9 1.0 02/17/04 17:56 PN1 75-00-3 1.0 02/17/04 17:56 PN1 75-69-4 1.0 02/17/04 17:56 PNI 75-09-2 l,l-Dichloroethene ND ug/l 1.0 02/17/04 17:56 PNI 75-35-4 trans-l,2-Dichloroethene l,l-Dichloroethane Ls Chloroform nen l,l,l-Trichloroethane =ama Carbon tetrachloride ND ug/l 1.0 ND ug/l 1.0 PZ ND ug/l 1.0 Doom ND ug/l 1.0 2 I 5 HH ND ug/l 1.0 02/17/04 17:56 PNI 02/17/04 17:56 PNI Eanes 02/17/04 17:56 PNI mma 02/17/04 17:56 PNI L pme aan eni as 02/17/04 17:56 PNI 156-60-5 75-34-3 67-66-3 71-55-6 56-23-5 Benzene ND ug/l 1.0 02/17/04 17:56 PNI 71-43-2 1,2-Dichloroethane Trichloroethene prac1,2-Dichloropropane i, Bromodichloromethane trans-l,3-Dichloropropene Ls Toluene loa cis-l,3-Dichloropropene Shl,l,2-Trichloroethane nin Tetraehloroethene LR, Dibromochloromethane in Chlorobenzene iy Ethylbenzene a Xylene (Total) Fs Bromoform Ei mae l,l,2,2-Tetrachloroethane ND ug/l ND ug/l ERT: NR He vk ats ND ug/l 2 2 1 nana: ~D ug/l ND ug/l Doom mma es ND ug/l 2 Dmenuen ND ug/l SIT NE Hc os 3s ND ug/l 2 = 2 Zambia ND ug/l PE = imam ND ug/l 2 2 i] mpm ND ug/l i = 3 ZEmngh ND ug/l Een ND ug/l 2 2 0 mene ~D ug/l 2 3B Zmimbss ~D ug/l 1.0 02/17/04 17:56 PNI 107-06-2 1.0 02/17/04 17:56 PNI 79-01-6 1.0 02/17/04 17:56 PNI 78-87-5 1.0 02/17/04 17:56 PNI 75-27-4 1.0 02/17/04 17:56 PN1 10061-02-6 1.0 02/17/04 17:56 PNI 108-88-3 1.0 02/17/04 17:56 PNI 10061-01-5 1.0 02/17/04 17:56 PNI 79-00-5 1.0 02/17/04 17:56 PNI 127-18-4 1.0 02/17/04 17:56 PNI 124-48-1 1.0 02/17/04 17:56 PNI 108-90-7 1.0 02/17/04 17:56 PN1 100-41-4 3.0 02/17/04 17:56 PNI 1330-20-7 1.0 02/17/04 17:56 PNI 75-25-2 1.0 02/17/04 17~56 PNI 79-34-5 Date: 02/26/04 Page: 19 of 34 ionhelHaec: momen RR EPOE RTOP OFFLLAO ABBOORR RAATTOT ORRYY AANNAALLYYSSIISS 'Thi~ r'epn~ shall n~t I~ r~pro~u~, eept i. f~ll, without the written consent of Pace Analytical Services, Inc. EE -- en CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00005500 aw isescs 3M MN01538436 aceAAnnaallyyttiiccaall eto Pace Analytical Services, Inc. 1700 Elm Slreet, Sm'te 200 Ee Minneapolis, MN 55414 IT Phone: 612.607,1700 Fax: 612.507.6444 oe i Ier OIE icins 5 Lab Sample No: 105333199 I rw rman dl Client Sample ID: E04-0120-67487 Field Blank IO Parameters Er le ets pat 1,3 Dichlorobenzene pn PZ amen 1,4 Dichlorobenzene me Doom Emma 1,2-Dichlorobenzene Iai 1 2 2 Homme 2-Chloroethylvinyl ether men ann nen Dibromofluoromethane (S) Toluene-d8 (S) te, } Eats 4-Bromofluorobenzene (S) Results ND ND ~D ~D 94 77 81 Lab Project Number: 1084665 Client Project ID; E04-0120 CG Carbon System Test Project Sample Number: 1084665-007 Matrix: Water Date Collected: 02/12/04 00:00 Date Received: 02/13/04 12:10 _ Uni_ ts Report Limit Analyzed By ug/l 1.0 02/17/04 17:56 ug/l 1.0 02/17/04 17:56 ug/l 1.0 02/17/04 17:56 ug/l 5.0 02/17/04 17:56 PNI % 02/17/04 17:56 % 02/17/04 17:56 02/17/04 17:56 PNI CAS No. 541 73 1 106 46 7 95-50-1 110-75-8 1868-53-7 2037-26-5 460-00-4 Qual RegLmt 1,2-Diehloroethane-d4 (Si 90 02/17/04 17:56 PNI 17060-07-0 Date: 02/26/04 ionhelAtaec,: momen RREEPPOORRTTOOFFLLAABBOORRAATTOORRYY AANNAALLYYSSIISS 'This r'epn~ shall rio'( I~e r~pro~uce~, eept i. f~ll, without the written consent of Pace Analytical Services, Inc. EE -- en CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00005511 Page: 20 of 34 awiss 3M MN01538437 iceAAnnaallyyttiiccaall eto Pace Analytical Services, Inc. en 1700 Elm Slreet, Sm'te 200 Minneapolis, MN 55414 fri Id T Phone: 612.607,1700 Fax: 612.507.6444 Lab Project Number: 1084665 II cn ir Client Project ID; E04-0120 CG Carbon System Test oe i er OE is 5 Lab Sample No: 105333421 sw ll Client Sample ID: E04-0120-67489 Travel Blank Project Sample Number: 1084665-008 Matrix: Water Date Collected: 02/12/04 00:00 Date Received: 02/13/04 12:10 Hag mon 85Sa mer Seiin fm Parameters te GC/MS Volatiles aw wpm Volatile GC/MS by 624 se mnie So mimi wy Chloromethane Sn, YZ mpm Vinyl chloride on cs Doom mmmnam oe Bromomethane Te 2 2 4 Hwan Chloroethane Sma 2 2 0 manag Trichlorofluoromethane [Er = iB mansE Methylene chloride Sa : Z # Imwanad l,l-Diehloroethene mee 3 ZU mmneou trans-l,2-Dichloroethene a: BT l,l-Dichloroethane Gh EE aes Chloroform en Doom mmmnam ow l,l,l-Trichloroethane Sm PZ 5 amiin Carbon tetrachlor~de om 2 2 5 Emma Benzene nen Doom mame 1,2-Diehloroethane Trichloroethene [Ere Doom mmmnam oe 1,2-Dichloropropane sn 2 ZB maine: Bromodichloromethane mente LP mn mmmnamon trans-l,3-Dichloropropene fr PZ 3 Hanan as Toluene Sate. BZ 5 Enel cis-l,3-Dichloropropene Boni 25 4 Liane l,l,2-Trichloroethane Hip I 2 3B gman Tetrachloroethene fr Doom amano Dibromochloromethane a 2 Zi manana Chlorobenzene Sm ERT:I HC al Ethylbenzene Xylene (Total) ne 2 THis as Bromoform l,l,2,2-Tetrachloroethane i 2 2 1 Hannes 1,3-Dichlorobenzene mse Doom mano 1,4-Dichlorobenzene Jes 2 = i Harn 1,2-Dichlorobenzene meer 1 2B Hamel, 2-Chloroethylvinyl ether one 3 7 Si Dibromofluoromethane (S) Results _ Uni_ ts Report Limit Analyzed By CAS No. Method: EPA 624 ND ug/l ND ug/l ~D ug/l ND ug/l ND ug/l ~D ug/l ~D ug/l ~D ug/l ~D ug/l ND ug/l ~D ug/l ND ug/l ND ug/l ND ug/l ND ug/l ~D ug/l ~D ug/l ~D ug/l ~D ug/l ~D ug/l ND ug/l ~D ug/l ~D ug/l ~D ug/l ~D ug/l ND ug/l ~D ug/l ~D ug/l ~D ug/l ~D ug/l ND ug/l ND ug/l 96 1.0 02/17/04 17:28 PNI 74-87-3 1.0 02/17/04 17:28 PNI 75-01-4 1.0 02/17/04 17:28 PNI 74-83-9 1.0 02/17/04 17:28 PNI 75-00-3 1.0 02/17/04 17:28 PNI 75-69-4 1.0 02/17/04 17:28 PNI 75-09-2 1.0 02/17/04 17:28 PNI 75-35-4 1.0 02/17/04 17:28 PNI 156-60-5 1.0 02/17/04 17:28 PNI 75-34-3 1.0 02/17/04 17:28 PNI 67-66-3 1.0 02/17/04 17:28 PNI 71-55-6 1.0 02/17/04 17:28 PNI ~6-23-5 1.0 02/17/04 17:28 PN1 71-43-2 1.0 02/17/04 17:28 PNI 107-06-2 1.0 02/17/04 17:28 PN1 79-01-6 1.0 02/17/04 17:28 PNI 78-87-5 1.0 02/17/04 17:28 PNI 75-27-4 1.0 02/17/04 17:28 PNI 10061-02-6 1.0 02/17/04 17:28 PNI 108-88-3 1.0 02/17/04 17:28 PNI 10061-01-5 1.0 02/17/04 17:28 PNI 79-00-5 1.0 02/17/04 17:28 PNI 127-18-4 1.0 02/17/04 17:28 PNI 124-48-1 1.0 02/17/04 17:28 PNI 108-90-7 1.0 02/17/04 17:28 PNI 100-41-4 3.0 02/17/04 17:28 PNI 1330-20-7 1.0 02/17/04 17:28 PNI 75-25-2 1.0 02/17/04 17:28 PNI 79-34-5 1.0 02/17/04 17:28 PNI 541-73-1 1.0 02/17/04 17:28 PNI 106-46-7 1.0 02/17/04 17:28 PNI 95-50-1 5.0 02/17/04 17:28 PNI 110-75-8 02/17/04 17:28 PNI 1868-53-7 Qual RegLmt SE I Toluene-d8 (S) 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (Si 77 % 82 89 Sravan di, 02/17/04 17:28 PN1 02/17/04 17:28 PNI 02/17/04 17:28 PNI 2037-26-5 460-00-4 17060-07-0 Date: 02/26/04 Page: 21 of 34 ionhelHaec: momen RR EPOE RTOP OFFLLAO ABBOORR RAATTOT ORRYY AANNAALLYYSSIISS 'Thi~ r'ep(:,~ shall n~t I~ r~pro~u~. ~ept i. f~ll, without th~ written consent ~f Pac~ ,~naly'~ical Servi~e~, Inc. EE -- en CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00005522 aw isesce 3M MN01538438 aceAAnnaallyyttiiccaall esteon, Pace Analytical Services, Inc. 1700 Elm Slreet, Sm'te 200 howe: 6126a071700 Minneapolis, MN 55414 Phone: 612.607,1700 Fax: 612.507.6444 Lab Project Number: 1084665 BLIIR Hs woman Client Project ID; E04-0120 CG Carbon System Test ET PARAMETER FOOTNOTES J . ND Not detected at or above adjusted reporting limit NC Not Calculable ee he posh id ton ts sk ee he id i J Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit I Deters MDL Adjusted Method Detection Limit Sa Surrogate Bs sr st titeson oat svt a rine Sinn smite Ill The BOD dilution blank QC criterion was not met. Acceptable method performance is based upon the remaining mr batch QC. UE [2] The analysis was initiated more than 24 hours but less than 48 hours after collection. E BESedo itn et Confirmed by second analysis and/or re-extraction. [4] The surrogate recovery was outside QC acceptance limits due to matrix interference. Date: 02/26/04 ionhelAtaec,: momen RREEPPOORRTTOOFFLLAABBOORRAATTOORRYY AANNAALLYYSSIISS 'This r'epn~ shall rio'( I~ r~pro~u~, eept i. f~ll, without the written consent of Pace Analytical Services, Inc. CSONEFIDE-NSTUBIIAECLT T0 A PROTECTIVE OROER ENTERED CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00005533 Page: 22 of 34 au orsseass 3M MN01538439 iceAAnnaallyyttiiccaall eto Pace Analytical Services, Inc. en 1700 Elm Slreet, Sm'te 200 Minneapolis, MN 55414 fri Id T Phone: 612.607,1700 Fax: 612.507.6444 QQUUAALLIITTYY CCOONNTTRROOLL DDAATTAA rm R AAAE I TE rm QC Batch: 104174 Si eh QC Batch Method: EPA 625 Lab Project Number; 1084665 Client Project ID: E04-0120 CG Carbon System Test Analysis Method: EPA 625 Analysis Description: 625 Wastewater GC/MS SVOA Associated Lab Samples: 105333132 105333140 105333157 105333165 105333173 105333181 METHOD BLANK: 105336473 Associated Lab Samples: pen hJ eh , Parameter pa es S3e g=h 5 Phenol 105333132 Units us/l 105333140 105333157 105333165 Blank Result ND Reporting Limit Footnotes i0. niepwo.d bis(2-Chloroethyl) ether us/l 2-Chlorophenol ug/l 1,3-Dichlorobenzene ug/l 1,4-Dichlorobenzene ug/l 2SEJND 10. ND i0. ND i0. ND 10. bb1il,se2(i-2aD--iCCchhhlilooorrroooithseeoonppzrreoonppeyyll)) eetthheerr nemo N-Nitroso-di-n-propylamine Le Nitrobenzene fie Isophorone tl 2-Nitrophenol St 2,4-Dimethylphenol HE bis(2-Chloroethoxy)methane J 2,4-Dichlorophenol uuugss///lll NNDD 1i1000..0 worn ug/l ND i0. FOug/l ND i0. 2 =: = ug/l ND i0. EAug/l ND i0. EAug/l ND 10. WL OX ug/l ND i0. worn ug/l ND i0. 1,2,4-Trichlorobenzene ug/l ND i0. Sianaty Naphthalene Nexachloro-l,3-butadiene 4-Chloro-3-methylphenol EEE ug/l ND i0. ug/l ND i0. ug/l ND i0. 2,4,6-Trichlorophenol ug/l ND i0. 2-Chloronaphthalene ug/l ND i0. I woe Dimethylphthalate ug/l ND i0. Sa EE Acenaphthylene ug/l ND i0. 2,6-Dinitrotoluene ug/l ND i0. Tr EA Acenaphthene ug/l ND i0. 2,4-Dinitrophenol ug/l ND 50. 4-Nitrophenol ug/l ND 50. Lee ee 2FE 2 1 2,4-Dinitrotoluene ug/l ND i0. Diethyiphthalate us/l ND i0. 4-Chlorophenylphenyl ether us/l ND i0. Fluorene us/l ND i0. 105333173 105333181 Date: 02/26/04 Page: 23 of 34 ionhelAtaec,: momen RREEPPOORRTTOOFFLLAABBOORRAATTOORRYY AANNAALLYYSSIISS 'This r'epn~ shall rio'( I~ r~pro~ucs~, eept i. f~ll, without the written consent of Pace Analytical Services, Inc. EE -- en CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00005544 [pT 3M MN01538440 iceAAnnaallyyttiiccaall eto Pace Analytical Services, Inc. en 1700 Elm Slreet, Sm'te 200 Minneapolis, MN 55414 RaIi nTd Phone: 612.60Z 1700 Fax: 612.507.6444 QQUUAALLIITTYY CCOONNTTRROOLL DDAATTAA METHOD BLANK: eT 105336473 RE Lab Project Number; 1084665 AAAI TE rm -- Client Project ID: E04-0120 CG Carbon System Test Associated Lab Samples: 105333132 donne bdaet StorEtion pe Parameter mmm 4,6-Dinitro-2-methylphenol DT 4-Bromophenylphenyl ether Site EE Hexachlorobenzene a RE Pentachlorophenol fe woe ow Phsnanthrene oy 2 3: = Anthracene Pres = 2 I Di-n-butylphthalate er EE Fluoranthene foWOEmoorSE Pyrene Units ug/l ug/l ug/l us/l us/l us/l us/l us/l ug/l 105333140 105333157 105333165 Blank Result HD HD ND ND ND ND ND HD ND Reporting Limit 50. 10. i0. 23. 10. 10, 10, 10. Footnotes 105333173 105333181 Butylbenzylphthalate ug/l ND 3,3'-Dichlorobenzid~ne ug/l ND 20. ChBCrehnryzyssose(nnaee)anthracene uugg//ll ug/l NNwDD 111000..0 She 3 L bls(2-Ethylhexyl)phthalate ug/l ND 10. Di-n-octylphthalate ug/l ND 10. dene 2 i Benzo(b)fluoranthene ug/l ND 10. aaI NE BA Benzo(k)fluoranthene ug/l ND i0. oe EA Benzo(a)pyrene ug/l ND i0. EEC Indeno(l,2,3-d)pyrene ug/l ND idl SEE Dibenz(a,h)anthracene ug/l ND i0. Benzo(g,h,i)perylene ug/l HD 10. a wor Hexachloroethane ug/l ND 10. Nitrobenzene-d5 (S) % 7O memmesd x 2-Fluorobiphenyl (S) % 7O mn : : Terphenyl-dl4 (S) % 82 Phenol-d6 (S) % 74 Lt : i 2-Fluorophenol (S) % 68 2,4,6-Tribromophenol (S) % 76 LABORATORY CONTROL SAMPLE a LCSD: 105336481 RN. Parameter Phenol LS bis(2-Chloroethyl) ether Units us/l us/l 105336499 JIE Spike EW A... Cone. 50.00 A HE 50.00 LCS Result 44.51 42.92 LCSD Result 43.62 41.50 LCS % Rec 89 86 LCSD % Rec 87 83 OGY RPD Footnotes 2 3 Date: 02/26/04 Page: 24 of 34 ionhelAtaec,: momen RREEPPOORRTTOOFFLLAABBOORRAATTOORRYY AANNAALLYYSSIISS 'This r'epn~ shall n~t I~ r~pro~ucs~, eept i. f~ll, without the written consent of Pace Analytical Services, Inc. EE -- en CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00005555 pr 3M MN01538441 ceAAnnaallyyttiiccaall eto Pace Analytical Services, Inc. 1700 Elm Slreet, Sm'te 200 Ee Minneapolis, MN 55414 eIn 2T60 Phone: 612.607,1700 Fax: 612.507.6444 QQUUAALLIITTYY CCOONNTTRROOLL DDAATTAA ----------------------R A--A--AE I--T--E --r--m ---- LABORATORY CONTROL SAMPLE & LCSD: 105336481 105336499 pew S I S EE Parameter Units Spike Cone. LCS Result Lab Project Number; 1084665 Client Project ID: E04-0120 CG Carbon System Test LCSD Result LCS LCSD % Rec % Rec RPD Footnotes 2-Chlorophenol us/l 50.00 43.30 42.40 87 85 2 i Jee ae OIF 1,3-Dichlorobenzene ug/l 1,4-Dichlorobenzene ug/l 1,2-Dichlorobenzene ug/l bis(2-Chloroisopropyl) ether us/l 2m3aBmE 2d2d 4SRwSs 50.00 50.00 50.00 50.00 41.85 41.72 42.26 44.73 41.17 41.70 42.22 43.50 84 82 2 83 83 0 84 84 0 90 87 3 N-Nitroso-di-n-propylamine us/l 50.00 46.61 46.27 93 92 1 Nitrobenzene us/l 50.00 46.55 45.49 93 91 2 Isophorone us/l 50.00 48.73 48.99 98 98 1 meee SE 2-Nitrophenol us/l 2,4-Dimethylphenol ug/l bis(2-Chloroethoxy)methane ug/l ue owewwoou 50.00 43.40 43.28 87 50.00 18.67 18.16 37 50.00 45.03 44.97 90 oy87 0 36 3 I,i 90 0 2,4-Diehlorophenol ug/l 50.00 43.42 43.86 87 8~ ~ N1aa,gp2hh,tt4hh-aaTllreeinneeshlorobenzene wuga/nl us/l S500.000 4413..8306 50.00 43.36 a4421..n7635 8874 88o36w a0I Nexachloro-l,3-butadlene ug/l 50.00 42.96 42.99 86 86 0 4-Chloro-3-meth1phenol us/l 50.00 46.79 47.76 94 96 2 2,4,6-Trichlorophenol ug/l 50.00 46.49 47.47 93 95 2 2-Chloronaphthalene ug/l 50.00 45.85 47.41 92 95 3 ie Dimethylphthalate Acenaphthylene 2,6-Dinitrotoluene EE EE ug/l 50.00 47.65 49.11 95 98 3 ug/l 50.00 47.25 48.15 94 96 2 ug/l 50.00 48.24 50.00 96 100 4 Acenaphthene ug/l 50.00 47.86 49.82 96 100 4 2,4-Dinitrophenol ug/l 50.00 39.41 42.95 79 86 9 4-Nitrophenol ug/l 50.00 49.84 53.46 I00 107 7 2,4-Dinitrotoluene Diethylphthalate on 4-Chlorophenylphenyl ether Fluorene ooSRE 4,6-Dinitro-2-methylphenol a Goma 4-Bromophenylphenyl ether ug/l 50.00 45.78 48.47 ug/l 50.00 47.00 49.60 2 SE Zw ah ug/l 50.00 48.08 49.60 ug/l 50.00 48.55 49.28 SEE ug/l 50.00 41.56 44.83 = wi ue e wdoan ug/l 50.00 49.14 50.69 du 92 97 6 94 99 5 96 99 3 AnoEn 97 99 83 90 98 I01 1 8 3 es Hexachlorobenzene Pentachlorophenol Phenanthrene ome aw memo us/l 50.00 50.68 51.77 I01 104 2 ug/l 50.00 44.50 47.08 89 94 6 ug/l 50.00 47.10 48.77 94 98 3 ion Anthracene Di-n-butylphthalate Flucranthene EE ug/l 50.00 46.95 47.99 94 96 2 us/l 50.00 50.27 52.64 I01 105 5 us/l 50.00 49.15 50.52 98 I01 3 Pyrene us/l 50.00 46.16 48.33 92 97 5 Date: 02/26/04 Page: 25 of 34 ionhelAtaec,: momen RREEPPOORRTTOOFFLLAABBOORRAATTOORRYY AANNAALLYYSSIISS 'This r'epn~ shall n~t I~ r~pro~ucs~, eept i. f~ll, without the written consent of Pace Analytical Services, Inc. EE -- en CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00005566 awissue 3M MN01538442 iceAAnnaallyyttiiccaall ee tn o Pace Analvtical Services, Inc. 1700 Elm Slreet, Sm'te 200 1neI2601T170 Minneapolis, MIV 55414 Phone: 612.607~ 1700 Fax: 612.507.6444 QQUUAALLIITTYY CCOONNTTRROOLL DDAATTAA ----------------------R A--A--AE I--T--E --r--m ---- LABORATORY CONTROL SAMPLE & LCSD: 105336481 105336499 Lab Project Number; 1084665 Client Project ID: E04-0120 CG Carbon System Test pew SS EE Parameter Se a se Butylbenzylphthalate 3,3'-Diehlorobenzidine Lon TD ES SE Benzo(a)anthracene Units us/l ug/l ug/l Spike Cone. 50.00 50.00 50.00 LCS Result 46.97 28.52 46.75 LCSD Result 49.55 27.96 48.79 LCS LCSD % Rec % Rec RPD 94 99 5 57 56 2 94 98 4 Footnotes Chrysene ug/l 50.00 46.74 48.59 94 97 4 bis(2-Ethylhexyl)phthalata us/l 50.00 48.30 ~0.60 97 I01 ~ Di-n-octylphthalate us/l 50.00 46.77 48.56 94 97 4 Benzo(b)fluoranthene Benzo(k) fluoranthene an Benzo(a)pyrene r melmlesm Indeno(l,2,3-cd)pyrene u~/l 50.00 46.65 us/l 50.00 46.69 moonw ode us/l 50.00 44.97 wn uoeo apqa ug/l 50.00 47.06 47.97 48.58 owmon on 46.46 sownodoap 49.14 93 96 93 97 90 93 94 98 3 4 3 4 Dibenz(a,h)anthracene ug/l 50.00 47.28 49.54 95 99 5 Ben~o(g,h,~)perylene u~/l 50.00 47.30 49.29 95 99 4 WHietxraocbholnosraoneet-haan5e (5) Nitrobenzene-d5 (S) us/l :50.00 42.66 42.; 40 w 8G w8~ 1 2-Fluorohiphenyl (S) 83 83 Terphenyl-dl4 82 84 FR. Phenol-d6 (S) 2-Fluorophenol (S) 2,4,6-Tribromophenol (S) ion 82 79 76 75 87 88 Date: 02/26/04 ionhelAtaec,: momen RREEPPOORRTTOOFFLLAABBOORRAATTOORRYY AANNAALLYYSSIISS This report shall not I;e reproduced, except in full, without the written consent of Pace ,a,nalytieal Services. Inc. EE -- en CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00005577 Page: 26 of 34 awisa 3M MN01538443 iceAAnnaallyyttiiccaall ee tn o Pace Analytical Services, Inc. 1700 Elm Slreet, Sm'te 200 1neI2601T170 Minneapolis, MN 55414 Phone: 612.607,1700 Fax: 612.507.6444 QQUUAALLIITTYY CCOONNTTRROOLL DDAATTAA rm R AAAE I TE rm QC Batch: 104292 Th TR QC Batch Method: EPA 624 Lab Project ttumber; 1084665 Client Project ID: E04-0120 CG Carbon System Test Analysis Method: EPA 624 Analysis Description: Volatile GC/MS by 624 Associated Lab Samples: 105333132 105333140 105333157 105333165 105333173 105333181 105333199 105333421 METBOD BLANK: 105340681 Associated Lab Samples: 105333132 105333140 105333157 105333165 pm m m. SSYif mw3at,i wto=p sie Parameter 105333421 Units Blank Result Reporting Limit Footnotes Zono Chloromethane Vinyl chloride Bromomethane Ch]oroethane 2 a 2i u~/l ND ug/l ND 1.0 ug/l ND 1.0 ug/l ND 1.0 TMreitchhylleonreoflcuholroorimdeethane uugg//ll NwD 11.00 Methylene chloride ug/l ND 1.0 a SZ 3 l,l-Dichloroethene ug/l ND 1.0 trans-l,2-Dichloroethene ug/l ND 1.0 ohm 2 = 2 l,l-Dichloroethane ug/l ND 1.0 pr F- i Chloroform ug/l ND 1.0 Seow =f i l,l,l-Trichloroethane ug/l ND 1.0 iid SE i Carbon tetrachloride ug/l ND 1.0 fred wo Benzene ug/l ND 1.0 1,2-Dichloroethane ug/l ND 1.0 i woos i Trichloroethene ug/l ND 1.0 1,2-Dichloropropane ug/l ND 1.0 poms m2 i Bromodichloromethane ug/l ND 1.0 trans-l,3-Dichloropropene ug/l ND 1.0 Toluene ug/l ND 1.0 ee hE i cis-l,3-Dichloropropene ug/l ND 1.0 Te 2 Of i l,l,2-Trichloroethane ug/l ND 1.0 bh wo i Tetrachloroethene ug/l ND 1.0 rr Ne i Dibromochloromethane u~/l ND 1.0 er a i Chlorobenzene ug/l ND 1.0 iy Sa i Ethylbenzene ug/l ND 1.0 SE a 2 Xylene (Total) ug/l ND 3.0 B1r,o1m,o2f,o2r-mTetzachlorosthane uugs//ll ND 10 l,l,2,2-Tetrachloroethane us/l ND 1.0 1,3-Dichlorobenzene us/l ND 1.0 105333173 105333181 1053331S9 Date: 02/26/04 Page: 27 of 34 ionhelAtaec,: momen RREEPPOORRTTOOFFLLAABBOORRAATTOORRYY AANNAALLYYSSIISS 'This r'epn~ shall n~t I~ r~pro~ucs~, eept i. f~ll, without the written consent of Pace Analytical Services, Inc. EE -- en CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00005588 aw iseass 3M MN01538444 iceAAnnaallyyttiiccaall eto Pace Analytical Services, Inc. en 1700 Elm Slreet, Sm'te 200 Minneapolis, MN 55414 fri Id T Phone: 612.607,1700 Fax: 612.507.6444 QQUUAALLIITTYY CCOONNTTRROOLL DDAATTAA mC R AAAE I CTIE ErE m METHOD BLANK: 105340681 Lab Project Number; 1084665 Client Project ID: E04-0120 CG Carbon System Test Associated La5 Samples: 105333132 i05333140 i05333157 105333165 105333173 105333181 i05333199 105333421 dene bperh Parameter pe He 1,4-Dichlorobenzene Mame m TE 1,2-Dichlorobenzene ier OL 2-Chloroethylvinyl ether boll = Dibromofluoromethane (S) Toluene-d8 (S) ma | : 4-Bromofluorobenzene (S) me) 2 1,2-Dichloroethane-d4 (S) Units ug/l ug/l ug/l % % % % Blank Result ND ND ND 94 78 83 91 pin Reporting SE Limit =1.0 >1.0 325.0 Footnotes LABORATORY CONTROL SAMPLE: 105340699 pewE woe hpe Parameter pm a a ma Chloromethane Vinyl chloride on EA Bromomethane ind 5 is Chloroethane SE SA mon Trichlorofluoromethane a 5 mi Methylene chloride mn ie 2 is l,l-Dichloroethene iT. ow DMS trans-l,2-Dichloroethene l,l-Dichloroethane Lh ET Chloroform Units ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l Spike Cone. 20.00 20.00 20.00 20.00 20.00 20.00 20.00 20.00 20.00 20.00 LCS Result 14.23 18.06 16.43 20.33 20.40 20.34 20.76 20.98 20.84 21.65 LCS % Rec 71 90 82 102 102 102 104 105 104 108 Footnotes l,l,l-TrichloroeChane Carbon tetrachloride oe Benzene A 1,2-Dichloroethane Trichloroethene Sew 1,2-Dichloropropane nt Bromodichloromethane trans-l,3-Dichloropropene fo, Toluene cis-l,3-Dichloropropene Piife l,l,2-Trichloroethane ug/l 20.00 19.72 99 ug/l 20.00 20.25 i01 EAug/l 20.00 19.53 98 2 mira ug/l 20.00 22.46 112 ug/l 20.00 19.03 95 2 ios ug/l 20.00 20.07 i00 RE ug/l 20.00 19.78 99 ug/l 20.00 18.56 93 2 Sz 3 ug/l 20.00 17.96 90 us/l 20.00 20.33 102 oa 2 us/l 20.00 19.43 97 Tetrachloroethene us/l 20.00 18.93 95 Date: 02/26/04 Page: 28 of 34 ionhelAtaec,: momen RREEPPOORRTTOOFFLLAABBOORRAATTOORRYY AANNAALLYYSSIISS 'This r'epn~ shall rio'( I~ r~pro~ucs~, eept i. f~ll, without the written consent of Pace Analytical Services, Inc. EE -- en CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00005599 [pr 3M MN01538445 iceAAnnaallyyttiiccaall eto Pace Analytical Services, Inc. 1700 Elm Slreet, Sm'te 200 Ee Minneapolis, MN 55414 IT Phone: 612.607,1700 Fax: 612.507.6444 QUQUAALLIITTYY CCOONNTTRROOLL DDAATTAA ------------------------R A--A--A--E I --TE--r ----m ---- LABORATORY CONTROL SAMPLE: 105340699 pen S woe Se 5 pe Parameter Dibromochloromethane ar oT mn: Chlorobenzene fren ES Ethylbenzene me, 5 ai Xylene (Total) ts 2 Mos Bromoform PS me 2 ZR 20 2 l,l,2,2-Tetrachloroethane Wipe. 5 202 1,3-Dichlorobenzene fis 2 Bah 2 1,4-Dichlorobenzene Pies. Zan EE 1,2-Dichlorobenzene Game. wh Em oEn oa 2-Chloroethylvinyl ether nnn es i" Dibromofluoromethane (S) To]uene-d~ (S) el i 4-Bromofluorohenzsne (S) SR, 1,2-Dichloroethane-d4 (S) Units us/l ug/l ug/l ug/l us/l us/l us/l us/l u~/l ug/l Lab Project ttumber; 1084665 Client Project ID: E04-0120 CG Carbon System Test Spike Cons. 20.00 20.00 20.00 60.00 20.00 20.00 20.00 20.00 20.00 20.00 LCS Result 18.93 19.79 18.54 57.90 20.50 18.74 18.54 18.02 17.92 22.81 LCS % Rec 95 99 93 96 102 94 93 90 90 114 105 90 90 104 Footnotes piwen a W wr EwmSE MATRIX SPIKE: 105348122 Parameter Chloromethane Units ug/l 105333140 Result 0 Spike Cons. 20.00 MS Result 17.94 MS % Rec 90 Vinyl chloride ug/l 0 20.00 23.55 118 S i E Bromomethane Chloroethane Trichlorofluoromethane Methylene chloride S2 AL| ug/l 6.650 ug/l 0 ug/l 0 ug/l 0 B Emaosn 20.00 13.08 32 20.00 27.10 136 20.00 22.53 113 20.00 25.61 128 a l,l-Dichloroethene trans-l,2-Dichloroethene l,l-Dichloroethane Sas ug/l 0 20.00 24.69 124 ug/l 0 20.00 24.84 124 ug/l 0 20.00 23.87 119 Chloroform ug/l 0 20.00 23.37 117 l,l,l-Trichloroethane ug/l 0 20.00 22.21 Iii Carbon tetrachloride ug/l 0 20.00 21.41 107 Benzene ug/l 0 20.00 21.63 108 ee 1,2-Dichloroethane Trichloroethene 1,2-Dichloropropane 2 Bu ug/l 0 20.00 22.90 114 us/l 0 20.00 20.73 104 us/l 0 20.00 21.01 105 Bromodishloromethane us/l 0 20.00 21.41 107 Footnotes Date: 02/26/04 Page: 29 of 34 ionhelAtaec,: momen RREEPPOORRTTOOFFLLAABBOORRAATTOORRYY AANNAALLYYSSIISS 'This r'epn~ shall n~t I~ r~pro~ucs~, eept i. f~ll, without the written consent of Pace Analytical Services, Inc. EE -- en CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00006600 aw iseuss 3M MN01538446 iceAAnnaallyyttiiccaall eto Pace Analytical Services, Inc. 1700 Elm Slreet, Sm'te 200 Ee Minneapolis, MN 55414 MiIgs dTois Phone: 612.607,1700 Fax: 612.507.6444 QUQUAALLIITTYY CCOONNTTRROOLL DDAATTAA R AAAE I TE rm Lab Project ttumber; 1084665 Client Project ID: E04-0120 CG Carbon System Test pen E a Le MATRIX SPIKE: 105348122 Parameter Units 105333140 Result Spike Cone. MS MS Result % Rec Footnotes trans-l,3-Dichloropropene us/l 0 20.00 18.78 94 Toluene ug/l 0 20.00 19.54 98 cis-l,3-Dichloropropene ug/l 0 20.00 21.20 106 l,l,2-Trichloroethane ug/l 0 20.00 19.12 96 Tetrachloroethene us/l 0 20.00 19.93 100 Dibromoehloromethane us/l 0 20.00 19.36 97 Chlorobenzene us/l 0 20.00 20.48 102 Ethylbenzene u~/l 0 20.00 19.72 99 EE ne Xylene (Total) Bromoform l,l,2,2-Tetrachloroethane SAL u~/l 0 ug/l 0 ug/l 0 Emm 60.00 59.42 99 20.00 21.56 108 20.00 18.80 94 ],3-Dichlorobenzene ug/l 0 20.00 ]~.23 91 VLienra oO 111.,,242--DDDiiiccckhhlllaoorrrooobbbeeennnzzseeennneee wuuass//nll 2-Chloroethylvlnyl ether ug/l Dibromofluoromethane (S) 3 MW :4, 000 022000..00000 11w88..s5139 99931 0 20.00 0 0 90 minim, 2 Toluene-d8 (S) 81 4-Bromofluorobenzene (S) 93 1,2-Dichloroethane-d4 (S) 85 Ss SAMPLE DUPLICATE: is Parameter Gimlien Chloromethane ---- 105348114 willl om Units E I C fr ug/l 105333132 Result 5.400 DUP Result 1.800 2-- RPD Footnotes i01 2 Vinyl chloride ug/l Bromomethane ug/l a IR ER Sp Chloroethane ug/l DEE m2 BX Trichlorofluoromethane ug/l a 2 N=I Methylene chloride u~/l ry 2 I=I l,l-Dichloroethene ug/l tee 2 3 1 trans-l,2-Dichloroethene ug/l San 2 Es l,l-Dichloroethane ug/l Chloroform us/l Sve 2 2 3 OZ l,l,l-Trichloroethane us/l BieS ES Carbon tetrachloride us/l ND 19.00 ND ND ND ND ND ND ND ND ND ND 13.00 ND ND ND ND ND ND ND ND ND ttC 36 2 NC NC NC NC ttC NC ttC NC NC Date: 02/26/04 Page: 30 of 34 ionhelAtaec,: momen RREEPPOORRTTOOFFLLAABBOORRAATTOORRYY AANNAALLYYSSIISS 'This r'epn~ shall n~t I~ r~pro~ucs~, eept i. f~ll, without the written consent of Pace Analytical Services, Inc. EE -- en CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00006611 aw issasr 3M MN01538447 iceAAnnaallyyttiiccaall eto Pace Analytical Services, Inc. 1700 Elm Slreet, Sm'te 200 Ee Minneapolis, MN 55414 IT Phone: 612.607,1700 Fax: 612.507.6444 QQUUAALLIITTYY CCOONNTTRROOLL DDAATTAA ----------------------------R A--A--A--E I --T--E --r----m---- SAMPLE DUPLICATE: 105348114 pew S wmw ree Parameter = a me Benzene ier FE 1,2-Dichloroethane a wor ox Trichloroethene en Es 1,2-Dichloropropane SPoeb,a nm 22 E2sd Bromodiehloromethane Units us/l ug/l ug/l ug/l us/l Lab Project ttumber; 1084665 Client Project ID: E04-0120 CG Carbon System Test 105333132 Result ND ND ND ND ND DUP Result ND ND ND ND ND RPD Footnotes NC NC ttC NC ttC trans-l,3-Diehloropropene Toluene em cis-l,3-Dichloropropene Dlg l,l,2-Trichloroethane Vie Tetrachloroethene Sam. Dibromochloromethane Tr Chlor~benzene i, Ethylbenzene SEXylene (Total) as Bromoform een 1,1,2,2-Tetrachloroethane Viipuoem 1,3-Dichlorobenzene Vimesess 1,4-Dichlorobenzene fee 1,2-Dichlorobenzene mea 2-Chloroethylvinyl ether us/l ND ND ttC us/l 20.00 18.00 8 3 2 I 2 us/l ND ND ttC 3 37 #7 4 us/l ND ND ttC wor rx ug/l ND ND ttC : 2 i ug/l ND ND ttC 25a: u~/l ND ND ~C ZT us/l ND ND NC on Sr eS ug/l 3.600 3.700 2 2 age ug/l ND ND NC oo 3 fT 4 ug/l ND ND NC 5 3 = f ug/l ND ND NC mx mx ug/l ND ND NC oF = 4 ug/l ND ND NC Es ug/l ND ND NC Dibromofluoromethane (S) % 96 94 Toluene-d8 (S) % 89 85 4-Bromofluorobenzene (S) % 97 93 1,2-Dichloroethane-d4 (S) % 92 91 Date: 02/26/04 ionhelAtaec,: momen RREEPPOORRTTOOFFLLAABBOORRAATTOORRYY AANNAALLYYSSIISS 'This r'ep(:,~ shall n~t I~ r~pro~ucs~. ~ept i. f~ll, without th~ written consent ~f Pac~ ,~naly'dcal Servi~e~, Inc. EE -- en CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00006622 Page: 31 of 34 aw issuse 3M MN01538448 iceAAnnaallyyttiiccaall eto Pace Analytical Services, Inc. en 1700 Elm Slreet, Sm'te 200 Minneapolis, MN 55414 fri Id T Phone: 612.607,1700 Fax: 612.507.6444 QQUUAALLIITTYY CCOONNTTRROOLL DDAATTAA rm R AAAE I TE rm QC Batch: 104133 P50 aaTa QC Batch Method: Lab Project ttumber; 1084665 Client Project ID: E04-0120 CG Carbon System Test Analysis Method: SM 5210B Analysis Description: Biochemical Oxygen Demand, Associated Lab Samples: 105333132 105333140 105333157 105333165 105333173 105333181 105333199 METHOD BLANK: 105331664 Hp r en 2shJ eh S,Epy Associated Lab Samples: Parameter 105333132 Units 105333140 105333157 105333165 Blank Result Reporting Limit Footnotes BOD, 5 day ms/l ND 6 3 105333173 105333181 I053331S9 LABORATORY CONTROL SAMPLE: 105331672 d Hy em He E om S hwee 1% Parameter Units Spike Cone. LCS Result LCS % Rec Footnotes BOD, 5 day mg/l 198.00 193.0 97 3 SAMPLE DUPLICATE: 105331847 f eyee. Parameter BOD, 5 day i Units mg/l ie om sp 105330583 DUP Result Result RPD 467.0 579.0 21 Se Footnotes Date: 02/26/04 ionhelAtaec,: momen RREEPPOORRTTOOFFLLAABBOORRAATTOORRYY AANNAALLYYSSIISS 'This r'epn~ shall rio'( I~e r~pro~ucs~, eept i. f~ll, without the written consent of Pace Analytical Services, Inc. EE -- en CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00006633 Page: 32 of 34 aw iseuss 3M MN01538449 ce Aniamliynteiscoanl Facehat soe, Pace Analytical Services, Inc. Sh 1700 Elm Slreet, Sm'te 200 Minneapolis, MN 55414 Aa Phone: 612.607,1700 Testa Fax: 612.507.6444 Emm QC Batch: 104181 Gc ato thd 8h 40.4 QC Batch Method: EPA 420.4 Reomiuted sphereTose Associated Lab Samples: 105333132 105333181 QQUUAALLIITTYY CCOONNTTRROOLL DDAATTAA Cb Prec mbes, 1RAGES Lab Project ttumber; 1084665 hit procs To 40130 Cs Cubs apstem Test Client Project ID: E04-0120 CG Carbon System Test mwewese wma Analysis Method: EPA 420.4 Snsleis baeeiption, Hosatice otal. in tates Analysis Description: Phenollcs Total. See seme whe an 105333140 105333157 105333165 ses 105333199 in Water 105333173 METBOD BLANK: 105336622 Restated uh Spiers SDDI SIMO LSI SONS LSND Associated Lab Samples: memes mie d[eIl i--e-- mess Parameter = wn 0 ie Phenol 105333132 Units us/l 105333140 105333157 105333165 105333173 Blank Result ND Reporting Limit Footnotes 25.0 less 105333181 esse 105333199 LABORATORY CONTROL SAMPLE: = ome Parameter Phenol 105336630 mie cmhee ewel Swiee Units WAT ees wee ug/l Spike Cone. i000.00 LCS Result 1178 LCS % Rec 118 mes Footnotes MATRIX SPIKE: 105336648 =ome Parameter Phenol wmo e GeWT t Geoeo iwe sed Viaee eta Units ug/l 105319651 Result 0 Spike Cone. 1000.00 MS Result 1055 MS % Rec Footnotes 106 SAMPLE DUPLICATE: 105336655 B =ossa mwnie el0s Parameter Phenol Units ug/l 105327324 Result ND l wB R DUP Result RPD ND NC fs Footnotes Date: 02/26/04 `onwela ac: Rm EPORT Om F LABORm ATORY . ANALYSIS REPORT OF LABORATORY ANALYSIS 'This r'epn~ shall rio'( I~e repro~ucs~, eept i. f~ll, without the written consent of Pace Analytical Services, Inc. `CHEOGNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIJDJIEAESCCTLTTRTITCOOT AACPOPRUROROTTT.EECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR.2E6E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00006644 Page: 33 of 34 SW_MNO1838450 3M MN01538450 iceAAnnaallyyttiiccaall eto Pace Analytical Services, Inc. en 1700 Elm Slreet, Sm'te 200 Minneapolis, MN 55414 a IT Phone: 612.607,1700 Fax: 612.507.6444 Lab Project Number: 1084665 II cn ir Client Project ID; E04-0120 CG Carbon System Test one concn en ABER ToS QUALITY CONTROL DATA PARAMETER FOOTNOTES St oT CARNES 4 HH 9 0 0 HE 8 Consistent with EPA guidelines, unfounded concentrations are displayed and have been used to calculate % Rec and RPD values. 0 arn oes sore ton LCS (D) neti MS (D) FZT aHtTa mn DUP Laboratory Control Sample (Duplicate) Matrix Spike (Duplicate) Sample Duplicate E I DiT oraSu A SR BA ND Not detected at or above adjusted reporting limit NC Not Calculable J Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit MDL Adjusted Method Detection Limit RPD Relative Percent Difference E BI Lr I Er T nest rtm bd ei [1i]] ThTShueerrsosagpfailtkeee rreeccoovveerryy wwahse oouuttseiiddee ooff ascocceeppthaannccee lHiamlittss.. [2] The calculated RPD was outside QC acceptance limits. [3] The BOD dilution blank QC criterion was not met. Acceptable method performance is based upon the remaining batch QC. Date: 02/26/04 ionhelAtaec,: momen RREEPPOORRTTOOFFLLAABBOORRAATTOORRYY AANNAALLYYSSIISS 'This r'epn~ shall rio'( I~e r~pro~uce~, eept i. f~ll, without the written consent of Pace Analytical Services, Inc. EE -- en CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00006655 Page: 34 of 34 pr 3M MN01538451 LEESIETENIIIIiiriaieiseraesiiesiriren gg - [E! = Tm i | | ef5 IHp]a I| 3 i3sg - |i |e ~ | | 1 [I 5 f# i [4 : e|. l :a Jo { l| o]| | Ll | I | Il4s)4 I] | IE A GFEOANNEFRIICDOUE.NNTSYUTBDJIIESCATTRTIC0TAPCROOUTRETCNTGI.V2E7GOuRnOiEoR26E8N0T3ERED CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00006666 swnosso452 3M MN01538452 DRaetpaortFilDea:te:/va2r3/-cFheebm-/20l001mss1i2:210/021303.b/04908.d Pace Analytical Services, Inc. Pace Analb%icai Services, Inc TTEENNTTAATTIIVVEELLYY IIDDEENNTTIIFFIIEEDD CCOMMPPOOUUNNDD~S CLCllaiibeennS[trpNNaaIvmdee::: 1303MH533EEb3NF1V~32 OsLOpaapbemerpraalSmtte~ooprrLoTdc:::atKKiSS1oKK0n5:333132 SASSnaaaammmlpppylllseeeisMLMaaottcTrrayiitpxxei:::on:WWSAAVTTEERR Analysis Type: SV NHuummbbeerr TTIICCs~ ffoouunndd:: 1144 CCCllliiieeennnttt SSSODmGGp:: IDC0:221188E000444-0120-67432 SSCSaalammimpepplnlletee DPDSaaomttipeen::ti:~:12~-0F4E-B-02102004-67432 DLDSaeaavttmeeepll:eRReeccLPeeoOiJiWvvneet:d@:: 1133--FFEEBB--22000044 0000::0000 Level: LOW (CCuOOgNN/CCLEENNoTTrRRAAuTgT/IIKOOsNN) bUlNuqIgIT/TSLS:: (ugiL o~ ug/L cCaASs ~N-UMMBBEERR T2I1T N111557-2222:-00 a233] 662255--2255--22 6s5.. 3314a133111-449--688633--55 78670. 1i11i111i110----99996008---5600 85. 109 . 155591962027---67975686---7-5737-0 II11@I21) 5111560527?2-6665~-5811--7773--966-8 1111323a. 2103-010705--5-086-14-9 14 2315-61-S CCOOMMPPOOU~NDD NN~AMMEE U3|n-3k-Hniyoydwdrnrcoxxyy--83--mm~etthhyyll--22--bbuuttaannoo| UU2|nn-2kkH-nenHopoewtpwntanannooll,, 22--mmeetthhyyllUEF|Ftunurhkraanannon,e,w,n29,~133,--1d'di-ihohyxydydrbroio-c-a(A-2-m-memeteththyhylol|| EE||2ttE-hhtpaahrnanoneoop~lla,,no~2l2-I,-({22-1--o,eez1tt'yhh-booo~xxxsyyy[eeb2tti-hhsmoo-exxtyyh))o| 2l||1--1-P,HHr2eeo-pppbtteaeennnnzoeeeln,edIi~c]ar~b-oonxiytbrli~l-e, |21|2-,2-F2-Fi-PluBruoeooprnreozno-ea-6nm6-ei-nddneii,tst~arorNo~b-pho(he1ne,nin1oto-]rldiilmee,t| 2l1|-~,BP33tr--haoDDnipiooeclxn,xoaolml2aai-nnd(eee2,,,(4N22----((((1sl4,-~-1mlm,e-e3tdt,hih3omo-xextyt||y Ethanol, 2 [2-[4-(1,1,3,3-8 RrTT 3.115.~ 72726111.] 143 . 2517628698 445..297927874866 5555 .072783234411 576 .800882886467 7877 1.120i562~7775 111335... 020270764475 15 .207 EEsStT.. cCoOnNcC.. | 11_..4229s9] N NaJIT I 313l1-s33000| MaZ= 2_17.~.58860]] WNaa 2212.179756)]8 MMTT| 2661.1.677176]7) NmTo| 2I1l7-s.58e874]] NNTT L3337000,4s84]] NNITT 8O5 `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACPOPRUROROTTT,EECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR-2E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00006677 33MM_MMNNO011553388445533 DRaotapeFFii!lbeea::al/ivvaarr/icchheemni/1i0o~nssssl1.1i//002211880044.bb;/~044931133.d H~por[ t3ate: ~23 F~:-~b 20@4 1pa2c:e21Analytical Services, Tne. TENTATIVELY TDRTIFIED CovPOUDS Pace Anai'ynical Services, !no. fCrCLfllariibye~nnStzmp wame: nlName: id: Oan oHv 3H E~{~ IOS333181 SCCCCallinHiiopeenlEnnttte SSBS5D0mnuC0pot:.e1I5D0io::22a118soEr000ae144no0ns1zo~0o0-n-s677a44422 yOSFpreEaeriasszsorILLooRcuR: aeetiKE:iSoKonn.SiWvrAaIEnR DBSsSvaAiaaTtnmmEegppallleeeReeticDpPeeaooitiiivevnne:ettd:d,:12-1F3E-Br-e2m0-@24004 00:00 Matrix: ~alysis Type- SV NNuum~beerr TTIICCss ffoouunndd:. 88 concavmaroy UNITS: L@vel: LOW CONCBNT~hTION UNITS: [(uu~gi/LL oo~r uugg//KKGG)) ug/L c~aSs NNuUMMBBEERR i From I 3 sas-saes |Propemainitrile, methylens| 2 922-64-5 3 Erbe 3 30 108-276 [Faken 2,3 dinydro-3 methyl| 4 1708-27-6 5 aman SL Tah 5 53778-73-7 6 49622-18-6 5 See |S ancyaniaine 7 503-86-6 oI TERI 8 563-46-2 SCO'MOPMOPUON~DD. HNAAHMEE Unknown Propanedinitrile, Unknown [uran, 2,3-dihydro-3-methyl 2 Butanol, l-methoxyEecane. 3,3,4-trimethyi~ l-Butene0 2-methyl- RT RT TTT 4 3.430 REE 4.490 $33 15 | 4 ,784 4.538 isl we 4 .985 5 58) wo 5 ~197 ~o279 BH Hit ~_515 si 33) 5 6.882 EsSsTt.. cCOoNeC.- | a | HJ 1 59 J I 48 9 21 2 03 3 19 373 RCOENNFINDEENRTICAOLUNSTUYBDJIESCTTRTIOCTACPORUORTTE.CNTGI.V2E7 OORuD1E0.R28E8N6T3ERED IN CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00006688 sw_otsssise 3M MN01538454 DRaetpaortFilDea:te:/v2a3r-/Fcehne-n2/01004ms1s2l:.2i1/02180 0j04913.d Repo~"t Date: 2 ~-~e~-2004 ~2:2 aPaccee AA~naallvytt~iccaa]l 9Seerrvviicceess~, IInncco. Data file : /var/chRBeAAmSS/EEl,,0mNHsEBsUUlTT.R~1Ah/LL0,,21AA8CC0II4DD.5Q@/UU0IA4~N5{TT13AA.NNdDD R~ATTIIOO REPORT REPORT DLLIaaanjbtba SSDKaufitpipeleIIdd::: 111i003v55-a33Fr33Ei33Bc11-h882e110m0/4IO2m0s:s3l7~ii02]804 si0C4Cl9li1iee3nn~ttd SSmmpp IIDD:: EE0044--00112200--66774444~2 O OStpppeerraIatnt ofror ::: KK11S8S0KK-5F3E3381-821004 2@:37 [Tnnsstt IID D:: 10mesl.i 10mssl.i MSmC~~iopssmccmeInnIItfnnoffoo :: : 105333181 RCRA 8270C - SEMIVOLATILES MCMMeeoettmhhtmohedDnaottde :: R/2iC3vvR-aaAFrre/in8cc-2hh27ee00mm0C/i411001mm1Sss:~es1Mll4I.oViiOki/~k00hi22Tn11Ig88L00E44S~.bbi/SSQVVuO0aT7n--t00~4T33y~.pmme: 1STD MMCCoaogllthDDbDaaotttaeettlee:: 211i3322---FFFeEEbB~---22200000044~ 22I09I:::4]44~5 @CCouallantFFiillTeey::pe:004433I00S77T~D.d4 AD DIlinisltl egbFFaroacatctttotolorre:r::: H113P.00R0T0E0 Compound Sublist: 625.sub T~anrtgee~traVVteeorrrss:iiooHnnP:: RTE33.5500 Compound Sublist: 625 sub Warges CCoonncceennttrraattiioonn FFoorrmmuullaa:: AAmntt * * DF DF * ~ UE Uf + * Vt/(Vo vti(Vo * Vi) * Vi} * * CpndVariable NNaammee vVaalluuee DDeessccrripp[t~ioonn DoueFF I11.o.0000000000000~0 nDgDiilluunutittiioonncorFFraaecctctotoriron factor UVvvefto I111o0000O0000000o.,00000000000O00000 VVnVoogollluuuummmneeeitooofffcorfsfiiarnnmeaapclllteLoeenxextxtrtrfaraacacctctttoer{(duuLl))(mk) VVviio iI1.0000000~0o000000000 VVvooollluuummmeee oiifnnjjseeaccmttpeeldde ((euuLLx))tracted {mL) Cpna variable Cpnd Variable LLooccaall CCoommppoouunndd VVaarriiaabbllee 1I S5T1D0 RwTr AaREaA AMOUNT +* 95 11,,a4--DDiicchhlloorroobheennzzeennee--ddi4 ~+ 2288 Naphthalene-ds 55_.999988 7~.557788 11221155002211 11771100881111 33..000000 40.000 `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBDBIJIJSEAETCCLRTTITTCOOT AACPOPRUROROTTT,EECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR-2E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00006699 I3MM_-MMNNO011553388445555 DD RaeatptaoartFFiilDleaet::e:/ivvaa2rr3i-/cFcnehebem -m2/ii0LO 004m msss1gl2l:..i2i!1/002211880044.bb//0044991133.dd Report_ Date. 23 Feb eere, 3seit ae aso aes QQCc NFllaagg Legend LL- OOppeerraattoorr sseelleecctteedd aann aalltteerrnnaattee lliibbrraarryy sseeaarrcchh mmaattcchh.. `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEEASCCTLTTRTITCOOT AACPOPRUROROTTT,EECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR-2E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00007700 IM_MNO1538455 3M MN01538456  E8228 fF 23 EEL EERE Joeeony " Fiiiid % rrr 1{vi1i32Ei3si%E : R-E tvrcneornemwenn ait na BEtiEheRirs PE ---- i 5 reese vt} 5 5 PE---- i . 5 rneaiz * 5] . eit o o 5 Tress . ; i 4 i Hiielrt: ilie;i dt gitHI HE +] : `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITOCOT AACOPPURRROOTTT.EECNCTOT.IIVV2EE7-OOCRR\-DD1EE0RR-2E6E3NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00007711 _MotsasesT 3M MN01538457 JieR ernpne rrsr Sopot J one Gos we0.25 owt renin RS i~o~ feel Gh | NLS A aNN oo . = CG ETETR Re we, RR Ww % % > CCHOEONNNNFEIDFPEIINNTDCIAOELU-NN- TSSTUYUIBBDJJIAEESCCLTTTRTIT0COT AACPOPRUROROTTT.EECNCTOT.IIVV2EE7 -OOCRRV-DD1EE0RR.2E0E0NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00007722 a uorssedss 3M MN01538458 en overt wim J mens es J---- pn -- tr Snips Trr-- moomoo 922-~4-5 Lam : . -- A i. ow | | i2 wll | Io: omfa | x| = RT SRT 0 = 5 Fol a ool ue | = . | m |. -- Ee Po Ne ads d| n ms CCHEOONNNNFEIDFPEIINNTDCIAOELU-NN- TSSTUYUIBBDJJIAEESCCLTTTRITTCOOT AACPOPRUROROTTT.EECNCTGT.IIVV2EE7 -OO0RR1DD1E0E.RR8EE8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00007733 su_wmoressss 3M MN01538459 Lenni ore tumor --_-- or ui on = = RE lO~O~ io Bol mle me ot ~ RE Sr ar a a a a a EE ES EE ET TE eT CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00007744 3M MN01538460 fom et 1 DN S roI t - RE genera Hesvore 1708-27-6 ms NBS75K.I a 5w u77n w1a%m : -------- 8.0] A ii ; N n al J. dll, Ii =7 .sr esl - le ye en) | Hh ideale po TT - "N i i. ~ M| aal ~J DN -- se 4 ld] ie a?/42 4\ / "A daaltheule bLbei)h wo ea CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00007755 3M MN01538461 vrmrtp r m--r-- wr ewe owt een ---- is it yy ony fo T wnT ww Om rheew om - TR RR o - \ 1 cof Ew ii. : lll, NEotNe " ~ Le i TM Pe fool - ~ Wal dl Nl Al NN ee A TT /2~ TT. - Eil =" ole wrtalas -- T Lthy Np R ygmyi we EN IN 2 nN . a LZ = A, INNS CONFIDE-NSTUIBJAECLT TO APROTECTIVE ORDER ENTERED IN CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT. NG. 27-0110.8862 HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00007766 su_wmoressss2 3M MN01538462 DDRaaettpaaortrilLea:te: /2va3r-/Fcekbe-m/21000m4ool1.2:2/0021804.b/04909.d Report bate ~ :-Feb-2004 12:20 Pace Aralytical Services, inc TTEENNTTAAT%I[VVEELLYY IIDDEENNTTIIFFIIEEDD CCOOMMPPOOUtN~DDSS CCLallbiieennSttupNNaa1vmdee::~ 1330HM53E3E3}N1V~40 OOLSppaaeebmrrpaalSzetmooprrLol:cd; :atKKiSS1oKK0n5:333140 SASanamamplplyleseisMMLaaottcTrrayiip<xxe:::o~:WWSAVATTEERR A~alzsls T~pe: SV CCCllliiieeennnttt SSSDDmGCp:: ID00:221188E000444-0120-67434 CSSSlaaaimmmepppnlllteee DDSPaamottipeen::tI:D:1!22E--0FF4EE3-~--022100200044-67434 DDLaeavtteeel:RReeccLPeeOoiiWivvneetdd=:: 1133-FFEEBB--22000044 000~:@000 Level: LOW NNuum~beerr TTIICCss ffoouunndd:: 55 (CCuOOgNN/CCLEENNoTTrRRAuAgTT/IIKOOsNN) U[~NuTTgZT/TSLS:: (ug/L or ugiKG] ugiL CGAASS NNUIM~BBEERR TI2i0o11I111550--228227~20-_0 12330... 25~10331577070-788-8-70-7-1792-33-77 545..~ 121110225--03-3606-1-7-73 CCOOMMPPOOU-UNN~DD NN~AIMEE |32|-H3H--ypAdyyrrdarnxo,yxy--333-,-m4me-edttihhnyyylld--r22o--b-buuttaannoo| 22||2PH--r-BBopuupvttaraananncnooi,llc,, a3cil,i--4drm-,eedtt~hrh2ooy-xxdm~yre--ot-hyl-, | EEPttrhhoaapnnaeen~,oic1l,,1alc''i--doo,xxyyb2bi-isms(e[2t2-h-eyetlth-ho~oxx| RRTT 311.1797181070] 5545 .1219188882777 555 ..772338020 BEsSTT.. cCoOnNcC.~ | @Q 1.201i.l]2s0) NwJT 441I7l~99922728)| NmIT I11l_.e99878| NIT `CHEOGNNONFEINDPEIFNNITCIDAOLEU-N-NSTSTUUYBBIDJJIAEESCCTLTTRITTCOOT AACOPPURRROOTTT,EECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR.2E6E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00007777 I3MM_MMNNO011553388446633 DRaetpaortFileb:ate:/v2a1r-/Fcehbe-n2/0l008mss1l2.:12/0021804 b/04909.d Repcr~ ~:a~e ~ ~Feb-2004 12:20 PPaaccee AAnraallyyttficcaall SSeerrvviicceess,, I[nncc Data file : /var/chBBeAAmSS/EE1.,0mNNsEsEUlUT.TRi-A/L-0,,21AA8CC0II4DD.5QQ/UU0AA4NN9TT09.AAGNNDD RATIO RATIO REPORT REPORT DLLIaaanjtbbaSDSammftppieleIIdd::: 11L!500v.55aF33rE33iB33c1-1h424e000~0i410m1s7s:l0,3i,i021804~biOCC4ll9i~0ee9nnot<d SSmrpp IIDD:~ E04-0120-67434 OosIpmpnjeperraaDIttanotoferro :::: KK118Ss0KK5F3E3B3-1240004 17:04 IInnsstt IIDD:: 11008m1ssssii. i HMCSiiomssmpccmeinnIZtfnmoffoo : : ~C5333140 RCRA 8270C - SEMIVOLATILES MMCMeeoettmthmhhoeonddDtate : : : 2R!/C3vv~-aahFrxei/b8cc-2hh27ee00nm0C//41100mm1ss1S:ssE11Ml4I..V1iO/!kL0k0Ai22Tn11gI88L00E44S..bb/iSSQVVu0Oa77n--t004433Ty..pmme: ISTD CAHCalaellsthDbDoaDatttateetlee:::: 2115232--FFFeEEbBB---222000000444 22I00I:::144455 kking QCCuaa]alntFFiillTeey::pe:004433I00S77T.D.4d ADDIilniltlsegbFFroaaactcttttoolorrer:::: H91P.0R0T0E00 Compound Sublist: 625.sub TTIaanrrtgqeeegtrtatVVoeerrr:ssiiooHnnP:: RTE33.~5500 Compound Subl~st: 625~sub CCoonncceennttrraattiioonn FFoorrmmuullaa:: AAmmtt *~ DDFP * UUfE *+ VVtt/!((VVoo + VVii)) +* Cpndvariable NNaammee Vvaalluuee DDeessccrriippttiioonn DoveFF 1].1.0o0@000000000000 ngDbiiullnuuitctiioonncorFFraacecttcootrrion factor Vvvteo 1I10000000{0.~,000000000000000 VVVooollluuummmeee ooofff fsfiainnmaapllleeexexttxrrtaarccattcte((duuLl))(mL) Vvv~io 111..000@@0O00,000000000 vVVooollluuummmeee oiifnnjjesecacmttpeeldde ((euuLlx})tracted (mL~) CCppnndd VVaarriiaabbllee LLooccaall CCoommppoouunndd VVaarriiaabbllee 1510 RT ARER AMOUNT +~ 9 1,4-Dichlorobenzene-dd 9 i, 4 -Dichlorobenzene-d4 66o.000011 11330011332233 33..000000 + ireny-s-mec3os ane a nears `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEEASCCTLTTRTITCOOT AACPOPRUROROTTT,EECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR-2E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00007788 33MM_MMNNO0115533B8446644 DRDaaettpaaortFFiillDeea::te://vv2aa3r~-/iFccehhbee-mm2//0110004mmssss12ll:..2ii0i/0022i1S80044..b5i/0044990099o.dd Report Date: 23-Feb~2004 1910 `CHCEOONNNNFFEIIDPDEIENNNTTCIIAOALLUN-- STSUUYBBDJJIEESCCTTTRITTCOOT AACOPPURRROOTTT,EECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR-2E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00007799 3M_MNO1538465 3M MN01538465 = L ) ostroR: FitT ote odos ono LE - |IR - [-E= BN a re - } I -- ls | oN sf bal "x 5 l ee . . #| 5 I 11|* %4 1 CHEONNNEFPIINDCOEU-NNTSTYUIBDJIAESCLTTRITCOTACPORUORTT.ECNTG.IV2E7-O0R1D1E0.R8E8N6T2ERED IN CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00008800 [HiEh {ee F=aH tHIHEE3i : i 8 3 {: :3| su_woresssss 3M MN01538466 top ts 2.08 8 85 5 egies . -- [HH jiiEiE .. RE E ceeY ctr?y-- r sien ffHliieHeh]syi pu :3 ; . -- x\ .: . Lots . : ; ` eh i! gifl oir + HiE!E diiN s , Te tn CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00008811 3M MN01538467 wrens I re =] Se nme tt vy a one gue mt Bb mao mown Doom G of Se R io]e IN ~ oo adil, NN ~~ 5= rE rr EE E a Er RE E EE ; | Eio =~ | poATer a ow AT NS BERr z 5 " i] HpAe e ~Neer lls. a ml e ~ f ~~ -- TR SigE e-l | ;: in ol ema Oe = lL ~ r ~4 68 7~ 76 8~ 84 88 SE CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00082 3M MN01538468 A aps ie signer dsm sore sane nr Gary Gy we mm ow rive Tae wm Fa pn | on owe toms ow om am fee =. TM = rT no "~ Eel zl lll ou=l I - rR li cof | | --ie H of Fe ~- wlll ST rr ", [ Tr : of PA EN 3 nd ee CCHEOONNNNFEIDFPEIINNTDCIAOELU-NN- TSSTUYUIBBDJJIAEESCCLTTTRTITOCOT AAGPOPRUROROTTT.EECNCTOTIIVV2EE7 -OO0RR1-DD1EE0RR.0E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00008833 Su uotssedss 3M MN01538469 ---------- ne en a mie = ee T - T62944 47 CSN&~ 88 i.i J Lal N1o .0e0 ye - TT . Eel ~ be2.0] . dd "~ ds TLa one | - TR ee sel - i] Ns J] v = SN RAR ihe -" Bowslo oN=~ le\m > nn me a res CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00008844 3M MN01538470 vLeLrt naLlnpat rei a mgSuomesoGmmimagwmn 3B zooomamr oo3nm i om : | "~ : I RE rE Te re re ne " | wfi In Al 1 lL ~d= u -- rT : HH =~ hl |~~ on . o Ca ld JN wo rT res eof 7" > EioTs) eedoJm l dn ms SLATE I NL TREen E CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00008855 rp 3M MN01538471 Some to von vee ete 31 38 Ctra sowncovuns mtn Co, 1esters JR--_-- mm nme Garey wks ma Eu Git romis tet own eam = ES Ea EE i pn Eo = fo oa all e| S -D tN - Ue ee asl de Al [1 pm a oo eel EE J IR JLON N J TT TT TT RT foo L- = oY i = {eel - aula | -- - Jide pre ye LNae ae 2 eo > 8 ol | > `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITOCOT AACOPPURRROOTTT,EECNCTOT.IIVV2E7E-OOCVRR-DD1EE0RR28EE8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00008866 _MNO1S384T2 3M MN01538472 DDRaaettpaaort}f~iilDeIa:et:e: i/vva2ar3r/-/cFchehebe[-mt2/i01i00O4~nssss1li2.:.2(0/021604.b/04908.d Report Date PPaaccee AAnnaallyyttiiccaall SSeerrvviicceess,, IInncc~. Data file : /var/chBBeAAnSS/EEl,,onNNsEEsUtiT.RRiAA/LL,021AA8CC0II4DD.bQQ/UU0~A4iN9qT0T8A.AdNNDD ~RATTIIOO RREEPPOORRTT DLLIaaanjtbbaSDStarfotpipeleITdd:~:0 !1110v80Sa-53Fr33E3/3B3c~-1h323e202m0i410m1s6s:i10 i/021804 b/04CC9ll0iie8ennottd SSmtwopp I1DD~: EE0064--00112200--6677443322 OSIpnmjepraDItanotfero :::: KKi1SS@0KK-5F3E3B3-1230204 16:10 IInns~tt I1DD:: it0ommssssllo.ii MHSCiiomssmpmcceinnIItfnnoffoo :::: i0S333~32 RCRA 8270C - SEMIVOLATILES MCMMoeeerttt~hhhT.ooeddDnatte :::: R/2/C3vvP-aa~Frrhe//bcc8-hh22e7e0m0m0/C/4l1O0-mv1s1sSs:sEl1lM4.i~ iiVk//O0@i~22nT11Ig83L00E44S.b5i/s5vVQ00u77a-n-0t04433Ty..pmme: 1STD MCACaaolllsthDbDaoaDttattetelee:::: 82i1322-o-FFFeEEbBB---22200O000444 212010::~144455 kkin~ QCCuaalalntFFiillTee~::e:00443I3S00T77D~.dd ADDIlin!sltegbFFroaaatccttttoloorerr:::: H8l1P~.00OR00T00E000 Compound Sublist: 625.sub TTIaanrrtggeegetrtatVVoeerrr:ssiiooHnnP:: RTE33~.5500 Compound Sublist: 625.sub CCoonncceennttrraattiioonn FFoor~muullaa~: AArmtt *+ DDFF ** UUff +* Vvtt/i({VVoo * VVii)) ** CCppnnddvVaarriiaabbl]ee NNaammee vVaalluuee Description DoueFF 11i...0000000000O0000 nDgDiillunuuitttiioonncorFFraaeccctttooirron factor vUVvofte 111I00.000000000O.,.00000000000000000 nVVVgooollluuuummmneieetooofffcorfsfriaennmaacpltleioeenexxtxtrrt~aaraccacttcttore[(duulL))(mL) VVviio 1~l..O0O000000.0OO0O0000 VVVooollluuum~seee oifnjescatmeplde ((euulLx))tracted {mL) CCponndd VVaarriiaabbllee LLooccaall CCoommppoouunndd VVaarriiaabbllee 1870 RTR.'~ AREA AREA AAHwOoiU~NTT + 9 1,4-Dichlorobenzene-di * 9 l~a-Dichlorobenzene-d4 ** 4455 AAcceennaapphhtthheennee--ddl100 +~ 6622 PPhheennaanntthhrreennee--ddli0o 6.002 6 902 I100~.224455 1122o.776688 11330011668822 22115522901155 11776699338833 33~.000000 4400.000000 4400.00@000 Spo.seca 3 vanene as a ainane `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACPOPRUROROTTT,EECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR-2E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00008877 I3MM_MMNNO011553388447733 RDDeaapttaoartFFiillDeea::te:/!vvaa2rr3i-/cFchehebem-mi2/01004mss1l2.:2i0/021804.b/04908.G Repot5 Date: 2S-Feb-2004 2 per, 2mm Suen 23. aumpo.t mecoy. 12061593 2? 7984718 xvod, 2-4 -stonpesiny en ain xen sienns nse [R---- pp Ethan~io 2~[2~|4~<i,~o3,S[e[ramethy]bu: `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACPOPRUROROTTT,EECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR-2E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00008888 IM_MNO1538474 3M MN01538474 . el Lot FiI il i ig i ilMiE li i i ! i - + - 5 # a [Ea CJ 8 x spring 2 = i i ifsiyz.g3 HH ind staizi $BiEEEiRlSE | rp Rade * . [PU emma a nrg ha smi ; sess l iar Ra 5 ="4 sEuEuRuusissusqsaaiiiudsasaiiaiiiiqsaiitiasing `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACOPPURRROOTTT.EECNCTOT.IIVV2EE7-OOCRR\-DD1EE0RR-2E6E3NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00008899 _Mo1s3ers 3M MN01538475 sion On SIwTm me erin frCeEeossis pmeeim rn ere ovr FgrEhwRen Suite too ire ee we nl i Jl me] np eo ~ aol a --ETE WN EB OT E RO6 4 T W ATm ORTeew ne 8 oe 6 Eie A =EEE "- dA do & WER R R Rm WwWR G6 WwAWeee 8 [2s oi o bl Cem ses sd jw RA I CR Lx Pe of | Fo Flo mm "~ re me = ~ r ET TE eT CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00009900 3M MN01538476 i, aSlee meoi ton i _ eg Fel oN me mm |, J = ERTE ww Mm Wea No Ge 2 wm om om oo we & : | CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00009911 3M MN01538477 a re -- corer tap --_--ieny - poernrot att SE. TowpnRe ITmmESa =3we wL 3omo w a T_T hE3o.. N~ po Jl ll owo%s po TET, Te ren RD ES fe be Ny SL Ng mee 7. -- , -- BS EERTTRse je A we me ie io Eo ~ 2 Ee | | be l Nha i ald, ~~e oe TT Tg Er RT 59~ Ee ,, i Pe wO l pN A L le Nm pe ,em _ GFOENAFINDEERNITICAOU-NTSYUBDJIESCTTRTIC0TACPORUORTTECNTGI.V2E7OGuRnOiEoR26E8N0T3ERED CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00009922 swosso478 3M MN01538478 r---- ea tora ana 42 RR PT SS od | 2. i and ON = FEANERI COUNTY DISTRICT COURT NG. 27Gunio26803 CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00009933 3M MN01538479 evan S~mple ~o~ :=J wir U--r | "Ne T swee ins TMwsrm. Ri~-Pen,te~al. (E)- Ts 1576-87~ mm NBS75K.I : wn wn sen ww mmx am 62733 ~ ow mw ~HSO 8~ = i J all] Hl | . 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NG. 27-0110.8862 HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00009944 su_wmoresssso 3M MN01538480 Sol Cems rir E o J e e rg in anry ie won win a wmCA Nr~beewl r mmoewmemoon,opmsofmmcmoomn 12859 i~-7 -- i N i2.0] J de a"~ se - Tr eo c ne eo -~ = pelr t r NL i NON ES be J 1 dr mm fe pe oe me ~ rstrer Go , Eo EEN on ble Lol nL A a em ee ~z ET TE eT CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00009955 3M MN01538481 ire hr copa I i Jes - cron r+ Tater i rsd ion pcmeaeoiawls B grdlnlol ogooehln ---------- ey hteo ~ =os ill D=~ T " os Fadsi - ar TT t=o EN Aa -> "Ltll"l ~JT l, e T | L WoT fm Tm "af08 16 ciL lls - - rT Ir Eo ,, FT 2 Iof t Y EaNb~p eli l en CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00009966 3M MN01538482 Crs--en--ear re: ---- Tore Sty Fort w=- i a oveerenSiseeerony vTises mwmsa mwme a6 cceuem we ~P~o~i ~ ~ ( ~-me~hoxl~l~h~l e~b~) i - | i ol : - J be] ~~ ror, TT RR , [8 wo |Ae| pe : wl Jil uly om Le mpm -- ET TTT El Noo son ie J Woe me Lee me on ET TE E ool w bs -~ on - Woe [oe ln oo SE CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00009977 3M MN01538483 oomre voesreseae 0 Cotres aay SwenSvat en J----" een Sars 938 on ay Gs Guts fonts omnaTemrie,sre ~ oa = S wmre eoR mma aes 592-7~7 N~?SK~I ~324:2 ~ sown om~9 we CTMi4 ~ i N -we lly galI lLLS ~ ePsSw -- eg Te re Lroe p| u | ,. in 22 I -- . I all a RE TR ~ LO rr iC ~ Ee 2= oa ad I wn EL | oe co ~ ) foal . Ls L bh |i Uo Ie Lp O| S l | ifter CCHEOONNNNFEIDFPEIINNTDCIAOELU-NN- TSSTUYUIBBDJJIAEESCCLTTTRTITOCOT AAGPOPRUROROTTT.EECNCTOTIIVV2EE7-OO0RR1-DD1EE0RR.0E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00009988 Suuorssadss 3M MN01538484 on el fm -- wim e wa no a ren ve mm mew mew OR -- Pla ow | - - 2.0] Fad ul b= e asea TL me eeCETTE we TR wm we ale me me we ee15 me Eo E aol a fe ops fT ge ] = Tr RT Ta Ir -- He ann em mee ige | ree wR eI we | || >. a Es CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00009999 3M MN01538485 even oe ta sire ---- rome neem 10.0 TTT J an Con Uw ry ai is toon J Se mma ne ow wee mw a 0GE an 7 ed Carasieds (GEES go ilggo g fo ilred t | foaurloiy ofyflmg gyroek, -- RT RT -- 2 ool hoi el ~= d - |adeN) aNA oo " -- TR TTT TT -- ol me fieel po .ow Lo NL w y J pe , 1 ooh alt ane sll losin Jb NA A -- TT TE Ee ; i. ~ a =~| opm . | | i | foi 1 TM CHOENNFNIEDPEINNTCIAOLUN- TSYUBDJIECSTTRTICOTACPORUORTT.ECNTG.IV2E7-O0R1D1E0R.8E8N6T2ERED IN CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED N HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00110000 su_wmoresssss 3M MN01538486 J---- Com ry oy at mis bg sF TiTgant Twrtwipne ws ims -- ww -a % m eBwwwoE 2 I RR - sa Ju HoaYk d ~ | L TM ~Lh en oo SY TT :5 col of o :W PE b H| o| SN -- ET .Ne Ld ge L- n el ~ | oe deh i= TTFe Ws Tie : po N | 2 ~ wo gg il AtiWef hd i tll yeg l e ri y CCHEOONNNNFEIDFPEIINNTDCIAOELU-NN- TSSTUYUIBBDJJIAEESCCLTTTRTITOCOT AAGPOPRUROROTTT.EECNCTOTIIVV2EE7 -OO0RR1-DD1EE0RR.0E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00110011 Sw uotsseds 3M MN01538487 -- a vi Sos Sieg Ste Sr SsS oiepsS,p rim i gsn how, --e mw we wf 3 tLaoenzo" - TIT RT Bo - se fe dAoTd aNLNLLL 1 LLL a mY = TR Ent ko EN From ooh - (7 ee |. boda dA Jobsite dez Lg lo L - i= iioe ACO. s N_d so) 2 " ' | ooodes TT T ad E || ZO ~ 60 8~ IOO I~ i~ i~O 180 200 220 240 1 2 Fbd pd feAem e lonny dbl b 0tn hx pal omt ho i , ||| 240 CHOENNFNIEDPEINNTCIAOLUN- TSYUBDJIECSTTRTICOTACPORUORTT.ECNTG.IV2E7-O0R1D1E0R.8E8N6T2ERED IN CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00110022 su_wnoresssss 3M MN01538488 a anzten SR, pS i avee riib in ogtl | sEidoWwmnE t Ed5m 3jcmws - I ET 8~C 1% oo pe } pe dans -- os om doe mm |e TTPET Tr ey es = eAfI . rr, a om Lo me er re i iP.ls nN om me mT EN be =L e Lr ke. oe iN Bol Log, a , i" SE CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00110033 3M MN01538489 pa - gEAE : E Ei E * pad - f+] 3% 1s | Ls 5 h:l| i --| I| a 4a { Gl5 ia i] i ridin 7 i 1 Z| 3 | gi a Bl iE BiHuhEeh| ----=: . H|E sinnssseisasasisaaniaaaiataniasniaiasatta=i3ss HE anes Roar `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NTSSTYUUBBIDJJIAEESCCTLTTRITTCOOT AACOPPURRROOTTT.EECNCTGT.IIVV2EE7-OOGRRu-DD1EE0RR.2E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00110044 aW_Notssseso 3M MN01538490 DRaetpaortFilDea:te:/va2r3-/Fcehbe-n2/0l004nsa1l2.:i21/021804.b/04912.G PPaaccee A Annaallyyttiicc~a.l! Services, Serv~ces~ lac?r~c TENTATIVELY IDENTIFIED COMPOUNDS T~NTATIVELY IDENTIFIED COHPOUNDS C CLlal~ibeennS~tupNNaa1mm de:e:~ 1330H4533EE3NN1VV73 OL O spaapemberpralSaetKzo~orLr oIdc~:~atKKiSS1oKK0n5:333173 ASSnaaam mlpplylese isM L MaotTacrytiarpxitex:io:: ~:WSWAVATTEERR Ana]ys~ Type: SV CCCllliiieeennnttt SSSDmGGp:: 1000:221188B000444-0120-67435 CSSSlaaaimmmepppnlllteee DDSPsaao~ttipeen::tI:D:1122E--0FFE4EB-B-0-21200200044 67435 DLDSeaaavttmeeepll:eRReeccLPeeooiiwivnvtee.dd:: 1133--FFEEBB--22000044 0000::0000 Level: LOW Number TICs found: 16 Number TICs found: 16 (CCuOOgNN/CCLEENHoTrTR~A'uTgf/IlKOOeNN) UUNNuIIgTT/SSL:: [u~/L or uqiKG) ugiL CcAaSs NNUuMMBBEERR TT21I. T6iI31557--T292222--0370 341 637-92 3 1708-31-2 65.. 311Ii711i017~-9-979366--6164-62-5 786.0 31314178198-775--01-6L4044---445 10589. 515195122---977066--770 11Li120i.) 11155022266---51127-7-5-66 111a332l] 071C--07-O206O-0--8-3o2O05--29 111i5654.. 757771146332--46353656--8-2522-7 16 54669- 89-7 CCOOMMBPOOUUNHDD. NHAAHMEE |P3rh~oyHpdyardnorexo,yx.y2--33e--tmmheeottxhhyyy-ll2---22m-behutuhttyaalnn-o|o| UUP|Pnnrukokrpnnaaoonn,wwenn~2,52--deithhyodxryo--23--mmeetthhyyll-| |EF|CtuEyhrtcaahlannnoe~eh~,e2xa,1n5,e-1,'d-~oh(xy1yd,br1i-osd-[i32m--emmteenttyhhlyopl|| [CB|Epyeetcnnhlttaaoannhneoee~lx,an222e,~,(222---dd(eiiltcc,hhhloll-xoodyrrieoomt-ehtohxyyl)p| uEt-|tnH 1hk-aenHnpoeopuwltene.nnee 2-(2-ethoxythoxy} |U9|T2-nrF -kiFnlbulouwo urorny rloa--6m6-i-nnn~ eittrroopphhen nooll T PP|hhrPeeihbnneuoonll<a,,nytlha22rm --enfinell,euuoorr9,oo1--04d---dnniiihttyrraoor--o-| EP||thBEhyetarnhnraanoonolltlo,h,(r21e2,-n-2e-[,[a44l---(9(11~i,,i,310l,---5ddd-iiitmhmreyeitdtahrhzyoyil-l|| Pyrro!o[l,2-a]- [,3,S-triazi rRTT 14.1.7o21761t9l 4-269 4.9i87881 4./8"/ ~555....292228823823 55.55.,.525708036260 6567.8..7808382s057 27770_..L10352557777 81.2781..536305036761 111353..091662225 15o125 EEsStT. CcOoNnCco. | @Q 511l..a88244|) NNNaJI_T| 5111i..6s49s)26| aWHJJTT] 22i17.7o.6.82126|] NNTo 222I00~~02606816]] NNNJIT 3228ll.o8s281881|| NaNNJ~T-- 2il9.a..84s473)8| WNNJio| 3911256o...850"0)]7 NNIo 337211.688.00)5| NNNNJJITT 37.8 `CHEOGNNONFEINDPEIFNNITCIDAOLEU-N-NSTSTUUYBBIDJJIAEESCCTLTTRITTCOOT AACOPPURRROOTTT,EECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR.2E6E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00110055 33MM_MMNNo011S5388449911 DDRaaetptaoartFFi~lDieae:te: /va23r-/Fcehbe-m2/01004mss1l2.1211/021804.b/04912.8 Remort Pace Analytical Services, inc Data file : /var/chBBeAAmSS/EE1,,0mNsNEsEUlUT.TRi~A/hL0~,31AA8CC0i4I~.D5Q/@U04A9N1T2.AAdN~D] HRAATTTIO RREEPPOORRTT DLLIaanajtbbawDSamfpptieleI1dd::~: /i110v0855a-33F~33Ei33B~11-h772e320m0i4lOm1s9:s4$4~i/O2{804~b/O4GC9lli1ie2ennottd SSmmpp II~D:: EE0@44--0011220@--667744B355 osO~ pnpeeprraaDIttanootferro ~::: KK11SS08ZK5-3[E3~3-1270304 Z9:44 IImns~tt !1DD:: 1lOommssssli..mi MMCSoiiom~spmcceInnIItfnnoffoo ~~:: i0533317~ RCRA 8270C - SEMIVOLATILES MMMCeeeot~ttmhhheoonddDtate ~::: ~/2/3vvC-aa~Frre/ibc~~-2hh27ee00mm0C/i41100- mm1ssS1:ssE1Mll4I..ViiOk//~k00Ai22Tn!1gI88L00~44S..bbi/SSQVVu00a77n--t004433Tyo.pmme: ISTO MCACaoallltshDDbaoDatttateetlee:::: 21112322---~F~eEEbBB---222000000444 22~009:::~4~455 kkin9 CQ~aaul@antFFiillTee~::e:004433I00S7T7D.~dd ADDIilinllstegbFFroaaatcctgttoloorerr::~: H11lP2.o0000R00T0@S0i Compound Sublist: 625.sub TTIaanrrtggeeegttratVVoeerrrs~siiooZnnP:: RTE39..5500 Compound Smbl$s%: 625,sub CCo@nncceennttrSaattiioonn FFoorrmm~ullaa~: AAmT[t *~ ODFF~* UUff *+ V~Et/i((VVoo ** VVif)) ** CCppnnddvvaarriiaabbllee NHaammee vVaallu~ee DDeessmcrr~ippttiioonn uoDeFF 11l...00O00000000000~ ng~DiiullnuuitttiioonncorFFraaeccctttooirron factor vvVUetof 1l!10~000000O0000.o,00000000000000000 VnVVo~oo~lluuuum~mmeieetooofffc~rfsfmiainenmaacplllteieeenxxettxrrtfaaraccactttcotre((duuLL))(ml) vVvioi 1l]..00OO00o00.0000O0O0@ VvVooollluuummmeee oiifnnjjseac~mttpeldde ((euulLm)}tracted CCppnndd Vvaarriiaabbllee Lhooccaall CCoommppoouunndd VVaarriiaabbllee 1870 RRTT A~REEAA AAMHOOU'~NNTT. tSTD +* 991~,,44--DDiicchhlloorro~bbeennzzeennee--ddd4 ** 4455 AAcceennaapphhtthheennee~-adll00 +~ 62 Phenanthrene-d10 62 Phenant hrene- dl 0 6.001 10.245 t0.2~5 12.767 1337006 2021525 202~526 1767471 3.000 40.000 40.000 Mo Nm olou Ww mwa SA usw Lesa Caos ea tena. xen uss `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOTAACPOPRUROROTTT,EECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR-2E8E8NN6TT2EERREEDD IINN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00110066 33MM_MMNNO011553388449922 DRaetpaortFilDea:te:/va2r3/-cFheebm-/2i0Q0m4ssl1.2:2i1/U21804.b/04912.d Pocan2.5.6smytr seri Eehane .10 ats3my Creve, 1 summiprepn {~c~o~exane~ {l.{-dimethylpro~yl - G 9 a amen as 0 nee os 4 ssnens FT on mens memsntenn 3,35 ding Sena 3-4 (4.1 dimnpr preny precoloit1 a1-11.5 tries. carbon a means ou aes oa uaese0.7 `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACPOPRUROROTTT,EECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR-2E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00110077 3M_MNO1538493 3M MN01538493 = - EE , hs 2-Fluerchipheny! = i 2,4,6-Tribroscpnenol (5) :.E. ve Fa ai 2] | of ol hres J " i 3 : ; ]: iyEsiEis: ii8i8l3H3 tH] 3 3 i | 1 j| og 5 11311}{ gl1a7;3 if CONFIDENTIAL SURMTECTTT0 ATPROETEGEE OREOERTENTERED I CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00110088 worsen 3M MN01538494 Lom ------ Ty Gri press ee oT a a EE Wa EE Te mms m NB~7~<.I iO0 . on 45 CM~3 59 EiEe. "~ = TT Int hl 2 ~ TER B B @ % me & % No #8 % % = a pe ioe Sl mal "ll nL es me me -- ST RT - jo " : HI M -- 5.0, E- i ~RS ~ RRR -~ = 3 E I E CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00110099 3M MN01538495 A S-- se oGany rnml Sglse ~K.I Lehn ,~75K~1 ~ 337~ wy fh LGuR z or EL ii ~ . fe Call Zl NN y --- ~0 Ce 3O | eoeo | [Bol i oo on ~ Bel wal ie Lon we jm T TSTET od Tle eal r | i eo hE a alli Dal AN * pn TM i ~~ FEANERI COUNTY DISTRICT COURT NG. 27Gunio26803 CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00111100 3M MN01538496 Sa~l~ ~o~ ~0~333173 , orem tent tote. 0 0 = TTR / \ / 0~0 z74 84% ~ || ,: { CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00111111 3M MN01538497 hLeero o-- n , I Sr R see = -- es--ot rte Sore Sot win si J EmeL wmm somnDogoeomoonn i 16326~98-0 N'BS75t<.I 17O~ ~o c~o0~ la hat Be" | | Hpa A L~ ol,, - EE ee " =9 t2o | Ne a| | dwemel ill. All a --- RTT Eh aN i | en L- | = er er g to Vad | = ~ ia. etlel, Wr hlLo - SE CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00111122 3M MN01538498 ove fren aes 4 rentett -- nie wy i tamale ---- - PERNT Beg, im om-- 2] i. a i ll I. IN NT pm ew - TT TT Ew 1} w ol lml alf Cl l Nm ~ ees = rT ; ideaCo l = sm fr em mee Ee oo , Bo : / Baw SN ( | A Tul J alles om nm | ethyl Ns ~o 50 60 70 80 ~ i~ i~O I20 130 CONFIDENTIAL SURMEECTTT0 ATPROETEGe E OROET R ENTERED I CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00111133 worsens 3M MN01538499 wLienotiaren 1 teen ebortoeset vS aiEs s neiu = o ll TEeMo = po rR aa ves oe to i+ PM nEiNr mA. dUFe a ~ / isos sgn o 3NL Es I2 em aa ed Le I cof E oor N= 42o, a ihl lalla rE.) LN = pp |bo ww om - ee Pl HECIlN l| b|e JN- ne ' pVed o rT i. ~ in pa edltehIL libp lIl .e LL N =e COSNFIDEENTIAL - SUBIECT T0 A PROTECTIVE OROER ENTERED CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00111144 au orssesoo 3M MN01538500 A jJ enset na -M~rf~ol el r mfSeegartoseNae ~75-~8 0 N~S75K~I 56~ nT | at ny LiCkee EGpEs R 38 C~HI~2 131 iene = "~ TM - or ol Mol hh ae - Tp TT :. N .43 ~9 ~ i. no | EN | =~ a = Se Dail ddd ds TN ET = 2~ ET TT P |e ew . |Vaid ii..Soa sl| susnNe onNL od"e wo TR Ro :: Lo | 5- 29 aov o77 n2l PANaa den Lone GNONFIEDENTICALO-TSYUBTJERCTITEO ASPoROaTrECNT37IVEuORrDeERzeEsNeTsEREDIN CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00111155 swmorssesor 3M MN01538501 son a dist ene Wenrirm eatnt ie Soe ges ge St Ttaeg teisirti, gs th~ol, 2~<2-ethoxl~et~ox~>~ aS REtNaoSehsWeen ST yie e 2 = rE ------ Bie - i= dh Nd ~dls oe ~ TT RR fe 14 eo = ~ |pe --- ws wi wellh a ?hdle L MT. L 0 -SS< .ii. .. oo io EN ol all il 1 | OON ~ pe eo , ol NC A COSNFIDEENTIAL - SUBIECT T0 A PROTECTIVE OROER ENTERED CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00111166 au orssesoz 3M MN01538502 SL sides tt oe re Sr J SARE re Sim E ST TEaTT = a ol aol ol iui WS yreedst ES a . LL Ladd Yay " 1 pve Re - fre prt anal. ini Twante2 7 Eiwz - iLP o | J | )Il ll| rE . || A9~ ~a eS 0D TTT Eo 3 : Ae 72 RR hy "| - wll ws . A SLA TNL Reeen ms CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00111177 J 3M MN01538503 Cem me men = rrne for wig wn son 0 ~ o Tr -- FtlTI 7 A2 ull "| ~~ r - se i o " e rs ET TE eT CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00111188 3M MN01538504 oe t-- iy evencop rn pmuaisrimcmteannd -- ora x one Uber oiry aati fomis ee wTweesr mwwommwaas m ammmwvhewmmewow TST = ii ps | ~ | moJa wo sip ee l dialle le N2T Ld .TM, t| -- I TAT TTR = g ~= IA S TM ls Nw ne 7,oe or TTT poe 8ioo ~o fi eo oom | oo I Nwa [A- oodles plone Jd i. -- Te TT TT oe . Ze , E. = - : i. ~ | pp ol EELgRR| Aoh w ieMe 2~) 30 40 ~ CCROEONNNFNIDFEEIRNTDCIAOELU-NN- TSSTUYUIBBDJJIAEESCCLTTTRITTCOOT AACPOPRUROROTTT.EECNCTOT.IIVV2EE7 -OO0RR1-DD1EE0RR.2E8E9NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00111199 aw_morsaasos 3M MN01538505 nT rr e---- drain meer i i Ih ieo norms J | a SBELE ES o_o, fn me Yom e wEoke n Ed E: ool PA A be G0 ml on = a ERew ae fem me ie me km 6.04 - be cose) Lop -- 2O 4O EE 220 aw P ero ln gl ~ um mm om me fro oR TT RT |r "| Efoe ~| ~ , |ooolo alipAl~ eN gN l C All DE ad= Gili NE COTY TRIE Soar N37 ure zeses CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00112200 3M MN01538506 ---------- ev Sp i eal Ar ( - RR p-- od = a ge a Lo bl th VL LF - te Se = eo ii. w~ | wa Iso ol ey ANS et Le - rT -- od - - So i pe 1f2.y0 a~l" hddgedl ANCA LNw.n, ow ro TTT RE -- ii5 oo me nda Nnnie om ool ual lon Mad WC 1 GFEOANNEFRIICDOUE-NNTSYUTBDJIIESCATTRTIC0TAPCROOUTRETCNTGI.V2E7OGuRnDiEoR26E8N0T3ERED CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00112211 swnots33507 3M MN01538507 i naph--i--n be ra it iene in rien aniline Ea rT ---- 5i. mt me oo ee e e l de d= - RT 2E,o i: te Cspeemn = RR TT ET Bi. la = T~V~ ] om mm- | fe = wo 10 ry Mo 1k we me me #6 ]| i ae GNONFIEDENTICALO-TSYUBTJERCTITEO ASPoROaTrECNT37IVEuORrDeERzeEsNeTsEREDIN CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00112222 swmorssason 3M MN01538508 se tints AT rarer me ---- wo -- ta. ouny --n s fmeiCe oce------ | yotr o--m -- m En R mom - RR 7 9 : o- ie2a) t boolaopNtT Pn e|deLUN po TV Tn TT Ty 2 = 1f} =e laaMfm e m Nhed e|t ~) ||e pe TE TT TiFr oe - bn Osu | CL -- RT TE oe ~~ es -| ) ol ih f fAelpm ete ady "~LSlob |la"id| aToYn HCOENNFNIEDPEINNTCIAOLUN- TSYUBDJIECSTTRTICOTACPORUORTT.ECNTG.IV2E7-O0R1D1E0R.8E8N6T2ERED IN CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00112233 su_woresssos 3M MN01538509 Mims eme R Ea ei roe an re nes RoR RE Ci SR Y SaErs wo A oe See we ne ee ME SL TS = rT [ ge oS: i.i oar | g|h x d rT TT RT ies EEE Feel wr en rrrpee mae re Te ~ 100 120 Ea 15 0 eo Fo 2% 0 I& sof oy ns EO en NER ba h ope CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00112244 3M MN01538510 we - cp SILCTORTEPEEIIIRRNEERRRLRRNNLLIIIIIANNEIILALLS i e= . FH TTT TTT gil ee H reemee 3 of gv 5) + sr | l 8] ei}l| s i ; li s [4] CCHEOONNNNFEIDFPEIINNTDCIAOELU-NN- TSSTUYUIBBDJJIAEESCCLTTTRTITOCOT AAGPOPRUROROTTET.CENTCIOTVIVE2E7O-O0RR1D-D1EE0RR.0E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00112255 FE 3 E | i| sumotsssisi 3M MN01538511 Repor~ Date~ i { ::~eb HO04 IS ~l TEHTATiVELY IDBNTIFIED COHZObT[DS Lab 8mp Id, 1053H. 316% Opergtor : KSK Sample hocaElon ; Sample Mat fix : WATER Analysis Type : SV ~u~ber TICs found: 14 Client SDG; 021804 Client Sm@ ID: E04-0120-67438 Sample Date: 12-FE8-2004 Sample Point; J ---- Date ~ceived~ Level: LOW CONCENTRATION t~iTS: {ugiL or [om] CAS ~TJMBER | 17 111155-52222-700" 584-03-2 565-75-3 922-64 5 6 107-86 8 7 111-96-6 ]1] -90-0 110-98 -5 1o 629-06-I ii 1526-17-6 12 1730-37-6 13 ~ 00-0 14 2315-61-9 comers COMPOUND |3T-hHyyddrrooxxyy--33 -mmeet<hnyyli -"22 -bbautta~nnoo| i, 2-Butanedioi Pentane~ 2,3,4 <rimethylPro~anedintrile ~ Unknown 2 -But enal 3 -methyl Ethane~ i~ l~-oxybis[2-metho Ethanol 2- (2-enhoxyethoxy) 2-Propanol, i, l Heptane~ l-ch]ore 2 - F I uoro - 6 - nit rophenol l,l-Doxolane, 2- (4-methoxy Ethanol, ? [2- [4 (1, ] ,3,3-t mL EST. COHC~ Q 1.771111 11.o6666) NI 538 2 292 4 48 516 3 o12 787 4 988 2 o 71 5 22~ 5 73O 2 6 ] 6 897 14 NJ 7 156 io92 12 331 31_6 13 962 156 125 51o8 CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00112266 3M MN01538512 DRaetpaortFilDeaste/:var23/-cFheebm-/21000m4ss1)2.12i1/021804.b/04s11.d Repo~:t [}~te~ 23 Feb-2~ ~ Pace Analytical Services, Inc. Services~ inco Data file : /var/chBBeAAmSS/EEl~,0mNNsEEsUU1TT.RriAa/LL0,,31A8AC0C4II.DD5Q/@U0UA4~N9TT11.AANdN[D) RATIO ~ATiO REPORT REPORT DLLInaaajtbbaSDSmamfptpfel~TIdd::: /I11v@80a5-5r~F3!E33B33c-11h266em055i04 18:50 CClliieenntt SSmmpp IIDD:: EE0044--00112200.~6677443388 osOiptnp3eperraaDItatnotofrero:::: KK11SS80KK-5F3E3B3-1260504 IInnsstt IIDD~: 1l0omme~ssil.~ii wCSMi~oisspm me mInlIen [nnoffoot::: I@5333&65 RCRA 8270C - SEMIVOLATILES MMCMeoewettt,hm hhooenddD<ate :: 2R /3vC-a~Fre/bc8-2h72e@ 0m0C/3l0m1sS1Es:1lH4.IV i/kO0k~2ihn1Tg8!L0E4S.5/SVQ0u7a-n:043Ty.pme: 1STD CAH CalaellsthbbDoaaOtttateetlee:::: 21111B 22---FF8Ee3Bb---222000000444 22[00]:::t44455 kking Q CC~au]lanFF: ii~lTeey::pe:006433IS00T77D~.d6 ADDIilinllstebFgFoaratcacttttloooerrr:::: HI1IIP.~0000R00T00E00 Compound Sublist: 625.sub TTIaanrrtggeeeDttratVVoearrr:ssiiooHnnP:: RTE3.50 Compound Sublist: 625.sub CCoonncceennttrraattiioonn FFoorrmmuullaa:: AAmmtt ~ * DDFF ** UUff * * Vt/(Vo * Vt/(Vo * Vi) Vi) * ~ Cpndvariable Name Vvaalluuee Description ovDeFF 1.11,.0300C00000000O0 nDDgiilluunuitttiioonncoFrFaracecttcootrrion factor vUVvoeft I1~10000000C000o0..00000000900000000 VVnVoogollluuuumnmmieeetooofffcorfsfriiannemaacplltleioeenxexttxrrtfaaraccacttctotre((duulL))(nL) vVvii~ i1]@.00~C0c~0000oO00~@@ VVvooollluuummmeee oiifnnjjeesaccm tteepddle (ul)extracted (~L) (mL) Cpnd vVaarriiaabbllee "LLooccaall CCoommppoouunndd VVaarmiiaabbllee 1I5ST1D0 RRTT A~ REA AAMMOOLU~NTT * 5 1,4-Dichlorobenzene-di ~ 9 1,4-Diehlorobenzene-d4 + 6622 PPhheennaanntthhrreennea--dali0o 66..0O0011 1122..776677 11442277555577 118877~8228833 33.o000000 ~400~.000000 `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBDBIJIJSEAETCCLRTTITTCOOT AACPOPRUROROTTT,EECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR-2E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00112277 33MM_-MMNNO011553388551133 DDRaaettpaaortFFiillDeea::te:/!vvaa2r3r/-/cFchehebem-ml2/J01t00h4nmsoss1]2l:.2i.~ 1//002211880044..bb//0044991111o.@9 Pipusnsiniriie, sethyane ase as PR -- rcpt. 3am 2 river & nitromaned en ame as a ems 6067 oe a sssene `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACPOPRUROROTTT,EECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR-2E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00112288 SM_MNO1538514 3M MN01538514 RJF SERCERRLOSTERCILECELTIRERODSRLEIRERERCECINEL oe, . =TTI a . eae tanita J Foipiriniyyt pnHiigtissr Hti HH EL : Fairer5 le rosie vs oraz .v a" restos of x iil l2i eFPs. iH Hi10 n; ; b 2 a `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTYUBBIDJJIEAESCCTLTTRTITOCOT AACOPPURRROOTTT,EECNCTOT.IIVV2E7E-OOCVRR-DD1EE0RR28EE8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00112299 _MNO1S38515 3M MN01538515 rje us-- ti-- n Com oes vs pe Cg po SrTonto simmons tn acorncseoars 98 are vy | Colu~ ~ia~eter= wg0.25 wigs wma we ny ors in ger 2 - RR ge ~~ in: Ndls om pe Tg RR i+] =~ i] ~ " |waNle lla NLrNem Nie ee | - TR A BE 1 | "- | \ i.deE f~e alE |e le Roe l| e ~E ese | = TT o t wo po i. on AlwlNdG N\ = | r Al e A r CCHEOONNNNFEIDFPEIINNTDCIAOELU-NN- TSSTUYUIBBDJJIAEESCCLTTTRTITOCOT AAGPOPRUROROTTT.EECNCTOTIIVV2EE7 -OO0RR1-DD1EE0RR.0E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00113300 suumorssesis 3M MN01538516 oe ------ srr oe -- --_-- Tw fo - oo 2 2. --i .= Eo 2E oo ieosdie tg ~39~ ---- ~ -, " EE ome No ~ - Le Jodlte NeTtl, Tu gn B.ip. GNONFIEDENTICALO-TSYUBTJERCTITEO ASPoROaTrECNT37IVEuORrDeERzeEsNeTsEREDIN CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00113311 rp ---- 3M MN01538517 jAoenviesri oh A mem wa pron arenes sun srgmin ogra Sy Gry uity Fenian pSr U -- er J Tw m --oIvo n o= = eS RR ;2.ol - : | I a ol--ggiilAebbegrpeollned] NA LAre Cw -- ee TAea Tn WD Eo " aol " Feeedl TMitll| ll - -' -- NL oo ~ . col Er heot elelll om{7emw ae ~ --- RT rT AS BSele ~ ' Ht | ol, adil, 7n. N sn " CCHEOONNNNFEIDFPEIINNTDCIAOELU-NN- TSSTUYUIBBDJJIAEESCCLTTTRTITOCOT AAGPOPRUROROTTT.EECNCTOTIIVV2EE7 -OO0RR1-DD1EE0RR.0E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00113322 sw umorssesis 3M MN01538518 on repr comps hpra rp ers agtm 922-G~-5 Gh NB975~oI el relrv linc Wn wee ~2~5 7~ - Sg 00 go Eee , oe H7 eoe gtN i frrpro~p | IA[N i= tt - TRA Ts 20 ~ : : . fe " BeHe deweeSlam TTR 78 i i Bol eoeens m=ls l|le ~S~ e NLl | PN . fig . ke | | | j| nl|| || || GFEOANNEFRIICDOUE-NNTSYUTBDJIIESCATTRTIC0TAPCROOUTRETCNTGI.V2E7OGuRnDiEoR26E8N0T3ERED CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00113333 swoss3519 3M MN01538519 Sari Cilew~t nt~D~ oI Von tects 0: 1.0 fe ---- Litany sare Conn ten Greats 5x Coton ater: 0.58 Gomme Uy Ges Gali emis eign -- To a eo thCERGATTaWE adi WRedea WNRAwN e www = `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIJDJIEAESCCTLTTRTITOCOT AACPOPRUROROTTT.EECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR.2E6E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00113344 IWMNO1838520 3M MN01538520 oe eit v3 sinoo ore J oe air-sea a wSaynde I07-8~8 -- wsrois NBS75K.~ ---- NBS75K~ wm r o8 ~2726 38 ~7 P22F mwee a C~HSO 84 -a C~HSO 84 : | n\em (om I 84~ 3? oe A, J | J LL 1 bo fm, me Fo TER TET i EEN i | na ~ |- ----- TTR TE g> |~ nN | :- i. - ol I Wl 2 |- = TE TR 1 co . y ; A3aol lA lama| " 1| | en CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00113355 3M MN01538521 oo Eons f---- O~er~to~; KSK ern Sore i ens a roe on ant wm mb mn E=Cert. honeoro I a. nam om i ~~ sol oo al. - eb slla wg 1 e NL sTeoeee -Is 0} 2 ol a,\ Lo =dsl das C~ ee o - rr i Pele = so i "of Bee oo Al ee my es ee PR , hu - os lplomh on nom eee CONFIDENTIAL SUBJECT 10 A PROTECTIVn EORDEe R ENTERED CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00113366 wwnsesz 3M MN01538522 ~a~e ~ iS-FE~-2OO~ t8~50 en em Clie~t ID~ E04-0120-~7438 S~ple ~o: I053331~5 A tn ps ve rrco:yar oy shun wn RI ua) m0d.weomnwt IIi-~--5 N~$75K~I ooh60oe8n~m n7 ommmemes ~8 C6M1403 - ER Rm oo 2 pd Fool JZ~ ~59 / d| D ~\ NA EN -- TT TEA RT so om : : =o! = | | IN | on od whe ad le Mm NT ee wo TR TTSR AT Cn TT SE ela 2 wl IN I| Lf meae = er rr ee ' Vane/z7 nal s~x al aN ae STEEL TNL OReRn : CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00113377 awmises 3M MN01538523 eset SI i he Seay ie = |gII e - re te a mis m rSsL m mm mHGO BESaGLmunoLn i fie . - JL L a = rr nn 5 a. EN io || - ll des 0 Le mm - TR A te R - P SeN E lo bl deE L{"oe le. m eee o | ;po , { i hr " fo | Bde Lullee a e eaeeeeeeee COSNFIDEENTIAL - SUBIECT T0 A PROTECTIVE OROER ENTERED CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00113388 aw orsseszs 3M MN01538524 wr fri rn | oh ste pris ip Coane sg =Tres ~utene~ Z-methsl~ |-oo nM S m ow, paw 2 fons 14~7-79 4 wm ~S7~ ~ mew 205 ~ owe C~-~42 om 70 =~ i : = - abllh pt ZZIL LTM Pad po A Hed JT : I = i ~ | dea ler /93 lle mLoR = : TE . EL Bae # moa = " -- l rggmeil a g | ee 83 , i 4wdl 1 [ hlNn| - GNONFIEDENTICALO-TSYUBTJERCTITEO ASPoROaTrECNT37IVEuORrDeERzeEsNeTsEREDIN CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00113399 swmorssaszs 3M MN01538525 wermie moni e mgm soiree SRT 2-Fluo~o-4-nltr~l immn an one to rn ws ven Cw gent SR mm dm 8 nm ow TOT - 1 ull dro gie S; ~ | ~ pe ~~ / wo Er A --&~7~ 6 ~ oN a20 L e~da| d db NJaTma fAT e | - RTT RE = | . ~~ = Foo ao ow | - I Noms Aa | eg iglteian a stilRalRloT g n JlT i W RlC R n odL g | B- oo Eo 1 , | Ei.ool A~CLo "= | en m p tL COENAFINDEEPNITICAOLUNSTUYBDIIESCTTRITCOTACPORUORTT.ECNTG.IV3E71OR0D2E8R8E6N3TEREDIN CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00114400 swmorsseszs 3M MN01538526 e--t -- NC I on Soe wy po -- : wor ne oo wn a wm gE || W 20 d=~ NN mTon pe = -- Ln i.MA ENEL-,N "~TMN 1 FL WaN TM en CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00114411 3M MN01538527 a tort nt Erie - fm ------ do o_o AE i Tn EomRE Zon -------- eo8~a4 iE, Ea ii. L~ed NNnN A gel oeTe = EE Tr OR to = fof om (7 ee |. po wohl lo dd la rsh LL = A lL] in iPo NieCeem N tp Od LN pe ee] |e -- TR TR s.0f - / 7 , JAA L PPS EENLL| L" ma wo, GNONFIEDENTICALO-TSYUBTJERCTITEO ASPoROaTrECNT37IVEuORrDeERzeEsNeTsEREDIN CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00114422 swmorsseszs 3M MN01538528 Be rn sents aa won I oi oy o_o r S rigei yall a Wg wm ony mmmREom 223 Le I. Tes oo | IAlIE CPalraad d ws mnman | o/ ~ 5 TE ER TT Beed i ly dn g p eget LEB Bits oore] Fr TTS a SS Se TAee /435 ee fe | |- _-- TE ET feo ) Fed aN uo, | wl LCE Am L "| 77\ 2~04 \ O oOJ - we me we We me ae 2 =e @e mw NE COTY TRIE Soar N37 ure zeses CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00114433 3M MN01538529 ELIESI SH | Taser TEESEE - coe SSE + iF HE - 3 .