Document zQ20jv2B5dpO9xgBLa4G7Jonz
SEVERN
TRENT
STL
STL Chicago
241 / Bond Street University Park, IL 6 0 4 6 6
Tel: 78 5 3 4 5 2 0 0 Fax: 70S 5 3 4 5211 www.stl-inc.com
SEVERN
TR ENT
L A B O R A I:o r i e iW :\,
JOB NUMBER: 232676
P r e p a r e d.;E d U C;
We t on So lue ion IllC . 1400 Weston Way C O L B U l C d h h g ^ b - 2.......
W e s t C h e s t e r ,:P:A 19 3 8 0 -14 99
P r o j e c t :Conf i.dent ial D e c a t u r FC 1r.vesc iq a t r on
At ce ncion : Ja i Kesari
.. '.Date-"::' 1 2 / 2 7 / 2 0 0 4 .
F - M a i 1 : r w r i g h t o s t l - i n c Tc o m
This Report Contains Leaders in Environmental Testing
_________ _________________ Date STL Chicago 2417 Bone] St reet University Park, IL 60466
PHONE: (708) * 3 4 - 5 2 0 0 FAX. . : (708) 534-521.1
) Pages
Severn (re n t Laboratories, Inc.
WET CHEMISTRY DATA PACKAGE CONFIDENTIAL DECATUR - FC INVESTIGATION
JOB# 232676
Data Summary............................................................... 1 Chain of Custody....................................................... 15 Case Narrative............................................................. 19 Raw Data...................................................................... 21
STL Chicago is part of Severn Treni Laboratori e??, Ine.
' SAMPLE INFORMATION Date: 12/27/2004
Job Humber.: 232676 Customer.,,: Weston Solutions, Ino. Attn...... : Ja Kesari
Project Number...... 20004891 Customer Project ID___ : CONFIDENTIAL DECATUR Project Description,... : Confidential Decatur - PC Investigation
'.Laboratory!! S e m p l e ID 232676-1 232676-2 232676-3 232676-4 232676-5 232676- 232676-7 2 3 2 6 7 6 -
... C u s t o m e r S a m p l e i d .!!!!!!!!:
DF9-S&-131R -0-0000 DF09-SB-131R-0-0005 OF 09-SB~131R-0-001 DF09-SB-131R-0-2 DF09-SB-131B--0000 DF09-SB-131B-0-0005 DF09-SB-131B-0-0010 D F0 9 TS B - 1 3 1 B - 0 - 00 20
' Matrix Soil Soil Soil soi l Soi L Soil Soil Soi L
Date !vsampled
.. ." ! T i m e ! Sampled
12/03/2004
13:15
12/03/2004
13:25
12//2004
13:40
12/08/2004
13:50
12/08/2004
14:20
12/08/2004
14:35
12/08/2004
14:50
12/08/2004
15:10
.Date
Time
R e c e i v e d ' R e c e i v e d
12/10/2004
10:00
12/10/2004
10:00
12/10/2004
10:00
12/10/2004
10:00
12/10/2004
10:00
12/10/2004
10:00
12/10/2004
10:00
12/10/2004
10:00
Page 1
1
STL Chcalo is part of Severn Trent Laboratories, Inc,
Job Number: 232676
. COSTCHER: W eston so l u t I o n s , I n c . : :
Customer Sampie ID: DFOV-SB-IBIS-0-0000 Date Sampled...... :12/08/2004 Time Sampled...... :13:15 Sairple Matrix..... :Soil
TEST ;METHOD Lloyd Kahn
:PARAMETER/TE ST ;DESCRI Pf [ON
Total Organic Carbon (Soils) TOC Average Duplicates, Solid
w
LABORATORY
TEST
RESULTS
PROJECT: CONFIDENTIAL DECATUR - TT' '
Laboratory Sample ID: 23276-T Date Received....... : 12/10/2004 Time Received....... : 10:00
D a te :12/27/2004 ATTN:.; J a i K e s a ri
SAMPLE RESULT 8100
FLAGS
MOL: 290
RL 1100
ID 2LUT [OM LIMITS BATCH DT DATE/TIME TECH
1
mg/Kg 137251
12/T4/04 1458 els
* In Description - Dry Wgt.
Page 2
STL Chicago is part of Severn Trent Laboratories, 3nc. Job Number: 232676
LABORATORY
TEST
RESULTS
Date :12/27/2C04
* [n Description = Dry Wgt.
Page 3
STL Chicago is part of Severn Treni Laboratories, Ine.
I
I Job Number: 232676
: CUSTOMER: Weston Solutions, Inc,
Customer Sample ED Date Sampled..... Time Sampled..... Saitple Matrix, ....
DF09-5E-131R-0-0010 12/00/2004 13:40
Soi \
TEST METHOD Lloyd Kahn
;PARANETER/TEST;D ESCR1PTION:
Total Organic Carbon (Soils! TOC Average Duplicates, Solid
LABORATORY
TEST
RESULTS
PROJECT: CONFIDENTIAL DECATUR
Laboratory Sample ID: 232676-3 Date Received....... : 12/10/2004 Time Received....... : 10:00
Date:12/27/2004 ATTN: /ai Kesari : .
1
:SAMPLE RESULT 1700
FLAGS
MDL 22 D
RL
DE LUTEON
OMITS
B A T C H 07 DATE/TIME. TECH!
070
mg/Kg
137251
12/14/04 1533 els
* In Description = Dry Wgt.
Page 4
STL Chicago is part of Severn Trent Laboratories, [nc.
if)
* In Description = Dry Wgt.
Page 5
STL Chicago is part of Severn Trent Laboratories, [nc.
to
* i n Description = Dry Wat.
Page 6
STL Chicago is part oi Severn Trent Laboratories, ]nc. Job hlunber: 232676
CUSTOMER: Weston So lut ions, Inc. ;/
LABORATORY
TEST
RESULTS
; PROJECT: CONFIDENTSAL DECATUR
Date:12/27/2004 ATTN : Jai Kesari ;/
* ]n Descrlption = Dry Wat.
Page 7
STL Chicago is part of Severn Trent Laboratories, Inc.
Job Number: 232676
I CUSTOMER: Weston solutions, Inc. :
Customer Sample ID: DF09-SB-131B-G-QOTQ Date Sampled......: 12/08/2004 Time Sampled..... : 14:50 Sample Hat ri y .... : Soil
TEST METHOD Lloyd Kahn
:PARAHETER/TEST DESCRIPIN
Total Organic Carbon (Soils) TOC Average Duplicates, Solid
QO
LABORATORY
TEST
RESULTS
/L;: PROJECT: CONFIDENTIAL DECATUR
Laboratory Sample ID: 232676-7 Date Received....... : 12/10/2004 Time Received....... : 10:00
Date:12/27/2004 ATTN: Jai Kesari
SAMPLE RESULT ..0 FLAGS : 2300
MOL 240
RL D LOT [ ON : UKITS- ' BATCH DT DATE/TIME TECH
950
mg/Kg 137258
12/15/04 1123
In Description = Dry Ugt.
Page 8
STL Chicago is part of Severn Treni Laboratories, Ino.
Job Number: 232676
CUSTOMER: Weston Solutionsr;tnc.
Customer Sample ID: DF09-SB -13TB-Q-Q2 Date Sampled...... :12/08/2004 Time Sampled...... :15:10 Sample Matrix..... :Soil
TEST METHOC Lloyd Kahn
:PARAMETER/TEST DESCRl PT]Ok .
Total Organic Carbon (SoiIs) TOC Average Duplicates, Solid
O
LABORATORY
TEST
RESULTS
; PROJECT: CONFIDENTIAL DECATUR :;
Laboratory Sample ID: 232676-3 Bate Received....... : 12/10/2004 Time Received....... : 10:00
Date:12/27/2004 .ATTN : Jai Kesari
SAMPLE RESULT !q /LAGS: 1700
MDL: 220
RL DILUTION ! UNITS . BATCH BT DATE/TIME TECH
870
mg/Kg
137258
12/T5/04 1139 c Is
* In Description = Dry Wgt.
Page 9
STL Chicago is part of Severn Trent Laboratories, Inc.
Job Number: 232676
LABORATORY
CHRONICLE
Date: 12/27/2004
CUSTOMER: Westen Solutions, . . l n c ; \ ..
