Document ymk6VdDBXK9Gk10bVxDDDwOmE

RSinS BOOK N? 1270 PIGMENT, COLOR & CHEMICAL DIVISION Th e Sh er w in - Wil l iams Co mpan y CHICAGO, CLEVELAND, NEW YORK, OAKLAND 0007-PMC-000000732 PIGMENT, COLOR & CHEMICAL DIVISION Th e Sh er w in - Wil l iams Co mpan y 300 WEST LAKE STREET, CHICAGO 6, ILL. 101 PROSPECT AVENUE, CLEVELAND 1, OHIO 100 PARK AVENUE, NEW YORK 17, N. Y. 1450 SHERWIN AVENUE, OAKLAND 8, CALIFT 655 BEACON STREET, BOSTON 15, MASS. 616 MAIN STREET, CINCINNATI 2, OHIO 2036 WOODWARD AVENUE, DETROIT 26, MICH. 4110 SO. MAIN STREET, HOUSTON, TEXAS 363 SO. MISSION ROAD, LOS ANGELES 33, CALIF. 325 NO. BROAD STREET, PHILADELPHIA 7, PA. 515 SPRUCE STREET, SAINT LOUIS 2, MO. EXPORT OFFICE -- 100 PARK AVE., NEW YORK 17, N. Y. Copyright 1953 0007-PMC-000000733 ^oreu/oriJ When the Sherwin-Williams Company first started production of alkyd resins--some twenty-five years ago--an alkyd was an expensive novelty which produced a hard tough film provided you were able to apply the finish by spraying. A brushing alkyd was unknown. During the ensuing years the outstanding characteristics which can be obtained from alkyd resins have been recognized and through constant development work the technologists of the paint industry have adapted alkyds to more and more finishes until a majority of the protective coat ings produced in this country contain some form of alkyd. Furthermore, all indications point to an even larger use in the future. It has been possible for such a major change to take place in a large industry in so short a time, only because the suppliers and consumers have worked together closely and in complete harmony. The Sherwin-Williams Company is proud of the part that its tech nologists have played in the utilization of alkyd resins. We recall the con tributions which we made to the development of brushing type alkyds with the through drying characteristics required for finishes of this type. This one development contributed greatly to the advancement of alkyds since it opened up the entire field of architectural enamels and shelf goods. Other contributions, which have not been as spectactular, have--year in and year out--helped make better finishes for more and more different applications." ' To our customers who have served so well as friendly critics and collaborators we offer our deep appreciation. It is our aim to serve you in the future to the utmost of our ability. 0007-PMC-000000734 This resin handbook is being prepared in a transition period--which has followed a period of shortages and restrictions and, we hope, precedes a period of abundant supply. We aim to present this handbook in the spirit of this transition period--the spirit of integrating the technological achievements of the past and looking forward to the out standing developments which will come in the future. In presenting the resins, an attempt has been made to list and discuss them in such manner that information can be found easily. The resins have been described in detail, two pages being devoted to each item. In addition they are listed in specification and usage charts where the characteristics can be readily compared and vehicle selection ac cording to use can be made. While the items listed are the most popular forms in each case, where variations are available, the parallel numbers are indicated by means of references in the individual writeups. RESIN CLASSIFICATION The method of numbering our resins has been so designed that the letter prefixes give an indication of either the general formulation class or usage type of the resin. The description of each classification is given on the index page preceeding that class. Throughout the definitions of these individual classes, the term "alkyd" is taken to mean the oil modified versions of the general class of polymers formed by the reaction of polybasic acids and polyhydric alcohols. DEFINITION OF SPECIFICATIONS Non-Volatile The term "Non-Volatile" refers to the total non-volatile content given as percent by weight based on the total weight of the resin solution. Volatile The term "Volatile" refers to the solvent content expressed as percent by weight based on the total weight of the resin solution. Weight Per Gallon The "Weight Per Gallon" standards have been established and are accurately con trolled by conventional hydrometer measurements made at 77 F. 0007-PMC-000000735 (n Viscosity The "Viscosity" standards were established and are accurately maintained by Gardner-Holdt standard viscosity tubes at 77 F. Acid Value The term "Acid Value" may be defined as the number of milligrams of potassium hydroxide required to neutralize one gram of the non-volatile content of the resin solution. Color Gardner Color Standards of 1933 are the basis of standard "Color" characteristics. Oil Content The "Oil Content" is given as percent by weight of oil based on the total weight of non-volatile. Phthalic Anhydride Content The "Phthalic Anhydride Content" is given as percent by weight based on the total weight of non-volatile. Type of Oil The "Type of Oil" refers to the major oil component. DRYING TERMINOLOGY Drier Recommendations Recommended percentages of "Driers" are given as percent metal based on non volatile. Set A film is said to be "Set" when gende pressure of the finger shows a tacky condition but none of the coating adheres to the finger. Dried Hard A film is said to be "Dried Hard" when maximum pressure exerted between thumb and finger (without twisting) does not move the film nor leave a mark which remains nodceable after the film is lighdy polished. The information contained in this book is believed to be true and accurate; however, all recom mendations are made without guarantee, since the conditions of use are beyond our control. Nothing contained herein shall be construed as a recommendation to violate any patent. 0007-PMC-000000736 DYAL POUNDS PER * NON-VOLATILE GALLON SOLVENT VISCOSITY % NON-VOLATILE GARDNER-1933 AT RESIN MODIFICATION 77* F E-G VISCOSITY XAC 1 XAC 2 XAC 9 PURE OIL MODIFIED ALKYDS - COLOR RETEKTIVE - DRYING 7.57 7.95 50 MINERAL SPIRITS w-x 70 MINERAL SPIRITS V-W 40 58 8.29 50 XYLOL Z-Z2 34 NONE NONE NONE XAC 39 8.22 50 XYLOL u-w 40 NONE XAC 42 7.60 50 MINERAL SPIRITS Z 2~Z4 36 NONE XAC 47 7.96 70 MINERAL SPIRITS z5-z4 50 NONE XAC 48 7.25 30 HI-FLASH MIN. SPTS. u-w 23 NONE XAC 66 8.40 60 XYLOL Zl_Z3 40 NONE XAC 76 XAC 83 XAC 93 XAC 97 XAC 99 XAD 26 XAD 37 XAR7 XAR S XAR 12 XAR 13 XAR 19 XAR 62 XAN 78 8.42 7.97 8.00 7.66 7.58 65 XYLOL Y-Z 70 MINERAL SPIRITS Z-Z2 70 MINERAL SPIRITS Y-Z, 50 MINERAL SPIRITS P-R 50 MINERAL SPIRITS Y-Z 56 51 50 42 40 PURE OIL MODIFIED ALKYDS - NON-COLOR RETENTIVE - DRYING 7.65 7.62 50 MINERAL SPIRITS U-W 50 MINERAL SPIRITS Z 2~Z3 41 36 RESIN MODIFIED ALKYDS 7.73 8.02 7.62 7.70 7.76 7.83 so 32% VM&P 18% XYLOL T-V Nc 1 1N 50 35% XYLOL 15%MIN. SPTS. 50 MINERAL SPIRITS X-Zj 50 VM&P NAPHTHA 55 30% XYLOL 15% VM&P G-l 50 35% XYLOL 15% VM&P T-V PURE OIL MODIFIED ALKYDS - NON-DRYING 38 45 38 35 50 42.6 j 8.35 50 XYLOL U-W 43 NONE NONE NONE NONE NONE NONE NONE PRESENT PHENOLIC PRESENT PRESENT PRESENT PHENOLIC NONE STYRENATED ALKYDS XAS 4 8.04 50 XYLOL O--R 40 NONE XMD 6 XMD 18 XMD 165 7.50 7.40 7.45 MALEIC AND FUMARIC ACID TREATED RESIN SOLUTIONS ` 50 MINERAL SPIRITS R-T 50 15%MIN. SPTS. 35% VM&P Q-S 50 MINERAL ___ SPIRITS____ Q-S OLEORESINOUS VARNISH SOLUTIONS 44 40 42 PRESENT PRESENT PRESENT XOR 31 7.98 50 XYLOL s-w 40 NONE XOR 34 7.98 50 XYLOL T-X 40 NONE PLASTICIZERS XPL 5 XPL 115 8.08 8.20 80 .XYLOL T-V 60 25% XYLOL 15% TOLUOL T-V EMULSION RESINS 65 PRESENT 43 PRESENT XRE 156 8.93 100 NONE SEMI-SOLID 58 NONE r 0007-PMC-000000737 COLOR ACID VALUE (ON N.V.M.) (GorAt-- Holdt) % PHTHAL1C an h y d r id e % OIL (ON N.V.M.) TYPE OF OIL ALIPHATIC SOLVENT TOLERANCE PURE OIL MODIFIED ALKYDS - COLOR RETENTIVE - DRYING 12 5 10 15 10 7 12-18 25-30 3-4 5 3 12 15-20 9 28 58 SOYA-LINSEED INFINITE 9 23 5-7 40 6 38 85 SOYA INFINITE 37.1 DEHYDRATED CASTOR NONE 41 SOYA 400% 9 34 so SOYA INFINITE 7 24 82 . SOYA INFINITE 7 10-11 11 PRESENT 38 35 SHORT 44.7 47 SOYA DEHYDRATED CASTOR SOY A _ INFINITE NONE 200% 7 23 64 SOYA INFINITE 8 23.8 82 SOYA INFINITE 9 35 52 SOYA INFINITE 8-9 30.5 57.5 SOYA 1500% PURE OIL MODIFIED ALKYDS - NON-COLOR RETENTIVE - DRYING 10 10 12 10 33 34.8 52 LINSEED 50.8 LINSEED RESIN MODIFIED ALKYDS INFINITE - 1500% 25-30 20-25 12 12 PRESENT 28 42 CHINA*WOOD 50% 34 LINSEED ' 500% 15 24-30 40-50 10 14 13 14 12 PRESENT 29 PRESENT 29.6 42 DRYING INFINITE 30 DRYING INFINITE 51 CHINA. WOOD 150% 51.7 SOY A. TUNG NONE PURE OIL MODIFIED ALKYDS - NON-DRYING 57 42.2 33 COCONUT STYRENATED ALKYDS NONE 15-20 8 PRESENT 32 DRYING 200% MALEIC AND FUMARIC TREATED RESIN SOLUTIONS 20-25 20-25 10-20 9 11-12 11 46 3t NONE 47.5 SOYA NONE _ 47.2 SOYA NONE 54 DRYING OLEORESINOUS VARNISH SOLUTIONS NONE -- -- NONE -- -- PLASTICIZERS 1500% 1500% INFINITE POOR POOR 7 20--30 6 12 NONE NONE 88 CASTOR 48 CASTOR EMULSION RESINS POOR POOR 5 9 PRESENT LONG SOYA INFINITE DYAL XAC 1 XAC 2 XAC 9 XAC 39 XAC 42 XAC 47 XAC 48 XAC 66 XAC 76 XAC 83 XAC 93 XAC 97 XAC 99 XAD 28 XAD 37 XAR 7 XAR 8 XAR 12 XAR 13 XAR 19 XAR 62 XAN 78 XAS 4 XMD6 XMD 18 XMD 165 XOR 31 XOR 34 XPL 5 XPL 115 XRE 156 0007-PMC-00000073 8 AMINE PL ANTI-RUS APPLIAN APPLIANC I ARCHITE 1ARCHITE i ARCHITE [ ARCHITE I ARCHITE 1AUTOMOT [ AUTOMOT | AUTOMOT BULLETI 1 1CABINET 1CABINET 1DRUMS I ENAMELS | ENAMELS 1 ENAMELS | ENAMEL I ENAMELS I ENAMEL | EMULSIO I ENGINE </> cl % r XAC 1 SSSS S P ps S S S S XAC 2 PP p XAC 9 P S P S SSS SSSsS XAC 39 S S $ S PPS PPPpPP S XAC 42 $$S S$ $$ P$ S sSS P XAC 47 PP S p XAC 48 P PP XAC 66 S P P SS ss XAC 76 S P S P s sS S s s S XAC 83 P P P p XAC 93 PP P p XAC 97 $ XAC 99 $ SSS ssS S s$$SsS s $sS$S sss sss s XAD 26 Sp S s s s s XAD 37. S PsS ss p XAN 78 P P s XAR 7 S s S Ss s s s PPPpp s XAR 8 XAR 12 XAR 13 ss Ps p PPPpp s P$ p$PSSs$ $ s P p P$$s$ $ $ XAR 19 XAR 62 Ss XAS 4 s s pps ss s s XMD 6 $ $ s $ $ $$ $ $ XMD 18 XMD 165 $s $ $$ $ $ XOR 31 P s s p pp XOR 34 P s s p pp XPL 5 s XPL 115 p XRE 156 P P-PREFERRED RESIN S-SUITABLE RESIN . S-LOW COST RESIN 0007-PMC-000000739 FARM MACHINERY FURNITURE CLEARS 1FURNITURE ENAMELS-METAL | FURNITURE ENAMELS-WOOD | GRINDING VEHICLES ! HAMMER FINISHES. I HOUSEHOLD ENAMELS I LACQUER MODIFIERS 1 LACQUER PLASTICIZERS 1 MARINE FINISHES I PAINTS - TRIM & TRELLIS 1 PUMP ENAfcELS 1 RAILWAY CAR FINISHES ! SIGNS-METAL I SIGNS - WOOD I SYNDICATE ENAMELS 1 TANK CAR FINISHES | TIN DECORATING I TOY ENAMELS | TRUCK FINISHES | VENETIAN BLIND ENAMELS | WASH MACHINE ENAMELS I WRINKLE FINISHES | ZONE MARKING PAINTS D Y A L SSSS S SSS S PSS PPPS S SS P S SSSS SSS S SSS S S P PS PS S Ss PS PSS PS $ S PpsSS S S SS P PPS p S S S P P S S S S SP S PS s ss S SSS , i' S SSS s PPSp S P Ss s PPSs S Ssss p S sS s S P P' Ssss S sS s SP S Ss S S Pps s s Pp s S s sP P PP P Sss s Sss P ps P sss sP $ ss $$$$ $ $$$$ S$ $$ $$$$ $$ $$s $ P s ssss S p ssss P s sss sss $$$$ s$ $ s P$ $ $$ P PP s PP P PP XAC 1 XAC 2 XAC 9 XAC 39 XAC 42 XAC 47 XAC 48 XAC 66 XAC 76 XAC 83 XAC 93 XAC 97 XAC 99 XAD 26 XAD 37 XAN 78 XAR 7 XAR 8 XAR 12 XAR 13 XAR 19 XAR 62 XAS 4 XMD 6 XMD 18 XMD 165 XOR 31 XOR 34 XPL 5 XPL 115 XRE 156 P-PREFERRED RESIN S-SUITABLE RESIN S-LOW COST RESIN U S A G E C H A R T 0007-PMC-000000740 Sherwin-Williams Dyal resins. 0007-PMC-000000741 *r A-.. 1 5 n DYAL XAC The DYAL XAC resins are pure oil modified alkyd resins that are of the drying type and are color retentive. 0007-PMC-000000742 XAC ft A view of a modern solvent tank farm at one of the Sherwin-Williams' alkyd producing units. A capacity of 300,000 gallons stored safely and efficiently assures an adequate supply to meet the needs of volume production of alkyd resins. 0007-PMC-000000743 TYPE: Medium Length Oil Modified Alkyd OUTSTANDING FEATURES: Fast Dry -- Versatility DYAL XAC-1 Dyal XAC-1 is outstanding in its versatility. It may be used to obtain maximum perform ance in a large variety of high quality finishes including both air drying and low temper ature baking types. Trade sales finishes made with Dyal XAC-1 apply easily by brushing and set up to give films that dry hard and are print resistant in a matter of only 4 to 6 hours. Industrial finishes made with this resin can be applied by brush, spray or dip. Dyal XAC-1 will give excellent performance when used as a vehicle for the following usages: 1. Architectural Shelf Goods Household White and Colored Enamels Painter Maintenance Finishes 2. Industrial Finishes Dairy Maintenance Enamels Implement Finishes Machine Enamels Toy Enamels Furniture Clears Dyal XAC-1 is suitable for either ball or roller mill grinding. Dispersion of a wide range of pigments may be accomplished without difficulty. It is recommended that pastes ground in Dyal XAC-1 be let down soon after grinding rather than be stored for any considerable length of time. Finishes made with Dyal XAC-1 will have excellent package stability when handled in this manner. In low pigment concentration it is advisable to use one or two pounds of aluminum stear ate per hundred gallons of enamel to control flow and insure pigment suspension. SPECIFICATIONS Non Volatile-----------------------------------50% Color (max.)9 Volatile-----------------------------------50% M.S. Acid Value12 Lbs. per gal.7.57 Phthalic Anhydride28% ViscosityW-X Oil58% Aliphatic Solv. Tol-------------------- Infinite Type Oil---------------------------- Soya, Linseed Solids at E to G Vis.40% Resin ModifiersNone 0007-PMC-000000744 FILM AND PERFORMANCE PROPERTIES Color Color Retention Gloss Gloss Retention Type of Film excellent good excellent excellent hard, tough, flexible Resistance to: Abrasion Acids Alkali Oil & Gasoline Water Weather good good good excellent excellent excellent Compatibility with: Pigments Nitrocellulose [long Alkyds I medium [ short f long Varnish 1 medium 1 short Oils Bodied Oils good none excellent excellent fair excellent excellent good excellent good DRYING AND DRIER RECOMMENDATIONS Air Dry--Set Air Dry--Hard Bake 45 min. 6 hours 250F. for 60 min. Air Dry Lead .3 to .6% Manganese none Cobalt .03% to .06% Calcium* 3% to .6% Zinc none to replace lead Bake none none .02% 3% 01% SUGGESTED FORMULATIONS Four Hour Gloss Red Enamel Lbs. Gals. 90 7.7 Toludine Red 90 Hi* Dyal XAC-1 418 55.0 Dyal XAC-1 146 22.3 Mineral Spirits 21 3.0 Dipentine 15 1.5 24% Pb Naphthenate 8 1.0 6% Co Naphthenate 1 0.1 Anti Skin Agent 789 102.5 Cream Industrial Maintenance Enamel Lbs. Gals. 190 5.5 Rutile Ti 02#* 15 0.3 Med. Chrome Yellow 154 20.3 Dyal XAC-1 479 63.2 Dyal XAC-1 85 11.5 Mineral Spirits 12 1.5 24% Pb Naphthenate 3 0.4 6% Co Naphthenate 1 0.1 Anti Skin Agent 939 103.0 Roller Mill Grind for 6 to 7 Hegman Lbs. per gal. -- 7.68 Viscosity -- 70 to 72 K. U. Set -- 60 min. Hard -- 4 hours **0. A. 17-19 Viscosity No. 4 Ford Cup -- 97 to 107 Lbs. per gal. -- 9.03 Brushing -- Reduce with Kerosene 5% Spray -- Reduce with VM&P 15 to 25% 5-53 0007-PMC-000000745 DYAL XAC-2 TYPE: Long Soya Oil Modified Alkyd OUTSTANDING FEATURES: Low Viscosity, High Oil Content, Compatibility Dyal XAC-2 is a long oil soya modified pentaerythritol alkyd characterized by excellent drying, excellent application properties and having excellent durability. Fine quality architectural finishes may be formulated using Dyal XAC-2 as the sole vehicle. With its high oil content, Dyal XAC-2 is more suitable for use in high vehicle solids for mulations than other resins generally recommended for architectural enamels such as Dyal XAC-47 and Dyal XAC-83. Dyal XAC-2 will reduce faster than the other two alkyds be cause of its lower initial viscosity. The initial color of Dyal XAC-2 is slightly darker than the color of either Dyal XAC-47 or Dyal XAC-83. However, because of the inherent exceptional brushing properties of this alkyd along with its extremely good compatibility, Dyal XAC-2 can be combined with shorter alkyds such as Dyal XAC-99 and Dyal XAC-1 to improve the application character istics of high quality trade sales and industrial finishes of the following types: 1. Trade Sales Shelf Goods Architectural White Enamels Tinting Colors One Coat Gloss and Semi-Gloss Enamels Trim and Trellis Paints 2. Industrial Finishes Mill 'Whites Metal Furniture Finishes Maintenance Finishes Dispersion of most pigments in Dyal XAC-2 requires no special procedure or precautions since this vehicle wets pigments well and forms stable pigment bases which can be let down with little difficulty. .. SPECIFICATIONS Non Volatile70% Volatile30% M.S. Lbs. per gal7.95 Viscosity V - W Aliphatic Solv. Tol---------------------.Infinite Solids at E to G Vis58% Color (max.) ..................... 9 Add Value _____________________ 5 Phthalic Anhydride23% Oil-------------------------------------------------- 65% Type Oil -------------------------------- Soya Resin Modifiers .None 0007-PMC-000000746 FILM AND PERFORMANCE PROPERTIES Color Color Retention Gloss Gloss Retention Type of Film good excellent good good tough, flexible Resistance to: Abrasion Acids Alkali Oil & Gasoline Water Weather fair good good excellent good excellent Compatibility with: Pigments Nitrocellulose f long Alkyds 1 medium [ short [long Varnish [ medium [ short Oils Bodied Oils _ excellent none excellent excellent poor excellent excellent poor good good DRYING AND DRIER RECOMMENDATIONS Air Dry--Set Air Dry--Hard Bake 254 hours 10 to 12 hours not recommended Air Dry 'Lead 03% to 0.6% for colors Manganese none Cobalt 0.03% to 0.06% Calcium* 0.3% to 0.6% Zinc none to replace lead in whites SUGGESTED FORMULATIONS White Architectural Gloss Enamel Lbs. Gals. 250 7.2 Rutile N. C. Ti 0; 28 0.6 Zinc Oxide 3 03 Aluminum Stearate 160 20.0 Dyal XAC-2 455 57.0 Dyal XAC-2 26 4.0 Water White Kerosene 79 12.0 Mineral Spirits 6 0.8 6% Co Naphthcnate 7 1.0 Anti Skin Agent (20%) 1014 102.9 Grind -- 6 to 7 Hcgman -- Roll Mill Viscosity -- 69 to 72 K. U. Gloss -- 87 to 92 Photocell Dry -- 8 to 12 hours White Semi-Gloss Enamel Lbs. Gals. 175 5.0 Rutile N. C. Ti O, 372 13.7 Ti Cal Rutile. N. C. 4 Soya Lecithin 2 Aluminum Stearate 192 25.1 Dyal XAC-2 268 35.4 Dyal XAC-99 130 20.0 Hi Flash M. S. 16 2.0 4% Calcium Octoate 3 0.4 6% Co Naphthenate 7 1.0 Anti Skin Agent (20%) 1170 102.6 Grind -- 6 to 7 Hegman -- Roll Mill Viscosity -- 72 to 74 K. U. Gloss -- 68 to 79 Photocell Dry -- 4 to 6 hours B-SS 0007-PMC-000000747 DYAL XAC-4 TYPE: Medium Length Color Retentive Baking Alkyd OUTSAN DING FEATURES: Cost, Color Retention, Fast Baking Schedule, Hardness XAC-4 is an inexpensive medium length alkyd designed for formulating baking finishes. One of the outstanding features of XAC-4 is color retention. Protective coatings formu lated from XAC-4 will show less yellowing on aging than most color retentive alkyds. XAC-4 may be used with XRU-1 to formulate economy priced baking enamels. These amine resin modified enamels will have fast baking schedules and give hard films. The compatibility of XAC-4 is another important feature. Mixing varnishes such as XMD-1 may be used with XAC-4 to formulate low cost baking finishes. As an example, the formulation listed on the reverse side of the XMD-1 sheet will bake in from 10 to 20 minutes at from 280' F. to 300 F. The resultant film will be hard and tough and have good flexibility. We recommend the use of XAC-4 for formulating the following types of protective coatings: 1. Metal Cabinet Enamels 2. Farm Machinery 3. Venetian Blinds 4. Fluorescent Light Fixtures 5. Hardware Enamels 6. Metal Furniture Enamels PHYSICAL CHARACTERISTICS Non Volatile .......................................50% Volatile.................... 50% Mineral Spirits Pounds per Gallon................................7.53 Viscosity..................................................X-Z Aliphatic Solv. Tol........................... Infinite Solids at E. to G. Viscosity.................39% Color............................................... 9 Max. Acid Value....................................10 Max. Phthalic Anhydride ...........................29% Type of Oil.........Color Retentive Drying Resin Modifiers............................... .None 0007-PMC-000000748 FILM AND PERFORMANCE PROPERTIES Color ....-....................... Color Retention............. Gloss ............................... Gloss Retention.............. Type of Film.................... Resistance to: Abrasion ................ Acids ....................... Alkali....................... Oil and Gasoline.. Water....................... Weather.................. Pigment Wetting and Dispersing Properties .. .. .Excellent Compatibility with: Long Alkyds ................ Medium Alkyds........... Short Alkyds................ Long Varnishes ........... Medium Varnishes . .. ........... Good Short Varnishes ......... ........... Good Oils ............................... ............. Fair Bodied Oils.................. ............. Poor BAKING AND DRIER RECOMMENDATIONS Baking Schedule: Twenty minutes at 300 F. using 0.5% lead, 0.05% cobalt and 0.05% manganesemetal based on resin solids. With amine resin modification, the time and temperature of bake will vary with the degree of modification. An example would be 30 minutes at 300 F. for 30% urea resin modification. Sandstone Brown Baking Enamel Lbs. Gals. Material 165 4.75 Ti02 Rutile R-610 571/2 1.7 Ferrite Yellow, Lt. Lem. 31/2 .08 Red Oxide, R3098 3 .3 Soya Lecithin 250 33.0 Dyal XAC-4 711/, 11.0 Mineral Spirits Ball Mill to 7H 324 43.0 Dyal XAC-4 1.9 Lead Naphthenate 10% 1 1.0 Manganese Naph. 2% 1 1.0 Cobalt Napth. 