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Confenfs introduction................................................. PART I Principles General Principles............................................................ 7 Preparation of Warning Labels............................................................... 8 labels for Small Commercial Packages.................................................... 11 Labels for Samples and for New Products for Investigational Use . 12 Definitions....................................................................................................... 13 Container Handling and Storage............................................................... 18 Copyright 1945, 1916, 1949 ly Manufacturing Chemists' Association, Enc. ADOPTED .................1915 REVISED.................... 1946 SECOND REVISION. .. 1949 I he information, recommendations and illustrative talxrts contained in this Manual have Irecn umipilrd from sources ftelicvrd to lie reliable and to represent tiie licst current opinion on (he subject- No warranty, guarantee or representation is made by the Association as u the alisohitc correctness nr siifliciency of any infor niation, recommendation oi illustrative laliel contained in this Manual, and Manu larturing Chemists' Assentation assumes no responsibility in connection therewith; nor can it lie assumed dial all warnings and piecauttonary measures are con tained in this Manual, oi that other or additional measures may not be rci|Hired under particular or exeptional conditions or <irrumstanees. PART II Itlostrotivo Warning Labels for Industrial Chemicals Preface Product Labels 19 21 PART III illustrative Warning Labels for Economic Poisons Preface Product Labels . 65 . . . . 68 CMA035913 MANUAL L-1 WARNING LABELS A Guide for the Preparation of Warning Labels for Hazardous Chemicals INTRODUCTION The development of new chemical products and the introduction of chemical processes into ever-widening fields have accentuated the need for furnishing appropriate information in those cases where there are hazards requiring special precautions. Precautionary infor mation should, so far as practicable, reach every person using, han dling, or storing chemicals. The most practical means for the seller to disseminate this information appears to be by warning labels af fixed to containers of hazardous chemicals, bearing appropriate pre cautionary statements expressed as simply and briefly as circum stances permit. Such labels, however, cannot take the place of the ed ucation of employees regarding chemical hazards and the use of safety clothing and equipment which are and must remain the direct responsibility of employers. Many chemicals present no hazards in normal handling and storage and for these products no precautionary statements are necessary on the label. To achieve uniform and more adequate labeling of hazardous chemical products, the Labels and Precautionary Information (LAPI) Committee of the Manufacturing Chemists' Association, Inc., has prepared this Manual for the benefit and guidance of its members. Part I sets forth principles for the preparation of warning labels. Part II contains suggested warning labels for specific chemicals illus trative of the application of these principles. Part III contains sug gested warning labels showing the application of the principles of Part I to a group of chemical products used in the economic poisons field. Individual statutes, regulations or ordinances may require that particular information be included in a label or that a specific label CMA 036914 CMA 036915 relating to characteristics of the container as well as those of its tomeiiis, anti is discussed separately under Container Handling mid Storage instructions, page 18. (f>) The inclusion of the word "POISON" and the skull and cross1 Hines on a label slum id be limited to those cases where the product is a poison according to a definite toxicity standard* or where such use is prescribed by law. When used, this legend should be in ad dition to the other label warnings and should not take the place of the signal words DANGERI, WARNING!, and CAUTIONI which are designed to show the relative degree of hazard. (7) A nondescriptivc code designation or trade name should not be used as the only identification of a hazardous chemical. If the com plete chemical name is not shown, the label should clearly state the type of chemical, c.g., "corrosive acid," "lead compound." (8) Warning statements should be located prominently on the label and should be printed in easily legible type which is in contrast by typography, layout, or color with other printed matter on the lal>cl. The label should be affixed firmly to and in a conspicuous piace on the container. Preparation of Warning Labels In preparing a warning lal>cl for a hazardous chemical, all General Principles should be kept in mind. As outlined in General Principle No. 5, the following information should he considered for inclusion on the label: A. Name of Product This is important information for the safety of handlers and users. It is preferable that the chemical name of the product he used. The recommendations of the American Chemical Society for nomenclature should be followed. Trade names may l>c used in addition to chemical names. A non-dcscriplive code designation or trade name should not be used as the only identification of a hazardous chemical. If the complete chemical name is not shown, the label should at .least clearly state the type of chemiral, e.g., "corrosive acid," "lead compound." H. Signai. Worij This word is intended to draw attention to the presence of hazard, and to indicate the degree of severity. The signal words recommended are, in the order of diminishing sever ity of hazard: See flefinilions page 13. 8 (1) DANGER! (2) WARNING! (3) CAUTION! Degree of severity can be expressed only in relative terms. "Dan ger" is the strongest of the three words and should be used for those products presenting the most serious hazards. "Caution" is recommended for those compounds presenting the least serious hazards. "Warning" is intermediate between "Danger" and "Cau tion." Reference to the illustrative labels in Part II of this Manual will help in the selection of the proper signal word. C. Statement of Hazards This statement should give notice of the hazards that are present in connection with the customary or rea sonably anticipated handling or use of the product. Examples are: CAUSES BURNS VAPOR EXTREMELY HAZARDOUS Many chemical products will present more than one type of hazard, in which case appropriate statements for each significant type should he included on the label. While any compound may be hazardous if improperly used, it is impractical to cover every possible contingency on a label. Efforts should be directed toward giving notice of the significant hazards. In some instances where a mild caution is indicated, the statement of hazards may be omitted and adequate information provided by the signal word "Caution" followed by the statement of precautionary measures. D. Precautionary Measures These instructions are intended to supplement the statement of hazards by briefly setting forth meas ures to be taken to avoid injury or damage from stated hazards. Examples are: Keep away from heat and open flame. Avoid breathing dust. Precautionary measures may be included for less serious hazards not considered of sufficient importance to require inclusion in the statement of hazards. In some instances, the omission of a pre cautionary statement may be justified where the measure to be followed is obvious from the statement of hazard. For example, "Do not take internally" is unnecessary when the statement of hazard contaitfs the words, "May be fatal if swallowed." 9 C M A 035916 E. Instruct ions in Case of Contact or Exposure The primary purpose of a warning Jahcl is to prevent injury or damage. How ever, instructions in rase of contact or ex|>osnre may he included in those instances where the results of contact or exposure are severe and immediate treatment is highly desirable, and where simple remedial measures may be taken safely by non-professional persons before mcdital assistance is available. Instructions should he limited to recognised first aid procedures based on simple methods and commonly available materials. In structions for strictly medical treatment should be omitted except when specifically required by law. Itecause of the serious and lasting effects that may result from eye injut ies, a recommendation to get medical attention should accom pany any specific instructions directed to treatment of the eyes. In certain instances simple remedial measures such as washing or removal of clothing may be included where they will serve to avoid serious injury following contact or exposure. All precautionary information should appear on the label as a unit anti should be printed in the order given above. The labels in ('arts II and III illustrate suitable arrangements and indicate rel ative prominence that should Ire given to the individual statements. Such tela live prominence may be achieved in a number of ways such as by variation in type si/.e, color, or layout of the printed material. Table I, on Page ](i, is intended as a guide in the selection of precautionary statements for warning labels. Listed are classifica tions of materials according to the hazardous properties most freipu ntly encountered in chemical products. Opposite each classifica tion ate given statements of hazard, precautionary measures and, in some cases, instructions in case of contact or exposure. It is important to recognize that t hetnicals can have inherent in them more than one of such hazardous pro|>eities, and that the label wording for such products should include an appropriate combination of the pertinent statements. As each chemical product must be treated individually in the light or its own (haractcvistii s and customary ot reasonably anticipated handling or use, there will l>e many instances in which the illustra tive statements in Table 1 wilt not be applicable, cither because they do not act to atcly express the degree of hazard or because they fail to cover the pariitulat t haiat (eristics. In such cases, suitable state ments should be < hosen to fit the situation. The illustrative labels in Part II of this Manual may be helpful in the choice of appropriate wording. 10 Labels for Small Commercial Packages The principles governing the preparation of warning labels dis cussed in Part I and the illustrative labels in Part II of this Manual have been developed primarily for bulk packages of chemicals in tended for industrial use. The general principles apply, however, to chemicals packaged in small containers. These may include, among others, chemical products in retail packages intended for the ultimate consumer; highly purified chemicals intended for research, testing, or control; and chemicals intended for professional use such as in pharmacy. As stated in the General Principles on page 2, each chemical prod uct presents a distinct problem and must be treated individually in the light of its own characteristics. This same principle will apply to small containers. Small containers may present a problem of less available space for labeling purposes. Careful and selective shorten ing of warning statements for such containers may be in order if necessary to permit legibility, or if the wording on labels for the chemical in industrial packages is not applicable. Consideration should always be given to (1) the intended or reasonably anticipated handling or use of the particular product, (2) the training and ex perience of the expected user, and (3) the extent to which the hazard is modified by the size or type of container. The following principles are recommended for condensation of suggested label wording where necessary or advisable: (1) Retain the Signal Word; (2) Retain the Statement of Hazards, shortened if necessary to a practical equivalent; (3) Consider omission of Precautionary Measures if they are clearly indicated or implied from the Statement of Hazards or can be clearly indicated or implied by revising the Statement of Hazards; (4) Consider omission of wording relating to hazards that may be less serious because of the particular characteristics of the package, the nature of the use, and the training and experience of the user. Care must be taken to include precautionary measures for any ad ditional hazard which may be present as a re.sult of such character istics, use, or training and experience. (5) Care should be taken that labels prepared in accordance with the above principles include all information required by law (see footnote page 6). 