Document yk76EYagOmxVGELrJgww8n5k4

VRD 0002 0 2 220 1 (conoeo) Conoco Inc. Request For Duplicating Work Date A Employee D)ivi$sion 09 U tofzx_j No. of originals Ext. 5(ob9 Room-Bldg. </SJS > lO Special Instructions 8-1/2x14 hole OCS^iodU. ($yrQ( 4-57 PB, 7-79 <YRD 0002022282 ETHYLENE DICHLORIDE/VINYL CHLORIDE MONOMER EDC/VCM 1 in iu u n aa^ A. GENERAL INFORMATION Ethylene dichloride and vinyl chloride monomer are intimately linked in the chemical industry. In any given year, 80 to 90 percent of ethylene dichloride production goes to make vinyl chloride monomer. Ethylene dichloride is a colorless liquid that boils at 83C. It is also known as 1,2-dichloroethane or glycol dichloride. In the chemical industry, it is abbreviated as EDC. Vinyl chloride is a gas at room temperature. It is also known as chloroethylene and ethylene chloride. In the chemical industry, it is known as VCM for vinyl chloride monomer. It is interesting that although they are linked by the large usage of EDC to make VCM, these two chemicals can exhibit different growth demands on a year-to-year basis. Apparently, when VCM production is down due to lower demand, certain producers continue to make EDC as a convenient way to store chlorine or future VCM. In the following year, although VCM use is increasing, EDC production does not keep pace due to the use of inventoried product. B. CHEMISTRY EDC is prepared by the direct chlorination of ethylene and by the oxychlorination of ethylene. It is common practice to link these two processes with the production of VCM. The three reactions together make up the so-called "balanced oxychlorination process." Vista Chemical Company uses this process at its facility in Lake Charles, Louisiana. The first step in the process is the direct chlorination of ethylene with chlorine gas to produce EDC. CH2 = CH2 + Cl2------ ^ Cl --CH2 --CH2 --Cl ethylene dichloride The reaction is catalyzed by FeCI3 and is run in the liquid state at --70C. The reaction produces heat. Temperatures up to 135C have been reported. The second step is the pyrolysis of EDC to produce VCM and by-product HCI. Cl-- CH2-- CH2-- Cl cahtaelaytst> CHa = CH -- Cl vinyl chloride + HCI EDC is passed through a tube containing a catalyst at 450-500C. The catalyst is usually pumice or charcoal. The EDC is cracked and splits out hydrogen chloride to produce VCM. Although the selectivity approaches 95 percent, a 50 to 60 percent conversion is usually realized. The three products then are separated. EDC is recycled back to cracking, vinyl chloride is sent to storage, and the hydrogen chloride is sent to the third step in the process. The third step is the oxychlorination of ethylene. Ethylene, oxygen, and hydrogen chloride (from EDC cracking) are reacted in a reactor over a special catalyst to produce EDC. 2CH2=CH2 + 4HCI + 02------- >2CI --CH2--CH2 --Cl + 2 H20 The reaction is run at 350-450C and can be run in a fluidized or fixed bed reactor. Although oxygen could be supplied by air, it is general practice to use pure oxygen. This step is the heart of the whole process. It allows the producer to use ail of the chlorines available and not lose one of them as hydrogen chloride. Vista's process now uses oxygen. The overall reaction of the "balanced oxychlorination process" is: 4 CH2=CH2 + 2 Cl2 + 02 4 CH2=CH--Cl + 2 H20 2/ VRD 6002822204 A C. PROCESS The process is diagrammed below. The EDC/VCM process can be run to maximize yields of any of the three products: VCM, EDC, or HCI. EDC is prepared in reactors by direct chlorination and oxychlorination. It is purified by washing with acid and then base. TTie EDC is drawn off and sent to a light ends column where a light ends distillate is removed. These light ends have commercial value and have been sold in the past to Vulcan Chemical. The bottoms from the light ends column are distilled to give EDC. The tar bottoms have been sold to PPG. The purified EDC is sent to furnaces to be cracked. Quench columns cool the products and remove tarry products. The products are refrigerated and hydrogen chloride is removed by distillation. The hydrogen chloride is either sent back to the oxychlorination unit or used at the Lake Charles Chemical Plant to produce methyl chloride from methanol. In general, about 10 percent of the hydrogen chloride is sent to the methyl chloride unit. After HCI removal, VCM is distilled from the remaining mixture. The VCM product is sent to storage while the unreacted EDC is sent back for recracking. D. PRODUCT SAFETY 1. Ethylene Dichloride EDC exposure may produce irritation to eyes, nose, and throat. Overexposure can result in headache, mental confusion, fatigue, loss of appetite, and possible bodily damage to kidneys, lungs, and digestive and nervous systems. EDC is an experimental animal carcinogen and mutagen. The 1984-85 ACGIH TLV recommended exposure limits for EDC are 15 ppm as an eight-hour time-weighted average and 15 ppm time-weighted average for 15 minutes. EDC should be handled in a closed system and only in well-ventilated areas. Local exhaust is recommended. EDC reacts slowly with water, producing a corrosive action. It will react violently with ammonia and NHx-containing compounds. 2. Vinyl Chloride Vinyl chloride is a gaseous, flammable material which can form an explosive mixture with air. It should be kept away from ignition sources, and all equipment should be grounded to avoid static electricity. Vinyl chloride should not be transferred or stored in vessels or fittings containing copper, aluminum, or their alloys. Vinyl chloride has been found to be carcinogenic. Its use is strictly regulated by an OSHA standard which sets permissible exposure limits of 1 ppm averaged for 8 hours with a ceiling of 5 ppm for any 15-minute period. E. THE VCM INDUSTRY 1. Background Tracking and anticipating the growth of PVC, the largest VCM end use, the U,S. VCM industry saw a strong increase in both demand and capacity during the 1970's. U.S. VCM production rose from 4.0 billion pounds in 1970 to 7.5 billion pounds by 1979, an average of 7 percent annually. Capacity increased by 7.5 percent annually, from 4.3 to 8.2 billion pounds, over the same period. Selling prices increased along with raw material prices. Since prices in Europe and the Far East rose more rapidly than domestic prices, U.S. VCM exports gained importance over the period. They went from 600 million pounds to 1.2 billion pounds and varied between 10 to 15 percent of total U.S. production. 