Document zOEN3OgqJvD81MjdQEGe59aB

MONSANTO CHEMICAL INTERMEDIATES COMPANY INDUSTRIAL HYGIENE SECTION LOSS PREVENTION AND SAFETY DEPARTMENT TEXAS CITY, TEXAS NOVEMBER 1980 INDUSTRIAL HYGIENE STATUS REPORT FOR THE TEXAS CITY PLANT STATUS REPORT NO. 4 (UPDATE 1/1/80--7/1/80) MAP 005130 John E . Fox Lorris W. Williams LAM000956 I DISTRIBUTION 1. D.N. Campbell .2 G.A. Danner 3. G. W. Daues 4. B. W. Eley - St. Louis 5. J.E. Fox .6 J.A. Glass 7. W.G. Juhl .8 D.E. Kaldenberg 9. H. M. Keating - St. Louis .10 C. M. McCullough .11 J.J. Murphy - St. Louis .12 C.F. Navarrete 13. G.T. Ryan 14. J.G. Trafton 15. G.L. Tromblee 16. Industrial Hygiene Lab 17. Extra 18. Extra MAP 005131 ) LAM000957 TABLE OF CONTENTS I. INTRODUCTION II. SUMMARY III. CONCLUSIONS IV. RECOMMENDATIONS Page 1 1 1 2 LIST OF TABLES I. Summary of Personnel Sampling that Exceeded the Permissible Exposure Limit (PEL) II. Area Samples that Exceeded Allowable Limits III. Data Sheets IV. Initial Determination (ID) V. Analytical Methods in Use at Texas City VI. Industrial Hygiene Monitoring Schedule--1980 3 4 5 6 7 8 MAP 005132 LAM000958 INDUSTRIAL HYGIENE STATUS REPORT FOR THE TEXAS CITY PLANT I. INTRODUCTION In 1977, World Wide Environmental Protection Guidelines were developed for Corporate Monsanto. Guideline #5, which pertains to Industrial Hygiene, will "determine and monitor workplace stresses and maintain Monsanto workplace environment standards." In late 1978, an additional Corporate guideline program was established which includes the requirement for issuance of semiannual Industrial Hygiene Status Reports. The first Industrial Hygiene Status Report for the Texas City plant was issued January 2, 1979. The present status report includes an update of the plant-wide industrial hygiene results from January through June 1980. II. SUMMARY This Texas City Industrial Hygiene status report updates and summarizes the personnel exposure measurements, area and short-term surveys we have recorded for the chemicals and/or physical agents in the departments and areas of the } Texas City plant. Approximately 6,250 analytical measure ments are recorded since the status report of July 1979. Included in the data sheets, as a separate table, are a number of materials for which initial determinations were not monitored (I.D.'d). These individual chemicals, because of low personnel exposure potential, were elimi nated from actual measurement for initial baseline determinations. The status of the Method Development Program and the ini tial Industrial Hygiene Monitoring Schedule for 1980 is included. III. CONCLUSIONS 1. Extensive personnel sampling has indicated that per sonnel exposures do not normally exceed established limits and/or regulatory standards. 2. No new or revised regulated areas required. 3. Exceptions to the established limits during the six month period were 10 noise and 3 chemical overexposures. As noted in the report, six of the ) noise overexposures appeared to be spurious results -1MAP 005133 LA A/1000959 INDUSTRIAL HYGIENE STATUS REPORT FOR THE TEXAS CITY PLANT and not reproducible. The chemical exposures occurred at the docks. Although so classed as overexposures by regulation, breathing protection was actually in use on two of the three occasions (OSHA requires moni toring reports as if no breathing protection was in use). A summary of the personnel sampling that exceeded the permissible exposure limit (PEL) is outlined in Table I. 4. Table II is a listing of the area samples that exceeded the allowable limits. As noted, many of these samples were taken under unusual conditions, such as during a spill or decontamination. No person nel overexposures are known to have occurred during these periods. IV. RECOMMENDATONS 1. Continue the scheduled plant-wide monitoring program. 2. Personnel receiving this report disseminate the results of these surveys to their supervision. As monitoring continues daily, more up-to-date data may be available from the I.H. group. MAP 005134 -2 LAM000960 TABLE I SUMMARY OF PERSONNEL SAMPLING THAT EXCEEDED THE PERMISSIBLE EXPOSURE LIMIT (PEL) Dept, or Area Material Function PEL NO. >PEL Prot. Equip. Used High Results Comments 13/14 25 35 F 44 Power 2 Dock 1 Dock 1 Dock 2 Noise Noise Noise Noise Noise AN Styrene AN Maint. Maint. Prod. Maint. Prod. Pipe Fitter 90dBA 1 of 32 90dBA 1 of 22 90dBA 6 of 50 90dBA 1 of 11 90dBA 1 of 40 10 ppmC 4 of 12 No No No Yes No Yes Pumper G. 100 ppm 1 of 1 No Pipe Fit. 10 ppmC 5 of 12 Yes 93 Slag Gun and Grinder 99 161* 93 99 25.3 138 15 Min. Ceiling; Hose ConnectDisconnect Sampling During Ship Loading 72 15 Min. Ceiling; Hose ConnectDisconnect * This appears to be a spurious result because exposure times, noise level, and job function did not agree with high results. Repeat of survey resulted in lower deter minations (all <PEL). MAP 005135 -3- LAM000961 TABLE II AREA SAMPLES THAT EXCEEDED ALLOWABLE LIMITS Dept. or Area 13/14 13/14 13/14 35 F Material PEL Benzene 10 ppm Ethyl Benzene 100 ppm dl Ethyl Benzene 100 ppm Welding Fumes 5mg/M^ 51 513 (24) Bulk Load. P.T. AN Ammonia PA Welding Fumes 2 ppm 