11 Labels for Samples and for New Products for Investigational Use Samples: In general, (he lal>cl lor samples of a product already in commer cial production should bear the same precautionary information that is on the commercial label. Labels for samples of products not in commercial production should be prepared in accordance will) the principles stated in the introduction and General Principles. New Products for Investigational Use: Toxicological data should be obtained on any product before it is distributed. However, when new chemicals are being packaged and delivered for investigational use, certain exceptions for labeling sam ples of these chemicals may be necessary. The quantities of investiga tional products available for delivery arc sometimes so small, and the usefulness of the chemical so uncertain, that complete chemical or toxicological studies are not practicable. Also the chemical may re quire packaging for and delivery to investigators for the purpose of obtaining the data necessary for adequate lalxding. To cover such cases (and such cases only) the following guide is suggested for pre paring labels during the period of investigation: (NAME OR DESCRIPTION Of PRODUCT) FOR INVESTIGATIONAL USE ONLY SIGNAL WORD) STATEMENT OF KNOWN HAZARDS Appropriate precautionary measures Appropriate instructions in case of contact or exposure IMPORTANT! The chemical, physical, and toxicological prop erties of this product have not been fully investigated and its handling or use may (be hazardous) (present additional hazards). Exercise due care. Definitions Plammadi.e Liquid1--Any liquid which gives olf flammable vapors (as determined by flash point from Tagliabue's open-cup tester, as used for test of burning oils) at or below a temperature of 80F. Extremely Flammaiile I.iquid2--Any liquid which gives off flam mable vapors (as determined by flash point from Tagliabue's open-cup tester, as used for test of burning oils) at or below a temperature of 20F. L>)RROsive2 (Physiological)--An agent which in contact with living tissue will cause more or less severe destruction of tissue by chem ical action. As used in warning labeling, the term "corrosive" refers to action on living tissue and should not be confused with action on inanimate surfaces such as metals, glass or wood. Irritant2 (Physiological)--An agent which in contact with living tissue will induce either immediately or after prolonged or re peated contact a more or less severe local tissue reaction not lead ing directly to destruction of tissue. Sensitizer2 (Physiological)--A material which as ordinarily han dled does not necessarily cause any discernible reaction in living tissue but which after initial or repeated contact with the tissue of some individuals may, at a later date, produce a prompt inflam matory reaction on contact, even in minute amounts, with the tis sue of the same individuals. Oust*--Solid particles generated by handling, crushing, grinding, rapid impact, detonation and decrepitation of organic or inorganic materials such as rock, ore, metal, coal, wood, grain, etc. A dust does not tend to flocculate except under electrostatic forces; it docs not diffuse in air but settles under the influence of gravity. Fume*--Solid particles generated by condensation from the gaseous slate, generally after volatilization from molten metals, etc., and often accompanied by a chemical reaction such as oxidation. A fume flocculates and sometimes coalesces. Mist*--Suspended liquid droplets generated by condensation from the gaseous to the liquid state or by breaking up a liquid into a dispersed state, such as by splashing, foaming and atomizing. 13 CMA 035918 Gas2--A normally formless fluid which occupies the space of enclo sure and which can he changed to the liquid or solid state by the effect of increased pressure or decreased tem|>erature or both. A gas diffuses. Vapor2--The gaseous form of a substance which is normally in the solid or liquid state. A vaj>or diffuses. Poison2 Nolo: The true <lr terminal inn nt tire "poisonous" properties of a chemical or ini store of chcmiials must l>c based on its effect on humans. The collection of adctpialc data from human experience is usually impossible. In the alscnec of such data it is desirable In establish for labeling purposes some arbitrary standards based on past experiences and some methods of testing which will permit the presump! ion of the possible hazards inherent in a given product. The use of laboratory animals for this purpose is now cons id ered the m<l reliable method generally available when conducted under controlled conditions. A poison is commonly understood to Ire a product, contact with which will lead to fatal results, usually in a short peritxl of time. Earlier definitions have in most instances considered only oral intake. It is Incoming more gen erally recognized, however, that other modes of enntart or routes of entry, in particular inhalation and absorption lbrough the skin, may have similar fatal effect. Any definition of poison should, therefore, include Ihcse three common routes of entry. --A chemical or mixture of themicals which falls within any of the following categories: (a) Produces death within 48 hours in half or more than half of a group of 10 or more lalxiratory white rats weighing 200-300 grams at a single dose of !>0 milligrams or less per kilogram of Iroily weight, when administered orally; or (b) Produces death within 48 hours in half or more than half of a group of 10 or more laboratory white rats weighing 200-300 grams, when inhaled continuously for a period of one hour or less at an atmospheric concentration of 2 milligrams or less per liter of gas, vapor, mist, or dust, provided such concentration is likely to be encountered by man when the chemical product is used in any reasonable forsceable manner; or (c) Produces death within 48 hours in half or more than half of a glintp of 10 or more rabbits tested in a dosage of 200 milligrams or less per kilogram body weight, when administered by contin uous contact with (he bare skin for 24 hours or less. If available data on human experience wit]) any chemical in the alMjve-natiled concentrations indicate results different from those 14 obtained on animals, the human data shall take precedence in determining whether the product falls within the definition of poison. MiXTIJRe2-A physical commingling of two or more substances which mayor may not bear a fixed proportion to one another and which have not reacted chemically with one another. Economic PoisoN4-Any substance or mixture of substances intended for preventing, destroying, repelling, or mitigating any insects, rodents, fungi, weeds, and other forms of plant or animal life or viruses, except viruses on or in living man or other animals, which the Secretary (of Agriculture) shall declare to be a pest. t ICC definition. While the term "inflammabte" has been used by the ICC the preferred form "flammable" is used in this Manual, and is approved by the ICC. 2. MCA definition. J. As defined in Chapter II "Engineering Control of the Air Contamination of the Working Environment" (Allen IV Brandt, D.Sc.) page 198, Manual of Industrial Hygiene." USI'HS. Emm Federal Insecticide, Fungicide and Rodcnlicide Act. ft should be under stood that there are laws, ordinances, and regulations in certain slates which declare to l>e pests tilings which may not lie so considered at present under the Federal Act. 15 TABLE 1 Product! will be encountered that present hozords varying in kind or degree from those * lilted. Appropriate statements of hazards procautionary nuaiura ond in*trwlM in cam of contact or exposure ihould bo prepared on tho basil of tho properties of Hi* prod uct following Hi* pattern and gintrd phraseology of tho following table. Pounlbtficol words In tho table oxprnis variations in kind or degree and are to be used where appli-b cable. ! Clow of Haiard Statements of Hazard , Precautionary Measures Selection to be based an ocfuol hazards of use and^ Selection to be based on octuoi hazards of use ond degree of haiard / degree of hozard Instructions in Case of Contact or Exposure Selection to be based on necessity for prompt action in order to avoid serious effects I, Flammoble Liquids (flash points ore determined by the Togliabue Open-Cup Method) A. Flash point 20f. or below B. Flash point above 20*F. to IO*F. inclusive II. Oxidising Agents Extremely Flammable -F-la-m--m--a-ble Strong Oxidant Contact with Combustible Material May Couse Fire Keep away from heot (sparks) and open flam*. Keep container dosed (and away from heat). j Use with adequate ventilation. 1 Store separately (away) from ond avoid contact with combustible materials. Avoid contamination of dolhing as it becomes dan gerously flammable when dry. Keep container dosed (and owoy from heal). Avoid contact with skin and eyes. In case of contact, immediately flush skin or eyes with plenty of water for (at least) 15 minutes; far eyes, get medical oltention. Wash dothing thor oughly at once. Sweep up spillage ol once. Flush or absorb tpUloge with ............ III. Moteriols Giving Vapors lapidy Toxic or Extremely Irritating on Exposure for a Short lime or to Low Concentrations Vapor (Extremely) Hazardous (trritoting) Hazardous liquid and Vapor (Got under Pressure) Vapor Poisonous If Inhaled | Vopor May Be fotal If Inhaled Nete: POISON* should be Induded If the product/ meets the definition of "poison" given on Page 14 or Is required by law. Do not breathe vapor. Do not get in eyes, on skin, on dolhing. Use only with adequate ventilation. Keep container dosed (and away from heat). Have air line respirator or self-contained respirator available for emergency. oxygen tn case of contact. Immediately flush skin or eyes with plenty of water for (of least) 15 minutes; for eyes, get medical attention. Remove and wash dothing before re-use. Note: If POISON* is used, odd ontidote statement as required. IV. Materials Giving Vapors Hazardous from Pro longed or Repeated Exposures or Exposure to High Concentrations Vopor Harmful Causes Irritation of Eyes, Nose, and Throat Use only with adequate ventilation. Avoid (prolonged or repeated) breolhing (of) vapor. Avoid contoct with skin, eyes, and dolhing. Keep container dosed (and away from heat). If spilled on dothing, remove and wash before re-use. In case of exposure to high concentrations, remove to fresh air. V. Gases and Vapors Physiologically Inert Gas (Vapor) Reduces Oxygen Available for Breathing Releases Heavy Goa (Vapor) which May Cause Suf focation Use with adequate ventilation. Keep container dosed. Do not enter storage areas unless adequately venti lated. If affected by exposure, remove to fresh air. If breathing has stopped, apply artificial respiration. VI. Materials In Dust Form Hazardous from Inhalation or Contact Hazardous (Harmful) Dust Harmful If Inhaled Couset Irritation of SkJn, Nose, and Throot Do not breothe dust. Avoid breathing dust. Wash thoroughly before eating or smoking. Avoid contact with skin, eyes, and dothing. In case of contact, immediately flush skin or eyes with plenty of woter for (at least) 15 minutes; for eyes, get medical attention. Remove and wash dothing before re-use. Vli. Skin Irritants--Corrosive VIII. Materials Causing Skin Irritation after IX. Materials Toxic through Skin Absorption X. Materials Toxic if Swallowed 16 OB S <o Causes Severe Burns Causes Burns Do not gel in eyes, on skin, on clothing. n Avoid contact with skin, eyes, and dothing. May Couse Burns Causes Skin Irritation May Cause Skin Irritation r Avoid exposure to (concentrated) vapor. T Avoid (prolonged or repeated) contact with skin. * Wash thoroughly before eating or smoking. Avoid exposure to (concentrated) vapor. Hazardous Solid (liquid) Rapidly Absorbed through Skin r iAbsorbed through Skin Note; POISON* should be induded If the produ* meets the definition of "poison" given on Poge 1 or Is required by low. Do not get in eyes, on skin, on clothing. Avoid contact with skin, eyes, and dothing. Poisonous If Swallowed Wash thoroughly before eating or smoking. May Be Fatal if Swallowed Wash thoroughly after handling. Harmful if Swallowed Do not breathe dust (vopor). Note: POISON* should be Induded if the prodod f Avoid breathing dust (vopor). meets the definition of "poison" given on Page 14^ Do not take inter noli y (only if statement of hozard or is required by law. does not make this dear). `Poison with Skull and Crossbones in cate of contact, immediately flush skin or eyes with plenty of woter for (at least) 15 minutes; far eyes, get medical oltention. Remove and wash dothing before re-use. In case of contoct, immediately remove all contami nated dothing and flush skin or eyes with plenty of water for (at least) 15 minutes; for eyes, get medical attention. Wash dothing before re-use. Note: If POISON* It used, odd antidote statement os required. Note: If POISON* is used, odd antidote statement as required. Poison with Skull and Crossbones 17 CMA 035920 Container Handling and Storage Care should always be exercised in handling and storing containus of hazardous chemicals and in removing the contents. The Con tainer Committees of the Manufacturing Chemists' Association have recommended the general precautions given below for handling and storing certain classes of containers. Applicable phrases may he selected from these statements. These may be used either as separate labels or in combination with the warning labels given in Part II. Where the ptoperties of the chemical require special or additional precautions, such instructions are indicated in some instances in conjunction with the individual label in Part II. Melal Drum Handling and Storage (for liquid, amt .ai-iiqu>d>) Krpp |tlug up lo prevent leakage. Keep ilrmn out of *im anil away from licat. Relieve internal pressure when received ami at least weekly thereafter by slowly loosening plug. Relighlcn immediately. Never nsc pressure to empty. Keep lights, fire, and sparks away from drum oftenmgs. Drum most not Ik* washed out or used for other purjmses. Replace plug after eath withdrawal and return with empty drum. In ease of spillage. Hush with plenty of water. Glass Carboy Handling and Storage Before moving ciirlniy le sure rfosme is srrmelv fastened. Ijxtfrn closure carefully. Keep out of sun amt awat from heat. Never use pressure to empty. Completely drain tarlmy before returning. In case of spillage, flush with plenty of water. W oden Barrel Handling and Storage (for liquid, and ,,mi-liquid,) Keep out of sun and away from heal. Store with bilge bung up. Never use pressure lo empty. Drain completely. Keep barrel moist--.shrinkage may rau.se leaks. In case of spillage, flush with plenty of water. Cylinder Handling and Storage Keep away from heat. Do not store in sunlight. Never drop cylinders. fie sure connections are tight. IfX Regulations prohibit refilling <>lim1er without permisson of owner. II avr airline respirator or sclf-umlaiurd oxygen respirator available for emergency. 