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no A O4i9p9 CONF r^FNrrA,
MATERIAL SAFETY DATA SHEET CFR. 1910.1200 OSHA Hazard
.omaunication Rale Format
MINE SAFETY APPLIANCES COMPANY
P. 0. Box 426
Pittsburgh, PA 1S230 PHONE (412) 967-3000
NOTE: This produce contains Stannic Chloride, a substance subject to the Pennsylvania W rker and Community Right-To-Know Act.
PRODUCT IDENTITY
LABEL IDENTITY CHEMICAL NAME -
MSA P/N 5607 Ventilation Smoke Tube Assembly MSA P/N 5645 Ventilation Smoke Tubes (pkg. of 12)
Stannic Chloride Sorbed on pumice
ADDITIONAL IDENTITIES - Smoke Tubes
FORMULA -
SnCl4 0,1 Pumice
APPLICABLE CHEMICAL CONTENTS
"'annic Chloride (CAS 7646-78-8) mice (CAS 1332-09-8)
X 50-60
40-50
TLV 2mg/m3*
lOog/m3
*As inorganic tin compounds
Each tube contains approximately 2 gms. SnCl4
CAUTION:
SnCl4 reacts with moisture in air yielding tin oxides smoke, and hydrochloric
acid. This mixture is irritating to the eyes and mucous membranes. Avoid
contact with smoke puffs pumped from the tube.
Tube effluent contains
TLV
HC1 (CAS 7647-01-0)
7mg/mJ Cei1ing
Tin Oxides (no CAS number known)
2mg/m3 (*s inorgani
Tin Compounds)
SnCl4 (CAS 7646-78-8)
2mg/m3 (as inorgani
Tin Compounds)
ACGIH TLVs 1987-88
Page 1 of 4
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4?9 TOfm
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MSA P/N 5645
PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE AND ODOR - Gray Co Black Granules, Acid Odor
BOILING POINT - SnCl4 235* F
SPECIFIC GRAVITY (H20-1>" >l
VAPOR PRESSURE - SnCl4 l0-20mm HG at Room Temp.
PERCENT VOLATILE BY VOLUME - Appro*. SOI
VAPOR DENSITY (AIR.- 1) - 1
SOLUBILITY IN UATER ~ SnCl^ soluble decomposes
PHYSICAL HAZARD INFORMATION
PHYSICAL HAZARD - SnCl4 is strongly acidic and reacts with water vapor yielding tin oxides smoke and corrosive hydrochloric acid mixture.
CONDITIONS OR MATERIALS TO AVOID - Avoid strong bases, alcohols, ethylene oxide, alkyl nitrates, and amines.
FLASH POINT - SnCl4 is not flammable. EXTINGUISHING MEDIA - As needed for surrounding fire.
LEL N/A
UEL N/A
SPECIAL FIRE FIGHTING PROCEDURES - Wear impervious covering and self-contained pressure demand breathing apparatus with full facepiece.
UNUSUAL FIRE AND EXPLOSION HAZARDS - Tubes may rupture and emit toxic fumes and dense smoke under fire conditions. Avoid contact with run-off water which may be acidified by leached tube contents.
HEALTH HAZARDS
HEALTH HAZARDS - Corrosive, Toxic, Irritant
SnCl4; inh Rat LC50 2300mg/m^ 10 minutes HC1: INH Human LCLo 1300ppm 30 minutes
SIGNS AND SYMPTOMS OF EXPOSURE - Eye, skin, and respiratory system irritation, coughing, shortness of breath, headache, nausea, vomiting. Direct contact with liquid
SnCl4 produces acid burns.
PRIMARY ROUTES OF ENTRY: Eyes, nose, mouth, skin
TARGET ORGANS: Eyes, mucous membranes, skin
N/A - Not Applicable
Page 2 of 4
0 a 04i90. c-ONFTD FNTTAl.
MSA P/N 5645
;EDICAL CONDITIONS GENERALLY RECOGNIZED AS BEING AGGRAVATED BY EXPOSURE - No information
EXPOSURE LIMITS - See page I
CARCINOGENICITY DATA - Not listed in NIOSH RTECS.