3 VRD 0002022205 VCM - EDC PROCESS SCHEME ETHYLENE DICHLORIDE VINYL CHLORIDE s 4 Two and one-half years of recession In the United States, from 1980 to 1982, led to decreased demand for PVC building products and, consequently, vinyl chloride monomer. Because of lowered domestic prices due to over capacity and lowered U.S. demand, VCM exports remained competitive and ran at levels between 800 to 900 MM pounds. With an upturn in the U.S. economy in 1983 and 1984, both PVC and VCM domestic demand have increased some 10 to 12 percent over low 1982 levels. There are signs, however, that U .S. exports of VCM are on the downturn due to higher U.S, prices and increasing competition from Canada, Europe, and the Middle East in traditional U.S. Far East markets, Some minor permanent shutdown of older, inefficient VCM capacity (5 percent) occurred in 1982/83, along with a 700-MM-pound-per-year Shell plant at Norco, Louisiana. 2. Industry Conditions U.S. production of VCM hit a record 7.54 billion pounds in 1979, but was followed by a 14 percent decrease to 6.46 billion pounds in 1980, where it remained over the 1980-1982 recessionary period. By 1983, VCM production had recovered to 6.95 billion pounds, a 7.5 percent increase over 1982 but still 8 percent under the 1979 banner year. The production of PVC resins continues to be the major end use market for vinyl chloride monomer. It accounts for 85 to 90 percent of all U.S.-produced VCM. Exports have fluctuated between 800 to 920 million pounds over the past three years, for another 8 to 10 percent of the market. Chlorinated products Involve a minor 2 to 3 percent of the marketplace and are growing only with the economy. PVC growth is concentrated in the building products area, with pipe and fittings accounting for over 40 percent of all PVC pounds sold. Siding, window profiles, and food grade packaging and bottles are other areas of strong PVC growth. 3. Outlook VCM/PVC has enjoyed a long growth period, but there are signs that U.S. growth rates are slowing in the 1980's due to some maturing of markets and worldwide overcapacity and competition. Imports of VCM/PVC are also being targeted toward the U.S., especially from North American neighbors such as Canada. From 1950 to 1974, growth averaged 12 percent per year. Over the 1970's when large volumes of U.S. and foreign capacity were added, U.S. VCM/PVC demand still grew at a healthy 7 to 8 percent per year. During the 1980's, U.S. growth in demand for VCM/PVC is expected to average under 4 percent annually. However, this is trom a 5-to-6-billion-pound-per-year base. Thus the United States will continue to be the largest domestic market for VCM/PVC in the world. Building and construction end use markets for PVC will continue to drive U.S. demand for VCM/PVC. PVC pipe and fittings, a 2.0-biliion-pound-per-year market, will continue to grow at rates above GNP. PVC siding, window profiles, and other building extrusions are relatively young markets which will show strong growth over the decade, reaching 1.0 billion pounds by 1987. PVC rigid and flexible packaging and bottles, especially food grade, will increase in usage from the mid-to-late 1980's. The potential exists for development of better PVC extrusion and molding products and the use of blended and alloyed PVC to penetrate new market areas, The significant rise in the cost of crude oil over the 1970'$, especially in 1979, has led to a worldwide search for cheaper feedstocks. The start up and expansion of VCM/PVC capacity in areas of inexpensive feedstocks such as Canada, Mexico and the Middle East will mean increased worldwide competition for markets. World overcapacity and slowly rising demand, dependent as it is on the increasing health of world economies, may have a dampening effect on prices short term. However, other than Saudi Arabian and some minor Middle Eastern and Far Eastern projects, no large new volumes are expected over the rest of the decade. This should lead to a gradually improving world VCM/PVC supply and demand situation. In the United States, 1981 saw the last year for large increases in VCM capacity. A Georgia-Pacific grassroots plant (1.0 MMM lb) and a PPG expansion (500 MM lb) brought U.S. capacity to 10.7 billion pounds per year. 5 VRD 0002022206 A L iiiis n s s an* In 1982/83, shutdowns of older, inefficient plants occurred as producers either exited the business (Stauffer-175 MM; Ethyl-300 MM) or streamlined (Dow-200 MM). Shell temporarily shutdown a 700-MM-pound plant at Norco, Louisiana, in May 1983 to bring present U.S. VCM capacity to 9.0 billion pounds. This plant could be restarted over the next year or two. Other than a Formosa Plastics grassroots plant which started up in late 1982 (530 MM pound), no new U.S. capacity is planned. 4. Manufacturers a. Ethylene Dichloride PRODUCERS--ETHYLENE DICHLORIDE--1984 Producer MM lb Capacity Dow B. F. Goodrich PPG Georgia-Pacific Shell1 Formosa Plastics Vista Borden Arco Vulcan Union Carbide Total 4,800 3,380 2,700 1,595 1,400 1,390 1,185 510 450 350 300 18,060 'One plant only; Norco plant on temporary shutdown since May 1983. b. Vinyl Chloride PRODUCERS--VINYL CHLORIDE--1984 Producer MM lb Capacity B. F. Goodrich Dow Georgia-Pacific PPG Shell1 Formosa Plastics Vista Borden Total 2,600 2,100 1,000 840 840 830 700 600 9,5102 'One plant only; Norco plant on temporary shutdown since May 1983. ^his amount of VCM consumes roughly 16 MMM pounds of EDC in its manufacture. 6 80ZZZ0Z000 ciiy F. DEMAND--END USES 1. Ethylene Dichloride The largest end use for EDC is the production of VCM. In recent years, from 80 to 90 percent of EDC production has been used for this purpose. VCM will be discussed in a following section. The second largest end use for EDC is as a chemical intermediate for chlorinated organics such as 1,1,1trichloroethane, trichloroethylene, and perchloroethylene. 