Document zQJ6md9N33oQ3dQVb1no4ZLmR
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26 3 -7S"21
AXYS METHOD MLA4 31 Rev 01 PFOS_s1 _0e Fonm 1A12
PEtFLUO tINATED SURFACYANi ANALYSIS REPORT
CLIENT lb:
Sample CoBecUoa ;
08-Mw-2M 11 :00
Lob Name: A](YS ANALYTlCAL . SERVICES
Contract No.: 4191 Lab Saatpla 10: L7652-27R2
Matrix: SERUM SaanPle Sfie: 100 mL
Sample Receipt dMeo 104Aar-2005 Mltlal Ca ftatlon Dale-
BRACKETING CAL
Extraction Dale: 21-Apr-2M
hobo 0: MMSIMS
Anaylaia Oats:
22-Apr-2005 Tdrw: 1 :37:18 LC Column ID: C18, Z oibaoc XDe
Extract Vdtwae (atL): 2 Sample b a1a10e: PFSSG OSaSO47
Infection Volume (PL): 30.0
Blank Data Fihaeats: PFSSG 058S026
Dilation Factor Concentration UnMs :
N/A MulBpfa Cal. data Flianamem PFS5G 0585029 PFS5G 058S038
nglml. PFS6G 056S050
COMPOUND
LAB CONIC FLAG' FOUND
DETECTION LIMIT
RETENTION TIME
PSPeA U 0 312
PFFDtA U
0. 103
PFHPA 0838 00608 3 .87
PFOA
786
0.0510 5 38
PFNA 1-07 00417 5.73
PFDA 0.488 0.0168 606
PFUnA
0.198 0A079
6 40
PFDoA 0 044 0.0102
6 .76
pFBS 0.117 OD588 3 4 4
PFHxS 17 3
0 .128 5.52
PFOS 112 0204 6 22
LABELED COMPOUND
LAB SPIKE CONC.
R1*1 RETENTION
FLAG' CONC.
FOUND TiMIE
(n8) (n9)
13C-PFQA 12A 8.80
733
5 36
13C-PFDA 12 0
9 .43
785
608
(1) U=notdefected (2) R (%) = PaceM tecauery
15825PFUt z As. SIG Approved bjr_
1o-0S-?L05
Z~-
p. 2
AXY8 METHOD MLA-031 Rev 01 CLgNT ID: a>=Os S I-os Form 1A12
PERFLUORINATED SURFACTANT ANALYSIS REPORT
Sample Co9edlaq: 084Aarv200B 11 :00
Lab Name: AXYS ANALYTICAL SERVICES
Coa4rac! Na:
091 Lab Sample ID:
1.7652-25R2
Isatrlx: SERUM SaMple Slze: 1 .0D
ML
Sample Receipt datw 10dJah2005 6aUaf Calibration Date: BRACKETING CAL
Extraction Dale: 21-Apr-2005 IsslrunwM V.
LCdNS/MS
Analysis Dale:
22-Apr-2M5
T6av: 12426 LC Column ID: C18, Zarbau )CDS
Extract Volume ( oL) : 2
Sample DatatNe : PFSSG_OSYSW6
Irljedlon Vofmne ({d.): 30.0 81aNc Data Weeanw: PFSSG 058S026
Dilution Factor.
N/A
Concentration Unqs : nghnt.
Multiple Cal. data F9a+ames PFS5G 0585029 PF85G_058S039
PFS5G 058S050
COMPOUND
LAB CONC DETECTION RETENTIO N FLAG FOUND LWT TIME
PFPeA U 0.181
PFHxA
U 0.114
PFHpA
0.117 0.0734 397
PFaA 693 0.0541 534
PFKA
112 04129 5_73
PFDA
0 .288 00157 606
PFiknA 0.115 0.0159 6.38
PFDoA U 00377
PFBS U 0051 9
PFHxS 189 00749 5 50
PFOS
102 0171 622
LABELED COMPOUND
LAB SP11CE CONC.
FLAG' CONC.