EMERGENCY AND FIRST AID PROCEDURES -
Smoke puff generation ie under manual control of the user by actuation of a squeeze bulb and overexposure is unlikely under intended conditions of use. First aid procedures follow should overexposure somehow occur. Eyes: Remove victim from exposure. Flush eyes with water for 15 minutes holding eyes
open and raising eyelids to flush underlid areas. SEE A PHYSICIAN IMMEDIATELY.
Inhalation: Remove from exposure. Give oxygen if breathing is difficult. Give artificit respiration if breathing has stopped. GET MEDICAL ATTENTION IMMEDIATELY
Ingestion: If tube contents are somehow ingested, give 2 glasses of water to dilute chemical. Do not induce vomiting. GET MEDICAL ATTENTION IMMEDIATELY.
SAFE HANDLING AND USE
YGIENIC PRACTICES - Wash hands after using product.
PROTECTIVE MEASURES DURING REPAIR AND MAINTENANCE OF CONTAMINATED EQUIPMENT - Not Applicable
PROCEDURES FOR SPILL OR LEAR CLEANUP If contents of a tube are released, leave area until smoke generation subsides. Avoid skin contact with spilled material and avoid breathing any smoke generated. Fill a buckc 3/4 full of water and add l ounce of sodium bicarbonate. Sweep up the tube and spilled contents and place in the bucket overnight to completely deactivate remaining chemical. Filter solids from water and dispose to trash. Neutralized water can be poured down drain.
Page 3 of 4
On
O-OMp * 4 1 93p TnONTjAl
MSA P/N 5645
WASTE DISPOSAL - Tape over eada of exhauated cubea and diapoae in accordance with Local, and federal regulariona.
STORAGE - Store tubes in a cool dry Location protected from crushing and inpact forces.
CONTROL MEASURES PERSONAL PROTECTIVE EQUIPMENT - Due to the limited amount of SnCl^ per tube and the contr
smoke release rate, use of personal protective equipment is not indicated under antici conditions of use. The user is cautioned to avoid breathing the tube emissions which irritant.
ENGINEERING CONTROLS - Not Applicable. WORK PRACTICES: This product is for use in determination of direction and velocity of
ventilation air currents. Avoid breathing emissions from tube. DATE OF PREPARATION - January 1988
The information provided herein has been compiled from sources believed t be reliabLe. However, Mine Safety Appliances Company makes no warranty as to the accuracy, completenes or sufficiency of the information and in no event will Mine Safety Appliances Company be responsible for loss or damage of any nature whatsoever resulting from use of the infor mation.
Page 4 of 4
Oo
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A 04 j
tofNt
Curtin Matheson Scientific, Inc.
9999 VETERANS memorial --l DOCK C
HOUSTON, TX 77038
FISONS
' 1. -'k ""
' `:
MAIL TO: " OOW USA : LA LOUISIANA HIGHWAY 1
BLOG: 6604 PLAQUEMINE . LA 70764
MANUFACTURER NAME AND ADDRESS EM SCIENCE
A DIV OF EM INDUSTRIES
P.O. BOX 70
smm
NJ 06027
phone 800-424-9300
COMMON NAME (ON LABEL)
' SODIUM bromide_____________ i RADc NAME i> S t"NOiVVMS
SODIUM BROMIDE
NAfiflE./AND'' PRODUCT/-'03f'
I CHEMICAL NUMBER: MSX0390-1....... ITEM NtiMBEfei" 0404017 VNDR CATLG NBR: ENTRY DAffr 02-24-90 CHANGE DATE: 02-24r90~ PO NUMBER: 000001469703
CHEMICAL FAMILY
INORGANIC SALT
CHEMICAL FORMULA
NABR
'
PAGE 1 or
SODIUM BROMIDE
SECTION 2
HAZARDOUS COMPONENT
HAferoouj^^
CAS
% (WT)
7647-15-6 100.00
TLV .000 SEC.5
PEL .000 SEC.5
PEL: Psrmiaaibls Expoxura Limit establixhtd by tha Occupational Safaty and Maalth Admmiatratlon IOSHAI. YLV*. Thrachold Limit Value extablixhsd by tha American Conferanca of Govarnmental Industrial Hygienists, 1666*87.
OTHER INGREDIENT INFORMATION N,A.
^-1?^^!:!:^:' .