. PROJECT:.' CONFIDENTIAL DECATUR
ATTN: Jai Kesari
Lab ID: 232676-1 METHOD
EDD Lloyd Kahn
Client ID: DF9-SB-131K-0-D000 DESCRIPTION Electronic Data Deliverable Totat Organic Carbon (Soils)
Lab ID: 232676-2 Client ID: DF9-SB-131R-0-0005
METHOD
DESCRIPTION
Lloyd Kahn
Total Organic Carbon (Soils)
Lab ID: 232676-3 Client ID: DF09'SB-131R-Q-010
METHOD
DESCRIPTION
Lloyd Kahn
Total Organic Carbon (Soils)
Lab ID: 232676-4 Client ID: DF09-SB-131R -0-0020
METHOD
DESCRIPTION
Lloyd Kahn
Total Organic Carbon (Soils)
Lab ID: 232676-5 Client ID: DFD9-SB-131B-0-00O
METHOD
DESCRIPTION
Lloyd Kahn
Total Organic Carbon (Soils)
Lab ID: 232676-6 Client ID: DF09-SB-131B-0-005
METHOD
DESCRIPTION
Lloyd Kahn
Total Organic Carbon (Soils)
Lab ID: 232676 -7 METHOD
Lloyd Kahn
Clieht ID: DF09-SB-131B--0010 DESCRIPTION Total Organic Carbon (Soils)
Lab ID: 232676-8 Client ID: DF09-SB-131B-0-020
METHOD
DESCRIPTION
Lloyd Kahn
Total Organic Carbon (Soils)
Date Recvd: 12/10/2Q4 Sample Date: 12/08/2004
RUN# BATCH# PREP BT #CS)
DATE/TIME ANALYZED
1
1 137251 137251
12/14/2004 1458
DILUTION
Date Recvd: 12/10/2004 Sample Date; 12/08/2004
RUN# BATCH# PREP BT #<$)
DATE/TIME ANALYZED
1 137251 137251
12/14/2004 1513
DILUTION
Date Recvd: 12/10/2004 Sample Date: 12/08/2004
RUN# BATCH# PREP BT #(S)
DATE/TIME ANALYZED
1 137251 137251
12/14/2004 1533
DILUTION
Date Recvd: 12/10/2004 Sample Date: 12/08/2004
RUN# BATCH# PREP BT #(S)
DATE/TIME ANALYZED
1 137251 137251
12/14/2004 1553
DILUTION
Date Recvd: 12/10/2004 sample Date: 12/08/2004
RUN# BATCH# PREP BT #(5)
DATE/TIME ANALYZED
1 13725S 137258
12/15/2004 1032
DILUTION
Date Recvd: 12/10/2004 Sample Date: 12/08/2004
RUN# BATCH# PREP BT #(S)
DATE/TIME ANALYZED
1 137258 137258
12/15/2004 1109
DILUTION
Date Recvd: 12/10/2004 Sample Date: 12/08/2004
RUN# BATCH# PREP BT #(S)
DATE/TIME ANALYZED
1 137258 137258
12/15/2004 1123
DILUTION
Date Recvd: 12/10/2004 Sample Date: 12/08/2004
RUN# BATCH# PREP BT #(S)
DATE/TIME ANALYZED
1 137258 137258
12/15/2004 1139
DILUTION
Page 10
id
Job Number.: 232676 CUSTOMER; Westen Solution?., Inc.
QUALITY CONTROL RESULTS PROJECT: CONFIDENTIAL DECATUR
Report Date.: 12/27/2004 ATTM: Jai Kesari
Test Method:-t
Lloyd Kahn
Method Description:! ..total Organic carbon (Sol Is)
Pa rame tor .:!.!;t : . :: organic Carbon, Tot. (TOC) '
QC Lab ID
Reagent
Uni ts
ICV 137251-002 I04LSTTC2 MB 137251-003 LCS 137251-004 JQ0FSTLK3
LCD 137251-005 I0FSTLK3
mg/Kg mg/Kg mg/Kg mg/Kg
QC Result
QC Result
1845.40
32.00 U
5253.57
3766.01
5253.57
CCV 137251-015 I04LSTTC2 CCB 137251-016 CCV 137251-015 I4LSTTC2
CCB 137251-016
mg/Kg mg/Kg mg/Kg mg/Kg
1912.79 32.00
1946.33 32.00
U u
Batch..... Equipment Code ... : TDC-i
Analyst...: els Test Code.: TUC ..-
True Value 2000.00
4780.00 4780.00
2000.00
2000.00
orig. Value QC Calc. F * Limi ts
Date Time
202.37 182.86
92
U no U 79
33 96
97
% 85-115 12/14/2004 0912 12/14/2004 0915
% 53-140 12/14/2004 0924 % 53-140 12/14/2004 0945 * R 30 % 85-115 12/14/2004 1238
12/14/2004 1244 % 85-115 12/14/2004 1622
12/14/2004 1626
Test -Method.
Lloyd Kahn
Method Description.. Total Organic Carbon (Soils)
. Parameter..
:' Organic CarborT; Tot. (TOC) .
' Batch..... ,..... .'..;Equi pment :Code...
';A n a l y s t . ..els Test Code.: TOC
QC Lab ID
Reagent
Units
QC Result
QC Result
True Value orig. Value QC Calc. F it Limi ts
Date Time
ICV 137258-002 I04LSTTC2 MB 137258-003 LCS 137258-004 I00F5TLK3 LCD 137258-005 I00FSTLK3
mg/Kg mg/Kg mg/Kg mg/Kg
2155.26 32.00
4127.36 4745.15
l) 4127.36
2000.00
4780.00 4780.00
108
196.92 U 86 187.55 U 99
% 85-115 12/15/2004 0908 12/15/2004 0915
% 53-140 12/15/2004 1016 % 53-140 12/15/2004 1024
CCV 137258-015 104LSTTC2 CCB 137258-016
CCV 137258-015 I04LSTTC2 CCB 137258-016
mg/Kg mg/Kg mg/Kg mg/Kg
2208.49 32.00
1927.07 32.00
U u
2000.00 2000.00
n o % 85-115 12/15/2004 1501 12/15/2004 1508
96 % 85-115 12/15/2004 1621 12/15/2004 1623
"Test Method. ;:-.;v:.f :!"!L'<nyd Kahn
Method Description.. :..Tott Organic Carbon (Soi ls)
Parameter... -. .
TOO Average Duplicates
QC Lab ID
MS 232676-8 MSD 232676-8
Reagent
Uni ts
I04LSTTC2 mg/Kg I04LSTTC2 mg/Kg
QC Result
5728.26 6999.00
QC Result 5728.26
Batch___ ;.
137258
Equipment code ___ : TOC4 '
Analyst.. .: els ' Test ..Code .: TOCAV2
True Value
2000.00 2000.00
Orig. Value
1731.20 1731.20
QC Calc. F * Limits
Date Time
100.3 147
3S
% 53-140 12/15/2004 1155 N 12/15/2004 1350
Page 11
* %=tt REC, R=RPD, A=AB5 Diff.F D=% Diff.
aJltr/ I
Q U A LH--TvY/;!/; A S S 'J R A N C E H F H D D S R E f E R E N C E S AND n o t e s Report Date: .H/27/Z0QA.
REPORT COMMENTS 1) All pages of this report are integral parts of the analytical data. Therefore, this report should
be reproduced only in its entirety, 2} Soil, sediment and sLudge sample r-esuLts are reported Dn a "dry weight11 basis except when analyzed for
landfill disposal or incineration parameters. All other solid matrix sampLes are reported oh an "as received" basis unless noted differently. 3) Reporting limits are adjusted for sample size used, dilutions and moisture content if applicable. A) The test results for the noted analytical method(s) meet the requirements of NELAC. Lab Cert, ID# 100201 5) According to AOCFR Part 136.3, pH, Chlorine Residual and Dissolved Oxygen analyses are to be performed iimnediately after aqueous sample collection. When these parameters are not indicated as field (e.g. pH field) they were not analyzed immediately, but as soon as possible on laboratory receipt.
Glossary of flags, qualifiers and abbreviations (any number of which may appear in the report) Inorganic Qualifiers (Q-Column) U Analyte was not detected at or above the stated limit. < Not detected at or above the reporting limit, j Result is less than the RL, but greater than or equal to the method detection Limit. B Result is less than the CRDL/RL, but greater than or equal to the IDL/MPL. S Result was determined by the Method of Standard Additions. F AFCEE: Result is legs than the RL, but greater than or equal to the methoddetection limit. Inorganic Flags (Flag colurnh)
lev,CCV,ICE,CCB,ISA,I SB,CRI,CRA,MRL; Instrument related QC exceed the upper or lower control limits. * LCS, LCD, MD: Batch QC exceeds the upper or lower control limits, + MSA correlation coefficient is Less than 0,995. A MS, MSD: The analyte present in the original sample is A times greater than the matrix spike concentration; therefore, control limits are not applicable. E SD: Serial dilution exceeds the control limits. H MB, EBl, ERZ, EB3: Batch QC is greater than reporting Limit or had a negative instrument reading Lower than the absolute value of the reporting limit. N MS, MSD: Spike recovery exceeds the upper or lower control limits. W AS(GFAA) Post-digestion spike was outside 85-115% control Limits, organic Qualifiers (Q - Column) U Analyte was not detected at or above the stated Limit, ND Compound not detected. J Result is an estimated value beLow the reporting limit or a tentatively identified compound (TIC). Q Result was qualitatively confirmed, but not quantified. C Pesticide identification was confirmed by GC/MS. Y The chromatographic response resembles a typical fuel pattern. Z The chromatographic response does not resemble a typical fuel pattern. E Result exceeded calibration range, secondary diLution required. F AFCEE:Result is an estimated value below the reporting Limit or atentativelyidentified compound (TIC) Organic Flags (Flags Column) B MB: Batch QC is greater than reporting Limit. * LCS, LCD, ELC, ELD, CV, MS, MSD, Surrogate: Batch QC exceeds the upper or Lower controllimits. EBl, EB2, EB3, MLE: Batch QC is greater than reporting Limit A Concentration exceeds the instrument calibration range a Concentration is below the method Reporting Limit (RL) B Compound was found in the blank and sample. D Surrogate or matrix spike recoveries were not obtained because the extract was diluted for analysis; also compounds analyzed at a dilution will be flagged with a D. H Alternate peak selection upon analytical review I Indicates the presence of an interfence, recovery is not calculated. M Manually integrated compound. P The lower of the two values is reported when the % difference between the results of two GC columns is
Page 12
o, - r
Q U A L I T Y A S S U R A N C E M E T H 0 D S'
. R E T E R E N C E S AND .NO TE S
Report Dato; 12/27/2D4
.
greater than 25%.