1,1,1 -trichloroethane is used fo prepare vinylidene dichloride (VDC). VDC accounts for 3 percent of EDC demand. VDC is used as a monomer or comonomer in halogenated polymers. Cl Cl I\ Cl--C--CH3 -------- > C = CH2 + HCI I/ Cl Cl vinylidene dichloride Many of the chlorinated solvent uses for EDC and its derivatives have been curtailed due to health effects and pollution controls. EDC finds widespread use as a solvent in the textile industry, it also has application as a solvent for metal cleaning and in adhesives. It can also be used as a fumigant in grain, upholstery, and carpets. Grain fumigants in the United States generally contain 20 percent EDC and 80 percent carbon tetrachloride. Ethylenediamine is prepared by reacting ethylene dichloride with ammonia. Cl -- CH2 -- CH2 -- Ci + 2 NH3------- > H2N -- CH2CH2 -- NH2 + 2 HCI It is used to produce chelating agents and carbamate fungicide. Ethylenediamine accounts for 3 percent of EDC demand. EDC has been used as a lead scavenger in gasoline, but its use here has declined as the use of unleaded gasoline has increased. Only a negligible amount of EDC is now used for this purpose. The attached figure depicts EDC end uses graphically. 1983 ESTIMATE OF EDC END USES Derivative Percent2 Vinyl Chloride Poly-Chlorinated C2's Ethylenediamine Lead Scavenger Export Miscellaneous 83 9 3 nil 5 Nil 2. Vinyl Chloride Monomer (VCM) Vinyl chloride monomer is used almost exclusively to produce polyvinyl chloride resins (PVC). These can be homopolymers or copolymers. VCM is compatible with a variety of vinyl monomers such as vinyl acetate, ethylene, propylene, vinylidene chloride, or acrylates in making the manufacture of copolymers. Polymer processes are so refined that variables such as molecular weight, particle size, and surface characteristics can be controlled to produce a particular resin with specific physical and chemical properties. 7 t VRB 0002022209 1983 EDC END USES ETHYLENEDIAMINES (3.0%) CHLORINATED ETHANES (9.0%) EXPORT (5.0%) VCM (83.0%) 1 9 8 4 VCM END USES PVC (86.951) A 30 03 S3 S3 CO ro 03 -* 1 H 2 xa r O 9 PVC resins are particularly compatible with a wide range of plasticizers and modifiers. All proportions of plasticizers, from low (5 to 10 percent) to high (near 100 percent) can be used, and this gives finished products a wide range of properties. PVC can be made hard and stiff or soft and flexible with varying degrees of each. Additionally, with expertise in the area, PVC resins can develop good resistance to weather, water, and chemicals. The ease of working with PVC resins has also helped its growth. It can be used in all types of normal plastics processes. PVC can be extruded to produce rigid forms such as pipe or siding or flexible forms such as garden hose or wire insulation. PVC resins are calendered to produce film and sheet products which can be rigid or flexible. These can be laminated to give wall coverings. Blow molding produces a wide range of containers, white injection molding produces automotive parts, toys, machine covers, and pipe fittings. The PVC end use pattern, which shows percentages of PVC used in construction, electrical/electronics, consumer products, home furnishings, packaging, transportation, and in exports and miscellaneous, is shown In the following figure. G. VISTA POSITION 1. History in 1966, Conoco entered into an agreement with the Stauffer Chemical Company concerning use of Staufferdeveloped VCM technology. Conoco and Stauffer were to enter into a 50/50 joint venture to construct a 600-MMpound-per-year plant in Lake Charles, Louisiana. The plant was to be engineered and operated by Stauffer. Plant construction began in late 1966. A court ruling in 1966 stated that the agreement was in violation of federal antitrust laws, and the court ordered Stauffer to divest itself of its interest in the Lake Charles plant to Conoco. Conoco was required to sell its PVC interests in Massachusetts. Conoco was allowed to continue operating the PVC facility at Aberdeen, Mississippi. The plant was officially Conoco'swhen start-up began in early 1968. At its start-up, it was the largest VCM plant in the world, This VCM plant was the first to use large reactor technology developed by Conoco. Several design flaws had to be remedied before it finally operated at design capacity in 1971. Minor debottlenecking and operational improvements have brought the plant to its present capacity of 670 MM pounds per year. A VCM plant turnaround in the spring of 1983 was combined with the conversion from air to oxygen technology at Lake Charles. This conversion brings Vista into compliance with Louisiana EPA regulations and provides potential production efficiencies from the more modern process. 2. Business Strategy Vista's basic strategy is to combine the best available manufacturing technology with high-capacity utilization to achieve above average earnings in the VCM industry. Our VCM output is directed primarily at the Vista Polymers PVC plants with the goal being to supply all of their requirements In a reliable and economic fashion. Purchases and sales of VCM are utilized to fine tune our supply/demand balance and optimize profits. 3. Strength and Weaknesses a. Vista has a well-integrated feedstock position. Current ethylene requirements can be supplied out of its Lake Charles ethylene plant, which has excellent reliability and production economics. A major part of the chlorine requirements will be supplied by pipeline from PPG. b. Our manufacturing facility is very reliable and efficient and has had a better operating history than our competitors. 