1
BOILING POINT
1390C MELTING POINT
755C EVAPORATION RATE (
N/A APPEARANCE AND ODOR
WHITE CRYSTALS OR
if-::
' ,;,:;;|||SECTlON-:3 D
VOLATILE 3Y VOLUME (%) N/A
VAPOR DENSITY N/A
SPECIFIC GRAVITY
3.21
OTHER PHYSICAL DATA MOLECULAR WEIGHT., 102.90
i vXiX
VAPOR PRESSURE N/A 20CC SOLUBILITY IN WATER 47
^0 A (:0NrT^Nn^
Cftntinnnri nn Revere* Sirf*
4
SIGNS AND SYMPTOMS OF EXPOSURE SYMPTOMS OF EXPOSURE ...........: -MODERATELY TOXIC LARGE OR REPEATED DOSES MAY
CAUSE NAUSEA, STUPOR, DEPRESSION, ATAXIA AFFECTS CENTRAL NERVOUS SYSTEM PROLONGED SKIN CONTACT CAN CAUSE IRRITATION.
. H 04 1 9^
I SODIUM BROMIDE
SECTION 5 - HEAtTH HAZARD DATA (CONTINUED)
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE MEDICAL COND. AGGRAVATED BY EXP: DATA NOT AVAILABLE.
PAGE 3 OF
CARCINOGENICITY
INDICATORS NOT GIVEN NTPri Yes rai -No
CARCINOGENICITY................. : SEE COMMENTS. SECTION X, IF NO INFORM- ATION
APPEARS, THE MATERIAL IS NOT LISTED AS A CANCER CAUSING AGENT.
IARC- w n Yes D No
OSHA- Yes - .No
EMERGENCY AND FIRST AID PROCEDURES EMERGENCY FIRST AID.............: GET MEDICAL ASSISTANCE FOR ALL CASES OF OVEREXPOSURE EYES. IMMEDIATELY FLUSH THOROUGHLY WITH LARGE AMOUNTS OF WATER SKIN: WASH WITH SOAP AND WATER THOROUGHLY INHALATION. REMOVE TO FRESH AIR INGESTION IF CONSCIOUS. INDUCE VOMITING GIVE ARTIFICIAL RESPIRATION IF BREATHING HAS STOPPED.
THRESHOLD LIMITS / TOXICITY DATA ACGIH TLV/OSHA PEL ITWAI....... : A PEL: NONE ESTABLISHED. TOXICITY DATA.............. -ORL-RAT LD50 3500 MG/KG.
^=-,. ^V-^SECTION 6 - REACTM1T = PAff$
STABILITY
Unstable O StaDle ^
CONDITIONS TO AVOID CONDITIONS TO AVOID .....: -NOME.
INCOMPATIBILITY (MATERIALS TO AVOID) MATERIALS TO AVOID........ I I WATER (XI ACIDS I I BASES ( I CORROSIVES I I OXIDIZERS (XI OTHER. HEAVY METAL SALTS. ALKALOIDAL SALTS, BROMINE TRIFLUORIDE.
<C>Y vsa;: i.4>l
1
REACTIVITY DATA: |dpN^tJED)j
HAZARDOUS DECOMPOSITION OR BYPRODUCTS HAZARDOUS DECOMPOSITION... -BROMINE. HBR, NA20
*
PAGE 4 OF S
&U
HAZARDOUS POLYMERIZATION May Occur Dum Not Occur n
CONDITIONS TO AVOID t ^ _ HAZARDOUS POLYMERIZATION.: DATA NOT AVAILABLE.
/
LEAK, AND DISPOSAL HOC^
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED SPILL RESPONSE: "TAKE UP AND CONTAINERIZE FOR PROPER DISPOSAL.
; v, ' >; v,v..;;
WASTE DISPOSAL METHOD WASTE DISPOSAL; TO BE PERFORMED IN COMPLIANCE WITH ALL CURRENT LOCAL. STATE AND FEDERAL REGULATIONS.