18 PART II Illustrative Warning Labels for Industrial Chemicals The warning labels in this section have been prepared to demon strate the practical application of the principles in Part 1 to a number of chemical products intended for industriaf use. The user should familiarize himself with Part I before adapting any of the label state ments contained in Part II to bis products. The chemicals were se lected to illustrate labeling for the major types of hazards commonly encountered. Consequently the listing covers only a relatively few of ihe hazardous chemicals for which warning labels are necessary. In many cases these labels are applicable to other products some of which are listed with appropriate cross references. The labels are based on the properties of the named chemicals; the presence of other substances, including impurities, may alter these properties and necessitate additional or different precautionary in formation. General information regarding the handling and storage of con tainers is not included on these labels. This subject is discussed under the heading, "Container Handling and Storage," page 18. First aid treatment is given for a few products only. Such informa tion may be desirable on other products. Where "clothing" is men tioned in first aid instructions, it should be understood to mean all articles of clothing, including shoes, garters, and other accessories. Shoes are specifically named in some instructions, because of special hazards arising from absorption of the chemical by leather. The United States Public Health Service has approved the text of the warning labels shown in this section for the following chemicals covered by labeling agreements between the Surgeon General and manufacturers of such products: Methanol Chlorinated Diphenyls Carbon Disulfide Chlorinated Diphenyl Oxides Aniline Oil Carbon Tetrachloride and similar Benzene volatile chlorinated Chlorinated Naphthalenes liquid hydrocarbons lhe notation, "MCA Chemical Safety Data Sheet available," ap pearing with certain labels in this section refers to Data Sheets pub- 19 lished by the Manufacturing Chemists' Association, Inc. These jin hi it a lions contain detailed informal inn on the chemical, physical, and toxicological [iiopcrlics of the jiroduct, as well as information on shijijiing toniaineis, lalieling, storage, hamlling and jiroteclivc equip ment. Prices and a comjiletc list ol available Data Sheets may be obtained from the Association. . The warning labels suggested in this Manual should he used in addition to, or in combination with, any label required by law. ACETALDEHYDE DANGER! EXTREMELY FLAMMABLE Keep away from heat, sparks, and open flame. Keep container dosed. Use with adequate ventilation. Avoid prolonged breathing of vapor. Chill thoroughly before opening. ACETIC ACID, GLACIAL DANGER! CAUSES SEVERE BURNS Do not get liquid or vapor in eyes, on skin, on clothing. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. *Glacial Acetic Acid freezes at 62F., forming hard lumps (which may break carboy when moved). *Slore in area maintained above 62 F. *lf frozen, thaw by carefully moving carboy to warm area. ACETIC ACID, 80% DANGERI CAUSES SEVERE BURNS Do not get liquid or vapor in eyes, on skin, on clothing. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attenti n. ACETIC ACID, 56%--70% WARNING! MAY CAUSE BURNS Avoid contact with skin, eyes, and clothing. In case of contact, immediately flush skin or eyes with plenty f water for at least 15 minutes; for eyes, get medical attenti n.* *Addition to "Conlainar Handling and Storago," p. 18. 20 21 CMA 035922 Container Handling and Storage Care should always be exercised in handling and storing contain ers of hazardous chemicals and in removing the contents. The Con tainer Committees of the Manufactuiing Chenlists' Association have recommended the general precautions given below for handling and storing certain classes of containers. Applicable phrases may be selected from these statements. These may be used either as separate lairds or in combination with the warning labels given in Part II. Where the properties of the chemical require special or additional precautions, such instructions are indicated in some instances in conjunction with the individual label in Part If. Metal Drum Handting and Storage (far liquids and t*m4qui4t| Keep plug up to prevent leakage. Keep drum out ot sun and away from heal. Relieve internal pressure when received and at least weekly thereafter hy slowly loosening plug. Ketighten immediately. Never use pressure to empty. Keep lights, fire, and sparks away from drum o|>enings. Drum must not lie washed out or used for other purposes. Replace plug after each withdrawal and return with empty drum. In case of spillage. Hush with plenty of water. Gloss Carboy Handling and Starago Ik-fore moving car boy be Mire clusuic is sccindp fastened. Irooscn closure carefully. Keep out of sun and away from lieat. Never use pressure to empty. Completely drain carboy before returning. In case of spillage, flush with plenty of water. Wooden Barrel Handling and Storage {for liquids awl --mi liquid*) Keep out of sun and away from heat. Store with bilge bung up. Never use pressure to empty. Drain completely. Keep barrel moist--shrinkage may cause leaks. In case of spillage, flush with plenty of water. Cylinder Handling and Storage Keep away from heat. Do not store in sunlight. Never drop cylinders. He sure connections are tight. ICC Regulations prohibit reft I Ling cylinder without |x.Tmisson of owner. Have airline respirator or self-contained oxygen respirator available for emergency. IB PART II Illustrative Warning Labels for Industrial Chemicals The warning labels in tbis section have been prepared to demon strate the practical application of the principles in Part I to a number ol chemical products intended for industrial use. The user should familiarize himself with Part I before adapting any of tbe label state ments contained in Part If to his products. The chemicals were se lected to illustrate labeling for the major types of hazards commonly encountered. Consequently the listing covers only a relatively few oi the hazardous chemicals lor which warning labels are necessary. In many cases these labels arc applicable to other products some ol which are listed with appropriate cross references. Tbe labels are based on the properties of the named cbeiuiial^ tlie presence of other substances, including impurities, may alter these properties and necessitate additional or different precautionary in formation. General information regarding the handling and storage of con tainers is not included on these labels. This subject is discussed under the heading, `Container Handling and Storage," page 18. First aid treatment is given for a few products only. Such infoi illa tion may be desirable on other products. Where "clothing" is men tioned in first aid instructions, it should be understood to mean alt articles of clothing, including shoes, garters, and other accessories. Shoes are specifically named in some instructions, because of special hazards arising from absorption of the chemical by leather. The United States Public Health Service has approved the text of the warning labels shown in this section for the following chemicals covered by labeling agreements between the Surgeon General and manufacturers of such products: Methanol Chlorinated Diphenyls Carbon Disulfide Chlorinated Diphenyl Oxides Aniline Oil Carbon Tetrachloride and similar Benzene volatile chlorinated Chlorinated Naphthalenes liquid hydrocarbons The notation, "MCA Chemical Safely Data Sheet available," a|>pearing^vith certain lalrels in this section refers to Data Sheets pub- 19 CMA 036923 lishcd by the Manufacturing Chemists' Association, ` Inc. These publications contain detailed iniunnalion oil the chemical, physical, and toxicological properties of the product, as well as information on shipping containers, labeling, storage, handling and ptotective equip ment. Prices and a complete list ol available Data Sheets may be obtained from the Association. The warning labels suggested in this Manual should be used in addition to, or in combination with, any label required by law. 20 ACETALDEHYDE DANGER! EXTREMELY FLAMMABLE Keep away from heat, sparks, and open flame. Keep container closed. Use with adequate ventilation. Avoid prolonged breathing of vapor. Chill thoroughly before opening. ACETIC ACID, GLACIAL DANGER) CAUSES SEVERE BURNS Do not get liquid or vapor in eyes, on skin, on clothing. In cose of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes,- for eyes, get medical attention. *Glacial Acetic Acid freezes at 62,JF., forming hard lumps (which may break carboy when moved). *Store in area maintained above 62 F. *lf frozen, thaw by carefully moving carboy to warm area. ACETIC ACID, 80% DANGER! CAUSES SEVERE BURNS Do not get liquid or vapor in eyes, on skin, on clothing. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. ACETIC ACID, 56%--70% WARN1NGI MAY CAUSE BURNS Avoid contact with skin, eyes, and clothing. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention.* *Addition to "Container Handling and Slorogi," p. 19. 21 I i i i j ACETIC ACID, 28% CAUTIONI MAY CAUSE BURNS Avoid contact with skin, eyes, and clothing. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. ACETIC ANHYDRIDE WARNINGI CAUSES BURNS VAPOR HARMFUL Avoid contact of liquid or vapor with skin, eyes, and clothing. Av id breathing vapor. In case f contact, immediately flush skin or eyes with plenty of water for at least IS minutes; for eyes, get medical attention. MCA Chwnical Softly Data Slwtl available ACETONE DANGER! EXTREMELY FLAMMABLE Keep away from heat, sparks, and open flame. Keep c ntainer closed. Use with adequate ventilation. Av id prolonged or repeated contact with skin. ACETYL CHLORIDE DANGERI FLAMMABLE CAUSES SEVERE BURNS Keep away from heat and open flame. Keep container closed. Do not get in eyes, on skin, on clothing. Av id exposure to concentrated vapor. o In case f contact, immediately flush skin or eyes with plenty of s> water for at least 15 minutes; for eyes, get medical attention. o Do not allow water to get into container. ACRYLONITRILE DANGER) VAPOR HAZARDOUS FLAMMABLE Do not breathe vapor. Do not get in eyes, on skin, on clothing. Use with adequate ventilation. Keep away from heat and open flame. Keep container closed. POISON ^ First Aid Treatment--Antidote (Uh iamt first aid treatment as rsconrunindsd for CYANIDES, INORGANIC) MCA Chamkal Safely Data Sfesl available ALLYL ALCOHOL DANGER) RAPIDLY ABSORBED THROUGH SKIN VAPOR EXTREMELY HAZARDOUS FLAMMABLE Do not get in eyes, on skin, on clothing. Do not breathe vapor. Keep away from heat and open flame. Keep container closed. Do not take internally. In case of contact, immediately remove all contaminated clothing and flush skin or eyes with plenty of water for at least 15 minutes; for eyes, gel medical attention. Wash clothing befor re-use. ALLYL CHLORIDE DANGERI VAPOR HARMFUL FLAMMABLE Do not gel in eyes, on skin, on clothing. Do not breathe vapor. Keep away from heat and open flame. Keep container closed. AMMONIA, ANHYDROUS WARNING) HAZARDOUS LIQUID AND VAPOR UNDER PRESSURE LIQUID CAUSES BURNS VAPOR EXTREMELY IRRITATING Do not breathe vapor. Do not get in eyes, on skin, on clothing. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes. Call a physician at once in case f burns, especially to the eyes, nose, and throat, or if the patient is unconscious. AMMONIA, AQUA-See AMMONIUM HYDROXIDE AMMONIUM DICHROMATE WARNING) FLAMMABLE HARMFUL DUST MAY CAUSE RASH OR EXTERNAL ULCERS Keep away from heat, sparks, and open flame. Keep container closed. Avoid c ntact with skin and eyes. Avoid breathing dust or solution spray. In case f contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Wash clothing before re-use. Use fresh clothing daily. Take hot shower after work using plenty f soap. AMMONIUM HYDROXIDE WARNING) LIQUID CAUSES BURNS VAPOR EXTREMELY IRRITATING Avoid breathing vapor. o Av id contact with skin, eyes, and clothing. s In case of contact, immediately flush skin or eyes with plenty of > water for at least 15 minutes; for eyes, get medical attention. co MCA Owniut Safety Data Shoot avaHabfe 01 (to0 24 Ot iso-AMYL ACETATE CAUTION! Avoid prolonged breathing of vapor. Use with adequate ventilation. Avoid prolonged or repeated contact with skin. ANILINE DANGER! RAPIDLY ABSORBED THROUGH SKIN VAPOR HAZARDOUS Do not get in eyes, on skin, on clothing. Avoid breathing vapor. Use only with adequate ventilation. In cose of contact, immediately remove all contaminated clothing, including shoes, and flush skin or eyes with plenty of water for at least 15 minutes; for eyes, gel medical attention. Wash clothing before re-use. POISON ^ MCA Chamical Safety Data Shoal ovculabla ortho-ANISIDINE WARNING) ABSORBED THROUGH SKIN VAPOR HAZARDOUS Avoid contact with skin and eyes. Avoid breathing vapor. In case of contact, flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. para-ANISIDINE WARNING) ABSORBED THROUGH SKIN VAPOR HAZARDOUS Avoid contact with skin and eyes. Avoid breathing dust or vapor. In case of contact, flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. 25 ANTIMONY TRICHLORIDE DANGER) CAUSES SEVERE BURNS VAPOR HAZARDOUS Do not get in eyes, on skin, on clothing. Do n I breathe vapor. Keepc ntainer closed. In case of contact, immediately remove oil contaminated clothing and flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Wash clothing before re-use. ARSENIC TRICHLORIDE DANGERI CAUSES SEVERE BURNS VAPOR EXTREMELY HAZARDOUS Do not get in eyes, on skin, on clothing. Do not breathe vapor. Keep container closed. in cos of contact, immediately remove all contaminated clothing, including shoes, and flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Wash clothing before re-use. POISON ^ BARIUM CHLORIDE WARNING! MAY BE FATAL IF SWALLOWED Avoid inhalation of dust. BARIUM NITRATE WARNING! CONTACT WITH COMBUSTIBLE MATERIAL MAY CAUSE FIRE MAY BE FATAL IF SWALLOWED Keep container closed and away from combustible material and o heat. >s Avoid contact with skin and eyes. Sweep up and carefully remove spilled material. co 8 26 to CD BENZENE (BENZOL) DANGERI EXTREMELY FLAMMABLE VAPOR HARMFUL-POISON Keep away from heat, sparks, and open flame. Keep container closed. Use only with adequate ventilation. Avoid prolonged or repealed breathing of vapor. Avoid prolonged or repealed contact with skin. BENZIDINE warning! hazardous solid and vapor RAPIDLY ABSORBED THROUGH SKIN Avoid breathing dust or vapor. Avoid contact with skin and eyes. In case of contact, immediately wash skin with soap and plenty of water; flush eyes with plenty of water for at least 15 minutes and get medical attention. BENZOYL CHLORIDE WARNING! CAUSES BURNS VAPOR IRRITATING Avoid contact with skin and eyes. Avoid breathing vapor. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical alt ntion. BENZYL CHLORIDE WARNING) CAUSES BURNS Avoid contact with skin, eyes, and clothing. Avoid breathing vapor. In case of contact, immediately wash skin with soap and plenty of water; flush eyes with water for at least IS minutes and get medical attention. For Carboy* or Nickol Drumti Do not transfer to ordinary metal containers without first adding stabilizer. Get instructions from manufacturer. `For Stool Orunt: This product contains a stabilizer. Before transferring, get instruc tions from manufacturer. BROMINE DANGERI CAUSES SEVERE BURNS VAPOR HAZARDOUS Do not get in eyes, on skin, on clothing. Do not breathe vapor. In case f contact, immediately remove all contaminated clothing, including shoes, and flush skin or eyes with plenty of Water for at least 15 minutes; for eyes, get medical attention. Wash clothing before re-use. n-BUTYL ACETATE-Same label as iso-AMYL ACETATE BUTYL ALCOHOL (normal or secondary}-- Sam label as iso-AMYL ACETATE O >S Addition lo "Contouiof Handling and Storagn/' pi IB. 03 Ol N<0 28 tert.-BUTYL ALCOHOL WARNING) FLAMMABLE Keep away from heat and open flame. Keep container closed. Use with adequate ventilation. Avoid prolonged breathing of vapor. Avoid prolonged or repeated contact with skin. n-BUTYLAMINE WARNING) FLAMMABLE MAY CAUSE SKIN IRRITATION Keep away from heat and open flame. Keep container closed. ' ' Use with adequate ventilation. Avoid exposure to vapor. Avoid contact with skin and eyes. In case of contact, flush skin or eyes with plenty of water for at least 15 minutes; for eyes, gel medical attention. para-tert.-BUTYLCATECHOL WARNING) CAUSES SKIN IRRITATION CAUSES BURNS WHEN MOIST Do not get in eyes, on skin, on clothing. In case of contact, immediately wash skin with soap and plenty of water; flush eyes with water for at least 15 minutes and get medical attention. n-BUTYL CHLORIDE DANGER! EXTREMELY FLAMMABLE Keep away from heat, sparks, and open flame. Keep container closed. Use only with adequate ventilation. Avoid prolonged breathing of vapor. Avqid prolonged or repeated contact with skin. 29 n-BUTYL ETHER CAUTIONI TENDS TO FORM EXPLOSIVE PEROXIDES ESPECIALLY WHEN ANHYDROUS Use with adequate ventilation. Avoid prolonged breathing of vapor. Avoid prolonged or repeated contact with skin. Do not allow to evaporate to near dryness. Addition of water or appropriate reducing agents will lessen peroxide formation. BUTYRALDEHYDE-Same label as ETHYL ACETATE CALCIUM CYANIDE DANGER! LIBERATES POISONOUS GAS Av id breathing gas or dust. Av id contact with skin. Keep away from acids. Slor away from feed or food products. Keep container lightly closed and dry. POISON First Aid Treatment--Antidote (U tom first aid Ireatment as racommandad far CYANIDES, INORGANIC) CARBON DIOXIDE, SOLID ("DRY ICE") WARNING! EXTREMELY COLD (109F. below zero) CAUSES SEVERE BURNS UBERATES HEAVY GAS WHICH MAY CAUSE SUFFOCATION Do not get on skin or hands. Do not taste. o Do not put in stoppered or closed containers. Do not enter places where used or stored until adequately o ventilated. 03 S 30 S CARBON DISULFIDE DANGER! EXTREMELY FLAMMABLE VAPOR HARMFUL HIGHLY VOLATILE Keep away from fire, sparks, or heated surfaces. Store in coot piace and keep container closed. Use only with adequate ventilation. Avoid breathing vapor. Avoid contact with skin and eyes. ^ POISON ^ MCA Chamkal Softly Data Slwat avoiiobl* CARBON TETRACHLORIDE WARNING) VAPOR HARMFUL Use only with adequate ventilation. Avoid breathing vapor. Avoid prolonged or repeated contact with skin. Do not take internally. MCA Chamkol Softly Data Shatl availabia CAUSTIC SODA-See SODIUM HYDROXIDE CAUSTIC POTASH-See POTASSIUM HYDROXIDE CHLORAL DANGER! EXTREMELY HAZARDOUS LIQUID AND VAPOR INHALATION MAY CAUSE DELAYED FATAL LUNG INJURY Do not get in eyes, on skin, on clothing. Do not breathe vapor. Use only with adequate ventilation. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. In case of inhalation or suspicion of inhalation, remove patient at once to fresh air and call physician. Keep patient absolutely quiet and start oxygen inhalation through suitable equipment. 31 CHLORINATED DIPHENYL, MONO-, DI-, or TRISame label as CHLORINATED NAPHTHALENE CHLORINATED DIPHENYL OXIDE, MONO-, DI-, or TRISam label as CHLORINATED NAPHTHALENE CHLORINATED NAPHTHALENE (For TRI- and HIGHER CHLORINATED NAPHTHALENES) CAUTION1 Avoid repealed contact with skin. Av id repeated inhalation of fumes and dust. CHLORINE DANGER! HAZARDOUS LIQUID AND GAS UNDER PRESSURE Av id breathing air containing this gas. Avoid contoct with skin or eyes. D not heat cylinders. Have available emergency gas masks opproved by U. S. Bureau f Mines for Chlorine service. Handle and use only in accordance with practice recommended by the chlorine producer. In case of exposure, remove patient to fresh air, keep him warm and quiet, and send for a physician. CHLOROBENZENE (MONOCHLOROBENZENE) WARNINGI VAPOR HARMFUL o Use nly with adequate ventilation. Avoid contact with skin and clothing. Avoid prolonged breathing of vapor. CHLOROFORM WARNINGI VAPOR HARMFUL Use only with odequate ventilation. Avoid breathing vapor. Avoid prolonged or repeated contact with skin. Do not take internally. CHLOROPHENOL (MONOCHLOROPHENOL) (orth , meta, or para)--Same label as PHENOL CHLOROSULFONIC ACID DANGER) CAUSES SEVERE BURNS Do not get in eyes, on skin, on clothing. Avoid breathing vapor. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Do not allow water to get into container. CHLOROTOLUENE (MONOCHLOROTOLUENE) CAUTION) VAPOR HARMFUL Use with adequate ventilation. Avoid prolonged breathing of vapor. CHROMIC ACID DANGER! CONTACT WITH COMBUSTIBLE MATERIAL MAY CAUSE FIRE CAUSES SEVERE BURNS Keep container closed. Avoid contact with skin and eyes. Avoid breathing dust or solution spray. In cose of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Wash clothing before re-use. Use fresh clothing daily. Take hot shower after work using plenty of soap. CREOSOTE OIL {COAL TAR CREOSOTE) CAUTIONI MAY CAUSE SKIN IRRITATION Avoid prolonged or repeated contact with skin. Avoid prolonged breathing of vapor. Use with adequate ventilation. CRESOL (CRESYLIC ACID) DANGER! RAPIDLY ABSORBED THROUGH SKIN CAUSES SEVERE BURNS D not get in eyes, on skin, on clothing. Av id breathing vapor. D not take internally. O In case of contact, immediately remove all contaminated clothing, including shoes, and flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Wash o clothing before r -use. w CYANIDES, INORGANIC (Excluding HYDROCYANIC ACID and CALCIUM CYANIDE) (NAME OF CYANIDE) DANGER) CONTACT WITH ACID LIBERATES POISONOUS GAS Avoid breathing gas or dust. Avoid contact with skin. Keep away from feed or food products. Keep container closed and store in a dry place. POISON ^ First Aid Treatment--Antidote Carry patient to fresh air. Have him lie down. Remove contaminated clothing but keep patient warm. Start treatment immediately. Call a physician. If Cyanide Gas is Inhaled: Break an amyl nitrite pearl in a cloth and hold lightly under nose for 15 seconds. Repeat 5 times at about 15-second intervals. Use artificial respiration if breathing has stopped. If Cyanide is Swallowed: Break an amyl nitrite pearl in a doth and hold lightly under nose for 15 seconds. If patient is conscious or when consciousness returns give emetic (1 tablespoonful of salt to each glass of warm water) and repeat until vomit fluid is clear. Repeat inhalation of amyl nitrite 5 times at about 15-second inter vals. Use artificial respiration if breathing has slopped. Never give anything by mouth to an unconscious person. MCA ChMicat Safety Data Shoot available far SODIUM CYANIDE CYCLOHEXANE DANGER! EXTREMELY FLAMMABLE Keep away from heat, sparks, and open flame. Keep container closed. Use with adequate ventilation. Avoid prolonged breathing of vapor. 35 CYCLOHEXANOL CAUTION! VAPOR HARMFUL Use only with adequate ventilation. Avoid prolonged breathing of vapor. Avoid prolonged or repeated contact with skin. CYCLOHEXANONE-Same label as CYCLOHEXANOL DIACETONE ALCOHOLSam label as ETHYL ACETATE DICHLOROETHYLENE WARNING) FLAMMABLE Keep away from heat and open flame. Keep container closed. Use with adequate ventilation. Avoid pr longed or repeated breathing of vapor. Avoid prolonged or repeated contact with skin. D not take internally. DICHLOROETHYL ETHER WARNING! VAPOR HARMFUL Use nly with adequate ventilation. Avoid pr longed or repealed breathing of vapor. Avoid prolonged or repeated contact with skin. Do n I take internally. 