FOUND
(am
tnw
R RETENTION TOME
13C-PFOA 120 9 .99 832 534
13C-PFDA 12.0 11 .7
979
8.06
(1) LI= node (2) R (%) = Percent n coueyr
15ezsM01 2 :fs. sts Appro-d by
QA/QC Chemist
:nas20e5 dd-- rrrs
~X~ AxYS ANALVTIGe.L SERVICES LTC~ ea rox r~)1 . 7a5 Mats 1a t~ESt 4u~t~ ~ c . aNtw Yet as8 m usol us3eoo lur ~zsm ~5~5a n
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Form 1 A
ORGANICS ANALYSIS REPORT AXYS METHOD MLA-042 Rev 08 PERFLUORINATED AXYS ANALYTICAL SERVICES P .O . Box 2219, 2045 MILLS RD . WEST. SIDNEY . B .C., CANADA V8L 3S8 TEL (250) 655-5800 FAX (250) 655-581 1 Contract No.: 4191 Lab Sample I.D. : L9303-3
Matrix :
SERUM
Sample Size :
0.500 mL
Sample Receipt Date :
21-Sep-2006
Initial Calibration Date:
26-Sep-2006
Extraction Date :
26-Sep-2006
Instrument 10 : LC MS/MS
Analysis Date :
27-Sep-2006 Time : 00 :48 :24 Column ID : C1 8
Extract Volume (uL) : 2000
Sample Data Filename: FC6G_399 S: 24
Injection Volume (uL) : Dilution Factor:
15 Blank Data Filename: FC6G_399 S: 21
N/A Cal . Ver. Data Filename :
FC6G_399 S : 14
Concentration Units : ng/mL
COMPOUND
LAB FLAG 1 CONC . DETECTION RETENTION
FOUND LIMIT
TIME
PFBA
U
0 .576
PFPeA
U
0.544
PFHxA
U
0.476
PFHpA
U
0.556
PFOA 23 .8 0.556
PFNA
1 .43 1 .21
PFDA
0 .905 0.504
PFUnA
U
0.512
PFDoA
U
0 .576
PFBS
U
1 .41
PFHxS 7 .74 1 .29
PFOS 40.3 1 .16
PFOSA U 0 .480
4 :45 5 :04
5:24
4:57 5:34
(1) Where applicable, custom lab flags have been used on this report ; U = not detected .
Approved by : -------Henry Huang----- __ QA/QC Chemist
For Axys Internal Use Only [ XSL Template: FC-FormlA.xsl ; Created: 27-Sep-2006 13:19:27 ; Application : XMLTransformer-1 .7 .13 ; Report Filename : PFC_FC_LC_PFOA_L9303-3_Form1A_SJ593458 .htmt ; Workgroup: WG20188; Design ID : 261 ) These pages are part of a larger report that may contain information necessary for full data evaluation .
Page 1 of 1(WG20188 - PFC_FC_LC_PFOA_L9303-3_Form1A_SJ593458 .html)
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AXYS METHOD MLA-042 Rev 08 CLIENT SAMPLE N O
Form 1A PERFLUORINATED ORGANICS ANALYSIS REPORT
Sample Collecti on: 22_Aug_200617:55
AXYS ANALYTICAL SERVICES
P.O. Box 2219, 2045 MILLS RD. WEST, SIDNEY, B .C ., CANADA V8L 3S8 TEL (250) 655-5800 FAX (250) 655-581 1 Contract No.: 4191 Lab Sample I .D.: L9208-2 R
Matrix: SERUM Sample Size : 0 .500 mL
Sample Receipt Date : 24-Aug-2006 Initi al Calibration Date: 22-Sep-2006
Extraction Date :
20-Sep-2006
Instrument ID: LC MS/MS
Analysis Date: 23-Sep-2006 Time: 0121 :08
Column ID: C1 8
Extract Volume (uL) : 2000
Sample Data Filename : FC6G_394 S : 22
Injection Volume (uL) : 15 Blank Data Filename :
FC6G_394 S : 21
Dilution Factor. N/A Cal . Ver. Data Filename : FC6G_394 S : 14
Concentration Units : ng/mL
COMPOUND LAB FLAG'
CONC . DETECTION RETENTION FOUND UMIT TIME
PFBA
U
0 .576
PFPeA
U
0 .544
PFHxA U 10.9
PFHpA U 0-556
PFOA
14 .9 0.556
PFNA
U
0.468
PFDA
U
0.504
PFUnA
U
0.512
PFDoA
U
0.576
PFBS
U
1 .41
PFHxS
444 1 .29
PFOS
23 .6 1 .16
PFOSA U 0.480
4:45
4 :57 5 :34
( 1) Where applicable, custom lab flags have been used on this report ; U = not detected.