$:section a special protection information
RESPIRATORY PROTECTION VENTILATION. RESPIRATORY PROTECTION, PROTECTIVE CLOTHING. EYE PROTECTION: -MATERIAL SHOULD BE HANDLED OR TRANSFERRED IN AN APPROVED FUME HOOD OR WITH ADEQUATE VENTILATION PROTECTIVE GLOVES (NEOPRENE, PVC OR EQUIVALENT) SHOULD BE WORN TO PREVENT SKIN CONTACT SAFETY GLASSES WITH SIDE SHIELDS SHOULD BE WORN AT ALL TIMES
LOCAL VENTILATION SEE SECTION 8 - RESPIRATORY PROTECTION
MECHANICAL VENTILATION SEE SECTION 8 - RESPIRATORY PROTECTION
SPECIAL VENTILATION SEE SECTION 8 - RESPIRATORY PROTECTION
DO
CO/vp- rn 04190?
0p^rA/
SODIUM BROMIDE
SECTION 8 - SPECIAL PRCHECTnON;{INFORM^
OTHER VENTILATION SEE SECTION 8 RESPIRATORY PROTECTION
PAGE 5 OF
PROTECTIVE GLOVES
SEE SECTION 8 - RESPIRATORY PROTECTION EYE PROTECTION
SEE SECTION B RESPIRATORY PROTECTION OTHER PROTECTIVE CLOTHING OR EQUIPMENT
SEE SECTION S RESPIRATORY PROTECTION.
SECTION 9 - SPECIAL PRECAUTIONS
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
HANDLING A STORAGE
-KEEP
CONTAINER CLOSED STORE AT CONTROLLED ROOM
TEMPERATURE WASH THOROUGHLY AFTER HANDLING
DO NOT BREATHE DUST. DO NOT TAKE INTERNALLY
DO NOT GET IN EYES AVOID
PROLONGED OR REPEATED SKIN CONTACT DO NOT TAKE INTERNALLY.
WORK/HYGIENIC PRACTICES. WASH THOROUGHLY AFTER
HANDLING. DO NOT TAKE INTERNALLY. EYE WASH AND SAFETY EQUIPMENT SHOULD BE READILY AVAILABLE.
SECTION 10 - OTHER INFORMATION:
MISCELLANEOUS INFO.
PREPARATION DATE ......... OCT 27. *97 INFORMATION PHONE NUMBER :
-609' 39*-9200 HEALTH
o flammability o reactivity : c Special hazards.; n/a
DOT SMIPPINS NAME; N/A. DOT
NUMBER
N/A COMMENTS...................
-TESTS ON LABORATORY ANIMALS INDICATE MATERIA'. MAY PRODUCE ADVERSE
REPRODUCTIVE EFFECTS REV.
12/96 N/A. N/A - NOT AVAILABLE..
' '<
N "-"S VmTPP.al SAFETY
Oo .
7
CMS MAKES NO W ARRANT'* Oc ANY KIND WHATEVER WITH RESPECT THERETO AND
MATERIAL SAFETY * DATA fekEfeT
EM SCIENCE
NO,
Ship To:103366
DOW CHEMICAL PO BOX ISO BLDG 6601 PLAQUEMINE, LA 70764
|1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Manufacturer........................... :
EM SCIENCE A Division of EM Industries P.O. Box 70 480 Democrat Rd. Gibbstown, N.J. 08027
Preparation Date.: 01/24/92 Date MSDS Printed.: Apr 10, 1993
Information Phone Number.: 609-354-9200 Hours: Mon. to Fri. 8:30-5 Chemtrec Emergency Number: 800-424-9300 Hours: 24 hrs a day
Catalog Number(s): SX0570
Chemical Name....: Sodium Formate Trade Name.............. : Formic Acid Sodium Salt Chemical Family. . .* Organic Salt Formula..................... .. HCOONa
Molecular Weight.: 68.01
2. COMPOSITION / INFORMATION ON INGREDIENTS
Component
CAS #
Appr %
Sodium Formate
141-53-7
100*
|3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW Handling care generally in keeping with safe laboratory practices is recommended.
Appearance.................................: white crystalline powder
MSDS #SX0570
,, 00 A 0419
CONi- j DFNT
Page # l (continued on next page)
vr",Jt,,:
POTENTIAL HEALTH EFFECTS (ACUTE AND CHRONIC)
Symptoms of Exposure: No harmful effects indicated from available information. Handling care generally in keeping with safe laboratory
practices is recommended.
Medical Cond. Aggravated by Exposure: Data not available.