25 ppm 1 ppm 5mg/M^ No. >PEL High Results 3 of 17 21.9 1 of 17 149.4 1 of 17 145.3 1 of 2 8.7 1 of 2 1 of 4 1 of 2 2 of 2 5.2 29 25 16.3 Comments Spill; Breathing Prot. Used Part Time Spill; Breathing Prot. Used Part Time Spill; Breathing Prot. Used Part Time 3' Downwind of Weld ing Galvanize--Only 2.9 ppm inside Helmet Decontamination Tank Car jSAAP 005136 lW*000962 -4- TABLE III DATA SHEETS W.AP 005137 > -5- LAM000963 Ethylene Propylene Dimethyl Formamlde Sodium Hydroxide Hexane Ethane Condensate O il (Snlfo) Acetylene Quench O ils Noise-Dosimeters V0P06 _______ "INIVWI _ _____ XXXX X 5a <Vi 0 z x01 CM h-- Z i FUNCTION AND NUMBER [jm [AREA X S aVY < PEL (Bhr. C e llin g ) X to/>. < c ^ l/J <UJ Z 5 pH h- < z h-- Z i OO Zo. h-- z b<e I PROD. 1 100 < UJ --z < z o Z i oz z i o Z 1 PROD. 1 Z z Asphyx. I u 44->> o X 2 P S|2 pH CM CM r> TEXAS CITY . INDUSTRIAL HYGIENE STATUS REPORT z sZ UJ CL INITIAL DETERMIN ATION 1 NOT MONI TORED TOTAL SAMPLES U(/J} HIGH sfx!t- CM CM CO ON 9> 6 0 -r 1 0*01 1 CM "H. CM pH pH CO Xv) 3 CM a s CM in CM CO PH. t0 to o o CO CO >o o oo Dept, or Area Dept. 10 (Ethylene) Date July 1980 S** >m-J Z AVERAGE NO. >PEL DATE BREATH ING EQUIP MENT USED CORRECTIVE ACTION OR STATUS o i) i U nit shutdown i permanently Hay 198U h* ao ON iO CM OoO pH rOo O*N4 mo O00N w m tmo mo LrO j) ON - -xlON nr ze. pH XX o^H o Z PH < lx Benzene Butane Propane Z < z Zc. z i Z < uJ z Asphyx. Asphyx. MAP 005138 LAM000964 ucGrsJ( C ) CCOl kIuVOX<3aaSuJ)i 0) 3C<oUsu.1. _> UJ Benzene (Uz) Styrene (SM) UJ CO TEXAS CITY INDUSTRIAL HYGIENE STATUS REPORT --------------------------1 FUNCTION AND NUMBER PEL (8Mr. C e llin g ) Other IN IT IA L - DETERMIN ATION ! TOTAL NOT MONI TORED | SAMPLES IL A S SAMPLES [PROD^ | T o o> aa O z -- < -2uCl < 33Ca. -- < <UJ e<s d o a M eA 1 I 100 100 z < 1___ S J I | ll'JIII c* ? gZ 13auaa-0J cm CO r 1N0 0 CCOM 0M to to 0O 3 rmsi om S3i 0"Nu* ^4 33 0 Jl -*s4. Jsl. S> 33 0 rUn1 ** kk Paye 1 of 2 Dept, or Area: Dept. 13/14 ( Alk-LB) Date: July 19UO 1 < -- H- O & si (tsOj ro SURVEY AVERAGE >PEL DATE 08/9 1 Ur-i1 m T3<oL33o. Ua woa. QVL.. CORRECTIVE ACTION OR STATUS [A s s ig n e d to Keduce 3 o cr 3 3 3 3 3 PM 3 3 3 3 3 3 1___ U______ 1 33 O 03 ** CSJ r> 3 o CM 3 3 r> rj 0 '*# m 0 r*. 0 m 0 Mwm**t M *ci---m< 0V c^sj r*N-* 00CVS*i -C-apM ^0 *CSJ M-H 0V VCOM M-4 0VO^CM CM Q3O3C. Uru! L0 COM z < be c<y Wo q} 3 J>O3--- 5 =i k * "** u 33 m k0r V <LiJ CS. < Toluene (Tol) <UccJ < 1-^ z < 3 PCC CL 100 I 100 CM 8 0 Hydrogen Chlorlde(IICL) AREA Ethylene | z < 33oae Asphyx. 3O Xa Sodium llydroxlde(NaOli) Ethyl Chloride (EthCT) z < cuJ> CC z < ---------------1 1000 1 33OaC u Z < Aluminum Granules NOTt: AH maintenance samples (except noise) record ed since 1979 are on Dept. 15/16 sheets since thes e perseinnel work both XXXX CM CO 0 3 8 8 CM V V >4 3 3m * Measured[ In and around a s p ill ** Breathing equlpnent used part tin e JPSJ, CM pi! 0 3 0 PU i CL NT LAIV1000965 5 l3 g Page 2 o f 2 Dept, or Area: Dept. 13/14 (Alk-EU) Date: July 198!) --o- zo-- <t--o ce G to 8< <WS* z-Uu--3'syZ--j:Ii) oc=n<c r E *- MAP 005140 LAM000966 Dept, or Area; Dept. 15/lb (Styrene) ~ _________ --=. s l/l O O-- *t--E Sc </> Uate: July 19UQ Page 1 of 2 S<W5 2-UwO--3'SpZu--jUsa^ o cr GO so s PO O i3 cc< 30 CSI . CM lO On CJ ma on X o -* m o CM - CM O M T5 O a o CM e! P 35 : CM r*. On lH CM ro C\j in m cm cn. I*)CMPn on -- h on ^ --< CM "* CM -- CM as x a KUJO LU UO N<^ZoSH- 0) Si TEXAS CITY INDUSTRIAL HYGIENE STATUS REPORT u 5 '--i in o o O OS --^z1-<z0s0U2J CL $ m o oo r--c. X<--< G<S X< a Ol -- n 4-> U >*CJ u o aon T5 i La, *-- S-3 LAW1000967 Ccon*<0 MAP 005142 LAM000968 oo i O -- ac se2uot xO) TEXAS CITY INDUSTRIAL HYGIENE STATUS REPORT Y-- Z --> oc t3 wi 8* Is S'* 3 CD <ac Page 2 of 2 Dept, or Area: Uept. lb/16 (Styrene) Date: July 1980 eo cVoO e 5o 2 c 4VV-O>I 1 N-- 2 tn X XX s o o so:* ^a. zos G0.. iCrM> oos MAP 005143 J <o co Hydrogen Cyanide Methane Oos Z I ioOS FUNCTION AND NUMBER 1TEXAS CITY INDUSTRIAL HYGIENE STATUS REPORT INITIAL DETERMIN B 5? _j z oUaSsJ.t PEL (Bhr. C e llin g ) j ATION LAST SURVEY NOT MONI TOTAL Other j TORED SAMPLES | SAMPLES | HIGH AVERAGE ______ 1__________1 I 10 KZ Asphyx. Uo-i A oZ Dept, or Area: Uept. 19 (IICN) Date: July I9UO 1 EQUIP MENT DATE USED CORRECTIVE ACTION OR STATUS i OS Pt-Rh C atalyst S u lfu ric Acid Noise-Dosimeters OS z i as z i I 1 1 MAINT. VSP06 *CM m m o LAM000969 Hydrogen Cyanide Isobutylene S u lfu ric Acid Sodium Hydroxide t-B u ty l Amine Noise-Dosimeters Sodium Formate TUNCTION AND NUMBER I AREA 1 MAINT. oZ zo> z a. o Cm n TEXAS CITY INDUSTRIAL HYGIENE STATUS REPORT (Dept, or Area: Dept. 25 TUA) Date: July I960 PEL (8 h r. C e llin g ) Other "TO TTO DETERMIN ATION NOT MONI- TOTAL 1 TORED SAMPLES h >- U>J OC 3 JO GO < PERSONNEL SAMPLING SAMPLES II9III AVERAGE 1 ON 1` >PEL [ Equip- MENT DATE USED _________1 I CORRECTIVE ACTION OR STATUS r*. eg O V* V a a <: z 1 PROD. 1 n SO CM XXX i i L _ 6 6 ____ ____ic n 1 09- 1 r3T* 5* rt Oao CD 4 eg z -- Ui m a Z ac o Q o < ICC Z c- 9\ eg M a% O eg ro l_u g <z cc I a. ! PROD. I 1 o z la z I ' 90dBA n 1 26 i eg CM 1 Bo) lennaker . XX XXX C c. < cc V c 0> ">) 4-* 3 a o iA > o c. Formic Acid i PROD. | z lea o cc Om z <cz te rt-B u ty l Alcohol a o cc i te rt-B u ty l Formamlde I Chlorine AREA hZ I 100 tn - n CO to o o o CM e o o In by-product In by-product solution By-product In solution MAP 005144 LAIVI000970 TEXAS CITY INDUSTRIAL HYGIENE STATUS REPORT Dept, or Area: Dept. 27 (LN) Date: July 1980 >-- o OO I-- == => UOh* auv) s< B--a d zo uj i: 2S-uoj'!uCj <3/> z 5! <H- 5C^. P 3E g --^eucjzo 55 oS Sj:&g "D<Zh t3 : g<5 o aC..