2,4-DICHLOROPHENOL WARNINGI MAY CAUSE BURNS D not get in eyes, on skin, on clothing. Do n t breathe vapor. Do not lake internally. o In case f contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Remove and wash clothing before re-use. DIETHYLAMINE DANGER! EXTREMELY FLAMMABLE MAY CAUSE SKIN IRRITATION Keep away from heat, sparks, and open flame. Keep container closed. Use with adequate ventilation. Avoid exposure to vapor. Avoid contact with skin and eyes. In case of contact, flush skin or eyes with plenty of water for ot least 15 minutes; for eyes, get medical attention. DIETHYLENETRIAMINE--Same label as MORPHOLINE DHSOBUTYL KETONESame label as iso-AMYL ACETATE DIMETHYLANILINE--Same label as ANIUNE DIMETHYL SULFATE DANGER! EXTREMELY HAZARDOUS LIQUID AND VAPOR CAUSES SEVERE BURNS Do not get in eyes, on skin, on clothing. Do not breathe vapor. Use only with adequate ventilation. Wear goggles and rubber gloves when handling. In case of spillage, cover immediately with dry soda ash. ft POISON ft First Aid Treatment--Antidote Call physician immediately Eyes: Immediately flush with water for at least 15 minutes. Skin: Immediately remove all contaminated clothing and flush skin with woter for at least 15 minutes. Inhalation: If breathing becomes difficult, start oxygen inhalation through suitable equipment. MCA Chimical Sofcty Data Shatl available 37 DIOXANE (1,4-DIETHYLENE DIOXIDE) WARNING! FLAMMABLE VAPOR HARMFUL TENDS TO FORM EXPLOSIVE PEROXIDES ESPECIALLY WHEN ANHYDROUS Keep away from heat and open flame. Keep container closed. Use only with adequate ventilation. Avoid prolonged breathing of vapor. Avoid prolonged or repeated contact with skin. Do not allow to evaporate to near dryness. Addition of water or appropriate reducing agents will lessen peroxide formation. DIPROPYL KETONE-Same label as iso-AMYL ACETATE ETHYL ACETATE WARNING! FLAMMABLE Keep away from heal and open flame. Keep container closed. Use with adequate ventilation. Avoid prolonged breathing of vapor. Av id prolonged or repeated contact with skin. ETHYL BROMIDE WARNING I VAPOR HARMFUL Use nly with adequate ventilation. Avoid prolonged breathing of vapor. Keep container dosed, out of sun, and away from heat. ETHYL CHLORIDE o DANGER) EXTREMELY FLAMMABLE Keep away from heat, sparks, and open flame. <# Use with adequate ventilation. 8 Keep container closed, out of sun, and away from heal. C3 M 3B ETHYLENE CHLOROHYDRIN (ANHYDROUS or 38 /o) DANGER I EXTREMELY HAZARDOUS LIQUID AND VAPOR MAY BE FATAL IF INHALED, SWALLOWED OR ABSORBED THROUGH SKIN Do not get in eyes, on skin, on clothing. (Ordinary rubber gloves will not prevent skin absorption.) Do not breathe vapor. Do not take internally. In case of contact, immediately remove all contaminated clothing and flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Wash clothing before re-use. ^ POISON ^ First Aid Treatment--Antidote ' ' - If swallowed; Make patient vomit immediately by putting finger down throat or by giving warm mustard water or salt water freely. General: Keep patient warm; if conscious, give black coffee. Call physician. Do not give Adrenalin. ETHYLENED1AMINE--Same label as MORPHOLINE ETHYLENE DIBROMIDE WARNING) VAPOR HARMFUL ABSORBED THROUGH SKIN Avoid breathing vapor. Avoid contact with skin, eyes, and clothing. In case of contact, immediately remove ail contaminated clothing, including shoes, and flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Wash clothing and air shoes thoroughly before re-use. 39 ETHYLENE DICHLORIDE WARNING! FLAMMABLE VAPOR HARMFUL Keep away from heat and open flame. Keep container closed. Use only with adequate ventilation. Av id prolonged or repealed breathing of vapor. Av id prolonged or repeated contact with skin. D not take internally. MCA Chemical Sarfety Data Shoot available ETHYLENE GLYCOL MONOMETHYL ETHER Sam label as CYCLOHEXANOL ETHYL ETHER DANGER! EXTREMELY FLAMMABLE HIGHLY VOLATILE TENDS TO FORM EXPLOSIVE PEROXIDES ESPECIALLY WHEN ANHYDROUS Keep away from heat, sparks, and open flame. Keep container tightly closed. D not allow to evaporate to near dryness. Addition of water or ppropriate reducing agents will lessen peroxide formation. ETHYL FORMATE DANGERI EXTREMELY FLAMMABLE Keep away from heat, sparks, and open flame. o Keep container closed. Use with adequate ventilation. Avoid prolonged breathing of vapor. 2-ETHYLHEXANOL--Same label as iso-AMYL ACETATE 2-ETHYLHEXYL ACETATESame label as iso-AMYL ACETATE ETHYL METHACRYLATE MONOMER WARNING! FLAMMABLE Keep away from heat and open flame. Keep container closed. Use with adequate ventilation. Avoid prolonged breathing of vapor. Avoid contact with skin, eyes, and clothing. FORMALDEHYDE SOLUTION WARNING) CAUSES IRRITATION OF SKIN, EYES, NOSE AM) THROAT Avoid prolonged or repeated contact. Avoid prolonged breathing of vapor. Use with adequate ventilation. ^ POISON ^ First Aid Treatment--Antidote Call a physician at once If swallowed; Give milk freely, or 1 glassful of water containing 1 tabiespoonful of ammonium acetate. Produc vomiting with a pint or more of warm salt water (I cupful per quart) or warm soapy water. Repeal 3 times. Follow with milk and raw eggs. MCA Chemical Safely Data Sheet available 41 FORMIC ACID-Same label as HYDROCHLORIC ACID GLYCOL DJACETATESame label as iso-AMYL ACETATE GLYCOL DIFORMATE-- Same label as iso-AMYL ACETATE HEPTANOL-2--Same label as iso-AMYL ACETATE HEXANOL-Same label as iso-AMYL ACETATE HYDROCHLORIC ACID WARNING! CAUSES BURNS Avoid contact with skin and eyes. Av id breathing vapor. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. HYDROCYANIC ACID DANGER! POISON GAS Do not breathe gas. Avoid contact with skin. D not drop container. Keep cool and away from open flame. 0 POISON 1 First Aid Treatment--Antidote o (Uii soma first aid liMtinint os recommended for CYANIDES, INORGANIC} CO HYDROFLUORIC ACID, ANHYDROUS DANGERI EXTREMELY HAZARDOUS LIQUID AND VAPOR CAUSES SEVERE BURNS WHICH MAY NOT BE IMMEDIATELY PAINFUL OR VISIBLE Do not get in eyes, on skin, on clothing. Do not breathe vapor. Store out of sun and away from direct heat. UNLOAD ONLY IN ACCORDANCE WITH PRACTICE RECOMMEND ED IN MANUFACTURING CHEMISTS' ASSOCIATION MANUAL H-iO. Read also MCA Chemical Safety Data Sheet SD-25. Copies furnished on request. First Aid in Case of Contact or Suspicion of Contact. Always have on hand a supply of magnesia paste (magnesium oxide and glycerin). Immediately flush skin (until whiteness disappears) and eyes (for at least 15 minutes) with plenty of water, paying particular attention to skin under nails. Apply magnesia paste. Get med ical attention. Remove and wash clothing before re-use. MCA Chamkal Safer Dali Shoal arnilobla HYDROFLUORIC ACID, AQUEOUS DANGER) HAZARDOUS LIQUID AND VAPOR CAUSES SEVERE BURNS WHICH MAY NOT BE IMMEDIATELY PAINFUL OR VISIBLE Balance of warning labal lama ai for HYDROFLUORIC ACID, ANHYDROUS. MCA Chemical Safety Data Sheet available CMA 035935 HYDROGEN PEROXIDE (stronger than 7.4% and not exceeding 50%) CAUTtONI STRONG OXIDANT Avoid contact with skin and eyes--wear rubber gloves and gog gles. Avoid contact with combustible materials. Drying of this concen trated product on clothing or other combustible materials may cause fire. in case f contact, immediately flush with plenty of water for at least 1S minutes; for eyes, get medical attention. Avoid contamination from any source, including metals, dust, etc. Such contamination may cause rapid decomposition, generation of large quantities of oxygen gas, and high pressures. * Store in original closed container. *Be sure that the container vent is working satisfactorily. *Do not add any other product to this container. `When empty, rinse thoroughly with clean water. HYDROGEN PEROXIDE (7.4% or 25 volume) CAUTION! STRONG OXJDANT Av id c nlact with skin and eyes--wear rubber gloves and gog gles. Av id contamination from any source, including metals, dust, etc. Such contamination may cause rapid decomposition, generation f large quantities of oxygen gas, and high pressures. *Stor in original closed container. *Be sure that the container vent is working satisfactorily. *Do not add any other product to this container. `When empty, rinse thoroughly with clean water. 'Addition lo ''Container Handling and Slorogi," p. 19. HYDROGEN SULFIDE DANGER) POISON LIQUID AND GAS UNDER PRESSURE FLAMMABLE BEFORE USING, READ M.C.A. CHEMICAL SAFETY DATA SHEET SD-36 Do not breathe gas. Keep away from heat and open flame--may form explosive mix ture with air. NOTE: This gas deadens the sense of smell. Do not depend on odor lo detect presence of gas. POISON First Aid Treatment--Antidote Carry patient to fresh air. If patient has slopped breathing, apply artificial respiration im mediately. Keep patient warm. Call physician. MCA Chamical Safety Data Sheet available LEAD ACETATE WARNING! HARMFUL DUST Avoid breathing dust. Wear dust mask approved by U. S. Bureau of Mines for this purpose. Wash thoroughly before eating or smoking. Keep away from feed or food products. LEAD MONOXIDE (LITHARGE)-- Same label as LEAD ACETATE MALEIC ANHYDRIDE WARNING! CAUSES BURNS Avoid contact with skin, eyes, and clothing. Avoid exposure to concentrated vapor. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. 45 MERCURIC CHLORIDE (MERCURY BICHLORIDE) DANGER! MAY BE FATAL IF SWALLOWED Do not breathe dust. Keep away from feed or food products. Wash thoroughly before eating or smoking. Use fresh clothing daily. Take hot shower after work using plenty of soap. POISON MESITYL OXIDE-Same label as iso-AMYL ACETATE METHANOL DANGER! FLAMMABLE VAPOR HARMFUL MAY BE FATAL IF SWALLOWED CANNOT BE MADE NON-POISONOUS POISON ^ First Aid Treatment--Antidote If wallowed: Give a tabiespoonful of salt in a glass of warm water and repeat until vomit fluid is clear. Give two teaspoon fuls f baking soda in a glass of water. Have patient lie down and keep warm. Cover eyes to exclude light. Call a physician. If splashed in the eyes: Immediately flush with water for at least 15 minutes. Get medical attention. For product* containing mathanof in proportion luAkitnl to create hazard btcauw of metfionol content, ubo tam statements as abort, with addition of; CONTAINS OVER........ % OF METHANOL O 2 The word "flammable'"' may be omitted from the label if the product hos o flash > point obove 80 F. MCA Chemical Safety Data Sheet available METHYL AMYL ACETATESame label as iso-AMYL ACETATE METHYL AMYL ALCOHOLSame label as iso-AMYL ACETATE METHYL n-AMYL KETONESame label as iso-AMYL ACETATE METHYL BROMIDE DANGER) VAPOR EXTREMELY HAZARDOUS HIGHLY VOLATILE CAUSES BURNS Do not breathe vapor. Do not get in eyes, on skin, on clothing. Keep away from heat. Keep container closed. ^ POISON First Aid Treatment--Antidote Remove to fresh air. Use artificial respiration if breathing has stopped. Get immediate medical attention. Keep patient absolutely quiet and start oxygen inhalation through suitable equipment. On Can Latl Add; IMPORTANT! The contents of this can are under pressure. Do not use ordinary can opener. Special handling equipment is avail able. Contact ........................................... for information on equipment (NAME OF MANUFACTURER) and proper use. MCA Cbemieal Safety Data Shssl available 47 ' ! | [ 1 METHYL iso-BUTYL KETONESame label as METHYL ETHYL KETONE METHYL CYCLOHEXANOLSame label as CYCLOHEXANOL METHYL CYCLOHEXANONESam label as CYCLOHEXANOL METHYLENE CHLORIDE CAUTION I Use with adequate ventilation. Avoid prolonged or repeated breathing of vapor. Avoid prolonged or repeated contact with skin. Do not take internally. METHYL ETHYL KETONE WARNING) FLAMMABLE Keep away from heal and open flame. Keep container closed. Use with adequate ventilation. Avoid prolonged breathing of vapor. Av id prolonged or repealed contact with skin. METHYL METHACRYLATE MONOMER WARNING) FLAMMABLE MAY CAUSE SKIN IRRITATION Keep away from heat and open flame. Keep container closed. o Use with adequate ventilation. >3 Avoid prolonged breathing of vapor. o Avoid contact with skin, eyes, and clothing. METHYL MORPHOLINE--Same label as MORPHOLINE METHYL iso-PROPYL KETONESame label as iso-AMYL ACETATE MIXED ACID (Sulfuric and Nitric) DANGER! CAUSES SEVERE BURNS VAPOR EXTREMELY HAZARDOUS MAY CAUSE NITROUS GAS POISONING Do not breathe vapor. ' ' Do not gel in eyes, on skin, on clothing. In cose of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Spillage may cause fire or liberate dangerous gas. MONOCHLOROPHENOL-Same label as PHENOL MORPHOLINE WARNING I HAZARDOUS LIQUID AND VAPOR MAY CAUSE SKIN IRRITATION Use with adequate ventilation. Avoid exposure to vapor. Avoid contact with skin and eyes. x alpha-NAPHTHYLAMINE (containing 5% betaNAPHTHYLAM1NE)-- Same-label as beta-NAPHTHYLAMINE 49 b ta-NAPHTHYLAMINE WARNING! HARMFUL DUST AND VAPOR REPEATED ABSORPTION MAY RESULT IN BLADDER TUMORS Avoid breathing dust or vapor. Avoid contact with skin. Do not take internally. MCA Onnwcal Softly Data Shoot available NITRIC ACID DANGERI CAUSES SEVERE BURNS VAPOR EXTREMELY HAZARDOUS MAY CAUSE NITROUS GAS POISONING Do not breathe vapor. Do not get in eyes, on skin, on clothing. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; get medical attention. Spillage may cause fire or liberate dangerous gas. MCA Chemical Safety Data Sfeal availaU* NITROANILINE (meta or para) WARNING) ABSORBED THROUGH SKIN Avoid contact with skin, eyes, and clothing. Av id breathing dust. In case of contact, immediately flush skin or eyes with plenty f water for at least 15 minutes; for eyes, get medical attention. Wash clothing before re-use. m ta-NITRO-para-ANISJDINE-- Sam label as NITROANILINE (meta or para) O NITROBENZENE-Same label as ANILINE NITROGEN DIOXIDE DANGER! EXTREMELY HAZARDOUS LIQUID AND GAS INHALATION MAY CAUSE DELAYED FATAL LUNG INJURY READ MANUFACTURER'S MANUAL FOR DETAILED HANDLING INSTRUCTIONS Do not breathe gas. Avoid contact with skin, eyes, and clothing. Do not allow to mix with combustible materials. In case of inhalation or suspicion of inhalation, ram v at once to fresh air and cat) a physician. Keep patient abs lutely quiet and start oxygen inhalation through suitable equipment. NITROPHENOL (MONONITROPHENOL) WARNING! MAY BE ABSORBED THROUGH SKIN Avoid breathing dust. Avoid contact with skin and eyes. In case of contact, immediately wash skin with soap and plenty of water; flush eyes with plenty of water for at least 15 minutes and get medical attention. para-NITRO-ortho-TOLUIDINE-- Same label as NITROANILINE (meta or para) OLEUM (FUMING SULFURIC ACID) DANGERI CAUSES SEVERE BURNS Do not get in eyes, on skin, on clothing. Avoid breathing vapor. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Do not add water to contents while in a container because of vAiolent reaction. OXALIC ACID WARNING! HARMFUL IF SWALLOWED CAUSES SKIN IRRITATION Avoid breathing dust. Avoid contact with skin and eyes. Do n t toke internally. Keep away from feed or food products. In case of contact, immediately flush skin or eyes with plenty of water for at least IS minutes; for eyes, get medical attention. PARAFORMALDEHYDE WARNING! CAUSES IRRITATION OF SKIN, EYES, NOSE AND THROAT Av id prolonged or repealed contact. Avoid breathing dust or prolonged breathing of vapor. Use with adequate ventilation. ^ POISON First Aid Treatment--Antidote Cali a physician at once. If swallowed: Give milk freely, or I glassful of water contain ing I lablespoonful of ammonium acetate. Produce vomiting with a pint or more of warm salt water (1 cupful per quart) or warm soapy water. Repeat 3 times. Follow with milk and raw eggs. PARALDEHYDE CAUTIONI VAPOR HARMFUL Use nly with adequate ventilation. Avoid prolonged or repeated breathing of vapor. a Do n t take internally. Solidifies at ab ut 54F. (I2C.) and may break container. Store in a moderately warm place. PERCHLORETHYLENE-See TETRACHLOROETHYLENE PERCHLORIC ACID SOLUTION DANGER) STRONG OXIDANT CORROSIVE LIQUID CONTACT WITH COMBUSTIBLE MATERIAL MAY CAUSE FIRE CHt EXPLOSION, ESPECIALLY IF HEATED Keep container closed and away from combustible material, dehydrating agents and heal. In case of spillage, flush with plenty of water and remove con taminated articles. In case of contact, immediately remove all contaminated clothing and flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Wash clothing before re-use. MCA Chemical Safety Data Sheet available PETROLEUM NAPHTHAS AND SOLVENTS, INDUSTRIAL (For solvents having a flash point 20F. or BELOW, Tagliabue Open Cup Method as specified by Inter state Commerce Commission) (NAME OF PRODUCT) DANGER) EXTREMELY FLAMMABLE Keep away from heat, sparks, and open flame. Keep container closed. Use with adequate ventilation. Avoid prolonged breathing of vapor. Avoid prolonged or repeated contact with skin. PETROLEUM NAPHTHAS AND SOLVENTS, INDUSTRIAL (For solvents having a flash point ABOVE 20"F. but not above 80"F., Tagliabue Open Cup Method as specified by Interstate Commerce Commission) (NAME Of PRODUCT) WARNING! FLAMMABLE Keep away from heat and open flame. Keep container closed. Use with adequate ventilation. Avoid prolonged breathing of vapor. Avoid prolonged or repeated contact with skin. PETROLEUM NAPHTHAS AND SOLVENTS, INDUSTRIAL (For solvents having a flash point ABOVE 80F., Tagliabue Open Cup Method as specified by Inter state Commerce Commission) (NAME Or PRODUCT) CAUTION! Use with adequate ventilation. Avoid prolonged breathing of vapor. Av id prolonged or repealed contact with skin. PHENETIDINE (ortho or para)-- Same label as ortho-ANISIDINE O > o w 54 PHENOL DANGER! RAPIDLY ABSORBED THROUGH SKIN CAUSES SEVERE BURNS Do not gel in eyes, on skin, on clothing. Avoid breathing vapor. Do not take internally. In case of contact, immediately remove all contaminated clothing, including shoes, and flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Wash clothing before re-use. POISON ^ MCA Chwnkol Safety Dola Shall available para-PHENYLENEDIAMINE CAUTION) MAY CAUSE SKIN IRRITATION Avoid contact with skin and eyes. Avoid breathing dust. PHOSPHORIC ACID CAUTION) CAUSES SKIN IRRITATION Avoid contact with skin and eyes. In case of contact, flush skin or eyes with plenty of water for at least 15 minutes,- for eyes, get medical attention. PHOSPHORIC ANHYDRIDE WARNINGI CAUSES BURNS Avoid contact with skin and eyes. Wear rubber gloves and goggles. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Open carefully. Do not add water to contents while in a container because of violent reaction. MCA Chamkal Safety Data Skt available 55 PHOSPHORUS (For Wet Shipments) DANGERI CAUSES SEVERE BURNS Contents packed under water and will ignite if water is removed. Do not get on skin or in eyes. Wear heavy rubber gloves and goggles or face shield. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; keep skin area wet until medical attention is obtained. Keep drum out of sun and away from heat. ^ POISON MCA Chanical Safety Data Sh*t availabl* PHOSPHORUS PENTACHLORIDE WARNING) HAZARDOUS DUST CAUSES BURNS Do not breathe dust. Do not gel on skin or in eyes. Wear rubber gloves and goggles. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, gel medical attention. Do not add water to contents while in a container because of violent reaction. `Open carefully. PHOSPHORUS OXYCHLORIDE DANGERI CAUSES SEVERE BURNS VAPOR EXTREMELY IRRITATING D not breathe vapor. Do not get in eyes, on skin, on clothing. In case of contact, immediately remove all contaminated clothing and flush skin or eyes with plenty of water for at least 15 min utes; for eyes, get medical attention. Wash clothing before re-use. In case f spillage, flood carefully with LARGE VOLUME of water and provide adequate ventilation. D not add water to contents while in a container because of vio lent reaction. `Do not open unless you have been properly instructed. *Do not use this container for any other product. MCA Climcl Safety Data Sht avaMabfe 'Addition to 'Xwilainir Handling and Storage," p. IB. PHOSPHORUS TRICHLORIDE DANGER) CAUSES SEVERE BURNS VAPOR EXTREMELY IRRITATING CONTACT WITH WATER MAY CAUSE FLASH FIRE Do not get in eyes, on skin, on clothing. Do not breathe vapor. In case of contact, immediately remove all contaminated clothing and flush skin or eyes with plenty of water for at least 15 min utes; for eyes, get medical attention. Wash clothing before re-use. In case of spillage, flood carefully with LARGE VOLUME of water and provide adequate ventilation. Do not odd water to contents while in a container because of violent reaction and possible flash fire. `Do not open unless you have been properly instructed. `Do not clean or re-use this container. MCA Cbwnical Saf*ty Dale Shoot availabl* * Addition t'Co1ain*, Handline and Slofogo," p. IS. 57 CMA 0 POTASSIUM CHLORATESame label as SODIUM CHLORATE POTASSIUM HYDROXIDE-- Same label as SODIUM HYDROXIDE iso-PROPYL ACETATE WARNINGI FLAMMABLE Keep away from heat and open flame. Keep container closed. Use with adequate ventilation. Avoid prolonged breathing of vapor. Avoid prolonged or repeated contact with skin. PROPYLENE CHLOROHYDRIN-- Same label as ETHYLENE CHLOROHYDRIN iso-PROPYL ETHER-Same label as ETHYL ETHER PYRIDINE WARNING! FLAMMABLE Keep away from heat and open flame. Keep c ntainer closed. Use with adequate ventilation. Av id prolonged breathing of vapor. SILVER NITRATE WARNING! CAUSES BURNS D not get on skin or in eyes. O In case of contact with eyes, get medical attention. ft POISON *ft SODIUM CHLORATE WARNINGI CONTACT WITH COMBUSTIBLE MATERIAL MAY CAUSE FIRE All clothing contaminated with chlorates is DANGEROUSLY FLAM MABLE. Remove and wash thoroughly with water. Do not get on floor. Spillage may cause fires with combustible material. Sweep up and remove immediately. When not in use keep tightly closed in original metal container. Keep away from fire. Store separately from flammable material. SODIUM CYANIDE-See CYANIDES, INORGANIC MCA Chemical Safety Data Sh*t available SODIUM DICHROMATE WARNING! HARMFUL DUST MAY CAUSE RASH OR EXTERNAL ULCERS Keep container closed. Avoid contact with skin and eyes. Avoid breathing dust or solution spray. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Wash clothing before re-use. Use fresh clothing daily. Take hot shower after work using plenty of soap. SODIUM FLUORIDE WARNINGI MAY BE FATAL IF INHALED OR SWALLOWED Avoid breathing dust. Wash thoroughly after handling. Clean up spillage. 59 CMA SODIUM FLUOSILICATE-- Same label as SODIUM FLUORIDE SODIUM HYDROSULFITE CAUTION) SUBJECT TO FIRE IF ALLOWED TO BECOME DAMP Keep container tightly closed. Use only dry, clean utensils in handling. St re in a cool, dry place. SODIUM HYDROXIDE (CAUSTIC SODA) WARNING) CAUSES SEVERE BURNS TO SKIN AND EYES Avoid contact with skin, eyes, and clothing. Do not take internally. When handling, wear goggles or face shield. While making solu tions, add Sodium Hydroxide slowly to surface of solution to avoid violent spattering. In case of contact, immediately flush skin with plenty of water and wash with vinegar; for eyes, flush with plenty of water for at least 15 minutes and get medical attention. MCA Chmicat Solely Data Sfcnl avoHabl* SODIUM ORTHOSILICATE-- Same label as SODIUM HYDROXIDE SODIUM SESQUISILICATE-- Sam label as SODIUM HYDROXIDE SODIUM SULFHYDRATE-- Same lab I as SODIUM SULFIDE 60 SODIUM SULFIDE (Containing 35% or more combined water) DANGER) CONTACT WITH ACID LIBERATES POISONOUS GAS BURNS SKIN AND EYES Avoid breathing dust. Avoid contact with skin and eyes. Keep container closed and away from acids, combustible ma terial, and heat. Sweep up spillage. Do not flush to sewer which may contain acid. STYRENE MONOMER-Same label as CYCLOHEXANOL SULFUR CHLORIDE WARNINGI CAUSES BURNS VAPOR IRRITATING Avoid contact with eyes, skin, and clothing. In case of'contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Do not allow water to get into container. SULFUR DICHLORIDE-- Same label as SULFUR CHLORIDE SULFUR DIOXIDE WARNING! EXTREMELY IRRITATING GAS AND LIQUID UNDER PRESSURE Avoid breathing gas. Do not drop cylinder. Do not allow cylinder temperature to reach 130"F. 61 i 4 SULFURIC ACID DANGER! CAUSES SEVERE BURNS Do not get in eyes, on skin, on clothing. In cose of contact, immediately flush skin or eyes with plenty of water for at least IS minutes; for eyes, get medical attention. Do not add water to contents white in a container because of violent reaction. SULFURYL CHLORIDE-- Same label as SULFUR CHLORIDE TAR ACIDS-Same label as CRESOL TETRACHLOROETHANE DANGER! VAPOR EXTREMELY HAZARDOUS Use only in completely enclosed system. Do not breathe vapor. Do not gel in eyes, on skin on clothing. Do not take internally. POISON TETRACHLOROETHYLENE (PERCHLOROETHYLENE) WARNING! VAPOR HARMFUL Use only with adequate ventilation. Avoid prolonged or repeated breathing of vapor. i Avoid prolonged or repealed contact with skin. Do not lake internally. o MCA Chemical Safsty Data $h*t available TETRACHLOROPHENOLSame label as PENTACHLOROPHENOL TETRAETHYLENEPENTAMINE-- Same label as MORPHOLINE THIONYL CHLORIDE-- Same label as SULFUR CHLORIDE TOLUENE (TOLUOL) WARNING! FLAMMABLE Keep away from heat and open flame. Keep container closed. Use with adequate ventilation. Avoid prolonged breathing of vapor. Avoid prolonged or repeated contact with skin. TOLUIDINE (ortho or meta) WARNING! HAZARDOUS LIQUID AND VAPOR RAPIDLY ABSORBED THROUGH SKIN Avoid contact with skin, eyes, and clothing. Avoid breathing vapor. ifse only with adequate ventilation. In case of contact, immediately remove all contaminated clothing and flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Wash clothing before re-use. 63 para-TOLUIDINE WARNINGI HAZARDOUS SOLID AND VAPOR RAPIDLY ABSORBED THROUGH SKIN Avoid contact with skin, eyes, and clothing. D n t breath vapor. Use only with adequate ventilation. In case of contact, immediately remove all contaminated clothing and flush skin or eyes with plenty of water for at least IS min utes; for eyes, gel medical attention. Wash clothing before re-use. TRICHLOROETHYLENE WARNING! VAPOR HARMFUL Use only with adequate ventilation. Avoid prolonged or repealed breothing of vapor. Avoid prolonged or repeated contact with skin. Do n t take internally. MCA Ckmital Sfty Data Shoot available TRICHLOROPHENOL (all isomers) CAUTION! MAY CAUSE SKIN IRRITATION Avoid prolonged or repeated contact with skin. TRIETHYLENETETRAMINE-- Same label as MORPHOLINE TRIMETHYLCYCLOHEXANOLSame label as iso-AMYL ACETATE VINYL CHLORIDE DANGERI EXTREMELY FLAMMABLE Keep away from heat, sparks, and open flame. Keep