Document ypexQ9Je8QD39qKMz4jxZEokd

;| LL Sim AR126-00T8 Eis - 00 Laboratory Report LCMSMS Analysis of Extracts reported in: "Preliminary Report Analysis of i Perfluorinated Compounds in Environmental Samples" by P. Jones and K. Kannan i i- - - Report number: FACT-GEN-008 Testing Laboratory 3M Environmental Technology & Safety Services 3MEnvironmental Laboratory Fluorine Analytical Chemistry Team (FACT) 2-3E-09 935 Bush Avenue, 00St. Paul, MN 55106_ Laboratory Contact Kris Hansen, PhD. Bldg. 2-3E-09 P.O. Box 3331 St. Paul, MN 55133-3331 Phone: (651) 778-6018 nnReguenner FAX: (651) 778-6176 3M/Battelle Exposure Team (c/o Susan. Beach) 3M Company Environmental Lab 2-3E-09 St. Paul, MN 000514 fo | MENTHReOrEoNnTsAriiegroCResTnOaRS | " | 1. Introduction i; a i. MMSiiaccmrrpoolmmeaaessxsstQPrulaaacdt,oprrroneIp,a1area sbpiylngPql.eaJqodunpaedorslanpeodlieKn.LsKtCarMnuSnmea.nnTth(aLecCsIoeSarMEmnSe)0e,xwrFhaAicCcsThwpMerro4ev0ird,eesw-etrmerosrnerdsebinyeeFdvAeuCsaTinngiaaegsa tbheaen lsiniglmeqwuiiadhnitnhsaeiLmCtumMeSenM.Sdn.ieferences atmayprovide flepositiveresponsein CMS analystsen PthRExoOtsreSacdutsseifnrgoemthsreamLupisOlieMnsngSoLMfeCsSeMdInc.nlg1eesnleka,esPy,RtbOhSadtlmecvaeltlsiedeitnletaerrmafie,nreeandncbeyatsLohrwCaerMrouaVnndwalryczesesd4qp3p9rucoosamipailtielcyahfaotfrhoef | o`rsgmipnlaelsFLoCrMthSe LaClyMsSisM.TShansaltyyspieso,fqmuaanttitiatmieonrwfaersebnaseneedaarnmtahses449999h5a9s9b,e1c3adbsaergve ionncshersspbinosgiecal | cVIaanultsheeesdLaarOneManSopMmioSlcaonauaslylsyiblsi,ogwlheorwtelhseapvnoenlshseooiefnrPhFeeOLpSO(tM<bS5yapJpnob)eswsea.rnedeKtaencntaendin1seveerallyoftthhatefisehssamipleese;tnhesse | `NAogaPinR,OShiasb5ove tchoealsittootfhdeiLcOtMiEoSnvaansydse.c inte rein fh samples needbyLCMSME, Additonal, allsamplesofclepasawerescreened fore followingflucrochersicals PFOSA, :1 PPVFReOOySSlAAoAAw,,MMv35e87s60,,(<MP5SOpSAb6A,),PooOrfAMPA3F,7OP0SHwAwaSes,rdaeenctdhescPetFrvDenS(asiyneteshAeupNppoerentdh.iAxmBefroircdaenfbinaitdioansgoefpFlaAsCTascrpoineysms.).No || 'ePFHSlwasadeltf aectedineeveryB)alticseaneadgleplcasvmassNamphle,whilePeFnDa Swas y prelimnay (0oo%standard | "Thisdaiscreeuanl innlgy.Only `wereextractedandanalyzed. 2bigh level (250)POS tix kesupe (eagleplasm) : aPn.sJloynzeesdabytKheKmansnianng adnelEinvveirreodnsmaemnptlaelsLoabtLeEOMnvianrMaornchs1L5b-.19T,h1e99s9.plAftewreLrCeMxStaancailoydsiasntdhe | `xiatchtthsewseamrpelseusb.miItiedatsouFmAeCdTtfaorsaLmCpMlSevMoSalnealaynsidsf.aThleerxetwraacstnvooetxterawcetrieontpaepsearnweo.rk submited. i ERdg E Te E T E T + Theres oholding timereissocistewiththesesamples forLC/ESMSM aris. 000515 Pacezors | wesiREPgORoTNOn. FrCToGinasn | 4 Methods - AnalayndtPriepcaraatolry >] | AaaflrFyoAtmCiTSc-eaMrl:um3emt1oh,roOEdtshxertFlruiodaffcoProAtinaasosliyunsmisPUseinrgHuPoLCr-EoleoccrotsparnaoryeOMtashsesuSlpFelfucotorrooncmhaeemttiyc:eaml CoodmpioubfnydiNs.eOdT | foSofXrmUqoTuAsaCnttnoigftatathimeoaant.rrgiTexhctiusfrmuvooerdfoiocbrhceuamstieicioannlqwuialrnltoiamtvahteiteohfnei.shgArtepiarstese-useetxiesfrfteeiclntigokcenulrtyvhteeo,fbeexhtSrgasncatimecpdlafenrslo.ymExrtlarobawbceittrisoenaraen,hwteahssonusiscesd. i | fFcFrlAouCoimTdt-UnhMs4ei.spn1l,giatHosbdmAeanm.eaP`ilFnyrosiritLmeshuiimdsPr.Coetaasso-sn,iuLmCPEMSSepMelcSrrroefempoernltyec:domvadlrruiesofooobrortyOhqstceahfreisdtrhpiFttlaiiasonsargunoescsuheameympmplisleceassMllsvihnoefSaueelrdobu8seman.onrdaOsathreer curve racedfrom rabbitsea,nofrom thesamplemai. I H1PHPLCL,anOaalnidqEuEotPoLSf CexEtMSraMcSiSMinSjctdan column.Basedonthe afinity of theanalyte fpoasthseedsatthiroonuagrhyprheavseerisnepthheac:oiluimdn rcehlraotimvaettoograpfhiiqcuid | msaoonlabulityiltoeenpehPxatFsreOa,cStmtehdaefarynoaclmhygtereaoutinrd8ew0tamatiienertdiefnosrh.iaRscahenaratalacytsieirsniwsttieimrceaesmmbaeottucwhreeeodfnoanvsteah.neFdHoaPrrLdPaCmFspyOsltese,omutiniowSoinatahcidnrt1eh%e | odrFegtoaelncltioiwcoicnnoogmHfmpPooLluCencduslespaiarnracotnhisoinn,giEsBgSoenMreaSrcaMhlleSympoirpocevraialdtsee.dEaaltrcealopasitdpiaevnaedlyy,amciarladtteenizato mepaesrfeaor.canMahloyuzalinegeiacwaizqrudaoelnsroyaengf,soeor f ] a`dnseduacbspierdqiumeanrty onco,llcisihonasrraactteersimsalolfertshenealctso,finsosiedelreaacgtrr.mTeynhtissuonniqiusetbootmhbeaprderdwiitihozhni,gwahh-iercnehryagrygas | `For example,for PFOS (CJF,SOy)analysis, ion 499isselected asthe characteristic primaryion. Thision ithsefsreagsmeecnotnedadirnyftrooatghmeernitosnisssduetcehcatesd8a0aemcua(nbcoeruresspdotnoddiinfgetroeSnOty),aPnRdO1S3f0oamm (heCcFom;pSouEOnadycsht)oa.ft | smeicgohntdhaarvyeftoensfaagmmeecnhtaaraicotnerpisatticem4s9.9amapriaryion,butdifferentchemical compositions and | | 5.1 FrQuoatnthittaetiLvVeSAnaanldyLsCisVISSsys quiverssd poncompan aye | + pTPaelhaaesktmeaaxrrcpaacitenwilitoohnteehsfslifaniimtchpliemlerneacawetyniogtiefehovsaPcnfReaqyOleu.ySatfnetrlpioaemtaissokena.rreoaIfssgotelhnieekreralayntitehmdaautlstsihnegaesxatbsraeacntniddoaendtesfriemcxiianeecndtceytdofbfrePobRmetOrwSaefbebrniotms7cc5aa..9g5e% | a 52 Qualitative Analysis | PHmEaSgl,oepalnaandnsamlPayFistDeaSmr.epttDleuenrtoeiionxngairctmhtees.waeOrtrahleyeqsraslt,thaahivereexltlarytasicvctesrcweoeemnrpeeadrbiorsraocPknEe,tOnSobAy,aaPrFmOitSnAieAm,ruemMs5ut5m6sb,aeeMrSo7vf0as,atbaPnlOdeaA.rAd,s t response of3reasonabledaughic ons (599-580,59, 130) atareasonableeenton ime. | 000516 : Paceaces i WeWIRO ETL aoRuTORY REPORTNO. FACT.-GEN-008 | 53 Blanks i: pTrweopacroendt.NaionearabllyatneksswweerreedperteocvtieddeidatnhdeexxaaccttseodfbeyileJrontehse aCnodKnannneanr. sExotrracrteieonbelannkssiwertealso . i 5.4 Matrix Spikes `sOpinkeePssRhOoSwmeadtgrixespikse at25800e%pporbowvaensrypreparedforcachoftwoeagleplasmasamples.Bothmatrix 55 Laboratory Control Samples LaboratoryControlSamples renot componentof hissy. | 5.6 Sample Related Comments | vAelrldparreliisimisnacryr, aesteqhueanlidtiryoannclgoy.neAflfilcaineanlcyytoicfaltrheetsurseoffforhotchsemeicexatlracftsosmhouhledsbemeacosnosnisdeeredctobe