Document yrzGpmdqkba6rr21RKe4mDMLn

E. f. d u Po n t o e Ne mo u r s & Co mp a n y Wil min g t o n . De l a w a r e 19898 e n g in e e r in g d e p a r t me n t September 28, 1982 CCS A. J. Pahnke N. F. Vagner D. W. Marquardt C. G. Pfeifer 1C 31 * Applied Statistics E. S. JACOBS PETROCHEMICALS DEPARTMENT PETROLEUM LABORATORY CHAMBERS WORKS EFFECT OF SOIL AND DUST LEAD ON LEAD LEVELS IN CHILDREN i have reviewed the Silver Valley and Omaha Lead Studies as you requested. These studies indicate that the lead concentration of the air, soil, and household dust all have a significant effect on the blood lead level of children. It appears, however, that soil and dust lead have larger effects and that the effect of air lead may be smaller for children, ages 1-5 years, than it is for older children. This suggests that hand-to-mouth transfer is the greatest source of lead exposure for children. This conclusion is sup ported by the studies of Roels, et al. Unfortunately, the question, "How much of the lead in the soil and dust is due to fallout from the air?", remains unanswered. Low correlations between air lead and soil lead were observed in both studies (Silver Valley r * 0.52, Omaha r 0.37). A summary of my review of these studies is attached, please let me know what further work you would like me to do on this subject. ENGINEERING SERVICE DIVISION RDSscak Atch TEH 0470040 EFFECTS OF AIR LEAD, SOIL LEAD, AND HOUSEHOLD DUST LEAD ON BLOOD LEAD LEVELS IN CHILDREN Summary A review of the Silver Valley and Omaha lead studies was made to determine the importance of the affects of air lead, soil lead, and household dust lead on blood lead levels in children. It is concluded that all three variables have significant' positive effects with the combined effects of soil lead and house hold dust lead being larger than the effect of air lead. Although the two studies do not completely agree, there is evidence to suggest that household dust Pb is the most important source of lead for children ages 1-5 years. It also appears that the effects of soil lead and household dust lead on the blood lead level of older children are approximately equal in mag nitude and larger than the effect of air lead. The studies do not appear to answer the critical question of how much of the lead in the soil and household dust is due to fallout from the air. Silver Valley Lead Study This summary of the Silver Valley Lead Study is based on the reports of Yankel, et al (1977), waiter, et al (1980), and Snee (1982). It is concluded that the variables in order of importance are household dustiness, air lead, and soil lead (Table 1). In the 1974 study, the combined effects of household dustiness and soil lead (9.4 + 17.6% increase in blood Pb) is approximately 85 percent larger than that of air lead (14.6% increase in blood Pb). The household dustiness effect was largest for ages 1-5 years while the soil lead effect was largest for ages 4-7 years. In 1974 the air lead effect was approximately the same for all ages 1-9 years? however, in 1975 no significant air lead effect was observed for children aged 1-3 years. The correlation between blood lead level and the lead concentration of house hold paint or household dust was not statistically significant. The latter result, together with the significant correlation between blood lead and household dustiness, suggests that, in this study, the critical variable is the amount of household dust rather than the concentration of lead in the household dust. * Omaha Lead Study This summary of the Omaha Lead Study is based on the report of Angle and Mclntire (1979), the key results of which are summarized in Tables 2 and 3. I have some reservations concerning the data and associated the statistical analysis? however, the results, as reported, suggest the following conclusions: e The blood lead levels of suburban children (mostly white in this study) are not affected by the air lead, soil lead, and household dust lead levels to which they were exposed (Table 2). The blood lead levels of urban children, ages 1-5 years (mostly black in this study), were due to household dust lead concentrations and not to air or soil lead (Table 2). TEH 0470041 DUP050082861 N42421.01 % jf -2- The urban children, ages 6-18 years, showed significant correlations between blood lead and air lead, soil lead, and dust lead, with air lead having the smallest effect and the effects Of soil and dust lead being larger and of approximately equal magnitude (Table 2). A multiple regression analysis of the combined