- ee | 3 --_-- 2 ot --- || | ge x ol ol| El +| +! `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACOPPURRROOTTT.EECNCTOT.IIVV2EE7-OOCRR\-DD1EE0RR-2E6E3NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00114444 3 yJ g : || i _Mo1s38s30 3M MN01538530 iCeport ~ace: 23oFeb-2004 22:20 Pace A~a]yKical Services, Eric. tENTATIVELY IDENTIFIED COMPO~:DS Client Name: Lab Smp Id: 105333197 Fa Operator : KSK Ray Matrix: WATER Analysis Ty~,e; Client SDG: 021804 Client Smp ZD: E36-0120-6743~ gy Sample Date: 12-FEB-2004 Sample ryDate Received: 13-FEB-2004 0O:00 mi ee Level; LOW Humber TICs found ~ 8 cern | CAS ~s~BER mmm | ow COHPO~D N~ME RT mom] EST. CONC~ 21.0 7171955--2820--04 2 7795-80-4 [3|2-3-H-MyHedytrdhoryxolyx-y-2-3,3-3-m-mepetethnhyytlla--n22e--dbibuoutltaannoo| 2-Methyl-2,3 pentanediol 131 .5o77211500 3 o 11103s35))8 Nnoa 3 565-75-3 Pent~neo 2,3.4-trimethyl- 4.292 ] 60 922-64-~ ~ropaned~.nitrJle~ methylene 4 492 Unknown 4 o 786 I 41 6 615-29-2 3-Hexanol, 4-methyt ~o199 9 93 ? ilI-90-0 8 592-76-7 Ethanol, 2- (2-ethoxyethoxy] 2-Hepten~ 5729 6873 2 36 CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00114455 3M MN01538531 DRl_ae~tp{aotartP FiilLleae:t:e: //vva2ar3r.-/lcFchehbee-m n2//0ll0t0)4m@ sss1ls2l.:_i2i0//00221iS80044 .b/04310.d b,' %Q910.c Rep~rr~ bate 23 -Feb-204 12 : 2@ Pace Analytical Services, Inc. Pace Anatytice:L Services, Data file : /var/chBeBAAmSS/EEl,omNNsEEsUUlTT.RRiAA/lL,0,,218A~0CC4T~.DDb/QQ0[U4~A9NN1TT0.AAdNNDD RRAiTTIIOO RREEPPOORRTT DLLInaaajtbbaSSDmamfptpieleTIdd:::: 11i1800v-55aF33rE33/B33c-11h255e077m0!4]01m7s:s5l7_n/O21804.b/04CCl9lf!ife0en.ntdt SSmmpp IIDD:: EE0044--00112200-6677443399 oSOINmpo]peerraaDItatntofoeror :::: KK11Ss08KK5-F3E3B3-1280704 17:57 IInnsstt IIDD:: 10msel.i MMC5iioms~smccmeInnIItfnnoffoo ::: I05333!57 RCRA 8270C - SEMIVOLATILES MMMCeeeotttmhhhmeoonddDtate i::: R2//3vvC-aa~Frre//b~cc-2hh27ee00mm0C//4~lOo1mmS1ss:Ess1Mll3Io.Vi/Ok[0LkO2Ai21Tn18Ig80L04E4.S.bb//SSVVQ0uOa77n--t0O443T3y..pmme: ISTD CAMCaalollsthDbDoaaDtttateetlee:::: 21110322---FFFeE~bBB---222000000444 22]~001::.:441554 kk~ng CQCaaullantFFiillTeey::pe:094433I00S7T7.D.d4 ADDIiIinlsltebgPForaatcacttttloooerrr:~:: H1iloP0.O0O0R0T00E000 Compound Sublist: 625.sub Target Version: integrator: HP Target Version: RTE33.5500 Compsund Sublist: 625osub CCoonncceennttrraattmioonn FFoorrmmuullaa:: AAnmtt * DF * Uf + VE/(Vo + Vi) * Cpndvariable Name ~ame Value Value Description Description ouDFtP 11l..o00O000000000000 nDgDiilulnuuitntiioonmcorFFraaecctctotoriron factor vVvUoetf 11!] 000_00000000...000000000000000000 VVVnoogollluuuummnmeeiezooofffcosrffariimnneaapclllteieoeexnxxttrtrfaaraccacttcttoer((duulL))(mL) Vvio 2i.000000,0000000 VVoolluummee o{fnjescatmepd%e (eukx)tracted (mS] Vi _.OOOOO Vo]~mle ~t]3ected (uL) Cpnd vVaarriiaabbllee LLooccaall CCoomnppoouunndd VVaarriiaabbllee 57D RT AREA nMoUNT +* 9S 1I ,~4--DDiicchhlloorr0cbheenn~zeennee--dd4d * 26 Nephthalene-ds 66 .000000 77..558800 11332200778822 11778899337777 3.000 4400..000000 ny mth 3 anne 4 sare `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACPOPRUROROTTT,EECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR-2E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00114466 33MM_MMNNO011553388553322 cars oo tition "rove Pr01660/Q" 408TZ0/0T2":2T18SUO0T02/-UGO0YdD-/LZA/ 9381 13TTS 3aodoy TILA CCHOEONNNFNFIEIDDPEEINNNTTICIAAOLLUN-- STSUUYBBDJJIEESCCTTTRITTCOOTAACOPPURRROOTTT,EECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR-2E8E8NN6TT2EERREEDD IINN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00114477 33MM_MMNNO011553388553333 | | iilt HiEnHk ti is} 3 i . ` . L e J 1 # a| ans eed? || . a .ol i 3j.Bi815e, j1i8i1s3s1s8 gen 3B3iEl3edsd |, rte amr.8) tovayd1o -078w 2 mind -E pomon. ry - = 5 yyy esr res ery ying - `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NTSSTUYUBBIDJJIAEESCCTLTTRITTCOOT AACOPPURRROOTTT.EECNCTGT.IIVV2EE7-OOGRRu-DD1EE0RR.2E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00114488 aunorsassas 3M MN01538534 -- er ------ me et SA apnea nrmer T swnn ewsrtonig moiwse in N~S7~K~I ~477 78 CSHE~O~ EO~ N~ST~.I ~ ~ 04H9~ ~7 -- rp io so~3 / te ENA =~ Fe BEEN poTR Rm CSgy OOB 6ow mom wa % Tr TR Wm % % wm 3 Nr i. L~~oon ~Wl nl om .Ne ee --I I a aa rg a a ro iiI L Ses o ee ~ee = ": ~ ~ 35 pT ~ 45 bO ~ &O ~5 70 ~z 75 ~ Noee 8~ ~ ~ 0.0 =~ I , / i i oo wl e th e l~ ~ NG ~ ~ 35 Ag 40 45 = 7 COSNFIDEENTIAL - SUBIECT T0 A PROTECTIVE OROER ENTERED CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00114499 au orssesas 3M MN01538535 Sa is--e------rer ePermT ioreten JwE re Tonl NBST~K~I onTE Bm NBS75Kol ~E~ ~477 a ee Lom on = TR 8~O El a i Aros roam / 84-, ps EE R A 7~ 75 ~0 85 9~ 9~ i~ Eo i.of oo [lI L -- i id Glo ~~ " tly Nil i or TT R T TT . N =~ | LL nl es om Ne me , || | | CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00115500 3M MN01538536 wrongs stmt enor ii For ier wns wwe wn om ew wo gg -- f& ie.e Lo w oa abl 2 AN me om" ~0 a ~ ~0 7O 80 ~ iO0 lpeo. n7~n fl lo wr dem ah bl e LN % 20 ~0 ' || l NE COTY TRIE Soar N37 ure zeses CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00115511 | | || | 3M MN01538537 Treo srr en apueairin, sie: Gon tn Gary arity Femi mas wma amon ween : Nn -- ST -- <SCALED> | oo! | Ee oa I 2.0] ro pdb. 7 I7h" MN. |al -- rT A TR al ~~ lz +ool a EN =~ ilth 2 le ie | pNtt lL Mp -- TR TE i. Nom Al aes lls 2 ll NALIN CCHEOONNNNFEIDFPEIINNTDCIAOELU-NN- TSSTUYUIBBDJJIAEESCCLTTTRTITOCOT AAGPOPRUROROTTT.EECNCTOTIIVV2EE7-OO0RR1-DD1EE0RR.0E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00115522 Sw umotssesss 3M MN01538538 st resign re rn = CS Sty os Fo1 l r mo. | Ia/ . nNe A eee.~ee7n 42 SE CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00115533 3M MN01538539 AA ae ewe 1 apm von sa Tovomerr mereenn p---- ~-But~cl. i-mebbox~- mr cn ot ss on sn sn TooLw omumommom oeonunomooem on 5377~73-7 NBS7~K.I 190 = SE io0.0] |-, i"o : i Ladle N dlle0 .y BEI I EEI EE oe Tr VE SSeT o (re TT CRE co Pp EHePe ill I "il ENE& = TT r-- ee Eee ie 2.0} i. TM . A-l , de =~ apm a AL fo i ; we -~ s | ~ | | el A TE ow 0 em wwe ie RR CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00115544 3M MN01538540 en teen ars 8 sie seers mien [ Sovmeiar cteoor-- inns tens ome nw Gy Suiits min Seige a wTsr ww --s R o ew -6 owMeemeooaw geo 2 oo oo : ab sh deo me g | -- TTTA TrTE :.. ~ [feo | ~N 1 =eo aa del iya oN soon me --E C EE TE R TAT C Tr RT igE evol n- "Ea all ie oo . LONE Ps TR TT WR CRE feAof n Ne ENalemwLNA `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NTSSTUYUBBIDJJIAEESCCTLTTRITTCOOT AACOPPURRROOTTT.EECNCTGT.IIVV2EE7-OOGRRu-DD1EE0RR.2E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00115555 awNotsssset 3M MN01538541 wen pea Cau va: Sh 43 trarySeach omen ot aCovonamet13e0rs 0.8 Gono ners Eu ee etn Neh wma Gas wo ES -- os = kf bad 0 Fee Ee pos RT TE Eo ch Focele --~-- ~ I. |AL I ll .SL 2 ~ Tg Te TO RT ran goo [oe I AL Lull 4 aati Peis bet ow om 7 | = | ee 1 Eo . " | Ze EN R A TSS R ew `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITOCOT AACOPPURRROOTTT,EECNCTOT.IIVV2E7E-OOCVRR-DD1EE0RR28EE8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00115566 M_MNO1S3Bs42 3M MN01538542 RPaetpdortFilDea:te:/ch1e5-mM/aLro-m2s0v0d4.i/120:2218704a.b/04812.D Pace Analytical Services, Inc. - H MiinnnneeSs@ ottaa T~ENNTTAATTIIVVEELLYY IIDDEENNTTIIFFIIEEDD CCOOMHPPOOU~NDDSS LCalbienStmp NaImde:: 136M533E3N1V40 OspaemrpaletorLoc+ atBiNoLn: SAoitmlypslise MatrTyipxes: VUONRTER CClliieenntc S8DwGp: ID0:217E0044a-0120-67434 CSSS~aaaimmmepppnlllteee DDSPaamottpieen::tI:D:1122-E-F0FE4EB-~--02210O20O044-6~434 DLeavteel:RecLeOiWved: 13-FEB-2004 00:00 Leve ! : LO~ moe FiCe tounds 4 (CuOgN/CLENoTrRAuTg/IKOGN) UNuIgT/SL: swings 453: 55036-1 1-1 | covooum wie a | moro | | sasmerncossommnmmmmsemanen|==sessss|ansssmnsazazs lan0ces |Uunnkknnoowwnn | Unknown 21..946245 8.e3s)| NNoI__|| 5.031 fo] Ran 5.641 a. NT] CCHEOONNNNFEIDFPEIINNTDCIAOELU-NN- TSSTUUYBIBDJIJAESECTCLRTTITTCOOT AACOPPURRROOTT,TEECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR-2E8E8NN6TT2EERREEDD IINN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00115577 S3MM_-MMNNO011553388554433 bata File: Jehen/ionert. 21700 B/08612.0 ] DRRaeeuppaoorrttFilDDeaa:ttee::/c!1h55e--m~M/aa!rrO--m22s00v00444.~_1i!.~2v2"::~~2276604a .b/04812 D 3 face Aslyiical Services, Tne. - Minnesota Cit Lo IEitie EeeDnRStP-~=n A0x00al02a 5< 3o6...0h.8I SvMeoOruvnRirciIez2seiA%exneIenscoRsTop Minnesota zo: moa-o120-67038 nae 10: tomers ID: E04-0120-67434 20:}0 ID: SSAeE FsEacRon LvoOuRntIius BwsvNoss pvoacsote.m 8260B VO~ATILE REPORT He. | I i re, 1am /chemi!Omsv4.i/C21704a.b/Ve404040.m See | She otis ELIE 15-Mar-2004 12:!7 rmchnobr Quans Type: ISTD 10-FEB-2004 02:45 Ca! Fi!e: 04007oD panel 38~2 BPElReEiRn aVoohwoo compound Sustiss: allo ~,OOOOO HP ET~ Co~ou~d Sublis~: 3 ~0 GPonsenA tratiR on ForFmualhaesnemnnt DF + UE * Vo + Conaciable Concentras!on Formula: Amt ~ DZ ~ Uf ~ I!Vo ~ wae vase sescripsion Value a Tae Siiuion reer D? _ 0OO00 EFA OREN ERNESERS U ~.00000 cond vas Lible Loca Componne Vasiasie .:.; .ODOD0 D~Ut~ ng u~lis correction factor Samole Volume purged (mL) Local ComFound Variable x+ m43 Fruorobenene ew ss s sss m20o.00n0 ~ 43 Fiuorobenzene 4+905 701598 20.000 CAS = 6957% 43 ~B CONFIDENTIAL SUBIECT 10 APROTECTIV ORDER ENTERED I: HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00115588 hs 3M MN01538544 DDReaapttoaartPFiillDeea;:te:/icchh1ee5m-miM/1a10r0m-ms2ov0v40do4.~i,/1'0202:21216770044aa.o5b//0044881122-.E0 ii Report Daze: 15-Mar-2004 12;26 CC Flag tegend L c..p..sa~tteor~ selected ~-e!.~,<:~ree aann a~lltteerrrn~aattee library library search search match @atch. `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEEASCCTLTTRTITCOOT AACPOPRUROROTTT,EECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR-2E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00115599 IM_MNO1538545 3M MN01538545 = ------ en et srrrprsntaignnaty sr: r aie Hi 4 [3g |e --_-- a a I3[ [FiEeah Boa fr if2 1 i It l e - fi | BH -f 4 TLome Tuten (31 A3 bB[ie=d ins o 3 [+f Erion = L|Iu=sd } |! a `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACOPPURRROOTTT.EECNCTOT.IIVV2EE7-OOCRR\-DD1EE0RR-2E6E3NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00116600 | iad| W_Mo1s3sses 3M MN01538546 aR SLeothn Rr z ey Epr s a LL Sn ver bey s y nls m y a netm 5 gee be -- Bog5 aif be ole a = er eT ii -= f2e] A I i= Ty me pee LL fl si om 2.0] a on i lL Al : Il. ENJig > A a Fi iElli = Shayne ~ CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00116611 3M MN01538547 Es SaEna tRi y ha mr --------w -- = rLeErbin R Reais S SpEgLfoGeE RT = Ee 1S2 wel - Th Lh = i RaR riR l mielLe eop i : 2. ER = 3 -- A. 1 J 1 TTB B ow HG % om GG wm Hw ae 0.0] . id Eo = ~| foaf Ii Sdy sl Sv b -5 = rr a gait 3ao Jlh i il ill lI i CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00116622 3M MN01538548 Sa~ele l~o= 105333i81 eS seheseoHnaedne--s i ~oZume I~je~te~ (I~L)= i Srrn mrs mWEmN or hs fs vi a ge nig gm a270 70 = ATS fo Ie o~ ol 1" iEL a aE | - -- Se iI wo ~~ [ a |Hi} eal. Ll LL J. pos ee ee 2co EN Ea = ~r EEN Ey NP - rir TT 2i eof da -~ ~~ | > be len an a|n CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00116633 3M MN01538549 [gmat = sneer I| B snihi | 3 Fi [ = | = Se id Fu Ii ENTS 1| %1 ; |& I: r&}en e 2 1 11 I. 1|| hs| I] ie] | |+ J-- r | 33| 2 q gl i3 | | ; COSNFIDEENTIAL - SUBIECT T0 A PROTECTIVE OROER ENTERED CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00116644 au orssesso 3M MN01538550 bata File: fvar/chen/ oma. i/0217080.b/08510. Data File: /varichem/lOmsv4.i!O21704a.b/O481O.D Report Date: 23~Feb-2004 21:08 TovTATIVEY TORTIE CoNROUNDS Pace Analytical Services, Inc. Minnesota TENTATIVELY IDZNTIFIED COMPOI~DS Client Name: 3M Eb-g Lab Smp Id: 105333132 Operator : PNI Fo Tih, Sample LocatioN: Sample Matrix: WATER Sw Analysis Type: VOA NNuummbbeerr TTIICCss ffoouurn,dd:: 22 Clien< SDG: 021704a Clien< Smp D: E04-0120-67432 Sa~pie Da%e: k2-FEB-2C04 Soros Dae: Point: Date Received: 13-FEB-204 00:00 BRS fered Level: LOW J CONCENTRATION L~tTS : ((uugg//LL oorr ug/KG) ug/L | cas woven CAS NUMBER J---- COMPOUN~ N}%J~[E TiT9966-2-22-02-0 3|-3P-epnetntaannoonnee [rome 590-50-1 629-5G ob free 2-Pentanone, Tridecane @,4 dimethyl- wr | BT "Ts5l.e600a4 Me7o180 14o559 mor cove.| o EST~ CONC. Q Ta4szo0 a~gJl meee 5.4 NJ 2~8 HJ RO CS DTT Sono. aos CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00116655 3M MN01538551 ~RDaeatptaoartFFiillDeea:=re:/icc2hh7ee-mmF//e11bO0-mm2ss0vv0444..i1i/100022:111377@0441a..bb!/0044881100~.DD Renorn Dat~ : 27 F~h-2004 ] [] : ~ PPaaccee AAnnaallyyttiiccaall SSeerrvviicceess,, ZInncco. - MMiinnnneessoottaa Data file : /chen/10msv4.1/02188722066400aB8.bVV/OO0LW4%A8TT1II0LL.EEDRREEPPOORRTT LDLInaaajbbsaSDSammfptpileelIdd:::: !11107c05-8h3F3e3E3m3B3!1-113230202m0s4v4 19i:!00421704a_b!04810cC~llDiieenntt Smp Smp ID: ID: E04-0120-67432 E04-0120 67432 SoOImnppipeerrDaaIaztntooferro :: P11NN"0I!5I-3F3E3B1-322004 i9;04 TInns~tt IIDD:: 1lo0mmssvva4._ii MMCSliomssmpccmeInnIItfnnoffoo :: 82608 VOLATILE REPORT MMMCeeeotttmhhhmooeddDnatte :: [28!3v2v-a6aF0rreB//bcc-Vhh2Oee0Lmm0A//4Tl1Io0Lmm2Es0s:vv4d4R7._EiPi/Op/0RnOT2g2u11y77e00n44aa..bb/!QVVu00a44n00t4400T44y00p..emm: ISTD CAMCalaellsthDbDoaDattatteetlee:: 11210030---FFFEeEBbB---22200@00046 209022:::444755 p~l~uyen CQCaaullantFFiillTee}::~e:03I0S7T.D0 ADDIi]~nlIstegbFFroaaatccttttoloorrer::=: H1iib0.00R000T00OE0C Compound Sublist: all.sub TTIaanrrtggeeegttratVVoeerrr:ssiiooHnnP:: RTE33..5500 Co~pound Sublist; all.sub CCoonncceennttrraattiioonn FFoo[r-mmuu~:laa:: AAmmtt ** DDFF {* UUEE ** 1/Vo *~ CCppnnddvVaarriiaabbliee Name value Name Value Description voDeFF 15.I1~000000000000000 VvUfoo 5551_,000000600000000 ngDD=iiulnJuitttiioonncorFFraaecccttotoriron factor snS@aamKppullneeiu VVoocllouurmmreeecptpiuunrrng~eeddfac(tmLo)r pCpnndd VVaarriiaabbllee LLooccaall CCoommppoouunndd VVaarriiaabbllee i1S87T0D ~ &r AARREEAA AuouNT AMOUNT +* 4433 FFlluucorroobbeennzzeenne~ + 63 Chlorobenzene-ds * 63 Chlorobenzene-d5 87 1,4-Dichlorobenzene-ds 87 1,4-Dichlorobenzene-d4 44..990044 8.250 8.250 11.365 ii~365 602266888033 908867 908867 1000673 1000673 2200..000000 20.000 20.000 20.000 20.000 `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACPOPRUROROTTT,EECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR-2E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00116666 33MM_MMNNO011553388555522 DR13aeatptaoartFb'iilDleae::te:jicc2hh7ee-mmF/ie1ib0O-mm2ss0vv04a4..i1//1O0022:11173]0044aa.bb//(044881100..DD Date: 27-Feb-2004 I0 oQcC FFllaagg LLeeggeenndd ILJ - Oo~peerraattoorr sseelleecctteedd a~]n1 aa]ltt~e_rrn}a~ttee lliibbrraarryy sseeaarrcchh mmaa~tcchh~ `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACPOPRUROROTTT,EECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR-2E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00116677 3M_MNO1538553 3M MN01538553 . SRIRRIRTRESRITRINRNLSRARRILNNNRNI0D | HponHy rir THiHis3]isf ol in fri{itHii@ . i i of JEtt pete : "hm encri.orctmntenenss - ) HH 3bl Hgeiy o8g 3:1 HEE le 1% * GFEOANNEFRIICDOUE-NNTSYUTBDJIIESCATTRTIC0TAPCROOUTRETCNTGI.V2E7OGuRnDiEoR26E8N0T3ERED CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00116688 swnossoss4 3M MN01538554 RDeaptoartFilDea:te:/ch2e7-mF/e1b0-m2s0v0a8.:/1002:113704a.b/04814.D Pace Analytical Services, Inc. - Minnesota Pace ServAces, tat Minnesota TTEENNTTAATTIIVVEELLYY IIDDEENNTTIIFFIIEEDD CCOOMMPPOOU~NDD~S CLCallbi~eennSttmpNNaa1mmde:e:: 10335uM33~B3NN1VV65 OOSLaappbmeeprrlaaSettmooprrLocd:: :atEPiNN1oI10n5:333165 ASS~naaaammmlpppylllseeeisMMLaaottcTrrayiitpxxei:::on:VWOAATER ~ype; VOA CCCllliiieeennnttt $SS0Dm6Gp:: I0D0:221177E000444a2-0120-67438 SSCSaalaimmmepppnlllteee DDSPaa~ottiDeen::tI:D:1122-E-F0FEE4BB---022100200@44-674Ss DDLeaavtteeel:RReecLcPeOeoiKiivvneetdd::: 1133--F~EEBB--22000044 0000::0000 Level~ LOW NNuutr,bheerr 'TrIlCcss ffoounndd:: 22 (CCuOOgNN/CCLEENHoTTrRRAAuTgT/ITKOOGNH) UNNNuI[gTT/SSL~: <ugiL or ugiKG) cas NuMBER CAS NUMBER 112!o.76992669--2-25220--0-05 2. 629-50-5 COMPOUND NAME ||3T-rPiednetcaanneone =RrT 1s53.o5s5359292| EBSSTT., CCOONNCCo. | Q 10110.02|0) I NNNIJ_T| I~2 NJ~ `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACPOPRUROROTTT,EECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR-2E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00116699 33MM_MMNNO011553388555555 DRDaeatptaoartFFiillDeea::re://cchh2ee7m-m/F/'e1Ib0O-mm2ss0vv0444..1J/1/00O:221113770084aa..bb//0044981144.0~ Pace Analytical Services, Inc. - Minnesota Pace Services, Inc= Minnesota Data file : /chem/10msva.1/0215872260600458a.bVVO/OLL0AA4TT5II1LL4EE.DRREEPPOORRTT DLILnaaajtbbaSD8mamfptpieleIIdd=::r 11i1700c-55hF33eE33mB33i-1112660055m0s4v4_2i0i:05261704a.bi0481C4Cl.liDieenntt SSmmpp IIDD:: 8E0044--00112200--6677443388 oOSpnpmjeperraaDIattntooferro ::: P11N07L5-3F3E3B1-625004 20:56 Inst 1D: lomsvi.i MCSHoimimspsmceeInnI!tfnnoffoo ::: 105333165 8260B VOLATILE REPORT MMMCeeeottt~hhhmooeddnDtate :: 28//32vv-6aaF0rr5e/ibcc-Vhh2Oee0~mn0hi/4Tl1IO0L2mmE0ss:vv4R4a7E=.PiinOi/RO0gT22ul1yT7eO0n44aa_.bbi/VYQOu04a4n00t440044T0y0p,.emm: ISTD CAMCalaellsthDbDoaaDtttateetlme:: 211i4300---FFFeBEbBB---22200O000444 020202:::444557 pnguyen QCCaaullanzFFiillTeey::pes004400I00S77T.oDDE DA~Iiilnllstegb~koraatacc~ttt:ooolrrre:t: H1]P4.O00R00T00E000 Compound Sublist: all.sub TIn artegegtraVtoerrssioHnR: RTE3.50 Compound Snhlists all.sub Version: 3~5@ CCoonncceennttrraattiioonn FFoorrmmuullaa:: AAmmtt +~ DFF ** UUfL +* 1I/!VVoo +* Cpndvariable NNaammee value Value Description Descr~mt~on DvOeeF 5112.000~29O00O00O00 vU%oof 5bb1~_O00D93000O00O60 nDDgiillunuuitttiioonncor~Fraaeccctttooirron factor Sn~ampulneit VVoocllouurmmreeecpp<uu~rrnggeeddfac((mtmoiL))r pCpnndd VVaarri=aabbilee LLooccaall CCoommppoouunndd VVaarriiaabbllee 1510 RT AREA AmoUNT ISTD ~T AREA +* 443{ F~lluuoosr-oobbeennzzeennee +* 8877 1i ,44--DDiicchhll<o~ro0bbeennzzeennee--dds4 4.903 4.9@4 ]111..3~665q 718805 718806 1100_8,9~7,_544 20.000 20.000 2200.000000 `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACPOPRUROROTTT,EECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR-2E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00117700 33MM_MMNNO011553388555566 . SEF EISRE IEEEIRERI ITIIINE NY tfaviengs =a FH 1 kK Pse1iLiEiEt B i.co ee tpn |[2 Efi5Ea3i] . i5 orerLaoce onvscthatns (55 elias 3 E P-- . | TT i 3 ier ito d fiz 2d it GFOENAFINDEERNITICAOU-NTSYUBDJIESCTTRTIC0TACPORUORTTECNTGI.V2E7OGuRnDiEoR26E8N0T3ERED CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00117711 swnos33557 3M MN01538557 DRaetpaortFilDea:te:/ch2e7m-/Fie0bm-a2v0a0.4i/0102:117304a. 0815.0 Report Date: 27 Feb-2004 PPaaccee AAnnaallfyttiiccaall SSeerrvviicceess,, iInncc,. - MMiinnnneessoottaa TENTATIVELY IDENTIFIED COMPOUNDS TENTATIVELY IDENTIFIED CMPOUNDS CClliieenntt NNaammee:: 33HM ENV CClllieennnt S$D06G:: 0022117700848a WNW OLOLSpaaapebbmerprSalaSetmmtpoporrLoIIddc: ~:atPi]1Lo00n55:333333117733 SCSSalaamimmpepplnlletee DDSpaaomttipeen::tI:D:1122E--0FF4EE-BB-0-21202000044so HEP2fx1oy ASSSnaaaammmlpppyl=lseeeisMMLaoatcTtrayriptixeix::on:WVWOAARTTEERR DTSDaaaavttmeepell:eRReeccPTeoooiiiwnvvtee:dd:: 1133--FFEEB~--22000044 00:00 Analysis Type~ VOA Level: LOW conceNTRATION UNITS CONCENTBTION D~ITS: NNuummbbeerr TTIICCss ffoouunndd:: 44 ((uuggi/LL oorr uugg//KKGG)) ug/L CCAASS NNUUMMBBEERR I `CCOOMHPPOOUN~D NNAAMMEE | RR7T | 2510.119559169962-00-72--223525-0-0C070--)51I 3-|32Pp[--o2ePP-deenvennetcttnaaatannanncnooocnnnneeee,, 44.o44-~ddiivmeetthhyyll-- || 13557~5...517!59883%800 | weno i12-40-~ 629-50-5 mE Dodecane !Trid~cane 1356s 13 . 573 i~ , 565 EESSTT.. CCOONNCC.o [] 2322t22_e0C1l| Na maT pa.6t 2 .C `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACOPPURRROOTTT.EECNCTOT,IIVV2EE7:OOCRRV-DD1EE0RR-2E6E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00117722 _Motsassse 3M MN01538558 DRDaeatptaoartFFJillD.eae::te:/icc2hh7eemmF//el1bO0mm3ss0vv044..ii//10002:3]11.3770044aa..bb//0G44881155.oDD Report Date: 2?-FeD 2004 10:13 PPaaccee AAnmaallyytticcaall SSeerrvviicceess,, IInncco. - MHinnnneessootcaa 8822650@8B VVOOLlAaTTIILLEE RREEPPOORRTT DLDLInaaaajtbtbaaSDSmavffptpiielleeI1dd;:::~ 105333173 Client //cchheemm//1l0@mmesvv4..i//0O2211770044aa..bb//O0448811B5~.D0 1170-5F33E331-723004 21:23 Client sSempp 10: E04-0120-d24s5>s- SwSOSIihpnmpjnppeeerraDaI!taznnIotoffnerorofo |||::: 1BP1NN?0IL-3F3E3B3-127004 105333173 21:23 IInnsstt 1IDD:= 1t0ommsevv4ao.ii CvMMMCeieeootsttmmchhhmeoomnddDietanntfeto :::|i 8/28/322vv-66aaF90rreB8/!bcc-VVhh2OOee0LLmm0AAi/8TT11II00LLmm2BE0se1vv3RR4a7EE..PFi1OOpi/RrR00TaT22u11y77e00n44aao.bb!/QVVu00a44n00t~300T44y00p..emm: ISTO ADCHACalaleil~ssrbDbbFDoaoaDatttcattttetlloeeeer:!:~:: 111215.0300.-=0~FF0eEE0bB30-=222000000844 029022:::443755 pnguyem QCualan~File: 04007.D Cal File: 04007oD TDIIiannltrtegegeg~rtraaactttVoooerrrr:s::ioHWnPP: RRTTES3.50 Compound Sublist: all.aub Sublist: all,sub Target Version: HPa7lof CCoonncceennttrraattiioonn FFoorrmmuullaa:: AAmmtt * DF DE + * U~ff * + I1!/VYoo ** CCpprnddvVaarriiaabbllee Have vate Description VooDootfFF ~o Cond variable Cppd Varisb]e 121.0O000000000000 5__.5090000000000O0 1DD9iilluuuntittiioonnCorFFraaeccc%ttooirron factor SnS~aammpuplnliee= VVoocllouur~rreeecp:p~uuorrnggeeddfac((nmmLoL))r focal Compound Variable Variable 1510 T ARsA avout RT AREA + 43 Fluorobenzens * 43 Ftuorobenzen~ + 63 Chlorsbenzens-ds * 63 Chlersbenzen~-d5 +~ 87 1,4-Dichlorobenzene-dd 87 i,4-Dichlorobenzene-d4 4.504 4.904 8.250 8.250 1II.~337711 eels 663116 s194s 919445 1]0016634488 20.000 20,000 20.000 20.000 20.000 `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACOPPURRROOTTT.EECNCTOT,IIVV2EE7:OOCRRV-DD1EE0RR-2E6E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00117733 _Motsasss 3M MN01538559 DDRaaettpaaortFFiillDaeet::e: /icc2hh7ee-mnFi/e1lb00-mm2ss0vv04d4..ii//1~00022:1113770044aa..bb/i0O448S1l5S..DD Repcr~ Date: 27-Feb-20C4 69019 ~'L QQCC FFllaawg Legend _L - OOppeerraattoorr sseel!eecctzeedd aann aalltteerrnnaattee lliibbrraarryy sseeaarrcchh mmaattcchh. `CHOECNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACPOPRUROROTTT,EECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR-2E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00117744 33MM_MMNNO011553388556600 : SERGTRSCSSPINLIRECEEILOUERRSECRENIINLY | p[oRpEeELS Tren hig - 1 1eh1 iid Lngoe $i 8 *er-- ne gE! |. rn B : - PO : -- 3 ii i g11i0z: i i |+ i FEANERI COUNTY DISTRICT COURT NG. 27 Gun 26803 CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00117755 3M MN01538561 DEDaeatptaoartFFiilDleea:t:e:/icchh2ee7m-mFi/Ze1b0m -m2ss0vv0a44..i1/0/120012:V 113700@ 4aa.obb/i0064S3}166.0 Fepo~t ~,ate; 27-FED-2004 10.-3.3 Pace Analytical Services, Inc. - Minnesota Services, Knco Minnesota ~T: EENNTTAA~T~IIVV~EmL,~Y" IIDDEENNTTIIFFIIEEDD CCOOMMPPOOIU]N~DSS CLCallbiieenSntmtpNHa1amdme::er 1330HM833EE3N~1V81 O OSLapapbmeeprrlaSaemttooprLroldc:: a: tPPiNN1oL0!n5333181 ASSnaam amlppyllseeisML HaoatTtcrryaiptxxei~::onVW:WAOATATEERR Analysis Type~ VOA CcCllliiieeennnttt sSSnmDGwG:p: ID00:2R1177E0004442a-0120-67442 CSSSlaaai~mmepppnlllteee DPSDaoamtitpeen::tI:D:1122-E-F0FE4EBB---02210020e014-67442 LDDSeaaavttmeeepl:leRReeccLPeeooiiiWvvneted:d:: 1133--FPEEBB--22000044 0000::@0O0 Level: LOW NNuun~beerr TTIICCss ffoouunndd:: 0 (CCuOOgNN/CCLEENoNrTTRRuAAgTT/IIOO0NN) UL~NuNIgIT/TSLS:: (ugiL or ugiL CRS NUMBER CoMpoUND NAME |T oar |T Bor. conc. | Q `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACPOPRUROROTTT,EECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR-2E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00117766 3M_MNO1538562 3M MN01538562 RDaetpaortFilDea:te:/c2h7e-mF/e1bo-m2e0v0a4.i/1002:113704a.b/04816.D Pace Analytical Services, Inc. - Minnesota PaGe Ana]ytzcat Services, Inc~ Minnesota Data file : /chen/10meva.i/021857220560048Ba.VVbO/0L0~A4TTEII1LL6EE.0RREEPPOORRTT LDLIanaajtbbaDSSammftppieleIIdd:::: !1117c00-h55F33eE33m33B/11-18820110m0s4v4.2i1:/50121704a.bi04816cC~llOiieenntt SSmmp~ IIDD:: EE0044--00112200--66774444~2 oOSIpnpmleeprraaDIttantooferro :::: R11a7NN0I153FE3B31821004 21:5i iInnsstt I: lomeva.i CMMSoiimmsspcmceInnIItfnnoffoo ::: I01333181 8260 VOLATILE REPORT MMM CeeoetmttmhhheoonddDtate :~:: /8[2v23va6-ar0FricBe/hbce-~hm 2Oe0L/ml0~/O4TlmI0~s2mvE0s4:vo4iR~7E./P1OOp/2Rn01Tg27u10y74e0an8oab.ibV/OQV4u0@ a4n04t40044T6y0~p.m e1: ISTD CAHCalaellsthbDDoaaDtttateetlee:::: 21116300---FFFeEEhBB-~-222000000444 02@20Z:::4447~5 pnguyen QCCauallan~FFiillTeey::pe:004~0I00S07T~D.DD ADDIliinlsltegbFFroaaatccttttoloorerr:::: H1[P6.0R00T0E0 Compound Sublist: all.sub TTIaanrrtggeee@ttratVVoeerrrs:siiooHnnP:: RTE33..5500 Sublist: all~sub - NNOO TTEENNTTAATTIIVVEELLYY IIDDEENNTTIIFFIIEEDD CCOOMMPPOOUUNNDDSS - `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOTAACPOPRUROROTTT,EECNCTOT,IIVV2EE7-OOCRRV-DD1EE0RR.2E8E8NN6TT2EERREEDD INN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00117777 33MM_MMNNO011553388556633 ir pe o . REee Hig [13si | peli [EEfeL:3 i: Li|| | re . SF + tromtturcnann 5 5 J GFEOANNEFRIICDOUE-NNTSYUTBDJIIESCATTRTIC0TAPCROOUTRETCNTGI.V2E7OGuRnOiEoR26E8N0T3ERED CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00117788 hii Aigseif ] PsE d swnorsssso4 3M MN01538564 DRDeaapttoaartF FiilDeea:t~e:/Icchh2ee7m-miF/~ei~b0~m-m~2s40~v.0a4i.ii/010202:1117370044aa.. 5b/i0044881166..DD Report Date: 27-Feb-200~ i0:13 Pace Analytical Services, Inc. - Minnesota Pace Analytical Ser~sices, Inc. - Minnesota Data tile : /chem/10mav.1/02188722066400aB8.bVV/OO0L~4AT8TI1IL6LEEDRREEPPOORRTT DLLInaaajtbbaDSSammfpptieleiIdd~::: 1/I1c0705h5-3e3FS3mE33iB111-880211m0s0v4.2i1/:50121704aob/O481~CC.llDiieenntt SSmpp IEDD:: BE0044--001i2200--6677444422 oO SpmpeoerraDIatan,otfoeror ::~: P1P1N70N-8t F3E3B3-1821004 2!:~I lInnsstt IIDp:: 10meva.i 10msv4_i CMMSoiimmssomcceInInItnfnoffoo :~ : 105333181 82608 VOLATILE REPORT MMMCeeeotttmhmhheoonddDtate :::: /28/32vv6-aa0FrrBe//bcc-VhhO2ee[0mm.0//~4.1lT0OImm2%ss0Rv:v4i4R7.~E1PiO//pR0rOT2g2u11y77e00n44aa.~bb/iQVVu0Oa44n00t440044Ty0Gp.~emm: ISTO MCAraelallsthDbDoDaatatttteelee:::: 2I1106S0--FFFeEEbBB---222000000444 2000~2:::444755 pnguyen QCCaaullanzFFiillTeey::pe:00440I0S00T77E..DD ADDIiiInllstegbFFroaaatccttttoloorerr::~: 1H16P.00RT0E00 Compound Sublist: all.sub TTIaanrrtggeeegttratVVoeerrr:ssiiooHnnP:: RTE33..5500 Suhlist: all sub - NO TENTATIVELY IDENTIFIED COMPOUNDS - `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACPOPRUROROTTT,EECNCTOT,IIVV2EE7-OOCRRV-DD1EE0RR.2E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00117799 33MM_MMNNO011553388556655 Danth nd : Data File: /chen/iomsvi.i/021704a.5/04813.D Data F~_le: icheff:/i~sv4= /021704a,b/@~813oD Pace Analytical Services, Inc. - Minnesota Report DaTe: lS-Mar-~u0-~ ~ 28 Pare ~na.~._]cal Services, Inc. Minnesota i ~ : GrES a EceorAnt RE whranee: ,eEaYreenr IENTAFEVELY TORNTCHCSSn IallmnFtepJ alIeeeeDnnlstFiCoBOE5A Bi0Non0Pih:sOtieUa.N-- o,DzSir1u3s-- araep0su-s02os0s0i4ns00:00 Number TTIICCss ffoouunndd:: 4~ Client SDG: 02!704a Client Smp ID: E04-0120-67439 Date : 12 DaLe Received; 13 F~%B 2004 00~00 Level : LOW (CuuOggN//LCEooNrrTBAugT/1OKGN) UuNgIT/SL : [---- compoup wane CAS NUmbER fen en Sa 503805 4 6 -~ - <18 - I 2 75 ~- 0 Pl3 ien |[iDntBe e : -{ | COMPI~]D NAME [unknown Unknown <]nknown Unknown wr | ser cove. | CONCo | RT "lw 2561 i, 619 2. 964 B13e% sal = 3. @ 31 so9l6 NT 24 NJ~ __ LET EAT TAL Rae: HENNEPIN COUNTYDISTRICT COURT, NO. 27-CV-10-28862 CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00118800 aw3MAMMbNMY0E15S328455606: DRDaeattpaaortFFiillDema:tes/!cch1he5em-m/M/1al0r0m-m~2ev0v40.4ii/1/0202:21217870044aa.5b/I0044881133.DD !J Report D>s.L~: 15-Mar-20@4 12:28 Pace Analycical Services, Inc. - Minnesota Doanta 510: AEfchen/lPoamceevi~.t1a/ly2n1$s27c540aa8l.5VS/Oe0Lr3Av6Tz1Ic3LCe.EisDf, eRnEZtFnOcoKsTme Hinnesoca 10: 04-0120-67439 SFiavag 2335 2004 20:26 Inst 1D: l0meva.i : ;> | JC 8oh2e0mi/ e LVVoCOrLKaA,AvTTsIT.L1L,E1E53//30RR0252EE11PP7OO7T0RRa04TTc4ahaoab.oiboV/r0V40044Q00u34a00n4t1.m 0Type: 18TD 10-38 2004 a1221: a1s7 r.qchnobr GQaula"nRtiiTe~yrpe 04I0S0T7D0 ACCiaHsteooFirlaitoeonrt: WL1E3oRoTEe 02:45 Cal File: 04007~D Compound Sublist: all.sub PFairceSeerosVienrgsiHoons:t: h3p.o50hemsz Compound Sublist : all.sub CEoonncceennttrraat:i~oonn FFoorrmmuullaa:: AAmmt: +* DDFF +~ UE Uf + * iil/VVoo *~ Cpndvariable Name. vaValluuee Description Name ToDuYvefoeP 553i5.11l0o00o3o0000o0000000000 Descr:pnlon oSmgD Dgripiluullunu netiltnitioovnnoccloourF Frmraraeeecctccto otptiriurorongnedffaacc(tato lo)rr . To ~.09oo0 Coad variable Sample Local Volume Compound Variab(lmeL) Local Compound Variable 1510 + 43 Fluorobenzene ,12 Ftuorobemzer:e &7 AEA AAMMOOUUNNT T 46..90055 e67r7r76s4 20.000 20 O00 4~ `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACOPPURRROOTTT.EECNCTOT,IIVV2EE7:OOCRRV-DD1EE0RR-2E6E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00118811 Reser 3M MN01538567 [RG%aerptaoartFFi]lDeea::te:/ch1e5-mM/a11r00-mm2ss0v0v74.~ii/i1020:2221i8770044aa.obbi/O0448811330.DD i RoR2~rt ~te: IS-Mar-200 1 ~8 rlag Legend 1<9 L, gend Operator selected an alternate library search match. sel{cted at alternate search match. `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTYUBBIDJJIEAESCCTLTTRTITCOOTAACPOPRUROROTTT,EECNCTOT.IIVV2EE7-OOCRVR-DD1EE0RR-2E8E8NN6TT2EERREEDD IINN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00118822 3M_MNO1538565 3M MN01538568 I ud cmzuavaey BE 4 = ] > 1-- | 1"Fr in NE -------------- esate | 53%] Fi 1[551g5 [3d | z2 | E[ataSrntaraews >0 | Te reams p| ro 1 || ; Bd 2 |1 gi {1 =J S---- 1 I=1 || |1 { `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACOPPURRROOTTT.EECNCTOT.IIVV2EE7-OOCRR\-DD1EE0RR-2E6E3NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00118833 b | _Motsasses 3M MN01538569 sata File: /chem/Lonsvi.1/0217050.5/04816.D Data F~le: /chemi10msv4.ii021704aob/04816~D foesBia: femme an Report Date: 27-Fmb-2004 i0:13 face Analyeical Services, Tuc. - Hinesota Pace Analytical Services, inc0 - Minnesota TENTATIVELY. TOUNTIFIED COMPOUNDS TENTATIVELY IDENT! FIED COMPOUNDS Client Name: am av A -- Client Name: 3H E}rV me Cent 500 Ot a0.araez Lab Smp Id: i053331@I Gram Gamers Bebe ia bas Bios Operator : PNI en Sos toe Sample Location: Sale eee are He erotued: 13-FE8-2004 00:0 Sample Hatrix: WATER LL EEE Reet Analysis Type: VOA yume TECH founds T concmmn mzion mairse Nu~er TICs found: 0 Client SDG: 021704a Client Smp ID~ E04-0120-67442 Sample Date: 12~FEB-2O04 Sample Point: Date Received: I~-FEB-2004 00:O0 Level: LOW CONCENT~T!ON U~{!TS: (usiL or ugiKG) ug/L ~ |e] CAS ~ER J---- wr | esr. conc.| o | J ---------------- CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HHEENNNNEEPPIINN CCOOUUNNTTYYDIDSISTTRRIICCTT CCOOUURRTT,, NNOO.. 2277--CCVV--1100--2288886622 11993377..00118844 ---- 3M MN01538570 - i$PEEISS ISS .7 EE FERREREREREENE o EEae gore i HH Hie seiiil Fix 3 i : JF| |. - nent * tet btn d i gi18g 1 fio[a z ii 5 `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NTSSTUYUBBIDJJIEAESCCTLTTRITTCOOT AACOPPURRROOTTT.EECNCTGT.IIVV2EE7-OOGRRu-DD1EE0RR.2E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00118855 aw_mNotssssTt 3M MN01538571 FFlluuoorroocchheemmiiccaallss FFIINNAALL RREEPPOORRTT EEVVEENNTT 11 EE0044--00112200 FFeebbrruuaarryy 1122,, 22000044 CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 1937.0186 3M MN01538572 ~s \ePa rg osrt c Re eh ar.n. Proven Results. AAnnaallyyttiiccaall RReeppoorrtt FFliuuoorroocchheemmiiccaall CChhaarraacctteerriizzaattiioonn ooff AAqquueeoouuss SSaammpplleess CCoottttaaggee GGrroovvee AAccttiivvaatteedd CCaarrbboonn SSyysstteemm FFCC MMoonniittoorriinngg ((EE0044--00112200)) EExxyyggeenn RReesseeaarrcchh LLaabboorraattoorryy RReeppoorrtt NNoo.. LL00000011687744 TTeessttiinngg LLaabboorraattoorryy 30EE5xx8yyggReeennseRRaeerssceehaarDrcrcihhve "SStt3aa0tte5e8CCooRllleleesggeeea,,rcPPhAAD11r66iv88e0011 PPrroojjeecctt LLeeaadd `aM Environmental JTJeeecsshssnEEolllddorrgiidydggeaend Safety Services 3M EnvironmeBnutia39ll3d5T5ienBBgcuhu0ssn0hho0l2AoA.gvv0yee3nn-auuEnee:d0S0 afety Services StBuPailudPPliOnO,gMBB0Noo0xx05332533-013333333-11E--303931 St. Paul, MN 55.!33-3331 `CHGEOONNNNFFEIIDPDEIENNNTTCIIAOALU-LN- STSUUYBBDJJIEESCCTTTRITTCOOT AACOPPURRROOTT.TEECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR.2E6E8NN6TT2EERREEDD IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00118877 X30i 50 Resch rBife , usa p~e058RCeosleleagrceh, DPAriv1e6801, USA 7 op02n319 : 8~1.281.3219 PRR F: 814.272.1019 ova exygen.com IM_MNO1538573 3M MN01538573 11 IInnttrroodduuccttiioonn Fe(RsBeousguteltssna)arfreoemrereptophrootrMteedd ftoorar gthheeeaGanrnaaoylwyssaissocofyf.asTqchuueeeooEuuxssysgsaaemmnpplsleehssyrrnaeuccemiebveeddrbabsyysEigExnxyeygdgeeonn oReespsereaoajrreccchht i(sExoyogoerne)rfer,om the 3M Cottage Grove facility. The Exygen study number assigned to the project is L0001874. `SSpepceicfifiicc fflluuoorroocchheemmiiccaall cchhaararactceteririzzaattiioonnbbyyliliqquuiiddcchhrormoamtoagrtaophgyr//tataanpnddheeymmmmaassss ssppeectcrtroommetertyry ( (LC/ML S/MSC )wwaassM rereqqueuS setsteeddM ffoorraaS lll ssaamm) pplleess.. AAttoottaallooff 2233ssaammplpeless ((iinncclluuddiinnggffiieelldddduuplpiliccaatteess,, lank,and kes) wer ecehed or anaes blanks, and spikes) were received for analysis. Thesamplesvere prepare and analyzedby LOMSIS for he folowing of rahi: The samples were prepared and analyzed by LC/MS/MS for the following list of fluorechemicals: + Tab: Target Ass Table 1: Target Analysis Compound Name Perfluorobutanesulfonate Peffluorohexanesulfonate Perfluorooctanesulfonate Perfluorohexanoic Acid Perfluorooctanoic Acid Acronvm C4 Sulfonate (PFBS) C6 Sulfonate (PFHS) C8 Sulfonate (PFOS) C6 Acid (PFHA) C8 Acid (PFOA) Theanayicalmethodsused war orghalydevelopedfor groundwalrsamples andwero The analytical methods used were originally developed for groundwater samples and were valbiy Exdygaan, Thevalidation pracaand resus a on fl ihExygen. Only theG3 validated by Exygen. The validation protocol and results are on file with Exygen, Only the C8 Sonate andC8Actwere nada inteorignalmthodvaldaton. shou bsrte iat ta Sulfonate and C8 Acid were included in the original method validation. It should be noted that the quaycorr! clomnts incu 143 ales camonstatate8plcabity of ho mahodto ho quality control elements included in this analysis demonstrate the applicability of the method to the adore snches additional analytes. 22 SSaammppllee RReecceeiipptt Thowal samples wer submitedin asiccontains.Samswer ecelvedonwetco aa The water samples were submitted in plastic containers, Samples were received on wet ice at a ttemepmepraeturreaooftf0u0.1.r1CeC.. SSaammplpelesswwerereessttoorreeddaatt 44CCffrroommrerecceeiippttuuntnitill aannaalylyssiiss,. TTwweenntyty--tthhrreeee incu Continers wer racove. Fels Samples vers cole on 2120. Same were individual containers were received. Field samples were collected on 2/12/04. Samples were 190000Z16TAD5A. Cra cusody omaions reseed 1 ATachmentC. received on 2/13/04. Chain-of-custody information is presented in Attachment C. 33 HHoollddiinngg TTiimmeess Fldand boston spikes of these uorochemialshaveshownsbi forprodsGosler Field and laboratory spikes of these fluorochemicals have shown stability for periods greater han cays. Samples wa nsec Wh 30 Gaysof colecton than 90 days. Samples were analyzed within 30 days of collection. `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACOPPURRROOTT,TEECNCTOT.IIVV2E7E-OOCVRR-DD1EE0RR28EE8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00118888 racezrs PAGE 2 OF 5 M_MNO1S38STS 3M MN01538574 44 MMetethhooddss -- AAnnalyaticlalaaynnddtPPrireeppcaarraaattoolrryy 444.1111 SLLaCmOp/MMleSSP/MMSrS opfaor LrOaMStMSiAnaolynsis 4.1.1 Sample Preparation for LC/M,~I8 Analysis rWeWimaeotevrresseraemmsppceleussevwecrreiorecrnineit.iaaSllloyyvdterepaahltaeesddewweixitthhr2a2c00ti00ounuLL(ooSffPE22)55w00ammsougls/LessdoofddoiupamreHptihaoirosesututhlfaaeltsesamsspotllueotisonnftotoor LCirLeCtMmi/SMooIvSnewM/MarSeSssainpadanoulaaryllsyoiscmsihs.ol.odrAAipnrpepi.rootSrrtooio0lnindoeofpxfshasaacasmmtepoplenleexiwtrnwaaoacsrstdiioednrtilue(0tSedPdsEstooIafwfootarttyshym-umiaslifelildeilfictrteossrsowpfwriemitphhaarTrTeyyxpptheoeen|I hswwaaaatmnetecrpr,el.emseTTnfhhoteer "STdTcihhlruiiestsieomnnmaiinawrgtarriiusxxenpsneenhprhfaeoanrrnmccomeemdmeepednrnitotorwnwtaoatssehexotsobreabsscseateirmorvpvneleieddnsio.innrTdceeharaoteroliderlreissessaaedmnmspptahlmesepsfelfrfefresoocmmtWsootrthiofsismlroaloactrncaixsatttoeioonnrnhoaadannnc0ddefmaiferCoonmumt. SsnSPcParEeEncea6cnraitnrrtggriiddrugghene..stTTpheh-erefoccraoamrrteirldiddggoeednowwftahcateshsseoieeotlutsetaneedmdwpcwliseitahshem. 55pmTlnmheLLesotpofdifilau11r00te000d%t%asmnamotamehyptnhsaleasnsn.oow.l.eTTrhehiisstrvatreneasaiftemmrereenndtt rtroeossauulCtte1ed8d in an eight-fold concentration of the diluted samples prior to analysis. 44.11.22 SSaammpplleeAAnnalyasislbbyyyLLCOs/MMiSS/MMsSS cIInnolHHuPmPLnL,CC,B,aaansneaaldliioqquunootthooeffeaexfxtftirrnaatccyttosisf iijnejeecctnteedldaaannddfpoparastsshseeeddsatrhtoroonuuaggrhhy aaphqliaqusuieitd-piphhatahsesececohclrhuorommmnataoatoggroraapph(hii0cc HhtchPooeLlulCqmiqusnuioi.ddpaBmaraobasbbleoildeenp,ohpEnhaaSsthsaAee,,Sahtfhpfeirenoaitavynniaoadlfelysttheeaisrarnareeapatldyaiatiennnedfddofrafootchrrceuaarcsahctlaahrotaaimorcaontceaatrreniyrssisptithficocaasaamemnoaionuluyntnhztteionofcgfottaliumeime.dn. arFFerlolaaolnltoiwgvwieeoinntfggo omoHrriPggdaLanCniticcosmeoccpsooarmmarpatpotuoiurouennnsd,d;sEs,M,Sii/nnMocceSlcuidunpilrngosgvfiafudlruaeeorsroooaccnhrhezaempemii,dcicaaaflnlr.sda. gaEEmcleecnucttroraeotdsepamcranedyiasisndrgasgelefonocneortereardaan.llalsylyooozpnpienesprgraacathteearwdrdaaidcatetearrareiallsnaatgtivyivecoeloolyyff rmoildwtefmpueraoturers; moolaecrcouolhebsseearrveemidoanniizdedqc,ufaraangamtieendteadg,aianns!d sdteantedacrtedsd.. Ions characteristic of known fluorochemicals are observed and quantitated against standards. 2AAnHaHoleywwzioleetttht-PPoaasccakkmaarprddlHoHPPa'11a1100c00 .HHPPLALCnCassylysystteemmwcacosocupppalleerddfo0tom.aedMMiuiccsrrionomgmaasssosslUeUtcliitiammdaafMMoSaScM/MiSoSwnwamaassnutussoeenddnt0go aa(n(SSnaRRlaMylMy)iz.)c.eaSSlatahdmmaeptlpaselfeasssmpwrwpoolerevrieedeeeexxdtxtrtaiarncactAcstt.oeaddAocnonanhl2y2/s/ei11s88nD/0w0.44aasannpddearanfonaralmylyzezededdubbseeitntwgweesoeennle22c2/t22e00d/004r4eaaancntddio3n32/02m0/04o4n..itoRRriaanwwg analytical data is provided in Attachment D. 55 AAnnaallyyssiiss 55.11 CCAa7al-lipibborirnaacttaiiloionbnrationcavewasanalyzedai thobeginningandendoftheanalyticals0quonce focAf55or00rt070,o-t,hhpeeoaacninnncddtooccma11mpl00ibowo00rupa00anstnidonnosgnoot/uiloLfcfundi((rirnnpv7etpedpert)or)aweersssafcf.otosai.rrTcaThhLLnhoeCapeOl/cyMMocnazalSeS.lbdi/bMMrUraaSsaSttitiotnohanagnennpaaplbonlyoeysneisgniiissastns..nwriweeTTngreghhroroeeeaspnsnipindrsrospeinetaprrwnuuardmimreeooeddnfnt1tttahxterrw0e0e,eas,si2npp2g5aoo5h,lnny,isstni5e8ecg00a,,,vvl eehs11rre00essq00uu3u,,ss26e2n5pt5thc00h0ee,e,, concentration was plotted for each point. Using linear regression with 1/x weighting, the slope, AVciarlibrrcaalpotnancdurcvaerlatcocnapcioasfliocfien2t0(.)9a8n5d(c2oo0f97e0n).ofdelamination () erecetemired. y-intercept and correlation coefficient (r) and coefficient of determination (rz) were determined. A calibration curve is acceptable if r >0.985 (r~ _> 0.970). GCaalltibrraatiionnssttaannddaarrddssaarroepprreeppaarreedduussiningg hesameSPEproosciure the same SPE procedure sed used orfor sampies. samples. CtCahralolbiburgraahttoioountnctchhheeecckkasnstatalanyndsdaiasrrddsssewwqeuerreoenacanenaa.llyyCzzoeemddppploearrionocdciioccaailllsyy ((ceabvveierrayynttehrdreeoeft0othfievvo.esssiaaammnpdplaleerdiinnjjenecctatiootnrsse)) cthrouoghonut tchearaoawnailnynsis+t-2se0qa%uoefnichee. oaCctoumanlpvliaaslnucee. is obtained if the standard analyte concentrations are within +/-20% of the actual value. Acalbraton craworemetfor isanalysis. All calibration criteria were met for this analysis. `CHEOGNNONFEINDPEIFNNITCIDAOLEU-N-NSTSTUUYBBIDJJIEAESCCTLTTRITTCOOT AACOPPURRROOTT,TEECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR.2E6E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00118899 PPAaGcEes3oOrFs5 IM_MNO1538575 3M MN01538575 55.22 ExBBtrllaaacnntikkossnbarkswerepropare andanalyzedwiiheveryextactnbatchofsamples.The eExhxoxtttlrrraaaocccwtttiiioooannnvbbobalalncanaknklksssbssahwhioooeuunrelddsapnnnrooedttpahharaardevvd.oeFaaaonnnrydytttahaaonrrgsgaeealyttSzaaaenmndapalllwyyotiseth,s ehprvroeeexssreyennaettaxatrtnaoocrrtioaabnbbaoonbvvkeaestctwhh0eeroccefoocsnnoaccmmeapnnptarlreaarstoti.on.Tnohofef the low-level calibration standard. For these samples, the extraction blanks were compliant. InJInosvstet!ruumcmaoelnbntrtbabtaloarnnkkssstaiinnntdthahered,ffooarrmnmdoofafflctolreaanknnmomewtenhthaiangnoho!lossvoolevllveensntatwmweperirooe.aailssAoogaaaninna,allyyhzzoeaddbaaafnftkersrasevhveoerurkyyhdhiniggohh-t- `hahlaemavvpveoellacoaansnlyipybtrraaotartsiroaggnneeittsoatadanhnnaeadrylayoitredshs, poaprnrondesssiaoerfnntuettmraeatkntnotoborrwaGnraokbhosiwgvahe-tltehhcvooeemlkplolsoiawwamo-nlveptov.leelsl .ccaaAlligbraraaitntoi,ontnhsesttabanlnaddnaakrrsdd.s.hFoFouolrdr henot the samples presented here the instrument blanks are compliant. 55.33 SSSuururorgrraootggeaasttieekssosarenotacomponentof theLOMSIMSanalyticalmethods. Surrogate spikes are not a component of the LC/MS/MS analytical methods. 55.44 FMMiasat)trraiinxxdSSappbioikrkaeetsosryspkoswerepreparedusingall compoundsof erest,Fld spies wore parpnFaroieelplpydataearresnoddbbyblyaytabhadoodrdladiatinonbgrogyraaasmipmreikyaeepasssruwurireeeroddevsvhpooiruepluuppmimanroeegdoocffounfsiteeianlldidgnsseaaarlmlmspcfpoiolmaerspt0aoomauapncldcoesoncnaoltifaleniinncoettreirsroesnpsp.ti.eLkeaFddibeWowladaithshtpotikhhyoeeststpaawirrekggereeestt occaofonnnaosslxiyiststetatesecddtboooyfnft.hlaelFiquluadobstosHroaaoftnfokuruyvnss-psprppioiaikreestdodcsoffihienielspdspssitanaamgmpdclpooelfensstlatatihhnboaaerltraswwtofeeorrrryevfsafarolmroitiprfeileefddcoaoatlrtlertdhceetaiolllnaa.bbtoohrLraeaatbtooaorrbryyaottraotarlythhoeseyptatiiikmnmedees Lsasonbhfioipreppaxptteeraoddcrtwywioicinthho.ntFtthhioeeolldsssapabimmlkapenplsklee(Sssocpenoiakthseatesaiincncooeorrnnsss1ist50o.te6t)dthhaeorff fsiileaalbmdoparlanaentdosdrobybfawaclcaakktbe1ortr0oafotttrohhtrioefyilewadalabtobaorotrartasthotpeorkryylfoadbfooaorrtaatanthonaerayylsymassnie.sd. eooLxffatbeaeoxrcrtataratotocinrtoiyeonfnc.i.ocnEiteEaronacclcyshh,ptitakyyenppseedo(msofaef estspipscekikceeetfpiofrpneorcov5tvi.si6dd)eetsahsiarenlinmfsfooaamrmmaytpaiilteoimosnpnnoafenceletaeadbdnoeeradady1toit0orcyaaawslssraseeteesssrussfsaspe.ninkMaeaaldlyltaeitsstsahtsaebpbtiiiilmkit,eye, extraction efficiency, and matrix effects that may impact rmeactoviersieoskarroecGoivveer,si.n AtachmenBt. Pleasess Section recoveries are given in Attachment B. Please see Section 5.foradditonaldiscussion of analytical results. Matrix spike 5.7 for additional discussion of matrix spike recoveries. 55.55 FiDDouupdplaliinccdaalttaeebssoratorydupicates iroproprod for ach fied samp. Duplca resus aro venalongwihth samplefoots inAsachmentA. Field and laboratory duplicates were prepared for given along with the sample results in Attachment A. each field sample. Duplicate results are 55.66 FLLoaarbbLoorGraMattSooMrrSyyaCCnoaolnnytstreroso,llMSSiaalmmpwpallleeossrwas spikedwitall compoundsof ioresat 100and 551F00o00rnLn3iCggn//emMa0LScd/MdhuurLSi%rCinnagSgn.eaeRalyaecscshehuos,elxxsMtvraiallraicqetciogwitnavseotseenenrt.a.wlAoaAnlsgll rswrepeicickhooevtvdheerwriieaistshfwofdaorallratcaalollminccpAooomtmuappncooduhusnmndedosfsnwtinwiDtere. rreeesbbteetatwtwe1eeIeXnn) 7a70n0d-- 130% in each LCS. Results are given along with the raw data in Attachment D. 55.77 SSatstaaattdeeommneenontstuootffsoAAfccfccluurrsaapcciyykes, laboratory forfod fl sampic,fd ink pics, and flalBiababolsorberaaldttaoonorrnykysccporoeinnskitueroolstlsl,ssplopaafikbseofir,sea,ldttohherseypacainkonelnaystl,rylotcillcaaaslblpoiaarakccectcosuurrryaaanccfoyydroltofiaffaibealodllrl cactitooeommldrppyoosmuuannmaddpsrsleessxop,cipfekiepetltdsPPfFbFoBlrBaSanSlkliiscs+po3imk30pe0so%%,u.nadnAAsdlll lafxeiexvclcdeeeppbwttlaaPPnsFFkBBssSSgpsniskhfheocosw,waereladdtbryorebercacootovolveroeryiwriecetsosnhbtboroeotStlwwaseempeepiknnle7o7s0_0c%a%onandancnledadnbr11oa3r3ai00to%o%nreyexxwmccieaephtprttixihinsoGpcafiaksoseeelssslwfwowhirhenearglreleectxohhcemeesppspotpkuoiiknnnindsggs. LaSlLebahvoboerowlaretawdotoararsyyslsopspwiigikenreosifscficoofavonrertrPlPyyFF(HHb4Ae4Al%os)swhhfooornwtheePeddFhHshiSagi.gmhhRrpereleeccsoovcsveoernricfieeoerssn..PtArAFalltosEioo,Sn, tathhrweoiltthlaahbbeotrorheraefatotoorrferoynyslloposiwtpkiqikeneugfoafornerxtrIcnaefulptuteaiitonnvntsde3. Sshhoouwedboaulsoewdraescsocvreeryen(i4n4g%c)atfoar ualPFHS.rRlye.suAltls sfoprikPedFaBtSaaarreotrhoeproerftoordeinnohteqduaalnatittaatidveesa.nd should be used as screening data quality only. All spike data are reported in the data tables. 66 DDaattaa SSuum mmmaarryy PpPlaolreatassspaeosrs0eb0ielAAontttaa(ccshhpmmb)aenn(tt1AA9Hffoo)rr.aa cdteatalileedd slisitninggooff tthheaannaallyytiiccaal rreessuultss. Reasoruepolrtesdin Results are reported in parts per billion (ppb) (ng/mL). `CHEOGNNONFEINDPEIFNNITCIDAOLEU-N-NSTSTUUYBBIDJJIEAESCCTLTTRITTCOOT AACOPPURRROOTT,TEECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR.2E6E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00119900 PAGE 4 OF 5 IM_MNO1538576 3M MN01538576 Sn oto in maneanoon a as rs somp yop--r w--e --st--d 8 77 DDaattaa//SSaammppllee RReetteennttiioonn Samples are disposed of one month after the report is issued unless otherwise specified. All electronic data is archived on retrievable media and hard copy reports are stored in data folders maintained by Exygen. o Attachments 8 Attachments 61 mms 8.1 Attachment A: Results 52 Ahm Mas pha Feoneres 8.2 Attachment B: Matdx Spike Recoveries 54 tachment: Faw AatcalDain 88.33 AAttttaacchhmmeenntt CC:: C Chahinooe ffCCui ussttoonddyy 8.4 Attachment D: Raw Analytical Data 99 SSiiggnnaattuurreess EA no eC s CoM ur Paul Connolly, Team Leader - LCflIS hn. Farry, Vd Pronk 2h fle? /John M. Flaherty, Vice/ President eras MombersCnttngto Daa Other Lab Members Contributing to Data Karn Karen Smith w tae w 3 fo! Date ioeby Date GFOENAFNIEDREINCTOIUA-NSTUYBDJIESCTTRITC0TAPCROOUTRETCNTGI.V2E7OGRunOiEoR26E8N0T3ERED CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00119911 HE swossss77 3M MN01538577 SECTION A `CHCEOONNNNFFEIIDPDEIENNNTTCIIAOALUL-N- STSUUYBBDJJIEESCCTTTRITTCOOT AACOPPURRROOTT,TEECNCTOT,IIVV2EE7-OOCRRV-DD1EE0RR.2E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00119922 3M_MNO1538578 3M MN01538578 \ gen | ~Pre~cPrisoFercowRRenesseeRaaerrsccuhhk..s Proven Results. `SSuummmmaarrYy ooff CC66 aanndd CC88 AAcciiddss aanndd CC44,, CC66 aanndd CC88 SSuullffoonnaatteess iinn WWaatteerr SSaammpplleess Sample. Sample ID Triuonts Influent 3 nfoont 5 Influent 3* .., Infents Dup Influent 3 Dup Comb Effuent Comb Effluent Com Eun Comb Effluent* Comb Effuont Dup Comb Effluent Dup Porth Port 4A Por 4 Port 4A* PoteA Dup Port 4A Dup Eifuents Effluent 4 Effuont + Effluent 4* Effuent4 Oup Effluent 4 Dup nflort 12 Influent 1/2 Inn 12 Influent 1/2" fluent 1204p. Influent 1/2 Dup Tip Bank Trip Blank Analyte Analyte 8 Acid PFHA C6 Acid PFHA puctuoronsancitc Perfluorohexanolc Acid 55053.0 art47.1 5245.2 00871 0.0871 00828 0.0828 00746 0.0746 2525.5 2426.4 22 '.. 28.2 No . ND NNooND 8508.S0 8208.24-, 8398.39 ".. NOND Found Found ((nnCgg8limmAtLc))id PFOA C8 Acid PFOA ___purirpcoacinsc es Perfluorooctanoic Acid F222867l108 2NNN6Doo9 2NNN3DDo8 7.38 I84s6.81 8NnN.4DDD1 INNNDDgD 13.5 112s211.5 ND12.2 ND Sample D Sample ID Tne Influent 3 nent 3" Influent 3* nflvent3 Dup Influent 3 Dup Comb Eftuont Comb Effluent Comb Effuent Comb Effluent* `Comb Effuent Dup Comb Effluent Dup Po 4A Port 4A Por 4A" Port 4A* PotA Du Port 4A Dup Eftuent 4 Effluent 4 Effuont 4+ Effluent 4* Eftuont 4 Dp. Effluent 4 Dup font 12 Influent 1/2 nfuent 172 Influent 1/2" nfvent 1200p Influent 1/2 Dup Tap lank Trip Blank CSulfonato PFBS AnCaSlSyutlefFoonuatned P(FngHiSm) G8 Sulfonata PFOS. C4 Sulfonate PFBS Putoobumenstersts __ putsochesssmstecws__Puturescamessonss Perfluorobutanesulfonate 56 5% 8 86.6 72 6% 583 75.2 671 728 iss 67.1 005i ND ND 0.0544 00800 ND ND 0.0600 Na ND ND NQ 70 219 an 70.0 63 217 205 68.3 728 253 as 72.4 ND ND ND ND No ND ND ND No No ND ND 14s ash 650 145 2 42 S04 127 12 aso oat 132 no No ND ND ., Analyte Found (nglmL) , C6 Sulfonate PFHS ", Perf]uorohexanesulfonate 6.90 6.90 7.28 , ND "ND 2.53 ND ND ND 4.54 4.23 4.49 ND C8 Sulfonate PFOS Perfluorooctanesulfonate 59.8 56.3 45.4 ND ND ND 3.10 2.85 3.52 ND ND ND 6.60 5.94 6.41 ND HO =Not dotoca=d Respons0sbda00v2enegn. ND : Not detected : Response between 0 and 0.025 ng/mL. 0 otunital = Response bovean 0.028 gin. 4% LOG 0050 nl) NQ = Not quantifiable = Response between 0.025 n~/mL and LOQ (0,050 ng/rnL) "Labora uplste *Laboratory Duplicate `CHCEOONNNNFFEIIDPDEIENNNTTCIIAOALUL-N- STSUUYBBDJJIEESCCTTTRITTCOOT AACOPPURRROOTT,TEECNCTOT,IIVV2EE7-OOCRRV-DD1EE0RR.2E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00119933 ~3058 Research Drive Rist Boon usa ~ ~State College, PA 16801, USA 8142721009 13": 814.272.1039 HER ~F: 814.231.1580 ncn exygen.com 3M_MNO1538570 3M MN01538579 STANDARD TERMS AND CONDITIONS STANDARD TERMS AND CONDITIONS sence povidedby Engen Research re ed to theterms Service~ provided by Eygen Research are limited to the terms and condiions sat Hern, ues thee agreed ma and conditions stated herein, unless otherwise agreed to in a formal contac formal contract. common ees En owe) CONFIDENFtALITY-xygen Research d'Exygen,~' "u_~,'' or "we") ta antes corto 1 mii, 3 maintains the strictest confidentiality in all of our client interactions. If a Cardconcn semen std we nd ose on. 11 signed confidentiality a~reement is required, we will provide one ~[ a Ey oy apo aio, he wh x ed re~ula[ory or lesaf body subpoenas in,equation, the cl~en~ wil~ be notified rane heh pro eps pare rama promptly. The client agrees nol to use Exy~e~ s name and/o~ da~a ~n ~ny rr mt eg are a og eo> bone manner that might cause harm to Exygen's reputation or business. eat tae, te ie gf ie cit Approval mus~ be ob[ained, h~ wd~ng, before Exygen's name can be jiimivoo pub,}shed in any way CONTR4AscCtTuS se wii to ev sd pos CONTRACT.~-AII contracts are subject to review and approval by Rares ape 3 pr Exygen's le.~al-council and must be si~ned by a corporate officer. PAMENTTEAMS rion ot fot Pin rc, PAYMENT TER/14~--Unless otherwise set ~orth in lhi~ ~ulchase OTter, cmgayl re et 30s 0s eeshone or yr hE {emm of payment are "Net 30 Days." The time allowabk, for payment sh~ll Be ol 0 ns cEo ET 00 010 be~in after both: (a) client's receipt of Exysen's invoice; and (b) the Stay pra hesnes CoE hk A 15% satisfactory performance o1 the services contemplated hereunder A 1 iy eet cogs all sada ok okEres monthly service charge shall be added to all past due balances. twinay pyre moh ort bi 1 Notwithstanding any payment t~rms to H~e cor~hary set forth in this Io Ore or ykdeh rs Wg orett Purchase Order, Exygen~ in ~ts sole discretion, r~serves th~ right to r~qucst Former secret nn evn 5 Go oy payment in advance ~rom client. In th~ event o~ default ~n payment for Coren, openhh io es ot of hci, sexy}cos rendered, Exygen sha~ 9e enlit~d to reasonable costs o~ collection, ed tet i, stg includieg, but nol limited to, attorneys' fees. SLUNGtc 18 rswe A cy nhs BILLINg-All fees and charges are billed d~rectly to the client requesting Toe peoa:hry id gn ko serv}ces. 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Title and risk of loss with respect to submitted samples strol! at all msm a antpoco cep 1 yin Spe times remain with client prior to acceptance by an fxygen sample coda rnwhCtlo Aes wot OTH custodian. Exygen wilt initiate a chain-of-custody upon sample receipt ish Crt des coe wih th 1) By COTE unless the client includes one with the s~mp!e(s). By request, Exy~en will vie fio rms or rs provide chain-of-custody forms for client's use. gl tds compe: pach crsgred All sample~ submit[ed must be accompanied by: purchase order, or signed tm vit soon aman evar quotation; sample description, including ~mple type~ source, time and efoon: get oe eqs, Lg cnc date of collection: specific analyses requested; estimated concentration I, RUE Ce in AS, 0 TCT levels; requested report date; current biling address; and other relevant oman. information. Un eat Cyi wpe spe ample cota, Upon request, Exygen wiil provide and ship appropriate sample containers aims Tose mane wi de 1 Sop Sn to clients. These containers wil! include *.he appropriate preservative if Pon meee on LAD ea om particular analyses require one. It is the responsibility of the client to hand!e Ba peed corte ay snd srg petiey these preserved containers safely, and using all appropriate safety mason les eased Oo dh of te rs wl precautions. Clients requesting overnight delivery of sample containers will keds 0h 4b 0 MRS 3 ST be invoiced for freight. Eygen reserves the right tu charge a fee for sample wes containers. SAMPLE PSA ti ee fo cr tn sh .f;AMPLEDISPOSAL--Exygen retains samples for one month after ern ete, Gos ns. i he it reporting results, then disposes of or returns the sample. Unless the client sues tt hesrg be ears, on ro sgeens vebn requests that the sample(s) be returned, or prior arrangements have been atcnof ws ers en m~de for Ion..,~-term storage, Exygen sh~,tt dispose of the sample(s). Exygen 151 0 1 TT RL shall charge a monthly fee for I~ny,-term storage. SaiT~ples found or Lynl do woe, ebo ee s ie 0d suspected [o contain hazardous waste, a(~:ording ~o definitions in state and Je cts, wi eared one irupon mpl /or ederal uide~ines, wil! be returned to the client upon completion of the rn To cnt tor orgs we nd hk analysis. The cost of retumMg the sample(s) will be invoiced to ~he mans Ah dr+Btt fo ded [xygen reserves the right to charge a disposal fee for the disposal of any Sg oe TERE Cn ace rl and all samples unless returned by Exygen to client Exygen shall unless ere aching fi~e nature and character of fl~e sample didakes otherwise, store all samples bgenes e Ce pce UnCvarecSonin, c1 hr under locked, temperature-controlled conditions. An intern!! chain-of- custody is maintained for each tot of samoles received. 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QUALITYASSURANCE yHnA wi foram sgervsicicenter ith QUALtTYAS.CURANCE Exygcn will perform services consistent with its TT Quality Assurance Standard Operating Procedures (SOPs), the terms of pry orphv og lant, vin ert which are expressly incorporated herein by reference; provided, however, it pt tn ust prs er rn hts shah be the exclusive responsibility of the client to confirm that Exygen's tyes wih te ork eh oi nod standard prackices wil~ meet the client's needs prio~ to placin~ a~ order for rvcet de 1 arn oSONt 10 work, In ~he event client desires an alternative to these SOPs, such requests raee mde wr sr on Soe must be made ~n wr tin~ prior to sample submission and acceptance by ~ygen. ETHsICS POUY--Eaygn ames sve gre 1: hn th he ETHIC~ POLICY---Exygen Research strives to provide it~ dienis with the ihe andy oa 1 ft ai aud re kr highest quality data in the fastest realistic turnaround time. 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Ee amount paid to Fxygen for the work herein covered. Exygen wilt, ~f nun yn i. a coofmtarssfo as ~equested by the client, furnish ce~ificates of insurance flora its carrier GEIR Ae ce OE evidencing appropriate insurance coverage. WARRANTYAND UNOFILABTRITSY-- csi sy ws, WARRANTY AND LIMITS OF LIABILITY--In accepting analytical work, yn oreshe soy f he olbsis Exygen guarantees the accuracy of the test results for the sample as SE we 0 lee oti oe SO Wedc sry submitted within the tolerances set forth in the SOPs, We disclaim any nr ware, peed ety ns B35 dos rot cet ry other warranties, expressed or implied by law. Exygen does not accept any Epona) 5 hhdah is 115 legal responsioility for the purposes for which client uses the test results. on not cpt oy pre reo 4 tot kt Eygen wil! not accept any purchase order or any ot~er order for work that 056 Os 4 or he Sond Condon. includes conditions that vary ~rom t~ese Standard Cond tions. ACCEOPF UTRCAWANSEOCRDEER Th hse Orebicame3s ACCEPTANCE OF PURGHASE ORDER-This Purchase Order becomes in cert, pect em sdcorbin ed binding agreement, subject to the specific terms and conditions stated Per, pin Sys commencement of wk herein, upon Exygen's commencement ot work. `CHGEOONNNNFFEIIDPDEIENNNTTCIIAOALLUN-- TSSUUYBBDJJIEESCCTTTRITTCOOT AACOPPURRROOTTT.EECNCOTT.IIVV2EE7-OOCRRV-DD1EE0RR.2E6E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00119944 SW_MNO1838580 3M MN01538580 E en Xysen., ProPcrovReenseRaschk RocovorPySrouvemnmRaersuyltfs.orC8and CB Acidsand C4, C8 and C8 Sulfonatos in Water Recovery Summary for C6 and C8 Acids and C4, C6 and C8 Sulfonates in Water same Sample ". osscnpton Description ToLoo wSoF Influent 3 Low Spk . nso 10 ppb Spike no3HightSpk Influent 3 High Spk em 100 ppb Spike tu3 3s9k C Influent 3 Spk C priebint Laboratory Spike Cor EfLowtpk Comb Effluent Low Spk Tomson 10 ppb Spike CorbEfHightspk Comb Effluent High Spk ton 100 ppb Spike CorbEfnt sok0 Comb Effluent SpR D Lsome Laboratory Spike Port 4h Lowsk Port 4A Low Spk Tomine 10 ppb Spike pon ighspk Port 4A High Spk reste t0o ppb Spike PortenspkE Port 4 A Spk E Citmryn Laboratory Spike Effluent sLow spk Effluent 4 Low Spk nso 10 ppb Splice Euahighsnpk Effluent 4 High Spk ti 100 ppb Spike Euan aspr Effluent 4 Spk F Cssme Laboratory Spike fe72 Lon wSp Influent 112 Low Spk pe 10 ppb Spike nue 72 igShpk Influent 1/2 High Spk orton 100 ppb Spike nfo 17255K 6. Influent 112 Spk G tts Laboratory Spike TipBlaLonwSkp Trip Blank Low Spk Toms 10 ppb Spike TpBlaHignh Skk Trip Blank High Spk Eo10o ppb ArtFoucnoancAiampronn RrFomacocAamparton Amount Samp Recowred Recovery| inSampie RecovaedRecovery Spiked pipet) | ogimt) ingen get gm (n~l/mL) C6 Acid PFHA Amt Found Amount Recovery in Sample Recovered (ng/mL) (n~l/mL) (%) C8 Acid PFOA Amt Found Amount in Sample Recovered Recovery (ng/mL~ (n~llmL) (%) w | so ms o 10 53.0 54.0 [mae os 278 276 wf me 100 53.0 wm ow | om 156 103 278 ww 369 91 of me wr a | om ws 10 53.0 35.7 278 189 wo [oom wz wm | ow 0.0871 11.2 111 ND em wm 9.38 94 w [own ws 190 3.0871 87.6 ow | Ww 88 ND ne on 71.9 72 0 | oo.68n71 1w5s.o 1w5s5 | wows ND ws 10 11.5 115 wo | ms ws 10 25.5 " 38.5 ow | rw 130 7.38 we ow 16.8 94 wo| ms 100 ww | tm ows om 7.38 90.5 83 wo | ms 10 25.5 ws ow | tm 4~6 151 7.38 ws we 18.3 109 0 | wo 10 ND ze wm 12.0 . 120 wes we ND 9.95 100 wo| ww 100 ND 124 wm | ow ND ws ws 105 105 wo | wo 10 ND we wm | wo 15.8 ND me we 11.8 118 o | se we wo | ws ome ow 10 8.59 19.6 110 13.5 21.9 84 wo | sm we ow | ws sr ow t00 8.59 118 109 94.1 81 w | ese 10 8.59 ar an | ows 25.7 171 13.5 ms ow 26.5 130 wl we ow | oe mom 10 ND 10.1 101 ND . 7.82 78 w | 100 ND wi ow | ow 99.1 99 ND ms ow 82 ND =Nodated Response sawoon 0and D025rp ND = Not detected = Response belween 0 and 0.025 ng/mL. 40 Not uarbl Resproboween 025 rig 37d LQ 0.050 ink) NQ = Not quantifiable = Response between 0.025 nglmL and LOQ (0.050 ngimL) "Same eso cance SobelSGC,Drs 3n acl acre arntbe Ac ^Sample residue exceeded the spiking level significantly; therefore an accurate recovery cannot be celculav 205 egorv, ~ 3058 Research Drke oeCo, Bn, usa ~' ~State College, PA 16801, USA 7:s00m1 210 ~ T: 800.281.3219 RET ~ F: 814.272.1019 enpicom exygen.com `CONFIDE-NSUTBIJEACLTTO APROTECTIVE ORDER ENTERED IN 3M_MNO1538S81 CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO, 27-CV-10.28862 HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 3M MN01538581 11993377..00119955 XyPs rogeResen arch ., Precise Research Frown Resoks. Proven Results. Recovery Summaryfor C8 and C8 Acids and C4, C8and CB Sulfonates In Water Recovery Summary for C6 and C8 Acids and C4, C6 and C8 Sulfonates in Water Sample _ Ctsutonsepras . 6sutonss priRsecovery TIrnSiaFmopu8lnesSRoecAuomsvouaanrte0dRSecovery Sample oe hs op 0 gn Description Tiverton S70 Influent 3 Low Spk, rene wo | ws wa ue | swe wa ow | sme ar 10 ppb Spike . Amount Spiked (ng/mL) C4 Sulfonate PFBS Amt Found Amount Recovery in Sample Recovered (n~llmL) (n~l/mL) I%) C6 Sulfonate PFHS Amt Found Amount C8 Sulfonate PFOS t Amt Found Amount in Sample Recovered Recoveq/ in Sample Recovered Recovery (n~llmL) (n~l/mL) (%) (n~llmL) (ng/mL) (%) 10 86.6 99.2 126 6.90 17.2 103 59.8 46.1 ven 3 ighSp Influent 3 High Spk se wo | ess am ow | sw ws we | sme ws ss 10o ppb Spike 86.6 281 194 6.90 115 108 59.8 146 86 toon 335k C: Influent 3 Spk C frre 0 | ms was | ew wa ow | sms ws Laboratory Spike 86.6 39.3 6.90 11.3 44 59.8 46.3 Comp EuLaowsnok Comb Effluent Low Spk frre w | emu me we | wo ws ws | wo wz ow 10 ppb Spike 0.0544 12.9 128 ND 10,5 105 ND 10.2 102 Com EffuHiaghn3t5k Comb Effluent High Spk ote wo [ose wm | ow wr ow | ow mew 100 ppb Spike 10o ,,.0.0544 111 111 ND 80.7 81 ND 87.4 87 Comb Euant 85k. Comb Effluent Spk D frisimiis wom wz ow | wo wm ow | ww wm ow Laboratory Spike lO 0.~544 15.2 151 ND 9.22 92 ND 7.89 79 Port Low spk Port 4A Low 8pk ors w | me we + | ae me wa me ow 10 ppb epike lO 70.0 " 92.2 2.19 13.9 117 3.10 11.4 83 Port aa igShok Port 4A High Spk mospbe wo | me a om [ze we me | sw ws ow 100 ppb Spike 100 70.0 274 204 2.19 116 114 3.10 86.3 83 PotssprE Port 4 A 8pk E Leyton w | me mr a [ae ws wm [aw wr ow Laboratory eplke 10 70.0 84';7 ^ 2,19 10.5 83 3.10 11.7 86 Euan sLowspk Effluent 4 Low Spk Tomas ww ms am | mw we wm | ww ow 10 ppb Spike 10 ND 20.8 208 N D 10.4 104 ND 9.00 90 Eftauiaghnstp Effluent 4 High Spk see wl ow om wm | ow ow om | ow ow ow t00 ppb Spike lOO ND 154 154 ND 122 122 ND 92,2 92 Emonsspur Effluent 4 Spk F pie wl ww wr ow | wo ss om | wm ow Laboratory Spike 10 ND 8.05 81 ND 7.80 78 uot 12LowSpk Influent 1/2 Low Spk oir wo | ws ows x | us wr ow | em ws ow 10 ppb Spike 10 145 135 4.54 14.7 102 6.60 15.3 87 no12oignnpk Influent 1/2 High Spk msn wo | ws wm | as wm ow | so ws ow 10o ppb Spike 100 145 263 118 4~54 101 96 6.60 100 99 oot 255K 6 Influent 1/2 Spk G Loysmn wo | ws ow | as wr ow | ee wz ws Laboratory Spike 10 145 160 6.60 17.2 106 TipBiLnowSkk Trip Blank Low Spk Toms ow az oe | ow ex ow | ow ws ow t0 ppb Spike 10 ND 8.22 82 ND ".. 9.36 94 ND 11.3 113 Tip Bin High spk Trip Blank High Spk Ey w | wo me ow | ow | owe ww 10o ppb 100 ND 75.6 76 ND ~i04 104 ND 109 109 ND =Netdlocto Raspsbowen0304 0 25rg ND = Not detected = Response between 0 and 0025 ng/mL. NO < otcanta =Respon bvween 0023 TL 43LOQ 0050 i) NQ = Not quantifiable = Response between 0.025 ng/mL and LOQ (0.050 nglmL) "Sane esi examen Spi evel Scant: Brees inSccle ecoreycanto HOU ^Sample residue exceeded the spiking level significantly; therefore an accurate recovery cannot be calcula `CHEOCNNONFEINDPIEFNNITCIDAOLEU-N-NSTSUTYUBBIDJJIEAESCCTLTTRTITCOOT AACPOPURRROOTT,TEECNCTOT,IIVV2EE7-OOCRRV-DD1EE0RR.2E8E8NN6TT2EERREEDD IINN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00119966 3058 serchDeve 058 Research Drive REE Poon, use te College, PA 16801, USA 7.3002813210 : 800.281 3219 HR F: 814.272.1019 copa exygen.com 3M_MNO1538582 3M MN01538582 -_ SECTION B `CHCEOONNNNFFEIIDPDEIENNNTTCIIAOALUL-N- STSUUYBBDJJIEESCCTTTRITTCOOT AACOPPURRROOTT,TEECNCTOT,IIVV2EE7-OOCRRV-DD1EE0RR.2E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00119977 3M_MNO1538583 3M MN01538583 SECTION C `CHCEOONNNNFFEIIDPDEIENNNTTCIIAOALUL-N- STSUUYBBDJJIEESCCTTTRITTCOOT AACOPPURRROOTT,TEECNCTOT,IIVV2EE7-OOCRRV-DD1EE0RR.2E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00119988 3M_MNO1538584 3M MN01538584 E IY sooo rane ata272-1038 3058 Research Drive i SSttaattee CCoolllleeggee,, PPAA 1166880011 Phone: 814-272-1039 FFaaxx:: 881144--223311--11558800 "Login #: 1984. PrPorj~eecctt: PDPO000000B64444 J Company Name: STEW osreon Submitted By: LLooggiinn TTyyppee:: CoStarted: Er Tem Date Start: Fw om Due Date: S Tio S Sum Received Date: 3M KENT LINDSTROM IImmmmeeddiiaattee RReecceeiippttooff SSaammpplleess T 02/16/2004 03/01/2004 02/13/2004 Semias aTe Conform COC Sample: CoCnofnoforrmm CCOOCC:: Conform Sample: Conform Request: Truruee TTrruuee. True True Received By: Spread Sample: AMMERMAN, MARK =Label: ES ion: cota etd Carin ys Pusher FOUTRE Project Title/Type: Cottage Grove Activated Carbon System Fluorochemical Monitoring / ROUTINE Erect Te: tom Exygen SD/PI: Sonor Login Notes: RISHA, KAREN er. Conform Notes: com oom RIr CES ren, Package fo ran p LEeER Eorefr po PK0002470 Carton Mail Date I Condition Packages / Containers Sl~ipper I_ID 2/13/2004 11:45:28PM Package & Contents Uncompromised FEDEX 3168014411000001792570 728697201 Temp. Control/Temp. Wet Ice 0.1 opt Gover ot cowie meme Container # a i Pe C0027262 -- = io ee C0027263 -- Ee ee C0027264 oo =e C0027265 -- ET C0027266 -- poi E --i--eee C0027267 Gross Weight pH Container Type 613.8 g 603.6 g 255.5 g 254.1 g 600.9 g 603.4 g 500 ml Clear Plastic Narrow 500 ml Clear Plastic Narrow 500 ml Clear Plastic Narrow 500 rnl Clear Plastic Narrow 500 ml Clear Plastic Narrow 500 ml Clear Plastic Narrow Preservative NONE NONE NONE NONE NONE NONE Mfg._Lot oss Dira~ionlHandled By pre e. RECEIVED wee AMMERMAN, MARK Mfg. ID C0027268 254.5 g 500 ml Clear Plastic NONE -- C0027269 C0027270 250.1 g 596.2 g EE Narrow 500 ml Clear Plaslic Narrow 500 ml Clear Plastic eeNONE NONE C0027271 a C0027272 o_o C0027273 a C0027274 J C0027275 -- oa C0027276 591.3 g 252.6 g 257.8 g 598,7 g 599,2 g 266.2 g Narrow 500 ml Clear Plastic Narrow =e 500 ml Clear Plastic oo Narrow 500 ml Clear Plastic Narrow EEL 500 ml Clear Plastic Narrow = ee 500 ml Clear Plastic Narrow Cl 500 ml Clear Plastic EEL ee Narrow NONE NONE NONE NONE NONE NONE C0027277 267.2 g 500 ml Clear Plastic NONE Narrow ssen 2/1712004 Login.rpt rovenrnsons Report Version: Feb 9 2004 11:07AM Page I of 5 me instance: sion R0086666 [DRERRRIN CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN 3M MN01538585 HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00119999 nProyjnekct Project: PO0008"44. aii P0000644 `SCCuoobmmmppiaatnneyyd NNBaya:mmee:: SLSLtoaougrgbitimnnediTTt:tyyeppdee:B: y: DDSDautaafetreoteSDSadttt:raetr:t:: RRDReouecceceoeiiDivvvaeeetdedd:BDDayat:tee:: SLSRappebrerceele:aaivddeSSdaaBmmypp:lle:: EPLPrxarooybjjegeelecc:tnt TTSiiDtlIlePe/ITT.yyppee:: CLLEoooxnggyifginoerNnNomotSteNeDsos:/t:Pehs: Conform Notes: 33KMMENT LINDSTROM KENT LINDSTROM TImmediate Receipt of Immediate Receipt of SSaammpplleess 00T03221/11066127/22000000444 0A00223V/1/M01113E3///R22200M0000A444N, MARK AMMERMAN, MARK CCRooIttSttaHaAgg,eeKGGArrooRvvEeeNAAccttiivvaatteedd CCaarrbboonn RISHA, KAREN SSyysstteemm -- FFuluoorroocchheemmicicaall Coonfnorm TCOCo: RTruee e CCCCoooonnnnffffoooorrrrmmmm SRCSoaaOqmmupCelp:selet::: ~~ TTTTrrrruuuueeee. Conform Request: True MMoonniiotorriinngg // RROOUUTTININEE. vn package canon Package Pronnzare PK0002470 Carton Packages | Containers Packages / Containers Mat One Constion Suppl Mail Date I CondJtion Shipper I_ID razon sraszsou Foe 2/13/2004 11:45:28PM Pack& Caagnnea Uncompronised S1GSDILATIORO001TOZ5T0 Package & Contents Uncomprornised FEDEX 3168014411000001792570 Temp Conoffemp. Temp. Control/Temp. wetico Wet Ice oF0.1 DirectonMansessy Dire~ion/HandledB Receneo RECEIVED ANERUAN, MARK AMMERMAN, MARK Consior# Container # zr C0027278 wm C0027279 comm C0027280 com C0027281 ame C0027282 mm C0027283 came C0027284 GussWeght Gross Weight stag 591.3 g sro 600.7 g 2sa2g 258.2 g ws10 265.1 g 30 251.3 g 23g 253.3 g 220g 252.8 g pH ContaherTypo pH Container Type S00 Glew sic 500 ml Clear Plastic Nano Narrow 500 GearPiast 500 ml Clear Plastic Nao Narrow 500miClosPasi 500 ml Clear Plastic Narrow 00mGearPaste 500 ml Clear Plastic Narn Narrow 00m Ciow Pas 500 ml Clear Plastic Nano Narrow 500 miClosPast 500 ml Clear Plastic Nao Narrow 500mCla laste 500 ml Clear Plastic Namo Narrow 728697201 EPrroesoseevnrveaattivvee NONE nove NONE Howe NONE none NONE none NONE nove NONE none NONE Mig Lot Mfg._Lot ry Mfg. ID 2172004 Lo2g/1i7/n2p00t4 RReeppoorrtt VVeerrssiioonnP::agFFoee2bbol99s22.000044 1111::0077AAMM `CHCEOONNNNFFEIIDPDEIENNNTTCIIAOALUL-N- STSUUYBBDJJIEESCCTTTRITTCOOT AACOPPURRROOTT,TEECNCTOT,IIVV2EE7-OOCRRV-DD1EE0RR.2E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00220000 Instance: Instance: IWRRARERI Roses R0086666 3M_MNO1538585 3M MN01538586 [ET SamplelD woviareoonn L0001874-0001 ood L0001874-0002 loowrioon L0001874-0003 LoOa0l L0001874-0004 Lootoeas L0001874-0005 LOETio00 L0001874-0006 operant L0001874-0007 LOETA000 L0001874-0008 L0001874-0009 Comrie L0001874-0010 LETT L0001874-0011 oot L0001874-0012 Loowrions L0001874-0013 Lootcots L0001874-0014 loowraons L0001874-0015 Lootecots L0001874-0016 loowraons L0001874-0017 Loowions L000t874-00t8 LOA L0001874-0019 odio L0001874-0020 lotion L0001874-0021 looweams L0001874-0022 ood L000t874-0023 Matrix G06 LIQUID UGUD LIQUID UQUD LIQUID UGUD LIQUID OUD LIe UID UGUD LIC UID UGUD LIe UID UGUD LI~ UID LIC UID UGUD LICUID UUD LIe UID UGUD LIG UID UGUD LIGUID UGUD LIQUID Uo LIQUID LGD LIG UID UoUD LIQUID LOUD LIQUID UGUD LIQUID LOUD LIQUID UOUD LIQUID LGD LIQUID LOUD LIQUID CRI a) Samples Fraction Vas imam Water wa ienaom Water Weer bmeadlovspue Water Wem nenaion Soke Water Wee ComEd Water Wem Corb EManioup Water aw Com EMlnionsete Water Wawr Carb Efantigh tobe Water Water Wem hetiadw Water Ww Per Alowspie Water We Patianonee Water Wem End Water Wel Eleni Water ew Emiovsske Water Wem Em anonie Water Wem hens Water Wee bieai2on Water Wier Inet PL Spe Water Wem be izichse Water Wow Trade Water Wem IrpBanciowspie Water Weer TrpSiestaSpe Water Samples Sample Influent 3 Influent 3 Dup Influent 3 Low Spike Influent 3 High Spike Comb Effluent Comb Effluent Dup Comb Effluent Low Spike Comb Effluent High Spike Port 4A Port 4A Dup Port 4A Low Spike Port 4A High Spike Effluent 4 Effluent 4 Dup Effluent 4 Low Spike Effluent 4 High Spike Influent 1/2 Irtfluent 1/2 Dup Influent 1/2 Low Spike Influent 112 High Spike Trip Blank Trip Blank Low Spike Trip Blank High Spike OSstorgDloRoovge Date Sampled Date Received Ca wes 02/12/2004 02/13/2004 a es 02/1 2/2004 02/1 3/2004 mos tous 02/12/2004 02/13/2004 am oor 02/12/2004 02/13/2004 i ol 02/12/2004 02/13/2004 mos cos 02/12/2004 02/13/2004 wa oes 02/12/2004 02/13/2004 Grn ove 02!12/2004 02/13/2004 02!12/2004 02/13/2004 Gos wus 0211212004 02/13/2004 i ves 02/12/2004 02/13/2004 mor camo 02/12/2004 02/13/2004 Grn wes 02/12/2004 02/13/2004 mos Games 02!12/2004 02/13/2004 mos coin 02/12/2004 02/13/2004 mos Goamos 02/12/2004 02/13/2004 Grn ones 02/12/2004 02/13/2004 Gr wes 02/12/2004 02/13/2004 mos cramer 02/t 212004 02/13/2004 os cos 02/12/2004 02/1312004 Gros 02/13/2004 rv 02/13/2004 Gaon 02/13/2004 wou Date Due Gaia 03/01/2004 covzios 03/01/2004 cots 0310112004 caovzios 03/01!2004 covzios g3/01/2004 covzos 03/01!2004 ovo 03/01/2004 coral 03/0112004 03!01/2004 Govan 03/01/2004 ovo 03/01!2004 ois 03/01!2004 covzos 03/01/2004 ois 03/01!2004 caovaos 03/01/2004 Govmos 03/01!2004 caval 0310112004 caovzos 03/0112004 cots 03/0112004 caovzos 03/01!2004 cats 0310112004 coves 03101/2004 caovaos (]3/01/2004 on re 2004 2/17/2004 Report Version: Fob 92004 1:07AM Report Version: Feb 9 2004 1 "i :07AM Login.rpt Page 3 of 5 `CHGEOONNNNFFEIIDPDEIENNNTTCIIAOALUL-N- TSSUUYBBDJJIEESCCTTTRTITCOOT AACOPPURRROOTT.TEECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR.2E6E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00220011 stance: Instance: RAR Rovssass R0086666 SW_MNO1838587 3M MN01538587 L0001874-0001 L0001874-0001 Container Container [Er TR---- C0027262 1 500 ml Clear Plastic Narrow / NONE LL00000011887744--00000022 C02C7Con2otnaTtaiinn8e1err0l0or PiastNarrINoONwE C0027263 ! 500 ml C~ear Plastic Narrow / NONE LL00000011887744--00000033 CoC0o2Cn7otnaTtiaSniOneerr Close Pas Narrow NONE COD27264 ! 500 ml Clear Plastic Narrow/NONE LL00000011887744--00000044 (CnaCrCoEnoAtnata3iinn0ee4rr Cla PlastNarr/NoONwE. C0027265 f 500 ml Clear Plastic Narrow/NONE LL00000011887744--00000055 (C0aCrCoanEot8na$taiin0neerr Cla Past NoIrNONtE. C0027266 f 500 ml Clear Plastic Narrow/NONE 1LL00000011887744--00000068 C02CoCnetTnatianinmeerr Clot Pas NarIrNOoNwE C0027267 ! 500 ml Clear Plastic Narrow / NONE LL00000011887744--00000077 CoC0o2CnoTtnaAtiaTnin0eer0r Clar Ps NarrINoONwE C0027268 / 500 ml Clear Plastic Narrow / NONE LL00000011887744--00000088 C002CCo7n2oln3at8ai7inn$eme0rtr Clot PlasNarrow NONE C0027269 / 500 ml Clear Plastic Narrow / NONE 1LL00000011887744--00000099 Co0C2CoTnoElnTatOaiiTnneEeri0r ClosPastNarIoNOYwE C0027270 / 500 ml Clear Plastic Narrow / NONE L0001874-0010 L0001874-0010 Container Container Co027ET 70m Gar Ps Narow NONE C0027271 / 500 ml Clear Plastic Narrow / NONE LL00000011887744--00001111 COCOConTotnEata0iTin0neeirr Csr Pasc Haron NONE. C0027272 / 500 ml Clear Plastic Narrow / NONE 1L0001874-0012 L0001874-0012 Gontainer Container COO TE30 i iar Pa row NONE C0027273 / 500 ml Clear Plastic Narrow / NONE BBoottttlleess MMeetthhoodd MMeetthhoods MMeetthhoodd MMeetthhoodd MMeetthhoodd MMeetthhoodd Method Method MMeetthhoodd MMeetthhoodd MMeetthhoodd MMeetthhoodg Motnos Method 2172004 2/17/2004 Lognrpt Login.rpt RRepeoprotrtVVeresrsioionnP::agFFeoedbbo99f22000044 11.07AM 11:07AM Page 4 of 5 `CHCEOONNNNFFEIIDPDEIENNNTTCIIAOALUL-N- STSUUYBBDJJIEESCCTTTRITTCOOT AACOPPURRROOTT,TEECNCTOT,IIVV2EE7-OOCRRV-DD1EE0RR.2E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00220022 Instance: Instance: [IIWIt1I11ARARRRR I 0R0008866065656 3M_MNO1538585 3M MN01538588 L0001874-0013 L0001874-0013 Container Container Con ls Past No NRE C0027274 t 500 rnl Clear Plastic Narrow / NONE L0001874-0014 L0001874-0014 Container Container COLLIS 300 TH ls lsc Now NONE C0027275 t 500 rnl Clear Plastic Narrow / NONE[ CoCnoneta8 iner le Ps aro HE LL00000011887744--00001155 Container C0027276 ,~ 500 ml Clear Plastic Narrow / NONE L0001874-0016 L0001874-0016 Container Container Cana HRi et Pasi Narn KONE C0027277 / 500 ml Clear Plastic Narrow / NONE L0001874-0017 L0001874-0017 Container Container OnE E00 les Past ron NONE C0027278 / 500 ml Clear Plastic Narrow / NONE L0001874.0018 L0001874-0018 Conines Container TT ---- C0027279 1 500 ml Clear Plastic Narrow ! NONE Lo001874-0019 L0001874-0019 Conner Container CroSSE S08 osPas aro ONE C0027280 / 500 ml Clear Plastic Narrow ! NONE ona ContEsinHer CsPst Naru NONE LL00000011887744--00002200 Container C0027281 /500 ml Clear Plastic Narrow/NONE ConCoenai5n8er ine Pash Now NORE LL00000011887744--00002211 Container C0027282 J 500 ml Clear Plastic Narrow ! NONE CoCnoentsainer lsh ron NONE L1L00000011887744--00002222 Container C0027283 t 500 ml Clear Plastic Narrow / NONE ConoConntSainHer Clones row NONE LL00000011887744--00002233 Container C0027284 t 500 ml Clear Plastic Narrow/NONE Meio Method Method Method MMeetthhoodd MpMeeetththoeadd rMMeeetthnroeod MMeetthhoodd MMeetthhoodd gMveeetthnotoda wetoa Method MMeetthhoodd Method Method Pe 2/17/2004 CognLogin.rpt Report Version: Fob 92004 107A Report Version: Feb 9 2004 11:07AM Page sols Page 5 of 5 `CHCEOONNNNFFEIIDPDEIENNNTTCIIAOALUL-N- TSSUUYBBDJJIEESCCTTTRITTCOOT AACOPPURRROOTT,TEECNCTOT.IIVV27EE-OOCVRR-DD1EE0RR28EE8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00220033 IInnssttaannccee:: IRARATY Roosssss R0086666 M_MNO1S38589 3M MN01538589 EE~xRyESgEeeRARnTnCLH CHAIN OF CUSTODY/ANALYSIS REQUEST FORM CHAIN OF CUSTODY/ANALYSIS REQUEST FORM Si m em i merr ro Exygen Research Sample Receiving 3117 Research Orive State College, PA 16801, USA T: 814.231.8032 F: 814.231.1580 exygenresearch.com Page. of __ Cig am me ae dres: reajenctaagnaegrer!