J HSwasdct vy ic acai wk DSa iit sed | | Pt`FhEoxOtsreSadcutesstifenrrogmTminhseeadmLpuClseiMsnSogMLfSC.MaSIa.ngIglteespnlearse,ulaPy,tFbhOalStmldeacvategliespdneattfseeamri,enanecndedbafytisoLhrwCaeMrrSoeuManEndamwlaeyszrsed4aq5pu9panrctoixotaitmmievptelyyafaotrafeof rLeCsMpoSnsaen.aMlyastisi.xForrtfherLeOnMeaStM4S99anbaalsyseies,nquhanatviteatdioinnwaos basieodloognictahlest4a9p9l>es 99, 130daughterions | | aHln`oiaLwgolwehyrlzeeetsvdhpebaolnyntoshLfeoCisPnMrFteOhSpSeao(Lrnt<Cde5MdLpSbCypaVn)JaSwolMyneseSrisess.d.neTdtheKicatsnetndyaipneno.sIfetvaeniroamlakolefylhtehhafstiseahseanmtciphleert;vrtehfdersyeovtFalAcuCeaTsnoadrnes4oighsnimfciccuamtplyle NoPFOSabovethlimitofdetectionwasdetected the remaining fishspl analbyyLCzMSeMSd. | F`AVAFdegdOraiySitlinAo,ontAwah,lielMsiyvS,sei7asn0lc(l,o<unMmt5SrpSapise6bts,t)oPooftOfehAaePgF,LiOCSPMlFAaSwHsSea,nraaelwnyeodsbrisPeses.FrDevSee(dmsieensdtAhfepoNpotehrnetdhfioAxlmlBeforwoiircndgaeSnfubioanrlidoticcohnaesomgiefcpalFlaAssC:mTsPaFscOraSoAmm,yms). 'PFOSAA, M556,POAA,or S70wasdecidinanyspies. p. No were exascndtanaelyded materialavailableforconfimmation)detectedinevery NothAmericanbald eagleplasmasample. i `Thisdataisscreening quality only. `Only 2highlevel(250-ppb)PFOSmatrixspikesamples (cagleplasma) i1 BBi pman RE TE E `Samplesandextractswillberetained forfutureevaluation,if necessary. 000517 raceaces i: WERREPEORNTNTG FLuAsGoemCToaTRss | AA en RE I RE ! i 8.1 82 AAthtamchementt AB:TaabblleeooffLFCACMTSaMScResyults fortrhemAnsalysisofEagle PlasmaandFishTissue. 8843 AAttttaachcmhemnetCnDt:: LDaCtMaSarepsortsbywoi.tJchoLneCisMaSandMKSt.aKneaalymsdaisn: | Fdahro.ld Jonson, =n 2 7 Nh | Ph.D, FACTGroupLeader lala Dae [2/99 Date. | i|| . 000518 Paaesoes 3M Environmental Lab - Fluorine Analytical Chemistry Team FACT-GEN-008 WWIIEEAA-SSWWEE9-933.-001270 SSeeaa EEaaggllee PPllaassmmaa. WIE6A2S9W38E29633012 SBaeladEaEgalgelPelPalsamsama 662295308721614 BBalddEEaagglleePPllaassmmaa 6622993365358497 BBaallddEEaagglleePPllaassmmaa 6622993377002310 BBaalldd EEaaggllee PPllaassmmaa. BBaaltiicc N.BAamleircica NN.. AAnmcerriica NN. AAmnerciaa NN.. AAmneerriiaa 59 ddeetsccitedd 1A6s5 detcted detected 1998 ddeetteeccteedd 120647 ddeetteecctteedd Emn ddeettesccteedd | fr totqumsmm soncopy | FFOS8700038152 LCaarkpe,Twrhooultewbhoodlye body PiSinsekiRwiivte,r,MMIU BBLDD | FO0310 1998095 Lake Trout whole body Siskivit, MI Brown Trout muscle Detroit River, MI BLD BLD 1F979880795 CBirsocwonweTtrmouuscLliever DeLmakietSRuipveerr,ioMrI BBLLQD | 11999986006644 CChaammeellCCaaftfishheegggg LLaakkeeSSttCChliirm,,MMII BBLLQQ | FFBSO80001008811 LLWaakkieeTTsrroouuw,,hwwihhooellheebbooddyy PDiLanakmeeRiiSvuRepree,riMsolrd BBBLLQDD 1998064 Chanel Catfish muscle Lake St Claire, MI BLD BLD =limitofdetection (approximately 1ppb) 3M Confidential -Attomey/Client Work Product Privileged - Do Not Disclose 000519