2% 40 5-4 Solvesso 150 ? -- Dispersed Black 943 103.13 Viscosity...................... 42" #4 Ford Cup Lbs. per Gal........................................... 9.10 Grind 7H...................................... Ball Mill NVM ................................................... 55% Bake....................................18' @ 300 F. Cherry Blossom Pink Baking Enamel Lbs. Gals. Material 227 6.5 31 0.8 2 0.2 189 25.2 8 1.1 283 37.7 174 20.5 41/2 0.6 9% 1.3 60 8.3 988.0 102.2 Ti02 Rutile R-110 Cad. Lithopone, Med. Red Soya Lecithin Dyal XAC-4 Pine Oil Dyal XAC-4 Dyal XRU-1 0.4% DC 200 Siii. Sol'n. Diethylamine Ethanol Xylol Viscosity......... 90-100 sec. #4 Ford Cup Lbs. per Gal............................................ 9.68 Grind 7H....................................Roller Mill Reduction. .20-25% with Xylol for Spray Bake....................................30' @ 300 F. 0000007A9 0007-PMC- ____DYAL XAC-9 TYPE: Short Oil Modified Alkyd OUTSTANDING FEATURES: Hardness, Gloss, Gloss Retention, Adhesion Dyal XAC-9 is a short oil dehydrated castor modified alkyd designed for use with urea or melamine in high quality baking finishes. Finishes made with Dyal XAC-9 and modified with normal amounts of amine resin will exhibit excellent gloss, excellent gloss retention, excellent color and color retention, along with exceptional alkali and acid resistance. Such films are hard, mar proof and adhesive. Dyal XAC-9 may also be used without amine modification and baked or air dried. For most bake applications driers are not required; however, where baking temperatures are below 250 F. it is recommended that small percentages of metallic driers be added. Best results are obtained at higher baking schedules. Excellent force dry and air dry enamels and clears can be made when Dyal XAC-9 is blended with hard maleic resins. A blend of two or three parts of Dyal XAC-9 with one part of maleic ester cut in xylol can be used to formulate fast and hard air drying enamels and clears at moderate cost. Suggested applications for Dyal XAC-9 are the following: 1. Refrigerator Enamels 2. Refrigerator Primers 3. Appliance White and Colored Finishes Cabinets Light Reflectors Venetian Blinds 4. Furniture Finishes Air Dry Clear Finishes Low Bake and Force Dry Clear Finishes Metal Furniture Enamels Aromatic solvents are recommended for reduction of finishes made with Dyal XAC-9. Small amounts of normal butanol or anhydrous ethanol may be used for viscosity control without appreciably decreasing the resin solid content. SPECIFICATIONS Non Volatile____________ ------------- 50% Volatile__________________ --50% Xylol Lbs. per gal______________ _________ 8.29 Viscosity ________________ ________Z-Z2 Aliphatic Solv. Tol.______ ________None Solids at E to G Vis______ ------------- 34% Color (max.) 7 Acid Value10 Phthalic Anhydride______ .40% Oil37.1% Type Oil------------------Dehydrated Castor Resin Modifiers _____None * 0007-PMC-000000750 FILM AND PERFORMANCE PROPERTIES Color Color Retention Gloss Gloss Retention Type of Film excellent excellent excellent excellent tough, hard, flexible Compatibility with: Pigments Nitrocellulose long Alkyds J medium t short Resistance to: Abrasion Acids Alkali Oil & Gasoline Water Weather excellent good good good excellent good f long V arnish -{ medium i short Oils Bodied Oils excellent good poor fair fair poor fair fair poor poor DRYING AND DRIER RECOMMENDATIONS Air Dry--Set Air Dry--Hard Bake 30 min. 4 to 5 hours 250F. to 425 F. 45 min. to 45 sec. Air Dry Bake** Lead 0.2% to 0.4% none Manganese none none Cobalt 0.02% to 0.04% 0.02% to 0.04% Calcium* 0.3% to 0.5% none Zinc none *to replace lead **use metallic driers only when urea or melamine is absent SUGGESTED FORMULATIONS White Baking Appliance Enamel With Urea Lbs. Gals. 300 8.5 Rutile Ti 02*** 168 20.0 Dyal XAC-9 297 36.0 Dyal XAC-9 252 30.0 Urea Formaldehyde Solu tion (50%) 65 9.0 Toluol 1082 103.5 ***Oil Absorption -- 17 to 18 Viscosity No. 4 Ford Cup -- (Reduced 25% Xylol) -- 27" to 32" Lbs. per gal. -- 10.5 Spray -- Reduce with Xylol 25 to 30% Hardness (Pencil) -- 2H Air Dry Industrial White Enamel Lbs. 175.0 Gals. 7.9 Rutile Ti 02**** 3.0 0.3 Soya Lecithin 2.0 0.2 Aluminum Stearate 199.0 24.0 Dyal XAC-9 382.0 129.0 43.2 2.9 1.2 1.4 46.0 Dyal XAC-9 18.0 Xylol 6.0 High Solvency Naphtha 0.3 Pb Naphthenate 24% 0.15 6% Co Naphthenate 0.20 Anti Skin Agent 1038.7 103.05 ****Oil Absorption -- 17 to 18 Viscosity No. 4 Ford Cup -- (Reduced 25% Xylol) -- 90 sec. Lbs. per gal. -- 10 Spray (Reduce with Xylol) 25% Gloss -- Photocell -- 93 to 95 Dry -- Set -- 30 min. Hard -- 4 to 5 hours 8-93 0007-PMC-000000751 TYPE: Short Oil Modified Alkyd OUTSTANDING FEATURES: Color, Color Retention, Fast Cure DYAL XAC-39 This vehicle is designed for industrial applications where hard, mar-resistant finishes are desired. Dyal XAC-39 is very pale in color, very color retentive and its gloss and gloss re tention are outstanding under most exposure conditions. It may be used for air-drying finishes or for very fast baking finishes with, or without, urea or melamine. Dyal XAC-39 finishes will "set" and air dry very rapidly or bake in short cycles at low temperatures giving hard, flexible, durable films. It may also be employed in the production of nitrocellulose lacquers to which it will impart excellent gloss, color re tention, durability and adhesion. The excellent properties of Dyal XAC-39 have established it as one of the best available resins for the production of white and light-colored industrial finishes. Some of the sug gested applications are: 1. Appliance Finishes Venetian Blinds Furniture Cabinets Toys Refrigerators 2. Maintenance Enamels 3. Anti-Rust Primers 4. Nitrocellulose Lacquer Plasticizer Dyal XAC-39 possesses excellent compatibility with pigments along with such grinding properties as good pigment wetting and mill stability. To insure best gloss and stability it is recommended that grind bases made with Dyal XAC-39 be let-down shortly after com pletion of the grind. SPECIFICATIONS Non Volatile----------------------------------- 50% Volatile---------------------------------50% Xylol Lbs. per gal--------------------------------------8.22 Viscosity-------------------------------------- U-W Aliphatic Solv. Tol------------------------- 400% Solids at E to G Vis------------------------- 40% Color (max.)6 Acid Value10-20 Phthalic Anhydride________ 38% Oil41% Type OilSoya Resin Modifiers None 0007-PMC-000000752 FILM AND PERFORMANCE PROPERTIES Color Color Retention Gloss Gloss Retention Type of Film excellent excellent excellent excellent hard, flexible Resistance to: Abrasion Acids Alkali Oil & Gasoline Water Weather excellent good good good excellent good Compatibility with: Pigments Nitrocellulose Alkyds f long ) medium \ short f long Varnish 4 medium 1 short Oils Bodied Oils excellent excellent poor fair g0ood poor poor fair poor poor DRYING AND DRIER RECOMMENDATIONS Air Dry--Set 15 min. Air Dry--Hard 4 to 5 hours Bake -- No Urea or Melamine 25 to 50 min. at 250 to 275F. 10% to 30% Melamine 15 to 45 min. at 250 to 275 F. 10% to 20% Urea 5 to 45 min. at 300 to 325 F. Lead Manganese Cobalt Calcium Zinc Air Dry none Bake (without Amine) none none none 0.03% to 0.07% 0.2% to 0.4% 0.01% to 0.02% none none 0.1% SUGGESTED FORMULATIONS White Cabinet Enamel Lbs. Gals. 275 8.6 Anatase Ti O. 160 20.0 Dyal XAC-39 15 2.0 Pine Oil 296 111 36 134 7.7 37.0 13.0 5.0 18.0 1.0 Dyal XAC-39 Melamine Sol'n.** Xylol Naphtha*** Ethyl Alcohol 1034.7 104.6 Viscosity -- 20% Reduction Xylol -- No. 4 Ford Cup 17" Spray -- Reduce with Xylol 15 to 20% Bake -- 15 min. at 300F. **50% NVM ***K. B. -- 40 to 54 Blue Toy Enamel Lbs. Gals. 40 3.2 Solfast Sky Blue CP1037 10 0.3 Ti 02 Rutile 164 20.0 Dyal XAC-39 7 1.0 Pine Oil 502 61.0 Dyal XAC-39 '9 58 4 53 1.0 6% Co Naphthenate 8.0 Xylol0.5 8% Zn Naphthenate 8.5 VM&P Naphtha 847 103.5 Wt. per gal. -- 8.20 Ball Mill -- 8 to 12 hours for 6 Hegman grind Bake -- 25 min. at 275 F. 5*53 0007-PMC-000000753 DYAL XAC-42 TYPE: Medium Oil Modified Alkyd OUTSTANDING FEATURES: Hi Viscosity, Color Retention, Gloss, Gloss Retention Dyal XAC-42 is a medium length soya oil modified alkyd that was developed for applica tions where maximum utility at the lowest possible cost is the prime consideration. The high viscosity of Dyal XAC-42 enables the formulator to use only a minimum of vehicle solids and still obtain an enamel with normal package consistency. Dyal XAC-42 may be used with normal amounts of driers for both air dry and bake appli cation or with urea and melamine for baking to obtain additional hardness. Dyal XAC-42 has exceptionally good color retention; therefore, it can be used in white and colored en amels. This alkyd is of appropriate oil length to give maximum through drying and ex hibits exceptional gloss and gloss retention in gloss enamel formulations. Dyal XAC-42 will permit very heavy pigment loadings; therefore, it is possible to formulate semi-gloss or flat finishes of maximum film uniformity which may be applied by spraying or brushing. A few suggested uses for Dyal XAC-42 are as follows: 1. Industrial Finishes Farm Implement Enamels (Brush, Spray or Dip) Freight and Passenger Car Finishes (Spray or Brush) Hardware Enamels (Spray, Brush or Dip) Metal Furniture Enamels Metal Primers 2. Others Automotive Refinishing Enamels Specification Finishes (Brush, Spray or Dip) Traffic Paints Roller Coat Finishes Dyal XAC-42 has good pigment compatibility and will disperse the most difficult pigments with ease. With one exception no more care than normal is necessary when Dyal XAC-42 is used with reactive pigments. The one exception is Zinc Oxide; therefore, it is recom mended that the amount of Zinc Oxide used does not exceed 25 to 30 pounds per 100 gal lons of finished enamel. SPECIFICATIONS Non Volatile 50% Volatile __50% M. S. Lbs. per gal________________________7.60 Viscosity ....... ........ ,Z2 - Z4 Aliphatic Solv. Tol. ___........ ........ Infinite Solids at E to G Vise______________ 35% Color (max.) ................. 9 Acid Value __________________ .10 Phthalic Anhydride____________ 34% Oil 50% Type il -------------------------------- 1____Soya Resin Modifiers ___________ None 0007-PMC-000000754 FILM AND PERFORMANCE PROPERTIES Color Color Retention Gloss Gloss Retention Type of Film good excellent excellent excellent tough, hard, adhesive Resistance to: Abrasion Acids Alkali Oil & Gasoline Water Weather good good good excellent excellent good Compatibility with: Pigments Nitrocellulose Alkyds [ long < medium short 1 long Varnish -{ medium 1 short Oils Bodied Oils _ good none good good fair good good fair good fair DRYING AND DRIER RECOMMENDATIONS Air Dry--Set Air Dry--Hard Bake 30 min. 6 to 8 hours 1 hour at 275 to 300F. Lead Manganese Cobalt Air Dry .1% to 3% .01% to .03% .02% to .03% Calcium* .2% to .4% Zinc none to replace lead Bake none none .01% to .02% none .1% to 2% SUGGESTED FORMULATIONS Jade Green Maintenance Enamel Lbs. Gals. 20 0.6 Micro Fast Chrome Green 11232 15 0.6 Micro Fast Chrome Green 11235 150 5.5 Titanium Calcium** 4 0.5 Soya Lecithin 150 20.0 Dyal XAC-42 428 54.0 Dyal XAC-42 10 1.0 28% Pb Naphthenate 6 0.6 6% Co Naphthenate 130 20.0 Mineral Spirits 909 102.9 **Oil Absorption 21-22 Wt. per gal. -- 8.75 Roller Mill Grind -- 6 to 7 Hegman Viscosity -- 72 to 74 K. U. Railway Car Zinc Chromate Primer Lbs. Gals. 266 7.4 Iron Oxide 83% Fe2Os 188 6.4 Zinc Chromate 12054 77 32 Magnesium Silicate 5 0.6 Calcium Stearate 209 27.5 Dyal XAC-42 9 0.9 24% Pb Naphthenate 1 0.1 Anti Skin Agent 66 92 Xylol 289 38.0 Dyal XAC-42 5 0.6 6% Mn Naphthenate 5 0.6 6% Co Naphthenate 61 8.5 Xylol 1181 102.0 Ball Mill -- 10 to 12 hours Viscosity -- 70 K. U. at 77F. Recoat -- 6 hours Hard -- 8 hours Wt. per gal. -- 11.55 s-ss 0007-PMC-000000755 DYAL XAC-47 TYPE: Long Oil Modified Alkyd OUTSTANDING FEATURES: Color, Color Retention, Gloss, Gloss Retention Dyal XAC-47 is a long oil modified pentaerythritol alkyd that was developed for use in the highest quality white and colored architectural finishes. The modifying soya oil is present in Dyal XAC-47 in such length as to complement its good application properties with rea sonably fast set and rapid through dry. Enamels made with Dyal XAC-47 possess good "flow" and "leveling" and brush well to give films that will dry hard in four to five hours, showing good print resistance and marproofness. These finishes have excellent initial color, excellent color retention, excellent gloss and excellent gloss retention. Dyal XAC-47 surpasses Dyal XAC-2 and Dyal XAC-83 in gloss retention and is noticeably better than Dyal XAC-2 in initial color and color reten tion. Dyal XAC-47 will also take a greater solvent reduction than Dyal XAC-2 and Dyal XAC-83. Dyal XAC-47. will give the utmost in performance for the following applications: 1. Architectural Enamels High-Hiding Whites Painter Type Enamels Trim and Trellis Enamels Top Quality Four Hour Household Enamels 2. Industrial Quality Maintenance Finishes High-Hiding Mill Whites Structural Primers Railway Car Finishes 3. Others Bulletin and Sign Colors Marine Finishes Lawn Furniture Enamels Cabinets (Wood or Metal) Enamels Zinc oxide may be used with finishes made with Dyal XAC-47. This resin is a very good grinding and pigment dispersion medium and requires no special treatment when used thusly. Small amounts of anti skin agent should be added to finishes made with Dyal XAC-47. Guaiacol is not recommended for use with Dyal XAC-47. SPECIFICATIONS Non Volatile70% Volatile--------------------------------- 30% M. S. Lbs. per gal7.96 ViscosityZ2 to Z4 Aliphatic Solv. TolInfinite Solids at E to G Vis50% Color (max.)7 Acid Value7 Phthalic Anhydride34% Od ------------------------------------------------ 63% Type OU-------------------------------- ;____ Soya Resin ModifiersNone 0007-PMC-000000756 FILM AND PERFORMANCE PROPERTIES Color Color Retention Gloss Gloss Retention Type of Film excellent excellent excellent excellent hard, tough, flexible Resistance to: Abrasion Acids Alkali Oil & Gasoline Water Weather good good good excellent excellent excellent Compatibility with: Pigments Nitrocellulose Alkyds ( long -j medium short 1 long V arnish -J medium 1 short Oils Bodied Oils excellent none excellent excellent good excellent excellent good excellent good DRYING AND DRIER RECOMMENDATIONS Air Dry--Set Air Dry--Hard 60 min. 4 to 5 hours Air Dry Lead 0.3% to 0.6% for colors Manganese none Cobalt 0.05% to 0.07% Calcium* 0.20% to 0.40% Zinc none *to replace lead SUGGESTED FORMULATIONS Architectural White Enamel Lbs. Gals. 252 7.2 Color Retentive Ti-Pure** 28 0.6 Zinc Oxide 3 0.3 Aluminum Stearate 4 0.3 Soya Lechithin 152 19.0 Dyal XAC-47 426 53.5 Dyal XAC-47 37 5.6 Kerosene 92 14.0 Mineral Spirits 6 0.8 6% Co Naphthenate 7 1.0 4% Calcium Naphthenate 1007 1023 **Oil Absorption 17 -- 18 Viscosity No. 4 Ford Cup -- 74" Lbs. per gal. -- 9.82 Gloss -- Photocell -- 90 to 93 Drying -- Hard -- 4 to 5 hours Wet Edge -- over 20 min. Toluidine Red Exterior Enamel Lbs. Gals. 100 8.6 Toluidine Red 10451 46 2.0 Micronized Talc 2 0.2 Soya Lecithin 4 0.4 Calcium Stearate 240 30.0 Dyal XAC-47 280 35.0 Dyal XAC-47 78 10.0 "D" Bodied Linseed Oil 93 15.0 Mineral Spirits 10 1.0 24% Pb Naphthenate 5 0.6 6% Co Naphthenate 2 0.2 Anti Skin Agent 865 103.0 Viscosity No. 4 Ford Cup -- 110" to 130" Lbs. per gal. -- 8.42 Brushing -- Reduce with Kerosene -- 5% Spraying -- Reduce with VM&P -- 15 to 25% Dry -- Set to Touch -- 2% to 3 hours Dry Hard -- 5 to 6 hours S-53 0007-PMC-000000757 ____ DYAL XAC-48 TYPE: Pure Oil Modified Flat Wall Alkyd OUTSTANDING FEATURES: Non Penetration, Uniformity, Color Retention Dyal XAC-48 is a pure oil modified alkyd that was developed specifically for use as a flat wall paint vehicle. This alkyd resin was formulated to combine the desirable properties in herent in alkyds such as washability, durability, and color retention with the non penetrat ing and thixotropic qualities of the calcicoater type of flat wall vehicles. The outstanding feature of this vehicle is its non penetration or hold out over porous sur faces. Flat wall topcoats, primers and sealers made with Dyal XAC-48 show exceptional uniformity over surfaces of variable porosity. Finishes made with Dyal XAC-48 may be applied easily by either brush or roller-coater to give films of smooth and uniform sheen that will flow sufficiendy to prevent "lapping." Flat wall finishes made with Dyal XAC-48 will withstand many more washings than the best of the oleoresinous base finishes. Excellent color retention is assured with the use of Dyal XAC-48 because this vehicle is a soya oil modified alkyd that contains no other modi fying resins. The excellent pigment wetting qualities of Dyal XAC-48 along with its excel lent package stability permit formulation of flat wall topcoats with a wide range of PVC to give any desired sheen. To obtain maximum performance in the formulation of flat wall finishes it is recommended that Dyal XAC-48 be used as the sole vehicle because of its limited compatibility with bodied oils and long oil alkyds and varnishes. SPECIFICATIONS Non Volatile ------------------------------- 30% Volatile_________70% M. S. (Hi Flash) Lbs. per gal------ ----------- 7.25 Viscosity -------------------------------------- U-W Aliphatic Solv. Tol--------------------- Infinite Solids at E to G Vis.----------- --------- 23% Color (max.) ................. 8 Acid Value __________________ ___10-18 Phthalic Anhydride Present Oil Short Type Oil ___ ______________ ________Soya Resin Modifiers ............ ......................None Dyal XAC-48 may be obtained at a higher non volatile content on a special order under the sales assignment of XAC-C40. The specifications for Dyal XAC-C40 are the following: Non Volatile .................... 40% Volatile..... ........ --60% M. S. (Hi Flash) Lbs. per gal__________ 7.5 Viscosity ___________________ Zed- Aliphatic Solv. Tol.................... ..... Infinite Color (max.) 8 Acid Value ____________ __ ______ 10 -18 Phthalic Anhydride _____________ Present Oil ------ Short Type Gil ____ Soya Resin Modifiers ................................. None 0007-PMC-000000758 FILM AND PERFORMANCE PROPERTIES Color Color Retention Gloss Gloss Retention Type of Film good good -- tough, flexible Resistance to: Abrasion Acids Alkali Oil & Gasoline Water Weather fair good good good excellent fair Compatibility with: Pigments Nitrocellulose Alkyds ( long < medium 1 short ( long Varnish 4 medium 1 short Oils Bodied Oils good none poor fair fair poor poor poor poor poor DRYING AND DRIER RECOMMENDATIONS Air Dry--Set Air Dry--Hard 2*4 hours 6 to 8 hours Lead Manganese Cobalt Calcium Zinc Air Dry 0.2% to 0.4% none 0.03% to 0.06% none none SUGGESTED FORMULATIONS One Coat Flat Wall Paint Lbs. Gals. 50 1.4 Rutile Titanium Dioxide 390 14.1 Rutile Titanium Calcium 55 2.5 Celite 5 0.6 Calcium Stearate 290 40.0 Dyal XAC-48 162.0 Anti Skin Agent (20%) 304 42.0 Dyal XAC-48 22 3.0 Hi Flash M. S. 6 0.6 6% Co Naphthenate 1138 104.2 Viscosity -- 85 to 90 K. U. Gloss -- 10 to 15 Photocell (low Eggshell Visual) Dry to Touch -- 2 to 4 hours Wt. per gal. -- 10.7 to 11.0 P. V. C. -- 49% Ti O. per gal. -- 1.54 lbs. Lbs. 148 10 116 537 30 16 5 "862 Primer and Sealer Gals. 4.0 Rutile Titanium 1.2 Calcium Stearate 16.0 XAC-48 74.0 XAC-48 4.0 60% Cold Cut Ester Gum 2.0 Heavy Bodied Oil 0.5 6% Co Naphthenate 10L7 Viscosity -- 69 K. U. Gloss -- High (Visual) Dry to Touch -- 8 to 12 hours Dry to Recoat -- 24 hours Wt. per gal. -- 8.46 P. V. C. -- 14.5% 5-53 0007-PMC-000000759 DYAL XAC-49 & DYAL XAC-50 TYPE: Alkyd Flat Wall Vehicles in Odorless Mineral Spirits OUTSTANDING FEATURES: Dyal XAC-49 -- Excellent Uniformity & Non-Penetration, High Viscosity, Retained Flexibility, Low Odor Dyal XAC-50 -- Retained Flexibility, Low Odor, Low Viscosity with Good Non-Penetration Dyal XAC-49 and Dyal XAC-50 were developed to meet the demands for architectural flat and semi-gloss systems requiring the use of low K. B. odorless solvents. Dyal XAC-49 will permit lower paint solids formulation giving lower material costs while maintaining the highest quality performance. Dyal XAC-50 was designed for use in higher hiding high paint solids flat and semi-gloss formulations. Dyal XAC-49 will perform with maximum uniformity and non-penetration in flat wall films over surfaces of variable porosity. This performance may be attributed to the resin to solvent relationship that also contributes excellent flow and leveling to brushed films of wall finishes made with Dyal XAC-49. The use of Dyal XAG-49 permits formulation of quality flat and semi-gloss finishes with a wide variety of pigment combinations and concentrations. Dyal XAC-50 may be formulated into high solids, high hidipg, non-penetrating wall finishes that possess excellent application properties. Both of these vehicles will give excellent color retention and are of sufficient oil length to have maximum retained flexibility to insure against cracking and peeling of aged films. Good package stability is obtained by the use of recommended amounts of anti-skin agent along with proper initial viscosity adjustment. Initial viscosities of flat wall finishes made with Dyal XAC-49 and Dyal XAC-50 should be 82 to 94 K. U. A six to seven percent maximum increase in viscosity will be noted upon aging. The good odorless solvent tolerance of these vehicles permits brush cleaning and ordinary clean-up with the low K. B. odorless solvent. SPECIFICATIONS DYAL XAC-49 Non-Volatile----------------------------------- 40% Volatile-------------------60% Odorless M. S. Lbs. per gal----- ---------------- 7.18 Viscosity @ 40% NVM------------------ Z8+ Color (max.)8 Acid Value4 max. Odorless M. S. Tol-..Infinite Viscosity @ 30% NVM_________ U to X DYAL XAC-50 Non-Volatile--------------------------... .40% Volatile-------------------60% Odorless M. S. Lbs. per gal__________________ .7.10 Viscosity @ 40% NVM------------- X to Z Color (max.)