-_ CoC ~' oO z~ *>o o J MAP 005145 LAIVI000971 Dept, or Area: Dept. 29 (ACY) Date: July 19U0 >3 --1-5 3(S> aOUJt MO t<t---- C <-J S'* ,,U32UJ 23 Ot sf. UJ < 2 Z O oo < --i OX-- c. is i PoLgU <--izoh-iO2g-c "WSu TEXAS CITY INDUSTRIAL HYGIENE STATUS REPORT MAP 005146 lA^000972 CORRECTIVE ACTION OR STATUS Uept. or Area: Dept. 33 (L a c tic ) Date: July 1980 cTOaaf e bV0e)I BREATH ING EQUIP MENT USED U--J cQ -* r*L X u*> to CM r-* CM ZO zUJ A oS O AVERAGE j S si i >U>cizncsJ- M e> o V _> z 8<UzXJ <--ini zco ar*>* o "V* o N kf> ru ^4 - r ** > LO lO s CM CO er> A O o <o oo o CM rs V AAOO CO r> o CM StCM J3 V ro 9r> en CM iD mCSI CM CM AO CM lA CO AO o CoM V CM V fH SAMPLES SAMPLES NOT MDNI- TOTAL TEXAS CITY INDUSTRIAL HYGIENE STATUS REPORT M r> M CO CM AO p- - Si --1 ^4 T0RE0 0ETERMIN-! ATI ON INITIAL XX XXX 90 dBA Other C io ac o> s o CM LO 4> o *-- u 1 LO o PEL (8hr. Cell ac a. Lf> LO Z o CL. CM ^ Oo o CM K Cl 4 to < tH in o o CL. < L- oo < z c o Z Q 2> o o o oo z Cl lJ z < < UJ 5 i o z Cl i O z Z -- l-- h- ho z oZ Dz < Z Qz z -- H- L_ ZOzz o z CL i o Z Cl i O Z CL i UJ 5 z CL < Z X i z z i z z < s: z z i FUNCTION AND NUMBER I 1 1 MAINT. 1 I 1 1 1 AREA Noise/Dosimeters Hydrogen Cyanide Methanol Methyl Lactate . Ammonium C hloride Methane Methyl Chloride Microwave Ovens Lactic Acid Hydrogen C hloride Aiimonla Sodium Hydroxide Carbon Dust L a c to n ltrlle *0 u LO QJ c o \n k. o LAM000973 MAP 005148 ) LAM000974 TEXAS CITY INDUSTRIAL HYGIENE STATUS REPORT Dept, or Area: Dept. 35F (PE) Date: July 19B0 C O R R E C TIV E A C T IO N OR STATUS W ip e T e s t Page 1 of 2 Dept, or Area; Dept. 351' (PE) Date: July 1900" TEXAS CITY INDUSTRIAL HYGIENE STATUS REPORT E Q U IP MENT USED 1 5 si UJ SO 30 00 X* *x> o O 5" PO .d a. ZA ooo AVERAGE _________________ 1 s UJ a. oc 40 n CM CM 40 x. ro Lft _i 40 9% ro "X a! Z < --J 3 3W S 55 Of UJ C. "X CO x* ro CM 30 rx. 'x, O CM aO u oV j> O X) V --a CM l" V ' V CM ui J1 LJ s s rx* rx. X* rx. "x* PO 3r rx* CM o o CO 91 Px. 9 u ro m O o ro ro Si o CO no CO o V CM CM MX. n ro SAMPLES j TOTAL SAMPLES | Other TORED NOT MONI DETERMIN j ATION ^ ro V CM CM CM PO CM CM LfJ ro CO ro o Z CT> z z Q- O O CL. o CM XX XX X CM 90 dBA CM CM ro O iO Si o o cm e L. E ir> K) CM C e llin g ) INITIAL Asphyx. 5(HCL)-- I Asphyx. | PEL (8hr. 1 MAI N T . MAI NT. FUNCTION AND NUMBER rpROc: L __________' 1N1W1 1 h-- M- -- -- -- < UJ ZO << ZO O --J UJ o o z < -j z s z o z < Ui oZz ooo 2z < UJ < ce z ce a. Of < z< Of Of a. < z Of < < z Of < c. z Of a. < OC Cl. s < z Cf a. < z o: a. < z oac. < |Of Z< < z Cf < Calcium Hydroxide Polyethylene Isobutylene I Butane | Hydrogen Chloride Titanium Tetrachlorldd Hexane Sodium Hydroxide Aluminum Hydride (A Radiation Oi- Isobutanol o 0) MAP 005149 S Acetylene (O F.thylene 0 o c1 fO GJ o 1/) +> O z 5 O CJ z LAM000975 TEXAS CITY INDUSTRIAL HYGIENE STATUS REPORT Page 2 of 2 Uept. or Area: Dept. 3bP (PE) Date: July 1980 cc <-> m s* < -- i S3 Z-- ucjryj :< aec CS X WO OX- H- < X-- i S cn to: ez U 3 O q. -- h- O -- -J 2?S 3 OJ YTS 4-> ~ 5 MAP 005149 LAM000976 H^at -- t*<--- K Olfl O C WC J3--DHZ-- I at oo ZD < Out z IS) UJ x3 a. 5to ocef ^ o Pgs2 .--EozfceasS-- o in in o o Cl. < 5 i zo--: <zo:: C\ U3 CO o oo l_3 o *o Honitors near equipment - re s tric te d area - l i t t l e personnel exposure- -"masks required when indicated by ro n lto r- LAM000977 Page 1 of 2 Dept, or Area:Dept. 4U-5b(Uxo-ester) Date: July 19B0 G CO 8^ <--; rsr ur-.r ^ TEXAS CITY INDUSTRIAL HYGIENE STATUS REPORT < --J h- CO 1 s s zui^oS 1 a --< dd IO IO ao: Q O t a. T o-- & CC o fiK ac < sQ. <21 J> -5^ "<c LAW1000978 LAM000979 MAP 005152 Carbon Dust Chromates Radiation F iIte r Aid Sodium Phosphite Microwave Ovens FUNCTION AND NUMBER a- PEL (8hr. C e llin g ) ro Ot I PROD. I < Z %I [ PROD. I I <UJ z I I o AREA 3z lQ3a. I I AREA uE UE"> 33 LE. 3 L. co> 3 X XX CO TEXAS CITY INDUSTRIAL HYGIENE STATUS REPORT -m m] at DETERMIN1 j ATI ON NOT MONI- 1 TOTAL TORED SAMPLES | j SAMPLES ____________I o V - 33 3** 3 V r> <r a UosJ- CL. 3 <LO -J *as L>kJ o3uos -j & >- AVERAGE | UJ 3 CZA Tage 2 o f 2 Dept, o r Arca:Uept. 48-56(0xo-ester) Date: July 1980 1 u EQUIPDATE j EtNT USED CORRECTIVE ACTION OR STATUS | See Results-Dept. 51 1 Wipe Tests 33 *. CM O3 o 3rj u 'C--O LO o < .01 LAM000980 005153 TEXAS Cl TV INDUSTRIAL HYGIENE STATUS REPORT A cetic Acid FUNCTION AND NUMBER ___________ PROD. CL e X v TV X PEL (8hr. C e llin g ) Other INITIAL DETERMIN ATION NOT MONI TORED TOTAL SAMPLES PERSONNEL SAMPL INS pelO>e l- <--1 SAMPLES HIGH AVERAGE _________ _____ ________________ 3D m r> O z i Tv Twmt AREA TV x. > f bo in a Tv 30 TV cm no Xi CM Tv CM CM * CM