Document yrXyqn8mn3Zw8vzNzX0QnGGD6

p0r* Approved 0MB fie. 4*-Rl 3S7 APprovil Expires: July 30, 1972 8.:. DEPABTOEHT Of 1*552 MATERIAL SAFETY DATA SHEET form No. OS1 Hiy, 1971 2i j 0 2. -" *---- A. SPCMXVLM 1---- I^L.1 LL-L-J ^ V -- - -------- _ _ il -A ------------------- --------1 UCT10M 1 g MONSANTO COMPANY ____________________________ M1U) Soil-: inn Nor^TlIlIfldbriFr^ouivVr^, St. Louia, Miaaocrl 63166 | . MlXT-\iT9__________ 1 M*ee aS itmwvmi I Aroeln- l?ti2 j `"ETftorlnated aromatic Mixture I l| ii _J 1 SECTION n S riaM. rl*VAfi*tV 4 MivtaM fUtwae) G4t4lTT ixttT 4* rt4i.Lf eearaai um mr+ 44ton "~1 ~1 Vf<U lOivien *oe<Tfv(s Ots**f . MiTAujc cornua laii MVTA4 nuf OK CMI U/1 0TiM sjzTueci w tTHta leciat, a* wui I TUV SECTION HI PHYSICAL DATA MH.WC *o*t rvj _ f . 7 60 SB ------ -- 165-210*0 ] 4^oa MatrtT iaj4*ii Mecca-v,rv -i'f2,/25eC^ 3 SB rRrNvCOfWl \tMVOC<%ATTU nkt Irell iyP4Brieai UT| -------- m ___ kn.oit " 1. NAN W.1 . <1 SECTION IY FINE AND EXPLOSION HAZARD DATA D" C.O.C. 196*C CITiwQyitwi^ft m&A *m* 6tn - r-y r-< nr. ripor or cases is possible: --flrtl Sf.tr t--UatlliT!--12_ _______________________ lff^Jy^^^aTfsVrrbhlorldss and chlorine) can bs evolved In fires of this product. PRR 002794 A 0009407 WATER PCB-00048201 /roclor 1221 SECTION V health HAZARO OATA ' >t| k>ui U ***< vAt^t Nos Available 'TAVlrrTtaUo,n In the form of chloracne , systerna leads to nausea, vomiting, ToTS o: v.-ei^nt, cwt.i.a ; P(Me*ref^%rv4eN(I Mfro1lm* txn21oOOstufSr*. Per.ove contam.ina_ted, c,,lothl. contacted area with larpe amounts or water And sc to physician. . S 4#.. 1 .tniki | |T*U SECTION YI REACTIVITY OATA 1 ^ J' 4 I* *.0`Q x1 "" *42a400w* OKPWOtAfti **OOwC T| CO, ~42*AOOUt *44v oecua a *or occu* CO?, smoke, X soot, chlorides and Ji ' SECTION VII SPILL OR LEAK PROCEDURES y A oM rt on clav, savduss or otr.er absor.-an. rvate.al. 5". ac m drumc. Bury in approved chemical landfill in accordance wi local and state renulations, **^urn*VrT an3 approved incinerator in accordance with local and ctatc regulations. ` J SECTinn VIII SPECIAL PROTECTION INFORMATION 1........ ................................S'dreau of Tines approved respirator for orrar.is 1 V(**!lt^t4* .oc**,^.s. y## _ fop vtpoP3 Ci a^wTl . M(UM(M (UmJ* Pt>H4 * jj Oi( ; *i *| C.ovll rubber 1 ?- 440^1 C Ttvf tOw**'*** |Tf AZOTIC TlO* chemical toggles i j , SECTION IX J**(C* ' C>k 'Jr I ' ' ** aay l ` U " Avoid skin and eve ecntact Avoid inhalation of vapors. 1 G-t AtCawiiOMi SPECIAL PRECAUTIONS PRR 002801 lt While the inforniticn ind r ec case nd < t i on s set forth herein ire bI! to be iecu rite is of the ditt hereof. MONSANTO COMPANY MAKES NO 'w`i:,,' 'PITH RESPECT THERETO 450 OISCUIHS *11 LUSIUTY FRO" RHEIUAN*CcE; ThE.>r 1 JAG:1;0H:J7G:W3P A 000940S WATER_PCB-00048202  Monsanto material safety data OCCUPATIONAL CONTROL PROCEDURES Inhjltnon--Workplace exoosure should be maintsintso ths OSHA signt-hour , *3* Threshold Limit Value (TIVI. At room tmofnir*, me hetara of Inrwttior, , Jr ~"'r,M?rn*3 absent. Chemical cartridge moirrton or gM miua soorovad for protection recommended m me event of soilH or tasks of hot fluid*. These mil provide 9OO0 r,*n< * concentrations shown on me soorovai labels and me odor will give ampi* warning ,f ,, ro,*c,'0n uo t,, J? deiica. Self-contained breathing apparatus mould t>* worn wnan flCl's an encounte^T** ---- :-- " in an --ncio Threshold Limit Valua (TLV)--Chlorodiohenyl (*2% chtonnel 1.0 mgreu.m. Chlorodipnenyl (54% chlonnel 0.5 mgicu.m. Sltin wrtn Contact--Avoid prolonged or rapaatad PCI's. protective Clothing imparvtoua to akin contact. Where amployaaa PCI's should be worn. Gloves. bmoaoty*,coomvaarv'"i1o0at8irw aprons met cover ma boot tops should