10 VRD 0002022211 A 1 9 8 3 PVC END USES MISC. (4 .0 % ) TO A O <S5 CSD 5 r-o C3 r-o SJ hO --* r~i o oz W H a C o Ul A o a 11 u u im n ay c. A large, and still increasing, captive requirement provides a strong baseload to our business, leading to higher capacity utilization. d. Our very well-developed international network for VCM logistics and marketing provides flexibility and enables Vista to react to changes in market conditions. e. Our 100 percent dependability on chlorine is a weakness under market conditions as prevailing in 1980,1981, and 1982 (chlorine/caustic imbalance). Chlorine-driven competition (approximately 50 percent of U.S. nameplate capacity) can be aggressive in their pricing based on lower value of chlorine while we can take little advantage of such low-priced chlorine values. Additional flexibility will be considered in future contracts. 4. Product Volume The VCM plant is scheduled to operate at capacity in 1984 with one scheduled turnaround and should produce 670 MM pounds. Domestic supplies will be supplemented with total purchases of 100 MM pounds from PPG and B.F. Goodrich. 690 MM pounds of the VCM will be shipped to Conoco PVC plants, 50 MM pounds will be sold domestically, and 50 MM pounds will be exported, primarily to Brazil and the Far East.' 5. Feedstocks The production of 670 MM pounds of VCM requires 320 MM pounds of ethylene (50 percent of the Lake Charles ethylene unit's production) and 216 M tons of chlorine. This amount of ethylene is readily supplied by Lake Charles producing the required ethylene, while the chlorine supply is covered by contracts with two major suppliers, PPG and Diamond Shamrock. All chlorine arrives at Vista via the PPG pipeline. Additional chlorine for incremental EDC production can come from spot purchases. Spot purchases of EDC may also be used to supplement EDC production. 6. Pricing Strategy In the domestic VCM market, Vista does not have a strong enough position to be a price setter. Our strategy is to keep aware of market trends and increase our prices where possible. Vista must constantly be aware of the effects of irresponsible VCM pricing upon PVC prices; our stake in the latter is much greater. 7. Marketing Strategy Since Vista's capacity to consume VCM in our PVC plants exceeds capacity to produce VCM, our position in the merchant market is limited. Because of cycles in Vista's production and consumption of VCM, we maintain both purchase and sales contracts to balance the swings in our system. For example, we purchase more VCM when our production is down or sell more VCM when internal demand is depressed. Merchant sales are divided between the export and domestic markets. The export market operates primarily on a spot basis and is thus well suited to handle swings in our supply/demand balance. In the domestic market, we direct our sales efforts to those accounts where we can complement rather than compete with our PVC marketing program, 8. Manufacturing Strategy We are now forecasting only one turnaround in 1984 (February/March) depending on our experience with the new oxygen-based oxy technology and a new catalyst. Besides turnarounds, we are projecting to run at full operating rates in the three years ahead. 12 VRD 5002022214 9. Customers In 1984, Vista will toll process about 100 MM pounds of VCM through PPG and B. F. Goodrich. Major Vista customers and approximate volumes are: Customer MM Pounds Aberdeen PVC Plant * Oklahoma City PVC Plant CertainTeed Diversitech Uniroyal Export 425 265 25 15 10 50 13 BUSINESS Major Changes Could Confront Basic Petrochemicals This Year C3 *53 1 ;i * I ^ro I| As new foreign producers9 lower-cost output rises, lines, plant capacities, and operat ing methods. Some of the changes could be more severe than the Some 2.5 billion lb of dehydroge nation capacity to make butadiene was shut down from 1974 to 1984, U.S. industry faces changes in present situation warrants, say some industry sources. For example, the with as much as 80% apparently being scrapped. Much of this ca product tines, plant capacities, well-known shift by producers of pacity was replaced by coproduct commodity chemicals to specialties butadiene from the rapid expansion I and operating methods may be overdone, with the profit of steam cracker capacity during the ability of the shifts now in question second half of the 1970s. Bruce F. Greek, C&EN Houston in many cases. Another example is A large amount of steam cracker in current growth in grades and capacity fits into the category of This could be the year in which product specifications aimed at pro- potential shutdown. And any shift long-forecast major changes begin toward the heavier feedstocks for to affect the basic U.S. petrochem ical industry. Most industry sources Key Chemicals steam crackers could increase the effective capacities of important expect only modest, if any, gains in coproducts such as propylene, bu production in 1985. But, after this tadiene, and the aromatics. year, small declines in output could viding a product obtainable only A secondary effect on petrochem begin as a result of loss of export from a single source. This may be a ical capacity could result from the markets for most petrochemical de worthwhile marketing technique, perceived impact of petrochemical rivatives. And increased competi but it does boost inventory costs. products from the new plants in tion in U.S. markets will develop Capacity to make basic petrochem the Middle Hast. The seriousness of from imports of derivatives made icals certainly will decline for some this effect will become clearer in a in other countries with lower-cost time under price pressure as it af year or so after most of the Middle feedstock and fuel costs. fects profitability. For some prod Eastern units are operating. This leveling-off of production ucts, the shutdown could be huge-- For more on the outlook for basic growth of basic petrochemicals will as large as the already-completed petrochemicals, see the following lead to many changes in product shutdowns of butadiene capacity. pages. j;-s- 22 March 25, 1985 C&EN Key Chemicals Ethylene CH2=CH2 <53 <53 r-o Cp rw ro O*. Production ho/ding Capacity may rise Prices down PRODUCTION/CAPACITY Billions of lb ^ f/T Production Capacity* 1983 1984 1985 a First quarter; Includes shutdown capacity not expected to restart. MAJOR PRODUCERS Arco Chemical, Dow Chemical, Exxon Chemical, Shell Chemical, Union Carbide HOW MADE