(ame Emal Adres: C|ient (name & address): Project Manager (Name & E-mail Address): .- h fByeepoee Tderna ea eresin st Fax:Phone: SR e AJitE wage Cain $e Fax: i~- 453. Project Name: PO# oyoone Quotation #: ses to form evlpto eae msmigntrer veda Tor Please fill out this form completelyto ensure correct analysis and proper handling of your samples. SAMPLE ANALYSIS Li SAMPLE ANALYSIS ~~.-~= [ose Tae seme ston 115) 888cToomer Ic~llectionI Collection Ex)'UMS# Client Sample Identification Date 13me ~ u ~'U Speci~ Matrix Comments [avers Dlalofloab[<1 Teter | TTT 11 Cy 3p 1TUHCHTTTT" T1T7T1T1T1 S218 ICaeenuerr|Heese -- 1 HH H e er e0%E 2 8 HH ~8 USE ONLY CCHHAAIINN OOFF CCUUSSTTOODDYY Cov8eLaritr coe. 0.2L |ets Det Cooler ID # L"/~,',';-'P~ Cooler Temp. (C) ~ ,/ Results Deadline: [RelR iiqque lshedi~p~q- uis TouDhtateeedtTiip mmee y|[RoRcecoeiivvedebdyy __ JoDwatee TvTmimee ||___________ [AA Dl[Hab| [zoje /en| ike| |LaLbaobroarattoorryyRReeppoorrttOOptpitioonnss:: xrT AT | []sSeammpelerreesstusltsoonnyly | 1 CC TT1 | CFl-iaAdddccaasseernaamrraattivee CT C T CTT] | Il~]aAcceldqquuaalityyccoonnttrooll ssuummmmaary EH LAB USE ONLY [~.~AAddddcaclailbibrraattiioonn ssuummmmaarryy promo----------|gil " OTHER INFORMATION Cote - [] Add raw data [] Othe~ freA paar CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 3M_MN01538590 11993377..00220044 Ex \N n RESEARCH CHAIN OF CUSTODY/ANALYSIS REQUEST FORM CHAIN OF CUSTODY/ANALYSIS REQUEST FORM CopgenResearch SampleReceiving + 317 ResearchDrive taeColege, PA 16001, USA. Exygen Research Sample Receiving - 3117 Research Drive State College, PA 16801, USA Sp _-- T: 814.231.8032 F: 814.231.1580 exygenresearch_com Page __ of __ Cit ame addres Project Manager (ame & Emil Adres Client (name & address): Project Manager (Name & E-mail Address): EI aIma e RsidT e w a aYEe i etaes o-- uhenToh Phone: Res i Fax: ~~(--q,~;~-2.~?_~I ee Tat Ouotsion 5 Sampler:~ Project Name: RO. #: ~-~" ~ Quotation #: ot tata eth om SETI: Please fill out this form completely'to ensure correct analysis and proper handling of your samples. [SSEAAsMMsPPTLLnEEsAAomNNeAALLaYnYStSoIInSS[RTLi8li88 ms Teme Collection Collection Ex~ILIM$# Client S~ple Identification Date Time specify Matrix Comments [ Meovdn Hlalgifwas[=< | [eke| TT TTT I opruplootows [1 [I [TU[1T I T" 1] Toes WABgwopne |N11 TTTTTT 111711 I lerwgerd Qala(T( TCT1TTT T1111 va TT T I TT T1111 CTTeens |TTT OFC TT" 1111711 SS VJ 21:1 2 SS A CHAIN OF CUSTODY LAll USE ONLY CHAIN OF CUSTODY Coo cress cotter 0.2L | ts Dre Cooler Temp. (C) d, Results Deadline: Se Re inquishe b Date Time EeadRd l[l MR| [ Received t~ e bfDim at/e m:|yTipmec||LLaabboroarattoorryy RReeppoorrtt OOppttiioonnss:: = = or A TTT | D[]seSvapmlpelereressuulmtssoonnlyy TT | C[]aAsdddacsasee nme narrative -------- 1 1 1 SS S-- -- [] Add a quality -- control summary O[OTTHHEERR IINNFFOORRNM~AATTIIOONN LAB USE ONLY [m pre ReRO)I `CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY ET Se DISTRICT COURT, NO. 27-CV-10-28862 EeAdd raw data " [] Add calibration summary [] Add raw data [] Other IM_MNGTS38501 3M_MN01538591 11993377..00220055 EiW(yOoRena, CHAIN OF CUSTODY/ANALYSIS REQUEST FORM CHAIN OF CUSTODY/ANALYSIS REQUEST FORM m A TSmMem sa can non anton Exygen Research Sample Receiving 3117 Research Drive o State College, PA 16801, USA 1"." 814.231,8032 F: 814.231.1580 exygenresearch.com Page of__ Ci gue =tte) pm----r---- Client (name & address): Project Manager (Name & E-mail Address): PoGl ag os iSmwMsaege fmoerint I~,q~ffanl uhmeis Bo EYRe i hte Phone: ~-~~ Fe Jt goles Fax: FoFaas Quoin Sampler: ~,o~ Project Name: RO. #: E~o~Quotation #: et ee aT AT----r Please fill out this form completelyto ensure correct analysis and proper handling of your samples. SAMPLE ANALYSIS Lil SAMPLE ANALYSIS [ems[ansmeenter[5 8 eTm emes Ex~tLIMS# Client Sample Identification Collection Collection "~= Date Time ~ ~o =o~=- U Z~ Specif7 Matrix Comments Tv eee LvTe =< TT ITague TU <P TT TTTT1T71T1 CT wggpue TT [0 =011 T" TT" Cee -- TT TTT--T"T TT T T EE esbak loge | TTTTT TTT TTT11 Tbrhogs gate | | | TTT T7"T7171 A --~-- yey ,LAB USE ONL~ CHAIN OF CUSTODY Co00Ckreseco 0002 [Hesbane] CHAIN OF CUSTODY Cooler ID # ~7,~.'~-~" Cooler Temp. (C) ~ ( Results Deadline: [ ReliR nguise hedl b~, n . gusTohDmaete e TdvTmb imee y|[ReRceocieivveeddbb~y/ ToDsatee IvTmimee | [(Z--chlT BRINGS |[comma Dli/ey| vr] |LaLbaobroartaotorryyRReeppoorrtt O Oppttiioonnss:: 7 = &1 77 - [77 TOs [] Samplerrsesuutltssoonnlyy TT TT |D[]aAsdddacsaseennaaarrtantivee C1777 CTT |E[l]aAdddqquuaiallittyy ccoonnttrroollssuummmmaarryy mn Roi LAB USE ONLY [] Add calibration summary RR Hse , OTHER INFORMATION r~Add raw data [] Other rt COI:'4FIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 3M_MN01538592 11993377..00220066 anand 2/12/2004 PPrroojjeecctt:: EE0044-00112200 3M 5M EEPrNNelVViIImRiRnOaOrNNyMMUnEEtNNsTTthAAoLLriLLzAeAdBBOORReRpAAoTTrtOORRYY Preliminary/Unauthorized Report Page lof18 Page 1 of 18 Requester: Galloway, Tia M. 145.01, COTTAG PDRDreeeopqpjauearcertttsmmteNenerutn:m:tGb: ea11rl11l:o22w5588a33y, Site Sources 01673120 Tina M. (145-01, COTTA(3 Site Source: 016Z8120 DPDParraojetjeeecRcRtetecNDceieusvicmverebiddpe::tri:21o/n11:/12/C20o0t00a44ge Grove Carbon System Testing Copy List: Mader, Brisn Q3E.09) Project Description: Cottage Grove Carbon Copy List: Mader, Brian (2-3E-09) System Testing Comments: Comments: CPCrooommjpelpcetletLtiieooannd:DDaJatteee::s. Eldridge PPPEmhhroaaojirneleectANNdLuduemrmabedsbe:ser.Jr::ess66s5l5S11d..-77Er77l8i8d.-rd5i5d22gg33e3e3 @mcmoem Email Address: jseldridge@mmm.com "Th Filtered TOC needso be Fiered with Teo Filer The Filtered TOC needs to be filtered with a Teflon filter. TOC sample were preserved tiofcmollecetion. Thepreservedsamples were feredbefor analysis(RAS-Pace-21204). TOC samples were preserved at time of collection. The preserved samples were filtered before analysis (RAS-Pace-2/12/04). 3M Sample Number SumpledDate__ Sample Description En3oMnzS0am.6p7le4N02umber 212008 Sampled Date SInafmlupelnet DPheasscreip1t2i,on PLAELaA0Cn4BE-0120-674A32nATsoniasltyOctriacgaallnMiMect2Ce/tha1hot2od/od2n004 CoCFimolmpllenondonfnlTreuanaetnsnOtrPghaanseC1a/r2bon PaPAcCeE 50DTotal (ste) Organic Carbon FBiilotcehreedmiTcaoltalOOnyrggaennicDCemarabnodn PaPPPAAaccCCeeEE BOD (5-day) Earaes0s EPA 420.4 Biochemical Oxygen Demand PLheLnoTli(AbAeP)tans Phenol (AAP) PACE EPA 624 l, 1,1-Trichloroethane 1L1122T2rThelrodeieodoasnteane l, 1,2,2-Telrachloroethane Li Dicrctase 1,1,2-Trichloroethane 1,l-Dichloroethane 1,1-Dichloroethene 12Dictortenzoe 1,2-Dichlorobenzene 12 Dictrctbane 1,2-Dichloroethane 12 Diorproure 1,2-Dichloropropane LiDesioteniene 1,3-Dichlorobenzene LiDiotersne 1,4-Dichlorobenzene 2 ChoosViyEber 2-Chloroethyl Vinyl Ether Bens Benzene Bromadichomactine Bromodichlommethane [ry Bromoform Bromomctince Bromomethanc Caton exci Carbon tetrachloride Chlrotensene Chlorobenzene Chlacthns Chloroethane Chlroom. Chloroform Crlromethne Chloromethane 1 3Dicroprpene cis-l,3-Dichloropropene Dirmosbloamtire Dibromochloromethane -- Ethylbenzene Meter horde Methylene chloride Tarlac Tetraehloroethene Tolooe Toluene rns 12-Dchoroceee trans-l,2-Dichloroethene as 3Dicklovopapre trans-l,3-Dichloropropene Trablorthes Trichloroethene BeaResult BRLL oui Qualifier `CHCEOONNNNFFEIIDPDEIENNNTTCIIAOALLUN-- STSUUYBBDJJIEESCCTTTRITTCOOT AACOPPURRROOTT,TEECNCTOT,IIVV2EE7-OOCRRV-DD1EE0RR.2E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00220077 3M_MNO1538593 3M MN01538593 2/12/2004 ao IM ENVIRONMENTAL LABORATORY 3M ENVIRONMENTAL LABORATORY Prelminary/Unsuthorized Report Preliminary/Unauthorized Report Project: 040120 cont) Project: E04-0120 (cont.) 3M Sample Number Sampled Date Sample Description 3M Sample Number Sampled Date E0120.67452 (cont) 2122000 fluent Phase 12 E04-0120-67432 (cont.) 2/12/2004 Lan AmbitMethod Components Rot LAB FAG Enea) Tocomioroncie PACE Analytical Method EPA 624 (cont.) race eras [2Hr22HV+DT2 N1PT1No22NHC2DA2p 1o1A2D+F4BHPA.iPDFPJ 4B.422piyo-4aiiciCeoer42leDnuaohyebCDDt0maobccDDahnom6b4ahcoDDDtoDoieihbmcipaaipCmelsrlinrCTio-c Tiinlooerpsthonincirnhoe essuesonmpib iycnvifpoencboiocprbroiebeieegorineoeoeodtasttrfcnrshpnrasnhooneDretappb:agueh--eebtbbaeototyoeenpehsyheskdranitn-- cniseevorrclcn)szoqiedanpahnattanaralebtbcenislepmeeteeeoanercrn!etcnyynti((skaeteuutseenmrrss:)e) PACE EPA 625 Sample Description Influent Phase 1/2 Components Trichlorofluoromethane Vinyl chloride 1,2-Dichloroethane-d4 (surf) 4-Bromofluorobenzene (surf) Dibromofluoromethane (surf) Toluene-d8 (surr) Phenol bis(2-Chloroethyl)ether 2-Chlorophenol 1,3-Diehlorobenzene 1,4-Diehlorobenzene 1,2-Dichlorobenzene bis(2-Chloroisopropyl)ether N-Nitroso-di-n-propylamine N itrobenzene Isophorone 2-Nitrophenol 2,4-Dimethylphenol bis(2-Chloroethoxy)methane 2,4-Dichlorophenol 1,2,4-Trichlorobenzene Naphthalene Hexachlorobutadiene 4-Chloro-3-methylphenol 2,4,6-Trichlorophenol 2-Chlomnaphthalene Dimethylphthalate Acenaphthylene 2,6-Dinitrotoluene Acenaphthene 2,4-Dinitrophenol 4-Nitrophenol 2,4-Dinitrotoluene Diethylphthalate 4-Chlorophenyl-phenylether Fluorene 4,6-Dinitro-2-methylphenol 4-Bromophenyl-phenylether Hexachlorobcnzene Pentachlorophenol Phenanthrene Anthracene Di-n-butylphthalate Fluoranthene Pyrene Butylbenzylphthalate Result `CHCEOONNNNFFEIIDPDEIENNNTTCIIAOALLUN-- STSUUYBBDJJIEESCCTTTRITTCOOT AACOPPURRROOTT,TEECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR-2E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00220088 Puge20018 Page 2 of 18 BLR.~_L Oui Qualifier IM_MNO1S38594 3M MN01538594 2/12/2004 ao 3M ENVIRONMENTAL LABORATORY 3M ENVIRONMENTAL LABORATORY Preliminary/Unsuthorized Report Preliminary/Unauthorized Report Project: E0012 (cont) Project: E04-0120 (cont.) 3MSample Number Sampled Date __ Sample Description 3M Sample Number Sampled Date E0020 (cont) 2122008 neat Phase 12 E04-0120-67432 (cont.) 2/12/2004 an AmmiclMthod Compeners Rest LAB Fac: Baas SrDiemberitioe PACE Analytical Method EPA 625 (cont.) Ea FishAc Tes 96 [PBBBCiDBIDHN222irTFe.eFe4eedsir6hrmrenieeooeaiTobmoAelntehitneanatcotopacmrhnmohettty2aabmearr--euateTotannrnireidelnne3ntd)reysb(pe9ecrurueasurnrrdnr))neryeeb))slsr) ERA ERA Tot Res Chie, TouResaCire ERA Ea ArmoniaNiogen Ammonia GNI) ERA ERA wt it ERA Era Conta Contativty ERA Era DisohedOmen DisoledOugenFe) ERA era Tenpontae Tempers ERA MELA EISLiS0 a0 3M_ENVLAB Fish Acute Test - 96 Total Res Chlorine Ammonia Nitrogen pH Conductivity Dissolved Oxygen Temperature ETS-8-148.0 Boon Loss SeeeareAroreeorrersstssttsee EXYGEN LCMS ome mm mePrJeronoxsseme E04-0120-67433 2/12/2004 un AnahiMeret Components Bek LAB Ed "ol OrgricCaen Fire To Organic Caton PACE ns Mery EA 1631) Mewuy NSA Ba FhAceTx96 FishAce Tet 9 her ERA Ea To ResCarine Tod ResiChine ERA Era AmmonisNissen AmoarsNSa) ERA Analytical Method Total Organic Carbon Mercury (EPA 1631) Fish Acute Test - 96 Total Res Chlorine Ammonia Nitrogen Sample Description lnfluent Phase 1/2 Components 3,Y-Dichlorobenzidine Benzo(a)anthraecnc Chrysenc bis(2-Ethylhexyl)phthalate Di-n-oet~lphthalate Benzo(b)fluoranthene Benzo(k)fluoranthene Benzo(a)pyrene Indeno(1,2,3-od)pyrene Dibanz(a,h)anthracen Benzo(g,h,i)perylene Hexachloroethane Nitrobenzene-d5 (surf) 2-Fluorobiphenyl (star) Terphenyl-dl4 (sun) Phenol-d6 (surf) 2-Fluorophcnol (surf) 2,4,6-Tribromophenol (surf) Fish Acute Test - 96 hour Total Residual Chlorine Ammonia (as NH3) pH Conductivity Dissolved Oxygen (Field) Temperature APE0 APE1 APE2 APE3 APE4 APE5 APEI4 APE15 APE16 PFOS PFHS PFBS PFOA PFHA Influent Phase 3 Components Filtered Total Organic Carbon Mercury Fish Acute Test - 96 hour Total Residual Chlorine Ammonia (as NH3) Result Result `CHCEOONNNNFFEIIDPDEIENNNTTCIIAOALLUN-- STSUUYBBDJJIEESCCTTTRITTCOOT AACOPPURRROOTT,TEECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR-2E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00220099 Page sor Page 3 of 18 BL Oui Qualifier mo Oui Qualifier IM_MNO1S38595 3M MN01538595 2/12/2004 2004 3M3M Project: E0120 cont) Project: E04-0120 (cont.) 3M Sample amber Sampled Date 3M Sample Number Sampled Date 001206733 (cont) 2122008 E04-0120-67433 (cont.) 2/12/2004 Lan AniMahed LAB Ea BH ERA Ea Connery ERA Era DialedOxygen ERA boa tempee ERA Boo Low, EXYGEN Analytical Method pH Conductivity Dissolved Oxygen Temperature LCMS Teme Dia E04-0120-67434 2/12/2004 Lan AmineMahe LAB FAGE Tom OpaanCaten PACE Pc BoD PACE Pace Eeanos PACE pace rv PACE Analytical Method Total Organic Carbon BOD (5-day) EPA 420.4 EPA 624 EEPrNNeVVlIImRiRnOOsNNrMyMUEEnsNNuTTtAAhoLLriLLzAAeBBdOOReRRpAAoTrTtOORRYY Preliminary/Unauthorized Report __ Sample Description Sample Description eat Phase lnfluent Phase 3 Components Ren Components EpH Contry Conductivity Disoled uy Fick) Dissolved Oxygen (Field) Tenperae Temperature #05. PFOS reus. PFHS ProsPFBS Fron PFOA [i PFHA EmoeiCabont Effluent Carbon 4 prm-- Ret Components FiteToOrg aon Filtered Total Organic Carbon Bich Oxygen Deed Biochemical Oxygen Demand Fad (AT) Phenol (AAP) Litre: 1,1, l-Trichloroethane 1122Terscrctane 1,1,2,2-Telrachloroethane WaT I, 1,2-Trichloroethane 11Diborcine 1, l-Dichloroethane 1 Dickens 1,1-Diehloroethene 12Dihlrbensns 1,2-Diehlorobenzene 12Dihlrochue 1,2-Dichloroethane V2Dikrapeopne 1,2-Diehloropropane 13 Dibltensse 1,3-Dichlorobenzene Result Result 2Corsi Vil ter 1,4-Diehlorobenzene 2-Chloroethyl Vinyl Ether Benzene Bromodiehloromethane Bromo Bromoform Brommmetze Bromomethane Catone Carbon tetrachloride Chlorsentse Chlorobenzene Cocchi Chloroethane Color Chloroform Comctne Chloromethane ce Dilororpene eis- 1,3-Dichloropropene Divomosbomebunt Dibromoehloromethane [oe Ethylbenzene Metischoi Methylene chloride Tenors Tetrachloroethene Toke Toluene 2 ictorsers trans-l,2-Dichloroethene rn copes trans-1,3-Diehloropropene Tresor Trichloroethene Tralee Trichloro fluoromethane Vim cde Vinyl chloride 12Dihrothan4e a) 1,2-Dichloroethane-d4 (surf) `CHCEOONNNNFFEIIDPDEIENNNTTCIIAOALLUN-- STSUUYBBDJJIEESCCTTTRITTCOOT AACOPPURRROOTT,TEECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR-2E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00221100 PPaaggee4dooff 11gs _ BM Outer Oualifier BLa_b.~ Quite Oualifier IM_MNO1S38596 3M MN01538596 agen 211212004 3M3M Project: EOLO120 cont) 3PrMojSeactm:pEle04N-0u1m2b0e(rco_nt._) Sampled Date 3EMMIS2a0m.p6l7e4N0u4mb(ecront) 2122004 Sampled Date FLAaCnE AEmPAbcaitt(wMna)hed E04-0120-67434 (cont.) 2/12/2004 LAB Aoal~'tieal Method PACE EPA 624 (cont.) Pace Eads PACE EPA 625 EEPrNNeVVliIImRRiOnOaNNrM yMUEEnNNauTTtAAhoLLriLLzAeAdBBOORReRpAAoTTrtOORRYY Preliminary/Unauthorized Report Sample Description Sample Description Effluent Carbon Effluent Carbon 4 Compracas Components "Bromaonten(sucrs) 4-Bromofluorobenzene (surr) Ditromaoronciin (ar) Dihromofluoromethane (surf) Toeaeds ur) Toluene-d8 (surf) Phel Phenol Jrcm---- bis(2-Chloroethyl)ether 2.Chlompherol 2-Chlorophenol 13 Dichltenos 1,3-Dichlorobenzen LeDichaotesre 1,4-Diehlorobenzene 12 Dichrbesseoe 1,2-Dichlorobenzene HCi horisproepteyr bis(2-Chloroisopropyl)ether ironi propylanie N-Nitrosa-di-n-propylamine Nirtenere Nitrobenzene Lobos Isophorone pre 2-Nitrophcnol 2.Dmenypenal 2,4.Dimethylphenol bola Cherocthothnanye bis(2-Chloroethoxy)methane 24Diicmpnnt 2,4-Dichlerophcnol 124TrNrtezse 1,2,4-Trichlorobenzene Nupur Naphthalene Hearbsdons Hexachlorobutadiene pr ------ 4-Chioro-3-methylphcnol 246 Thoropeon! 2,4,6-Triehlorophenol 2Chomenpbiners 2-Chloronaphthalene Dinctyphiban: Dimethylphthalate Acie Acenaphthylcne 26-Disiune 2~6-Dinitrotoluene J Aeenaphthene 2. Diasropheel 2,4-Dinitrophenol Nuepbesel 4-Nitrophenol 2.4 Dials 2,4-Dinitrotoluene Dietyiphbase Diethylphthalate Coaphns phere 4-Chlorophenyl-pheny1ther Paes Fluorene 46Di2imineon 4,6-Dinitro-2-methylphenol "romopphetn yi 4-Bromophenyl-phenylether Hoahorsbesioe Hexachlorobenzene [r-- Pentachlorophenol Phenstene Phenanthrene Antcene Anthracene Diba Di-n-butylphthalate Fisorsbene Fluoranthene Pye Pyrene Buonpane Butylbenzylphthalate 33 Dickoteidioe 3,3'-Dichlorobenzidine Beamanbncere Benzo(a)anthracene Chine Chrysene BRaessutlt `CHCEOONNNNFFEIIDPDEIENNNTTCIIAOALLUN-- STSUUYBBDJJIEESCCTTTRITTCOOT AACOPPURRROOTT,TEECNCTOT,IIVV2EE7-OOCRRV-DD1EE0RR.2E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00221111 PageSof18 Page 5 of 18 RBLL Quite Qualifier - 3M_MNO1538507 3M MN01538597 2/12/2004 SM ENVIRONMENTAL LABORATORY 3M ENVIRONMENTAL LABORATORY PrciminaryUnauthorised Report Preliminary/Unauthorized Report Projects Eako120 ont) Project: E04-0120 (cont.) IM Sumple Number Sampled Date Sample Description 3M Sample Number Sampled Date Boron0erise cont) 2122008 `Muent Carbon E04-0120-67434 (cont.) 2/12/2004 LE AMs ee Compunaan ow LAB a aes [ra PACE Analytical Method EPA 625 (cont.) ma Fue Te 96 PrDDBDBHNpT22Fe08ooieiTeetetpneisocmshoAoorapectangvecthsyshershraiepeaoieheuTlmrmrinemsdrninpe)neoiaosrrtmeu9)nr:s)reei6)h}snare) ERA x TotesCorre TotReso Cie ERA x An No resent ERA Hy wr ERA ma Contry Contr ERA ox Ditoved gen Died Oger(Fk ERA on Tempers Tengen ERA pws Essie wprrorAarreeteoeeisses 3M_ENVLAB Fish Acute Test - 96 Total Res Chlorine Ammonia Nitrogen pH Conductivity Dissolved Oxygen Temperature ETS-8-148.0 Sample Description Effluent Carbon 4 Components bis(2-Ethylhexyl)phthalate Di-n-oetylphthalate Benzo(b) fluoranthcne Benzo(k)fluoranthene Benzo(a)pyrene Indeno(l,2,3-cd)pyrene Dibenz(a,h)anthracene Benzo(g,h,i)perylene Hexachloroethane Nitrobenzene-d5 (surr) 2-Fluorobiphenyl (surr) Terphenyl-dl 4 (surr) Phenol-d6 (surr) 2-Fluorophenol (surr) 2,4,6-Tribmmophenol (sur0 Fish Acute Test - 96 hour Total Residual Chlorine Ammonia (as NH3) pH Conductivity Dissolved Oxygen (Field) Temperalure APE0 APE 1 APE2 APE3 APE4 APE5 APEI4 APEI5 Result Pages Page 6 of I 8 mo omie Oualifier Exo tows, EXYGEN LCMS Tormey TEE E04-0120-67435 2/12/2004 1Ab Asevere LAB WE fiOumccems PACE We BoDGm) PACE ce pans PACE [ovPACE Analytical Method Total Organic Carbon BOD (5-day) EPA 420.4 EPA 624 APEI6 osPFOS JiePFHS ssPFBS FronPFOA inPFHA Eee Effluent Carbon 1 Compmsens Components Hhond TomtOmiccuton Filtered Total Organic Carbon Boni Gg Domnd Biochemical Oxygen Demand mene Phenol (AAP) Thine 1,1,1 -Triehloroethane 1122 erate 1,1,2,2-Tetrachlorocthane 2 mosee 1,1,2-Triehloroethane Dirt 1,1-Dichloroethane iDebrnbon 1,1-Dichloroethane -- Bout BL Quit Result Qualifier `CHCEOONNNNFFEIIDPDEIENNNTTCIIAOALLUN-- STSUUYBBDJJIEESCCTTTRITTCOOT AACOPPURRROOTT,TEECNCTOT.IIVV2EE7-OOCRRU-DD1EE0RR.2E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00221122 u_mnotssasss 3M MN01538598 -_-- 2/12/2004 00d 3M ENVIRONMENTAL LABORATORY 3M ENVIRONMENTAL LABORATORY PreiminaryUnauthorized Report Preliminary~Unauthorized Report Project: 040120 cont) Project: E04-0120 (cont.) 3M Sample Number Sampled Date Sample Description 3M Sample Number Sampled Date EOLO1067455 (cont) 2122000 Effluent Carbon 1 E04-0120-67435 (cont.) 2/12/2004 Lan Amica Method Compencss Rest LAB ACE mene 2erBBCCCCCc11 J 1VDEMrCroh2ho3eDrooiamoDihhraDiiomamorioioebortdbnnvl2 smomtnvoiDeoooeeerccuc-- nmiotcmetoHsoetcrubrtonneosek ermeeVnrenrsnmoziiziapecnanbpeeieenenteeec. PACE Analytical Method EPA 624 (cont.) Sample Description Effluent Carbon 1 Components 1,2-Dichlorobenzene 1,2-Dichloroethane 1,2-Dichloropropanc 1,3-Dichlorobenzene 1,4-Dichlorobenzcne 2-Chloroethyl Vinyl Ether Benzene Bromodichioromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroeth~me Chloroform Chloromethane cis- 1,3-Dichloropropene Dibromoehloromethane Ethylbenzene Methylene chloride Result ace sacs PACE EPA 625 Tetrachloroethene Tole Toluene mn 2 Doreen trans- 1,2-Dichloroethene an ichorprones trans- 1,3-Diehloropropene Trehrsebene Triehloroethene Trtimaamemetine Trichlorofluoromethane Vint hrc Vinyl chloride 12 Dinroctined wm 1,2-Diehloroethane-d4 (surf) Bmor(eur) 4-Bromofluorobenzene (surr) Dionn(ear) Dibromofluoromethane (sun) Toland ar) Toluene-rig (surf) Pool Phenol HCahactyter bis(2-Chloroethyl)ether 2Chhoprndt 2-Chlorophenol 13 Dihrberene 1,3 .Dichlorobenzene VeDihcbenne 1,4-Dichlorobenzene 12Dichrtenzne 1,2-Dichlorobenzene Hoa Choppeeyr bis(2-Chloroisopropyl)ether NNieusodvpraompiyn N-Nitroso-di-n-propy lamine None Nitrobenzene gh Isophorone 2gpert 2-Nitrophenol 2.Dinconipennt 2,4-Dimethylphenol aCe coe bis(2-Chloroethoxy)methane 24Dicer 2,4-Dichlorophenol 124 Tckoteazse 1,2,4-Trichlorobenzene Nori Naphthalene `CHCEOONNNNFFEIIDPDEIENNNTTCIIAOALLUN-- STSUUYBBDJJIEESCCTTTRITTCOOT AACOPPURRROOTT,TEECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR-2E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00221133 Page7of1s Page 7 of 18 Bo Quine R._~..L Qualifier 3M_MNO1S38599 3M MN01538599 _--_-- F 2/12m/20t04 Project:E040120 (cont) Project: E04-0120 (cont.) 3M 3M EEPNrNiVVmIIiRRaOrONyNUMMnEEsuNNtTThAAoLLriLLzAAeBdBOORRRepAAoTTrtOORRYY Preliminary/Unauthorized Report 3M Sample Number Sampled Date EO4OIZ0-6438 (cnt) 2122008 E04-0120-67435 (cont.) 2/12/2004 Lan Amalie LAB AGE EPA) PACE Analytical Method EPA 625 (cont.) Sample Description Eas Carbon 1 Effluent Carbon 1 compos Components enahrsdine Hexachlorobutadiene Chor Snebens 4-Chloro-3-methylphenol 246Tiree! 2,4,6-Trichlorophenol 2 CHrmphilre 2-Chloronaphthalene Din tc Dimethylphthalate Acute Acenaphthylene 26Diners 2,6-Dinitrotoluene cmptene Acenaphthene 2Dicpel 2,4-Dinitrophenol exten! 4-Nitrophenol 24Dibens 2,4-Dinitrotoluene Die Diethylphthalate "Humpty 4-Chlorophenyl-phenylether Fiore Fluorene a2 n mega 4,6-Dinitro-2.methylphenol rompers 4-Bromophenyl-phenylether Pensa! Hexachlorobenzene Pentachlorophenol Raw Result Phenanthrene ee FebAceTx 00 ERA Fish Acute Test - 96 Es To es Cire ERA Total Res Chlorine a Anan ison ERA Ammonia Nitrogen a ERA pH Anthracene [rr Di-n-butylphthalatc Fuori: Fluoranthene rye Pyrene Buyers Bulylbenzylphthalate 33 Diensenidon 3,3'-Dichlorobenzidlne Benatar Benzo(a)anthracene Chore Chrysene No Bayes bis(2-Ethylhexyl)phthalate Dinocyphiae Di-n-octylphthalate Beebe Benzo(b) fluoranthene Baus wrnboe Benzo(k)fluoranthene Beas Benzo(a)pyrene Ind d ps Indeno(1,2,3-cd)pyrene Dictate Dibenz(~,h)anthracene eg hip: Benzo(g,h,i)perylene Henchomeare Hexachloroethane Nite5(ucr) Nitrobenzenc-d5 (surr) Lumber) 2-Fluorobiphenyl (surf) Tepe um) Terphenyl-dl4 (surr) Fred ur) Phenol-d6 (surr) 2por) 2-Fluorophenol (surr) 2.46 Tree(n0) 2,4,6-Tribromophenol (surr) in Aect 5ebot Fish Acute lest - 96 hour Toul Resid Chri Total Residual Chlorine pre") Ammonia (as NH3) pn `CHEOGNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTYUBBIJDJIEAESCCTLTTRTITCOOT AACPOPURRROOTT.TEECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR.2E6E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00221144 PPaagge e8 8ofo11f88 Bo oui R._~.L Qualifier SW_MNO1838600 3M MN01538600 nos 2/12/2004 3M ENVIRONMENTAL LABORATORY. 3M ENVIRONMENTAL LABORATORY PreliminaryUnsuthorzed Report Preliminary/Unauthorized Report Project:E040120 cont) Project: E04-0120 (cont.) 3MSampleNumber __ Sampled Date __ Sample Description 3M Sample Number Sampled Date Sample Description EDO067ES (cont) 2122008 Effluent Carbon 1 E04-0120-67435 (cont.) 2/12/2004 Effluent Carbon 1 Lan AmtuialMate Comprncas: Bast BL LAB Era Contry Conttivy ERA a DiscivedOnygen DisoiedOxygen (Fld) ERA Ea Tempenase Tenpenaee ERA SMEWLAR ETSE160 ArawrappApererreeEeeteeesnssss 3M_ENVLAB Analytical Method Conductivity Dissolved Oxygen Temperature ETS-8-148.0 Components Conductivity Dissolved Oxygen (Field) Temperature APE0 APEI APE2 APE3 APE4 APE5 APEI4 APEI5 APEI6 Result RL Eovoi0-e7i% Te Efent Carbon 11 E04-0120-67436 2/12/2004 Effluent Carbon 11 Lan Asaitical Method Companeat: Ret BL LAB PACE TolOrgsCarbon FiredTt Ori Cason PACE Ns Nery (BPA 1631) Merry NSA ERA Fh Acs Tet 96 Fh Ac Tet 96 ose ERA ERA Toul ResChore Tot Residual Choi ERA EN Amoi Nig Armonia Ni3) ERA era " wo ERA EN Conti Consocivny ERA EN Disolved Oxygen DisoleedOuygen Fed) ERA Era Temperature Temperanre ERA EXYGRN Lows pros EXYGEN Analytical Method Total Organic Carbon Mercury (EPA 1631) Fish Acute Test - 96 Total Res Chlorine Ammonia Nitrogen pH Conductivity Dissolved Oxygen Temperature LCMS Beemer Zen eePprrrroioss.nxEfuent Carbon 13 E04-0120-67437 2/12/2004 Components Filtered Total Organic Carbon Mercury Fish Acute Test - 96 hour Total Residual Chlorine Ammonia (as NH3) pH Conductivity Dissolved Oxygen (Field) Temperature PFOS PFHS PFBS PFOA PFHA Effluent Ca rbon 13 Result an Anat Methad Componeans Baa BL LAB PAGE Tol Orne Gabon Fired TaalOrga Carbon PACE Ns Nery (EBA 1631) Merry NSA ERA FishAce Tet 96 Fh Ace Test 9hos. ERA ERA Tol Res Chorio TotResidualChie ERA Ba Armonia Nivogen Armonia (NH) ERA EN wi m ERA J Contutivy Conscity ERA EN DiscivedOsten Disoleed Oxygen (Fick) ERA EN Tompemuse [-- ERA EXYGRN LOMS pros EXYGEN Analytical Method Total Organic Carbon Mercury (EPA 1631 ) Fish Acute Test - 96 Total Res Chlorine Ammonia Nitrogen pH Conductivity Dissolved Oxygen Temperature LCMS Boomers 20sppFprrroonssnCamenbPeriA --- E04-0120-67438 2/12/2004 Components Filtered Total Organic Carbon Mercury Fish Acute Test - 96 hoar Total Residual Chlorine Ammonia (as NH3) pH Conductivity Dissolved Oxygen (Field) Temperature PFOS PFHS PFBS PFOA PFHA Carbon 4, Port A Result PPaaggee 990of1188 Quite Qualifier Oui Qualifier Oui Oualifier `CHCEOONNNNFFEIIDPDEIENNNTTCIIAOALLUN-- STSUUYBBDJJIEESCCTTTRITTCOOT AACOPPURRROOTT,TEECNCTOT,IIVV2EE7-OOCRRV-DD1EE0RR.2E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00221155 3M_MNO1538601 3M MN01538601 e-- e ---------------------------------- 2/12/2004 aes SM ENVIRONMENTAL LABORATORY 3M ENVIRONMENTAL LABORATORY PrelimiaaryUnsoborsed Report Preliminary/Unauthorized Report Prot: 040120 ont) Project: E04-0120 (cont.) 3M Sample Number Sampled Date __ Sample Description 3M Sample Number Sampled Date Borers (cnr 212200 Carbon Port A E04-0120-67438 (cont.) 2/12/2004 Lp wavs cone Bo LAB BE aomccaws hho oa onmecan PACE es Boban BiGDemand PACE mc ead Pol AAD) PACE ne Ear [pein PACE Analytical Method Total Organic Carbon BOD (5-day) EPA 420.4 EPA 624 me mes NLfDBoCe CoCt bbJ\1frDBTTapfTViT11221DNSf[ NeDV1rore2DDo2ourEe2r2lrkD itealrroim3tnoioeremorrroivaiiTohaetnrloexgyemeteee1oledmmnhaesDtsyo bo avrrc ctnocreicotbtootrmsorroomtnkmbonnsicdeeesob trrueaemoaeeebnbdtemiseVreormmseor nreterea)aeatp nnmtsaretesastttmdineenuebnnia oiErs reeebsyree(lrrroe)r)e) PACE EPA 625 Sample Description Carbon 4, Port A Components Filtered Total Organic Carbon Biochemical Oxygen Demand Phenol (AAP) 1,1,1 -Trichloroethane 1,1,2,2-Tetrachloroethane 1,1,2.Trichloroethane 1,1-Dichloroethane 1, l-Diehloroethene 1,2-Dichlorobenzene 1,2-Dichloroethane 1,2-Diehloropropane 1,3-Dichlorobe~zene 1,4-Diehlorobenzene 2-Chloroethyl Vinyl Ether Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlornbenzene Chloroethane Chloroform Chloromethane cis- 1,3-Dichloropropene Dibromochloromethane Ethylbenzcne Methylene chloride Tetrachloroethene Toluene trans- 1,2-Dichloroethene trans- 1,3-Dichloropropcne Trichloreethene Trichlorofluoromethan Vinyl chloride 1,2-Dichloroethane-d4 (surr) 4-Bromofluorobenzene (star) Dibromoflaoromethane (surr) Toluene-d8 (surr) Phenol bis(2-Chloroethyl)ether 2-Chlorophenol 1,3-Dichlorobenzen 1,4-Dichlorobenzene 1,2-Dichloroben2ene bis(2-Chloroisopropyl)ether N-Nitroso-di-n-propylamine Result `CHCEOONNNNFFEIIDPDEIENNNTTCIIAOALLUN-- STSUUYBBDJJIEESCCTTTRITTCOOT AACOPPURRROOTT,TEECNCTOT.IIVV2EE7-OOCRRU-DD1EE0RR.2E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00221166 Fie l0r1s Page 10 of 18 Bo Quite RL Qualifier u_mnotssssoz 3M MN01538602 --_--_-- 2/12/2004 ha 3M ENVIRONMENTAL LABORATORY. 3M ENVIRONMENTAL LABORATORY Preliminary Unauthorized Report Preliminary/Unauthorized Report Project: 040120 (cont) Project: E04-0120 (cont.) SMSimple Number SumpledDate SampleDevripion 3M Sample Number EOO1Z067458 (com) 2122008 Carbon 4, Part A E04-0120-67438 (cont.) Sampled Date 2/12/2004 Las Anil Mitkod Componcts Rast LAB Face EPA an) H2"2N.CHN22LC"2A2ADC212D2o44oi4eDhcoTa46p.iDrph6ouDCNcaTrbihiihepaDmcorroclhb-nuhhperiinkcbtostiosbipooerptbnu:eibeemopateencesnrphreiensspntdpysi:eshieoitpbeereleerosneonoeslenrteynre PACE Analytical Method EPA 625 (~om.) Sample Description Carbon 4, Port A Components Nitrobenzcne Isophoronc 2-Nitropheaol 2,4-Dimethylphenol bis(2-Chloroethoxy)melhane 2,4-Dichlorophenol 1,2,4-Trichlorobenzene Naphthalene Hcxachlorobutadiene 4-Chloro-3-methylphenol 2,4,6-Trichlorophenol 2-Chloronaphtlmlene Dimelhylphthalate Acenaphthylene 2,6-Dinitrotoluene Aeenaphthene 2,4-Dinitrophenol 4-Nitrophenol 2,4-Dinitrotoluene Diethylphthalate 4-Chlorophcnyl-phenylether Result Fluorene Dino2 metyptel 4,6-Dinitro-2-methylphenol Bmpr pheayebes 4-Bromophenyl-phenylether Hobobensioe Hexachlorobenzene ---- Pentachlorophenol enn Phenanthrene Aces Anthracene Dinbuphatse Di-n-butylphthalate [i Fluoranthene Fe Pyrene Buyer Butylbenzylphthalate 3 5 Diclobensidos 3,Y-Dichiorobenzidine Benzoiaiacee Benzo(u)anthracene Choe Chrysene ve Ebise bis(2-Eth~lhexyl)phthalate Dioctyphialse Di-n-oetylphthalate Bersoorniz Benzo(b) fluoranthene Benanortene Benzo(k) fluoranthene Benton Benzo(a)pyrene Iadeot123 pyrene Indeno(1,2,3-cd)pyrene Disaaspmdcene Dibenz(a,h) anthracene Henn peyns Benzo(g,h,i)~rylene Horslredune I-Iexaehloroethane Niobe oer) Nitrobenzene-d5 (surf) 2Fucrtiben] (a) 2-Fluorobiphenyl (sun) `CHGEOONNNNFFEIIDPDEIENNNTTCIIAOALLUN-- TSSUYUBBDJJIEESCCTTTRITTCOOT AACOPPURRROOTT,TEECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR.2E6E8NN6TT2EERREEDD IINN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00221177 PPaaggee 1111 oorf 1188 BRLo oui Qualifier 3M_MNO1538603 3M MN01538603 2/12/2004 n 3M ENVIRONMENTAL LABORATORY 3M ENVIRONMENTAL LABORATORY FrelmiryUnsuthorized Report Preliminary/Unauthorized Report Projcs E0120 cont) Project: E04-0120 (cont.) SM Semple Number SampledDate __ Sample Dscripion 3M Sample Number Sampled Date EDO (ont) 2122000 Carbon Port A. E04-0120-67438 (cont.) 2/12/2004 AL Aubevos Comms Bow LAB ne me Semmmbit a) PACE Analytical Method EPA 625 (cont.) ex Fi A Test 56 F 22P4o4rmTprei eeTrdelmoac 9)r0h(ar) ERA Ex Tot esCie Toul Rs Colors ERA Ea Ami igen Ammon NH) ERA ex w ERA x Contin Contin ERA i Died Oyen Disohes Oot ERA I ome Tempe ERA ewan Essien 3M_ENVLAB ion Low ros EXYGEN Fish Acute Test - 96 Total Res Chlorine Ammonia Nitrogen pH Conductivity Dissolved Oxygen Temperature ETS-8-148.0 LCMS rT rFrirvsnosn IN TY - E04-0120-67439 2!12/2004 LL AubeMo Compaen Bot LAB BG Telommscesn Phe tonlOgaicCuton PACE hE ob Biba Ove Oem PACE ee en Presa OAD PACE a ae eCCCoCoBea eiT1T MFDj1121221eoDiehihDi2tlrnrbmDnat2eorriotomroioloiTnb eaDrcenerboymeeeesnlhaoearohntbrarnneeraoihoh VndosonepnptitieeoeeoeiennBeeb:c PACE Analytical Method Total Organic Carbon BOD (5-day) EPA 420.4 EPA 624 Sample Description Carbon 4, Port A Components Terphenyl-dl 4 (sun) Phenol-d6 (surf) 2-Fluorophenol (surf) 2,4,6-Tribtomophenol (surf) Fish Acute Test - 96 hour Total Residual Chlorine Ammonia (as NH3) pH Conductivity Dissolved Oxygen (Field) Temperature PFOS PFHS PFBS PFOA PFHA Carbon I, Port A Components Filtered Total Organic Carbon Biochemical Oxygen Demand Phenol (AAP) 1,1,1 -Trichloroethane i, 1,2,2-Tetrachloroethane 1,1,2-Trichloroethane 1,1-Dichleroethane I, 1-Dichloroethene 1,2-Dichlorobenzene 1,2-Dichloroethane 1,2-Dichloropropane 1,3-Dichlorobonzene 1,4-Dichlcrobenzene 2-Chloroethyl Vinyl Ether Benzene Bromodiehloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroelhane Chloroform Chloromethane is-l,3-Diehloropropene Dibromochloromethane Ethylbenzene Methylene chloride Result Result `CHCEOONNNNFFEIIDPDIEENNNTTCIIAOALLU N-- TSSUYUBBDJJIEESCCTTTRITTCOOT AACOPPURRROOTT,TEECNCTOT.IIVV2EE7-OOCRUR-DD1EE0RR.2E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00221188 Page 20018 Page 12 of lg Bowie a...b.L Qualifier Bowie R._L_L Qualifier u_mnotssssos 3M MN01538604 -------------------------------------------------------------- 2s/1i2m/20o0n4 Project: E0410 cont) Project: E04-0120 (cont.) SM PErNiVmIiRONMUEnNsTthAoLriLnAedBORRepAoTrtORY 3M ENVIRONMENTAL LABORATORY Preliminary/Unauthorized Report 3M Sample Number BOOTH (nt) 222008 Coron, PortA E04-0120-67439 (cont.) Sampled Date 2/12/2004 IAL owls Comms LAB he ae = PACE Analytical Method EPA 624 (cont.) ner mas jSiCTa eTTpVVTfNNpIfj 3NSoo2p DppApSjDiTppCfD poPP2soo-- iromtoeooiaDraorisohoririeoDn6emerdCeriaokitmomseebrinnrrasvntbiso c bodineatimDwoomiuDieetaodneeinmsemheatanaoaognmnmooisnmiohasieenbaynmoe ev e itnmlysercendleeoetnalicnseesasenerttmsitseenonnsrri)) PACE EPA 625 Sample Description Carbon 1, Port A Componeats Tetrachloroethene Toluene trans- 1,2-Dichloroethene trans- 1,3-Dichloropropene Trichloroethen Trichiorofluoromethane Vinyl chloride 1,2-Diehloroethane-d4 (surf) 4-Bromoflaorobenzen (~urr) Dibromofl~oromethane (surf) Toluene-rig (surf) Phenol bis(2-Chloroethyl)ether 2-Chlorophenol 1,3-Diehlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene bis(2-Chloroisopropyl)gther N-Nitroso-di-n-propylamin Nitrobenzene Isophoron 2-Nitrophenol 2,4-Dimethylphenol bis(2-Chloroethoxy)methane 2,4-Dichlorophenol 1,2,4-Yriehlorobenzene Naphthalene Hexachlorobutadien 4-Chloro-3-methylphenol 2,4,6-Trichloroph~nol 2.Chloronaphthalene Dimethylphthalate Accnaphthyl~n 2,6-Dinilrotoluene Acenaphthene 2,4-Dinitrophenol 4-Nitrophcnol 2,4-Dinitrotolucn Diethylphthalate 4-Chlorephenyl-phenylether Fluorcne 4,6-Dinitro-2-methylphenol 4.Bromophenyl-phenylether Hcxachlorobcnzene Pentachlorophenol Phenanthrene Bast Result `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACOPPURRROOTT.TEECNCTOT.IIVV2EE7-OOCRR\-DD1EE0RR-2E6E3NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00221199 PPaaggee 1133ooff1138, Bowe RL Qualifier am_Morsassos 3M MN01538605 -- 2/12/2004 Fanos IM ENVIRONMENTAL LABORATORY 3M ENVIRONMENTAL LABORATORY Prelminary/Unautborized Report Preliminary/Unauthorized Report Project: 040120 (cont) Project: E04-0120 (cont.) 3MSample Number Sampled Date __ Sample Description 3M Sample Number Sampled Date 00120709 (cont) 2122008 Carbon 1, Port A E04-0120-67439 (cont.) 2/12/2004 Lan Assi Method Compeners Rest LAB Face EP 62s ont) ice PACE Analytical Method EPA 625 (cont.) Ba FhAc Tes 96 FBBPiDFFB3BCND[DBHN2T22eedhee34osiouFesosnanDehreTaeuaeEiooiaoeeiArmrciitgioteasuobcloondcgaelyrlmmeheshinsmtaboaeniaiGpsemttdTnmpeaamitnetosroenenyanterm)rpeythacirerp-eetnouteiun)6beerercl)srnnisb))s(rser) ERA Ea Totes Coie ToolRoda Corio ERA Ba Armonia Nitogen Amora NS) ERA EA wi ot ERA EN Cnttivty Contucviy ERA Era DivoledOven DisOoryhFekd) ERA Ea Tampere Tempera ERA MEWLAB ETSS1450 avn 3M_ENVLAB Fish Acute Test - 96 Total Res Chlorine Ammonia Nitrogen pH Conductivity Dissolved Oxygen Temperature ETS-g-14g.0 omeea mmmeweoveeAreniGresssrteseenre E04-0120-67440 2/12/2004 a AnshtilMthad Componcats Rest LAB FACE Tout Orga Caon Fie Tol Ore Caron PACE Nsw Mery (GPA 163) Merry NSA Ea FhAceTex 96 FhAce Te96 t ERA Ea Tol Res Cie Tol Resi Cone ERA Ea Amos Nirogen Ammon NI) ERA Analytical Method Total Organic Carbon Mercury (EPA 1631) Fish Acute Test - 96 Total Res Chlorine Ammonia Nitrogen Sample Description Carbon 1, Port A Components Anthracene Di-n-butylphthalate Fluoranthenc Pyrene Bntylbenzylphthalate 3,3'-Dichlorobcnzidine Benzo(a)anthracene Chrysene bis(2-Ethylhexyl)phthalate Di-n-octylphthalate Benzo(b)fluoranthene Benzo(k)fluoranthene Benzo(a)pyrene Indeno( 1,2,3-cd)pyrene Dibenz(a,h)anthracene Benzo(g,h,i)perylene Hexachloroethane Nitrobenzene-d5 (surr) 2-Fluorobiphenyl (surr) Terphenyl-d 14 (surr) Phenol-d6 (surr) 2-Fluorophenol (surr) 2,4,6.Tribromophenot (surr) Fish Acute Test - 96 hour Total Residual Chlorine Ammonia (as NH3) pH Conductivity Dissolved Oxygen (Field) Temperature APE0 APEI APE2 APE3 APE4 APE5 APE14 APE15 APEI6 Carbon 11, Port D Components Filtered Total Organic Carbon Mercury Fish Acute Test - 96 hour Total Residual Chlorine Ammonia (as NH3) Result Result `CHCEOONNNNFFEIIDPDEIENNNTTCIIAOALLUN-- STSUUYBBDJJIEESCCTTTRITTCOOT AACOPPURRROOTT,TEECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR-2E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00222200 Page 40018 Page 14 of18 Bo ou R.~_L Qualifier BoR_b_L Oui Oualifier IM_MNO1S38606 3M MN01538606 2008 2/12/2004 33MMEPErNNeVlViIImRRiOnOaNNrMM y EUEnNNaTuTtAAhLLoLrLiAzABeBdOORRReApAoTTrtOORRYY Preliminary/Unauthorized Report PP3rrMoojjeSecacttm::pEEle004N1-0u21m20b0ec(rcoo_nnt_t).)_ Sampled Date __ Sample Description 3EMDSS0a1m20p6le7N64u0mb(ecront) 2122008 Sampled Date "SCaamrbpalen 1, Port D Description E04-0120-67440 (cont.) 2/12/2004 LERBA AmwiviclMethod LAB Analytical Method Carbon CoFmE]ponents Components 11, Port D Beat Result ERA EJRAERA DCipCosHoonnldvuctetidviitnyye CCDioosnodnluvtcetidivOintxyygen (Frid) EBRoAA EERAGY Dissolved Oxygen TLeonMpSenie Temperature Dissolvod Oxygen TPermopsernize Temperature (Field) EXYGEN LCMS PPrpiFFenHOssSS. PFFrBoSn PFOA Ere Timor E04-0120-67441 2/12/2004 Lan AmbialMabel LAB PACE Toul OrganicCarbon PACE sa Merry (EPA 1631) NSA EA Fh Ace Tet 96 ERA EA ott KeCoe ERA Ba Ameria Niven ERA Boa m ERA ERA Contstivy ERA Bra DisolvedOxysen ERA EN Tempura ERA EXYGRN Lows EXYGEN Analytical Method Total Organic Carbon Mercury (EPA 163 I) Fish Acute Test - 96 lotal Res Chlorine Ammonia Nitrogen pH Conductivity Dissolved Oxygen Temperature LCMS Booogie Zar E04-0120-67442 2/12/2004 LAB AmalMahe LAB Pack "ott Organ Canon PACE Pace BOD (ste) PACE PACE Pass PACE race EA PACE Analytical Method Total Organic Carbon BOD (5-day) EPA 420.4 EPA 624 PFHA Carbon 13, Por > Carbon 13, Port D Compenens Components FiTrot eOgdi Cabo Filtered Total Organic Carbon Merry Mercury Fil Ace Test 95 bur Fish Acute Test - 96 hour ToulRese Corio Total Residual Chlorine Aria (NH) Ammonia (as NH3) mnpH Conductivity Conductivity DisonetOxygen Fd) Dissolved Oxygen (Field) Tempers Temperature vros PFOS prs PFHS Pens. PFBS Pron PFOA Prin PFI-LA Combined Bffuent Combined Effluent Componcai: Components FiTrea Oergad Cubon Filtered Total Organic Carbon Biochemical Onygen Demand Biochemical Oxygen Demand Fret (AAD) Phenol (AAP) LL Tibetans I, 1,1-Triehloroethane L122 Teneiowctane 1,1,2,2-Tetrachloroethane 112 THMoctne 1,1,2-Triehloroethane 1 Dikimeebae 1,l-Dichloroethane Li Dickienhene 1, l-Dichloroethene 12 Didimchenene 1,2-Dichlorobenzen 12 Dine 1,2-Dichloroethane JE -- 1,2-Dichloropropane 13 Dihoobeaene 1,3-Dichlorobenzene Li Diderobeaene 1,4-Dichlorobenzene 2H Voy Er 2-Chloroelhyl Vinyl Ether Basso Benzene Bromodicioomciunc Bromodichloromethane Bromo Bromoform Bromomete Bromomethane Ret Result eats Result `CHCEOONNNNFFEIIDPDEIENNNTTCIIAOALLUN-- TSSUUYBBDJJIEESCCTTTRITTCOOT AACOPPURRROOTT,TEECNCTOT,IIVV2EE7-OOCRRV-DD1EE0RR.2E8E8NN6TT2EERREEDD IINN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00222211 PPaaggee 11550o0f1818. Bo Oui Qualifier BL Quik Qualifier BL Qui Qualifier 3M_MNO1538607 3M MN01538607 2004 2/12/2004 3MENVIRONMENTALLABORATORY 3M ENVIRONMENTAL LABORATORY Preliminary Unauthorized Report Preliminary/Unauthorized Report Project: EO40120 cont) Project: E04-0120 (cont.) 3M Sample Number __ Sampled Date Sample Description 3M Sample Number Sampled Date EOO120.67442 (cont) 2122008 `Combined Effluent E04-0120-67442 (cont.) 2/12/2004 Lap AmboMabel Components Rea LAB FACE EPA 24 (on) Cabo tachi PACE Analytical Method EPA 624 (cont.) Pace Eras DVb2r22CCiiTr TTMFDi CCi2PTN2pTNN 111T"2A2ADC4H1.Bhho4iii.aeea.62e4a2rrhoeiCcbe43i2hlDl4CrDlabchcyrt2egDuaDhcpeoa)ihwDDs4ortiD6raaohitcyehDbeiomltC1sitoeCimiimnosmomCeinhklooDomTopra T3Denahhnopireaktcce2srrhrrocsao euorhtirieocloseeetsmenwzuernltreDDotololrchcompodrcrittneeeiprreh-ypeirseomkceiwsdoauobrsehuocnaeehb3didonerppcoeerrleroihusreiems eeerle-reeiabetpooeonenoapeu !remeeinbdknhmerrpo)mndoesacnmetoseeceaoecnslicepeobrrptndneeritptneepeee4hsepat eossoeneenrslencps elnnseeteoedeeaeiisnrtsserrn)saeye)r) PACE EPA 625 Sample Description Combined Effluent Componeats Carbon tetrachloride Chlorobenzene Chlorocthane Chloroform Chloromethane cis. 1,3-Dichloropropene Dibromochloromethane Ethylbenzene Methylene chloride Tetrachloroethene Toluene trans-l,2-Dichloroethene trans-l,3-Dichloropropene Trichlorocthcnc Trichlorofluoromethane Vinyl chloride 1,2-Dichlorocthane-d4 (sun) 4-Bromofluorobenzene (surf) Dibromofluoromethane (surr) Toluenc-d8 (surf) Phenol bis(2-Chloroethyl)ether 2-Chlorophenol 1,3-Dichlorobenzene 1,4-Dichlorobcnzeno 1,2.Dichlorobenzene bis(2-Chloroisopropyl)ether N-Nitroso-di-n-propylamine Nitrobenzene Isophorone 2-Nitrophenol 2,4-Dirnlhylphenol bis(2-Chloroethoxy)methan 2,4-Dichlorophenol 1,2,4-Trichlorobenzene Naphthalene Hexachlorobutadien 4-Chloro-3-methylphenol 2,4,6-Trichlorophenol 2-Chloronaphthalene Dimcthylphthalat Aeenaphthylene 2,6-Dinit~otoluene Acenaphthene 2,4-Dinitrophenol 4-Nitrophenol Result `CHCEOONNNNFFEIIDPDIEENNNTTCIIAOALLUN-- TSSUYUBBDJJIEESCCTTTRITTCOOT AACOPPURRROOTT,TEECNCTOT,IIVV2EE7-OOCRVR-DD1EE0RR.2E8E8NN6TT2EERREEDD IINN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00222222 Page 160718 Page 16 of18 BRLo oui Qualifier 3M_MNO1538608 3M MN01538608 2/12(2004 pe 3M ENVIRONMENTAL LABORATORY 3M ENVIRONMENTAL LABORATORY PreiminaryUnsuthoried Report Preliminary/Unauthorized Report Project EO40120 cont) Project: E04-0120 (cont.) 3M Sample Number Sampled Dae __ Sample Description 3M Sample Number Sampled Date E0006 (cont) 2122004 Combined Efucnt E04-0120-67442 (cont.) 2/12/2004 IAB AubiclVee r-- Ret LAB FACE ERAGE (om) ZD"iCDhiiraensreyemsnbsenete PACE Analytical Method EPA 625 (cont.) Sample Description Combined Effluent Comlmnents 2,4-Dinitrotoluene Diethylphthalat 4-Chlorophenyl-phenylether Result Fluorene Date ype 4,6-Dinitro-2-methylphenol Chromeo 4-Bromophenyl-phenylether Homann Hexachlorobcnzene Peoachorerst Pentachlorophenol Pentre Phenanthrcn Antrcenn Anthracene Detain Di-n-butylphthalate Fuerst Fluoranthene [oe Pyrene Bonetti Butylbenzylphthalate SD ermerrdee 3,3'-Dichlorobenzidine Berstmabrcers Benzo(a)anthracene Conese Chtysene so Bybee bis(2-Ethylhexyl)phthalate Dincic Di-n-octylphthalate Benson Benzo(b)fluoranthene Ben harmon Benzo(k)fluoranthene Besar Benzo(a)pyrene Inde 23g Indeno(1,2,3-cd)pyrene Detar Dibenz(a,h)anthracene Beasghperin Benzo(g,h,i)perylene a Fi Ae Tes56 ERA ia Tes imine ERA In Amaia Niegea ERA ea we ERA i Cantu ERA a Dishes Ouren ERA a fo ERA MENVLAD TSAO 3M_ENVLAB Fish Acute Test - 96 Total Res Chlorine Ammonia Nitrogen pH Cenduetivity Dissolved Oxygen Temperature ETS-8-148.0 Hexachloroethane Nbc ur) Nitrobenzene-d5 (surr) Lira ou) 2-Fluorobiphenyl (surf) Tepes ne) Terphenyl-dl4 (surf) Peds ur) Phenol-dr (surf) Farol se) 2-Fluorophenol (surr) 246 Tivemesbeorurs) 2,4,6-Tribromophcnol (sun) Fi Ac Tsou Fish Acute Test - 96 hour Tol Resiane Total Residual Chlorine jusnpmtey Ammonia (as NH3) apH Contry Conductivity Dinahed Oogen (Fi) Dissolved Oxygen (Field) Teapots Temperature areAPE0 otAPEI reAPE2 reAPE3 reaAPE4 rsAPE5 ne APEI4 `CHCEOONNNNFFEIIDPDEIENNNTTCIIAOALLUN-- STSUUYBBDJJIEESCCTTTRITTCOOT AACOPPURRROOTT,TEECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR.2E6E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00222233 PPaaggee 11770o1f118g Bo oui R._~_L Qualifier 3W_MNO1838509 3M MN01538609 aos 2/12/2004 3M 3M EEPrNNeVVliIImRRiOnOaNNryMMUEEnNNtTaTtAAhLLorLLzAAeBBdOOReRRpAAorTTtOORRYY Preliminary/Unauthorized Report 3PPrrMoojjSeecacttm::pEEl0Oe44N-00u11m22b00e(orcno_ntt)._) Sampled Date __ Sample Description E3MOLSOamIp0le6N7u2mb(ecront) 2122008 Sampled Date S`CaommpblieneDdeEscfrfiupetniotn aSHnENVAD AETsS-s4-i1a05M0stonhto)d E04-0120-67442 (cont.) 2/12/2004 LAB Analytical Method Copmeprasncass Combined Components Effluent Baw Result 3M_ENVLAB Exon ETS-8-148.0 (cont.) tos AAaPrPrPoEEssIIe56 EXYGEN LCMS PFOS PPPPFFroBHoasSS PPFrOiAn PFHA Page 180f18 Page 18 of 18 BL Quite Qualifier `CHCEOONNNNFFEIIDPDEIENNNTTCIIAOALLUN-- STSUUYBBDJJIEESCCTTTRITTCOOT AACOPPURRROOTT,TEECNCTOT,IIVV2EE7-OOCRRV-DD1EE0RR.2E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00222244 3M_MNO1538610 3M MN01538610 E ,gen Xysen.. . RESEARCH ror Rigch Precise Research. Et Proven Results SSaammppllee ""CCoonnddiittiioonn UUppoonn RReecceeiipptt"" FFoorrmm PrPortootoccooll #. Vz ------------------ EExxyegeennSSutuddyys _ * to 1874 DDatae &&tTTiiemmee RReecceeiivveedd _3f/alyms ger CCoonnddiititoinoofnf SSaammpplleess wif Teo Hei ~ - TeTmepmoproararryy SSttoorraaggee LLooccaattiioonn ___ 1, [ lo_neecaf2 tenhbd IInniittiiaallss && DDaattee sean ffoslors Wasbill# Waybill # 7930 9a gui) Fed KX Comments: Swit fo Ad And gra20s ee mma .,'vla>' 24, 2002'3 WORD prosesvlugi SanpleCondiononRecipi ox Q: \VI)RD proccss-login,SamplcConditiononReceipt.doc `CHEOGNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIJDJIEAESCCTLTTRTITCOOT AACPOPURRROOTT.TEECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR.2E6E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00222255 ()58 Rcseamh Drive CR! Pann, ate College, PA 164()1, ~lrTI :800.281.3219 USA SU_MNo183E611 3M MN01538611 FedEx I Ship Manager I l.abel 7925 7072 8697 Page 1 of 1 REVENUE BARE;ODE | SEEnEnEoEor MVRs=g To: John Flaherty [800)281-3219 Exygen Research SHIP D~TE: 12FEB04 WEIGHT: 55 LB3 3058 Research Drive State College, PA, 16801 DiwmnsaN.U .SC.EA Fi Ref: (CONFIDENTIAL SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 aw morsassrz 3M_MN01538612 11993377..00222266 SECTION D `CHCEOONNNNFFEIIDPDEIENNNTTCIIAOALUL-N- STSUUYBBDJJIEESCCTTTRITTCOOT AACOPPURRROOTT,TEECNCTOT,IIVV2EE7-OOCRRV-DD1EE0RR.2E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00222277 3M_MNO1538613 3M MN01538613 TR ser ozo D SETTER REJECTED RLrN Tr REASON [] Poor Chromatography Sree [] Drifting Baseline 5Doing ResonTio [S~~U.DnUrnssittf~tab~blgleeRRReesetespnpotoninosnseeT'mae [] Power Interruption a. ~ Unacceptable RecoSvveernies Scie [] Apparent Colltamjnation [] Other:. or goa " o te:Bumsfiges | THEBe INTEETEDSST (EHEeaheit u SSEX TOR e-INfECTON See Det SET 02(804AR | CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00222288 3M MN01538614 es rere F2anta ee mn - : fecompoeatn----t----a-- foane 1s fr --permsmtrem-- mee omnes marr rn ER irene msor ror (ioc 4 ctfmore| a a Ti a ER E E S S e e emma rn a havipea] eos eee cmoro g s faves fission [ouones ost eo ED EES a re r me n er Boyy i:ywar f Jr 7 [DLSOL N rrer Exygen Research Page i of 2 SETEA RARTSY CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 snot 3M_MN01538615 11993377..00222299 m EEA. wl5leg [-- Project; D:~Analyst Data\Projects\Ruoroche~\~903_04_29 Batch:0~ Tab:Sam - T AcqMethod:NPDES dam re -- ~[~'~ 021904444 161 - _ 02~9~4-~45 v ~ 021~04D\L1874 021~04D%L1874 ~'~ L1874-19 DF = 100 ~ ErioerorecE S(iEy ES ~-6 .......................................................................~2"~'~Z~" '~--~ ~..... ror ..................... ~ '~ .......... ~0219~DkL1874 0219~D~L1874 Methanol Wash L187~Z1 InstrLtlnenZ NO.: LC/MS/MS # 8 CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 ~age 2 of 2 3M_MN01538616 11993377..00223300 i Pita: Na Protocol:No.: None NetoaNe: 8 Method No.: .~ Cn AL RESEARCH 30S88cReseiarch eDiven 3058 Research Drive State College, PA 16801 Fo 14311580 Prone: 514272.109 Phone: 814-272-1039 Fax: 814-231-1580 PREPARATIONOF EXTRACTED CALIBRSATTANIDAORDNS PREPARATION OF EXTRACTED CALIBRATION STANDARDS [-- sie Tete Exygea Stud)' No.: N~A es CACC Sema iat Ana!ytes: C4.C5.C6.C7 and Cg Acids: Matrix: Type I Water~ Sample Vol: 40mL C4 C6 & C8 Sulfonate~ Sponsor Exygen Fort. Fort. Fort. Micropipet Fort. Final Sample Sample Sample Solution Soln. Conc. Volume used Level Solution Reagents/ Lot # [oaID omeIDmo opeDerscwripatioene| ID # ** '. i Materials 1.TT.T-Troonomn| wena [f5sesus} [oaNA ]ores0 0106020 |mews Type I Water^ [ronoeso] 0 | w10o0o| am200 | os [vXoCm0i21o00w4-s0 |cise Methanol fessioq)| NA 0106020 Type I Water^ t:012004-10 10 25 XC021004-1 C18 SPE a oro | mete[eomoness[10[ow| 0| 30 tconows[ptm| wa | NA 0106020 T)q~ I Watera F012004-10 10 200 200 50 XC021004-2 Type I Water NA [a]oncom rewae |ronan] to | 00Taw 1 wooTxemioossI 1 1 NA 0106020 Type I Water" F012004-10 ! 10 400 200 100 XC021004-3 {va ones |mp | moines[iw | woo|a0 | asoIvemioows I] NA 0106020 Type I Water~ F012004-9 100 100 200 250 XC021004-4 [a ouoson0[wipe wae | voszoot | aon | 00| a0| soo[vommoous [1 NA 0106020 Type I Water~ F012004-9 100 200 200 500 XC0210IM-5- [oa 1 oromo | roperwuee | roizones | ve eo | we w| a0e | iooo Ixcwmicors| E 1 L NA 0106020 Type I Water^ F012004-9 100 400 200 1000 XC021004-6 Co TT TTT me Dole Initials/Date: Versa sem den meer Vertical arrows in aif.olumn indicate identical values. Te ee a Bed dtno D KCUNDDIT 4133 - **This must be a unique number. Use this system: Extracted Calibration Soln 1D #: XCMMDDI~Y-O,1,2,3. etc. Somme vrs 35 Toe 1655 isu EHH ass ANEXAGTCOPY! Samples removed fro~/freezer # ~ ~ Time: i65"0 Initials/Date: eS, mgr qe 40 mL of each sample~measureudsing a ~.~ 0 mL graduated cylinder. temem ain re Tires 32 Tos 10 wie BT2lsl gy. After measuring, samples returned to~ / freezer # S~- Time; Samir ed iso glo Samples fortified: mon a GCllot SPEclean=up (omitting 40% Wash): . Initials/Date: Initials/Date:t~ta , ,, ~ hc spt Si fenton" ar Final voltm,e adjusted t0 5 mL: Initials/Date: Eurotot3e5s ue RE STANDARDEXPTRATION DATE: 3205 L) -- -- STANDARD EXP]2~ATION DATE: commas Tt e ee he r dv pea Comments: ^This type I water has been filtered through a hypercarb filter etalni reemi PecmeFOS, ro ose ROSA P53 POA Wo $$ Method of Analysis for the Determination of Perfluorooctane sulfoaate (PFOS), Perflaorooctane sulfonylamide (PFOSA), and Perfluoreoctanoate (POAA) in Water 2/24/04 July 10, 200110 CICOSONTNFRFIIIDDCEETNNTCTIOIAARLLT-,SSUUNoBB.JJEE2CC7TT.TCTV0O1AAP02PR6R8OO82TTECETCIVETOOIRRDVDEEERR ENITNHEENNERPINECOUNDTY ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 aw_notssse17 3M_MN01538617 11993377..00223311 i on ema on sm ---- rinting Date: Monday, March 01, 2004 ~i wa Exygen Study Number: L1874 Set Number: 021904D ACSFM Page I of 1 CEDASF (0 50 rear ages (11%Wag y=S077 SUAS (woos i~" 021904D ACSFM.rdb (C6 acid): "Linear" Regression ("1 / x" weighting): y = 597.073 x + 54748.5 (r = 0.9674530) 2087.0e5- Joos i~ 6.Se5- Joos6.6e5- Jos6.4e5- 16.2e5- cos6.0e5- 4 ae5.8e5- sos5.6e5 - . a5.4e5- Dae5.2e5- a ses5.0e5 - dv4.8e5 - caus * aes4.6e5 4.4e5 - aes4.2e5 - snaes .. 3.8e5 - hE3.6e5 - 3.4e5 - : Besas3.2e5- 0s 3.0e5 ~ oe 1 22.88es5 2.6e5 - 2.4e5 - caus2.2e5 "os2.oe5~ | 11..886e55:~ qe , 1.6e5 ~ 1a1.4e5 - 1a1.2e5 - noe] 8, - 11..006e55.8.0e4 - ade o6.0ee4 - . 4.0e4 - 2.0e4 - --- -o0.o % Canning I 0(~0 220~)0 ~0)0 4~00 556600 060000 7(3~0 8o~)o0 Concentration, ng/mL . . / ya w90o 0 as 100 1000 o CONFIDE-NSTUIBJAECLTTO APROTECTIVE ORDER ENTERED IN CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT GOURT. NO 27-01-10.08862 HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00223322 Su umorssests 3M MN01538618 i me one ~rinting Date: Monday, March 01, 2004 Set Number: Printing Time: 02:17:16 PM so 021904D ACSFM _-- Page 1 of 1 LC/MS/MS #8 oA Gaee sm | Exygen Study Nun~ber: L1874 021904D ACSFM.rdb (C8 acid): "Linear" Regression ("1 / x" weighting): y = 1241.09 x + 17250.5 (r = 0.9983752) i u| sro oamse 1.2Oe6: 8 1.15e6 / ._ : pa : 1.11.1000e56: | ose 1.05e5 1r.0o0es6 - Ves 9.50e5w owes 9.00e5 sso 8.50e5- ofoe # 58.0o0ose.5- rem 7.50~. roe] 7.o0~ o ossooeos!s! . &SeeS- sons! 5.00e5cones bo s4.5o0se5!4 4.00e5 ~ "= a3.s5e0ees5 33,.0000e055- . . 2asa5mt0es . 2.00e5 sooense!]i - o Te100 m 200 wsoo 4w 60Cocas nio iso60n,rn.6w 60 w760 ww - ' Concentration, ng/mL CCH".EOONNNNFEIDFPEIINNTDCIAOELU-NN- TSSTUYUIBBDJJIAEESCCTLTTRTITCOOT AAGPOPURRROOTT.TEECNCTOTIIVV2EE7 -OO0RR1-DD1EE0RR.0E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00223333 Su umorssesto 3M MN01538619 iShes, ~rinting Date: Printing Time: Te Monday, March 01, 02:17:22 PM 2004 Exygen Etudy Number: L1874 SSeert Npuusmhbeerrs: oz Ass 021904D ACSFM hah' Page 1 of 1 LC/MS/MS #8 4 W 002211990044DAACCSSFFIMLI.rGdSb((CC44ssuulflfoonnaattee))::""LLiinneeaarr""ReRgergeressssiioonn(("11 7/ x"wweeiigghhtiinngg)): yy==114411..004455xx++000.000110077776677((1r==000.9880011228686)) Ye | 1.15.50e55.1.4e5 ` ! 1.14.48e55: 1.3e5 1.13.30e55. i1.2e5 ho1.2e5 41.1 e5 we1.1 e5 1.0e5 on9.5e4 ve9.0e4 vo . | 8580.54e4. 8.0e4 4ic --1 on7504 7.5e4 y < 6560.54e4. 4 6.0e4 po5.5e4 * s.o~4 -4.5e4 4.0e4 T wo : 3.5e4 - a3.0e4 po2.5e4 "20 1510.54e4. & om . . 55000000.00~ 9 . o.o! EEE J Ee 0 1 ~0 2~0 3~0 400 500 600 700 800 Concentration, ng/mL 2 // * 9~0 10'00 j - CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00223344 3M MN01538620 Miri st rn hos mrs asers onan ~rinting tinting Date: Time: Mondays March 02:17:27 PM 01, 2004 ern SnirSaat 3430 Exygen Study Number: L1874 Set Number: 0219G4D ACSFM Page 1 of 1 LC/MS/MS #8 4 ETDRCSF GsseraUnease C17worn y=TTT 78%TOOT (wosomorasy 021904D ACSFM.rdb (C6 sulfonate): "Linear" Regression ("1 / x" weighting): y = 711 376 x + 0.014289 (r = 0.9943144) I 77..008e55:- /e 6.8e52 1~ ones 1 6a.m6ees5 - sas. * ozs6.2e5- Pa 6.0e5 -" pprreess5.8e5 - sass sas5.2e5 ] sos5.0e5 oauss La 4.6e5 pres4.2e5 Plg rams3.8e5 -- WNo=g oo3.6e5 ase - : < azs No sos i|I 3.0e5 - [I 2.8e5 - Lp20052.6e5 | 2.205- pw2.0e512051.8e5- pros1.6e5- 1 1.405. 1205. / 1.2e5 ~ PRS | sow 3 w Swooes] o 2000 Uo ! Te mw ww @ we w_ wwnoo ww -- 7 -- 7 0 1 ~0 ~0 300 400 zoo 650 7~0 800 950 1 o'oo Concentration, ng/mL ii " `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACOPPURRROOTT,TEECNCTOT.IIVV2E7E-OOCVRR-DD1EE0RR28EE8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 M_MN01S38621 3M MN01538621 11993377..00223355 wi Se ,~,frinting Date: Monday, March 010 2004 ~Printlng Time: 02;17:33 PM a Ir, Exygen Study Nuz~ber: LI~74 eer eso Set Number: 021904D ACSFM _---- Page 1 of 1 LC/MS/MS #8 4 W O0E2T1R900R4DDAACCSSFFM.rdb ((CCB8 suolfornaattoer).: L"Liinneeaarr"RReagrsesssion(("11 1/x"Wwoehighitinng)):yy==55483.112222x ++ 68800.338077((r ~=o0o.9s8o69w5o0o3n} | sass 5.4e5- 4 em5.2e5. 5.0e5- es4.8e5 . ms4.Se5| a4.4e5Pp4.2e5 - pe4.0e5a3.8e5 - sous3.6e5 - 8 u3.e4se.5- ! 332.20e55:- e sos 3.0e5- 2.8s5- of ht HE2.6e52082.4e5- teas2.2e5- lt] 3 / // . . res 1.Te5- Teel 1.4e5- ww1.2e5- 7 1.0e5- - soos! . 4[= - . 4.06=4- 20m2.0e4- `I e JREr eeSCI 0.0~ 0 ~00 ~00 3oo 4oo 5bo abo Concentration, ng/mL | E I ET 7do abo ~do idOO CHEONNNEFPIINDCOEU-NNTSTYUIBDJIAESCTLTRTICOTAGPOURROTT.ECNTOIV2E7-O0R1-D1E0R.0E88N6T2ERED IN - CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00223366 Sw uotssesz2 3M MN01538622 LL pp we tinting Date: Monday, March 01, 2004 Prlntlng Time: 02:18:07 PM Study Number: L1874 wn worse Set Number: 021904D ACSFM . Page 1 of 13 LC/MS/MS #8 fl Ee WEEE IZ Bier HF Ty memmensan san ssm sncee ss i ren~, m+n ~ ew i -f fis # I= EE itt EE "iE i : EEE zl [Ee ia 3 BE fp em "Es EE ,,Ii " CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00223377 | | | | | nn 5 | 3M MN01538623 CT Ie ee l~rinting~ Date: Monday, March 01, 2004 ~rinting Time: 02:18:08 PM EE Exyqen Study Number: L1874 mae ore Set Number: 021904D ACSFM J Page 2 of 13 LC/MS/MS #8 Lr wBhE 5hw iow fe HE = aIE SH a LL aEI`nErFeEerE igWEraT =s o dElzgEefm10) | | 1| | t EEE Yo oo Fl Br HF I =r WE EE h ET SEE JE --- fs = " Peher dinirtopsseapirformu nl CHOENNFNIEDPEINNTCIAOLUN- TSYUBDJIESCTTRTICOTACPOURROTT.ECNTG.IV2E7-O0R1D1E0R.8E8N6T2ERED IN ,-,|t CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00223388 L a apo v ee su_wmoressse 3M MN01538624 wi on ll~rinting Date: Monday, March 01, 2004 Printing Time: 02:18:09 PM EE Exygen Study Number: L1874 ms i Set Number: 021904D ACSFM . Page 3 Of 13 LC/MS/MS #8 ya " pr : [Fer WE Tae Ee T~i, rain eon nase sensn " | | _ 0.5 t.O 1.5 2,0 2.5 3.0 3.5 4.0 4:5 5:0 5:5 e:O 6:5 7:0 7:5 9:0 8.5 g:O 9:5 160 I~5 I~0 115 120 "I'I~, n~n "ilii - CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00223399 3M MN01538625 sii Se th osmn l~rinting Date: Monday, March 01, 2004 ~rlntlng Time: 02:18:09 PM Set Number: 021904D ACSFM Exygen Study Number: L1874 a Him HEa 0 WEElE HT [- Be WE JE TE R sBoegns wften "BEEEE hwoaI= EEE EB Tm QE a, [EEE Erne =e FE AEEBEEEEELE OHEE TL:1D04 EECLa EE ws E IEEE Fm a CCHLOlEONNNFNIFEDIDPEEINNNTTICIAAOLLU--NSTSUYUBBDJJIEESCCTTTRTITCOOT AAGPOPRURROOTT.ETCENTCIOTVIVE2E7O-O0RR1D-D1EE0RR.0E8E8NN6TT2EERREEDDIINN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00224400 J. Page 4 of 13 LC/MS/MS #8 | I || | | | ou snmonanes seisn| : | \|i . | Sw uotsseezs 3M MN01538626 [A !iPrinting Date: Monday, March 01, 2004 Printing Time: 02:18:10 PM -- Set Number: 021904D ACSFM ms Page 5 of 13 LC/MS/MS #8 Exygen Study Num~ber: L1874 Er | iEeEE eo eee FFEoir: e -I WEE HE og eo anes HTERT || | EE foe J Ee Loa J x Beg a CC-HiOEONNNFNIFEDIDPEEINNNTTICIAAOLLU--NSTSUYUBBDJJIEESCCTTTRTITCOOT AAGPOPRURROOTT.ETCENTCIOTVIVE2E7O-O0RR1D-D1EE0RR.0E8E8NN6TT2EERREEDDIINN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00224411 | Sw uotssesz 3M MN01538627 jPrinting Printing Date: Time: A Monday, March 01, 2004 02:18:11 PM Set Number: 021904D ACSFM Exygen Study Number~ L1874 tr Page 6 of 13 LC/MS/MS #8 EET LIE Er Ew 3 | AEE ER a - Ee = mn| | LEI EEL EI AEEE a n HE mm a nianamaneB sn itm mnie |} = - CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00224422 3M MN01538628 2 Se oe ~prriinnttiinnog DTaitmee:: M0o2n;d1a8y:,12MaPrMch 01, 2004 La Exygen Study Number: L1874 EEL ove vt me Set Nut,bet: 021904D ACSFM EE GE FH EEREE I - wr Page 7 Of 13 LC/MS/MS #8 J | i sss reser SEL pm am fERe HI WET a e[eEE ETT = Ha 2 { eae mmm on T crm WSEEEE GETino | o Timi IZ WG iltl CC"HEOONNNNFEIDFPEIINNTDCIAOELU-NN- TSSTUYUIBBDJJIAEESCCTLTTRTITCOOT AAGPOPURRROOTT.TEECNCTOTIIVV2EE7-OO0RR1-DD1EE0RR.0E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00224433 J RII Sw uotssesz 3M MN01538629 Writse re orn, ee vr 0iPrinting Date: Monday, March 01, 2004 Set Number: Printing Time 02:18:13 PM E~ygen Study Nun~ber: L1874 cn do 021904D ACSFM ,| oF 3 aan Page 8 of 13 LC/MS/MS #8 | br i= : | we = i= | = 0.5 1,0 LS 2.0 25 3.0 3.5 4,0 45 50 $.G 6.0 O.5 7.0 75 6+0 8.5 !+0 g5 100 105 110 115 tZU+ py TilT)l, [Tin ! JE HED a CCH.EOONNNNFEIDFPEIINNTDCIAOELU-NN- TSSTUYUIBBDJJIAEESCCTLTTRTITCOOT AAGPOPURRROOTT.TEECNCTOTIIVV2EE7 -OO0RR1-DD1EE0RR.0E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00224444 J ~ Su uotsseeso 3M MN01538630 - A ge liPrinting Date: Monday, March 01, 2004 --Printing Time: 02:18:14 PM PII Exygen Study Number: L1874 mee ss Set Number: 021904D ACSFM es Page 9 of 13 LC/MS/MS #8 aEEr fWaem rl |1 Epes rer sir 3 mn 20 EEE EE WW EERILY a ne ---- 1 [=E &r i EEA = vo JRE Tani e Be REO w il EET TE = im, lV Thin, ndn . CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00224455 3M MN01538631 wri l~Printin. g. Date: Monday, March 01, 2004 Pr~ntang Time: 02:18:15 PM Es Exygen Study Nuanber: L1874 es aresoe Set Nualber: 021904D ACSFM EEEre E dE E13 mm, = ae Page i0 of 13 LC/MS/MS #8 ] PRT| Peli i = fz op -- MEE Ea Hw nest Be NEE REAR ape,ge) ay . NER JE -- b EBEEL GE no:o iE E'S . { E Bainm he = | ABEeE EHaE ETL EE _ . A ne | .......... /lm;, rain .... ,.s elo ~;s ,6.0 ,6s ,~.0 ~,~ ,~ GO"NFIDENTIA - SUBJECT T0 A PROTECTIVE ORDER ENTERED CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN FEANERI COUNTY DISTRICT COURT NG. 27 Gunio26803 HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 swnos33632 3M MN01538632 11993377..00224466 rt sn nn ~Printing Date: Monday, March 01, 2004 Printing Time 02:18:16 PM ma, msn Set N~u~ber: 0219~4D ACSFM [. Page ii of 13 LC/MS/MS #8 Exygen Study Number: L1874 aman 1 E FE a Br oo || EERhTL hfaomoge ii FEE BT | aE i EEE TIm~, m~ FEBEEEEETdheonm ge Tim, mln He WEE = Time rain "h~ CONFIDENTIAL SUBJECT 10 APROTEGTIVE OROER ENTEREDIN CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN EE CBA hey SER vo 5 oer HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00224477 } | I -- 3M MN01538633 ib se ~Printing Date: Monday, March 01, 2004 Printing Time: 02:18:16 PM a Te ET Exygen Study Number: L187~ me sac Set Nu-~ber: 0219~4D ACSFM si Page 12 of 13 LC/MS/MS #8 == -- - i EEEEm ie EE Ed 17 | ! | | Tr he Ban SE hz am Jt tHE HE 1] or WBEEBEEa spa itr?" i i J w Titrm CHOENNFNIEDPEINNTCIAOLUN- TSYUBDJIESCTTRTICOTACPOURROTT.ECNTG.IV2E7-O0R1D1E0R.8E8N6T2ERED IN -. CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00224488 su_wmoresssse 3M MN01538634 te ll~rinting,~ Date: Monday, March 01, 2004 Printing Time: 02:18:17 PM Exygen S~udy Number: L1874 cFn ET Ee TEEeeieil= HE lf eee sac Set Number: 0219G4D ACSFM Ee oe b=IE sn Page 13 of 13 LC/MS/MS #8 |i| pws pe en|| a ee dgEE TIrm, CHOENNFNIEDPEINNTICAOLUN- TSYUBDJIESCTTRTICOTACPOURROTT.ECNTG.IV2E7-O0R1D1E0R.8E8N6T2ERED IN " CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00224499 mi20n| su_woresssss 3M MN01538635 wi se I~ri. nti. ng Date: Monday, March 01, 2004 Prlntlng Time: 02:18:45 PM Exygen Study Number: L1874 se os Set Number: 0219~4D ACSFM I. Page 1 of 13 LC/MS/MS #8 ES | BEE # = Te WE a rrr ed 0:5 1:0 1:5 2:0 ~5 3:0 3:5 4:C 4:5 FS:0 5:5 e:(} 6:S 7:~~ 90 9.5 100 105 110 115 12< Te feo VHEeE HEEEF - on sos asses!| " CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00225500 3M MN01538636 WT Be wows mas mas l~Printing~ Date: Monday, March 01, 2004 ~rinting Time: 02:18:46 PM E EERE EE EE] Exygen Study Number: 51874 Set Number: 021904D ACSFM Page 2 Of 13 LC/MS/MS #8 EFL 3 aE HT 1BE% ~ | W IEEE E waE a E . EERE ERs SEE BE ar " | TE "BEiE , E 17= kl " CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00225511 | Wakcait i 3M MN01538637 WN a oe i~rinting Date: Monday, March 01, 2004 ~rinting Time: 02:18:46 PM Emm Exygen Study Number: L1874 es son Set Number: 0219~4D ACSFM Be UE EEE 1i7o MbBovailmg rTxL 2 EE Giz oo WERE HE 1 == GEER WEE CH i _ Page 3 Of 13 LC/MS/MS #8 fe monn ;: ii SE he i Tene, rnin L|lt SETA LATTE ATL ORR NeEneros o COI'4FIDFN-IIAL - SUSJFCT I-O/% P~OI-t=CTIVF O~Dt=R FN-IF~FD IN I-It=NNt=~IN COUN-I DISTRIC-I- COURI-, NO. 27-CV-'10-28862 11993377..00225522 aw rsossa 3M MN01538638 ari pon os frinting Date: Monday, March 01, 2004 Printing Time: 02:1~:47 PM Exygen Study Number: L1874 ar " Fgepd w= 0 tm ha oa mes sens Set Number: 021904D ACSFM = te HE EEE fen oo are Page 4 of 13 LC/MS/MS #8 1 | | | re] Fr ! - TT ; RR wEE ET ----ETT ii -CONFIDENTIAL - SUBJECT TO APROTECTIVE ORDER ENTERED IN CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT. NG. 27-0110.8862 HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00225533 ie su_wmoresssso 3M MN01538639 it ~i~rinting Date: Monday, March 01, 2004 ee sac Set Nut.her: 021904D ACSFM sary Page 5 of 13 Printing Time: 02:18:48 PM LC/MS/MS #8 == fd } Exygen Study Number: L1874 mm~m iw i Gow zn | | Yee [A re 5 | | | T~w ~n F =z ............. 0.5 10 1.5 2.0 2.S 3.0 3.5 4.0 4.S 5.0 5.5 5.0 0.5 70 7.5 8.0 5:5 9.0 9:5 10.0 105 110 BE eo aE EE, 05 10 1.5 2.0 2.5 3.0 35 4.0 4.8 50 5.5 8,0 6.5 7.0 75 8.0 8:5 tO S5 100 105 11o 1~$ 124 CREONNNFEIRDCOEU-NNTSTYUIBDJIAESCTLTRITCOTACPOURROTT.ECNTO.IV2E7-O0R1-D1E0R.2E89N6T2ERED IN ,.,|1 CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00225544 awmorsassio 3M MN01538640 FE ~prriinnttlnngg DTaitmee:: M0o2n:d1a8y:,49MaPrMch DI, 2004 ETE Exygen Study Number: L1874 === hi ---- Set Number: 021904D ACSFM ssn Page 6 of 13 LC/MS/MS #8 SETS al HE EER RRR RR eR TT SER ChE or Ee Iz er ET er EE ERT SEEEE. h8s [a2o BEE = EEE CZ rr ' RR Re EEE Yi lz || aBgee Sa E B IL)fNae3 l]n~, rain G.ONFIDENTIA - SUBJECT T0 A PROTECTIVE OROER ENTERED CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN NE COTY TRIE Soar N37 ure zeses HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00225555 . SePY | swors 3M MN01538641 wr we li~rinting Date: Monday, March 01, 2004 Printing Time: 02:18:50 PM Exygen Study Number: 51874 et mn on Set Number: 021904D ACSFM IBEe E heEs R Ewe og nt Page 7 of 13 5C/MS/MS #8 -- 2 ails Een. 2 | 5o f:e m 1 1E | i PalPo s] Tt 3 EEE El fie CHE . CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00225566 _ gaanI2 m 000um 3M MN01538642 TA ~Imrinting Date: Monday, March 01, 2004 lWPrin~ing Time: 02:18:51 PM Ee Exygen Study Number: L1874 esa sisson Set Number: 021904D ACSFM p Page 8 of 13 LC/MS/MS #8 EET LE WEEE i = BEE Ig Em fw - A Be r"BRF . CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00225577 i | 3M MN01538643 wi~rinting Date: Monday, March 01, 2004 Printing Time: 02:18:52 PM ree nen Se~ Number: 0219~4D ACSFM prin Page 9 of 13 5C/MS/MS ~8 Exygen Study Number: L1874 flEERE | a Eg itm IyZm { EE fF EID | EEE EES ESR ea eg SHEE FE =Iu . CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00225588 on ppp 3M MN01538644 wiz me ~rinting Date: Monday, March 01, 2004 Printing Time: 02:18:53 PM Exygen Study Number: L1874 Set Number: nn 021904D ACSFM sn Page i0 of 13 LC/MS/MS #8 ts Eo SEE EEE 3g \ de) Mie fer 7 RE ~ _--llllullliiiliubii iii BEE EET fe) Mensa slimes? re TkT~, Te HE g ane Te fy. C ene sane | ~ CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00225599 3M MN01538645 Wi st oe wis ~rinting Date: Monday, March 01, 2004 '---Printing Time: 02:18:53 PM Set Number: Exygen Study Number: 51874 00 021904D ACSFM Em Page ii of 13 LC/MS/MS #8 IE | I 3 == TEE fw MSEEER dHs Xal WEET Be THE Toss peppy -- _ " `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NTSSTUYUBBIDJJIEAESCCTLTTRITTCOOT AACOPPURRROOTT.TEECNCTGT.IIVV2EE7-OOGRRu-DD1EE0RR.2E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00226600 aunotsaseds 3M MN01538646 oti te l~rinting Date: Monday, March 01, 2004 -~rinting Time: 02:18:54 PM mei sm Set Number: 021904D ACSFM es Pase 12 of 13 LC/MS/MS #8 EE]1 Exygen Study Number: L1874 Ee fen ! HEF E10 EEE " Mtn few WEEEEE hHTn fm JE BE EER fhe FEe EEE hs EF Hope ! J| wcmonrare seat To | Em owe a] coo - Ansar ---_ COCH"NEOFNNNIFEDIDPEEINNNTTICIAAOLLU--NSTSUYUBBDJJIEESCCTTTRTITCOOT AAGPOPRURROOTT.ETCENTCIOTVIVE2E7O-O0RR1D-D1EE0RR.0E8E8NN6TT2EERREEDDIINN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00226611 emptor! Has _ Su uotssess 3M MN01538647 RR ge rlntlng Date: Monday, March 01, 2004 ~ tinting Time: 02:18:56 PM EEE Ex~gen Study Number~ L1874 oe Set Number: 0219~4D ACSFM J. Page 13 of 13 LC/MS/MS #8 wR IE RE A Er FEF te do Reia nRE | Ti~rm EE i EEE ELI. WEEEEE HT ifzel i ee | wil HT w C.ONFIDENTIAL - SUBJECT TO APROTECTIVE ORDER ENTEREDIN CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN NE COTY TRIE Soar N37 ure zeses HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00226622 TT Ee ar, swmorssaoss 3M MN01538648 ins a rinting Date: Monday, March 01, 2004 ~SHEE rinting Time: 02:19:20 PM Exygen Study Number: LIS~4 ne Set Number: 021904D ACSFM Bhs: 1 tEnmr Da = EFL I Em ia men fe J. Page 1 of 13 LC/MS/MS #8 RJ ke wfll To | oil Tri To TT a Ee Bo. .. | EEE Ls sen BTR ee ae A rary "RE. E ID ' CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00226633 3M MN01538649 EA, ~rinting Date: Monday, March 01, 2004 Set Number: 02190~D ACSFM --Printing Time: 02:19;21 PM ~xygen Study Number: L1874 -- Page 2 of 13 LC/MS/MS #8 BBiEwiM.ILT3 ! BES. Em . WREEEm iRE TEI: oi a 3) Ee aE ELAN AN COS N.FIDENTE IAL - SUBIECT T0 A PROTECTIVE OROER ENTERED CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00226644 dFT eTth yh " WE pat JAY ey Lo aw orssesso 3M MN01538650 l~rinting Date: Monday, March 01, 2004 Printing Time: 02:19:22 PM Exygen Study Number~ L1874 Set Number: 021904D ACSFM Page 3 of 13 LC/MS/MS #8 S=i= hBeEdd Teel lh dr Wola JST ri i TIL EE EEE SESRRR el TE ERE rr -- . CI . CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00226655 | 3M MN01538651 Wines per on en l~rinting Date: Monday, March 01, 2004 Printing Time: 02:19:23 PM LE va rte Exygen Study Number: L1874 Set Number: cs som 021904D ACSFM fo Page 4 Of 13 LC/MS/MS #8 Em 1 Yom he I | SEEEREheaIr I i I EEE a EC EE Lz 4--D sEEL HT jo EEE I 1 a = Tim. rain iBSEE FE ha I EE hE iE EEE E 37 SEEeE He E n oJ AE ES wm zs [Ee TEE a AL ii --- `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NTSSTUYUBBIDJJIAEESCCTLTTRITTCOOT AACOPPURRROOTT.TEECNCTGT.IIVV2EE7-OOGRRu-DD1EE0RR.2E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00226666 o wn Rs pire nen | au_mnotsases2 3M MN01538652 PE l~rinting Date: Monday, March 01, 2004 Printing Time: 02:19:23 PM Ip se Exygen Study Number: L1874 ---- Set Number: 021904D ACSFM J. Page 5 of 13 LC/MS/MS #8 WPeiEerrT aEWEaE]- L MdSA A sili oCPART gh =e {Bie wy w ans Hed WEEEEEhsT 1 i Eee EE dum 3 M, ELEE 2 " CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00226677 wsi 3M MN01538653 A ~rinting Date: Monday, March 01, 2004 Set Number: xEPxryyiggneetnniSngtStuTudidymye:WNeusm0bb2ee:rr1::9:241L1188P77M44 -- 021904D ACSFM J Page 6 of 13 5C/MS/" MS #8 MEE. HZ | aE 3n EEOET ID) BEEP g | ga HE OI EEE SBELETSF ae ow I| I T TP e WT E LIN hed SED sent nt BeRrIm A i ger - sR ETT EreE HE Tle) hoC. e mmm a Tim* r~ COuNFIDENTIAL - SUBJECT TO APROTECTIVE ORDER ENTERED IN CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT. NG. 27-0110.8862 HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00226688 SoFninr su_wmoresssse 3M MN01538654 sri Sy on l~rintn~ Date: Monday, March 01, 2004 Printing Time: 02:19:24 PM Exyg~n Study Number: L1874 eseE= Set ers Number: cs 021904D samACSFM fect Page 7 of 13 LC/MS/MS #8 EE 2]. Yo leeds = EE vr wm iW Li IEEE el EEE me EEE = 11mm, " CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..0022669 3M MN01538655 CB mrJ=rinting Date: Monday, March 01, 2004 I'~rinting Time: 02:19:25 PM mas srsn Set Number: 021904D ACSFM tr Page 8 of 13 LC/MSiMS #8 = Exygen Study Number: L1874 FE 1 aE 3 viel ees hiEr . bE A [a WEEE SEER LEA | SEE g EE iE . GCFOEONANFNFIEIDDREEINNTTCIIOAAUL-N- TSSYUUBBDJJIEESCCTTTRITTC0OTAACPOPRUROROTTTEECNCTGTI.IVV2EE7OOGRRunDDiEEoRR26EE8NN0TT3EERREEDD IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00227700 swnots33055 3M MN01538656 mmm ~rin~ing Date: Monday, March 01, 2004 Printing Time: 02:19:26 PM Exygen Study Number: L1874 mvs Set Number: 021904D ACSFM J. Page 9 of 13 LC/MS/MS #8 Er | EEE hi l == IEEE UE T heli WBEE endHT 13po T | ile mHiee mEeEF 2 ll|e| Sen eter emROE Foon NIix . CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00227711 3M MN01538657 Up rinting Date: Monday, March 01, 2004 ~tinting Time: 02:19:27 PM aEx-~,gen Study Number: L1874 Set Number: -- 021904D ACSFM an Page I0 of 13 LC/MS/MS #8 Te nom oy | WEEfE ET IC Ee REF IL Cor Lx E ETE ESF peo | GELETHD 7 Be HE mo Era en : ESE WEEE lw ene ANA en)\ ice - i sp ATGR Wt ne - ET . aE E C BETE I= | " | Pe COSNFIDEENTIAL-SUBIECT T0APROTECTIVE OROER ENTERED " CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 2Y-CV-'I0-28862 11993377..00227722 au orssesss 3M MN01538658 Wein BS oe rinting Date: Monday, March 01, 2004 ~rinting Time: 02:19:27 PM Set Number: Eee Exygen Study Number: L1874 os som 021904D ACSFM pr Page 11 of 13 LC/MS/MS #8 SE hw HE | I LES =i - SEE 2 MEEEE OHhTS3 EEE IEEEEE Lwiea EE ET 4 EE 05 10 t.