Routes of Entry.............................. ............... : Inhalation, ingestion
Carcinogenicity............................................... : The material is not listed (IARC, NTP, agent.
OSHA)
as cancer causing
|4. FIRST AID MEASURES
Emergency First Aid: GET MEDICAL ASSISTANCE FOR ALL CASES OF OVEREXPOSURE. Skin: Wash thoroughly with soap and water. Eyes; Immediately flush thoroughly with water for at least 15 minutes. Inhalation: Remove to fresh air; give artificial respiration if breathing has stopped. Ingestion: Get immediate medical attention.
|5. FIRE FIGHTING MEASURES
Flash Point (F).......................: N/A Flammable Limits LEL (%),: N/A Flammable Limits UEL (%).: N/A Extinguishing Media............:
Water, C02, Dry chemical, "Alcohol" foam
Fire Fighting Procedures.: Wear self-contained breathing apparatus.
Fire & Explosion Hazards.: Thermal decomposition produces toxic fumes.
6. ACCIDENTAL RELEASE MEASURES
V.
Spill Response:
Evacuate the area of all unnecessary personnel. Wear suitable protective equipment listed under Exposure / Personal Protection. Eliminate any ignition sources until the area is determined to be free from explosion or fire hazards. Contain the release and eliminate its source, if this can be done without risk.
MSDS #SX0570
no a ~ c
Page # 2 (continued on next page)
940
Take up and containerize for proper disposal as described under
Disposal.
Comply with Federal, State, and local regulations on reporting releases. Refer to Regulatory Information for reportable quantity and other regulatory data.
17. HAMMING AND STORAGE
Handling & Storage: Keep container closed. Store at controlled room temperature. Do not breathe dust. Do not get in eyes, on skin, or on clothing.
|8. EXPOSURE CONTROLS / PERSONAL PROTECTION
ENGINEERING CONTROLS AND PERSONAL PROTECTIVE EQUIPMENT:
Ventilation, Respiratory Protection, Protective Clothing, Eye Protection Material should be handled or transferred in aM approved fume hood or with adequate ventilation. Protective gloves should be worn to prevent skin contact (Neoprene or equivalent) Safety glasses with side shields should be worn at all times.
Work / Hygenic Practices: Wash thoroughly after handling. Do not take internally. Eye wash and safety equipment should be readily available.
EXPOSURE GUIDELINES
OSHA - PEL: Component
TWA PPM MG/M3
Sodium Formate
STEL PPM MG/M3
PPM
MG/M3 Skin
ACGIH - TLV:
TWA
STEL
CL
MSDS #SX0570
Page # 3 (continued on next page)
Component
PPM
Sodium Formate
. V -- _ " .v
MG/M3
PPM
MG/M3
PPM
9. PHYSICAL AND CHEMICAL PROPERTIES
Boiling Point (C 760 mmHg).: N/A Melting Point (c)................ . .: 253C Specific Gravity (H20 -1).: 1,92 Vapor Pressure (mm Hg)..........: N/A Percent Volatile by Vol (%): N/A Vapor Density (Air l)....: N/A Evaporation Rate (BuAc * 1): N/A Solubility in Water (%)....: Soluble Appearance.......................................:
White crystalline powder
MG/M3 Skin
1
|10. STABILITY AND REACTIVITY
Stability.................................. : Yes
Hazardous Polymerization:
Does not occur
Hazardous Decomposition.: Na20
Conditions To Avoid........... :
Excessive heat
Materials To Avoid............: ( )Water ( )Acids ( )Bases ( )Corrosives (X)Oxidizers ( )Other :
11. TOXICOLOGICAL INFORMATION
Toxicity Data:
orl-mus LD50: 11,200 mg/kg
Toxicological Findings: None Cited in Registry of Toxic Effects of Substances (RTECS)
12. DISPOSAL CONSIDERATIONS
rjO 4
MSDS #SX0570
Page # 4 (continued on next page)
-- - fti/ --i / \r, - --',-r. _.!* `mV * _.'v
Special Hazards:
Revision History: 09/01/84 10/27/87 03/01/91
| = Revised Section N/A Not Available N/E -= None Established
The statements contained herein are offered for informational purposes only and are based upon technical data that EM SCIENCE believes to be accurate. It is intended for use only by persons having the necessary technical skill and at their own descretion and risk. Since conditions and manner of use are outside our control/ we make NO WARRANTY, EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS OR OTHERWISE.