Abbreviations
AS Post Digestion Spike (GFAA Samples - See Note 1below)
Batch Designation given to ident if/ a specific extraction, digestioh, preparation set, or analysis set
CAP Capillary Column CCB Continuing Calibration Blank
CCV continuing Calibration Verification
CF Confirmation analysis of original
C1 Confirmation analysis Df A1 or DI
C2 Confirmation analysis of A2 or D2
C3 Confirmation analysis of A3 or D3
CRA Low Level Standard Cheek - GFAA; Mercury
CRI Low Level standard Check - ICP
CV Calibration Verification Standard
Dil Fac Dilution Factor - Secondary di luti.on analysis
D1 Dilution 1
D2 Di lut ion 2
D3 Dilution 3
DLFac Detection Limit Factor
DSU Distilled standard ' High Level
DSL Distilled Standard - Low Level
DSM Distilled Standard - Medium Level
EB1 Extraction Blank 1
EB Extraction Blank 2
EB3 DI Blank
ELC Method Extracted LCS
ELD Method Extracted LCD
1c a l
Initial calibration
1CB initial Calibration BLank
Icv Initial Calibration verification
IDL Instrument Detection Limit
ISA interference Check Sample A - ICAP
ISB Interference Check Sample B - ICAP
Job No. The first six digits of the sample ID which refers to a specific client, project ahd sample group
Lab ID An S number unique laboratory identification
LCD Laboratory Control Standard Duplicate
LCS Laboratory Control Standard with reagent grade water or a matrix free from the analyte of interest
MB Method BLank or (PR) Preparation Blank
MD Method Duplicate
MDL Method Detection Limit
MLE Mediun Level Extraction Blank
MRL Method Reporting Limit Standard
MSA Method of Standard Additions
MS Matrix Spike
MSD Matrix Spike Duplicate
ND Not Detected
PREPF Preparation factor used by the Laboratory's Information Management System (L1MS)
PDS Post Digestion Spike (ICAP)
RA Re'analysi5 of original
A1 Re-ana lysis of DI
A2 Re-analysis of D2
A3 Re-analysis of D3
RD Re-extraction of dilution
RE Re-OXtraction of original
RC Re-extraction Confirmation
RL Repotting Limit
RPD Relative Percent Difference of duplicate (unrounded) analyses
RRF Relative Response Factor
RT Retention Time
Page 13
QUAL 1 T Y A S S U R A N C E MET R FERENC E S A D NOTE Report Date: 12/27/2004 :
RTW Retention Time Window Sample IP A 9 digit number unique for- each sample, the first
six digits are referred as the job number
SCB Seeded Control Blank
SD Serial Dilution (Calculated when sample concentration exceeds 50 times the MDL)
UCB Unseeded Control Blank
ssv Second Source verification standard
SLCS
Solid Laboratory Control Standard(LCS)
PHC pH Calibration Check LCSP pH Laboratory Control Sample
LCDP
pH Laboratory Control Sample Duplicate
MDPH
pH Sample Duplicate
MDFP
Flashpoint Sample Duplicate
LCFP
Flashpoint LCS
G1 Gelex Check Standard Range 0-1
G2 Gelex Check Standard Range 1-10
G3 Gelex Check Standard Range 10-100
G4 Gelex Check standard Range 100-1000
Note 1: The Post Spike Designation on Batch QC for GFAA is designated with an "S" added to the current
abbreviation used. EX. LCS S=LCS Post Spike (GFAA); MSS=MS Post Spike (GFAA)
Note 2: The MD calculates an absolute difference (A) wheh the sample concentration is less than 5 times the
reporting limit. The control limit is represented as +/- the RL.
Page 14
JL k
CHAIN OF CUSTODY
CHAIN OF CUSTODY /ANALYSIS REQUEST FORM
Severn Trent Laboratories
T: 708-534-5200
F: 708-534-5211
2417 Bond Street
University Park, IL 60466
PAGE j o f (
PROJECT INFORMATION Client: Weston Solutions, ine.
1400 Weston Way, Bldg. 5-2 West Chester, PA 193S0 T: 610-701-3761 F: 610-701-7401
Project Manager: Jai Kesari em aiE: i.kesariweston sol uti ons.confi
Project Name: Reference No:
Decatur, Alabama 02181-129-081-0001
| ANALYSES REQUESTED
Sampler:
T FrEnakr A Murphy
P.O. #: Quotation #:
SAMPLE ANALYSIS
ExyLIMS # \
z
S-
*7 A
Client Sample Identification j DF09 SB 131R 0 0000 DF09 SB 131R 0 0005 DF09 SB 131R 0 0010 DF09 SB 131R 0 0020 DF09 SB 131B 0 0000 DF09 SB 131B 0 0005 DF09 SB 131B 0 0010 DF09 SB 131B 0 0020
Collection Date
8-Dec-04 8-Dec-04 8-Dec-04 8-Dec-04 8-Dec>04 8-Dec-04 8-Dec-04 8-Dec-04
Collection Time 13:15 13:25 13:40 13:50 14:20 14:35 14:50 15:10
CHAIN OF CUSTODY
- R elm qut^rB y: ^ j,
Dgte
7/
Cooler ID No.:
Time
Received By:
Fej Ex
H I1 Q
Grab Sample Composite No. of Containers TOC
X1 X1 X1 X1 X1 X1 X1 X1
Sample
Matrix SOIL SOJL SOIL SOIL SOIL SOIL SOIL SOIL
1_____
_
Comments
0-3 INCHES
0.5-1.0 FEET
1.0-1.5 FEET
2.0-2.5 FEET
0-3 INCHES
0.5-1.0 FEET
1.0-1.5 FEET
2.0-2.5 FEET
X X X X X X X X
'
I
____I
PROJECT REQUIREMENTS
Cooler Temp. (C):
Results Deadline:
Date Time
Laboratory Report Options:
4(<?* t0 *
Sample Results Only Add Case Narrative Add Quality Control Summary Add Calibration Summary
Add Raw Data Other:
X t
Sample Lot#:
nS ' i l
(a
STL Chicago Internal Sample Custody Transfer Record
Client:
Coarti*
Sample No.
Analysis
-i W L* .
Relinquished by: Received by:
,, y jr 1O
T S ^ P
TJ
Date
Time
Comments
p ' / ' i ' W a : JT)
al- fi
CHI-22-11-001/C-1/99
rpjsckl
Job Sample Receipt Checklist Report
Joh Number.: 232676
Location.: 57222 Check List Number,: 1
Description.:
Customer Job ID....,:
Job Check List Pate.: 12/10/24
Project Number.: 20004891 Project Description.: Confidential Decatur - FC investigation
Customer...... : Weston Solutions, Inc.
Contact.; .Jai Kesari
Questions ?
(Y/N) Comment;
V2
Date of the Report..: 12/27/204 Project Manager.... : rew
Choin-of-Custody Present?.......................... Y
Were samples dropped oft at or picked up by STL?.. N
Custody seal on shipping container?..... ......... Y
...If '`yes", custody seal intact?................. Y
Custody seals on sample containers?..,........... N
...If "yes", custody seal intact?...............
Samples iced?................................
Y
Temperature of cooler acceptable? (4 deg C +/- 2). Y 3.8
Samples received intact (good condition)?........ Y
Volatile samples acceptable? (no headspace)......
Correct containers used?........................ Y
Adequate sample volume provided?.................. Y
Samples preserved correctly?...................... Y
Samples received within hoLding-time?.........
Y
Agreement between COC and sample labels?......... Y
Radioactivity at or below background levels?...... Y
A Sample Discrepancy Report (SDR) was needed?..... N
If sampLes were shipped was there an air bill #?.. Y
Sample Custodian Signature/Date................... Y
Page 1
17
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CASE NARRATIVE
Client: Job#:
STL Chicago Wet Chemistry Case Narrative
Weston Solutions, Inc, 232676
D ateR ec'd: 12/10/04
1. This narrative covers the analysis of the samples in the above Job ft for TOC by the Lloyd
Kahn Method.
The samples were analyzed for TOC in duplicate by furnace combustion and nondispersive infrared detection on a Dohrmann Phoenix 8000 TOC analyzer, after acidification to remove inorganic carbon, and drying. No correction was made, therefore, for moisture content. The average o f the sample burns is reported.
2. The method-recommended holding time o f 2 weeks was met. Refer to the Laboratory Chronicle Page for dates o f sampling, receipt, and analysis.