$ 2.0 2.5 3.0 3.5 4..0 415 5.0 5.S n6"Om~ IL5 7.0 7'5 8'0 815 910 915 1(~0 165 11'0 115 120 wEEEEL hHETs [u [[EtE eTEcE i _} -- `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NTSSTUYUBBIDJJIAEESCCTLTTRITTCOOT AACOPPURRROOTT.TEECNCTGT.IIVV2EE7-OOGRRu-DD1EE0RR.2E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00227733 au_Notsasess 3M MN01538659 r~rinnting en I rlnting TDiamtee:: M0o2n:d1a9y:,28MaPrMch 01, 2004 em ne Set Number: 021904D ACSFM a. Page 12 of 13 LC/MS/MS #8 Exygen Study Number: L1874 ee ] Ei he = | TE lhEK gee WEEE ---- a SES no ear rreet Beereres TSE |. EEha = s Fa el \ Ee HF ily Lh i iIr R vAe el RA gol ' i " CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00227744 3M MN01538660 ~ rinting tinting Date: Time: Monday, March 02:19:29 PM 01, 2004 Ex~gen Study Number: LI~74 Set Number: 021904D ACSFM Page ]3 of 13 5C/MS/MS #8 =r EE a! - T| BEEF hr siti okHWTie EI EE See Mesa lieaipl IEEE EE bow 3 EEE -- ee WEE ETE GEE ge h " CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00227755 E-- | 3M MN01538661 ID Ege --~Printing Date: Monday, March 01, 2004 ImPrinting Time: 02:19:52 PM RIE Exy~en Study Number~ L1874 ee sos Set Number: 021904D ACSFM --- Page 1 cf 13 LC/MS/MS #8 TEsfek0:, o EFRi,E 1p:e i er F hw lwe o) r EEE | mGe r 71 Thiai LbeTe 1 i Te Te iTlo ry LTE . EEL BE |. EEE EET EEE ------ a EE LET GwONFIDENTIA - SUBJECT T0 A PROTECTIVE ORDER ENTERED CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN FEANERI COUNTY DISTRICT COURT NG. 27 Gunio26803 HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00227766 swnors33662 3M MN01538662 Wi rn a ho ~rin~ing Date: Monday, March 01, 2004 Printing Time: 02:19:52 PM Exygen Study Number: L1874 ms tosc Set Number: 021904D ACSFM J. Page 2 of 13 DC/MS/MS #8 ea. f=: Hi . | | we EI aFnisz Fhee aS ow tS EE eFE ET Of EE Pra F EF2 EgEEms foe EERE 1] W E HeTE HF 3 | w " CCHEOONNNNFEIDFPEIINNTDCIAOELU-NN- TSSTUYUIBBDJJIAEESCCTLTTRTITCOOT AAGPOPURRROOTT.TEECNCTOTIIVV2EE7 -OO0RR1-DD1EE0RR.0E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00227777 |iHI | in 1 wal PRYR ARedd Su unotssesss 3M MN01538663 CE Ee ~prriinnttiinngg DTaitmee:: M0o2n:d1a9y:,53MaPrMch 01, 2004 Ser Exygen Study Number: L1874 tes come Set Number: 021904D ACSFM ss Page 3 of 13 LC/MS/MS #8 EMIT ITE ia - * FEF ro GBEmET] V1 WEEE T 1 i hr ThEiNer LLTH [i ad EEE "EE ID EE WEL J -- | 1 COuNFIDENTIAL - SUBJECT TO APROTECTIVE ORDER ENTEREDIN CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN NE COTY TRIE Soar N37 ure zeses HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00227788 swmorssaoon 3M MN01538664 Wee set oo I~rinting Date: Monday, March 01, 2004 9rznting' Time: 02:19:53 PM Exygen Study Number: L1874 me onsm Set Number: 021904D ACSFM so Page 4 of 13 LC/MS/MS #8 EE Lz 3 EEE [1 Line (SE : E= EL ET (IT [er nn HE 3 EEEEGLz oEo T BeEHEF gI | | | SEE WE : AEE Ea 2D w -- u,I,i `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NTSSTUYUBBIDJJIAEESCCTLTTRITTCOOT AACOPPURRROOTT.TEECNCTGT.IIVV2EE7-OOGRRu-DD1EE0RR.2E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00227799 | au_mnotsassss 3M MN01538665 frm mee l~rinting,. Date: Monday, March LEE LOE Printing Time: 02:19:54 PM sn 01, 2004 Set Number: a 021904D ACSFM ors Page 5 of 13 LC/MS/MS #8 Exygen Study Number: 51874 EE 1 Waitan - 1 EERE fae 7 | SePe i 1- a WCEolEneOE4 T TM EEE bo eo EoEllL ET jE [ He "WE I ERE TEE TL. g WETa ul ETN LATTE ATL OAR NeEneros " CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00228800 J . { awroses 3M MN01538666 ME BE oes l~rintlng Date: Monday, March 01, 2004 .....Printing Time: 02:19:54 PM Set Number: Exygen Study Number: 51874 stn 021904D ACSPM a. Page 6 of 13 LC/MS/MS #8 VE ra | er WEBEEEEREELx oGzTEZ re Ere ny FpEAET TD T~I, Bin Ve I = WEEEE GHTn o 3 E25 = iz | EBeE wTE 1) ll .,IL GONFIDE- NSUTBJIECAT T0 APROTECTIVE ORDER ENTERED CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN FEANERI COUNTY DISTRICT COURT NG. 27 Gunio26803 HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00228811 : I liIy Jol \Ld. , swnorsss667 3M MN01538667 ipe pe to ~rinting Date: Monday. March 010 2004 Prznting Time: 02:19:55 PM we sn se Sat Number: 021904D ACSFM me Page 7 0 13 LC/MS/MS #8 EEEErite Rxygen Study Number: L1874 T 1i Yer 0.70 Wa] LIE IR Er EE Ln EE 13 0.71 ET Be HF [ tT fl pli lleo nn = [A i LEEEE dae 2 WElEiSNA OT imi IE ; EE HET ! Tr E hee EER ET 05 1.0 1.5 2.0 2.5 3,0 35 4.0 4.5 $.0 55 0.0 6:5 7:0 7:$ 8:0 8:5 5:0 ~s' ,d.o ,ds ,,o ",,~ ,~4 = [Ra | LIETEEE = - `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NTSSTUYUBBIDJJIEAESCCTLTTRITTCOOT AACOPPURRROOTT.TEECNCTGT.IIVV2EE7-OOGRRu-DD1EE0RR.2E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00228822 ---- au_mnotsassss 3M MN01538668 ~rinting Date: Monday, March 01, 2004 Set NLun~er: 021904D ACSFM Page 8 of 13 Printing Time: 02:19:55 PM LC/MS/MS #8 EE] Exygen Study Number: L1874 wer. I aEEE UfeIE= i Tamme en E JERE - ee | - | IEE Hr Be 2 YE " CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00228833 3M MN01538669 FE l~rlnting Date: MDnday, March 01, 2004 erinting Time: 02:19;55 PM Set Number: --021904D ACSFM ns Page 9 of 13 LC/MS/MS #8 == E EEEafEa =T w it | BEEFR Ehom o1T] eo] | === eT SON .PEE Ta d il , ._% ....... ,Iii - CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00228844 I | nl 3M MN01538670 JOI~ririnnttiinngg TDiamtee:: M0o2n:d1a9y:,56MaPrMch 01, 2004 EE Exygen S~udy Number: L1874 ei | YEE I: r Set N~mber: -- 021904D ACSFM sr Page i0 of 13 LC/MS/MS #8 I \ re 11 Yer fa EELdErmTEog VEE DL E EEE CEE ow ELEC i iljwlee wp : ||i pd || VEE oF = BEE IZ .eli CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00228855 T 3M MN01538671 Wes de tuon ~rinting Date: Monday, March 01, 2004 Printing Time: 02:19:56 PM Exygen Study Nu/~ber~ L1874 sn irome Set Number: 021904D ACSFM sens Page ii of 13 LC/MS/MS #8 EEE mT 1 WEE hE i [3:02 i ETE | Weg 12 AEE E _-- EAT : Peak Name: "C~ ~llooai" Mall{el):"399,(l~0,0 ainu" Trim, rtJ a[ni=EFER=. "aEE 1 OE il `CHwoEOCNNONFEINDPEIFNNITCIDAOLEU-N-NTSSTUYUBBIDJJIAEESCCTLTTRITTCOOT AACOPPURRROOTT.TEECNCTGT.IIVV2EE7-OOGRRu-DD1EE0RR.2E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00228866 _ | . [ . L | au_mnotsaseT2 3M MN01538672 wi ge ~rinting Date: Monday, March 01, 2004 Printing Time: 02:19:57 PM Ee Exygen Study Number: L1874 nr Set Number: 021904D ACSFM . Page 12 of 13 LC/MS/MS #8 EEE DT | wE oErT2E | i rrr ere heres, RH 17 Eee shi Ee th Ew BErEw EoUN mii .il CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00228877 Mor mM A1 { bt bo 3M MN01538673 ~rinting Date: Monday, March 01, 2004 *wPrinting Time: 02:19:57 PM Exyoen Study Number: L1874 Set Number: 021904D ACSFM i eBuiz ahla. EEE EO) Ee 7] ml . Tor ern Page 13 of 13 LC/MS/MS #8 Tlie ar dv e rT oT LY a on i111RA 11o 115 12( o : EEE EE rerRe Tire, CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 - 11993377..00228888 3M MN01538674 Wt He ns ~Printing Date: Monday, March 01, 2004 Set Number: Printing Time: 02:21:30 PM Exygen S~udy Number: L1874 ss 021904D ACSFM rit Pa~e 1 of 13 LC/MS/MS #8 =3 EBFAEeLEE EhEF ed1K EEre EPEy Lael to Loerie Ide.l E==ET A = I= : | hmneTil r snna;l iea)F 7 EY Wh | || Br EF la o snes eB WEE EER. | Va EEL EID He EEE W IR R i RR Te 21o 215 30 ee he SEE hE po WES a = | GO"NFIDENTIAL - SUBJECT TO APROTECTIVE ORDER ENTEREDIN CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN en HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00228899 swmorssaors 3M MN01538675 Wr ec os ,~rinting Date: Monday, March 01, 2004 Printing Time: 02:21:30 PM rs hn Set Number: 021904D ACSFM mass Page 2 of 13 LC/MS/MS #8 Ee re Exygen Study Number~ L18~4 . | EE Lz oo | Ee Hr 5 EEE i[eAEE ryt Ere #0 | i | | | | iL [renal y FEE Bes he LEE WRT O,S t.O 1,5 2,0 2.S 30 15 4.0 4.5 S. 55 e.O e.S 7.0 7.~ e.o e.~ so e~ ~oo ~ z~ o ~ ~ ~z ~ l EEE TY om wig W[EEEEe GHEEE J w CPMONFIDE-NSTUIBJAECLT TO APROTECTIVE ORDER ENTERED IN CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT. NG. 27-0110.8862 HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00229900 eh Agta] PWreeneMpn hi su_wmoresests 3M MN01538676 wis mr l~rinting Date: Monday, March 01, 2004 l--~rinting Time: 02:21:31 PM Exygen Study Number: L1874 se sn Set Number: 021904D ACSFM se Page 3 of 13 LC/MS/MS #8 SE CWE Md lg bgp a ad pba do 7 EEE Er BE os BER EEE CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00229911 3M MN01538677 Sp ps l~rinting Date: Monday, March 01, 2004 Set Number: 021904D ACSFM Printing Time: 02:21:31 PM Exygen Study Number: L1874 _ Page 4 of 13 LC/MS/MS #8 wR BE | |i THEE. 3 WEEE EE 1 i ! W HefH, EF J7 || EBEES. LZ x: GEE TEED EE | | i . ! 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Date: Prlntlng Time: 02:21:32 PM aT Exygen Study Nun.=r: L1874 mee ssw Set Number: 021904D ACSFM tat Page 6 of 13 LC/MS/MS #8 Jf EE------ Em fe FE ET gE | !! a | EEE IEE iE ao ml Ee [EEEEE ad=z az: Sd 2 T ! be - t Ee Le CS - eEEEE dHEhm [oa2n Ee Ea e 7 NEE Wt mtn| Tit T este eer teees ee " CCHEOONNNNFEIDFPEIINNTDCIAOELU-NN- TSSTUYUIBBDJJIAEESCCTLTTRTITCOOT AAGPOPURRROOTT.TEECNCTOTIIVV2EE7 -OO0RR1-DD1EE0RR.0E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 Su unotssesso 3M MN01538680 11993377..00229944 Mgt me nn oe {~rinting Date: Monday, March 01, 2004 Printing Time: 02:21:33 PM I I Exygen Study Number: L187~ I se ann sn Set Number: 021904D ACSFM BEE ET EEE poten Page 7 of 13 LC/MS/MS #8 " ! Posi GBEeE HTEEF 4 Em [i RE WEEE ET = FE SEER HT (2 VEE EE, `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NTSSTUYUBBIDJJIAEESCCTLTTRITTCOOT AACOPPURRROOTT.TEECNCTGT.IIVV2EE7-OOGRRu-DD1EE0RR.2E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00229955 Aopr erm 1 | i | au_Norssssst 3M MN01538681 J l~rinting Date: Monday, March 01, 2004 Printing Time: 02:21:33 PM Sn Exygen Study Number: L1874 Set Number: ---- 021904D ACSFM my Page 8 of 13 LC/MS/MS #8 WET i Pht EE HT [o EEeE EWsE JI EEE pBo e HfEe. x WEE HT po EEE 2 eee a ET EE Lz VEEL HTT | | L Tim. rain | | || TEE La oo EE ws Y [EiE 1d He THEI -- Tilts, mifl "i~i CONFIDENTIAL - SUBJECT TO APROTECTIVE ORDER ENTERED IN CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT. NG. 27-0110.8862 HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00229966 | ; ,I su_wmoressss 3M MN01538682 a Ae :~rnting Date: Monday, March 01, 2004 ERE TE Printing Time: 02:21:34 PM Set Number: 0219G4D ACSFM ~xygen ~tudy Number: LI~74 I. Page 9 of 13 LC/MS/MS #8 Err re 1 Ee ba x : EElhEEeIZ ii [Ee HE I | Em 1 [= i IE (Ee HE EEE " E tnT , 3 E =OZ Te TL : WEEeE EEEa 1 ji a . CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00229977 i| 2nie 3M MN01538683 se Sen tase hll~rinting Date: Monday, March 01, 2004 Printing Time: 02:21:35 PM Exygen Study Number: L1874 EEE =y FE EEEEEETE hEiF FE Ta EE on. EE WE LR mess sans pone Set Number: 021904D ACSFM ps Page 10 of 13 LC/MS/MS - re T | | ' AT Nprsees ee rr I RE Sm fa EEEF OBEde 1o3T Br TEE LM TSE re tor ger eea -. i o.=o He HEF | o.s ~.o <s 2.0 2s s.o ~s ~.o ,.s so s.s T~m s's 7o z.s e.o ss ,~.~ ,,is ~6o ~ ,i0 ~s ~ f) , Bim he o og i= Wp Ee R - | u CCHOEONNNFNIFEDIDPEEINNNTTICIAAOLLU--NSTSUYUBBDJJIEESCCTTTRTITCOOT AAGPOPRURROOTT.ETCENTCIOTVIVE2E7O-O0RR1D-D1EE0RR.0E8E8NN6TT2EERREEDDIINN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00229988 Su uorssesss 3M MN01538684 l~rinting Date: Monday, March 01, 2004 ~rintlng Time: 02:21:35 PM Exygen Study Number: L1874 Set Number: 0219040 ACSFM Page ii of 13 LC/MS/MS #8 e EEEe hkm oe. I Eg WERE IZ ER Es Io a VEER wi [ini GEEE.ETOns og1D WEEE EEE one Cu EE WEEE LHTc fIm =EWE 2 po S[EFeEeaHEEe TERE Ew EW " | i| eT ew . | WEEEEE hETc uER Es 2 ,aii TI~, rain CCH"OEONNFNNIFEDIDPEEINNNTITCAIAOLLU-N- TSSUYUBBDJJIEESCCTTTRTITC0OT AACPOPRURROOTT.ETCENTCOIT.VIVE2E7O-OCRRVD-D1EE0RR.2E0E0NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00229999 | | a uorssesns 3M MN01538685 Me rn lll=rinting~ Date: Monday, March D1, 2004 ~rinting Time: 0~:21:35 PM Set Number: Exy~en Study NLu~ber: L1874 se 021904D ACSFM FR. Page 12 of 13 LC/MS/MS #8 WEEE TD Eas ~ml min EEF aw VEEE ER dHEam {gmo=w WEEE EEE WEEEmEiHC Iofo ASErE Euee of . CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00330000 1 . |! Joga "fht d A 3M MN01538686 I I lll~rinting Date: Monday, March 01, 2004 Printing Time: 02:21:36 PM LE Exygen Study Num~er~ L1874 ewes samo Set Number: 021904D ACSFM fp Page 13 of 13 LC/MS/MS #8 WEEFSEiOETEi EE1; E Ee ewE 0Lg) IN ` EEE -- Pl. WE 3 a | Hee opa {tated bly } sl oo 7 EEE HT HD JE THE. E Lm ar a geal WEE HE 1 Tillnl, nil1 0 :,Hi - CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00330011 3M MN01538687 RAW DATA REPORT " E FET swiETT Rm Code NO. Fa~r (pp0 (ppt/ (%) CS 021804AR-201 (pOpl) 1444 XC922494-1 c$ 021804A~-202 25 9138 XC022404-2 CS 021804AK-203 80 15958 XC022494-3 cs 021804AR-204 100 30609 X~622464-5 cs 021804AR-205 256 cs 921804Ag-206 606 77022 140756 CS 821804AR-207 1000 262457 C 821804AR-208 4987 C 021804&R-209 7288 ND LCS 021804AR-210 19747 63.9 50 128 504 500 rio IOOO 11653 10600 L1874-1SpEC 1oo 95428 33700 10000 -173 lOO 43462 15600 10000 155 L1874-9 Spk E 11874-18 Spk F 100 107992 40600 10000 151 1oo 44006 15000 1oooo 158 L1874-17 SpkG 100 69630 25700 10000 171 XC022404-1 25 - 9490 1o00 16777 L1874-1 Re9 1ooo 14822 L1874.2 1oo 140040 53000 1oo 124693 47100 L1874-2 1oo 119813 45200 L1874-2 L1074-3 L1574-5 Influmt 3 High S~k p~ct 4A Pert 4A port 4A I~p 1014366 1042865 I00o 16653 100O0 I00 144063 1000 43625 156000 100000 103 17096 25723 57.1 24623 22505 74.6 100 32O42 11200 10000 1000 25847 87600 100000 1~ 27633 ioo 69053 25500 71291 26400 Ioo 76099 28200 651496 Port 8A Dup Ioo 1ooo 142000 100000 117 100 ND ND ND ili 1oo 12000 10600 120 1ooo 124O00 1 o00o0 124 200 100 100 100 1000 8590 8240 0390 19600 100~3 [ 18000 100000 109 " Gi mE LE Eo. ND 100 10100 1000~ 101 99100 1600O0 99 IOOO Recova3,(%) = [a~al~te fom~d (ppt)-amalyte found in conffoI (~0pt)] x 100 `Ii EACK = Chel~ Sma~ml =. .,`| Tm CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00330022 Boh 3M MN01538688 . nora i RAW DATA REPORT - For Bee Be FB Bp fe . FEET UTE Code (,~pt) Fag~r Area (ppt) ~ppl) (',b) Cg 0~1R04AR.701 o 6237 . Ei ,ill SRNL C~ 021804AR-202 CS 021504AR-203 CS 021804AR-204 1oo CS 821804AR-205 250 500 E14980 27297 36696 71629 158954 1ooo 279485 EEL gE DE Eis 3396 3784 ND 19267 44,8 50 90 530 5~0 106 1ooo IOO - BEE (EER IEEE ioo I0o . FE Influml 3 1o0o 1ooo looo 278000 25L000 269000 ` oN En iEE LE 278000 -20 lOO Influe~t 3 High Spk 869000 100000 % IE Eni iL 3ND ND : ND 9380 100O0 . Eom Em Tz oR 71900 1OO000 ioo IOO 1oo 7380 ` BH ih (EEE RAd IOO IOOO 8410 16800 90800 10000 IOOOOO ND 4 E 5 EE iE Ea ND IOO 9950 10090 IOO 105O00 100000 io5 250 - 200 200 200 100 13500 |00 11500 100 100 1000 ND 1oo 7820 1O0~0 lOOO 8160O 1 ~O000 . CA, Remw-y (%) = [aaalyte found (ppt)-ana~te bund in coalrol (ppt)] x 100 EE StaadaxdC~v : Lin~ (l/x wdghted) Intffcep! = 7136.88 arflmmt added (ppl) Slope = 271.0O8 Coef OfDet = 0,992051 . LEE CK = Check . reerBe tel CCHaEOONNNNFEIDFPEIINNTDCIAOELU-NN- TSSTYUUIBBDJJIAEESCCTLTTRTITCOOT AAGPOPRUROROTTT.EECNCTOTIIVV2EE7-OO0RR1-DD1EE0RR.0E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00330033 Su unotssesss 3M MN01538689 f aawsnsaront it RAW DATA REPORT " PF fe He 5B Bom Fe SpomoI StudyNO: Exy~m St~ly No: Atmlyte: Ions Mmtitor~ NA L]874 Per4ltto rob uta~J alfonale 299 -> 99 MM:tim Volta e: 15 ~L Analyst: Ka~en R~slm Site: NA u TTT ET Tes EE Conc. Dilution Peak XC022404-0 XC022404 t ==XC022404-2 XC022404-3 XC022404-4 XC022404.5 XC022404-0 (ppt) Factor CS O21804AR-201 0 CS 021804AR-202 25 328 TmuEE Cc Ro CS 021804AR-203 50 230 CS 021804AR-204 100 697 CS 021804AR205 250 3162 CS 021804AR-206 500 5454 CS 021804AR-207 I00o 10926 Methanol Wash C 021804AJ~-208 0 ,"i Saas i 1B man Lom wm om ow 0106020 Control ira C 021804AR-209 0 ND 440 6182 589 5oo 118 L1874-1 Spk C hafluent 3 LF L1874. I Spk C [nflaent 3 LF 1000 IO0 460 4106 * 3930o 10000 10000 -473 -J ane = bam hn im em L1874-5 Spk D Comb Efflumt LF L1874 9 gpk E Port 4A LF L 1874-13 Spk F EI~lUent 4 LF 100 1543 15200 100o0 151 !00 8923 84700 10o00 147 100 1499 14700 1oo00 147 L1474-17 Spk G Influent I/2 LF 1O0 16874 160000 10000 15o XC022404.1 - CS 283 1000 725 a,j Liner Mat DG eam owe 1000 1O00 100 9129 86600 100 7920 75200 100 67100 'ii BE Sh (BE iF. L1874.3 Inilu~mt 3 Low Sl~k FF 77736 10 76627 75336 1000 99200 10CO0 126 t00 9092 ` "IE EERE 1000 2914 2~1000 10O0O0 194 512 54.4 600 267 NQ L 1874-7 Comb Efl]umt Low Spk FF 1oo 1309 12900 10000 128 a = ----. TOSMED Tw A a 1o00 1oo 1034 1oo 7364 7000O EB o gmc iEv 1oo 72400 85094 77315 1 en r---- 7 anna oT we em 92640 1oo 9721 92200 10000 222 Ll874-12 Port 4A High Spk FF 100o 2844 274000 1000O0 204 ` di. EL TEER LG 100 0 ND 0 ND 0 2141 20~100 10ooo 208 A EE1ooo 1572 154000 1O0O00 1~4 250 3104 20o 7639 145000 200 6671 127000 6940 132000 I0o 12330 ". 5 EE IERIE: I0o 11626 11477 132001 10 139671 10o 14307 135000 10o0o -100 1000 2721 263000 100000 118 4992 O 0 M A er lL p Ese L1874-23 Trip BlankHigh Spk FF 100 10O0 737 1000 ` ota C = ConW31 sample , FF : Fildfor~fiedsampl . rtm treme ---- ".i GONFIDE- NSUTBJIECAT T0 APROTECTIVE OROER ENTERED CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN FEANERI COUNTY DISTRICT COURT NG. 27Gunio26803 HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00330044 swNo5336% 3M MN01538690 fl " ` " " " 0 ` a ` ` - eg ww = XC0224~4-2 aJ ow uramoer RAW DATA REPORT Ex % = x fw 5x EH BT CS 0218~4AR-202 25 1228 S smn Bn CS 0218~4AR-203 50 C~ 0218C4AR-204 I00 ---2472 4951 11956 24645 47959 BFE 0 l 3 41.0 hd 50 82 2 = IEE .igER BOE Ee: OE IEE LUE on were = CorrlD Effiumt Low Spk ~ Effi~t Hi~ Spk xa Oh Em me 15h: FF 0218~4AR-235 F~ 0218~-236 HECS 0218~AR-237 S 0218~4AR-240 S 021804AR-241 Er S 021804AR-242 $ 021804AR-243 FF 021804/LR-244 FF 0218~4AR-245 1E3 $ 021804A~-248 S 021804AR-249 FF 0~18~1AR.250 FF 021804AR-251 CS 0218~4AR-252 pda S 0218~4AR-253 S 021804AR-256 - 1~O 4854 - 1000 3747 wom I00 4091 100 105~ 1~ 105 807~ 100~00 81 10 9993 219~ ita 10 9880 2170 10 11513 100 6352 13900 100~0 117 100~ 5347 116000 100~00 114 5403 iL EA 1 0 ND I 0 ND - I 0 ND 100 4813 10400 I0000 104 - 1000 5605 122O00 1~o~oo 122 25O - 12511 Coz oR 200 1155 200 1083 200 1061 100 1994 100 1629 |oo 1756 10 19143 4230 10 2O368 449fl 100 6734 14700 10000 102 96 " EE gmat ` =. Emm TE pea ' eesti opted 4 . CCHEOONNNNFEIDFPEIINNTDCIAOELU-NN- TSSTUYUIBBDJJIAEESCCTLTTRIT1CO0T AACPOPRUROROTTT.EECNCTOT.IIVV2EE7 .OO0RRV-DD1EE0RR.2E6E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00330055 aw_morsaeeon 3M MN01538691 . ovum RAW DATA REPORT BE He EB. EB Hr If u ETE. ITE Alea XCO224O4-0 Xco224o4 i CS 021804AR-201 o o CS 021804AR-202 25 748 "4 fr XCO224O4-2 XCO224O4 3 Soman ow - CS 021804AR203 50 CS 021804AR-204 CS 021804AR-205 250 1742 3512 7487 CS 0218(MAR-206 500 17100 XC022404-6 CS 0218(MAR-207 1000 33473 " BE 1 sEE: IE %:i: C C LCS 021804&R-208 0218~4AR=209 0218U4AR-210 o o 1468 14546 LF 021804AR-212 I00O 1637 LF 0218(MAR-213 IOO 14840 o x & 13:32 %1: LF 021504AR-214 LF 021804&R-216 LF 0218OIAR-217 IOO 2555 3775 100 2526 t00 " = Tr Eiri S 021804AR 219 S 0218(MAR-220 S 021804AR-221 S 021804AR-222 1ooo lOOO too 1676 S 021004AR-223 56300 S 021804AR 224 1oo 45400 " BE fF EEC LIB LE I~flmmt 3 Dup laflue=t 3 Low Spk S 021804AR-225 S 021804AR-226 S 021804AR-227 FF 021804AR-228 1ooo * 1oooo PF 021804AR-229 100 46100 1oooo ' BE om TEETIT 2 ldlumt3 High Spk FF 021804AR-230 C~ 021804AR-231 S 021804AR-232 S 021804AR-233 1ooo 146000 ND ND 100000 021804AR-234 021804~R-235 FFF 021B04.a.R-236 ioo ~93 IOOO ND 10200 10000 102 87400 1000~o 87 " rin = CS ow 021804AR-237 lOO - ow 3100 ` ENE FREER EE 3520 1140O 10040 ND ` BoE op EE LB OR om os E~uen14~ E~.emt 4 Low Spk ND ND 9000 92200 100(30 1oooo 66OO 5940 6410 15300 106000 100~0 ND 1000 M rw eeE waT -- Recover(%)= Ianatyte found (lVt)-anal~IC foun4 i~ onoI (ppt)] x 1 00 an~tm! a~dcd (PP0 11300 100~0 113 109000 100000 109 ` TE CK = Chick Standmd ` . " 4 CCHEOONNNNFEIDFPEIINNTDCIAOELU-NN- TSSTUYUIBBDJJIAEESCCTLTTR IT1CO0T AACPOPRUROROTTT.EECNCTOT.IIVV2EE7.OO0RRV-DD1EE0RR.2E6E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00330066 awmorsaeson 3M MN01538692 " E N_ eon TE 3058 Research Drive CIN on Fob hn State College, PA 16801 Phone:814-272-1039 Fax:814-231-1580 " IInntteerrnnaall CChhaaiinnooffCCusutsotdoyd/yF/oFrotritfiificcaattiioonn SShheeeett Bugental pro Exygen Study Number: L1874 . Se Sm oh 5 Sponsor Study/Protocol No: NA ; amet wet cnn tie The samples listed below were removed from refrigerator No. Matrix: Water Tie G0 wore Ei is _EH. Time ~)~ 0 Date Initials ~/ ') [Chw ENCTLISENATNSFAMLPELTE DID TT FEoXXVY6GGEEGNN1oIDhNwNUUaMMBT BEERR | |I VVOOLLUwUMbolEEo(| (mmiL,)|I FFOORRTTIIFF] IICCAATTIIOONN((aneg)) | E osmoswaT | wo | 20 | 0106020 Control 40.0 0106020 Spk A 40.0 2.0 Em na 1 o0o1s06m02o0sSpwksB | w40o.0 | 0 20.0 | Ww wens na lnfluent 3 |e1w.18e74i-1sSpwk Ce | w40o.0 [we4n 00.0 | [Com Comm b Effls uent | Li18w74s-5sSupkbD | w40o.0 | w4o00o.0 | [pmaPor rt 4A uLm18e74s-9 Spk E | s40e.0o| w4o00o.0 | u [ eEmffeluemnta4 |L18o 74-13 Spks F | wan 400.0 [ s aw o 400.0 e ] il [ wInnfwlueenat i1/z2 | iLw18w74i-17sSkpkeG |wo40e.0 | s40e0.o0 | --aeeInnfluenst 3 1 wwe L1874-1 w40e.0 | I wInefmlumeentw3s | hL1e87n4-1rReyp | w40o.0 |) a I olnmflueenmts3 oDuwp 1 vL1i87s4-a2 1w40o.0 [istewlniflutenot 3wLsowpSphk | nLe18w74-s3 1 we40a.0 |] ["etIwnfleuennts3 gHihghsSpk | vLi18e74w-4s | w40o.0 |] 4 I Combe Comb Effluent -- | mL1i87e4-5s |w40o.0 |] cCoommbmEfmflueenst --T uLi18s74e-5sRreep [wo 40.0 [1 | CCoommbbEEmffulueenmtbDeupp | vLi18e74w-6s 1 w40o.0 1 . [ComCobmbEEMffMlueenottLtoownsSpgk | wis L1874-7 Two 40.0 1 1 [ Comb Effluc ent High Spk o | m weL18e74s-8 m Two o 40.0 | n] s pPeorwt a4Aa oL1w87e4-s9 Two 40.0 " [pom Port 4A wL1e874r-9 Reep | w40o0 [| [ PPoormt 4aAaDbupe| mL1e87w4-1n0 w4o 0,0 | [ronsaPortt 4oA LwowsSpgk | L1e8w74a-1n1 w4e 0.0 |] ` CC rPoonrto4nAmHgigrhsSppke | wLe187n4-1n2 | w4o 0,0 |] [SF pSipbikiinnggSSeloulutitioonnUUsseedd VVoolluummT eeUUsseeddffoorrSSppiikldinngg|_ipjiaibate| umeso |rmsumes | soscomms|8 pl 0106020 Spk A F01200~- 10 (10 n~/mL) 200 laL (200 vL trficropipet) a | wowospn 1 ronan bagel | 20,1000, meegipen |ected |umeiswe 0106020 Spk B L1874-1 Spk C TT rootaoongmy [:012004-9 (100 n~/mL) F012004-8 (1000 n~,/mL) |sourcoop manpgen|BE 200 pL (200 pL micropipct) 400 FtL (200 i.tL micropipet) iaipkd] I enssuo | rouoorsuomopmy | wo ceo mevpeer|BE olbbl L1874-5 Spk D F012004-8 (1000 n~mL) 400 ~L (200 ~tL micropipet) - [ uososwe | rouoossmomgmt) | soycoop meoppen | BE piled i L1874-9 Spk E F012004-8 (1O00 ng/mL) 400 ~L (200 pL micropipet) [wenger | rouoorsaomagnt) | 00, 0o0,tmcroppen |WE solid LlE7d-13 Spk F F012004-8 (1000 ng/mL) 400 pL (200 i.tL micropipet) L1874-17 Spk O F012004-8 (1O00 ng/mL) 400 pL (200 btL micropipet) BITE All samples were measured: Time t 000 ou gfe ~L//~/,/(L/ Date . =?) Initials ~-7--/ RE SA i EH - Aftermeasuringsampleswerereturned to atorNo.3 i After measuring samples were returned to~e~igel'ator No. Time I~(~ Date //~,,/~'[ Initials ~-2-/ u Comments, 2 gn me sh tsiim inne Colnlllents; 200 pL of 250 mg/mL sodium thiosulfale was added to all samples before spiking. Initials/Date: AnAanlaylyssiissSSuummmmararyy:: DDataataSSeett: {~?,]t~ (]~I ~n2D~ IInniktiiaallsy/DDaattee:: lf ee flagh ues psi ` DataSex: = Inish/Date: = Data Set: Data Set: 0 2~ ~t3~t~ ~ Initials/Date: Initials/Date: z Sexexuacionadamtaavelriyfisedbsy:__QO Set extraction/analysis data verified by: ~1~/...- oDantee:3~ ]~/~NdY q ` soso (~uly 26, 2001/6 pod f `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NTSSTUYUBBIDJJIAEESCCTLTTRITTCOOT AACOPPURRROOTT.TEECNCTGT.IIVV2EE7-OOGRRu-DD1EE0RR.2E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 au_mNotsasee 3M MN01538693 11993377..00330077 ` E I. oscomsone TY 3058 Research Drive CIN | aii eo State Collese, PA 16801 Phone: 814-272-1039 Fax: 814-231-1580 hd InIntteerrnnaall CChhaaiinnooffCCusutsotdoyd/yF/oFrotritfiificcaattiioonnSShheeeett apap: a ti Exygen Study Number: L1874 Matrix: Water , 2 5 Sponsor Stady/Protocol No: N.__A Te a OR) mmmD,a.sti -- I T~iimeeSam~t~ed below were removed from refrlgera~No~)._,~ CLIENT SAMPLE ID EXYGEN ID NUMBER VOLUME (mL) ` Teme Efflues nt 4 wLe18e74-n13 w4o 0.0 1 [omen Efflues nt 4 | tLs187n4-n13rRegp |w40o.0 | TETfTfluent 4 DupSE L17 874-T14 S T40.0S i [omstEtfflouenwt 4sLosw Stpk | wLe18e74-1s5 | w40e.0 [| [oteeEffdluemat 4gHni[;hsSpk | wLe187e4-1s6 | w40o.0 |] I Im nflueent 1e /2 wL1e 874-n 17 w40e.0 | i`! [inInfe luent 1/s 2 | CL18e 74-17m Rep [emeniaoe| wes | w40o.0 |] | we | [atesiIznfilueontw1/2sDgupt | wee L1874-18 L1874-19 | wo 40.0 40.0 Influent 1/2 Low Sl~k [ameeInfnlueint z1/2 mHiggh sSpk | wLe18e74s-20 Two 4.0.0 1 vpTrwip Belasnk | wLe18e74-n21 Two 40.0 | [rbnTtripoBlwanksLpowiSpeike | wLe18e74-n22 | w40o.0 [| TpbuTiripiBlganhk Hsigph Sxpieke | www L1874-23 | w40o.0 [| ` -- r --- Trr T T rr 1 1 rr Tr rr r r 1 PS I ES a theLe OS 1 rT 1 1 . -------- 11 [CC TT SoSipiikminggSSoouluitoionnUUsseedd |VoVloluummeeUUsseeddffoorrSSppiikkiinngg| InInititiiaatl/DDaactee| rr 1 11 " ---------- rT m T 1 r ------ d r r 1 - rT 1 --rr 1 1 fr Nitisp owe _r Y15J0 iis EH1 Time 7(~6~ Date - AAfr fter mmeeaasstuur'ing sampelesswwereererreeattrtrenedd tto;~.~/~r~ Noo.. 3. semper 2 on Time [~ GO Date Initials " Cmts nmttie eSIO Collamellts." 2~aL~f25~mg/mLs~d~umthi~sulfatewasaddedt~aIIsamp~esb~f~espiking.~nitia~s/Date~ ~I~L~'- Avalyis Summary: Anal sis Sunnna busses 02F104D Data Set 02"~0t4 ~ ilsDote: I Initials/Date . PesHeese panto ` DataSet: a In-tialsDate: WC-- " Scudua rm otsty Pe vue lerde Set extraction/analysis data verified by: ~ Date: ~luly 26, 200116 G"ONFIDE- NSUTBJIECAT T0 APROTECTIVE OROER ENTERED CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN FEANERI COUNTY DISTRICT COURT NG. 27 Gunio26803 HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00330088 swnots33694 3M MN01538694 faa hEr xygeRne kpsenaerm he----en 3058 Research Drive en omeem, mums State College, PA 16801 Phone:814-272-1039 Fax:814-231-!580 SAMPLE EXTRACTION ANDANALYSIS TRACKING SHES SAMPLE EXTRACTION AND ANALYSIS TRACKING SHEET ------ I EXYGEN STUDY NUMBER: L1874 MATRIX: Water METHOD: $_* PROTOCOL NUMBER: NA ANALYTES: C~, C~ C7 & C8 Acids C, C6 &Cg sulfonatcs Client ID I il ol il llA ee |e| na Fee na Efeea ee na Influent 3 Pe ree ee s Comb Effluent a nt es | Port 4A ees re He Effluent 4 ee a Influent 1/2 Fm maneFH Pe et lnfluent 3 Exygen ID STEP 1 STEP 2 Dilutions (mL/raL) 0106020 Control 0106020 Spk A ~ - oneTTT Toh 011~5020 Spk B / L1874-1 Spk C L1874-5 Spk D L1874-9 Spk E L1874-13 Spk F a't/io o. t~. |/~ L1874-17 Spk L1874-1 STEP 3 | Dilutions (mL/mL) -- TU! ge--e - STEP 4 Reagents/ Materials Lot # TT Type ] 7 Wamr NA P Fe e t Fr ee eee s lnfluent 3 Dup L 1874-2 lnfluent 3 Low Spk L 1874-3 [ > n | a HH EHnE ee E meme Influent 3 High Spk Comb Effluent 1wwe L18744 L 1874 5 Em e a e sn Comb Effluent L1874-5 Rep Eom me HHPe Comb Effluent Dup L1874-6 Fa PEE m HE He EF Comb Effluent Low Spk L1874-7 Emakm e e Comb Effluent High SI" L 1874-8 Port 4A L1874-9 Port 4A L1874 9 Rep i en me ea Port4A Dup L 1874-10 EE nmee Me A eEr || Port 4A Low Sp,k L1874-11 TTT ~ o.~.O -- -- HPLt B EE Ea ET Port 4A High Spk L1874-12 *Initials/Date STEP 1: SPE column clean-up (omitting 40% wash) STEP 2: Final volume to 5 mL collected in 15 mL polypropolene tubes STEP 3: LC/MS/MS analysis SARRE oSoo riBAL Initial#Date STEP 4: LC/MS/MS reanalysis, ,~, -~ i be cs 3) Petts ill PROS. Pec FON 5 Initials and date u dcr each step indicates the personnel that performed this step. 55 Method of Analysis for the Detelmination of Perfluorooctane sulfonate (PFOS), Perfluorooctane sullbnylamide (PFOSA), and Perfluorooctanoate (POAA) in Water COMMENTS: Sesgons e 32 160 EH ve Yet Final extractsstor~i, mfiigcratm ~- Ialdals: ~ Date: a July 19, 200114 R E Ey T ------------ CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 snes 3M_MN01538695 11993377..00330099 foe mk tr E Be eee No 3058 Research Drive hE oes AL Phone: 814-272-1039 State College, PA 16801 Fax: 814-231-1580 TETRA A IA TEACH HERE SAMPLE EXTRACTION AND ANALYSIS TRACKING SHEET JR.ueie J is as EXYGEN STUDY NUMBER: L1874 METHOD: ~ PROTOCOL NUMBER: N-~A MATRIX: Water ANALYTES: C4, C6. C7 & C8 Acids C4. C6 & cg sulfonates Client ID Foe oael iTlTl F ISATERTTLS E ELe omens Effluent4 Effluent 4 1 Exygen ID STEP STEP Dilutions STEP Dilutions STEP Reagents./ 1 2 (mL/mL) 3 (mL/mL) 4 Materials Lot # ewnng [|TT cnn ate | L 1874- 13 L1874 13 Rep - ~ -- Methanol C~S SeE mm mamatovstTiers --TTLSY Effluent 4 Dup Effluent 4 Low Spk L 1874-14 L1874-15 = -- Type I Water a Effluent 4 High Spk LISV4-16 ~*'~O'~/t,~ - lnflueut 112 Eree 5%. mee lnfluent 112 ose L1874-17 L1874-17 Rep [1 = TT ei~)~.O~.~O~. | [ Initialo s/Date orm gig E F r e se HrGeee reea Tnfluent 1/2 Low ~pk L 1874-10 - Poms E eee PEE ee Influen~ 1/2 High Spk L1874-20 Trip Blank Trip Blank Low Spike EoF r F F T Eees1 ee s1It F e t elF y t r ee e LB+eT fBevl= s= a r = Ttel || TripBlank Hi~;h Spike L L 874-21 L1874-22 L1874-23 HPLt Type I water NA TEP 1: a ES CE ei GEO I 0, 100 sed200 FE STEP 2: pal, STEP 3: STEP 4: SPE column clean-up (omitting 40% wash) Final voltm~e to 5 mL collected in 15 mL polypt opolene tubes LC/MSIMS analysis LC/MS/MS reanalysis. T ES E AaTS rc is oR n tem 0 *Initials and date under each step indicates the personnel that performed this step. to, I~0 o~a- 200 $$ Method of Analysis for the Determination of Perfluorooctane sulfonate (PFOS), Perfluorooctane sulfonylamide (PFOSA), and Perfluorooctanoate (POAA) in Water couse COMMENTS: Fasumesmtn tine32 initeEHve IY July 19, 200114 CR ouPTAL. sr ie 04 poTEETE ORRENTER ECE CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 swore 3M_MN01538696 11993377..00331100 _-- Protocol No.: None me Method No.: $$ ==Tr Sponsor Exygen en am, ee n 3058 ResearchDrive 3058 Research Drive State College, PA 16801 Phone: 514-272-1009 Phone:814-272-1039 Fax:814-231-1580 nano on ACTCATTOANA PREPARATION OF EXTRACTED CALIBRATION STANDARDS PN or etna Exygen Study No.: rn Se Analytea: A BBoiA nbse Fort. Fort. N~A CA,C5,C6,C7 and C8 Acids; C4~ C6 &C8 Sulfonates Fort. Micropipct Fort. Matrix: Type I Water~ Sample Vol: 40 mL Final Sample Sample Sample Solution Soln. Cone. Volume used Level Solution Reagentst Lot # ID [oaNA ID Description IO tng/mL) /~tL} /~tL/ oom|mperwaer|.1.T -[ - T ./PPt} ID # ** Materials | conmeeo | viewa [Gear] 0106020 Type I Water~ XC022404-0 Methanol [a NA o0w1o0s60o2m0 |nTpyeperIwWisateer~ [oFo01s20e04i-1o0 | w1o0 | o10o0 | a2w00 |a25 |vXoC0w22s404-1 | cCilgsSePE |WaieTel| wisn|mperwae |romeo] 0 | wo| aw | wo[xowssses| oT. | mNAofo0106020 Lomi Type 1 Water~ LFo012o004s-10] NA 0106020 Type I Water" F012004-10 0 10 Joo20n0 [o2e00 |o5o0 foXCn022e404-2 LoTympeiI Wvateer ] wNeA | 10 400 200 100 XC022404-3 [iaNA o01o060m20 | ToyppeerIvWinateer~ |rFo0n12o0n04s-9s| t1o00o | w10o0o| o2w00 | a2s50o|woXCw0s22a40m4-s4 |.| [oNaA To0s1060o20| TiyyppeeItWwaatenr~r[ooFm01o2o00s4-s9| 101000 |o2w00 | a2000 | s5o00o[wXoCo02m2w40m4-s5 [1 NA 0106020 Type I Water~ F0120~--9 100 400 200 1000 XC022404-6 CT1 1 TT 1 1 TT=] wn Initia]sfl')ate: I Vertical arrows in a column indicate identical values. **This m~z~t be a unique numbar~ Use this system: Extracted Calibration Soln ID #: XCMMDDYY-O, 1,2. 3 etc. eeeh egiro oeeS Samples removed from ~ freezer# ~ Time: ~ lnitialsfDate:~fi~Z,q~[ 40 mL of each sample measured using a ~.~.~__~mL graduated cylinder, lnitials/Date:_._~/ ff2j~0~ Rs oe EF After measuring, samples returned to,L~ freezer #~ Time: ~=~ Initials/Date: == Po Samples fortified: Sn mei SPE clean-up (omitting 40% Wash): lnitials~Date: _j~/_.~2~,/~, Initials/Date: .~/~._~.~ 113~ Te Final volume adjusted to 5 mL: Initials/Date: on amor ss Extracts placed in refi'igerator # .~7,--- Initiatsh3ate:_~ /)~]Lq'!0~[ STANDARD EXPIRATION DATE: atiAn Comments: ^This type I water has been filtered through a hypercarb filter SoDom--e -- n $$ Method of Analysis for the Determination of Perfluorooetane sulfonate (PFOS), Perfluorooetane sulfonylanaide (PFOSA), and Pexfluorooctanoate (POAA) in Water Duly 3t9/04 J- July 10, 2001/0 cprposss sreoens ornoe rE ED EEC CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 semen 3M_MN01538697 11993377..00331111 PEE EL kek As ome eR ome oan Mast SapmplseList. ANAT, Masslynx - Sample List Protec:WonMar01 10.37.362008 Wied Sample List: C:\MASSLYNX\FIuorochem.i~IIs.PRO\SarnpleDB\021804AR CG ACSFM.SPL ExEyxyggeennsStTuUoDYyNNoO.. _~ LLBTY_ prPont Page 1 hi Page Position: {21, )1) oat ce en sw J Vial File Name LIMS ID ClientlD SampleDescdption Matdx SampleType Conc (nglL) Conc B ConcC TestlD DF LEE - WEE CEE Lk =: 1 11 021804AR-201 ..... iE - Emam cE CC 2 12 021804AR-202 ..... (i00- - Eom - EEL - - 3 13 021804AR-203 ..... 4 14 021804AR-204 ...... 2 EEE EE BEEEERE 5 15 021804AR-205 ...... El EE EEEEEERER 6 16 021804AR-206 7 17 021804AR-207 .... Ei PEER ..hE EB EERE 8 92 021804AR-208 --- -- g 21 021804AR-20g -- JFREIE E NN: :v Elm EO E wZO:zz: 3o8 10 22 021804AR-210 ...... 11 23 021804AR-211 ...... El FER. rEEE EERE; 12 24 021804AR-212 ...... XC022404-0, 0 ngJL Standard --- Standard 0 .... 0 XC022404-1,25 ng/L Standard -- Standard 25 ..... 0 XC022404-2, 50 ng/L Standard --- Standard 50 ..... 0 XC022404-3, 100 ng/L Standard --- Standard 100 ..... 0 XC022404-4, 250 ng/L Standard -- Standard 250 ..... 0 XC022404-5, 500 ng/L Standard --- Standard 500 ..... 0 XC07.2404-6, 1000 ng/L Standard --- Standard 1000 ...... 0 Methanol Wash -- Blank ......... 0 0106020 Control --- Blank ....... 0 0106020 Spk A, 50 ng/L --- QC 50 ..... 0 0106020 Spk B, 500 ng[L --- QC 500 ..... 0 L1874-1 Spk C, 10000 ng/L, DF=1000 --- QC 10000 ..... 0 1 1 1 1 1 1 1 1 1 1 1 1000 13 25 021804AR-213 .... 14 26 021804AR-214 -- -- F 121t EEEFR. EES . GRRL. Yx EE& I EERE | 15 27 021804AR-215 -- -- PREEENC C HneEmER- = OB - : 16 28 021804AR-216 -- 17 29 021804AR-217 .... OZEBRMC CEERI fe, BC C80 18 12 021804AR-218 ...... JIgEE- - EEE OE OC im 19 30 021804AR-219 .... 20 31 021804AR-220 -- -- oiasme- - dmmE EE EEEERE 2t 32 021804AR-221 -- -- YIgEE: : a. DEC DDE 22 33 021804AR-222 -- -- 23 34 021804AR-223 .... Pik: : unr IEE: iB 24 35 021804AR-224 .... 25 36 021604AR-225 .... Sig: - Were SE: Zi 26 37 021804AR-226 .... 27 38 021804AR-227 .... 21 EEE W IF 3 2215 28 39 021804AR-228 .... ini: Zn FF 3:1? 29 40 021804AR-229 ..... ff EEE EE. B::: 30 41 021804AR-230 .... PIE: BE Tew CE. & CC fF 31 13 021804AR-231 .... 32 42 021804AR-232 .... 33 43 021804AR-233 -- -- IEE HER IEE CC} 34 44 021804AR-234 .... i EER. DER Le If 35 45 021804AR-235 -- -- Piggy - ib... 22. BCC} B 36 46 021804AR-236 -- -- 37 14 021804AR-237 .... T Et I FLE Ray SEEe PCiL x 38 47 021804AR-238 .... 39 48 021804AR-239 .... 40 49 021804AR-240 -- -- Ei E R 8: 2:13 41 50 021804AR-241 -- -- F300: - IL. EE: 2:17 42 51 021804AR-242 -- -- 38 E]EER( EC ECR BI.R : B 8% z3. :2 :11% % 43 52 021804AR-243 -- -- L1874--1 8pk C, 10000 ng/L, DF=100 --- QC 10000 ..... 0 L1874-5 8pk D, 10000 ng/L, DF=100 --- QC L1874-9 Spk E, 10000 ng/L, DF=100 -- QC 10000 10000 ..... 0 ..... 0 L1874-13Spk F, 10000 ng/L, DF=100 -- QC 10000 ..... 0 L1874-17 Spk G, 10000 ng/L, DF=100 -- QC 10000 ..... 0 XC022404-1,25 ng/L Standard --- Standard 25 .... 0 L1874-1, DF=1000 --- Analyte ....... 0 L1874-1 Rap, DF=1000 --- Analyte ...... 0 L1874-2, DF=1000 --- Analyte ....... 0 L1874-1, DF=100 --- Analyte ...... 0 L1874--1 Rap, DF=100 --- Analyte ...... 0 L1874-2, DF=100 --- Analyte ...... 0 L! 874-1, DF=10 -- Analy'ta ...... 0 L1874-1 Rap, DF=10 -- Analyte ....... 0 L1874-2, DF=10 -- Analyte ....... 0 L1874-3, DF=1000 --- QC 10000 ..... 0 L1874-3, DF=100 --- QC 10000 ..... 0 L1874-4, DF=1000 --- QC 100000 ..... 0 XC022404-2, 50 ng/L Standard --- Standard 50 ..... 0 L1874-5 --- Anaiyte ........ 0 L1874-5 Rep -- Analyte ........ 0 L1874-6 --- Analyte --- ..... 0 L1874-7, DF=100 --- QC 10000 ..... 0 L1874-8, DF=1000 --- QC 100000 ..... 0 XC022404-3, 100 ng/L Standard --- Standard 100 ..... 0 L1874-9, DF=100 --- Analyte ........ 0 L1874-9 Rep, DF=100 --- Analyte ........ 0 L1874-10, DF=100 -- Analyte ........ 0 L1874-9, DF=10 -- Analyte ........ 0 L1874-9 Rep, DF=10 -- Analyte ....... 0 L1874-10, DF=10 -- Analyte ........ 0 100 100 100 100 100 1 1000 1000 1000 100 100 100 10 10 10 1000 100 1000 1 1 1 1 100 1000 1 100 100 100 10 l0 10 44 53 021804AR-244 .... L1874-11, DF=100 -- QC 10000 ..... 0 100 S CONTET NT, SUS RE 0e . PROTECTIVE GROERENTERED WN HEMMEPW COTY CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 Pp-- 3M_MN01538698 11993377..00331122 LB sa Lk ea Eee amao. me. MoseSapient Masslynx - Sample List Sample List: C:\MASSLYNX\Fluorochen~icals.PRO\SampleDB\021804AR CG ACSFM.SPL BR SR ops aleee n OAn s Pdnted: Men Mar 01 10:37:35 2004 ~.~ID,IO~ Mowabos MS Method 1 upescisssus 1 C6 8 ACIDS CA 6 8 SULF 2 C6 8 ACIDS C4 6 8 SULF Pogo 3 C6 8 ACIDS CA 6 8 SULF i giEmdinh 4 C6 8 ACIDS CA 6 8 SULF i ogiesnan: 5 C6 8 ACIDS CA 6 8 SULF i giematar 6 C6 8 ACIDS CA 6 8 SULF Gikmnanr 7 C6 8 ACIDS C4 6 8 SULF i{ggiiemvdnea 8 G6 8 ACIDS C4 6 8 SULF 9 C6 8 ACIDS C4 6 8 SULF gnemases 10 C6 8 ACIDS C4 6 8 SULF 11 C6 8 ACIDS C4 6 8 SULF "12 C6 8 ACIDS C4 6 8 SULF SiEsoal 13 C6 8 ACIDS C4 6 8 SULF Siamciii "14 C6 8 ACIDS C4 6 8 SULF gio: t5 C6 8 ACIDS CA 6 8 SULF giemciie 16 C6 8 ACIDS C4 6 8 SULF 17 C6 8 ACIDS C4 6 8 SULF 3I gSrhemiocsihmis 18 C6 8 ACIDS C4 6 8 SULF 3 giemciie 19 C6 8 ACIDS CA 6 8 SULF Semon 20 C6 8 ACIDS C4 6 8 SULF 21 C6 8 ACIDS C4 6 8 SULF 22 C6 8 ACIDS C4 6 8 SULF 2 oaremcnn: 23 C6 8 ACIDS C4 6 8 SULF SiEmoih: 24 C6 8 ACIDS C4 6 8 SULF Siemciie 25 C6 8 ACIDS C4 6 8 SULF gicmciime 26 C6 8 ACIDS CA 6 8 SULF B aiomcaim 27 C6 8 ACIDS CA 6 8 SULF | SifRGii: 28 C6 8 ACIDS C4 6 8 SULF 3 gnemcims 29 C6 8 ACIDS C4 6 8 SULF 30 C6 8 ACIDS C4 6 8 SULF 31 C6 8 ACIDS C4 6 8 SULF gifRdiish 32 C6 8 ACIDS CA O 8 SULF gitRdiish 33 C6 8 ACIDS C4 6 8 SULF 34 C6 8 ACIDS C4 6 8 SULF 3 gremcnny 35 C6 ~ ACIDS C4 6 8 SULF Simian 36 C6 8 ACIDS C4 6 8 SULF ggiimtahnamn:s 37 C6 8 ACIDS C4 6 8 SULF 38 C6 8 ACIDS C4 6 8 SULF 3 Simons: 39 C6 8 ACIDS C4 6 8 SULF 7 gnemonny 40 C6 8 ACIDS C4 6 8 SULF 41 C6 8 ACIDS C4 6 8 SULF i Sgiiteasdntaae 42 C6 8 ACIDS C4 6 8 SULF Sista 43 C6 8 ACIDS CA 6 8 SULF 44 C6 8 ACIDS CZl 6 8 SULF Hic nesM8Toner Wine PIPLC Method MS TuneFile Inj.Volume sh franc 1% ~fbswater ~fbswater mow oem ~fbs water mm am a ~fbs water mm amen ~fbs water mms Amen :fibs water mE Asem :fibs water mae ame 3T~S water mw mem :fibs water .fbs water mow An ~fbs water )fbs water mm am ~lbs water mm nom )fbs water mE nme ~fbs water 3fbs water SE ame 3fbswater mI am ~fbs water Seme ppemn 3fbs water ~fbswater mv pf ~fbs water ~s water mov pm ~fbs water Sit mee fibs water mn pm fibs water mae pm fibs water mune pre fibs water MET UE: ~fbswater fibs water mony pm fibs water ~fbs water mE ame: ~fbs water mE ame: ~fbs water fibswater mne pon fibs water mune pen pfi0s water mos av pfbswater mus nem v pfbswater mus pee pfbswater DIT fmf pf'os water pt~s water mes neem pt~swater mmeS ammeen pt~s water Fluomchems 15 Fluorochems 15 Fluorochems 15 Fluorochems 15 Fluorochems 15 Fluorochems 15 Fluorochems 15 Fluorochems 15 Fluorochems 15 Fluorochems 15 Fluorochems 15 Fluorochems 15 Fluorochema 15 Fluorochems 15 Fluorochems 15 Fluorochems 15 Fluorochems 15 Fluorochems t 5 Fluorochems 15 Fluorochems t5 Fluorochems 15 Fluorochems 15 Fluorochems 15 Fluorochems 15 Fluorochems 15 Fluorocheme t5 Fluorochems 15 Fluorochems 15 Fluorochems 15 Fluorochems 15 Fluorochems 15 Fluorochems 15 Fluorochems 15 Fluorochems 15 Fluorochems 15 Fluorochems 15 Fluorochems 15 Fluorochems 15 Fluerochems 15 Fluorochems 15 Fluorochems 15 Fluorochems 15 Fluorochems 15 pfbs water Fluorochems 15 BEoxgygeenn sStTUoDrYnNoO,.LB Pogez Page 2 Perma) S CONFIDER NCTIaAL SUBIECOT r0 A SPoROTECTIVE ORDER ENTERED I HENNEPIN COUNTY CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 awnctsassn 3M_MN01538699 11993377..00331133 foe = 4 4 4 mo: osx oz oma om ox oa ws osto op vo. BUBLT Mas$1ynx - Sample List ECR Eve Sample List: C:~MASSLYNX\Fluorochemicals.PRQ\SampleDB\021804AR CG ACSFM.SPL Exygen STUDY NO. ~ Printed: Mort Mar0t 10:37:352004 ~ ~!{~1~ eePage 3 [-- Page Position: (1, 2) Vil Fite ME Clio Srp ecision Vial File Name LIMS ID ClientlD Sample Description 4% meas uwenene 45 54 021804AR-245 .... 46 14 021804AR-246 ...... oigmms- Co ommeemes 47 55 021804AR-247 ..... aopsmEeeammiEmcc CGe on 48 56 021804AR-248 ..... L1874-12, DF=1000 XC022404-3, 100 ng/L Standard L1874-13 L1874-13 Rep 49 57 021804AR-249 .... 50 58 021804AR-250 .... o8 EMEC oC URE 51 59 021804AR-251 -- =- BoREBMEC CD Nees 52 15 021804AR-252 .... FEEEER- - fmWERLTT 53 60 021804AR-253 .... 54 61 021804AR-254 .... iEEEE- - HhER 55 62 021804AR-255 ..... 56 63 021804AR-256 ...... FIER EE 57 64 021804AR-257 ...... 3 oEEemEmc CGE 58 65 021804AR-258 ...... Gogmem- - SBE. 59 66 021804AR-259 ...... 60 67 021804AR-260 ..... PSEEEE:- hE 61 68 021804AR-261 ..... L1874-14 L1874-15, DF=100 L1874-16, DF=I000 XC022404-4, 250 ng/L Standard L1874-17, DF=200 L1874-17 Rep, DF=200 L1874-18, DF=200 L1874-17, DF=100 L1874-17 Rep, DF=100 L1874-18, DF=100 L1874-17, DF=10 L1874-17 Rep, DF=10 L1874-18, DF=10 a REEMA CRE 62 69 021804AR-262 ...... 6:3 70 021804AR-263 ..... 64 16 021804AR-264 ...... L1874-19, DF=100 L1874-20, DF=1000 XC022404-5, 500 ng/L Standard 65 92 021804AR-265 ..... 66 71 021804AR-266 ..... on ERAE CT I 67 72 021804AR-267 ..... 8 pam c C 68 73 021804AR-268 ..... 8 DERMED 69 17 021804AR-269 ..... Methanol Wash L1874-21 Gee L1874-22, DF=I00 nEEe L1874-23, DF=1000 BRIaees XC022404-5, 1000 ng/L Standard Ma SapTie Matrix Sample Type Sk --- QC --- Standard oc odme --- Analyte DSoEmeR -- Analyte Coo) Gore Cone Tet OF Conc(nglL) Conc B ConcC TestlD DF mm o- - 5 om 100000 ..... 0 100 ..... 0 0 o-oo ....... 0 0oC ZZoo Ioib dod ....... 0 1000 1 1 1 --- Analyte ....... 0 --- QC 10000 ..... 0 TE Be = I 8 0% -- QC 100000 ..... 0 Ewe ZZ ff --- Standard 250 ..... 0 CF Co: fk --- Analyte Analyte ....... 0 ...... 0 Eo: ig -- Analyte ....... 0 -- Analyte ....... 0 DEE: zoo o --- Analyte ......... 0 Dome Zoom --- Analyte ....... 0 cc f48 :- : : i -- Analyte ....... 0 --- Analyte ........ 0 EER oD Ii oR -- Analyte ....... 0 1 100 1000 1 200 200 200 100 100 100 10 10 10 CT fee 0 ZZ 8 --- QC 100 O0 ..... 0 --- QC 100000 ..... 0 --- Standard 500 ..... 0 100 1000 1 --- Blank ....... 0 --- Analyte ........ 0 IO we II ie --- QC 10000 ..... 0 DOE mm oI --- QC 100000 ..... 0 Bee WZ 2 0 --- Standard 1000 ..... 0 1 1 100 1000 1 SCOTNRFIICDTENCTOIUALR.T:SUNOB.JE3C7T.TO10A ePR6O0T3ECTIVE ORDER ENTERED IN HENNEPIN COUNTY CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 wmorsaeren 3M_MN01538700 11993377..00331144 feet tra ae asa Mi assy SC ampleit RTC CT pr Co UN Masslynx - Sample List Sample List: C:\MASSLYNX\Fluorochamicals.PRO\SampleDB\021804AR CG ACSFIk,I.SPL Printed: Mon Mar 01 10:37:35 2004 ~!~)' II~ ExyRen STUDY NO, ~ J. MS Method HPLC Method MS TuneFile Inj.Volume 3 ggyytmmamnmneyy mmmo ammmomo 45 C6 8 ACIDS C4 6 8 SULF gianum 2m End 46 C6 8, ACIDS CA 6 8 SULF gitmdniy 2m EY 47 C6 8, ACIDS C4 6 8 SULF gitedniy 2m EE 411 C6 8 ACIDS C4 6 8 SULF giteanty 2 EE 49 C6 8 ACIDS C4 6 8 SULF f gifRanty 2x mE 50 C6 8 ACIDS C4 6 8 SULF i gitRdnly Bx BEY 51 C6 8 ACIDS C4 6 8 SULF gitndniy Ex EEL 52 C6 8 ACIDS CA 6 8 SULF andi Ex Eel 53 C6 8 ACIDS C4 6 8 SULF 54 C6 8 ACIDS (34 6 8 SULF anal 2m El 55 C6 8 ACIDS C4 6 8 SULF aititnm 2m mmm 56 C6 8 ACIDS CA 6 8 SULF ~fbswater :)fbs water ~fbs water ~fbs water 3fbs water 3~s water 3fbs water :~fbs water 3fbs water :)f~s water fis water =f'os water Fluorochems 15 Fluorochems 15 Fluorochems 15 Fluorochems 15 Ftuorocheme 15 Fluorochems 15 Fluorochems t5 Fluorochems 15 Fluorochems 15 Fluorochems !5 Fluorochems 15 Fluorochems 15 57 C6 8 ACIDS C4 6 8 SULF 5B C6 8 ACIDS C4 6 8 SULF 2 SBietpmEannNiEy 5g C6 8 ACIDS C4 6 8 SULF sivmaiay 60 C6 8 ACIDS CA 6 8 SULF 61 C6 8 ACIDS CA 6 8 SULF SSiitginaainii 62 C6 8 ACIDS (34 6 8 SULF l 63 C6 8 ACIDS C4 6 8 SULF 64 C6 8 ACIDS C4 6 8 SULF gn 65 C6 8 ACIDS CA 6 8 SULF aRail 66 C6 8 ACIDS C4 6 8 SULF Gishauly 67 C6 8 ACIDS CA 6 8 SULF i Sishdnl 68 C6 8 ACIDS C4 6 8 SULF fiswater fis water 2mxn fis water 2m ~fbswater fis water 2EE fibs water fie water fis water pf'os water 2m pfbs water 2 pfbswater 2 pfbs water Fluorochems 15 Fluorochems 15 E EESRE Fluorochems 15 Gumi Fluorochems 15 Fluorochems 15 UEnefl Fluorochems 15 Fluorochems 15 Fluorochems 15 Fluorochems 15 met Fluorochems 15 Emm Fluorochems 15 EE Fluorochems 15 69 C6 I] ACIDS C4 6 8 SULF pfbs water Fluorochems 15 aos oa romEsx Page 4 Page Position: (2, 2) SCONDRE RBT 104 SROTECTIE CROSR ENTERED HENIGPN COUNTY CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 swmorse 3M_MN01538701 11993377..00331155 LC/MS/MS SYSTEM AND OPERATING CONDITIONS ` LC/MS/MS SYSTEM AND OPERATING CONDITIONS SponsorProtoss!No.NA Sponsor Protocol No: NA EExxvyzgeenn SStuuddyy NNoo:: LL1I8S7?4 " IInnssttrruummeenntt:: `MMiiccrroommaassss QQuuaattttrroo UUllttiimmaa ((LLCC//MMSS//MMSS UUnniitt ##66)) B Comput: COMPAQ Profesional Workstation AP200 Computer: COMPAQ Professional Workstation AP200 Soars Microsoft Windows NT: Version 4 Bid 1381 Servi Pack Software: Microsoft Windows NT: Version 4 Build 1381: Service Pack 5 Micromac Limes Ma3.lBudy004 Micromass Limited: MassLynx 3.4 Build 004 " HPLC Equipment Hewlt Packard (1) Series 1100 HPLC Equipment: Hewlett Packard (HP) Series 1100 I Bin ap ir Vacuum Degen I-IP Bin Pump I-IP Vacuum Degasser " 1 Awosmier HE Cota Oven HP Autosampler HP Column Oven HPLCColmm: Genesis C4, Sma 21 mic x4 Baye D: T4A) HPLC Column: Genesis C-8, 5 cm x 2.1 mm i.d. x 4 ~t (Exygen ID: 74A) A ONESCHROVATOGRAPITY: prt No PR9626) ii (JONESCHROMATOGRAPHY: Part No. FK5962E) MNoobwi PPhaacsee()4:: M2emthManAem!monium Ace n Tye | War i 4 At Mobile Phase (A) : Mobile Phase (B) : 2 mM Ammonium Acetate in Type I Water Methanol " Anat KE5F0axr3rpa8egnneRnR6ieRs1eahsa6er2ac1Dhr1iv0e,5StFeAXC.o(l1e9g25P1A-115688001 He Analyst: Karen Risha Exygen Research 3058 Research Drive, State College, PA 16801 Phone: (814) 272-1039 FAX: (814) 231-1580 0 NOTE: The next 3 pages are computer generated printouts from NOTE: Tthheemnaesxstl3ynpxagseosftawraerceopmrpogurtearm.genThereatpeadgepsricnotnotuatisnftrhoem the masslynx software program. The pages contain the 0 iinnssttrruummeenntt sseettttiinnggss uusseedd ffoorr tthhee aannaallyyssiiss ooff tthhiiss ddaattaa sseett.. ' AAllll HHaannddwwrirtittteenn PPeeaakk IIDD'ss bbyy:: = ili! " " ` CONFIDE-NSTUIBJAECLT TO APROTECTIVE ORDER ENTERED IN CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT. NG. 27-0110.8862 HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00331166 su_wmoresso2 3M MN01538702 " 4 SSccaannnniinngg MMaetthhoodd RReeppoorrtt MMLeeattshhtooddM::odified: CMC:o:n\\MMAJSaASnSLY2SN0LX\1YF5NL:U3XO2:R\3OF6CHLE2UM0I0CC3RALOS..CPPHRROEO\VMAACCIQQCUUDDABB\L\CCSS6 88 AACCIIDDSS CC44 66 88 SSUULLEF. a Last Modified: Mon Jan 20 15:32:38 2003 Printed: Mon Max 01 10:37:40 2004 Printed: Mon Mar 01 10:37:40 2004 (5! 4 SSoollvveenntt DDeellaayy (( mmiinnse)) :: 00..0000 AAFnnuaanllcootggionCChhaa: nnnn1eell 4 M:: {UUnnouufsseedd5 Mass Pairs ( ESP- ) . Function : 1 MRM of 5 Mass Pairs ( ESP- ) Inter Channel Delay ( Secs ) 0.03 WenSSSSIatptpnaaaatrnrneetrTi(( nCTTehiDibmanaaenell(nttweoo((ilnnssnMMiDiene)n))slsa:+)y) ::( Secs ) : 0000....00000003 01.20.000 RERenepdpeeaaTttissmCeha:: n(neMlinsPaz} en: t Daughter 1D11u2e.l0l0 (Sess) Coll Energy (eV) Channel Parent Daughter Dwell (Secs) Coll Energy (eV) ~I~''~D'~~'O" t~ Cone (V) Cone ( V ) " 21 1 223991993...000000 929969.9.00.0000 000...222000 04100 24009 ` 3233 333191919393...000000000 82830066..9300..000000 0000....22220000 33i1s500 25n5OO 5 4 5 441195393..0000000 939569.9.00.0000 000..222000 0I0 40 I0 3O a Praaggee 11 . " " a 1 a `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACPOPURRROOTT,TEECNCTOT,IIVV2EE7-OOCRRV-DD1EE0RR.2E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00331177 3M_MNO1538703 3M MN01538703 jo veehod Report Method Report MMTaeattrehhooWddodFFiiillfeei::ed: 4 printer Last Modified: = Printed: fl H#P9I1I10000 1LCc Pruummpp IInniittiiaall CCoonnddiittiioonnss Sovents a Solvents A% :' 5BCc%%r 4 SFFhlloooDwrw%T((immmlle//nmiinnni))ne) OiVMMSvaiatnenxxonppPPprTTrrreieeeesmsmsseespssuuuuerrrrre(eee.amtiun((((srbbbb)eaaaasrrrL))))ett (vc) uo Oven Oven TTTeeemrmpppeeerrraaarttiuurrrsee RRLieigfghtht(t((C6)C)) HP1300 1c Pump Gradient Timetable HPII00 LC Pump Gradient Timetable " The gradiont Tinctable containo 8 The Tine gradient a Timetable a contains 8 Time A% B% 220.l.000000 99000...000 1ii0000..000 ` sal55599i :1...0055500000 1i100a50..9.0000 11130990000000::...000000 . 211440..305000 9s00l..o00 00 100.0 i0.0 20.00 90.0 i0.0 Psaaggee 1 NCC1o:Vn\dAMeASyS,SELWYaNrXe\nFPLLU0I1OO,RROO2CC0HE0EN4MIICC1AA0LL:SS1.9P:RR0OO0A\ACCOQTUDDBBA\ppfbbas wwaatteerr MMoonnddaayy,, WMaazrcchh 0011,, 22000044 1100::1397::0408 . Monday, March 01, 2004 i0:37:48 ~ ~ LE~)~C1L~-- 5900..00 a i000...000 200000...30230000 04052000o0..00 a 35.0 35.0 entries which are : entries eowhich are : on Flow Pressure C% D% Flow Pressure o00..o00 o00..l00e 000...333000000 444000000 0.0 0.0 0.300 400 x oo 2300 00 0.0 0.0 0.300 400 0 oi 2360 0 0.0 0.0 0.300 400 ol 0 aa i 0.0 0.0 0.300 400 0.0 0.0 0.300 400 oe a pe 0 0.0 0.0 0.300 400 4 FPO HPII00 L5Cc PPuummp EExxtteerrnnaall Evveenntt TTiimmeettaabbllee he Timetable contains entries which are + u The mTTTiiiismmmteeeatable coCCnootllauuimmBnnnes sS6uwiietsncethhriCCeoosnnEttwaaohccittc:lh areCCo:onSntitaaecctt2a Iniooa00tl..oiod00oas05l oottOOOofffeeefff StSoOOOffneeff Se&SOOOefffeefff " 12n1i1.0..39i000 oOOoeffeff SiSOOeffteff SStOOinfef 12.00 Off Off Off CCoonmtooOtafeeafcctt3d sto&OOOtfffrefff SiOOfnef CCoonntSoOttrafaeefcctt4 oSoOOOrttffftetfff SOfif Off HAPPIII10000 AAuuttoossaammpplleerr IInniittiiaall CCoonnddiittiioonnss BEDDErljrlaeeaacwcwttSrsppoSSeesp~eeeieddet~ddion((s~3I(//tnmm)iinn)) 22i20000002...0000 = GfDSIIertnnotaojSpepweEcaTTtcPiiiionmooseennitViVi(ooonmlnliiununmasm())eem(m(#)5l1)) 212i5s0500..1.0000000 Vial Number 99 a 1 ,aI `CHEOGNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIJDJIEAESCCTLTTRTITCOOT AACPOPRUROROTTT.EECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR.2E6E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00331188 SW_MNo1S38704 3M MN01538704 " PE --. Tuning Method Report MMeetthhoodd:: C4:\\MMAASSSSLLIYONKX\\FFLLUUOORROOCCKHRENMLICCAALLSS..PPRROO\VAACCQQUUDDBB\\EFLLUUOCRROOCCHHEEMNSS Wu EPrriinntceedd: MHoonn yMaarr 0011 1100::3377::5599 22000044 VER TTR ,,! ' | Dlichierfol BTOE1 To | J h SEE b SEY A ah fh i SARA . WE ia ] Cig he a osTP ana3l S gaaRras}] . FoTi ENE e Aa DawT1g99.00 Re ea " Dau 499.00 soumce ( gsv-) se ax Aoalyses 4 cCCSoaOpnUpieRiiClEliaaryy( ESP- ) Set Rdbk 3F3..0000r)-22..0933 Analyser L1oM1t RRReeess 111 owAHTCHpoeeee ennnxeraaatgppuoood rttlesee 1211 ooo2000..koo00 -20 CHETEIoMnEnentntnnrRereaierassnsgnyciytee1n11 STHSeoesSuxoraiEcpveoaltetBilooo2nc:kk tTTeeemmmppp... Desolvation Temp. 130% 120%0 0.0 I00 i00 300 299 CELEoxMnoielthhlReeeissssio272n - wHITMiEenlnReeierrpsgolyyi2e22r Multiplier JR -- ax Gas Pow AGAPonnraaaetlsbyysessuleretrersvVaaccuuuumm Rdbk orOFeFes GCScaoeosnneeotFvlGGaaoasswtsion Gas Cell 3.0e-3 Desolvation rage 1 Page 1 { Sot mane S11he4..tt00 Rdbk 3-112F2E.4%0.0 ow 12 bf2111i54e.0o0 14 16 2p[1.hE40)R.0 65O -648 ra Rdbk f11i22t90.99 749.8 - : ,.Ibl " `CH~,i~EOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACOPPURRROOTTT,EECNCTOT.IIVV2E7E-OOCVRR-DD1EE0RR28EE8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00331199 _MNO1S38T05 3M MN01538705 . QquuaaanttiitfT yy CcaultiibbrraaR tviioonn RRoeppeorrsthisoom, xe pacerca/a0/as, ansiyssix.nisna [ Page 1 W Study No.:LI874, Set No.:021804AR, Ext.Date:02/18/04, Analyst:K.Risha Calibration: 7r\Data\LCHENGE Hass ym PiuorochROeNCnuEivecDBa\OZlLAa04.AR Calibration: P : \Data\LCMSMS6\Masslynx\Fluorochemicals. PRO\CurveDB\021804AR CmEmRT FMaams Rbe TIataRs NTies Last modified: Tue Mar O~ 12:21:48 2004 CG CG AGS 5 ACSFM Printed: Tue Mar 02 14:05:18 2004 o [Coromma:pcormpa Compound 1 name: C6 Acid PFHA (Goof Dcetercminatoion: 0.988257 Coefficient of Determination: 0.988257 Coloration ure 29818. x 245.64 | Calibration curve: 258.118 * x + 3246.64 Response ype Extomal S10. res i Response type: External Std, Area 0 Coreen GgExe,Waging: isAi vrs Noro Curve type: Linear, Origin: Exclude, Weighting: I/x, Axis trans: None | 22.6622e55- a a 1. ||| || | ,| | | Rospon / | a * | Response- 1 | x | i [I %b oho wooo S060 id - | a| | | | Oe F ter 0 0.0 200.0 400.0 600.0 800.0 1000.0 a Exon Research, 3056 Resaasch Drive, tate Coilege, A 16801 E~gen Research, 3058 Research Drive, State College, PA 16801 CCHOEONNNFNIFEDIDPEEINNNTTICIAAOLLUN-- TSSUYUBBDJJIEESCCTTTRTITCOOTAAGPOPRUROROTTET.CENTCIOTVIVE2E7O-O0RR1D-D1EE0RR.0E8E8NN6TT2EERREEDDIINN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 Sw umotsseros 3M MN01538706 11993377..00332200 M quantity caltbeation Report nt Quantify Calibration Report o OTHERIT i, srroumersinsn, smatprnsive Study No.=LI874, Set No.=021804AR, Ext.Date=02/18/04, Analyst:K.Risha Page 2 Cxttbrasion: 7:\OReVEHINSE Wat yna\Piuosochen cals. PRO\GHveDEAOTAOARR CO ACEH Calibration= P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\CurveDS\021804AR CG ACSFM priv gh Last modified: Tue Mar 02 12:21:48 2004 , EER mE EESRE Printed: Tue Mar 02 14:05:18 2004 o [Gmonizrane:caraaion Compound 2 name: C8 Acid PFOA ocho Dasma 0992061 Coefficient of Determination: 0.992051 Cortonnv TYchTr3e83 Calibration curve: 271.048 * x + 7136.83 Romponesspe: ral 6Ares ' Response type: External Std, Area [CCuurrvveetytyppee:: LLiinneeaarr,, OOrriiggiinn:: EExxcclluuddee,, W Weeigighhttiinngg:: 1l//xx,, AAxxiiss ttrraannss:: NNoonnee | 22.7790es5- .b a a . . Response ,.,| Response ' | - "| } LL % "Ii | 0 0.0 Te a ah 200.0 400.0 600.0 800.0 u Seren Reseach, 305 Reseach Drive, State College. PA 16801 Exygen Research, 3058 Research Drive, Stake College, PA 16801 ,m GCFOEONAFNNIEDFREINITCDIAOLUE-N-NTSSUYUTBBDJJIIEESCCATTTRITTC0OTAPACROPOURTROETTCENTCGIT.IVV2EE7OOGRuRnDDiEEoRR26EE8NN0TT3EERREEDD IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00332211 | | et | 1000.0 sw_orsso707 3M MN01538707 M W QQuuaannttiitfyyR Ccaalliibbrraattiioonn RRReeTppoorrtti0uan, Ext.Date:02/10/04,Analyst.nisha sPaaggee 33 W TCELCSHaaaatMlrsluRititdTbbyErrmnRaaoNaettdosiii.toof=nniLi=:eIed8s=74,TPTPRuo:res\SDe\ItMtaaatDrrNao\aD.L00=25Ct0M2S11aG1M228\=0S02564L11\EA=1MOR44a,88sMsl2N1S00Ey00NxnE44tx.\\DFaaltuseo=rs0o2cl/h1ey8m/in0cc4aea,lls\s.A.FnPFaRRllOOy\\usCCtuUo=rEKvrv.eVoRDaiBDcs\\h00ha2211e8800n44KAsRR C0 CG ACS ACSFM Printed= Tue Mar 02 14:05:18 2004 (C([CCaGoloobmeCarftpfaihctooiiaueonnnntdmtcoo3uffvrpnDDvaaeeemm:toteere0:r:mmG6uiCi1inn45aaSnSt1oiiounnndl:f:oan00isa.8-9t65e89598P2.2F555B4S44S62 {CCR[uRaeerlsisbpeprooatnnytisspoeeen:ttycyLpupioernv::eeaEE:rxx,1tte0Oar.rm6niag1ali5ln1:SStt*Edx.,xcAAl+ruree-d6aea5,.5W4ei6g2hting: x, Ax trans: Nore +0008 Curve type: Linear, Origin: Exclude, Weighting: l/x, Axis trans: None . 1.09e4- ,`| ,`| ,! || || || { | ,i 0 a Response: x . Response- 4 . . | ' | assi 000 a abo ho 1000ot " | #4 * ! -65.5 .................................... , .... , ng/L 0.0 200.0 400.0 600.0 800.0 1000.0 a Sxygen Research, 3058 esearch Drive, State College, PA 16801 Exygen Research, 3058 Research Drive, State College, PA 16801 - `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NTSSTUYUBBIDJJIAEESCCTLTTRITTCOOT AACOPPURRROOTT.TEECNCTGT.IIVV2EE7-OOGRRu-DD1EE0RR.2E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 au_mnorsasTos 3M MN01538708 11993377..00332222 " uP QguuaannttaitfI yy CCaalliibE brraattiioonn RRReepphoorrett em, ext Date:02/10/04,Asalystix. isha PPaaggee 4 Study No.=LI874, Set No.=021804AR, Ext.Date:02/18/04, Analyst:K.Risha CSCaaalnlitibbrrmaaottdiiioofnni::ed:P:up\=mD\aDtHaeat\raL\CL0H3CSMMS1SM3E1S\361M\1aM4sa8sssily20ym0nx4x\\FFlluuoorroocchheenmiiccaallss..PPRROO\CCHuErVveeDDBB\\O022L1080044AARR CO CG ACS ACSFM . Last modified: PPrriinntteedd:= `TTTuuueee MMMaaarrr 000222 111424:==200155==:411888 222000000444 yu C[(CEoomoempfpcooeunnutdnog4f nnDaemteaer:mCCimnB6aStSuiueoflnfnona0:.at9tee85PP9FF0H8SS ReCC(saopleiCboffrniacstiaeioenntlycocupufrerDvb:veee:E:t4exr45rt5m.a.0mai0na33al00toS7i7otn*,:nxA0++r.9e811a115559..02281155 W (CRuersvpeotnyspee:tyipnec:aEr,xteOrrnigailnS: tEdx,cAlruedae, Weighting: 1x, Avs trans: Nene ,Iii 48004 Curve type: Linear, Origin: Exclude, Weighting: l/x, Axis trans: None x 4.80e4- a" | || . X . || ' | ` | | | [l | N || | Respons Response- `I,| | "| 1) ho wo abo " 0 " 0.0 200.0 400.0 600.0 BEexyyggeenn RReesseeaarzcchh,, 33005388 RReessesaarzcchh DDrriivvee,, SSttaattee CCoolllleeggee,, PPAA 1166880011 u `CHCEOONNNNFFEIIDPDEIENNNTTCIIAOALLUN-- TSSUUYBBDJJIEESCCTTTRITTCOOT AACOPPURRROOTTT,EECNCTOT.IIVV27EE-OOCVRR-DD1EE0RR28EE8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00332233 abo 800.0 10id8"n /L 1000.0 _MNO1S38709 3M MN01538709 W QQuuaannttS iiHfteyy.cCCTaaill0iiTbbArr,aattiiSoeonfnNRReeeppiooGrrItti00AR, Ext.Dater02/13/04, AnalyatiK.Rishe rage s Page 5 a CCrCLSaaaatitslsuititdnbbyrrmmaaaoNottdoiiii.soof:ininLe0=e:Idd8%::74B,DTPT\uuu:Daee\SaDeMdatataatrarNra\o\.LL000:32C3C0MH2S1211M3a2S81i:SE0302643s1\MA1i:MaR4d4as,8s8sssl2L200E0y000xnyk44tx.m\DFaeltue\o:r0Po2c/ih1e8um/i0oc4a,rlsoA.PnPcRaROlOhNy\CBCeutur:rmvKva.eiDRDBiBc\s\Oh0aZa2I1lS800s44AA.RR CCGG AACCSFSM Printed: Tue Mar 02 14:05:18 2004 4 [Compounds name Casuiortapros Compound 5 name: C8 Sulfonate PFOS oafofDiotercminaitioon:09n94t708 Coefficient of Determination: 0.994708 ibraon curve: 3200x2+2 91.5162 3alibration curve: 32.0022 * x + 31.5152 Response po: ExamalSt Ares Response type: External Std, Area " [Cpurrnvaettiyppsei: LLiinneeaarr,, OOrriiggiinn:: EExxcclluuddee,, W Weiegighthitinngg:: 1l//xx,,AAxxiissttrraannss:: NNoonnee ||| asses, . 3.35e4- X ` | ' . ' 1 | ` || ReRsesppoonnse- * ,| | " 0OTTra en wwaon a edbo" a acho . 0.0 200.0 400.0 600.0 Sxygen Research, 1058 Rasessch Drive, State College, PA 16601 800.0 Ex~rgen Research, 3058 Research Drive, State College, PA 16801 - `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEEASCCTLTTRTITCOOT AACOPPURRROOTT.TEECNCTOT.IIVV2EE7-OOCRR\-DD1EE0RR-2E6E3NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00332244 | | wooddt 8 1000.0 _morsseTio 3M MN01538710 . M oS Qquuaannttiitfyy Ssaaumnppilee sRaeTppRoorrNtseoateoian, mat.Dater0a/18/04, Anaiystix.nisha [IPage 1 onLSE SSautassume~pdplylE meeoNdoLLi.iifss=,ittLe=:Id8=74P,TpaPiu=\oe\SGeDeahMtattaatarrNa\Lo\L.L60UC=25CHB0MS2S1dAH1Ma2S8v=SE0o064n7\WA=Maa0R0gag0,0ssesbl2yy0Eymom0xnakc4tx\.\FPDFlualutouoeror=oro0occ2chh/ehe1nen8tmi/cic0aca4lal,sls.s.A.PnPPRaRROlOO\y\\NsSSRtaaE~mmAKppD.lLRRe\aiDGDsBoEh\rNa0GG2rE1eI8vB0e04,AARNREDCCEOGSAAC6C3SE2FC1M04 MLTeaatsehtoedmm=osedaitftiieeda=: Non Feb 65 o7io0ris 00k on P=\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\MethDB\CotGrove Mon Feb 02 07:04=42 2004 NPDES 012104 Job Code= ~$ ~ , Pproiinntceeda=: TTuuee MMaazr 0022 1144:=0055=:2222 22000044 Rin# Zr sume: cas00200 i.i NTTaeemxxett==: 021804AR-201 1. co noid orn _ I: C6 Acid PFHA ` |XXCC002222440044--00,, 00 nngg//LL SSttaannddaarrdd 21804AR 201 Sm (hn, 20) MofRLGChIaM MnnSoIlMSE5- 021804AR-201 Sm (Mn, 2x3) " 100 Le 1 (oi~~ | y MT ~ \ ,i 885.500 1"4a444-~ 0011--MMaarr--22000044 1100::5544::117 LClMS/MS #6 MRM of 5 Chan33n11e33l>s> E22S669-9) 11..44008e44, ~ Area \ Time| ". L ........20.0... 2.00 , ....4.,00.... 4.00 , ....66..0,000.... , ...8..0, 0.... 8.00 , ...1.100..,0000.... , ....1122.,00T00ime | 2 ct acta pron _ 2:C8 Acid PFOA a X1XCC002222440044--00,, 00 nngg//LL SSttaannddaarrdd 218044 201 Sm (hin, 2) MRM of Ghana E5- 021804AR-201 Sm (Mn, 2x3) . fw Essys ~io"saeaeead 1( 8.96 6237-~ 0011--MMaarr--22000044 1100::5544:1:1: 7 LLCC//MMSS/IMMSS #6 MRM of 5 Channels ES413 > 369 4.23e4 _.~_~~ Area ,ii . | 256 abo --s--w--ab 10 om 2.00 4.00 6.00 8.00 10.00 Time 12.00 Ne p-- _ : C4 Sulfonate PFBS [XC022404.0, 0 ngiL Standard TT oiMara0010:584:17 XC022404-0, 0 nglh Standard - 01-Mar-2004 10:54:17 LLCC/IMMSS/IMMSS #6 o21e04R201 $m (4, 2:0) zy JSC5| 021804AR-201 Sm (Mn, 2x3) |1" 00 TH 7.34 aT[i%4 10s," 1.6263) MRM of 5 Channels ES- 9.2394.488 1111..6600 299 > 9999) 1.62e3 ors rez 2077085 |astem op ws NEA er AWA M IPRS ASR SK SR \ 0.74 1"622 1 3.7~4 4.51~ ~4.82~ 5/7.6 6.~3 8. ~ \7/67, i E -- ........ , .... ~ .... ~ .... , .... ~ ~ .... ~ ,, , ~ .... ~ , , , i .... ~Time ` 0% iH ab 55 Wo 0 i| 2.00 4.00 8.00 8.00 10.00 12.00 ",| Seven Research, 3058 Reseaceh Drive, State College, TA 16803 Exygen Research, 3058 Research Drive, State College, PA 16801 a. `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NTSSTUYUBBIDJJIAEESCCTLTTRITTCOOT AACOPPURRROOTT.TEECNCTGT.IIVV2EE7-OOGRRu-DD1EE0RR.2E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 a_mNorsssirt 3M MN01538711 11993377..00332255 4 QqSuuuaaennyttiiftWyby.CssAaaEsmSgpIllAee. RReeSppGooNrrttWo.:021804A%, Ext.Date:02/10/04, Aaalystix.Risha PPaaggee 22 LSSSaaatsmmutppdllyemeoNdoLL.iiifss:ittL:e:1d8:743,TP:o:\s\SDDeaWattateraN\o\L.L0CC3H:M0SS12MM31SS18E600\\47WMA1aRe0s,s0ssil3yy0Emn0xxx4t\\.TFDllauutooerr:oo0cc2hh/ee1mm8ii/cc0aa4l,lss..AnPPaRRlOOy\\sSStaa:mEKpp.lLReAiDDsBBh\\a0O2Z1I860044AARR CO CG ACTH ACSFM a MTLeLLeoaaat~nsssnhtttoocdmommn=toooaddd:iiifftiiseeeddd::: MTPiou=\ne\oDaMaFtatearab\\LL00C23CHMES10NM27SS:166007\0M=1Ma04as03ss2a1200y00ny44x\aFluEor\ochFemLiccaaullsso.PPRRrOOV\HoMSeEtcEhDDBhBA\CCeOoLtGaGXrootvvee Mon Feb 02 07=04:42 2004 NPDES NPDES 017104 012104 bJorbiCnodee= mae war 02 14:05:22 2004 Printed= Tue Mar 02 14:05:22 2004 ws A oNsaammmee= 0z100432-201 021804AR-201 T4:extc=s sutfonate seus 4 4X[:XCCC0062222S44u00l44f-o00n,,a00tenngPglhFHSSSttaannddaarrdd 1021804AR 201 Sm (Mn, 263) |021804AR-201 Sm (Mn, 2x3) 0011--MMaarr--22L00C00M44S11I00::M58S44::#14767 MRM MRM of of 5L1CCC7hh/5aMa.nnS3nne9/elM5lss.SEE8SS#-0-6 203 ',Ii! won hvarvepo Vo ` 2E 00EE 400 E 500 500 .................... ~ .... , .... ~ .... , .... e1r 00 rr20i0te , .... , .... ~ .... ,Time 2.00 4.00 6.00 8.00 10.00 12.00 5: 5: [cC8oXsSCuull0tfoo2nnaa2ttneeg4lpPL0rFOoS4Ssta0nd,ar0d 01-Mar-2004 10:54:7 XC022404-0, 0 ng/h Standard 021804AR-201 Sm (Mn, 2x3) 0M1R-MAaorf-25LL0CC0ohl4aMMn1nSSe0IMlM:5sSS4E:1#S76 ar021804AR-201 Sm (Mn, 2x3) MRM Hn Te of 5 Channels ES- ' %i%" 500mm, 178arnKon118 48I2S51R5oomp 1704B0e0pmSUR \ 012 2% 0.12 3.59 2 ,5.155 1(i/~. 8235.5 6.55 7.,42~ 915971 a W/ A 9~.1.59..7~110;42. 11.10499>991.49e3 SN ..... , , , , ,, , , , , , , , .... , , , , , , .... , .... , , .... ,Time LTT 400 560 800 F000 200 2.00 4.00 6.00 8.00 10.00 12.00 ' ,"j Sxygen Research, 3050 Resossch Drive, State College, TA 16001 Exygen Research, 3058 Research Drive, State College, PA 16801 . `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACOPPURRROOTT,TEECNCTOT.IIVV2E7E-OOCVRR-DD1EE0RR28EE8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00332266 _MNotS38T12 3M MN01538712 . quantity Semple Repose res Quantify Sample Report 0 SL ET asvun, senotestsiaet, ripen ise Study No.:LI874, Set No.=021804AR, Ext. Date:02/18/04, Analyst:K.Risha Page 3 Sample List. De\beteVLCHISE\Wassyue\Piuorochenicis. PRO\SAmpLOSEAGZSG4RR CO AGS Sample List: P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\SampleDB\021804AR CG ACSFM EE a Toma ea os Last modified: Tue Mar 02 12:07:00 2004 Ne eetntd hotsiyns\FitoroPcRhOeNnhIiBe\Caorldrsov.e NPDES 013104 li Method: P:\Data\LC~ISMS6\Massly~x\Fluorochemicals. PRO\MethDB\CotGrove NPDES 012104 atta mores Sr oreot ren Sion LaSt modified: Mon Feb 02 07:04=42 2004 a Job Code: " PPrriinntteedd:: TTuuee MMaarr 0022 1144::0055::2222 22000044 yen emseano Name= 021804AR-202 J Text: i: C6 Acid PFHA LP216044 202 5m (i, 26) " XXCC002222440044--11,, 2255 nngg/lLL SSttaannddaarrdd 021804AR-202 Sm (Mn, 2x3) | i"ora8.48 9138~ 0011--MMaarr--22000044 1111::1155::5577 LLCC//MMSS//MMSS##66 MRMof 5 Grams 5. MRM of 5 Channels ESper 313 > 269 5.1404 5.14e4 -Area [a1001 premA eJrs) Tine ........ , .... , .... , .... , .... , .... , .... , .... , .... , .... , .... ,Time ' pr) i 50 aw ooo Ha 2.00 4.00 6.00 8.00 10.00 12.00 2: ca seid pron ) 4 2X[:XCCC0082222A44c00i44d--11P,,F22O55Annggi/hl SSttaannddaarrdd ` o"2ts04ar202 5m i, 2) aTM MRMof 5GranpnrlTsieE5d. 021804AR-202 Sm (Mn, 2x3) 0011--MMaarr.-22000044 1111::1155::55~7 LLCC//MMSS//MMSS ##~6 8.98 MRM of 5 Channels ES-/ 413 > 369/ 8.99e4] % ~Tiomoer of: re . im i Sa oa wo ....... 3+ ct suitonsse ors 3:C4 Sulfonate PFBS _ metEr e A eper THT i ''' " '1'oio '"'"'12.oo [XxCC002222440044--11,, 2255 nngg//LL SSttaannddardd " |002211880044AARR--220022 Smm ((MMnn,, 2x33)) PL218i EaS pra, sPeoed 10%01 01--MMaarr--22000044 1111::1155::557 LCCI/MMS//MMSS #6 MMRRMM ooff 5 CChhaannnneellss EESS-- 8.13 299 > 99 328- 2.02e3 ~W~,~ Area A NS n/ 0 || Fd V e AAe mr Are rr pre \i ................ , .... , .... , .... , ........ , .... ,-.... , .... ,Time . 30 i 5% a ioe TH 2.00 4.00 6.00 8.00 10.00 12.00 I| "i sxrgon Rensach, 3058 Reseach Drive, State College, BA 16001 Exygen Research, 3058 Research Drive, State College, PA 16801 uil CONFIDE-NSTUIBJAECLT TO APROTECTIVE ORDER ENTERED IN CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT. NG. 27-0110.8862 HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 s3Mu_wMmNo0r1e5s3s87711s3 193377..003327 QQSuutaaundntytiiNtfoyy.:sSLaaimm6pp7ll4ee, RRSeeepptoorrttNo.:02104AR, Ext.Date:02/18/04, Analysti.Risha rPaaggee 4+ Study No.=LI874, Set No.=021804AR, Ext.Date=02/18/04, Analyst=K.Risha # TeLSSaaarassmmnktppollameme:ooddLLiiiiffsstiti:=eedd=:PrTTPP\uu=IDee\\tDDMNaAaaaC\tArraL\\CLL00KC32CSHMHSS11SHM22ESS=:\6060M7\7\a=:Ms00aNs00slsayl22ny00sx00n\44xsF\lF1ulouyorromocchhxeenm\iicccFaaalllsLss...PuPPRRROoOO\\\NzSSeaatnmohppDllcRee\DDhCBBo\\et00a22nz11o88v0i04e4AARRNPDCCEGOSAAC0CS1SF2F1M04 MLJLeaaotasnhttocdmom=dooeddriiffiieedd=: Non Fab 03 07504142 2004 P=\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\MethDB\CotGrove Mort Feb 02 07:04=42 2004 NPDES 012104 Job Code= |I Pprriinntceeda=r TTuuee MMaarr 0022 1144:=0055:=2222 22000044 ",il oNNaeamsee=: 002231680044AAR%--220022 Text= 4: co sulfonate pris 11 (4XX:CCC0062222S44u00l44f--o11n,,a22t55e nnPggFi/HLLSSSttaannddaarrdd i 100w221o1880044AARR -220022 $m Sm (Mn, (Mn, 263) 2x3) | _ 01-Mar-2004 11:15:57 0M1R-MMaorf-2LL0CC0OhI4aMMn1nSSe1/lM:I1sS5ME#:S5#S6.76 28a.7787 MRM of 5 Channels ES- 307>778603 399 > 80 ~ `rea 7.77e3 ~~ i 200 400 60 80 1000 1--2T0i0me 2.00 4.00 6.00 8.00 10.00 12.00 55::CC8o sSuullffoonnaattee PpFrOSo_s 1 [XxCC002222440044--11,, 2255 nngg//LLSSttaannddaarrdd 0011--MMaarr--22L00C00I44M11S11I::M11S55#::555~7 100|2211880044AARR-220022 $m Sm (Mn (Mn, 2:3) 2x3) as MRM MRM of of 55LCCChhIaMann4nSnee/9lMlss>SEE05S#-0-~ 1t0 i9.15 499 > 99 48r0e3al) 4.88e3A~a [] o | tt S ene S tom eAm N PR - ....."..2.........4.00.. 2.00 4.00 ~ 60 .... , .... 6.00 , ....86, 0.... 8.00 , ....00, 0.... 10.00 , ....12,0T0ime 12.00 " . " Ragen Research, 3058 Reseach Drive, State College, PA 16801 Exygen Research, 3058 Research Drive, State College, PA 16801 - `CHEOGNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIJDJIEAESCCTLTTRTITCOOT AACPOPURRROOTT.TEECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR.2E6E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00332288 SW_MNO1S381T4 3M MN01538714 ` J -- res Quantify Sample Report w BEI use, scons, seston stase Study No.=LI874, Set No.=O21804AR, Ext. Date:02/18/04, Analyst:K.Risha Page 5 Fe Sar ZA TTA NSAEIASNR 53 3557 Sample List= fm in, eosin: Last modified: a Be Eom erocvniosta. owes 08S 057106 Method: EL Last modified= ae Job Code: P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\SampleDB\021804AR CG ACSFM Tue Mar 02 12:07=00 2004 P=\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\MethDB\CotGrove NPDES 012104 Mon Feb 02 07:04=42 2004 # Psrriinntteeda:: TTuuee MMaarr 0022 1144:=0055:=2222 22000044 0 Nwnaemnmea: onsotra-a0n 021804AR-203 ,ii T1.extc=e sesa smn : C6 Acid PFHA I] X[XCC002222440044--22,, 5500 nngg//hL SSttaannddaarrdd |0201280148AR0-420A3RSS-mm2((M0Mn3n,, 22xx33)) n ]h 1I00, 1885.4408858 0011--MMaarr--22000044 1111::3377::336 LCmons LC/MS/MS #6 MMRRMMooff 55CChhaannnneellss EESS-331133>> 226699 80u66t4. 8.05e4Area iii vl Toe awA a eo Ro 00"0 ~,"-~ --~% '=,' , , , , .... , .... , .... , .... , .... , , , =1 , 5] , ,-,,, .... , ....~ TTiimmee 2.00 4.00 6.00 8.00 10.00 12.00 a 1 2[X:XCC0C082222A44c00i48d-22,P, F55O00Annggi/hL SSttaannddaarrdd |002211880044AARR--220033 SSmm ((MMnn,, 22xx33)) |r ! 8s 353S6o9 | 28r.29967 01-Mar-2004 11:37: 01-Mar-2004 11:37:36 LLCC//MMSS/IMMSS #6 MMRRMMooff 5 CChhaannnneellss EESS-- "1.6208 413 > 369 1.52e5 Area ` | ,,I| ohn ~} --_ T|e - .0r'~'=' ' 200 ~ .... 2.00 I 4.00 .... I .... 4.00 ~ B00 .... I .... 6.00 , ....88..0,000.... , .._..1100.,0000.... i ....1122.,00T00ime | TET th 3:C4 Sulfonate PFBS Guz24043,50 ng. Standard ar 2004 T1574 - IXC022404-2, 50 nglL Standard 002211880044AARR--220033 SSmm ((MMnn,, 22xx33)) "| = 21e60l3 100, 01-Mar-2004 11:37:36 LLCC/IMMSS//MMSS #6 MMRRMM ooff 55 CChhaannnneellss EESS-- L8.o1d3 229999 >> 9999| 2.16e3 Area " pen ANN ApAaN A A meTime . Te ee eR 2.00 4.00 6.00 8.00 10.00 12.00 ,"|1 Soran wove 488 Togheens Sire Saks Subieate 3h HHH Rxygen Research, 3058 Research Drive, State College, PA 16801 EN. -- CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN en HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00332299 [pr-- 3M MN01538715 Wi QSQuuuaaanantytiitNfySy.iSSLaaEmmOppTllAee.RReeSppGooNrrttMo.:021804AR, Ext.Date:02/18/04, Amalystix.Risha Praaggee 6 SLSSaaatsmmutppdllymeeoNdoLLiii.fss:ittL:e:Id8:74,PPTo:\m\DSDeaHtataterNa\o\L.L0C=3CH0MS2S1M1M2S8S1E006\47\MA1MaR0as,0sssil2yyEm0xnx0tx\.\FDFlalutuoeor:ro0oc2ch/he1en8mi/ic0ca4al,lss.A.nPPaRRlOOy\\sSStaa:mEKpp.l1ReaiDDsBBh\\a002Z11880044AARR CCGO AACCSFTM @ MLLLoeaaaantSssthttthocodammma:soooeaddstiiefftiioeeddd::= HTP1ou=\ne\DDaMaFtaatarba\\L00c32CuMS01sM72S1:s00674\H:1Ma04as03sssl2L20y0y00ni48xa\\Flluouroorcohcehaeimciaclasl.s.PFRROO\\MNeStthhDDBD\\CCoottGGrEoovvee Mon Feb 02 07:04:42 2004 NNPPDDEESS 001122110044 Wo JpoobinCtoedse= Tee war 02 14:08:22 2004 Printed: Tue Mar 02 14:05:22 2004 ,HI [p---- Nnaemeez 021804AR-203 Text= 4: co sutonate pus 4: C6 Sulfonate PF[4S ` XC(C002222440044--22,, 5500 nngg//LL SSttaannddaarrdd J021804AR 203 Sm (Mn, 268) bo | 021804AR-203 Sm (Mn, 2x3) . |* il `I | 11o/~ 200rr400 2.00 4.00 5: co sulfonate pros 4 5X[:xCC0C028222S44u00l44f-2o2,n, a55t00e nnPggFi/OLLSSSttaannddaarrdd ` 002p211880044AARR.-220033 Sm Sm (Mn, (Mn, 23)2x3) 1 (i/~ oo 500 6.00 _ a2r2r 284.7727~1 0011--MMaarr--22000044 1111::3377::3366 LLCC//MMSS//MMSS##66 MRM of 5 Channels E5- MRM of 5 Channels ES680 399 > 80 Tazed 1.A4"a2rreeea4al SSNPS2s cnt Time 500 000 700 8.00 10.00 12.00 0011--MMaarr--22000044 1111::3377::36 ai9T.r1se5e MM RMoofR f 55LLCCCChha//MA anMnnSSne9//elMDlM9ssaSS5Ev5Se#%-s-6 499 > 99 `ea i LTR TTT eww ww ok ILS. ,e RT ie 01,-T~, , .... ,, , , , .... , ,, , , , ..1 .. , 7 .... 4 , ...2 . , .~ ... , ime 2.00 4.00 6.00 8.00 10.00 12.90.409e3Area " tl - ,'i [ Exygen Research, 3058 Ressazch Drive, State College, PA 16001 Exygen Research, 3058 Research Drive, State College, PA 16801 `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEEASCCTLTTRTITCOOT AACOPPURRROOTT,TEECNCTOT.IIVV2EE7-OOCVRR-DD1EE0RR28EE8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00333300 _MNOIS3BT16 3M MN01538716  WB QQuuaannttiitI fyy sSaammppllee rReeHppeoosrteNe.02100488, Bet.Date:02/10/04, Aalystix.Risha rage 7 Page 7 Study No.:LI874, Set No.=021804AR, Ext.Date=02/18/04, Analyst:K.Risha herSLLSoaeaasmsmntptpllmsemeooddLLiiiifssfitti:e=edd::PrTPPT\iuu:D\ee\aDDtNMaaaaatE\rra\L\LCL00CH27CHSMSNS11HSM22SES=:0\6077\Mk=:Maa00asa00sssll2y210y0my00nx44x\\\FPFlluuoLorrooUcchheeOnmiicEcaallOss..PPPCRRROOeO\\SSMaaRmsppRllDLeeBDD\aBCB\O\0L0LZG21E16o8s0v04e4AARNRFDCCEG~SAACC0S2ST2F1HM04 MLLoeaantsahttocmdmoo:odddasiftiieedd=: Mon ab 03 07104142 2008 P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\MethDB\CotGrove Mon Feb 02 07=04:42 2004 NPDES 012104 0 rJoibteCosd:e: tue ar 02 14:05:22 2004 Printed= Tue Mar 02 14:05:22 2004 NHpaemm=ee= o0~a1a8s0o4uAaR--a2o0e4 Text= | 4 L[iX:oCc0Co622aA4cc0it4da3p,PeF1m~0IsA0 ng Standard _-- XC022404-3, 100 ng/L Standard u 100|2211880044AARR-220044 Sm Sm (Mn, (Mn, 263) 2x3) . |* ,i LoMSIMS -- --01-Mar-2008 11:59:1 01-Mar-2004 11:59:17i 30s86.s40s88 MRM MRM of of 5LCCChh/aMann3nSn1oe/l3Mlss5S2EES6S#-9~- "tes, 313 > 26 rea) 3060L 1.51e5Area ` | ` 200 400 ,, 550 .... , .... , ....o8s5, 0.... ~ ...E .10,00..I .. , , , , 2,0~,0TTinmee 2.00 4.00 6.00 8.00 10.00 12.00 4 22[:.XCcC0o822A4A0cc4ii:da3,pPrF1oO0nA0 nglL Standard _ 01-Mar-2004 11:50:1 XC022404-3, 100 ng/L Standard . 002I211880044AARR-220044 Sm Sm (Mn, (Mn, 23)2x3) 0M1R-MMaorf.25LL0CC0ohl4aMMn1nSSe1/MlM:5sSS9E:S1#-76 ss MRM of 5 13> 389 Channels ES- Ey 8.98 4132>0Ar33e65a9l "> 2.03e5Area Time| ., ,~ .... ~ .... ~ .... , .... , .... , .... , .... , 3 ..6 ..6, 9..~ .. ~ .... , .... ,Time < Tam 00 500 800 1000 200 2.00 4.00 6.00 8.00 10.00 12.00 3: cs sulfonate seas 3: C4 Sulfonate PFBS XC022404-3, 100 nglL Standard 01-Mar-2004 11:59:17 XC022404-3, 100 ng/h Standard " 021804AR 204 Sm (Mn, 29) MRMof LGChMaSnInNaESlS#s-6 021804AR-204 Sm (Mn, 2x3) . p [7rs 2030550539 100~ % rea| ~ 8.15 697~ I 01-Mar-2004 11:59:17 LCIMSIMS #6 MRM of 5 Channels ES299 > 99 4.35e3 Area - oFmee \ eS e mTim 0~,, ~ ,,,, i, ,, ` 200 prs 500 80 1000 200" | 2.00 i, ,,, ~,, ,, r-,, ,, ~ .... , .... ~ .... , .... , .... ~ .... ,Time 4.00 6.00 8.00 10.00 12.00 w EExxyyggeenn RReesseeaarrcchh,, 33005588 RReesseeaarrcchh DDrriivvee,, SSttaattee CCoolllleeggee,, PPAA 1166880011 - `CHEOGNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIJDJIEEASCCTLTTRTITCOOT AACPOPURRROOTT.TEECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR.2E6E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00333311 SW_MNo1S38717 3M MN01538717 " 4 QQSutuauandntytiiNffoyy./sSLaazim~opp7ll4ee, RReSepepotorrNtto.:021604AR, Ext.Date:02/16/04, AnalystiX.Risha PPaaggee 8s Study No.=LI874, Set No.=021804AR, Ext.Date=02/18/04, Analyst=K.Risha SLSaaamsmptpllemeodLLiiifssitte::d: TPu=s\DDva:atra\\0L3CDMS1M3aS:06t7\:M0a\0ssLl20y0nC4x\HPFlluuSoorrMoocchhSeenmSticcaa\llssH..PPRaROO\\sSSaamsnppllleeDDBBy\\00m2Z1168e0044\AARR CO CG ACSF ACSFM 4 aMLLeaattssnhttooddmm:=ooddiitfiioedd:= NTPPou:\en\DDaMaTtaatabra\\LL00a72CHMSS01NM72SS1:S600\47H:1Ma04as02sssll22yy00n00nx44x\\FFlluuoorroocchheea~iiccaallss..PPRROO\\NMOetthhDDBB\\CCoottGGrroovvee NNPPDDEESS 001122110044 SLJaoabbS.tcCmoododeeds:ified= Mon Feb 02 07:04=42 2004 4 eriavea: Tue Max 02 14:05:22 2008 Printed: Tue Mar 02 14=05:22 2004 J MNeammee:= c02a1s8s0o4uAaRn-a2o0s4 Text= 4 4[4::KGcC0o6Z2sS4uu0ll4ff3oo,nnaa1tt0ee0 PpnFguHisSL Standard XC022404-3, 100 ng/L Standard " l0012211860044AARR-220044 5m Sm (vn, (Mn, 263) 2x3) 00 . %1 1~ % I _ ao88.77t77 0011--MMaarr--22L00C00M44S11I11:M:55S99#::11677 MMRRMM ooff 5LCCChh/aMannnS3ne0/elMl9ssSEE6SS#-0-6 399 > 80 27r5e0a4 2.75e4 Area 4 . Or;,,, ~ .... ~ .... ~ .... ~ .... ~ .... ~ .... ~ .... ~ .... ~ .... ~, ~" 200 400 500 800 1000 495~ Se12~0TT0iimme~ 2.00 4.00 6.00 8.00 10.00 12.00 4 5X5: C:0Cc28a24Ss0uu4ll-ffoo3nn,aa1tt0ee0 pPnrFgOolSsL Standard _ 01-Mar-2004 11:59:17 iii XC022404-3, 100 nglL Standard 0218047204 Sm (Mn, 263) 0M1R-MMaorf.2LL0CCC0hIl4aMMnS1nSI1e/M:lM5Ss9SE#:1S#76-61 %021804AR-204 Sm (Mn, 2x3) a79.17 4%9>59 MRM of 5 Channels ES- ' 499 > 99 1 3812 11.99"1r1eeead4l '* Area RRS ime] - , 200) .... , .... 2.00 , 4400 .... , .... 4.00 , 50 .... , .... 8.00 , soo oo .... , ......... , .... 8.00 10.00 , ....1122.~00T0i0m"e) " i'l ,,a|1 Exygen Reseszch, 3058 Resessch Drive, State College, PA 16801 Exygen Research, 3058 Research Drive, State College, PA 16801 a,~11 `CHEOGNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIJDJIEAESCCTLTTRTITCOOT AACPOPURRROOTT.TEECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR.2E6E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00333322 SW_MNo1S38718 3M MN01538718 4 QSQutuauanndttyiitNfeyy. sSLaa0mm7ppll4ee,RReeSppatoorrttNo.:021004AR, Ext.Date:03/13/04, AnalyetiK.Risha rege Page 9 Study No.:LI874, Set No.:O21804AR, Ext.Date=02/18/04, Analyst:K.Risha UH dLSGSoaaaatsnmmhttppollamemerooddLLiiiiffssiitte:e:dd:: TPTPProu:iae\\\DDDaNMaataattarraa)\\\LLL0032CCaMHsSS11sMM23S:S1e06S07\7N\:1MNa00aag00sssssll212y0y00n0ny44xx\\xFPll\uuooPrroolcchhueemnoiiccxaalloss..cPPPRRRhOOO\\\eNSSeaanImmppiDllReecDDBBaC\\oI0lt22r11so88v00.44eAARNRPDCCEGGSAAC0CS1F3S1M04 TMLYoeaantsshttocdmom:ooondt:itflieedd:= Won Fab 03 07104143 2004 P=~Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\MethDB\CotGrove Mon Feb 02 07:04:42 2004 NPDES 012104 Job Code= | veined: Printed: Tue Tue war Mar 0022 1104::0055:=3222 22000044 UrNsaae mmea= 002211800044A7R8--220058 Text= 1:: cco6 Anciiad PpFeHnA ,4hll X[XCC002222440044-44,, 225500 nnggi/LL SSttaannddaarrdd 00|2o218y1048AR02-240055ASSRmm((MMhn,, 226x83)) 1 1i PE _ __ 0011--MMaarr--22000044 12210. 12:21:04 848 M MRMoofR f 55LLCCCChah/I3M ManMnnS1Sne/e/lM>lMssSS2EE6SS#9--6) 8.48 313 > 269 mz 44..3"3a00r8ee55a, Area 2: co ct spor a 22..0000 44..0000 2:C8 Acid PFOA . [XXCC002222440044-44,, 225500 nngg//LL SSttaannddaarrdd 002P211o88n0044AARR-220055 5m (Mn, Sm(Mn, 233) 2x3) 1i |% , .... , .... , .... ,.. ., - 200 +00 2.00 4.00 3: cs suifonate pms 3: C4 Sulfonate PFBS - [XXCC002222440044-44,, 225500 nngg//LL SSttaannddaarrdd |002211880044AARR--220055 SSmm ((MMnn,, 22xx33)) - 100o,l|1 " 1 oh , .... , .... , .... -, .... , M 200 00 2.00 4.00 66..0000 88..0000 oem Time 1100..0000 1122..0000 69s8.98 Tio71629-~ 0011--MMaarr--22000044 1122::2211::0044 LLCC//MMSS/IMMSS #6 MRM of 5 Channels ES- MRM of 5 Channels ES3% 300 413 > 369 40265 4.02e5 `hres, Area ii 500 500 1000 200Time .... , .... , .... , .... , .... , .... , .... h T{me 6.00 8.00 10.00 12.00 28a1.1647 311 0011--MMaarr--22000044 1122::2211::0044 LCIMSIMS #5 LCIMSlMS #6 MMRRMMooff 5 CChhaannnneellss EESS-- 99>59 299 > 99 prov 1.66e4 "area Area EE Te .... ~- .... , .... , ,,-~,, .... , .... , .... ,Time 500 800 100 7200 6.00 8.00 10.00 12.00 . Exygen Rossarch, 3058 Research Drive, State College, PA 16801 Exygen Research, 3058 Research Drive, State College, PA 16801 i - `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACOPPURRROOTT,TEECNCTOT.IIVV2E7E-OOCVRR-DD1EE0RR28EE8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00333333 _MNO1S38T19 3M MN01538719 , II " 4 GSQuuEaennNtt~icyy SSaammppllee RReSepep.oorrttonteoun, exe.Dates02/26/04, Aastyscik. aisha rage 10 Page I0 STSSaeatrmmutppdllymeeoNdoLLi.iifss=ittL:=eId8:74B,TP:u:\s\SDDeawtatataraNo\\.L0u=C5C0MS2S1N13MS81S600647\WA1MaR0as,0seslTlyhyEmonxestx\.\FDFlalutuoeor:ro0oc2ch/he1em8m/il0cc4aa,llas.A.nPPaRRlOOy\\sSSataa=mpKp1.leReDiDBsBAh\O0aZ2L1S800A4RARR CCGG AACCSSTFHME 4 StMLLTeaaaohtssrnohtttoondrmmm::oooaaddnitifefisieeeddd=:: TPwou:ne\bDaMaFtaetabra\LL0032CoMS0e1M72S1:6004\7K:1Ma04as07sesl212y0000ny48x\Fmlunoro\chFemilccaaullss..oPPRRcOO\\HMoeettchEDDhBR\)CCaoottsGGrrooivvee Mon Feb 02 07=04:42 2004 NNPPDDEESS 001123110044 JroibmeCosdse= mue war 02 24005.22 2008 Printed: Tue Mar 02 14:05:22 2004 [pS -- eNTaemxeet== 021804AR-205 40ce suronate pris 4:C6 Sulfonate PFHS . XC(C002222440044--44,, 225500 nngg//LL. SSttaannddaarrdd [= "x|002211880044AARR-220055 Sm Sm 1,(Mn, 26)2x3) 1 ' | *} _ kior8.77 0011--MMaarr--22000044 1122::2211::0044 LCIMSIMS #5 LCIMS/MS #6 MRMof Channel ES- MRM of 5 Channels ES- 59880 399 > 80 Sas6.81e4 eaArea | "=== Time 0~,,,,, .... , .... , .... ~ .... , .... , .... , .... , .... , .... , .... ` 2% ao ho 5% 000 200" 2.00 4.00 6.00 8.00 10.00 ,Time 12.00 5 co suitonate pros _ 5:C8 Sulfonate PFOS a Xeo2044,250 ng Standard 01-Mar-2004 12:21 XC022404-4, 250 nglh Standard (0218044Sm2(0M5n, 263) MRMof 5 ChanneEl5s- 021804AR-205 Sm (Mn, 2x3) '1 ss Te | " Tier "0e10a4 a | 9.16 7487| 01-Mar-2004 12:21:04 LLCC/IMMSS/lMMSS #6 MRM of 5 Channels ES499 > 99 4.0 le4 Area . 