Portions copyright Ariel Research Corporation, 1991. Restricted use conditions apply. Selected regulatory information in this MSDS has been derived from Ariel Research Corporation's International Chemical Regulatory Monitoring System (ICRMS). Use of this data is provided Subject to the terms of the License Agreement between EM Industries and Ariel Research Corporation. Further distribution is prohibited without authorization.
MSDS SSX0570
Page # 6
no A 041 04O CONFTDFNT TAI
" - /s\ i
r
; fii.v. `.v/.i.Vv
VwA ,
epa Waste Numbers: Treatment:
Material does not have an EPA Waste number and is not a listed waste, however consultation with a permitted waste disposal site
(TSD) should be accomplished. ALWAYS CONTACT A PERMITTED WASTE DISPOSER (TSD) TO ASSURE COMPLIANCE WITH ALL CURRENT LOCAL, STATE AND FEDERAL REGULATIONS.
13. TRANSPORT INFORMATION
DOT Shipping Name................... non-regulated
DOT Number................................... none
14. REGULATORY INFORMATION
TSCA Inventory..........................: The CAS number of this product is listed on the TSCA Inventory.
Component
SARA
EHS (302)
SARA
EHS TPQ (lbs)
CERCLA
RQ
(lbs)
Sodium Formate
Component
Sodium Formate
OSHA Floor List
SARA 313
DeMinimis for SARA 313
(%)
15.OTHER INFORMATION
Comments:
None
NFPA Hazard Ratings:
Health
:0
Flammability : 1
Reactivity
:0
MSDS #XQ57Q
Dn A 041944
oonftdfnt M(
Page # 5 (continued on next page)
MATERIAL SAFETY DATA SHEET
EM SCIENCE
\*A ~ - * * 1
W,
Ship To:103366
DOW CHEMICAL PO BOX 150 BLDG 6601 PLAQUEMINE, LA 70764
Jl. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Manufacturer............................ :
EM SCIENCE A Division of EM Industries P.0. Box 70 480 Democrat Rd. Gibbstown, N.J. 08027
Preparation Date.: 12/10/92 Date MSDS Printed.: Apr 10, 1993
Information Phone Number.: 609-354-9200 Hours: Mon. to Fri. 8:30-5 Chemtrec Emergency Number: 800-424-9300 Hours: 24 hrs a day
Catalog Number(s):
SX0813
SX0814
SX0815
SX0818
6509
6516
Chemical Name.... Trade Name.......
Chemical Family.. Formula.....................
Sodium Thiosulfate Sodium Hyposulfite Inorganic Salts Na2S20j . 5H2O
Molecular Weight.: 248.19
2. COMPOSITION / INFORMATION ON INGREDIENTS
Component
CAS #
Appr *
Sodium Thiosulfate
10102-17-7
100%
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW EMITS TOXIC FUMES WHEN HEATED. MAY EE HARMFUL IF SWALLOWED. IRRITATING TO SKIN, EYES AND MUCOUS MEMBRANES.
Appearance.................................: Colorless, odorless crystals
MSDS &SX0815
on
Oo/vp
*
04194;
T^NTr^i
Page # 1 (continued on next page)
r-**i`vAVW. 'i".I?f. t' v** -` i.'vi
POTENTIAL HEALTH EFFECTS (ACUTE AND CHRONIC)
V
:;;'i Symptoms of Exposure: Irritating on contact with skin, eyes or mucous membranes; also
irritating to G.I. tract. Toxicity is considered low; however, toxic effect has been
evident in blood. Ingestion of large quantities has cathartic action.
Medical Cond. Aggravated by Exposure: Data not available.
Routes of Entry................................. Inhalation, ingestion
Carcinogenicity.............................................. : The material is not listed (IARC, NTP,
agent.
OSHA)
as cancer causing
4. FIRST AID MEASURES
Emergency First Aid: GET MEDICAL ASSISTANCE FOR ALL CASES OF OVEREXPOSURE. Skin: Wash thoroughly with soap and water. Eyes: Immediately flush thoroughly with water for at least 15 minutes. Inhalation: Remove to fresh air; give artificial respiration if breathing has stopped. Ingestion: If conscious, drink water and induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person.