3. The TOC calibration curve and the initial and continuing verification standards and blanks met acceptance criteria.
4. The method blanks were less than the reporting limit.
5. The LCSs were within acceptance limits, although the RPD between the LCS and LCD in batch 137251 was high, at 33,
6. Duplicate matrix spikes were done on sample 2.32676-8. The MS recovery was within acceptance limits, at 100%, but the MSD was high, at 147% recovery. The RPD between the MS and MSD was high, at 38. Please see the Quality Control Results pages for additional detail,
7. On the first attempt for sample 232676-3, the analyst failed to insert the sample boat into the furnace within the allotted time window, and the result, an erroneous non-detect, was not reported. The same thing happened at the second burn attempt for sample 232676-5, but that burn was cancelled.
Diane L. Harper Wet Chemistry Section Manager
RAW DATA
7 dC
#** RUN LOG
***
<V2 )
12/17/04 12:12
Total Organic Carbon (Soils) Method Code..: TOCS Batch Code...: 137251
Status,..-... RVWD Batch Date... 12/16/04 Batch Time... 1228
User Name..... : els GC Code.... ...: TOCS Calc Code...,,.: TOCS
Location Code..: 57222 Equipment Code.: T0C4 Iirport Code--- ;
TEST CODE
TTTTTTTTTTT TT
00OO0O CCC I11
cCCCCcCSssCCC
234AAA 2Ass5
VVV
V 2A
234 2 2
SAMPLE: Grp Pos Sample ID
Di lution
TEST POS Date / Time
123 456 7 11 122 2 789 0 12
11
___ICAL_I04LSTTC1_
0
12
___ICV_I04LSTTC2_
12/14/04 0912 0
15
___MB__
12/14/04 0915 0
14 15
___LCS_IQ0FSTLK3_3 ___LCD_I00FSTLK3_3
12/14/04 0924 0 12/14/04 0945 *
16
232472J 4 J ___
12/14/04 0954
0
17
23 24 72_14_S_MS_104LSTTC2_6
12/14/04 1Q19
0
18
232472J 4^S_MSD_104LST Tc2_fi
12/14/04 1026
0
19
232472_15_S___
12/14/04 1036
0
1 10 232472_16_S___
12/14/04 1052
0
1 11 252472 17 S
12/14/04 1117
0
1 12 232472 18 S
12/14/04 1135
0
1 13 232472_19_S___
12/14/04 1153
0
1 14 232472m 20_S___
12/14/04 1218
0
1 15 __ CCVJ04LSTTC2_
12/14/04 1238 0
1 16
CCB__
12/14/04 1244 0
1 17 232472_21_S___
12/14/04 1257
0
1 18 232472_22_S___
12/14/04 1355
0
1 19 1 20 1 21
232472_23_Su__ 232472_24_S___ 232676_1_S___
12/14/04 1426 --
12/14/04 1444
12/14/04 1458
0
0
....
0
1 22 232676^25___
12/14/04 1513
0
1 23 232676_3_S___
12/14/04 1533
0
1 24 232676 4 S
12/14/04 1553
0
1 25 ___CCV_104LSTTC2_
12/14/04 1622 0
1 26 ___CCB__
12/14/04 1626 0
Page 1
--
*** OC SuTITtry
m>
Total Organic carbon (SoLs)
Report pate; 12/17/04 12:12
Method Code..: TOCS Batch Code...: 137251 Status....... : Rvup
Batch Date...: 12/16/04 Batch Time...: 1228 User Name :els
QC Code........ : TOCS Calc Code......: TOCS Location Code..: 57222
Equipment Code.: T0C4 irrport Code....:
Grp Smp Sample IP
Pcs Test Result
Known
Original Alternate GC Res F QC Res F
12
ICV IQ4LSTC2
1 TOC 1845.40 2000
92
1 3 ___MB__
1 TOC -3.31
14 15
___ LC_I0QFSTLK3_3 ___LCD_I00FSTLK3_3
1 TOC 1 TOC
5253.57 3766.01
4780 4780
-3*31 -3.31
5253.57
110 79
33 *
1 7 Z32472J4^S_MS_104LSTTC2_
1 8 232472 14_S_MSD_IQ4L STTC2_6
1 15 ___CCV_il04LSTTC2_
1 16
CCB
5 TOCAV2 28670.30 2000 5 TOCAV2 27895.17 2000 1 TOC 1912.79 2000 1 TOC -2.58
13600.90 13600.90
28670.30
95 91 96
5
1 25
CCV I04LSTTC2
1 26 ___CCB__
1 TOC 1 TOC
1946.33 -2.56
2000
97
Page 1
*** RAW TEST DATA
***
<V2 )
Total organic Carbon (Soils)
Method Code,. rocs Batch Code... 137251 Status....... RVWD
Batch Date...: 12/16/04 Batch Time...: 1228 User Marne___ : els
SAMPLE:
Grp Pos Sample ID
11
tCAL I04LSTTC1
12
ICV I04LSTTC2
13
MB
14
LCS 100FSTU3 3
15
LCD J0DFSTLK3 3
1 6 232472 14 S
1 7 232472 14 S MS IQ4LSTTC2 6
1 8 232472 14 S MSD I04LSTTC2 6^
1 9 232472 15 S
1 10 232472 16 S
1 11 232472 17 S
1 12 232472 18 S
1 13 232472 19 S
1 14 232472 20 S
1 15
CCV I04LSTTC2
1 16
COB
1 17 232472 21 S
1 18 232472 22 S
1 19 232472 23 S
1 20 232472 24 S
1 21 232676 1 S
1 22 232676 2 S
1 23 232676 3 S
1 24 232676 4 S
1 25
CCV I04LSTTC2
1 26
CCB__
QC Code... Calc Code. Location Code..: 57222
Di luti on
TOC mg/Kg
T0C2 mS/Kg
Report Date: 12/17/04 12:12
Equipment Code.: TOC4 Iirewrt Code,... :
T0C3 mg/Kg
T0C4 mg/Kg
QCAV2 mg/Kg
1845.40 -3.31 5253.57 3766.01 14295.89 28670.30 27895.17 12274.05 19750.03 13700.38 12711.67 18230.22 3597.36 1912.79
-2.53 38990.97
1945B.21 6678.50 4123,68 3533.01 5555.61 1965.99 1532.89 1946.33
'2.56
12905.90
14946.84 22226.99 12114.72 11678,18 18103.89 1649*59
39113.10 18206.35 B473.30 3893.25 7579.76 4477.76 1512.31 1327.76
13600.90 2B670.30 27895*17 13610.44 20988.51 12907.55 12194.92 13167.06 2623.72
39052.04 18332.28 7575.90 4008.47 8056.39 5016.68 1739*15 1430.33
Page 1
4
*#* RAW TEST DATA
***
(V2 )
Total Organic Carboh (Soils)
Method code..: TOCS
Batch Code .**: 137251
status___
RVWD
Batch Date...: 12/16/04 Batch Time__ : 1228 User Mame.... : tls
SAMPLE:
Grp Ros Sample ID
11
ICAL I04LSTTC1
12
ICV I04LSTTC2
13
MB
14
LCS I0FSTLK3 3
15
LCD IDDFSTLK3 3
1 6 232472 14 S
1 7 232472 14 S MS I04LSTTC2 6
1 8 232472 14 S MSD I04LSTTC2 6
1 9 232472 15 S
1 10 232472 16 S
1 11 232472 17 S
1 12 232472 18 S
1 13 232472 19 S
1 14 232472 20 S
1 15
CCV I04LSTTC2
1 16
CCB
1 17 232472 21 S
1 18 232472 22 S
1 19 232472 23 S
1 20 232472 24 S
1 21 232676 1 S
1 22 232676 2 S
1 23 232676 3 S
1 24 232676 4 S
1 25
CCV I04LSTTC2
1 26
CCB
oc Code...