^8 Acid Value; 20 to 25 Odorless M. S. Tol300% Viscosity @ 30% NVM__________ F to H 0007-PMC-000000760 FILM AND PERFORMANCE PROPERTIES Color Color Retention Resistance to: Abrasion Acids Alkali Water Oil & Grease Compatability with: good good Pigments Long Oil Alkyds Long Oil Varnishes fair good good good good good excellent good For maximum performance blending should be in odorless solvent systems DRYING AND DRIER* RECOMMENDATIONS Air Dry-Set Air Dry-Hard (Clear Films) Dyal XAC-49 30 to 60 min. 6 to 8 hours Dyal XAC-50 30 to 45 min. _ 6 to 8 hours *% Metal on Resin Solids Lead Cobalt A.S.A. 3 to 5% 3 to 5% 3% Ti 02 Rutile____ Ti Cal Talr ______ Ca Stearate ....... Ca Carbonate**** lecithin Dyal XAC-49___ Dyal XAC-50___ Odorless M. S.__ 24% Pb Naphth'te 6% Mn Naphth'te 6% Co Naphth'te Anti Skin Agent.. SUGGESTED FORMULATIONS Wall Primer and Sealer Lbs. Gals. 210.0 7.8 3.0 215.0 4.0 .3 9.6 .5 426.0 137.0 10.0 2.0 2.0 .5 60.0 21.5 1.0 25 .25 .05 Flat Wall Formula No. 249 Lbs. Gals. 572.0 52.0** 6.0 21.2 22 .6 2.0 321.0 2 44.6 210.0 2.0 32.8 .2 1.0 .1 .5 .05 Flat Wall Formula No. 649 Lbs. Gals. 137.0 3.9 ' 215.0 7.9 83.0*** 3.7 8.0 .8 187.0 8.4' 2.0 2 331.0 46.0 197.0 2.0 30.8 2 1.0 .1 .5 .05 Flat Wall Formula No. 250 Lbs. Gals. 154.0 4.4 241.0 8.9 95.0*** 42 9.0 1.0 202.0 9.0 3.0 3 355.0 152.0 2.0 50.1 23.8 2 1.0 .1 .5 .05 Total Input___ _ 1009.0 Total Output___ 1007.0 101.3 1166.5 100.0 1142.0 101.95 1163.5 100.0 1142.0 101.95 1224.5 100.0 1200.0 101.95 100.0 % pvc . 46 % NVM 61 Grind 4H Mad. Cost/gal. $130 Viscosity 82-84 K.U. Wt./gal. 10.07 Lbs. Ti 02/gal___ __ .63 Washability . -- Dry vs. Wet Hiding-- -- Uniformity Good 10 minute Lap Good Sheen 32-38 60 65 3H to 4H $130 82-84 K.U. 11.42 1.7 Fair Excellent Excellent Excellent 5-10 60 66 4H $1.44 82-84 K.U. 11.42 2.01 Good Good Excellent Excellent 10-15 59.8 69 4H $1.51 82-84 K.U. 12.00 2.25 Good Good Excellent Excellent 10-15 Talc --8 Micron particlesize -- O.A. 28 -- 3"4 Hegman Grind Limit *** Talc -- 1 Micron particlesize -- O.A. 44 -- 6% Hegman Grind Limit ****Ca Carbonate -- 4 Micron particlesize -- O.A. 17 -- 5J4 Hegman Grind Limit 0007-PMC-000000761 Th e Sh er w in - Wil l iams Co . June 1, 1956 REVISED PRICE LIST -- SYNTHETIC RESINS Effective June 1, 1956--All prices subject to change without notice. DYALS % SOLIDS 1-9 DRUMS 70 DRS. TO C/L C/L DRUMS cm. XAC-1 XAC-2 XAC-9 50 $21.00 $20.50 $20.00 70 22.75 22.25 21.75 50 25.50 25.00 24.50 XAC-17 70 23.75 23.25 22.75 XAC-39 50 22.50 22.00 21.50 XAC-42 50 22.00 21.50 21.00 XAC-47 70 22.75 22.25 21.75 XAC-48 30 17.00 T6.50 16.00 XAC-49 40 20.50 20.00 19.50 XAC-50 40 20.50 20.00 19.50 XAC-66 60 25.50 25.00 24.50 XAC-76 65 25.00 24.50 24.00 XAC-83 70 22.75 22.25 21.75 XAC-93 70 22.75 22.25 21.75 XAC-99 50 20.50 20.00 . 19.50 XAC-C17 70 27.75 27.25 26.75 XAD-26 50 21.75 21.25 20.75 XAD-37 50 20.75 20.25 19.75 XAD-116 90 29.00 28.50 28.00 XAD-165 50 18.00 17.50 17.00 XAN-1 60 28.50 28.00 27.50 XAR-7 50 25.50 25.00 24.50 XAR-8 50 23.50 23.00 22.50 XAR-12 50 17.50 17.00 16.50 XAR-13 60 22.50 22.00 21.50 XAR-19 55 30.00 29.50 29.00 XAR-62 50 22.50 22.00 21.50 XAR-C9 50 30.50 30.00 29.50 XAR-C11 90 25.00 24.50 24.00 XAS-4 50 24.25 23.75 23.25 XAS-8 50 22.50 22.00 21.50 XMD-6 50 17.75 17.25 16.75 XMD-165 50 16.25 15.75 15.25 XOR-6 59-61 151.00 150.50 150.00 XOR-13 47 23.75 23.25 22.75 XOR-14 51.5 39.00 38.50 38.00 XOR-15 36 48.00 47.50 47.00 XPL-5 80 30.00 29.50 29.00 XPL-115 60 23.00 22.50 22.00 XRE-1 100 31.00 - 30.50 30.00 TANKCAR, and in some locations, TANKTRUCKS--$2.00 under C/L Drums. 0007-PMC-000000762 DYPHENES XRV-5 XRV-80 DYPHENITES XRV-133 DYMALS XRP-149 7-9 DRUMS $43.00 42.00 29.00 22.00 10 DRS. TO C/L $42.50 41.50 CARLOADS CWT $42.00 41.00 28.50 21.50 28.00 21.00 Supersedes all previous price lists. All previous prices for resins not listed are withdrawn, but are available upon request. GENERAL TERMS OF DELIVERY AND SALE All prices quoted are for shipment F.O.B. factory or warehouse (seller's option), minimum transportation allowed to destination in shipments of one drum or more to ail points in the United States except: Arizona, California, Idaho, Montana, New Mexico, Texas, Utah, Washington, Wyoming. Prices in these states are $7.00 per CWT additional. 1 Combinations of the various resins may be ordered to qualify for quantity dif ferentials. PACKAGES DYALS Shipped in Non-Returnable 55-gallon steel drums. DYPHENES ) DYPHENITES > Shipped in fibre containers, 250 lbs. net weight. DYMALS J PACKAGE DIFFERENTIALS DYALS 5-gallon pails, $5.00 cwt. additional. DYPHENES ] JDYPHENITES > Less than barrels, $5.00 cwt. additional. DYMALS TERMS Net cash 30 Days. THE SHERWIN-WILLIAMS CO. Cleveland 1, Ohio Chicago 6, Illinois New York 17, New York Oakland 8, California 101 Prospect Avenue, N. W. 300 West Lake Street 100 Park Avenue 1450 Sherwin Avenue 0007-PMC-000000763 DYAL XAC 75 DYAL XAC 77 TYPE: Soya Oil Modified Alkyds in Odorless Mineral Spirits OUTSTANDING FEATURES: DYAL XAC 75 -- Good Non-Penetration, Low Viscosity, Low Odor, Retained Flexibility. DYAL XAC 77 -- Low Solids, High Viscosity, Low Odor, Retained Flexibility. Dyal XAC 75 and Dyal XAC 77 were developecLto meet the demands for architectural gloss and semi-gloss systems requiring the use of low K. B. odorless solvents. Both of these vehicles will give excellent color retention and are of sufficient oil length to have maximum retained flexibility to insure against cracking and peeling of aged films. Dyal XAC 75 may be formulated into high solids, high hiding, non-pene trating wall enamels that possess excellent flow and leveling properties. Dyal XAC 77 will permit lower paint solids formulation giving lower material costs while maintaining the highest quality performance. The good odorless solvent tolerance of these vehicles permit brush cleaning and ordinary clean-up with the low K. B. odorless solvent. SPECIFICATIONS DYAL XAC 75 Non Volatile ---------------------------------- 70% Volatile----------- 30% Odorless Min. Spts. Lbs. Per Gal.7.78 Viscosity V-W Color (Max.)__9 Acid Value___ __________ ___5 Maximum Phthalic Anhydride ...... ....................... 24% Oil _______________ 67% Type Oil ................. Soya Odorless Min. Spts. Tol.................. Infinite DYAL XAC 77 Non Volatile ---------------------------------- 45% Volatile----------- 55% Odorless Min. Spts. Lbs. Per Gal-------------------------------------- 7.25 Viscosity-----------------------------------------Y-Z, Color (Max.)--------------------------------------- 8 Acid Value__ ____________ ______ 15 to 25 Phthalic Anhydride ........................ ... 30% Oil57% Type OilSoya Odorless Min.Spts. Tol----------------- Infinite 0007-PMC-000000764 FILM AND PERFORMANCE PROPERTIES ColorExcellent Color RetentionExcellent GlossGood Gloss Retention _---------------------------Good Resistance to: Abrasion_____________________ Good Acids_____________ ___ i.Good Alkali----- -- ---------------------------- Good WaterExcellent Oil & Grease __Good Pigment Wetting & Dispersing Properties -------Excellent Comparability with: Long Oil Alkyds------------------- Good Long Oil VarnishesGood For maximum performance blending should be in odorless solvent systems. DRYING AND DRIER* RECOMMENDATIONS DYAL XAC 75 Air Dry--Set.......... ....... 30 to 60 Minutes Air Dry--Hard------------------4 to 6 Hours DYAL XAC 77 Air Dry--Set30 to 60 Minutes A.S.A. Air Dry--Hard5 to 7 Hours Lead ______ _0.3 to 0.6% Calcium**______ _ 0.3 to 0.6% Ckhalt ------------------------------- -05 to .1 % (Clear Films)____* %' Metal on Resin Solids ** to replace lead SUGGESTED FORMULATIONS Low Odor Semi-Gloss White Enamel Lbs. Gals. 180 382 3 3 184 44 252 85 17 13 6 1169 5.1 13.9 02 0.3 23.7 6.1 34.8 13.5 2.1 1.6 0.9 1022 Rutile N.C. Ti02 Ti Cal. Rutile N.C. Bentone 34 Aluminum Stearate XAC 75 XAC 77 XAC 77 Odorless Mineral Spirits 4% Calcium Naphthenate 6% Cobalt Naphthenate Anti-Skin (17% Solution) Low Odor Gloss White Enamel Lbs. Gals. 292 3 2 125 100 392 56 13 17 4 1004 8.35 0.3 0.1 16.1 12.9 54.0 8.9 1.6 2.1 0.6 104.9 Rutile N.C. TiO, Aluminum Stearate Bentone 34 XAC 75 XAC 75 XAC 77 Odorless Mineral Spirits 6% Cobalt Naphthenate 4% Calcium Naphthenate Anti-Skin (17% Solution) NOTE: The drier and the anti-skin should be of the odorless type. Lbs./Gal. -- 11.43 Viscosity @ 75 F -- 73 to 76 K. U. Gloss -- 55 to 69 Photocell P.V.C. -- 36.8% Lbs./Gal. -- 9.56 Viscosity @ 75F -- 72 to 75 K. U. Gloss -- 85 to 91 Photocell P.V.C. -- 16.3% 4/56 0007-PMC-000000765 THE SHEH'JIN-IULLIAMS CO June 1, 1956 SYNTHETIC RESINS NOT IN' STANDARD LIST Effective June 1, 1956 SPECIAL DIALS CA DRUMS SPECIAL DYALS C/L DRUMS XAC-97 019.00 XAR-86 022.50 XAC-189 19.50 XAJWJ6 23.00 XAC-C6 20.00 XAR-C23 19.00 x a c -c ii XAC-C29 22.75 27.50 XAR-C2ii XAS-C7 21.50 23.25 XAC-C33 19.75 XEN-1 19.25 XAC-CiiO 18.25 XHD-lli 16.75 x a c .c 55 XAC-C69 21.00 21+.75 XMD-18 XMD-C1 16.75 111. 25 XAC-C73 XAC-C76 21.75 21.00 XMD-C22 XMD-C23 17.00 111. 00 XAD-1 21.50 XOR-31 111;. 00 XAD-17 XAD-C28 17.50 3.9.25 X0R-3U XPL-C7 llO.OO 29.00 XAN-78 29.00 XRE-C13 20,00 XAN-81; 29.50 XRE-C18 27.50 ALL PRICES SUBJECT TO CHANGE UI1HOUT NOTICE All previous prices for other resins not listed are withdrawn, but are available upon request. 0007-PMC-000000766 TYPE: Short Oil Modified Alkyd OUTSTANDING FEATURES: Adhesion, Fast Set, Durability DYAL XAC-66 Dyal XAC-66 represents an outstanding vehicle for use in primers of exterior quality. It has been employed successfully in Naval Aircraft primers where the rapid solvent release and the short recoat time of this vehicle are used to advantage. Dyal XAC-66 may be used in industrial primers for air drying or baking with application by spraying or dipping. Primers composed of Dyal XAC-66 will possess a fast "set to touch" and handling time along with fast through dry giving a film which will have excellent adhesion, good water and hydrocarbon resistance. This vehicle will also give excellent package stability. Dyal XAC-66 is primarily intended for fast air-dry primers but it may also be adapted to short infra-red baking. For baking the lead and cobalt concentration may be greatly re duced. With the proper solvent balance, either spray or dipping primers may be formu lated. For spraying or dipping small objects, xylol or toluol may be employed as a solvent. For dipping large objects, a slower solvent such as "hi-solvency" naphtha may be used. Because of its high acid value, Dyal XAC-66 cannot be used with reactive pigments such as zinc oxide, but rather it is especially suited for formulations containing less reactive pig ments such as zinc chromate, iron oxide, and titanium dioxide. The water content of zinc chromate pigments should be low, preferably below 0.25% to 0.50%, because of the exces sive "after-bodying" of primer formed in a medium having more water. If such "afterbodying" should occur, 3 pounds of triethanolamine per 100 gallons of primer will prevent excessive bodying. SPECIFICATIONS Non Volatile ............. ..........................60% Volatile .............. ...................... 40% Xylol Lbs. per gal8.40 Viscosity ---------------------- ------- --------Zi - Z3 Aliphatic Solv. Tol.___ ___________ None Solids at E to G Vis........... ................ 40% Color (max.) _______________ ________ 11 Acid Value_____ _____ _________30 to 35 Phthalic Anhydride 38% Oil 44.7% Type Oil........ ..........--Dehydrated Castor Resin Modifiers _____ __________ None 0007-PMC-000000767 FILM AND PERFORMANCE PROPERTIES Color Color Retention Gloss Gloss Retention Type of Film fair good good good hard, tight Resistance to: Abrasion Acids Alkali Oil & Gasoline Water Weather good good fair good excellent good Compatibility with: Pigments Nitrocellulose Alkyds f long 1 medium 1 short [long Varnish j medium 1 short Oils Bodied Oils excellent good poor fair good poor fair good poor poor DRYING AND DRIER RECOMMENDATIONS Air Dry--Set Air Dry--Hard Bake 15 min. Lead 6 hours Manganese 250F. for 10 to 20 min. Cobalt Calcium Zinc Air Dry 0.5% to 2.0% 0.01% to 0.03% 0.01% to 0.05% none none Bake none SUGGESTED FORMULATIONS Lbs. 290.0 50.0 3.0 3.0 67.1 64.5 2.9 0.72 403.0 78.0 93.0 4.0 1059.22 Zinc Chromate Primer Gals. 8.5 2.2 0.3 0.3 8.0 9.0 Zinc Chromate 12054 Micronized Talc Maleic Anhydride Aluminum Stearate Dyal XAC-66 Xylol 0.3 Pb Naphthenate 0.1 Anti Skin Agent 48.0 Dyal XAC-66 12.0 Mineral Spirits 13.0 Xylol 0.5 6% Co Naphthenate 102.2 Yellow Primer For Implements Lbs. 100.0 91.0 32.0 19.0 4.0 4.0 159.5 5.75 2.4 64.6 0.72 Gals. 2.9 4.1 1.9 0.4 0.4 0.4 19.0 0.6 0.3 9.0 0.1 Rutile N. C. Ti O, Micronized Talc Diatomacious Silica Medium Chrome Yellow 12152 Aluminum Stearate Soya Lecithin Dyal XAC-66 24% Pb Naphthenate 6% Co Naphthenate Xylol Anti Skin Agent 923.27 97.7 Lbs. per gal. -- 10.30 Ball Mill -- 5 to 6 Hegman Grind Recoat -- 5 min. This primer has excellent adhesion to metal and forms a protective coating by itself. Wt. per gal. -- 9.43 Ball Mill -- 5 to 6 Hegman Grind This primer was originally set up for small tractor parts. 5-53 0007-PMC-000000768 DYAL XAC-76 TYPE: Medium Oil Modified Alkyd OUTSTANDING FEATURES: Compatibility, Fast Set, Color and Gloss Retention Dyal XAC-76 is a medium oil modified general purpose vehicle. It is especially well suited for applications where high solids are required. Dyal XAC-76* has a wide range of compatibility making it useful in applications involving the use of nitrocellulose, chlorinated rubber, urea and melamine, as well as other alkyds and varnishes. Because of its good compatibility, Dyal XAC-76 is used to great advantage as a grinding base vehicle in formulations which require the use of shorter more reactive alkyds. Dyal XAC-76 will not adversely affect the setting and drying time of the shorter alkyds. Dyal XAC-76 can also be used to make color bases for nitrocellulose lacquers where it will serve as a modifying resin for the nitrocellulose. This alkyd may be used alone in air dry or bake schedules for spray or dip applications. Some suggested uses for Dyal XAC-76 are as follows: 1. Metal Furniture Finishes 2. Metal Tile Enamel 3. Chlorinated Rubber Formulations 4. Nitrocellulose Lacquer Modifier and Plasticizer 5. Urea and Melamine Plasticizer Dyal XAC-76 possesses excellent pigment compatibility and will disperse most pigments with no special treatment being required. This alkyd is of appropriate oil length to permit roller or ball mill grinding. SPECIFICATIONS Non Volatile65% Color (max.)11 Volatile ___35% Xylol Acid Value_________________ 5 Lbs. per gal-------------------------------------- 8.42 Phthalic Anhydride________ ________ 35% Viscosity____________________ Y-7. Oil_____ ______________________,___47% Aliphatic Solv. Tol.200% Type-Oil___________________________________ Soya Solids at E to G Vis.---------------- 56 - 57% Resin ModifiersNone 0007-PMC-000000769 FILM AND PERFORMANCE PROPERTIES Color Color Retention Gloss Gloss Retention Type of Film good excellent excellent excellent hard, durable, flexible Resistance to: Abrasion Acids Alkali Oil & Gasoline Water Weather good good good good good good Compatibility with: Pigments Nitrocellulose Alkyds f long medium | short l long Varnish -{ medium 1 short Oils Bodied Oils _ good excellent excellent excellent good excellent excellent good good fair DRYING AND DRIER RECOMMENDATIONS Air Dry--Set Air Dry--Hard Bake-- With Driers Bake-- With Amine 15 to 30 min. 4 to 5 hours 30 to 50 min. at 275F. to 350F. 30 min. at 300F. L^ad Manganese Cobalt Calcium* Zinc Air Dry 0.3% to 0.6% 0.03% to 0.06% 0.03% to 0.06% 0.3% to 0.6% none to replace lead Bake (without Amine) o.i% none 0.01% o.i% 0.01% SUGGESTED FORMULATIONS Lbs. 274 109 75 8 282 84 83 29 69 13 1026 White Metal Tile Enamel Gals. 7.8 13.0 9.0 1.0 Titanium Dioxide, Rutile Color Retentive Dyal XAC-76 Dyal XAC-9 Pine Oil 34.0 10.0 10.0 4.0 11.0 2.0 Dyal XAC-9 Plaskon 3353 Rcsamine 878 Toluol High Solvency Naphtha Anhydrous Alcohol 101.8 Viscosity No. 4 Ford Cup -- 60" to 65" Wt. per Gal. -- 10.00 Grind on Roller Mill -- 7 Hegman Pencil Hardness -- F This formula is a good example of the use of Dyal XAC-76 as a plasticizer for both amine resins and a short oil alkyd. Lbs. 140 150 340 3 254 27 101 -152 104 34 7 1312 White Baking Primer Gals. 4.3 3.2 9.5 0.3 30.0 3.5 Titanium Dioxide, Anatase, Full Chalking Zinc Oxide Blanc Fixe Soya Lecithin Dyal XAC-76 Pine Oil 12.0 Dyal XAC-76 20.0 Dyal XAC-99 14.5 Xylol 5.0 Butanol 1.0 17% Guaiacol Sol'n. 103.3 Viscosity No. 4 Ford Cup -- 50" to 60" Wt. per gal. -- 12.66 Grind on Roller Mill -- 6 Hegman Bake -- 30 min. at 350F. 8-03 0007-PMC-000000770 DYAL XAC-83 TYPE: Long Oil Modified Alkyd OUTSTANDING FEATURES: Excellent Gloss, Color Retention, TT-R-266, Type i. Class A Dyal XAC-83 is a long soya oil modified pentacrythritol alkyd especially suited for use in quality high solids and heavily pigmented architectural and general purposes enamels. Gloss and semi-gloss enamels made with Dyal XAC-83 have excellent application proper ties and will produce films that arc color retentive, mar proof and durable. Dyal XAC-83 has been improved to give better gloss retention and increased viscosity. This resin has better initial color and better gloss retention than the longer oil Dyal XAC-2. Dyal XAC-83 will compare rather closely in performance with Dyal XAC-47. Dyal XAC-83 conforms to the requirements of Specification TT-R-266, Type I, Class A alkyd. Dyal XAC-83 may be obtained at 60% NVM under the assignment of Dyal XAC-C33 to conform to the requirements for the TT-R-266, Type I, Class B vehicle. Dyal XAC-83 is recommended for the following uses: 1. Architectural' Finishes High-Hiding Whites Master Painter's Enamels High Quality Wall Finishes 2. Industrial High-Hiding Mill Whites Quality Maintenance Finishes Marine Finishes Awning Paints Silk Screen Finishes 3. Shelf Goods Trim and Trellis Paints Household Enamels (blended with Dyal XAC-1) Lawn Furniture (blended with Dyal XAC-1 or Dyal XAD-26) Because of its general compatibility and relatively long oil length, Dyal XAC-83 is ideally suited to improve the brushing and leveling of more viscous alkyds and to extend shorter vehicles without increasing the drying"time or contributing to the after tack. Dyal XAC-83 is neutral to reactive pigments including zinc oxide. Its excellent flow and good pigment wetting characteristics make it a good grinding vehicle. SPECIFICATIONS Non Volatile -------------------- 70% Volatile ________________ 30% M. S. Lbs. per gal------------------------------------- 7.97 Viscosity --------------------------------------Zi - Z2 Aliphatic Solv. Tol----------------- Infinite Solids at E to GVis____ ____________50% Color (max.)7 Acid Value5 - 10 Phthalic Anhydride23% Oil -----------------------------------------------64% Type OilSoya Resin Modifiers _____ None 0007-PMC-000000771 FILM AND PERFORMANCE PROPERTIES Compatibility with: Color good Pigments Color Retention excellent Nitrocellulose Gloss excellent Gloss Retention excellent ' long Type of Film tough, hard, very flexible Alkyds medium Resistance to: short Abrasion good Acids good long Alkali good Varnish medium Oil & Gasoline good short Water excellent Oils Weather excellent Bodied Oils excellent none excellent excellent good excellent excellent good excellent excellent DRYING AND DRIER RECOMMENDATIONS Air Dry---Set Air Dry---Hard 1% to 2>/2 hours 6 to 7 hours Whites Colors Cobalt 0.05% 0.05% to 0.08% Calcium 0-2% to 03% 0-.2% to 03% SUGGESTED FORMULATIONS White Architectural Brushing Enamel Lbs. Gals. 250 72 Color Retentive Ti On* 28 0.6 Zinc Oxide 3 03 Aluminum Stearate 4 0.3 Soya Lecithin 153 19.0 Dyal XAC-83 415 52.0 Dyal XAC-83 26 4.0 Kerosene 117 18.0 Mineral Spirits 6 0.8 6% Co Naphthenate 7 1.0 Anti Skin Agent 1009 107.2 Oil Absorption 17 -- 18 Viscosity -- 69 to 72 K. U. Gloss Photocell -- 87 to 92 Dry -- 8 to 9 hours Wet Edge -- 20 minutes White Architectural Semi-Gloss Lbs. Gals. 100 2.8 Color Retentive Ti CL** 500 18.6 Ti Calcium*** 75 3.3 Micronized Talc 28 0.6 Zinc Oxide 3 0.3 Aluminum Stearate 272 34.0 Dyal XAC-83 52 8.0 Kerosene 144 108 4 _" 4 18.0 Dyal XAC-83 20.5 Mineral Spirits 0.5 6% Co Naphthenate 0.5 Anti Skin Agent 1290 103.1 Oil Absorption 17-18 Oil Absorption 21 - 22 Viscosity -- 60 to 74 K. U. Gloss Photocell -- 50 to 60 Dry -- 7 to 8 hours Wet Edge -- 15 min. 5-53 0007-PMC-000000772 TYPE: Long Oil Modified Alkyd OUTSTANDING FEATURES: Color Retention, Ease Of Application DYAL XAC-93 Dyal XAC-93 is an all purpose color retentive alkyd having excellent brushing character istics and possessing excellent retained flexibility. Originally developed for use in high grade architectural brushing enamels, for which it is still unequalled, its versatility has led to its employment in many other related types of finishes such as: 1. Architectural Finishes Super White Enamels Fume Proof Whites 2. Trade Sales Finishes Household Enamels (blended with XAC-1 to increase solids, and control the flow while taking advantage of the faster drying and greater hardness of Dyal XAC-1) 3. Industrial and General Marine Finishes Topside Superstructure and Hull Paints Highway Maintainance Paints In addition to giving excellent brushing, this alkyd will promote sufficient flow to give good leveling without sagging. The viscosity and solids are such as to give a good build for high gloss. Dyal XAC-93 wfll furnish excellent exterior durability and meet the Specification TT-R-266, Type I. It is also compatible with all reactive pigments and maintains its gloss well at high pigment concentration by virtue of its excellent grinding properties. Petroleum thinners may be used exclusively and in any proportion with Dyal XAC-93. This vehicle is compatible with large amounts of raw boiled or blown oils making it of great value in hardening long "all oil" type enamels. SPECIFICATIONS Non Volatile---------------------------------- 70% Volatile---------------- .