Thermal (steam) and catalytic cracking of hydrocarbons ranging from ethane to heavy gas oil MAJOR DERIVATIVES (U.S.) Polymers 50%, ethylene oxide 20%, vinyl chloride 15 %, styrene 5 % MAJOR END USES (U.S.) Fabricated plastics 70%, antifreeze 10 %, fibers 5 %, solvents 5 % FOREIGN TRADE Exports and imports negligible PRICES About 16 cents a lb for most merchant sales (about 30 % of production) U.S. ethylene production last year, at the only addition to capacity other than about 31.2 billion lb, may not be debottlenecking programs, which are surpassed until late in the 1980s. expected to add minor amounts to the That's about when domestic demand capacity total during 1985. finally will have made up for losses in However, some of the very old ca exports of ethylene derivatives being pacity, built more than 15 years ago, supplied instead by new foreign could be taken permanently out of competitors. potential operability during the next Production of ethylene in 1985 like year. This old capacity accounts for ly will match last year's. That output between 10 and 15% of the name level will depend on the current eco plate total. If a fifth of it Is scrapped in nomic trends continuing into the sum 1985, the loss would be about equal mer, and it also takes into account to expected additions. The shutdown increasing exports of ethylene deriva and scrapping of all the old capacity tives by newcomer producers in the will come along in bits and pieces, Middle East and elsewhere. It might be probably over five years. a different story, of course, if the U.S. Scrapping of old capacity depends economy improves and if exports of on many factors, most important of derivatives from other parts of the which is profitability. Even though deworld decline just modestly, perhaps predated, such capacity is inefficient 10% on the average. In that case, to operate. To raise the efficiency of 1985 production could surpass last some units might cost as much as to year's by about 500 million lb. If, on rebuild completely, and could possibly the other hand, the U.S. economy fal cost more than would additions to a ters in the second half of 1985, and if more modern unit. Moreover, an old foreign producers of ethylene deriva unit might require more costly feed tives take away a larger part of U.S. stocks than are available, as a result exports, then ethylene production could of changes in demand for various hy decline--as much as 1 billion lb, or drocarbons from petroleum and natu about 3%, by some estimates, to 30 ral gas. billion ib. A decision to buy ethylene rather Currently, more than 36 billion Ib of than to make it also could cut into old nameplate capacity is available for capacity. And a large decline in ex ethylene production. Not all of this ports of ethylene derivatives also could capacity is operating, because of low speed decisions to discontinue ethyl profitability or no profitability to pro ene operations at marginal production ducers at today's prices. It's widely units. Although a producer might now estimated about 2 billion Ib of capaci have little export business in deriva- ty currently is Idle but could be operat tives, competition still could increase ing. These figures mean that opera because other producers need to find tions at an annualized rate of about 31 a place for derivatives that they can't billion Ib are at almost 90% of the export profitably. on-stream capacity and at 85% of Even with some probable loss in available nameplate capacity. exports of ethylene derivatives, with Some small additional capacity like strong competition for sales, and with ly will be returned to operable name some shifting around in operating ca- plate capacity within a year. For ex pacify, the overall use pattern for eth- ample, by early 1986, an ethylene unit, ylene will not change much in 1985. now owned by Occidental Chemical Polymers will continue their slow gain but built by Cities Service near Lake in the share of total consumption at Charles, La., will be modernized and the expense of some of the smaller restarted, adding about 500 million Ib uses such as chlorinated derivatives to the total U.S. capacity. That will be used as solvents. j j J s j 1 ! * { ) 1 j j . 1 ; ; r* 9 CM Key Chemicals Propylene ch2=ch--CH3 Production up a bit Capacity fiat Prices down PRODUCTION/CAPACITY Billions of lb 1983 1984 1985 Note: All grades, a First quarter. MAJOR PRODUCERS Amoco Chemical, Arco Chemical, Dow Chemical, Exxon Chemical, Shell Chemical HOW MADE Recovered from cracked gas streams from steam crackers and refinery catalytic cracking units MAJOR DERIVATIVES (U.S.) Polymers 35 %, acrylonitrile 20 %, propylene oxide 10%, cumene 10% MAJOR END USES (U.S.) Fabricated plastics 50%, fibers 15%, solvents 15% FOREIGN TRADE Exports--negligible, imports-- holding at about 500 million lb for 1985 PRICES Chemical grade 16 cents per lb, polymer grade 17 cents per lb The outlook for propylene has at least one similarity to that tor ethylene--a nearly complete halt in production growth during 1985 after a major re covery in 1984. Production of all grades of propylene in 1985 will be up slightly to about 15.7 billion lb from about 15.2 billion lb last year. This covers all uses of propylene for making chem icals and polymers, but excludes re finery uses for making gasoline com ponents such as alkylate. The produc tion gain of slightly more than 1% compares with a nearly 11 % gain in 1984, the slowdown resulting from more severe competition in many ex port markets for U.S. propylene derivatives. Most polypropylene derivatives are made from chemical and polymer grades of propylene. A few excep tions use "refinery grade," whose pro pylene content may range from 35 to 90%. Gasoline components also use refinery-grade propylene, thereby act ing as competition for chemical uses. These uses also are in competition with the upgrading of the refinery-grade propylene stream for use in making derivatives. Roughly two thirds of propylene is produced in refineries, mainly in fluid catalytic cracking units; the other third is produced as a coproduct of ethyl ene in