TOCS
Calc Code. .... : TOCS
Location Code..; 57222
Dilution
TQCAV3
mg/Kg
TCAV4 mg/Kg
Report Date: 12/17/04 12:12
Equipment Code.: TOC4 import Code
T0CR1 ug
TQCR2 ug
T0CR3 ug
92.2698 -0.5304 132.9154 105.4482 100.0712 180.6229 178.5291 169.3819 183.6753 135.6338 111.8627 187.7713 35.9786 95.6397
-0.4125 386.0106 266.5775 79.4741 72.1644 160.4206 100.0009 39.9095 43.5342 97.3167 -0.4104
114.8625
182.3515 173.3705 95,7063 133.1313 204.5740 25.2388
320.7274 205.7318 94.0536 76.6971 125.8240 97.1674 39.1688 37.4427
Page 2
; P--*
*** RAW TEST DATA
***
<V2 )
Total Organic Carbon (SoiLs)
Method Code .: TOCS Batch Code, *: 137251 status.... .: RVWD
Batch Date.. : 12/16/04 Batch Time.. : 1228 User Name... : Cl3
SAMPLE:
Grp Pos Sample ID
11
ICAL I04LSTTC1
12
ICV I04LSTTC2
13
MB
14
LCS 1Q0F5TLK3 3
15
LCD I00FSTLK3 3
1 6 232472 14 S
1 7 232472 14 S MS I04LSTTC2 6
1 8 232472 14 S MSD 104LSTTC2 6-
1 9 232472 15 S
1 10 232472 16 S
1 11 232472 17 S
1 12 232472 13 S
1 13 232472 19 S
1 14 232472 20 S
1 15
CCV I04LSTTC2
1 16
CCB
1 17 232472 21 S
1 IS 232472 22 S
1 19 232472 23 S
1 20 232472 24 S
1 21 232676 1 S
1 22 232676 2 S
1 23 232676 3 S
1 24 232676 4 S
1 25
CCV I04L5TTC2
1 26
CCB
QC Code...... Calc Code*___ Location Code. -i 57222
Dilution
T0CR4 ug
UT1 g
Report Date: 12/17/04 12:12
Equipment Code.: TC4 Import Code..*.:
UT2 WT3 ag
WT4 3
0.05 0.16
.Q253 0.0280 0.0070 0.0063 0.0064
0.0138 0.0093 0.0099 0.0038 0.0103 0.0100 0.05 0.16 0*0099 0.0137 0.0119 0.0175 0.0188 0.018Q 0.0203 0.0234 0.05 0.16
0.0089
0,0122 0.0078 0.0079 0*0114 0.0113 0.0153
0.0082 0.0113 0,0111 0.0197 0.0166 0.0217 0.0259 0.0282
Page 3
*** RAW TEST DATA
**
Total Organic Carbon (Soils)
Method Code..: TOCS Batch code... : 137251 Status....... : RVWD
Batch Date.. : 12/16/04 Batch T ime.. : 1228 User Name... : els
SAMPLE:
Grp Pos Sample ID
11
ICAL IQ4LSTTC1
12
ICV 704LSTTC2
13
MB
14
LCS I0QFSTLK3 3
15
LCD I0FSTLK3 3
1 6 232472 14 S
17
1a
232472 14 S MS I04LSTTCZ 6 232472 14 S MSD I04LSTTC2 6-
1 9 232472 15 S
1 10 232472 16 S
1 11 232472 17 S
1 12 232472 18 S
1 13 232472 19 $
1 14 232472 20 S
1 15
CCV I04LSTTC2
1 16
CCB
1 17 232472 21 S
1 18 232472 22 S
1 19 232472 23 S
1 20 232472 24 S
1 21 232676 1 S
1 22 232676 2 S
1 23 232676 3 S
1 24 232676 4 S
1 25
CCV I04LSTTC2
1 26 ___CCB__
oc code.___
TOCS
CaLc Code..... : TOCS
Location Code..: 57222
Dilution
DLFAC H/A
TCS mg/Kg
3.2000 1.0000 6.3241 5.7143 20.1258 25,3968 25.0000 12.3077 18.7135 17.9775 15.8416 14.8148 12.6482 3.2000 1.0000 17.6796 12.8000 13.9130 8.6022 9.0395 8,0605 6.9264 5.6537 3.2000 1,0000
<VZ )
Report Date: 12/17/04 12:12
Equipment Code.: TQC4 Import Code___ :
TCS2 mg/Kg
TCSAV2 mg/Kg
TICS mg/Kg
Multiple Analysis Report Print Date/Time: 2004/12/1511:25:58
Sample ID
Result Std, Dev. RSD Mode ALT
ICV
92.2698
TC
ICB-MB
-0.5304
TC
LCS
132.9154
TC
LCD................................ 105.4482............. ...TC ..
232472-14
100.0712
TC
232472-14
114.8625
TC
232472-14ms........ ............... -0.3342...
.......... TC
232472-14ms
180.6229
TC
232472-14ms
178.5291
TC
232472-15............. ............ 1693819...
.......... TC
232472-15
182.3515
TC
232472-16
183.6753
TC
232472-16............. ............ 173.3705...
...........TC
232472-17
135.6338
TC
232472-17
95.7063
TC
232472-18............. ............ 111.8627...
...........TC
232472-18
133.1313
TC
232472-19
187.7712
TC
232472-19.......................... 204.5740... ...........TC
232472-20
35.9786
TC
232472-20
25.2388
TC
c c v ....................... ........ 95.6397.............. ...TC ,,
CCB
-0.4125
TC
232472-21
386.0106
TC
232472-21.......................... 320.7274...
.......... TC
232472-22
0.2170
TC
232472-22
266.5775
TC
232472-22.......................... 2057318... ...........TC
232472-23
79,4741
TC
232472-23
94,0536
TC
232472-24............. ............ 72.1644...
...........TC
232472-24
76,6971
TC
232676-1
160.4206
TC
232676-1........................... 125.8240...
.......... TC
232676-2
100.0009
TC
232676-2
97,1674
TC
232676-3................ ........... 0.5417............ . ...TC ..
232676-3
39.9095
TC
232676-3
39.1688
TC
232676-4................ .......... 43.5342...
.......... TC .
232676-4
37.4427
TC
CCV
97.3167
TC
CCB....................... ........ -0.4104.............. ...TC ..
Calibration Report Print Date/Time: 2004/12/15 7:57:25
Cal. Curve ID:
SOILCURVE
Created:
12/13/200413:36
Calibration Factor (m): 9,841e+04
Y Intercept (b): -250134
r-squared:
0.99935
Standard ID Y X Expected Measured Message
Date &
Raw Data ug C ug C
Time
0 ugram C
-8891 0.000 2 451 No Sample Det 12/13/2004 11:24
10ugramC
911065 10.000 11.800
12/13/2004 11:42
20 ugram C 1853385 20.000 21.375
12/13/2004 11:48
40 ugram C 3745719 40.000 40.605
12/13/2004 12:04
120 ugram C 11194916 120.000 116.302 Endpoint Time 12/13/200412:28
200 ugram C 18654032 200.000 192.099
12/13/200412:46
300 ugram C 29462156 300.000 301.928
12/13/2004 12:59
400 ugram C 39451668 400.000 403.439 Endpoint Time 12/13/200413:19
Detailed Analysis Report Print Date/Time: 2004/12/15 11:26:07
Sample ID: ICV Method: boat CaL Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12140906
Timestamp: 12/14/2004 09:12 Sample Type: Cal. Verification-^-
Rep # ppm C ug C Raw Data Beginning Ending Integration
Baseline Baseline Time
1 92.2698 92.2698 8829986
0.935 1.934 292
Sample ID: ICB-MB Method: boat CaL Curve: SOILCURVE Operatorio: CAROL
Mode: TC Filename: 12140912
Timestamp: 12/14/2 Sample Type: Sample
Rep # ppm C ug C Raw Data Beginning Ending Integration
Baseline Baseline Time
1 -0.5304 -0.6304 -26435
1,499 1.164 120
Last Message: No Sample Detected
Sample ID: LCS Method: boat CaL Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12140918
Timestamp: 12/14/20 Sample Type: Sample
Rep # ppm C ug C Raw Data Beginning Ending Integration
Baseline Baseline Time
1 132,9154 132.9154 13105751
1.035 2.033 301
Sample ID: LCD Method: boat CaL Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12140940
Timestamp: 12/14/20 Sample Type: Sample
Rep # ppm C ug C Raw Data Beginning Ending Integration
Baseline Baseline Time
1 105,4482 105.4482 10402746
1.156 2.154 279
Sample ID: 232472-14 Method; boat CaL Curve: SOILCURVE Operator ID: CAROL
>Mode: TC Filenah^: 12140948
Timestamp: 12/14/201 Sample Type: Sample
Rep # ppm C ug C Raw Data Beginning EiTding Integration Baseline Baseline Time
1 35.9706 35.9 36 3566356
1.395 2.392 251
Sample ID: 232472-20 Method: boat Cal, Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12141221
Timestamp: 12/14/200412:25 Sample Type: Sample
R ep# ppm C ugC Raw Data >Beginning Ending Integration
Baseline BastoJine Time
1 25.2388 25.2388 2509477
1.649 2.619 212
Sample ID: CCV Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12141231
Timstamp: 12/14/2004/12:38J Sample Type: Cal. Verificar"
Rep # ppm C ug C Raw Data Beginning Ending Integration
Baseline Baseline Time
1 95.6397 95.6397 9161611
1.287 2.287 301