---------------- 30% M. S. Lbs. per Gal.------------------------------------- 8.00 Viscosity--------------------------------------Y - Zi Aliphatic Solv. Tol.--------------'Infinite Solids at E to GVis.50% Color (max.)8 Add Value _________________ _________10 Phthalic Anhydride________ 23.8 Oil62.0 Type Oil_______________ Soya Resin Modifiers.None 0007-PMC-000000773 FILM AND PERFORMANCE PROPERTIES Color Color Retention Gloss Gloss Retention Type of Film excellent excellent good good tough, flexible Resistance to: Abrasion Acids Alkali Oil & Gasoline Water Weather excellent good good excellent excellent excellent Compatibility with: Pigments Nitrocellulose Alkyds [ long -1 medium 1 short (Tong Varnish -! medium 1 short Oils Bodied Oils excellent none excellent good fair excellent good fair excellent excellent DRYING AND DRIER RECOMMENDATIONS Air Dry--Set Air Dry--Hard 2% hours 7 to 9 hours Air Dry Lead 03% to 0.6% Manganese none Cobalt 0.02% to 0.06% Calcium* 03% to 0.6% Zinc none *to replace lead SUGGESTED FORMULATIONS Lbs. 300 171 32 278 39 215 117 30.3 3 1185.3 Hull Paint Gals. 7.6 7.4 0.7 35.0 6.0 Iron Oxide (85% Fe203) Micronized Talc Zinc Oxide Dyal XAC-93 Mineral Spirits 27.0 15.0 4.0 0.3 Dyal XAC-93 Mineral Spirits 4% Ca Naphthenate 6% Co Naphthenate 103.0 Viscosity -- Heavy Lbs. per gal. -- 11.40 Brushing (Reduce with M.S.) -- 15% This particular hull paint has performed well under many deep water conditions. Red Exterior Enamel Lbs. Gals. 100 8.6 Toluidine Red 10451 46 2.0 Micronized Talc 2 0.2 Soya Lecithin 4 0.4 Calcium Stearate 240 30.0 Dyal XAC-93 280 35.0 Dyal XAC-93 78 10.0 "D" Bodied Linseed Oil 98 15.0 Mineral Spirits 10 1.0 24% Pb Naphthenate 5 0.6 6% Co Naphthenate 2 0.2 Anti Skin Agent 865 103.0 Viscosity No. 4 Ford Cup -- 110" to 130" Lbs. per gal. -- 8.42 Brushing (Reduce with Kerosene) -- 5% Spraying (Reduce with VM&P) -- 20% 5-53 0007-PMC-000000774 TYPE: Medium Oil Modified Alkyd OUTSTANDING FEATURES: Color Retention, Versatility DYAL XAC-97 Dyal XAC-97 has been developed for the type of industrial and shelf goods usage that de mands the best in quality and performance for either spray, dip or brush application. This general utility vehicle will produce films that exhibit excellent color retention, gloss reten tion, mar proofness and abrasion resistance. Formulation of a line of enamels for a broad range of application is a relatively simple task with Dyal XAC-97. Some of the suggested uses of Dyal XAC-97 are as follows: 1. Industrial Maintenance Enamels 2. Automotive and Transport White Enamels 3. Furniture Enamels 4. Farm Machinery 5. Cabinets -- wood or metal Dispersion of all types of pigments with the exception of the most reactive types such as zinc oxide, present no problem with the use of this alkyd. Dyal XAC-97 will show good compatibility with most long or medium alkyds as well as with bodied oils and varnishes. It may also be used with naphtha tolerant urea and melamine resins. Dyal XAC-97 com plies with the requirements of the government specification TT-E-489. SPECIFICATIONS Non Volatile50% Volatile50% M. S. Lbs. per gal7.66 Viscosity P-R Aliphatic Solv. Tol---------------------- Infinite Solids at E to G Vis.42% Color (max.)9 Add Value12 Phthalic Anhydride35% Oil------------------------------------------------ 52% Type Oil----------------------------------------Soya Resin Modifiers__________________ None 0007-PMC-000000775 FILM AND PERFORMANCE PROPERTIES Color Color Retention Gloss Gloss Retention Type of Film excellent excellent excellent excellent hard, flexible Resistance to: Abrasion Acids Alkali Oil & Gasoline Water Weather excellent good good excellent excellent excellent Compatibility with: Pigments Nitrocellulose Alkyds [long 1 medium | short [long Varnish 1 medium | short Oils Bodied Oils excellent none excellent excellent good excellent good good good good DRYING AND DRIER RECOMMENDATIONS Air Dry--Set 30 to 60 min. Air Dry Air Dry--Hard 4 to 5 hours Lead 0.3% to 0.5% Bake 30 to 60 min. at 250 F. to 300F. Manganese** 0.01% to 0.03% \ Cobalt 0.03% to 0.05% Calcium* 0.3% to 0.5% Zinc none to replace lead only for tints & colors Low Bake 0.2% to 0.4% 0.01% to 0.03% 0.01% to 0.03%. none 0.01% SUGGESTED FORMULATIONS White Brush Maintenance Enamel Lbs. 260.0 2.0 199.0 12.0 11.5 Gals. 7.4 Ti 02 Rutile (Non Chalking) 0.2 Calcium Stearate 26.0 Dyal XAC-97 1.5 4% Ca Naphthenate 1.15 24% Pb Naphthenate 383.0 40.0 5.0 3.0 2.0 60.0 50.0 Dyal XAC-97 5.0 Dyal XAC-2 0.6 6% Mn Naphthenate 0.5 6% Co Naphthenate 0.4 Anti Skin Agent 9.5 Mineral Spirits 977.5 102.25 Lbs. per gal. -- 9.54 Viscosity -- 70 to 72 K. U. Air Dry -- Set -- 45 min. Air Dry -- Hard -- 4 to 6 hours Transport Semi-Gloss Enamel Lbs. 350.0 120.0 Gals. 11.3 Titanium Calcium-Rutile 3.4 Ti 02 Anatase 4.0 0.45 Calcium Stearate 96.0 12.5 Dyal XAC-93 92.0 11.5 Dyal XAC-97 7.0 1.0 Anti Skin Agent 20% 306.0 40.0 Dyal XAC-97 9.0 1.2 24% Pb Naphthenate 4.67 0.7 6% Mn Naphthenate 2.33 0.33 6% Co Naphthenate 123.0 19.0 Mineral Spirits 1114.00 10138 Lbs. per gal. -- 10.95 Viscosity No. 4 Ford Cup -- 75" to 90" 5-53 0007-PMC-000000776 TYPE: Medium Oil Modified Alkyd OUTSTANDING FEATURES: Rapid Thru Drying, Color Retention DYAL XAC-99 Dyal XAC-99 is an excellent air dry vehicle for use in super white enamels where good mar and abrasion resistance and excellent color retention are desired. It may also be used in formulating baking and dipping enamels completely free from wrinkling on the bead. Dyal XAC-99 is unique in the unusual combination of color retention and toughness with print resistance, durability and chemical resistance. -- Examples of suggested use are the following: 1. Architectural and Household Baking Enamels > 2. Low and High Temperature Baking Enamels 3. Good Wood Cabinet Enamels both White and Colors 4. Enamels of Unusually High Water Resistance 5. Dipping Enamels -- using Dyal XAC-99 alone or in conjunction with other alkyds to eliminate wrinkling in the bead Dyal XAC-99 works well with bases ground in Dyal XAD-26 and these two liquids sup plement each other in many respects. White enamels may be ground in Dyal XAC-99 to take advantage of its superior color retention. Zinc oxide may be used in very small quan tities only. For other colors, Dyal XAD-26 is recommended as the grinding medium. For applications which require faster solvent release these resin solids may be obtained re duced in VM&P naphtha under the assignment of Dyal XAC-189. SPECIFICATIONS Non Volatile 50% Volatile50% M. S. Lbs. per gal7.58 Viscosity Y - Z Aliphatic Solv. Tol______________ 1500% Solids at E to G Vis______ ________ 40% Color (max.) ------------------------------------ 9 Acid Value 12 Phthalic Anhydride30.5% Oil.57.5% Type Oil:__________________________ Soya Resin Modifiers __________________ None 0007-PMC-000000777 FILM AND PERFORMANCE PROPERTIES Color Color Retention Gloss Gloss Retention Type of Film Compatibility with: excellent Pigments excellent Nitrocellulose good f long good Alkyds -1 medium hard, tough, mar resistant | short Resistance to: Abrasion Acids Alkali Oil & Gasoline Water Weather excellent good good excellent excellent excellent f long Varnish [ medium 1 short Bodied Oils Oils good none good good fair good good good good good DRYING AND DRIER RECOMMENDATIONS Air Dry--Set Air Dry--Hard Bake 45 to 90 min. 4 to 6 hours 250F. to 275 F. for 30 min. to 60 min. Air Dry Lead 0.2% to 0.4% Manganese 0.01% to 0.02% Cobalt 0.02% to 0.04% Calcium* 0.3% to 0.5% Zinc none to replace lead Bake 0-2% none 0.01% none 0.01% SUGGESTED FORMULATIONS V R. R. Express White Enamel Lbs. Gals. 310.0 9.8 N. C. Anatase Ti CL** 75.0 1.6 Antimony Stearate 2.0 0.2 Aluminum Stearate 152.0 20.0 Dyal XAC-99 13.0 2.0 Mineral Spirits 386.0 110.0 10.0 6.0 51.0 Dyal XAC-99 17.0 Mineral Spirits 1.0 24% Pb Naphthenate 0.7 6% Co Naphthenate 1064.00 103.3 **Oii Absorption 26 -- 27 Viscosity No. 4 Ford Cup 80" to 90" Lbs. per gal. -- 10.32 Brushing -- Reduce with Kerosene Spraying -- Reduce with VM&P 20% Dry -- Set -- 1 hour Hard -- 6 hours White Dipping Enamel Lbs. Gals. 309.0 8.75 Rutile Ti 02*** 2.05 0.21 Aluminum Stearate 3.09 0.31 Soya Lecithin 218.0 28.80 Dyal XAC-99 344.0 107.0 14.75 5.92 2.50 45.30 16.50 2.10 0.62 0.31 Dyal XAC-99 Mineral Spirits 14% Guaiacol Sol'n. 24% Pb Naphthenate 6% Co Naphthenate 1006.31 102.90 ***Oil Absorption -- 17 -- 18 Viscosity No. 4 Ford Cup -- 50" Lbs. per gal. -- 9.70 Dip -- As is for large objects VM&P for short objects to re duce viscosity to 20" Bake: -- 250F. for 30 min. 5-53 0007-PMC-000000778 XAC C84 TYPE: Metal Decorating Baking Alkyd OUTSTANDING FEATURES: Color, Color Retention, Gloss, Film Hardness, Flexibility, and Baking Schedule XAC C84 is an alkyd that was designed specifically for metal decorating. It may be used to formulate wet ink varnishes or white enamels for ground coat. Wet ink finishing varnishes formulated from XAC C84 will bake in 12 to 15 minutes at 280 F. to 300 F. One of the outstanding properties of-these wet ink varnishes is the good flow and resulting excellent gloss. This good flow is also instrumental in producing a production job that has a minimum of ''embossing" which means that the small print will be readily legible. Still another outstanding property is the lack of bleed. When XAC C84 finishing varnishes are used over the most difficult inks, the amount of bleed is never great enough to detract from the appearance of the finished article. Silking is seldom a problem either when using XAC C84 to formulate wet ink varnishes. This lack of bleed and -silking is due in great part to the fact that the wet ink varnish formula does not contain any aromatic solvent. (See back of this sheet for formulation.) This absence of aromatic solvent will mean that the raw material costs will be lower. Superior type rollercoating white enamel or ground coat for metal lithography may be formulated from XAC C84. This enamel will have exceptional flexibility, and coated stock may be formed into double tight can covers without any rupture of the film. This same enamel will have exceptional gloss. One quarter pound electrolytic tin plate, when coated with the enamel will give a 90 gloss reading on the 60 Gloss meter. The white enamel formula listed on the reverse side of this page will bake out in 15 minutes at 280 F. There will be no color degradation even with a 15 minute overbake at 300 F. With the. normal baking schedule, XAC C84 enamel will exhibit a film hard ness of F as measured by the pencil hardness test. The excellent flow properties of XAC C84 also manifests itself in the rollercoating white enamel. This means, that the white ground coat will be extremely uniform and free from any blemishes due to the roller coating operations. PHYSICAL CHARACTERISTICS Non-Volatile .......................................60% Volatile.................... 40% Mineral Spirits Lbs. Per Gal............................................ 7.83 Viscosity............................................. Z5-Z6 Aliphatic Solv. Tol........................... Infinite Color (Max.) ..............................................8 Acid Value (Max.)...................................10 Phthalic Anhydride..........................25.5% Type of Oil..................................... Drying Resin Modifiers................................ Present 0007-PMC-000000779 FILM AND PERFORMANCE PROPERTIES Color .................. Color Retention . Gloss .................. Gloss Retention . Type of Film...., .Tough, Hard, Flexible Resistance to: Abrasion ... Acids ......... Alkali .... Oil and Gasoline...................Excellent Water.....................................Excellent Weather ................................ Excellent Pigment Wetting and Dispersing Properties .. .. .Excellent Compatibility with: Long Aikyds................ .. .Excellent Medium Aikyds........... Short Aikyds................ ........... Good Long Varnishes........... Medium Varnishes .... ... Excellent Short Aikyds................ Oils ............................... Bodied Oils.................. BAKING AND DRIER RECOMMENDATIONS Air Dry--Set.... not recommended Air Dry--Hard. .not recommended Bake...................... 280 to 300 F. for 12 to 15 minutes Bake: > #1 Lead ........... Manganese . Cobalt......... Zirconium . Rare Earth . .0.1 to 0.2% Accelerator .05% to .075% #2 None .002% to .005 .002% to .005 .04% to .06% None None *6% Activ-8 Solution SUGGESTED FORMULATIONS Rollercoat Enamel, White Lbs. 340 121 Gallons T,02, Rutile R-510 15.4 Dyal XAC C84 "419 184 7% 1% 53.5 25.5 1 % Dyal 2^AC C84" High Solvency Aromatic Naphtha* Rare Earth Naphthenate, 4% Activ-8 Solution, 6% 1073 104.4 Withhold 3 gallons for Viscosity control Wt/Gallon--10.34 Viscosity--70" - 75" @ 75 F. #4 Ford Cup Roller Mill Grind--7 Hegman Wet Ink Vehicle Lbs. 490 1% 9% iVi 226% Gallons 621/2 Dyal XAC C84 Vi Activ-8, Solution 6% 1% Paraffin Wax Solution 1 Rare Earth Naphthenate, 4% 34/g Mineral Spirits 735 100 Weight per Gallon--7.35 Viscosity--40" - 44" @ 75 F. #4 Ford Cup %NVM--41% 0007-PMC-000000780 - avx / DYAL XAD The DYAL XAD resins are pure oil modified alkyd resins that are of the drying type and are non-color retentive. DYAL XAN The DYAL XAN resins are pure oil modified alkyd resins that are of the non-drying type. They may be color retentive or non-color retentive. 0007-PMC-000000781 / XAD A battery of modern Dow-Therm alkyd kettles representing a fraction of the total facilities available for manufacture of Dyal resins. 0007-PMC-000000782 TYPE: Medium Oil Modified Alkyd OUTSTANDING FEATURES: Compatibility, Versatility DYAL XAD-26 Dyal XAD-26 is a medium oil modified alkyd which is used extensively as a grinding and flushing liquid for color bases because of its excellent compatibility with most other alkyds, its non-reactivity with most pigments, and its excellent pigment wetting properties. Dyal XAD-26 is also used as the basic resin in many general industrial finishes. Its good drying speed, excellent through hardness, excellent durability, and good brushing make it suitable for applications such as the following: 1. Metal Primers 2. Pump Enamels 3. Truck Enamels 4. Brushing Enamels Pigment and color bases may be flushed or ground in Dyal XAD-26 with all of the usual types of equipment. Such bases have a minimum lengthening effect on short oil alkyds and do not seriously affect drying and hardness characteristics. At the same time they have a minimum shortening effect on long oil alkyds so that in both cases the final film character istics reflect those of the extending alkyd. It is advisable to incorporate anti-oxidants when grinding color bases to be stored for long periods in order to insure stability and freedom from skinning. This is especially important with high concentration of reactive colors such as iron blues, etc. Skinning may be con trolled by the use of from 0.01% to 0.03% guaiacol based on the vehicle solids. This will improve gloss and package stability. SPECIFICATIONS Non Volatile--------------------------------- 50% Volatile---------------------------------50% M. S. Lbs. per gal--------------------------------------7.65 ViscosityU-W Aliphatic Solv. To!----------------------Infinite Solids at E to G Vis.------------------------ 42% Color (max.)10 Acid Value10 Phthalic Anhydride33.0% Oil52% Type OilLinseed Resin ModifiersNone 0007-PMC-000000783 FILM AND PERFORMANCE PROPERTIES Color Color Retention Gloss Gloss Retention Type of Film good fair good good hard, tough Resistance to: Abrasion Acids Alkali Oil & Gasoline Water Weather excellent good good excellent excellent excellent Compatibility with: Pigments Nitrocellulose f long Alkyds I medium ( short f long Varnish l medium 1 short Oils Bodied Oils excellent none excellent excellent good excellent excellent excellent excellent excellent DRYING AND DRIER RECOMMENDATIONS Air Dry---Set Air Dry---Hard Bake 60 to 90 min. 8 hours 275 F. for 1 hour Lead Manganese Cobalt Calcium Zinc Air Dry 0.3% to 0.6% 0.00% to 0.06% 0.03% to 0.06% none none Bake 0.2% 0.02% 0.02% none none SUGGESTED FORMULATIONS Light Green Shading Base Lbs. 780.0 500.0 102.0 0.4 Gals. 21.5 65.0 15.6 0.4 Micro-Fast Chrome Green 12132 Dyal XAD-26 Mineral Spirits Anti Skin Agent 1382.4 102.5 Output -- 100 gals. Roller Mill -- 6 Hegman Grind Lbs. per gal. -- 13.50 Zinc Chromate Primer Lbs. Gals. 290 10.0 Zinc Chromate 12054 56 1.3 Zinc Oxide 67 2.5 Titanium Calcium 180 7.8 Micronized Talc 243 32.0 Dyal XAD-26 52 8.0 Mineral Spirits 152 20.0 Dyal XAD-26 137 21.0 Mineral Spirits 7 0.7 24% Pb Naphthenatc 3 0.3 6% Co Naphthenate 1187 103.6 Viscosity No. 4 Ford Cup -- 65" to 75" Lbs. per gal. -- 11.50 Brushing -- as is Spraying -- as is or reduce slightly with VM&P 5-53 0007-PMC-000000784 TYPE: Medium Oil Modified Alkyd OUTSTANDING FEATURES: Durability, Hi Viscosity, Rapid Drying DYAL XAD-37 Dyal XAD-37 is an excellent air drying or baking industrial alkyd that may be utilized for brush, spray or dip application. This medium length linseed vehicle promotes faster drying than the usual vehicle employing the conventional slow-evaporating mineral spirits type of solvent. As is characteristic of most linseed type vehicles Dyal XAD-37 is not strongly rec ommended for use in white enamels. It is not reactive with most basic pigments. Some of the suggested uses are as follows: 1. Implement Finishes (dear & pigmented) 2. Furniture Enamels (wood & metal) 3- Pump Enamels 4. Automotive and Transport Enamels 5. Industrial Maintenance Enamels One of the most attractive assets of Dyal XAD-37 is its extremely heavy viscosity which permits "low-solids" formulations and therefore gives cost savings. Also, excellent dip-tank stability may be expected from this vehicle. It possesses exceptional durability and therefore is very suitable for exterior type paints. SPECIFICATIONS Non Volatile50% Volatile------------------------------- 50% M. S. Lbs. per gal.7.62 Viscosity ------------------------------------_Z2-Z8 Aliphatic Solv. Tol.1500% Solids at E to G Vis.36% Color (max.)