5. FIRE FIGHTING MEASURES
Flash Point (F)..................... : Noncombustible Flammable Limits LEL (%).: N/A Flammable Limits UEL (%).: N/A Extinguishing Media............ :
Use any suitable for adjacent material.
Fire Fighting Procedures.: Wear self-contained breathing apparatus.
Fire & Explosion Hazards.: Thermal decomposition produces toxic fumes.
6. ACCIDENTAL RELEASE MEASURES
Spill Response: Evacuate the area of all unnecessary personnel.
MSDS #SX0815
Page # 2 (continued on next page)
ftU t
VA .'U
Wear suitable protective equipment listed under Exposure / Personal Protection. Eliminate any ignition sources until the area is determined to be 4 :f) free from explosion or fire hazards. Contain the release and eliminate its source/ if this can be done without risk. Take up and containerize for proper disposal as described under Disposal. Comply with Federal, State, and local regulations on reporting releases. Refer to Regulatory Information for reportable
quantity and other regulatory data.
7. HANDLING AND STORAGE
Handling & Storage: Keep container tightly closed. Store in a cool, dry, well-ventilated area away from oxidizers. Do not breathe dust. Do not get in eyes, on skin, or on clothing. Retained residue may make empty containers hazardous; use caution!
B. EXPOSURE CONTROLS / PERSONAL PROTECTION
ENGINEERING CONTROLS AND PERSONAL PROTECTIVE EQUIPMENT:
Ventilation, Respiratory Protection, Protective Clothing, Eye Protection Material should be handled or transferred in an approved fume hood or with adequate ventilation. Protective gloves (Nitrile, PVC or equivalent) should be worn to prevent skin contact Safety glasses with side shields should be worn at all times. Respiratory Protection: If workplace exposure limit(s) of product or any component is exceeded (see TLV/PEL), a NIOSH/MSHA approved air supplied respirator is advised in absence of proper environmental control. OSHA regulations also permit other NIOSH/MSHA respirators (negative pressure type) under specified conditions (see your safety equipment supplier). Engineering and/or administrative controls should be implemented to reduce exposure.
Work / Hygenic Practices: Wash thoroughly after handling. Do not take internally. Eye wash and safety equipment should be readily available.
MSDS #SX0815
Page # 3
00 A 041947 C.ONF TDFNT TA1
(continued on next page)
1 -:c;z}:ch
* v_ v * \ "_
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t-
EXPOSURE GUIDELINES
OSHA - PEL:
*
Component
TWA STEL
CMG/M3
PPM
MG/M3
PPM
MG/M3
PPM
Skin
Sodium Thiosulfate
ACGIH - TLV: Component
TWA PPM MG/M3
Sodium Thiosulfate
STEL PPM MG/M3
PPM
CL MG/M3 Skin
9. PHYSICAL AND CHEMICAL PROPERTIES
Boiling Point (C 760 minHg) . : decomposes Melting Point (C).......................: 48C Specific Gravity (H20 -1).; 1.729 Vapor Pressure (mm Hg)..........: N/A Percent Volatile by Vol (%): N/A Vapor Density (Air = 1)....: N/A Evaporation Rate (BuAc = 1): N/A Solubility in Water ()....: Soluble Appearance..................................... :
Colorless, odorless crystals
10. STABILITY AND REACTIVITY
Stability.................................. : Yes Hazardous Polymerization:
Does not occur
Hazardous Decomposition.: S0X, Na20
Conditions To Avoid......... : Excessive heat
Materials To Avoid............. : ( )Water (X)Acids ( )Bases
MSDS #SX0815
Ohlp
0< TOpN
I 94S
r?4l
Page # 4 (continued on next page)
Material Safety Data Sheet
May .be used to comply with OSHA's Hazard Communication Standard. 29 CFR 1910.1200. Standard must be
consulted (or specitic requirements.
IDENTITY (At Used On Lobol and Ust)
SUPER JET
Section 1
Manufacturer's Name Southern Chem Industries, Inc.