S e TV o z i Carbon Monoxide o CM CO ri o 3 * x. O r> PO XX Methanol Rhodium Iodide iodine Methyl Iodide Potassium Hydroxide Hydroqen Iodide Noise-Dosimeters i LU oc <c o QC i i &I X< MAINT. PROD. 1 AREA 1 PROD. 1 m1 1 Z z-- < t-- z . -- *-- zz I z to 200 n JZ cc CM 90 dBA o 9 -J 1 1 no no O M TV O 4 TV 9 r M n-x. no -H 1 1 S> r-N. I*** j >4 CM 1 1 i 1 i i i-- o *>n Methyl Acetate Nickel Carbonyl 1 I o cc no TV o t Ii j X xj 1 i u i z z fO' *"4 tn o i 1 n 1n z <' a. 1. a. X| Q. iX| CL 11 Q S Q Propionic Acid Rhodium Carbonyl Microwave Ovens 1 o sc < I AREA z z; J 1 n 4 lJ j H <0.1 <0.1 r! H or 3T 3^1T to oo o 0 CM CM CM no wr XX. o O i i 1 CO a_LAU). Z Irj MJ Dept, or Area: Dept. SU (A ce tic) Date: July 1980________________ 1 Is C3 -- Equip- MENT DATE USED CORRECTIVE ACTION OR STATUS tao. <0 < 1 ox -^1 v0/1l no U z+0J tf<oo TTx. 3nTx, 9nxT* CVI PO TV Report by L. Garban Making up Catalyst onoxn*r,i ST X* 3T XX. a40Ua>3L-11.! 1 ~1 I zy T*T*! a i No Method *04 K2C Dept, or Area: Dept. SO (A cetic) Date: Ju ly 19B0 TEXAS CITY 1 S U R V INDUSTRIAL HYGIENE STATUS REPORT t X Sn ss CORRECTIVE ACTION OR STATUS Report by L. Garban 1 Making up C atalyst a_* < 03 LO U SJ u3 < 4_ 1o "u "U So 1A 3 a l 3 *u aSs.1 fl3 T) 3 u u "U. 33 "u J>u1, ru. Mu CSJ CO in m*. MU -u s 3 33 iE Y 1 EquipDATE | MENT USED 1 UJ 3 a. ZA 33 333oo 3O33 3 m 3o OS os 3 3 "u 3 3 0 s n8 33 ru, ji -u Mu u -u 3 3 33 3 3 3 3 33833 m rs CSJ B 8 n OS 3 ______________ i AVERAGE PERSONICL SAMPLING LAST 3 30 3 -M + 3 3 33* 3 3 CSJ OS m 3 CSJ < UJ u 3 OS CSJ 3 CSJ 3 a. wU S 3 3 N CSJ O CM ro u 3 s n 3 OS 3 8 CSJ 3 T> 3 u 3 <r u o 3o *3 JZ 0w u jlJ 8 1 o z 13/9 3 P4 o V os^ u 3 3 ro OS CSJ 3 CSJ u 3 O n cn 3 ru u. 3 Csi 3 - SAMPLES NOT MONI TOTAL Other TORED INITIAL DETERMIN j ATION XX n J= u CSJ X a. 3i<u oo in o csj z o ^3 9 0 dBA XX -ttB; U 1 3 JZ 3 cc cn 3 o Map 005154 PEL (8hr. C e llin g ) Nickel Carbonyl 1 trod: i MAINT. | PROD. I 1 MAINT. | PROD. 1 Potassium Hydroxide 1 MAINT. | Hydrogen Iodide 1 1 PROD. 1 MAINT. | MAINT. I 1 1 | FUNCTION AND NUMBER 1 PROD. I 1 AREA h- <3Z I UJ 3 Q i OZ< o cc i UJ 3z 3 CC < c. <z3 UJ z i 3 X a- aZ 3 C < CU s: Z3z < o C i be Rhodium Carbonyl Microwave Ovens (A Methyl Acetate Acetic Acid Carbon Monoxide Methanol Iodine u ) Ct O) o 3 o> +J 3 3 O3 sB? u < O (A u o o 8 c 3 o3 > O *-> 0J iA a 2 JLJ z L. LAM000981 in int in o o a. LAM000982 MAP 005156 LAM000983 ts> u d> QJ l/> O a o <s> O z "frj u s lo TEXAS CITY INDUSTRIAL HYGIENE STATUS REPORT Sodium Hydroxide (MaOH) Chromates (Cr 4 * s ) C atalyst Dust Radiation Sodium S u lfite Methane Propylene Microwave Ovens z <Z z oZ Z TUNCTION AND NUMBER 1 PROD. 1 I AREA MAINT. I 1 UJ < s: IPR0D. 1 < z: AREA se CO s: _J ec. UJ C_ INITIAL DETERMIN i r . C ellin g) I ATION NOT MONI Other TORED TOTAL SAMPLES PERSONNEL SAMPLING : SURVEY SAMPLES HIGH j AVERAGE j _________________ 1 X CJ o X) 3 o 30 o o o o X* VVo V fx. m oO pU to M <0 |X* S ^4 O.OS 1 90 dBA o ou OE . 216 162 oc < c. XXX g PROD. I PROD. I MAINT. AREA 1 Asphyx. I I Asphyx. <.03 CO to o <n O V - o o CM o 1 ii UJ O Cl. Z Sk IS) < Page 2 of Z Dept, or Area: Dept. 51 (AN-5) Date: July 1980 ; J I EQUIP MENT DATE USED CORRECTIVE ACTION OR STATUS - rrrs U1 x* 00 Xte CO x. to to CNJ I Wipe Tests 0J L> <9 CL IS) (J c UJ 1 u 01 c CJ Oj L. <0 " ' ....... Dept, or Area: Dept. 53 (P hthallc)' B R E A T II- 1NG EQUIP- Date: July 1980 CORRECTIVE ACTION OR STATUS O) E m 5! o AC c 3 4> U J .* a. U 3 <0 u -- M u X C al t u *J c --<0 c o J h -- 3 SB Ul ui uo Z3 UJ V-- c 3 _J UJ 3 O. u<vt >- ar N ST w br n. 9% Ov 3 333n Ul >4* Ni. s 3 UJ -J O. 55 >jU- 3 < C UJ ae > P> < --< 93n * m Si sc C r 3 => f? IA -* m i = X yj a. " n X) Old Not Hear Masks 1 i ! CM 1 2 rn LA i *-1 M C O' N9*t VN. 3" sso. 3 a"N.r 9t SN ' D> S' 9 9 i W> 0J >- |i aa aN*r *N 333333 33 - CM 3 33 3 3 3 r> 9 CM o 9X)i j 33 3333 Tt 91 rM c- O -N i 3 C rsj 3 *r >4 99 T) o V) 0J -- 01 & Z 31 a *Nk "'O' CO M VO o y 3 o V i TT 3 .M 3 3 v| i 1 i o V A SAMPLES TOTAL SAMPLES TEXAS CITY INDUSTRIAL HYGIENE STATUS REPORT CM ' pM 01 p-4 CO CM CM J pCM4 s 4 'IN IT IA L DETERMIN ATION NOT MONI TORED Or c ai o r> cn u 00 a. a. UJ Q. Other X imr 21 3 U. CM X p4 l - U) CM Z I-- ~+\ So o 90 dBA XXX i 11_____ ~n r> D 33 lE-l 3 B u 3B LEA i i 1 kT> CM SKIN 100 i j ! ii r-. 1 FUNCTION AND NUMBER tIOO<To1 )( ,Cl. PROIh trod; 1 -- 3 2= < yj < a: El K ------ z i < yXj c < z *1< pz< yj < C XK i 1 <yXj < ~\ 3 3 <1 SC a. -- Z3 3 < EE p. b^ Z -- < 3 X3 a. < yj : Q . <i 3 3 a:1 -i Z < 53 3Xa. pPc-'.1(O3 ts me. , Sa.! b- <E! < UXJ < < UJ (X < <i 0-Xylene S ulfur Dioxide Vanadium Pentoxlde Sodium Hydroxide Phtha1ic Anhydride Maleic Anhydride Hydrazine Sulphuric Acid Noise-Dosimeters Maleic Anhydride Phthallc Esters Sodium S u lfite P hthallc Tars Radiation Microwave Ovens LAIV1000984 LAM000985 Ammonia Noise-Dosimeters Acetone A cetonitrile Acrolein A crylonitrile Microwave Ovens MAP 005158 FUNCTION AND HUMBER TEXAS CITY INDUSTRIAL HYGIENE STATUS REPORT Dept, or Area: Dept. 513. 