246 Wh. e eho 0 1000 20T0ime , .... , .... , .... , .... , .... , ........ ~ .... ,, ,, ,--TT, , ,, .... ;Time 2.00 4.00 6.00 8.00 10.00 12.00 . . Exygon Resescch, 3058 Rasaaich Drive, State College, BA 16801 Exygen Research, 3058 Research Drive, State College, PA 16801 . `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACOPPURRROOTT.TEECNCTOT.IIVV2EE7-OOCRR\-DD1EE0RR-2E6E3NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00333344 m_Morsserz0 3M MN01538720 . @ QSQtuuuaadnnyttiiHtfoyy. sSLaa1mm6ppll7ee, RReSepepoborrtNto.:021804AR, Bxt.Date:02/18/04, Analystik.Risha Page 11 Pave ii Study No.=LI874, Set No.=021804AR, Ext.Date:02/18/04, Analyst:K.Risha a SvGLSiaaaaemnsmrtptpnlloemmed:ooddLLiiiiffssitit=e:edd:= TTPPuu=r\ee\\DDMNaaaaDttrraa\\LL00aC23CHMSS11tHM22SS=:E006a\77\HM=:Ma0a0a\s~0saasl1l22Ly00yyn00nax44x\\C\PPFlLluuuHooorrroooSccchhheeeHnnmtticccEaaalllsss...SP5RRROOO\\NSSSaaEmzRppDllBeeAdDCBBo\\t00G22r11o88v00e44AARNRPDCCEGGSAAC0C1SS2FI1M04 MTLLeaoatsnahttmocdomo=dodadiritfiieedd:= Non ab 03 07104143 2004 P:\Data\LCMSMS6\Masslynx\Fluorochemicals. Mon Feb 02 07:04=42 2004 PRO\MetllDB\CotGrove ~-PDES 012104 0 JiobneCosde= Tae Maz 02 14:05:22 2004 Printed= Tue Mar 02 14=05=22 2004 a emer oasoon-0s Name= 021804AR-206 Text= I1:: Ccs6 aAcciidd PpFrHiAn @ |X[CX0C02222440044.-55,, 550000nngg//LLSSttaannddaarrdd PRE1Y002211880044AARR-220066 Sm (Mn, Sm(Mn, 243) 2x3) PE . 200 200 2.00 4.00 4 22[::XCcC08a224An0co4ii.dd5,pPrF5Oo0An0 ngiL Standard XC022404-5, 500 ng/L Standard . 102180448206 Sm (4n, 233) 021804AR-206 Sm (Mn, 2x3) %1 O01 ` - ob 200 200 2.00 4.00 32[::XCcC0a4224sS0uu4il-tf5oo,nnaa5tt0ee0 PsnFegBalSsL Standard - XC022404-5, 500 ng/L Standard 10p0221y1880044A4RR.-220066 Sm Sm (Mn, (Mn, 2x3) 2x3) -h "1 01-I Mar-2004 12:42:5 0M1R-MMaorf-2LL0CC0ohI4aMmn1nsS2aImlM:4ssS2E:S5#-06 1a80.i745s8 s MRM of 5 Cha3n31n1e337l5s.>4E622S0665-99) rea) 140756~ 7.46e5Area - 550 800 000 1200 6.00 8.00 10.00 12.00 i} _ _ 0011--MMaarr-.22L000O044M11S22M::44S22::550 as MRMof MRM of 55LGCChhiMaan4Snn1e/n3Mls5eES3ElS6S#s0--6 s8e.g98s 6.35) 413 > 369 =8.83e5 158954~ Area 5600 80 6.00 8.00 S88i.1o133a 1000 2 00T"i me | | 10.00 12.00 0011--MMaarr--22L00C00M44 S11I22::M44S22::550 MRM MRM of of 5LCCChh/aMannnSn2ee/l0Mlss9S5EES0S#-9-6 29229,22r>09o4e9a)49) Area * . Ol| rrr e 200 430 e 500 "800e "1000 200Ti|| 2.00 4.00 6.00 8.00 10.00 12.00 a EExxvyggeenn RReesseeasrscchh,, 33005588 RReesseeaarzcchh DDrriivvee,, SSttaattee CCoolllleeggee,, PPAA 1166880011 - `CHEOGNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIJDJIEAESCCTLTTRTITCOOT AACPOPURRROOTT.TEECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR.2E6E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00333355 SW_MNo1838721 3M MN01538721 . wo QQSuueannttEiiefyyAsSaammLppllee RReRepep.oorrott rsean, xt oater02/10/04,Anaiyetik.nish rage 12 Page 4 aLSSSSAaaatcTsmmuoEtppdnllySmee,eoNfdoLLii.iiTf=ssiittL:e=eIdd8=,74B,uTpiu=\se\SDDeDaaMtMattaataarNra\o\LL.L00OC=25CHN0MEE2S11S13M2E81S=\0006W477\Aa1=MaRs00ag,00sslsyyl22m00yE00cxDn44t\x.\TeDFlalutuo\eor=ro0ocL2ch/he1enu8mi/ic0ccaao4all,lsss..zA.PnPFRaRRoOlOONy\\SsScKAtaE~mmBKpphD.lLBRea\iDeDCsBNoh\0ta0s2G21r10o8t0v0e44AARRNECDCEOGSAAC0C1SS2FT1MH04 MLSTeaaotsnhtkocdmmo=aoeddriitfiieadd=: Won ab 05 07104141 2004 P=\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\MethDB\CotGrove MOrt Feb 02 07:04:42 2004 NPDES 012104 0 JpoubinCoedse= ue war 02 1er05iz2 2008 Printed= Tue Mar 02 14=05=22 2004 ame: 031004208 Name= 021804AR-206 3 Text= 4: cs sutonase pms _ EE 4 4[XX:CCC00622224S40u04l4-f-5o5,n,a55t00e00 PnnFggH//SLLSSttaannddaarrdd a (o0o2116044250m5 (i, 2:3) am MRMof Chan3n0epl>o55-0 021804AR-206 Sm (Mn, 2x3) 8.79 24845 0011--MMaarr--22000044 1122::4422::50510 LLCC/M/SM/SM/S#M6S MRM of 5 Channels ES-, 3919.3>3850) 1.33e5Area | 1 Tine ,.i , .... , .... 22..0000 , .... , .... 44..0000 , ....66..0,000.... , ....88..20,0040.6.4.5.~, ....1100.., 000.0... , ....112~2,..00T00ime 5. co curtonace pros _ 5:C8 Sulfonate PFOS 4 [xC0Z2404.5, 500 ngiL Standard 01-Mar-2004 12:42:50 XC022404-5, 500 ng/L Standard (:02160448205 Sm (in, 2:3) MRMof 5 Ghannels E5- 021804AR-206 Sm (Mn, 2x3) [] r91i7a 00o5e5s0 ,| rea, * II Tine ` | 9.17 17160] 01-Mar-2004 12:42:50 LLCC//MMSS//MMSS ##66 MRM of 5 Channels ES499 > 99 8.98e4 | Area . 2h an hobo Too 200 '' ' ' ~.b~' ' ' '' "4.~)(~" ' '' ' '6.~)0 '' '' ' 8.~)0' ' '' '1'0100 -~'12.00Time u .,ill I.ll Sxrgon Research, 3058 Research Drive, State College, 7A 16801 Exygen Research, 3058 Research Dr~ve, State College, PA 16801 - `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACOPPURRROOTT.TEECNCTOT.IIVV2EE7-OOCRR\-DD1EE0RR-2E6E3NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00333366 m_morsserz2 3M MN01538722 u 4 qQSuutaaunndtytiiNffyoy.sS:aaImm8pp7ll4ee, RReeSpptoorrttNo.:021804AR, Ext.Date:03/18/04, AmalystiK.Risha aPaggee 1133 Study No.=LI874, Set No.=021804AR, Ext.Date:02/18/04, Analyst=K.Risha LSSaaasmmtppllmeeodLLiiifsstit::ed:PrTP\u=De\aDtMasat\raL\M0LS2CMMSS12M6:S\06M7\a:Ms0as0slsyl2n0yx0n\8xF\lFulouroorocchheemmiiccaallss..PPRROO\\SSkaEmpplleeDDBS\\002Z11860044AARR CCGG AACCSEFPM & MLLveaaetssthcthoedmmd=oo:ddiitfiieedd=: MTP1uo=\en\DDaMFataetarba\\L0L0C22CHMSS01K7M2S::SS006\74\M=:Ma04as02sasll22y00yn00nx48x\\FFlluuooorcohcehneimciaclasl.s.PPRROO\\MNeAtChDDBB\\CCoottGGroovvee NNPPDDEESS 001122110044 3LJoa0bstCCmoododeed=rified= Mort Feb 02 07:04:42 2004 pPrriinntteedr: TTuuee MMaarr 0022 1144::0055::2222 22000044 a Ndaemmee= 0m21s80o4AnR-s20w7 ,i Text= 1:: CC66 AAcciidd PPFEHAA a X[XCC002222440044--66,, 11000000 nngg//LL SSttaannddaarrdd a 00f22o1188o0044AARR:-220077 SSmm ((MMnn,, 226x33)) 1 O0I%] " %] 288852.5040 7 0011--MMaarr--22L00C00/44M11S33/::M00S44::#44363 MMRRMM ooff 55LCCChhIaMan3nnS1noIe3lMlss>S2EES6S#.9-6 "does 313 > 269 1.4A6ree6a Area " 0" .... 250 400 500 800 1000 120T0ime. 2.00 4.00 6.00 8.00 10.00 12.00 22::[XCcC0o822AA4cc0ii4d.d8,PpFr1oO0nA00 ng/L Standard 01-Mar-2004 13:04:4: XC022404-6, 1000 ng/h Standard (0218044R:207 Sm (Mn, 23) 0M1R.MMaorf.2LL0CCC0hII4aMMn1nSSo3I/lM:Ms0SS4E:S4#-36 |021804AR-207 Sm (Mn, 2x3) 27988.s4988 5 MRM of 5 Chan44n11e331ls>.>53E3360S669-9) 1 O01 1.53`eA6rAeraela " *1 - ol 200.... , a0 .... , .... , 500 .... , .... , 800 1000 .... ,27.9..4.85,~.... ~ .... , ....12,0TT0iimmee 2.00 4.00 6.00 8.00 10.00 12.00 3: cu sulfonate vrms " I3[x:XcC0C0242224S40u04l4-f64o,n, a11t00e0000PFnnBggS//LL SSttaannddaarrdd 0011--MMaarr--22L00C00/44M11S33/::M004S4::43 002211880044AARR-220077 SSmm ((MMnn,, 22x)3) - 100,1 18801.913236" MMRRMM ooff 5LCCChh/aMannnSn2e/el0Mlss9S>EESS#9-9-6) 2959.5>60949) I O01 10926 5.5`AA6rreeeaa4l "* . 20. 0 400 600 - 8.00 r 100r 0 r12,0TT0iimme|e 2.00 4.00 6.00 8.00 10.00 12.00 EBxxyyggeenn RReesseeaarrcchh,, 33005588 RReesseeaarrcchh DDrriivvee,, SSttaattee CCoolllleeggee,, PPAA 1166880011 - `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACPOPURRROOTT,TEECNCTOT,IIVV2EE7-OOCRRV-DD1EE0RR.2E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00333377 33MM_MMNNO011553388772233 " 4 qQSuutaaunndttyiifMfyoy.:sS6aaamm8pp7ll4ee, RReSepepotorrNtto.:021804AR, Bxt.Date:02/18/04, Analystik.Risha PPaaggee 1144 Study No.:LI874, Set No.:09-1804AR, Ext.Date:09-/18/04, Analyst:K.Risha GSSaaasmmtppllmeeodLniiifssitt::ed:DiTP\u:De\aDtaNata\raL\LO07CMMSSM1MS2S:S60\\7MM:aa0ss0ssll2yy0mn0ex4\\PFlluucorroocchheeamiiccaallss..PPRROO\\SSaammpplleeDDBB\\002211080044AARR CO CG ACSTH ACSFM a MeLLeaattasnhttoadmm::ooddiiftiieedd:: 5NTP:uo:\e\nDMFaDaatbraa\L0072CtMS01aM72S1:600\7\4:1ML04a02ssCl22y00H00n44x\SPFlluuNoorrSoocchhSeenm\iiccaaHllssa.PPRRnOO\\sKMSett1hhDDyBB\\CCnoottGxGrroo\vvee NNPPDDEESS 001122110044 JLoabst cmoodderified: Mon Feb 02 07:04:42 2004 Job Code= 8 ePrriinnvteeadr: TTuuee MMaarr 0022 1144::0055::2222 22000044 um Name: 0m21e80e4ARn-2a07 | iL 3998 Text= a 44[: X:CC0C66224sS0uu4ll-tf6oo,nnaa1tt0ee00PbFinHgsSlL Standard _ ~ 01-Mar-2004 13:04:4 XC022404-6, 1000 ng/L Standard 1021804AR207 Sm (Mn, 23) 0M1R-MMaorf-25LL0CCC0hII4aMnM1nSSe3IlM:M0sSS4E:S4#-36 021804AR-207 Sm (Mn, 2x3) MRM of 5 Channels ES- 1 O01 47950" 8.79 479591 39229.66A>44r6e8e55a0 Area . ` 22.0000 44.0000 5: co sulonate pros 4 X[X:CC0C082222S44u00l44f-.o66n,,a11t00e0000PFnnOgSg/L SSttaannddaarrdd p0022i11680044AARR.-220077 Sm Sm (Mn, (Mn, 2x3) 2x3) ,'| 56.0000 _ Time .... , .... , .... ,Time 830 1000 1200 8.00 10.00 12.00 0011--MMaarr--22L00C00I44M11S33/::M004S4::43 or MMRRMM ooff 55LGCChhlaMannnSn4oe/l9Mlss9S>EES9S#-9-6 394.1773 4919.r7>o89a59)] 1.78e5Area 1 | 200 Pan) 500 80- 0 1000 120T0imo , .... , .... , .... , .... , .... , .... , .... , .3..3.47~3.~... , .... ~ .... ,Time 2.00 4.00 6.00 8.00 10.00 12.00 " 4 iaiii Exyoen Ressarch, 3058 Reseach Drive, State College, PA 16801 Exygen Research, 3058 Research Drive, State College, PA 16801 - `CHEOGNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIJDJIEAESCCTLTTRTITCOOT AACOPPURRROOTT.TEECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR.2E6E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00333388 SW_MNo1S38724 3M MN01538724 4 qSQuuaannEttiitfIyy sS~TaumnppllEee RR.eeppoorrtot ntsoan, nst.pate0a/a0/00, AaslyetixRisha [IPage 15 a dLSr SSaaatasmmutppdtllyr meeeoNdoLLi.iif:sspitLt=e:Id8:74,PETPrru=\e\SoDeDaaMtatcataarNa\o\\L.L0LC:2CuH0MbS2Sr1uU1M2Ss8S:Er00647\kNA=MraaR0atg,0sessl2)yy0yEam0xns4tx\\.\iPDFulalouturoeoro:ro0soc2hch/ehe1enn8mtt/icc0cau4ail,lsss..A.PnPPRaRROlOOVy\VSsNSAtAam:EmpKAp1.DleRHeOi\DBCsB\oh\0ta02G21r18o80v04e4AARRNECDCOEGSAAC0C1S3FS1M08 MLaTeaatrshtttodmm=ecadtitfieedd:~ Kon Fob 05 07100045 2008 P=\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\MethDB\CotGrove Mon Feb 02 07~04:42 2004 I~PDES 012104 0 pJorbimCoedse: rue ar 03 10008132 2000 Printed= Tue Mar 02 14=05=22 2004 sane: 03100433208 a NTTaeemxxett==: 021804AR-208 4 [1i.M:etCcho6anaAoccliiddWaPosFmHhaA Methanol Wash 0 |(02c182041AR0-22000884SSRmm (hn, (Mn, 2)2x3) |1001 ee } 31-Mar-2004 13:26:3 0M1R-MMoafr-25LL0CCe0hI4iMaM1Ss3m/M:M2eSS6ElS:3#.s06| a8498.49 \L | 4987~ MRMof5 Zaetad 3135 289) Channels ES313 > 269 2.89e4 . 200 400 800 800 000 1200 0~ /.. .. ~ ~ ....2.0, 0.... , ....4.0, 0.... , ....6.0, 0.... ~ , ...~ .8.0, 0.... , ....10.~ 00.... , ....12.,0T0iAmreea 2: ca acie pron _ 2:C8 Acid PFOA a [MMeetthhaannooll WWaasshh 21804 208 5m (in, 2) MRMof 5 Channels E5- 021804AR-208 Sm (Mn, 2x3) 100, sor ios 300 " 1 ] 0011--MMaarr--22000044 1133::2266::33(0 LLCC/IMMSS//MMSS #6 MRM of 5 Channels ES- 3596 2554) 8.97 413 > 369 2.55e4 AArreeaa .. lo . Pr) Pn) 1m 6 ao enayime 2.00 4.00 6.00 8.00 10.00 12.00 5. ct suttenate peas 3:C4 Su]fonate PFBS Methanol Wash Gi-Mar-2004 13:26:30 Methanol Wash v- 01 -Mar-2004 13:26:301 LLCC//MMSS//MMSS ##6~ lc21020084SRm (hin, 2) MRM of annalESs- 021804AR-208 Sm (Mn, 2x3) M i 16 asst Sim0 [1 1noses 1, ote ase 186251 2m 38 en S13 520e2m27i bm Ne | ns,SAIN 0.99 1.66 2.51 2.82 3.67 4.13 5.73 16 SV MRM of 5 Channels ES- / 10.66 299 > 99 11.65 1.30e3 \ P FS -------- i 22..0000 44..0000 66..0000 88..0000 11000.000 1122.0oT0oime!| a Bergen Research, 3058 Reseasch Drive, State Collage, PA 16801 Exygen Research, 3058 Research Drive, State College, PA 16801 a `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NTSSTUYUBBIDJJIAEESCCTLTTRITTCOOT AACOPPURRROOTT.TEECNCTGT.IIVV2EE7-OOGRRu-DD1EE0RR.2E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00333399 aunorsasTzs 3M MN01538725 " 4 QqSutuuaadnnyttiiNfteyy. SsLaaTmmOppTAll,ee RRSeeepptoorrttNo.10ZL6OIAR, Bxt.Date:02/18/04, Analystik.Risha PPaaggeo 1166 ZSSSaaatnmmutppdllyemeoNdoLLi.iits:sittL:e:Id8:74TP,Piu:\s\SDeDWatatatarNa\o\L.L0C:3CH0MS2S1U1M2S8S:S006\47\Aa:MRs0a,0sslsy2ln0yE0xxn4t\x.\PDFlalutuoeoz:ro0oc2ch/he1en8mi/ic0ca4al,lss.A.nPPRaROlO\y\SsSatas:mpKpl.lsReDiDBsB\h\Ga02211880044AARR CCG5 AACCSFSM ,w,il eMoLLLreaaantssshtttoocdommm:doooedddriitefftiioeeddd::: oTP71u:ne\DDMtFaaetrba\\LL00C2C3HMSS10HM27SS:1S60087\1:Ma40as30sssly220y0m00na44x)\FFlluuoorroocchheenmiiccaallss.PPRROO\MNetAhDDBB\\CCoottGGrroovvee Mon Feb 02 07:04:42 2004 NNPPDDEESS 001172110044 Job Code: 0 poner Tue war 02 10:05:22 200 Printed: Tue Mar 02 14:05:22 2004 4 Ter omsoun-aos iJ Name: 021804AR-208 Text: 4: co sulfonate pews [Methanol Wash 4: C6 Sulfonate Methanol Wash PF~S a [a|02012810840A4RA-2R0-82SS0mm8(M(Mnn,,22xx33)) i` %]o1 _ _ se 01-Mar-2004 13:26: 01 -Mar-2004 13:26:30 LLCC//MMSS/IMMSS #6 MMRRMMooff 5 CChhaannnneellss EESS-- =. 1178305850 11.76-..399 > 80 1% | 3.923 020oN rlos se zi ams sas sSpoRn 9OH nT ~~ ' ' o 250 4% 550 850 050 er20Time 10.00 12.00 5: co sulfonate pros E ; ; _ u 5M [:MeetCth8haannSouolll fWWoanaassthhe PFOS ,i /02180487.208 5m (in, 265) MRM of5 Channel ES 021804AR-208 Sm (Mn, 2x3) a | s 108 99>59 a | HORI0.62,_ 1.26 BEAL 2.15 2.76 2.973.65 MN _ 548. 6.10 rm 7.27 0011--MMaarr-.220000441133::2266::3(~ LLCC/IMMSS//MMSS MRM of 5 Channels ES- fn 10.68 499 > 99 ^^^ 1039 ~ 108e3 891u.zu "-~ /\ ~ 8.~04 '~-~ /~ 9~68 z,.,//'~ ~ \ | 250 50 550 r 856 e10r 00 e720TT0imie 2.00 4.00 6.00 8.00 10.00 12.00 " " Bxygen Reseasch, 3056 Resessch Drive, State College, 7A 16001 Exygen Research, 3058 Research Drive, State College, PA 16801 - `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACOPPURRROOTT,TEECNCTOT,IIVV2EE7-OOCRRV-DD1EE0RR.2E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00334400 SU_mNotsss725 3M MN01538726 " quantiey sample Repore rage 11 Quantify sample Report 4 IT Ne conisouan, mxt.ave02/10/04, Analyatik.xisha Study No.=LI874, Set No.:021804AR, Ext.Date:02/18/04, Analyst:K.Risha Page 17 Sample List: pi\Gata\LCHSHSS Mags ymc\Puorochenicals. PRO\SSSPLADBNGA1804AR CO ASK Sample List= P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\SampleDB\021804AR CG ACSFM ET Seite Tua war 05 They 00 205s " MMLeeattshhtooddm:=odified= TPPu=:e\\DDMaaattraa\\LL02CCMMSS1MM2SS=606\7\M=Ma0as0sssl210yy0nn4xx\\F~lluuoorroocchheenmiiccaallss..PPRROO\\MMeetthhDDBB\\CCoottGGrroovvee NNPPDDEESS 001122110044 Tart attiag: won Fen 05 a70ksa3 2004 Last modified= Mon Feb 02 07=04~42 2004 ae Job Code= 0 races ee ver 03 20008132 2000 Printed= Tue Mar 02 14=05:22 2004 -- Name: 021804AR-209 oI dill Text: 3. co neid orn I: C6 Acid PFHA uw [ofoe0Comwol i Mar-2004 13:4871 0106020 Control 02180448208 Sm (4. 2:0) MRMof 5LCChIaMnSneIlNsSE5- | 021804AR-209 Sm (Mn, 2x3) " 100, 88.4488 7288 01 -Mar-2004 13:48:10 LC/MS/MS #6 MRM of 5 Chan33n11e33l>s> E22S669-9) 4.6804] P` E: A 20 m ek bbp e r0%searrae,20TrieOa 2.00 4.00 6.00 3. ca ncid pron 2: C8 Acid PFOA ` 0[0110066002200 CCoonnttrrooll |002211880044AARR--220099 SSmm ((MMnn,, 22xx33)) . | "\ Sarsaes 5523aed6oa0d |1001 t i,li - E 20% bo Shoy 17) TsoWN 2.00 4.00 6.00 3. ct sultonete seas _ 3:C4 Sulfonate PFBS 0106620Control i-Mar 2004 13:48:11 0106020 Control - l021604AR.200 Sm (in, 228) MofR5LCheainM nMeSlMSES- 021804AR-209 Sm (Mn, 2x3) -. [| 1941 Jage A. 100R BRANNsnA0NPmarefan os 2\ 0: 5 || AN 0.68 1.[66Rozsa 4! aaoS5.73 NC 8.00 10.00 12.00 0011--MMaarr--22000044 1133::4488:1:11 0 LLCC//MMSS//MMSS #6 MMRRMM ooff 55 CChhaannnneellss EESS-- 8.96 413 > 369 erm 31 7 2.44e4Area Ad , .... ,Time 8.00 10.00 12.00 01 -M ar-2004 13:48:1~ LCIMS/MS #~ MRM of 5 Channels ES- 9.31 gr MiSV 6610:99. 299 > 99 oY LA . 356 wh abo a5 SE 2.00 4.00 6.00 8.00 000 on 10.00 -- | Time 12.00 [] Exysen Research, 3058 Research Drive, State College, PA 16801 Exygen Research, 3058 Research Drive, State College, PA 16801 a. `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NTSSTUYUBBIDJJIAEESCCTLTTRITTCOOT AACOPPURRROOTT.TEECNCTGT.IIVV2EE7-OOGRRu-DD1EE0RR.2E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00334411 au_mnotsasTzr 3M MN01538727 u QSguuRaanaEttiifcEyy SsIaammppTllee nReeEppoorrt:. oneou, nxt paceroa/ae/on, meiyeti ashe rege 10 Page 18 BaLLSSSaatuAsmummtpdplylmmeooNdsoLLiii.ifzss:iittLe:e:Idd8:s74,oTP3u:rwe\\SDDeLaMtRaeaCtsrNaao\\.LL50o:C25Cu0HMi2ES11m1NM32a8S1S:t0S060437\WsA:M0aR0aa0p,0ss.sn2l2y60syEm00xn843tx.F\yDFalhmtueose;r0oo\2c/hF1re8ml/io0cu4ac,loshA.snFPRaeRRool0O\y\\ncHSsSeatahtcs;mhpKpecL.laeRennDaiDRCsBi\oh\lta02ca21ar1e08e.00vl44eKAsRRNECDCOEGSAAC0CS3F7S1M04 MSYLeaaatnSshttocdmnm:aoondasitfeiseads: won Tab 55 o7104raa 200k P:\Data\LCMSMS6\Masslynx\Fluorochemicals. PRO\MethDB\CotGrove Mon Feb 02 07=04:42 2004 NPDES 012104 pJoobinCtoedse= Tear 02 200mm 2000 Printed: Tue Mar 02 14:05:22 2004 oreNramm=e= onmscann 021804AR-209 4. c Text= surtonace sms 4:C6 Sulfonate PFHS 21820005m 4, 230) a [00110066002200 CCoonnttrrooll 021804AR-209 Sm (Mn, 2x3) ` 100, } I 0011--MMaarr--22000044 1133::4488::1100 LCMSIMS#6 LC/MS/MS #6 MRMof 6 Shan5- MRM of 5 Channels ES- 0% n Fe 11.35 399 > 80 1001 11.~~ 3.68e3 CE 2 O . r 2.00 r 4.00 ,.,, ...8..0~r 0.... ~ ...e .8.~00.... r ~ ....10.~ 0.0.e .. ~ ....12.~0TT0iimmee 2.00 4.00 6.00 8.00 10.00 12.00 5. co suonste pos 5:C8 Sulfonate PFOS [0106020 Control Mar2004 15:481 ,,| 0106020 Control 02160448209 5m (in,215) We 1 rans 5 021804AR-209 Sm (Mn, 2x3) | 100 SEH 5550 1 . P Cue 1t aam20a20m0 17oR ssesrsnao S SRFR \ .120.62 6.52 7.04 9.12 8.04 8.48 01 -Mar-2004 13:48:10 LLCC//MMSS/IMMSS #6 MRM of 5 Channels ES10.6811.33 499 > 99 1.07e3 . 3 abo ft) a0 e eeoo y 2TinTime 2.00 4.00 6.00 8.00 10.00 12.00 . " i ,,a1il Sxygen Resaazcn, 3058 Reseach Drive, State College, PA 16003 Exygen Research, 3058 Research Drive, State College, PA 16801 a. CCHEOONNNNFEIDFPIEINNTDCIAOELU-NN- TSSTYUUIBBDJJIAEESCCTLTTR I1TCO0T AACPOPURRROOTT.TEECNCTOT.IIVV2EE7 .OO0RVR-DD1EE0RR.2E6E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00334422 awmorsae2s 3M MN01538728 a. 4 QQSuuaannttEiiffyyIsSaammN ppllee RReeSppeoo.rrtot nteouan, mxDater02/26/04, Analyet.x.nish PPaaggee 1199 Study No.=LI874, Set No.=021804AR, Ext.Date:02/18/04, Analyst=K.Risha 4 eGLSSaaaatnsmmottppmdllmoeeroddLLiiiifssLitte::edds=PiTTp\uiu=Dse\\aoDtMNaaaaatt\rara\L\LCL06C2H3CHSMSHS11H2S2MS1=SEE006\77\MN=1Maa00ass00ssasll2l2yy00yum00nxx44x\\\FPFllluuuocorrroooccchhheeenmmiiicccaaalllsss...PPPRRROOO\\\GSKaaSmmEpphllDeeBDD\BCB\o\0t0Zd21r16o80v04e4AARRNPDCCEGOSAAC0CS1EF2P1M04 MLJLeaoatsbshttoCdomm:dooeddriiftiieedd:: Non Fab 03 07104143 2004 P=\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\MethDB\CotGrove Mon Feb 02 07=04=42 2004 NPDES 012104 Job Code: i Pprriinatteeda:r TTuuee MMaarr 0022 1144::0055=:2222 22000044 Nem casscuanano ii Name= 021804AR-210 Text= 2: cs ace rm . _ 4 i[0:01100C6660022A00ciSSdppkkPFAAH,,A5500 nnggllLL. 1020182041A8R-02211400ASSRmm (Mn, (Mn, 23) 2x3) aIi | MR1001 0011--MMaarr--22L00C0044I11M44S::00I99M#::556S55 s8so.a4as8r MMRRMM ooff 55LCCChh/aMann33nSn1e3eI3lMl5dss>S2eEE28SS#6s-0-69 "rea 1.14e5 Area `o 200 400 600 8I 00 1000 20i0me 2.00 4.00 6.00 8.00 10.00 12.00 4 22[::01c0Ca860A2Ac0ciiScdpipPrFAOo,An50 git 01-Mar-2004 14:09_:_55 0106020 Spk A, 50 ng/h " 0022211880044A4RR.-221100 Sm Sm (Mn, (Mn, 263) 2x3) 0M1R-MMaorf-25LL0CCC0hI/4aMMn1nSSe4//lM:M0sSS9E:S5##-566 1a9s28s7 MRM of 5 Chan1n3el1>s.3E06S00-5 8.98 413 > 369 1.`0r9ee5a 4 %n Area . Ord M 200 e abo r 660 m 800 a 700n 0 20TT0iimmee 2,00 4,00 6.00 8,00 10,00 12.00 3: ci sulfonate ves 3[0:1C04802S0ulSfpoknaAt,e50PFnBgSiL -- 01-Mar-2004 14:09:55 0106020 Spk A, 50 nglL - 1|02e1804AR 210 Sm (Mn, 263) 021804AR-210 Sm (Mn, 2x3) 8 01-Mar-2004 14:09:55 LCMSIMS #6 LC/MS/MS #6 MRM of 5 Chann2el0s05ES0-9 MRM of 5 Channels ES- - || 100~ a88.13 459~ 299 > 99 3.r15e0a3 3.15e3 % YL M epeeE e T A e e Ae Np A re ANe AA er r TR . 200 400 600 800 1000 200 10.00 Time 12.00 8.00 2.00 4.00 6.00 a Bergen Research, 3058 Ressaxch Drive, State College, PA 16801 Exygen Research, 3058 Research Drive, State College, PA 16801 a `CHEOGNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIJDJIEAESCCTLTTRTITCOOT AACPOPURRROOTT.TEECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR.2E6E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00334433 SW_MNo1S38729 3M MN01538729 - 4 QS quuaannttiiN ftyy ssaaA mmppllee RReeSppeoorrttonmoum, axe oates0a/10/04, Aaalystix.niche PPaaggee 2200 Study No.=LI874, Set No.=021804AR, Ext.Date=02/18/04, Analyst=K.Risha aaLSSataansmmhttppollnmeme:ooddLLiiiiffssiitt:ee:dd::P:TTP1\ou:D\se\aDDtaMMaetaeta\rra\L\LCL00H2%CuSMMS11sSM22ESs=1\0607M\H1=Maa00ass00ssssi2yl2y00ynn00nax44x\\\FFFluluouorororocochcheheaenmiiicccaaalllsss...PPFRRROOO\\\SSAaatmphpLDla\eDDCBBo\\tO0GZ2FI1o88v00e44AARRNPDCCEGOSAAC0CS1TF2H1M04 MoLLeaantSshttoCdmom=eoonda:itfeiseodd:: Mon Feb 03 07108r43 2004 P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\MethDB\CotGrove MOn Feb 02 07:04:42 2004 NPDES 012104 Job Code: pPrriinncteeadr: TTuuee MMaarr 0022 1144::0055=:2222 22000044 oeNamme= e02m18s0c4AoRn-2a1n0 4: cs suronate sms _ Text= 4: C6 Sulfonate PFHS a [00110066002200 SSppkk AA,, 5500 nngg//LL. 1021804AR 210 8m (Mn, 263) [i021804AR-210 Sm (Mn, 2x3) ~ arr 189.7873 19631 pTTS 0011--MMaarr--22000044 1144::0099::5555 LLCC//MMSS//MMSS ##66 MRM of Channel ES MRM of 5 Channels ES5s50 3919.2>00840) ea 1.20e4Area {1 ' (o/l Sr" | w prs 3 wo eH [5: co sultonate ros 2.00 4.00 6.00 + [50:01100C6680022S00ulSSfppokknaAAt,,e55P00FOnnSggi/LL 00:2128014AR8-2210100S4SmmA((MMRnn,, 23)2x3) ` % 8.00 ats 194,1685 A\ Time 10.00 12.00 0011--MMaarr--22L00O0044M11S44:M:00S09::55 M MRMoofR f55LCCChha/M Man"nn1Sen9leIMs5lsSEE55S#-0-6 4979.A>9r39e39a ! | - cE Tam ae 500 85e 0 1000 200Time I " " " Exygen Research, 3056 Reseasch Delve, State College, PA 16601 Exygen Research, 3058 Research Drive, State College, PA 16801 " `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACOPPURRROOTT,TEECNCTOT.IIVV2E7E-OOCVRR-DD1EE0RR28EE8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00334444 _MNO1S38730 3M MN01538730 " 4 QQSuutaaunndttyiitMfyay.rsSLaa1mm8pp7ll4ee,RReeSppeootrrttNo.:021804AR, Bxt.Date:03/18/04, AnalystiX.Risha Page 21 Page 21 Study No.=LI874, Set No. z021804AR, Ext.Date=02/18/04, Analyst=K.Risha Ww SLKLSaaaaessmmtttpphllommeeaooddLLiiiiffssiitte=e:dd:: PTiTPuuI=\ne\\DDDMAMaaatatarrat\\aLL00C22C\HMSLS11HM22CSS1:SH00677\MS=1Ma00aHn00sSssll22Ey0y0\n00nx44xM\\FaFllsuuosorriooccyhhneenmxii\ccaaFlliss.uPPPRoRROOOr\\\SoSNaaSczmEpphhllDeeSDDa\BBCi\\oO0tc22Ga11r88ol00vs44eAA.RRNPDCCEGGSAAC0CS1SF2I1M04 MLSYeaoatsnshttocdomm:dooedaritefiieedds= Mon Fab 07 07104142 2004 P=\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\MethDB\CotGrove Mon Feb 02 07:04=42 2004 NPDES 012104 Job Code= [ey Tue Maz 02 14105122 2004 Printed= Tue Mar 02 14~05~22 2004 NrNoaemmeex:= 0210048-211 021804AR-211 T2:extc=s acid pom 4 I0[:0110C0666002A200ciSSdppkkPFBBH,,A550000 nnggi/LL a |'00l22w11o880044AARR:-221111 Sm Sm (Mn, 2:3) (Mn, 2x3) ,| PE iii 16388.5550050 I 0011--MMaarr--22000044 1144::3311::4433 MRM of LLCCChI/aMMnSSnI/eMMlSSES##6.5 MRM of 5 Channels ES- 3138562e5s0 313 > 269 ea 8.65e5Area 10%0011~/,, . . . , .... , .... , .... , . . 1 250 400 2.00 4.00 2: co neid pron _ : C8 Acid PFOA 4 [0106020 Spk B, 500 nil 0106020 Spk B, 500 ng/L A002211860044A4R8-221111 Sm Sm (Mn, (Mn, 269) 2x3) `* 550 850 1000 120T0ime ., .... , .... , ...1.56, 5.6.0.~. , .... , .... , .... ,Time 6.00 8.00 10.00 12.00 _ 01-Mar-2004 14:31: 01-Mar-2004 14:31:43 LOMSIMS LCIMS/MS #6 MRM of 5 Channels ES- MRM of 5 Channels ES- se 13>359 8.98 413 > 369 150795 "v"arsoeas 8.39e5Ama | * . | 11o/1 200 2,00 330::10Cc84t62sS0uullSftpooknnaaBtt,ee 5Po0Fr0BeSsgil - 002110860042A0R S21p1k SBm, 5(0Mn0, n2g30/L) . 021804AR-211 Sm (Mn, 2x3) 100. | ,, .... , .... aI sk 4,00 6.00 eo R. 1050 20T0i|m|e , .... ,1.5.0.7.98,~.... , .... , .... ,Time 8.00 10.00 12.00 0Of1--MMaarr--22L00o004m4 s114i4::m33s11::43 MMRRMM ooff 5 Channols ES- LCIMSIMS #6 5 Channels ES- s88.e113z3 22993993>5>05949) `ha 3.35e4 Area - . e 200 p 200 e 500 e 8B0R0 1000 120T0ime 2.00 4.00 6.00 8.00 10.00 12.00 " Exygen Research, 3050 Research Drive, State College, 7A 16801 Exygen Research, 3058 Research Drive, State College, PA 16801 - `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACOPPURRROOTT,TEECNCTOT,IIVV2EE7-OOCRRV-DD1EE0RR.2E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00334455 SM_MNo1538731 3M MN01538731 " M qQSuutaaunndtytiiNftoyy.:SsLaaLmmSppTllAee, RReSeepptoorrttNo.:021804AR, Ext.Date:02/18/04, AnalystiX.Risha PPaaggee 2222 Study No.=LI874, Set No.=021804AR, Ext. Date=02/18/04, Analyst~K.Risha LSSaaasmmtpplleemodLLiiifsstti:=ed: Tpu:Pe\iD\NaDatarat\aL0\2CLMOS1HM2SS:S60\7\M:Me0as0sssl2ly0yn0nx4x\\PFlluuoorroocchheenmiiccaallss..PPRROO\\SSaammpplleeDDBB\\002211880044AARR CCGG AACCSSFTMH 4 MwLLeaaetssthttnoodmma=ooddiiffiieedd=: NTPPou:ren\\DDMFaAaatCrbAa\\LL00C22CHMSS10NM27SS:=S06087\\::MM40aa30ssss2l2L00yy00nn44x\\FPlLuuoorroocchheenmticcaallss..PPRROO\\MNeetthhDDSB\\CCoottGGrroovvee NNPPDDEESS 001122110044 0LJaobsbtCCmooddoeed:rified= Mon Feb 02 07:04:42 2004 IL i Pre inted: TTuuee MMaarr 0022 1144=:0055=:2222 22000044 breNNaammeee=: 002211880044AARR--221111 Text= 44::C66 Ssuullffoonnaattee pPFrHsS [00110066062200 SSppkk BB,, 550000 nnggl/LL (021804AR:211 Sm (Mn, 213) 4 fro 021804AR-211 Sm (Mn, 2x3) "% i 21887.787998 - 01-Mar-2004 14:31: 0MM1RR-MMMaoorff-255LL0CCCC0hh/I4aMaMnn1nSSn3o4/eI9lM:lM36ssS1S>EE:S4S#8.036-) 3919.`1>A7re86a05l 1.17e5Area a" , 250 .... , .... , 400 .... , .... , 6.00 .... ~ .... , 800 .... 2, 1.7.8.5.~, 1000 .... , .... , ...e.1n2,0TT0iimmee 2.00 4.00 6.00 8.00 10.00 12.00 5: Co sulfonate pros. _ 4 [500:110C06860022S00ulSSfppokknaB8t,e, 55P00F00OSnngg//LL. 0011--MMaarr--22L00C00/44M11S44/::M3311S::43 4 |1002211880044AARR-221111 Sm Sm (Mn, (Mn, 213) 2x3) 917 MMRRMM ooff 55LCCChh/aMannnSn"ee/lMliss>SeEESS#9s1.-)~ 194.5147 6 497975.0949) Area) % 7.75e4'Area `| - 200 400600 800 10001200Time , .... , .... , .... , .... , .... ~ .... , .... , ..1.4.54,6.~... , .... , .... ,Time 2.00 4.00 6.00 8.00 10.00 12.00 " ",11 " EExxyyggeenn RReesseeaarcchh,, 33005588 RReessseaarrcchh DDrriivvee,, SSttaattee CCoolllleeggee,, PPAA 1166880011 `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACPOPURRROOTT,TEECNCTOT,IIVV2EE7-OOCRRV-DD1EE0RR.2E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00334466 3M_MNO1538732 3M MN01538732 " a QQSuuaaEnnttiitfyy SSaammppllee RReeppoorrNtte. o21004an, Bt.Date102/26/04, Anayetik.nioha Praaggee 2232 Study No.=LI874, Set No.=021804AR, Ext.Date=02/18/04, Analyst=K.Risha 4 GWLSSaaaaantsmmthtppollameme:ooddLLiiiiffssiittee::dd:= TTPP1eur=ae\\DDDaaMaatattreraa\\\LLL00C52ECHMNSS11MSM23S=5SEE006\77\HM1=Maa00ass00ssssll0L2y0y0m0yn4c4x\T\FFleluuo\orrFooccLhheeunmiioccaarllsso..cPPPRRRhOOO\NNeSSaaAtmmZhppDil1Beac\DDCBBao\\t0OlG22r11ao88v00.e44AARENPCDCEGGSAAC0CS1SF3F1M04 Ly MLaeastshttoe dmp=ooddiiftiieedd=: von Feb 07 07504143 2004 P=\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\MethDB\CotGrove MOn Feb 02 07:04=42 2004 NPDES 012104 ,#j eJoobmcCeosdse= Tue war 02 10.05.22 2008 Printed: Tue Mar 02 14:05:22 2004 (em omsomnn Name= 021804AR-212 T1.extc=cnetasem i: C6 Acid PFHA a [hL11887744--11 SSppkk CC,, 1100000000 nngg//LL,, DDFF==11000000 |o2te20142a8rm (Mn, 20) 021804AR-212 Sm (Mn, 2x3) ( " |100- MofR 5LCChaMM nSneIlMs SES#-6 884.488 rea) 11633 0011--MMaarr--22000044 1144::5533::2299 LC/MS/MS #6 MRM of 5 Chan33n11e33ls>> E22S66-99 5.8164 " |J |i | or A p e ee --r ----Time| ........ ~ .... ~ .... ~ .... ~ .... ~ .... ~ .... ~ .... ~ .... ~ .... ~ .... , Time 200 00 500 800 000 200 2.00 4.00 6.00 8.00 10.00 12.00 i E[L: l7C8874A1ciSdpkPFCO,A10000 ngiL, DF=1000 L1874-1 Spk C, 10000 nglL, DF=1000 |oz12810254ma(4R0, 260) uo I021804AR-212 Sm (Mn, 2x3) | = 1 [i/I~ % ssa8as.9n6 0011--MMaarr--22L00o00M44 S11I44::M55S33::229 LC/MSIMS #6 MofR 5ChaM nnels ES- MRM of 5 Channels ESY>3d0 413 > 369 | 3.05e5Area | - ob 22.0000 24.0000 66.0000 3. cu sulfonate pris _ 3LL:118C877444--S11ulSSfppokknaCCt,,e1100PF00B00S00 nnggi/LL,, DDFF==11000000 - 0| 21804AR 212 5m (Mn, 263) 021804AR-212 Sm (Mn, 2x3) . i ""8 mpsr i|/ 100n wlt i 8.0058403~ 8.00 8.13 4601 101.0.0000 1122..0000 01-Mar-2004 14:53: MRM of 5 Channels ES- 01-Mar-2004LLC/CMS//MMSS14/:5M3:S291#6/ MRM of 5 Channels ES- / rea Cancel[3 2.60e3 | AMAA ANN Pl 250 reeaoreehoer 800 i 000 eooTi 2.00 4.00 6.00 8.00 10.00 12.00 ` Exygen Research, 3058 Research Drive, State Collega, FA 16301 Exygen Research, 3058 Research Drive, State College, PA 16801 - `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACOPPURRROOTT.TEECNCTOT.IIVV2EE7-OOCRR\-DD1EE0RR-2E6E3NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00334477 m_morsserss 3M MN01538733  quantity Sample Report rege 34 Quantify Sample Report SALE onisoumn, Bes.Dater02/20/04, Anaiyetix.Rlene Study No.=LI874, Set No.=021804AR, Ext.Date=02/18/04, Analyst=K.Risha Page 24 Sacpie List: Pr\Data\LCHSUSE Nasslyme\Fivorochentcals.FRO\SampleDB\OZL804AR C3 ACTH Sample List: P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\SampleDB\021804AR CG ACSFM Be mei tian Rebar UE Tare ee Toms a MeMLetatshhtooddm::odified: PTP:u:\e\DDaMatatara\\LL0C2CMMSS1MM2SS=E06\7\M:Ma0as0sssll2yy0n0nx4x\\FFlluuoorroocchheenmiiccaallss..PPRROO\\MMeetthhDDBB\\CCoottGGrroovvee NNPPDDEESS 001122110044 ee maattiags Hon Fen 05 rob Hoe Last modified= Mon Feb 02 07:04:42 2004 = Job Code= a PPrriinntteedd:: TTuuee MMaarr 0022 1144::0055::2222 22000044 oe omseunma Name: 021804AR-212 Text= 4: co surtonste prus 4L[:1LC81876744--S11ulSSfppokknaCCt,,e1100PF00H00S00 nngg//LL,, DDFF==11000000 c21802412A$Rm (Mn, 2) 021804AR-212 Sm (Mn, 2x3) " | * u I|N t1ony ,,| 0011--MMaarr--22000044 1144::5533::229 LLCCI/MMSS//MMSS #6 MRMof 5 Chamois 5- MRM of 5 Channels ES- or wr 55E55R0 83.7707 322e3 eee ` ' ' II 200 ....... 2.00 ) ...4.4..00' 00.... ' ...6.6..00' 00.... ' ....88..0'000.... ' ....1100..' 000.0... ' ....1122..,00T00ime 5. co suttonace pros_ 5:C8 Sulfonate PFOS a [i874 Sp C, 10000 ngiL, DF=1000 1:Mar-2004 14:53: L1874-1 Spk C, 10000 ng/L, DF=IO00 (ats0aAR212 5m wn, 220) MRMof 3Gramma E5- 021804AR-212 Sm (Mn, 2x3) a |r 1 Taorss ipop)reis 1001 01-Mar.2004 14:53:29 LLCC/lMMSS/IMMSS #6I 9.15 1637 MRM of 5 Channels ES- ] 499 > 99[ 8.01e3 Area `We aLET S T T R ae ee eSaSl, 2.00 4.00 6.00 8.00 10.00 12.00 - - - Bryson Research, 3058 Basesseh Drive, State College, PA 16801 Exygen Research, 3058 Research Drive, State College, PA 16801 - CCHEOONNNNFEIDFPEIINNTDCIAOELU-NN- TSSTUYUIBBDJJIAEESCCTLTTRTITCOOT AAGPOPURRROOTT.TEECNCTOTIIVV2EE7-OO0RR1-DD1EE0RR.0E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00334488 Sw umorsserss 3M MN01538734 " auantity Quantify sample sample RRTeeppEoorrtten oats0uan, mat.Dater02/20/04, Meaiyetim.nieha rage 25 Page 25 a epLSSSataatsmmuhtppdarllynmee:oNadoLLi.iifss=titLm::eId8=7P4i,SBTP\ru:De\SpaeDeaMttatataerNa\\o\L.LLr 0O=2CCI0~HU2S1B1SM2S8E=Sr E006\47\ahA:MseR0ass,0sr issyl2ym0yEm0cxna4tx\.\\lDFualFstureolo=r0cou2hc/heo1en8mc/ria0cl4oa,sl.csAP.nhPRBaRROlOOe\y\\SsSHnatam=mAtpKpDL.lBoaRe\DiDCasBBoh\\lta02G21sr14o80.v044eAARNREDCCEOGSAAC0CS13FS1M04 MLioeanttShtocdema=oandt:itfiiaesds= Hon res bs or sorsds pont P=\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\MethDB\CotGrove Mon Feb 02 07:04:42 3004 NPDES 012104 or Job Code: me er 03 a00m32 2008 Printed: Tue Mar 02 14:05:22 2004 orpmy omens Name, 021804AR-213 Text= i1:: CCE6 AAcciiddPPPFH}IAA _ -_ a. [LL11887744--11 SSppkk CC,, 1100000000 nngg//Lh,, DDFF==110000 |C02211880044AARR-221133 8m Sm (hn, (Mn, 2)2x3) | ase8.48 95428 0011--MMaarr--22000044 1155::1155:1:1f 0 LLCC//MMSS//MMSS #6 MofRCraM nnel ES. MRM of 5 Channels ESTia 200 313 > 269 44..22776e55] reaArea 1| 2.00 4.00 6.00 o 2: |: oL1Cp8874aA1gciiSdtpkgPFCrO,Ao02n0.00_00__ngiL, 4.00 DF=100 6.00 L1874-1 Spk C, 10000 nglL, DF=100 0o22211880044AARR-221133 $m Sm (hn,2) (Mn, 2x3) w a" 95428~ TT 88..0000 488s5.29e607 a -- 1100..0000 1122..0000 G-Mar-2004 15-7571 01-Mar-2004 15:15:11~ LLCC//MMSS//MMSS #t~ MofR 5GhaM nnool>s 356-0 Sooo] MRM of 5 Channels ES413 > 369 2.50e6 eaArea } pharm pemessr ge - o 3% ah Wa we 7%Time 33[:.LT8cC7e44-sS1uutlStfpooknnaaCtt,ee120Po.00Fe0B0mS0 ngiL, 4.00 DF=100 oo6.00 8.00 10.00 12.00 OT Mar 2004 15:15: - o2p 1804AR 213 8m (hn, 2) L1874-1 Spk C, 10000 ng/L, DF=100 021804AR-213 Sm (Mn, 2x3) an 01-Mar-2004 15:15:10 LCIMSIMS LC/MS/MS #6 MRM of 5 hanni a ES- MRM of 5 Channels ES- 8.13 299 > 99 - 4106 ea 11..7777ee44| "% Area .| i| 200 Pr) a0 500 00 2% 2.00 4.00 6.00 8.00 10.00 12.00 ,aill Sxyoen Research, 3058 Research Drive, State College, PA 16801 Exygen Research, 3058 Research Drive, State College, PA 16801 - `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NTSSTUYUBBIDJJIAEESCCTLTTRITTCOOT AACOPPURRROOTT.TEECNCTGT.IIVV2EE7-OOGRRu-DD1EE0RR.2E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00334499 auorsasTas 3M MN01538735 " Ww qQSuueaannattiiytfyy.sSEaammeppll,ee RReeSeppeoo.rrttonte0man, Bxt.Date:02/16/04, Analyst. Risha sage 26 Page 26 SSSSaatanmumpEpdllyemeoNLdoLi.iist=stiLt=e1d8:74,oPB=re\\SeDDMtAaaCtrRNao\\.LL0=C3C0HM2B1S1M3M8S1S0S064\7\AW1MRa0a,s0sssl2ly0Eym0xnx4tx\.\FDFialutuoeor=ro0oc2ch/he1en8mi/ic0ca4al,les.A.nPPaRRlOOy\\sSStAam~mpKpL.leReDiDBsBNh\Ga0Z211A80044AARR CG CG ACS ACSFM PR TSaontcmoadcaitied: Last modified: Method: Last modified: WTPeu=ne\DDaMeatatbara\L0L032CMES017M21:S00647\1=Ma04ag03assyl2200yr00n44x\eFlu\oroFchlemiucaallaos..zPRROOo\\WMeecttAhDDhBB\\eCCoottmGGrrooivvee Mon Feb 02 07=04=42 2004 NPDES B-PDES 012104 012104 & JsonbinCtoedae= mee war 02 1005132 2008 Printed= Tue Mar 02 14:05:22 2004 ame: 02300033-213 Name= 021804AR-213 nn Text: 4: ce surtonate pers 4: C6 Sulfonate PFHS a |LL11887744--11 SSppkk CC,, 1100000000 nngg//LL,, DDFF==110000 i(020182041A6R0-22114334SS8mm (Mn, (Mn, 2)2x3) *) oo _ 0011--MMaarr--22000044 1155::1155::11(~ LCIMSIM#S LC/MS/MS #1~ MRMof 5 Channel ES- MRM of 5 Channels sr 3% > 60) 8.77 399 . 80 a2 20004 2.69e4 eaArea 'ol| I 200 400 500 1) A100m 0 e 200 , .... , .... , .... , .... , .... , .... , .... , 5,-2, 1, ,~, .... ,,,,,,,~,,\,Time 2.00 4.00 6.00 8.00 10.00 12.00 5. co sutonate pros _ 5:C8 Sulfonate PFOS 4 [L774 spk C, 10000 ngiL, DF=100 07-Mar-2004 15:15: 51874-1 Spk C, 10000 ng/L, DF=100 i0v21602143A$Rm (in, 2) MRMof 5 Channols E5- 021804AR-213 Sm (Mn, 2x3) ` | v9i1d5o 957oei>e5ad9 i! 9.15 14840-~ 01-Mar-2004 15:15:10 LLCC//MMSS//MMSS #6 MRM of 5 Channels ES499 . 99 7.54e4 Area - 0 2% wo 60 abo Too ZoTim|e ,! ' , .... , .... , .... , .... , .... , .... , .... , .... , .... ~ .... ,, ,',, ,Time ,,me 2.00 4.00 6.00 8.00 10.00 12.00 [,]| ` Sxygen Research, 3058 Ressssch Drive, State College, TA 16001 Exygen Research, 3058 Research Drive, State College, PA 16801 " `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACOPPURRROOTT.TEECNCTOT.IIVV2EE7-OOCRR\-DD1EE0RR-2E6E3NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00335500 _MorsseTss 3M MN01538736 u 4 QQSuuiaaunndttyiitfNyey..SsLaaamm8pp7llAee,RReeSppaootrrtNto.:021804AR, Rxt.Date:02/18/04, AnalystiX.Risha Praaggee 27 Study No.:LI874, Set No.:021804AR, Ext.Date:02/18/04, Analyst=K.Risha 4 MLSGSaaaaasmnmhtptplalmemeroosdLLhiiifssftiti::eedd=: TTPuo=P\ea\DDraWMa\taatarraD\\LaL00C32CtHMSaS11HM32\S1S=6L00677\NC5=Ma00aNs00sSas1l22My00ySn00n44\xSF\\lFulaucsorrosoclchheyenmmiicccaa\llaFs...lPPFRuRROOOo\\\SrSNRaeommhpcpOLlRhee\DDeCBBno\\tO0iGZ2crL1Oo8aOv0lNe4AAaRKRFDCCEGGSAACC0SS1F2T1MH04 MLoLeaantsshttocdomm=sooeda:itfiieedd:: hon Fa 03 07104143 2008 P=\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\MethDB\CotGrove Mon Feb 02 07=04=42 2004 NPDES 012104 I JporbtncCeoad:e= Tue Mar 02 14:05:22 2004 Printed= Tue Mar 02 14=05:22 2004 oO p---- Name= 021804AR-214 Text= 1i:: cC6e Anecsid oPrF~nIA 4 [LL11887744:-55 SSppkk DD,, 1100000000 nnggi/LL,, DDFF==110000 ln002211880044AARR-221144 Sm Sm (Mn, (Mn, 23) 2x3) ,i 1u1e i,| li saa8s.i4ss8 z 0011--MMaarr--22L00o004m4 s115i5::m33s66::48 MMRRMM ooff 55LCCChh/aMann1nSne3/elMl>ssS2EE6SS#.0-6 31320>"42r06o59a) 2.04e5Area ' ~,....25, 0.... -, ....40, 0.... , ....50, 0.... , ...4 .80,3 0..4 .b .~, ._ ...1e 0,00.... r ,?~, ,7~20TT0iimmee , I 2.00 4.00 6.00 8.00 I0.00 12.00 4 22|L:1cC8874.nA5cciipdekPrFDoO,nA10000 nglL, DF=100 01-Mar-2004 15:36:4 L1874-5 Spk D, 10000 ng/L, DF=100 . (021804AR214 Sm (Mn, 263) | 021804AR-214 Sm (Mn, 2x3) 0M1R-MMaorf-25LL0CCo0hl4MaMnS1nSIe5/l:MM3sSS6E:S4#.8~ 882388 MRM of 5 Chan44n1e3l12>s>23E0336S0695- 8.98 % rea 2.20e5Area ! . | L O 200 r am r 500 800 , , .... , .... , .... , .... , .... , 3.8.2..68,~ 2.00 4.00 6.00 8.00 33[.L:1C8c47u4s-Su5ullSffpooknnaaDtt,ee10oP0FrB0sS0 ngL, DF=100 - L1874-5 Spk D, 10000 ng/h, DF=100 21604 214 5m 0,269) z021804AR-214 Sm (Mn, 2x3) a1 Lf u 100t 18.1433| ] " %1 Le ` 0 22.0000 a04.00 66.0000 88.0000 Time ,,, .... ,-:-~,, ,-, Time 1000 200 10.00 12.00 0OFt-MMaarr-22L0000o44 1ts55:3s366.:4488 LClMS/MS #6 W5 hal nna 5. 700559 MRM of 5 Channels ES- Toed 299.a`>Alre9e9a 1000 1200 10.00 | Time 12.00 " Ecygen Research, 3058 Research Drive, State College, PA 16801 Exygen Research, 3058 Research Drive, State College, PA 16801 - `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEEASCCTLTTRTITCOOT AACOPPURRROOTT,TEECNCTOT.IIVV2E7E-OOCVRR-DD1EE0RR28EE8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00335511 _3MMNMON10S135B38T733T7 4 qSQutuauandnttyiiffNyyo.SsLaa1mm0pp7ll4ee, RRSeepepotorrtNto.:021004KR, Ext.Date:02/10/04, AnalyatiX.Risha PPaaggee 2288 Study No.=LI874, Set No.:021804AR, Ext.Date=02/18/04, Analyst:K.Risha SGSaaasnmptpllemeodLLiiifsstti::ed: TPPu::e\\DDNaaattraa\\LL03OCHMSS1KM2S:S606\7\K:Ma0a0ssssll2y0yn0nc4x\\PFlluuoorroocchheenmiiccaallss..PPRROO\\SSaammppllaeDDBB\\O0Z2L188O044AARR CCGG AACCSEFPM 4 MMLLeeiattsshhttoomddma=sosdtitfiieedd:: MTPou:\ne\DDaMaTtaatarba\\LL00C32CHMSS01KM72S1S:0066 47\K1:Ma04as03ssll2200yy00n44xn\F\luPorlocuhecmircaolsc.FPhRROOe\\NMenetthihDDBcS\\CaCootltGGraroovv.ee KNFPDDEESS 001122110044 Ton coda Last modified: Job Code: Mon Feb 02 07:04:42 2004 M Pprriinntteeda:: TTuuee MMaarr 0022 1144::0055=:2222 22000044 NmTaemtee= oman 021804AR-214 Text= 4 [44:1:8Cc76s4Ss5uwlsiffpoonnkaa,ttee10pPFr0Hi0Ss0 ng, BF=Te0 1| L0121887044-A5RS2p1k4 D, 10000 ng/L, Sm (Mn, 263) DF=100 [IE021804AR-214 ,,ii Sm (Mn, 2x3) uw | * a87888.7s 4268~ 0011--MMaarr--22L00O004M4 S115I5::M336S6::4488 MRM MRM of of 55LCCChh/MaannSnn3/elMlss9SEES>S#81-0-~ 32293.3"0>r00ee84a40)l Area " | ok , 200 -- 400 .... , .... , .... , .... , ....60, 0....er, r....80, 0: ;B , , , ...e .10~00....e , ....20,0plleme 2.00 4.00 6.00 8.00 10.00 12.00 Wf 55[:L:TC8c87o4:sS5uullStfpooknnDaa,ttee10PpF0rOo0Ss0 ngiL, DF=100 01-Mar-2004 15:36: L1874-5 Spk D, 10000 ng/L, DF=100 0218044R.2S1m4 (Mn, 263) 0M1R-MMoafr-25LL0GCO0hIM4aMnS1nSIa5/iM:M3sSS6E:S4#-86 PREC021804AR-214 Sm (Mn, 2x3) 2s95.15r75 MRM of 5 Channels ES- 991.>45400 499 > 99 i 251 `area 1.44e4 Area 4 - 11O /1 ....Tr ar TTrrTape"TT The 2.00 4.00 6.00 eer Time| . : ....... r aoe oo ize) 8.00 10.00 . ~ Time 12.00 . ' . EEAe-yyggeenn RReesseeaarrcchh,, 32005580 RReesseeaazrcchh DDrriivvee,, SSttaattee CCoolllleeggee,, PPAA 1166880011 - `CHEOGNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIJDJIEAESCCTLTTRTITCOOT AACPOPURRROOTT.TEECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR.2E6E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00335522 SW_MNo1838738 3M MN01538738 quensity sample napoct rage 22 Quantify Sample Report WBE onsen, mee oasesoa/a0/00, seniyetix.sisha Study No.=LI874, Set No.=021804AR, Ext.Date=02/18/04, Analyst=K.Risha Page 29 Semple Lists 9r\oata\ LOBES Wassiym Fozochemical.PRO\GamplaDI\OELARAAR CG ACEP Sample List= i REA Cg Lest modified= a Eni assyae\FiuozocPhEO\eienhiDBc\CaotlGzso.va NEDAS 012104 Method= een maattieas Hen a os es Bons Last modified: a Job Code: P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PR0\SampleDB\021804AR CG ACSFM Tue Mar 02 12:07:00 2004 P=\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\MethDB\CotGrove NPDES 012104 MOrt Feb 02 07:04:42 2004 Ml ePrriinnteeeda:r TTuuee MMaarr 0022 1144::0055::2222 22000044 sume: aaato0s228 Name: 021804AR-215 4m Text: Goce: C6 Acid PFHA o LL11887744--99 SSppkk EE,, 1100000000 nngg//LL,, DDFF==110000 czte0anr.251m5 in 2) 021804AR-215 Sm(Mn, 2x3) . 100, 1 10887.4498862 0011--MMaarr--22000044 1155::5588::33 Lemsivs LCIMS/MS #6 MRMof Cramels 5. MRM of 5 Chan3 3n1e3l1 s>>2E263 S60-9] 4.90e5| Area 4.90e5Area a *! | rrr Tine , .... , .... , .... , .... , .... , .... , ...1.07,99.2.~.. , .... , .... , .... ', Time ` 7% pr) P) Tho oo 2% 2.00 4.00 6.00 8.00 I0.00 12.00 2+ cu peta oron _ 2:C8 Acid PFOA 4 [79 SpKE ono ng DF=t00 Giwara00155d63 51874-9 Spk E, 10000 ng/L, DF=100 c21804AR215 Sm i, 24) MRM of 5 Cramnas 6- 021804AR-215 Sm (Mn, 2x3) n os pial 1 01-Mar-2004 15:58:33 LLCC//MMSS//MMSS ##66 MRM of 5 Channels ES- 8.96 413 > 369 | w a So=re' 566511 3.01e5Area iw | LT| tThrrrerrggrea rerereh ppererreegpar5 eerereo preo eBrm eee ge| 000~.~~o'-~...~q" .... , .... , .... , .... ~ .... , .... , .... , .... , .... T.... ,;' ..~,Time 2.00 4.00 6.00 8.00 10.00 12.00 2+ cu suttonate pres 3:C4 Sulfonate PFBS LL11887744--99 SSppkk EE,, 1100000000 nngg//Lh,, DDFF==110000 - Lomsis ,m czts0aAR2155m 0, 2) MoR f 5 ChMal 5- 021804AR-215 Sm(Mn, 2x3) i an oo - 1 | 1%li 880.2133 0011--MMaarr--22000044 1155::5588::33:3 LCIMS/MS #6 MRM of 5 Channels ES- 2939..44>88e9e494) AArreeaal . | iole eir a l I) eooe o aTe 0~" ,- , , , , , , , , , , , , Time 2.00 4.00 6.00 8.00 10.00 12.00 " Eeygen Reseach, 3058 Resescch Drive, State College, PA 16801 Exygen Research, 3058 Research Drive, State College, PA 16801 . CCRO,4ONEFNNIFNDIDEEENRNTITCIAAOLLUN- STSUUYBBDJJIEESCCTTTRTITCOOTAPACROPUORRTOTE.TCENTCGIT.IVV2EE7 OOORRuDD10EE.RR28EE8NN6TT3EERREEDD ININ HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00335533 sw_otsssss 3M MN01538739 Wu SqQuuuaaunndttyiintfayy.ssLaaImmOppNll,ee RReeSppeookrrtNto.:021004A%, Ext.Date:02/38/04, Amalystix.Risha PPaaggee 3300 SLSSaaatsmmutppdlylmeeoNdoLLii.ifs:stitL:=eId8:74,TPPo:rsS\\eDDtWaaattrNeao\\.L0L:3CC0HM2S1S1H3M8S1S0E064\7\AM1MR0aa,0ssssi2ly0Eym0xnx4tx\.\FDFialutuoeor=ro0oc2ch/he1en8mi/ic0ca4al,lss.A.nPPaRRlOOy\\sSStaa=mnKpp.lLReeiDDsBBh\\aO0Z211880048AARR CO CG ACSF ACSFM a JMLvLLoeaaaetbsssrhtttnocodommmn=doooacdd:iiifftiiieeeddd:=: PMTPou=\ne\DDaMFataatarba\\L0L0C32CHMSS01HM27S=S10607\H1=Ma40as30sssil22y00ym00nx44x\\FFiluuoorroocchheenmtciaclasl.s.PFRROO\\MNeetthhDDBR\\CCoottGGrroovvee Mort Feb 02 07:04:42 2004 NNPPDDEESS 001122110044 I pJorbioCeodd:e: Tue wax 02 14:05:22 2004 Printed: Tue Mar 02 14:05:22 2004 aoNNaarmmee=s 002211800040AR--221155 T4:extc=o sultanate ms _ i [11674 Spk E, 10000 4:C6 Sulfonate PFHS L1874-9 Spk E, 10000 nnggi/LL,, DDFF==110000 002|211880044AARR-221155 Sm Sm (Mn, (Mn, 258) 2x3) ii 0011--MMaarr--22L00o004m4 S11I55::M55S88::333 077 MRM MRM of of 55LCCChh/aMannSnn2/eeMllsS>%EESS#81.0-~ ear8.77 39229.55`>1r1e0e8a440, Area wo 48411 0meeBOe TE Tine| , .... , .... ~ .... ~ .... , .... , .... , .... ~ .... , ............ ,Time i 2% 40 500 800 1000 200" | 2.00 4.00 6.00 8.00 10.00 12.00 5: co sulfonate pros 5:C8 Sulfonate PFOS 4 [L18749 SpkE, 10000 ngiL, DF=100 01-Mar-2004 15:58:3 L1874-9 Spk E, 10000 ng/L, DF=100 ' 0o2e1802415ASRm (Mn, 233) sis MRM of 5LCOhManSn0IelMs9SES>5.9 021804AR-215 Sm (Mn, 2x3) 01 -Mar-2004 15:58:33 LC/MS/MS #6 MRM of 5 Channels ES- 9.15 499 > 99 srs 2.o0a04) 2.04e4Area *% i repre reerBe Time , .... , .... , .... , .... , .... , .... , .... ,., 3.7,7,5~.... ~ .... , .... ,Time - TT am abo 600 800 1000 200 2.00 4.00 6.00 8.00 10.00 12.00 " a a Exygen Research, 3058 Ressszch Delve, State College, PA 16601 Exygen Research, 3058 Research Drive, State College, PA 16801 " `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACOPPURRROOTT,TEECNCTOT.IIVV2E7E-OOCVRR-DD1EE0RR28EE8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00335544 _MNOIS3B740 3M MN01538740 u gQSuueaaannyttiiafeyy ssTaammppRllee RReeppoorrtNte conmeoun, mer.Datesca/20/00, Asstyatox.nisna Praaggee 3311 Study No.:LI874, Set No.:021804AR, Ext.Date:02/18/04, Analyst:K.Risha SGSaeanmmeppllmeeodLLiiitsstit::ed:prDP\o:De\aDcMaeat\raL\C0LH3CSMM1SS3ME1S\067M\1aM0sa0sslsy2l0my0ne4x\\FFlluucorroocchheenmiiccaallss..FPRROO\\SSAazmppLleeDDBB\\O0Z211A800M~AARR CCGO AACCSSFTM a oTant cmaeditied: wen Tob 03 0704s 2004 MeMLetatshhtooddm:=odified:P1TP\u:De\aDMatatara\\LL0C2CMMSS1HM2S:S606\7\M:Ma0as0sssll2y0yn0nx4x\\FFlluuoorroocchheemmiiccaallss..PPRROO\\MNeetthhDDBB\\CCoottGGrroovvee Last modified: Mon Feb 02 07:04:42 2004 NB-PPDDEESS 001122110044 HU pJorbinCcoedse: Tue war 03 16105023 2008 Printed: Tue Mar 02 14:05:22 2004 (meme onsen Name= 021804AR-216 I! Text: 4 [L1i::187cCo464rA0ec3iiSddpoPkFmHFA, 10000 nglL, DF=100 L1874-13 Spk F, 10000 ng/L, DF=100 (02126160S4mA(MRn, 2) 021804AR-216 Sm (Mn, 2x3) w| asiss8.48 44006~ 0011--MMaarr--22L00C00I44M11S66I::M2200S::1%9 MMRRMMooff 55LCCChh/aMannT3nSn1iee/3leM2lss.>S1E2E250SS600.-95) ea 2.15e5 Area 1 | 200 .... , .... , abo .... , .... , 500 .... , .... , ....ab~ o.,... , ...e .10, 0....e , ....20,0TTimmoe | 3. cancie sro ,,| 2.00 4.00 6.00 8.00 10.00 12.00 Wu 2L[:1LC8187847-4A11c33idSSppPkkFFOF,A, 1100000000 nnggi/LL,, DDFF==110000 0011-.MMaarr--22000044 1166::2200::1199 021804AR216 5m (Mi, 23) EE021804AR-216 Sm (Mn, 2x3) 36s80.s9s8 M MRMoofR f55LLCCCChh/aIM ManMnn>SSne/e/lMlsMsSa SEE5S#--6 4132>1136659 | 390~u | rea 2.1 le5 Area i |% ,i,| | Oe re rrr eB Tine LL 200 abo 2.00 4.00 33[:L:TCc84174-sS1uu3ltfSoopnnakactFee, 1Po0Fr0BesS00 ngiL, DF=10_0 - L1874-13 Spk F, 10000 ng/L, DF=100 0218044215m6 (in, 23) 021804AR-216 Sm (Mn, 2x3) - 1 | 100. 6B.0000 88.0000 1100.0000 20 12.00 _TOT iMar200 16:24 0:19) 0M1R-MMaorf-25LL0CC0Ch/4MMe1SnS6/n:MI2e0SEMl:S1##s9S-6~1 MRM of 5 Channels ES- / iosa8.114 229099>> 9999/ 70`1a6a3, 7.01e3! Area! | 4 ] |b NN . 200 abo 550 ab i000 200 2.00 4.00 S.00 8.00 10.00 Time 12.00 ' Exygen Research, 3058 Resassch Drive, State College, Th 16001 Exygen Research, 3058 Research Drive, State College, PA 16801 . `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACOPPURRROOTT.TEECNCTOT.IIVV2EE7-OOCRR\-DD1EE0RR-2E6E3NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00335555 a_Morsseen 3M MN01538741 Wu qQSuutaaundntytiiNffoyy./SsLaa1mm6pp7ll4ee,RReeSppeootrrttNo.:DILSOAR, Ext.Date:02/18/04, Amalyat:K.Risha sPaaggee 3322 Study No.=L1874, Set No.=021804AR, Ext.Date:02/18/04, Analyst:K.Risha SSLaaammaptpllmeeodLLiiifssitte=:d:PiTP\u:De\aDtNaaat\raL\CL0M3CIMN1S2MI:SG06\7\N:Ma0as0sssl2ly0yn0ne4x\\PFlluucozroocchheenmiiccaallss..FPRROO\\SSaammpplleeDDEB\\O02211880044AARR CCOG AACCSSTFMH 4 LeMLeaattsshhttoodmms:ooddiiffiieedd:: HTPPou:1ne\\DDMaTaaattbraa\\L00L22CCMH0S1H7M2S::S600647\\::MN40a20sas2l2s00y00sn44x1\Fylunoxro\chPamliucaolsz.PoPRROcO\\hHMeeetHnhODiBB\cCCooattlaGzrsoovv.ee NNPEDEESS 001122110044 oLabstcomdoedrified: Mon Feb 02 07:04=42 2004 Job Code= id pPrriinntteead:: TTuuee MMaarr 0022 1144::0055::2232 22000044 | m~eammee:= o02s18e04aAnR-n21e6 Text= { 44:[:LC1c86s7s4S-u1ui3ltfSoopnnkaacFte,e 1Pp0Fr0HisS00 ngiL, DF=100 L1874-13 Spk F, 10000 ng/L, DF=100 021804AR218 Sm (Mn, 29) + [001 021804AR-216 Sm (Mn, 2x3) i 0* 0011--MMaarr--22L00C00I44M11S66I::M220S0::119 sn MRM MRM of of 55LCCChh/aMannnSn3ee/lM9lss>SEE8SS#-0-6) S8.4707 3929.A1>r8e80a40 | CE 0L ,~>--~-,,, ....a,e.... , ....40, E 0.... , ..6..0, 0.... , ...s.o, o.... , 2.00 4.00 6.00 8.00 55::CC8o Ssuullffoonnaattee pPrFoOsS _ wu |[187413 Sp, 10000 ngiL, DF=100 01-Mar-2004 16:20:18] L1874-13 Spk F, 10000 ng/L, DF=100 4 00:2128014AR82-210166S4SmmA((MMRnn,, 226x33)) 2925.112886 i= ..t..S oo,,o,s -;~-. ~~ ,,-,,1. ~2,0,. T0im|e 10.00 12.00 0M 1-MoarfR -52LL0CCC0hI/4aMM Mnn1SSa6I/iM:sM2SS0E:S1##-966 MRM of 5 Chann45e99l19s.>5>E3S09949-9]) Area 1.33e4Area | feo A - 256 50 600 800 1000 200 , .... , .... , .... ~ .... , .... , .... , .... , ..2..52,6.~.. ~, .... , .... ,Time 2.00 4.00 6.00 8.00 10.00 12.00 " ` . Exygen Resessch, 3058 Research Drive, State College, PA 16801 E~ygen Research, 3058 Research Drive, State College, PA 16801 . `CHEOGNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIJDJIEAESCCTLTTRTITCOOT AACPOPURRROOTT.TEECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR.2E6E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00335566 SW_no1s38742 3M MN01538742 . 4 QSQeuuaaalnnyttiitfneyy. sStaanmmTppellLee,RReeSppEoorrNtte.0210048, Ext.Dater02/10/04, Amalyetik.Risha Page 33 Page 33 Study No.=LI874, Set No.=021804AR, Ext.Date=02/18/04, Analyst=K.Risha 4 NLSLSaaaaatsmsmhtptpollamemerooddLLiiiiffssiitt=ee:dd:=P:TTP\~u=D\ee\aDDtaNMaataat\arraL\\CLL00MC23CHSMSMS11HSM22SS:S=\600BM77\N:a=Ma00sas00ssalslyl22y0n0yn00xnx44\x\\FFFllluuuocorrroooccchhheeennmiiicccaaallleas...PPFRRROOO\\\SSNaaAnmCppHllDeeEDD\BBC\\o00t22G11r68o00v44eAARNREDCCEGGSAACC0ES1T2F1HM04 MLGLeaaatssbhttocdomm=dooecdsiitfiieedds: Won Fab 03 57104143 2004 P=\Data\LCMSMSB\Masslynx\Fluorochemicals.PRO\MethDB\CotGrove Mon Feb 02 07=04=42 2004 NPDES 012104 Job Code: A rPrriinntceeda:r TTuuee MMaarr 0022 1144::0055::2222 22000044 d (emo NTeaemxret== 0c2a1v80s4oAmRw-2a1r7 3: co acta smn oo W IL[:L118C876744--A14c77idSSppPkkFHGGA,, 1100000000 nnggilLh,, DDFF==110000 310002201188;0044AARR-221177 $m Sm (Mn, (Mn, 268) 2x3) Ii 1 ES ried 0011--MMaarr--22L00C004/4 M116S6::/442M2#:S:13 18 MRM MRM of of 55LCCChh/aMann3nSn1oe/3lMls.sS2EE6SS#0-~- 8.48 313 > 269 3.3"a1vea5l Area Ll *1 '1 200 400 2.00 4.00 4 22[::L1c8C8a74.Aa1cc7iiedSppPkrFoO6nA, 10000 ngiL, DF=100 L1874-17 Spk G, 10000 ng/h, DF=100 |f002a211e880044AARR-221177 Sm Sm (Mn, (Mn, 23) 2x3) i |* { eB gi - 200 2.00 Ta4.0m0 33[:L:1Cc84a74-sS1uu7lltfSoopnnkaattGee, pP1rF0Bm0S0S0 nglL, DF_=100 - L1874-17 Spk G, 10000 ng/L, DF=100 021802417ASRm (Mn 28) - [ty 021804AR-217 100 Sm (Mn, 2x3) I.% 41 obe etl r tie PM 200 400 0 /~ ,j 2.00 4.00 600 500 6.00 8.00 888.99288 606.00 B8.0000 s86e.e11r3s 500 800 6.00 ~ 8.00 en Time | , .... ,, , ~-'. ,Time 1000 200 10.00 12.00 0011--MMaarr--22L00C00I44M11S66I::M442S2::113 M MRMoofR f55LCCChhIaM Mannn1Sna3e/'Mlss>SEE3SS#8-0-6 41344.>22r113e6e6a559) Area 1100.0000 200Time 12.00 0011--MMaarr--22L00C00M44S11I66M::44S22#;:113631 MRMof MRM of 55LCCChhlMaa2nSnn29e/9MnSl9s>oEeSt>ES9leS#9d-0s-96||// 5.91 e4 rea]|| Area 1000-- 10.00 1200 | Time 12.00 * EExxyygoeenn RReesseeaarrcchh,, 33005588 RReesseeaarcchh DDrriivvee,, SSttaattee CCoolllleaggee,, PPAA 1166880011 a `CHEOGNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIJDJIEAESCCTLTTRTITCOOT AACPOPURRROOTT.TEECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR.2E6E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00335577 SW_MNo1S38743 3M MN01538743 " W GQSuutaaunndttyiifNfyoy.:sSLaaimmopp7ll4ee, RReeSppeootrrtMto.:021604AR, Bxt.Date:02/18/04, AnalystiK.Risha PPaaggee 3344 Study No.;LI874, Set No.;021804AR, Ext. Date=02/18/04, Analyst=K.Risha Wo SLeLSaaeatssmmhttppollsmmee:ooddLLiiiiffssiitte::edd:=P1TPT\uu:Dee\aD1tMMaaaatcr\a\L\CL0022CHDMSS11UM22SA1S:E006\77\eC1:Ms00as00slsRsy1l22ny00yxm00n\\e44xP\\PlFLlulucuirooCorFcoohccHehhneeminEiicccaeallMlsas...PPSPRRROO\O\SSNSeaEmm\ppDllBee\KDDCBBo\\0ta02G21F16so800v44eAARNRPDCCEGGSAAC0CS1F2T1M04 MLJLeaoatSbshttocdomm:dooeddriitfiieedd:: Mon Feb 02 07104147 2004 P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\MethDB\CotGrove Mon Feb 02 07:04:42 2004 NPDES 012104 Job Code: Psrriinntteeda=: TTuuee MMaarr 0022 1144::0055=:2322 22000044 | MNeammee:; o0a2t1s8e0s4aAnR--221177 Text= 4 44[: :L1CC86674sS1uu7llffSoopnnkaattGee, p1PEF0HE0SS00 nglL, DF=100 ||L0128187044-A1R72S1p7kSGm,(1M0n.0020x3)nglL, DF=100 it 021804AR-217 Sm (Mn, 2x3) |% _ e88a.7r77s7 01-M_ar-2004 16_:42:1: 0M1R-MMoafr-25LL0CCC0h//4MaM1nSS6n//M:sM4SS2E:S1#-63; MRM of 5 Channels ES- 3%35>4804) 399 . 80 `Area 3.54e4Area i 1 ' 200 .... i .... ~ 400 .... i .... i 600 .... ~ .... ~ ee .... ~ .... i .... ~,, 800. 1000 6475~ 20T0 e ,~~Time 2.00 4.00 6.00 8.00 10.00 12.00 5: Co sulfonate pros _ 4 5L[L:11C8878744--S11u77lfSSoppnkkatGGe,, P11F00O00S0000 nngg//LL,, DDFF==110000 0011--MMaarr--22L00C00I44M11S66I::M4422S::113 4 |002o211o880044AAPR,2-21177 Sm Sm (Mn, (Mn, 23) 2x3) or MRM MRM of of 55LCCChhIaMannnSn9ee/'M9lssS>EESS#0--69 11 593.197 49299A.0r49a)9l 5] 5539~ | 2.93e4Area . LZ ry heer Time , .... , .... ~ .... , .... , .... , .... , .... , .... , .... , .... , .... ,Time 200400 600 800. 1000 200 2.00 4.00 6.00 8.00 10.00 12.00 ,a " ",1111 " EExxyyggeenn RReesseeaarrcchh,, 33005588 RReessseaazrcchh DDrriivvee,, SSttaattee CCoolllleeggee,, PPAA 1166880011 " `CHGEOONNNNFFEIIDPDEIENNNTTCIIAOALLUN-- STSUUYBBDJJIEESCCTTTRITTCOOT AACOPPURRROOTT,TEECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR.2E6E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00335588 IM_MNO1S38744 3M MN01538744 PM qQSuuaannttEiitfyyIsSaammppTllee RREeeppoorrtt omens, mxe.oater03/30/04, anadyetim.misha Psaaggee 3355 uw tSELSSaaatsrmuotppdnllynmeeoNdkLoLiii.fss:titLi::eId8=74,PPTPru:e\SoeDiuhMtateatenrNa\\o\.LL0b:e2CuD0Mb2S1r1M28:aSe006ey47\\A:tMcR00aa,00tsssaLlTy2yh0yEe0xnma\at4x.\sFDFial\LutuoeoFr=rCo0oic2ch/hvHe1en8moi/ic0Icra4al,loasS.A.cFnPRRaRhOOOlO\\y\eSHsSa\etanm=mtpKphilW.lDaReDcDiD\aCsBaa\oh\Ota0iZO2s3r1sAo80v0.s4e4AARNRPDCCEGOSAAC0CS1SF2I1M04 MLLSeaaatsrhteoadmma:oda!iftiieedd:s Yon Feb 05 070d Thre P=\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\MethDB\CotGrove Mon Feb 02 07=04:42 2004 NPDES 012104 JpoebiavCeoadre= Tue var 03 1105132 2008 Printed: Tue Mar 02 14=05=22 2004 Samar an600n 718 Name= 021804AR-218 [I~ Text= Ep. 4 iX[:XCC0C062222A44c00i44d-11,P, F22H55Annggi/LL SSttaannddaarrdd c21604AR 2185m tn, 2:0) MRM 0 5 Cranmots 5. 021804AR-218 Sm (Mn, 2x3) foo; ss Tanae0 00 ] o jo % 8.48 L9o490--~ 0O1l--MMaarr--22000044 1177::0033::59 LLCC//MMSS//MMSS #6 MRM of 5 Channels ES313 > 269 44..99000e44| Area "a 25 4b oh a a------2 Or m TEr I pee Ti 0' ,-T~, ,, .... , .... , .... , .... , .... , .... ,,, ,-~~~~-"'-'~"~, Time 2: co seid 2eon _ _ 4 [2XX:CCC0082222A46c00i44d-:1,P, F22O55AnnggiihL SSttaannddaarrdd cztsoaar218 5m (n 20) ry MRMOrSCramos ES. 021804AR-218 Sm (Mn, 2x3) a |o; oh arspeeoe 1 0011--MMaarr--22000044 1177::0033::550 LLCCl/MMSS/M/SM#S#~ MRM of 5 Channels ES- 8.98 413 > 369 Area |% | A Oe eer) Time | 0~T. ~., .-...-:~-~,, ~ .... , .... , .... , .... , .... , .... , .... , ....~Time . 35 Ww 5% ab om 20 2.00 4.00 6.00 8.00 10.00 12.00 3. co suitonste pens 3X(X:CCC00422224S40u04l4-f-1o1,n,a22t55e nnPggFl/BLLSSSttaannddaarrdd - c221608AR 2185m(0 250) MRM of 5 GhannoE'5s- 021804AR-218 Sm (Mn, 2x3) or Tensss = 01000yq 0011--MMaarr--22000044 1177::0033::5g LLCCIIMMSS//MMSS #6 MRM of 5 Channels ES- 2838.17 283- 29119..55>660e9339) Area o || O~Fe1 AmAAIpArNeAAe SAr NNrAr N A e[e ANe A\TiAne " L .......22..00.00 .......44...0000.......66..0~000.... ~ ....88..0~000.... ~-,,, 11,00..~ 00.00... ~ ....1122..,0T000ime " Srrsen Research, 3050 Resaseh Drive, State College, BA 16801 E~ygen Research, 3058 Research Dr~ve, State College, PA 16801 . CCHEOONNNNFEIDFPEIINNTDCIAOELU-NN- TSSTUYUIBBDJJIAEESCCTLTTRTITCOOT AAGPOPURRROOTT.TEECNCTOTIIVV2EE7-OO0RR1-DD1EE0RR.0E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00335599 Suumorsseres 3M MN01538745 a QQSuuaaannrttiiI ftyy sSaammppllee RReRepepo.orrttons0an, Extate:02/10/04, Anatystix.nisne Praaggee 3366 SSSSaetanmumepdplylmeeoNdoLLi.iiz:ssitLte:I:d8:7P4r,DP\o=De\SaeDttwaeatr\NaoL\.OL0:2HC0MS23SS13ME81S\006M47\aA1MsR0as,0slsy2lm0Eye0xn\4txP.\lDFualotuero:or0co2hc/he1em8mi/ic0ca4al,lss.A.FnPRaROlO\y\SsSatan:mpKpl.leReDiDEsB\h\0a0221188004~AARR CO CG ACS ACSFM 4 MLMGLeaeaattsnshhtttoocadmmmor=oooddddaiiiftfiiieeeddd:=s WTP7eu=ne\pDaMTataotabra\\L0L032eCMs0S172Ma1:S00647\W1=Ma40as30sssy2l200y00mn44xe\F\luPorLocuheomizcalos.cPRRhOO\eMHemtthihDOBcB\\CaCootltGEraoovv.ee Mon Feb 02 07:04:42 2004 NPDES NPDES 012104 012104 Job Code: 0 primes ve ar 02 10:08:22 2008 Printed= Tue Mar 02 14:05:22 2004 [-- Name, 021804AR-218 Go Text : 41 co sulfonate pms W 4X[:CXCC0062222S44u00l44-f-1o1,n, a22t55e nnPggFi/HLLSSSttaannddaarrdd 10218041R 218 Sm (Mn, 266) MRMof 5 Channa E5- 021804AR-218 Sm (Mn, 2x3) [ar 71 esa i ! "ara 1 i/~ 0011--MMaarr--22000044 1177::0033::59 LLCC//MMSS//MMSS #6 8.77 980 MRM of 5 Channels ES39 > 80 55..8822e33] Area w | ~M 9501 em \ | rrTine 0' .... ~ .... , .... , .... , .... , .... , .... , .... , ............ , .... ,Time 260 300 500 800 1050 7% 2.00 4.00 6.00 8.00 10.00 12.00 5: co sulfonate ros 5:C8 Sulfonate PFOS M XXCC002222440044--11,, 22,55 nngg//LL. SSttaannddaarrdd 0218044215m8 (4, 2) MofR 5LCOhaMM nSneIlMs SES 021804AR-218 Sm (Mn, 2x3) ` po , a7a6 0$5755030) i 9.16 783--~ 01--MMaarr--220004 177::03:5g LC/MS/MS MRM of 5 Channels ES499 > 99 rea 4.75e3 Area ~_~ +T a TT Te enTie| . Ta a0 660 Bho 000 200 2.00 4.00 6.00 8.00 10.00 12.00 - . " " Sxygen Research, 3058 Rasesich Drive, State College, FA 16001 Exygen Research, 3058 Research Drive, State College, PA 16801 a. `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEEASCCTLTTRTITCOOT AACOPPURRROOTT.TEECNCTOT.IIVV2EE7-OOCRR\-DD1EE0RR-2E6E3NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00336600 _MorsaeTes 3M MN01538746 Wu QQSuutaaunndtytiiNffeyy.isSLaaImmOppTllAee, RReeSppeotorrttMo.:021804AR, Bet.Date:0/33/04, Analyetix.Risha PPaaggee 3377 SSSSeaatmvmupypdllymeeoNdLoLiii.ssF:ttiL=:aId8:74,TPPir=a\\SDDeHtaattaNaeo\\.LL0:3CC0MH2S1S12MS81SE006\49\MA5MaR0as,0sssll2y0yEn0xnx4tx\.\FDFialutuceor:ro0oc2ch/he1en8mi/ic0ca4al,lss.A.nPPaRRlOOy\\sSStaa~mmKpp.lleRaDiDsBSh\\a0OZ2L1A8O0U4AARR CO CG ACST ACSFM 4 aMLTLLeaotaatSnssmhtttoocsdmmmo:=oooeaddrtiiffeiiieeeddd==s hTPou:\ne\DDaMFataeterba\\LL0023CCMS01s7M21=S00647\H1=Ma40as30sssl2L200yy00mn44xx\\PFlluuoorroocchheenmticcaallss..PFRROO\\MNeethhDDOB\\CCoottOGFroovvee Mon Feb 02 07:04:42 2004 KPDES NPDES 012104 012104 Job Code: I Pprriinntceeds=s TTuuee MMaarr 0022 1144::0055::2222 22000044 | ese: cases ,,i Name: 021804AR-219 Text= 1I:: eCo6 aAcciidd oPFrHmA _ Wu [C16741, DF=1000 SE 01-Mar-2004 17:25 L1874-1, DF=1000 021602419ASRm (Mn, 23) 021804AR-219 Sm (Mn, 2x3) a4 0M1R-MMaorf-25LL0CCO0hM/4aMSn1nSIe7MllM:S2sS5:E:S3#-86 MRM of 5 313 260) Channels ES- "8e.r4r8 3137>5et2ea6d9)| vw | _ 7.91e4Ama e sree, | " 11/1~ 0r, ,~,,, m...r.2,5.... , ....40, 0.... ~ ....50,r0..e..r,e... 16~ 80, 0 ~ 1000 12,5TT0iimmee 2.00 4.00 6.00 8.00 10.00 12.00 u 22:|:cLC1a8e7aAA1cc,iiDedF=PsFr1Oo0An00 _ 01-Mar-2008 17:25:3 L1874-1, DF=1000 y l0;20182041A8R20-211499ASSRmm((MMnn,,226x33)) ss 0M 1-MoafrR .52LL0CCo0h/m4aM Mnsn1Sei7/lM:Ms2SS5E:S3#-86 MRM of 5 35360 Channels ES- az "ares 8.98 413 > 369 ea i% LL 0 TTT ak 650 3:casulfonate 2o.r0e0s 4.00 6.00 - [Li874-1, DF=1000 3:C4 Sulfonate PFBS L1874-1, DF=1000 [|i 0a2a1t8s0o4sAaRr-z2t1s9 sm Sm wn,(Mn, 2)2x3) - | 1 i(~~~ B00 eB r 1000 e70i0| 8.00 10.00 12.00 MRMof 5 Channe5l. 01-Mar-2004 17:25:38 01-Mar-2004 17:25:38 LOMSIM#S6 LClMS/MS #6 MRM of 5 Channels ES- ar= 2297`50h6e%9a 8.13~2992"78e3Are> a 99 - *IAN AeA eSSn AAA ! ` | olor200 ao 500 p50r 0 eiaor0eeree25T0ive 2.00 4.00 6.00 8.00 10.00 12.00 " Exygen Research, 3058 Ressazch Delve, State College, PA 16601 Exygen Research, 3058 Research Drive, State College, PA 16801 " `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACOPPURRROOTT,TEECNCTOT.IIVV2E7E-OOCVRR-DD1EE0RR28EE8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00336611 _MNOIS3BT4T 3M MN01538747 guensisy sample saport [I Quantify Sample Report oo EENLEEILIIL onsous, xoater0s/ia/on, smaiyesix.sisne Study No.:LI874, Set No.:021804AR, Ext.Date:02/18/04, Analyst:K.Risha Page 38 sumple List | B\DaceLOSE Wasstyme\Fisorochenicnls FRO\SSspLaBAGALI0MN C8 Aco Sample List: pr reMe ryvrg Last modified: Em ewinagubagsyoe\rLuoroFRcOWheeCshaiBc\oetlosov.s NEDRS 013104 Method: Pr IA her Last modified: a Job Code= P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\SampleDB\021804AR CG ACSFM Tue Mar 02 12=07:00 2004 P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\MethDB\CotGrove NPDES 012104 Mon Feb 02 07=04=42 2004 M4 pPrriinntceed:= TTuuee MMaarr 0022 1144::0055::2223 22000044 J -- Name= 021804AR-219 Text= 4: C6 Su~ifonate PFHS W [L1L817847-4-11,, DDFF==1I000000 | (ete0unr5.m210 20) 021804AR-219 Sm (Mn, 2x3) ." | x h ii 11/~(~ 010-1M-Mara-r-22000044 1177::2255::38 LLCC/iMMSS//MMSS #6 MRMof Cram 5 MRM of 5 Channels ES- perf 88.7777 /A~ 33..8833e33 %) nSJ \ ~ ~ )9A>r8e0a l0r ! r .... , .... ~ ...r . e , ..r .. ~ ..r .. , .... r ~ ........ ~ .... e , .... p, r.e..m.ee~ r.r..e. ~TTiHmEe ` 3% a a a Too 2.00 4.00 6.00 8.00 10.00 12.00 5: ce suttonace pros 5:C8 Sulfonate PFOS 4 Lier, oF=1000 Ma 200 Tr 7253 L1874-1, DF=1000 "|o2z 16201954m in. 2) oors MRM of 5 CraTmeSeso5:e 021804AR-219 Sm (Mn, 2x3) 01-Mar-2004 17:25:38 LLCC/IMMSS//MMSS #6 9.17 MRM of 5 Channels ES499 > 99 |i *100l .0 %01 .... 2.00 1676~ 9.54e3 AArreeaa ~ E TEr rT ab em sho oom 4.00 6.00 8.00 IT arr Tine 10.00 12.00 L] " Seven esencch, 3038 Resescch Drive, State College, BA 16901 Exygen Research, 3058 Research Drive, State College, PA 16801 u CCROONEFNNIFNDIDEEENRNTITCAIAOLLUN- STSUUYBBDJJIEESCCTTTRTITCOOTAPACROPUORRTOTE.TCENTCGIT.IVV2EE7 OOORuRDD1E0E.RR28EE8NN6TT3EERREEDD ININ HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00336622 sw_otsssas 3M MN01538748 vgQuuaae nnttiifeyy Ssaamm. ppllee RReeppoorrttons0mn, axeDater02/10/04,Analyati nism Page 39 Page 39 SLSSaaatsmmu?ppdllymeeoNdLoLiii.fss:titL:=eId8:7p4r,TP\o=Da\SaeDttWaeat\NraoL\.LO0:3CM0MM21SS1M2G8S.\06M04\a7AMs1Ras,0slsyl2nEy0e0xn\4txP.\IDFaultoueor:ro0oc2ch/he1en8mi/ic0ca4al,lss.A.nPPaRRlOOy\\sSdtaa:msKpp.llReeiDDsBBh\\a0G211880D44AARR CCGO AACCSFSM 4 eMLLTLeaaoattssnshhtttocodammma=toooedddriiifffiiieeeddd==: MPTPiou=ae\\DaMPatateera\\LL00C32CuMES01N7M2a1S:00647\Ns=Ma40as30sssl122yy000Rn044Ex\\PFLluuooErooccehenmiccaallss.PPRROO\VMKeStEhADDBBA\CCoottGGrroovvee Mon Feb 02 07=04=42 2004 NNPPDDEESS 001122110044 Job Code= WH Pprriinctteeads: TTuuee MMaarr 0022 1144::0055::2222 22000044 ome ems Name= 021804AR-220 Text= W 1i::[L1cC8o674-nA1ecsiRadopsP,eFwDHnAF=1000 L1874-1 Rep, DF=1000 002211880044AARR--222200 SSmm ((MMnn,, 22xx33)) wf | 1 i/l...._`| ,| 84s14822 8.48 14822~ 01-Mar-2004 17:47 01-Mar-2004 17:47:24 LCIMSIMS LC/MS/MS #6 MMRRMM ooff 5 CChhaannnneellss EESS-- a> 269 31377.>.009920e6449) ea)Area KE rr me| 0r.~l .... ~ .... ~ .... ~ .... ~ .... ~ .... i .... ~ .... ~ .... i .... ~/Ime fl 200 a0 5% 800 000 200 2.00 4.00 6.00 8.00 10.00 12.00 2: co acta pron 2: C8 Acid PFOA LL11887744--11 RReepp,, DDFF==11000000 0o02o21h1880044AARR-222200 $m (Mn, Sm(Mn, 265) 2x3) " 5988.98 83304 0011--MMaarr--22000044 1177::4477:2:2:4 LLCC//MMSS//MMSS #6 MRM of 5 Channels ES- MRM of 5 Channels ESHa 369 413 > 369 4.455) rea 4.45e5Area - 1001 83304~ a -- 0~...q .... ~ .... , .... , .... , .... ~ .... , .... , .... , .... , .... , .... ,Time LTT 300 500 800 7000 200" | 2.00 4.00 6.00 8.00 10.00 12.00 3: co sulfonate ores 3[LL:11C8874744--S11ulRRfeeoppn,,atDDeFF==D11F00B00S00 - 2180148220 5m in, 225) MRM of 5 Chamois 5- 021804AR-220 Sm (Mn, 2x3) - oe asEsy 79382r>5e83a9 1'' 0011--MMaarr--22000044 1177::4477::2244 LLCC/lMMSS//MMSS ##66 8.15 MRM of 5 Channels ES299 > 99 3.25e3 Area C | ATie 0 ........ ~ .................... , .... ~ .... , .... [ .... ~ .... ~Time . | 200 400 500 800 000 70 2.00 4.00 6.00 8.00 10.00 12.00 '1| Exygen Research, 3058 Research Drive, State College, PA 16801 Exygen Research, 3058 Research Drive, State College, PA 16801 " `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACOPPURRROOTT,TEECNCTOT.IIVV2E7E-OOCVRR-DD1EE0RR28EE8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00336633 _MNO1S3BT4 3M MN01538749 o QquuaannttiiftyyI sSuammppilee RReeppoorrttNeontsounn, xe.Dater0a/16/00, smaiystik.nisna rage 10 Page 40 WLSfSSe aaatsmmutppdgllymeeoNdoLLii.ifss=ittL=eE :Id8=74,PT7u:N re\SDe\MtaaDtrNaao\.LS 0te=2Cna0M2S1t\1M2s8S=Le 006O47\WA=MaHR0as,0Ns) ssSbl2yy0EO0nax\4txt\.\mFDFialsutuoseor=rLo0os2ych/hem1es8m\i/ic0Fc4aai,llssuA.FonPPOaRRrlOO\y\\oSKsSacetam=mhhpKpoe.lRaRem\DiDaCsBi\\hoOc0atZ2GaL1oA8l0v04se4AA.RWRPDCCEG0SAAC0CS1F3S3M04 atReaaattcien Method= Last modified= Ton pon 05 rors 90k P:\Data\LCMSMS6\Masslynx\Fluorochamicals.PRO\MethDB\CotGrove Mon Feb 02 07=04=42 2004 NPDES 012104 Job Code= " PPrriinntteedd:: TTuuee MMaarr 0022 1144::0055=:2222 22000044 4 meme osama Name~ 021804AR-220 T4:extc~o sultonace pms 4:C6 Sulfonate PFHS " LL11887744-.11 RReepp,, DDFF==11000000 ce 21608AR5.m242,0 20) ar MofR5CraM mn3o5l5-55-0 u 021804AR-220 Sm(Mn, 2x3) 1 YE | wd tMset Port | | . 22..0000 44..0000 5. co sutonace oros 4 5[LL:11C8878744--S11ulRRfoeoppn,,aDtDeFF==P11F00O00S00 2:1608AR.252m0 n, 2) MRM of 5 Gramnos 5- 021804AR-220 Sm (Mn, 2x3) | a sena . si8.79 343 0011--MMaarr--22000044 1177::4477::24 LLCC//MMSS//MMSS #6 [V2 MRM of 5 Channels ES> 80 2.97e3 f Area 66..0000 88..0000 1100..0000 1122.00T00ime | 0011--MMaarr--22000044 1177::4477::2244 LLCC//MMSS//MMSS #6 MRM of 5 Channels ES- 195.1675 49889..55>44ee9393) Area " . o 200 ao fr abo WooAR = 2.00 4.00 6.00 8.00 10.00 12.00 ` . . Sxyaen Research, 3058 Ressacch Drive, State College, PA 16001 E~ygen Research, 3058 Research Drive, State College, PA 16801 CCHEOONNNNFEIDFPEIINNTDCIAOELU-NN- TSSTUYUIBBDJJIAEESCCTLTTRTITCOOT AAGPOPURRROOTT.TEECNCTOTIIVV2EE7 -OO0RR1-DD1EE0RR.0E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00336644 Sw umorsserso 3M MN01538750 guuncisy sumpte negort rose 12 Quantify Sample Report bo BERNER neon, smtpateron/t0/0n, amsiyasin iene Study No.:LI874, Set No.:021804AR, Ext.Date:02/18/04, Analyst:K.Risha Page 41 Sample vist. 3:\oaca\uUBUSSWasatymc\Plsorochenicals FRO\GSPOL4DR\GSL800 Co ACH Sample List: prvi ner Last modified= wana as73A\PLoochPeRO\sKatEHcDB\aCloteazo.ve ODES 012104 Msthod: Pra RA er Last modified: srJob Code: P=\Data\LCMSMS6\Masslynx\F1uorochemicals.PRO\SampleDB\021804AR CG ACSFM Tue Mar 02 12:07:00 2004 P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\MethDB\CotGrove NPDES 012104 Mon Feb 02 07=04:42 2004 # Prrriincvteeadr= TTuuee MMaarr 0022 1144::0055::2222 22000044 om omsounn Name= 021804AR-221 = Text= 1: ce acta oem i: C6 Acid PFHA a |Lierz, Dreion h1874-2, DF=1000 o2te0aAR221Sm in 2) 021804AR-221 Sm (Mn, 2x3) .I| | ksrs8.48 144221 Mar2004 18.091 01 -Mar-2004 18:09:04 LomsnS LC/MS/MS #6 MRMof Cra 5. MRM of 5 Channels ESTe 313 > 269 ooyl 7.06e4Area `| BE 20 2 ao , 110r/,1"7.' ~ -JT_-~~ '.... i .... i .... ~ .... ~ .... ~ .... i 2.00 4.00 6.00 2: co seta pron 2: C8 Acid PFOA " LL11887744--22,, DDFF==11000000 c2ts0anr.z21 Sm in, 23) 021804AR-221 Sm (Mn, 2x3) p)y1 - ] i,i| 1001 ! (o I 0I~',, ,~ .... , .... ~ .... ~ .... , .... , .... ~ - 3% wes 2.00 4.00 6.00 2+ ct suttonave orEs 3:C4 Sulfonate PFBS (Lie7a-2, DF=1000 L1874-2, DF=1000 - ozta0anr.z21 Sm 4. 23) 021804AR-221 Sm (Mn, 2x3) zoo1~ . |TM1uu-~ || %|NN t | 0 ,~,, ,,~-,~,22.0000,,,, ,, ,,44,.0,00,0,, ,, ...5.60.0,00.... , oo 4 oo Time .... ~ .... ~ .... ~ .... i .... ~/Ime 8.00 10.00 12.00 se MRMor GramTele5. 8.98 a 9007 0011--MMaarr--22000044 1188::0099:0:0:4 LLCC/lMMSS//MMSS #6 MRM of 5 Channels ES413 > 369 4.25e5) 4.25e5A~a 3A ios g ReTR 79997~ .... ~ .... , .... , .... , .... ,Time 8.00 10.00 12.00 si oiMRMMaorf25L0Co0r4mams1i3 8:u0s8:50-8 8.13 ES Te 828~ po|| I 01 -Mar-2004 18:09:04 LClMS/MS #6 MRM of 5 Channels ES299 > 99 4.19e3 Area Ce n ...8.8..00, 00.... , ...1.100.., 0000.... , ....12,0T0ime 12.00 . Seyoen Reseach, 3088 Sesescch Drive, State College, EA 16801 Exygen Research, 3058 Research Drive, State College, PA 16801 . CCROONEFNNIFNDIDEEENRNTITCAIAOLLUN- STSUUYBBDJJIEESCCTTTRTITCOOTAPACROPUORRTOTE.TCENTCGIT.IVV2EE7 OOORuRDD10EE.RR28EE8NN6TT3EERREEDD ININ HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00336655 sw_otsss7st 3M MN01538751  oo QQS uuaannttiiA ftyy SsaaI mmppllee RRieeppeoorrttonmmonnn, mxe.Date:02/10/04, Amsiyatim.nisha rage 42 Page 42 Study No.=LI874, Set No.=021804AR, Ext.Date=02/18/04, Analyst:K.Risha 4 MGLSSaaeaansmmtttpphllommeedooddLLiiiiffsstiit:=eedd::PiPTTP\iou=\Dse\DaDtaMWaeatat\rxeaL\\CL00LH23CeSMEHS11MSM23SSE::6060\77\NW:5Maa00ass00sassll212y0y0ym00nex44x\\\FFFllluuuooorzroooccchehesemmiiicccaaalllsss..PBPRRROOO\\SSMAazmAppDlleeBDDCBBo\\tO0dZ2r11oS8v00e44AARRNPDCCEGOSAAC0CS1S3FF1M04 MLoLeaantsshttomcdmoo:oaedtriftiieedd=: Won Pen 03 07100143 2004 P=\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\MethDB\CotGrove Mon Feb 02 07:04:42 2004 IqPDES 012104 Job Code= W|!o pPrriiantteedds: Tue war 02 10:05:23 2004 Tue Mar 02 14:05=22 2004 yeNaeme= onsen 021804AR-221 Text~ 44:[:LC1c6e87Ss4uu2ll,ftDooFnn=aa1tt0ee00pPFrHuSs L1874-2, DF=1000 (021804AR.21 Sm (Mn, 263) 021804AR-221 Sm (Mn, 2x3) oe i [1 % 0011--MMaarr--22L00O00M44 S11I88::M009S9:04~ or MMRRMM ooff 55LCCChh/aMann|Sn3n%e/e> M+llsiSEEoSS8#m.0-8s| 28.79 Area) i282 Vo a ---- 10'o ' ./.0..~ , .... , .... , .... , .... , .... , ........ , .... , .... ,Time " 200 ao 500 800 ido 700 2.00 4.00 6.00 8.00 10.00 12.00 5: co sultonate pros : C8 Sulfonate PFOS ao [L8742,0F=1000 Ot20M08 a5:09r.04 L1874-2, DF=1000 w x iarer LoMS4I0Mo9Steea5n)9 |002211880044AARR--222211 SSmm ((MMnn,, 22xx33)) 9.17 1715~ 01-Mar-2004 18:09:04 MRM of 5LCChaIMnnSe/lMsSES#6-| MRM of 5 Channels ES499 > 99 9.34e3 Area .| - ~ A i 22.0000 004.00 00800 6.00 8.00 7100.0000 200 12.00 w " . Bxygen Resssxch, 3058 Reseach Drive, State College, PA 16801 Exygen Research, 3058 Research Drive, State College, PA 16801 a `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACOPPURRROOTT,TEECNCTOT.IIVV2E7E-OOCVRR-DD1EE0RR28EE8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00336666 _mNots38Ts2 3M MN01538752 " a QQSuutaaunndtytiitNfyey.isSLaa1mm0pp7ll4ee, RReSepepxoorrttNo..021004AR, Ext.Date:02/10/04, AnalystiX.Risha PPaaggee 4433 Study No.:LI874, Set No.:021804AR, Ext.Date:02/18/04, Analyst=K.Risha a aLSSGaaaatsmmnmtpptollmeemsoodLdLiiiisffstiti:e=edd:: P DPToPu=ere\\DDMi Naaaattrraa\\\ L00L32CCMH1S1SD 3M2M1=SS006GK77\\1=a MaM00asa00sssss1t 0l2ly0y0ym0n4ne4xx\a \\FFFllluuuc\ oorrroooccchL hheeenminiciC cacalalsls.sH ..PPFRRROOO\E \\NSSeaatmahN ppDllBea\DDCS BIo\\t0GG22r6 11o08v004e4AARNRPDCCEOGSAAC0CS12FS1M04 oLMLeaantsshttoCdmmo:osoecdriiftiieedd=: Won Pen 03 07104143 2004 P=\Data\LCMSMSe\Masslynx\Fluoroche~licals.PRO\MethDB\CotGrove Mon Feb 02 07=04=42 2004 NPDES 012104 Job Code= [Qs Printed: Tvuee aMarr 0022 1144::0055::2222 22000048 ,i oaNanmmer= o022110800043A8R--222222 Text: 1:ce ncia orn i: C6 Acid PFHA a LL11887744--I1,, DDFF==I10000 PERl0E022118800441ARR-222222 5m Sm (Mn, (Mn, 26)2x3) i 100~ EE~ i60488.4488 140040~ I 0011--MMaarr--22000044 1188::3300::4411 LLCC//MMSSI/MMSS #6 MRM of 5 Channel ES- MRM of 5 31>269| Channels ES313 > 2691 Stes 6.54e5 "ar Area { +n Time 1 L 22..0000 44..0000 66..0000 88..0000 1100..0000 1122..00T00ime 2: co acta oron 2:C8 Acid PFOA a LL11887744--11,, DDFF==110000 ! l2021804AR.222 5m (Mn, 263) aso MRM of 5 Channe3l3s3E0S9 021804AR-222 Sm (Mn, 2x3) 0011--MMaarr--22000044 1188::3300::4411 LLCC/lMMSS//MMSS #6 8.98 MRM of 5 Channels ES413 > 369 1 | airy Vo=oed) 4.60e6Area Time | 1 200 400 600 500 10.00 200 | .... , .... , .... , .... , .... ~ .... , .... ,86..1.7.73,~.... ~ .... , .... ,Time | 2.00 4.00 6.00 8.00 10.00 12.00 2: ct suitomate pwms 3:C4 Sulfonate PFBS |LL11887744--11,, DDFF==110000 - - (0521804AR 222 5m (Mn, 263) S8i1zs MRM of 5 Chann2el93s01p5E7oS50-s94 021804AR-222 Sm (Mn, 2x3) 0011--MMaarr--22000044 1188::3300::4411 LLCC/IMMSS//MMSS #6 MRM of 5 Channels ES- 8.15 299 > 99 3.17e4 Area PB* | * elem 200 00 r 600 r lO800 1000 20T0ime| 2.0{3 4.00 6.00 8.00 10.00 12.00 " Sxygen Ressarch, 3058 Resessch Drive, State College, PA 16801 Exygen Research, 3058 Research Drive, State College, PA 16801 `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACOPPURRROOTT,TEECNCTOT.IIVV2E7E-OOCVRR-DD1EE0RR28EE8NN6TT2EERREEDD IINN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00336677 _MNO1S38T5 3M MN01538753 4 uf QQuuaannttiitfTyy SSEaammpp,llee RRSeeppioorrNtte. ont00uan, mxe.Dates02/10/04, Amslystk.nisha rage 14 Page 44 SSSSaaatnmmueppdllymeeoNdoLLi.ii.zss'ittL:e=1a8:74,DPPo=:s\SDe\wtaatDrNaoA\.L0C5C=M0aS12M13\S81L06047\CA1MR0aH,0sSslTUyEhxonSstx.\SDFa\ltueWo=ra0o9cs.h/se18mL/i0ccya4al,mlss.xA.nPF\aRRlOPOy\\isSStaRu:mmKpop.lLrReaiDDosBDh\c\0aO2hZ1Le800n44KAiRR CCGO AACCSSFFM 4 MGeLLeaaattnsshhtttoocdmmmea:odooadddriiifftiiieeeddd=:s wTP7eu:\en\DDaMaTcaotebra\\LL0023CMe0S17M2s1S=00647\a1=M04an03sssl23L0y000ny44xm\Fclu\orPociheumiocazlso.PcBRRhOO\\eKMeenCthhiDDBBc\\CCaoottlOGrrsoovv.ee Mun Feb 02 07=04:42 2004 NNPPDDEESS 001122110044 JsoebinCoedne= ue var 03 20005022 2000 Printed= Tue Mar 02 14=05=22 2004 dese onsen Name, 021804AR-222 T4:extc=e sulfonate prs a 4[:LCf6674S4u,]f0oFn=a1t0e0 PFHS L1874-1, DF=I00 l021804AR222 5m (Mn, 29) 021804AR-222 Sm (Mn, 2x3) 1, I| I oo 30a80.7m69 01-Mar-2004 18:30:41 01-Mar-2004 18:30:41 MRM MRM of Chann3ol0>E556-0 LLCC/IMMSS/lMMSS #6 of 5 Channels ES- 399 > 80 22r5e0a4 2.25e4 | Area | treBOn E TTiimnee 1 250 pr 60 85 100 20 2.00 4.00 6.00 8.00 10.00 12.00 5. co sulfonate ros 5:C8 Sulfonate PFOS ` [LL11887744--11,, DDFF==110000 0218044225m2 (in, 2) MRMof 5 Channsis E5- 021804AR-222 Sm (Mn, 2x3) . ois Soon 100- 0011--MMaarr--22000044 1188::3300::4411 LLCC//MMSSI/MMSS #61 MRM of 5 Channels ES- 29.4177 449999>>9999 | ea 1001 | | ii 19182~ 9.90e4Area . 2% I Bh abo oo 2Time /01 .... , .... , .... 2.00 ~ .... , .... 4.00 , .... , .... 6.00 , .... , .... 8.00 , .... , .... 10.00 , .... ,Time 12.00 - - i.| i. Exygen Resssrch, 3058 Resesceh Drive, State College, 7A 16801 Exygen Research, 3058 Research Drive, State College, PA 16801 - `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACOPPURRROOTT.TEECNCTOT.IIVV2EE7-OOCRR\-DD1EE0RR-2E6E3NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00336688 _orsaess 3M MN01538754 4 J -- rae 4s Quantify Sample Report a SILT onteeann, mee oatarta/a/08, ansiyati.sisha Study No.=LI874, Set No.=021804AR, Ext.Date:02/18/04, Analyst:K.Risha Page 45 Sumple Liat |Bo\Data\LOHNSEWasslyme\FluoBrRoO\cGahrge1enDi\GcALaA0l4AsR Go ACS Sample List= ELE, nner a Last modified: 4 nas yas\eiuorocheniosta. PROWethaE\Goccovs NEDES 013104 Method: Ee hateteas Hon he ot Te Last modified= sateen Job Code: P:\Data\LCMSMS6\Masslynx\Fluoroohemicals.PRO\SampleDB\021804AR CG ACSFM Tue Mar 02 12:07:00 2004 P=\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\MethDB\CotGrove NPDES 012104 Mon Feb 02 07=04=42 2004 Wem wear 03 sons sone Printed: Tue Mar 02 14:05:22 2004 wena czstoernaaa Name= 021804AR-223 om Text= 1. co seta smn i: C6 Acid PFHA - [511887744--11 RReepp,, DDFF==110000 PRoEzte0anr.zz3 Sm in, 2) os M015LCcrmTasmmsz5. 021804AR-223 Sm (Mn, 2x3) 0011--MMaarr--22000044 1188::5522::24 LC/MS/MS #6 8.48 MRM of 5 Channels ES313 > 269 | Si Aa 5.53e5Area oH 12463~ 100-~%~.~ a . L 0 .... , .... , .... 22..0000 , .... , .... 44..0000 , .... , .... 66..0000 , ...8.8..00, 00.... , ...1.010.~.0000,, ....1122.,00T00ime | 2: co rose smon 2: C8 Acid PFOA Pl |LL11887744--11 RReepp,, DDFF==110000 " o"zte0anr.z5zm3 un, 2) =oo bor CramTViopot5e:et 021804AR-223 Sm (Mn, 2x3) 0011--MMaarr--22000044 1188::5522:2:24 LLCC//MMSS//MMSS #6 MRM of 5 Channels ES- 8.98 413 > 369 4,Area14e6 ',,| . | of 7% i 5% i Too HSTim|e ,'-r .... , .... , .... ~ .... , .... , .... , .... ,79..5.4.57,~.... r .... , .... ,Time 2.00 4.00 6.00 8.00 10.00 12.00 3 ct stone oms 3: C4 Sulfonate PFBS [46741 Rop, DF=100 iar 2004 6522 L1874-1 Rep, DF=I00 - 241000223 5m un, 2) WR of 5LComhsainis5. 021804AR-223 Sm (Mn, 2x3) % ws Eai - 01 -Mar-2004 18:52:24 LC/MS/MS #6 MRM of 5 Channels E$- 78o.1250 29339..00>22e9449) Area , |LToTlEemrprryeprerrwewprerrae 0reroemeereeREing - | 2.00 4.00 ., .... , .... , .... , .... , .... , .... , .... ,Time 6.00 800 10.00 12.00 a Seyoun Rasaasch, 303 Rasencch Dev, State College, Th 16801 Exygen Research, 3058 Research Drive, State College, PA 16801 COCRNOEFNINFDNIEDENERTNITCAIAOLLUN-STSUUYBBDJJIEESCCTTTRITTCO0TAACPOPURRROOTT.TEECNCTGT.IIVV3EE7.OO0RRV-DDTEEoRR26EE0NN6TT3EERREEDD NIN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00336699 awmorsaerss 3M MN01538755 " 4 QQSuutaaundnyttiiNfteyy..SsLaa1mm8pp7ll4ee,RReSepepotorrttNo.:021000AR, Ext.Date:02/13/04, Analyet:K.Risha Page 45 Page 46 Study No.