container closed. Use with adequate ventilation. Avoid prolonged breathing of vapor. XYLENE (XYLOL)--Same label as TOLUENE XYLIDINES--Same label as meta-TOLUIDINE ZINC CHLORIDE (Granular, Fused, or Solution)-- CAUTION) MAY CAUSE SKIN IRRITATION Avoid prolonged or repeated contact with skin. I i PART III Illustrative Warning Labels (or Economic Poisons This section conuiiiis suggested warning lalteis for a group of hazardous chemicals commonly used as or in the formulation of insecticides, fungicides, rodenticides, and herbicides. Wording is based un the piinciples set forth in Part I. Careful study should be given to Part 1 and the special considerations discussed below before any suggested wording is used for an economic poison product. These labels have been selected for illustrative purposes only, and omission of a label for any particular product should not be inter preted to mean that such product requires no label warning. The principles in Part 1 apply primarily to the labeling of haz ardous chemicals intended for industrial consumption, some ol which are also used as, or for processing into forms of economic poisons intended fur home, farm, or other ultimate consumer use. Labels for such packages of economic ]>oisons require consideration of additional factors since they will be handled, stored, and used differently from those intended for industrial consumption. Also, economic poison labels should include warnings not only of hazards to man, but to domestic animals, useful invertebrates, and useful vegetation. A producer or distributor of an economic poison should be fa miliar with all pertinent laws governing economic poisons, including those of the federal government, states, territot ies, and other political subdivisions; and with any applicable statutes, ordinances, or reg ulations affecting labeling in general. Statements suggested in Part III should be used in addition to or in combination with any other wording required by law. Many economic poisons are marketed in a large variety of formu lations in which the ingredients may be obtained in various con centrations or combinations. Suggested wording in this section ap plies to the commercial chemical or, where indicated, to a definite concentration range of the chemical. Products formulated from two or more constituents may have properties that vary in kind or degree from those of the constituents; any warning statement should be based on the properties of the finished formulation. It has not been practical to propose statements for all special pack ages, extraordinary uses or other unusual circumstances surrounding individual products. Each statement is designed for the normal and customary use of a particular product when packaged for sale as an economic poison. Each labeler of an economic poison should recog- 67 CMA 035846 ntze that his puxliut mint be treated individually, in the light of tit own characteiistics, ini hiding, among otheis, mm entiution and giude, package sizes and types, channels of distribution, normal storage and transportation conditions, intended consumers, and in tended uses. l he label statements in Part ill ate confuted mainly to measures necessary to prevent injury to man and domestic animals arising out ol the ordinary handling, storage or use ol a product. Additional warnings may be indicated by the particular form or manner in which a product is sold or the circumstances surrounding its use. There also may he other hazards to man or animals which can atise only from specific uses (or which directions are given in the labeling. Frequently an economic poison may also he hazardous to useful in vertebrates or useful vegetation, or by reason of residues on edible vegetation. The omission of reference to any of these hazards from any statement in Part HI does not imply that they may be disregarded. As a rule such warnings are properly incorporated in directions for use. Even though they may be separated from the principal warnings they should, nevertheless, be prominently displayed. Examples: Do not apply within........ days of harvest Avoid use during flowering and pollination periods Do not consume fruits or vegetables until residue is removed Do not use this powder on drainboards, shelves or other places where contact with food is likely Do not allow spray to come in contact with garden plants The Federal Insecticide, Fungicide and Kodenticide Act and some stale Acts require the word "POISON" and the skull and crosshoncs on all products deemed "highly toxic to man." The definition of "Poison" in Part 1 of this Manual is essentially the same as the defi nition of "highly toxic to man" in the regulations under the federal act. The products in this section have been classified according to the "highly toxic to man" definition. 1'he term "Poison" has been commonly understood by the layman to mean toxic by oral intake only. The controlling definition consid ers oral intake, inhalation, and skin absorption. To clarify the use of the term, labels on packages of economic poisons "highly toxic to man" should specify the modes of entry into the body by which the product is poisonous. Examples: POISONOUS IF SWALLOWED POISONOUS BY SKIN CONTACT MAY BE POISONOUS IF INHALED POISONOUS IF SWALLOWED OR BY ABSORPTION THROUGH SKIN 68 It is not intended that the word "POISON" should Lake the place of a signal word. Any one ol the signal words "DANGER," "WARN ING" or "CAUT ION" may be applicable even when a product is poisonous. T he selection ol the appropiiate word will depend not only on the degree ol toxicity ol the product, but mote particularly on the risk of injury presented undei normal tondihons of handling or use. The word "POISON" (or its derivatives) should he teserved exclu sively for those products coming within the definitions of the lederal act as "highly toxic to man" except where it may he required by oilier laws or regulations. For products that are less toxic, statements like the following are preferred: MAY BE FATAL IF SWALLOWED HARMFUL IF INHALED OR SWALLOWED First aid treatment is given lor a few ptoducts only. T he Fedetal Insecticide, Fungicide and Rodentitide Act and some state Ads*'re quire a statement of an antidote for the economic poison on all prodm Is deemed "highly toxic to man."* Such informal ion may he desir able on other products. Where "clothing" is mentioned in fust aid instructions, it should he understood to mean all articles of clothing, including shoes, garters, and other accessories. Shoes arc specifically named in some instructions, because of special hazards aiising Irom absorption of the chemical by leather. An important principle of good labeling is to avoid the promis cuous use of precautionary statements since they tend to detract from the prominence and importance which should be given tu the vital warnings. Common sense indicates certain fundamental precautions in the handling ol nearly all household and farm supplies and a label statement cannot substitute lor it. Phrases such as "Keep away Irom children and domestic animals" atid*"Avoid contamination ol food" should he necessary only where the inherently high toxicity of the product, special use of the material, size of the package, likelihood ol mistaken identity, or actual use experience strongly indicate their need. "Ollier slates while not following the federal art on the definition of "highly toxic to mail" require the wind " i'OI SON" and the skull and u out tones and antidote oil all economic ijoisuiis which fad within the term a`|>oison" as defined in their jxtlson laws. 69 A CMA 035948 ACRYLONITRILE DANGER! POISONOUS IF INHALED FLAMMABLE Do not breathe vapor. Do not get in eyes, on skin, on clothing. Keep away from heat and open flame. Keep container closed. POISON (Antidote) Note: Directions for Uio should indude appropriate gas mask protection. ANTU-See alpha-NAPHTHYLTHIOUREA ARSENICALS, LIQUID 1. Containing 2% or more as metallic arsenic: WARNING! POISONOUS IF SWALLOWED Avoid contact with skin, eyes, and clothing. Do n l breathe spray mist; wear respirotor. In case of contact, wash thoroughly. POISON (Antidote) Note; Label should boar rtfsnnct to Iks avoidance of spray drift to valuable plants and restriction of animals from treated areas. 2. Containing less than 2% as metallic arsenic: WARNING! MAY BE FATAL IF SWALLOWED Av id contact with skin, eyes, and clothing. Avoid breathing spray mist. Keep away from food and out of the reach of children and domes tic animals. In case of contact, wash thoroughly. 70 BARIUM FLUOSILICATE CAUTION) MAY BE FATAL IF SWALLOWED Avoid breathing dust or spray mist. Wash thoroughly after handling. Note; Directions for Use should boar a slolement relative lo spray residues. BENZENE HEXACHLORIDE 1. For benzene hexachloride and dry formulations containing 25% or moro of benzene hexachloride: WARNING! HARMFUL VAPOR AND DUST MAY CAUSE IRRITATION OF SKIN AND EYES MAY BE ABSORBED THROUGH THE SKIN Avoid inhaling dust, vapor, or spray mist. Avoid contact with skin and eyes. Avoid contamination of foodstuffs. In case of contact, wash skin with plenty of soap and water; for eyes, flush with water and get medical attention. 2. For dry formulations containing less than 25% benzene hexa chloride: CAUTION! Avoid inhaling dust, vapor, or spray mist. Avoid contact with skin. Avoid contamination of foodstuffs. 3. For solutions or emulsions of benzene hexachlorid : Sines various solvents which differ In toxic properties may be used, labels should bear the precautionary information covering the combined hazards of benzene hexa chloride and solvent. Note: If the product is to be applied to plants that are used as food, a warning should Be Indtided In the Directions for Use to the effect that the material should not be applied where there is danger of a toxic residue, or residual odor or taste, remaining on foodstuffs or edible portions of treoted crops. CADMIUM SALTS Toxicity varies with the different products, hence, each product must be considered an its awn properties. 71 i CALCIUM ARSENATE-Same label as LEAD ARSENATE CALCIUM CYANIDE DANGER! UBERATES POISONOUS GAS Avoid breathing gas or dust. Avoid contact with skin. Keep away from acids. Keep container tightly closed and dry. POISON (Antidote) Note: Dificlioni for Indoor Uw should Indudi appropriate gat modi protection. CARBON DISULFIDE DANGER! EXTREMELY FLAMMABLE VAPOR HARMFUL HIGHLY VOLATILE Keep away from fire, sparks, or healed surfaces. Store in cool place and keep container closed. Avoid breathing vapor. Av id contact with skin and eyes. ^ POISON (Antidote) Note: Directions for ll should provide for adequate ventilation during the lime when product it being handled. CARBON TETRACHLORIDE WARNING! VAPOR HARMFUL Avoid breathing vapor. Avoid prolonged or repeated contact with skin. Do n I take internally. I Not*: Direction* (of U*o should provide for adequate ventilation during tho time 0 when product is being handled. CO 1<n 72 CHLOROFORM WARNING! VAPOR HARMFUL Avoid breathing vapor. Avoid prolonged or repeated contact with skin. Do not take internally. Hehi Direction* for Ue should provide for odoquote ventilation during the time when product b being handted. CHLOROPHENOL (MONOCHLOROPHENOL)Same label as PHENOL CHLOROPICRIN DANGER! POISONOUS IF INHALED Do not breathe vapor. Do not gel in eyes, on skin, on clothing. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical att ntion. Remove and wash dolhing before re-use. POISON (Antidote) Note: Direction* for liio should Include appropriate gai mask protection. COAL TAR CREOSOTE CAUTION) MAY CAUSE SKIN IRRITATION Avoid prolonged or repealed contact with skin. Av id prolonged breathing f vapor. 73 i CRESOLS (CRESYLIC ACID) DANGER! MAY BE FATAL IF SWALLOWED OR BY ABSORPTION THROUGH SKIN CAUSES SEVERE BURNS Do not get in eyes, on skin, on clothing. Do not breathe vapor. In case of contact, immediately remove all contaminated clothing, including shoes, and flush skin or eyes with plenty of water for ot least 15 minutes; for eyes, gel medical attention. Wash cloth ing before re-use. CYANIDES, INORGANIC (Excluding HYDROCYANIC ACID and CALCIUM CYANIDE) (NAME OF PRODUCT) DANGER! CONTACT WITH ACID LIBERATES POISONOUS GAS Avoid breathing gas or dust. Avoid contact with skin. Keep c ntainer closed and store in a dry place. ^ POISON ^ (Antidote) Mot*: Directions for Indoor Use should Indudi appropriate pas mask protection. rtho-DICHLOROBENZENE CAUTION! i Avoid prolonged breathing of vapor. Avoid pr longed or repeated contact with skin. DICHLORO DIPHENYL TRICHLOROETHANE (DDT) 1. For straight DDT Technical: CAUTION) DDT IS TOXIC AND WHEN IN SOLUTION CAN BE ABSORBED THROUGH THE SKIN Avoid inhaling dust and spray mist. Avoid contamination of foodstuffs. 2. For Petroleum Oil Solutions containing not more than 25% DDT Technical: CAUTION! REPEATED OR PROLONGED CONTACT WITH SKIN CAN CAUSE TOXIC SYMPTOMS Avoid excessive inhalation and skin contact. in case of spillage on the skin, wash with soap and water. Avoid contamination of foodstuffs. Do not use on household pets or humans. 