Approved by : Henry Huang - QA/QC Chemist
For Axys Internal Use Only I XSL Template: FC-FocmIA.xsl ; Created: 03-Oct-2006 10 :15 :16; Application: XMLTransformer-I .7 .13 ; Report Filename: PFC_FC_LC_PFOA_L9208-2_Form1A-SJ594693 .html ; Workgroup : WG20159; Design ID : 472 1
These pages are pa rt of a larger report that may contain information necessary for full data evaluation
~7
vJ
Page 1 of 1(WG20159 - PFC_FC_LC_PFOA_L9208-2_Form 1 A_SJ594693 .html)
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Form 1 A
METHOD MLA-042 Rev 08 PERFLUORINATED ORGANICS ANALYSIS REPORT AXYS
AXYS ANALYTICAL SERVICE S P .O . Box 2219, 2045 MILLS RD . WEST, SIDNEY, B.C ., CANADA V8L 3S8 TEL (250) 655-5800 FAX (250) 655-581 1 Contract No. : 4191 Lab Sample I .D . : L9303-2
(A)
Matrix: SERUM Sample Size: 0 .500 mL
Sample Receipt Date :
21-Sep-2006 Initial Calibration Date: 26-Sep-2006
Extraction Date:
26-Sep-2006
Instrument ID: LC MS/MS
Analysis Date :
27-Sep-2006 Time : 00 :19 :47
Column 10 :
C1 8
Extract Volume (uL) : 2000
Sample Data Filename : FC6G_399 S : 22
Injection Volume (uL): 15 Blank Data Filename :
FC6G_399 S : 21
Dilution Factor. N/A Cal. Ver. Data Filename :
FC6G_399 S : 14
Concentration Units : ng/mL
COMPOUND
LAB FLAG 1 CONC . DETECTION RETENTION FOUND UMIT TIME
PFBA
U
0 .576
PFPeA
U
0 .544
PFHxA U 10 .5
PFHpA
U
0 .556
PFOA 10 .5 0 .556
PFNA
0 .963 0 .468
PFDA
U
0 .504
PFUnA
U
0 .512
PFDoA
U
0 .576
PFBS
U
1 .41
PFHxS
6.00 1 .29
PFOS
35 .2 1 .16
PFOSA U 0 .480
4:45 5:07
4 :54 5 :31
(1) Where applicable, custom lab flags have been used on this report ; U = not detected .
Approved by: ____ Henry Huang_________ QA/QC Chemist
For Axys Internal Use Only [ XSL Template: FC-FormlA.xsl; Created: 27Sep-2006 13:19 :27 ; Application : XMLTransfonner-1 .7 .13; Report Filename: PFC_FC_LC_PFOA_L9303-2_Form1A_SJ593456 .html; Workgroup : WG20188; Design IO : 2611 These pages are part of a larger report that may contain information necessary for full data evaluation .
Page 1 of 1(WG20188 - PFC_FC_LC_PFOA_L9303-2_Form1A_SJ593456 .html)
_AJCCc
p. 6
AXYS METHOD MLA-042 Rev 08
Form 1 A
PERFLUORINATED ORGANICS ANALYSIS REPORT
AXYS ANALYTICAL SERVICE S P.O. Box 2219, 2045 MILLS RD . WEST, SIDNEY. B.C . . CANADA VOL 358 TEL (250) 655-5800 FAX (250) 655-581 1
Contract No . : 4191 Lab Sample I .D. :
L8863-2
Matrix :
SERUM
Sample Size :
0 .500 ml
Sample Receipt Date :
27-Apr-2006
Initial Calibration Date: 07-Jul-2006
Extracti on Date: 06-Ju1-2006 Instrument 10 : LC MS/MS
Analysis Date: 08-Ju1-2006 Time : 09 :08 :11 Column ID : C1 8
Extract Volume (uL): 2000 Sample Data Filename : FC6G_277 S: 23
Injection Volume (uL) : is
Blank Data Filename:
FC6G_277 Sr 21
Dilution Factor. N/A Cal . Ver. Data Filename :
FC6G 277 S: 14
Concentration Units : ng/ml
COMPOUND LAB FLAG' CONC . DETECTION RETENTION FOUND LIMIT TIME
PFBA
U
0.604
PFPeA
U
0.472
PFHxA
U
0.484
PFHpA 1 .08 0.532 4:17
PFOA 133 3.07 4:45
PFNA
1 .15 0.680 5 :08
PFDA
U
0.536
PFUnA
U
0.476
PFDoA
U
0.568
PFBS
U
1 .20
PFHxS
32 .7 1 .01 4 :56
PFOS 155 1-00 5 :33
PFOSA U 0.460
(1) Where applicable, custom lab flags have been used on this report; U= not detected .