Sample ID: CCB Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC
Filename: 12141240
X
Timestamp: 12/14/2004 12:44
Sample Type: Sample ( /
Rep # ppm C ug C Raw Data Beginning Ending Integration
Baseline Baseline Time
1 -0.4125 -0.4125 -14830
1.526 1.376 120
Last Message: No Sample Detected
Sample ID: 232472-21 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC alenarne: 12141250
Timestamp: 12/14/2004/12:57 Sample Type: Sample
Rep # ppm C ug C Raw Data "Beginning Ending Integration
Baseline Baseline Time
1 386.0106 386.0106 38012440
f 7 2 2.272 392
Sample ID: 232472-21 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: ^TC Filename: 12141347
T im estam p \l 2/14/2004 13:53 Sample Type: Sample
Rep # ppm C ug C Raw Data Beginning Ending^ Integration
1 94.0536 94.^536 9281424
1.776 2.772 258
Sample ID: 2324^2-24 Method: boat Cal. Curve. SOILCURVE Operator ID. CAROL
Mode: TC Filename: 12141440
Timestamp: 12/14/200414:44 Sample Type: Sample
Rep# ppmC u g C \R a w D a t a Beginning Ending Integration
iseline Baseline Time
1 72.1644 72.1644 71^7342
5.742 6.734 214
Sample ID. 232472-24 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12141446
"imstamp: 12/14/2004 14:61 SarHple Type: Sample
Rep# ppmC ugC Raw Data Beginning Ending Integration Baseline Baseline \T im e
1 76.6971 76.6971 7573402 1.620 2^19 255
Sample ID: 232676-1 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC
Filename: 12141452
"
Timestamp: 12/14/200|4 14:68
Sample Type: Sample l /
Rep # ppm C ug C Raw Data Beginning Ending Integration
Baseline Baseline Time
1 160.4206 160.4206 15812496
2.668 3.667 277
Sample ID: 232676-1 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode; TC Filename: 12141501
Timestamp: 12/14/2004 15:06 Sample Type: Sample
Rep # ppm C ug C Raw Data Beginning Ending Integration
Baseline Baseline Time
1 125.8240 125.8240 12407897
2.536 3.531 253
Sample ID: 232676-2 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12141508
Timestamp; 12/14/201 Sample Type: Sample
R e p # p p m C u g C Raw Data Beginning Ending Integration Baseline Baseline Time
1 100.0009 100.0009 9866688
3.611 4,610 238
Sample ID: 232676-2 Method: boat CaL Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12141615
Timestamp. 12/14/2004 15:20 Sample Type: Sample
Rep # ppm C ug C Raw Data Beginning Ending Integration
Baseline Baseline Time
1 97.1674 97.1674 9587855
2.002 3.002 260
Sample ID: 232676-a
Method: boat \
&
Cal. Curve: SOILCURVE A
Operator ID: CAROL \ ^ | ^
Mode: TC Filename. 12141521
Timestamp: 12/14/200415:24
^ Sample Type; Sample
Rep # ppm C ug C Raw Data Beginning Ending Integration
Baseline Baseline Time
1 0,5417 0.5417 79068
1.978 1,731 120
Last Message: No Sample Detected
Sample ID: 232676-3 Method: boat Cal. Curve: SOILCURVE Operator (D: CAROL
Mode: TC Filename: 12141527
Timestamp: 12/14/2004 15:33 Sample Type: Sample V
Rep # ppm C ug C Raw Data Beginning Ending Integration
Baseline Baseline Time
1 39.9095 39.9095 3953190
1.397 2.396 309
Sample ID: 232676-3 Method, boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12141538
Timestamp. 12/14/2004 15:43 Sample Type: Sample
Rep # ppm C ug C Raw Data Beginning Ending Integration
Baseline Baseline Time
1 39.1688 39.1688 3880307
1.342 2.342 247
Sample ID: 232676^4 Method; boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12141548
Timestamp: 12/14/201 Sample Type: Sample
15:53
Rep # ppm C ug C Raw Data Beginning Ending Integration
Baseline Baseline Time
1 43.5342 43.5342 4309889
1.615 2.615
243
Sample ID: 232676-4 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12141606
Timestamp: 12/14/2004 16:10 Sample Type: Sample
Rep # ppm C ug C Raw Data Beginning Ending Integration
Baseline Baseline Time
1 37.4427 37.4427 3710442
1.649 2.644 228
Sample ID: CCV Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename:' 12141617
Timestamp: 12/14/20 Sample Type: Cal. Verify
Rep # ppm C ug C Raw Data Beginning Ending Integration
Baseline Baseline Time
1 97.3167 97,3167 9326640
1.347 2 346 301
Sample ID: CCB Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12141624
Timestamp: 12/14/20' Sample Type: Sample
Rep # ppm C ug C Raw Data Beginning Ending lnte$
Baseline Baseline Time
1 -0.4104 -0.4104 -14625
1.748 1.571 120
Last Message: No Sample Detected
STL Chicago
Page No.:
TOC in Soils
Book No.: 3 ^
Method: Lloyd Kahn
Instrument: Phoenix 8000 TOC4)
LabNet Batch: / 3 I J i
Calculation:
Date of Standard Curve:
~
TOC (mg/kg) = ug C / grams sample
Book#.?9 ^ 7 Page bo f
MS MSD Known Cone, (mg/kg) = 100 ug C / grams sample
MS, MSD Observed (mg/kg) * ug C / grams sample
MS, MSD Ree. = robserved mq/ko - ava, sample result fmq/kqil x 100
known concentration in mg/kg
standard Traceability: (Note; Working Standards are prepared daily from the noted Stock Solutions.)
Stock l (Curve)
$rrc !
Stock II (ICV/CCV)
LCS Source ID
LCS True Value Y 7 _____ Acceptance Range ~
_
Sample ID:
Sample Weight (g)
ug C
Comments:
~ ozjy
O-OX
f2
~
o. fC
~~ LC0
0.XS3 ' 0 2 fX Y
Tcp -3-z p z ~ /y
-1 - / v
!
__:__
:
[ f
tiuj.s>
1 - 7W
a, oo-'Z'o' .OO 6 - OOSf
c0O ? O- ^
1. YYft/OOey/z 'N\ ,n . <20 y
---
/t.C'irUjr
i^yob'tybbijAci C0nihix,-
~
( ^ / iir/s? ni. oo 0 H /7YYC10/ 3-1 / 0O&O
1 - / . 0,0 /0 Y
-V r 0 .0 ,^
-10 1 -i<f
-
, oo ?? 6 oanx X, a o `t f
/ f f * } COX m o 7 '00 o r c?x
1 c l ~ l o-Oc?-> ? J r , 3 c c x
1 - i e . VO t ' P' / / / 6 2 - 7
T -L Y . o .o i H
zyi/3/
1____ -13 . n too --LS .0 ,0 l (7
/t? ? > 3 Toy 01Y6
-J-0 OtOo' -? r,71$Q
J - 2 c o. 0 1X7 _______ f l & / _ o . a ^
Cj f ,<^7
--,,
cj \
Prep Analyst Analyst Reviewed by:
Date: / ? fa f& x A \c ^ /?foo
Date:_ a f / Y & i
Date: ' / / / / 'fllN 2 5
CHr-*12-O90B4S/Q1
STL Chicago TOC inSoils
104
Pag* No.:_
Book No.: -2 2 V 7
Method: Lloyd Kahn
Instrument Phoenix 8000 fTOC41
LabNetBatch: ) H f l
Calculation:
Date of Standard Curve:
TOC (mg/kg) = ug C / grams sample
Book # ^ 7 ^ 1 Paoe # />?/
MS, MSD Known Cone, (mg/kg) * 100 ug C / grams sample
MS, MSD Observed (mg/kg) ug C / grams sample
MS, MSD Rec. = fobaerved mo/ko - avq. sample result (mg/kg)1 x 100
known concentration in mg/kg
Standard Traceability: (Note: Working Standards are prepared daily from the noted Stock Solutions.)
Stock I (Curve) 7 M C 7 T 1 C \ stock il (ICV/CCV) T c i'-f l 9 TJ <i 3
LCS Source ID C f^X V ^A CS True Value *1
Acceptance Range * f 1
Sample ID:
Sample Weight (g)
ugC
Comments:
c oft
0 32W i - Z !
:____ i
I1
-%a
LJo -- <" ?
I - 2 -2 .
Oil 0 ,00*17
. c) a ? 2 ~
o, O f f ^
ff- O f l ? O o ( t'l
1 ' 2 2 o . o i l * ?
-- `X y f
a oil 1
7rr. o / i 7o c l 7
~o y m '
'or oto
7,1 0 . 72.7/
--
/1
O:-
lrh/1
j
--
XCC,ac\
loS.i u p
7 7 , 77 V /
zrzz
72,
X Ctrl /
V - &(,-'!
--
-
-=b
Z35I
.---- z H
o\ o l i v
/7r (~y / C
(j O ( Y C
7o . o c u
O). o '^-3 --
O. 0202 6 .0 ^
0 <O'XStH
, 6 <22 2
ZOO. 0C ?
V-tw
.. Q S ' i n .
31
Z Z 7Z Z ^ 0
vi. V J V /
77 7V77
nm
------- O k . o - o * r ~ s ,u*
rM a .