24 (Haste) Date: Ju ly 19U0 2 s! Z SOUaSJ.i -Y Z; CTt j a. PEL (8hr. C e llin g ) Other INITIAL DETERMIN ATION NOT MINI- TORED TOTAL SAMPLES SAMPLES LAST SURVEY HIGH AVERAGE 1 NO. >PEL OATE ___ S3 StfS BREATH ING' EQUIP- CORRECTIVE ACTION OR STATUS a oQOS- 0 0 ' 01 pr**r CnM* VOP 06 P I-9N* r "T 3; C* CM CM ] if>\ cvjl 1 CM CM --1 --i --11 U<J g i o i i i i 0* 1 1 1 Sz i Z i, aoOS a. IZ i PROD. I PROD. 1 PROD. I MAINT. P-- t 1000 I I I 0.1 oo 0k 1 *! 01 i - a o wp* 3T 3T & 5* O! CM Cvi Ok Ok 9k CM ___ 1 1 n r a 0k 1 La oC a. tM P-- Z <311 --wr AREA l3Bd Eu <0.2 <0.2 o 6 /8 t Dept, or Area: Bulk Loading Date: July 1980'" C_> uj --<h- O s s au to PMUJ3 o 3= toO! *0 -- e3 OU. s? er 3000 ^ tO ^ o o o o oo o= VO 3 co^noo 5i S I=I2S cnj jsj csi evi cr in H in o o a_ TEXAS CITY INDUSTRIAL HYGIENE STATUS REPORT O( --I H- Q t = 1: 3 >. LAM000986 Dept, or Area: Control Lab Date: July 1980 TEXAS CITY INDUSTRIAL HYGIENE STATUS REPORT CORRECTIVE ACTION OR STATUS <c 0 c i aO E AwC. >C 1 No | BREATH- 1 ING EQUIPMENT USED ___ N 1 o zo o zo c o z zo ZO o zo CP s r-F Lv CM CM CM to N cm CM DATE UJ O Cl ZA oOoaso oOo 2 -J CL. s: $ >u>Qw>o-i Zto w<o uu m -u p rr> CM mo w F"* lO o V o V i CM O o CM art a\ V mCM CM M aa* ia O lo V 1 ____ 1 mm m mm fH PmO p-- r*i o m o - SAMPLES HIGH I AVERAGE j QI____ 1 mo O CM CM CM CM - - ON CM in 20 113 20 go 20 SAMPLES TOTAL TORED DETERMIH- | ATI ON NOT MONI Other oc o01 L. 2_ IcEn CO _J UCUJ Oo r-H 100 1 | 100 0001 cmsU. Z i CM P""T ruHCTION oc UJ CO X5zc Z< < [-<J z< z < < < z E<C < < z i z-- < < UJ <C <. <LckcJ. Upstairs `S0 >1 MAP 005160 nitialI [ARM_______ I ANAL. | 1 I IMAINT. MAC Non Aromatics (Hexane) Oenzene Ethyl Benzene Styrene Acetone A c ry lo n itri le Microwave Ovens LAM000987 LAM000988 II rs1 fO! *a 3o C2 1 j= _j i o| 1 A crylonltrile Acetic Acid Stryene Methanol S-790-S-711 Phenol Napthalene Vinyl Acetate Oxo Alcohol Ethyl Benzene u j-Culi 1X o Oil 07 o 1 ay. =3 3 az. z LkJ UJ cl Z as UJ UJ UJ Q u. ce UU FUNCTION AND NUMBER AREA H- a -- UJ < UJ < cr UJ LO UJ TEXAS CITY INDUSTRIAL HYGIENE STATUS REPORT PEL (Olir. C e llin g ) Other I n it ia l DETERMIN ATION NOT M3NI- TORED TOTAL SAMPLES PERSONNEL SAMPLING LAST SURVEY SAMPLES HIGH AVERAGE 100 7. BO m ov Of CM CM rvt CO LL a cm CO rj ou CtoT\ n r CM n cr> rn> kO o *Xtf* r- o NO. >PEL Page 1 of 2 Dept, or Area: Dock 1 Date: July 1980 -- UZZJ Ut/Ji L 00 37 g>et '-s. O in mO EQUIPDATE zo 01 >- >O-J >0~1 r tt CORRECTIVE ACTION OR STATUS _ Not Handled P re-project Board Vapor Col le c tio n Barge Loading Ship Loading n z zo z cl CMlO CM o a. p T38.0 I 136.0 o P*N zo a _J See Dock 2 ac tOcni3l Moo3 Q_ Q_ c. 001 001 Jn w s* V. C vCoL>t O a mjE l et -s - CM CM 3T -N, AO 3T 1 [ i1 i i j !i J J 11 5T PC w O O nin o _ i i_ n rj CpNM O 0 CM r*i XX UJ LO ce UJ < p-- < .j DC < CL Lu UJ a. n 3 CM < UJ 5 200 No Method n n CM o> m a aton CM | a U l CM -- 1 k ci W rL rpn* Lo C o o CM h* k i LL uu l> CM CM *T in 1 _____j n < ! 5. & z< g <z K5 l PIPE FITTERS 50 n CsJ o zO o zo Ship Loading Barge Unloading i j i i ot r 1CmTY o? m n M CM 1 UU CM CM XX i CM ar -- UJ < QUJ CL ID fE J i-------------------- L l b .M No Method ` Not Handled Downwind samples otf barge loading operation - high loloaaddiinng rates \ CcJ i LAM000989 Denzene SAB DUP Noise-Dosimeters FUNCTION AND NUMDER | i | f o in Z or Z 3 Z MC-JJ- CL. TEXAS CITY INDUSTRIAL HYGIENE STATUS REPORT INITIAL DETERMIN i r . C e llin g ) ATION 1 I NOT MONT-| TOTAL 1 Otner TORED j SAMPLES __________! LAST SURVEY SAMPLES HIGH 1______ l i X XX 90 dBA MAP 005162 a OF co= 2o 1 55 -J Uc_J ZA UJ S CGC of U><J _l i GL1UC CL Page 2 o f 2 Dept, or Area: Dock 1 Date: July 19BU | EQUIP- FENT DATE j USED | j CORRECTIVE ACTION OR STATUS TEXAS CITY INDUSTRIAL HYGIENE STATUS REPORT Page 1 of 2 Dept, or Area: Dock 2 Date: July I960 ... LAM000990 MAP 005163 \ U>J O^ -- m H- Z 3 U> O HUJ *-. < CCut- OoC o< d o 3[eu C\J l< S-- H- o O 3 Z UJ CT QV.< O.QC <o rs. r- 9 CO O UJ z cq uj <-- UXJ ofc < -J h- QO s: 3! Q -ccz( <* sO in o o Q- < oc < < LAM000991 MAP 005165 LAM000992 O1U/F1 CJ i0/> Qc11/u1 3 Benzene Ethyl Benzene Phenol (Urine) 3a. ec sUcuJ: TEXAS CITY INDUSTRIAL HYGIENE STATUS REPORT FUNCTION AND NUMOER PEL (8hr. C elling) Other in it ia l DETERMIN ATION NOT MONI TORED TOTAL SAMPLES SAMPLES II9IH _j 1</1 i ac u a. a. SURVEY AVERAGE 5 L0 CM CVI r* a r 3 sOi LO cm i CM - --. ^ o r-* ov mn M 1> 51 z: s &3 a. =(z i| < Uc<sJ FN. CM CmO CM r pH I *M eM CM 100 90 dBA Xl 3 M3 CM O LA em m CM CO nt 30.21 19.20 Z < 3 S rn Z UJ 3 3< 3 l O 3 3o3 UJ O O. 2A 3 m KO 3 9 3 icy eo <fwlJ --33 UO Q_ <o L. DATE H R EAtH - ING EQUIP MENT USED CORRECTIVE ACTION OR STATUS "O c M9 w u cj 0 u. a. 1 <u ST 1 30 I'm Downwlnd-Uarqe Unlo- Ocl 3i3 \ INDUSTRIAL HYGIENE STATUS REPORT Dept, or Area: Dock 4 Date: July 1980______ UJ qj -- Z ChO- UJ -- < BP"uiQS--.SDZUZsOQU'UJJ CO 3T& r** 0D O J3 0(0 iA <-- cP 3C !5E g t-- 5 o S -- -*---- ^ Z UJ H* -Q<Zh Hz oz<ez=a> z z< -- UJ < CC. se < MAP 005166 LAM000993 TEXAS CITY INDUSTRIAL HYGIENE STATUS REPORT Dept, or Area: Dock 5" Date: July 19U0' ~ >L--U Oc_2sEL t3o O t-- <->-*-< O (L<-->. H</-) [Sz9 OC > < --i -- o. rohw' o 3: <Z Q ~ H Zc s ao 6V cP C Q *-oe UZ ?