Approved by:
A6-~- ~
QA/QC Chemist
For Axys Internal Usc Only j XSL Template : FC-FormlA.xsl; Created: 12-JuI-2006 16:32 :12 ; Application: XivII.Transfonner-1 .7.4; Report Filenarne : PFC_FC_LC_pFOA_L8863-2_FocmlA_S7571307 .htmt; Worlcgoup: WGI9474; Design ID : 3321
These pages are part of a larger report that may contain information necessary for full data evaluation_
Page 1 of 1(WG19474 - PFC FC_LC_PFOA_L8863-2_Form1A_SJ571307 . html) 10l] NO <C]
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AXYS METHOD MLA-042 Ray 03 CLIENT ID :
PFOS St 012 Form 1A12
PERFLUORINATED ORGANICS ANALYSIS REPOR T
Lab Name: AXYS ANALYTICAL SERVICES
Sample Collection : 31-Aug-2005 10:32
Contract No-: 4191 Lab Sample 1D: L7932-53 I
Matrix :
SERUM
Sample Size : 1 00 mL
Sample Receipt date: 01-Sep-2005
Initial Calibration Date: 22-Sep-2005
Extraction Date: 21-Sep-2005
Instrument ID: LC-MS/M5
Analysis Dale : 23-Sep-2005 Time : 1 :09 :49
LC Column ID: ci s
Extract Volume (mL) : 2
Sample DataTile:
FCSG 181S056
Injection Volume ( pL): 100 Blank Data Fllename :
FC6G_181S070
Dilution Factor,
3
Concentration Units n91m L
Cal. Ver- Data Filename: FC5G_181504 8 CAL VER 10 : PFC-LIN-055CS-F
COMPOUND LAB CONC DETECTION RETENTION FLAG FOUND LIMIT TIME
PFPeA UD 0 639
PFHxA UD 0 620
PFHpA D 1 95 0 628 4 18
PFOA D 110 0 818 4 65
PFNA O 2 92 0 670 5 05
PFDA O 1 32 0 848 5 36
PFUnA UD 0 64 1 PFDoA UO 0 638
PFBS UO PFHXS D
0 635
200
0 638 4 80
PFOS 0 111 0 645 5 46
PFOSA UD 0 625
LABELED COMPOUND LAB SPIKE CONC. R(/,)= RETENTION FLAG' CONC . FOUND TIME (n9) (n9)
13C2-PFOA D 120 121 101 4 65 13C4-PFOS (8(I) D 120 120 996 5 46 13C4-PFOS (99) 0 120 12 7 106 5 46 13C2-PFDA D 120 108 900 5 36
(1) U = not detected; D= dilution data (2) R (X ) = Percent recovery 169e2PF01 _ 1 A, . _% Approved by: OA/QC Chemist d28-09-2DOS
010 Axes AfVALYi 1G~L SER\/I(__ES LTC :) P.0 BOX 2219. t0(5 60L1S OD . WKI. SIOOEI. A(, GNAOA y6( 3SB 1(( (250) 6SS-5000 FAX (250) 655-5111
p. 8
AXYS METHOD MLA-042 Rev 03 CLIENT 10 : PFos s1_ot2 Form 1Al 2
PERFLUORINATED ORGANICS ANALYSIS REPORT
Sample Collection: 31-Aug-2005 10 :03
Lab Name: AXYS ANALYTICAL SERVICE S Contract No . : 4191
Lab Sample ID :
L7932-52 1
Matrix : Sample Receipt date :
SERUM Sample Size : 1 00 mL
01Sep-2005
Initial Calibration Date: 22-Sep-2D05
Extraction Date: 21-Sep-2005 Instrument ID : LC-MSIMS
Analysis Date : 23-Sep-2005 Time : 0 :55:34 LC Column ID: C1 8
Extract Volume (mL): 2 Sample Detat-tle:
FCSG_181St155
Injection Volume (NL): 100
Blank Data Filename : FC6G_181S070
Dilution Factor.