urban and surburban data (Table 3} showed that - Air lead had no effect on the blood lead levels of the children, ages 1-5 years, and - All three variables had significant effects on the blood lead levels of the children, ages 6-18 years, with the following order of importance; soil lead, dust lead, air lead. The effects on blood lead of air, soil, and dust lead observed in the Silver Valley and Omaha lead Studies are summarised in Table 4. The results of the two studies are in general agreement with the exception that the air lead effect in the Omaha Study appears to be on the low side. Comparison to Reels1 Study The results of the Silver Valley and Omaha Studies suggest that hand-to-mouth transfer is a more important route of lead exposure for children than air lead exposure. This conclusion is also supported by the work of Heels, et al (1980), who found that air lead had no significant effect on children's blood lead level when the lead concentration on the children's hands (PbH) was considered, Hoels, et al (page 89), concluded "ingestion of lead from leadcontaminated hands is a much more important factor contributing to PbB (blood lead) than does PbA (air lead)". Calculation of Percent Increase In Blood Lead The following relationships were used to calculate the percent increase in blood lead summarized in Tables 1-4. Semilog Model where log Y * a + b log X V " blood lead X = source of environmental lead I * Increase in blood lead when X increases from X^ to X2 %I 100 (exp (b(X2-X1)] - 1) Log-Log Model log Y A + B log X %I - 100[(X2/Xj )3 - i] R. D. Snee 9/27/82 TEH 0470042 DUP050082862 -3REFERENCES Angle, C. R. and Mclntire, M. $. (1979). J. Toxicology and Environmental Health. 5, 855-870. Reels, H. A., et al (1980). Environmental Research, 22, 81-94. Snee, R. D. (1982). J. Air Pollution Control Assn., 32, 170-175. Waiter S. D., et al (1980). Archives of Environmental Health. 35, 53-58. Yankel, A, J., et al (1977). J. Air Pollution Control Assn., 27, 763-767, TEH 0470043 DUP050082863 TABLE 1 SILVER VALLEY LEAD STUDY - EFFECTS OF ENVIRONMENTAL LEAD Variable Air Lead Soil Lead Household Dustiness Variable Ranee 1.5-5,0 ng/m* 500-1000 ppm 500-2000 ppm 500-5000 ppm CleanModerately Clean Clean-Dirty Study Year 1974 1975 1974 1975 1974 1975 1974 1975 1974 1975 1974 1975 Percent Increase in Blood Lead Snee Yankel. et al All Data Air Pb^lO uq/m^ 15,4 14.6 20.0 14.6 17.1 1.6 4.6 1.4 NS 3.9 1*4 NS 3.2 9.4 NS 3.0 7,9 2.8 NS 9.9 16,1 5.0 NS 13,5 4.7 NS 9,1 9.0 -2.8 NS 8.0 -0.6 NS 19.0 17.6 16,9 16,3 21.3 NS * Variable has no significant effect on children's blood lead level. TEH 0470044 DUP050082864 TABLE 2 OMAHA LEAD STUDY - SINGLE VARIABLE REGRESSION RESULTS Group 1-18 years 1-5 years 6-18 years NO. of Children 1074 242 832 Air Pb ,0269 -.1331n s .0834 Loq-Loq Slope (b)* Soil Pb Household Dust Pb .1515 .1655 .2033 ,2170 .1560 .1921 1-5 years Urban Suburban 204 -.1150 .0417 38 -.0451 .3074 .1979 .0384 6-18 years Urban Suburban 620 .0899 .1695 212 -.0171 ,0231 .2258 .0151 Models Log Blood Lead = a + b Log X, where X Air Pb, Soil Pb, or Household Dust Pb. NS * Variable has no significant effect on children's blood lead level. TEH 0470040 DU P050082865 TABLE 3 OMAHA LEAD STUDY - MULTIPLE REGRESSION RESULTS Log Blood Pb * bg + b^ Log Air Pb + b2 Log Soil Pb + b3 Log Dhst Lead Group 1-5 yearsW 6-18 years Variable Range % increase in Blood Pb Air (bj.) NS 0.03 .04-1.66 MS/TM3 11.8 Soil (b2) * .10 60-900 M9/9TM 31.1 Household Dust <b3) * .07 100-900 mu /9TM 16.6 (1)Values of regression coefficients were not reported. NS * Variable had no significant effect oh children's blood lead level. *A statistically significant effect on children's blood lead level was observed. TEH 0470046 DUP050082866 TABLE 4 COMPARISON OR THE RESULTS OF THE SILVER VALLEY AND OMAHA LEAD STUDIES Age Group 1-5 years 2:6 years Study(*) Silver Valley (1974) Omaha Silver Valley (1974) Omaha Percent Increased In Blood Pb Air Lead Soil Lead Household 1.5-5.0 uo/m3 500-2000 ppm Dust 14.9 (T) NS 10.2(3) * 22.9(3) * 14.3 3.7 9,1 (2) 14,9 12.1 (33 16.6 (a)The Silver Valley (1974) results are based on an average of the regression coefficients found in Tables V and VI of Snee (1982). WAir lead effect was 10.0% increase for ages 1-3 in 1975 (Snee 1982, Table VI). (2) goU Lead effect was not significant in 1975. (3) Based on household dustiness variable. NS Variable had no significant effect on children's blood lead level. *A statistically significant effect on children's blood lead level was observed. TEH 0470047 DUP050082867