<D LAM000994 TEXAS CITY INDUSTRIAL HYGIENE STATUS REPORT Dept, or Area:Fence Line Date: July 1980'' U>J oQ -- IS> H- Z => O O <-- eic-J; o---- <<--/>t s*= I'JSZ UJ :i Z-- ujEj dcn sz! < --I H- Ca:. ^3! Q -- at, z o H- U O LU cn*** o O cc -- UJ h-OQ uzz z < =5 >uY1 < MAP 005168 LAIV1000995 con lO o o Q_ < Asbestos < LbJ s< FUNCTION AND NUMBER J PEL (8hr. C e llin g ) 1 S U R V E YNUUSTRIAL HYGIENE STATUS REPORT a -1 i. E K 2 o PO a: o. INITIAL DETERMIN j ATION NOT MONI-| TOTAL LAST HIGH j Dept. Date H o rn 1 EQUIP MENT Other TORED SAMPLES SAMPLES j AVERAGE >PEL DATE USED 1 Is a-- l 4-> c .o s= <0 O'* Ol -4 S_ < >1 Jr *3 o -o CORRECTIVE ACTION OR STATUS O0 OO cm CM ji t/1 a > OO 0 CM tr Lfl l- u 2u <+- QJ CM O. *> in o 1 1I I 1 0-1 1 1 SOT1__ C c (O k. )-- 0 C 0 Of o IX CM 0 0CM JI 0 0 O0 o0 0 tn T - CM -- X lO a. Wei ding Fumes Ozone (welding) AREA AREA 0.1 49 erv m a* - * : Plasma C utting ; Torch N itrous Oxlde(weldlnq) AREA 25 Nitrogen Dloxlde(weld) AREA << < kJ LkJ U-I X Breathing A ir S ilic a Microwave Ovens 1 1 AREA -- Noise Dosimeters MA1NT. 5Q(C0] 100(TC] 90 dBA "It k> 5" e to I 65 H 1 0.05 1 1 0.011 65 | 0 O CM r*. o lO 0 00CM V o 00CM LO oO oo CO 0 0 0J 0 VO 0 0 n* <r 0 u MM Oo o> <5 cQtz. uc 0c 0 IS! (0A1 Portable a ir sandblast areas Shops K- 4- W 0 cL. o 0 U 01 u LAM000996 TEXAS CITY INDUSTRIAL HYGIENE STATUS REPORT Dept, or Area: MIsc. Areas Date: July 19U0 uj ^ >O --m Q5C *2g-u^Oi'rELiSi~IS) CO 30 cac ^ SI Q Psiss ,-- sQ g*sZg>-- o fu _* LT> tn <---> oz ezaz MAP 005170 LA1V1000997 ^o517' LAM000998 Eox o oS- <3 1 Radiation Hexane Microwave Ovens _______ m u m ucj <c ooDaO. L r> - o > TEXAS CUT ' INDUSTRIAL HYGIENE STATUS REPORT Uept. Date: or Area: Polyethylene July 198tT ~La~b 1 u) 2 < IE_ -J V SCNJ INITIAL PERSONNEL SAMPLING PEL (8hr. C e llin g ) DETERMIN1 ___________________________________________________1 lJ-U* e3tox j ATION i EQUIP 3Z NOT MONI TOTAL MENT wC. A | O tnerj TORED SAMPLES SAMPLES HIGH j AVERAGE J DATE USED ' o Z mr CORRECTIVE ACTION OR STATUS - -- -- i_ V rsi n 3 Ot (C/N)J CNJ 100 x3 1 6/8*1 i Routine Monitor?nq o CO V CM 3o >i .aCJ s0C 1 "V0cC1Ii CO E IX. VO LC3_J LAM000999 MAP 005172 Noise-Dosimeters M uriatic Acid Styrene Tars Sodium S u lfite Methane U<J c<c z < oO PUNCTION AND HUMBER I TEXAS CITY INDUSTRIAL HYGIENE STATUS REPORT I IN IT IA L PEL (O lir. C e llin g ) DETERMIN J ATION NOT MONI | O ther TORED TOTAL SAMPLES PERSONNEL SAMPLING L>U CC LO < SAMPLES HIGH AVERAGE o\ cr 1 1 CVJ 90dBA il o LO o K. r* o CU V o LO VO o x o> x ca.. lo ao ccc_ z < CC33C. z i o33c j MAINT. 1 Asphyx. V31IV ________ flOMdl' ________ : ih iv h X X ;< X X cQa3c. h- Z < oCC voft - CO VO m - XXX z I Zinc Chromate <_u 5 Chlorine Poly isobutylene tert-B ut.yl Alcohol I<s: z i 1 PROD. 1 PROD. tort: L-- 3O CCCL i te rt-B u t.yl Tormamide Hydrogen Chloride AREA <LJ Hydrogen Cyanide Microwave Ovens 1 1 10 'us (J 3 lO LO T0 > 1` 30 CO SO LCOa lO to VO VO o oOO 3 oo 3 ooo \s m om- 1 OZ LCAUL OO Dept, or Area Power 2 (954) Date Ju ly 1980 X1 I l CD 1 Liquid solution 1 L0. 0UZ1L O V0L). ;JjC wM^y ue nTgR due tc anaiyttcal interference Dept, or Area: Process Teliclinolouy Date: Ju ly 1980 ctuw S** -- b- a ccSO^auSyjZSwUs) e> < 85 < ue >Y S: ,_o 0aa "O <_ --aui < oCL TEXAS CITY INDUSTRIAL HYGIENE STATUS REPORT < < 852s .c *o> o 00 P* -<in o o < 1-00Cl. O C --' UJ =2 E O QJ 6 H- < c. sic. z: < i-- c UJ Q < c. Hc-- <S LAM001000 TABLE IV INITIAL DETERMINATION (ID) Based on the following assessments, determination is made as to whether the chemical or physical agent may be eliminated from actual measurement for initial baseline determination due to low personnel exposure potential. 1. High TLV (100 ppm) 2. Low Vapor Pressure 3. Odor Threshold 4. Method of Handling 5. Work Practices 6. Ventilation 7. Concentration 8. Toxic Properties The following chemicals, in our judgment, meet the above cri teria for initial determination and will be so indicated in our 1isting. MAP 005174 lamooiooi MAP 005175 T3 05 f"H d) c cn 4-1 O J2 05 O0 H c H 4J o 4-1 c M 0) O H id 05 g > 0 0) Q| H J-t JZ (J1 c id ^4 4J id i-i 4-1 4J E-t id 3 64 H 04 r--1 C S-l > 05 rH r4 0) id SZ Ch cn 05 05 >4 rO OC 4-5 S4 c Uc 05 Q H aa 0U i4 04 'oO (d X 0 S 0 u 05 d) r4 4-5 M U <15 -H Qj X0 0 V4 E-* CU 1. Acetylene 10, 35P X 2. Aluminum Powder 13 3. Butane 10 X 4. n-Butanol 70, 71 X 5. Calcium Hydroxide 34F X 6. Carbon Dioxide 44 X 7. Carbon Dust 56, 33 8. Condensate (SNIFO) 10, 73 X 9. Copper Salts-Cat. 48 10. Diisobutyl Aluminum Hydride 35P X xl. Ethylene 13, 35P X 12. Flux Oil 14 13. Isobutylene 25, 35P X 14. Napthalene Cone. 10 X 15. Nickel Salts 44,48 16. Nitrilotriacetic Acid 13,44 X 17. Noise (selected areas) Grds, Docks, 513, Off. Labs, Trk, Str , Instr. 