3
Concentration Units : nglmL
CaL
Ver. Data Fitename : FC5G_181SO48 CAL VER ID ; PFC-LIN-055CS-F
COMPOUND LAB CONC DETECTION RETENTION FLAG' FOUND UMIT TIME
PFPeA UD 0 63 9 PFHxA UD 0 620 PFHpA UD 0 628 PFOA D 729 0 618 4 65 PFNA D 1 51 0 670 4 99
PFDA D 0739 0648 536
PFUnA UD 0 64 1
PFDoA UD 0 638 PFBS UD 0 635 PFHxS D 125 0 638 4 80
PFOS D 876 0 645 5 46 PFOSA UO 0 625
LABELED COMPOUND LAB SPIKE CONC. R(/ )2 RETENTION FLAG' CONC . FOUND TIME (n9) (n9)
13C2-PFOA D 120 122 102 4 65 13C4-PFOS (80) D 120 129 108 5 46 13C4-PF0S (99) D 120 132 110 5 46 13C2-PFDA D 120 103 856 5 36
(1) U= no( detected ; D= dilution data (2) R ( % ) = Percent recovery
16982PFOt_I AS. 85 Approved by:
OA/OC
Chemist
294W-2o0s dd.m m.yyy y
-40 AXYS A(VALYTiCAL SEFZ-\/ICES LTa F0 BOX 2 2 19 . 2045 UHLS RD 1NE51. SIOMfY.O ( . UTADAVAl3S8111(2S0) 6 55-5800 FAX 1250) 655-501 1
31
p. 9
AXYS METHOD MLA-042 Rev 03 CLIENT ID : PFOS Si oi2 Form 1Af2
PERFLUORINATED ORGANICS ANALYSIS REPORT
Sample Collection: 31-Aug-2005 10:30
Lab Name : AXYS ANALYTICAL SERVICE S
Contract No. : 4191 Lab Sample ID : L7932-54 i
Matrix :
SERUM Sample Size : 1 00 mL
Sample Receipt date : 01-Sep-2005
Initial Calibration Date: 22-Sep-2005
Extraction Date:
21-Sep-2005
Instrument ID: LC-MS/MS,
Analysis Date: 23-Sep-2005 Time : 1 :24b2 LC Column 10 : C1 8
Extract Volume (mL) : 2
Sample Datafile : FC5G 181S057
Injection Volume (NL) : 10 0
Dilution Factor.
3
Concentration Units : ng/mL
Blank Data Filename :
FC6G_181S070
Cal. Ver. Data Filename : FCSG_181SO4 8 CAL VER ID : PFC-LIN-055CS-F
COMPOUND LAB CONC DETECTION RETENTION FLAG ' FOUND LIMIT TIME
PFPeA UD 0 63 9
PFHxA UD 0 620
PFHpA UD 0 626
PFOA D 554
0 618 4 65
PFNA D 2 36 0 670 5 05
PFDA UD 0648 PFUnA UD 0 64 1 PFDoA UD 0 638
PFBS UD 0 635
PFHxS D 6 59 0 638 4 PFOS D 600 0 645 5 PFOSA UD 0 623
80 46
LABELED COMPOUND LAB SPIKE CONC. R(%)z RETENTION FLAG' CONC_ FOUND TIME In9) (n9)
13C2-PFOA D 120 118 982 4 65 13C4-PFOS (80) D 120 150 125 551 13C4-PFOS (99) D 120 134 112 5 46 13C2-PFDA D 12 0 101 844 5 36
(1) U = not detected ; D= dilution data (2) R (%) = Percent recovery
16982PFD1_i As s7 Approved by :
//~x9 . '
~/"'` ~._.-
28-09-2005
QA/QC Chemist ad-mm-vrvr
4K(Ce AKYS ANALYTICAL SERVICES LTC :) P0 i0x 2214, 2045 MII15 to YIE51_ 5WNEY.1 C . um yet 35a itl (250) 65 5-5 8110 1At 1250) 655-5911
~0 ~-
P . 10
AXYS METHOD MLA-0 42 Rev 02 CLIENT PFOS s1_ptz Form 1A12
PERFLUORINATED ORGANICS ANALYSIS REPOR T
10 :
Sample Collection-.
