Document ypNxpVzyqedRx0KE95O75O1md

DO 143790 CONFIDENTIAL iNi'IBQNNENJAL OPERATIONS WASTE CHARACTERIZATION gUMMARY ALL QUESTIONS MUST BE ANSWERED BEFORE WASTE CAN BE ACCEPTED FDR DISPOSAL 7sEe INSTRUCTIONS ATTACHED) DEQ/EPA WASTE NUMBER: TYPE NUMBER: 1. CONTACT PHONE NO. 3. PLANT ACCOUNT NC. 5. WASTE NAME_________________________________________________________________________ 6. IDENTIFICATION BY PROCESS KNOWLEDGE IDENTIFICATION BY COMP 051TI ON: uGNCEKTnATIDN CO i t r A N FRi_>CES5 nm 1000 FLASHPOINT: ________ __ _____ DEE F. dH~ _TM ZZZ_Z 10. CORROSIVE TO STEEL?__ __ __ _ " "" ~~ 11. CONSTITUENTS OF CONCERN:~ A. TOTAL HALOGEN CONTENT (ORGANIC & INORGANIC) < 17______, 1-107._______, >107______ ** B. NON-HALOGENATED ORGANICS: '17______, 1-107______ , : 107 C. FCB'S: <50 PPM_____ , >50 PPM______ _____ _ _ _____ _____ D. FREE CHLORINE: PRESENT_____ . ABENT_______ ' "_Z Z-ZZZZ E. SAND, DIRT, DEBRIS <17______, 1-107______ , >107____ F. WATER: <17_____ , 1-107______, >107____ "__ "_ZZ ~ ~ ____ G. OTHER: (SPECIFY)Z__ Z____ ANALYSIS REQUIRED FDR EPA HAZARDOUS WASTES GENERATED OUTSIDE LOUISIANA DIVISION. SEE ITEM 24 FOR SUPPLYING THIS INFORMATION. 1 1. CONSTITUENTS OF CONCERN (CONTINUED) PROCESS KNOWLEDGE ANALYSIS > H. SULFUR: <0.77._____ , 0.7-10*/.______ , >107.______ ____________ *________ * > I. LEAD: <100 PPM_____ , >100 PPM______ "__ "___ > J. MERCURY: <100 PPM_____ , >100 PPM______ K. NITROGEN: <17._____ 1-107._________, > 107 ~____ __ _______ ZZ_ZZ_ZZ 12. EF TOXIC? YE5_____ /NO____ 13. REACTIVITY:Z ______ Z_______________ _______ ZZ_Z~_Z" 14. PHYSICAL STATE (AT~70~DEG F.>" LIOUID_____ SOLID_______SLUDGE_____ SLURRY____ SINGLE PHASE_____ MULTI-PHASE" OIL/WATER____ 15. F'UMPABLE AT 70 DEG F. 16. HEAT OF COMBUSTION (BTU/LbT: <5000. 5000-15000____, >15000_ _ ~~ _ ____* _____ ____ * 17. EXPLOSION/FIRE HAZARD: IB. FERSONAL HANDLING EXPOSURE/PRECAUTIONS: 19. HOW CONIAI NED NQW:_ 20. REQUIRED PACKAGING: 21. VOLUME OF WASTE MATERIAL (IN POUNDS): INVENTORY:________ _____ _____ PER YEAR:__ 22. MATERIAL COMPATIBILITY: ______ _____ 23. ANNUAL REVIEW DATE/INITIAL: ______________ __ /________________________ /_________________________ _____________ /__ __ _____________ / _ _ ____ / / ANALYSIS REOUIRED FOR ERA HAZARDOUS WASTES GENERATED OUTSIDE LOUISIANA DIVISION. SEE ITEM 24 FOR SUPPLYING THIS INFORMATION. SOURCE PLANT SUPERINTENDENT DATE ENVIRONMENTAL OPERATIONS SUPERINTENDENT DATE (DISPOSAL METHOD DO 143791 CONFIDENTIAL ENVIRONMENTAL dperaiions waste characterization summary ANNUAL ANALYSIS UPDATE >24. ANALYTICAL INFORMATION (REQUIRED FOR EPA HAZARDOUS WASTES GENERATED OUTSIDE LOUISIANA DIVISION) TEST TO BE REPEATED ANNUALLY FOR ITEMS A & E. ITEMS B, C & D TO BE REPEATED ONLY IF PROCESS CHANGE OCCURS THAT WOULD RESULT IN SULFUR, LEAD, AND MERCURY BEING PRESENT. ANY PROCESS CHANGE RESULTING IN' A CHANGE IN WASTE CHARACTERISTICS REQUIRES A NEW COMPLETED WASTE CHARACTERIZATION SUMMARY TO BE SUBMITTED. TEST METHOD RESULT A. TOTAL HALOGEN CONTENT (WT 7. AS CHLORIDE) B. SULFUR CONCENTRATION (WT V.) C. LEAD CONCENTRATION (WT 7.) D. MERCURY CONCENTRATION (WT /.: E. Hr!.' (&TU/S) F. F'ROCESS CHANGE WITHIN 12 MONTHS THAT WOUuD CHANGE WASTE CHARACTERISTICS WITH REGARD TO SULFUR, MERCURY, AND LEAD? YES____________ NO____________ IF 'NO", REPEAT OF ANALYSIS FOR SU--FUR, MERCURY AND LEAD NOT REQUIRED. I CERTIFY THAT THE INFORMATION IN THIS SECTION IS TRUE, ACCURATE AND COMPLETE. SIGNATURE AND TITLE DATE DO 143792 CONFIDENTIAL WASTE ANALYSIS METHODS I. HEAT OF COMBUSTION - Oxygen Bomb Calorimeter ASTM D 240-76 ASTM D 2015 II. * TOTAL HALOGENS - By Oxygen Bomb Combustion/ ^0407 B Mercuric Nitrate or equivalent. Ill. LEAD AND MERCURY - Oxygen Bomb Combustion/ Total Metals: Digested Lead - Inductively Coupled Plasma EPA Method 200.7 *AA direct Aspiration EPA 239.1 Furnace EPA Method 239.2 Mercury - Cold Vapor EPA Method 245.1 or 245.2. IV. SULFUR - Oxygen Bomb Combustion/ I426C Turbidmetric Method or Equivalent. 1 Standard methods for the examination of water and wastewater 15th edition. * EPA 600-4-79-020 Methods for chemical analysis of water and waste. D0 143793 CONFIDENTIAL SUMMARY OF METHODS After ignition of the boob, the contents are vented into a beaker containing 300 ml. of 21 Na2C0^ with a teflon tube. The contents of the bomb are inspected for complete com-, bustion of the sample. The BTU determination is made on this sample with two exceptions to the specified ASTM procedures: (1) No correction for heat of formation ofj nitric acid, (2) No correction for heat of formation ofi sulfuric acid. Total organic halogens, surfuric and metal analysis uti lizing an oxygen bomb combustion calarimeter require that the sample be totally combusted. This may require the addi tion of an auxiliary fuel to ensure complete combustion (diesel oil or white oil). A blank analysis will be necessary to subtract for possible interferences contributed from the auxiliary fuel and Na^Oj. The 300 ml. of bomb scrubber water from the complete com bustion sample is used to rinse the bomb cylinder and cup. Transfer 50 ml. to a 250 ml. volumetric flask and dilute with DI water. Aliquots from this sample are to be use^l for I total organic halogen content expressed as chloride. Both organic and inorganic halogenated compounds in the waste are de termined . For lead and mercury analysis scrubber water to a container 1:1 HNO3. Acidify the sample Consult methods specified for transfer 200 ml. of bomb that has been pre-rinsed with HNO3 to a pH < 2. digestion and analysis. with Sulfur analysis is performed on the remaining 50 ml. of bomb scrubber solution. The turbidmetric method is based on the principle that sulfate ion in an HC1 medium with BaCl2 with form BaSOi* crystals of uniform size. A spectrophotometer is used to measure absorbance of the BaSOi* crystals. The sample may require filtration prior to acidification with HC1 if color or suspended matter is present in large amounts. DO 143794 CONFIDENTIAL