3. For Petroleum Oil Solutions containing more than 25% DDT Technical: CAUTIONI CONTACT WITH SKIN CAN CAUSE TOXIC SYMPTOMS Avoid inhalation and skin contact. In case of spillage on the skin, wash immediately with soap and water. Avoid contamination of foodstuffs. Do not use on household pets or humans. 4. For Emulsions containing not more than 25% DDT Technical: Sam* a (2) above. 5. For Emulsions containing more than 25% DDT Technical: Sam* at (3) abov*. 6. For Combustible Mixtures: Sam* at abov*, and add: CAUTION! Do not spray into or near fire or open flame. Do not smoke while spraying. 7. For Dust and Powder Formulations: CAUTION I Avoid excessive inhalation. Avoid contamination of foodstuffs. Note: If th* pfeporolion contains other hazardous ingredients or soi vents, appropriate additional coutions must be added lo Ihe foregoing. 75 DICHLOROETHYL ETHER WARNING) VAPOR HARMFUL Avoid prolonged or repeated breathing of vapor, Av id prolonged or repeated contact with skin. Do not take internally. Nolo: DirtcHom for Um ihouM provide for adequate ventilation during the time when the product 1 bring handled. 2,4-DlCHLOROPHENOL WARNINGI MAY CAUSE BURNS Do not get in eyes, on skin, on clothing. Do not breathe vapor. Do n t take internallyIn case of contact, immediately flush skin with plenty of water for at least 15 minutes; for eyes, get medico! attention. Remove and wash clothing before re-use. 2.4-DICHLOROPHENOXYACETIC ACID and DERIVATIVES 1. 2,4-D Acid, 2,4-0 Sodium Salt (When for mixing purposes only): CAUTION! IRRITATING DUST Avoid breathing dust. Avoid contact with skin and eyes. Do not use containers or equipment for handling other agricul tural chemicals. Store away from other materials. 2. Dry formulations of above containing 20% or more equivalent 2,4-D Acid (For consumer use): CAUTIONI IRRITATING DUST Avoid breathing dust. Avoid contact with skin and eyes. 3. Dry formulations containing less than 20% 2,4-0 or derivatives thereof: No health haiord warnings roquind. 4. Liquid formulations of 2,4-D Salts or Esters: CAUTIONI MAY CAUSE SKIN IRRITATION Avoid contact with eyes, skin, and clothing. Nate: AS wand kWir preparation* containing 2,4-0 or it* derivative* should awry odequate warning *tatea*ant regarding danger* of spray or dust drift to desirable plants, the necessity of using other equipment for handling and applying other agricultural chemicals, and`avoiding contamination of domestic or irrigation water uppiy- ETHYL BROMIDE WARNINGI VAPOR HARMFUL Avoid prolonged breathing of vapor. Keep container closed, out of sun, and away from heat. Note:,, Directions for Use should provide for adequate ventilation during the time when the product is being handled. 77 * CMA 035952 ETHYLENE DIBROMIDE WARNING! VAPOR HARMFUL ABSORBED THROUGH SKIN Avoid breathing vapor. Avoid contact with skin, eyes, and clothing. Do n I take internally. In case of contact, immediately remove all contaminated clothing, including shoes, and wash skin with soap and plenty of water; flush eyes with water for at least 15 minutes and get medical attention. Wash clothing and air shoes thoroughly before re-use. Meta: Direction! for llw ahoufd provide for adequate vontilotion during the timo whin the product ii being handled. ETHYLENE DICHLORIDE WARNING I FLAMMABLE VAPOR HARMFUL Keep away from heal and open flame. Keep containers closed. Avoid breathing vapor. Av id prolonged or repeated contact with skin. Do not take internally. Halt: Directions for lira ahould provide for adequate ventilation during the time when the product ft being handled. ETHYL MERCURY CHLORIDE (any effective concentration) DANGER) POISONOUS SOUD AND VAPOR Av id contact with skin, eyes, and clothing. Av id breathing vapor or dust. In case of contact, immediately wash skin with plenty of soap and water; flush eyes with water for at least 15 minutes and get medical attention. Wear fresh clothing daily. POISON (Antidote) Direction* for Um should include (hlailtd instructions for iaf handling of this product and moterials treated with It. 78 ETHYL MERCURY PHOSPHATESame label as ETHYL MERCURY CHLORIDE ETHYL MERCURY para-TOLUENE SULFONANIL1DE Same label as ETHYL MERCURY CHLORIDE FERRIC DIMETHYLDITHIOCARBAMATE (any ffective concentration) CAUTION) MAY CAUSE IRRITATION OF NOSE, THROAT, AND SKIN Avoid breathing dust or spray mist. Avoid contact with skin, eyes, and clothing. In case of contact, flush with plenty of water; for eyes, get medical attention. ' 1' *Keep away from fire or sparks. for duat mixture! 50% and over, and for lower corrcentrationt if dtiuent ia combuatible. FORMALDEHYDE SOLUTIONS (5% or over) WARNING) CAUSES IRRITATION OF SKIN, EYES, NOSE, AND THROAT Avoid prolonged or repeated contact. Avoid prolonged breathing of vapor. Use with adequate ventilation. POISON (Antidote) HYDROCYANIC ACID, LIQUID DANGER) POISON GAS Do not breathe gas. Avoid contact with skin. Do not drop container. Keep cool and away from open flame. POISON (Antidote) Note: Directions for Uso should include appropriate gas mask protection. 79 I * HYDROXYMERCURICHLOROPHENOL (any effective cone ntration) CAUTI Nl POISONOUS IF INHALED OR SWALLOWS) Avoid breathing dust. Av id contact with skin and eyes. In case of contact, immediately wash skin with plenty of soap and water; flush eyes with water for at least 15 minutes and get medical attention. ^ POISON ^ (Antidote) N#*: Directions for Uh should Indudo detailed hutrixlioiu for safe handling of this product and materials treated with Jb HYDROXYMERCURICRESOLSame label as HYDROXYMERCURICHLOROPHENOL HYDROXYMERCURINITROPHENOLSame label as HYDROXYMERCURICHLOROPHENOL LEAD ARSENATE CAUTION! POISONOUS IF INHALED OR SWALLOWED Av id breathing dust or spray mist. Wash thoroughly after handling. POISON (Antidote) Mote: Directions for Use should boar a statement relative to spray residues. LONDON PURPLE-Same label as LEAD ARSENATE O MAGNESIUM ARSENATE- % Sam label as LEAD ARSENATE 80 METHYL BROMIDE DANGER! VAPOR EXTREMELY HAZARDOUS HIGHLY VOLATILE CAUSES BURNS Do not breathe vapor. Do not get on skin, in eyes, on clothing. Keep away from heal. jfc POISON (Antidote) ^ IMPORTANT! The contents of this can are under pressure. Do not use ordinary can opener. Special handling equipment is available. Contact......................................................... for information n equip- (NAME OF MANUFACTIMtt) ment and proper use. Mata: Diructions for Use should provido for adequate ventilation during the time when the product Is being hondted. METHYLENE CHLORIDE CAUTION! Use with adequate ventilation. Avoid prolonged or repeated breathing of vapor. Avoid prolonged or repeated contact with skin. Do not take internally. MONOCHLOROPHENOL-See CHLOROPHENOL alpha-NAPHTHYLTHIOUREA (ANTU) (20% or more) WARNING! POISONOUS IF INHALED OR SWALLOWED Do not breathe dust. Store away from and avoid contamination of feed and food. Keep children, pets and livestock away, especially fr m bailed or dusted areas. POISON , (Antidote) SI Jl NICOTINE SULFATE SOLUTION (40%) DANGERI POISONOUS IF SWALLOWED ABSORBED THROUGH SKIN Do not get in eyes, on skin, on clothing. Wear protective clothing and goggles when handling. Do not breathe spray mist; wear respirator. St r away from food and out of reach of children and domestic animals. Wash thoroughly after handling and before eating or smoking. ^ POISON ^ (Antidote) NICOTINE DUSTS (5% or under) CAUTION! HARMFUL IF INHALED OR SWALLOWED Av id xcessive exposure to dust. Avoid contact with skin and eyes. Wash thoroughly after handling. Store away from feed and food products. Hals: Tlw p#ft*nlogf and form of nkoliiw prownl may call for potion labolinfl undor to roquiramontt of varkou* ttato lawi. PARIS GREEN-Same label as LEAD ARSENATE PENTACHLOROPHENOL WARNING! HARMFUL DUST Av id breathing dust. Av id contact with skin, eyes, and clothing. Do not take internally. In case of contact with dry material or its solution, immediately O 2 wash skin with soap and plenty of water; for eyes, flush with > plenty of water for at least I5 minutes and g t medical atten o tion. PENTACHLOROPHENOL (oil solutions) WARNING) CAUSES SKIN IRRITATION ABSORBED THROUGH SKIN Avoid breathing vapor. Avoid contact with skin, eyes, and clothing. Do not lake internally. In case of contact, immediately wash skin with soap and plenty of warm water; for eyes, flush with plenty of water for at least IS minutes and get medical attention. Remove and wash clothing before re-use. PHENOL DANGERI MAY BE FATAL IF SWALLOWED OR BY ABSORPTION THROUGH SKIN CAUSES SEVERE BURNS Do not get in eyes, on skin, on clothing. Avoid breathing vapor. In case of contact, immediately remove all contaminated clothing, including shoes, and flush skin or eyes with plenty f woter for at least 15 minutes; for eyes, get medical attention. Wash clothing before re-use. POISON (Antidote) PHENOTHIAZINE CAUTIONI MAY CAUSE SKIN IRRITATION Avoid contact with skin and eyes. Avoid breathing dust. In case of contact, wash skin with soap and plenty of water; flush 'eyes with water and get medical attention. 63 PHENYL MERCURY OLEATE (over 0.1% in oil or in oil-water emulsion) WARNINGI POISONOUS IF SWALLOWED IRRITATING TO SKIN Do not get in eye*, on skin, on clothing. D not breathe spray mist. In case of contact, immediately remove all contaminated clothing and flush skin or eyes with plenty of water for at least 15 min utes,- for eyes, get medical attention. Wash clothing before r -use. POISON (Antidote) Nate: Direction* lor U rhould Indudo dataUod imlruclioni far .of. handling of thii product and motorialc troatod with it. SODIUM CHLORATE WARNING! CONTACT WITH COMBUSTIBLE MATERIAL MAY CAUSE FIRE All clothing contaminated with chlorates is DANGEROUSLY FLAM MABLE. Remove and wosh thoroughly with water. Do not get on floor. Spillage may cause fires with combustible material. Sweep up and remove immediately. When not in use keep tightly closed in original metal container. Keep away from fire. Store separately from flammable material. Keep animals off freshly treated areas. SODIUM FLUORIDE WARNINGI MAY BE FATAL IF INHALED OR SWALLOWED Avoid breathing dust. Sweep up spillage. I Waih throughly after handling. 84 SODIUM FLUOSILICATE-- Same label as SODIUM FLUORIDE STRYCHNINE AND STRYCHNINE SALTS (any ff ctiv concentration) DANGER! POISONOUS IF SWALLOWED Do not breathe dust. Keep away from children, domestic animals, and foodstuffs. POISON ^ (Antidote) TETRACHLOROPHENOLSame label as PENTACHLOROPHENOL TETRAETHYL PYROPHOSPHATE (1% and over) DANGER! EXTREMELY HAZARDOUS IF SWAUOWEO, INHALED OR ABSORBED THROUGH SKIN OR EYES BEFORE USING see.........................................Company technical bul letin No.......... for safe handling instructions. Do not gel in eyes, on skin, on clothing. Wear protective clothing and goggles. Do not breathe spray or mist; wear mask or respirat r appr ved by U.S. Bureau of Mines for this service. Keep away from feed or food products. Wash hands, arms and face after handling and befor eating r smoking. *ln case of contact, immediately remove all contaminated cl thing, including shoes, and flush skin or eyes thoroughly with pi nty of water. Wash clothing before re-use. ^ POISON ^ Workers showing symptoms of shortness of breath, headach , tightness of chest or blurred vision should be removed from the job and immediately be given medical attention. (Antidote) *|f Hil* ilolNMnl i uwd In th ANTIDOTE Mction to provide tastraction* for Mtofnal finl aid treatment it will not bo nece*ary to thaw it In this location. Hotp; Aerosol* may require additional precautionary information. 5 TETRAMETHYLTHIURAMDISULFIDE (any effective concentration) CAUTION) MAY CAUSE IRRITATION OF NOSE, THROAT AND SKIN MAY BE HARMFUL IF INHALED OR SWALLOWS) Do not breathe dust or spray mist. Av id contact with eyes, skin or clothing. In case of contact, flush with plenty of water; for eyes, get medical attention. No**: Direction* for Ui* ihould inclod* instruction* for th* caf* hondiing of this product and malarial* treated with it. THIOCYANATES kcouiB of th dWriini in proper lies of members of this group; each product con taining thorn must bo reviewed individually. TRICHLOROPHENOL (all isomers) CAUTIONI MAY CAUSE SKIN IRRITATION Av id prolonged or repeated contact with skin. Do not take internally. ZINC ARSENATE-Same label as LEAD ARSENATE ZINC ARSENITE-Same label as LEAD ARSENATE ZINC DIMETHYLDITHIOCARBAMATE (any effective c nc ntration) A CAUTIONI MAY CAUSE IRRITATION OF NOSE, THROAT AM) SKIN MAY BE HARMFUL IF INHALED OR SWALLOWED Avoid breathing dust or spray mist. Avoid contact with skin, eyes, and clothing. In case of contact, flush with plenty of water; for eyes, get medical attention. *Keep away from fire or sparks. I rA*Fw dust mixtures SO ond over, and for lower concentrations If diluent is com bustible. 86 PRINTED IN U S A.