I -0 if/Of --
-- ----- ---
Prep Analyst; Analyst: f "3* ^ Reviewed by:_
dL
a '/AM
Date: / 2 A O l ______
Patei ^ y / ^ Y
Date:
iln{./N
CHI-22.12-9Sm-06rt)1
7 T>C
* * * RUN LOG
(V2 )
Total Organic Carbon {Soils) Method code..: TOCS Batch Code...; 137258
Status....... RPT Batch Date... 12/16/04 Batch Time... 1330
User Name,*___ : els QC code....... : TOCS Calc code..... : Toes
X ^ U .1 1
1 2 / W 0 4 14=37
Location Code..: 57222 Equipment Code.; TOC4 import Code____:
TEST CQOE
T TT T T T TTT T T TT
O0000CCC 111
C cC C C c C ssS C C C 234AAA 2A SSs
V VV
V 2A
234 2 2
SAMPLE: Grp Pos Sample ID
Dilution
TEST POS Date / Time
123 4 56 7 11 1222 78 9 0 12
11
___ICAL_I04LSTTC1_
0
12
___ ICV_I04LSTTC2_
12/15/04 0908 0
13
___MB__
12/15/04 0915 0
14
___LCS_I00FSTLK3_
12/15/04 1016 0
15
___LCD_I0DFSTLK3I_
12/15/04 1024 0
16
232676_5_S___
12/15/04 1032
0
17
2 3 2 6 7 6 6 S ___
12/15/04 1109
0
18
232676 7 s___
12/15/04 1123
0
19
232676_B_s___
12/15/04 1139
0
1 10 232676_8_S_MSj04LSTTC2_9
12/15/04 1155
0
1 11 232676_8_S_MSD_I04LSTTC2_9
0
12/15/04 1350
N
1 12 232677_1_J!___
12/15/04 1405
0
1 13 232677_2_S___
12/15/04 1422
0
1 14 232677 3 S
12/15/04 1443
0
1 15 ___CCV_ID4LSTTC2_
12/15/04 1501 0
1 16 ___CCB__
12/15/04 1508 0
1 17 232677 4 S
12/15/04 1513
0
1 18 232677_5^S___
12/15/04 1532
0
1 19 232677 6 S
12/15/04 1557
0
1 20 ___CCV_!04LSTTC2_
12/15/04 1621 0
1 21
CCB
12/15/04 1623 0
Page 1
7
QC Sunnary
**
(V2 )
Total Organic Carbon [Soils)
Method Code..: TOCS Batch code...: 137258 Status...... : RPT
Batch Date...: 12/16/04 Batch Time...: 1330 User Name____: cLs
QC Code....... : TOCS Calc Code....: TOCS Location Code,,: 57222
Grp Smp Sainple ID
Pos Test Result
Known
Original
12
ICV I04LSTTC2
1 TOC 2155,26 2000
1 3 ___MB__
1 TOC -2.36
1 4 ___LCS_I00FStLC3_
1 TOC 4127.36 4780
1 5 ___LCD_rI00FSTLK3_
1 TOC 4745.15 4760
1 10 Z32676_8_5_MS_I04LSTTC2J>
5 T0CAV2 5728,26 2000
1731.20
1 11 232676_8_SMSD_I04LSTTC2_9
5 T0CAV2 6999,00 2000
1731.20
1 15 ___CCV_I04LSTTC2_
1 TOC 2208.49 2000
1 16 ___CCB__
1 TOC -1.89
1 20 ___CCV_IQ4LSTTC2m
1 TOC 1927.07 2000
1 21 ___CCB__
1 TOC -2.28
Report Date: 12/16/04 14:3?
Equipeient Code.: T0C4 Inport Code___ ;
Alternate QC Res 106
F QC Res
F
5728.26
86 99 100.3 147.5
no
H 3?
96
Page 1
'8
* * * RAU TEST DATA
***
CVS )
Total Organic Carbon (Soils)
Method Code..: TOCS
Batch Code
137256
Status---
RPT
Batch Date.*: 12/16/04 Batch Time__ : 1330 User Name___ : cls
SAMPLE:
Grp Pos Sandte ID
11
ICAL I04LSTTC1
12
ICV I04LSTTC2
13
MB
14
LOS IQFSTLK3
15
LCD I00FSTLK3
1 6 232676 5 S
1 7 232676 6 S
1 8 232676 7 S
1 9 232676 3 S
1 10 232676 8 S MS IQ4LSTTC2 9
1 11 232676 8 S MSD I04LSTTC2 9
1 12 232677 1 S
1 13 232677 2 S
1 14 232677 3 S
1 15
CCV I4LSTTC2
1 16
CCB
1 17 232677 4 S
1 18 232677 5 S
1 19 232677 6 S
1 20
CCV I4LSTTC2
1 21
CCB__
QC Code,.
Cale Code.
TOCS
Location Code.,; 57222
Di Lution
TOC mg/Kg
TOC2 mg/Kg
Report Date: 12/16/04 14:37
Equipment Code.: TOC4 Import Code___ :
T0C3 mg/Kg
TC4 mg/Kg
TOCAVZ mg/Kg
2155.26
*2.38
4127.36
4745.15
14151.93 16628.09
4641.14 7437.13
2214.31 1526.24
2423,65 1936.16
5726.26
0 6999.00
7361.04 8603.97
2875,91 3732.21
1273,06 1736.95
2208.49
-1.89
997.27
1224,27
4311.65 5023.62
536.36
323.33
1927.07
-2.28
15390.01 6039.14 2318.98 1731.20 5728,26 6999.00 7962.50 3304.06 1506.02
1110.77 4667,64 429.85
Page 1
3
RAU TEST DATA
(V2 )
Total Organic carbon (Soils)
Method Code. : TOCS Batch Code r T , : 137258 statu?___ : RPT
Batch Date..: 12/16/04 Batch Time...: 1330 User Kme.,..: cLs
SAMPLE:
Grp Pos Sample ID
11
ICAL I04LSTTC1
12
1CV I04LSTTC2
13
MB
14
LCS IQ0FSTLK3
15
LCD 100FSTLK3
1 6 232676 5 S
1 7 232676 6 S
1 8 232676 7 S
1 9 232676 8 S
1 10 232676 8 S MS I04LSTTC2 9
1 11 232676 6 S MSD I04LSTTC2 9
1 12 232677 1 S
1 13 232677 2 S
1 14 232677 3 S
1 15
CCV I04LSTTC2
1 16
CCB
1 17 232677 4 S
1 18 232677 5 S
1 19 232677 6 S
1 20
CCV I04LSTTC2
1 21
CCB
OC Code... ....: TOCS Calc Code. ___ i TOCS
Location Code..: 57222
Di lut ion
TOCAV3 mg/Kg
TCAV4 mg/Kg
Report Date: 12/16/04 14:37
Equipment Code.: TOC4 Import Code __ :
TOCR1 ug
TOCR2 ug
TCR3 ug
107.7632
-0.3807
107.3113
129.5426
284.4537 237.7817
69.6171
132.3810
31.0003 67.8622
34.0351 45.6934
143.7793
0 195.9721
208.3173 230.5863
60.1065 108.2342
42.0115 60.8631
110.4244
-0.3020
36.0016 54.3576
193.5930 182.8598
44.2498 29.2286
96.3537
-0.3644
-- Page 2
*** RAW TEST DATA
***
<V2 >
Total Organic Carbon (Soils)
Method Code.. TOCS
Batch Code
137258
Status,...
RPT
Batch Date...: 12/16/04 Batch Time.,.: 1330 User Name___ : els
SAMPLE:
Orp Pos Sample ID
11
ICAL 104LSTTC1
12
ICV IQ4LSTTC2
13
MB
14
LES I0FSTLK3
15
LCD I00FSTC3
1 6 232676 5 S
1 7 232676 6 5
1 8 232676 7 S
1 9 232676 8 S
1 10 232676 8 S MS J04LSTTC2 9
1 11 232676 8 S MSD I04LSTTC2 9
1 12 232677 1 S
1 13 232677 2 S
1 14 232677 3 S
1 15
CCV I04LSTTC2
1 16
CCB
1 17 232677 4 S
1 16 232677 5 S
1 19 232677 6 S
1 20
CCV I04LSTTC2
1 21
CCB
DC code...
. TOCS
CaLc Code, ___ : TOCS
Location Code..: 57222
Dilution
T0CR4 US
UT1 9
Report Date: 12/16/04 14:37
Equipment Code.; TOC4 import Code, __ :
WT2 UT3 UT4 9S9
0.05
0.16
0.0260
0.0273
0.0201
0.0143
0.0150
0.0178
0.0140
0.0280
0.0223
0.0236
0.0251
0 0.0260
0.0283
0.0268
0.0209
0.0290
0.0330
0.0350
0.05
0.16
0.0361
0.0444
0.0449
0.0364
0,0625
0.0904
0.05
0.16
Page 3
sJL
*** RAW TEST DATA
***
Total Organic Carbon (Soils)
Method Code., TOCS
Batch Code ,i 137258
Status___
RPT
Batch Date...: 12/16/04 Batch Time...: 1330 User Name.... : els
SAMPLE:
Grp Pos Sample ID
11
ICAL I04LSTTC1_
12
ICV 104LSTTC2
13
MB
14
LCS I00FSTUC3
15
LCD I00FSTLK3
1 6 232676 5 S
1 7 232676 6 S
1 8 232676 7 S
1 9 232676 8 S
1 10 232676 8 S MS 1D4LSTTC2 9
1 11 232676 8 S MSD I4LSTTC2 9
1 12 232677 1 S
1 13 232677 2 S
1 14 232677 3 S
1 15
CCV I04LSTTC2
1 16
CCB
1 17 232677 4 S
1 18 232677 5 S
1 19 232677 6 S
1 20
CCV I04LSTTC2
1 21 ___CCB__
QC Code... ___ : TOCS Calc Code. Location Code..: 57222
Dilution
DLFAC N/A
TCS mg/Kg
3.2000 1.0000
6.1538 6.8608 9.3023
9.7561 7.6190 6.9717 6.3745 0 5.7143 5.8076
6.4128 4.7059 3.2000 1.0000
3.9752 3,9360 1.8508 3.2000 1.0000
<V2 )
Report Date; 12/16/04 14:37
Equipment code.; T0C4 Import Code.... :
TCS2 mg/Kg
TCSAV2 mg/Kg
TICS mg/Kg
Calibration Report Print Date/Time: 2004/12/16 7:35:41
Cal. Curve ID: SOILCURVE
Created:
12/13/2004 13:36
Calibration Factor (m): 9.841e+04
Y Intercept (b): -250134
r-squared:
0.99935
Standard ID Y X Expected Measured Message
Date &
Raw Data ug C ug C
Time
0 ugram C
-8891 0.000 2.451 No sample Det 12/13/200411:24
10ugramC
911065 10.000 11.800
12/13/2004 11:42
20 ugram C 1853385 20.000 21.375
12/13/2004 11:48
40 ugram C 3745719 40.000 40.605
12/13/2004 12:04
120 ugram C 11194916 120.000 116.302 Endpoint Time 12/13/2004 12:28
200 ugram C 18654032 200.000 192.099
12/13/2004 12:46
300 ugram C 29462156 300.000 301.928
12/13/2004 12:59
400 ugram C 39451668 400.000 403.439 Endpoint Time 12/13/2004 13:19
._ .
lur.r oat
1
ICB-MB
-0-3807
TC
LCS
107.3113
TC
LCD....................... .......... 129.5426.............. ...TC .