28-Jun-2005 10:27
Lab Name : AXYS ANALYTICAL SERVICE S
Contract No. :
4191 Lab Sample ID:
L7932-1
Matrix:
SERUM Sample Size : 1 00 mL
Sample Receipt Date : 29-Jun-2005 Initial Calibration Date : 05-Aug-2005
Extraction Date: 04-Aug-2005
Instrument 113; LC-MSIM S
Analysis Date : 05-Aug-2005
Time: 21 :17 :29
LC Column ID : Ci8- Zorbax XDB
Extract Volume (mL) : 2 Sample date Filename: FCSG 131SO40
Injection Volume (NL): 30 0
Blank data Filename : FC50_1315024
Dilution Factor : N/A Concentration Units : ng/m L
Cal. Var. date F)lename: FC5G_131S037 CAL VER iD: PFC-UN-039CS-F
COMPOUND LAB
CONG
DETECTION
RETENTION
FLAG' FOUND LIMIT TIME
PFPeA U 0 638
PFHxA U 0 620
PFHpA U 0 .251
PFOA
309
0 247 4 70
PFNA 260 0.268 507
PFDA 0 510 0 259 5 38
PFUnA 0 290 0 256 P FD oA U 0 255 PFBS U 0 254 PFHxS 6 03 0 255
5 4
67 90
PFOS 886 0258 PFOSA U 0 250
550
LABELED COMPOUND LAB
SPIKE
CONC . R(q, f RETENTION
FLAG ' CONC . FOUND TIME
(n9) (n9)
13C-PFOA 13C-PFDA
120 120 10
7 69 64 1 4 70
3
858
5 34
(1) U = not detected (2) R ( I ) = Percent recove ry
15535PFO2_1 ids. S2
Approved by;
OA/0C Chemist
24-0&2005 dd-mm-yyyy
(3) Concentrations are blank-correcte d O][(C4 AXYS ANALYTI C~L SER\/I(Z :ES LT C:> to BOX 2219 . 2045 RUltS BO WES). SIONEY. ! t .(AIIADA YOt 358 fit 1250) 655-580111AII (Z50) 655m] 1
,~ ~
p . 11
AXYS METHOD MLA-042 Rev 02 PFOS s1 ot2 Form 1A/ 2
PERFELORINATEO ORGANICS ANALYSIS REPOR T
CLIENT ID :
Sample Collection, 28-Jun-2005 10 :30
Lab Name: AXYS ANALYTICAL SERVICE S
Contract No_:
4191 Lab Sample ID: L7932-2
Matrix :
SERUM
Sample Size : 1 00 mL
Sample Receipt Date: 29-Jun-2005 Initial Calibration Date : 05-Aug-2005
Extraction Onto. 04-Aug-2005
Instrument ID : LC-MSIMS
Analysis Onto: 05-Aug-2005 Time : 21 :42 :08 LC Column ID: C18. Zorbax XDH
Extract Volume (rnL) 2 Sample Datafile: FCSG_131S042
Injection Volume (NL): 300
Blank Data Filename: FCSG_131S024
Dilution Factor:
NIA
Concentration Units : nglm L
Cal. Ver. Data Fllename: FC5G_1315037 CAL VER ID : PFC-UN-039CS-F
COMPOUND LAB CONC DETECTION RETENTION FLAG' FOUND LIMIT TIME
PFPeA U 0 638 PFHxA U 0 620 PFHpA U 0 25 1 PFOA 242 0 247 PFRA 1 48 0 268 PFDA U 0 259
4 5
70 07
PFUnA U 0 256
PFDoA U 0 255 PFBS U 0 254 PFHxS 6 23 0 255
4
90
PFOS 360 0 258 PFOSA U 0 25 0
550
LABELED COMPOUND LAB SPIKE CONC. R(+/ z RETENTION FLAG' CONC . FOUND TIME (n9) (n9)
13C-PFOA 12 .0 8 09 574 4 70 13C-PFDA 120 112 930 5 34
(1) U =not detected (2) R (%) = Percent recovery
16535PP02_t ,a: . sa Approved hy:
oAlaC
Chemist
29-0&2005
dd.,n,.ylyy
))H(Cs /~XYS AiV ALY7 ICAL SEI2N/ICES LTD to t012219, 2045 AM 40 INESI, SIOIOY 1[, ( OAOA YOE 350 iEt 1250) d55-5800 fN( (2501855-S01 1