=LI874, Set No.=021804AR, Ext.Date:02/18/04, Analyst=K.Risha 4 LSSaaasmmtppllmeeodLLiiifssitte::d: vLeatshtodmrodified: TPPTuru:Pe\e\rDD\ANMaDLaataarrat\\aLL\00C32CLHMCS1S1HM3M2IS::SM6006S77\EK::M\a00aMs06sasss3yl2s00yl00nny44xnx\xF\\lFulFourclooccuhheeommiirccaaollsac..PPPRhRROOO\e\\NSSSnaaLmmhippOllBcea\DDCaBBo\\tl00G2Trs1Lo8E.00v~AeAANRRPDCCEGGSAAC0C1S2FS1M04 MTLLeoaatbsshttoCdomm:dooeddriiffiieedd:: on Fab 03 07104143 2004 P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\MethDB\CotGrove Men Feb 02 07:04:42 2004 NPDES 012104 Job Code: 4 Prreinitnede: TTuuee MMaazr 0022 1144::0055::2222 22000044 [= NNaasmae:= 002212800040A0R8-222233 Text= W 44:[:LC1c86s74-sS1uuilRtfooopnn,aactDeeF=Pp1Fr0Hi0Ss L1874-1 Rep, DF=100 . 0I02211880044AARR-222233 Sm Sm (Mn, (Mn, 253) 2x3) a |* 0011--MMaarr--22L00C00I44M11S88I::M55S22::#22464 879 MMRRMM ooff 55LCCChh/aMannnSn3ee/lM9lss>SEESS#8--06 4268.79 3426 3919.a9>r00e84a0) 1.90e4Area SE SE -- \ rime ' 110/~1.'.. ~ 25 .... ~ .... 2.00 ~ 400 .... ~ .... 4.00 ~ 600 .... ~ .... 6.00 ~ 800__ J .... ~ .... 8.00 ~ 1000 .... ~ .... 10.00 ~ 200 .... ~Time 12.00 4 55[::18Cc78o4-sS1uullRffooopnn,aattDeeF=2P1Fr0Oo0Ss 01-Mar-2004 18:52: L1874-1 Rep, DF=100 0216044823 Sm (Wn, 263) 0M1R-MMaorf-25LL0CCO0hl4aMMn1nSSe8/MiM:5sSS2E:S2#-t4~ | roo 021804AR-223 Sm (Mn, 2x3) o196a.01r673 MRM of 5 i59926>0910) Channels ES499 > 99 i100l "aro i "l1 9,26e4Area | 0 Time %0t .... , .... , .... , .... , .... , .... , .... , .... , ..1.8.06~3~.... , .... , .... ,Time 2 abo eto sho doo 20 | 2.00 4.00 6.00 8.00 10.00 12.00 - . ' 1 EEexyyggeenn RReesseeaarrcchh,, 33005588 RReesseeaarrcchh DDrriivvee,, SSttaattee CCoolllleeggee,, PPAA 1166080011 4 `CHEOGNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIJDJIEEASCCTLTTRTITCOOT AACPOPURRROOTT.TEECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR.2E6E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00337700 SW_MNo1S38755 3M MN01538756 ` 14 QSQtuuuaadnnyttiiHffeyy. sSLaa1mm8pp7ll4ee, RReeSppaootrrtNto.i021804AR, Ext.Date:02/1/04, Analystix.Risha PPaaggee 4477 Study No.=LI874, Set No.=021804AR, Ext. Date:02/18/04, Analyst=K.Risha SGSaaamnmptpllemeodLLiiifsstti::ed: TPuP:s:\\DNDaaAtrtaa\\0L3LCOMHS1S2MH:S0S67E\:\M0Wa0assssl2l0y0yn4mxx\\FPlluuoorroocchheemniiccaallss..PPRROO\\SSaammpplLeeDDBE\\0O2Z118I00~AARR CCGG AACCSTFHM u NMLLeeiattasdhttoomddma::oddiiftiieodd:s YP TPou:me\DMr aTaatrba\\ L0023CMS01D M721S:00647\H1:a M0a4a0s3sss1t l22y00yn00nx44x\e \FFlluuo\ orroocchL heenmiiccCaallas..HPPRROO\S \MNeGtEhH ADDBE\\CICoottGrr\oovvee NNPPDDEESS 001122110044 Gab codes Last modified: Job Code: Mon Feb 02 07:04:42 2004 d ePrriinneteead:: TTuuee MMaarr 0022 1144=:0055::2222 22000044 4 NeTaemxmeters: o02z1s8e0a4nAnR--z2a2e4 Text: 1i.: cCe6 nAcciiad pPrFiHxA Wf [LL11887744-:22, ,DDFF==110000 `" |1002211880044AARR-22244 Sm Sm (Mn, (Mn, 23) 2x3) ,Iii | w _ 688.814188 3 1198131 0011--MMaarr--22L000o044m11S99M::11S44::1111 MRM MRM of of 5LCCChh/aMann33nSn11oe/33lMS.lss>1S2EEs26SS0#6.0~-95 veal 5.13e5 A~a ` 20 40% 60 800 100r0ee 120T0ime 2.00 4.00 6.00 8.00 10.00 12.00 4 22[::LC8c87o4AA2cc,ii0edF=PpF1rOo0An0 01-Mar-2004 19:14:11 L1874-2, DF=100 021804AR.224 Sm (Mn, 263) 0M1R-MMaorf-25LL0CCC0hI/4aMMm1SSe9I/'M:Ms1SS4E:S1#-16 +o021804AR-224 Sm (Mn, 2x3) 728s3.e59s838 MRM of 5 Channels ES- 133>7136689) 413 > 369 723536 A rea 3.71 e6 % Area a | ~ | - TT Pr 600 2.00 4.00 6.00 33[:L:1Cc84a74s2S,uullDffFoonn=aa1tt0ee0 PpFrBESs _ " L1874-2, DF--100 021804AR24 Sm (Mn, 263) 021804AR-224 Sm (Mn, 2x3) |TMi 800 8.00 7880.151s52 0.00 20T0im 10.00 12.00 0011--MMaarr--22L000o044m11S99M::14S44::1111 MMRRMM ooff 5LCCChh/aMannnSn2ee/lMlss9>SEE5S9#S9-6) 29229.66r>89e0e9a449 Area a 1 M o ....2.0.0l ... , ....40, 0....e , ....60, 0.... , ...l .80, 0.... ,e ....10,00..n .. , ....12,0TT0iimmee 2.00 4.00 6.00 8.00 10.00 12.00 4 EExxvyggeenn RReesseeassrcchh,, 33005588 RReesseeaarrcchh DDrriivvee,, SSttaattee CCoolllleeggee,, PPAA 1166680011 " `CHEOGNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIJDJIEEASCCTLTTRTITCOOT AACPOPURRROOTT.TEECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR.2E6E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00337711 SW_MNo1838757 3M MN01538757 . Quantify Sample Report Study No.:LI874, Set No.:021804AR, Ext.Date:02/18/04, Analyst:K.Risha Page 48 Sample List: P:\Data\LCMSMS6\Masslynx\Pluorochemicals.PRO\SampleDB\021804AR CG ACSFM Last modified: Tue Mar 02 12:07:00 2004 Method: P:\Data\LCMSMS6\Masslynx\Fluorochem~cals.PRO\MethDB\CotGrove NPDES 012104 Last modified: Mon Feb 02 07:04:42 2004 Job Code= a PPrriinntteedd:: TTuuee MMaarr 0022 1144::0055::2222 22000044 Name: 021804AR-224 Text= 4:C6 Sulfonate PFHS i LL11887744--22,, DDFF==110000 Nl *A 021804AR-224 Sm (Mn, 2x3) . 101(0,] ] 88.7799 3108 ' 22.0000 44..0000 66..0000 88..0000 0011--MMaarr--22000044 1199::1144::1111] LLCC//MMSS//MMSS #6 re]1 MRM of 5 Channels ES33990>>89800| 11..7711ee44| AArreeaa| 1010..0000 1122.00T00ime | 5:C8 Sulfonate PFOS L1874-2, DF=100 `| ik i 021804AR-224 Sm (Mn, 2x3) 9.17 14576 01-Mar-2004 19:14:11 LLCC/lMMSS//MMSS #6: MRM of 5 Channels ES499 . 99 7.37e4| 7.37e4Area F re , .... , .... , .... , .... i .... ~ .... , .... ~ ..1.4.57,6~.... ~ .... , .... ,Time } 2.00 4.00 6.00 8.00 10.00 12.00 } . .a Exygen Research, 3058 Research Drive, State College, PA 16801 CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00337722 3M MN01538758 " w QQSuutaaundntytiiNtfoyy..SSLaaamm8pp7ll4ee, RReSeepptoorrttNo.:021604AR, Ext.Date:02/10/04, Amalystik.Risha Pago 43 Page 49 Study No.:LI874, Set No. :021804AR, Ext.Date:02/18/04, Analyst:K.Risha i vLSLSaaeaatssmmhttppolldmeem,ooddLLiiiiffssiitte=e:dd::P:TPPT\uu=Dse\raDtWMae\aat\rraL\DCL00H23CaSMH1S1St3M2S1S:\006aN77\a1:Ms\00as00slsLyl22ny04Cx00n\44xPH\FlPlu1EuouororNorocochcShehemeSnimdcia\cclaaslNl.s..aPFPRRROsOO\\NSNSaeaaEmnD1ppllDeayDDCBBao\\t00G22xr11o86\v00e44AARRNPDCCEGOSAAC0CS1SF2FM104 MFLLeoaatsnahttocdmmo=odoeddriiffiieedd=: en Fab 03 07104143 3004 P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\MethDB\CotGrove Mon Feb 02 07=04=42 2004 NPDES 012104 Job Code= [Rr Tue Maz 02 14:05:22 2004 Printed: Tue Mar 02 14:05=22 2004 | me onsen Name~ 021804AR-225 Text~ 1i:: cCo6 RAeciidd rPFiHnA I] LL11887744--11,, DDFF==1100 . (o00B22o1188)0044AARR2-22255 Sm Sm (Mn, (Mn, 233) 2x3) i | of= | ot1001%t 200 300 2.00 4.00 4 [22L::8cC7a84rAcciiDddF=oP1rFOo0An L1874-1, DF=10 + 10[02i21o1880044A4RR.-222255 Sm Sm (Mn, (Mn, 263) 2x3) _ 10583.43482806 _ 0011--MMaarr--22000044 1199::3355::56 LLCC//MMSS//MMSS #6 MRM of Channels ES. MRM of 5 Channels a>269 313 > 269 50006, 5.00e6 AreaA~a 600 500 1000 6.00 1033206~ 8.00 10.00 | 20T0ime| 12.00 s1085.5978880 01-Mar-2004 19:35: 01-Mar-2004 19:35:56 MRM MRM ooff55LLCCCChh//aMaMnn4SSnn1e//e3MlSlMs>>aSSEEt33SSe#06-r-969 |" 3.46Ne7eArega ` S1E Time - Tam .... , .... 2.00 , a0 .... , .... 4.00 ~ 60 .... ~ .... 6.00 i 500 7000 .... 6, 4.9.5.7.89~~.... , .... 8.00 10.00 , 200 .... ,Time 12.00 33L:1:8Cc74o4-S1su,ullDffFoon=naa1tt0ee sPFrBsS 01-Mar-2004 19:35:5 - L1874-1, DF=10 1021804AR225 Sm (Mn, 263) 021804AR-225 Sm (Mn, 2x3) 515 0M1R-MMaorf-25LL0GOC0hMI4aMSn1nSIo9M/lM:S3sS5:E:S5#-~6 MRM of 5 70509 Channels ES- [| 1, 1 T81.11558 299 > 99 arena 2.83e5 |% A~a LA I Fa | ot 22.0000 a04.00 ew 6.00 sw8.00 000 200 10,00 TTiimmee 12.00 a ESxxyyggeenn RReessseaarrcchh,, 33005580 RReesseeaarcchh DDrriivvee,, SSttaattee CCoolllleeggee,, PPAA 1166080011 " `CHEOGNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIJDJIEAESCCTLTTRTITCOOT AACPOPURRROOTT.TEECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR.2E6E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00337733 SW_MNo1838759 3M MN01538759 ` quantity sumpie sapors Quantify Sample Report Page 50 Study No.=LIS?4, Set No.:021804AR, Ext.Date:02/18/04, Analyst=K.Risha Sample Lise: | B:\Daca\LCHEKAE Wags Lyme\Finorocheniculs. FRO\SARSLADBAORLSOURR GG ACOH Sample List= i [Ty Last modified= RE ictvwowatmata aspera omens e52s S1TLn Method: BE siete mora BTS Last modifi~d~ LE Job Code: P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\SampleDB\021804AR CG ACSFM Tue Mar 02 12=07=00 2004 P:\Data\LCMSMS6\Masslynx\Pluorochemicals.PRO\Me~hDB\CotGrove NPDES 012104 Mon Feb 02 07=04~42 2004 i` PPrriinntteedd:: TTuuee MMaarr 0022 1144:=0055::2222 22000044 PA-- ' NTTaeemxxett==: 021804AR-225 SEES 4:C6 Sulfonate PFHS o2182205 S4mA4R, 2) a ILL11887744--11,, DDFF==1100 021804AR-225 Sm (Mn, 2x3) i , i|kl lw MRM of 6oCmrsamts#5. 88..7799 Te| nn 0011--MMaarr--22000044 1199::3355::551] LC/MS/MS #6 MRM of 5 Chan3n9e0ls>E8S0- 399 > 80 1.71e5| Tie 1 { 31174~ '"' 2i..0~0 6'''''' '~4.,0.0~d''''''' ~6.0.0bd''''''' ~8.0.0~'''''' '1'0o.i00o' ' ' ' ' ' '1'22.:1o0"70~1em5;/Aereai SERA 5:C8 Sulfonate PFOS | [rat rete Mar2004 19.355 L1874-1, DF=10 a |co]"ts;0anr225 5m in, 260) oiar MRMor GrarmealBsspio5e.l 021804AR-225 Sm (Mn, 2x3) 01-Mar-2004 19:35:56 LLCCI/MMSS/IMMSS #6 MRM of 5 Channels ES- 9.17 499 > 99 7.64e5 A~a . | of 3 pr) oo wo HaTin|e i` IM 0! .... 2.00 4.00 6.00 8.00 10.00 12.00 R ol a. Exygen Research, 3058 Research Dr~ve, State College, PA 16801 GaONFIDE- NSUTBJIECAT T0 APROTECTIVE OROER ENTERED CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN FEANERI COUNTY DISTRICT COURT NG. 27 Gunio26803 HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00337744 swos35760 3M MN01538760 a qB QuuaannttiitfE yy sSaammspilR ee RReeppoorrtNte onsen, mxDacer0a/20/01, soaiysti.Risha sage 51 Page 51 A eSfLSSaaatimsmurtppdmllyeR meoNdLoLiii.fss=HtitL::eId8:7E 4,TPPu=e\SeDrMtaatrNa\o\L.L0o=2CDr0Mb2Si 1u1M2ea8S:e00647\ktA:MaR0ao s,0ssesll2y0yyE\0xnmo4tx.\sLFDFlal\utuoeOoFs=ro0olc2Hch/hue1en8moEi/ic0cra4aNl,loes.A.cSPnPRRaRhOOlOE\\y\eSNsSeetam\m:mHKpipO.llWRReceNiDGsBeaoh\Ota0lZG2s1EEs8Ao0.Ovs44eARNRREDCCEGOSAACGCS13FS1M04 a MLCeaatsrhttodmm=aoadiitfiiaedd:: Won vob 03 07 00ris Fhe P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\MethDB\CotGrove Mon Feb 02 07:04:42 2004 NPDES 012104 Unies Job Code: ee war 02 16103132 2004 Printed= Tue Mar 02 14:05:22 2004 -- Name: 021804AR-226 ft Text: Loco rear 1: C6 Acid PF~IA ll] LL11887744--11 RReepp,, DDFF==1100 . (| c2t804AR225 Sm in, 20) 021804AR-226 Sm(Mn, 2x3) aE I 0011--MMaarr--22000044 1199::5577::43 LLCC/IMMSS//MMSS #~ MofR5ChM omol 5. MRM of 5 Channels ES- ootiis s Tror2y0 8.48 313 > 269 ea 4.94e6Area Time I , ....22..0,000.... , ....44..0~000.... , ....66..0~000.... , ..1.0.188.4.0,0300.6.6.~. , ....1100.., 000.0... , ....1122..,00T00ime 2: co nese pron 2:C8 Acid PFOA |L1674 Rep, OF=10 Mar2004 19:57:4 L1874-1 Rep, DF=10 c21808AR226 Sm hn,20) MoR f 5ChaM mois 5- 021804AR-226 Sm (Mn, 2x3) Mol e| 0s soe 1i 8.98 6200222 01 -Mar-2004 19:57:43 LLCC/lMMSS//MMSS #e MRM of 5 Channels ES- "Area 413 > 369 3.2867) 3.28e7Area . } slTe ESepe py r,at si oe 2Time , .... , .... , .... ~ .... , .... , .... , .... 6,2.0.9.2.22,~.... , .... , .... ,Time 2.00 4.00 6.00 8.00 10.00 12.00 3: ct suttomsee ores 3:C4 Sulfonate PFBS LL11887744--11 RReepp,, DDFF=--1100 - (2180448.25 5m in 2) MRMofSo Gramois s 5. 021804AR-226 Sm (Mn, 2x3) o%e ois ie)a - 8.13 76627 0011--MMaarr--22000044 1199::5577::43 LC/MS/MS #6 MRM of 5 Channels ES- 2929.9>59e95 2.95e5Area 4 {i ,| , .... , .... ~ .... , .... , .... , .... , 76627~11~ .... , .... T, .... , r ....r ~ ..r .. ,TTiimmee | 22.0000 44..0000 66..0000 88..0000 1100..0000 1122.0000 | " Exyson Resaarch, 3058 Resencch Drive, State College, 7A 16803 Exygen Research, 3058 Research Drive, State College, PA 16801 . CCHEOONNNNFEIDFPEIINNTDCIAOELU-NN- TSSTUYUIBBDJJIAEESCCTLTTRTITCOOT AAGPOPURRROOTT.TEECNCTOTIIVV2EE7 -OO0RR1-DD1EE0RR.0E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 su umotssset 3M MN01538761 11993377..00337755 4 gQBouuuaadnnrttyiitnfeyy. ssIaammppLllee RneeSppeotorrtNto. co7e0mmn, mxe.ater02/10/04, Analyst:x.nisha rage 52 Page 52 Study No.=LI874, Set No.=021804AR, Ext.Date=02/18/04, Analyst:K.Risha @ eSGLSataaassmn?tmpolaemmerooddLLiiiiffsstiit:e:edd=:prTPPTi\iu:Dae\\aDaWMcataateerra\\\LLL00O32CMOMMSS11SM23SSS=1\0660W7\H5a:Ma0s0as00sssLsly221y00m0n0ye44x\m\PFleluuo\orrFoocclhheeunmicccaalrlsso..cPFPRRRhOOOV\\eHSSeaanLmnOppilBleecADDCBaEo\At0l0d22z1s1o88v0.0e44ARRWEOCCEGOSAAC0CS12FS1M04 MLoLeaantsshttocdamm=tsoeadriiftiieodd:: Mon Fab 03 0710143 2004 P=\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\MethDB\CotGrove Mon Feb 02 0?=04=42 2004 I~PDES 012104 ,J sJoobmCeodse= mee ar 02 10108122 2008 Printed: Tue Mar 02 14=05:22 2004 4 meme oman Name~ 021804AR-226 1 T4:extc~s sultonace prs 4 4:C6 Sulfonate PFHS |[18781 Rep, DF=10 L1874-1 Rep, DF=10 a" 100|:2211880044A8RR2-22256 Sm Sm (Mn, (Mn, 265) 2x3) ,,4 | sr8.79 3116031180-~ 0011--MMaarr--22L00o00M44 S11/99::M557S7::43 MRM MRM of of 55LCCChh/aMannnSne0e/lM0lssS>EES8S#-0-6 39 > 80 1.e6a9 1.69e5 Area " |* 1 ere Tit i i , 200 .... , .... , 400 .... , .... , 500 .... , .... , 800 .... , .... ~ ....10~50.... , 200 .... ,Time 2.00 4.00 6.00 8.00 10.00 12.00 J 55[: 1:8Cc78o4-sS1uullRffeoopnn,aattDeeF=Pp1Fr0OoSs 01-Mar-2004 19:57 L1874-1 Rep, DF=10 021804AR228 Sm (Mn, 235) yo 021804AR-226 Sm (Mn, 23) 017 0MM1RR-MMMaoorff-255LL0CCCO0hhMl4aMaSnni1nSIne90Me/lM:l0S5ssS75:EE:04SS93-) 150206 ates 9.17 499 > 99 rea i *11! 7.48e5Area - | 205 to 500 ab 1000 750Time 0~ .... , .... , .... , .... , .... , .... , .... , .... , .1.5.0.29, 6.~... , .... , .... ,Time 2.00 4.00 6.00 8.00 10.00 12.00 . ` " EExxyyggeenn RReesseeaarrcchh,, 33005588 RReessseaazrcchh DDrriivvee,, SSttaattee CCoolllleeggee,, PPAA 1166880011 " `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACOPPURRROOTT,TEECNCTOT.IIVV2E7E-OOCVRR-DD1EE0RR28EE8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00337766 _MNots38T62 3M MN01538762 " 4 QS QuuaannttEiiftyy sSD aammpplleee RReeppoorrttorteonn, mxe.pater02/19/04, Anatyetix.Risha rage 53 Page 53 Study No.:LI874, Set No.=021804AR, Ext.Date=02/18/04, Analyst=K.Risha 4 eGLSStaaaassmnmttppollnmmee:ooddLLiiiiffssiitt:ee=dd=:P:TPTP\iuu:Dse\\aDDtMaWaetaata\rxa\L\LCL00H23CoSMuMS11sSM23SE::e060\\77\NH=1Maa00ass00ssssll2y2yy00in00nex44x\\\FFFll1uuuooorrorocochcheheneaimicicacalalsls.s..FPBRRROOO\\\KSSSaaCmmhppDllRee\DDCBBo\\t0OG231r188o00v44eAARRNPDCCEGOSAAC0CS1SF2F1M04 MLoLeaantashttocdmmo:otoead:iifeiieedd:s on Feb 03 07100143 2004 P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\MethDB\CotGrove Mort Feb 02 07=04=42 2004 NPDES 012104 Job Code: VetProinetesd: tue ar 02 14:05:22 2008 Tue Mar 02 14=05=22 2004 aoNammene:= 002211800044A3R--222277 Text~ u [i1::ercCs6a aAcciioddF=pPtrFiK0nA L1874-2, DF=10 1021804AR.227 $m (Mn, 263) a | 021804AR-227 00) Sm(Mn, 2x3) |1 ",ii! * oo _oCT iMarz01-0Mar0-20404 2200::1199::2244 MRM of 5LLCCCh//aMMnnSSe//lMMsSSES##-66 10884.52508065 MRM of 5 Chan33n1e35l>1s>02E2263S0690-9| ea | 5.02e6Area | Tim|e 1` 22..0000.... , ...4.4..00, 00.... , ....66..00, 00.... ~ ..1.08.48..200, 800.6.5.~. , ....1100.., 0000.... , ....1122..,0T000ime 2: co acid pron _ : C8 Acid PFOA 1 1L8178744--22,, DDFF==1100 o21804aR227 5m in, 20) MoR f 5ChaM mois 5.| 021804AR-227 Sm (Mn, 2x3) ` poy% eszsisne Wavsso3e0t9|] i 0011--MMaarr--22000044 2Z0:a 19:z 24 LLCC/IMMSS//MMSS #6 8.98 MRM of 5 Channels ES413 > 369 | `Area 3.30e7Area - 0 200 400 500 800 70,00 200Time | .... i .... i .... i .... i .... ~ .... , .... 6i 2.4.3.0.43i~.... ~ .... i .... ~Time 2.00 4.00 6.00 8.00 10.00 12.00 3: ct sulfonate srs } : C4 Sulfonate PFBS [LL11887744--22,, DDFF==1100 - 021804AR 227 $m (Mn, 263) 021804AR-227 Sm (Mn, 2x3) - | 21 0011--MMaarr--22000044 2200::1199::2244 LLCC//MMSS//MMSS #6 MRMof 5 Channels ES- MRM of 5 Channels ES- 015 995% 8.15 299 > 99 73% 25165) 2.91e5 = Area - | A 20:0 200 ; 500 800 : 1000 ZoTTiimme|e 2.00 4.00 6.00 8,00 10.00 12.00 " Exygen Research, 3058 Ressazch Drive, State College, PA 16801 Exygen Research, 3058 Research Drive, State College, PA 16801 . `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACOPPURRROOTT,TEECNCTOT.IIVV2E7E-OOCVRR-DD1EE0RR28EE8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00337777 _MNO1S38T63 3M MN01538763 " SQquuE aannttiiftyy I ssaammppllee RRSeeepp.oorrttconeomn, axe oater02/10/04, Analyetix.ntena Pago 54 Page 54 i GSSSaaatsmmutppdllyeemoNodLL.iiissfattiL::eld8:74P,TPiu:\s\SDeDeWtataterNa\o\L.L0C:2CH0MS21SH1M2S8S.\0604N\1AaM0Rsa,0sslsy2ln0Ey0xxn8t\x.F\DFlalutuoeoz:ro0oc2ch/he1en8mi/ic0ca4al,lss.A.FnPaRRlOOy\\sSStaa=mpKpL.leReDiDBsB\h\a0O2T1L8O0O4AARR CO CG ACSI ACSFM 4 MTvLLLeeoaaatrnaSshntttoocadmmmar:oootcdedrtifefiiteeodda=:s wTPFuo:eAn\DDMFaeatEbra\LL0023CuMS10sM27:S1s00678\r:Ma40as30sssL2l20y0y00nn44x\PFlLuourocohezmicoalcs..PhPRROeO\MNnetAhiDDBBc\CCoaottOGlrrooavvee Mon Feb 02 07104:42 2004 NDE NPDES 012104 012104 Job Code: @,ii Prriinncteead:: TTuuee MMaarr 0022 1144::0055:=2222 22000044 same 02180488-227 if,! NTraeemxxet.:: 021804AR-227 4 44[::1C6c6e74sS2uul~DtfFoonn=aa1tt0ee pes PFHS L1874-2, DF=10 '021804AR 227 Sm (Mi, 23) a {oo1 021804AR-227 o% Sm (Mn, 2x3) ~ i" * EE _ sa88s7. s09 32887 0011--MMaarr--22L00C00I44M22S00:I:1M19S9::2#2464 MRM MRM of of 55LCCChh/aMan3nnSne6eIlMlss>SEE8SS#0--6 399 > 80 17e70a5 1.77e5 Area ' 0ir , , ,, ....25, 0.... ~ ....0~0.... ~ ....50, 0.... , ....80~ 0.... , ....10,00.... ~ .r..n.7-5,TT0iimmee 2.00 4.00 6.00 8.00 10.00 12.00 | 55|: :LC1c88o74Ss2uu,ltf0ooFnn=aa1tt0ee pros PFOS _ 01-Mar-200420:19 L1874-2, DF=10 ' 100:2211880044AARR2-22277 Sm Sm (Mn, (Mn, 268) 2x3) 0M1R-MMaorf-25LL0CCO0hMI4aMSn2nSI0eM/l:M1Ss9S:E:2#S14~ 2o62r10 MRM of 5 Cha"n1n0e55ls.E29S59-5 9.17 499 > 99 rea, EE 6.23e5Area Time , .... , .... , .... , .... , .... , .... , .... , .1.2.6.27, 0.~... , .... , .... ,Time . py) a0 6% 800 F000 1200 2.00 4.00 6.00 8.00 10.00 12.00 ~t - ,,1| "I,iltli Exygen Ressacch, 3050 Resossch Drive, State College, 7A 16601 Exygen Research, 3058 Research Drive, State College, PA 16801 . `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACOPPURRROOTT,TEECNCTOT.IIVV2E7E-OOCVRR-DD1EE0RR28EE8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00337788 _MNO1S3BT64 3M MN01538764 " 4 QQSutuauadnnyttiiNftoyy.rSSLaaImmEppTllSee, RRSeeapptoorrttWo.:021804AR, Ext.Date:02/13/04, AnalystiX.Risha PPaaggee 5555 Study No.=LI874, Set No.=021804AR, Ext.Date:02/18/04, Analyst:K.Risha LSSaaasmmtppllmeeodLLiiifssitte::d: TPPu:ie\D\MaetDraa\L0t2CMa1S2M\1SL067\C1M0aM0sSsl2Ny00nS4x\6F\luMoraocshsemliccyaalnlsse..PP\RROOP\\lSSaaummppolLreeDDoBB\\c022h116e80D4n4AAiRR CCOG AACCSTFHM 4 MMLLeeaattsshhttooddmm:=ooddiiffiieedd:: PWTP1eu=\en\DDaTMacaatabra\\LL00C32CHMA0S1N7M2S::SG00674\N::Ma04as02sss2l2y0y000nn48x\Feluo\roPchelmiccuaalloss..PPrRROO\\oNMeecEtAhDDhEB\\CCeoottnGGrroodvvee NNPPDDEESS 001122110044 ob coder Last modified: Job Code= Mon Feb 02 07:04=42 2004 ,4ii pPeriinntteeads: TTuuee MMaarr 0022 1144::0055::2222 22000044 ,LiI! Ne~aasmmee):~ 002221080044aA8R--222288 Text= i1:: cC6s AAcciidd PpFrHiAn 4 [LL11887744-33,, DDFF==1I000000 021802248ASRm (Mn, 23) 4 [0 021804AR-228 Sm (Mn, 2x3) j 0011--MMaarr--22L00C00I44M22S00I::M441S1::116 ois MMRRMM ooff5LCCChhIaMann3nSnee/lMl1>ssSE2E3S6S#.9-6 186.84883 3137.>r52e06a0l94 re A A A rrp rerrrnares\ rime Pol 0 200 r,'--~'-:,,i,-~---,= .... i 400 .... i .... i 600 .... i .... ,'' 8"0i 0 i 1000 200 ............ Time 2.00 4.00 6.00 8.00 10.00 12.00 2: co Acid pron ) 2L[:1188C78744-A33c,iDDdFF=P=F11O00A0000 0011--MMaarr--22L00C00I442M20S0:I:44M11S::11t~ 021804AR.228 Sm (Mn, 23) TE1 021804AR-228 Sm (Mn, 2x3) 53 MRM MRM of of 55LCCChhIaMann1nSne3e/lMl>ssS3EE6SS#.9~-) s8o.9r8a 43205 413 > 369 1 iO01 4.3A2reea5l iw Area UI IE | | - /~ 22.5000 44.0000 33[:L:1C8c47a4-Ss3uu,llDffFoonn=aa1tt0ee00pPFFBESS - L1874-3, DF=1000 1021804AR-228 Sm (Mn. 23) - 021804AR-228 Srn (Mn, 2x3) 100~ | 660.000, 88.0000 81s8.15 97987 1100.0000 1200Time 12.00 0T1a-Mrar2-20L00C04I4M2ZS0I0:M4A1ST:186#6 MRM MRM of of 5LCCChh/aMannnSn2ee/lMlss9>SEES59S#-9-6 | 294492.2"8>8h0ee933a9) Area = here rerer-- arer Js .................... i .... i .... i .... i .... i .... , .... i .... i, Time n 200, 400 600 800 10.00 200 2.00 4.00 6.00 8.00 10.00 12.00 " EExxyyggeenn RReesseeaarrcchh,, 33005588 RReesseeaarrcchh DDrriivvee,, SSttaattee CCoolllleeggee,, PPAA 1166680011 " `CHEOGNNONFEINDPEIFNNITCIDAOLEU-N-NSTSTUUYBBIDJJIAEESCCTLTTRITTCOOT AACOPPURRROOTT,TEECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR.2E6E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00337799 IM_MNO1538765 3M MN01538765 J QqS uuaannttiiE ftyy sST aammppllee.RReeppoorrttoneonn, exe.Dates02/10/04, Anatyatk. nian Psaaggee 5~66 SESSaaatmsmuptpdllymeeoNdoLLii.ifss=ittLe::Id8:7P4,:TP\u=De\SADetMtaeat\rNaLo\C.L0H,3CE0MN2S1S1M3S8S1\0604N3\Aa1MRs0a,s0sLsyl2myE9c0nx\4txP.\aDFualotureoo=rc0o2hc/eh1ne8im/ci0ac4la,sl.sA.nPFaRRlOOy\\sSGtRam=mpKp1.lLReeiDDsBDh\\0aO2Z1L8O0044AARR CCGO AACCSSFFM "otMTy LLeaaahtnsshkttoae dmmm=eoodddiiiftfiiieoeddd==: wTP2eu:en\pDaMaTtatoarba\LL0025CeM0S1n7M2SS:00647\1a=M40an30sssl21iy0000ny44x\Fmlucoro\chP~nilccaalulss..oBPROrO\\KMoeeEtshhDDRBh\\CCeoottOGnrrooivvee Mon Feb 02 07=04=42 2004 WNPFDDEESS 001122110044 eJoibntCeoddre= Tue Mar 03 1010833 2008 Printed= Tue Mar 02 14=05=~2 2004 aNoammene:= 03180438-228 021804AR-228 T4:extc=s sulfonate ois 4 [LT8743, DF=1060 4:C6 Sulfonate PFHS L1874-3, DF=1000 0011--MMaarr--22L00C00I44M22S00I::M4471S::116 0218044R228 Sm (Mn, 2:3) a [100 021804AR-228 Sm (Mn, 2x3) ari,e MRM MRM of of 55LCCChh/aMannnSn3e/elME lss0S>EE5S6S#-0-6 1 8.79 399 > 80 a~rdera a *% || + \ | 0~, , 250 .... ~ .... ~ a0 .... ~ .... ~ 6b .... ~ .... ~ 850 .... ~ .... ~ 00 .... ~ .... ~ ....200Time ,i 5. co sulfonate 2p.0r0os 4.00 6.00 8.00 10.00 12.00 [18743 DF=1000 5:C8 Sulfonate PFOS L1874-3, DF=1000 0011--MMaarr--22L00C00M48S220I0::M44S11::116 (0:2012810640A4R4-222288 5m Sm (i,(Mn, 2)2x3) arr MRM MRM of of 5 Chan5na550. LCIMS/MS #6 5 Channels ES- 9.17 499 > 99 fe om %| ~ + | -- 1869~ een 1.02e4 re ,~ Area - 200 400 500 B00 00 20 | 2.00 4.00 6.00 8.00 10.00 12.00 " " Sxygen Resssrch, 3056 Ressasch rive, State College, PA 16901 EA-ygen Research, 3058 Research Drive, State College, PA 16801 a. `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACOPPURRROOTT.TEECNCTOT.IIVV2EE7-OOCRR\-DD1EE0RR-2E6E3NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00338800 m_morssses 3M MN01538766 StuQQuudaannyttiiNffoyy.:sSLaa1mm6pp7ll4ee, RReeSppeootrrtMto.:021804AR, Ext.Date:02/13/04, AnalystiK.Risha PPaaggee 5577 Study No.=LI874, Set No.:021804AR, Ext.Date:02/18/04, Analyst:K.Risha 4 eSLLSataaassmmhttppollsmmee:ooddLLiiiiffsstiit:e:edd::PiTPTP\uru:Dee\\aDDtAMNataaatarr\a\L\L0CL0C72CHHMSS1S1UH22MSS:=SE0066\77\Ka::Mas00ass00slssy12l2n00yyx00n\44xmF\iFxulou\roorFocchlheeunmiioccarallsos..PcPPRRROhOO\\\NeSSGaaLnmmhppiDllEece\DDCBaBo\\t0l0G2Zr1s1o880.v04eAANRRPDCCEGGSAAC0CS1SF2F1M04 MLLTeaaotssbhttoCdomm:dooeddriiffiieedd:: Wen Feb 03 07:04:43 2004 P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\MethDB\CotGrove Mon Feb 02 07:04:42 2004 NPDES 012104 Job Code: 4 Pprriinnteeead:: TTuuee MMaarr 0022 1144:=0055=:2223 22000044 +o NNaasmae:= 00221280004A4R8-222259 Text: 4 [L1:1: 8cc76s43Ar,cciaDdF=PpF1rH0iA0 L1874-3, DF=100 4 00f2o21o8,1048AR02-224209ASSRmm (Mn, (Mn, 2:3) 2x3) 00 ]1 i` %%]1 148s4.a40s865 144063~ 0011--MMaarr--22L00C00I44M22S11I::M003S3::002 MMRRMM ooff55LCCChhIaMann3nSnoeIiMl1ss>SE2ES63S#-0-6) 3136>5r7266a95 | 6.57e5Area a : 250 2.00 4 22[::L1Cc88874Aa3cc,iiDddF=PpFr1Oo0An0 L1874-3, DF=100 11|100;2211880044A4RRo222299 Sm Sm (Mn, (Mn, 263) 2x3) ! " ! -o 230 2.00 33[: L:1C8c47a4-sS3uu,llDffFoonn=aa1tt0ee0 pPFrBsS - L1874-3, DF=I00 021804242. Sm (4n, 263) - Re 021804AR-229 Sm (Mn, 2x3) i | * ol| Orr 200 2.00 posal 40. 0 600 800 1000 200T"im|e| 4.00 6.00 8.00 10.00 12.00 _ 01-Mar-2004 21:_03:_0 0M 1 -MoarfR -52LL0GCO0na/4MMM nSn2SaI1i/:MMs0SS3E:S0#-26 638 MRM of 5 Chan"ne4l>s13E6S30- 7089.91881 3766) 413 > 369 3.76e6 | Area | 40 600 800709181~ 1000 20T0ime 4.00 6.00 8.00 10.00 12.00 0011--MMaarr--22L00C00M44 S221It::M0033S::02 ats MMRRMM ooff 55LCGChhIaMannnSn2oe/9'Ml5ss>SEESS#9--69 080.0125 29339.55r>89e0e9a449 Area 400 rr6r00 4.00 6.00 800 r1e000pre12T0i0me || 8.00 10.00 12.00 . EExxyyggeunn RReessaeaarrcchh,, 33005588 RReesseeaarcchh DDrriivvee,, SSttaattee CCoolllleeggee,, PPAA 1166880011 . `CHEOGNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIJDJIEEASCCTLTTRTITCOOT AACPOPURRROOTT.TEECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR.2E6E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00338811 SW_MNo1S38767 3M MN01538767 OQquuE aennttiiftyy E ssaammppllee RReeppoorrNtteon0n, mxDatenc2/10/04, Aaslystik.Risha sage 50 Page 58 STSSaaatmnmuptpdllymeeoNdoLLii.icss:ittLe::Id8:74B,PT:u:\a\SDDeaMtatatarNa\o\L.L0C5:CU0MS2S1H1M3S8S1S06043\WA1MaR0as,0sssllTyyEhmxnsctx\.\DFFalutuoeoo:rc0oh2cs/h1me8im/ic0ca4al,lss.A.nPFaRRlOOy\\sSStaa:mmKpp.l1ReaiDDsBBh\\0OaT2L1S80044AARR CO CG ACEH ACSFM 4 TeMLLaeaatntssnhkttocodommmn=doomeddariiitffiiieeeddds:: MTP2eu=ne\pDaMaTtaotabra\LL00e52CMvS01eM27S:1e0607\K1:M40aa30ssal220y0a00n44x\iFlyuooroxche\miFccaalllss.u.PFRoRO0\z\MNeeotChHcDDBB\hCCooattaGsrrooivvee Mon Feb 02 07:04:42 2004 NNPPDDEESS 001122110084 | eJroibntCeoddre= Tue war 02 10:03:32 2004 Printed= Tue Mar 02 14:05:22 2004 ron[ an -- Name: 021804AR-2~9 Text= 4:C6 Sulfonate PFHS & LL1188774-3, DF=1000 PE (021822064S4m (Mn,2:0) amo MRMof Chann5el5ES>8.0 021804AR-229 Sm (Mn, 2x3) A 8.70 0011--MMaarr--220000442211::0033::0022 LLCC//MMSS//MMSS ##66 MRM of 5 Channels ES399 > 80: Tab Siezeas ,'ii * 7851~ | 4.43e4~rea | Oe . , ....22.00, 00.... , ...4.4..00, 00.... , ....66..0,000.... , ...8.8..00, 00.... , ....1100..,00.00. ~, 1122..00T00ime 5: ca sulfonate pros _ @ L[:1L81C78874a-S33,u,lDDfFoFn==a11t00e00 PFOS vo (: c2162200 54mA(MR1, 269) 0 MRMof Chan9na5ES0- 021804AR-229 Sm (Mn, 2x3) 0011--MMaarr--22000044 2211::0033::00:2 LLCC//MMSS/IMMSS #6 MRM of 5 Channels ES- 9.17 499 > 99 % verre Torseea | 7.55e4Area . L0 TTE 2.00 W660 4.00 6.00 500 000 14776~ 8.00 10.00 ELTime 12.00 " Exygen Research, 3056 Resessch Drive, State Collega, PA 16901 Exygen Research, 3058 Research Drive, State College, PA 16801 `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACOPPURRROOTT.TEECNCTOT.IIVV2EE7-OOCRR\-DD1EE0RR-2E6E3NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00338822 m_morssses 3M MN01538768 4 gEQuuaaEnntiiEtfyy sSTaammppLllee RRReeppoorrNtte. cons0aan, BreDate:02/10/04, Asalystir.nisha rage 39 Page 59 Study No. :L1874, Set No.:021804AR, Ext.Date:02/18/04, Analyst:K.Risha SGSeaamnmptpllemeodLLiiifssitte=:d: PTPur=e\\DDMaaattxea\\LL0C3CHMSS1MM3SS1E06\3\M1Ma0as0sssll2y0ym0nc4x\\TPlluuoorroocchheemmiiccaallss..PPRROOV\SSAaEmpp1laeDDBB\\O02211080044MARR CCGO AACCSSFFM " Tyart mmnditiad MMLeeattshhtooddm:=odified= Lest modified= Men Tob 03 07104143 F004 TPPu=1e\\DMaDatraa\tL02aCM\S1LM2S=C067M\=MS0a0MssSl2E0y0n\4xM\Falsuosrlocyhnemxi\caFlls..uPPRoROOr\\MoMeectthhhDDeBB\n\CCiootctGGarrolovvsee Mon Feb 02 07=04=42 2004 NNPPDDEESS 001122110044 UnmJobeCotde= Tue var 02 24u0.32 2008 Printed: Tue Mar 02 14=05=22 2004 | NtTaemmoes= cazsouseaie 021804AR-230 Text= 3: ce eid oer i: C6 Acid PFHA i |hL11887744--44,, DDFF==11000000 . 1021804AR.2S3m0 (Mn,263) 021804AR-230 Sm (Mn, 2x3) je]i | 0011--MMaarr--22000044 2211::2244::5511] LoMSIMS LC/MSIMS #6 os MRMof Chanan>eE25l6-0 4386,5205 MRM of 5 Channels ES- 3131.>942e659| 1.94e5 rea 4361 Area lo " 22.0000 44..0000 4 2|:L: icCs8o7anAscc,iiOadF=pPrF1Oo0An00 L1874-4, DF=1000 . 021804ARS.m2(3Mn0, 263) 021804AR-230 Sm (Mn, 2x3) || 1 O0! |M 0L ~ , , ,--]" .... - 200 a0 2.00 3. ct sulfonate see : C4 Sulfonate PFBS [Ufe7a4,DF=t000 ~~ L1874-4, DF=1000 4.00 _= 1 |002211880044AARR--223300 SSmm ((MMnn,, 22xx33)) "| % | ober L 200 abo 2.00 4.00 pv Tine 66..0000 88..0000 1100..0000 1122.0000 | ass 1087.91805 0011--MMaarr--22000044 2211::2244::5511 MMRRMMooff LLCC//MMSS/IMMSS #6 Chang>s 05.0 5 Channels ES- rea 4135.>6030659] 5.60e5 Area 00 B60 000 720,0m" o| 6.00 107195~ 8.00 10.00 12.00 OiMar200421:245] 01-Mar-2004 21:24:51 LLCC//MMSS/lMMSS ##66 MMRRMM ooff 55 CChhaannnneellss EESS-- arr Tes 09 8.17 299 > 99 nk 150d, 1,15e4 reaArea 600 R 800 e s To00 r20r0 y 6.00 8.00 10.00 12.00 .ii Ergon Resescch, 3058 Resesich Drive, State College. FA 16801 Exygen Research, 3058 Research Drive, State College, PA 16801 `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEEASCCTLTTRTITCOOT AACOPPURRROOTT.TEECNCTOT.IIVV2EE7-OOCRR\-DD1EE0RR-2E6E3NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00338833 m_morssse 3M MN01538769 a QGSuuaaannyttiieffyy. SSiaaTmm0pp7llaee,RReeSpproorrNtto. 1021004aR, Bxt.Date:02/10/04, Analyst k.Risha PPaaggee 6600 ,J SLSSaaatumsunptdplylemeoNdoLLi.iifs:sittLe:=1d8:7P4r,TP\u=Da\SaDetMtaaat\rNaLo\C.L0=H2C0SM2HS11S2M80ES006\47\MA1MaR0as,0sssll2y0yEn0nxx4tx\.\FDFlalutuoeor:ro0oc2ch/he1en8mi/ic0ca4al,lss.A.nPFaRRlO0y\\sSStaa:msKpp.llReeDiDBsB\h\0a0Z211880044AARR CG CG ACET ACSFM ,B# etMLLheaatssehttomadmo:oddiiftiieedd=: MTPou=\en\DDaMaatatba~a\\LL00C23CHMSS01H7M2S1S=S00647\\1=M40aH30ssal220y0s00n84xa\Filuyoronchaem\iccPaallsls..FuPRRoOO\MMreEtoOhDcBB\\hCCooettGGnrroodvvee NNPPDDEESS 001122110044 Sab code: Last modified: Job Code: Mon Fe~ 02 07:04:42 2004 LIresy Tue Naz 02 14:05:22 2008 Printed= Tue Mar 02 14:05:22 2004 "aaNNaammnae:: 002211800046A3R2--223200 Text: 44: :Cc6e sSuullffoonnaattee PEFrHiS A LLi1887744-44,, DDFF==11000000 021804AR.230 Sm (Mn, 233) aoo 021804AR-230 Sm (Mn, 2x3) |i ,| x i 0011--MMaarr--22L00C00I44M22S11I::2M244S::5511 81 MRM MRM of of 55LCCChhlaMannnSn3ee/lMlss6SEES>S8#0--6 582.9797 39290>50840 5292L Areal .~,2.95e4Area ' 1'o/! 220.000 24.0000 66.0000 5. co sulfonate pros Lo . . |[5Li:1sC8n784-S4u,DlDFfoF=n=1a1t00e0000PFOS 102180448.230 Sm (Mn 243) u 021804AR-230 Sm (Mn, 2x3) [] % 88.0000 d90o.1s177 11000.000 200T"ime || 12.00 0011--MMaarr--22L00o0044M22s11M::22S44::5511 MMRRMM ooff 55LCGChhIaMann$nne10elMl9ssS>EESS#5-5-6) 49295A0>0r949a] 2.50e4Area | - nr 0/ .... 200 ra eree w prere8r00 4695~ 1000 2.00 4.00 6.00 8.00 10.00 200Tim|e 12.00 " " " W eExyyggeenn RReesseeaarrcchh,, 33005568 RReesseeaarrcchh DDrriivvee,, SSttaattee CCoolllleeggee,, P7AA 1166880011 `CHEOGNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIJDJIEEASCCTLTTRTITCOOT AACPOPURRROOTT.TEECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR.2E6E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00338844 SW_MNO1S38770 3M MN01538770 WB QQuuaannE ttiiftyy SsIaummDppllEee RReSeppioorrNtte c021000an, Ext.Date:02/20/04, Analystik.Risha Praaggee 6611 Study No. :L1874, Set No. :021804AR, Ext.Date.'02/18/04, Analyst:K.Risha PSLLS= aeaasmsmttppllmemeooddLLiiiiffssiittee=:dd=: TPTP7ou=rea\p\DDaWMaaaaettrra\a\\L0023CLnMOi1S1Mn2M2Se1=SE00677W\a1=Ma00ass00sassL21l2y0y0ym00mn44\cx\T\PlFuluouorororocochchehesenimicicacalalsls.s..PPPRRROOO\\\SGNasemmCpphl1DeaBDD\BCBo\\tO0GT2rL1oI8v00eA4AARRNECDCOGESAAC0GS1F2SM104 PTMLaeayrtshttodmm=oeddiiftiieodd=: Men Tob 05 0700143 F008 P=\Data\LCMSMS6\Masslynx\Fluorochenticals.PRO\MethDB\CotGrove Mon Feb 02 07=04=42 2004 NPDES 012104 pJooibntCeodd:e= Tue war 02 24:08:22 2004 Printed= Tue Mar 02 14=05=22 2004 EE Name= 021804AR-231 T1:extc~s Acid orn i: C6 Acid PFHA " XC(002222440044--22,, 5500 nngg//hL SSttaannddaarrdd 021804AR-231 Sm (Mn 263) 021804AR-231 Sm (Mn, 2x3) ali 100,1 | 11887.4048886 7096~ 0011--MMaarr--22000044 2211::4466::40 LCIMSIMS LClMS/MS MRMof Channol ES- 7.974] MRM of 5 Chan33n11e33ls>> 226699, 7.97e4 ea,| Area 3. co reid oro | 1 o 0 I/! ~~ r ,, .e ... , ....r , ....p , ....-- , ....-- ,,,, 7-- , ...I. -- , ....r -- , ....r -- , .... , TiimSe `,ii 22.0000 44..0000 66..0000 88..0000 1100..0000 1122..0000 4 2[X:CC08224A0c4i-d2,PF5O0AngiL Standard XC022404-2, 50 ng/L Standard 01-Mar-2004 21:46: 01-Mar-2004 21:46:40 (0216044 231 5m (4, 2) MRMof 5 Channols ES- 021804AR-231 Sm (Mn, 2x3) Lo |e ase 1353h6a9) | 28s.98 LLCC/IMMSS/IMMSS #6 MRM of 5 Channels ES- 4131.>3300659) 1.30e5Area u | *!1001%~ 239~L 0~, ' I .... I .... I .... I .... I .... I .... I- - ~ . 250 400 00 bo i000 200 2.00 4.00 6.00 8.00 ,, .... ,,,, ,"-, Time 10.00 12.00 3. co sulfonate orms 3:C4 Sulfonate PFBS [XG022404-2, 50 ngiL Standard T-Mar 2004 21:46:4 XC022404-2, 50 ng/L Standard - |002211880044AARR--223311 SSmm ((MMnn,, 22:x33)) = an pia - |1II"1 2882.9153 01 -Mar-2004 21:46:41~ MRMof 5LLCCCh/IaMMnnSSe//lMMsSSESMRM of 5 Channels ES29119A..8>r69e9e9a339 Area P.E S N 1 2% Y"ho n abo abo /NAW 050 --V"20 | 2.00 4.00 6.00 8.00 10.00 Time 12.00 " Sxygen Research, 2058 Resessch Drive, State College, TA 16001 Exygen Research, 3058 Research Drive, State College, PA 16801 a `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACOPPURRROOTT.TEECNCTOT.IIVV2EE7-OOCRR\-DD1EE0RR-2E6E3NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00338855 m_morsserT 3M MN01538771 QSQuuaeinnttiiTfcyy SsEaammppRllee RReRepepo.orrott raseaan, mxe.oater03/10/00, Anaiyatikmishe rage 62 Page 4 eLSCSSaae~ttsrmmuhstppdollymmeesooNddoLLii.iitfs:siitLte:e:Idd8=:74,PTTB2uu::ee\\SDDDeaaMatWtcaataerrNa)\o\LL.L00Ce5:2CH0MnS2S11Hs1M32S81S=eS0006437\WA1=MaaR00asa,00sasslilyT2yy0mEoh0cnxxo4t\x\.F\FDiFlaulutouoeroz=oro0coc2hch/aah1mse8iim/cci0aac4lla,ssl..sA.nPFPaRRRlOO0y\\\sSSataaG=mnkKppD.11BRee\iDDCsBBoh\\t0aOa2Tr1L8o00v44eAARNRFDCCEOGSAAC0CS1E2FP1M08 pMLTreaatsyrhttodmm=aodditfeiseodd=: Won rob 03 07104143 F004 P=\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\MethDB\CotGrove Mon Feb 02 07:04=42 2004 NPDES 012104 0 eJonbinCcoedse= me war 02 1010532 2008 Printed= Tue Mar 02 14=05=22 2004 4 Nepaemeet= casanan 021804AR-231 4T:extc=s suitonate ors 4: C6 Sulfonate PFHS _ _ a XC(002222440044--22,, 5500 nngg/lLL SSttaannddaarrdd |(0216014 251 Sm (Mi, 213) 021804AR-231 Sm (Mn, 2x3) wl 100, 010-1M-Marar--22000044212:14:466::4400) LCIMSIMS #5 LC/MSIMS #6 EY MRMof ChanTnEre5ael-a $8.7777 MRM of 5 Chann33e99l9s9>>E8880-0, | u 260 r abo e 0 550 OCe 000 myy eZooTi | 2.00 4.00 5: ca sulfonate pros _ I 5:C8 Sulfonate PFOS 4 [XC022404.2, 50ngiL Standard 01-Mar-2004 27:46: XC022404-2, 50 ng/h Standard 2150448 251 5m (Mn, 213) MRMof Channa 5. 021804AR-231 Sm (Mn, 2x3) PR ats S50 100 1 ~ " ea % | 6.00 .... ~ .... ~ .... ~ .... ~ .... ,Time 8.00 10.00 12.00 01-Mar-2004 21:46:40 LLCC//MMSS//MMSS #6 1696.125 MRM of 5 Channels ES- 4929.0>06939] 1l Area 9.00e3 ` | oe eT Te 0,,r~7~,,, ,-,, , ,,,, ....-T,,,,, .... , .... , .... , .... , .... ~ ,,, ,,,~-~,,,Time - 200 400 00 abo ino i200 2.00 4.00 6.00 8.00 10.00 12.00 . Bxygen Research, 3050 Ressacch rive, State College, 7h 16801 Exygen Research, 3058 Research Drive, State College, PA 16801 `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACOPPURRROOTT.TEECNCTOT.IIVV2EE7-OOCRR\-DD1EE0RR-2E6E3NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00338866 m_morsserr2 3M MN01538772 . coin sp ers es Quantify Sample Report Study No.=LI874, Set No.:021804AR, Ext.Date=02/18/04, Analyst:K.Risha Page 63 A Saunple List: P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\SampleDB\021804AR CG ACSFM mil, poms - MMLeeattshhtooddm::odified: TPP1u:\e\DDaMatatara\\LL0CC2KMSS1NM2SS:660\\7M:Ma0as0sssll2yy0n0nx4x\\FFlluuoorroocchheemmiiccaallss..PPRRO0\\MMeetthhDDBB\\CCoottGGrroovvee NNPPDDEESS 001122110044 a TT Last modified: Mon Feb 02 07:04:42 2004 Bn Job Code: ye=s cn b Perriinntceeda:: TTuuee MMaarr 0022 1144::0055=:2222 22000044 ,m NTaemxet:= 021804AR-232 2i:: CC66 AAcciid PPPFHHA ~~ ------ _ -- eo - - LL11887744--55 0011--MMaarr--22000044 2222::0088::2211 LLCC//MMSS//MMSS #6 ul 100, 021804AR-232 Sm (Mn, 2x3) 88.5500 _ = MRM of 5 Chan33n11e33ls>>2E26S69-9 1.45e5Area * a 11o/! 22.0000 eam 2: C8 Acid PFOA a L|L1i8s7T4a-5s 44..0000 smssmn 240 021804AR-232 Sm (Mn, 2x3) 66..0000 i. ...8.28.5.00,700.2.3.~. , ....1100..,000.0... , ....11"22".00T00ime EE 0011--MMaarr--22000044 2222::0088::2211 hs LC/MS/MS #6 rr MRM of 5 Channels ES- PEE| oe wt | 100 n 4133>831649 8.98 1970 Area i A o Se ITrrrr errr Time - A %0-!r/,'.,'?"/, , 200 .... , .... 2.00 , a0 .... , .... 4.00 , 600 800 1000 1200 .... , ........................ Time 6.00 8.00 10.00 12.00 : C4 Sulfonate PFBS L1874-5 = rap 2sz sma JL 021804AR-232 Sm (Mn, 2x3) " ot mSieca 100 | 01-Mar-2004 22:08:21 LLCC//MMSS//MMSS #6 MRM of 5 Channels ES299 > 99 AArreeaa 8.13 |aeT I T A Pe | u' .... , .... , .... , .... , .... ~ .... , .... , .... , .... , .... , .... , .... ,Time 2.00 4.00 6.00 8.00 10.00 12.00 . Exygen Research, 3058 Research Drive, State College, PA 16801 a CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00338877 3M MN01538773 auentity sample saport Quantify Sample Report rns Page 64 Study No. :L1874, Set No. :021804AR, Ext.Date:02/18/04, Analyst:K.Risha Sample Lishs Bi\oata CMOS asymPoochaPROnNSadmp1saTIaAO2l100s4 CO ACOH Sample List= fis pr RE rg Last modified= Ee T tveroo ntoatostastore aosoeowe Heras TirLts Method: et hiasttens Hon man oe Bo Last modified: ra Job Code: P=\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\SampleDB\021804AR CG ACSFM Tue Mar 02 12=07:00 2004 P=\Data\LCMSMS6\Masslynx\~luorochemicals.PRO\Me~hD~\CotGrove N~DES 012104 Mon Feb 02 0?=04=42 2004 ,| Pprriinntceed:: TTuuee MMaarr 0022 1144:=0055:=2222 22000044 Sane: crstotra a2 a TNTeaexmxtte:== 021804AR-232 : C6 Sulfonate PFHS a L[1L8e7a4-s5 c2te0inr252 5m in, 269) 021804AR-232 Sm (Mn, 2x3) a 100, | 0.14 wo100~ 0.14 CS 3.84 ES ,`J 22..0000 44..0000 5:C8 Sulfonate PFOS o [ees L1874-5 cztsoanr 232 5m tn, 269) 021804AR-232 Sm (Mn, 2x3) T0001. i ". |"1010 | 0.77-.~'04 set0rafAMNRAMoSwfiGr|ame"l25sh. | 6,94 7.82 ---- 66..0000 88..0000 0011--MMaarr--220000442222::0088::2211 LLCC//MMSS//MMSS #6 MRM of115.52.Chann3els9>E89S0-) 399 > 80 11.15 2.64e3 99.6611 9.13 A wn 1100..0000 1122..0000 Mar200422:08:71 01 -Mar-2004 22:08:21 LLCCI/MMSS//MMSS #6 WChb ama5, MRM of 5 Channels ESeo 29263 499 > 99 2.92e3 . | o | %1 0'1, [Ed ror we [\ ww ma2 7.07 8.03 oe 11. ,7 101..7755 5% A , ,, .... , .... , .... , .... , .... ~ .... , .... , .... , ..... , .... ,Time i is 5% on ad 2.00 4.00 6.00 8.00 10.00 12.00 PM . - - Exygen Research, 3058 Research Drive, State College, PA 16801 CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00338888 3M MN01538774 . J-- re Quantify Sample Report Study No.=LI874, Set No.=021804AR, Ext.Date=02/18/04, Analyst:K.Risha Page 65 OT Sample List: fret, peer Last modified: oe BenD ousroiessen ios i Method: Ee der Last modified: a Job Code: P:\Data\LCMSMS6\Masslynx\F1uorochemlcals.PRO\SampleDB\021804AR CG ACSFM Tue Mar 02 12:07:00 2004 P:\Data\LCMSMS6\Masslynx\Pluorochemicals.PRO\MethDB\CotGrove NPDES 012104 Mon Feb 02 07:04:42 2004 o TEme-- ,a| PPrriinntteedd:: TTuuee MMaarr 0022 1144::0055::2222 22000044 Name: 021804AR-233 Text: . creo ass mi2n 4 iL[:1L81C78647-A45c5iRRdeeppPFHA 021804AR-233 Sm (Mn, 2x3) N | 1 O01] | ,| | ot .... = .... ~ " 22..0000 serie 2: C8 Acid PFOA 1 L11887744.-55 RReepp rm ass smi 2 021804AR-233 Sm (Mn, 2x3) ' ou10 100 | Tol N | ,| I y em . %01I.,~.':/~.., .... ~ .... , 2.00 ia AAns 0011--MMaarr--22000044 2222::3300::005 LLCC//MMSS//MMSS #6 MRM of 5 Channels ES- 286.64285 24623L__ "13865, 313 > 269 Area) 1.38e5Area oe ne .... ~ .... 44..0000 ~ .... ~ .... 66..0000 ~ ....88..0~000.... ~ ....1100..~ 000.0... ~....~1122T..00i0m 0 e 0011--MMaarr--22000044 2222::3300:0:0!5 LLCC/lMMSS//MMSS #6 WC MRM of 5 Channels ESTe 413 > 369 et 88.9988 AArrceaa) A or | mee TTT ime | Re T R .... , .... , .... ~ .... , .... , ........ , .... , ....\, Time 4.00 6.00 8.00 22!2~,- 10.00 12.00 - m: oans min 21 3:C4 Sulfonate PFBS |LL11887744--55 RReepp 021804AR-233 Sm (Mn, 2x3) 0011--MMaarr--22000044 2222::3300::00:5 es LC/MS/MS #6 Sr =e MRM of 5 Channels ES- - f0 . |Lad e l i) e e A A T w T - | 1 a1 ea 29779..33>88e9393 8.13 Area 571 Time 2.00 4.00 8.00 8.00 10.00 12.00 ea a Slr eer) a Exygen Research, 3058 Research Drive, State College, PA 16801 CONFOENTIAL SUBJECTTOAPROTECTIaEEORDERsENTERED a CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00338899 [p-- 3M MN01538775 I oo Quantify Sample Report w THIET ions, wr ssessapingn, sopminsi Study No.=LI874, Set No.=021804AR, Ext.Date:02/18/04, Analyst:K.Risha Page 66 Sample List: Pr\Daca\LCHDUSE\Wasslyme\Piuorochemicels.PRO\SampleBB\OPLSOARR CO ACOH Sample List= rh. TI Last modified: En rtmtms tsss seuss fies Method: For NE Last modified: Sage zon Job Code: P:\Data\LCMSMS6\Masslynx\Pluorochemicals.PRO\SampleDB\021804AR CG ACSFM Tue Mar 02 12=07:00 2004 P=\Data\LCMSMS6\Masslynx\Pluorochemicals.PRO\MethDB\CotGrove NPDES 012104 Mon Feb 02 07:04:42 2004 Bret wee) these ii Printed: Tue Mar 02 14:05:22 2004 orm wan Name= 021804AR-233 Text= Sofie _ ~: C6 Sulfonate PFHS Il !ILL11887744--55 RReep o218048.255m3 4, 2) WAM ofCrrpels 6. 021804AR-233 Sm (Mn, 23) . | a= 1( 0 [| #0 oz mmaawe ?amse sseenw zm AS ors sW opoe sVMSRYVoTa 0.12 1.53 2.18 3.49 3.88 /~ ~5.15 7.21 6.19 0011--MMaarr--22000044 2222::3300::005 LLCCI/MMSS//MMSS #6 MRM of 5 Channels ES- 9.64 11.02 11.45399 > 80 \ 1.52e3 8.75 9.21 |A 3% pr wo 17) Toso a 2.00 4.00 ILE 5:C8 Sulfonate PFOS 6.00 8.00 10.00 12.00 LL11887744.-55 RReepp oasis smn. 201 021804AR-233 Sm (Mn, 2x3) . [am. E 1~ 0.76 0.93 EEFL|)| [i . po2.00 ee 4.90 i 5 4.00 6.00 we7.30 I)8.00 MRMof rameet5sH5s. 0011--MMaarr--22000044 2222::3300::0058 LLCCI/MMSS//MMSS #6 MRM of 5 Channels ES499 > 99 3.41e3 uw | 9.15 ONwmfmne ------ TimVeY oo is 10.00 12.00 w "i| . FTAA Doreen 450 Snsswesh Drives dovns dings 2h 4A E~ygen Research, 3058 Research Drive, State College, PA 16801 G- ONFIDE- NSUTBJIECAT T0 APROTECTIVE OROER ENTERED CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN FEANERI COUNTY DISTRICT COURT NG. 27 Gunio26803 HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00339900 swoss 3M MN01538776 " Wu SQQuhuaoananttyiitNfSyy.IsSLaaTzmEpp0llsee, RReSepepororrttNo.:021004AR, Ext.Date:02/10/04, Analysti.Risha PSaaggee 6677 Study No.=LI874, Set No.=021804AR, Ext. Date=02/18/04, Analyst~K.Risha SSLseaaaatnsmmhttppollammeeroodLLdiiiissftiti:e=edd=PrPTTP\iuu=D\ee\abDtaMWateaate\rra\L\LCL00H32CeSMM1S1mS32MS1=S\00667W7\H1=aMa00sas00ssslsy3Ll200ymy00mne44ex\\\PFFihluuucoorrroooccchhheeemmmiiicccaaalllsas...FPFRRROOO\\\SSMAaeZmtpphllOeeBDD\EBC\\oOt0ZG21z18o80v04e4AANRRPDCCEOGSAAC0C1S2FS1M04 MLgLeaetsnhottodmm=nsocdiiffiieodd=: Mon Fab 03 0710143 2004 P=\Da~a\LCMSMS6\Masslynx\Fluorochemicals.PRO\MethDB\CotGrove Mon Feb 02 0?=04=42 2004 NPDES 012104 Job Code= Perriinntteeda=s Tue ax 02 14108122 2004 Tue Mar 02 14=05=22 2004 a [p-- Name= 021804AR-234 Text= 1: cs acta orn [eres i: C6 Acid L1874-6 PFHA O 01 -Mar-2a 20L00o044MZS22Ir S:M5S1T:S5T7 LC/MS/MS #1] |Joroouscasesm on. 201 whos Gps | io 850 Has 260 021804AR-234 Sm (Mn, 2x3} 8.50 MRM of 5 Channels ES313 > 269 sis 216s) | "area 11! 221 1.21e5Area | % | [] | 1 SS pe |i 0-~~.... , .... I ' '' ' I' ' ' ' , ' ' ' ' ,' '' ; I ....~... ~ I ' ' ' ' , ' ' ' "1 Time . 200 +00 550 B60 000 200 2.00 4.00 8.00 8.00 10.00 12.00 siconciameon -- PC 2: C8 Acid L1874-6 PFOA |o21604ar234 5m vin.210) MRMof 5LCC/hMaSn/nMeS#l5s.6 021804AR-234 Sm (Mn, 2x3) a p 500 133>73`46e0a98 ,,| 0011--MMaarr--22000044 2222::5511::55771 LC/MS/MS #6[ MRM of 5 Channels ES- / 413 > 369! 3.74~ 9.00 Area 2524 (M _ i | 1(i/~ ,1, i oh EEE "2 yime| I l 0I, ,'~,, ~ 200 .... ~ .... 2.00 , 400 .... , .... 4.00 , 500 .... ~ .... 6.00 , 800 10000 .... , ........ ~ .... 8.00 10.00 ~ 1200 .... ,Time 12.00 2: cs suitonate peas 3:C4 Sulfonate PFBS Lie7as OF ar2004 22:5757 L1874-6 - 021804AR 234 Sm (Mn, 23) MRM of LCChIanMnSelMsS5. #|6] 021804AR-234 Sm (Mn, 2x3) - Ty 29895529093 100 | 1 "|| o2173 %1 /I, 01 -Mar-2004 22:51:57 LC/MS/MS #6 MRM of 5 Channels ES299 > 99 AArreeaa 8.13 267 lod ee A ul 2002.00 004.00 6006.00 8008.00 0001200 10.00 12.00 ," Exyoen Research, 3050 Reseach Drive, State Collage, PA 16301 Exygen Research, 3058 Research Drive, State College, PA 16801 . `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEEASCCTLTTRTITCOOT AACOPPURRROOTT,TEECNCTOT.IIVV2E7E-OOCVRR-DD1EE0RR28EE8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00339911 _MNO1S3BTTT 3M MN01538777 ) ome mre oe Quantify Sample Report Study No.:LI874, Set No.:021804AR, Ext.Date:02/18/04, Analyst=K.Risha Page 68 Edin, Le ene e tc Samiple List= P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\SampleDB\021804AR CG ACSFM ER Hea a Last modified: MeMtethhoodd: Tue Mar 02 12:07=00 2004 P#1:\\DDaattaa\\LLCCHMSSKMSS66\\MMasaslsynsx\lFylunorxoc\h~Fnlicualos..rPPRoROOc\\MNheetLehEDDnBB\i\CCcoottaGGrrloovvsee NNPPDDEESS 001122110044 EiLast modiEied; Mon Feb 02 07:04;42 2004 Job Code; en " PPrriinntteedd=: TTuuee MMaarr 0022 1144::0055::2222 22000044 " TNTeaexmxtte:== 021804AR-234 4:C6 Sulfonate PFHS ms omtinz a LL11887744--66 1 Rt021804AR-234 Sm (Mn, 23) 100~ be msm 0.14 illl % 2 45 3 09 3 92 0011--MMaarr--220000442222::5511::5577 LLCom/MSS//MMSS #4t~ wr 58 99.5586 MRM4141o14f 5 C1h1a4n3n3e9ls9E>S8-0 11.43399 > 80 wm we 9. ! ~ 6 01 8.42 / NWT10.46~ r r | 1.54e3 | "L .... , .... , .... , .... , .... , .... , .... , .... r 22..0000 4.4.0000 66..0000 88..0000 : C8 Sulfonate PFOS Lh L1874-6 angman 021804AR-234 Sm (Mn, 2x3) J a1.03 ~, , r,, , 1100..0000 Sy | ,Time 1122..0000 sw 01-Mar-2004 22:51:57 LCC/IMMS//MMS #6 ng HSE MRM of 5 Channels ES. eien 499 > 99 9.17 2.18e3 | won | LY10.44 10.87 11.71 RY amen10/\ 40m nn ,| 4.34 6.11 8.58 ~/~ q | Oleyr rrr ere Tie i El 2.00 4.00 6.00 8.00 10.00 12.00 . " - . vn st 245 noe ev, et Coton 60 Exygen Research, 3058 Research Drive, State College, PA 16801 CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00339922 3M MN01538778 WM QgSuutaeunndttyiiefNyyo.SsLaa0mm7ppll4ee, RReeSppeootrrtNto.:021004A%, Ext.Date:02/16/04, Analystik.Risha Page 63 Page 69 Study No.:LI874, Set No. :021804AR, Ext.Date:02/18/04, Analyst:K.Risha SLSaaamsmptpllmeeodLLiiifsstit::ed:PiPT\u=De\aDtaNaat\raL\CL0H2CSMHS1SM2E1S0\67M\1Ma0as0sssll2y0yn0nx4x\\PFlluuoorroocchheemmiiccaallss..PPRROO\\SSaammpplleeDDB\\O0Z2L1A8O0A4AARR CCGG AACCSSFFM 4 MMLLeeaattsshhttomoddmo::oddiifiioedd:: MTPPou:\ne\DDaMaTtaatabra\\LL00C32CHMSS01HM72SS1:E06047\M1=Ma40as30sssll22yy00n00nx44x\\FFlluucorroocchheenmiiccaallss.PPRROO\\MNeatEhHDDBR\\CCoottGGrroovvee NNEPDDEESS 001122110044 ab codes Last modified= Job Code= Mon Feb 02 0?:04=42 2004 4 ePriinnetesd:: Tuo Max 02 14:05:22 2004 Tue Mar 02 14=05:22 2004 C= NHaemmee=: 002211800040A2R--222355 Text= uw i[1::L1Cc86o74Aa7cc,iidd0FPp=F1eH0nA0 L1874-7, DF=100 0218044R.235 Sm (Mn, 23) PEE" 021804AR-235 Sm (Mn, 2x3) wo * 0011--MMaarr--22L000C044M2S23I3::1M13S3::445 ss MRM MRM of of 5LCCChh/aMann3nSne1e/l3Mlss5S2EES6S#-0-6 Ed 8.48 32042 313 > 269 1.r37e6a5 1.37e5 Area fl reer 20 400 600 800 1000 120T0ime 2.00 4.00 6.00 22::Cc8oAAcciidd pPrFoORA 4 [LL11887744-.77, ,DDFF==110000 0011--MMaarr--22L00O0044MS223I3::1M13:S32:44:5 a 50022181048A0R-423458SSm2m(3(MM5nn,, 263) 2x3) a882.s9958 8 MRMof MRM of 55LCCChh/aMann41nSn1e3e/3lMl15ss>7S3E7E300SS#65-996.|) | eal "1 i~ ' | ,i | 1.77e5Area - 2%, 2.00 , , am, , 4.00 , , 66.00, 00~ , 800 1000 , 325,58~ , 8.00 10.00 , , 1,2~0T0ime 12.00 P[33EL::1C6c74o4-Ss7uu,~lDffFoonn=aa1tt0ee0 pPFrBsS 01-Mar-2004 23:13: - L1874-7, DF=I00 0hi 02211880044AARR-223355 Sm Sm (Mn, (Mn, 263) 2x3) 0M1R-MMaorf-25LL0GCO0hIM4aMnS2nSIo3/':MM1sSS3E:S4#-16 813 MRM of 5 20> Channels 99ES- - |1 | ~i/! 5098.13 1309-~ 29779a.4`>ad4re9ee39a Area || osh ~ a SEE Time | Ww me TT mn | 0~ .... ~ .... ~ .... ~ .... ~ .... ~ .... ~ .... ~ .... ~ .... ~ .... ~ .... ~ .... ~Time ` 200 400 600 800 1000 1200 2.00 4.00 6.00 8.00 10.00 12.00 .,ill Exygen Resessch, 3058 Research Drive, State College, PA 16601 Exygen Research, 3058 Research Drive, State College, PA 16801 `CHEOGNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIJDJIEAESCCTLTTRTITCOOT AACPOPURRROOTT.TEECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR.2E6E8NN6TT2EERREEDD IINN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00339933 SW_MNo1S38779 3M MN01538779 ` WM gSQtuuuaadnnyttiiNfeoyy.:SsLaa1mm0pp7ll4ee, RReeSppetoorrNtto.:021004A%, Ext.Date:02/16/04, Analyst:k.Risha Page 70 Page 70 Study No.=LI874, Set No.:021804AR, Ext.Date:02/18/04, Analyst:K.Risha LSSaaaammtppllmeeodLLiiifssitt=e:d:i\TPDu=ae\tDaNa\atLraC\H0LS3CNMS1SM3G:S\06N7\a:Ms0as0slsyl3m0ye0n\4xP\lFulouorroocchheeamiicceallss.PPRROO\\SSAaRmpp1leeDDBB\\00Z211680044AARR CCGG AACCSFTM Ww HMLLeeaattsshhttooddmms=ooddiiffiieedd=: TP7N1ou=\ne\DDaaMFattabara\\L00L3C2CMHS01HM72S:S=E00647\M:=Ma40as30sssll22yy00n00ne44x\\FFlluuoorroocchheenmilccaallss.PPRROO\\MNeGtEhHDDBB\\CCoottGGrroovvee NNEPDDEESS 001122110044 ab coda: Last modified= Job Code= Mon Feb 02 0?=04=42 2004 4 pPrriinntceed:= TTuuee MMaarr 0022 1144=:0055=:2222 22000044 bo NTNaammeee=: 002211800040A8R2--223355 Text= 44::Cc6e sSuuiltfoonnaattee PpFrHiSs 4 [LL1188774-477,,DDFF==110000 4 0012211880044AARR-223355 Sm Sm (Mn, (Mn, 2:3) 2x3) | [I aes8r.7e7 _ _ 0011--MMaarr--22L00O0044M2S233I::M113S3::445 MMRRMMooff5LCCChh/aMannnSn3ee/lM9lss>SEE8SS#-0-6) 39229.44r>11e0e8a440l Ama | i/1 ~~ [ e | 1(o/l e 200 2.00 55::Cc8o_sSuuiltfoonnaattee PpFrOoSs u [L418877447-7,,DDrF==t10000 . 102128350Sm4(M4n, 233) 021804AR-235 Sm (Mn, 2x3) [ 10 40p0 ee 600 4.00 6.00 B 800 e 1000 e 200 8.00 10.00 12.00 0011--MMaarr--22L00O0044MS223I3::M113S3::45 or MMRRMMooff 55LCCChh/aMannnSn6ee/lM9lss>SEE9SS#9--6) 25 329 1.8004 1.80e4 a% 9.1~,~ Area 499 > 99 . | 0-~'-,, ,, ....2,0r .... e , ....e 40, 0.... m ~ ....60, 0.r ... , ...e .80, 0.... I, ....10,00.... ~, ,~~-T71~2,i,0Tm0imee 2.00 4.00 6.00 8.00 10.00 12.00 " a w ESxxyyggeenn RReessseaarrcchh,, 33005580 RReessesaarscchh DDrriivvee,, SSttaattee CCoolllleeggee,, PPAA 1166880011 .,,i| `CHEOGNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIJDJIEAESCCTLTTRTITCOOT AACPOPURRROOTT.TEECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR.2E6E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00339944 SW_MNo1835780 3M MN01538780 omgQuuaaannteiiTftyy SsEaammppTllee RReeNppRoorrtNte. ons0mn, Ext Date:02/10/04, Analystik.nisha sPaaggee 7711 Study No.=LI874, Set No.=021804AR, Ext.Date=02/18/04, Analyst=K.Risha Wo SESaaamsmptpllemeodLLiiifssitte:=d: etmos: Last modified: PTTpPuu=r\ee\\bDaaMaMctaeteerra\\\LL0LC032CHaMSS11MnM32SS:1dS060\73\MH:1Maa00ass00ssssll3L2y90yrm00mne44ex\\\FFFilluuuooorrroooccchhhaeennmiiicccaaalllsss...PPPRRROOO\\VSSNaaazmtpphllDeBeD\DECB\o\Ot02d21z18o80v04e4AANRFDCCEGGSAAC0C1SS3FF1M04 LMLaeantsehtocdomm:doaeddriitfiiaedd:= Men Tob 03 07100143 F004 P=\Data\LCMSMS6\Masslynx\Fluorochamicals.PRO\MethDB\CotGrove Mon Feb 02 07~04=42 2004 NPDES 012104 Job Code= ` PPrriinntteedd:= TTuuee MMaarr 0022 1144=10055:12322 22000044 J ---- a NTTaeemxxett==: 021804AR-236 1: co reid oem 4 I[5:L118C876744-A.8c8,iDDdFF=P=F11H00A0000 . (021804ARS.m2(3Mn8, 263) 021804AR-236 Sm (Mn, 2x3) | i | hs1001 0011--MMaarr--22000044 2233::3355::330 LLCC/IMMSS//MMSS #6 m MRMof 5 Chaen2n8eEl0Ss)- 8.48 MRM of 5 Channels ES313 > 269 sear 0605) 1.08e5 real Area | a --r- 260 "00 2: ca acid pron 2.00 4.00 4 2[L:L118C878744-A88c,,iDDdFF=P=F11O00A0000 a y002128014AR82-2303664SSmmA((MMRnn,, 22xx33)) "R 2~L~ 500 500 T00 200 | 6.00 .... ~ .... ~ .... ~ .r.r .. , .... ,TTiimmee 8.00 10.00 12.00 _ Cre 01-Mar-2004 23:35:30 MRMof LLCCCh//aMMmSeSl//MsMSS5#.6 MRM of 5 Channels ES- 2r50y13 >Vaarieeag,| 8.98 413 > 369 -- rm -- rrr -------------- T-- T Time . 20 io oho ab Tao 2% 2.00 4.00 6.00 8.00 10.00 12.00 5. co sulfonate pres 3:C4 Sulfonate PFBS l;oz212636054m(aiRn, 2x3) LL1t887744--88,, DDFF==1I000000 - 021804AR-236 Sm(Mn, 2x3) - 1. % Ir8.15 w1 e 0011--MMaarr--22000044 2233::3355::331(~ LLCC/IMMSS//MMSS MRMof 5Channel ES MRM of 5 Channels ES6 >50 29669..22>66e9e339 ea, Area `| . R 200 TE aa0 AAr A 60R 0 wabyore0ra 00arSoe,20Ty0imee| 2.00 4.00 6.00 8.00 10.00 12.00 " Sxygen Research, 3058 Research Drive, State College, FA 16801 Exygen Research, 3058 Research Drive, State College, PA 16801 "- `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEEASCCTLTTRTITCOOT AACOPPURRROOTT.TEECNCTOT.IIVV2EE7-OOCRR\-DD1EE0RR-2E6E3NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00339955 a_morsses: 3M MN01538781 4 QQSutuauandntytiiNftoyy..SsLaaImm8ppTllAee,RReeSppeootrrttNo.:021804AR, Ext.Date:02/18/04, Analysti.Risha PPaaggee 7722 ,4 Study No.=LI874, Set No.:021804AR, Ext.Date:02/18/04, Analyst:K.Risha SLSeaamsmp?pllemeodLLiiifssitte::d: PToP:a:\\DWDaaatrtaa\\L0L3CCMNS1SM3M1SS06S7\\1MM0aa0ssssl2ly0y0nn4xe\\FFlluuoorroocchheemmiiccaellss..PPRROO\\SSaAmEppl1eeDDBD\\002F11860044AARR CCOG AACCSSFTM Wo MLTMLLeaoeaatsntsshhtttoocddmmme:sooonddd:iiifefiiieeeddd:;: vTPou:\ne\DDaMaptatearba\\LL00C3C2HMSS01MM72ES5:E6004\7M1=Ma40an30sss1l22yy00m00nc44x\\PFlluucorroocchheenmiiccaallss.PPRROO\\MNeStEhHDDBR\\CCoottGdrroovvee Mon Feb 02 0?=04:42 2004 Nk-FPDDEESS 001122110044 Job Code: # ePrriinntteeda= TTuuee MMaarr 0022 1144:10055:12222 22000044 omeNam:e= 0o2r1i8s0o4uAsRe--2a3s6e 4: ce suizonste prus Text: 4:C6 Sulfonate PFHS a ILL11887744--88,, DDFF==11000000 021804ARS.m2(3Mn6, 2:3) 021804AR-236 Sm (Mn, 2x3) i" | oihrermrpre [cforas,oF=t000 ` { 22..0000 5: ca 5:C8 sSuullffoonnaattee pPrFoOsS L1874-8, DF=1000 1021804AR-236 Sm (Mn, 263) ro | 021804AR-236 Sm (Mn, 2x3) | a |1 - 200 11/I .... , .... , .... , 2.00 44..0000 a0 .... , .... 4.00 0011--MMaarr--22000044 2233::3355::33(0 LCIMSIMS LC/MS/MS #6 70 MofRChaM nne3l9s>ES8-0) 8.79 rar rooed 3747 MRM of 5 Channels ES399 > 80 1.99e4 reaArea _ || re ~ 66..0000 88..0000 1100..0000 1122..0000 TMar-2004 23:35 01-Mar-2004 23:35:30 LLCC//MMSS//MMSS #6 sr MRMof 5 Chann"ai9s E5S5. 9.17 MRM of 5 Channels ES499 > 99 Ey T4504Ar 1.49e4Area | rep Tine || , .... , .... , .... , ..2..82,7.~... ,, ,, .... ,Time 600 800 i050 200 6.00 8.00 10.00 12.00 " a " Sxygen Ressarch, 3050 Research Drive, State College, PA 16801 Exygen Research, 3058 Research Drive, State College, PA 16801 - `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACOPPURRROOTT,TEECNCTOT.IIVV2E7E-OOCVRR-DD1EE0RR28EE8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00339966 _mNots38TE2 3M MN01538782 " 4 gQSuutaaundntytiiNtfoyy..SSLaa1mm0pp7ll4ee, RReSeepproorrttNo.:021004AR, Ext.Date:03/18/04, AnslystiK.Risha PPaaggee 7723 Study No.:LI874, Set No.:021804AR, Ext.Date:02/18/04, Analyst=K.Risha PR LLSSaaaessmm?tppllememooddLLiiiiffssiitt:ee:dd::PiTPTPi\uu:\Des\DADaMWtaattaara\a\L\0L0CL32CSCMHHS11SMM22GSS1:\0066M77\\aM:1Msa00ass00slssy1l22m0y0yx00n4\4xmF\lFxulou\orroFocchlhaeusmioiccarallaos..cPPPRRRhOOO\\\eNSSSaaaLmsHpipDllBece\DCDBaoB\\t0lOd2Zr1aL8oE.0v04eAANRRPDCCEGGSAAC0CS1S2FI1M04 oMLLeaabtsshttocdomm:dooadd:iiffiieedd=: Non Tab 03 07104143 2004 P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\MethDB\CotGrove Mon Feb 02 0?:04:42 2004 NPDES 012104 Job Code= eeintes: ue uaz 02 14105122 2008 Printed: Tue Mar 02 14=05:22 2004 4 [ ren p-- Name= 021804AR-237 Text= { i1:: XCcC6s02An2ce4it04da3,PoFr1H0mA0 ng Standard _ oo _01-Mar-2004 23:57:1 XC022404-3, 100 ng/L Standard . 0218044R.237 Sm (Mn, 23) 021804AR-237 Sm (Mn, 2x3) ais 0M1R-MMaorf-2LL0CCe0h/4maMns2SnI3Ie:MMl5SS7E:S1#-76 MRM of 5 35.209 Channels ES- | 281.64835 31311>..3r382e8e60a595) Area wo | i | obtr 200 rrr "00pee500rer500rem100e0 re1200im| 2.00 4.00 6.00 8.00 10.00 12.00 A 22[::xCcC0o822Aa6cc0iidd43Pp,Fr1oO0nA0 ngiL _ Standard 01-Mar-2004 23:57:1 XC022404-3, 100 ng/L Standard 002p211o880044AARR-223377 SSmm ((MMnn,, 223x33)) 0M1R-MMaorf-25LL0CCO0h/M4aMnS2nSI3eIlM:M5sSS7E:S1#-76 890 MRM of 5 5.309 Channels ES- ` 292899.9898787| ea 41311.>.7713166e595) * Area ! | Ole AI Time L . 200, .... , 300 .... , .... , 500 .... r .... , 800 .... T'-''', 1000 .... , .... , 200 .... ~ Time 2.00 4.00 6.00 8.00 10.00 12.00 3: ce sulfonate pews - 3X[X:CCC00422224S40u04l4-f-3o3,n, a11t00e00 PnnFggB//SLL SSttaannddaarrdd 0011--MMaarr--22L00O00M44 S22I33::M55S77::17 100:2211880044AARR-223377 SSmm ((MMnn,, 226x33)) ats MRM MRM of of 55LGCChhIaMannnSn7a/eiM9lss0SEE5SS9#--69 1, 048.15 pene 299 > 99 4.24e3 | ea | % Area| H l| ener;Ate T -- e 22.0000 44.0000 65.0000 B8.0000 000 10.00 7%Time 12.00 a EExxyyggeenn RReesseesasrcchh,, 33005580 RReesseeaarscchh DDerlivvee,, SSttaattee CCoolllleeggee,, PTAA 1166680011 `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACOPPURRROOTT,TEECNCTOT.IIVV2E7E-OOCVRR-DD1EE0RR28EE8NN6TT2EERREEDD IINN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00339077 _MNO1S3878Y 3M MN01538783 LB J NL onsen, Quantify Sample Report mxe.oatersa/0/06, Amsiystixnisne J Page 74 SSLSaaatsmmutppdllymeeoNidLoLiii.ifss:ttitLise=Iid8e:74,BMPTu=he\SDeieMtaatsSrNa\o\.Lu0o=2CeD0Mb2ST11Ma2s8rS:a0e0647\eA:MicR0aoa,0essalT2yyy0Eam0snxs\4xt\.FFDFiialLtutuooeorr:rCoo0occ2chh/heeH1esm8mii/icc0Ncaa4al,llsssG.A.FnPROaRO\ElO\Ky\SGsS\LataIr=mTKpp.WlElRe\aiDCDsBao\h\RG0aGE2sr1Lo8Ov0Mse4AARPRDCCEOGSAAC0C1S7FO1M08 MSLeaatsnhthtodema=oedt!ifciieeda=: Hon ren Se ers P:\Data\LCMSMS6\Masslynx\Pluorochamicals.PRO\MethDB\CotGrove Mon Feb 02 07=04=42 2004 NPD~S 012104 Job Code~ " PPrriinntteedd=: "TTuuee MMaarr 0022 1144=:0055=:2222 22000044 | mm sous Name~ 021804AR-237 4T1extc~o surtonace prs 4:C6 Sulfonate PFHS a X[XCC002222440044--33,, 110000 nngg//LL SSttaannddaarrdd y (|cat6106AR.237 5m vn, 2) 021804AR-237 Sm (Mn, 2x3) as8.79 4040991~ 0011--MMaarr--22000044 2233::5577:1:17 LLCC//MMSS//MMSS #6 MRM of Chamois 5- MRM of 5 Channels ES50 399 > 80 22..22770e44) aArea [I o/ol | | berms pr reprerrr eer peBeer ne 0,--~--~-,,, .... , .... , .... , .... , .... , .... , .... , ~~ ...... , ,,~~,,,,~-~,, Time ' 28 ib 5 ab ooo po 2.00 4.00 6.00 8.00 10.00 12.00 5C::C88 Sulfonate PPPFOOSS____ ------ 1 [XxCco02222440044--33,, 110000 nngg//LL SSttaannddaarrdd 0011--MMaarr--22000044 2233::5577::117 LLCC//MMSS//MMSS #6 221806427 5m vn, 23) MRM 0 Grama 5- 021804AR-237 Sm (Mn, 2x3) or hs i i 9.17 3356 MRM of 5 Channels ES499 > 99 11..77666e44, | aArea | i | "1 I | B ~e .... , .... , .... , .... r .... , ,,, ,-~ ":,,,, .... , .... , .... , .... , .... "~Time | py prs o% a Too oe 2.00 4.00 6.00 8.00 10.00 12.00 . - a Exon Exygen RReesseeaasrcchh,, 33005588 RReesseeuasrcchh DDrriivvee,, State State College: College, TA PA 16001 16801 " CCHEOONNNNFEIDFPEIINNTDCIAOELU-NN- TSSTUYUIBBDJJIAEESCCTLTTRTITCOOT AAGPOPURRROOTT.TEECNCTOTIIVV2EE7 -OO0RR1-DD1EE0RR.0E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00339988 Sw umorsseTss 3M MN01538784 4 QQSuutaaundntytiiNtfoyy.iSSLua1mm8pp7ll4ee,RReSeepptoorrttNo.:021006AR, Ext.Date:02/19/04, Amalystik.Risha Pago 75 Study No.:LI874, Set No.:021804AR, Ext.Date:02/18/04, Analyst:K.Risha 4 LvSLSeaaaatssmmhttppollammeerooddLLiiiiffssilteee::dd=s TPPPTuu::iee\\D\DMaaaDatxtraaa\c\L00L22CeMC\1S1H2M2NL:=SSC006\77\UN:=Ma00Ma00gsSss2l2Ei00yy\00nm84xM\\aFFllsuusoorrloocychhneeameii\ccaaFlliss.vPPPoRRROOOr\\\SoSNaaecmmLpphH1DeeBeD\nDCBBio\\t0c2G21ar18o8l0v04se4AA.RRNPDCCEGOSAAC0CS1SF2FM104 MFLLeoaatnsshtocdmom=dooeda:itfeiteedd=: Mon rob 07 67108143 2008 P:\Data\LCMSMS6\Masslynx\Pluorochemicals.PRO\MethDB\CotGrove Mon Feb 02 07=04=42 2004 NPDES 012104 Job Code= ,,IIi erates: Printed= Tue Maz 02 14:05:22 2004 Tue Mar 02 14=05=22 2004 J dNaemmee: onsen 021804AR-238 Text: 1: cs neta pen 4 i[5:L1T8C87647-4A99c,i,Dd0FFP==F11H00A00 21804AR238 Sm (Mo, 2:3) 021804AR-238 Sm (Mn, 2x3) ' | *1 eaa80.u4ss83 0022--MMaarr--22L00C0044MS000I0::M11S99::000 MRM MRM of of 5LCCChh/aaMnn33nSn1e1el3lM3"lss5s>So2EE20S6S#6e-0-96s Area 3.00e5 Area | 1 ` 260 400 600 68000053~ re 1000 re20T0ime | 2.00 4.00 6.00 8.00 10.00 12.00 22[::18cCo874AascciiDddF=PpFe1Oo0Ar0 02-Mar-2004 00:19: L1874-9, DF=100 00o2211e880044A4RR--223388 5m Sm (Mn, (Mn, 2x3) 2x3) 858 0M2R-MMaorf-25LL0CCC0hI/4aMMnS0nSI0e/MlM:1sSS9:E:S0#.06 MRM of 5 415 Channels 3E0S9- : 10~ 21378 8.98 21378~ 41311.>.1r1993o8e6a559)) Area 4 % [= - Om...m .20, 0.... , e ....40, 0...e . , ....65,0.e ... ~ ....80, 0 , 1E ,0,00..S .. ,,S ,, 2,~0T0Tiimnee 2.00 4.00 6.00 8.00 10.00 12.00 33[:L:1C8c47a4-sS9uu,llDtfFoon=naa1ct0ee0 PpFeBaSs _ 02-Mar-2004 00:19:0 - L1874-9, DF=100 10218044RS:m2(M3n8, 2x3) 0M2R-MMoafr-25LL0CCC0hM/4aMSn0nSI0eM/:lM1Ss9S:E:0S#1-e: - 00,1 021804AR-238 Sm (Mn, 2x3) Taoi8a.1sd5 MRM of 5 26298150949) Channels ES299 > 99 1 ea) 2.81e4 Area O 1 e ee Tine| .... ~ .... , .... ~ .... , .... , .... , .... , .... ~ .... , .... , .... ~ Time , - 200 400 600 800 1000 200" | 2.00 4.00 6.00 8.00 10.00 12.00 .i Teygen Research, 3058 Research Drive, State College, 7A 16801 Exygen Research, 3058 Research Drive, State College, PA 16801 . `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACOPPURRROOTT,TEECNCTOT,IIVV2EE7-OOCRRV-DD1EE0RR.2E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00339999 Su_mNotssses 3M MN01538785 uw QSQuuuaadnnyttiiNffoyy.,SSLaa1mm6pp7ll4ee,RReeSppefoorrttNo.:031004K%, Ext.Date:02/18/04, Analysti.Risha Page 76 Page 76 Study No. :L1874, Set No. :021804AR, Ext.Date:02/18/04, Analyst:K.Risha u eLSLSataaasmmsntpptolldeemmsooddLLiiiiffssitit=ee:dd:=Pr7TTP\:uu=D\ee\aDDtaWMaataat\arraL\\CLL00HC23CSHMMSS11SHM23SSS::\6060M\7\7a=a:Ms00ass00slssyI2l2m00yay00n\44xFm\PFxiluu\oorrFooccihheeunmiioccarallsos..PPcPRRRhOOO\\\eSKSaAaasmHppDillRae\cDDCIBaoN\tG0lG22rL1s0o800.v44eAANRREDCCEGGSAAC0C1S2FS1M04 oLMLebaat"sshttocdomm=dooeddriifiioedd:: Non Fab 02 07:04:43 2004 P=\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\MethDB\CotGrove Mon Feb 02 07=04=42 2004 NPDES 012104 Job Code: sstneess Tue Mar 02 14105122 2004 Printed: Tue Mar 02 14=05=22 2004 , NNaemmea= o02n1s8o04sAnRa-2s3e8 | _ INIVSVAN Text= 44::LC1c86s74sS9uul,ltf0aoFnn=aa1tt0ee0 pPFrHiSs L1874-9, DF=100 [o21804aR-238 5m vin, 2) +| 100, 021804AR-238 10 Sm (Mn, 2x3) "ox 02-Mar-2004 00:19:01 i. 0M2R-MMaorf-2LL0CCO0h/M4aMnS0nSIe0/lM:M1sSS9E:S0#-06 809 MRM of 5 Chann9e95ls5>E16S830-) 809-~ rea 5.51e3 .Area | iL| 0 ' .... ] 20~ 0.... ' ....40' 0.... ' ....60' 0.... ' t ....80' 0._ ...~ ' .A ...10'00.... ' ....20,0Time 2.00 4.00 6.00 8.00 10.00 12.00 5::[LcC1o887sS4uu9ll,ffDooFnn=aa1tt0ee0 PpFrOosS _ _ 02-Mar-2004 00:19: L1874-9, DF=100 021604AR.2S3m8 (4n, 2x3) gy 0M2R-MMoarr-S2LLC0CC0rI4IaMMm0SSe0I/s:MM1ES9Ss:#0.60 LE 100, 021804AR-238 Sm (Mn, 2x3) ;1094.157 MRM of 5 29> 99 Channels ES- 4959.9>86939] |1 re 5.98e3 a %1 Area 1 - | e 256 prse 600 800 e 000 20T0ie 2.00 4.00 6.00 8.00 10.00 12.00 - " ` Exygen Research, 3050 Reseach Drive, State College, PA 16801 Exygen Research, 3058 Research Drive, State College, PA 16801 . `CHEOGNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIJDJIEAESCCTLTTRTITCOOT AACPOPURRROOTT.TEECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR.2E6E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00440000 SW_no1S3878 3M MN01538786 ; Quantify Sample Report Study No.:LI874, Set No.:021804AR, Ext.Date=02/18/04, Analyst:K.Risha Page 77 J Sample List: P=\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\Samp1eDB\021804AR CG ACSFM STL. Ln Last modified= Tue Mar 02 12=07=00 2004 i Ee ES wwrmivrnreteamoseme woe coe Method= P=\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\MethDB\CotGrove NPDES 012104 aEh h Last modified= Mon Feb 02 07=04=42 2004 Job Code= , rm f pPrriintteeadr= TTuuee MMaarr 0022 1144::0055=:2222 22000044 Name: 021804AR-239 Text: i: C6 Acid PFHA a:I, a [LL11887744--99 RReepp,, DDFF==110000 021804AR-239 Sm (Mn, 2x3) = | a 1 1'o/! 22..0000 44..0000 66..0000 2: C8 Acid PFOA , IA ` |LL11887744.-99 RReepp,, DDFF==110000 021804AR-239 Sm (Mn, 2x3) 10 i `| i . i/1 ETE 0,--'~'~-',~,-,, , , ,'~ , , ~ , , , 2.00 4.00 6.00 i"8.50 712! 88..0000 0022--MMaarr--22000044 0000::4400::55(C LLCC/IMMSS/IMMSS #6 a MRM of 5 Channels ESoe 313 > 269 LE3.08e5 = |Area a 1100..0000 | 1122..00T00ime wr9.00 2211338611-~ 0022--MMaarr--22000044 0000::440:0!:50 LLCC//MMSS//MMSS #6 aa MRM of 5 Channels ESes] 413 > 369 11..2211ee55/ =Area ae , , , , , , , Time 8.00 10.00 12.00 3:C4 Su~[fonate PFBS .,m enon 2 |LL11887744--99 RReepp,, DDFF==1t0000 021804AR-239 Sm (Mn, 2x3) . |% | | or 1'o/l TE ---------- 2.00 4.00 6.00 ES8.15 ee8.00 0022--MMaarr--22000044 0000::4400::!51~ LCIMS/MS PL MRM of 5 Channels ES- 299 > 99 5s2.55e4 2Area TR Tepe Tie 10.00 12.00 a . Exygen Research, 3058 Research Drive, State College, PA 16801 CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00440011 3M MN01538787 4 QSQtuuuaadnnyttiiNtfoyy.rSSLaaImm0pp7ll4ee, RReSepeptoorrttNo.:0Z1604AR, Ext.Date:02/16/04, Analyatik.Risha PPaaggee 7786 Study No.:LI874, Set No.:021804AR, Ext.Date=02/18/04, Analyst=K.Risha LSSaaasmmtppllmeeodLLiiifssitt=e:d::\TPDu=ae\tDeNa\atLraC\HL0SC3HMSS13M6:S\66N7\a:Ms0aa0slsy2lm0yx0n\4xP\lFulouroorcochheemmiiccaallss..PPRROO\\SSAammpplleeDDDB\\002211680044AARR CCOG AACCSSFFM W 3MLLeL6eaaatthssshhtttoCodommms=doooedddriiiffiiioeeddd:== TPN71ou=\ne\DDaMaFtaatabra\\LL00C3C2HMES01NM72SS:=66004\7a::M04as03sssl2y20y000na84x\xFl\uoFrolchuemoicoalcs.PPhRROOe\\NMseatEihDDBcB\\CaCoolttGraroov.vee Mon Feb 02 0?=04=42 2004 NNPPDDEESS 001122110044 Job Code= deiPnrinete:d= Tue Mar 02 14:05:22 2004 Tue Mar 02 14:05=22 2004 1 NNaammae:= 002211880040A%R--223399 rex: Text= 44:[:LC166674sS9uullRffooopnn,aattDeeF=Pp1Fr0Hs0S L1874-9 Rep, DF=100 l021804AR.239 Sm (in, 263) " we Sees . 4021804AR-239 Sm (Mn, 2x3) 0022--MMaarr--22000044 0000::4400::5500 MRM of 5LLCCChIIaMMnnSSeIIlMMsSSES##-65 8o.r7e9 MRM of 5 39>60 Channels ES- 399 > 80 Area, vz Bd ` 200 400 600 - 500 1000 120T0ime| 110%-~~,, , , .... _~ .... , .... , .... , .... , .... , .... , ~7~9, 9, ~, .~.....~~, .~.5.."0i 2..e.3. A,Trim eea 2.00 4.00 6.00 8.00 10.00 12.00 5: co sulfonate pros : C8 Sulfonate PFOS 4 [18749 Rep, DF=100 02-Mar-2L0O0M4S00I:M40S:5i ,| L1874-9 Rep, DF=100 021802439ASRm (Mn, 2x3) oy MRMorSCramatEs. 021804AR-239 Sm (Mr], 2x3) ` Toyi st 49559a55r0e03a ,j 10 9.17 961 ~ 02-Mar-2004 00:40:50 LC/MSIMS #6 MRM of 5 Channels ES499 > 99 5.55e3 Area i|=/~ | e e e Tne || O" .... , .... , ,,,, .... , .... , .... ~ .... , .... , .... , .... , .... , .... ,Time . 256 400 600 800 1000 200 2.00 4.00 6.00 8.00 10.00 12.00 - " o " Eeygen Research, 3050 Research Drive, State College, 7A 16801 Exygen Research, 3058 Research Drive, State College, PA 16801 a `CHEOGNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIJDJIEAESCCTLTTRTITCOOT AACPOPURRROOTT.TEECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR.2E6E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00440022 SW_no1s387E8 3M MN01538788 Lo QQSuuEaannNttiitfyy sample Sample TReeppoorrNtte. oamsoin, axe.nates02/10/04, Anaoyx naiatne sage 7 PR ESLSSaae~tssmmuetppdllyememooNddoLLii.iiffs=aiittL:ee.Idd8::74,Bu3PTu=:soe\\SDeOaMWatNaatCerraNa\o\\L.Lb0U:2CauO0MEd2S11N1M23S8S:1S0600\47\0WA=1MaRa00as,s00saasl2l2y0y0yEm50nnx44xt\.\FFDFialultuoeoou:rc0oho2ca/hs1zei8mc/ioa0c4lac,al.shA.nPPPeaRRRlOOOy\\\nSsSWAateiEm:EppHKcDLl.DeeR\aDDiCBBso\\hltO0aaT2aL1rA8o.OOvA4sAARRNEDCCEGOSAAC0CS1E1FH1M04 ,M MLm EeaatsshttoedBm=ooadtitfiiaedd:: Hon Feb 05 01 sods43 2000 P=\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\MethDB\CotGrove Mon Feb 02 07:04:42 2004 NPDES 012104 BenJtoboConde= me war 02 e052 2008 Printed= Tue Mar 02 14:05=22 2004 J -- ,1i TNTeaexmxtet:== 021804AR-240 3: co acid vem i: C6 Acid PFHA . (021804R5.m2t4n0, 29) 1 L18178744--1100,, DDFF==110000 021804AR-240 Sm (Mn, 2x3) | ss8.50 76099 0022--MMaarr--22000044 0011::0022::4411 LCIMSIMS #6 LC/MS/MS #6/ MRM of CharrE5o- MRM of 5 Channels ES- I 3105r2e60a 31333>..332226e595 `| *l 11o/1 760991 Area;i~ ` ok 200 ao obo ah 00em20Tima 2.00 4.00 6.00 8.00 10.00 12.00 3. co neta oron 2:C8 Acid PFOA . |I(C212480 05m4(MRn, 233) Pl L18187744--1100,, DDFF==110000 021804AR-240 Sm (Mn, 2x3) ' |" ,i Ba8s=.9e8 0022--MMaarr--22000044 0011::0022::4411 LLCC//MMSS/IMMSS #6 MofR5ChaM nel E5- MRM of 5 Channels ESpee 413 > 369 "apesAArreeaa | | 0eames memm se e SSSs SE Time ., .... ~ .... , .... , .... , .... , .... , .... , .... , .... , .... h Time oo 200 py 00 0) 00 20 2.00 4.00 6.00 8.00 10.00 12.00 3. ct suitonate seus 3:C4 Sulfonate PFBS L18178744--1100,, DDFF==110000 - (c2180424a0R 5m n. 29) MRM ofLCChIaMnnSeIlMsS5. 021804AR-240 Sm (Mn, 2x3) sir 255 e>3a0 " 0022--MMaarr--22000044 0011::0022::4411 LC/MS/MS #6 MRM of 5 Channels ES- 86.1177 29339..33.22e90494 A~a " %C 1 r rEp rere Tite . { , ....22..0,000.... , ....44..0,000.... , ....66..0,000.... , ....88..0,000.... , ...1.100..,000.0... ~ ....1122..,0T000ime a Exrgen Ressscch, 3050 Reseaceh Drive, State College, BA 16801 Exygen Research, 3058 Research Drive, State College, PA 16801 - `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NTSSTUYUBBIDJJIAEESCCTLTTRITTCOOT AACOPPURRROOTT.TEECNCTGT.IIVV2EE7-OOGRRu-DD1EE0RR.2E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00440033 au_norsasTas 3M MN01538789 " W qQSuutaaunndttyiitfNyyo.SS.aaLmmTppOll7ee, RReeSppaootrrttNo.:021004AR, Rxt.Date:02/16/04, AnalystiX.Risha PPaaggee 8800 Study No.:LIS?4, Set No.:021804AR, Ext.Date:02/18/04, Analyst:K.Risha LSSaaesmmtppllemeodLLiiifssitt:e:d:P:TP\u:De\aDtMaaat\raL\CL03HCSMSH1MS2S1E60\7\M1Ma0as0sssll2yy0m0nc4x\\FFlluuoorroocchheenmiiccaallss..PPRROO\\SSaamnpplleaDDBB\\0O2Z11860044AARR CCGO AACCSSTFHM MLoeLLeanaarts"ssehtttodcdmmom::doooedddriiifftiiieeeddd::: WTPPieu~\en\DDaMaTtataarba\\LL00C32CHMSS10HM27SS::S06074\\::MM04aa03nsssll22yy00m00nc84x\\FPlluuoorroocchheenmiiccaallss.PPRROO\NMSeEtHhDDNB\\CCoottGGrroovvee. KNFPDDEESS Mon Feb 02 07:04:42 2004 001122110044 Job Code: pPrriinntteedd:: TTu~ee MMaarr 0022 1144::0055::2222 22000044 rNNaaemmeesz: 002211080084A1R8--224400 Text~ #4 ~4[.::L8CC7664-sS1uu0ll,ffDooFnnaa=tt1ee00pPrFiHsS L1874-10, DF=100 10218042A40R Sm (Mn, 233) [EY 021804AR-240 Sm (Mn, 2x3) e"r908.79 990-~ 0022--MMaarr--22L00O0044MS001I1::M00S22::4411 MRM MRM of of 5LCCChh/aMannnSn9ee/lM9lss>SEESS#8--60 39689..0r0>44ee86a303) wo *1001 A |I Sad | Time| 0' .... , .... , . | 200 ao 500 500 1000 200 2.00 .~, .... , .... , .... , ........ ~ ? ~.. , .... ~ .... , .... ,Time 4.00 6.00 8.00 10.00 12.00 5: co sulfonate oros 5:C8 Sulfonate PFOS aw [L1874-10,DF=100 02-Mar-200401:02:41 L1874-10, DF=100 0[2w1o8y 044R.2S4m0 (Mn, 263) S0ot MRMof 5LCOhManSn9Iai9M5s.>Sr1E19eS63-)a) 021804AR-240 Sm (Mn, 2x3) 02-Mar-2004 01:02:41 LC/MS/MS #6 MRM of 5 Channels ES- 9.17 499 > 99 5.11e3 Area * a % _ rn 100~ ~ - 206 350 e650e 850 ---- 1000 --200 0I .... , ,,,, .... , .... , .... , .... , .... , .... , .... , .... , .... , .... ,Time 2.00 4.00 6.00 8.00 10.00 12.00 - " " a EExxyyggeenn RReessesaarrcchh,, 33005588 RReesseeaarcchh DDrriivvee,, SSttaattee CCoolllleeggee,, PPAA 1166880011 - `CHEOGNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIJDJIEAESCCTLTTRTITCOOT AACPOPURRROOTT.TEECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR.2E6E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 1993377..00440044 SW_MNO1838790 3M MN01538790 P 4 QqSuuaannttiiItfyy SsL aammppllee.rReeppoorrtot nsen, mesDacer6a/a0/00, aatystix Bish J Page 81 eLSESSaaeatsmemutp?pdmllySeemooNbdoLLiii.ifts:sititL:e:aIda8|=:74,PTBmuu::ea\S\cDeDuMataaat\ctraNaa\o\.L50w5:2CL0aMC2ST1HN1Ma2S8rS:E0o064)7\WMA=Ma0aR0asg0,0sassyl2y2m0y0EDa00nxH\s4tx\P.\FiDF3ualuotuoreooc:rcc0oh2hce/ehm1me8iim/cic0ece4Lal,alas..A.PPnPRaRROlOO\y\\SsSWAtaAS:mCOKpA1.lDAReDDiD\IsBGAh\oOa0L2LG1Ro8Gv0Ae4NARORDCCEOGSAAC0CS12FO1M04 sCerat aeteied: Method= Last modified: Kon veh 65 tod dh 200k P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\MethDB\CotGrove Mon Feb 02 07:04:42 2004 NPDES 012104 Wma Job Code= ve ar 02 200822 2004 Printed: Tue Mar 02 14=05:22 2004 ome onsousan Name= 021804AR-241 1: co nid mn Text= i: C6 Acid PFHA - |LL11887744--99,, DDFF==1100 jw|002211880044AARR--224411 SSmm ((MMnn,, 22xx33)) ] sso8.50 651496 020-2M-Marar--22000044001:12:244:2:2!1 LemsiNs LC/MS/MS #1~ MMRRMMooff 5 CChhaannnneellss EESS-- Taea5l0 31333..1>11e126eA6r6e9|a `| | , .... , .... , .... , .... , .... ~ .... , ...6.51,4.9.6.~. , .... , .... ~ .... ,TTiimmee | 35 iE 55 pry ow frit 2.00 4.00 6.00 8.00 10.00 12.00 3. cn seid oro : c8 Acid PFOA a4 LL11887744--99,, DDFF==1100 . crzsanR2415m 4, 23 22Is RWof ChaTmeolp yao5ee- 021804AR-241 Sm (Mn, 2x3) 9.00 207218| 0022--MMaarr--22000044 0011::2244::25 LLCC//MMSS/IMMSS #6 MRM of 5 Channels ES413 > 369 1.10e6 Area | - Tine | 0~ ,,, ~,,, ~ .... ~ .... ~ ........ ~ .... ~ .... , .... , .... , .... , .... ~Time - 20 We a5 Woo Ta 2.00 4.00 6.00 8.00 10.00 12.00 3: ct suitonate pens : C4 Sulfonate PFBS L1674-9, OF=10 Nar 2004 0124.2 L1874-9, DF--10 - (c:zsennR241 5m 0, 20) MRMof 5 Channel E5- 021804AR-241 Sm (Mn, 2x3) TM Too> a - 1~ po uv~ o || ~ 8.15 8585000944-~ I 02-Mar-2004 01:24:25 LLCC//MMSS//MMSS #6 MRM of 5 Channels ES299 > 99 33..0011ee55| Area A pry 5 I) a0 000 ToTime 0 Time 2.00 4.00 6.00 8.00 10.00 12.00 a Sxygen Reseach, 3038 Rasencch Drive, State College, TA 16801 Exygen Research, 3058 Research Drive, State College, PA 16801 - CCROEONNNFNIDFEEIRNTDCIAOELU-NN- TSSTUYUIBBDJJIAEESCCTLTTRITTCOOT AACPOPURRROOTT.TEECNCTOT.IIVV2EE7-OO0RR1-DD1EE0RR.2E8E9NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00440055 awmorsaaron 3M MN01538791 " a GSQuuRaannEttiiTfcyy SsRaammppLllee RReeRppeoo.rrtot ris0aan, xk.oate:02/10/04, Anaiyatik.Risha rage 82 Page 82 a LaSTSSaaeattsrmmuhttppdellynsmeesooNddoLLii.iizf:ssiitLte:e:Idd8::745,TuP:u:\se\SDDDeaaMtwattaataarrNa)\o\LL.0L0C:52CHe0MS2S11H1M32sS81:SS0006437\WkA1:MaaR00asa,00ssssil2L2y0y0Eym00nxme44txc\.\\PDFFialuutuooeozo:ros0och2che/hem1emi8imc/ci0aac4lla,ssl..sA.nPFPaRRRlOOOy\\\sSNSatemm:CppKK11.DaeHRDD\iBCBs\o\hOt0aTO2Lr10o8v00e44KARRNFCDCOGESAAC0CS1SF2FM104 MLECeaartsrhttodmm=ooddiitfsieedd:s won Tob 03 07104143 2004 P=\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\MethDB\CotGrove Mon Feb 02 07=04:42 2004 NPDES 012104 Wo JeoribntCeoddse: Tue war 02 14:05:22 2008 Printed= Tue Mar 02 14=05=22 2004 yepNaeemset= o02n1s80o4AoRn-2a4n1 4T:extc=e sulfonate pews 4:C6 Sulfonate PFHS - L18178744--99,, DDFF==1100 vo 00) PE (021804AR261 Sm (tn,2) 021804AR-241 Sm (Mn, 2x3) La as8.80 9993~ 0022--MMaarr--22000044 0011::2244::25 LCMSIMS LC/MSlMS #6 MRMof Channols ES. MRM of 5 Channels ES- 36H>rLe8a0 399 . 80 5.32e4Area | rere Time | .... ~ .... ~ .... ~ .... ~ .... ~ .... ~ .... ~ .... = .... ~, ~Time "| 250 Pry 5 abo 1000 200 2.00 4.00 6.00 8.00 10.00 12.00 5. casulfonate pros 4 5L|:L1C1878847-4S99u,,lDfDoFFn==a11t00e PFOS a | (w2o1,6084261 5m (Mn, 2:3) u9s1.0 MoR f ChaM nne5lss5E50- 021804AR-241 Sm (Mn, 2x3) 0022--MMaarr--22000044 0011::2244::22!5 LLCC//MMSS/IMMSS #6 MRM of 5 Channels ES- 9.19 499 . 99 |i `areal `* 9945~ | 5.29e4Area - 2600 ao 550 B00 Too 200 ober , , , , , , , ....b..e ...e. e ~ n, , 7TTiime 2.00 4.00 6.00 8.00 10.00 12.00 P " EE~xryggoenn RReessseaarrcchh,, 33005588 RReessesaarccehh DDrriivvee,, SSttaattee CCoolllleeggee,, P7AA 1166880011 `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACOPPURRROOTT.TEECNCTOT.IIVV2EE7-OOCRR\-DD1EE0RR-2E6E3NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00440066 m_morsseTse 3M MN01538792 " a QqSuuaaRnnttiicfTyy sSaaL mmpplleeS BReeppoorrtNto. onsen, xt.ate:02/10/04, Anaiyatok.Risha rage 32 Page 83 SESSaaatmsmuptpdllymeeoNdoLLii.ifss:ittLe=:Id8:|74P,TP:u=\e\SDDeaWtacatarNa\o\L.L0C5CtHM0SS12HM31S1S8S006\43\aA1MRs0a,0sslsylTmyEhcnxtx\.\FDFialutuoeor:ro0oc2ch/ha1en8mi/ic0ca4al,lss.A.nPFaRRlOOy\\sGSatam:mpKpl.1aReDiDDsB\h\0a0O2T1L800044AARR CO CG ACEH ACSFM 4 TaMLLaeaatntssmkhttocodmmmas=ooeedddriiifcfiiieeeddd=:= wTP22eu=ne\DDaMaTtatoarba\LL00e52CMvS10eM27S=1e60074\a1=Mn40as30sisylF2my00e0n0\44xF\lFulouroorcohcehmeimciaclasl.s.PFRROO\\MNeetShHDDBB\\CCoottGarroovvee Mort Feb 02 0?=04=42 2004 NNEPDDEESS 001122110044 eJorbatCoedde: Tue war 02 10105032 2008 Printed= Tue Mar 02 14=05=22 2004 oNwaanmnee:: 02190088242 021804AR-242 T1:extc:e reid oem 4 I[L:L1188C77644.-A99ciRRdeeppP,,FDHDAFF==1100 l0218240254mA(4R,269) 021804AR-242 Sm (Mn, 2x3) " 11( " *1 [a | 200 + 22[.:18cC78o4nA9ectiRadopPs,FrDOoAnF=2.1000 L1874-9 Rep, DF=10 . (021266205m4(44, 263) 021804AR-242 Sm (Mn, 2x3) "1 i/! 