ba uaad wnan r* This protacttva aqvi'io^iA" -- ^ rrguiarty inaoactsd for dafacxs and to ensure mat it is in dean and satisfactory "O'*' "9 condition1'00^ ** nstad clothing, glove*. stc.. mould ba disoosad of as prescribed by regulation*. V Con'Un. Era Contact--Eye protacoon should ba usad wnan man is s possibility of liquid spiashas. ingeeooo--ingestion of mass mstansls is generally not a pioblsm in industry. MATERIAL SAFETY DATA MonSifltO PHYSIOLOGICAL EFFECTS SUMMARY: Skin Contact--Can ba adsorbed through intact akin. Local acbon on skin is similar to mat of common orgm, aotvants wnan comaet Issda to removal of natural fata and oils wrtn tubssquam prying snd erseung 3< ^ skin. A potential exists for ma contracting of chtoracns. EveComaa--The liquid products and melr vaoon sn moderately irrttsting to sya tissue*. ingeepon--Ths acuta oral toxtcroe* of ma undikrtad compounds sn: LDk rats--1.56 gnvfcg for 42% wiennstad. and 11.9 grtvkg for 54% chlorinated "slightly toxic." Inhalation--Animal sxpanmants of varying duration snd at different sir concentrations show that for um.i* exoosun conditions, ma 54% ehtonnatad material producss mon liver injury man ma 42% cnionruoa material. Omar--Than an litantun raeorts that PCX's can impair reproduction function in monkey*. A study rsoortsd m thj literature with female rata using Arodor* 12*0 stated mat Arooor 1290 cauaad livar cancers. Monsanto sponsored animal feeding studies of Arocior1242.129d snd 1290. These com pounds, fad to bom taxes of rst*. did not produce cancer*. The National Cancer inadtute performed a study in l*77-usingA/ociori2S4wrtnoom saxes of rets. NO stated mat the PCS. Arodor 1294 was not carcinogenic under me conditions of ms* bin assay. . The consistent flndbig in animal studies with PCS'* is that thmr produce Irver injury fofemring prolonged md repeated axposurt by any routs, if the axpoeure is of sufficient degree snd duration. Uver injury >t produced first, and by exposures that are ieae than that alleged to cause cancer m rodents. Therefore, exposure oy hi routes should be kept sufficiency low to prevent livar injury. FIRE PROTECTION INFORMATION Fire snd Explosion--QUorodipnenyis are ssaarroaify non-combusObia compounds. They may dacomooss id form CO. C0r HO. pnanolica snd stdanydas under savers conditions such ta exposure to ftsma or not surfaces. No phosgene is formed. PR* 002017 X 0009410 WATER PCB-00048203 f M A II MIAI S A f'i; I Y D A FA ' Monsanto material safetv data3 ,,, RRE PROTECTION INFORMATION "" : fir* and Exptoaionr. PCBs art firs-rssistant compounds. They may dtcompcst to form CO. CC?. ~Ci ! i pntootica. ucenydts ana ome iox>c comoustion products unaer scvtrt conainons ! ! suen as txpesurt to ham* or not surface*. 1 At ttmpeaturt* m tnt rang# of 600-650*C m tna presence at excess oxvgtn PC8s ! ! my form pofyentonnateo PiDeizofurans (PCDFs). laooratory studies uncer similar | concitions navt atmonstrattc trial PCS* ao not proooc* poiycnionnatac cioanzo-p: dioxin* (PCDOs). i' j PCS* in electrical tcuiomtnt have bttn reported to procuca Both emonnatte cicxirs | (PCOOs) and furane (PCOFs) during hr* situation*. Tht* comoustion products -ay j result all. or m part, from non-PC8 component* of th# aititctnc fiuias or ctner J comouated mateiaia. Consult me #quiom*nt manufacture tor information regarding competition of tn* ate*ctnc fluids m eierrnr al apparatu*. I Standard fir* hghting w*anr>g apparel and s*ff<ontam*d breaming apparatus sncuid ; be worn wnei hgrmnq firt* mat involve postal* exposure to cntfmcai comoustion j products. Firt fignting equipment snould 0* tnorougnfy d*an*d and decontaminated after uaa. If a PCS transforme is invotv*d in a fireratatad