~~
p . 12
AXYS METHOD MLA-042 Rev 03 CLIENT ID :
PFOS St 012 Form 1A1$ PERFLUORINATED ORGANICS ANALYSIS REPOR T
Lob Name: AXYS ANALYTICAL SERVICE S
Sample Collection : 31-Aug-2005 09 :56
Contract No. : 4191 Lab Sample ID: L7932-51 1(A)
Matrix :
SERUM
Sample Size; 1 00 mL
Sample Receipt date : 01-Sep-2005
Initial Calibration Date: 22-Sep-2005
Extraction Date:
21-Sep-2005
Instrument ID: LC-MSIM S
Analysis Date : 23-Sep-2005 Time : 0 :27:07 LC Column 10 : C1 8
Extract Volume (mL): 2 Injection Volume (pL): 100
Sample Datalile : FCSG_181SD53
Blank Data Filename :
FCSG 181S070
Dilution Factor Concentration Units : ng1m L
3
CaL Ver. Data Fllename : FC5G_181S048 CAL VER ID : PFC-LIN-055CS-F
COMPOUND LAB CONC DETECTION RETENTION FLAG' FOUND LIMIT TIME
PFPeA UO 0 639 PFHxA UD 0 620
PFHpA UO 0 628 PFOA 0 270 0 618 PFNA D 1 55 0 670 PFDA UD 0 64 8 PFUnA UD 0 641 PFDoA UD 0 638 PFBS UO 0 635 PFHxS D 5 27 0 638
PFOS D 285 0 645
PFOSA t1D 0 625
4 4
4 5
65 99
60 46
LABELED COMPOUND LAB SPIKE CONC. R (%)2 RETENTION FLAG CONC . FOUND TIME (n9) (ng)
13C2-PFOA O 120 1 1 4 949 4 65 13C4-PFOS (80) D 120 146 122 546 13C4-PFOS (99) O 120 135 1 13 645 13C2-PFDA D 12 0 10 1 838 5 36
(1) U = not detected : D= dilution dat a (2) R (%) = Percent recovery YSSB21'FD1_1 is s3 Approved by: QA/0C Chemist 2a-09-20dd0 -mm-5 9yy9
3))0 AX-NS AIVALYi-ICAL SEf2VI(::ES LT1ED, PO 80X 7219 . 7045 fAlttS 10 WEST. SIOOEY. I C . CA8A0A VOL 3581fL (250) 8555800 fAx 1150) 45S Sel l
_3 ~-
p . 13
AXYS METHOD MLA-042 Rev 08 CLIENT SAMPLE NO .
AXYS ANALYTICAL SERVICE S
Form 1A Sample Collection :
PERFLUORINATED ORGANICS ANALYSIS REPORT
26-Apr-2006 09:15
P .O. Box 2219, 2045 MILLS RD . WEST, SIDNEY, B .C ., CANADA V8L 3S8 TEL (250) 655-5800 FAX (250) 655-581 1
Contract No. : 4191 Lab Sample I.D . : L8863-3
Matrix :
SERUM Sample Size : 0.500 ml
Sample Receipt Date :
27-Apr-2006
Initial Calibration Date :
07-Jul-2006
Extraction Date : 06-Ju1-2006
Instrument ID : LC MS/MS
Analysis Date : 08-Jul-2006 Time : 09 :22 :30
Column ID : C1 8
Extract Volume (ul) : 2000 Sample Data Filename: FC6G 277 S : 24
Injection Volume (ul) : 15 Blank Data Filename :
FC6G 277 S : 21
Dilution Factor : N/A Cal. Ver. Data Filename:
FC6G 277 S : 14
Concentration Units : ng/m l
COMPOUND
LAB FLAG 1 CONC . DETECTION RETENTION
FOUND
LIMIT 71ME
PFBA
U
0 .604
PFPeA
U
0.472
PFHxA
U
0 .484
PFHpA
U
0 .532
PFOA 20 .1 0 .484 4 :48
PFNA
3.46 0 .680 5 :08
PFDA
0 .768 0 .536 5 :27
PFUnA 0 .642 0 .476 5-47
PFDoA
U
0 .568
PFBS
U
1 .20
PFHxS 7 .74 101
PFOS 53 .5 1 .00
PFOSA
U
0.460
4:59 5 :37
(1) Where applicable, custom lab flags have been used on this report, U = not detected .