18. Phosphoric Acid 27 X 19. Phthalic Tars 53 20. Platinum-Rhodium Catalyst 19 21. Polyethylene Antistats 35F 22. Polyethylene Glycol V, _3. Polyisobutylenes 35F X 25 X 24. Propane 10 X X X X X X X X X X X X X X XXXX X XXX XXX XXX XXX XXX X X X IAf XXX XXX XXXX XXXX XXXX XX X X XXX XXX X X X X X X X X X -_X X X X X XX XXX XXXX XXXX X XXX X XXX X XXX X XXX X LAM001002 25. Propylene CO P C d> e P P Ifl a a) a TJ r--1 o ID X! p ID C p ai d) > o <v p E PI ap x: -P E-< m3 Eh P > co (0 x to P a tn S d> o X c 0 H P (0 P X) C p o <u H Q* X0 0p E-c CX X 26. Quench Oils-Dept. 10 10 X X X X X 27. Rhodium Iodide 50 X XXXX 2 8. SAB 70,71 X X XXX X 29. Sodium Formate 25 X X XXX V /I 30. Sodium Hydroxide 44, 51, 53, 70, 71, 13 , 16, 25, 27, 33, 35P X X XXX 31. Sodium Phosphite- Solid 44, 46 X X XXXX X 32. Sodium sulfite 51, 53, 954 X X XXXX X 33. Styrene Tars 16, 954 X XXX '-ad. Sulfuric Acid 19, 25, 56, 51, 53 X X XXX J - fih. -- LAM001003 T.C. No. IK-1 IH-2 IH-3 IH-4 IH-5 IH-105 IH-6 IH-7 IH-107 IH-8 IH-9 IH--109 IH-10 IH--11 IH-11B IH-12 IH-112 IH-13 IH-15 IH-16 IH-17 IH--18 IH--19 IH--20 IH-21 IH--22 IH- 23 IH-24 IH-25 IH--26 IH- 27 IH-28 IH- 29 IH-30 IH--31 IH-3 2 IH-3 3 IH-34 IH- 35 IH-36 TABLE V ANALYTICAL METHODS IN USE AT TEXAS CITY Analysis Sample Device Compounds GRV P. Balance G.C. G.C. G.C. G.C. G.C. G.C. G.C. G.C. G.C. G.C. G.C. G.C. G.C. G.C. G.C. G.C. G.C. G.C. G.C. G.C. G.C. G.C. Drager T. G.C. T.T. T.T. Dosimeter A. A. G.C. G.C. See 109 G.C. G.C. G.C. G.C. Filter P.` Balance Biol. T N Badge N N Badge T N Badge 101 101 T N Badge Filter Sperocarb N Filter NIOSH Glass/C N N Filter Impinger Impinger Filter Impinger FH .5 pi filter Impinger XAD-2 Tube Filter Sperocarb Dust by filter (PE, cat. silica, asbestos, cobalt, etc.) Dust by Piezo Balance (dust and welding fumes, cobalt) Phenol in urine (Bz exposure) TBA N-Hex. N-Hex. Phenol Hex, Bz, Tol, EB, SM, DiEB Hex, Bz, Tol, EB, SM MEI, MEA, HOAC ACN, DMK, ACK, AN ACN, DMK, ACK, AN Hex, DMK, AN, BZ, TOL, EB, SM, DiEB, Phenol Napt. Same as above - PPB calibration ACY, HOAC, DMF Hex, DMK, BZ, AN, EB, SM Hex, DMK, BZ, AN, EB, SM D-154 MEOH ACY, DMK NS I LN, MEL, LA DMF Heat N-Butanol Carbon Monoxide MEHQ (4, methoxy phenol) Iodine Hyd. Iodide Cont. Noise Stanous Oxlate Stilbene HQ-MEHQ (most any solid material) O-xyl, MA, PA (area sample) Stilbene (gas - aerosol Oxalic Acid ACH LAM001004 MAP 005177 METHODS AVAILABLE NEEDING ADDITIONAL WORK Method No. IH-14 Areas Used PA, MA, O-xyl Work Needed Method failed in first plant test METHODS IN DEVELOPMENT OR RECORDING STAGE Lead by AA METHODS AVAILABLE BUT NOT DEVELOPED FOR TEXAS CITY NIOSH Methods Chromium Ethanol Fuel Oil #6 Phosphoric Acid Sulfuric Acid Sodium Hydroxide 352, 56 160 216, 187 241 323, 333 152, 182 METHODS NEEDED BY PRIORITY 1. Oxo alcohol 2. S790/S711 3. Di-isobutanol 4. Titanium tetrachloride 5. p-tert-butylcatechol 6. HCL tube 7. Condensate mix 8. Polyethylene glycol 9. Methane 10. Sulfonated alkylbenzene -7a.- LAM001005 TABLE VI INDUSTRIAL HYGIENE MONITORING SCHEDULE--1980 LAM001006 -8 MONITORING SCHEDULE JANUARY 1980 Assign ment LW GC GC GC GC LW BM DC & LW DC & BM DC & BM LW DC Chemical and/or Physical Agent Acetaldehyde Acetonitrile Acrolein Acrylonitrile (AN) Acetone Stilbene Noise' Departments or Areas 27 51, Bulk Load, Dock 1, 2 51, Bulk Load, Dock 1, 2 51, Bulk Load, Dock 1, 2 51, Bulk Load, Dock 1, 2 ARMS Plant Wide Chlorine 15, 16, 44, 51, 513, 15, 24 Plantwide) Hydroquinone (HQ) 51 Methyl Ether of Hyroquinone (MEHQ) 51 Hydrogen Chloride 95 4, 13, 14 , 35P, 33 Phthalic Anhydride 53, 56, Bulk Load. -8a 1-A/VI007007 Assign ment BM BM BM BM BM GC GC GC GC LW LW DC BM BM LW LW LW BM LW GC GC DC & LW GC BM GC LW MONITORING SCHEDULE FEBRUARY 1980 Chemical and/or Physical Agent Departments or Areas Acetaldehyde Bulk Load Acrylonitrile (AN) Dock, PT, Mon Lab, 513 Acetylene 10, 35P Butane 10, 35P Butene Chlorine 35P 15, 16, 44, 1, 513, 25, 24 (Plantwide) Condensate (SNIFO) 10, Dock 4 Dimethyl Formamide (DMF) 10 Fuel Oil If6 Dock 4, Power 2 Lactic Acid 33, Mat'l. Hand. Lactonitrile 27, 33 Lead ASMS Maleic Anhydride 53 Phthalic Anhydride 53, 56, Bulk Load. Methyl Lactate 33 Nitric Oxide Maint. Shops (Plantwide) Nitrogen Dioxide Maint. Shops (Plantwide) 0--xylene 5 3, Dock 1, 2 Ozone Maint. Shops Propane 10 Quench Oil 10 Stilbene Styrene Tars Noise Benzene Radiation Wipe Tests (2/19 & 20) -8b.- ARMS 16, 954 Plant Wide ARMS Plantwide 005181 % LAM001008 MONITORING SCHEDULE MARCH 1980 Assign ment LW GC BM LW LW BM BM LW GC BM BM BM & DC BM DC & GC BM LW BM Chemical and/or Physical Agent Departments or - Acrylonitrile (AN) Dock, 51-N tert-Butyl Amine (TBA) 25, Bulk Load Calcium Hydroxide 35P, 35F, Power Carbon Dust 33, 56 Diisobutyl Aluminum Hydride (DIBAH) 35P Dinitrophenol (NS1) 15, 16 Ethyl Chloride 13, 14 Filter Aid 56 Hexane Bulk Load., PT, Mon Lab, PE Lab Hydrazine 44, 5 3 Isobutylene 25, 35 P Lead Propylene ARMS 51, 10 Stilbene Welding Fumes Benzene Carbon Monoxide (CO) ARMS Maint. Shops ARMS 44 35F, ,V00 -8c. - LAM001009 MONITORING SCHEDULE APRIL 1980 Assign ment LW LW LW Chemical and/or Physical Agent Acetone Acetone Cyanohydrin (ACY) Acetonitrile LW Acrolein LW Acrylonitrile GC Asbestos BM Benzene BM Styrene BM Ethylbenzene BM Diethylbenzene BM Toluene GC GC GC BM & DC GC GC DC & BM Breathing Air Ethane Ethylene Lead Nitrilotriacetic Acid (NTA) Stilbene Zinc Chromate Departments or Areas 29, Mon Lab, Dock 5, PT, 51, 513 29, Mat'1. Hand, Dock 5 51, Bulk Load, Mon Lab, Dock 1, 2, PT, 513, 51-N Daily 51, Bulk Load, Mon Lab, Dock 1, 2,' PT, 513, 51-N Daily 51, Bulk