_________________ 10 Add Value__________________________ 12 Phthalic Anhydride34.8 Oil-------------------------------------------------- 50.6 Type Oil-------------------------------- --Linseed Resin ModifiersNone 0007-PMC-000000785 FILM AND PERFORMANCE PROPERTIES Color Color Retention Gloss Gloss Retention Type of Film good fair excellent excellent medium hard, flexible Compatibility with: Pigments Nitrocellulose f long Alkyds -j medium | short Resistance to: Abrasion Acids Alkali Oil & Gasoline Water Weather good good good excellent excellent excellent f long Varnish -J medium | short Oils Bodied Oils excellent none good good fair good good fair good good DRYING AND DRIER RECOMMENDATIONS Air Dry--Set Air Dry--Hard Bake 30 to 90 min. 6 to 7 hours 250F. to 275F. for 30 min. to 60 min. Lead Manganese Cobalt Air Dry 0.1%to 0.3% none 0.02% to 0.06% Calcium* 03% Zinc none *to replace lead Bake 0.10% none 0.02% 0.03% 0.1% none SUGGESTED FORMULATIONS Railroad Green Striping Enamel Lbs. Gals. 100.0 4.7 Micro Fast Chrome Green 11235 228.5 30.0 Dyal XAD-37 32.5 5.0 Mineral Spirits 244.0 152.0 9.6 71.5 0.1 Anti Skin Agent 32.0 Dyal XAD-37 19.0 Dyal XAC-93 1.0 24% Pb Naphthcnate 11.0 Mineral Spirits 838.1 102.8 Viscosity No. 4 Ford Cup -- 75" to 90" Lbs. per gal. -- 8.10 Brushing -- Reduce with M. S. -- 5 to 10% Dry -- Slight Tack -- 3 to 4 hours Dry -- 6 to 8 hours Lbs. 25.0 42.0 35.0 15.0 200.0 78.0 Blue Pump Enamel Gals. 1.7 C P Milori Blue 11086 0.9 Zinc Oxide Azo-22** 1.6 Atomite Ca CO3 0.7 Micronized Talc 25.0 Dyal XAC-93 0.2 Anti Skin Agent 12.0 Mineral Spirits 312.0 9.6 5.6 118.0 41.0 Dyal XAD-37 1.0 24% Pb Naphthcnate 0.7 6% Co Naphthenate 18.2 Mineral Spirits 840.2 103.0 **(Am. Process-Accicular) Viscosity No. 4 Ford Cup -- 75" to 90" Lbs. per gal. -- 8.13 Brushing -- Reduce with Kerosene -- 5 to 10% Dry -- Slight Tack -- 3 to 4 hours Dry -- 6 to 8 hours S-S3 0007-PMC-000000786 DYAL XAN-78 TYPE: Short Non Oxidizing Oil Modified Alkyd OUTSTANDING FEATURES: Color Retention, Heat Resistance Dyal XAN-78 is a non oxidizing oil modified alkyd resin designed for use with urea or melamine resins for the production of quality "high bake" enamels. This resin is an out standing vehicle for finishes which must withstand heat without discoloration. It is superior to Dyal XAC-9 in this respect. However, Dyal XAC-9 finishes will show better adhesion. There are cases where it is advantageous to blend Dyal XAN-78 with Dyal XAC-9 to get improved adhesion. -- Dyal XAN-78 may be used as a modifier for a variety of low viscosity, high solids, lacquers and lacquer based materials. The alkyd content imparts improved adhesion, improved cold check resistance, improved print resistance and good rubbing and sanding characteristics. Enamels and lacquers made with Dyal XAN-78 find many applications on such articles as those listed below where high gloss, pale color, moderate heat resistance, and the retention of gloss and color is important: ' 1. Electrical Appliances 2. Stoves 3. Fluorescent Lighting Units 4. Hospital Equipment 5. Venetian Blinds Dyal XAN-78 is compatible in all proportions with most ureas, formaldehyde and mela mine resins. The use of Dyal XAN-78 with melamine tend to give better color. Urea modi fied Dyal XAN-78 vehicle combinations tend to have better adhesion. Dyal XAN-78 is recommended for top coat usage with primer coats based on alkyds such as Dyal XAC-9 and Dyal XAC-76. SPECIFICATIONS Non Volatile50/ Volatile------------------------------- 50% Xylol Lbs. per gal------------------------------------- 835 ViscosityU-W Aliphatic Solv, Tol------------------------- None Solids at E to G Vis43 Color (max.)6 Acid Value7 Phthalic Anhydride42.2% Oil ------ 33.0% Type Oil-------------------------------- .Coconut Other Resin Modifiers_______ None 0007-PMC-000000787 FILM AND PERFORMANCE PROPERTIES Color Color Retention Gloss Gloss Retention Type of Film excellent excellent excellent excellent hard, tough Resistance to: Abrasion Acids Alkali Oil & Gasoline Water Weather good good good excellent excellent fair Compatibility with: Pigments Nitrocellulose f long Alkyds ! medium 1 short f' long \ arnish -J medium 1 short Oils Bodied Oils _ excellent excellent none poor good none none none none none DRYING AND DRIER RECOMMENDATIONS Air Dry--Set Air Dry--Hard Bake none none 300F. to 400F. 10 to 60 min. for Lead Manganese Cobalt Calcium Zinc None required. To be fortified with urea or melamine SUGGESTED FORMULATIONS Melamine White Baking Enamel Lbs. 260.0 117.0 Gals. 8.0 Anatase Ti 02 L. O. 14.0 Dyal XAN-78 388.0 187.0 90.0 46.5 Dyal XAN-78 22.5 Melamine 50% NVM 12.5 Xylol 1042.0 103.5 Roller Mill or W. P. Mixer--6 to 7 Hegman Viscosity No. 4 Ford Cup -- 18" to 20" (25% Red.) Lbs. per gal. -- 9.92 Bake -- 300F. for 30 min. Urea White Baking Enamel Lbs. 250.0 100.0 101.0 Gals. 7.8 12.5 12.0 Anatase Ti 02 L. O. Dyal XAN-78 Urea Resin 50% NVM 367.0 101.0 79.0 21.5 13.5 44.0 12.0 11.0 3.0 2.0 Dyal XAN-78 Urea Resin 50% NVM Toluol Xylol Anhydrous Alcohol 1033.0 1043 Roller Mill or W. P. Mixer--6 to 7 Hegman Viscosity <-- No. 4 Ford Cup -- 22" (25% Red.) Lbs. per gal. -- 9.96 Bake -- 300F. for 30 min. 3-53 0007-PMC-000000788 DYAL XAN-78 TYPE: Short Non Oxidizing Oil Modified Alkyd OUTSTANDING FEATURES: Color Retention, Heat Resistance Dyal XAN-78 is a non oxidizing oil modified alkyd resin designed for use with urea or melamine resins for the production of quality "high bake" enamels. This resin is an outstanding vehicle for finishes which must withstand heat without discoloration. It is superior to Dyal XAC-9 in this respect. However, Dyal XAC-9 finishes will show better adhesion. There are cases where it is advantageous to Wend Dyal XAN-78 with Dyal XAC-9 to get improved adhesion. Dyal XAN-78 may be used as a modifier for a variety of low viscosity, high solids, lacquers and lacquer based materials. The alkyd content imparts improved adhesion, improved cold check resistance, improved print resistance and good rubbing and sanding characteristics. Enamels and lacquers made with Dyal XAN-78 find many applications on such articles as those listed below where high gloss, pale color, moderate heat resistance, and the retention of gloss and color is important. 1. Electrical Appliances 2. Stoves 3. Fluorescent Lighting Units 4. Hospital Equipment 5. Venetian Blinds Dyal XAN-78 is compatible in all proportions with most urea formaldehyde and mela mine resins. The use of Dyal XAN-78 with melamine tends to give better color. Urea modified Dyal XAN-78 vehicle combinations tend to have better adhesion. Dyal XAN-78 is recommended for top coat usage with primer coats based on alkyds such as Dyal XAC-9 and Dyal XAC-76. Non Volatile Volatile Lbs. per gal. Viscosity Aliphatic Solv. Tol._____ Solids at E to G Vis. SPECIFICATIONS 60% 40% Xylol 8A5 none 43 Color fmax.) Acid Value Phthfllic AnhyHriH#* Oil Type 0*1 Other Resin Modifiers f. 7 47 7 none 0007-PMC-000000789 FILM AND PERFORMANCE PROPERTIES Color Color Retention Gloss Gloss Retention Type of Film excellent excellent excellent excellent hard, tough Resistance to: Abrasion Acids Alkali CM & Gasoline Water Weather good good good excellent excellent fair Compatibility with: Pigments Nitrocellulose f long Alkyds -j medium 1 short [long Varnish -1 medium [ short Oils Bodied Oils -- excellent excellent none poor good none none none none none DRYING AND DRIER RECOMMENDATIONS Air Dry--Set Air Dry--Hard Bake none none 300F to 400F for 10 to 60 min. Lead Manganese Cobalt Calcium Zinc None required. To be . fortified with urea or melamine. SUGGESTED FORMULATIONS Melamine White Baking Enamel Lbs. Gals. 260.0 93.6 23.4 8.0 Anatase Ti 02 L. O. 10.9 Dyal XAN-78 3.25 Xylol 310.4 187.0 167.6 36.3 Dyal XAN-78 22.5 Melamine 50% NVM 23.3 Xylol 1042.0 10425 Roller Mill or W. P. Mixer--6 to 7 Hcgman Viscosity No. 4 Ford Cup--18" to 20" Lbs. per gal.- -10.00 (25% Red.) Bake--300F for 30 min. Urea 'White Baking Enamel Lbs. Gals. 250.0 80.0 20.0 101.0 7.8 9.4 2.75 12.0 Anatase Ti 02 L. O. Dyal XAN-78 Xylol Urea Resin 50% NVM 294.0 101.0 79.0 94.5 13.5 34.4 12.0 11.0 13.10 2.0 Dyal XAN-78 Urea Resin 50% NVM Toluol Xylol Anhydrous Alcohol 1033.0 104.45 Viscosity--No. 4 Ford Cup--22" Lbs. per gal.--9.90 (25% Red.) Bake--300F for 30 min. 0007-PMC-000000790 DYAL XAR The DYAL XAR resins are aikyds that are resin modified. They may be color retentive or non color retentive. They may be of the drying or non-drying type. DYAL XAS The DYAL XAS resins are aikyds that are modi fied with styrene. These styrenated aikyds may be color retentive or non-color retentive. 0007-PMC-000000791 I >! A view of a typical alkyd processing instrument panel used by the Sherwin-Williams alkyd resin plants. Modern control is combined with years of processing experience to assure the maximum uniformity in quality that is found in Sherwin-Williams Dyal Resins. 0007-PMC-000000792 TYPE: Short Oil Resin 'Modified Alkyd OUTSTANDING FEATURES: Rapid Set, Excellent Adhesion to Metal, Initial Hardness with Retained Flexibility DYAL XAR-8 The exceptional stability and very fast initial set of Dyal XAR-8 have proven it to be suitable for use as a vehicle in an established line of small package shop finishes. These finishes set up "out of dust" in a matter of several minutes to give finishes of excellent durability, high gloss, excellent adhesion, good flow and- leveling. Finishes made with Dyal XAR-8 can also be expected to have excellent gloss retention, with good initial hardness and retained flexibility. This excellent stability of Dyal XAR-8 has made this vehicle acceptable for dip tank application for air dry and bake production schedules. The current version of Dyal XAR-8 has improved color and color retention to give fuller and cleaner colors and tints. This vehicle can be used as a very fast setting furniture clear for air or low temperature force dry schedules on light or dark woods. The suggested uses for Dyal XAR-8 are the following: 1. Metal Primers 2. Automotive Primers 3. Hardware & Machinery Enamels 4. Drum Enamels 5. Tin & Metal Decorating Enamels 6. Furniture Clears Dyal XAR-8 will be compatible and stable with most pigments. Finishes may be prepared with this vehicle in roller and ball mills. SPECIFICATIONS Non Volatile __50% Volatile35% Xylol - 15% M. S. Lbs. per gal------------------------------------- 7.93 ViscosityU - W Aliphatic Solv. Tol.1000% Solids at E to G Vis.45% Color (max.) 1ft Acid Value5 to 9 Phthalic Anhydride29% Ofl-------------------------------------------------- 35% Type Oil---------------------------------------- Soya Resin ModifiersPresent 0007-PMC-000000793 FILM AND PERFORMANCE PROPERTIES Color Color Retention Gloss Gloss Retention Type of Film good good excellent excellent hard, tough Resistance to: Abrasion Acids Alkali Oil & Gasoline Water Weather excellent good good excellent excellent excellent Compatibility with: Pigments Nitrocellulose [long Alkyds [ medium 1 short f long Varnish 1 medium | short Oils Bodied Oils - good good poor good good poor good good poor poor DRYING AND DRIER RECOMMENDATIONS Air Dry--Set Air Dry--Hard Bake 15 min. 1 5 to 6 hours 225F .to 275F for 20 min. to 40 min. Air Dry Lead 0.3% to 0.5% Manganese 0.01% to 0.03% Cobalt 0.02% to 0.05% Calcium* 0.3% to 0.5% to replace lead , Bake 0-2% none 0.01% 0.02% SUGGESTED FORMULATIONS Gray Baking Primer Lbs. 285.0 190.0 135.0 4.0 4.0 301.0 115.0 .8 Gals. 8.9 5.4 6.1 0.4 0.4 38.0 16.0 0.1 Anatase Ti 02** Ti Barium Whiting Aluminum Stearate Lamp Black Dyal XAR-8 Xylol Anti Skin Agent 143.0 5.0 2.5 63.0 18.0 Dyal XAR-8 0.6 6% Mn Naphthenate 0.3 6% Co Naphthenate 9.0 Xylol 1248.3 103.2 Oil Absorption 26-27 Ball Mill Grind--24 hours This primer is to be force dried 30 min. at 120F Grind--4 to 5 Hegman Lbs. per gal.--12.10 Lbs. 400.0 1.0 198.0 13.0 8.0 2.5 65.0 2.0 254.0 108.0 65.0 1116.5 Gray Drum Enamel Gals. 10.8 Permolith 30M 0.1 Lamp Black 25.0 Dyal XAR-8 - 13 24% Pb Naphthenate 1.0 6% Mn Naphthenate 0.3 6% Co Naphthenate 8.0 Xylol 0.15 Anti Skin Agent 32.0 15.0 10.0 Dyal XAR-8 Xylol Mineral Spirits 103.65 Grind--6 Hegman Grind--16 hours on Ball Mill Lbs. per gal.--10.90 Force Dry--20 min. at 180F 0007-PMC-000000794 DYAL XAR-8 TYPE: Short Oil Resin Modified Alkyd OUTSTANDING FEATURES: Rapid Drying, Excellent Durability, Ease Of Application This short oil resin modified alkyd gives rapid hard through drying and exceptional dura bility. Dyal XAR-8 may be used in quality air dry and baking finishes for spray and dip applications. Other qualities to be noted are its fast set, high gloss and gloss retention, ex cellent adhesion, retained flexibility and good flow and leveling. Dyal XAR-8 will air dry "set-to-touch" in 5 to 10 minutes and will be dried hard in. 3 to 4 hours. Due to the phe nolic modification Dyal XAR-8 is limited to usage in tinted and colored enamel formu lations. Some of the suggested uses of Dyal XAR-8 are: 1. General Air Dry or Bake Finishes 2. Metal Primers 3. Hardware & Machinery Enamels 4. Automotive Refinishing Enamels 5. Hammered Effect Finishes 6. Drum Enamels 7. Tin & Metal Decorating 8. Automotive Chassis Caution should be exercised in the use of reactive pigments with this vehicle. Bases ground or flushed in Dyal XAD-26 may be used with Dyal XAR-8. However, to retain the fast set and through dry of this alkyd it is recommended that the more difficult pigments be ground in a faster setting alkyd such as.Dyal XAC-76. SPECIFICATIONS Non Volatile50% Volatile35% Xylol -- 15% VM&P Lbs. per gal------------------------------------- 8.02 ViscosityU-W Aliphatic Solv. Tol.500% Solids at E to G Vis.45% Color (max.)12 Acid Value___________________ 20 Phthalic Anhydride28% Oil--------------------------------------:--------- 34% Type Oil--------------------------------- .Linseed Resin ModifiersPhenolic 0007-PMC-000000795 FILM AND PERFORMANCE PROPERTIES Color Color Retention Gloss Gloss Retention Type of Film fair fair excellent excellent hard, tough Resistance to: Abrasion Acids Alkali Oil & Gasoline Water Weather excellent good good excellent excellent excellent Compatibility with: Pigments Nitrocellulose Alkyds f long 1 medium 1 short f long Varnish 4 medium 1 short Oils Bodied Oils -- good good poor good good poor good good poor poor DRYING AND DRIER RECOMMENDATIONS Air Dry--Set Air Dry--Hard Bake 15 min. 3 to 4 hours 225F. to 275F. for 20 min. to 40 min. Air Dry Lead 0.3% to 0.5% Manganese 0.01% to 0.03% Cobalt 0.02% to 0.05% Calcium* 0.3% to 0.5% to replace lead Bake 2% none 0.01% 0.02% SUGGESTED FORMULATIONS Gray Baking Primer Lbs. 285.0 190.0 135.0 4.0 4.0 308.0 115.0 .8 Gals. 8.9 5.4 6.1 0.4 0.4 38.0 16.0 0.1 Anatase Ti 02** Ti Barium Whiting Aluminum Stearate Lamp Black Dyal XAR-8 Xylol Anti Skin Agent 146.0 5.0 2.5 63.0 18.0 Dyal XAR-8 0.6 6% Mn Naphthenate 0.3 6% Co Naphthenate 9.0 Xylol 1258.3 103.2 * #*OiI Absorption 26 -- 27 Ball Mill Grind -- 24 hours This primer is to be force dried 30 min. at 120F. Grind -- 4 to 5 Hegman Lbs. per gal. -- 12.10 Lbs. 400.0 1.0 203.0 13.0 8.0 2.5 65.0 2.0 259.0 108.0 65.0 1126.5 Gray Drum Enamel Gals. 10.8 Permolith 30M 0.1 Lampblack 25.0 Dyal XAR-8 1.3 24% Pb Naphthenate 1.0 6% Mn Naphthenate 0.3 6% Co Naphthenate 8.0 Xylol 0.15 Anti Skin Agent 32.0 Dyal XAR-8 15.0 Xylol 10.0 Mineral Spirits 103.65 Grind -- 6 Hegman Grind 16 hours on Ball Mill Lbs. per gal. -- 10.90 Force Dry -- 20 min. at 180F. S-S3 0007-PMC-000000796 TYPE: Short Oil Resin Modified Alkyd OUTSTANDING FEATURES: Low Cost, Durability DYAL XAR-12 Dyal XAR-12 is a low cost resin modified alkyd in the short to medium oil range that is an excellent basic resin for applications where low cost with good durability and quality performance are requirements. Dyal XAR-12 can also be used with other vehicles such as Dyals XAC-42, XAD-26 and XAD-37 to lower cost and to give increased hardness and gloss without the sacrifice of durability, rate of dry or loss of application properties. Finishes made with Dyal XAR-12 can be applied by spray, brush or dip. The use of VM&P naphtha as let-down solvent will improve the set time of Dyal XAR-12 appreciably. Since Dyal XAR-12 has only fair initial color and color retention it is not recommended for use in white enamel formulations. The resin modification of Dyal XAR-12 contributes to its exceptional gloss and gloss retention and its durability. High quality finishes can be prepared with the use of Dyal XAR-12 for the following ap plications: 1. Industrial Farm Implement Enamels Freight and Passenger Car Finishes Drum Enamels Toy Enamels Hardware Enamels Furniture Clears 2. Others Metal Primers Automotive Refinishing Enamels Automotive Chassis Enamels Dyal XAR-12 will set pigments well and will disperse most pigments with little difficulty. The use of guaiacol as the anti-oxidant is not recommended with Dyal XAR-12 because of its deterrent effect on the drying of this vehicle. SPECIFICATIONS Non Volatile---------------- 50% Volatile---------------------------------50% M. S. Lbs. per gal-------------------------------------- 7.62 Viscosity--------------------------------------X - Z2 Aliphatic Solv. Tol----------------------- Infinite Solids at E to GVis------------------------38% Color (max.)14 Acid Value15 Phthalic AnhydridePresent Oil42% Type-Oil_____________________ ___Drying Resin ModifiersPresent 0007-PMC-000000797 FILM AND PERFORMANCE PROPERTIES Color Color Retention Gloss Gloss Retention Type of Film fair fair excellent excellent hard, tough Resistance to: Abrasion Acids Alkali Oil & Gasoline Water Weather good good good good excellent good Compatibility with: Pigments Nitrocellulose [long Alkyds -1 medium [ short f long Varnish -1 medium 1 short Oils Bodied Oils excellent fair good good fair good good fair good fair DRYING AND DRIER RECOMMENDATIONS Air Dry--Set Air Dry--Hard Bake 30 to 60 min. 6 to 8 hours 200F. to 300F. for 45 min. to 2 hours Lead Manganese Cobalt Zinc Air Dry 0.3% to 0.5% 0.01% to 0.03% 0.01% to 0.03% none Bake 0.2% 0.02% 0.02% o.i% SUGGESTED FORMULATIONS Blue Gray Lusterless Enamel Lbs. 106.0 2.0 270.0 4.0 244.0 15.0 75.0 Gals. 3.04 0.13 11.50 0.40 32.00 0.54 13.00 Ti O, Rutile N. C. Lamp Black Soapstone Talc Lecithin Dyal XAR-12 24% Pb Naphthenate VM&P Naphtha 111.0 14.0 155.0 7.0 1.0 14.50 0.70 27.00 0.8 0.10 Dyal XAR-12 6% Mn Naphthenate VM&P Naphtha 6% Co Naphthenate Anti Skin Agent 1004.0 103.54 Ball Mill -- 10 to 12 hours -- 4 Hegman Lbs. per gal. -- 9.70 Application -- Spray (Reduce 25% with VM&P) Red Machine Enamel 90.0 3.0 152.0 1.0 12.0 5.0 56.0 121.0 282.0 - 5.0 71.0 798.0 7.3 0.3 20.0 0.1 1.2 0.6 9.0 16.0 36.0 0.6 11.4 102.5 Para Red 10333 Lecithin Dyal XAR-12 Guaiacol 24% Pb Naphthenate 6% Mn Naphthenate VM&P Naphtha Dyal XAR-12 Dyal XAR-62 6% Co Naphthenate VM&P Naphtha Ball Mill -- 12 hours -- 6 Hegman Grind Lbs. per Gal. -- 7.76 Viscosity No. 4 Ford Cup -- 75" (25% Re duction with VM&P) Set to Touch -- 30 min. Recoat -- 2 to 214 hours 5-33 0007-PM0000000798 TYPE: Short Oil Resin Modified Alkyd OUTSTANDING FEATURES: Fast Set, Low Cost, Aliphatic Tolerance DYAL XAR-13 Dyal XAR-13 is a short length phenolated alkyd resin that sets up rapidly to give extremely fast air drying and baking films. This rapid setting and drying makes Dyal XAR-13 appli cable to many industrial air dry, force dry and bake schedules where time is the prime con sideration. Dyal XAR-13 offers low cost, good aliphatic solvent tolerance and hard gloss retentive films of good durability. Because of its very short oil length, Dyal XAR-13 will give films that are extremely hard and mar-resistant. Finishes made with this resin can be applied by spray or dip. Dyal XAR-13 has only fair initial color and has poor color retention because of its phenol modification; therefore, this resin is not recommended for use in white enamel formula tions. For air dry and bake schedules this resin may be used in light tints. A few of the recommended applications are the following: 1. Drum Enamels 2. Toy Enamels 3. Hardware Enamels .4 Furniture Clears 5. Metal Primers 6. Automotive Chassis Enamels Because of the very fast solvent used in Dyal XAR-13, pebble and ball milling are recom mended in preference to roller milling for pigment dispersion. Reactive pigments should not be used with this high acid vehicle. The more reactive pigments may be dispersed in Dyal XAC-76 and let down with Dyal XAR-13 without effecting too great a change in drying properties. SPECIFICATIONS Non Volatile____________ ____ ___ 50% Volatile.......... 15% Xylol -- 35% VM&P Lbs. per gal________________________ 7.70 Aliphatic Solv. TolInfinite Viscosity __________________ _____ __.Z - Z > Solids at E to G Vis___________ ____ 35% Color (max.) 13 Acid Value____________ ________ 24 to 30 Phthalic Anhydride!29% Ofi_________________________ ____ 30% Type Oil--------------------------------- Drying Resin Modifiers __________ Present 0007-PMC-000000799 FILM AND PERFORMANCE PROPERTIES Color Color Retention Gloss Gloss Retention Type of Film fair poor excellent excellent hard, mar proof Resistance to: Abrasion Acids Alkali Oil & Gasoline Water Weather good good fair good good fair Compatibility with: Pigments Nitrocellulose f long Alkyds 4 medium 1 short f long Varnish j medium J short Oils Bodied Oils fair none none fair good none fair fair fair fair DRYING AND DRIER RECOMMENDATIONS Air Dry--Set Air Dry--Hard Bake 5 min. 90 min. 15 to 60 min. at 140 to 260F. Air Dry Lead Manganese Cobalt Calcium* 0.2% to 0.4% 0.01% to 0.03% 0.02% to 0.04% none to replace lead Bake none 0.02% 0.02% 0.02% SUGGESTED FORMULATIONS Gray Drum Enamel Lbs. Gals. 146 4.2 Rutile Ti 02** 120 3.3 Lithopone-Med. Consis tency 2 0.2 Lampblack 1 0.1 Aluminum Stearate 293 38.0 Dyal XAR-13 316 41.0 Dyal XAR-13 94 15.0 VM&P Naphtha 2 0.2 24% Pb Naphthenate 2 0.2 6% Co Naphthenate 974 102.2 Oil Absorption 17-18 Roller Mill Grind -- 5 to 6 Hegman Viscosity No. 4 Ford Cup -- 25" to 35" (25% to 35% Red. with VM&P) Wt. per gal -- 9.60 Air Dry to Handle -- 60 min. Force Dry -- 180F. -- 20 min. Quick Drying Lusterless Blue Enamel Lbs. Gals. 96 2.75 Ti O., RNC 4 .25 C P Chinese Blue 11023 1 -- Micro-Fast Chrome Green 11232 253 10.8 Soapstone Talc 4 .4 Yelkin TTS 266 35.0 Dyal XAR-13 99 3 4.5 249 2 13.0 0.3 0.6 40.0 .25 Dyal XAR-13 24% Pb Naphthenate 6% Co Naphthenate VM&P Guaiacol 986.5 103.35 Roller Mill Grind -- 4 Hegman Wt. per gal. -- 9.50 5-S3 0007-PMC-000000800 TYPE: Short Oil Resin Modified Alkyd OUTSTANDING FEATURES: Fast Set, Low Cost, Aliphatic Tolerance DYAL XAR-13 Dyal XAR-13 is a short length phenolated alkyd resin that sets up rapidly to give extremely fast air drying and baking films. This rapid setting and drying makes Dyal XAR-13 applicable to many industrial air dry, force dry and bake schedules where time is the prime consideration. Dyal XAR-13 offers low cost, good aliphatic solvent tolerance and hard gloss retentive films of good durability. Because of its very short oil length, Dyal XAR-13 will give films that are extremely hard and mar-resistant. Finishes made with this resin can be applied by spray or dip. Dyal XAR-13 has only fair initial color and color retention because of its phenol modifi cation; therefore, this resin is not recommended for use in white enamel formulations. For air dry and bake schedules this resin may be used in light tints. A few of the recommended applications are the following: 1. Drum Enamels 2. Toy Enamels 3. Hardware Enamels .4 Furniture Clears 5. Metal Primers .6 Automotive Chassis Enamels Because of the very fast solvent used in Dyal XAR-13, pebble and ball milling are recommended in preference to roller milling for pigment dispersion. Reactive pigments should not be used with this high acid vehicle. The more reactive pigments may be dispersed in Dyal XAC-76 and let down with Dyal XAR-13 without effecting too great a change in drying properties. SPECIFICATIONS Non Volatile----------------------------------60% Volatile.20% Xylol - 20% VM&P Lbs. per Gal----------------------------------- 8.05 Aliphatic Solv. Tol----------------------Infinite Viscosity------------------------------------- Z3 - Z5 Solids at E-G Vis (in VM&P38% Color (max.) Acid Value Phthalic Anhydride Oil . . . Type Oil Resin Modifiers V) in tv, ?n - - -29%% lfi/ Present 0007-PMC-000000801 FILM AND PERFORMANCE PROPERTIES Color Color Retention Gloss Gloss Retention Type of Film fair fair excellent excellent hard, mar proof Resistance to: Abrasion Acids Alkali Oil & Gasoline Water Weather good good fair good good fair Compatibility with: Pigments Nitrocellulose (long Alkyds ( medium | short f long Varnish 4 medium | short Oils Bodied Oils fair none none fair good none fair fair fair fair DRYING AND DRIER RECOMMENDATIONS Air Dry--Set Air Dry--Hard Bake 5 min. 90 min. 15 to 60 min. at 140 to 260F Air Dry Lead 0.2% to 0.4% Manganese 0.01% to 0.03% Cobalt 0.02% to 0.04% Calcium* none to replace lead Bake none 0.02% 0.02% 0.02% SUGGESTED FORMULATIONS Lbs. 146.0 120.0 2.0 59.0 234.0 251.0 159.0 2.0 2.0 976.0 Gray Drum Enamel Gals. 4.2 Rutile Ti 02** 3.3 Lithopone-Med. Con sistency 0.2 Lampblack 9.45 VM&P Naphtha 29.0 Dyal XAR-13 31.1 Dyal XAR-13 25.55 VM&P Naphtha 0.2 24% Pb Naphthenate 0.2 6% Co Naphthenate 1033 **Oil Absorption 17-18 Roller Mill Grind--5 to 6 Hegman Viscosity No. 4 Ford Cup--25" to 35" (25% to 35% Red. with VM&P) Wt. per gal.