steam crackers. Practically all of the propylene made in steam crack ers is used to make chemical and polymer derivatives and an important part of refinery propylene also is used for derivatives. Except for the relative ly small quantity of derivatives made directly from refinery-grade propylene, most refinery-grade propylene used for derivatives must first be purified at a significant cost, The purification cost also makes the economics of deriva tive manufacture favor use of coproduct propylene wherever possible. Sufficient propylene capacity exists to meet demand if that available from refinery operations is included. But pro pylene must be priced high enough to justify its being drawn away from the fuel uses. This capacity could be ex panded, if returns on investment are sufficient, because cracking units in refineries produce more propylene than now is purified or used directly in mak ing derivatives. However, there is a limit to the quantity of propylene avail able at any time because the refinery cracking units are operated to make gasoline and other fuel components, and not to make propylene. Shifts In operation of steam crack ers and of refineries have led some derivatives producers to sound an alarm about a possible shortage of the chem ical and polymer grades of propylene. This alarm has caused higher prices of propylene relative to ethylene. Ten years ago, a rough rule of thumb was that the price of propylene was 70% that of ethylene. Now propylene prices are the same as ethylene prices or slightly higher, reflecting the apparently less plentiful supply. The causes of the current rough parity in prices for ethylene and pro pylene come from the economic squeeze of the early 1980s. The eco nomic recession led steam cracker operators to adapt to the lowest-cost feedstocks, largely ethane, to make ethylene at lowest possible cost. At the same time, refinery operations were cut back, because of lower demand for fuel products. More recently, im ports of fuel products have further reduced refinery operations. However, no real long-term short age of propylene is expected by in dustry sources. Even without steam cracker operators changing to heavier feedstocks to raise propylene yields to meet demands, more propylene could be taken from refinery fuel uses, if prices were to rise. The conditions of propylene prices and supply aren't expected to have any major impact on manufacture of derivatives. As is the case with ethyl ene polymers, polypropylene will grow faster than will most other propylene derivatives and will take a slowly grow ing share of propylene consumption. i 8TZZZ0Z000 Key Chemicals Butadiene \ ch2=ch--ch=ch2 i Production limited i Capacity large Prices holding U.S. butadiene producers will be push ing plants hard in 1985, including some recently restarted units. Nevertheless, they probably will be capable of sup plying less than 80% of the butadiene diene imported into the U.S., the situa tion is changing. Ethylene units are being shut down and their feedstock composition is changing toward light er hydrocarbons. All this is being done expected to be consumed domestically in anticipation of imports of ethylene this year. Imports, growing ever more derivatives from lower-cost feedstock PRODUCTION/CAPACITY difficult to obtain, will have to make sources in the Middle East. At the up the difference. same time, these changes are reduc Billions of ib Production of butadiene from ail ing the amount of coproduct butadiene sources in the U.S. will be about the available for internal use and for ex same as in 1984, a little more than port to North America and Japan. 2.5 billion Ib. But final output will de Therefore, the current question pend on a number of factors, including among consumers of butadiene is demand (largely for various elasto whether imports will be available to mers), feedstocks sent to steam crack meet the expected deficit In U.S. pro ers, and the strength of the dollar. duction. Countries other than in Eu Plenty of capacity exists to make rope have or appear to have little butadiene, either as a coproduct of capability to supply much butadiene. i making ethylene in steam crackers or Except for the strength of the dollar, by dehydrogenation of butylenes made competition could reduce this poten in refineries. This capacity is a mea tial supply. As long as the dollar re sure of the ability of producers to mains strong, the incentive to sell to 1983 1984 1985 First quarter: extraction capacity: includes shutdown capacity not expected to restart. extract butadiene from streams of C4 hydrocarbons produced in the U.S. or imported. During the past two years, it has been reduced as significant quan the U.S. will remain in preference to sales to countries such as Mexico where currency is being devalued. Prices of butadiene nevertheless MAJOR PRODUCERS Amoco Chemical, El Paso Products, Exxon Chemical, Shell Chemical, Texas Petrochemicals tities of capacity have been scrapped. Some of the capacity now counted in the total probably will be scrapped without ever being run again, but the "on-standby" designation hasn't yet might firm slightly during 1985 if de mand should increase again this year following the increase in demand of more than 9% in 1984. If prices firm by a small amount as the result of HOW MADE Recovered from steam cracker product streams; dehydrogenation of butylenes from refinery catalytic cracking been changed. Except for a small amount of buta diene produced by dehydrogenation of butylenes, all butadiene consumed in the U.S. is a coproduct of ethylene manufacture. Critical to butadiene pro perceived stronger demand in the U.S., then both imports and production could ' rise. Some increase in butadiene prices has not reduced consumption gains much from what had been anticipated MAJOR DERIVATIVES (U.S.) Styrene-butadiene rubber 40 %, polybutadiene rubber 25 %, duction is the feedstock used in steam crackers to make ethylene. If ethane is the feedstock, butadiene production is minimal. As feedstock to a steam with the economic recovery. In 1985, some of the smaller uses such