modem. tn* owne of tn* transforme may 0* required to report tn* modem. Consult and follow approonat* federal. stata. and local regulations. --" REACTIVITY DATA________________ PCS* are vey stao**. fir*-f**i*tarrt compound*. HEALTH EFFECTS SUMMARY Skin Contacti PCS* can o aoaoro*d tnrougn mtaa skm. Local action on sun is similar to mat of common orgete sotv*nt* wne* comae; itads to removal of natural tats and oils *<rn suosepueit drying and cnoong of tn* skin. A potential exists tor tn* contracting of emoraen*. Eya Contact Th* liquid products and tn** vaoors ar* mooeatafy irntannq to *y* nssuts. Infection: Th* acuts oral toaciB*t at tn* undilut*d comoounds are: LO^ rat*--8.65 gm.kg for 42% emonnafd. and 11.9 grrvkg for 54% emonnateo--"siigntty toxic." - Inhalation: Animal expenmrrt* of varying duration and at different air cancannations snow mat for sm*e txpoaur* conomon*. tn* 54% emormaud matanai prooucts mort nver in jury than tn* 42% emormatad matanai. Other: The* ar* Waratur* reoorts that PCS* can uneair reoroductrv* functions m mon*ys. a study reported in tn* irteatur* with fenal* rats uamg Arooor' 1260 stated mat Arocior 1260 ~v irrl live cancer. Monsanto soonsored ammai f**cmg studi** of Arocior 1242. 1254 and 1260. Th*** compounds. f*d to bom s*x** of rats, aid not oroouc* cances. Th* Nation* Cance insotuta p*rtorm*d a study m 1977 usmg Arocior 1254 with dotn him of rats. NCI stand mat tn* PCS. Arocior 1254. was not carcnogenc unde tn* conditions of mer otoassay. m*wm C.twen Summary Corwnuetf On ut*r Atger PAR 00262** Polychlorinated Biphenyls (PCBs) A 0009411 WATER PCB-00048204 PACE 1 OF * Monsanto material safet/ data Standard rirw lighting waanng soparsl snd saif-contamad arsathmg sooaratus should Oa *orn wn#n fignung firs* mat involve poaaibJa axpoaura to cniorodipnanyit. Firs fighting aquipmant must s tnorougniy eiasnao *nd dacontammatad aftar um. PHYSICAL 0ATA TA8L1 I Prepaitlat of Soiactad Araaiort Colir IAPVIA) Physical star* Stability Dansity . iit>gai 25*0 , S pacific gravity to is.rc Oistillation rang# PC) Acidity mg KOHIg, maximum Firs point rci Viacoaity (ioo* iota -- moola od i r\*n 11.40 1.31-1.37 *-2r 3Z3-354 non# to boiling point 71-1 itn 100 mobtia oil inart 9*8 1.11-1.19 *-2r 275-320 .014 17g 31-41 izn 100 mobiia oil 10.58 1.27-1.2* *-2r 290-325 .014 231 44-81 1243 100 mobiia oil inft 11.50 1.30-13* *-2r 325-3*1 .015 non# to boiling point E2-82 1248 100 mobiia oil inart 12.04 1.40-1.41 s-r 340-375 .010 nona to boiling point 118-240 1284 100 vtacoui lCuid mart 12.52 12*0 150 Jtictv r*in inrr 13.50 1.48-1.50 *88* 388-3*0 - 155*1 58 *90* 385-420 .010 .014 nona to boiling point nona to ' soiling point 1400-2500 -- REACTIVITY DATA PCI's art vary stabia, flra-raanram compound*. Monsanto MATERIAL SAFETY DATA SPILL LEAK k DISPOSAL INFORMATION if PCI's iaak or art sptHsd. ma JoMmanng atop* ahould ba takan immadiatafy: AJI non ataarttiaf parsonnai ahouM laava ma Iaak or spill araa. Tha araa should ba adapuaaafy varttUatad to pravam ma accumulation of vapors. Tha soillrtaak should ba oontamad. Loaa to aawor syatama. navigsbla wsrcarwayt tnd-atraams should ba ptaxamad. SpMaftoaks should ba ramowd promptly by moans of absorptive matahal, such a sawdust. varmieuUta, dry sand, day. dirt or omac similar matanaia. or trappad and ramovad by pumping or otnar surtaOM maana (trap*, dhip pan*, trays. aseJ. Paraonnai antarlng ma soik or Iaak araa ahould b* (umtanad wrtti aporoprtata paraonal protactna aduipmant and doming aanaadad. Paraonnal trainad in ma amargancy procadura* and protactad againat m* attandant hazards should shut off souroaa of PCI's, daan up spills. control and repair laaka and ftgm Area In PCI area*. Alt wastaa and raaiduaa containing PCTa (a.