232676-5
284.4537
TC
232676-5
-0.2819
TC
232676-5............... ............. 237.7817...
........... TC
232676-6
69.6171
TC
232676-6
132.3810
TC
232676-7............ ............. 31.0003... ........... TC
232676-7
67.8622
TC
232676-8
34.0351
TC
232676-8............... ............. 45.6934...
........... TC
232676-Bms
143.7793
232676-8ms
195.9721
232677-1............ .......... 208.3173...
TC TC ........... TC
232677-1
230.5863
TC
232677-2
60.1065
TC
232677-2............... .............1082342...
.. ...TC
232677-3
42.0115
232677-3
60.8631
ccv............. .......... 110.4241..............
TC TC ...TC .
CCB
-0.3020
TC
232677-4
36.0016
TC
2 3 2 6 7 7 -4 ............................. 54.3576...
........... TC
232677-5
193,5930
TC
232677-5
1B2.8598
TC
232677-6............ ............. 14.8402...
232677-6
44.2498
........... TC TC
232677-6
29.2286
TC
CCV....................... ..........143.5157..............
ccv
96.3537
...TC , TC
CCB
-0.3647
TC
/
Detailed Analysis Report Print Date/Time: 2004/12/16 7:53:18
Sample ID: ICV Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12150902
Timestamp: 12/15/20d Sample Type: Cal. Verifid
--- 09:08/
Rep # ppm C ug C Raw Data Beginning Ending Integration
Baseline Baseline Time
1 107,7632 107.7632 10354667
1.459 2.459 323
Sample ID: ICB-MB Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC
Filename: 12150911
s*
Timestamp: 12/15/2004 09:15
Sample Type: Sample V /
Rep# ppmC ugC Raw Data Beginning Ending Integration
Baseline Baseline Time
1 -0.3807 -0.3807 -11702
1.805 1.697 120
Last Message: No Sample Detected
Sample ID: LCS Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12151010
Timestamp: 12/15/2 Sample Type: Sample
Rep# ppmC ugC Raw Data Beginning Ending Integration
Baseline Baseline Time
1 107.3113 107.3113 10586095
0.759 1.759 305
Sample ID: LCD Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12151019
Timestamp: 12/15/2 Sample Type: Sample
Rep # ppm C ug C Raw Data Beginning Ending Integration
Baseline Baseline Time
1 129.5426 129.5426 12773842
2.063 3,062 290
Sample ID: 232676-5 Method: boat
Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC
Filename: 12151026
5
Timestamp: 12/15/2004 10:32
Sample Type: Sample 1
Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time
r * 3
1 284 4537 2&.4S37 28018388
2.017 3.017 333
Sample \D \ 232676-5 Method: boat Cal. Curve: SOILCURVE Operator ID: CApOL ^
Mode: TC Filename: 12151035 / M Timestamp: 12/15/2004 10:41 ik {0 Sample Type: Sample
Rep # ppm C 1 -0.2819
'ug C kaw Data Beginning Ending
Baseline Baseline Time
-1981
1.830 1.498
6
Integration
Last Message: Cancele
Sample ID: 232676-5 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: ' TC Filename: 12151041
Timestamp: 12/15/2004 10:48 Sample Type: Sample
Rep # ppm C ug C Raw Data Beginning Ending Integration
Baseline Baseline Time
1 237.7817 237.7817 23425476
1.507 2.507 386
=3SC3CSEz================E==?=ZZ3=r??3B35i;=========
Sample ID: 232676-6 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12151104
Timestamp: 12/15 /2 0 0 f 11:09 Sample Type: Sample ( /
Rep # ppm C ug C Raw Data Beginning Ending Integration
Baseline Baseline Time
1 69.6171 69.6171 6876671
1.542 2.540 284
Sample ID: 232676-6 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12151111
Timestamp: 12/15/200411:17 Sample Type: Sample
Rep# ppmC ugC Raw Data Beginning Ending Integration
Baseline Baseline Time
1 132.3610 132.3810 13053165
2.257 3.256 293
Sample ID: 232676-7 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC
Filename: 12151119
f
Timestamp: 12/1 b!20QAf11:23/
Sample Type: Sample
/
Rep # ppm C ug C Raw Data Beginning Ending Integration
w Baseline Baseline Time
1 31.0003 31.0003 3076454
1.945 2.945
231
Sample ID: 232676-7 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12151126
Timestamp: 12/15/2004 11:32 Sample Type: Sample
Rep# ppmC ugC Raw Data Beginning Ending Integration
Baseline Baseline Time
1 67.8622 67.8622 6703972
1.757 2.757 278
Sample ID: 232676-8 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12151135
Timestamp: 12/15/2 Sample Type: Sample
Rep # ppm C ug C Raw Data Beginning Ending Integration
Baseline Baseline Time
1 34.0351 34.0351 3375101
2.097 3.096 228
Sample ID: 232676-8 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12151141
Timestamp: 12/15/2004 11:48 Sample Type: Sample
Rep # ppm C ug C Raw Data Beginning Ending Integration
Baseline Baseline Time
1 45.6934 45.6934 4522376
1.806 2.804 319
Sample ID: 232676-8ms Method: boat CaL Curve: SOILCURVE Operator ID: CAROL
Mode: TC
Filename: 12151149
f
Timestamp: 12/15/2004 11:55
Sample Type: Sample
Rep # ppm C ug C Raw Data Beginning Ending Integration
Baseline Baseline Time
1 143J793 143.7793 14174854
3.476 4.476 310
Sample ID: 232676-8ms Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC
Filename: 12151343
/
Timestamp: 12/15/2004 13:5)
Sample Type: Sample (
Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time
1 195.9721 195.9721 193156
2.477 3.475 391
Sample ID; 232677-1 Method: poat Cal. Curve: ^SOILCURVE Operator ID: CAROL
Mode: TO Filename: 12151358
Timestamp: 12/15/2 Sample Type: Sample
Rep # ppm ug C Raw Data Beginning Ending Integration
Baseline Baseline Time
1 208.3173 208.3173 20525928
1.624 2.624 357
Sample ID: 232677-1 Method: boat 08 Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 121514
Timestamp: 12/15/2004 14:15 Sample Type: Sample
Rep # ppm C ug C Raw bata Beginning Ending Integration
BaselinW Baseline Time
1 230.5863 230.5863 227173&8
2.151 3.151 350
Sample ID: 232677-2 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
)de: TC Filename: 12151417
Titaestamp: 12/15/200414:22 Sample Type: Sample ^
Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Yfime
1 60.1065 60.1065 5940749 1.980 2.980 257
Sample ID: 232677-2 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12151421
Timestamp: 12/15/2004 14:34 Sample Type: Sampl
Rep # ppm C ug C Raw Data Beginning Ending integration
Baseline Baseline Time
1 108.2342 108.2342 10676918
1.663 2.660 32i
Sample ID: 232677-3 Method: boat Cal, Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12151436
Timestamp: 12/15/200^14:43^ Sample Type: Sample /
Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time
1 42.0115 42.0^15 4160050
5==a===s,=======^
2.057 3.055 243
Sample ID: 232677-3 \
Mode:
TC
Method: boat
\ Filename: 12151445
Cal. Curve: SOILCURVE \
Timestamp: 12/15/200414:51
Operator ID: CAROL
\ Sample Type: Sample
Rep# ppmC ugC Raw Data \Beginning Ending Integration
Baseline Basbline Time
1 60.8631 60.8631 6015201
1.970 2.968 276
Sample ID: CCV Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12151456
Timestamp: 12/15/201 Sample Type: Cal. Verity
15:01
Rep # ppm C ug C Raw Data Beginning Ending Integration
Baseline Baseline Time
1 110.4241 110.4241 10616519
2.494 3.492 287
Sample ID: CCB Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC
_____
Filename: 12151505
Timestamp: 12/15/2004 15:08
Sample Type: Sample [
7
Rep # ppm C ug C Raw Data Beginning Ending Integration
Baseline Baseline Time
1 -0.3020 -0.3020 -3957
1.693 1.635 120
Last Message: No Sample Detected
Sample ID: 232677-4 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC
Filename: 12151509
/
Timestamp: 12/15/20W 15:13
Sample Type: Sample
/
Rep # ppm C ug C Raw Data ^Beginning Ending Integration
Baseline B a rlin e Time
1 36.0016 36.0016 3568627
1.661 2.658 250
Sample ID: 232677-4 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12151515
Tim estam pV12/15/2004 15:20 Sample Type: sample
Rep # ppm C ug C Raw Data Beginning Ending Integration
4:9