--9.45 Air Dry to Handle--60 min. Force Dry--180F --20 min. Quick Drying Lusterless Blue Enamel Lbs. Gals. 96.0 4.0 1.0 258.0 53.0 213.0 2.75 25 -- 10.8 8.5 26.5 Ti Os RNC C P Chinese Blue 11023 Micro-Fast Chrome Green 11232 Soapstone Talc VM&P Naphtha Dyal XAR-13 80.0 3.0 4.5 269.0 2.0 9.95 0.3 0.6 43.0 25 Dyal XAR-13 24% Pb Naphthenate 6% Co Naphthenate VM&P Naphtha Guaiacol 987.5 10330 Roller Mill Grind--4 Hegman Wt. per gal.--9.55 0007-PMC-000000802 DYAL XAR-7 & DYAL XAR-19 TYPE: Resin Modified Wrinkle Finish Alkyds OUTSTANDING FEATURES: Uniformity, Adhesion, Toughness These resin modified alkyds, Dyal XAR-7 and Dyal XAR-19, were developed for use in wrinkle finishes. Dyal XAR-7 is a wood oil alkyd that is characterized by a uniform pattern and high gloss. Dyal XAR-19 is a longer oil modification of Dyal XAR-7 having consider ably more wrinkling power in its film, higher relief and a finer and duller pattern. It is then possible to obtain any desired wrinkle finish by the use of combinations of Dyal XAR-7 and Dyal XAR-19. Experience has shown that these combinations of Dyal XAR-7 and Dyal XAR-19 show no appreciable change in wrinkling characteristics upon aging. In the formulation of wrinkle finishes with Dyal XAR-7 and Dyal XAR-19 reasonably large quantities of top driers should be used. For good uniformity of wrinkle the drier combi nation should contain from 0.05% to 1.0% of cobalt metal based on total resin solids. 0.02% to 0.04% of manganese may also be used to aid the through drying of these resins. The amounts of adulterating vehicles introduced in shading bases should be kept at a mini mum to insure maximum uniformity. Due to the high acid values of Dyal XAR-7 and Dyal XAR-19, they are not recommended for use with reactive pigments. Dyal XAR-7 is somewhat more versatile than Dyal XAR-19 because of its shorter oil length. It is possible to formulate exceptionally good, fast setting and drying, high gloss enamels with Dyal XAR-7. The phenol modification of this resin will give topcoats and undercoaters with excellent hardness, adhesion and water resistance. Dyal XAR-7 has good compatibility with most amine resins. Baking finishes may be made with or without amine modifications. SPECIFICATIONS Dyal XAR-7 Non Volatile----------------------------------- 50% Volatile.-------- 18% Xylol -- 32% VM&P Lbs. per gal.------------------------------------- 7.73 ViscosityT-V Aliphatic Solv. Tol-------------------------- 50% Solids at E to G Vis------------------------ 38% Color (max.)12 Acid Value25-30 Phthalic AnhydridePresent Oil42% Type OilC. W. o! Resin Modifiers.Present Dyal XAR-19 Non Volatile----------------------------------- 55% Volatile--------- 30% Xylol -- 15% VM&P Lbs. per gal------------------------------------- 7.76 Viscosity---------------------------------------- G-I Aliphatic Solv. Tol-------------------------150% Solids at E to G Vis-------------------- 50% Color (max.)14 Acid Value40-50 Phthalic Anhydride.Present Oil51% Type OilC. W. O. Resin Modifiers Present 0007-PMC-000000803 FILM AND PERFORMANCE PROPERTIES XAR-7 Color Color Retention Gloss Gloss Retention Type of Film fair fair excellent excellent hard, tough Resistance to: Abrasion Acids Alkali Oil & Gasoline Water Weather good good good excellent excellent good XAR-19 fair fair XAR-7 Compatibility with: Pigments fair Nitrocellulose fair tough Akyds f long poor j medium fair | short fair good good good excellent excellent good f long Varnish < medium 1 short Oils Bodied Oils poor poor fair fair poor XAR-19 fair fair poor fair fair poor poor fair fair poor DRYING AND DRIER RECOMMENDATIONS Dyal XAR-7 (Gloss Finish) Air Dry--Set 15 min. Air Dry--Hard 3 to 4 hours Bake 300F. for 30 min. GLOSS Air Dry Lead 03% Manganese 0.02% Cobalt 0.02% Bake 0.2% 0.01% 0.01% WRINKLE Bake 0-1% 0.03% to 1.0% Dyal XAR-7 & Dyal XAR-19 (WrinkleFinishes) Bake 300 F. for 30 min. SUGGESTED FORMULATIONS Lbs. 33.0 33.0 2.0 191.0 84.0 2.0 355.0 6.0 5.0 115.0 1.0 1.0 828.0 Green Dipping Enamel Gals. 0.9 1.5 0.2 Micro-Fast Chrome Green Lt. 12132 Micro-Fast Chrome Green Dk. 12135 Lecithin 25.0 11.0 0.2 46.0 0.6 0.6 16.0 0.1 0.1 Dyal XAR-7 Xylol Anti Skin Agent Dyal XAR-7 24% Pb Naphthenate 6% Co Naphthenate Xylol Guaiacol Silicone Solution 102.2 Ball Mill -- 20 hours for 6 Hegman Grind 25% Reduction with Xylol or VM&P Bake -- 325F. for 10 min. Viscosity -- 90" to 102" -- No. 4 Ford Cup Lbs. per gal. -- 8.10 Lbs. 7.0 5.0 35.0 2.0 166.0 34.0 2.0 198.0 202.0 16.0 101.0 36.0 804.0 Black Wrinkle Finish Gals. 0.5 Lampblack 0.3 Carbon Black, Med. Color 1.9 Magnesium Carbonate 0.2 Lecithin 21.0 Dyal XAR-19 4.7 Xylol 0.2 Guaiacol 25.0 Dyal XAR-19 26.5 Dyal XAR-7 1.8 6% Co Naphthenate 16.3 VM&P Naphtha 5.0 Toluol 103.4 Roller Mill Grind -- 4 Hegman Viscosity No. 4 Ford Cup -- 65" to 75" Bake -- 225F. to 250F. for 30 min. Bake-- I. F. at 250F. for 10 min. Spray Application s-sa 0007-PMC-000000804 TYPE: Medium Oil Phenolic Modified Alkyd OUTSTANDING FEATURES: Exterior Durability, Fast Set, Good Dry DYAL XAR-62 Dyal XAR-62 is an excellent fast drying medium length pure phenolic modified alkyd. Finishes made with Dyal XAR-62 exhibit excellent exterior durability, toughness, flexi bility, along with mar and scratch resistance. These properties have made this alkyd espe cially suitable for use as a vehicle for automotive finishes^ Finishes using Dyal XAR-62 may be air dried, force dried, or baked. This alkyd was de veloped for spray application; however, it may be used in dip and flow-coat applications by adjustment of the solvent combination of the final finish. Dyal XAR-62 has been found to be extremely useful in the following applications: 1. Automotive Enamels 2. Farm Implement Enamels 3. Truck Finishes 4. Railway Passenger Car Finishes 5. Tractor Finishes Dyal XAR-62 should not be used with extremely reactive pigments. Ball mill dispersion is recommended when possible. Finishes of excellent quality and performance may be pre pared using Dyal XAD-26 or Dyal XAC-76 as the grinding medium along with Dyal XAR-62 as the let-down vehicle. SPECIFICATIONS Non Volatile50% Volatile35% Xylol -- 15% VM&P Lbs. per gal7.83 ViscosityT - V Aliphatic Solv. Tol._100% Solids at E to G Vis.42.6% Color (max.)12 Acid Value10 Phthalic Anhydride29.6% Oil ___ _51.7% Type Gil------------------------------Soya, Tung Resin Modifiers-------------- Phenolic Resins 0007-PMC-000000805 FILM AND PERFORMANCE PROPERTIES Color Color Retention Gloss Gloss Retention Type of Film good good excellent excellent hard, flexible Resistance to: Abrasion Acids Alkali Oil & Gasoline Water Weather excellent good good excellent excellent excellent Compatibility with: Pigments Nitrocellulose f long Alkyds { medium [ short [ long Varnish { medium [ short Oils Bodied Oils fair fair fair good fair fair good fair fair fair DRYING AND DRIER RECOMMENDATIONS Air Dry--Set Air Dry--Hard Bake 15 min. 3 to 4 hours 220F. to 280F. 30 to 60 min. for Lead Manganese . Cobalt Calcium Zinc Air Dry 0.3% to 0.5% 0.07% to 0.13% 0.02% to 0.05% 0.1% to 0.3% none Bake 0.15% 0.03% 0.02% none 0-2% SUGGESTED FORMULATIONS Orange Transport Enamel Lbs. Gals. 120.0 2.1 C P Chrome Orange 12082 118.0 15.0 Dyal XAR-62 32.0 21.6 9.6 1.0 5.0 Mineral Spirits 3.0 High Solvency Naphtha 1.0 24% Pb Naphthenate 0.15 Anti Skin Agent 482.0 88.0 4.0 2.4 7.8 61.5 13.5 0.5 0.3 1.0 Dyal XAR-62 Mineral Spirits 6% Co Naphthenate 6% Mn Naphthenate 4% Ca Naphthenate 886.4 103.05 Viscosity No. 4 Ford Cup -- 60" to 75" Lbs. per gal. -- 8.60 Spray: Reduce with Xylol or combination of Xylol and High Solvency Naph tha 20% to 30%. Dry: Slight Tack -- !4 hour Dry -- 4 to 6 hours Grind, Roller Mill -- 6 to 7 Hegman Prairie Gold Implement Enamel Lbs. Gals. 274.0 5.45 C P Chrome Yellow 12152 18.0 0.44 Lt. Red Iron Oxide (98% Fe?03) 3.0 0.34 Soya Lecithin 157.0 20.0 Dyal XAR-62 360.0 10.0 6.0 5.0 5.0 112.0 71.0 46.0 1.5 0.85 0.65 0.65 18.0 9.85 Dyal XAR-62 Guaiacol 15% Sol'n. 24% Pb Naphthenate 6% Mn Naphthenate 6% Co Naphthenate VM&P Xylol 1021.0 103.7 Viscosity No. 4 Ford Cup -- 65" to 75" Lbs. per gal. -- 9.81 Grind, Roller Mill -- 6 to 7 Hegman 5-53 0007-PMC-000000806 TYPE: Medium Length Resin Modified Alkyd OUTSTANDING FEATURES: Drying, Exterior Durability DYAL XAR-C6 Dyal XAR-C6 was developed specifically for use as a transportation finish vehicle. At higher cost than Dyal XAR-62, this vehicle will offer better drying especially under condi tions of high humidity. Finishes employing this vehicle will exhibit fast set, hard through dry and fast tape time. The phenolic resin modifier assures excellent durability, gloss and gloss retention. Aliphatic tolerance is limited to 100% due to the resin modification. There fore, a coal-tar solvent is recommended for obtaining full advantage of the outstanding properties of Dyal XAR-C6. With the suggested drier recommendations, enamels made with Dyal XAR-C6 will be "set to touch" within 10 minutes and they will "tape" within 5 to 6 hours. Some of the uses for Dyal XAR-C6 are as follows: 1. Automotive & Truck Refinishing Enamels 2. Railway Finishes 3- Metal Primers .4 Toy Enamels Finishes made with this vehicle will have good package stability if fortified with small amounts of anti skin agent or guaiacol. With the more reactive pigments it is also advisable to use approximately one-half percent of triethylamine. SPECIFICATIONS Non Volatile---------------------------------- 50% Color (max.)___________ _____________12 Volatile--------- 30% Xylol -- 20% VM&P Acid Value12 Lbs. per gal._____________ __________7.83 Phthalic Anhydride29% Viscosity-------------------------------------- U - X Oil52% Aliphatic Solv. Tol.__________ 100% Type OilLinseed Solids at E to G Vis42% Resin Modifiers.Phenolic 0007-PMC-000000807 FILM AND PERFORMANCE PROPERTIES Color Color Retention Gloss Gloss Retention Type of Film good good good excellent tough, hard, flexible Resistance to: Abrasion Acids Alkali Oil & Gasoline Water Weather excellent good good excellent excellent excellent Compatibility with: Pigments Nitrocellulose f long Alkyds -l medium ( short f long Varnish -( medium ( short Oils Bodied Oils good good fair good poor fair good poor fair fair DRYING AND DRIER RECOMMENDATIONS Air Dry--Set Air Dry--Hard Bake 10 min. 5 to 6 hours 200F. to 300"F. 30 to 60 min. Lead Manganese Cobalt Zinc Air Dry 0.2% to 0.4% none 0.03% to 0.05% none Bake 0.1% none 0.01% 0.02% SUGGESTED FORMULATIONS Blue Freight Car Enamel Lbs. Gals. 27.0 1.8 Milori Blue 26.0 0.7 Ti 02 Rutile 6.0 0.2 Ferrite Yellow Lemon 3.0 130.0 9.6 12.0 No. 305 0.4 Calcium Stearate 17.0 Dyal XAD-26 1.0 24% Pb Naphthenate 1.75 Methyl Ethyl Ketoxime (17% Sol'n.) 161.0 305.0 3.7 31.0 1.7 52.0 22.0 3.0 21.0 Dyal XAD-26 39.0 Dyal XAR-C6 0.5 6% Mn Naphthenate 4.0 Phenolic Resin Sol'n.* 0.25 6% Co Naphthenate 8.0 Mineral Spirits 3.0 High Flash Naphtha 0.5 Triethylamine 793.0 99.10 Viscosity No. 4 Ford Cup -- 90" to 115" Lbs. per gal. -- 7.95 *45% NVM Dark Gray Automotive Enamel Lbs. Gals. 42.0 1.2 Ti 02 Rutile N. C. 10.5 0.7 Lamp Black 50.0 6.6 Dyal XAD-26 550.0 13.0 4.0 10.0 3.0 3.0 110.0 30.0 70.0 Dyal XAR-C6 1.4 24% Pb Naphthenate 0.5 6% Co Naphthenate 1.1 8% Mn Naphthenate 0.3 Guaiacol 0.3 Anti Skin Agent 17.0 Mineral Spirits 4.2 Solvent Naphtha 825.5 103.3 Roller Mill -- 6 Hegman Grind Lbs. per gal. -- 8.00 Application -- Spray or Brush Reduction 25% for Spray Air Dry or Bake 5-53 0007-PMC-000000808 DYAL XAR-C9 TYPE: Short Oil Resin Modified Alkyd OUTSTANDING FEATURES: Rapid Dry, Outstanding Chemical Resistance Dyal XAR-C9 is an extremely fast drying short oil straight 100% phenolic resin modified alkyd. Dyal XAR-C9 with its extremely fast set and drying, may be applied by spray, or dip, to give films that are hard, tough and durable and possess exceptional chemical resistance. This rapid drying and excellent chemical resistance make~Dyal XAR-C9 extremely useful as a vehicle for fast setting primers and primer surfacers. The high phenolic resin modifi cation insures excellent gloss retention; however, it limits the use of Dyal XAR-C9 to col ored enamels because of its poor color retention. Dyal XAR-C9 may be formulated into air dry and low bake finishes that will conform to any type of high speed production line schedules which may be required for the following applications: > 1. General Industrial Air Dry and Baking Enamels 2. Metal Primers 3. Truck Finishes 4. Metal Cabinets 5. Toy Enamels 6. Drum Enamels Reactive pigments should be handled with extreme care when used with Dyal XAR-C9. The more reactive pigments should be ground in Dyal XAC-76 and let down with Dyal XAR-C9. Grinding should be done in ball or pebble mills. SPECIFICATIONS Non Volatile.................................... .....50% Volatile---------------------------------50% Xylol Lbs. per gal_____________________ ___8.25 ViscosityU - V Aliphatic Solv. Tol________100% to 200% Solids at E to G Vis____________ ___40% Color (max.) ____ Acid Value _______ Phthalic Anhydride Oil ______________ Type Oil _________ Resin Modifiers___ _____12 _____ 20 ------30% ------ 28% ..Drying Phenolic 0007-PMC-000000809 FILM AND PERFORMANCE PROPERTIES Color Color Retention Gloss Gloss Retention Type of Film fair poor excellent excellent short, hard, tough Resistance to: Abrasion Acids Alkali Oil & Gasoline Water Weather good excellent good excellent excellent good Compatibility with: Pigments Nitrocellulose Alkyds f long -1 medium | short f long Varnish medium [ short Oils Bodied Oils fair fair poor fair fair poor fair fair poor poor DRYING AND DRIER RECOMMENDATIONS Air Dry--Set Air 9ry--Hard Bake 5 min. 90 to 180 min. 5 min. at 300F. to 30 min. at 200F. Lead Manganese Cobalt Air Dry 0.2% to 0.5% 0.02% to 0.04% 0.03% to 0.05% Bake 0.02% 0.01% 0.01% SUGGESTED FORMULATIONS lbs. 285.0 190.0 135.0 4.0 4.0 314.0 115.0 0.8 129.0 6.0 2.5 65.0 1148.3 Gray Baking Primer Gals. 8.9 Anatase Ti O,** 5.4 Ti Barium 6.1 Whiting 0.4 Aluminum Stearate 0.4 Lampblack 38.0 Dyal XAR-C9 16.0 Xylol 0.1 Anti Skin Agent 18.0 Dyal XAR-C9 0.6 6% Mn Naphthenate 0.3 6% Co Naphthenate 9.0 Xylol 1032 **Oil Absorption 26 to 27 This primer to be force dried 30 min. at 120F. Grind Ball Mill -- 4 Hegman Viscosity -- 60" to 80" No. 4 Ford Cup Wt. per gal. -- 11.10 lbs. 53.0 30.0 4.0 206.0 16.0 6.5 57.0 380.0 100.0 7.0 7.0 866.5 Blue Equipment Enamel Gals. 3.5 C P Milori Blue 11086 1.0 Ti Cal, Rutile, N. C. 0.3 Soya Lecithin 25.0 Dyal XAR-C9 1.7 24% Pb Naphthenate 1.0 Anti Skin Agent 8.0 Xylol 46.0 14.0 1.0 1.0 Dyal XAR-C9 Xylol 6% Mn Naphthenate 6% Co Naphthenate 103.5 Viscosity -- No. 4 Ford Cup -- 90" to 115" Wt. per gal. -- 8.37 Grind Ball Mill -- 6 Hegman Reduction for Spray -- 25% VM&P Bake -- 3 to 5 Min. at 300F. S-33 0007-PMC-000000810 DYAL XAR-C11 TYPE: Medium Length Soya Resin Modified Alkyd OUTSTANDING FEATURES: Compatibility, High Solids, Low Cost Dyal XAR-C11 is a resin modified alkyd that was developed for use as a flushing or grind ing vehicle. Its success in that usage has been due to its wide range of vehicle and pigment compatibility, good drying properties and minimum effect on the drying of medium and short oil alkyds. The high non-volatile content of this vehicle increases its general utility and permits formulation of bases with a broad range of usage. Bases prepared with Dyal XAR-C11 may be used in air dry or bake applications. Dyal XAR-C11 is resin modified and therefore it is not recommended for use as a base vehicle for white enamels. However, this soya oil alkyd will give satisfactory color retention when used in tinting colors to make pastel finishes from white bases. The usual precaution of adding the proper anti-oxidants to bases made with this alkyd should be taken in order to insure stability and prevent skinning. The only anti-oxidant that is presently recommended for use with Dyal XAR-C11 is methyl ethyl ketoxime, which should be used in concentration of from 0.02% to 0.04% based on the vehicle solids. SPECIFICATIONS Non Volatile------------------------------------90% Volatile---------------------------------10% M. S. Lbs. per gal-------------------------------------- 837 Viscosity------------------------------------ Z to Z2 Aliphatic Solv. Tol------------------- Infinite Solids at E to G Vis-------------------------70% Color (max.)12 Acid Value10 Phthalic AnhydridePresent Oil54% Type Oil__________________________ Soya Resin ModifiersPresent 0007-PMC-000000811 FILM AND PERFORMANCE PROPERTIES Color Color Retention Gloss Gloss Retention Type of Film good good good excellent tough, hard, flexible Resistance to: Abrasion Adds Alkali Oil & Gasoline Water Weather good good good good excellent excellent Compatibility with: Pigments Nitrocellulose long. Alkyds medium short long Varnish - medium short Oils Bodied Oils excellent limited excellent excellent good excellent excellent good excellent good DRYING AND DRIER RECOMMENDATIONS Air Dry--Set Air Dry--Hard Bake V/2 hours 6 to 8 hours 240F. to 260F. 60 min. to 90 min. t Lead Air Dry 0.3% to 0.6% Manganese 0.0% to 0.06% Cobalt 0.03% to 0.06% Calcium* 0.3% to 0.6% *to replace lead Bake 02% 0.2% 02% none SUGGESTED FORMULATIONS Lbs. 63.8 47.9 28.0 500.0 110.0 21.3 14.5 8.0 1.0 794.5 Toluidine Red Enamel Gals. 5.5 5.7 43 Toluidine Red 10451 Dyal XAR-C11 Mineral Spirits** 66.0 17.0 3.0 1.5 1.0 0.1 Dyal XAC-1*** Mineral Spirits Dipentene 24% Pb Naphthenatc 6% Co Naphthenate Anti Skin Agent 104.1 Base Formulation Base Let Down Viscosity -- Stormer K. U. -- 68 Lbs. per gal. -- 7.80 Lbs. 239.4 54.2 222 495.0 104.0 213 9.6 4.0 1.0 950.7 Chrome Yellow Enamel Gals. 5.5 C P Chrome Yellow 12147 6.5 Dyal XAR-C11 3.4 Mineral Spirits** 66.0 Dyal XMD-6*** 16.0 Mineral Spirits 3.0 Dipentene 1.0 24% Pb Naphthenate 0.5 6% Co Naphthenate 0.1 Anti Skin Agent 102.0 **Base Formulations Base Let Down Viscosity -- Stormer K. U. -- 69 Lbs. per gal. -- 9.30 0007-PMC-000000812 TYPE: Styrenated Alkyd OUTSTANDING FEATURES: Fast Set, Rapid Thru Dry, Color Retention, Excellent Durability, Excellent Stability DYAL XAS-4 Dyal XAS-4 is a styrene modified alkyd that is fast setting and dries rapidly to give films that possess excellent durability, hardness, gloss, color, and color retention. Finishes made with Dyal XAS-4 have good stability and may be used for spray or dip applications which may be air dried, force dried or baked. Air dried and baked films of Dyal XAS-4 finishes are tough and show good adhesion over metal, paper and wood. Styrenated alkyds inherently show poor solvent resistance and present a problem in recoatability. Air dried finishes made with Dyal XAS-4 may be recoated in 30 to 120 minutes but not after that until 48 hours have elapsed. After 48 hours films of Dyal XAS-4 show reason ably good gasoline resistance. Dyal XAS-4 has proven to be very useful in the preparation of enamels to meet the require ments of Specification MIL-E-10689. Dyal XAS-4 is recommended for use as a grinding and let down vehicle in enamels covered by this specification. This gready simplifies form ulation, vehicle handling and vehicle inventories. Dyal XAS-4 is also recommended for the following usage: 1. Metal and Wood Cabinet Enamels 2. One Coat Hammer Finishes 3. Implement Enamels 4. Toy Enamels 5. Furniture Clears Highly reactive pigments, especially Zinc Oxide, should not be used in enamels made with Dyal XAS-4. Pigments may be ground in Dyal XAS-4 by any of the usual methods. Small amounts of pine oil and soya lecithin will improve the pigment wetting characteristics of this vehicle. The recommended drier combination will give good mill and package stability. Dip tank and package stability may be improved by the addition of a small percentage of the usual anti-oxidants. SPECIFICATIONS Non Volatile_______________________50% Volatile:_____________________ 50% Xylol Lbs. per gal7.99 -- 8.09 Viscosity __________________ ______ O - R Aliphatic Solv. Tol.... ........... 