1| : a --550 4.00 6.00 680284.64828 9 B50 8.00 o88i.99s8 0022--MMaarr--22000044 0011::4466::118 LLCC/lMMSS//MMSS #6 MRMof hanno ES- MRM of 5 Channels ES331133>> 226699 22..7733e66| rea) Area 000 76 | 10.00 TTiimmee 12.00 02-Mar-2004 01:46:1 02-Mar-2004 01:46:18 LLCC//MMSS//MMSS #6 MRMof 5 Channels ES- MRM of 5 Channels ESa0) 413 > 369 "orteeqa, 1.02e6Area 014 , ,, ~ .... , .... -, .... , .... , .... , .... , .... T,1.9.1.8.37,~.... , .... , .... ,TTiimmee . P10) a0 50 0 0% 2 2.00 4.00 6.00 8.00 10.00 12.00 3. co sutonate prs 3:C4 Su]fonate PFBS Lh1i887744--99 RReepp,, DDFF==1I00 - (" 0218240254m4(MRn, 2) MRMof 5 Channels E5- 021804AR-242 Sm (Mn, 2x3) | ar 26>e9s9 - 0022--MMaarr--22000044 0011::4466::1111] LLCC/lMMSS//MMSS 8.13 18 MRM of 5 Channels ES299 > 99 22..77446e55) Area "` || 50 206 eeabo 560 800 i050 20T0ime | 2.00 4.00 6.00 8.00 10.00 12.00 li " Sxrgen Rossarch, 3050 Reseacch Orive, State College, Th 16901 Er!gen Research, 3058 Research Drive, State College, PA 16801 . `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEEASCCTLTTRTITCOOT AACOPPURRROOTT.TEECNCTOT.IIVV2EE7-OOCRR\-DD1EE0RR-2E6E3NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 m_morssees 3M MN01538793 11993377..00440077 " W gQSuutauandntytiiHefoyy..sSLaaammwpp7ll4ee, RRSeeapptoorrttNo.i071004AR, Ext.Date:02/16/04, Amalystik.Risha Page 30 Page 84 Study No. :L1874, Set No. :021804AR, Ext.Date:02/18/04, Analyst:K.Risha & eZLSSaaatensmmnttppollameemsooddLLiiiiffssiitte=e:dd=:PrPTTPi\uu=\eDe\baDaMNtataaatarra\\\LLL00CC23CHHMSES11MMM23SE:S:SS060\\77\aN::Msa00asg00slssy3l2Im00ye00ny\44xF\mlPu1xuoor\rooFcchhleenmuiiccoaallras..oPPPRRRcOOO\\h\NSSAaeaCmmHappDl1Biee)DDCcBBo\\ta00G22rl1Lo88a00v44eAANRREDCCEGGSAAC0CS1EF2H1M04 MTLLeoaatbsshttocdmmo=odoeddriiffiieedd=: Non Tab 03 07104143 2004 P=\Data\LCMSMS6\Masslynx\Fluorochamicals.PRO\Metb_DB\CotGrove Mon Feb 02 07:04=42 2004 NPDES 012104 Job Code= Psrriincteead:: Tue Mar 02 14105133 2004 yg ,ill dTNe~ammtees:= o02n1s8o04sAeR--2e4z2 Tmxt: 44::CC66 Ssuuliftoonnaattee PpFrHiSs WM L[1L817847-499 RReepp,, DDFF==1100 1021804AR242 Sm (Mn, 243) a |r021804AR-242 Sm (Mn, 2x3) "* 0022--MMaarr--22L00C00I44M00S11I::M446S6::18 81 MMRRMM ooff 5LCCChh/aaMn7nnSn0eeIlM9lssS5EE8SS#-0-6 9888.709 39559.22r>11o0e8a440) Area `' | ot 200 400, 630 2.00 4.00 6.00 5: Ca sulfonate vros { 5|L:L11C8878744-S-9u9lRRfeeoppn,,atDDeFF==P11F00OS |0022116880044A4R2-24422 Sm Sm (Mn, (Mn, 233) 2x3) b |% 800 1000re 120T0im|e 8.00 10.00 12.00 or 991.1675 9165~ 0022--MMaarr--22L00C00I44M00S11I:dM4S6e:1g8#6 MRM MRM of of 55LCCChh/aMannnSn6ee/l0Mlss5SEE0SS#9--6) 40896r>094a9] 4.85e4Area -| , ....2,0.... , ....40, 0.... , ....60, 0.... , ....80, 0.... , ....10,00.... ,-, ;2,-0,0TTiimmoe 2.00 4.00 6.00 8.00 10.00 12.00 a " fl " ESAx-yyggeenn RReessseaaxrcchh,, 32005580 RReesseeaarcchh DDrriivvee,, SSttaattee CCoolllleeggee,, PPAA 1166880011 " `CHEOGNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIJDJIEAESCCTLTTRTITCOOT AACPOPURRROOTT.TEECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR.2E6E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00440088 SW_MNo1S38794 3M MN01538794 . StuQQuudaannyttiimtfeyy.iSSLaaimmEpp7llSee, RRSeeeppfoorrttNo.:021004AR, Ext.Date:03/18/04, AnalystiR.Risha sage 85 Page 85 Study No.:LI874, Set No.:021804AR, Ext.Date:02/18/04, Analyst:K.Risha PR SSfaeammnpptllemeodLLiiifssitte::d: Last modified: TTPP1uur:\ae\\DDDMMaaaaatttrrea\a\LL00\3C2CLHMcSS11MM23sS:1SE006\73\HM1:Maa00as0s0ssssill22yy00yim00n\e44xF\\lFFullouurooorrcoochchehanenimicicacalalsls.s..PPPRRROOO\\SSNaaSECmphp1DlaReD\DBCB\o\0t02G21r18o80v04e4AANRPDCCEGOSAAC0CS1S3FF1M04 CE MLaeatnshttoy dmm:oedtiiftiieedd:: wen Tob 05 07104143 F004 P:\Data\LCMSMS6\Masslynx\Pluorochemicals.PRO\MethDB\CotGrove Mon Feb 02 07:04:42 2004 NPDES 012104 Job Code: " PPrriinntteedd:: TTuuee MMaarr 0022 1144::0055::2222 22000044 Nsaammee=: 00a2119800043A8R--220423 " TTeexxtt=: iA:e GC6 RAeicdid BPPFEHAN 1 1L8178474--1100,, DDFF==1100 pe - . 1021804AR 243 Sm (Mn, 263) 021804AR-243 Sm (Mn, 2x3) | 1( no _ - adus8n,s5os0 i vrs 0022--MMaarr--22000044 0022::0088::0011 LCIMSIMS LCIMS/MS #6 MofR ChaM nnels E5-| MRM of 5 Channels ES- 0280 313 > 269 es 3.26e6 ea | Area + 200 400 600 800 1000 200TTiimme|e sicenciaveo2.n00 4.00 _6.00 8.00 10.00 12.00 i + |Lie7a0,0F=10 2:C8 Acid PFOA L1874-10, DF=10 0022--MMaarr--22L00C00I44M00S22I::0M088S::0011) 00z212e8e1048AR0o2244433A5SRmm (Mn, (Mn, 263) 2x3) 0 M MRMooR ff55LCCChh/aM Mamn3Sen%leIMsls3SEE0SS#0--6 1 | 2385.1948 4 rea 4131.>2430669) ` "] 1.24e6Area - ole 001% 01,,, ,'r-b ....a,0.... , ....Ta, m.... , ..6..00, .... ~ 235144~ ....80, 0.... , ....10,00.... ~ ....12,0TT0iimmee 3: co sulfonate 2p.0e0as 4.00 _ 6.00 8.00 _10.00 12.00 3[LL:11C8874744--S11u00l,,fDDonFFa==t11e00 PFBS 0022--MMaarr--22000044 0022::0088::0011 - |0cp2211y880044AARR -224433 3m Sm (Mn, (Mn, 223) 2x3) a M MRMoofR f55LLCCCChha//MM anMnnSSenTl/e/M5slMs5SSEE5SS#-06- " 1 ny1 czy8.13 299 > 99 33e00a5 3.33e5 - l Area o 20 ato 560 B00 050 7% | Time| 2.00 4.00 6.00 8.00 10.00 Time 12.00 LL} Sxygon Research, 3058 Research Drive, State College, PA 16801 Exygen Research, 3058 Research Drive, State College, PA 16801 a `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACOPPURRROOTT.TEECNCTOT.IIVV2EE7-OOCRR\-DD1EE0RR-2E6E3NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00440099 m_morssses 3M MN01538795 4. 4 qQSuutaaunndtytiiNfteyy.isSLua1am8pp7ll4ee, RReeSppeotorrttNo.:0Z1004AR, Ext.Date:02/10/04, Amalystik.Risha PPaaggeo 8866 Study No.:LI874, Set No.=021804AR, Ext.Date=02/18/04, Analyst=K.Risha LSSaaesmmtppllmeeodLLiiifsstit:=ed: TPu:Pe\rDNa\atrDa\aL02CtMa1S2M\:SL667\C:MH0a0sSsMl2y0S0nE4x\\Falusosrolcyhemmxic\aFlsl.PuPRRoOO\r\SSoaacmmpphlleeeDDaBB\i\O0cT2La1E8lO04a4AA.RR CCGG AACCSFSM 4 MTeLLLeoaaattsnsshtttnocdmmmoa:oodoadddriiifffiiieeeddd=:: PWTPiu=ee\\nDDaaMFtteaaabr\\LL00CC22HMES01MM72SS:=600\78NM::aa04ss03ssl2y2y00n00ax44\xFl\uoFrolchuemoicralos.cPPRRhOO\\eMKeSatCbHi-DDBc~A\CaCoolttGraroov.vee NNPPDDEESS Mon F~b 02 07=04=42 2004 001122110044 Job Code= Perriinntceeadr= TTuuee MMaarr 0022 1144:=0055:=2222 22000044 arNammaee:= 002211880040A8R--224433 Text= ~4:: cC6s Ssuullffoonnaattee PpFrHiSs 4 L[L11887744--1100,, DDFF==1100 (0218042A43R Sm (Mn, 263) wo 021804AR-243 Sm (Mn, 2x3) *) 0022--MMaarr--22L00C00I44M00S22I::M0088S::0011 81 MRM MRM of of 55LCCChh/aMan3nnSne9ellMlss>SEE6SS#-0-6 181.57193 rea) 3`959.>238004 8.23e4 Area We| rege] | 100!%t~ 22.0000 42.0000 606.00 5008.0101513~L 1100.0000 1122.0000 4 55[::8Cc78o4Ss1uu0llff0oonFnaa=tt1ee0 pPrFoOSs 02-Mar-2004 02:08:01 L1874-10, DF=10 02182430S4m(4Mn, 233) 0M 2-MoafrR -25LLC0CCh0Ia/4MM MnSn0Se/2/lMM:s0SS8:E:S0#-16 va021804AR-243 Sm (Mn, 2x3) i90.11s77 MRM of 5 5S9av9>ed Channels ES499 > 99 100~ 11291-~ 5.86e4 roa) [|| | || %1ole ~ TAmroea - ~ 22.5000 44.0000 66.0000 88.0000 1100.0000 200Time 12.00 " EExxyyggeenn RReesseeaarrcchh,, 33005580 RReesseeaazrcchh DDrriivvee,, SSttaattee CCoolllleeggee,, PPAA 1166880011 ali `CHEOGNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIJDJIEEASCCTLTTRTITCOOT AACPOPURRROOTT.TEECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR.2E6E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00441100 SW_No1S38796 3M MN01538796 . gSQtuuuaadnnyttiiNftyoy.SLsau1mm6pp7ll4ee,RReeSppeootrrtNto.:021004A%, Ext.Date:02/16/04, Analyst:k.Risha Page 87 Page 87 Study No.:LI874, Set No.:021804AR, Ext.Date:02/18/04, Analyst:K.Risha u eLSLSaateassmmnttppollnmeme,ooddLLiiiiffssiitte:e:dd::7:PTTP\uu=\Dee\DaDatMaMtaaatarr\a\\ULL0C0C22CHHMSSS11NHM22ISS::\0606N77\\a::Msa00as00slssyl22sm0y0e00n1\44xF\ylFmulouxroro\occhPhaelnmiuiccacallres..oPPPRRcROOOh\\\NSSeeaaCnmaHppDlliEee\DcDCBBoa\\t00lG22r11a6o800v.44eAARRNPDCCEGGSAAC0C1SS2FF1M04 oMLLeaabtsshttocdomm=dooeddriifiioedd:= bon Fab 03 07104143 2004 P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\MethDB\CotGrove Mon Feb 02 07:04=42 2004 NPDES 012104 Job Code: # pPrriinntceeda=r TTuuee MMaarr 0022 1144::0055::2222 22000044 Nama: 02180088-204 4 NnTaeemxxtet==: 021804AR-244 4 i[1::L1cC8o678An4cet1iad,DPpFF=rH1aA00 L1874-11, DF=I00 021804AR-214 Sm (Mn, 23) wo | 021804AR-244 Sm (Mn, 2x3) | a |% 1 i 1(o/l 22.0000 "4.0000 Wy 22[::L8cC7o8aAA1cc1ii,dd0FPp=FrOo1An00 L1874-11, DF=100 uf00o221188004A4R42-24444 SSmm ((MMnn,, 226x33)) 00 10882.5580085 _ 02-Mar-200_4 02:29:4 0M2R-MMaorf-2LL0CCC0h/4aMMn0nSS2e/Il:M2sM9SE#:SS4#-(6] MRM of 5 313>269) Channels ES313 > 269 47r8e0a5 4.78e5 Area | 500 800 1000 - 120T0ime | 6.00 8.00 , .... , .... ", Time 10.00 12.00 02-Mar-2004 02:29:4 0M2R-MMaorf-25LL0CCO0hI4MaMnS0nSIe2/lM:M2sSS9E:S4#-66 52995.008005 MRM of 5 Channels ES- 4132830550) 413 > 369 real 2.88e5Area % "|" | - | | O 256 r 450 00r 800 1000 .... , .... ,,, ~ . , .... , .... , .... , .... , 5..2.5.95,~.... , .... T2i00ma ~-,,, ,-,Time 2.00 4.00 6.00 8.00 10.00 12.00 3: ca sulfonate pres - 3[LL:11C8874744--S11u11~,,fDDoFnFa==t11e0000PFBS 0022--MMaarr--22L00C00I44M00S22I::2M92S:641~ 1021804AR 244 Sm (Mn, 233) " [1021804AR-244 Sm (Mn, 2x3) o8arts.z1v5 MRM MRM of of 55LCCChhIaMannnSn22a/e9iM9rl9ssS>e>EESS#59d-0-69) rea 3.77e4 Area | % " | w 0~ 200 400 600 800 1000 20T0ime 2.00 4.00 6.00 8.00 10.00 12.00 a EExxyygoeenn RReesseeaarrcchh,, 33005588 RReesseeaazrcchh DDrriivvee,, SSttaattee CCoolllleeggee,, PPAA 1166680011 [ `CHEOGNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIJDJIEAESCCTLTTRTITCOOT AACPOPURRROOTT.TEECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR.2E6E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00441111 SW_no1S38797 3M MN01538797 " MW gSQtuuuaednnyteiiNfsoyy.iSsLaeImmOppTllAee,nReeSppeootrrtMto.:021804AR, Ext.Date:02/18/04, AnalystiK.Risha Pago 08 Page 88 Study No.:LI874, Set No.=021804AR, Ext.Date:02/18/04, Analyst:K.Risha " eSLLSaaeatssmmhttppollammeerooddLniiiiffssiitte:e:dd:: TTPPPuu:\rse\D\DuMWacDaateraar\\LcL00C2Ca3HMI\S11NM2L2S1S:CE00677\HH=1MaS00as00sKssSl22y00yEm00ne\44x\\MFFialuusoorsroolcchyheemnmieicc\aalFlssi..uPPFRRRoOOOr\VNSSMouaecmCmphphDlaaBeD\DnBCBi\o\Gt0cZG2ar11o88lv00se44AK.NRFDCCEOGSAAC0C1SS7FF1M04 SMLLaeaatbsshttocdmom=odoedasitfeiseedd:: Non Feb 03 07104143 2004 P=\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\MethDB\CotGrove Mon Feb 02 07:04:42 2004 NPDES 012104 Job Code: Ppriinncteead:= Tnuuee wMaarr 0022 2144:10055=2222 22000044 4 mpNaemm=ee= o02r1s8004aAnRa-2e4s4 Text= a 44[: :LfCc86e74sS-uu1ll1ff,ooDnnFaa=tt1ee00pPFrHsS L1874-11, DF=100 10|02211880044AARR.-224444 SSmm ((MMnn,, 22x33)) ! |* 0022--MMaarr--22L00C00M44 S002I2::M22S99::4#4666 8.828%0 MRA MRM of of 5LCCChh/aaMnnnSn3eellMl9ssS9EESS#8>-0-6 3204 399 > 80 rea ' 0Phir~-- 200 -- a0 500 2.00 4.00 6.00 4 55[:L:TCc88o74sS1uu1ll,ffDoonnFaa=tt1ee00pPrFoOsS L1874-11, DF=100 . 021802444ASRm (Mn, 233) 021804AR-244 Sm (Mn, 2x3) 4 | *111 5006352~ 8.00 3090.11%99 A100EE20i 0 10.00 12.30.208e4Area 0022--MMaarr--22L00C00I44M00S22I:2M299S.:446 MRMof MRM of 55LCCChh/aMannnSn0eeIlM9lss>SEE9S#S9-6 4919.`>9r%9e49 - 200 4% 600 8A00 I 1000 200 366~L~ 1.99e4Area 0~,,,,, .... , .... , .... , .... , .... , .... , .... , .... , .... , .... , .... ,Time 2.00 4.00 6.00 8.00 10.00 12.00 . . " " Exygen Research, 3058 Research Drive, State College, PA 16601 Exygen Research, 3058 Research Drive, State College, PA 16801 " `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACOPPURRROOTT,TEECNCTOT.IIVV2E7E-OOCVRR-DD1EE0RR28EE8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00441122 M_MNO1S38798 3M MN01538798 . 4 gSQtuuuaednnyteiiNfteyy.:SsLaa1mm0pp7ll4ee, RneSepeptoorrttNo.:021004AR, Ext.Date:02/16/04, Analyst:k.Risha Page 83 Page 89 Study No.=LI874, Set No.=021804AR, Ext.Date=02/18/04, Analyst:K.Risha 4 MLLSSeaaeatssmmhttppolldmmee:ooddLLiiiiffssiitte=e:dd::7:TT7P\u1u:De\e\aDDtAMNaataat\ararL\\LCL00CH2C2HIMSNS11NSM22S6S::6\0067N7\\=:aMa00ass00sassl1l22yy0y0mm00nex44x\\\PPFllluuuocorrroooccchhheeeaamiiicccaaalllass...PPRRROOO\\\SSNaAanCmpHplD1eEeD\DDCB\o\0t03d21r16o80v04e4AARNREDCCEGGSAACC0SS12FT1MH04 SMLLaeaatbsshttocdmmo:odoeddriitfiieodd:s Kon Tab 03 07104143 2004 P=\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\MethDB\CotGrove Mon Feb 02 07:04=42 2004 NPDES 012104 4 rJoobsaCcoedae: Tuo Naz 02 14:05:22 2004 Printed= Tue Mar 02 14:05:22 2004 NHmaaemmxea:=: 002211800040A3R%--2244S5 Text= W i1::[L1cC8o674An1ec2ti,adDFPoF=rH1nA000 L1874-12, DF=IO00 Ie0022118810044AARR.-224455 Sm Sm (Mn, (Mn, 263) 2x3) 98885.5005 3981 _ 0022--MMaarr--22L00O0044M0S02I2::5M51S1::34 MRM MRM of of 5LGCChh/aMann33nSn11ce/3l3Ml"ss5>sS2EEe2S6Ss#6-9-6,9 Area 1.83e5Area ole | ' | t1hr 200 .... I .... I 2.00 2. co acid pron P= : C8 Acid PFOA L1874-12, DF=1000 i (00E2211S8801044AARR-224455 SSmm ((MMnn,, 226x33)) |o0 * % errrMBs Te .... I .... I, '-'' I .... I .... ~ .... I .... I .... I ....~,Time a 500 800 1000 1200 4.00 6.00 8.00 10.00 12.00 90 0M2R-MMarof-52L0CO0_h4Man0Sn12eI:3lM5s>1SE:3S-0 9,00 atest 17r60e5a, 31661-~ 02-Mar-2004 02:51:34 LC/MS/MS #6 MRM of 5 Channels ES413 > 369 1.76e5 Area - | O ....20, 0...m . , ....40, 0.... , ,e ., , 6,.0, 0.... ,, , ,~-s~or Vo~-77,, ....10,007,, ,~-~-,,1~2,0TT0iimmee 2.00 4.00 6.00 8.00 10.00 12.00 33[:L:1C8c47a4-sS1uu2ll,ffDooFnnaa=tt1ee00pP0FrBsS 02-Mar-2004 02:51: - L1874-12, DF--IO00 I(02108024A1R82-244055S4Smm4((MMRnn,, 263) 2x3) ar 0MM2RR-MMMaoorff-255LL0CCCC0hIhI4MaMan0SSnn22Ie/5:nM5lM>se1ESS:5El3SS#~s.91-1~ . 288.1478 29119.11r>33e0e9a449l) "| * Area | a sp 200 e 400 p 600 ---- 800 10e 00 n120T0ime | 2.00 4.00 6.00 8.00 10.00 12.00 " EExxyyggeenn RReesseeaasrcchh,, 33005588 RReesseeaarrcchh DDrriivvee,, SSttaattee CCoolllleeggee,, 7PAA 1166080011 w `CHEOGNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIJDJIEEASCCTLTTRTITCOOT AACPOPURRROOTT.TEECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR.2E6E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00441133 SW_MNo1838799 3M MN01538799 . Guensity seveie reper ern 98 Quantify Sample Report v BLE ert, sensmsisapiason, sosigritoniaes Study No.:LI874, Set No.=021804AR, Ext.Date:02/18/04, Analyst=K.Risha Page 90 Sampte Liss: 5r\SueAVLENENEE VaastuPiaeroshemtcala.PRO\SeRpIABRAGTEROARR C5 ACHP Sample Lis~= P=\Data\LCMSMS6\Masslynx\Pluorochemicals.PRO\SampleDB\021804AR CG ACSFM I Se LA Last modified= Tue Mar 02 12=07=00 2004 be ahaa Fiuorochesieuis. RG\NeEAGH\CotGrove WPORS 017304 ,,4 Method= P=\Data\LCMSMS6\Masslyllx\Fluorochemicals.PRO\MetllDB\CotGrove NPDES 012104 Last modified= Mon Feb 02 07=04=42 2004 a Job Code: Pprriinntceesd:= TTuuee MMaarr 0022 1144:=0055=:2222 22000044 me sss Name= 021804AR-245 Texts ~: C6 Sulfonate PFHS - 1LL11887744--1122,, DDFF==11000000 . o-- o)]021804AR-245 Sm (Mn, 2x3) 0022--MMaarr--22000044 0022::5511::34 LLCCI/MMSS/lMMSS #6 an WCo han55. 8.79 MRM of 5 Channels ES399 > 80 = aet 2.76e4 UN || ion EE |Area 5347~ " 22.0000 44..0000 66..0000 88..0000 1100..0000 1122.0000 | 5: C8 Sulfonate PFOS ,i,Ii LL11887744--1122,, DDFF==11000000 c2ts02a45n5rm 4. 269) 021804AR-245 Sm (Mn, 2x3) 1 1 | 100, || 1 | 1 . 2 pr) 2.00 4.00 0022--MMaarr--22000044 0022::5511::34 LLCCIlMMSS//MMSS #6 Ee MRM or 5 CramelpsRe5tal|! 99..1199, MRM of 5 Chann44e9gl9s9>>E9S99-9 r so e ok Boe o, m 6.00 8.00 10.00 12.00 " " ` " ssmgon Tosasss, 3458 Sosaneah ive, Seses Cllogh, Fh Exygen Research, 3058 Research Drive, State College, PA 16801 GFEOANNERFI ICDOUE-NNTSYUTBDJIIESCATTRITC0TAPCROOUTRETCNTGI.V2E7OGRunOiEoR26E8N0T3ERED - CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00441144 swNo538300 3M MN01538800 4 gSQtuuuaadnnyttiiNftyoy.SSraaLmm8pp7ll4ee, RReSepepotorrtNto.:021804rR, Ext.Date:02/18/04, Analystik.Eisha PPaaggee 9911 Study No.=LI874, Set No.:021804AR, Ext.Date:02/18/04, Analyst=K.Risha W MLSLSeaeaatsmsmhtptpolldemmesooddLLiiiiffssiitte:e=dd:=p\PTTPiauu:\eet\DDeawMa\taatLarrac\\SLL00MC32CHSMSES11H\M32SMS=1S060a7\7sK=:Msa0aals00syssmll32c0y0y\00n4F4xml\Fuelour\oorcFohcalhneuimciocaalrlss.o.PPPcRRRO0Oh\\\SSNeaaSmzLnppHl1DieaRDDCcBBo\Nta0OG22lr118o8s00v44eAANREEDCCEOGSAAC0CS1S2FF1M04 LSMLaaeabtsshttocdomm:dooeddriiffiieedd:= Hon Feb 03 07104143 3004 P=\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\MethDB\CotGrove Mon Feb 02 07=04=42 2004 NPDES 012104 [en Job Code= Tue ax 02 14:05:22 2004 Printed= Tue Mar 02 14=05=22 2004 4 me Name= 0o2n18s0o4AaRn-2a4s6 Text= Wu I(1::XCcC0s622As4ce0it4da3,PsF1eH0mA0ngiL Standard XC022404-3, 100 ng/h Standard ". 0218044RS.m2(4Mn6, 2:3) 021804AR-246 Sm (Mn, 2x3) Wo 02-Mar-200403:13:2: 02-Mar-2004 03:13:25 i. MRMof MRM of LLCC/IMMSS//MMSS #6 5 Chanan5eElSs- 5 Channels ES- ry8.50 313 > 269 or ! rea 1.54eSArea i | B mmr200 2e 00 600 50e 0 1000 200 | 2.00 4.00 2: co acid prOR | [2XX:CCC00822224A40c04i4-d-33,P, F11O00A00 nngg//LL SSttaannddaarrdd , (02128460S4mA(4nR, 25) MRM of5 Channel ES. 021804AR-246 Sm (Mn, 2x3) [I | 900 35.3ro0a9) 1 6.00 ....3, 1 ..3 .. 4 , .~ ... i .... ~ , , , ~,Time 8.00 10.00 12.00 9.00 32087 0022--MMaarr--22000044 0033::1133::22!5 LLCC//MMSS//MMSS #6 MRM of 5 Channels ES- 4131>.8396095 1.89e5 Area | , .... , .... , .... , .... ~ .... , .... , ....S , ....S , ...S . , .S ... ,Time - 200 a0 500 800 1000 200 32~ 2.00 4.00 6.00 8.00 10.00 12.00 3: co suifonate pris 3:C4 Sulfonate PFBS [XXCC002222440044--33,, 110000 nngg//LL. SSttaannddaarrdd - 1021804AR-246 Sm (Wn, 233) MRM of 5 Ghana's ES- 021804AR-246 Sm (Mn, 2x3) Id a7 705e0a9 - 0" 1,,~ 0022--MMaarr--22000044 0033::1133::222 LLCC/lMMSS//MMSS #6 Cl8.17 838- MRM of 5 Channels ES- 44063 299 > 99 4.40e3 Area | of - SS SS | | Arrrr permease ersTis 0" ........ , .... , .... , .... , ........ , .... , .... , .... ,Time " 200 400 60 800 1000 1200 2.00 4.00 6.00 8.00 10.00 12.00 u EBxxyyggeenn RReessseaarrcchh,, 33005580 RReesseeaarrcchh DDrriivvee,, SSttaattee CCoolllleeggee,, PPAA 1166880011 u `CHEOGNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIJDJIEAESCCTLTTRTITCOOT AACPOPURRROOTT,TEECNCTOT.IIVV2E7E-OOCVRR-DD1EE0RR28EE8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00441155 S1_MNo183E801 3M MN01538801 4 QqSuutaaunndttyiiefHyoy..sSLaa1mm0pp7ll4ee,RReeSppeootrrttNo.:0216041%, Bxt.Date:02/18/04, AnslystiX.Risha Page 52 Page 92 Study No.=LIS?4, Set No.:021804AR, Ext.Date=02/18/04, Analyst:K.Risha 4 LMLSSeaaaatssmmhttppolldmemesooddLLiiiiftssiittee::dd:: TPTou:P\me\DD:aWMa\taatarraD\\aLL00C32CtHMaSS11HM23\S:S:LE06077\CM::MaH00aa00sSssM1l23yy00Sm00nS44ax\\\FlMluuoaorsrooscchlheeynmimicccaal\lssF..PlPPRRuROOO\o\\SSrNaaSmomEppcHllDehe\DDeCBBo\m\tO0iG22r1c1o88av00a4l4AAsRRNPDCCEGGSAAC0CS1SF2F1M04 LoMLeaabtsshttocdomm:dooeddrtiefsieead:: on peb 03 07504143 2004 P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\MethDB\CotGrove Mon Feb 02 07:04=42 2004 NPDES 012104 Job Code: pPrriinmteesd:= TTuuee Mwaarr 02 02 014::0085::2222 22000084 [p-- Name= 021804AR-246 i TTeexxtt=: 44::Cc6o sSuultfoonnaattee pPFuHsS } _ _ " X(CC00222240044--33,, 110000 nngg/lLt SSttaannddaarrdd uf021804AR 245 Sm (Mn, 23) 8st MRM of 5 Chann0el0s5.ES0-0 021804AR-246 Sm (Mn, 2x3) 0022--MMaarr--22000044 0033::1133::2255 LLCC//MMSS//MMSS #6 MRM of 5 Channels ES- 8.81 399 > 80 Soy 26r3e04a] i * | 2.93e4Area 11o/! 5403~ | ee 0 ,~-,, , , .... , .... , .... , .... , .... , .... , .... , .... , ,~,, ~,~,Time i 200 500 500 800 1000 200 2.00 4.00 6.00 8.00 10.00 12.00 5: co sulonate pros : C8 Sulfonate PFOS ,1i XXCC002222440044--33,, 110000 nngg//LL SSttaannddaarrdd ' (100201,8h04AR 245 Sm (Mn, 263) 021804AR-246 Sm (Mn, 2x3) ] a0149.19 3304~ 0022--MMaarr--22000044 0033::1133::22!5 LLCC//MMSS//MMSS #6 MRM of 5 Channels ES- MRM of 5 Channels ES"19T9rea5d9 499 > 99 1.7Ar8e~a4| ` 1 . 11l /I ....e20e 0 ra0 r6r 00 r 800 Br 100 r7r 200 ve 2.00 4.00 6.00 8.00 10.00 12.00 " " 1 Eoxyyggeenn RReesseeaarrcchh,, 33005588 RReessseaarxcchh DDrriivvee,, SSttaattee CCoolllleeggea,, PPAA 1I6~880011 . `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACOPPURRROOTT,TEECNCTOT.IIVV2E7E-OOCVRR-DD1EE0RR28EE8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00441166 M_mNots3B02 3M MN01538802 a qE QuuaannttiitfyyI Ssaammppllee RReSeppEoorrNtte0210048, Bx.Date02/10/04, Analyetik.Risha PPaaggee 9323 Study No.:LI874, Set No.=021804AR, Ext.Date:02/18/04, Analyst=K.Risha 4 NLSLSaaae~tnsmmh?tppollsmmee:ooddLLiiiizfssiittee::dd=:PiuTP\u:aD\e\aDDtaMwaetaat\erraL\\OLL00U2C5eEMxMS11aSM32E1S=6\006M77\Ha=1Ma00sa00ssslsyl22sy0m00neas4x\\yFFimluuoeosro\occhFheeLmmiuiccaoallsEs..oPPPRcRRO0O\h\VSSMaaaSmmEmppEllDieeBDcD\BGBAao\Ot0l2d21r1aAo80v0.4e4AANRRPDCCEGGSAAC0S1S3FT1M04 rMLLyeaattsshttodmm=ooddiitfiieedd:: Men Feb 05 07104143 2000 P=\Data\LCMSMS6\Masslynx\Fluoroche~icals.PRO\MethDB\CotGrove Mon Feb 02 07:04=42 2004 NPDES 012104 Job Code= 4 pPrriinntteeda:: TTuuee MMaarr 0022 1144=:0055:=2222 22000044 [-- 4 tNTeaexmxtte:== 021804AR-247 1: cs reid pen _ i: C6 Acid PFHA ". L1L8187744--1133 a"1002211880044AARR.-224477 Sm Sm (Mn, (Mn, 263) 2x3) | _ aosa8.r5o0 I 0022--MMaarr--22000044 0033::3355::0099 LCMSIMS #6 LC/MS/MS #6 MRM of 5 Channels ES- MRM of 5 Channels ES- e200 4.5804 313 > 269 ea 4.58e4 A -- i \ re] a | 11 pra ' 04,,~, ~, ,~-,22,.,0000.... , ....40.0,00..... , ....56.0,000.... , , , ,885.000 0100.000 2120.000 3. ca reid pron. _ ies 2:C8 Acid L1874-13 PFOA 0022--MMaarr--22000044 0033::3355::009 w (0l0n2211880044AARR--224477 Sm Sm (Mn, (Mn, 263) 2x3) MRM MRM of of LLCC//MMSS//MMSS #6 5 Chaangi0ES- 5 Channels ES- "1100 le aa09.00 36e0ad 413 > 369 Area || A - oi MN 200 abo 600 abo i050 700Timo 3. ct sulfonate 2s.0e0ns 4.00 6.00 8.00 10.00 12.00 - Lie7a43 : C4 Sulfonate L1874-13 PFBS 0022--MMaarr--22L00o0044m00s33M::33S55::009 (021804AR 247 Sm (Mn,263) " 021804AR-247 100,10088 100 0,66 Sm (Mn, 2x3) MRMof MRM of 55LCCChh/aMan2nnSne6e/lMlss>SEE5S#0--96 5003 299 > 99 Dad | " [|1 | pm 2228 um t 1.33 2.32 2~3 9.96 11.52 | OS I Tr Time| 0 r .... , .... , .... ~ .... , .... I .... , .... , .... , .... , .... , .... ] .... ,Time " 2% a0 50 abo 1050 0 2.00 4.00 6.00 8.00 10.00 12.00 " EExxyyggeenn RReesseeaarrcchh,, 33005588 RReesseesasrcchh DDrriivvee,, SSttaattee CCoolllleeggee,, PPAA 1166680011 " `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTYUBBIDJJIEAESCCTLTTRTITCOOT AACOPPURRROOTT.TEECNCTOT.IIVV2EE7-OOCRR\-DD1EE0RR-2E6E3NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00441177 am_morsassos 3M MN01538803 I -- Quantify Sample Report oI Er vsoeera, sevsusmesafiasot, sustyeeinaninin Study No.:LI874, Set No.=021804AR, Ext.Date=02/18/04, Analyst=K.Risha Page 94 Sample Liat: Br\Daa\LCHDUSEWass yue\Pivoroshendcals P20\SamplaBe\OFL064RR C0 Aco Sample List: Ee ition Beam eee ee Last modified: Ee thesaoa\vivorosThHeRmiOeCsoiroaw.a ETH TATRA Method= He stetsas hae oe Last modified= saa Job Code: P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PR0\SampleDB\021804AR CG ACSFM Tue Mar 02 12:07:00 2004 P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\MethDB\CotGrove ~-PDES 012104 Men Feb 02 07:04:42 2004 ,.,| PPrriinntteedd:: TTuuee MMaarr 0022 1144::0055::2222 22000044 R-- Wo rNTeaexmxeet:=s 021804AR-247 5.08 suttonase ems ] 4:C6 Sulfonate PFHS + fren G2Mar2004 03:35:08 L1874-13 0218042478 Sm in, 2) MRMofSLmoemlsies5#.5 021804AR-247 Sm (Mn, 2x3) . | oIgaEmeES, wlo0.1TM4 Co es wwe aR VN | 2.97 02-Mar-2004 03:35:09 LCIMS/MS #6 MRM of 5 Channels ES- 9.58 11.62 399 . 80 ats) | wre 11.04 9.13 \2.02e3 5.15 7.88 8.27 7.11 ee 4 22.8000 44.0000 66.0000 88.5000 1100.0000 200"Time 12.00 | 52 08 suttenate bros 5:C8 Sulfonate PFOS [wrens G2Mar2004 03:35: !h1874-13 c21300AR5.m2i4,7 26) MRMofGrnmels 5. 021804AR-247 Sm (Mn, 2x3) > i" ppriio 100 | \ l ~ | " ~ | fe ee ---- 02-Mar-2004 03:35:09 LLCC//MMSS//MMSS #6 MRM of 5 Channels ES- 499 . 99 9.19 2.64e3 185 ArAereaa| IN 0I, ,,, .... , .... , .... , .... , .... , .... , .... ~ .... , .... , .... ~ .... ,Time - pr) pr) a a FY" 2.00 4.00 6.00 8.00 10.00 12.00 - " Ll " Ecygen Reseach, 3088 Beseucch Drive, State College, 7A 16801 . Exygen Research, 3058 Research Drive, State College, PA 16801 CRCOOENNNFFINIDDEEENRNTTICIAAOLLUN- STSUUYBBDJJIEESCCTTTRTITCOOTAPACROPUORRTOTE.TCENTCGIT.IVV2EE7 OOORuRDD10EE.RR28EE8NN6TT3EERREEDD ININ HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00441188 sw_notssssos 3M MN01538804 a qQuuaannttiiftyy Ssaammppllee RReeppoorrtNtecaasonan, me oaces0a/20/04, Ansiyssix Bisa rege 55 Page 95 4 eLSESSaaatasmmurtppdhllymmeeoNdoLoLi.iif:sakittL:e=Iad8:74B,PTTE:Yu:a\e\SoDiDeuRMatataatne\raN\Lo\LO.Lb0N:e2Ca0SM2SE1b1M2\8rS:sM0e06a\4)7\sAH:M1sRa0a3l,s0s0yssnil22ayyE0\m0sxnF4taxi.\FuDFaolltrueoou:rs0oho2ce/hs1eri8mc/ioa0cl4ac,sl.shA.PnPPRaReROlOO\y\\aSsSNataesi:mCpKphlc.lOeReRDeiDCBsB\oh\l0t0a2G21sr18o80v.04e4AARRNPCDCEGiSAAC0C1SS2FI1M04 t MLEeaatsrhtoedRm:aoadiicfiieedds: Kon Feb 05 0h sob is 0s P=\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\MethDB\CotGrove Mon F~b 02 07=04:42 2004 NPDES 012104 ii oJorbinCeosdse: ee ar 02 24108122 2004 Printed: Tue Mar 02 14=05:22 2004 [EE Name= 021804AR-248 " TTeexxtt:= pr. 4 iL[:L118C876744-A14c33idRReePppFHA a o21304AR248 5m 4, 20) 021804AR-248 Sm (Mn, 2x3) sso8.50 s5e84r1-~ 0022--MMaarr--22000044 0033::5566::5544. LLCC//MMSS//MMSS ##66 MRM of Crannos E5- MRM of 5 Channels ESToreaa 31333.>.88323e60494 t | ,,i 1001 NN oe i 0', T', ~,7~,,20, 0JT, , , , ....40, 0.... , ....6.,00.... , , , 8, .00 2.00 4.00 6.00 8.00 2: cs pid oeon : c8 Acid PFOA errr Tine | AN 1100..0000 1200" 12.00 1 L11887744--1133 RReepp , ca1s0eAR.248 Sm vn, 26) 021804AR-248 Sm (Mn, 2x3) \ 0022--MMaarr--22000044 0033::5566::54 LLCCIIMMSS/lMMSS #6 MRMof Channa ES- MRM of 5 Channels ESpred 413 > 369 Sores 3.91e4 99..0000 AArreeea) 15Ol 0 EE ..E.e.--~ -- ~ ree S TTiimmee . 26 Ww ob a oo os 2.00 4.00 6.00 8.00 10.00 12.00 3: cs suitonste prns LL1:188C77444--S11u33lfRRoeenppate PFBS |0c221r8o0n4eAnRn-z2e4n8 SSmm ((MMnn,, 22xx33)) ` a? TeSsaaas0 100 0.66 0022--MMaarr--22000044 0033::5566::54 LLCC//MMSS//MMSS #6 MMRRMM ooff 5 CChhaannnneellss EESS-- 299 > 99 9.45e3 | "|| " | Li 201 peso X00 we %1-~ I~/ 1.30 2~1 1100.337 4091 7.11 8.90 .... 10"91 11.85 | oe Tin 0I"", -~..~ .."."-.~ ..~.~ . ~.... ~ .... ~ .... ~ .... ~ .... ~ .... ~ .... ~ .... ~ .... ~Time . 28 bs obs abo oo a 2.00 4.00 6.00 8.00 10.00 12.00 ou Exysen Research, 3058 Ressazeh Drive, State College, BA 16801 Exygen Research, 3058 Research Drive, State College, PA 16801 - CCHEOONNNNFEIDFPEIINNTDCIAOELU-NN- TSSTUYUIBBDJJIAEESCCTLTTRTITCOOT AAGPOPURRROOTT.TEECNCTOTIIVV2EE7-OO0RR1-DD1EE0RR.0E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00441199 Su unotssesos 3M MN01538805 u wo qQS uuaannttiitE yy SsaammppllL ee rReeppoorrtNte. ontsoun, met.Daterca/a0/0t, Amatyatix Bish rege 36 Page 96 ULSBSSa aeeatsmemutptpdllyeiemoNdoLLtii.ifs:stittL:e=I,d8=74,TPBRu=1oee\\SaDDeuMtaaaatCSrrNaHo\\.L6L0E5:2CCu0MHi2SaB1k1M2Urs8S=See006E47\\kA=MWouR0aabn,0sssssil22yy0yEna0snxat4xt\\.\FFDFiialuutuooeorr:roo0occ2chh/hea1enn8mt/iic0cca4aal,lls.s.A.PnPPRaRROlOO\y\VSsSNataAs:mLKppA.lD1RDeei\DBCsBBoh\Ar0aOd2Lr1So8Gv0Ae4NANRREDCCEOGSAAC0C1S5FS3M08 TsMLaeatishttoedmh:oedatirftieeads: Han rob ba ovsorris Beet P=\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\MethDB\CotGrove Mon Feb 02 07:04=41 2004 NPDES 012104 Job Code= . PPrriinntteedd:: TTuuee MMaarr 0022 1144::0055::2222 22000044 FR Name= 021804AR-248 oom Text= 4: c6sutonace pms a _ } 4:C6 Sulfonate PFHS or |LL11887744--1133 RReepp 0022--MMaarrL--22C00M0044S0I033M::5S566#::55544 LC/MS/MS #6 c21a02448n5Rm 0 20) Mf Gross 5 021804AR-248 Sm (Mn, 2x3) MRM of 5 Channels ES- JL aa0 100~ Loe ol7 wBnArN ed q~ 0.12 Vo Tene Ras Rew sma sn SN | % 070~ 4.59 4.996.52 7.21 8.11 9.56 9.17//~I 111-1"8-1~,u~ '9>80 I0.7xi ,y~X-/~' 1.74e3 ~.,,~ v ~'~ | 1 I 35 ib 55 55 ioe whTine ,II| 0I .... , .... ~ .... , .... ~ , 2.00 4.00 ,,, , ,,, ....... ~ ............ , .... ,Time 6.00 8.00 10.00 12.00 5: ct suttonace pros 5:C8 Sulfonate PFOS u |LL11887744--1133 RReepp czta0uR248 5m 0, 20) 021804AR-248 Sm(Mn, 2x3) u| f|o A1 1 0022--MMaarr--22000044 0033::5566::54 LLCC/IMMSS//MMSS #6 MRMofS hamel 5- MRM of 5 Channels ES- 499 > 99 "ane 3.24e3 a% = 9.19 Area - 38 iB 85 Joe | oe 2.00 4.00 6.00 210 Aa ee TTiinmee a0 oo 8.00 10.00 12.00 " "li iall Faygen Rasaareh, 3030 Reseach Drive, State College, BA 6801 . Exygen Research, 3058 Research Drive, State College, PA 16801 CCROEONNNFNIDFEEIRNTDCIAOELU-NN- TSSTUYUIBBDJJIAEESCCTLTTRITTCOOT AACPOPURRROOTT.TEECNCTOT.IIVV2EE7-OO0RR1-DD1EE0RR.2E8E9NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00442200 awmorsaasos 3M MN01538806 a 4 QQSuutaaunndtytiiNtfoyy.rSsLaaTmm8pp7ll4ee, RReSeepptoorrttNo.:021SO4AR, Eet.Date:02/16/04, Analystik.Risha Page 37 Page 97 Study No.=LI874, Set No.=021804AR, Ext.Date=02/18/04, Analyst:K.Risha Uo HLSLSaaaaatssmmhttppollammeesooddLLiiiiffssiitte=e:dd=: TTPPu1u:ie\e\DD\aMwataatDarxa\a\LL00tC2C3KMaSS11MM3\2S:S=6L00677\MC=:Ma00aHs00ssSsIl32N0y0y00nS44xm\GFx\luN\oraFocsihaeumlicocyaarlmlsseo..PPF\RcRROOPO\h\\KiSSGeaAuLmRHspoDp1R1ire\eDCDocBo\\ct0a0ZG2h1rl16eo80s0vn44eAAdRNRPDCCEGOSAAC0C1SS2FF1M04 aMLLeaabtsshttocdomm=dooeddriiftiieodd=: Non Fab 03 07104143 2004 P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\MethDB\CotGrove Mon Feb 02 07=04=42 2004 NPDES 012104 pJorbinCocdee= Tue ar 02 14:05:22 2004 Printed= Tue Mar 02 14=05=22 2004 eNammae:= 002211080004aARR--224489 Text= 4 I1[::UEcCe6TaaAccatida PoFrHmA L1874-14 10|0r2211880044AARR--224499 Sm Sm (Mn, (Mn, 263) 2x3) . || 10%01 02-Mar-200404:18:43 0M2R-MMaorf-25LL0CCC0hI/4aMMn0nSSe4I/lM:N1sSS8E:S4##-635 b88r.550y0 MRM of 5 Cha3n31n1e33Sl5sa>2mE2e6S6d6-9]) 4446~ `real 3.35e4 Area An ~ [IR AOe %~/~ A Ar . 0.]. 200 ,'~,,,~'~r.'.--7". ; ,.,--'--T,, 2.00 , 400) .... , .... 4.00 , 600 .... , .... 6.00 , 800 .... , .... 8.00 , 10.00 .... , .... 10.00 , 200 .... , Time 12.00 2: : cCo8 aAcciidd PprFoOnA - [Li1e87r4a-t1a4 0022--MMaarr--22L00O004M4 S004I4::M118S8::44:3 wl 002211880044AARR.-224499 Sm Sm (Mn, (Mn, 263) 2x3) MRM MRM of of 55LCCChhlaMannnS1nee/alMlssS3EE5SS#0--6) i 10'~ A^ . | *1 41333.>.88535e60494 250001 ue 9.00 Area | 0iJ OS --JED SSNS,\ ime - 200 2.00 450 4.00 66.5000 88.5000 EY) 10.00 200 12.00 3: ct sutfonate res - L874-14 3:C4 Sulfonate h1874-~ 4 PFBS 0022--MMaarr--22L000o044m004s4::m116S8::4~ J0oTo2,211880044AA0RR8:-4224499 Sm Sm (hn, (Mn, 263) 2x3) MRM MRM of of 55LCCChhIaMannnSn2ae/iM9lss>SEE0SS#-0~- . 10^ [0.64 2989.5>30939] 8.53e3 Ei y " | wl /1 /I 1o 91 2683e 351 40m 5 t os es; s8.7m3 s9oe~s8 w1t0n.m70 n11~snp5 || n u-,,, ,, .~ ...20, 0....~ , ...4.0. , ,I ....60~ ~ 0.... , ....80, 0.... ,,, ,1,0,00~,~, ,~-~1m20i0me 2.00 4.00 6.00 8.00 10.00 12.00 Eeygen Research, 3058 Research Drive, State College, PA 16801 Exygen Research, 3058 Research Drive, State College, PA 16801 `CHEOGNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIJDJIEAESCCTLTTRTITCOOT AACPOPURRROOTT.TEECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR.2E6E8NN6TT2EERREEDD IINN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00442211 S3MW_MMNNo011853388880077 Temi STE ET -- Quantify S~unple Report y EIR ions, sensetessarissoi, sips Study No.=LI874, Set No.=021804AR, Ext.Date=02/18/04, Analyst=K.Risha FO Sample List= rip AE eg Last modified= Et Ee srmslcmardmwmorrore wits wrath Method= FroLaSt modified= are mest Job Code: P=\Data\LCMSMS6\Masslynx\~luorochemicals.PRO\SampleDB\021804AR CG ACSFM Tue Mar 02 12=07=00 2004 P=\Data\LCMSMS6\Masslynx\Fluorochemicals.PEO\MethDB\CotGrove NPDES 012104 Mon Feb 02 07:04=42 2004 a PPrriinntteedd=: TTuuee MMaa~r 0022 1144~:0055=:2222 22000044 Seats N~me= 021804AR-249 mmText: a: cs surtonate seus 4:C6 Sulfonate PFHS . L1L8187744--1144 cz1s0iAR219m (i, 28 VoriCramg et 25. ] 021804AR-249 Sm (Mn, 2x3) who as 016pr VA 1001 %~ 07140 87 CIE ------S ------L --&-- 0 WA A .| o ,~~ M ~ ' ' ' I ' ' ' ' I .... I ' ' ' ' I ' ' ' 200 4.00 2.00 4.00 '5..I0~'5 ' ' 66'..00I 00' ' ' ' 22 co surtomse sos o LieTads 5:C8 Sulfonate L1874-14 PFOS PYc2190003.254m9 i,23 MofRn CraMmFsd5 A 021804AR-249 Sm (Mn, 2x3) ,i A a hen ued ,I . o%e we oare 2.00 4.00 6.00 0022--MMaarr--22000044 0044::1188::43 LLCC//MMSS/IMMSS #~ MRM of 5 Channels ES- oss A 11.54~ /\ 23763 399 > 80 2.37e3 88.0000 1010..0000 1122.000 0! 0022--MMaarr--22000044 0044::1188::43 LCIMS/MS #6 MRM of 5 Channels ES- oF 3003 9.17 499 > 99 3.02e3 228 8.00 10.00 Time 12.00 " M a STAR ReseSEESS 0H TAREE Tre, ShARS SATINGRS TA S645 Exygen Research, 3058 Research Drive, State College, PA 16801 "i GONFIDE-NSTUIBJAECLT TO APROTECTIVE ORDER ENTEREDIN CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN NE COTY TRIE Soar N37 ure zeses HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00442222 swmorssason 3M MN01538808 i . 4 QQS uuaannttiiR tfyy SSL aammppllee.RReeppoorrott tsenan, mxt.pater03/10/04, Anayeti.nishe Page 99 Page 99 LSSSaaatrmmu?ppdllymeeoNdoLLii.ies:sittLa::IdS:?4,T5Pu=:e\SDe\watatDrNaao\.0Lt5=C0Ma2S31M3\8S1u00647\cA1MR0au,5sssl2u0yE0xns8tx.\sDF\altuKeo=ra0o2cs/h1se8ml/i0ccya4al,mlss.eA.nP5\aRRlOF0y\\iSsSataum=mpKpol.eerRDDioBsB\h\s0aO2hT1Le800sA4AAiRR Co CG ACSI ACSFM a eoMLLLeaaantsssthtttocodaSmm=aoooeaddritifefitieoeddd=:s TPk1ou=ne\pDaMartaotabra)\LL0032CMoS01M72kS1=06047\K1=Ma40aa30sssl122y000n0y44x\mFluuo\roFchle~uicoalrs.oPFRcROO\h\MNeeatCshHDDcBR\CaCootltaGraroo.vvea Mon Feb 02 07=04:42 2004 NNFPDDEESS 001122110048 mess Job Code= ue ar 02 24.08.22 2004 Printed= Tue Mar 02 14:05=22 2004 ote canons Name: 021804AR-250 T1:extc=o acid orm_ _ i: C6 Acid PFHA a |LL11887744--1155,, DDFF==110000 + (00B2211880044A4R2-25500 Sm Sm (Mn, (Mn, 2:3) 2x3) i |% . | 240 ao 2.00 4.00 2: co neia sron 2: C8 Acid PFOA a |LL11887744--1155,, DDFF==110000 0(It22181084A0R4-2450RSS.mm2((M5Mn0n,, 2:3) 2x3) `| " _ 06.00 sei85.o55e00 0022--MMaarr--22000044 0044::4400::26 LLCC//MMSS/IMMSS #6I MRMof Channels E5- MRM of 5 Channels ES- [ 20 313 > 269 Todos! 1.64e reaArea 500 1000 2%Time | ....34 i .1 ..~ . L~ .... i .... ~,,, Time _8.00 10.00 12.00 sm 3490.0509 0022--MMaarr--22000044 0044::4400::26 LLCC//MMSS/lMMSS #6 MRMof 5 Channols ES- MRM of 5 Channels ESenAea 4131>.8306e95 3409~, 1.90e5Area - | oo 20 3. co sultonase ors 2.00 3:C4 Sulfonate PFBS ........ ~ ; ~ ........ ,,,-T--~,,, TTiimmee ano 500 80_0 _000 200 4.00 6.00 8.00 10.00 12.00 LL11887744--1155,, DDFF==110000 - (0216044250 Sm (Mn, 2) 021804AR-250 Sm (Mn, 2x3) - %l110000, 2141 MRMof 5 ChannelBse5Ee50n-) s8.1w7 0022--MMaarr--22000044 0044::4400::226 LLCC//MMSS//MMSS #6 MRM of 5 Chann22e99l99s >>ES99-99 8.89e3 Area DreA . 200 abo 550 Bho EO) 25% 2.00 4.00 8.00 8.00 10.00 12.00 . Exygen Research, 3058 Rasesceh Drive, State Collage, PA 16801 Exygen Research, 3058 Research Drive, State College, PA 16801 - `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACOPPURRROOTT.TEECNCTOT.IIVV2EE7-OOCRR\-DD1EE0RR-2E6E3NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00442233 _Morssssos 3M MN01538809 ,a 4 QSQutuauandntytiiWftoyy.isSLaa1mm8pp7ll4ee, RReeSppotoorrttMo.:021804AR, Ext.Date:03/18/04, Analystik.Risha PPaaggee 2i0000 Study No.=LIS?4, Set No.=021804AR, Ext.Date=02/18/04, Analyst~K.Risha . aLSLSaeatasmsmhtptpollnmemesooddLLiiiiffssiitte=:edd::P:PTTP\uu=\Dee\baDatMaMtaatea\rra\L\LCL00C2H2CHSMSSH11MMS22SS1:ES060\77\MM1:Maa00asn00sssslll22yy00ny00nx44x\m\PFilxuuoo\rroolcchhueemmoiiccraalloss.PPcPRRROOOh\\\SNSeeAammEnpRpllDieeBDDcBCB\o\aOt02G2l1r16o8s00v44eAARRNPCDCGEGSAACC0SS1T2F1HM04 LaMLeaabtsShttocdomm=dooeddsiieftieedd:: Non Feb 02 07104142 2004 P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\MethDB\CotGrove Men Feb 02 07:04:42 2004 ~-PDES 012104 Job Code= f ePrriinncteeda:r TTuuee MMaarr 0022 1144::0055::2222 22000044 NNnaeamseee:: 002211800040A8R--225500 Text= 4 44[:L:1C8C67o4-Ss1uu5ll,ffDooFnnaa=tt1ee00pPFrHiSs L1874-15, D F= 100 021804AR-250 Sm (Mn, 20) 0 021804AR-250 Sm (Mn, 2x3) ow _ o.r 18.81 | 02-Mar-2004 04_:40:21 0M2R-MMaor-f62LL0CCC0hII4aMMn0nSS4oI/lM:M4sS0SE:S2#-66 MRM of 5 Chan3n39e92l99s6>>E8S008-40 2.6AA8rreee4aa . 200 400 rrr 0.- .... , .... , .... , .... , .... ~ 600 .... , .... , 850 -- .... , .... b, .s..e.10m~ 00T~ IT, T)120TT0iimee 2.00 4.00 6.00 8.00 10.00 12.00 oa 55:L:1CC88s74sS-uu1ll5ff,ooDnnFaa=tt1ee00PpFrOosS 02-Mar-2004 04:40:26 h1874-15, DF=100 p00r2211e88g0044AARR--225500 Sm Sm (Mn, (Mn, 2:3) 2x3) 0M2-MRaMr-2o00f4LLCCC/MhIaSM/nMnSSeI0l4Ms:4S0E:#2S6-6#6 519 MRM of 5 99>59 Channels ES- . h 29.1129 49"96>60949 | Area ` o"h rrr Se Tine | 0 t ? T'; T ~-7 T T 7 ~: 7"T 7 I .... I .... ~ .... I .... ~ .... I ' ' T T - 200 4% 600 800 1000 1200 2.00 4.00 6.00 8.00 ............. 10.00 12,00 - -,m . " EExxyyggeenn RReesseeaarrcchh,, 33005588 RReessseaaxrcchh DDrriivvee,, SSttaattee CCoolllleeggee,, PPAA 1166880011 - `CHEOGNNONFEINDPEIFNNITCIDAOLEU-N-NSTSTUUYBBIDJJIAEESCCTLTTRITTCOOT AACOPPURRROOTT,TEECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR.2E6E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00442244 IM_MNO1538810 3M MN01538810 " 4 gQSuutaausndttyiifotyy.1sSLaa1mm0pp7il4ee,RReeSpputoorrttNo.:021604AR, Ext.Date:02/10/04, Anslystik.Risha PPaaggee 1I0011 Study No.:LI874, Set No.:021804AR, Ext.Date=02/18/04, Analyst=K.Risha a vLLSSeeaaarssmmnttppollnmmee,ooddLLiiiiftssitit:e=edd=: PTTPPHuu:\\es\DDDaAMaWtCataearxa\\\LLL00CC23CHHMSSS11HHM23SS=S:E060\\77\NH=:Maa00ass00ssasld3l2yy00ymm00nxx44x\\\FTFllluuuooorrroooccchhheemesimicicacalalsls.s..PPPRRROOO\\NSSKaaemmEpphilDeeRDD\BBC\\oO0tZ2GA1E88o00v44aAANRRPDCCEOGSAAC0C1SS3FI1M04 oLMLeaantsshttocdomm:eoondd:iiefiieedd:= Hon Fab 03 710414 3004 P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\MethDB\CotGrove Mon Feb 02 07:04=42 2004 NPDES 012104 Job Code= Fre, ue wax 02 14105122 2008 Printed: Tue Mar 02 14=05:22 2004 3 nNaammee:= oz10003-251 021804AR-251 Text~ a I1[::L18cC7s64.nA1ce6i,idDFpPeF=nH1nA000 L1874-16, DF=1000 . 1| 002211880044AARR-225511 SSmm ((MMnn,,226x33)) ] uw | *11o/o0~ oo = i 02-Mar-2004 05:02:2 M02R-MMoafr-2LL0CCe0hI4MMas0Sn5I/n:MM0eE2SSl:S2#s-(6] 5)8.50 MRM of 5 3 Channels 2E0S9- 313 > 269 | 1.5AA5rreeea5a 0,,~-~,, .... , .... , .... ~ .... , .... , .... , .... , .... , .... ~ .... , .... ,Time ` 250 pr) 600 800 1000 7200 ,J 2.00 4.00 6.00 8.00 10.00 12.00 2: co ncia pron : c8 Acid PFOA ' |LL11887744--1166,, DDFF==11000000 (021804AR.251 5m (Mn, 263) seo MRMGrSCramels eS. 021804AR-251 Sm (Mn, 2x3) a f|ri ie >fr3or0a9) ' %1 0022--MMaarr--22000044 0055::0022:2:2(0 LLCC//MMSS//MMSS #6 MRM of 5 Channels ES- 8.98 413 > 369 1.88e5 Area 1 _ | mre 200 00 2.00 4.00 3: ca suitonate pms 3:C4 Sulfonate PFBS |LL11887744--1166,, DDFF==11000000 - (021804AR 251 Sm (Mn, 2x3) 021804AR-251 Sm (Mn, 2x3) . pwyly11~~ 606 800 1000 erry 6.00 35496~ 8.00 TT 10.00 200Time 12.00 0022--MMaarr--22000044 0055::0022::2(~ LOMSIMS LC/MS/MS #4 ais MRM of 5 Chann2el0s 5ES% 8.15 MRM of 5 Channels ES299 > 99 Tor 7s5e3 7.95e3 reaArea | shee A------ | 0-", ,,, .... , .... ,, ,~ ,, ~ .... , .... , .... , .... , .... , .... ,Time | 200 00 500 B00 000 20 ,i 2.00 4.00 6.00 8.00 10.00 12.00 EEx~yyggeenn RReesseeaarrcchh,, 33005588 RReesseeaarrcchh DDrriivvee,, SSttaattee CCoolllleeggee,, PPAA 1166880011 - `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACOPPURRROOTT,TEECNCTOT.IIVV2E7E-OOCVRR-DD1EE0RR28EE8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00442255 M_MNO1S3B811 3M MN01538811 u u QSQuuRaannEttiiTftyyESsaaDmmppllLee RReRapepo.orrottnteouan, mee.pater02/18/04, Amatyatix.nisha Page 102 Page 102 SLSSaeatnmmutppdllyeemoNdoLLi.iitss:ttiL::eId8:74,BTPor:s\\SDeDwtaaettNraao\\.L0u:5CC0MH2S1E13M8S1S0E064W0\A1aMR0as,0seslTlyhyEmonx\sxtF.\iDPualotureoo:r0co2hc/eh1es8mi/ic0ca4al,lss.A.nPFaRRlOOy\\sSStaa:mmKppl.1eReDiDBsB\\h0OaT2L1O80044AARR CCOG AACCSFEM weMGLLreaaatnsshtttaocdmmom:dooteddiriitffiiieeeddd::: wTPue=en\DDaMTataotabra)\LL002C5EMS01E7M21S:00647\K1=Ma04as03seslTi2hy0y00n44xn\~mlu\orFoclheumiocarlso.cPPRRhO0\\eMNeesCtHhiDDRBc)\CCaoottlGGrraoovv.ee Mon F~b 02 07=04:42 2004 NNPPDDEESS 001172110084 0 JmoibnCeodse: rue war 03 24005.23 2008 Printed: Tue Mar 02 14:05:22 2004 ,L|I same: 03300003-252 Name= 021804AR-251 T4:extc=o sulfonate pms 4 ~[:LTeC76a-S1u6l,fDoFna=t1e00P0FHS L1874-16, DF=1000 (021804AR251 Sm (Mn, 2) |n021804AR-251 Sm (Mn, 2x3) | | a _0M2R-MMaorf-2C0h0a4n0n53o:9l092E:6S2.0 8.79 rea| 5605 02-Mar-2004 05:02:20 LLCC/IMMSS/IMMSS #6 MRM of 5 Channels ES- 329.29.9911>Ae8er4e40a| 5: ca sulfonate pros | ok 1 22..0000 44..0000 5:C8 Sulfonate PFOS eS Time| 66..0000 ....88..00, 5 00..6.0 . 5, ~ ....1100.., 0000 ~,~'~11'~22',,.00T00ime | . 1LL11887744--1166,, DDFF==11000000 0022--MMaarr--22000044 0055::0022:2:2(0 LLCC/IMMSS/IMMSS #6 21804AR251 Sm(Mn, 213) MRMof 5 ChanneEl5s- 021804AR-251 Sm (Mn, 2x3) 0 sin 65 ,i | 1] MRM of 5 Channels ES- 299.1872 49119A6.r62>2e09e4a49)l Area " . 1 | | _ | | em , ....e , ....r , .... , .... , .... , e..e..e, E .... , .S ... , ...S . ~ ....E , .... ~, TTiimmee - 200 ao 600 860 1000 7200 2982~ 2.00 4.00 6.00 8.00 10.00 12.00 . " ,.| Exygen Resasrch, 3050 Reseacch Drive, State College, 7A 16801 Exygen Research, 3058 Research Drive, State College, PA 16801 - `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACOPPURRROOTT.TEECNCTOT.IIVV2EE7-OOCRR\-DD1EE0RR-2E6E3NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00442266 m_orsasstz 3M MN01538812 " quuatity sae report Quantify Sample Report rege 103 Page 103 Study No.:LI8?4, Set No.:021804AR, Ext.Date=02/18/04, Analyst:K.Risha Sample Liat. Bi\Daca\UOHDSE\Wasslyma\iuorochentcals.PRO\SaspeDIAOZL8OAAR CO ACS Sample List: P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\SampleDB\021804AR CG ACSFM fr pr pr gr MMeLeattshhtooddms:odified: TPPu=1e\\DDaMatatara\\LL0C2CMMSS1HM2SS:E06\7\M:Ma0as0sssll2yy0n0nx4x\\FFlluuoorroocchheemmiiccaallss..PPRROO\\MMeetthhDDBB\\CCoottGGrroovvee NNPPDDEESS 001122110044 Pry EA deo Last modified: Mon Feb 02 07=04:42 2004 fat noms Job Code= 0 prea ve ar 02 200s 200k Printed: Tue Mar 02 14:05:22 2004 ame: ozis0n252 a NTTaeemxxtet~~: 021804AR-252 1: co seid mn i: C6 Acid PFHA ,-i XC(C002222440044--44,, 225500 nngg/lLL SSttaannddaarrdd | czty a02i52A5Rm 4, 230) PRE| Si 021804AR-252 Sm (Mn, 2x3) So ns88.5500 0022--MMaarr--22000044 0055::2244::008 LLCC//MMSS//MMSS #6 MoR fGrM n E5- 313.>269) MRM of 5 Channels ES313 > 269 pe 4.38e5 ara|Area `| ,i 7% pry wa wa ooo aTin|e 2.00 4.00 6.00 8.00 10.00 Time 12,00 2: C8 Acid PFOA d [XXCC002222440044--44,, 225500 nngg//hL SSttaannddaarrdd c2ra02u52a5Rm i. 233) 021804AR-252 Sm (Mn, 2x3) . fo 1 i111 TM7093.0006 0022--MMaarr--22000044 0055::2244::008 Lomsms LClMS/MS #6 Mew of 5 Gran 5. MRM of 5 Channels ES- ; pr 4133>931659 pov 3.91e5Area `. 75 prey i sw abo A ooro re 2 | ,,| 0'~, , ~ .... ~ .... ~ .... ] .... ~ .... ~ .... = .... ~ 7..0.3.06~ ~.... , .... ~ .... ~Time 2.00 4.00 6.00 8.00 10.00 12.00 3XX."CC00C242224S40u04l4-f-4o4,n, a22t55e00 PnnFggB//SLL SSttaannddaarrdd -| c2ta02452A5Rm 4, 220) MofR5haI mels 5- 021804AR-252 Sm (Mn, 2x3) : as Toes - youd | %- 8.15 nos 31 0022--MMaarr--22000044 0055::2244::008 LLCC//MMSS//MMSS #6 MRM of 5 Channels ES299 > 99 116.677ee44| Area e M i ee A, .... , .... , .... , .... , .... , .... , .... , .... , .... , .... , .... , .... ,Time A To wm ak ao eae 2.00 4.00 8.00 8.00 10.00 12.00 " Exygen Research, 3058 Research Drive, State College, PA 16801 "C. ONFIDE-NSTUIBJAECLT TO APROTECTIVE ORDER ENTERED IN CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT. NG. 27-0110.8862 HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00442277 su_wmoreses1s 3M MN01538813 - Ww QqSuutaaunndttyiitfHyoy.:sSLaaTmm0pp7ll4ee,RReeSppeoofsrttNo.:0210IAR, Ext.Date:02/18/04, AnslystiK.Risha PPaaggee 110040 Study No.:LI874, Set No.:021804AR, Ext.Date:02/18/04, Analyst:K.Risha PR LLSSaaaessmmttppllmemeooddLLiiiiffssiittee::dd::FP1TTP\\ou:DmeD\aDatWMaecaat\arraL\\CL0L0H32CuSMHiS11SM23sE:S5e\006M77\(a1=MHs00aas00pslasyl23ym00ymx00nx44\x\F\FlFluluuooorrroooccchhheeeaamiiicccaaalllsss...PFPRRROOO\NSSNAaSRmEppH11DeDeD\DICB\o\Ot0Za21z10o80v04e4AARRNEDCCSGOSAAC0CS1SF7F1M04 LTMLeaoatssnhttoCdmom:a~ondd:iifeise~dd:= on Feb 03 67504143 2004 P=\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\MethDB\CotGrove Mon Feb 02 07:04:42 2004 NPDES 012104 pJroiborCeoadre: Tue war 02 24:05:22 2008 Printed: Tue Mar 02 14:05:22 2004 'l C= [p-- Name: 021804AR-252 T4:extc:o suionate pus _ _ a. Ml i4X:[CXC0C602222S44u00l44f--o44,n, a22t55e00 ng/L PFHS nglL SSttaannddaarrdd 0022--MMaarr--22L00e0044MS005I5::M224S4::0048 21604AR 252 Sm (Mn, 253) wo foo 021804AR-252 Sm (Mn, 2x3) 12838.70)91 MRM MRM of of 5LCCChhIaMannnSn33e/e9lMpl99ssSoE9>ESSa#8e>-0-60 | 1251 Ave " | he 3 '~ |i 6.93e4Area ` , ....25, 0.... , 50 .... , .... , ....60, 0.... , ....8%, ...10. 00 . cr .20,0TTiimmee ,i 2.00 5: co sultonate pros 4.00 6.00 8.00 10.00 12.00 X:C[0CX82C20S42u20l44f0-o444n,,a22t55e00 ng PFOS ng/L SSttaannddaarrdd 0022--MMaarr--22L00o004M4 S005I5::M224S4::0018 l002;211880044AARR2-25522 5m Sm (Mn, (Mn, 238) 2x3) a MRM MRM of of 55LCCChh/aaMnnnSn3eeI9lMlss9$5EESS#9--69 . T9o.1s7? 499 > 99 aoAtreeda 4.01Aree4a " | ~ " 250 Soo eo abo ri0r00a 7200 2.00 4.00 6.00 7652~ 8.00 10.00 12.00 - . " EExxyyggeenn RReesseeaarzcchn,, 33005588 RReesseeaarrcchh DDrriivvee,, SSttaattee CCoolllleeggee,, PPAA 1166080011 " `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACOPPURRROOTT,TEECNCTOT.IIVV2E7E-OOCVRR-DD1EE0RR28EE8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00442288 _MNO1S3B184 3M MN01538814 - a QQSuutaaunndtytiiNffoyy.rSSLaa1mmopp7llaee,RReeSppeootrrtNto.:021804AR, Ext.Date:02/18/04, Analyst:E.Risha Sage 105 Page 105 Study No. :L1874, Set No.:021804AR, Ext.Date:02/18/04, Analyst:K.Risha a vLLSSaaaaatssmmhttppolldmmeerooddLLiiiiffsstiit:e:edd::PrPTTP\uiu:Da\e\aDDtAMWataaata\rra\L\LCL00CS23CHHMISS31NE2M2S1\:S6006N77\aN:1Msa00asg00slssy13l2m00ycy00n\44xFa\PFlxluuo\orroFocchIheemumiicocaalrlss.o.PPPRcRROOO\h\\NSSAeaaCmmHnppOlLBiea\DDCcBBo\\ta0GG22rl11o80s00v44eAANRREDCCEGGSAAC0C1S2FS1M04 MLLoeaantsahttmocdama:todediriffileedd:: Non Fab 03 07104143 2001 P=\Data\LCMSMS6\Masslynx\~luorochemicals.PRO\MethDB\CotGrove Mon Feb 02 07:04:42 2004 I~PDES 012104 Job Code~ ,i cine Printed= Tue Mar 02 1:05.22 2004 Tue Mar 02 14:05:22 2004 [p-- a TNTeaexmxtte~:~ 021804AR-253 i1:: Cc6s Anceitda PpFeHnA 4 L|L11887744--1177,, DDFF==22O000 0022--MMaarr--22000044 0055::4455::55(0 (00|2211880044AARR-225533 Sm Sm (Mn, (Mn, 263) 2x3) ass MRM MRM of of 55LLCCCChh//aMaMnnnSSne3/e/lMl5MssSS2EE6SS#.0-6 h 686.4286 3137.>1620649) |J Areal 7.16e4 Area ,"m * | | o ...m . , , , p 2~ r 00 ,, , ...r .40, 0.... , ....60, 0...e . ~ ....80, 0.... , .r ...i0o 5, 0..s .. i ,T..Te ..20,T0Tiimmee 2.00 4.00 6.00 8.00 10.00 12.00 22:: cCo8 aAcciidd rPFoOnA o L[1L817847-41-71,7,D0FF==220000 0022--MMaarr--22000044 0055::4455::5500 |0p2018204A1R82-255033SS9mm4((MMRnn,, 265) 2x3) us MM RMoofR f55LLCCCChh/alMM anMnnpSSna/ie/rMslMsSSeEESS##s~--6 ,"J 28m.9a8r aves! 413 > 369 | 1.4AA0rreeea5a . | | - 2%2.00 4004.00 5006.00 008.00 1i00.5000 20 12.00 3: co sultonaee orm 3: C4 Sulfonate PFBS czte02i52n5Rm 4. 20) LL11887744--1177,, DDFF==220000 - %021804AR-253 Sm (Mn, 2x3) -| * - Orr 0-~ 200 ato 2.00 4.00 618.13 od 65.0000 88.0000 020-2M-Marar--22000044 5 05:45] :50 LLCC/IMMSS//MMSS #6 MRM of 5 Chamei5-s| MRM of 5 Channels ES- El 299 > 99 226.633ee44| Area|Area 1000 2 e Time| 10.00 12.00 a Exygen Ressaxch, 3058 Reseach Drive, State Collage, PA 16801 EA-ygen Research, 3058 Research Drive, State College, PA 16801 - `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACOPPURRROOTT,TEECNCTOT.IIVV2E7E-OOCVRR-DD1EE0RR28EE8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00442299 _MNO1S38815 3M MN01538815 " 4 QSQuuuaannlttiitwfeyy. sSTaaimmepprllsee,RReeSppeooerrttFo.:021004AR, Ext.Dete:02/10/04, Analystik.Risha PPaaggee 110066 Study No.=LI874, Set No.:021804AR, Ext.Date:02/18/04, Analyst:K.Risha " SLLSvaaaaassmmtttpphllommeaerooddLLiiiiffssiit~e:e=dd:: TPTPPiuur:\ea\\DDDaMWaataattarrae\\\L0LL0o32CCHMHES11SMM22S1:SE0064\77\MK1:Maa00asn00sssslly22y0y0m00nmc48x\\Pe~llu\uoorProoclchheuenmioiccarallsos..PPPcRRROOOh\\\NSSeSaaCmnnHppDl1iEea\DDcCBEo\Oat02d21lr10o80sv04e4AARNREDCCEOGSAAC0CS1T2FH1M04 TMLLoeaatnsshttmoCdomo:eodndi:itfiieedd:= Mon Tab 03 07104143 2004 P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\MethDB\CotGrove Mon Feb 02 07=04=42 2004 NPDES 012104 Job Code= iiii boiovear Printed: Tue war 02 24:05:22 2004 Tue Mar 02 14:05:22 2004 . sama: 02180438-252 Name= 021804AR-253 Text= 4: co sulfonate pms W L[:1L8TC876744-.S11u77l,,fDDonFFa==t22e0000PFHS "r((3aC22118870044AARR.-225533 Sm Sm (Mn, (Mn, 263) 2x3) i100~ 0022--MMaarr--22L00C00I44M00S55I::M4455S7:550 a8.7e7s9 MRM MRM of of 5LCCChh/aMannnSn33ae/9lMrl9ss9SaE>ES>S#8d-0-6 rea) `= ~N\ | _____ ~~ % 0-~ ..~ .. ., ~ ...~ . ~ " 200 00 600 800 000 200 2.00 , , , .... , .... ~- ....-~-, , 4.00 6.00 , , ~ ....~ , ..~ .. , ..._ .. ,..~ ... iTiAmreea 8.00 10.00 12.00 5: co sulfonate pros 5:C8 Sulfonate PFOS Wu |L187847,DF=200 02-Mar-200405:45:5( L1874-17, DF=20O "o|yxozta0a2n5s3 5m i. 269) Taazo MRM of 5LCOhMa"nSn1Ia0iM79s.S3E69S093.)) 021804AR-253 Sm (Mn, 2x3) 9.17 1326~ 02-Mar-2004 05:45:50 LC/MS/MS #6 MRM of 5 Channels ES499 > 99 7.38e3 Cei rea| 1001 a~ SUN ,~ Area OT re Time 0~ .... , .... , .... , .... , .... , .... ~ .... , .... , .... , .... ~ .... , .... ,Time - 200 a0 600 800 7000 200 2.00 4.00 6.00 8.00 10.00 12.00 .i,II ` ES~xyyggeenn RReessseaarrcchh,, 33005580 RReesseeaarrcchh DDrriivvee,, SSttaattee CCoolllleeggee,, PPAA 1166080011 . `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACOPPURRROOTT,TEECNCTOT.IIVV2E7E-OOCVRR-DD1EE0RR28EE8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00443300 _MNO1S3B816 3M MN01538816 w 4 GSQtuuuaadnnyttiiNfoyy.rSslaaimm9pp7ll4ee, RReeSppeootrrtNto.:021804AR, Ext.Date:02/19/04, Analyst:X.Risha Page 107 Page 107 Study No. =L1874, Set No.:021804AR, Ext.Date:02/18/04, Analyst:K.Risha LSSaaesmmtppllmeeodLLiiissftti=:ed:PiTP\u:eD\aDNtaaatra\\LL0C2CMMSS1N2MS:SS06\7\M:Ma0as0sssl2ly0ym0n\4xF\lFu1ouroroocchheenmiiccaallss..PPRROO\\SSAammpp1leeDDBB\\O02211880044AARR CCOG AACCSSFTHM PR Last modified= MLoLeaabtsshttmocdomo=dodedriffiieedd=: PNPToru:n\e\DDAMTataatabra\\LL00C3C2HMIS01NM72SS1=600674\\=1MN04a03sasl22ay0000sn44xl\Fylunoxro\chFemliucaolsr.PoPRRcOO\\hKMAeeCtHnhDDRiB\\cCCooattGlGrroaovv.ee. NNEPDDEESS Mon Feb 02 07:04=42 2004 001122110044 Job Code: 4 rPriinncteeadr= TTuuee MMaarr 0022 1144::0055::2222 22000044 oe Name~ e02n18e04mARa-25s4 Text= i1[::L1Cc86o7Aa4cc7iiddRoPpprF,iHnADF=200 L1874-17 Rep, DF=200 woo; 021804AR254 Sm (Mn, 23) 021804AR-254 Sm (Mn, 2x3) |: a he ser Toren _ 0022--MMaarr--22L00C00I44M00S66I::M007S7::38 848 MRM MRM of of 65LCCChh/aMann3nSn1eel3lM.lssS2EES6S#-0-6 8.48 313 > 269 Area) 7.07e4 Area | . L obv .... ; 200 .... ~ .... I e 4% e 600 e80e 0 1000 T 1200 | .... , .... , .... I .... , .... , .... , .... I .... , .... ;lime 2.00 4.00 6.00 8.00 10.00 12.00 4 22[::18Cc78o4-AA1cc7iiddRePsppF,oOnADF=200 02-Mar-2004 06:07:3 L1874-17 Rep, DF=200 (02160448254 Sm (Mn, 263) 0M2R-MMaorf-25LL0CCC0hl4aMMn0nSSo6/MlM:0sSS7E:S#3-68 a 1TM 10 021804AR-254 Sm (Mn, 2x3) 23880.99881 MRM of 5 Channels ES- 131>2336005 413 > 369 | 23361 rea 1.23e5 Area % - 200 400 2.00 4.00 3[3:L:1C8c4a74-sS1uu7tlffRooonnpaa,tteeDFPs=Fr2Bs0S0 - L1874-17 Rep, DF=200 . 0| 02v211y880044AARR-225544 SSmm ((MMnn,, 22xx33)) i |1 600 800 6.00 8.00 o88o.11rs5 000 1200 10.00 12.00 0022--MMaarr-.22L00C00/44M00S66/::M0077S::338 MMRRMM ooff 55LCCChh/aMannnSn22e/e9lMPl9ss9Sr>EEe9S>S#9-d-69 2.5AAr2reeeaa4) :uo L| b 0~eer 200 ,J 2.00 ne40A 0 500 800 100M0 a 200T"ime | 4.00 8.00 8.00 10.00 12.00 xExyyggeenn RReesseeaarrcchh,, 33005588 RReessesaarrcchh DDrriivvee,, SSttaattee CCoolllleeggee,, 7PAA 1166880011 . `CHEOGNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIJDJIEAESCCTLTTRTITCOOT AACPOPURRROOTT.TEECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR.2E6E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00443311 SW_MNo1S38817 3M MN01538817 " Wu QQSuutaaundntytiitfNyyo.sSraaLmm6pp7ll4ee,RReeSppooborrttNo.:021804AR, E<t.Date:02/16/04, Analyst:X.Risha PPaaggee 110088 Study No.=LI874, Set No.=021804AR, Ext.Date:02/18/04, Analyst:K.Risha LSSa~asmmtppllmeeodLLiiiessitt=e:d:PrTP\u:Do\aDtNaaat\raL\CL0M2CSMN1SS2M:ES06\7\M:Ma0as0sssl2ly0ym0nx4x\\FFlluuoorroocchheesmiiccaallas..PPRROO\\SSaamsppl1eaDDBB\\0G2211880044AARR CCGG AACCSFSM PR Last modified= MLeatshtodm:odified: PKTPe1u:en\\DDMaFaatatbraa\\0L0L32CCMHS01M7M2S1S=S00647\\N1:Ma40as30sss1l22y0y0m00nx44x\\PFlluuoorroocchheea~iiccaallas..PPRROO\\MNeAtChHDDBS\\CCoottdGrroovvae NNPPDDEESS 001122110044 JGLooabbs"tCcomoddoeed=rified= Mon Feb 02 07=04:42 2004 Ml Pprriinntteedd:: TTuuee MMaarr 0022 1144=:0055::2222 22000044 4 eNammeer~ c0a2n1s8o0e4aAnR--a2s5e4 Text= Wd 44[:L:1C8c67s4-sS1uu7llffRooonnpaa,tteeDFsP=Fr2Hs0S0 L1874-17 Rep, DF=200 | 00|22i1188]0044AARR--225544 SSmm ((M4n,, 226x33)) 1001 +* a18r0.789_3 1083~ ht . 0022--MMaarr--22L00C00I44M00S66I::0M07S7::338 MRM MRM of of 55LCCChhlaMannnSn3aellM9lssS>EESS#8--60 3959.5>60830] 8.56e3 | fl || ob 22.0000 44.0000 55: :Cc8o Ssuullffoonnaattee PpFrOSo_s 4 |!L1L01128187874044-11A7R7-2RR5ee4pp,S, mDDFF(M==n22,0020013) fozeo021804AR-254 Sm (Mn, 2x3) eer\ rTael 600 500 1000 200 6.00 8.00 10.00 12.00 0022--MMaarr--22L00C00I44MC0S6I:nM07S:38 MRM of 5LCCh/aMnnSa/iMsSES#-6 MRM of 5 Channels ES- y oHeo mBoess [IE 9.15 1131~ `real 409 > 99 6.30e3 Area | = ~ | O 1HCr o m eee Timo i .... ~ .... ~ .... ~ .... ~ .... ~ .... ~ .... ~ .... ~ .... ~ .... ~ .... ~Time - 250 abo 650 850 1000 200 2.00 4.00 6.00 8.00 10.00 12.00 - . a EEexyyggaenn RReesseeaarrcchh,, 33005588 RReesseeaarrcchh DDrriivvee,, SSttaattee CCoolllleeggee,, TPAA 1166800011 - `CHEOGNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIJDJIEAESCCTLTTRTITCOOT AACPOPURRROOTT.TEECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR.2E6E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00443322 SW_MNo1S38818 3M MN01538818 " wilQquuaaynnttiitfweyy.sSTaaImm6pplleee,RReeSppEooRrrttNo..021004A%, Ext.Datesc2/10/04, aalystiK.Eisha PPaaggee 120099 Study No.:LI874, Set No. :021804AR, Ext.Date=02/18/04, Analyst:K.Risha 4 vLSGSeaaaatsmnmhtptpollsmemesooddLLiiiiffssiittee:=dd:= PTT75uu=.ee\oD\aMaWtDaatarraa\\LtL00e32CaxM\S11iM23Le=S1C00673\Ua1=M00asM00ssSsl2i2E0y0\00nys4xH\eaFlsu\sorlFoyclhmemeui\coaTllslrs..uPPoPoRRROOOrc\\\oSSNhaaecmmCpphLellDeaeBzD\DmBCBi\io\0t0c2O2cLar18o8l0av04es4XAK.RNEDCCEGOSAAC0CS1S2FI1M04 LoMLeeanntshttocmdmoe:eodnd:iifiiaedd:= Mon Tob 03 07104143 F004 P=\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\MethDB\CotGrove Mon Feb 02 07:04:42 2004 NPDES 012104 Job Code= a,,| PPrriinntteedd:= TTuuee MMaarr 0022 1144::0055:=2222 22000044 [-- . NTTaeemxxett==: 021804AR-255 1: ce reid orn i: C6 Acid PFHA _ _ _ a 1LL11887744--1188,, DDFF==220000 (021604AR255 Sm Mn, 2:0) MRM of Channol ES- 021804AR-255 Sm (Mn, 2x3) 4 fw "assor S280 100 Totes | "/i~ 8.48 15967 0022--MMaarr--22000044 0066::2299::22((~ LLCC/IMMSS//MMSS #6 MRM of 5 Channels ES313 > 269 7.16e4 AArreeaa| i|| *obr er ere rr r ng i ........ IT,,, r .... I .... I .... I .... I .... , .... I .... I .... I .... ,Time . 260 a0 500 800 1000 200 2.00 4.00 6.00 8.00 10.00 12.00 2. co ned pron 2: C8 Acid PFOA . hL11887744--1188,, DDFF==220000 |({c0I220112860044AARR-225555 S5mm ((MMnn,, 22:x33)) s2s81.59o48 0 0022--MMaarr--22000044 0066::2299:2:2(0 LLCCI/MMSSIIMMSS #6 MRMof 5 Channels ES- MRM of 5 Channels ESeo 1708 413 > 369 1 1.17e5Area| |"* | 1001%~ 2194~ aw 0-,~",--~-~----~i , ~ .... ~ .... ~ .... ~ .... ~ .... ~ .... , .... ~ .... , .... ~ .... r,,, >', Time _ 260 ao eo abo ilo 200 2.00 4.00 6.00 8.00 10.00 12.00 3. co sulfonate ora 3:C4 Sulfonate DFBS [L1874-18, DF=200 02-Mar-2004 06:29:2 L1874-18, DF=200 - (c21604AR255 5m (Mn, 2:0) MRMof 5LCChIaMnSnIaMS5. 021804AR-255 Sm (Mn, 2x3) |{| or%eo an Sesre0a0, eo 02-Mar-2004 06:29:20 LC/MS/MS #6 MRM of 5 Channels ES- 680.1430 292293.31>16e9449] Area - I O : r 200 m aon e500 2.00 4.00 6.00 00 r 1000r20T0im|ei| 8.00 10.00 12.00 o Baygen Research, 3058 Research Drive, State College, IA 16801 Exygen Research, 3058 Research Drive, State College, PA 16801 `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACOPPURRROOTT.TEECNCTOT.IIVV2EE7-OOCRR\-DD1EE0RR-2E6E3NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00443333 m_morsassto 3M MN01538819 " qQSuutauandntytiiNtfoyy.:SSLaa1mm8pp7ll4ee, RReeSpapotorrtNto.:021004AR, Ext.Date:03/19/04, Analyst:X.Risha Page 120 Page ii0 Study No.:LI874, Set No.:021804AR, Ext.Date:02/18/04, Analyst:K.Risha LSSaaesmmtppllmeeodLLiiissfttl=:ed:PrTP\u=De\aDNtaatara\\LL0CC2SMHS1S2ME:S\66M7\a:Ms0as6slsyl2m0yx0n\4xP\lPu1ouorroocchheesmiiccaallss..PPRROO\\SSaamspplleeDDBB\\G022L1080044RARR CCGG AACCSFSM uatMTLLLeoeaaantsss"dhtttoc:dmmom=odooedddriiifffiiieeeddd::: PNTPou=ren\\DDMaTtataarba\\L00O72CMHS01N7M21S=E00647\N1:Ma40aa30sssll220y0y00n44xn\Fxlu\orFocIheumiocralos.cPPRRhOO\\eNMAenCtHhiDDE~c\\CCaoottlGGrrsoov.vee KNEPDDEESS Mon Feb 02 07=04:42 2004 001122110044 Job Code: W Pprrinntceeda: Tue Maz 02 24:05:22 2008 Tue Mar 02 14:05:22 2004 CI aNammee:: 002211080064aARR--225555 Text~ 44:[:LC1c86e74-sS1uu8il,tfDooFnnaa=tt2ee00pPrFHiSs !L1874-18, DF=200 a 1|002211880044AARR2-25555 Sm Sm (Mn, (Mn, 263) 2x3) || 0a671180,6719-~1 a 0022--MMaarr--22L00C0044M0S06I6:2:M29S9:2:210 MRM MRM of of 55LCCChh/aMannnSn3ee/lMlss9SEES>S#8-0-6 396927>0830) 6.27e3 Area [I || o3 r ee | | a | 200 400 600 500 1000 200T 111/~ 2.00 4.00 6.00 8.00 10.00 12.00 a 55[::18Ca784-sS1uu8llffDooFnnaa=tt2ee00pPrFoOsS 02-Mar-2004 06:29:20) L1874-18, DF=200 0218044R.255 Sm (Mn, 23) 0M2R-MMaorf-25LL0CCC0hI/4MaM0nSS6nI/M:aM2SS9E:S2##.066| 00, 021804AR-255 Sm (Mn, 2x3) a8 MRM of 5 59>99 Channels ES- 00 9.16 499 > 99 |m 5 2 1 ~ 1 1175~ re 6.16e3 * Area % ~ ` | eihu S ee EN R eS re 0/'C-,C-, .... , .... ~ .... , .... r, ,,-T-T-~,,-,, ,, ,~,,, ;,, .... , .... , .... ,Time - 206 450 600 800 1000 200 2.00 4.00 6.00 8.00 10.00 12.00 - - . Bxygen Ressarch, 3056 Reseach Drive, State Collage, PA 16801 Exygen Research, 3058 Research Drive, State College, PA 16801 . `CHEOGNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIJDJIEEASCCTLTTRTITCOOT AACPOPURRROOTT.TEECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR.2E6E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00443344 SW_MNo1838520 3M MN01538820 . w GQuuaannttiifsT yy Ssaemmpilse RReeppoorrttNeate00an, mt.Dacer02/10/04, dmaiyetik isha rage 112 Page iii a dLSESSaaaaattsmrmuitpnpdollyRnemeosoNkdoLLiii.iFfss:iittL::eIed8:=74,PTTBu=o:e\SaoD\ebuMatDetatrarNaAo\\E.L0L0:s2Coa0Mu\2SET11kMa2U8ssS=C0e064r7\KMA:MaSR30ag,00sHssSl2y2y0EE00nxnm\4tx.\aMD~aal\t~seoFs:r0oil2c/yuh1em8om/ei0rc\4a,FolsiAc.uPnPPRahRRoOlOOrNye\\SsSNoamtaem:smhiKppOh.llBcRee)iDDnGasBOho\i\la0t2c2r1s1ao68iv0.0e44sRA.NRRPDCCEGOSAAC0CS12FS1M04 t rMLeattshtomdmR:oadaticfiieeads= hon Tob 05 ors0rr is 008 P=\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\MethDB\CotGrove Mon Feb 02 07:04:42 2004 NPDES 012104 ocea Job Code= me ar 02 20005132 2008 Printed= Tue Mar 02 14=05=22 2004 sane casos 256 Name= 021804AR-256 Text= Rp I: C6 Acid PFHA a |LL11887744--1177,, DDFF==110000 c| 21800AR255 Sm 4 20) MofR6Ca haM nnel 5. a |i021804AR-256 Sm (Mn, 2x3) I'd as "r=oses, , 0022--MMaarr--22000044 0066::5511::006 LC/MSlMS #6 ois 13>209] 8.48 MRM of 5 Channels ES313 > 269 1.0905 Area | = A ! 100)%~ " -- . 35 i 179 a do oe -'w~'' ' ' ....2.0' 0.... ' ' ' 2: co neta pron 2:C8 Acid PFOA 2~ ret Time | ' '~-''' ~--~-~6''.50.. ' ... .... .lO.OO.. '... . '" I'2:0~me - LL11887744--1177,, DDFF==1100O0 WFc2t825054SmAinR, 2:0) sss MRMofSChaTmeonsie5ss- 021804AR-256 Sm (Mn, 2x3) 0O22--MMaarr--22000044 0066::5511::006 LLCC//MMSS/IMMSS #6 MRM of 5 Channels ES- 8.98 413 > 369 oo,1 a iea 2.27e5Area | %| | | G-- rr-- r--------------r I, Vie 1(i/l 43730~ 0,~--~~-~,,, ~ .... i .... ~ .... i .... i .... ~ .... ~ .... ~ .... ~ .... ~ .... ~ .... ~ Time LTTE ETT Th ow 2.00 4.00 6.00 8.00 10.00 12.00 3: ca suitonste pros : C4 Sulfonate PFBS Lia77, DF=100 02ar-2004 06:5T:0 L1874-17, DF=10O - lc:21004AR256 5m n. 20) MRMof LCohmasninvesl.5- 021804AR-256 Sm (Mn, 2x3) ors 256 >50 po * 8.15 12330 02-Mar-2004 06:51:06 LCIMS/MS #6 MRM of 5 Channels ES299 > 99 44..2255e44. | Area " | . ~ Tine|i .... , ,, -,~, .... ~ .... , .... , .... , .... , .... , .... , .... ,Time | 75% bs obs 800 oo a il 2.00 4.00 6.00 8.00 10.00 12.00 a Erygen Resaasch, 3058 Reseazch Drive, State College. 7A 16803 EAqrgen Research, 3058 Research Dr~ve, State College, PA 16801 - CCHEOONNNNFEIDFPEIINNTDCIAOELU-NN- TSSTUYUIBBDJJIAEESCCTLTTRTITCOOT AAGPOPURRROOTT.TEECNCTOTIIVV2EE7-OO0RR1-DD1EE0RR.0E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00443355 su motsssz1 3M MN01538821 . W QQSuutaaunnyttiitfWeyy. SS1aaLmmTOppTllAee, RRSeeepproorrtto.:G21004AR, Bxt.Date:02/16/04,Analyst. Risa sage 112 Page 112 LSSSaaatrmmu?ppdllyeemoNdoLLi.iizs=sittL:e:Id8:74,TPPu::a\\SDDeataattreNao\\.LL0:C2C0HM2SS11UM38SS10S6047\\A1MaR0as,0sssLlTyyhEmonxxsxt\.\PDFalutuoeor:ro0oc2ch/he1en8m/il0cc4aal,lss.A.nPPaRRlOOy\\sSStau=mmKpp.l1ReaiDDsBDh\\0a02Z1L80044AARR CCGO AACCSEFHM Last modified= ato Method: Cantemaoaettsod: Last modified: 7wTPou:e\nDDaaMTttaoaarb\\LL00C25EMES01NM72SS1:600\47HM1:a40as30sslF2y00an00x44n\FFlluuoorroocchheemiiccaallss..PPRRO0\\MNeetClKlDDRB\\CCoottGGzroovvee Mon Feb 02 07:04:42 2004 NNPPDDEESS 003112110044 JcoboCondec: ave war 02 24:05.32 2008 Printed: Tue Mar 02 14:05:22 2004 a memes ozsomaase Name= 021804AR-256 Text= 44: :Cc6s sSuulrftoonnaatcee oPFuHsS a 1L1887744--1177,, DDFF==1IO000 . ||002211880044AARR2-25566 Sm Sm (tn, (Mn, 213) 2x3) [x8.79 104 0022--MMaarr--22000044 0066::5511::0066 LLCC/IMMSS//MMSS ##66 MRMof Channel ES- MRM of 5 Channels ES39> 00 3919.0>68840. rea A.0re6ea4l: ` |* 1994~L RE a 11o/l Ep NR ere TiS 0r,"~. , .... , .., .. .... , .., .. .... , .., .. .... , --~'- -- ~ ~Time | 200 4% obo 0 1000 200 2.00 4.00 6.00 8.00 10.00 12.00 5: ca sulfonate pros 5:C8 Sulfonate PFOS [memoeo 02-Mar-2004 06:51: L1874-17, DF=100 02-Mar-2004 06:51:06 (0|2f 0182041A8R-02546S4Smm2(5(M45n,, 2)2x3) LCCI/MMSIIMMS #6 MRMof Channa E5- MRM of 5 Channels ES- 17 9055) 9.17 499 > 99 1 O01 | 252215 1 A rea 11..1177eed4) - r 200 a6 e eho 00 B i000 T 1200 2.00 4.00 6.00 ~~itea .... ~ .... ~ .... ~ .... ~ .... ~/Ime 8.00 10.00 12.00 - - . Sxygen Resessch, 2058 Ressssch Drive, State College, FA 16901 Exygen Research, 3058 Research Drive, State College, PA 16801 `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACOPPURRROOTT.TEECNCTOT.IIVV2EE7-OOCRR\-DD1EE0RR-2E6E3NN6TT2EERREEDD IINN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 193377..004436 m_orsassz 3M MN01538822 . a QGuuaannttiicfLyy sSIaammpLlpe RReeRppeoorrttonnon, mxe.ater02/10/01, asiyetix.nisha rage 113 Page 113 oaLSTSStaaaatssmmutkppdhllymeemoNodoLLsi.iiifss:iittLe:=eIdd8:=74,PTFTBuu=o:ae\SnDe\MtawtDaaterNraAo\L.L00t=52oCu\0Mi2S11L1M218S=K00063H47\W1A=MEa0R0ad,00Csss\l32i0y0EM00nxy44atx.\nsDFalsat~leo\=ry0Fo2cm/lhe1eu8m\/io0Tc4ari,lsuoA.PonPPcRaRRrOlOOh\yN\oNSseScaetaa=mmhhKppOi.lelBReecs)iDDGsBiOeoh\\tca0l2O2a1r1s6o8lOv.0s4e4RA.NRRPDCCEGOSAAC0CS12FS1M04 ,m m MLHeaetsihttoedam=oidcitfieeads= Fon ren oher sob is oot P=\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\MethDB\CotGrove Mon Feb 02 07=04=42 2004 NPDES 012104 Job Code= a PPrriinntteedd:= TTuuee MMaarr 0022 1144:=0055::2222 22000044 a sama: 02380038-287 Name= 021804AR-257 T1:extc=o neta orn i: C6 Acid PFHA . _ .ai,m |LL11887744--1177 RReepp,, DDFF==110000 c21802457ASRm n, 2) MRMof GhannEcSl- 021804AR-257 Sm (Mn, 2x3) sir "oereas . 110,0~- 0022--MMaarr--22000044 0077::1122::5511| LLCC//MMSS//MMSS #6 MRM of 5 Channels ES- 88.5500 331133 >> 226699| 1.07e5 Area | " ~ i | 0-'~'' ', .... , .... r .... , .... , .... , .... , .... , ....=~=.=... , .... , .... ,Time . 2) i ok amo 1000 2% 2.00 4.00 6.00 8.00 10.00 12.00 24 ca seta pron 2: C8 Acid PFOA 4 [Li876:17 Rop, DF=100 24ar2008 07:12:51 L1874-17 Rep, DF=100 02-Mar-2004 07:12:51 (cars04aR257 sm hn, 2) 021804AR-257 Sm (Mn, 2x3) a [10 | 1 ss MofRGraM nTnelsn5- a88.3984 38a1 LLCC//MMSS//MMSS #6 MRM of 5 Channels ES- 20805, 413 > 369 2.0Ar8eea5| - - 7% i 5 reab 00 2T%ino 2.00 4.00 6.00 8.00 10.00 12.00 : C4 Sulfonate PFBS |LL11887744--1177 RReepp,, DDFF==110000 - |oztensar.2s5m7 in. 200 021804AR-257 Sm (Mn, 2x3) . oe00 | %1% M e1 rrr o~ . | 5% PS 2.00 4.00 ai83.1s5 PY) abo 6.00 8.00 0022--MMaarr--22000044 0077::1122::5511) LCMSIMS LCIMS/MS #6 MofR5 haM nna ES- MRM of 5 Channels ES- Tes 09 259 > 99 Gases 4.49e4 oaArea | 00 20Time| 10.00 12.00 a Exygen Research, 3058 Research Drive, State College, PA 16801 `.CONFIDE-NSTUBIJAECLT TO APROTECTIVE ORDER ENTERED IN CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT. NG. 27-Gu-10.28862 HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00443377 au_mnorsaszs 3M MN01538823 ,.J a QS Quueannttiifse yy aSammppll. ee RReeppoorrtot nt0aan, mxe.Date102/18/04, AmalystiR.Rishe PPaaggee 112104 SESSaatammutppdllymeeoNtoLL.iii.tss'ittL::eIa8:74B,TPiu=\s\SDeDatWatatarNa\o\L.LbCiC:HM0IS12S3M1E18S\006K43\aA:MsR0a,e0slsy2lm0yEe0nx4\txT.\DlFalutuoeor:ro0oc2ch/he1em8mi/ic0ca4al,lss.A.nPFaRRlOOy\\sSGtas:msKpp.llReaiDDsBOh\\a0OT2L1080044AARR CCaG AACCESTFIMC Last modified= oto Method= S Tent emsastiod: Last modified= HBTPYou=ne\oDuMFataetabra\\LL0052CMiS61M2s7S=0607\W0=Ma0ass0sssl22i0y000ny44x\mFlauo\roFchuemoicralos.FcPRRhOO\\eNMAemtChHiDEBRc\)GCeoottlaGrrsoovv.ee Mon Feb 02 07=04=42 2004 NNPPDDEESS 001132110044 Job Code: A Porriinnteeeda= TTuuee MMaarr 0022 1144::0055=:2222 22000044 sea: 0z100028-287 LI Name= 021804AR-257 Text= 4: ce suitonase eens ,4i [187417 Rop, DF=100 : C6 Sulfonate PFHS L~874-17 Rep, DF=IO0 c21e0a2sr? sm on. 220) 021804AR-257 Sm (Mn, 2x3) fw sn Toeas 1 | 1O0I1 0022--MMaarr--22L00C004I4M00S77::I14S22::5#5116 MRM of LCCh/MamSaIMlS#56 MRM of 5 Channels ES- oe8.79 Seed 399 > 80 9.6`AA2rreeeaa3l PEEO ol . | o 1. 200 b ho 50e abo EEfr rr-- e) e~ eaTime 5. cs suatonate 2e.0r0os 4.00 6.00 8.00 10.00 12.00 |L1874:47 Rap, DF=100 5:C8 Sulfonate PFOS L1874-17 Rep, DF=100 0022--MMaarr--22L00C0044I00M77S::11I22#::M585S11 ||| 0c2a118s0044AaRr-225577 sm Sm vn.(Mn, 220) 2x3) arr MRM MRM of of 55LCCChh/aMannnSnWoeIeiMlsssS>E55S#.9-6| ory9.17 49V9a>se9s9] 1977-~ rea 1,08e4 `|| |Area le ~I - r 200 e ib 6r 0 ab Ie 00ITDfr ie 2.00 4.00 6.00 8.00 10.00 12.00 - . I Exygen Research, 3038 Reseaich Drive, State Collage, Th 16801 Exygen Research, 3058 Research Drive, Sta~-e College, PA 16801 " `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NTSSTUYUBBIDJJIAEESCCTLTTRITTCOOT AACOPPURRROOTT.TEECNCTGT.IIVV2EE7-OOGRRu-DD1EE0RR.2E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00443388 au_norsasezs 3M MN01538824 " guantisy sample sapere ee 708 Quantify gample Report 0 BEIT onions, wm mssescariato, sepsis Study No. :L1874, Set No.:021804AR, Ext.Date:02/18/04, Analyst:K.Risha Page 115 A ------ Sample List= Ira, Snr Las~ modified= et busi Wate rosFivorocFhROeWestihmc\cuovairosve APTES 12104 Method: EET ities, SERRE r Last modified~ LE Job Code= P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\SampleDB\021804AR CG ACSFM Tue Mar 02 12=07=00 2004 P=\Data\LCMSMS6\Massly~x\Pluorochemicals.PRO\MethDB\CotGrove NPDES 012104 Mon Feb 02 07:04:42 2004 Breet Tue ar 03 von 2004 Printed~ Tue Mar 02 14=05=22 2004 tm onmuee Name: 021804AR-258 0 0. 20st rm Text : I: C6 Acid PFHA . o21304AR5.m245,8 2) a |LL11887744--1188,, DDFF==110000 021804AR-258 Sm (Mn, 2x3) | =I 1(/~"~~ i"F.28.48 23821 ~ 0022--MMaarr--22000044 0077::3344::44(0 LLCCI/MMSS//MMSS #6 MRMof Gramel5s. MRM of 5 Channels ES- wh 313 > 269 oes 1.08e5 ArAreeaa yo]| ,x'-I ola ` 22..0000 2: C8 Acid PFOA 44..0000 66..0000 ....88..00, 00.... , ....1100.., 000.0... ,,,, 1122..00T00ime ILL11887744--1188,, DDFF==110000 IE215250854m i4, 2) ries MEMOISCRmposFcyiS.e 021804AR-258 Sm (Mn, 2x3) 0022--MMaarr--22000044 0077::3344::40 LLCC//MMSSIM/SM#S#6 8.98 MRM of 5 Channels ES413 > 369 2.A8reea5l * = a | 4 NN---- -- ..... ,, , , , ~ ,, , ,, 40249,~ , , ,Time . 7% pr) a a oo am 10oi~ 2.00 4.00 6.00 8.00 10.00 12.00 Tas. ITE 3:C4 Sulfonate PFBS 1L8178474--1188,, DDFF==110000 .- cztonsar5mzi5na, 2) MRM ofSLGormaams5. 1%021804AR-258 Sm (Mn, 2x3) = Tr=oe 1'' 0022--MMaarr--22000044 0077::3344::44((~ LCIMS/MS #~ 813 Ro 8.13 MRM of 5 Channels ES299 > 99 4.10e4 Area % - | i Omer TE _. 0 ~ .... , .... ~ .... , .... , .... ~ .... , .... , .... , .... , .... , .... , .... ,Time . pr) prs wo 50 Tose 2.00 4.00 6.00 8.00 10.00 12.00 ','U a Sargon Reseacch, 3088 Resessch Drive, Stave College, BA 16803 . Exygen Research, 3058 Research Drive, Sta~ College, PA 16801 GCFOEONAFNNIEDFREINITCDIAOLUE-N-NTSSUYUTBBDJJIIEESCCATTTRITTC0OTAPACROPOURTROETTCENTCGIT.IVV2EE7OOGRuRnODiEEoRR26EE8NN0TT3EERREEDD IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00443399 swnoss3025 3M MN01538825 . a qQSuuaaannttiiN ftyy SsaammppS llee RReeppoorrNtte contour, mxt.Daten0a/10/04, Anatyatix.nisha Page 116 Page 116 Study No.=L1874, Set No.=021804AR, Ext.Date=02/18/04, Analyst:K.Risha 4 LaSLSaeaatsmsmttppollremmeooddLLiiiifrssiittee::dd=:prTPTF\ou:\Deu\DADaWMCataataarra\\\LL0L0O23CoMMiMS11nSM23Ss=S1\060M7\K1:aMa00asa00ssssl1l22y0y0my00n\44xFI\iP\vlouProorIocchuheemomiicFcaalOlssC.PPRhRROOO\e\NASSnEaAmRELpDplD1ce\DDCaBBO\OEL02G21Es10O80.V044eAARRKFCDCEOGSAAC0CS1F2S1M08 MTLLeoaatnashttocdmmo:otoedd:iiffiieedd:: on Fab 03 07104143 2004 P=\Data\LCMSMS6\Masslynx\P1uorochemicals.PRO\MethDB\CotGrove Mon Feb 02 07:04:42 2004 ITPDES 012104 Job Code: # Perriinnteeead:: TTuuee MMaarr 0022 1144::0055=:2222 22000044 Nase: 02180428-258 i. TNTeaexmxtet:=, 0~1804AR-258 4: ce suitonate vem 4:C6 Sulfonate PFHS _ I_ -ii |LL11887744--1188,, DDFF==110000 (21825084SmA(MRn, 233) MRMof ChanneElSs- ~021804AR-258 Sm (Mn, 2x3) a. | a7 399=-0] 100lo/o~. 178.769 17i 0022--MMaarr--22000044 0077::3344::40 LLCC//MMSS//MMSS #6 MRM of 5 Channels ES- 3919.0>00840) | % Pe ---- I Te|| . L 0'~, 22,.,0000..,.~.--~ -~,.44..0~000.... , ...6.6..00, 00........8.8..00, 00.... ~ ...1.100..,0000..~.1...0.0.e.11422..A ,00T00rimeea sco some pros _ _ _ 4 L|:1L8C178847-4S1-u81l,8fD,oDnFFa==t11e0000PFOS (C21820548ASRm (Mn, 263) MofR 5ChaM nnels ES. oy 021804AR-258 1 = | Sm (Mn, 2x3) 0022--MMaarr--22000044 0077::3344::440 LLCC//MMSS//MMSS #6 017 45> 990) MRM of 5 Channels ES- 9.17 499 > 99 58 11..1144e044 Area ,"ii I{ !1 | - L oC-- rT Ta-- e ap---- eme-- ee w I dT osIaT Teim)e| 2.00 4.00 6.00 8.00 10.00 12.00 - - u . EEcxyyggeenn RReesseeaarrcchh,, 33005588 RReesseeaarrcchh DDrriivvee,, SSttaattee CCoolllleeggea,, PPAA 1166880011 . `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEEASCCTLTTRTITCOOT AACOPPURRROOTT,TEECNCTOT.IIVV2E7E-OOCVRR-DD1EE0RR28EE8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00444400 _MNO1S38825 3M MN01538826 . 4 QQSutuauandntytiiNffyoy.SSLaa1mm6pp7ll4ee, RReeSppetoorrttNo.:0Z1804AR, Ext.Date:02/16/04, Anslyst:k.Risha PPaaggee 111177 Study No.:LI874, Set No.=021804AR, Ext.Date=02/18/04, Analyst=K.Risha SLSaaamsmptpllemeodLLiiifsstit::ed:P:TP\u:De\aDtWaaet\raL\CL02NCSMHS1MS2:SS06\7\M:Ma0as0sssll2y0yn0nx4x\\PFlluuoorroocchheemmiiccaallss.PPRROO\\SSeammpplleeDDBB\\O022118800I4AARR CCGG AACCESTFHM 4 avLMLLeeaaabttsssnhtttoocdaommm=:doooedddriiicffiiieeeddd::= NTP7ou=\ne\DDMaTaatarbat\eL0032C\MLS10M27CS::H60047\S::M40aN20sSs2l260y0\00n44xN\aFlsuaor1oychnexmi\cPalls..uPPoRROzO\\oMMeectEhhHDDeBBn\\CCiootctGGaErolovvsee. NNPPDDEESS Mon Feb 02 07=04:42 2004 001122110044 Job Code= # rPrriinntceeda=r TTuuee MMaarr 0022 1144::0055::2222 22000044 [INNaa=mmee=: 002211880040A4R8--225599 Text= 4 I1L::18cC7s64Aa4cc7it,daDFPpF=rHm1An0 oo L1874-17, DF=10 0218047250 Sm (Mn, 233) "Ir| 021804AR-259 Sm (Mn, 2x3) ` |* _ 2288.45500088 _ ) 0022--MMaarr--22L00C00I44M00S77I::M55S66::2#2050 MRM MRM oeff5LCCChh/aMann1nSne3e/lMl>ssSEE2S#S6-06 31311>..00A552r6e6e669a,11 Area " O" .... 22,0000 44.0000 4 22|::LC1C88o74RA4ec7iidd,DPpFF=rO1oA0 L1874-17, DF=I 0 1021804AR-250 Sm (bn, 2:3) PE 021804AR-259 Sm (Mn, 2x3) i a | *1001 56.0000 800 224986~ 8.00 1100.0000 20T0ime 12.00 36995.070050 9 0022--MMaarr--22L00C00/44M00S77/::5M566S::22(] MRM MRM of of 5LCCChhlaMann4nSneeIlMl1>ssS3EE36SS#9--6) 413 > 369 2A0r0e0a6 2.09e6 Area 395759~ w | - | 01,, ,~ 260 .... , .... , 400 .... , .... , 650 .... , .... , 850 .... , .... , 1000 .... , .... , 200 .... ,TTiimmoe 2.00 4.00 6.00 8.00 10.00 12.00 3L3:1:8Cc74a4-sS1uu7ll,ffDoonnFaa=tt1ee0 PpFaBsS 02-Mar-2004 07:56:20 - | L1874-17, DF=10 (002211880044A4RR.-225599 SSmm ((MMnn,, 22xx33)) 0M2R-MMaorf-2LL0CCC0h//4aMMn0nSS7e//lM:M5sS6SE:S2#-06 815 MRM of 5 269>99 Channels ES- | 1382.10501 29496`>%r5e)a | 4"69e959Area 11! 132001~ ot : Time 0~ .... , .... , .... , .... , .... , .... r ........ , .... , .... , .... , .... ,Time u 200 400 600 800 10.00 200" | 2.00 4.00 6.00 8.00 10.00 12 " BExxyyggeenn RReesseesasrcchh,, 33005586 RReesseeaarrcchh DDrriivvee,, SSttaaktee CCoolllleeggee,, PPAA 1166880011 . `CHEOGNNONFEINDPEIFNNITCIDAOLEU-N-NSTSTUUYBBIDJJIAEESCCTLTTRITTCOOT AACOPPURRROOTT,TEECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR.2E6E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00444411 3M_MNots38827 3M MN01538827 . 4 QqE uuaannttiiE tfyy dSaaT smppllee RReeSppeoo.rrttcons0aam, mxt.Daterca/10/04, AmalystiK.nisha rage 110 Page 118 LSSSaaatnmmu?ppdllyemeoNdoLLi.iifss=ittLe=:Id8:74,mPBo:=a\\SDDesataattraNa\o\L.L0C=5C0HM2SS11MM38SS10E0647\WA1MaR0as,0ssslSl0yE0nxy4xt.\mDFaletueo\:r0oF2c/hl1e8mu/i0co4a,lrsA.oPnPRaRsOlO\y\hsStaen=mpKpn.laRieDiDBscBh\\aa0022l1188s0044.AAR CO CG ACHP ACSFM PR Tartemaeceitied: Last modified: Method: Last modified: MTP7e~=ne\DDaMavtatearba\LLo0s2CeMS10nM27S=1eT0074\1:MK40aa30sassl2FLy00y00nX44x\\FPl1uuoorroocchhaesmciaclasl.s.PPRROO\\MKeetEhRDDBR\\CCoottGGrroovvee Mort Feb 02 07=04:42 2004 NEDES NPDES 012104 012104 # bJroibntCeoddre: me war 03 14:08:22 2008 Printed: Tue Mar 02 14:05:22 2004 4 emer Name: o02z1i8s0e4aARm-a2s5s9 h 4: ce TTeexxtt:; sutonate sus 4:C6 Sulfonate PFHS " |LL11887744--1177,, DDFF==1100 + 0([221581084A0R4-2A59RSS.mm2M(5Mn0n,, 2:3) 2x3) | a| ast8.81 20569 0022--MMaarr--22000044 0077::5566::22(0 LCMSIMS LC/MS/MS #6 MRMof ChanneEl5s- MRM of 5 Channels ES- 2950 3919.0>7e8s0! rea,| 1.07e5Area | Tim|e " i O" .... , ....22..0,000.... , ....44..00, 00.... ~ ....66..0,000.... , ....88..02~0000.5.6..9~~ ...1.100..,0000.... , ....1122..,00T00ime soca sultonmerros : C8 Sulfonate PFOS [Lf87417,DF=10 02-Mar-2004 07:56:2 51874-17, DF=10 (216044 259 5m (Mn, 2:0) Rof 5CM hannels ES- 021804AR-259 Sm (Mn, 2x3) PESy [2917 5To9s, 00 02-Mar-2004 07:56:20 LLCC//MMSS//MMSS #6 9.17 MRM of 5 Channels ES499 > 99 eaArea wo % 1 Time | 0I .... ; .... , .... , .... , .... , .... ~ .... , .... , .... , .... , .... ~, , ,', ,Time . LF 200 abo 600 abo 050 Zo 2.00 4.00 6.00 8.00 10.00 12.00 a " Sxygen Resescch, 1058 Resescch Drive, State Collage, TA 16801 Exygen Research, 3058 Research Drive, State College, PA 16801 ,.j `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACOPPURRROOTT.TEECNCTOT.IIVV2EE7-OOCRR\-DD1EE0RR-2E6E3NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00444422 m_orsassze 3M MN01538828 . PA" oo Quantify Sample Report Study No.=LI874, Set No.:021804AR, Ext.Date:02/18/04, Analyst=K.Risha Page 119 BR Sample List: EYL, Last modified: i EE i evmamteinmeets som mone Method= Last modified= Eo Job Code= P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\SampleDB\021804AR CG ACSFM Tue Mar 02 12:07:00 2004 P=\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\Metb-DB\CotGrove NPDES 012104 Mon Feb 02 07=04:42 2004 # ePrriinncteeadr= TTuuee MMaarr 0022 1144::0055=:2222 22000044 F-- rNTaemxate== 021804AR-260 esa i: C6 Acid PFHA . nnzsrsmon. 20 a |LL11887744--1177 RReepp,, DDFF==1100 021804AR-260 Sm (Mn, 2x3) a"8.50 0022--MMaarr--22000044 0088::1188::009 LLCC//MMSS/IMMSS #6 ert asd MRM of 5 Channels ESme 313 > 269 ==1.07e6 vd a 22.0000 rir 2: C8 Acid PFOA ` [LL11887744--1177 RReepp,, DDFF==1100 ovomnanoman ct |021804AR-260 Sm (Mn, 2x3) | .`| .o 2.00 3:C4 Sulfonate PFBS Cine ron 3 L1874-17 Rep, DF=I0 -. ic- umsgm. 