*.. wiping dotha. adaerbant matariai. uaad diaooaaeia oro tacttvs giovaa. doming. me.) ahould ba eoilactad. piacad in prooar eomamtars. mamad and disooaad of in ma mannar praacribad by &A regulations (40 CFR 711). Various fadarai and stasa regulation* may raouira raoomng of PCI spills. Consult your srtomay or appropnata raguiartory official* for information raiaong to soiH reporting. PRK 002*i8 A 0009413 WATER PCB-00048205 Monsanto St. Louis - Gaasral Offic* .... Uarch 17, 1969 ......... ... TO TO REGIONAL WATER QUALITY CONTROL BOARD Thair Uttar to you of March. 7 from Mr. Frad H. DUrkar : 3-H. S. Bergen - HBERG ^ About Aroclor used ia tha dieUctric area, we respond to itame ind 7 of Mr. OUrktr'a lattar as follow*: S, 6, 4) The solubility of Aroclor la tap w&tar at 25* C. i a* follows: Product Solubility la Water Aroclor 1242 203 t 10 ppm Aroclor 1249 106 t 14 ppm l Aroclor 1254 50 t 2 ppm Although tha solubility of Aroclor 1260 has aot baaa d*tarmiaad tha above data cartaialy serves to ladicata xbm mors highly chloriaatad Aroclor* such as 1260 ar* tha Uast solubla ia watar. Aeeordiagly, It Is quita reasonable to say that tha solubility of Aroclor 1260 ia watar would ba significantly lowar than 50 ppm. 5) Aroclor 1242 aad a small amount of Aroclor 1254 ars usad la ha rma tic ally saalad capacitors. Tha harm* tically saalad can construction is of aluminum, mild steal, aad staialass staaL Thasa capacitors era usad 1mbaddad ia asphalt la fluorascant lighting systama. Thay ar* usad for powar factor correction oa utility liaas. Thay are also usad as motor ra capacitors for air conditioning tystam*. Attached are tha specifications for Aroclors 1242, 1254, 1249, aad 1260, which describes tha physical properties of thasa materials. Aroclor 1260, sad to a Ussar axteat Aroclors 1242 aad 1254, are used as components in transformer fluids of tha askaral type. Ia gaaaraL the amount of Aroclor usad ia tha trans formers fluid ranges from 45 parcaat to 60 pereaat. PRR 004669 " i, A 0009415 WATER PCB-00048206 H. S. Bergen -2- March IT, 1969 On the West Csttt in 1968, about 300, 000 pound* of Aroclor wti coauutd m the transformer askarel fluid uitd in id*: region :o mix* rriaiform* The** askarel transformer* *r ilo hcrmiuctUy sealed, non-breathing apparatus. Very little of id* fluid is u**d to replace pent fluid. A*k*r*l true formar fiilura that would require rpi*c*m*at of id* fluid ia vary rare. Tor axampla, id* Edioa Elactnc la* arut* found that tha iacidaat of *uch failura i* in tha rang* of 0. 05 percent. 6) No Aroclor capacitor* ara mada on tha Wait Coast. Tranaformar manufacture rs on tha Watt Coaat who haadla Aroclor containing fluid iacluda: federal Pacific - Santa Clara, CaXoraia Hill Magnetic a - Redwood City, California H. K. Portar - 3a 11moat, California Siarra Tranaformar - Redwood City, California Spokane Tranaformar - Spokane, Waahingtoa 7}. ' In tha normal uaa of capacitor or tranaformar fluid / containing Aroclor, Monsanto adviaaa tha capacitor tranaformar manufacturara to avoid breathing vapor a that would be emitted from tha fluid if it ware haatad to alavatsd temperature*. Monsanto al*o adviaaa tha u*ar of the fluid a to avoid cotanu* ous contact with tha akin. If clothing bacomea saturated, tha workman ia adviaad to Lauadar it baiora wearing it again. If there haa bean (pillage an tha akin, it should ba removed by washing with soap and water. Normal, ordinary good housekeeping practice is regSmmaadsd. Normal Itratiou of tha fluid it dona ia tha electrical industry has not presented health hasard provided that ordinary normal cleanliness is followed. i PAR 006870 A 0009416 WATER PCB-00048207