200% Solids at E to G Vis..... ......................40% Color (max.)8 Acid Value10-20 Phthalic AnhydridePresent Oil ------------------------------------------ 32% Type Oil------ ------------------------- ---Drying Resin Modifiers__________________ None 0007-PMC-000000813 FILM AND PERFORMANCE PROPERTIES Color Color Retention Gloss Gloss Retention Type of Film good excellent excellent excellent hard, tough Resistance to: Abrasion Acids Alkali Oil & Gasoline Water Weather good good good good excellent good Compatibility with: Pigments Nitrocellulose ( long Alkyds medium 1 short 1 long Varnish medium [ short Oils Bodied Oils _ good poor none none fair none none fair fair none DRYING AND DRIER RECOMMENDATIONS Air Dry--Set Air Dry--Hard Bake 5 to 15 min. 90 min. 15 to 30 min. at 300F. Air Dry Bake Lead 0.2% to 0.4% none Manganese* 0.02% to 0.04% 0.03% Cobalt 0.02% to 0.04% none Manganese is not absolutely necessary how ever, it will enhance drying. SUGGESTED FORMULATIONS Lbs. 165 115 1 161 8 58 372 65 56 1 4 3 1019 White Cabinet Enamel Gals. 4.7 Titanium Calcium 3.8 Ti O, 0.1 Soya Lecithin 20.1 Dyal XAS-4 1.0 Pine Oil 8.0 Xylol** 46.0 9.0 9.0 0.1 0.4 0.4 Dyal XAS-4 Xylol C-8 Naphtha Guaiacol 24% Pb Naphthenate 6% Co Naphthenate 103.5 **For Roller Mill grinds add this solution in let down Viscosity No. 4 Ford -- 49 seconds Air Dry -- Hard -- 30 to 35 min. Gloss Photocell -- 89 Wt. per gal -- 9.87 Green Hammered Effect Enamel Lbs. Gals. 20 1.70 Non Leafing Aluminum 9 0.80 Flushed Solfast Green FL-346 32________ 4.00 Dyal XAS-4 607 75.50 Dyal XAS-4 7 1.00 Heavy Mineral Oil 2 0.25 Silicone Solution 58 8.00 Xylol 50 8.00 C-8 Naphtha 5 0.65 6% Co Naphthenate 1 0.10 Guaiacol 791 100.00 Mix all materials above line until smooth paste is obtained. Then let down with the remainder of the materials. Strain. Wt. per gal. -- 7.90 Air Dry, Force Dry, or Bake Spray Full Body 5-33 0007-PMC-000000814 DYAL XAS-8 TYPE: Styrenated Alkyd OUTSTANDING FEATURES: Low Cost, Recoatability, Gasoline Resistance, Fast Set, Rapid Thru-Dry Dyal XAS-8 is a lower cost version of Dyal XAS-4 which possesses most of the desirable characteristics of the latter. In addition, Dyal XAS-8 offers gready improved gasoline resistance. Gasoline resistance, which is of major importance in specifications, was investigated thru a series of tests that conformed to specification TT-P-141A. These tests revealed Dyal XAS-8 to have gasoline resistance equivalent to, or better than, other more expensive styrenated alkyds. It also compared very favorably against a vinyl-toluene type vehicle. Clear and pigmented films of Dyal XAS-8 have shown excellent gasoline resistance after only 7 hours of air-dry time. Enamels made with Dyal XAS-8 were recoated after 1, 2, 4, 8 and 16 hours air-dry time without effect on gloss or lifdng of the film. This vehicle is manufactured in a way which gives a product essentially free of monomeric or dimeric styrene, which accounts for the excellent recoating properties. Dyal XAS-8, like Dyal XAS-4, possesses excellent stability with or without driers. There fore, it can be used in spray, dip or flow-coat applications. Maintenance of dip tanks when using fast-setting Dyal XAS-8 requires only normal amounts of anti-oxidants along with the regular replacement of lost solvent. SPECIFICATIONS Non Volatile50% Color (max.);9 Volatile------------ 20% VM&P, 30% Xylol Acid Value10-20 Lbs. per gal.---------------------------------- 7.80 Phthalic Anhydride_..Present ViscosityT - W Oil....................... 32% Aliphatic Solv. Tol.------------------------50% Type Oil __________ Drying Solids at E to G Vis.----------------------38% Resin Modifiers.None 0007-PMC-000000815 FILM AND PERFORMANCE PROPERTIES Color Color Retention Gloss Gloss Retention Type of Film (air dry) Type of Film (bake) good good good good hard, short hard, tough Resistance to: Abrasion Acids Alkali Oil & Gasoline Water Weather good excellent good excellent excellent good Compatibility with: Pigments Nitrocellulose Hong Alkyds ( medium 1 short pong Varnish ! medium (short Oils Bodied Oils good poor poor poor fair poor poor poor fair none DRYING AND DRIER RECOMMENDATIONS Air Dry--Set Air Dry--Hard Bake 5 to 10 min. V/2 to 1)4 hours 15 to 30 min. at 250-275 F Air Dry Bake Lead 0.2% to .0.4% none Manganese* 0.02% to 0.04% 0.03% Cobalt 0.02% to 0.04% none Manganese is optional,' however it will enhance drying somewhat. SUGGESTED FORMULATIONS Green Implement Enamel Lbs. 58.0 58.0 3.0 5.0 42.0 Gals. 1.38 Chrome Green Light 138 Chrome Green, Extra Lt. 0.30 Soya Lecithin 0.65 6% Mn Naphthenate 6.00 Xylol Grind 6 hours or to 6H Add and Grind 15 minutes 65.0 8.00 Dyal XAS-8 520.0 10.0 5.0 137.0 65.00 1.50 0.60 19.25 Dyal XAS-8 17% Sol'n. A.S.A. 6% Co Naphthenate Xylol . 903.0 104.06 Wt./gal. -- 8.68 Viscosity -- 50" on #4 Ford Ball Mill -- 7 hours Grind -- 6H Reduce 30% in Xylol for spraying Lbs. 165.0 115.0 1.0 156.0 8.0 58.0 360.0 65.0 ' 56.0 1.0 4.0 3.0 _ 1002.0 White Enamel Gals. 4.7 3.8 0.1 20.0 1.0 8.0 Titanium Calcium TiO, Soya Lecithin Dyal XAS-8 Pine Oil Xylol** 46.0 9.0 9.0 0.1 0.4 0.4 Dyal XAS-8 Xylol C-8 Naphtha A.S.A. 24% Pb Naphthenate 6% Co Naphthenate 103.5 Wt./gal. -- 9.70 Viscosity -- 45" on #4 Ford Grind -- 6H **For roller mill grinds add this solvent in let-down. 0007-PMC-000000816 DYAL XMD The DYAL XMD classification includes varnishes or solutions based on maleic or fumaric treated resins. DYAL XOR The DYAL XOR classification is a miscellaneous group of drying and non-drying types of oleoresinous combinations. o 0007-PMC-000000817 XMD - XOR \ This view shows pipelines leading from the filter presses to the alkyd storage tanks. The filtering of Sherwin-Williams Dyal Resins through plate and frame presses assures maximum clarity and freedom from minute suspended particles. 0007-PMC-000000818 DYAL XMD -1 TYPE: Short Oil Mixing Varnish OUTSTANDING FEATURES: Low Cost. Stability. Gloss, Adhesion Dyal XMD-1 has wide application as a mixing varnish in formulating low cost finishes of many types. Although air dried or baked films of XMD-1 tend to be brittle, similar films, when modified with medium and long oil alkyds, oleoresinous varnishes and blown or heat bodied oils, display good hardness, high gloss, good toughness and good adhesion. The overall material cost of these finishes would be difficult to duplicate with any other vehicle system. The formulator of low cost finishes will find the use of XMD-1 a convenient way to meet exacting competition, keeping in mind the following points: 1. The degree of modification of XMD-1 should be governed by the performance desired. 2. XMD-1 is reactive with basic pigments. 3. Superior pigment dispersions are usually obtained when the forti fying alkyd or oil is used as the grinding vehicle or as a portion of the grinding vehicle. 4. Lead driers produce excellent film hardness with XMD-1, but ex cessive quantities promote viscosity. Because of this fact, only nominal amounts of lead should be used. Any tendency towards after bodying can then be satisfactorily controlled by the fortifying oil or alkyd, guaiacol and National Aniline's ASA. 5. Improved gloss may often be obtained when 2 per cent to 4 per cent zinc resinate is incorporated. Examples of low cost finishes formulated from XMD-1 are as follows: 1. Drum Enamels 2. Chassis Enamels 3. Freight Car Paints 4. Syndicate Enamels (Colors) 5. Toy Enamels PHYSICAL CHARACTERISTICS Non-Volatile ....................................... 50% Volatile............................... Mineral Spirits Pounds Per Gallon................................ 7.50 Viscosity.................................................. Q-R Solids at E to G Viscosity...................43% Color ...................................... 13 Maximum Acid Value ................................... 15-25 Phthalic Anhydride............................None Oil Length........................................... 48% Resin Modifiers................................ Present 0007-PMC-000000819 FILM AND PERFORMANCE PROPERTIES Color ................. Fair Color Retention.................................. Good Gloss ............................................. Excellent Gloss Retention ........................... Excellent Type of Film........................ Hard, Brittle, except when modified Resistance to: Abrasion .................................... Good Adds ............................................. Fair Alkali............................................. Fair Oil and Gasoline....................... Good Water.................................... Excellent Weather .........................................Fair Pigment Wetting and Dispersing Properties .... Excellent Compatibility with: Long Alkyds ........................Excellent Medium Alkyds..........................Good Short Alkyds................................ Poor Long Varnishes ............................Fair Medium Varnishes...............Excellent Oils ..............................................Good Bodied Oils ...................................Fair DRYING AND DRIER RECOMMENDATIONS Air Dry--Set.................................3 Hours Driers............ Air Dry Bake Air Dry--Hard .........................Overnight Lead..........0.3 to 0.6% Same Bake............................. 250 F. to 275 F. Manganese 0.02 to 0.05% Same for 1 hour depending on Cobalt .. .0.04 to 0.07% 0.01 to 0.06% type of modification Note: The quantity and type of driers to be used with Dyal XMD-1 is greatly influenced by the quantity and type of modifying resin. However, in general, the above ranges, expressed as per cent metal on the resin solids basis, are representative of common usage. SUGGESTED FORMULATIONS Red-Brown Freight Car Paint Lhs. Gals. 80 2.1 Red Oxide NR4284 80 2.0 Syn. Red Oxide, Cl 548 8 0.1 Litharge 62 8.0 Blown Fish Oil 4 0.5 Soya Lecithin 143 19 Dyal XMD-1 23 3 Lead Naphthenate, 10% Ball Mill Grind to 5-H 119 14 Dyal XMD-1 96 12.5 Blown Fish Oil 37 5 Ht. Bodied Linseed Oil (Reduced--65% NVM) 14 2 Mang. Naphthenate, 2% 14 2 Cobalt Naphthenate, 2% 72 11 Mineral Spirits 88 14 VM&P Naphtha Lbs. Per Gallon....................................8.61 Grind......................................5H Ball Mill Viscosity......... 60-72" on # 4 Ford Cup Drying........................1 to 2 hours--touch 3 to 5 hours--handle 1 to 4 hours--recoat Black Baking Enamel Lbs. Gals. 20 1.4 Channel Black L.C. Beads 2 0.2 Aluminum Stearate 2 0.25 Soya Lecithin 10 1 Lead Naphthenate, 24% 7 1 Guaiacol Solution 74 10 Dyal XAC-4 37 6 VM&P Naphtha 39 6 Mineral Spirits 450 60 14 2 74 12 14 2 Dyal XMD-1 Mang. Naphthenate, 2% VM&P Naphtha Toluene Lbs. Per Gallon....................................7.31 Grind.....................................7H Ball Mill Viscosity......... 30"-40" on #4 Ford Cup Baking Schedule................10' @ 300 F. 0007-PMC-000000820 DYAL XMD-6 TYPE: Short Length Resin Modified Mixing Vehicle OUTSTANDING FEATURES: Gloss, Gloss Retention, Low Cost This vehicle can find a wide variety of uses in the Trade Sales or Industrial Finishes line giving a very low vehicle cost. These finishes, when properly formulated, may be air dried or baked, brushed, sprayed, or dipped. Dyal XMD-6 wiH give exceptional exterior dura bility in comparison to oleoresinous varnishes in the same cost range. It is reactive with zinc oxide and to some extent with carbon blacks. In many applications Dyal XMD-6 may be used to give quality performance at low cost and may also be used in conjunction with other vehicles, like Dyal XAC-93 and Dyal XAC-1, to lower cost without affecting the quality. Anti-oxidants such as guaiacol and anti skin agent are suggested when especially good stability in partly-filled containers and dip tanks is required. The stability is a matter of proper balance between driers, anti oxidants and pigments. For Industrial Finishes applied by spray or dip where faster setting and increased build are requirements Dyal XMD-18 is recommended. Dyal XMD-18 contains the same resin solids as Dyal XMD-6 reduced in VM&P naphtha. The viscosity of Dyal XMD-18 is slightly less than that of XMD-6. In all other respects it is equal to Dyal XMD-6. SPECIFICATIONS Non Volatile50% Volatile50% M. S. Lbs. per gal-------------------------------------7.50 ViscosityR - T Aliphatic Solv. Tol1500% Solids at E to G Vis.______________ 44% Color (max.)11 Acid Value20 - 26 Phthalic AnhydrideNone Oil47.5 Type Oil----------------------------------------Soya Resin ModifiersPresent 0007-PMC-000000821 FILM AND PERFORMANCE PROPERTIES Color Color Retention Gloss Gloss Retention Type of Film good good excellent excellent hard, short Resistance to: Abrasion Acids Alkali Oil & Gasoline Water Weather good fair fair good excellent fair Compatibility with: Pigments Nitrocellulose f long Alkyds -j medium 1 short ( long 1Varnish -j medium short Oils Bodied Oils fair fair excellent excellent fair excellent excellent fair excellent fair DRYING AND DRIER RECOMMENDATIONS Air Dry--Set Air Dry--Hard Bake 2!4 to 3 hours 4% to 5 % hours 250F. to 275 F. for 1 hour Lead Manganese Cobalt Air Dry 0.3% to 0.8% 0.01% to 0.08% 0.06% to 0.08% Bake 0.5% 0.03% 0.03% SUGGESTED FORMULATIONS Industrial White Enamel Lbs. 240 2 113 19 "262 198 39 65 7 4 2 941 Gals. 7.5 Anatase Ti 02* 0.2 Aluminum Stearate 15.0 Dyal XMD-6 3.0 Mineral Spirits 35.0 Dyal XMD-6 26.0 Dyal XAC-99 5.0 60% Ester Gum Sol'n. 10.0 Mineral Spirits 0.7 24% Pb Naphthenate 0.5 6% Co Naphthenate 0.2 Anti Skin Agent 103.1 Oil Absorption 24 to 25 Viscosity No. 4 Ford Cup -- 85" to 95" Lbs. per gal. -- 9.23 Brushing -- Reduce with Kerosene -- 5% Dipping or Spraying -- Reduce with VM&P -- 15% to 25% Red and Brown Freight Car Paint (Quick Dry) Lbs. Gals. 165 4.6 Iron Oxide (85% Fe203) 10 0.1 Litharge 6 0.6 Aluminum Stearate 96 12.0 Heavy Blown Fish Oil 46 7.0 Mineral Spirits 240 60 149 . 88 10 6 6 32.0 7.5 23.0 14.0 1.0 0.8 0.8 Dyal XMD-6 Bodied Linseed Oil Mineral Spirits VM&P Naphtha 24% Pb Naphthenate 6% Co Naphthenate 6% Mn Naphthenate 882 103.4 Viscosity No. 4 Ford Cup -- 95" to 105" Lbs. per gal. -- 8.53 Brushing -- Reduce with M.S. -- 3% to 7% Spraying -- Reduce slightly with VM&P 5-S3 0007-PMC-000000822 DYAL XMD-165 TYPE: Short Length Resin Modified Mixing Vehicle OUTSTANDING FEATURES: Low Cost Dyal XMD-165 is a low cost vehicle developed for use in syndicate type enamels. It pos sesses good color and dry for this particular type of vehicle. Films produced by XMD-165 are high in gloss, gloss retentive and maintain a fair degree of flexibility. This vehicle is compatible with long oil alkyds and may be extended in this way to improve flexibility and durability. This type vehicle has been proving itself highly satisfactory in the following type of finishes: 1. Implement Enamels 2. Drum Enamels 3. Freight Car Paints .4 Toy Enamels It is suggested that reactive type pigments should be avoided when using Dyal XMD-165. Also, it is recommended that with the given drier combinations 0.2% of Anti-Skin Agent based on the resin solids should be employed. SPECIFICATIONS Non Volatile50% Volatile ____________________ 50% M. S. Lbs. per gal------------------------------------- 7.45 Viscosity_____ __Q - S Aliphatic Solv. TolInfinite Solids at E to G Vis_______________ 42.5 Color (max.)11 Acid Value____________________ 10 to 20 Phthalic Anhydride__________ None oa------------------------------------------------ 54% Type Ofl------------------------------------ Drying Resin Modifiers ..... .....Present 0007-PMC-000000823 FILM AND PERFORMANCE PROPERTIES Color Color Retention Gloss Gloss Retention Type of Film good fair fair good hard, slighdy britde Resistance to: Abrasion Acids Alkali Oil & Gasoline Water Weather good fair fair good good fair Compatibility with: Pigments Nitrocellulose long Alkyds 4 medium 1 short ( long Varnish 4 medium 1 short Oils Bodied Oils - good none good fair poor good fair poor good good DRYING AND DRIER RECOMMENDATIONS Air Dry--Set Air Dry--Hard Bake 4 to 5 hours 12 to 16 hours 250 F. to 275 F. for 60 min. Lead Manganese Cobalt Zinc Air Dry 0.5% to 0.7% 0.02% to 0.04% 0.05% to 0.08% none Bake 0.3%, 0.01% 0.03% 0.01% SUGGESTED FORMULATIONS Lbs. 27.0 592.5 52.0 9.4 3.5 50.0 3.0 737.4 Black Drum Enamel Gals. 1.85 79.0 8.0 1.25 0.5 Carbon Black Dyal XMD-165 Mineral Spirits 24% Pb Naphthenate 6% Mn Naphthenate 8.0 VM&P Naphtha 0.42 6% Co Naphthenate 99.0 Wt. per gai. -- JAl Grind -- 16 to 18 hours Bail Mill Spray -- Reduce 20% with VM&P Naphtha Interior Ivory Ceiling Paint Lbs. 500.0 3.0 150.0 44.0 Gals. 18.4 35 20.0 6.0 Titanium Calcium Calcium Stearate Mixing Varnish -- Med. Length (Soya Rosin Ester) Dyal XMD-165 246.0 79.0 40.0 9.6 4.7 2.3 26.0 33.0 10.0 5.0 1.0 0.7 033 4.0 Dyal XMD-165 Non-Break Linseed Oil Heat-Bodied Linseed Oil 24% Pb Naphthenate 6% Co Naphthenate 6% Mn Naphthenate Mineral Spirits 1104.6 98.7 Viscosity No. 4 Ford Cup -- 80" to 120" Wt. per gal. -- 11.10 0007-PMC-000000824 DYAL XOR-6 TYPE: Modified Silicone Resin Solution OUTSTANDING FEATURES: Heat Resistance, Flexibility, Adhesion Dyal XOR-6 is a modified silicone resin solution developed specifically for use in "heat resisting finishes." The use of Dyal XOR-6 permits formulation of this type of finish at lower cost than is obtained with the use of unmodified silicone resins. Dyal XOR-6 enamels approach the performance of ceramic finishes to the same degree as the much more expenseive straight silicone finishes. Results of evaluations of finishes made with Dyal XOR-6 indicate that Dyal XOR-6 will replace the higher cost, straight silicone resins and ceramic finishes for many applications.- SPECIFICATIONS Non Volatile....... ....................... 59 to 61% Volatile H. S. Naptha & MIBK Wt./gal.................... ............................... 8.95 Color............... ....................................4 max. Acid Value on NVM......... ..........14 to 20 Viscosity............ ............. ...................O to Q Specific advantages of enamels made with Dyal XOR-6 modified silicone resin solution are as follows: (1) Appearance A. High gloss--87 to 90 on 60 photovoltmeter. B. Porcelain-like appearance. C. Excellent mar resistance (slick silicone feel). (2) Color Rentention A. Exposed to 400 F temperature for 16 hrs. without change. B. Extended tests at 400F for 400 hrs. show only slight color change. (3) Gloss Rentention A. Exposure at 400F temperature for 16 hrs. without a drop in gloss. B. Extended heat tests show maximum of a 20% drop in gloss read ing after 160 hrs. at 400F with no further drop after 160 hrs. up to 400 hrs. at this temperature. (4) Flexibility and Adhesion A. 120 inch pounds on phosphatized metal or double this on solvent cleaned metal. B. No cracking over % in. conical mandrel. C. No loss in flexibility or adhesion after exposures up to 400 hrs. at 400F. (5) Grease Resistance A. 10 cycle immersion at one minute intervals in and out of grease at 500F --almost equal to straight silicone finish. B. Immersion in grease at 500F for 5 minutes--equal to straight silicone finish. (6) Weathering A. Excellent weathering properties--which indicate permissable use as replacement for ceramics for outdoor signs and dispensers. 0007-PMC-000000825 (7) Stain Resistance A. Not affected by common household foodstuffs and reagents. (8) Chemical Resistance A. Not affected by 1% NaOH solution or 5% HC1 after 24 hrs. at room temperatures. Salt Spray--20% NaCl at 95F for 200 hrs. with no rust creepage. (9) Humidity Resistance A. Over phosphatized steel with a 30 min. at 400F curing cycle--up to 1000 hrs. ' B. Over phosphatized steel with a 30 min. at 500F curing cycle-- over 1500 hrs. To attain the maximum performance from finishes prepared with Dyal XOR-6, a few precautions must be observed: 1. The metal surface to be finishe'd must be clean, that is, properly solvent cleaned, or must be clean and phosphate treated. 2. Manufacturing and application equipment must be clean. 3. Most important of all--a proper baking cycle for the applied film is required. The baking cycle should be at least 30 min. at 400F, wherein the metal is maintained at 400"F metal temperature throughout the schedule. Pigmentation of this vehicle is limited to those pigments able to withstand the high curing cycle. Pigments should also be alkali and lead free to insure maximum storage stability. Dispersion on roller mill is recommended, however, pebble milling is permissible. In either case, the mill should be clean and free from alkali or lead contamination. Enamels prepared on a production scale with titanium dioxide pigmentation have shown excellent storage stability requiring no stabilizing agents. Dyal XOR-6 enamels do not require the use of a curing catalyst or driers. The compatability of Dyal XOR-6 with common film forming materials is very limited. Contamination with other film forming materials will detract from the inherent excep tional performance of this vehicle in heat resisting type finishes. SUGGESTED FORMULATIONS Heat Resisting White Enamel Lbs. 300.0 144.0 Gals. 8.6 Ti02 Rutile 16.0 Dyal XOR-6 549.0 97.0 25.0 61.0 Dyal XOR-6 13.5 Toluol 4.0 C-8 Naphtha 1115.0 103.1 Roller Mill Grind--7 Hegman Reduced viscosity--18 to 20 sec. #4 Ford NVM--60% Reduce--20% with Toluol for spraying Wt./gal.--10.82 Output--100 gals. Bake at 400F --30 min. Heat Resisting Aluminum Paint Lbs. Gals. 175.0 225.0 448.0 14.25 Al. LiningPaste E.F. 2525 Dyal XOR-6 62.50 Xylol 848.0 102.00 Blend in Clean Agitator Tank Wt./gal.