2 021804AR-260 Sm (Mn, 2x3) 44..0000 66..0000 ET 4.00 6.00 2188.5.0080031~ 1100..0000 Area - | 1122.0000 | 59.0000 360382 :380382~ 8.00 Aos8.15 0022--MMaarr--22000044 0088::1188::009 LLCC//MMSS//MMSS #6 rs te MRM of 5 Channels ES5389] 413 > 369 1.9306 =1.93e6Area eei 10.00 12.00 aEOE 02-Mar-2004 08:18:0~ ses LCIMS/MS #1~ wa Ete MRM of 5 Channels ESmE 299 > 99 S7o4.67e5 Area -. | i TE wT ewTTiimmee| 2.00 4.00 6.00 8.00 10.00 12.00 " sets semen 334 seme Sse se uo 8 Erygen Research, 3058 Research Drive, State College, PA 16801 c"onor suA et To AoTECTE Or eves CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 Bp 3M MN01538829 11993377..00444433 II I I fl WS QQuuaannttiiT ftyy SSaaR mmppllee RReeRppNoo.rrttoatenaan, met.Date:03/18/04,Analyst. nisha rage 120 Page 120 CSSSauatnmmusppdllyaemoNioLLi.iiT=ssitLt:e.Id8:7B4,\uPD:sa\SDetwtaaat\rNaUo\U.L0H=5CS0ME2S11\3M8W1S006a47\sA1MsR0al,0sysm2leyE0\nx8Txt.l\DFualotureoo=rc0oh2ce/h1ne8im/ic0ca4al,lss.A.nPFaRRlOOy\\sSstam=mpKp1.laReDiDDsB\h\Oa0T2L1080044AARR CO CG ACH ACSFM u yvTMLLaaeaattrsshehtttoondmmmsn:ooaddiiitffiiioeeddd::: MTPue=en\DDaMFateatabra)\LL002C5EMS01N7M21=SS00607\K1:Ma40an50sesl1220y00ny44x\mFl\uoFrolchuemoicralos.PcPRRO0h\\NMaaeCtshhDDtRB\\CcCootltaGsrroo.vvee Mon Feb 02 07:04:42 2004 NPDES 17PDES 013108 012104 U pJorbinCcoedae: Tue dar oz 10:08132 2004 Printed: Tue Mar 02 14:05:22 2004 "- sNaammee:~ o220041-260 021804AR-260 ce Text= sultmaseres 4 4L|L:11C8876744--S11u77lfRRoeenppa,,teDDFFP==F11H0S0 0) . (c2126600S4mA(MRn, 2) 021804AR-260 Sm(Mn, 2x3) 1l1 "op !J " 22..0000 44..0000 u s5[1:c8Co788-sS1u7olfRnoosnpa,steDeFrP=Fr1O0oS s L1874-17 Rep, DF=10 Pf p0(r2e108g:024A1R28-266000 S4SmmA((MMRnn,, 223) 2x3) 1 O01% ` |% olsts8.81 19143~ 0022--MMaarr--22000044 0088::1188::0g LLCC//MMSS//MMSS #6 MRMof 5 Ghannol ES. MRM of 5 Channels ES59% >0 399 > 80 Tous 1.04e5 rea, Area 66..0000 88..0000 Time 1100..0000 | 1122..0000 s9ao.1or7s 19044~ 0022--MMaarr--22000044 0088::1188::09 MRMof MRM of 5 Channacis E05- LLCC//MMSS//MMSS #6 5 Channels ES- 49a9nr>ie9da9 9.81e4Area LUTTE am ek a 1000 2 - .... I .... I .... IT .... I .... TI .... I .... T~ .... , .... , .... , .... i TTiimmee 2.00 4.00 6.00 8.00 10.00 12.00 . " ` .ii Exroun Resescch, 3050 Resescch Drive, State Collage, 7A 16801 Emygen Research, 3058 Research Dr~ve, State College, PA 16801 . `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACOPPURRROOTT.TEECNCTOT.IIVV2EE7-OOCRR\-DD1EE0RR-2E6E3NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00444444 _Mo1s3ss30 3M MN01538830 II I i . 4 QQSuutaaunndttyiiffWyoy.:SSLaa1mm8pp7ll4ee, RReeSppeootrrttNo.:021004AR, Ext.Date:03/10/04, AnalyetiX.Risha PPaaggee 112211 Study No.:LI874, Set No.:021804AR, Ext.Date=02/18/04, Analyst=K.Risha TSSaaermmtppllmeeodLLiiiesstti=:ed:PrPT\u:De\aDtMaaat\raL\CL03HCSMMS1MS2S:E06\7\M:Ma0as0sssll2y0ym0nc4x\\FPiluuoorroocchheenmiiccaallss.PPRROO\\SSaammpplleeDDBB\\0O2Z1L8O0O4UAARR CCGO AACCSSTFHM 4 LmLMaeeasttsthhtooddBm::ooddii[lieedd:: HTPPiou:\ne\DDaMaetatbara\\LL00C22CHMSS10MM27SS=1E00674\\1:MM40aa30snssll22yy00n00n8x4x\\FFlluuoorroocchheenmiiccaallss..PFRROO\KMSeEtHhDDDB\\CCoottGGrroovvee NNPPDDEESS 001122110048 Sob" cod: Last modified: Job Code: Mon Feb 02 07:04:42 2004 ,4i rPriinnteed:= TTuuee MMaarr 0022 1144::0055::2222 22000044 4 NNTaaemmeen:: 0022110800442A2R--226611 Text: 1I.:CC66 hAecsidd pPrFmHAA u [LL11e877a4--t1e8,,DDFF==1100 |0o2a1r8e0044AaRr-226611 Ssmm ((Mvnn,, 226x03)) aa1( |RE ,i | 22.0000 a04.00 uo 22[::LCics8o7aAn1cci8di,0dPFeF=O1rA0 h1874-18, DF=10 002|211880044AARR-226611 Sm Sm (Mn, (Mn, 213) 2x3) 00 . L 3% | 1 a | %!11 Io 2.00 4.00 33::Cc4a sSuuiltfoonnaattee PpFrBeSs - frL1e87n4d-188,, DDFF==1100 [0oS221ta8600444ArR2-286115Smm (n, (Mn, 260) 2x3) . 1( 1 ] - *i a ol 250 400 2.00 4.00 66.0000 es_6.00 66.0000 2t58s.5e5020r 58.0000 E9e0.000 383645~ ; 8.00 13580.1165571 0022--MMaarr--22L00C00I44M00S88I::3M39S9::55!5 MMRRMM ooff 5LCCChhIaMann3nSn1ee/l0Mlss.SEE2S0S#8--6 31311>..0A082r8e68e696a Area oe 1000, .... 10.00 , , , 1200 ~, ,Time 12.00 0022--MMaarr--22L00C0044IM0088S::3I399M:#:5S5:5 MRM MRM of of 55LCCChh/aMamn44nSn1ae/3iMl12>ss>0S3E6E336S0S#696--96)) 2.0AAr6reeea6a) ee aeTime ( 10.00 12.00 _ 0022--MMaarr--22L000O044M00S88:M:339S9::55:1 MMRRMMooff 55LCCChh/aMannnSn2ee/lMlss5SEES>S#5.19-~ prod 299 > 99 4.8AAr6reeeaa5) 800 1000 120TT0iimmee| 8.00 10.00 12.00 a ESxxyyggeenn RReesseaaarrcchh,, 33005588 RReesseeaarrcchh DDrriivvee,, SSttaattee CCoolllleeggee,, PPAA 1166880011 . `CHEOGNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIJDJIEEASCCTLTTRTITCOOT AACPOPURRROOTT.TEECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR.2E6E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00444455 SUMNo1838831 3M MN01538831 u 4 gSQuuiaannattiiWfeeyy. SIsaaTmmppElle,e RReSepeproorrNtto.:021004A%, Ext.Date:02/19/04, RaalystK.Risha Page 122 Page 122 SLSSautavmum?ppdllymeeoNdoLLi.iiT:ssitLte::Id8:74,9eP:=s\\SDDeawtatetaNra\o\U.L0:K5C0SM2N1S1S3M8E1S0\064W0\Aa1MRs0a,e0slsyTlmEyehxn\txP.\iDFualotureo=or0co2hc/ah1se8im/ci0ac4la,sl.sA.nPPaRRlOOy\\sSStaz=mpKp1.laReiDDsBOh\\a0O2T1L80044AARR CCOG AACCSEFPM verMLSSLneaoaatosnnshtttnocdmmmo::oooddeddriiitffiiieeeddd=s= TwPeu=ne\DDaMTatoatabra\L0L052CEMS0N1M721S:06047\K1=Ma40as30sesil22y0y0o00nx44x\\FFlluuoorroocchheemmiciaclasl.s.PFRROO\\MNeetGhEDDBH\CCoottGGrroovvee Mon Feb 02 07=04:42 2004 NNFPDDEESS 001122110048 4 JvoebinCoedde= Tue wer 02 14:05:22 2008 Printed: Tue Mar 02 14:05=22 2004 mesNaammnee:= o2190033-261 021804AR-~61 4T:extc=o suitonate peu _ 4|:LCi6oTSeutlsf,oOnra=t1e0 PFHS L1874-18, DF=10 1 01 1 l022e11880044AARR-225611 SSmm ((Mtnn,,22:x03)) 0022:-MMaarr-22L00C004M40S08I8::M339S9::5#5565 28a.s8o0 LC/MS/MS #6 MofRChaM nnels 5.| MRM of 5 Channels ESepreed 399 > 80 Area 1.09e5 Area |* | 1 Time | .... ~ .... ~ .... ~ .... ~ .... ~ .... ~ .... 2~ 0.3.4..8~~ .... ~ ; ,-, , ~ .... ~Time ` 250 60 50 IY) 000 200 2.00 4.00 6.00 8.00 10.00 12.00 5. ca sulfonate sros _ 5:C8 Sulfonate PFOS . IILLl1887744--1188,, DDFF==1100 21804AR261Sm (Mn. 238) MoR f ChaM nnels 5. !021804AR-261 Sm (Mn, 2x3) . |I " 200a10 9T50v95e095s 100) 0022--MMaarr--22000044 0088::3399::555 LLCC//MMSS//MMSS #6 9.19 MRM of 5 Channels ES499 > 99 1.05e5 Area `|iL ako 50 50 1000 700 | o T ,,, ~ .... ~ .... ~ .... ~ .... ~ .... . .... , ..2.0.53, 7.~... , .... ~ .... ,TTiimmee 2.00 4.00 6.00 8.00 10.00 12.00 " " " Rxygen Ressarch, 3058 Rasonich Drive, State College, PA 16601 Exygen Research, 3058 Research Drive, State College, PA 16801 " `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACOPPURRROOTT.TEECNCTOT.IIVV2EE7-OOCRR\-DD1EE0RR-2E6E3NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00444466 m_morsasss2 3M MN01538832 fl WB GQuueasnsti~tyy sSaaemppilee sReeppoarTrte. catenan, mae.Dates02/10/04, Amaiystik.niene sage 123 Page 123 uaSLSSStaaeatsrmmutsppdellymmeeooNddoLDii.iiffss:iittL=ee:Idd8::74,TPT3uu::se\So\DeuaWMtataattakNraao\a\.L00L:32Cs0OM2S13U1M21eS8S:0S060047\1aA:Ma0R0a,p00sssssl220yE0ye05xn4atx.\FFDFLaloitureoo=ur<0o2hco/eh1enr8mi/ic0oca4al,lcssA.PPhnPRRaROOlOeN\y\SHsSmeatacm:mhiKppo.lsaRec\DiDCBsBaoAh\Osa0ZGi2Lr1Ao8a0v0Ae4A.ARNRPDCCEGOSAAC0CS1F3S1M04 ME TLeaatsthtoodmm=oadaitfciieeds= Non toh 05 Sr iorr is 008 P=\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\Me~hDB\CotGrove Men Feb 02 07:04:42 2004 NPDES 012104 Job Code: . PPrriinntteedd:= Tue Mar 02 14:05:22 2004 meme onsonsan Name= 021804AR-262 T3:extc=e acia ven I: C6 Acid PFHA - LL11887744--1199,, DDFF==110000 a" l0022o11860041AARR2-25622 5m Sm (4,(Mn, 20)2x3) || ,| | * ss8.50 sars4 0022--MMaarr--22000044 0099::0011::4477 LLCC//MMSS/IMMSS #6! MofR haM nno E5- MRM of 5 Channels ES- / Tose 31322.>.33222e6595 eaAreal | ,, ,, .... , .... , .... , .... , .... , ....53,79.4.~.. ,F .... , ..E .. , .... ,TTiinmee ` 2% Pr) oh oh oo 20 2.00 4.00 6.00 8.00 10.00 12.00 2. co noid orn 2: C8 Acid PFOA 221804aR.262 5m (vn, 2) PF |LL11887744--1199,, DDFF==110000 021804AR-262 Sm (Mn, 2x3) ' | 111 a |% ace8.98 66438 0022--MMaarr--22000044 0099::0011::4417 LLCC//MMSS//MMSS #6 MRM of Channels ES- MRM of 5 Channels ESpeed 413 > 369 347e5 ea 3.47e5Area bee tie 0-~,,,--~ .... , .... , .... ~ ......... , ........ , 6.6..4.38,~.... , .... , .... ,Time . 7% % o% a 00 20 2.00 4.00 6.00 8.00 10.00 12.00 3. cu suisonate seus 3:C4 Sulfonate ~FBS !1hL11887744--1199,, DDFF==1IO000 -- || c; 2%1606AR5.m20542, 20) 021804AR-262 Sm (Mn, 2x3) 0022--MMaarr--22000044 0099::0011::4417 LemsiMs LC/MS/MS #6 MRMof 5 GranneEl5s- MRM of 5 Channels ES- oir EE 8.17 299 > 99 sir HK 5.24e4 reaArea u | 0~ e25rr abs 2.00 4.00 abs 800 . Too 6.00 1~ 8.00 10.00 maoe 12.00 " Srygen Reseasch, 3058 Rasensch Drive, State College. PA 16801 Exygen Research, 3058 Research Drive, State College, PA 16801 `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NTSSTUYUBBIDJJIEAESCCTLTTRITTCOOT AACOPPURRROOTT.TEECNCTGT.IIVV2EE7-OOGRRu-DD1EE0RR.2E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00444477 au_norsases 3M MN01538833 " + qQSuuaaannyttiietfyy.sSEuaTmmppEilee,RReeSppeoorrNtto.1021004AR, Bxt.Date:02/10/04, Asalysti.nisha Page 126 Page 124 Study No.,LI874, Set No.=021804AR, Ext.Date:02/18/04, Analyst:K.Risha PR SLSaaasnmp?pllemeodLLiiifsstit:=ed: Last modified: TPTpuur:\ea\\bDDaWMaataacterrea\\\LLL003C2CaHMSS13nMM23SeS:1E006\77\HM1:Maa00as0s0ssssll22yy0y0mm00nee44x\\\FFFiiluuuooorrreooccchhhaeeaamiiicccaaalllsss...PPPRRROOO\\VSSNaAamEHppD11Rea\DDCBBo\\t0Oa2Zz11o88v00e44AAKRNPDCCEGOSAAC0CS1SF3FM104 SMLYoeaatsnshttocdomm:coaadt:itfieedd:: Mon Pan 03 07100143 2008 P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\MethDB\CotGrove Mon Feb 02 07=04:42 2004 NPDES 012104 4 pJroibntCeodd:e= Tue war 02 10:05:22 2004 Printed: Tue Mar 02 14:05:22 2004 a Nmsaammmea~ 0z1000AR-262 021804AR-262 Textz 4 44|: L:iCc86o7asS-uu1rl9tf,ooDnnFaa=tt1ee00PpFrHuSs h1874-19, DF=100 lw(021804AR.2S6m2 (Mn,263) Wo {| 021804AR-262 Sm (Mn, 2x3) ,| | 0022--MMaarr--22000044 0099::0011::4417 oa8r.r7as9 MRMof MRM of 5LLCCCChh//MaManSSnn3/e/0nMSlM9seaESSElv8SS#es0--6d 399 > 80 6734 real 3.32e4 Area a L0TT 5: co sultanate 2p.0r0os 4 [L871 DF=100 5:C8 Sulfonate PFOS L1874-19, DF=100 ,,i l021804AR.262 5m (Mn, 263) oo 021804AR-262 Sm (Mn, 2x3) ` %l1 a4.00 TTT6e.00o | a0 m Toe on eeTiz0T0im|e | _8.00 oo10.00 12.00 0022--MMaarr--22000044 0099::0011::4417 i99o.1177 MRMof MRM of 5 Chann0el9s>E9S-9 LLCC/IMMSS/IMMSS #6 5 Channels ES- 49297>20949 es 2.72e4 1 Area 200 00 600 800 1e 000 m200Timo , .... , .... , .... , .... , .... , .... , .... , .... , .... , .... , .... ,Time 2.00 4.00 6.00 8,00 493~i1L0.~ 00 12.00 r~ o ` Exygen Ressarch, 3050 Resossch Drive, State College, BA 16603 Exygen Research, 3058 Research Drive, State College, PA 16801 - `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACOPPURRROOTT,TEECNCTOT.IIVV2E7E-OOCVRR-DD1EE0RR28EE8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00444488 _MNO1S3B834 3M MN01538834 II " Ww QgSuutaaunndttyiisfKyoy..sSLaa3mm0pp7ll4ee, RReeSppaootrrttNo.:021004AR, Ext.Date:02/19/04, Analystik.Risha PPaaggee 112255 Study No.=LI874, Set No.=021804AR, Ext.Date:02/18/04, Analyst=K.Risha SLSeaamsmptpllmeeodLLiifssitte:=d: PTu=Pe\D:Ma\atraD\aL02CtMaS1M2\S:L067\C:M0aH0sSsl2M0yS0n4xS\\Flausorsolchyemmieca\lFs..lPPRuROOo\\SrSaaommppcllheeDDeBBm\\O0iZ2cL1O8a00l44AAaRR CCGG AACCSSFTMH a eMMLLLeeaaabttssshhtttoocddommm=:doooedddriiitffiiieeaddds== TPNFiuo=\en\DDaMaTtaatarba\\LL00C32CHMES10HM27SS~10066 74\\1=MK40aa30sasal22l0y0y00nm44xa\\l1uuoorroocchheenmiiccaallas..PPRROON\KMSeEtHhDDBB\\CCoottGGrroovvee Mon Feb 02 07=04:42 2004 NNPPDDEESS 001122110044 Job Code= Wo ePrxiintteedd:= Tuo Nar 02 14:05:22 2004 Tue Mar 02 14:05=22 2004 [INNaa=mmea=: 0022128000040A2R--226633 Text= iB:iCc6eArccidiaPwFHeAmn a [LL11887744--2200,, DDFF==1I000000 a ||021804AR-263 021804AR-263 Sm Sm (Mn, (Mn, 2x3) 2x3) AE| 1001 EaE8s.49 0202M-Maarr-22L00O0044MS00I99:M22S33:4411 MMRRMM ooff 5LCCChhIaMannnSne/elMlssSEESS-- | m0 pr 313 > 269 | 1.5`AA8rreeea5a | okO/o '~ ' ' ~ I-' ' ' 250' I-' ' '' I ' ' ' 50' I .... I ' ' ' 630' ]" ' ' ' ' I ' ' ' 8-50 1000 1200T"ime|| 2.00 4.00 6.00 8.00 10.00 12.00 22::Cc8o AAcciidd pPrFoOnA u L[1L8i87744-:2200,, DDFF==11000000 0022--MMaarr--22L00O00M44 S00I99::M22S33::4411 (00122011088,0044AARR2-2633 Sm Sm (Mn, (Mn, 263) 2x3) 89% MRMof MRM of 55LCCChh/aMannnSneIelM>lssS3EE0SS#-0-6 `T TMi 2288.959 8 413 > 369 1.r85e0a5 1.85e5 321 Area 4i Op rr eepee BernTie ~ TTT , .... 2.00 , am .... , , ~ 4.00 eo 500 .... , ....-~ .... , .... 6.00 8.00 , 1000 .... T .... 10.00 , 200 .... ~ Time 12.00 31::67Cc44u-2Ss0uul,lffDooFnnaa=tt1ee00Ps0FrBsS 02-Mar-2004 09:23:41 - L1874-20, DF=1000 |021804AR.263 5m (vn. 203) 0M2R-MMoafr-25LL0CCC0h/4aMMn0nSSe9IMl:M2sSS3E:S4#-16 " in021804AR-263 Sm (Mn, 2x3) e88.31l86 MRM of 5 Chann22e95l19s.>3>E45S900-94) || wf 1.3Ar4reeeaa41 w | ore eT Time ~ .... , .... , .... , .... , .... , .... , .... , .... ~ .... , . b 250 450 600 800 1000 1200 2.00 4.00 6.00 8.00 10.00 Time 12.00 . EExxyyggeenn RReesseeassrcchh,, 33005588 RReessseaarxcchh DDrriivvee,, SSttaattee CCoolllleeggee,, PPAA 1166800011 - `CHEOGNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIJDJIEAESCCTLTTRTITCOOT AACPOPURRROOTT.TEECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR.2E6E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00444499 SW_MNo1838835 3M MN01538835 - a P S QuanO tiE fy -- SaE mple -- ReHep.ortoateouan, mxt.Dater03/16/00, Amalyetix.nisha PPaaggee 112266 Study No.:LI874, Set No.:021804AR, Ext.Date:02/18/04, Analyst=K.Risha a eGLSSaaaacsnmmottppnllmeem:ooddLLiiiiftssiitte:e:dd::P:TPT7\eu:Dee\oaDaetMataatrara\\\LL0LC025CHeMS1nS1M3M2Ss1S:E006\77\Na1=Ma00ams00ssssll2Syyy0eom0n\sc4xP\\lPPuu1oourroorocochcheheeaamiiicccaaalllsss...PPPRRROOO\\\SNSatamhppOalBDe\DBCB\o\Ot0ZG21r1So80v04e4AANRREDCCSOGSAAC0CS1F2T1M04 MS TLeaatnshktoe dmm=eoddiitfiieodd:: wen Tob 05 07104143 304 P:\Data\LCMSMS6\Masslynx\~Zuorochemicals.PRO\MethDB\CotGrove Mon Feb 02 07:04=42 2004 NPDES 012104 0 nJonbcCeodae: ree war 02 20i05132 2004 Printed: Tue Mar 02 14:05:22 2004 a ,i eTNammeoer= o021n80s4ARe-2n63 Text= 4: ca sulfonate sis ~: C6 Sulfonate PFHS ,aI ![LL11887744--2200,, DDFF==11000000 021826034SmA(WRn, 20) 021804AR-263 Sm (Mn, 2x3) | "1 |oe1001 8886.4800d 4644~ 0022--MMaarr--22000044 0099::2233::4411 LoMSIMS LC/MS/MS #6 MRMof 6 Channol ES- MRM of 5 Channels ES- 29>00 24984 399 > 80 2.49e4 rea |Area or0r .... , .... , .... , .... , .... , .... , .... . .... , .... , ,e~ rm EN, ,~T'~iTimmee| . 200 3% 600 550 1000 7200 2.00 4.00 6.00 8.00 10.00 12.00 5. cs sultonaze pros : C8 Sulfonate PFOS " LL11887744--2200,, DDFF==11000000 (2160448263 Sm (Mn, 2:3) . | 100, 021804AR-263 7 Sm (Mn, 2x3) |i 2189.18 3420 0022--MMaarr--22000044 0099::2233::4411|1 LLCC//MMSS/IMMSS #6! MRMof Channels ES- MRM of 5 Channels ES- t >roa 4919.8>1e949|/ 4 | - | Or 200 abo S 660 T 860 100E 0 720 1(i/l 3429j~~ 1.81e4/Area/ 0~:7: ;T~ ~ ; ;7~ ;~ , .... , .... , .... , .... , .... ,,, :,,--~ ?-'7~-~ , .... , , , ,~Time 2.00 4.00 6.00 8.00 10.00 12.00 . " - i`ll Bxygon Resanrch, 3058 Research Drive, State College, TA 16801 Exygen Research, 3058 Research Drive, State College, PA 16801 - `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEEASCCTLTTRTITCOOT AACOPPURRROOTT.TEECNCTOT.IIVV2EE7-OOCRR\-DD1EE0RR-2E6E3NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00445500 _Motsassss 3M MN01538836 a Wl gQSuuteaunndetyiiNtoyy.isSLaaImmOppTllAee, RneSeepptoorrteNo.i021804AR, Bet.Date:02/18/04, Amalystik.Risha Page 127 Page 19-7 Study No.:LI874, Set No. :021804AR, Ext.Date=02/18/04, Analyst:K.Risha 4 aLLSSaaatassmmittppollnemem:ooddLLiiiiffssiitt=ee:dd=: BTPPTiuu=\\ee\DaDatWMateaaterxa\\\LLL00CC2C2HHMSES11HM23SSS=1EE060\7\7NN:1Maa00ass00ssssll221yyy00ma00nxx44x\\\FFFi1uuioorrouocchoheeamriiccaoallscs..PPFhRRROOOeV\\SNSnaamAppc1DleBeDa)DOBo\l\t00aZ2sr11Oo80.v04e4AARRN P CCOG DES AACCSFSM 017104 LoMLaeantsshttocdmma=ooead:tiefiieoda=: wen Feb 03 07108143 2004 P=\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\Metb-DB\CotGrove Mon Feb 02 07:04:42 2004 NPDES 012104 M JbomibmrCeosdse: ue var 02 10.0522 2004 Printed= Tue Mar 02 14:05:22 2004 [rp -- ,i rNTaeemxtee== 021804AR-264 a i1[::XCcC06s2n2A4ic0ia4d5,ePF5Hn0A0 nglL Standard ~XC022404-5, 500 ng/L Standard 1021804R264 Sm (Mn. 258) 021804AR-264 Sm (Mn, 2x3) a 100, | |= oo 127881.553001 0022--MMaarr--22L00o00M44 S009I9::M44S55::33 MRM ofLCChIaMnnSeIlMsSES#-6 MRM of 5 Chan33n11e336ls.>>6E262S6e695-9)| | 6A.6rA6ereeaa5l . [ 250 : 50 550 500 100 200Tim|e | 1 2.00 4.00 6.00 8.00 10.00 | Time 12.00 2: cs noid ron 2: C8 Acid PFOA 4 [XC0224045, 500 ngiL Standard 02-Mar-2004 09:45: XC022404-5, 500 ng/L Standard (21804AR 264 Sm (Mn, 2x3) 00 MRM of5LCChIaMn4nS1eI3lMs5SE3S6-9 a [1007 021804AR-264 Sm (Mn, 2x3) 00 `|| o] roa) ,,i % 1298.07062 128762] 02-Mar-2004 09:45:33 LC/MS/MS #6 MRM of 5 Channels ES- 4137.>1390659) 7.19e5 Area {| 1d - re Time .... ~ .... ~ .... ~ .... ~ .... ~ .... , .... ~ .... ~ .... ~ .... ~, ~ ,~, ~Time - 200 200 500 800 i050 200 2.00 4.00 6.00 8.00 10.00 12.00 3: c4 suionate prms 3:C4 Sulfonate PFBS XC022404-5, 500 ng/L Standard 02-Mar-2004 09:45:3 XC022404-5, 500 ng/L Standard - |021804aR 264 5m (tn. 258) MRMof 5LCohMaSnnMeSl:ES- 021804AR-264 Sm (Mn, 2x3) too, 0at2s T2=1A0r00e4a0] 1'" 02-Mar-2004 09:45:33 LCIMSlMS #6 8.15 MRM of 5 Channels ES299 > 99 2.18e4 Area ~ 7 |J -------- RT ! 0-' .... , .... , .... r .... ~ .... , .... , .... , .... , .... , .... , .... , .... ,Time . 200 400 600 800 1000 20 2.00 4.00 6.00 8.00 10.00 12.00 i.i Exrgen Research, 3058 Research Drive, State College, PA 16801 E~ygen Research, 3058 Research Drlve, State College, PA 16801 . `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIDJJIEAESCCTLTTRTITCOOT AACOPPURRROOTT,TEECNCTOT.IIVV2E7E-OOCVRR-DD1EE0RR28EE8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00445511 _MNO1S38837 3M MN01538837 . quantity sample report rage 28 Quantify Sample Report a SSttuuddyy NNoo..::LL1I8S7?44,, SSeett NNoo..::002211880044AARR,, EExxtt..DDaattee=:0022//1188//0044,, AAnnaallyysett:=KK..RRiisshhaa Page 128 Sample List. 31\Daca\UCHUSE\WassLyma\riPuROoNsSuoscp1haeDAnOi31c8l0a4A.R CO ACS Sample List: rp er Last modified: a Couiuaehaasiyat\FluorFoROc\NhACaKnDMiCcotadrlosv NEDES 013104 Method: Eon acto bone 65 error as Book Last modified: a Job Code: P:\Data\LCMSMS6\Masslynx\Fluorochemlcals.PRO\SampleDB\021804AR CG ACSFM Tue Mar 02 12:07:00 2004 P:\Da~a\LCMSMS6\Masslynx\Fluorochemicals.PRO\MethDB\CotGrove NPDES 012104 Mon Feb 02 07:04:42 2004 0 enmen ear 03 aeosia 00s Printed: Tue Mar 02 14:05:22 2004 P-- Name: 021804AR-264 f= Text: 41 co sutonace srs 4XX:CCC00622224S40u04l4-f-5o5,n, a55t00e00 PnnFggH/lShL SSttaannddaarrdd fJ|[ eotanuansnt sm an23 021804AR-264 Sm (Mn, 2x3) 3v%o . 8.79 20124-I 0022--MMaarr--22000044 0099::4455::3333 LCMSIM#S6 LC/MSIMS #6 MAMGSHmAsES MRM of 5 Channels ES- Soihn 399 > 80 1.07e5 eeArea `|| ol me| ,,,, .... , .... , .... , .... , .... , .... , .... , .... , .... ~ .... ~ .... ,Time 25 p17) oh 5 Toon 7 2.00 4.00 6.00 8.00 10.00 12.00 5. co suitonste pros 4 5X:C[C0X82C202S42u04l40f-4o5.n,5a,5t500e00 PnnFggO//SLL SSttaannddaarrdd c:21604AR.284 Sm (4, 2) MRMor ramets 5. 021804AR-264 Sm (Mn, 2x3) | I'El fors 5 Soeoan i| 9.17 15894-I 0022--MMaarr--22000044 0099::4455::33 LLCC/IMMSS//MMSS #6 MRM of 5 Channels ES499 > 99 8.59e4 Area a | \ Te , .... , .... , .... , .... , .... , .... , .... , .... ~ .... , , ,--, , , , , ,-",Time . 35 7) i% i We po 2.00 4.00 6.00 8.00 10.00 12.00 - ,a1i a Exygen Raseacch, 3038 Kaseucch Drive, State College, TA 16801 Exygen Research, 3058 Research Drive, State College, PA 16801 - CCHEOONNNNFEIDFPEIINNTDCIAOELU-NN- TSSTUYUIBBDJJIAEESCCTLTTRTITCOOT AAGPOPURRROOTT.TEECNCTOTIIVV2EE7-OO0RR1-DD1EE0RR.0E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00445522 Sw uorssesss 3M MN01538838  ---- A Quantify Sample Report BRIE revs, snsvnpia, mann Study No.:LI874, Set No.=021804AR, Ext.Date=02/18/04, Analyst=K.Risha Page 129 gots Tits BIT nss atmoR sSNEE OF HAF Sample List= Joe th, Du Last modiEied: i BE essai in anata OURS S404 Method: EL Last modified: was Job Code: P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\Samp1eDB\021804AR CG ACSFM Tue Mar 02 12:07:00 2004 P:\Data\LCMSMS6\Massllrnx\Fluorochemicals.PRO\MethDB\CotGrove NPDES 012104 Mon Feb 02 07:04=42 2004 J. Printed= Tue Mar 02 14=05=22 2004 J " TNTeaexmxtet=:= 021804AR-265 ---- So Co . IM:elotCht6haanAncoolildWWaPasFsHhhA 2160488.255 5m 4, 2) MRM of Cre6. It021804AR-265 Sm (Mn, 2x3) Be Foorueld 1001 88.5500 5128i 0022--MMaarr--22000044 1100::0077::1144. LCLICM/MSSI/MMSS##56 onze MRM of 5 Channels ES313 > 269 2.57e4 . em ,| (he \ %0t/-~~r-,R,,S, = O ...O. S~ .A..,.S ~ .... E ~ .... A ~ , ` 260 ao oto 5 ooo 2s 2.00 4.00 ~ Area , , ~ .... ~ .... ~ .... ~ .... ~ .... ~ .... ~Time 6.00 8.00 10.00 12,00 TET a 2M[M:eeCtth8haannAocolil dWWaPasFsOhhA 1 icztancar 255.5m in, 269) awnn RM ofS CrTaSemE5. 021804AR-265 Sm (Mn, 2x3) 8.98 2111-~ 0022--MMaarr--22000044 1100::0077::11.4 LLCC//MMSS//MMSS #6 MRM of 5 Channels ES413 > 369 1.74e4 | 3 = 1001 `_ | j TTR -- eeeaaeE a TTJIaw dpeaerpaeaA n] 2.00 4.00 SILI MMo:ettChh4aannSooulll fWWoanasasthhe PFBS - manasa in 20 MRMof CLormsmus5. 021804AR-265 Sm (Mn, 2x3) o fem w osreEfSi 100 om Sed age \ 1 32 | thRIAN EE am"R8828 WEVA %~_/x~ ~ .... 4.76 6.00 o.o, 8.00 10.00 12.00 0022--MMaarr--22000044 1100::0077::1144 LCIMSlMS #6 MRM of 5 Channels ES- 9.38 11 " 68~ 299 > 99 8.40 10.83 "~'~ ~J ~ v - ~ v 1.23e3 \ || LS1 --, | 0~ .... , .... , .... , .... , .... ~ .... , .... ~ .... , .... , .... , .... , .... ,Time . 7% 2 eho we Woo 2.00 4.00 6.00 8.00 10.00 12.00 a Sevens Resoeeiny 3008 Bapesess Brive, Suite Setieger 7a 2640S EA~gen Research, 3058 Research Drive, State College, PA 16801 . GCFOEONAFNNIEDFREINITCDIAOLUE-N-NTSSUYUTBBDJJIIEESCCATTTRITTC0OTAPACROPOURTROETTCENTCGIT.IVV2EE7OOGRuRnODiEEoRR26EE8NN0TT3EERREEDD IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00445533 swNo1s38539 3M MN01538839 ". Guneisy sample Report sage 130 Quantify Sample Report I Ee cnson, ee pater0a/10/04, Anaiyetir.nisha Study No.:LIS?4, Set No.:021804AR, Ext.Date:02/18/04, Analyst:K.Risha Page 130 Sumpie ishs | Bi\Daca\LCHINSOWasriyme\Fiuorochesieals. FRO\SArpIeDIGTLO04RR CG ACSTH Sample List: P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\SampleDB\021804AR CG ACSFM Ee meitian wes Se Tare on Tos . MMLeeattshhtooddm::odified: TPPu::e\\DMaDatraa\tL02aCM\S1LM2S:C60K7\:MS0a0HssSl26y00n\4xM\Falsuosrlocyhnemxi\caFlsl..uPPRRoOOr\\MMoeectthhhDDeBB\\mCCioottcGGarroolvvsee NNPPDDEESS 001122110044 Ee iaateieds ho ren Se sorts Tos Last modified: Men Feb 02 07:04:42 2004 Seat Job Code: a PPrriinntteedd:: TTuuee MMaarr 0022 1144::0055::2222 22000044 [A -- Name: 021804AR-265 ft Text: csontmers 4:C6 Sulfonate PFHS a MMeetthhaannooll WWaasshh as|002211880044AARR--226655 SSmm ((MMnn,, 22xx33)) 102sose J 0080 100! PR Y %~ 0/12 1185, 3995 60 0022--MMaarr--22000044 1100::0077::1144~ LLCC/IMMSS/IMMSS##66 MMRRMMooff 5CChhaannnneellss EESS-~ 11.68.~399 > 80 10-92~A /~ 2.47e3 ~o.~/~,J ~./ N R rnm d iy nsurers 4 0-1... , ....20, 0.... 2.00 , ....44..0,000.... , ....66..0,000.... , ....88..0~000.... , ....1100.., 000.0... , ....1122..,0T000ime sco stoners 4 [5MM:eeCtt8hhaannSouolll fWWoanaassthhe PFOS c21800AR265 Sm Mn,20) MEM of Chamne5l- 021804AR-265 Sm (Mn, 2x3) | Ju art rooris[| H 1/2E 008 100 0202--MMaarr--22000044110:00:07:71:1:4 LLCC//MMSSIIMMSS #6 MRM of 5 Channels ES499 > 99 9.11 10.1,5 2.01e3 [|I 0 mam an mre/AN WW Ll| 1.95 2.82 .9,2 J 35 We ae idm 2a | 0oI .... , .... , .... , .... , .... ~ .... ,S .... , ...t . , .. e ..s , .... ,TTimEe 2.00 4.00 6.00 8.00 10.00 12.00 a - ,.| |. Sargon Resoacen, 3058 Resaarch Drive, State College, PA 16003 Exygen Research, 3058 Research Drive, State College, PA 16801 CCH,eEOONNNNFEIDFPEIINNTDCIAOELU-NN- TSSTUYUIBBDJJIAEESCCTLTTRTITCOOT AAGPOPURRROOTT.TEECNCTOTIIVV2EE7 -OO0RR1-DD1EE0RR.0E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00445544 Sw umorssesso 3M MN01538840 . a J QSuaEntify Sampl-- e ReporNtecatsonn, xeoacerta/10/08, Ansiyssix Rina rage 122 Page 131 ovaSLLSSaaaattesmmurtppdllyeSmeeooNudoLLii.iitfs:siitLte:e:IdaS::?43,TTP.uu:\oae\SDuDeaMwtattaataasrNa\o\BL.bL0Ce:g2CH0MnI2SS1eE1iM2sE8sS:0\0064M)7\Aa:M0R0sa,00rssll3y20E0ym00xna4ktx\.\FFDFiialnutuooeorz:roo0osc2chh/hee1es8smi/ilc0cca4aa,lll.ssA.nPRRaROOlO\\y\NSsSSataCr:mhpKpDL.lSaRe\iDECsBaoh\Gk0aTG2Ar1Ao80v04e4AADRR ECCoGSAAC0C1S3FS1M08 rMLTeaaytsrhttodEm=eoadLitfiieeda=: Won Fb bi 67ers 200k P=\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\MetllD~\CotGrove Mon Feb 02 07:04=42 2004 NPDES 012104 pJoobimCoadse= mee var 03 2400s.22 2004 Printed= Tue Mar 02 14:05:22 2004 [-- - TNTeaexmxtet:== 021804AR-266 1: co nia orn So ILL:1188C7764a-A22c11id PFHA | |o2tsosag.2s5 sm vn, 2) MofR ChaM nnels 021804AR-268 Sm (Mn, 2x3) a 100, 88,5500, 77888844-~ 020-2M-Marar--22000044 1100::2288::5522 LLCC//MMSS//MMSS ##66 MRM of 5 Chan33n11e33ls>>2E26S69-9) 44..3388e44. || = 1001 | | | ot-- e Time| 0,,~, ,,~--, , ~-,,,,, .... i .... i .... ~ .... i .... i .... i .... i .... i .... i/Ime ` 2 abs 173 ab Wo 20 2.00 4.00 6.00 8.00 10.00 12,00 2. cs peta oron 2L:|1L8CE78T4a-A2zc1tid PFOA lc21904AR.265 5m vn 26) MofR haM nno ES- 021804AR-266 Sm (Mn, 2x3) | on sosios oarsed 1( 0022--MMaarr--22000044 1100::2288::5532 LLCC/IMMSS/IMMSS #6 9.00 MRM of 5 Channels ES413 > 369 wli I -,m ] ~~ ------e Areal 1.87e4 Area ee \ - TTT Ta2.00e T4a.00b eb6o.0l0 m8.o0o0 3. cu suitonase eras : C4 Sulfonate PFBS [Lrerazt Har2004 10:25 L1874-21 - |o21804aR-268 $m (Mn, 203) 021804AR-266 Sm (Mn, 2x3) . |TM; sop | 9 ar Be"8T5i0e0d 1( " wpN i VI 20 a8 seTMs sm sm ANY W | {080095 77.5555 paz '6 4.40 4. 5,78 6.80 t10o.o0o0 1i22.00T00ime gM5 Cramois 5. 02-Mar-2004 10:28:52 LLCC//MMSS//MMSS #6I MRM of 5 Channels ES- I 9.67 299 > 99 NL | 10.02 11.21 1.33e3 ~/~11.75 . 35 iho oh ato a wo TE -- 2.00 4.00 6.00 8.00 10.00 12.00 " Sxygen Research, 3038 Resaazch Drive, State College, PA 16002 Exygen Research, 3058 Research Drive, State College, PA 16801 `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NTSSTUYUBBIDJJIEAESCCTLTTRITTCOOT AACOPPURRROOTT.TEECNCTGT.IIVV2EE7-OOGRRu-DD1EE0RR.2E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00445555 awNotsssset 3M MN01538841 ,.m 0 QS quuaannttiiftyy sSaL ammppllee RReeppoorrttTeersten, xeDasero3/10/04, Analyatik.nione [ Page 132 a LSFSSaeeatsemmuttppdllyomeeobNdoLiLi.iitf=sshittLae:=Icd8:=74,TBFPu:.ue\\SaDeavtMacaatarrNa\o\CL.L00Co5=2CHE0MI2S1kSM12M1sS8:Soe0E06T4\7\iA:aMa0R0sab,00sess3S22lyy0F0yEm00nxe48txL\.\FDFiualutuoeoor:ro0ors2c/hh1aeo8nm/iic0cc4al,hlss.A.PePnPARaROGalO\Ay\SNsSiatamE=mpcHEpll.OaeRaDDiBCBs\lo\hOt0a2d2s11r88oG.0vA4eAARNRPDCCEOGSAAC0C1SS3FI1M04 = Ee heatcio Method: Last modified= kon re 65 ores Soon P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\MethDB\CotGrove Mon Feb 02 07:04:42 2004 NPDES 012104 Were Job Code= ,W ear 02 2405.22 2004 Printed: Tue Mar 02 14=05:22 2004 ome onsen Name= 021804AR-266 4: co suttonace sms Text= 4:C6 Sulfonate PFHS . Co2m1802466ASRm (4. 230) a LL11887744--2211 021804AR-266 Sm (Mn, 2x3) MRM of 5 harealos h5- 0022--MMaarr--22000044 1100::2288::5522 LLCC//MMSS//MMSS ##66 MRM of 5 Channels ES11.77. 10.62 ` - son \ ,i 0.14 9.17 9.71 EEJ ----------Y ------------ Time ` pn 0% 50 5 Woah 2.00 4.00 6.00 8.00 10.00 12.00 51 ca sutonate pros 5:C8 Sulfonate PFOS [wren C2Mar2004 107835 |t1874-21 o21004AR266 Sm (1,2) MRMof ChanonenElS.os a A021804AR-266 Sm (Mn, 2x3) 02-Mar-2004 10:28:52 LLCC//MMSS//MMSS #6 MRM of 5 Channe s ES- 900 Na IE 222 ole \ | 9.09j | ere | 1.1 ...~ ....~ .... , .... , .... , .... , .... , .... , ..... ~ .... , .... ,Time . 70 ib 55 555 oe 2.00 4.00 6.00 8.00 10.00 12.00 Pp Pp " a Berson Resaarch, 3050 Resaarch Drive, State College, PA 1603 Exygen Research, 3058 Research Drive, State College, PA 16801 . CCROEONNNFNIDFEEIRNTDCIAOELU-NN- TSSTUYUIBBDJJIAEESCCTLTTRITTCOOT AACPOPURRROOTT.TEECNCTOT.IIVV2EE7-OO0RR1-DD1EE0RR.2E8E9NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00445566 awmorsaase 3M MN01538842 . Gussity sample epost sage 133 Quantify Sample Report a BLA casonn, xe.oatersa/a0/06, Ansiysein.nisna Study No.:LI874, Set No.:021804AR, Ext.Date:02/18/04, Analyst:K.Risha Page 133 Sample Lists 3.\Daa\LOSE\Masaiynn\FiuoPRrOoNSsashpelesDBi\c02a18l0s4A.R CO ACS Sample List= oer Seiko es mas bg Taser on sven Last modified: Rn FeNT ---- Method: He mattieds mo ten SE ers ey Last modified= ma Job Code= P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\SampleDB\021804AR CG ACSFM Tue Mar 02 12:07:00 2004 P:\Data\LCMSMS6\Masslynx\Fluorochemlcals.PRO\MethDB\CotGrove NPDES 012104 Mon Feb 02 07:04:42 2004 Bb eines ve war 02 1405172 2008 Prin~ed= Tue Mar 02 14=05:22 2004 0 deme ons Name~ 021804AR-267 -- Text~ I: C6 Acid PFHA . [1LL1188774-222,, DDFF==1100 |002211880044AARR2-26677 SSmm ((MMnn,, 22xx33)) ' |i "| . 1 750 x 0~ 2.00 4.00 " 289.45004 29404i S-- LCIMSIMS #6 0022--MMaarr--22000044 1100::5500::2288 LC/MSIMS #6 MMRRMM #of55CChhaannngey sls Eo S- eepo 31311.>.441216ee9551! roheerah loosoling| 6.00 8.00 10.00 Area, 12.00 225:C1088 AEcEiEd, PPFOA cee ------------------------ a [LL11887744--2222,, DDFF==110000 0022--MMaarr--22000044 1100::5500::28 LOMSIMS LC/MS/MS #6 ca128570Sm4tan, 2) MofR5GraMne 5- 021804AR-267 Sm (Mn, 2x3) : a0 pa CI 28044 9.00 28344-~ MRM of 5 Channels ES- "16085 413 > 369 1.60e5 eaArea a | 1 sSSL ~ .... ~ .... ~ .... ~ .... ~ .... ~ .... , .... ~ : ;: . ~, ,,, ,',,, , ~,,~"~,,~Time - 25% i 55 5 fr fs 2.00 4.00 6.00 8.00 10.00 12.00 3. cu sulfonate pres 3:C4 Sulfonate PFBS . 1LL11887744--2222,, DDFF=--1I0O00 1002211880044AARR--226677 SSmm ((MMnn,, 22xx33)) 100~ | "J wwrr8.17 807~ 1 0022--MMaarr--22000044 1100::5500::2281 LLCC/IMMSS/lMMSS #6I MMRRMM ooff5 CChhaannnneellss EESS-- ( me 299 > 99/ Tres 4.12e3/ eaArea! . 356 Po) ob a oo He || o IA e A ee ee e an me e Ae Time | 2.00 4.00 6.00 8.00 10.00 12.00 ` Sxysen Research, 3050 Research Drive, State College, PA 16801 Exygen Research, 3058 Research Drive, State College, PA 16801 CCHEOONNNNFEIDFPEIINNTDCIAOELU-NN- TSSTUYUIBBDJJIAEESCCTLTTRTITCOOT AAGPOPURRROOTT.TEECNCTOTIIVV2EE7-OO0RR1-DD1EE0RR.0E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00445577 Sw umorssesss 3M MN01538843 III I . 4 QSQtuuuaadnnyttiiNffyyo.SsraaLmm6ppll7ee, RReSeapptoorrNtto.:021004AR, Ext.Date:02/18/04, AnalystiK.Rishs PPaaggee 113344 Study No. :L1874, Set No. :021804AR, Ext.Date,02/18/04, Analyst=K.Risha GSSaeanmmtppllmeeodLLiiifssitte.:d:PrTP\u:De\aDtNaaatr\aL\LC0C3HMSS1H2MS:SE66\7\a:Ms0as6slsyl2n0yx0n\4xP\l~ulouroroocchheexmiiccaallss..PPRROO\\SSaammppLleeDDEB\\O02211880044AARR CCGG AACCSFPM 4 MTLeLLeoaaattbssshtttnocdmmmoa:odooedddriiifffiiieeeddd::: NPTPoiu:n\e\DDaMTataatabra\\LL00C32CHMES01N7M2S1S,0066 47\\1,MN40aa30ssssll22y0y0n00n4c4x\\FFlluuoorroocchheenmiiccaallss..PPRROO\\MNeAtEhHDD~E\\CCoottGdrroovvee M~n Feb 02 07:04:42 2004 NI~FPDDEESS 001122110044 Job Code: d,i pranceas Printed= Tue Tue Maz Mar 02 02 1144::0055::2222 22000084 HrNaaezmxee::= 002~210800443A2R--226677 Text: 44::cCo6 sSuuiltfoonnaattee PprFiHsS SE a L[L11887744--2222,, DDFF==110000 C02-HMar-2L0O04MS1I0:M5S0:28 W10||0002211,880044AARR2-26677 SSmm ((MMnn,, 226x33)) o8a.7mw9 MMRRMM ooff 5LCCChhIaMan3nnSn3e9eI9lMlP9ss>aS>EEs8SSe#80-d-06)| I] `rea 2.43e4 Area ho | {olr i 432811 BB ___ ~ TIS ime|| " , 200 .... , .... 2.00 , 200 .... , .... 4.00 , 650 .... , .... 6.00 , 800 .... ,,, 8.00 1000 ~,-~, 10.00 ,, 200" ,~,Time 12.00 | 55::Cc8a Ssuullffoonnaattee 2PFrOoSs 4 [L11887744.-2222, 0DFF==110000 0022--MMaarr--22000044 1100::5500::2288 | Loma3s6 1I002211880044AARR2-26677 SSmm ((MMnn,, 226x33)) i] i a1 MRM MRM of of 55LGCChh/aMannnSniaeIi6Mlss9S>EES9S#.0-6| ae9s.1?7 49195>50949) ~ .95e4 Area) vo * | ---- { | ole rere rere -r~-,, ~-, ~ ,-~-~ , , rr a me | ;~ ,~--T'T~,~ , ~ .... ~ , , , "~TAimreea - L200 2.00 44.0000 660.000 808.000 3652~10100.000 1122.000 | Ill . -,il "iii " ESxxyygoeunn RReessseaarrcchh,, 33005588 RReesseeaarcchh DDrriivvee,, SSttaattee CCoollllaeggee,, PPAA 1166880011 . `CHEOGNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIJDJIEAESCCTLTTRTITCOOT AACPOPURRROOTT.TEECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR.2E6E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00445588 SW_MNo1S38844 3M MN01538844 . 4 QSQuuuaalnnyttiioftyy.rSSLaa6mm7ppll4ee, RReeSppeoobrrNtto.:021004AR, Ext.Date:02/18/04, Aaslystik.Risha PPaaggee 213355 Study No.=LIS?4, Set No.=021804AR, Ext.Date=02/18/04, Analyst=K.Risha SGSaaasmmtppllmeeodLLiiissftti:=ed: TPuP=e:\\DwDaaatrtaa\\L03LCCMH1SS3MH:S0S67S\:\M0aa0ssssl2l0yy0sn4xx\\FFl1uuoorroocchheesmiiccaallss..?PRRoO\\SSaasmpplleepDBs\\002311880044AARR CCGG AACCSSFIM 4 MLaLeaattsshhttmoodmoa:odditfhioedds: TNFPuo=ien\\DDMTaaaattbraa\\0L0L32CeMwS01NM72s1:S0066 47\\1a:M40as30sssl2120y000ny44x\mFlcuo\roFchlemuicoalos.cPPRRhOO\\eKMSemCtHhiDDEBc\\CCaootltGGarroo.vvee NNPPDDEESS 001122110044 Fob Code Last modified: Job Code= Mon Feb 02 07:04:42 2004 4 princess Printed: Tue Tue Maz Mar 02 02 1144::0055::2222 22000044 . N2 Neammae:= 002211800044A%R--226688 Text= iL:[iL1cC86e74nA2cc3i,tdaDFwP=FeH1sA000 L1874-23, DF=1000 |0218260854mA(MnR, 213) wo (|" 0120108,04AR-268 Sm (Mn, 2x3) |1 28880.525005 28825| 0022--MMaarr--22L000C044M11S11:M:112S2:1:110 MRMof MRM of 55LCCChh/Maan3nSne3leMll>sS2EE6SS#9-6- "ea, 13105) 313 > 269 1.31e5 Area Es || {| -~250 306 65 800 1000 1,2~,0TT0iimmee 2.00 4.00 6.00 8.00 10.00 12.00 Z2:iCc8enAcciiddwPFoOrA 4 [LL11887744--2233,, DDFF==11000000 0022--MMaarr--22L000O044M1S1aM:1S2n :10 (0218044R268 Sm (Mn 263) YO [1021804AR-268 Sm (Mn, 2x3) 89 MRM MRM of of 55LCCChh/aMannn1Sns3e/iMls>sSEE3SS8#.9-6)| it 8.98 15505 413 > 369 roa 1.55e5 ` |* | Area 29241~ i/l - |LOorrr 20 a r eo | bo r "doo "120T0ime 2.00 4.00 6.00 8.00 10.00 12.00 . | 4eee N . A p(3i1:c1C8e47s42Sw3u,]ofDomFnca=t1ee0v0P0FeBsS s =150128187044-A2R3,26D88F=$1m0(0M0n. 263) wojoan1 021804AR-268 Sm (Mn, 2x3) ass8.15 7737 ~ 0022--MMaarr--22L00C00I44M11S11I::1M122S::11(3 MMRRMMooff 55LCCChhIaMannnSn2ee/lM9tss6SEE-S3#S-69| 29339.66A>55r0e9e339a aL| S 200 r ato 6g 50 e ee8g 50 ene 1e 000rpeeoseTi || 2.00 4.00 6.00 8.00 10.00 12.D0 . EExxyygoeunn RReessseaarrcchh,, 33005588 RReesseeaarcchh DDrriivvee,, SSttaattee CCoollllaeggee,, PPAA 1166880011 `CHEOGNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIJDJIEEASCCTLTTRTITCOOT AACPOPURRROOTT.TEECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR.2E6E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00445599 SW_MNo1S38845 3M MN01538845 . vere seme mee vn Quantiy Sample Report Study No.:LI874, Set No.:021804AR, Ext.Date=02/18/04, Analyst=K.Risha Page 136 St. SEP MIeon e a s otEH 8 3 i Sample List= P:\Data\LCMSMS6\Masslynx\Fluorochemlcals.PR0\SampleDB\021804AR CG ACSFM 2 IL, HT ey Last modified= Tue Mar 02 12=07:00 2004 IE Method= P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\MethDB\CotGro~e NPDES 012104 E Fi E Last modified= Mon Feb 02 07:04:42 2004 Job Code: 1 PPrriinntteedd=: TTuuee MMaarr 0022 1144=:0055=:2222 22000044 P=Name= 021804AR-268 ,| Text= erstoeme 4:C6 Sulfonate PF~S a LL11887744--2233,, DDFF==110000 hargsensim 20 Wc Se 021804AR-268 Sm (Mn, 2x3) .| an ose | 8.79 a47m7e6~ 0022--MMaarr--22000044 1111::1122::1100 LLCC/IMMSS//MMSS##66 MRM (~f 5 Channels ES399 > 80! 22..55A44r8ee44a. Area . [oJle erE rr EE errs enn i 1'o/l '"' cr tte ce oo 4 [L1874:23,DF=1000 5:C8 Sulfonate PFOS h1874-23, DF=1000 fersmrnasnsmn 201 or crnsete "021804AR-268 Sm (Mn, 2x3) we | ,,,, ~,o- .oo-~, Time I 249.17 -~ 02:Mar-2004 11:12:1 02-Mar-2004 11:12:10 LLCC/lMMSS//MMSS #6 oied MRM of 5 Channels ES499 > 99 1.84e4 J Area Oiberg ere epee peer pr eI I .... , .... ,, ,~,, ,~~,, .... , ....---T,,,, .... , .... ",Time . | Err eee 2.00 4.00 6.00 8.00 10.00 12.00 . - " a Exygen Research, 3058 Research Drive, State College, PA 16801 COS .NFIDENTA IAL SUBJR ECTT0 API ROTECTIVETORDEERIsENTERED CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00446600 nse 3M MN01538846 ,.m @ GSQtuuuaadnnyttiiNffeyy.rSSLaaimmepp7ll4ee, RReeSppeootrrtNto.:021804AR, Ext.Date:02/19/04, AnalystiK.Risha PPaaggee 113377 Study No.:LI874, Set No.=021804AR, Ext.Date=02/18/04, Analyst=K.Risha SLSeaamsmptpllmeeodLLiiifssitt::ed: PTiu:\e\DDaaMtetara\\LL02CCMHS1SM2NS:S60\\7K:Ma0as0sssll2yy0m0ne4x\\FFlluuoorroocchheeamiiccaallss.PPRROO\\SSaamzpplleeDDB\\00Z2L1O80044AARR CCGG AACCSSFTM 4 mMLLeaeatssthtteoddmm::ooddiitfiieedd=: TPPKou:ne\1DMaFaet\bra\DL002C2MaS01M72S::t06047\N:a=Ma40as20s\ssll22yy00Lm0n0x48x\C\FFlluHuoorrSoocchNheenmiSiccalaSal.s.PPRROO\\NMAeEtRhDDBB\\CCoottGGrroovvea NNEPDDEESS 001122110044 ab coder Last modified: Job Code: MOn Feb 02 07=04:42 2004 0 ePriinnetend:: TTuuee aMaxr 0022 1144::0055::2322 22000044 oNNaaammae:= 002211800044A2R8--226695 Text= 1 il :[(CX6Ce 02A2c4i0c d46,PF1Hs 0A00 nh giL c Standiardapmm XC022404-6, 1000 ng/L Standard I Ey 002211880044AARR-228699 SSmm ((MMnn,, 2)2x3) wo [00 o8.s5t1 ||| | | re 0022--MMaarr--22L00C00/44M11S11/::M33S33::#5544 MRM MRM of of 5LCCChh/aM ann3nSn1e3/elMlssS2EES68#-0-6 313 > 269 1.27e6 rea|( Area ` | ~ ,,,, ....20, 0.... , ....40, 0.... , ....60, 0.... , 500 ...2.33, 6.0.5.~. , ....10,00.... , ....Zo,ToTiimeme|| 2.00 4.00 6.00 8.00 10.00 12.00 4 m:[XoCC802s2A4c0ih4d-6i,PF1O0dA00wnrg Standard XC022404-6, 1000 nglL Standard |0o2z1188004A4RR-226699 5Smm ((Mann,, 226x03)) , 00 1 I 1 %%]1 " 2390.0000 0022--MMaarr--22L00O0044MS111I1::M33S33::54 MRM of 5LCCh/aMnnSa/lMsSES#-6 MRM of 5 Channels ES- mE1.2206) 413 > 369 1.22e6 [Area | |0 e L200 2.00 404.000 33::CC44suSulltfoonnaactee pPrFeBsS - [XxCC002222440044--66,, 11000000 nngLlL SSttaannddaarrdd {1002010280148A0R-426A9R$S.mm2(6(MM9nn,, 23) 2x3) - | bs - 10~ 660.000 800223900~ 8.00 1100.0000 Time 11220.000 788.311555 I 9735~ 0022--MMaarr--22L00o00m44s11i11::m333S3::5~1 MMRRMMooff 55LCCChh/aManmSno2e/i0Ml6ssS>EESS#0-6-0 29559.00AA>66rr0eee94aa49]| | . 200 ry 600 500 1000 200 | | Time| U/il'~ '"' I .... I .... I ....-[ .... l .... I ' ' ' ' I '--' ' ' =' ' ' I ' ' ' ' I ' ' ' ' I .... i Time 2.00 4.00 6.00 8.00 10.00 12.00 . Exygen Resessch, 3058 Research Drive, State College, PA 16801 Exygen Research, 3058 Research Drive, State College, PA 16801 . `CHEOGNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIJDJIEAESCCTLTTRTITCOOT AACPOPURRROOTT.TEECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR.2E6E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00446611 SW_MNO1838847 3M MN01538847 . @ QqSutuauandntytiiNffoyy.1Ss5aa1mm6pp7ll4ee, RReeSppeootrrttNo.:021004AR, Ext Date:02/19/04, Amalystik.Risha Page 138 Page 138 Study No.=LI874, Set No.:021804AR, Ext.Date:02/18/04, Analyst:K.Risha SLSaaamsmptpllemeodLLiiifsstit::ed: PTuP:e:\\DDaNaattraa\\L0L2CCMHS1SM2HS:S60E\7\:MK0aa0ssssl2l0yy0nn4xx\\FPlluuoorroocchheemmiiccaallss..PPRROO\\SSaamEpplLeeDDBB\AOO2Z11860044AARR CCGG AACCSSTFHM 4 eLaMLLaeaatbstssnthttocadommm:=doooedddriiifffiiieeeddd::= HTPPeu:rne\\DMaFDaetbraa\tL0032eCM\S01LM72S1=C0604H7\1:MS40a30NssIl22\y0000nK44xa\Fslsuolryocnhxem\iFcailus.oPPrRROOo\\cMNeShtCDehDnBB\i\CCcooattGalrrsoovv.ee INTPPDDEESS Mon Feb 02 07:04:42 2004 001122110048 Job Code: f ePrriinntceeda:r TTuuee MMaarr 0022 1144=:0055::2222 23000044 Nnraaemmxee.=: 002211800046ARR--226659 Text= a [44:(:XcCC660s2S2uu4ll0f4ot,noa1tn0e0a0pPtFrnHegsSiL Standard EE 02-Mar-2004 11:33: XC022404-6, 1000 ng/L Standard LCMSIMS 02-Mar-2004 11:33:54 LC/MS/MS #6 01| 0220118080044aARR.-225699 5Smm ((Mhnn,, 22xx33)) w28.n800 MMRRMM ooff 5 CChhaannnn3e8e9l2l99ss2>0>EE08SS85-0-0]) | eal [I I 40720~ || 2.20e5~rea . ol 200 .... I .... r ry .... , .... i 600. .... i .... , 500 .... , .... =... 1000 '., .... , ....i2,0TT0im ime|e 2.00 4.00 6.00 8.00 10.00 12.00 55::Cc88 Ssuullffoonnaattee PpFrOoSs X[CX0C02222440044--65,,11000000 nnggllLL SSttaannddaarrdd 0022--MMaarr--22000044 1111::3333::54 | LLCCI/MMSSI/MMSS #6 5|002211880044AARR-225699 SSmm ((MMnn., 221x33)) 0 MMRRMMooff 5 CChhaannnn9eel9lss5EE9SS-9- +] 090.1475 4919.o5>7w9095s a %7 1.57e5Area | - . 250 ao em 800 1000 200Time| 2.00 4.00 6.00 30045~ 8.00 10.00 12.00 - a Exygen Research, 3058 Reseach Drive, State College, PA 16801 Exygen Research, 3058 Research Drive, State College, PA 16801 a `CHEOGNNONFEINDPEIFNNITCIDAOLEU-N-NSTSUTUYBBIJDJIEEASCCTLTTRTITCOOT AACPOPURRROOTT.TEECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR.2E6E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00446622 SW_MNo1838848 3M MN01538848 MMeettaallss FFIINNAALL RREEPPOORRTT EEVVEENNTT 11 EE0044--00112200 FFeebbrruuaarryy 1122,, 22000044 CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 1937.0463 3M MN01538849 North Shore Analytical, Inc. WMODNLLEub 0329701157713880 Du56k12aMi0lesTS58u1 g, Sate 1. FPaie18@)18)75294-549658 Analytical Report tens I`AMunC:oTotmeaGlroovse C1o0t7a4genGroovvae,tMioNRdn.$5B0l1d6g 145 PFhaoneG11..44585285.92600 Fax: 651-458-2596 Date Repone: 224108 Date Repo~ed: 2/24/04 Sample nformadon: ClaSnaampCluesdtB:y: WM0A70M TMG Method: BPA 1631 Swen T3h Laborato~- Vhles Mercury Swit Sowers MEcDoruL PhaFseIdEfalekene 3s0o1u9 <Zooss vvioan vvaamm o0r Lolo rsy ols ar rvgen Henk sorte 4 ls ou ave any guetons garding i part,las call 213) 29-4658. If yo~ ~ave ar~y ques~iors r lag {his repo~ please eai! {2 ] g~ 729~465g Sicerey, SCoohJes t7 le ---- Lint Christnsen Chemical Engineer `CHEOCNNONFEINDPEIFNNITCIDAOLEU-N-NTSSTUYUBBIDJJIAEESCCTLTTRITTCOOT AACOPPURRROOTTT.EECNCTGT.IIVV2EE7-OOGRRu-DD1EE0RR.2E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00446644 au_Notsaseso 3M MN01538850 North Shore Analytical, Inc. VDOiNLLba0235-93017731580 S6D1u2,MilaeNr TS8k11iw Sie1 FFarroin2)1094260ss Analytical Report Glens: 3AMCoTtoamsBGariotvse C10o7t4a6snoGrvoavtei,oMnNRa.55B0l1y8. 145 Colt~e Grr~veo MN 5~016 PFhoxan:6561541.548528.529032 ~:~51458-259g simpen er FEdeblnk 8001476 Dut Reported: 22404 Sample formations CliSfaGpulteyd. 3N7A0M TMG ~ "MG Mero: EPA 163) -- Swvetuy Awe To 0s aobaa mwmaamwer 0o1l tomiomimery rent erage tin sreed Reviewed By: (He J 17300 have anyquesions gain is por laocall 18) 29-4658. sie Sincerely. ole 7 CF Ce CLiinr~tdeeamCiahrrBrisoitneee~nnr CCHEOONNNNFEIDFPEIINNTDCIAOELU-NN- TSSTUYUIBBDJJIAEESCCTLTTRTITCOOT AAGPOPRUROROTTT.EECNCTOTIIVV2EE7-OO0RR1-DD1EE0RR.0E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00446655 su umotsssst 3M MN01538851 SDriltsabtorsseipsom n Handi vis Tren js > Chain of Custod aamt:i Frmeemnmime TEww = H Cougecae WN sors Ps = omes| LFoana] weTeT] compaerny R| pctsT[ecot]setee]| 1 EeTPotT]osveeesy) So Ea RO Ga --L_ T Te rT-x---------- ---------- {FBeETT eesn pterooroe[e 0 R [0emueTmol t TTNTT etree. toc lo 1 -T--2--t ec mmo) | PJye ET SEeEEr t TIOANT TT SFRSNE) FS EES rEE n r EA,e SPU ASS)e ES SSPe OTFE e WR" e VV y 1] Voce!7 Taullogyy | Da|Toe1 Jegemm | Ow | Gee| Com J} Uv Cl Per Reo Tle ly100 Loner 1 Ee LIT rera ee attsstg eem etTee Fre StE=e SeeFTE] [FeCT TomLA iatseSmep==.tFo m0 S e1,r7a STsPCReoIre:SRSIA=rT3ES.TE TetE eSeIITmal SRrOAS Sl FRO7 pte sme BE CSOTNRFIICDTENCTOIUALRT:SUNOB.JE3C7T.T1O0A.2P6R63OTECTORIDVEER ENTINHEENNERPINECOUDNTY DISTRICT COURT, NO. 27-CV-10-28862 BER | w_norsssssz 11993377..00446666 MRMeeestuthhlootd:d::CW WGWWWTTWPPTSSPccaaCnnarbon Study Event 1 E04.0120 Result: CG WWTP Carbon Study Event 1 E04-0120 sh 20636 pe 4k cCaailiibp hs 188.979 As 188.979 4k cps)em (cps) ~~ (cps)em (cps) o 0~).000Calib Eqn: Lincc,oonCnaccl(lmcmggn/tlL)) 100 00.000Calib Eqn: Lincc,oonCncca((cmmgan/tiL)) 001.0( ' ore Coeff: Calib Eq'n: Corr Coeff: 0.386360 Li~, Ca~ 0o999369 lnt 2 ore Coeff: Calib Eq'n: Corr Coeff: 0.389258 Li~, Catc 0o99258 lnt Ba 3Ta07 Comasis El 3M -- 5st1kk ~ ps)em (cps) > ps)em (cps) > 0l).000Calib Eqn: Lincc,oonnCcacll(mmcggnl/LtL)) 100 00.000Calib Eqn: Lincc,oonCncca((cmmgan/tiL)) 101.0( 3 Corr Coeff 0.388716 Calib Eq'n: Li~% ~lc Corr Coeff: ~o99871 ~ 4 Cor Goer: 0.356705 Calib Eq'n: Li~% Calc ~nt Corr Coeff: 0o~9870~ c3 arn Ceara s2 Pp ook 52k 66k coepm ms) ~ epemm s) (cps) (cps) o0.o0oCalib Eqn: Licnco,onnCcac(l(mmcagnl/tLL)) 5 Corr Coeff 0.958540 Calib Eq'n: Li~l, CaIc Corr Coeff: 11.000~ . 00.000Calib Eqn: Licnco,onnCcca((mcmggIln/LtL)) CCoarlribCEoeqf'nf: L0#.~9,5C86a3lc5 Corr Coeff: PPaaggee 11 `CHGEOONNNNFFEIIDPDEIENNNTTCIIAOALLUN-- TSSUUYBBDJJIEESCCTTTRITTCOOT AACOPPURRROOTT.TEECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR.2E6E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00446677 11.000( WWiinnLkaabb3z2 SW_MNo1S38853 3M MN01538853 Method: WWTP Scan Result: Method: Result: GG WWTP Carbon WWTP Scan CG WWTP Carbon SSttuuddyy EEvveenntt 11 EE0044.-00112200 Niz31.608 400kk cCaalliibb Pb 220353 Pb 220.353 212k (c(ceppmss)) - (cps)em (cps) " 0~)0.000Calib Eqn: Lincc,oonnCcac(l(mmcggiInL/tL)) 7 CCCooarlrrirbCCoEoeqef'fnff;:: 0L0o.i~~9,99C8865a88lc00 lr~t 6196.02 x3k 1001.01~ 00.0000Calib Eqn: Lincc,oonCnaccl(m(cmgIng/tL)) GCoarlibCoEeqf'fn:: L0.in9,98C8a2t1c Zs6n2i38s7 Corr Coeff: 0998821 Zn 213.857 2 8Bo9kk (c(ceppmss)) or ((cceppmss)) > 0I).0000Galib Eqn: Lincc,oonnCcac(l(mmcggiInL/tL)) GCoarlibCoEeqf'fn:: L0i.~%99C95a4ic5 5 Corr Coeff: 0.999543 11.0010~ 10 10 00.0000Galib Eqn: Lincc,oonnCaccl((mcmggILn/tL)) GCoarlibCoEeqf'fn:: L0i.~%99C85a5lc0 ~nt Corr Coeff: 0.998650 7 100 1.0( _ 100 1.0( PPaaggee 22 `CHCEOONNNNFFEIIDPDEIENNNTTCIIAOALLUN-- STSUUYBBDJJIEESCCTTTRITTCOOT AACOPPURRROOTT,TEECNCTOT,IIVV2EE7-OOCRRV-DD1EE0RR.2E8E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00446688 WWiinnLLaabb33z2 3M_MNO1538854 3M MN01538854 n Sample ID 0.4ppm ~ Sample Name Date EOTime PdInitial Sample vel Wt 212012004 9:42:23 AM 2/20/2004 9:42:23 AM 2/20/2004 9:42:23 AM 2/20/2";004 9:42:23 AM 2/20/2004 9:42:23 AM 2/20/'~004 9:42:23 AM 2/20/2004 9:42:23 AM 2/20/~004 9:42:23 AM 2/20/2~004 9:42:23 AM 2/20/2004 9:42:23 AM EsE rs MDL Analyte Name Reported Conc (Calib] Calib Units Sb 206 838 0 382 mg(L As 188.979 0375 mg/L Be 313.107 0369 mg/L Co 228.616 0.35 mgtL Cd 228.802 0356 mg/L Cr267.716 0361 mgtL Ni 231604 0385 mg/L Pb 220.353 0.33 mgtL Se 196.028 0357 mgtL Zn 213.857 0342 rn~tL sons Reported Conc Samp (Samp) Units 0 382 mg/L 0.375 mg/L 0.369 mg/L 035 mg/L 0.356 mg/L 0.361 mg/L 0.385 mg/L 033 mg/L 0.357 mg/L 0.342 ms/L 1 QC Recovery 95 56 93.77 82.14 87.51 89.00 90.35 96.35 82.52 89.30 85.5 CCHOEONNNFNFIEIDDPEEINNNTTCIIAAOLLUN-- TSSUUYBBDJJIEESCCTTTRITTCOOT AACOPPURRROOTTT,EECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR-2E8E8NN6TT2EERREEDD INN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00446699 33MM_MMNNO011553388885555 & Sample ID VlP-04-163 rs VlP 04 164 V~P 04 165 V]P-04-166 ee rIP-04-166 MS er V1P-04-177 be VlP-04-167 bw V1P 04 168 bm V1P-04-169 ---- Sample Name Field Blank rm Field BlankDup Influent 1/2 Influent 1 / 2 Dup ne Influent 1 / 2 Dup weLab Blank Port 1A neon Port 1ADup eaPort 4A " me Initial i Pt nm Ew = Sample Reported Reported Conc Calib Conc Samp QC Date Time Wt MDL Analyte Name (Calib} Units (Samp) Units Recovery 2/20/~004 9:46:22 AM 1 004 Sb 206 836 -O 034 mg(L ND mg/kg 2/20/2004 9:46:22AM 1.0041iiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiAs 188.79 -0019 mg/L ND mg/kg 2/20/2004 9:46:22 AM 1.004 i!!!i!i!i!i!!i!i!i!i!!i!i!i!ii!i!i!i!i!i!i!i!!i!i! Be 313.107 -0.02 mg(L ND mg/kg 2/20/';004 9:46:22AM 1.0041iiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiCo 228.616 -0018 mgtL ND mg/kg -0018 mg/L ND mg/kg 2/20/:004 9:46:22AM .004i:::i:i:i:i::i:i:i:i::i:i:i:iii:i:i:ii:!i:i:i!:i::i:i:Cr261.716 -0017 mgtL ND mg/kg 2/20/2004 9:46:22AM 0.01 mg/L ND mg/kg 2/20/~004 9:46:22AM 1.004~Pb220.353 -0013 mgtL ND mg/kg 2/20/~004 9:46:22AM 1.004~Se 196.026 -0011 mgtL ND mg/kg 2/20/~004 9:46:22 AM 1.004 Zn 213.~57 -0.02 m~tL ND m~/k~ 2/20/2004 212013004 BEBE OE SNE 2/20/2004 EERIE GER 2/20/~004 9:50:14 AM 9:50:14AM 9:50:14AM 9:50:14AM 1.034 ~ Sb 206.836 1.034;~As 188.79 1.034~Be313.107 1 034~Co ~28 616 -0039 mg(L ND 0023 mgtL ND OB 2 3 -0.02 mgfL ND -0 018 mgtL ND SBIR O2 3 -0019 mg/L ND mg/kg mg/kg mg/kg mg/kg mg/kg -0017 mgtL ND mg/kg 2/20/2004 9:50:14AM 1.034~Ni2316,34 -0009 mgtL ND mg/kg 2/20/2004 9:50:14AM -0014 mgtL ND mg/kg -0015 mg/L ND mg/kg -0021 m~tL ND m~/k~ -0045 mg(L ND mg/kg -0019 mgtL ND mg/kg -0.02 mg/L ND mg/kg 2/2~/~00d 9:5d:08 AM ].0] S ~ Co 228.616 -0018 mgtL ND mg/kg 0019 mg/L ND mg/kg 2/2~/200~ 9:5~:08A~ .0~Cr267.7~6 -0017 mgtL ND mg/kg -0 009 mglL ND mg/kg 2/20/~004 9:54:08AM 1.016~Pb220.353 -0013 mgtL ND mg/kg 2/20/2004 9:54:08AM 1.016~Se 196.026 -0011 mg/L ND mg/kg LEE 2/20/~004 9:58:01 AM 1 034 :~:~:~:~:~:~:~:~:~i:~:~:~:~: :~:~:~: ~i:~:~:i~:~:~:~ As 188 979 EERE] -0018 m~tL ND -0058 mg/L ND -0 02 mg(L ND -0.02 mgtL ND m~/k~ mg/kg mg/kg mg/kg 2/20/2004 9:58:01 AM 1 034~Co228 616 -O 017 mgtL ND mg/kg -0019 mgtL ND mg/kg ESE SEER 2/20/2004 2/20/2004 2/20/~004 2~0/2004 9:58:01 AM 9:58:01 AM 9:58:01 AM 9:58:01 AM 034~Cr267716 1.034~Ni2316,~4 1 034~]~]~]~]~]~]~]~]~]~]~]~]~]~]]~]~]~]~]~]~]~]~]~]~]~]~ Pb220 353 1.034~8e 196.026 -0 017 mglL ND -0008 mg/L ND 0 013 mgtL ND -0018 mg(L ND mg/kg mg/kg mg/kg mg/kg 2/20/3004 2/20/2004 2/20/~004 EEEEEFE BE 2/20/2004 BE BEE EB BEE 2/20/2004 2/20/2004 2/20/2004 ESE EET 2/20/2004 BATE IE 2/20/3004 9:58:01 AM 10:01:55 AM 10:01:55AM 10:01:55 AM 10:01:55 AM 10:01:55 AM 10:01:55 AM 10:01:55 AM 10:01:55 AM 1 034 ~ Zn 213 S57 1.034 Sb 206.830 1 034 As 188 979 1.034 Be 313.107 1 034 Co228 616 1 034 1 034 1.93 Cd228 802 Cr 267 716 1.034 Ni231604 1 034 Pb220 353 -0 02 0918 0 889 EBRE F ER nOE, B 0821 BR AW Eh 0738 0747 0 828 BE HE a 1 0972 EE AEE 1 199 m~tL mg/L mgtL mgtL mglL mg~L mg/L mgtL mgtL ND m~/kg 4437 mg/kg 42 98 mg/kg 39.7 mg/kg 35 68 mg/kg 36 13 mg/kg 40 Q5 mg/kg 47 mg/kg 58 mg/kg Se low recovery; 100 ppm std ok, appears to be sample matrix 92% 89% 82% 74% 75% 83% 97% 120% 2/20/2004 10:01:55 AM 1.034 8e 196.026 0585 mg/L 2831 mg/kg problem 59% 2/20/~004 2/20/2004 10:01:55AM 10:05:54AM EEmoin Hs 23: 2 2/20/~004 oR mE ony ROR 2/20/2004 DES BRCET ZX FE EF 2/20/2004 2/20/~004 EEEmSi OpR ee HRI ZB 2/20/2004 Com my OR 2/20/~004 2/20/2004 gE oR Es an 2/20/2004 Hl -inetis--1% 2/20/~004 10:05:54AM 10:05:54AM 10:05:54 AM 10:05:54 AM 10:05:54AM 10:05:54 AM 10:05:54AM 10:05:54 AM 10:09:51 AM 1 034 Zn213 857 1.32~Sb206.836 1.32~Be313.107 1 32~Co 228 616 1.32~ Ni 231604 1 32 :~:~:~:~:~:~:~:~:~i:~:~:~:~::~:~:~:~i:~:~:i~:~:~:~ Pb 220 353 1.32~]~]~]~]~]~]~]~]~]~]~]~]~]~]]]~]~]~]]~]~]~]~]~]~]~]~]~Se 196.026 1.32 ~ Zn 213.857 1.08~86206.836 BEBEElEoDyInE BBT.EhcCmEEtaRrEs SEHE3ZYN:EEEDBB% 2/20/~004 2/20/2004 EEL INE: Brin 2/20/2004 10:09:51 AM 10:09:51 AM 10:09:51 AM 1.08~ ~Cr267.716 1.06~]~]~]~]~]~]~]~]~]~]~]~]~]~]]~]~]~]~]~]~]~]~]~]~]~]~ Ni 231604 1.08~Pb220.353 1 357 0.06 -0 021 -0.02 -0 017 -0019 0018 -0008 -0 012 -0021 -0021 -0076 -0.02 -0.02 -0018 -0018 -0018 -0009 -0013 mg([ mgtL mglL mgtL mglL mg/L mgtL mg/L mgtL mg/L mgtL mgtL mg/L mg/L mgtL mg(L mgtL mg/L mgtL 65 62 mg/kg ND mg/kg ND mg/kg ND mg/kg ND mg/kg ND mg/kg ND mg/kg ND mg(kg ND mg/kg ND mg/kg ND mg/kg ND mg/kg ND mg/kg ND mg/kg ND mg/kg ND mg/kg ND mg/kg ND mg/kg ND mg/kg 136% 2/20/2004 10:09:51 AM 1.08~]~]~]~]~]~]~]~]~]~]~]~]]]~]~]~]]~]~]~]~]~]~]~Se 196.02 0011 mg/L ND mg/kg 2/20/2004 10:09:51 AM 2/20/2004 2/20/2004 ERG 2/20/2004 2/20/~004 10:13:47AM 10:13:47 AM 10:13:47AM 10:13:47 AM EEEEEEiEGy 2/20/~004 10:13:47 AM EEA 2/20/2004 2/20/2004 2/20/~004 2/20/2004 10:13:47AM 10:13:47AM 10:13:47AM 10:13:47 AM 1.08 ~ Zn 213.857 1 02~]~]~]~]~]~]~]~]~]~]~]~]~]~]]]~]~]~]]~]~]~]~]~]~]~]~]~Sb206 836 OB mE 1.02~Be313.107 1.02 ] ~ ~ ~ Co 228.616 OSZReo , GBEEE 1 02 ~::~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~: Cr26/716 OB mR 1.02~]~]~]~]~]~]~]~]~]~]~]~]~]~]]~]~]~]~]~]~]~]~]~]~]~]~ Ni 231604 1.02~ Pb220.353 1.02~Se 196.02~ 1.02 ~::~:~:~:~:~:~:~:~:i~:~:~:~:~:~:~:~:i~:~:~i:~:~:~:Zn 213.857 -0.02 mg/L ND mg/kg -0 066 mg/L ND -0022 mg/L ND m3 Ro; -0.02 mg(L ND -0018 mgtL ND BOE 3 -0017 mg/L ND -0 017 mgtL ND E OR OB -0013 mg/L ND EYER -0013 mgtL ND m3 OR -0011 mgtL ND -0019 mg/L ND mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/k~ 2/20/2004 2/20/2004 10:17:43AM 10:17:43 AM Erp: 2/2~/~00d ]0:] ~:d3 AM EER 212~1200~ ]0:]~:dg AM EBEERA 212Q1~004 10:17:43AM 1.113~Sb206.83~ 1.113 ~::~:~:~:~:~:~:~:~:i~:~:~:~:~:~:~:~:i~:~:~i:~:~:~:As 188.979 masRE ]. ~ ] 3 ~ CO 228.616 IR, SEE . ] 3 :::::::::::::::::::::::::::::: Cr26LM6 om TThEERE 1 113]]]]]]]]]]]]]]]]]]]]]]]]]]]]]]]]]]]]]]]]]]]]]]]]]]]]]]]]]]]8e 196 026 -0074 mgtL ND 0019 mgtL ND -0.02 mg(L ND 2% FOR -0018 mgtL ND SIR 2 3 -0018 mgtL ND -0017 mgtL ND ER ROR -0011 mgtL ND -0015 mg/L ND WIR 0 016 mgtL ND mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg 2/20/2004 10:17:43 AM 1.113 ~;~ Zn 213.857 -0017 mg/L ND mg/kg GNONFIEDENTICALO-TSYUBTJERCTITEO ASPoROaTrECNT37IVEuORrDeERzeEsNeTsEREDIN CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED N HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00447700 swmorssasso 3M MN01538856 = pt Initial se FE Ee 2 Sample Reported Reported Conc Calib Conc Samp QC Sample ID Sample Name Date Time Wt MDL Analyte Name (Calib) Units (Samp) Units Recovery 2/20/~004 10:21:39 AM Sb 206 836 0342 mg(L 0 342 mg/L 85 62 2/20/,;004 10:21:39 AM As 188.979 0353 mg/L 0.353 mg/L 88.35 2/20/2004 10:21:39 AM Be 313.107 0359 mg/L 0.359 mg/L 88.73 2/20/';004 10:21:39 AM Co 228.616 0324 mgtL 0.324 mg/L 80.88 3.4ppm 2/20/2004 2/20/,;004 10:21:39 AM 10:21:39 AM Cd 228.802 Cr 267.716 0.33 mg/L 0352 mgtL 033 mg/L 0.352 mg/L 82.62 87.95 2/20/,;004 10:21:39 AM Ni231694 0373 mg/L 0.373 mg/L 93.20 2/20/`;004 10:21:39 AM Pb 220.353 0316 mgtL 0.316 mg/L 79.06 2/20/';004 10:21:39 AM Se 196.026 0332 mgtL 0.332 mg/L 83.04 2/20/,;004 10:21:39 AM Zn 213.857 0328 rn~tL 0.328 m~/L 81.90 bonV1P 04 170 mee Port 4A Dup ZEEEEEE 2/20/2004 2/20/`;004 2/20/2004 2/20/~004 2/20/2004 10:25:37 AM 10:25:37 AM 10:25:37 AM 10:25:37 AM 10:25:37 AM EOR w 1.182 1.182 1.182 1 182 82 SMEEE Sb 206.836 A9188.979 Be 313.107 Co228616 Cd 228 802 O2BI%E O2E O3W -0153 mg/L ND 0.03 mgtL ND -0.02 mgfL ND -0 018 mgtL ND -0017 mg/L ND mg/kg mg/kg mgfkg mg/kg mg/kg 2/20/`;004 10:25:37 AM . 82 Cr26/.716 -0017 mgtL ND mg/kg 2/20/,;004 10:25:37 AM 1.182 Ni 231 6,34 -0018 rngtL ND mg/kg 2/20/,;004 10:25:37 AM 1.182 Pb 220.353 -0021 rngtL ND mg/kg 2/20/2004 10:25:37 AM 1.182 Se 196.026 -0012 mg/L ND mg/kg 2/20/`;004 10:25:37 AM 1.182 Zn 213.857 -0021 rn~tL ND m~/k~ 2/20/2004 10:29:35 AM 1.064 8b206.636 -0069 mg/L ND mg/kg 2/20/`;004 10:29:35 AM 1.084 As 188.979 -0.02 mgtL ND mg/kg 2/20/2004 10:29:35 AM 1.064 Be 313.107 -0.02 rng/L ND mg/kg 2/20/,;004 10:29:35 AM 1.084 Co228.616 -0016 mgtL ND mg/kg V]P 04 171 Effluent 1 2/20/,;004 2/20/`;004 10:29:35 AM 10:29:35 AM 084 .064 Cd 228 802 Cr267.716 0014 rng/L ND -0018 mgtL ND mg/kg mg/kg 2/20/S004 10:29:35 AM 1 084 Ni 231 6,34 -0 025 rng(L ND mg/kg 2/20/,;004 10:29:35 AM 1.084 Pb220.353 -0021 mgtL ND mg/kg 2/20/2004 2/20/`;004 2/20/2004 2/26/2004 2/20/2004 10:29:35AM os 10:29:35 AM 10:33:34 AM 10:33:34 AM 10:33:34 AM 1.064 Se 196.026 oe 1.084 1.07 1 07 1.07 Zn213.857 8b206.636 As 188 979 Be 313.107 -0012 mg/L ND rr: -0016 rn~tL ND -0059 mg/L ND -0 015 mg(L ND -0.02 rngtL ND mg/kg =m~/k~ mg/kg mg/kg mg/kg 2/20/2004 10:33:34 AM 1 07 Co228 616 -0 015 mgtL ND mg/kg V1P-04-172 berVlP-04-173 Effluent 1 :up Effluent 4 2/20/,;004 2/20/2004 2/20/2004 2/20/g004 EEL pan 2/20/2004 2/20/2004 2/20/2004 EL 2/26/2004 EERE ZEEE 2/20/,;004 BEDE ELE 2/20/2004 2/20/2004 Sager 2/20/2004 2/20/2004 taki 2/20/2004 10:33:34 AM 10:33:34 AM 10:33:34 AM 10:33:34 AM 10:33:34 AM 10:33:34 AM 10:37:33 AM 10:37:33AM 10:37:33 AM 10:37:33 AM 10:37:33 AM 10:37:33 AM 10:37:33 AM 10:37:33 AM 1.07 ::::::::::::::::::::: ::::: ::: :::: Cd 228.802 1 07 Cr 267 716 1.07 Ni 231 6,34 1 07 Pb 220 353 1.07 Se 196.026 1 07 Zn 213:57 1.055 Sb206.:39 1 055 As 188 979 1.055 Be 313.107 1055 Co228616 1 055: :::::::~: ~: :::::: Cd 228 802 055 Cr 267 716 1.055 Ni 231 6,34 1 055 Pb 220 353 -0012 rngtL ND mg/kg grr -0 018 rnglL ND -0028 mg/L ND 0 023 mgtL ND -0011 mg/L ND mg/kg mg/kg mg/kg mg/kg -0 013 rn~tL ND -0072 rng/L ND -0 013 mgtL ND =BY: EZo -0.02 rngtL ND EZ EOE -0011 mg(L ND -0 01 rngtL ND 23: 2 -0 02 rng/L ND -0029 mgtL ND ER -D 031 mgtL ND m~/k~ mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg boreV1P-04-174 be VlP-04-174 MS oe Effluent 4 Dup oe Effluent 4 Dup 2/20/2004 2/26/2004 2/20/,;004 Bre 2/20/2004 BEI 2/20/,;004 SEE 2/20/2004 EEE 2/20/2004 BEiIE 2/20/,;004 10:37:33 AM 10:37:33 AM 10:41:33 AM 10:41:33 AM 10:41:33 AM 10:41:33 AM 10:41:33 AM 10:41:33 AM 1.055 8e 196.026 1 055 1.09 oe 1 09 5 BE 1.09 E gBineeacE alEr 1 09 Zn 213 857 Sb 206.836 As 188 79 Be313.107 Co 228 616 -0003 rng/L ND mg/kg -0 012 mg![ ND 0057 rngtL ND -0 012 mg(L ND EBS2RtE: 2 -0.02 mgtL ND : EOE -0 009 rngtL ND BY ER -0009 mg/L ND B2i3: 2B 0022 mgtL ND mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg 2/20/,;004 2/26/2004 55 rE 2% 2/20/2004 2/20/2004 2/20/,;004 ETBB E EaEeE weT 2/20/2004 SEE: i BE gE Ei 2/20/2004 BE BE 3, GEE EE EE PE 3 2/20/2004 EEE s-08 2 EE EE 2/20/2004 2/20/,;004 IEE BE EE Ho 2/20/2004 10:41:33 AM 10:41:33 AM 10:41:33 AM 10:41:33 AM 10:45:33 AM 10:45:33AM 10:45:33 AM 10:45:33 AM 10:45:33 AM 10:45:33 AM 10:45:33 AM 1.09 1 09 1.09 1.09 1.09 1.09 1.09 1.09 1.09 1.09 1.09 Ni231694 Pb 220 353 ,Se 196.02: Zn213.:57 Sb 206.836 As 188.:79 Be 313.107 Co 228.616 1.83 Cd 228.802 Cr 267.716 Ni 231 6,34 -0026 -0 04 0012 -0012 0.54 0533 0618 0734 0761 0725 0684 mg/L mgtL mg(L mgtL mgtL mg/L mg/L mgtL mg/L mgtL mg/L ND mg/kg ND mg/kg ND mg/kg ND mg/kg 2477 mg/kg 2446 mg/kg 2833 mg/kg 3366 mg/kg 34.9 mg/kg 3324 mg/kg 31 36 mg/kg low recovery; 100 ppm std ok= appears to be ~ample 54.00% 53.30% 61.80% 73.40% /6.10% 72.50% 68.40% 2/20/2004 10:45:33 Ak4 1.09 Pb 220.353 0802 mgtL 36.8 mg/kg matrix 80.20% fonV1P 04 178 wee Lab Blan k Dup 2/20/,;004 10:45:33 AM 1.09 Se 196.028 2/20/2004 2/20/2004 Eos 2 i 2/20/2004 EEE E tm 2/20/2004 2/20/:004 EEE 2ow SEH 2/20/2004 EElHiigEm 2/26/2004 he 2/20/2004 2/20/2004 EEE tm 2/20/`;004 2/20/2004 10:45:33 AM 10:49:31 AM 10:49:31 AM 10:49:31 AM 10:49:31 AM 10:49:31 AM 10:49:31 AM 10:49:31 AM 10:49:31 AM 10:49:31 AM 10:49:31 AM 1.09 Zn 213.:57 1 098 Sb 206 838 ::::6:::::::::::::::::::::::::::::::::::: 1.096 Be 313.107 1.096 Co228.616 096 Cd 228_ 802 1 ::::::::::::::::::::::::::::::::::: 716 1.098 Ni 231 6,34 1.096 Pb220.353 1.098 Se 196.028 :::::::::::::::::::::::::::::::::::::::::::: 0675 mg/L 3096 mg/kg 0958 mg/[ -0 048 rnglL =x -0005 mg/L EB -0022 mg(L -0004 mgtL EZ EB OB -0007 mg/L -0 026 mgtL 223:B2 -0008 mg/L -0067 mgtL Ei 0025 mgtL -0011 m~/L 4396 mg/kg ND mg/kg ND mg/kg ND mg/kg ND mg/kg ND mg/kg ND mg/kg ND mg/kg ND mg/kg ND mg/kg ND m~/k~ problem 67.50% 95.80% CORNEFINDNEENRTICAOLUNSTUYBIDIESCTTRI1C0ATPCROUORTTE:CNTGI3V7O-R1D0ER6E8N8T2ERED I: CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED N HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00447711 awmorssssr 3M MN01538857 Sample ID VlP-04-175 3 4ppm V~P 04 176 V1P-04-177 herIP-04-180 -3.4ppm smo ow =Initial FrSample pt Reported Reported ona Eo Conc Calib Conc Samp QC Sample Name Date Time Wt MDL Analyte Name (Calib] Units (Samp) Units Recovery 2/20/~004 10:57:27 AM 1 178 Sb 206 836 -O 051 mg(L ND mg/kg 2/20/2004 10:57:27 AM 1.178 As 188.979 -0.01 mg/L ND mg/kg 2/20/2004 10257227 Aft1 1.178 Be 313.107 -0022 mg(L ND mg/kg 2/20/';004 10:57:27 AM 1.178 Co 228.616 -0003 mgtL ND mg/kg Comb Effluent 2/20/2004 2/20/2004 10257227 AM 10:57:27 AM 76 Cd 228_ 602 . :::::::::::::::::::::::::::::::::::::: -0008 mg/L ND -0026 mgtL ND mg/kg mg/kg 2/20/2004 10257227 AM 1.178 Ni 231 6,34 0001 mg/L ND mg/kg 2/20/`;004 10:57:27 AM 1.178 Pb 220.353 -0075 mgtL ND mg/kg 2/20/';004 10:57:27 AM 1.178 Se196.026 0028 mgtL ND mg/kg 2/20/';004 10:57:27 AM 1.178 Zn 213.657 -0012 m~tL ND ms/k~ 2/20/2004 11:26:32 AM Sb 206.836 0436 mg/L 0.436 mg/L 108.98 2/20/`;004 11:26:32 AM A 188.979 0415 mgtL 0.415 mg/L 103.87 2/20/2004 11226232 AM Be 313.107 0433 mgfL 0.433 mg/L 108.19 2/20/~,004 11:26:32 AM Co 228 616 0 456 mgtL 0 456 mg/L 11412 2/20/2004 11:26:32 AM Cd 228.802 0458 mg(L 0.458 mg/L 114.51 2/20/`;004 11:26:32 AM Cr 267.716 0434 mgtL 0.434 mg/L 108.54 2/20/';004 11:26:32 AM Ni 231 6,34 0398 mgtL 0.398 mg/L 99.50 2/20/';004 11:26:32 AM Pb 220.353 0412 mgtL 0.412 mg/L 103.06 2/20/2004 11226232AM Se 196.026 0464 mg/L 0.464 mg/L 115.97 2/20/`;004 11:26:32 AM Zn 213.857 0452 m~tL 0.452 m~/L 113.03 2/20/2004 11230242 AM 1.274 Sb 206.836 -0031 mg/L ND mg/kg 2/20/`;004 11:30:42 AM 1.274 A 188.979 -0014 mgtL ND mg/kg 2/20/2004 11:30:42 AM 1.274 Be 313.107 -0.02 mg/L ND mg/kg 2/20/2004 11:30:42 AM 1.274 Co 228.616 -0012 mgtL ND mg/kg Comb Effluent Du~ 2/20/';004 2/20/`;004 11:30:42 AM 11:30:42 AM 274 .274 Cd 228 802 Cr 267.716 0011 mg/L ND -0019 mgtL ND mg/kg mg/kg 2/20/2004 11:30:42 AM 1 274 Ni 231 6,34 -0 029 mglL ND mg/kg 2/20/';004 11:30:42 AM 1.274 Pb220.353 -0027 mgtL ND mg/kg 2/20/2004 2/20/`;004 2/20/2004 2/20/~004 2/20/';004 11230242 AM os 11:30:42 AM 11234237 AM 11234237 AM 11:34:37 AM 1.274 Se 196.026 oe 1.274 1.32 1 32 1.32 Zn 213.857 8b206.636 As 188 979 Be 313.107 -0009 mg/L ND rr -0011 m~tL ND -0038 mg(L ND -0 013 mgtL ND -0.02 mgtL ND mg/kg =m~/k~ mg/kg mg/kg mg/kg 2/20/';004 11234237 AM 1 32 Co 228 616 -0 014 mgtL ND mg/kg Lab Blank -- 100 ppm Check 2/20/';004 2/20/2004 2/20/2004 2/20/~,004 2/20/2004 11:34:37 AM 11:34:37 AM 11:34:37 AM 11:34:37 AM 11234237 AM ELE 1.32 ::::::::::::::::::::: :::: ::: :::: Cd 228.802 1 32 Cr 267 716 1.32 Ni 231 6,34 1 32 Pb 220 353 1.32 8e 196.026 2/20/~,004 2/20/2004 2/20/~004 EEREEEEE IBE 2/20/';004 EE .. EE 2/20/2004 2/20/2004 EEE EE 2/20/2004 2/20/2004 Zane Mp 2/20/~,004 11:34:37 AM 11:38:34 AM 11238234 AM 11:38:34 AM 11:38:34 AM 11:38:34 AM 11:38:34 AM 11:38:34 AM 11:38:34 AM 1 32 0.622 0 622 0.622 0 622 0 622 0 622 0.622 0 622 3.22 Zn 213 857 8b 206.836 As 188 979 Be 313.107 Co 228 616 Cd 228 802 Cr 267 716 Ni 231 6,34 Pb 220 353 2/20/2004 2/20/~004 2/20/';004 fF2/20/';004 Seid 2/20/';004 FE2/20/2004 2/20/2004 SE 2/20/2004 Sia 2/20/2004 11:38:34 AM 11238234 AM 11:42:37 AM 11242237 AM 11:42:37 AM 11:42:37 AM 11:42:37 AM 11:42:37 AM 11:42:37 AM 0.622 0 622 86 196.026 Zn 213 857 Sb 206.836 iE As 188 79 iE Be 313.107 gr Co 228 616 Cd 228.802 gE Cr 267.716 EE Ni 231 6,34 -0012 mgtL ND REE -0 018 mgIL ND -0028 mg/L ND 0 024 mg(L ND -0002 mg/L ND -0 012 m~tL ND 1 003 i-ng/L 1 26 mgtL I47E 1 279 mgtL EE1 304 mgIL 2 1 277 mgIL 1 302 1 285 1 334 oEI 1312 1 399 0336 EI O 427 E320441 #3 D 443 0442 2 0437 EE0408 mgIL mgtL mgtL mg/L mg([ mgtL mgIL mgtL mg~L mg/L mgtL mg/L mg/kg mg/kg mg/kg mg/kg mg/kg 8059 101 3 EBEm 102.8 EE 104 8 23 102 7 m~/kg mg/kg mg/kg mg/kg mg/kg mg/kg 104 6 103.3 107 2 2 105.5 112 5 0.336 23 0 427 230.441 #3 0 443 0.442 == 0.437 20.408 mg/kg mg/kg mg/kg mg/kg mg/kg mg/L mg/L mg/L mg/L mg/L mg/L mg/L 81% 101% z103% z105% g103% 105% 103% 107% 2106% 113% 84.06 2106 86 2110.15 i:11080 110.46 i109.22 "101.84 2/20/~004 2/20/2004 2/20/2004 EA 11242237 AM 11:42:37 AM 11:42:37 AM amd Pb 220 353 Se 196.026 Zn 213.857 Gwe 0 424 mg(L 0448 mg/L 0451 mgtL Gh 0 424 mg/L 0.448 mg/L 0.451 mg/L 8 105 96 112.00 112.64 CORNEFINDNEENRTICAOLUNSTUYBIDIESCTTRI1C0TACPORUORTT:ECNTGI3V7O-R1D0ER6E8N8T2ERED I: CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED N HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00447722 awmorsssss 3M MN01538858 Method: WWTP Scan caiip Calib RMeesuthlot:d: WCGWWTPWTScPanCarbon Study Event 1 E04-0120 no digest Result: CG WWTP Carbon Study Event 1 E04-0120 no digest sh 20636 hs 188.979 As 188.979 x 3k 4k cps)em (cps) (cps)em (cps) 0fD.O00Calib Eqn: Lincc,oonCnaccl(lmcmggn/tlL)) 1001.00 00.000Calib Eqn: Lincc,oonCncca((cmmgan/tiL)) 001.0( Calib Eq'n: Li~, Ca~c B' a 3Ta07 Corr ef: 0.988471 Corr Coeff: 0999471 Calib Eq'n: Li~, Catc C2 omasis Corr Coeff: 0.335280 Corr Coeff: 0999280 228.61~ El -- sok ~ 3M 50k Pes)em (cps) o ps)em (cps) > 0D.o0oCalib Eqn: Lincc,oonnCcacll(mmcggnl/LtL)) 100 00.000Calib Eqn: Lincc,oonCncca((cmmgan/tiL)) 101.0C 3 Corr Coeff 0.388716 Calib Eq'n: Li~% C~lc Corr Coeff: 0o998716 4 Cor Goer: 0.358867 Calib Eq'n: Lio, Calc ~Rt Corr Coeff: 0o~98~87 c3 arn Ceara so50kk Pp 6% 63k ~~ oepm em) - (cps) em Pe cps)em (cps) 00Calib Eqn: Licnco,onnCcac(l(mmcagnl/tLL)) 5 Corr Coeff 0.958815 11.000~ . 00.0000Calib Eqn: Licnco,onnCcca((mcmggIln/LtL)) CCoarlribCEoeqf'nf: L0#.~9,5C86a2lc5 h~ Corr Coeff: 0o998~2G PPaaggee 11 `CHGEOONNNNFFEIIDPDEIENNNTTCIIAOALLUN-- TSSUUYBBDJJIEESCCTTTRITTCOOT AACOPPURRROOTT.TEECNCTOT.IIVV2EE7-OOCRRV-DD1EE0RR.2E6E8NN6TT2EERREEDD IN IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00447733 11.00C0 WWiinnLkaabb3z2 SW_MNO1838859 3M MN01538859 Method: WWTP Scan cCaalliibb Result: Method: Result: GW CGGWW WTPWWTSTPcPanCCaarrbboonn SSttuuddyy EEvveenntt 11 EE0044--00112200 nnoo ddiiggeesstt Ni 231.604 PPbb 222200..335533 4400k 7 111Kk ((cecppmss)) a 0~.)0.000Calib Eq'n: Licnco,onnCcac(l(mmcggIln/LtL)) CCCooarlrrirbCCoEoeqef'fnff::: 0L0.i~99,998C866a85~22c lnt 57196.026 *3k ((cecppmss)) i 11..0010~ 00..0000Calib Eq'n: Licnco,onnCcac(l(mmcagIln/LtL)) CCCooarlrrirbCCoEoeqef'fnff::: 0L0o.i~~9,9988C77a~1t1c1 238 0213857 Zn 213.857 - 8833Kk ((cecppmss)) or ((cecppmss)) Id 0I)..0000Calib Eqn: Licnco,onnCcac(l(mmcggIln/LtL)) CCoarlribCoEeqf'fn:: L0i.~9%39C37a6ic. 5 Corr Coeff: 0.999376 11..001~0 1100 00..0000Calib Eqn: Licnco,onnCcac(l(mmcagIln/LtL)) CCoarlribCoEeqf'fn:: L0i.~%998C6a1l1c ~nt Corr Coeff: 0.~98611 ~ 11.000( -- 11.000( PPaaggee 22 CCHOEONNNFNFIEIDDPEEINNNTTICIAAOLLUN-- STSUUYBBDJJIEESCCTTTRITTCOOT AACOPPURRROOTT,TEECNCTOT,IIVV2EE7-OOCRRV-DD1EE0RR-2E8E8NN6TT2EERREEDD IINN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00447744 WWiinnLLaabb3322 33MM_MMNNO011553388886600 Sample ID l.0.4ppm aI nf 112 on Field Blank wo Comb 1 / 2 Port 4A we Port 4A MS - Lab Blank uw a pe Initial Fora Sample Analyte Reported Conc Calib peeReported Eo Conc Samp aQC Dete Time Wt Name (Calib) Units 2/23/2004 10:59:35 AM Sb 206.836 0365 mgtL 2/23/2004 10:59:35 AM As 188 979 0 357 mgtL EEaE EREEr 2/23!2004 2/23/2004 10:59:35 AM 10:59:35 AM Be 313.107 Co 228 616 0363 molL 0 359 mgtL 2/23/2004 ZB Wray 2/23/2004 10:59:35 AM 10:59:35 AM Cd 228802 Cr 267716 0358 molL 0.36 mgJL 2/23/2004 10:59:35 AM Ni 231.604 0358 mg/L 2/23/2004 10:59:35 AM Pb 22a 353 0 354 mgJL BEEN MRE 2/23!2004 10:59:35 AM Se 196.026 0367 molL ($amp) Units 0.365 mg/L 0 357 mglL 2 0.363 mglL ER OB 0 359 mg/L 0.358 mg/L 92 2 C.36 mglL 0.358 mg/L 0 354 mglL Ex oE 0.367 mglL Recover 91.19 89 29 g0.69 89 78 89.54 89.89 89.57 88 38 gl.67 2/23/2004 10:59:35 AM Zn 213.857 0361 mgtL 0.361 mg/L 90.27 2/23/2004 2/23!2004 2/23/2004 lar or 2/23/2004 2/23/2004 BmEa E a ow SrBE 2/23/2004 2/23/2004 TEE 2/23!2004 May Tas 2/23/2004 2/23/2004 2/23!2004 n= 2/23/2004 h OIo E E TmE hrE t3 2/23/2004 11:03:33 AM 11:03:33 AM 11:03:33 AM 11:03:33 AM 11:03:33 AM 11:03:33 AM 11:03:33 AM 11:03:33 AM 11:03:33 AM 11:03:33 AM 11:07:27 AM 11:07:27 AM 11:07:27 AM 100% Sb 206.836 ~),055 mgtL As 188.979 ND molL Be 313.107 ND mgtL Co 228616 ND molL Cd 228802 ND mg~L Cr 267716 0,048 molL Ni 231 604 ND mgJL Pb 220.353 ND mgtL Se 196.026 ND mgtL Zn 213.857 ND mgtL 8b 208.836 ND molL As 188.979 ND mgJL Be 313.107 ND molL mg/kg mglkg mglkg =mg/kg mglkg 3mg/kg z#g5mglkg mglkg mg/kg =mg/kg mglkg =mg/kg 2=Bmg/kg 2/23/2004 2/23/2004 BE 2/23/2004 2/23!2004 2/23!2004 ry 2/23/2004 2/23/2004 2/23/2004 BE iE 2/23/2004 Boat 2/23/2004 2/23/2004 2/23/2004 BEER 2/23/2004 2/23!2004 2/23/2004 EEE 2/23/2004 11:07:27 AM 11:07:27 AM 11:07:27 AM 11:07:27 AM 11:07:27 AM 11:07:27 AM 11:07:27 AM 11:11:22 AM 11.11.22 AM 11:11:22 AM 11:11:22 AM 11:11:22 AM 11:11:22 AM 11:11:22 AM 11:11:22 AM 11:11:22 AM 100% oo SogTtBEmhuEaEeesERnsms3Oo2Xi 100% Co 228 616 ND mgtL Cd 228802 ND Cr 267716 ND molL mgtL Ni 231.604 ND mgtL Pb 220.353 ND mgtL Se 196.026 ND mgJL Zn 213.857 ND molL Sb 206 836 0,e54 mgtL As 188.979 ND rrlylL Be 313 107 ND mgtL Co 228616 ND Cd 228802 ND molL mgtL Cr 267716 ND molL Ni 231.604 ND mgJL Pb 220.353 ND mgtL Se 196.026 ND molL mg/kg mg/kg mg/kg 2mg/kg mg/kg mg/kg =mglk.,g mg/kg mg/k8 =mg/kg 3mg/kg =mg/kg 3mg/kg mglkg mg/kg mg/kg 2/23/2004 2/23/2004 2/23/2004 SEE EET 2/23/2004 Ea. 2/23/2004 11:11:22 AM 11.15.17 AM 11:15:17 AM 11:15:17 AM 11:15:17 AM Zn 213 857 ND mgtL 8b 206.836 0,048 rrlglL As 188 979 ND mgtL Be 313.107 ND molL Co 228616 ND mgtL mg/kg mg/k8 mglkg =mg/kg =mg/kg 2/23!2004 2/23!2004 2/23/2004 Eo 2/23/2004 Ty 2/23/2004 11:15:17 AM 11:15:17 AM 11:15:17 AM 11:15:17 AM 11:15:17 AM 100% Cd 228802 ND Cr 267716 ND Ni 231.604 ND LE Pb 220.353 ND mer Se 196 026 ND mgJL mgtL EBmgtL molL mgtL mglkg mglkg mg/kg zmg/kg =mg/kg 2/23/2004 2/23/2004 2/23/2004 Bm 2/23/2004 2/23/2004 2/23/2004 BBEm EoHl 2/23/2004 2/23/2004 2/23/2004 EEE 2/23/2004 11:10:17 AM 11:19:12 AM 11:19:12 AM 11:19:12 AM 11:19:12 AM 11:19:12 AM 11:19:12 AM 11:19:12 AM 11:19:12 AM 11:19:12 AM SEpSBaEEENm BEaEwEEoE wESeREE STS3 SE 3OoRw 100% Zn 213.857 ND mglL Sb 206.836 1 243 mgJL As 188.979 1.23 molL Be 313.107 1196 mgtL Co228616 1134 mgtL Cd 228802 1173 molL Cr 267716 1 176 mgtL Ni 231.604 1 292 mgJL Pb 220 353 1 451 mgtL 8e 196.026 1.01 molL MS recovery high forzinc, 100ppm std check ok, possible mafri~ intefferen~,e mg/k.g mglkg mg/kg mg/kg mglkg mg/kg mg/kg mg/kg mg/kg mg/kg 124% 123% 120% 113% 117% 118% 129% 145% 101% 2/23/2004 11:19:12 AM Zn 213.857 3013 mg/L mglk,g 301% 2/23/2004 11:23:15 AM Sb 206.836 ND molL mg/kg 2/23!2004 2/23/2004 2/23/2004 Hg Tun XY 2/23/2004 E Pn ESe: las 2 2/23/2004 3 71730004 Slory 2/23/2004 muy sash 2/23/2004 2/23/2004 11:23:15 AM 11:23:15 AM 11:23:15 AM 11:23:15 AM 11:23:15 AM 11 7315 AM 11:23:16 AM 11:23:15 AM 11:23:15 AM 100% As 188.979 ND Be 313.107 ND Co 228616 ND Cd 228802 ND Cr 267716 ND Ni 731 604 Nr3 Pb 220.353 ND Se 196.026 ND Zn 213.857 ND mgtL molL molL mgJL molL m0tl mglL mgtL molL mglkg mg/kg mg/kg =mglkg 3mg/kg Z#mg/kg zmg/kg mglkg =mg/kg GEOANFNIEDPENITICAOU-NTSYUBDJIESCTTRTIC0TACPORUORTTE.CNTGI.V3E71OR0O2E8R8E6N3TERED CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00447755 swvorssose1 3M MN01538861 ew a For Initial Sample Analyte pe pee Reported Reported oo Conc Calib Conc Samp QC Sample ID \1 Eff Date Time 2/23/2004 11:27:12 AM 2/23!2004 11:27:12 AM og Tm: 2/23!2004 11:27:12 AM EEL iE 3 2/23/2004 11:27:12 AM Eo gmhE 3% 2/23/2004 11:27:12 AM 2/23/_9004 11:27:12 AM TE er B 2/23/2004 11:27:12 AM alt Ds x 2/23/2004 11:27:12 AM Wt 100% Name Sb 206.836 As 188 979 Be 313.107 Co 228 616 Cd 228802 Cr 267716 Ni 231.604 Pb 22Q 353 (Calib) 0.[~ ND ND ND ND ND ND ND Units mg/L mgtL mglL mgtL mg/L mgJL mg/L mgJL ($amp) Units mg/kg mglkg =mg/kg Zmg/kg 3mglk.g mg/kg =mg/k.g =mg/kg Recover 2/23!2004 11:27:12 AM 8e 196.026 ND mglL mg/k.g .Elf 4 oPort 1A 2/23/2004 2/23/2004 2/23!2004 LE rs 2/23/2004 B= oad fal 2 2/23/2004 2/23/2004 iam 3 2/23/2004 momar 3 2/23/2004 Eo LE] 2/23!2004 2/23/2004 Ma Tas 2/23/2004 2/23!2004 a 2/23/2004 a er 2/23/2004 EE 2/23/2004 Miya JSR % 2/23/2004 Err 2 2/23/2004 11:27:12 AM 11:31:09 AM 11:31:09 AM 11:31:09 AM 11:31:09 AM 11:31:09 AM 11:31:09 AM 11:31:09 AM 11:31:09 AM 11:31:09 AM 11:31:09 AM 11:35:06 AM 11:35:06 AM 11:35:06 AM 11:35:06 AM 11:35:06 AM 11:35:06 AM 100% 100% Zn 213.857 ND mgtL Sb 206.836 f},~9 mgtL As 188.979 ND mglL Be 313.107 ND mgJL Co 228616 ND mg/L Cd 228802 ND mg/L Cr 267716 ND mg/L Ni 231 604 ND mgtL Pb 220.353 ND mgtL Se 196.026 ND mgJL Zn 213.857 ND mgtL 8b 206.836 0~ mglL As 188.979 ND mgtL Be 313.107 ND mg/L Co 228 616 ND mgtL Cd 228802 ND mg/L Cr 267716 ND mgtL mg/k.g mg/k.g mg/k.g =mg/kg 3mg/k.g mg/kg 3mg/k.g 3mg/kg =mg/k.g mg/k.g =mg/k.g mg/kg =mg/kg Zmglkg =mg/kg 3mglkg 2mg/kg be0 4ppm 2/23!2004 2/23!2004 2/23/2004 Rl 2/23/2004 2/23/2004 = ns 2/23/2004 2/23/2004 TIE 2/23/2004 2/23/2004 BE SEE 2/23/2004 2/23!2004 2/23/2004 I 2/23/2004 11:35:06 AM 11:35:06 AM 11:35:06 AM 11:35:06 AM 11:39:04 AM 11.39.04 AM 11:39:04 AM 11:39:04 AM 11:39:04 AM 11:39:04 AM 11:39:04 AM 11:39:04 AM 11:39:04 AM Ni 231.604 ND mgJL Pb 220.353 ND mgtL Se 196.026 ND mgtL TE = Zn 213.857 ND mg/L Sb 206 836 0 336 mgtL oe 2 As 188.979 0327 rrlylL Be 313 107 0 336 mgJL IEE gE oo Co 228616 0332 mg/L Cd 228802 0334 mgtL SRE BE ER = Cr 267716 0332 mg/L Ni 231.604 0332 mgtL Pb 220.353 0325 mgtL EERE 8e 196.026 0336 mg/L mg/kg mg/kg mg/kg m g/k.,g 0 336 mg/L 0.327 illy/L 0 336 mg/L 0.332 mg/L 0.334 mg/L 0.332 mg/L 0.332 mg/L 0.325 mg/L 0.336 mg/L 84 03 81.75 84 08 83.04 83.68 83.07 82.97 81.15 84.07 2/23/2004 2/23/2004 2/23/2004 LE2/23/2004 EN. 2/23/2004 11:39:04 AM 11.43.02 AM 11:43:02 AM 11:43:02 AM 11:43:02 AM Zn 213 857 8b 206.836 As 188 979 BEE. FEE Be 313.107 EEE EB Co 228616 0 335 mgJL 1 124 m#lL 1 097 mgtL 1 074 mg/L 1 008 mgtL 0 335 mg/L MS recovery high for zinc, mglkg mglkg mg/kg 83 63 112% 118% 107% 101% Port 1A MS 2/23!2004 2/23!2004 2/23/2004 EN 2/23/2004 My 2/23/2004 11:43:02 AM 11:43:02 AM 11:43:02 AM 11:43:02 AM 11:43:02 AM 100% Cd 228802 Cr 267716 pm Ni 231.604 Pb 220.353 Se 196 026 1 047 1.03 1 093 FE 1 042 an 1 024 mgtL mgJL mgtL mg/L mgtL 100 ppm std check ok, possible EEE matrix men HX interf~rense mg/kg mg/kg mg/kg mglkg mg/kg 105% 103% 109% 104% 102% on Field Blank 2/23/2004 2/23/2004 2/23/2004 SE on an 2/23/2004 2/23!2004 2/23/2004 EE TEE wm SEER 2/23/2004 BEE 2/23/2004 2/23/2004 EGE GEE 2/23/2004 11:43:02 AM 11:47:07 AM 11:47:07 AM 11:47:07 AM 11:47:07 AM 11:47:07 AM 11:47:07 AM 11:47:07 AM 11:47:07 AM 11:47:07 AM 100% Zn 213.857 Sb 206.836 ND As 188.979 ND Be 313.107 ND Co 228616 ND Cd 228802 ND Cr 267716 ND Ni 231.604 ND Pb 220 353 ND 8e 196.026 ND 1 567 mglL mgtL mg/L O2RmgJL mgtL mg/L mgtL mg/L mgtL mgJL mglk.g mg/kg mglkg =mg/kg mg/kg mglkg =mg/kg 2mglkg mg/kg =mg/kg 157% 2/23/2004 11:47:07 AM Zn 213.857 ND mg/L mg/k,g 2/23/2004 11:51:07 AM 8b 206.836 ND mg/L -0.197 mglkg - Lab Blank 2/23/2004 2/23/2004 2/23/2004 Hu 2/23/2004 2/23/2004 ER ?/73!2004 1 2/23/2004 2/23/2004 Way 2/23/2004 11:51:07 AM 11:51:07 AM 11:51:07 AM 11:51:07 AM 11:51:07 AM 115107 AM 11:51:07 AM 11:51:07 AM 11:51:07 AM EdsT-ERaunsEnEEh EE2Y 1.096 As 188.979 ND Be 313.107 ND Co 228616 ND Cd 228802 ND Cr 267716 ND Ni ?.31 604 Nr3 Pb 220.353 ND Se 196.026 ND Zn 213.857 ND mgtL mg/L mg/L mgtL mglL mgtl mgJL mgtL mg/L -0.755 0.175 -0.079 od -0.016 po -0.083 mg/kg mg/kg mglkg mg/kg mg/kg BR -0 183 -0.091 -0.163 -0.199 mg/kg mg/kg mg/kg mglkg GFOENAFINDEERNITICAOU-NTSYUBDJIESCTTRTIC0TACPORUORTTECNTGI.V2E7OGuRnOiEoR26E8N0T3ERED CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00447766 swnoss3362 3M MN01538862 8ample ID [-0.4ppm uw a For Initial Sample Analyte pe pee Reported aE Conc Calib Reported Conc oa Samp QC Date Time Wt Name (Calib) Units 2/23/2004 11:55:00 AM Sb 206.836 0329 mgtL 2/23/2004 11:55:00 AM As 188 979 0 321 mgtL ao YE TE 2/23/2004 11:55:00 AM Be 313.107 0.33 mglL 2/23/2004 11:55:00 AM Co 228 616 0 332 mgtL ma Immo 3 2/23/2004 11:55:00 AM Cd 228802 0335 mg/L 2/23/2004 11:55:00 AM Cr 267716 0333 mgJL 1 BB BE BEB BEB 2/23/2004 11:55:00 AM Ni 231.604 0332 mg/L 2/23/2004 11:55:00 AM Pb 220 353 0 318 mgJL I BB BB Ei 2/23/2004 11:55:00 AM Se 196.026 0331 mglL ZEEE IM SE 3 B 2/23/2004 11:55:00 AM Zn 213.857 0336 mgtL 2/23/2004 11:57:23 AM Sb 206.836 0337 mgtL 2/23/2004 11:57:23 AM As 188.979 0325 mglL IR EB Bl 2/23/2004 11:57:23 AM Be 313.107 0336 mgJL 1B EB EB 2/23/2004 11:57:23 AM Co 228616 0335 mg/L 2/23/2004 11:57:23 AM Cd 228802 0336 mg)L IE EBB 2/23/2004 11:57:23 AM Cr 267716 0336 mg/L CEE OE. BRE 2/23/2004 11:57:23 AM Ni 231 604 0 335 mgtL LS BEE Eo 2/23/2004 11:57:23 AM Pb 220.353 0326 mgtL 2/23/2004 11:57:23 AM Se 196.026 0338 mgtL BEDI SER BR OBR OB 2/23/2004 11:57:23 AM Zn 213.857 0338 mgJL (Samp) Units 0.329 mg/L 0 321 mglL C.33 mglL 0 332 mg/L 0.335 mg/L 0.333 mg/L 0.332 mg/L 0 318 mglL 0.331 mglL 0.336 mg/L 0.337 mg/L 0.325 mglL 0.336 mg/L 0.335 mg/L 0.336 mg/L 0.336 mg/L 0 335 mglL 0.326 mglL 0.338 mg/L 0.338 mg/L Recover 82.16 80 26 82.42 82 93 83.67 83.25 82.88 79 46 82.63 83.97 84.17 81.33 83.96 83.82 84.00 83.88 83 73 81.45 84.48 84.55 GFOENFAINDEERNITICAOLU-NTSYUBDJIESCTTRITCOTACPORUORTTECNTG.IV2E7OGuRnDiEoR26E8N0T3EREDIN CONFIDENTIAL - SUBJECT TO A PROTECTIVE ORDER ENTERED IN HENNEPIN COUNTY DISTRICT COURT, NO. 27-CV-10-28862 11993377..00447777 Pr3M MN01538863