as acrylonitrile-butadiene-styrene resins may grow faster than will the major MAJOR END USES (U.S.) cracker is shifted toward heavier hy elastomer uses. This growth, slowing Fabricated rubber products 75 %, fibers 10% drocarbons, the butadiene yield rises rapidly. On the average in 1984, the yield of butadiene in steam crackers after a large gain in 1984, will not be large enough to change the end use pattern much. In spite of some devel FOREIGN TRADE was less than 8% of the ethylene opment work with this unusual diolefin, Exports--holding at about 150 yield, an output of two thirds or less of no new uses will appear to take signif million Ib in 1985, imports--may the yield of butadiene relative to ethyl icant quantities of butadiene. j fall to about 600 million Ib in 1985 ene in Europe where naphtha still con At current and expected prices for j PRICES tinues to be the major steam cracker butadiene for 1985, production will just j feedstock. about hold steady or inch up slightly. j Y About 30 cents per Ib In Europe, the source of most buta Consumption will hold about even. t \ Marrh?S iqflfrtACN ?R Key Chemicals Benzene Production flat Capacity holding Prices firming PRODUCTION/CAPACITY Billions of gal 3 Production Capacity* 1983 First quarter. 1984 1985 MAJOR PRODUCERS Amoco Oil, Arco Chemical, Coastal Corp., Exxon Chemical, Gulf Oil Products, Shell Oil, Sun Oil HOW MADE Separated from aromatic streams from refineries, olefin plants, coke ovens; dealkylation of toluene MAJOR DERIVATIVES (U.S.) Ethylbenzene 50%, cumene 20%, cyclohexane 15%, aniline 5% MAJOR END USES (U.S.) Styrenic plastics 35 %, phenolic resins 20%, nylons 15% FOREIGN TRADE Exports--small, remaining at about 20 million gal in 1985; imports-- slipping to 150 to 160 million gal in 1985 PRICES List price $1.17 per gal The best news to come to benzene producers this year is a slight firming of prices. Beyond that, it's a pretty ho-hum outlook for benzene: Produc tion probably will not grow appreciably, nor will capacity rise further following the addition of a new Sohio plant at the end of 19S4. The price firming, however, may not do enough for benzene producers. Spot prices for benzene, reflecting only a part of total sales, increased in small increments beginning in January. By early March, they were above the list price, which had dropped significantly in 1984. These spot prices reflect mainly de mand factors and feedstock conditions beyond those in the chemical industry. The spot price rise went along with firming of gasoline prices, and was related to the value benzene has in gasoline, both as a volume compo nent and as an octane contributor to the total pool octane value. Some mi nor effect was felt from the drawdown of benzene inventories in 1984 and from anticipated improved demand for some end products of benzene. During 1984, benzene prices fell more than 30 cents a gal, or nearly 20%, because of stagnant demand, lower prices for some derivatives, large inventories, and declines in crude oil prices. Spot prices ranged slightly be low list prices during the second half of the year, further hurting profits from recovery and selling of benzene. That situation changed during the first quarter of 1985. Now, questions are developing as to whether these price increases, small as they are, will hold for the rest of the year. Benzene demand in the second quarter proba bly will be as good as in the first quarter. Later on, demand may weaken, pulling down production as inventories build. Benzene production for all of 1985, therefore, likely will end up about the same as in 1984, at 1.3 billion gal. This hold on production could mean that a slight decline will occur in the operating rate for total nameplate ca pacity, but it essentially will remain at about the same 55% rate that it has been the past two years. Nameplate capacity, much of which is in or closely attached to refineries, long has been considered to be well overstated. If sufficient aromatics streams could be obtained, then the nameplate capacity might nearly be reached. But even so, capacity still could be overstated because of units, long shut down at steel mills and small refineries, which are not expected ever to be run again, in addition, several relatively large benzene units currently are shut down, with questions about future operation concerning some of them. Some small amounts of capacity have been scrapped, but during the fourth quarter of 1984, Sohio Chemi cal started up its new unit with a nameplate capacity of 115 million gal a year. The actual net gain in capacity for 1985 operation is hard to pin down, but probably at least two thirds of Sohio's new unit capacity should be added to the total. Part of benzene capacity is attached to steam crackers where benzene is separated from the pyrolysis gasoline fraction of the product stream. Typi cally, benzene produced in steam crackers has accounted for about 25% of production, or a bit more. The other part of benzene supply--imports-- could decline a bit in 1985 unless domestic prices rise. As U.S. selling prices decline during 1984, imports also decline because of little or no profit to traders in benzene. This year, imports could supply at least 10% of U.S. benzene demand, but certainly not more than 15%. None of the major uses of benzene will show much gain in demand during 1985. One--styrene--because of im ports of polymers, could decline slightly. The result, then, for benzene will be a year of minor change in production and a struggle to squeeze a bit of profit from a slight price firming. 28 March 25. 