Load, Mon Lab, Dock 1, 2, PT, 513, 51-N Daily Plantwide 10, 13, 14, 16, Mon Lab, Dock 3, PT 10, 13, 14, 16, Mon Lab, Dock 3, PT 10, 13, 14, 16, Mon Lab, Dock 3, PT 10, 13, 14, 16, Mon Lab, Dock 3, PT 10, 13, 14, 16, Mon Lab, Dock 4, PT Plantwide 10 10, 13, 14, 35P, 35F ARMS 13, 44 ARMS Power 2 ^AP 005183 -8d- lAMOOIOIO MONITORING SCHEDULE MAY 1980 Assign ment GC LW LW LW LW BM & DC LW BM Chemical and/or Physical Agent Acrylonitrile (AN) Aluminum Aluminum Chloride Catalyst Ammonia Freon 22 Lead Methane Methanol BM Mixed Olefins GC Oxalic Acid GC Stannous Oxalate LW Stilbene RM Monomers Lab Survey RM Benzene Departments or Areas Dock, 51-N 13, 14 13, 14 19, 33, 35P, 51, 513, PT Plantwide ARMS 19, 16, Power 2 33, 44 , 35P, 35F, 50, Dock 1 Bulk Load 48 56 56 ARMS ARMS -8e LAW1001011 MONITORING SCHEDULE JUNE 1980 Assign ment BM RM GC LW GC RM BM & DC DC GC DC & LW GC BM BM GC Chemical and/or Physical Agent Acrylonitrile (AN) Calgon SL 500 (NTA) Carbon Dioxide Chromates Copper Salts Diundecyl Phthalate (DUP) Lead Oxo-alcohols Phosphoric Acid Silica Stilbene PT Labs Benzene Microwave Ovens Departments or Areas Dock, Dept. 51-N 13, 14, 15, 16, 44 44 35F, 51, 48, 56 (Plantwide CT) 48-56 48-56, Dock 1, Mat'l Hand ARMS 48, Dock 1 27 13, 33, 56, Sandblasting ARMS ARMS Cafeteria, CED, Mon Lab, Shops PT MAP 005185 -8 f. - LAM001012 MONITORING SCHEDULE JULY 1980 Assign ment BM Chemical and/or Physical Agent Acrylonitrile (AN) BM Acetonitrile BM Acetone BM Acrolein LW Asbestos LW Breathing Air LW Cobalt LW Heat BM Lead GC Noise RM S-711 GC Stilbene GC Benz ene RM Plant Chemicals LW Status Report Departments or Areas 51, Bulk Load, Mon Lab, Dock 1, 2, PT, 513, 51-N Daily 51, Bulk Load, Mon Lab, Dock 1, 2, PT, 513, 51-N Daily 51, Bulk Load, Mon Lab, Dock 1, 2, PT, 513, 51-N Daily 51, Bulk Load, Mon Lab, Dock 1, 2, PT, 513, 51-N Daily Plantwide Plantwide 48-56 15, 35P, 35F, 44, Bulk Load, (Plantwide) ARMS Plant Wide 48-56, Dock 1 ARMS ARMS Fence Line Plantwide -8 g. - Laivioi0i3 MONITORING SCHEDULE AUGUST 1980 Assign ment LW LW GC LW LW BM RM GC BM - GC GC RM GC RM LW Chemical and/or Physical Agent Acrylonitrile (AN) n-Butanol tert-Butyl Alcohol tert-Butyl Catechol (TBC) tert-Butyl Formamide (TBF) Carbon Monoxide Flux Oil Hydrogen Chloride (HC1) Lead Muriatic Acid Noise Stilbene Titanium Tetrachloride (TiCl^) Benzene Radiation Wipe Tests (8/20 & 21) Departments or Areas Dock, 51-N Dock 1, 2 25, Power 2 15, 16, PT 25, Power 2 44, 50, 48-56, Breathing Air 14 Power 2, 13, 14, 35P, 33 ARMS Power 2, 15, 16 Plantwide ARMS 35P ARMS -fih . - LAM001014 MONITORING SCHEDULE SEPTEMBER 1980 Assign ment BM GC LW Chemical and/or Physical Agent Acetic Acid Acrylonitrile (AN) Benzene LW Styrene LW Diethyl Benzene LW Toluene GC Iodine RM Lead BM Methyl Acetate BM Methyl Iodide LW Noise BM Propionic Acid GC Rhodium Carbonyl GC Rhodium Iodide RM Stilbene RM Benzene Departments or Areas 50, Bulk Load, Dock 1, Dock, 51 -N 10, 13, 14, 16, Mon Lab Dock 3, PT 10, 13, 14, 16, Mon Lab Dock 3, PT 10, 13, 14, 16, Mon Lab Dock 3, PT 10, 13, 14, 16, Mon Lab Dock 3, PT 50 ARMS 50 50 Plantwide 50 50 50 ARMS ARMS oos^8 -8i lAM001015 MONITORING SCHEDULE OCTOBER 1980 Assign ment GC Chemical and/or Physical Agent Acetonitrile (AN) GC Acrolein GC Acrylonitrile BM Ammonium Chloride BM Asbestos LW Breathing Air LW Lead LW Noise RM Phthalic Esters RM Phthalic Tars BM Stilbene BM Benzene Departments or Areas 51, Bulk Load, Mon Lab, Dock 1, 2, PT, 513, 51-N Daily 51, Bulk Load, Mon Lab, Dock 1, 2, PT, 513, 51-N Daily 51, Bulk Load, Mon Lab, Dock 1, 2, PT, 513, 51-N Daily 33 Plantwide Plantwide ARMS Plantwide 56, Dock 1, 2, 5 3, Bulk Load 56 ARMS ARMS -8j U/W00707S MONITORING SCHEDULE NOVEMBER 1980 Assign ment LW BM RM LW GC BM GC RM BM GC GC BM Chemical and/or Physical Agent Acrylonitrile (AN) Bisphenol A Formic Acid Lead Methyl Chloride Polyethylene Dust Polyisobutylenes Sodium Formate Stilbene Sulphur Dioxide Sulfuric Acid Benzene Departments or Areas Dock, 51-N 48-56 25 ARMS 33 35P, 35F, Mat'l Hand 25, Power 2 25 ARMS 51, 53 19, 25, 51, 56, 53 ARMS LAM001017 -8k MONITORING SCHEDULE DECEMBER 1980 Assign ment BM LW LW BM LW LW GC GC Chemical and/or Physical Agent Acrylonitrile (AN) Glycerol Monostearate Ionol Lead Polyethylene Anti-stats Polyethylene Glycol Potassium Hydroxide Sodium Hydroxide GC Sodium Phosphite GC Sodium Sulfite RM Stilbene RM Benzene Departments or Areas Dock, 51-N 35F 35F ARMS 35F 35F 50 10, 44, 51, 53, Dock 16 , 25 , 27 , 33, 35P 44, 56 51, 53, Power 2 ARMS ARMS -81.- LAM001018 MONITORING SCHEDULE DO AS UNIT'S OPERATIONS PERMIT Assignment Chemical and/or Physical Agent Departments or Areas RM Copper-Zinc Compounds 44 LW Dehydro Catalyst 15, 16 RM Acrylonitrile Catalyst 51, PT BM Hydroquinone (HQ) 51 BM Methyl Ether of Hydroquinone (MEHQ) 51 GC Naphthalene Bulk Load (932), Dock 1, 2 LW Napthalene Concentrate Dock 4 LW Nickel Carbonyl 44, 50 LW Nickel Salts 44, 48 GC Olefins Mix 48-56, Dock 2 GC Phenol Dock 1, 2 BM Urine Phenol 13, 14, Dock 3 RM Sulfonated Alky Benzene (SAB) Dock 1, 2 GC Vinyl Acetate Dock 1, 2 BM Vanadium Pentoxide 53 &1 -8 .m- LAM001019