Approved by : QA/QC Chemist
For "s Intemal Use Onty [ XSL Template: FC-FormIAxsl; Created: 12-hil-2006 16 :32 :12; Application: 3cMLTransformer-1 74 , ReportFilename: PFC_FC_LC_PFOA L8863-3_FormlAS1571308 .htrnt ; Wodcgroup_ WG19474; DesiFp ID : 332 J These pages are part of a larger report that may contain information necessary for full data evaluation
Page 1 of 1(WG19474 - PFC_FC_LC_PFOA_L8863-3_Form1A-SJ571308 .html )
~6
p . 14
AXYS METHOD MLA-042 Rev 02
PFOS Sl 012
Form tA 1 2
PERFLUORINATED ORGANICS ANALYSIS REPOR T
CLIENT 10 :
Sample Collection : 18-Aug-2005 18:15
Lab Name : AXYS ANALYTICAL SERVICES
Contract No . :
4191 Lab Sample ID: L7932-39 Y 4
Matrix-
SERUM Sample Size : 1 00 mL
Sample Receipt date : 23-Aug-2005 Initial Calibration Date : 12-Sep-2005
Extraction Date : 29-Aug-2005
Instrument ID: LC-MS/MS
Analysis Date: 13-Sep-2005 Time: 0 :18 :25 LC Column ID : C1 8
Extract Volume (mL) : 2 Sample Dataflle: FC5G_167S056
Injection Volume (NL): 300
Blank Data Filename : FCSG_167S031
Dilution Factor. NIA Concentration Units : nglrnL
Cal . Ver. Data Filename : FC5G_167SO4 4 CAL VER ID : PFC-LIN-044CS-F
COMPOUND
LAB CONC DETECTION RETENTION FLAG' FOUND UM1T TIME
PFPeA U 0 256
PFHxA U 0 248 PFHpA U 0 25 1 PFOA 9 66 0 247
4
70
PFNA
1 35 0 268 5 05
PFDA 0 375 0 259 5 36
PFUnA U 0 257
PFDoA U 0 255 PFBS U 2 5 4 PFHxS 4 52 2 55
4
87
PFOS 266 0 258 5 51
PFOSA U 0 250
LABELED COMPOUND LAB SPIKE CONC . R(x)2 RETENTION FLAG CONC . FOUND TIME (ng) (n9)
13C2-PFOA 120 9 15 762 4 70 13C4,PFOS(80) 120 138 115 5 56 13C4-PFOS(99) 120 128 107 5 56 13C2-PFDA 120 128 106 5 36
(1) U = not detecte d (2) R (%,) = Percent recovery
16755PF D2t xls si2 Approved by:
OA/OC Chemist
19-09-2005 dd~n-yyyY
-00 AXYS AtV ALYrI CAL SER\/ICES LT [D PO BOX 2 219- 2045 MNIS 10 WEST. SIOOEI.O (_ UOAOA Vii 3581E1 (250) 655S5 600 FAX 1250) 655 5811 /
p . 15
AXYS METHOD MLA-042 Rev 02
PFOS_51 U1? Form 1A1 2 PERFLUORINATED ORGANICS ANALYSIS REPOR T
Sample collection:
CLIENT IDt 15-Aug-2005 13:54
Lab Name: AXYS ANALYTICAL SERVICES
Contract No : 4191 Lab Sample ID : L7932-28 Y 2
Matrix : SERUM Sample Size:
1 00 mL
Sample Receipt date : 17-Aug-2005 Initial Calibration Date: 12-Sep-2005
Ex traction Dote: 29-Aug-2005 Instrument ID ; LC-MSIM S
Analysis Date: 12-Sep-2005 Time: 2210 :04 LC Column 10: C1 8
Extract Volume (mL): 2 Sample Dataflle: FC5G_167SO47
Injection Volume (NL) : 30 0
Blank Data Filename : FCSG_167S031
Dilution Factor:
NIA
Concentration Units : ng/mL
Cat
Ver-
Data Filename: FC5G_167SO4 4 CAL VER ID: PFC-LIN-044CS-F
COMPOUND LAB CONC DETECTION RETENTION FLAG' FOUND LIMIT TIME
PFPeA
U
0
25 6
PFHxA U 0 248 PFHpA U 0 25 1 PFOA 5 92 0 247
4
70
PFNA 1 32 0 268 PFDA 0 486 0 259
5
05 541
PFUnA 0 272 0 257 5 75
PFDoA U 0 255 PFBS U 2 54 PFHxS 3 76 2 55
4
87
PFOS PFOSA
U
295 0
0 258 5 56 250
LABELED COMPOUND LAB SPIKE CONC . R(y.)z RETENTION
FLAG
CONC. FOUND TIME
(n9) ing )
13C2-PFOA 13C4-PFOS(80) 13C4-PFOS(99) 13C2-PFDA
120
10 5
120 113
120 104
120 136
872 944 864
113
4 70 5 56 5 56
541
(1) U = not dete cted (2) R ( % ) = Percent recover y
18755PF_03_1 +Js 53
Approved by:
OAlOC Chemist
dd-mm.yyyy
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