--8.30 Viscosity--10 to 12 sec. #4 Ford NVM--29% No reduction for spray application Bake at 400F --30 min. 0007-PMC-000000826 DYAL XOR-31 TYPE: Modified Ether Resin Solution OUTSTANDING FEATURES: Chemical Resistance, Stain Resistance, Color Retention, Adhesion Dyal XOR-31 is a modified ether resin solution which was developed for use in highest quality baking finishes. Baking finishes made with Dyal XOR-31 will exhibit exceptional stain resistance and outstanding chemical resistance. This modified ether resin will also give films that possess excellent adhesion, excellent color retention, excellent gloss and build. The outstanding stain and chemical resistance of Dyal XOR-31 greatly surpasses that of the very best alkyd resins. Dyal XOR-31 may be formulated to utilize these proper ties to full advantages for use in the following: 1. Appliance Finishes 2. Metal Decorating 3. Specification Finishes .4 Metal Primers 5. Toy Enamels 6. Electrical Wire Enamels Dyal XOR-31 may be used for air drying finishes with conventional driers; however, air drying does not properly cure this resin. Therefore, the full benefits of the vehicle will not be realized unless it is used in a baking finish. Baking finishes made from Dyal XOR-31 may be formulated with or without amine resins. Amine modification results in completely cured films that offer the utmost in performance. It is recommended that 15% to 30% of the total resin solids be amine resin. Finishes made with Dyal XOR-31 may be sprayed or dipped. The baking schedule should fall within the following limits: 20 to 40 minutes at 275 F. to 325 F. SPECIFICATIONS Non Volatile____________ ____ ___ 50%, Volatile ____ ____ _____ ___ ___50% Xylol Lbs. per gal------------ ---- -------------. 7.98 Viscosity ___S - W Aliphatic Solv. Tol.............................. Poor Solids at E to G Vis............. Color (max.) ________________ Acid Value____________ 4 Phthalic- Anhydride None Resin Modifiers____________ 40% 6 None 0007-PMC-000000827 FILM AND PERFORMANCE PROPERTIES Color Color Retention Gloss Gloss Retention Type of Film excellent excellent excellent excellent tough, hard, flexible Resistance to: Abrasion Acids Alkali Oil & Gasoline Water Weather excellent excellent + excellent + excellent excellent fair Compatibility with: Pigments Nitrocellulose [long Alkyds J medium 1 short [long Varnish | medium | short Oils Bodied Oils - good none none none none none none none none none DRYING AND DRIER RECOMMENDATIONS Air Dry--Set Air Dry--Hard Bake not recommended not recommended 275F. to 325F. for 20 to 40 min. Bake* Lead none Manganese 0.02% to 0.04% Cobalt none Calcium none Zinc none when amines are not used SUGGESTED FORMULATIONS Appliance White Baking Enamel Lbs. Gals. 285.0 15.0 489.0 8.15 0.32 61.00 Titanium Dioxide-Rutile Zinc Oxide (Lead Free)** Dyal XOR-31 167.0 70.0 27.0 19.50 Urea Formaldehyde Sol. 10.00 Xylol 4.00 Ethyl Alcohol** 1053.0 102.97 For Package Stability Grind -- 6 to 7 Hegman -- Roller Mill Lbs. per gal. -- 10.22 Bake -- 300F. for 30 min. Aluminum Baking Enamel Lbs. Gals. 113.0 444.0 252.0 10.12 400 Mesh Aluminum Paste 55.62 Dyal XOR-31 35.25 Xylol 809.0 100.99 Cold Blend in order shown Viscosity No. 4 Ford Cup -- 26" Lbs. per gal. -- 8.09 Bake -- 300F. for 30 min. NVM -- 35.9% 5-83 0007-PMC-000000828 ___________________________ DYAL XOR-34 TYPE: Modified Ether Resin Solution OUTSTANDING FEATURES: Stain Resistance, Chemical Resistance, Color Retention, Adhesion, Flexibility Dyal XOR-34 is a modified ether resin solution which is similar to Dyal XOR-31 in such important properties as flexibility, adhesion and stain resistance. Dyal XOR-34 differs from Dyal XOR-31 in that the former has been modified to lower the cost. In lowering the cost it was necessary to sacrifice a slight degree of chemical and stain resistance; however, Dyal XOR-34 still retains a major share of the excellent chemical and stain resistance inherent in an ether resin, and it is to be recommended as far superior to the average alkyd in chemical and stain resistance. Dyal XOR-34 has a further advantage over Dyal XOR-31 in that the full benefits of Dyal XOR-34 may be obtained by means of an air dry finish; thus it is a vehicle with a broad range of applications. To summarize: Dyal XOR-31 is suggested for the ultimate in chemical and stain resistance where the finish can be baked, and Dyal XOR-34 is suggested where a lower cost finish or an air dry finish is desired. Among the finishes for which Dyal XOR-34 may be used are: 1. Appliance Finishes 2. Metal Decorating Finishes 3. Specification Finishes .4 Metal Primers 5. Toy Enamels 6. Machine Enamels 7. Baked Aluminum Enamels 8. Furniture Clears SPECIFICATIONS Non Volatile50% Volatile 50% Xylol Lbs. per gal-------------------------------------7.98 ViscosityT - X Aliphatic Solv. Tol.Poor Solids at E to G Vis.40% Color (max.)6 Acid Value3 Phthalie AnhydrideNone Resin Modifiers__ None 0007-PMC-000000829 FILM AND PERFORMANCE PROPERTIES Color Color Retention Gloss Gloss Retention Type of Film excellent excellent excellent excellent tough, hard, flexible Resistance to: Abrasion Acids Alkali Oil & Gasoline Water Weather excellent excellent excellent excellent excellent fair Compatibility with: Pigments Nitrocellulose [long Alkyds i medium | short [ long Varnish < medium ( short Oils Bodied Oils _ good none none none none none none none none none DRYING AND DRIER RECOMMENDATIONS Air Dry--Set Air Dry--Hard Bake 2 hours 6 hours 275 F. to 325F. for 20 min. to 40 min. Air Dry Lead 0-5% Manganese 0.05% Cobalt 0.05% Calcium none Zinc 0.02% When used without Amine Bake* none 0.03% none none none SUGGESTED FORMULATIONS See suggested formulations for Dyal XOR-31. These same formulations may be used with Dyal XOR-34 with only minor adjustments. 8-53 0007-PMC-000000830 DYAL XPL The DYAL XPL resins are used as plasticizers. DYAL XRE The DYAL XRE resins are for use in emulsion type coatings. J XPL XRE 0007-PMC-000000831 t f A partial view of modern alkyd resin storage tanks with capacity xOC large enough to assure uniformity and adequate supply for consumer demand. a. X if K 0007-PMC-000000832 DYAL XPL-5 TYPE: Alkyd Lacquer Plasticizer OUTSTANDING FEATURES: Retained Flexibility, Alcohol Solubility, Low Cost Dyal XPL-5 is a castor oil modified alkyd that has been found to be extremely useful as a lacquer plasticizer. Dyal XPL-5 exhibits good alcohol solubility, excellent flexibility, good durability, good ad hesion, excellent color and color retention when used in lacquer for applications on paper, fabric, wood, or metal. The most outstanding characteristic of this plasticizer is its excellent flexibility which remains unchanged after aging because Dyal XPL5 will not volatilize, oxidize, or separate from the film. This extended flexibility accounts for the good durability of lacquers plasticized with Dyal XPL-5. The initial color of Dyal XPL-5 is very good and ultraviolet light exposures show this plasticizer to have excellent color retention. The low viscosity and high solids of Dyal XPL-5 are also very desirable' in high solids lacquer formulation. A very important fact concerning Dyal XPL-5, that should not be overlooked, is that all of the desirable performance properties mentioned above usually require plasticizers that cost much more. Dyal XPL-5 actually costs considerably less than many lacquer plasticizers recommended for the same type usage. Dyal XPL-5 is compatible with nitrocellulose, ethlycellulose, and many short and medium length alkyd and maleic resins. The heat resistance of Dyal XPL-5 is only fair and its hydrocarbon resistance is only fair. Dyal XPL5 may be used in clear as well as pigmented lacquer formulations. SPECIFICATIONS Non Volatile---------------------------------- 80% Volatile -------------------------------20% Xylol Lbs. per gal-------------------------------------- 8.08 Viscosity------------------------------------- .T - V Aliphatic Solv. Tol.------------------------- Poor Color (max.)6 Acid Value7 Phthalic AnhydrideNone Oil86% Type OilCastor Resin Modifiers Present 0007-PMC-000000833 TYPE: Lacquer Modifying Resin OUTSTANDING FEATURES: Adhesion on Metal, Retained Flexibility DYAL XPL-115 Dyal XPL-115 is a non drying castor oil modified inter-ester type resin solution that has been proven exceptionally useful as a lacquer plasticizing and modifying resin. As a lacquer modifying resin the low viscosity and high solids of Dyal XPL-115 produces lacquer films of increased solids and increased build. As a lacquer plasticizing resin Dyal XPD115 shows outstanding adhesion and excellent retained flexibility. This inherent adhesion and flexi bility has made Dyal XPL-115 extremely useful in the formulation of automotive and in dustrial primers and primer surfacers. Lacquer primers and primer surfacers made with this plasticizing and modifying resin will be exceptionally tough and durable and will possess good sanding properties. In only a few minutes after application these primers and primer surfacers may be rccoated with no danger of lifting under lacquer topcoats. Heavy pigment loadings may be dispersed in Dyal XPL-115 and let down with nitro cellulose cuts. Dyal XPL-115 wets and disperses most pigments well; however, extremely reactive pigments should not be used with it. This resin is not recommended for white and pastel topcoats because of its color. It may be used for medium and dark shade topcoats. SPECIFICATIONS Non Volatile60% Volatile ........ .............................15% Toluol Volatile15% Toluol -- 35% Xylol Lbs. per gal--- --------------------------------- 8.20 ViscosityT - V Color (max.) 12 Acid Value ............ Phthalic Anhydride Oil ______________ Type Oil....... .......... Resin Modifiers___ _____ ___ 35 --------- None ----- :--48% Raw Castor ------ Present S-S3 0007-PMC-000000834 DYAL XRE-156 TYPE: Oil Modified Latex Emulsion Modifying Alkyd OUTSTANDING FEATURES: Compatibility, Ease of Emulsification, Good Drying, Color Retention Latex emulsion paints are becoming an ever increasing factor in Trade and Maintenance Paint Sales Markets. In general, two basic types of latex emulsion paint formulations have been involved and used with marked success. One type formulation is one which uses latices exclusively as the pigment binder and film former. The other uses a combination of latices with oleoresinous or alkyd modifiers. Experience has shown the alkyd modified latex emulsion paints to have several distinct advantages over the straight latex formulations. The most important advantages of the alkyd modified latex emulsion formulations are: 1. Alkyd modification contributes to the final paint a thixotropic con sistency which is desirable to obtain proper flow and leveling in appli cation. This thixotropic consistency' contributes the necessary "slip" under the brush and "leveling" for improved uniformity of coat. 2. Alkyd modification serves to hasten the conversion to an insoluble film to permit washing in a shorter period of time. 3. Alkyd modification gives the necessary post conversion plasticization which is desirable to maintain tough and durable films. This plastici zation is also necessary to permit satisfactory recoatability of aged films. 4. Alkyd modification gives equal washability to that obtained with the straight latex formulations. 5. Alkyd modification helps emulsion stability under extreme tempera ture changes. 6. In most instances the above advantages may be obtained with alkyd modification at costs equal to or below that of the straight latex formulation. SPECIFICATIONS Non Volatile:100% VolatileNone Lbs. per gal8.93 Viscosity Semi-Solid Aliphatic Solv. Tol----------------------Infinite Solids at E to G Vis.58% Color (max.)9 Acid Value5 Phthalic AnhydridePresent Oil_______________________Long Type Oil________________ _________ Soya Resin ModifiersNone 0007-PMC-000000835 Cont. - DYAL XRE-156 Proper alkyd modification of latex emulsion paints entails only the choice of proper modi fying agent along with the appropriate procedure for introduction of the alkyd into the emulsion system. Dyal XRE-156 is a tried and proven latex emulsion modifying alkyd. Experience has shown Dyal XRE-156 to contribute all of the desirable properties men tioned above. The correct procedure for handling Dyal XRE-156 is as follows: 1. Dependent on the type of latices used the recommended amount of oil modification is 25% to 55% of the total vehicle solids. (This amounts to approximately one-half pound to one pound of alkyd modifier per gallon of Latex Emulsion Paint.) 2. Addition of concentrated driers to give the following amounts of metal based on resin solids. .5 to .7 % Lead .05 to .07% Cobalt 3. Several methods of introduction of the alkyd into the Latex Emulsion Paint system may be employed. However, the most convenient method, one that requires no special equipment, is one in which emulsification of the resin is performed in a paste mixer. A processing schedule which has given consistently stable emulsions is as follows: A portion of the protective colloid solution and all of the pigments, colors and inerts are mixed in the paste mixer so that a smooth, heavy paste is obtained. The resin and driers are added at this time and the batch is allowed to mix 10 to 20 minutes. The mix is then reduced in body to grinding consistency with additional protective colloid solution and passed through a colloid type mill or other suitable grinding equipment. The latex, remaining protective colloid solution, shading bases, and water are then added to the ground paste in a thin down or shading tank. It is extremely important to have the alkyd properly emulsified prior to its addition into the Latex Emulsion Paint system. Most non-ionic and anionic types of emulsifiers will give good oil and water emulsions for this usage. 5-83 0007-PMC-000000836 XRV XRV XRV resins are for use in further processing in varnishes. They may be: DYPHENES (Pure Phenolic Resins) DYPHENITES (Modified Phenolic Resins) DYMALS (Maleic Modified Hard Resins) 0007-PMC-000000837 XRV Ample facilities are available for rapid filling and shipment of Dyal resins in drums, tank wagons, and tank cars. 0007-PMC-000000838 DYAL XRU-1 TYPE: Urea Formaldehyde Resin Solution OUTSTANDING FEATURES: Mineral Spirits Tolerance, Versatility, Low Viscosity XRU-1 is a low viscosity urea formaldehyde resin solution which may be used to formulate baking enamels for a multitude of purposes. These finishes will have upgraded properties when compared with unmodified alkyd baking finishes. A desirable feature of XRU-1 is its mineral spirits tolerance. As an example, XRU-1 may be used in conjunction with XAC-4. (See handbook sheet on XAC-4), to formulate low cost, high solids baking enamels. The high solids content of these enamels makes them especially desirable for one coat applications where good gloss and film hardness are required. In addition, the use of XRU-1 imparts light color, chemical resistance and marproofness. The use of XRU-1 is not confined to the formulation of only high solids baking enamels. All unmodified alkyd baking enamels will usually be improved by the addition of XRU-1. Here the improvement is manifested in the harder films and faster baking schedules, even when relatively small amounts of modifications are used. XRU-1 may be used for formulating the highest quality chemical-resistant furniture finishes. Here in conjunction with XOR-15 and XAN-1, flat varnishes may be formulated having any desired degree of sheen. Please refer to the back of the XOR-15 Resin Handbook Insert Sheet for specific formulation information. DYAL XRU-2 TYPE: Urea Formaldehyde Resin Solution OUTSTANDING FEATURES: High Viscosity, Fast Cure XRU-2 is a companion piece to the above mentioned XRU-1. Its main distinguishing feature is its more rapid curing rate. This means that harder films are obtained at similar baking schedules than in the case of XRU-1. XRU-2 modified protective coatings will require a shorter baking schedule to give equal film hardnesses when compared to XRU-1 modified protective coatings. Because XRU-2 has a high viscosity, it can be used to formulate low solids baking enamels such as in a two coat system. PHYSICAL CHARACTERISTICS Non-Volatile......................... Volatile .................................. Pounds/Gallon .................... Viscosity ............................... Acid Value........................... Color (APHA) .................. Xylene Compatibility......... Mineral Spirit Compatibility XRU-1 50% 30% Butyl Alcohol 20% Xylene 8.48 N-P 4-9 Water White 2000% 100% XRU-2 50% 30% Butyl Alcohol 20% Xylene 8.50 Y-Zl 4-9 Water White 2000% 100% 0007-PMC-000000839 DYPHENE XRV-5 TYPE: Pure Oil Reactive Phenolic Resin OUTSTANDING FEATURES: Light Stability, Improved Drying, Excellent Alkali Resistance Dyphene XRV-5 is an oil-reactive pure phenolic resin characterized by good color reten tion, fast dry and excellent alkali resistance. Because of the high reactivity of Dyphene XRV-5, it is an ideal resin for kettle modification with ester gum. Varnishes of this type using 15% to 20% of Dyphene XRV-5 based on the resin produce films of superior per formance with respect to speed and hardness of dry, color retention and soap and alkali resistance. The greater reactivity of Dyphene XRV-5 is an important factor in the resultant superior performance. Dyphene XRV-5 kettle modified resins have excellent petroleum solubility. Melting points of such resins may rise as high as 300 F. These resins show optimum performance with tung oil in the varnishes of the four-hour type. Clear varnishes of exceptional hardness, color retention and alkali resistance may be formu lated with Dyphene XRV-5; however, varnishes of this type, when using tung oil, should not be cooked in less than 30 gallon lengths. Dyphene XRV-5 is especially suitable for kettle modification of alkyd resins in the manufacture of high grade industrial finishes. This 100% phenolic resin is soluble in all varnish oils at temperatures of 360 F. to 380 F. Varnishes made with Dyphene XRV-5 and reduced with mineral spirits have infinite petroleum solvent tolerance. SPECIFICATIONS Melting Point--------------------------------- 175F. to i95F. (Modified Ring and Ball Method) Acid Number----------------------------------- ------------------------------ 15 to 25 (Salt Layer Method) Color------------------------------------------------------------------------- 9 max. (50% Solution in Toluol) Specific Gravity____________________________________________________________________ 1.10 0007-PMC-000000840 DYPHENE XRV-80 TYPE: Pore Non Reactive Phenolic Resin OUTSTANDING FEATURES: Exterior Durability, Chemical Resistance, Good Gas Proofing ' As ordinarily classified, Dyphene XRV-80 would be termed, "non reactive" because no foaming takes place when cooking with oils; however, Dyphene XRV-80 is reactive to the extent that when processed with tung oil it increases the bodying rate and will improve the alkali and water resistance of softer oils more than can be accounted for by dilution effect only. Dyphne XRV-80 varnishes show exceptional durability and chemical resistance, easily equaling or surpassing varnishes made from the so called reactive type resins. Varnishes made with this resin have good color and color stability, but are inferior in this respect to varnishes made with Dyphene XRV-5. Dyphene XRV-80 has very strong gas proofing qualities with tung oil. Generally speaking, this resin is better adapted to use with oils dry ing by polymerization than by oxygen absorption. Dyphene XRV-80 may be processed at any oil length desired. Spar varnishes of exceptional durability may be prepared with Dyphene XRV-80. This resin is also excellent for ketde modification of alkyd resins. Dyphene XRV-80 is insoluble in mineral spirits and has limited solubility in toluol. Oil varnishes containing this resin may be reduced with mineral spirits in the longer lengths (30 gallons and above). The shorter varnishes should contain some stronger solvents. Dyphene XRV-80 conforms to the requirements of Navy Specification 52-R-ll and this resin can be used to prepare varnishes conforming to Specification MIL-E-15218, Type II and Type VI. SPECIFICATIONS Melting Point---------------------------------250F. to 275F. (Modified Ring and Ball Method) Acid Number---------------------------------------------- .---------------------10 to 15 (Salt Layer Method) Color----------------------------- -----------------------------------------9 max. (50% Solution in Toluol) Specific Gravity _________________________________________________________1,07 5-53 0007-PMC-000000841 This section is intended for future use. Com parative Resin Data, Drying Charts, Hardness Charts and Compatability Charts are to be is sued as part of this book and are to be filed in this section. 0007-PMC-000000842 viva dsiw fc-nf! 0007-PMC-000000843 PIGMENT, COLOR & CHEMICAL DIVISION Th e Sh e r w n - Wil l iams Co mpan y ! ,300 WEST LAKE STREET, CHICAGO 6 ILL. 101 PROSPECT AVENUE, CLEVELAND 1, OHIO 100 PARK AVENUE, NEW YORK 17, N. Y. 1450 SHERWIN AVENUE, OAKLAND 8, CALIF. 655 BEACON STREET, BOSTON 15, MASS. 616 MAIN STREET, CINCINNATI 2, OHIO 2036 WOODWARD AVENUE, DETROIT 26, MICH. 4110 SO. ALAIN STREET, HOUSTON, TEXAS 363 SO. MISSION ROAD, LOS ANGELES 33, CALIF. ,325 NO. BROAD STREET, PHILADELPHIA 7 PA. 515 SPRUCE STREET, SAINT LOUIS 2, MO. EXPORT OFFICE -- 100 PARK AVE., NEW YORK 17, N. Y. } 1 "' V 0007-PMC-000000844