Address (Number, Street, City, State, and ZIP Code) P. 0. Box 222
LaPlace, Louisiana 70069-0222
SOUTHERN CHEM INDUSTRIES/ INC. P. 0. BOX 222
LAPLACE, LOUISIANA 70069-0222
Note: Blank spocos ore not pormittod. II any Horn It not applicable, or no Information Is available, tho space must be merkod to Indies :e dial.
Emergency Telephone Number
Telephono Number lor inlormntion
Dato Prepared
11-1-91
Signature ol Preparer (optional)
(504) (504)
652-5198 652-5198
Section II -- Hazardous Ingredients/Identity Information Hazardous Component* (Specific Chemical Identity; Common Namo(s))
Ollior Limit* OSHA PELACGIH TLVRocommondcdfc (optional)
Sodium Hydroxide
CAS #1310-73-2;2 mg/m
*Glvcol Ether
CAS //111--76--2
75 ppm (cV^r.)
^1
*This component is subject to the reporting requirements of SARA Title 313.
All other components in this product are considered nonhazardous according to the
following references:__________ l_________________________________________:_____________________________ 29CFR Part 1910, Subpart Z(OSHA) Toxic and Hazardous Substances
40CFR ACGIH NTP
Part 355. Appendix A (Extremely Hazardous Suhsi-anr-pg') EPA________________________ TLV for Chemical Substances______________________________________________________________ Annual Report on Carcinogens_____________________________________________________________
SnppHpc:--Material Safety Data Sheets
California - Proposition fiS______________
Section III -- Physical/Chemical Characteristics
Bolling Point
Vapor Pressure (mm Hg.)
Vapor Density (AIR 1)
Solubility In Wator
. Infinite
Appearance and Odor
212 F Not est. Not est.
Specific Gravity (HjO - 1)
Moiling Point
Evaporation Rato (nutyl Acnialn - t)
-- Clear red liquid, pleasant odor
Section IV -- Ftre and Explosion Hazard Data
Flash Point (Motltod Used)
Extinguishing Media
Special FJre Fighting Procedures -________
None
None None
rinmm.'thtu Limit/
1.08 N.A. Not est.
I Cl. UliL
Unusual Fire and Explosion Hazards ________ None
(Reproduce locally)
OSHA 174. Sept. 1985
QO A 041949 CONFIDENT! At
SUPER JET
Section V -- Reactivity Data
Stability
Unstable
Conditions to Avoid
Stable
X
Incompatibility {Materials to Avoid) ____ _________________________Strong acids
Hazardous Decomposition or Byproducts
Hazardous Polymerization
May Occur
Non e Conditions to Avoid
Will Not Occur
X
Section VI -- Health Hazard Data
Routers) of Entry:
Inhalation?
Skin?
Health Hazards (Acuta and Chronic) _Skin contact will cause irritation and dermatitis. Eve contact
Ingestion?
x
will cause burning and irritation. Swallowing may burn gastrointestinal tract.
Carcinogenicity:
NTP?
Not established
IARC Monographs?
OSHA Rogutatod?
-
Signs and Symptoms ot Exposure
Burning, redness, dryness of skin. Burning sensation in eves.
Medical Conditions Generally Aggravated by Exposure
Existing dermatitis
Emergency and First Aid Procedures Skin contact:
Wash with water and soap for 15 m
contact: flush with copious amount of water for 15 minutes, consult physician. Section VII -- Precautions for Safe Handling and Use ^alloying: drinl< Large quantity ot water, cs.;1
Steps to Be Taken in Case Material Is Released or Spilled _Small spill; Pick up with absorbent material. Large spill:
reclaim, put in containers. Neutralize before disposal.
Waste Disposal Method Neutralize, Flush with water. Follow federal, state & local regulations.
Precautions to Be Taken in Handling and Storing ------------------------------------------------------------ Keep container closed when not in use.
Other Precautions
Wash contaminated clothing before reuse.
Section VIII -- Control Measures
Respiratory Proioction (Specify Typo)
Ventilation
Local Exhaust
Use if mist present.
Special
Mechanical (Genera!) Use if mist present
Oilier
Protective Gloves
Rubber or neoprene Other Protective Clothing or Equipment
Eyo Protection Chemical goggles
Rubber boots, protective clothing. Eye wash on premises.
"
Avoid breathing mist.
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