1985 CAEN V'RD 0002022220 it l Key Chemicals p-Xylene j Production may slow [ Capacity up a bit Capacity to make p-xylene continues to expand. It grew again in 1984. But, although that doesn't help prices or are estimated to top 1 billion lb of p-xylene. This estimate depends upon a growing demand for the isomer for Prices couid firm profitability for producers, it does bring polyester fibers and for some fabricat a small increase to production, if for ed items in the Pacific Rim countries. i 1 PRODUCTION/CAPACITY no other reason than that it increases inventories necessary to meet expected sates volumes. It also depends upon continued pro duction difficulties at plants in devel oping countries that require p-xylene i i i Billions of lb Because of a net capacity increase during 1984 of about 400 million lb, output during 1988 likely will rise either for their own fiber production or to fill commitments for exports made before the plants were completed. slightly, perhaps about 100 million lb, If fiber demand in some of these to 4.4 billion lb. The final figure will countries rises steeply, partly spurred depend on availability to producers of by exports of apparel to the U.S., and mixed xylenes, on the export markets if operational problems get worse, ex for p-xylene (as well as for o-xylene), port demand for p-xylene could soar and on the size of imports of apparel by an additional 100 million to 200 made using polyester fibers. million lb in 1985. Of course, this rise A production total of 4.4 billion lb of in export demand would not translate p-xylene in 1985, however, will not back into an equally large increase in raise the plant operating rate. Name production. Most of the additional ex plate capacity for this year will reach ports of p-xylene would return to the 5.7 billion lb, with all of it expected to U.S. as apparel, offsetting consump 19B3 1994 1995 operate to supply sales demand and tion of polyester fibers for apparel a First quarter. inventory building as needed during made in the U.S. and reducing total the year. The actual operating rate demand for p-xylene by nearly an equal will be about 77% on the average, amount. MAJOR PRODUCERS Amoco Chemical, Arco Chemical, Chevron Chemical, Exxon Chemical, Koch, Phillips Chemical down slightly from the estimated aver age rate of 81 % in 1984. The various factors that Influence production probably will change only slightly during 1985 when growth in With almost 80% of p-xylene even tually ending up in fibers made in the U.S., the outlook for fibers and appar el demand continues to be critical to total p-xylene consumption. In gener ; HOW MADE Separated from mixed xylene ' streams made in oli refineries and steam cracking olefins plants output will be quite close to, but prob ably slightly below, growth in gross national product. But these factors also could strongly influence pxylene pro duction. For example, mixed xylenes al, polyester fiber demand In the U.S. is expected to do no better than hold even. A slight decline is more likely. But demand for p-xylene in making MAJOR DERIVATIVES (U.S.) i Dimethyl terephthalate 55%, ' terephthalic acid 45 % > could become more expensive because of the more rapid shift toward unlead ed gasoline, which results from lowered limits on use of lead alkyls, more strin polyester bottle resins, both the poly ethylene and the polybutene terephthalates, probably will increase an amount about equal to the decline in ! MAJOR END USES (U.S.) gent controls against misfueling of demand for use in fibers. catalytic-muffler-equipped cars, and a The result of a lower demand for s Polyester fibers 80%, blow-molded higher percentage of cars requiring p-xylene for making polyester fibers } t items (mostly bottles) 10%, films 5% premium unleaded fuels. If demand for and a higher demand for making bottle j FOREIGN TRADE p-xylene does not remain strong enough resins could make p-xylene one of the to pay the competitive price for it to few major-volume petrochemicals to i Exports--may exceed 1 billion lb in be removed from the mixed xylenes show a change in its use pattern in 1985, imports--may be greater than streams, then actual production could 1985, If a change to 75% or less of 100 million lb in 1985 decline. U.S. consumption for fibers and to PRICES At the same time, the export de more than 15% for bottle resins mand also could change. Based on doesn't occur in 1985, it certainly will List price 22 cents per lb delivered recent experience, exports for 1985 in 1986. March 25, 1985 C&EN 27 VRD 60020222 2 1 Villa Chemical Company VCM Vinyl CKIoHd* Monomer A Description: Vista vinyl chloride monomer (VCM) is a high purity, clear, colorless, sweet smellinggas at ambient tempera ture and pressures. It polymerizes readily in the presence ofair, sunlight, oxidizing agents, and free-radical cat alysts. to form a hard, white resin-polyvinyl chloride (PVC). Applications: Vista vinyl chloride monomer is used in the manufacture ofpolyvinyl chloride for use in pipe and pipe fittings, siding, window profiles, and food grade packaging and bottles. It is alsocompatible with a variety ofvinyl mono mers such as vinyl acetate,ethylene, propylene, vinylidenechloridc,andacrylates in the manufactureofcopoly mers. Vista vinyl chloride monomer is suitable for use as an intermediate in the manufactureof 1,1,1-trichloroechane for use as a solvent or degreaser. Properties Specification Typical Vinyl Chloride, Wt.%* Water,ppm MechylChloride, ppm Acetylene, ppm 1,3-Butadiene, ppm 99.98 min 100 max 70 max 2 max 12 max 99.98 <50 <50 <1 <10 Total C4 Unsaturates 40 max <20 Acetaldehyde, ppm 1.0 max <0.5 Non-Volatilcs, ppm Iron (non-filterable), ppm Acidity (as HCI), ppm 25 max 0.15 max 1 max nil <0.1 nil Oxygen in Vapor Space, ppm,vol. before loading after loading FreezingPoint,C 1,000 max 500 max <350 -153.7 BoilingPoint, "C Flash Point(COC),C SpecificGravicy, Liquid(20C/20C) Density, (20C), Lb./Gal, Solubilicy(HzOin VCM), Wt. % -13.8 -78 0.9121 7.6 0.11 Explosive Limits (Volume in Air), Vol. % UppcrLimit LowerLimit excludes water,oxygen and non-volatiles. 22.0 4.0 NOTE: For export shipment up to 5 ppm of hydroquinone inhibitor will be added. Safely and Handling: When inhaled at high concentrations, vinyl chloride monomer acts as an anesthetic.Prolonged exposure to excessive amounts ofVCM may cause cancer. Vinyl chloride is a highly flammable gas and can easily ignite at most normal atmospheric conditions.The handling, use and exposure to VCM in the workplace is strictly regu lated by OSHA. Refer to 29CFR, Part 1910.1017 for specific requirements. THE DATA CONTAINED HEREIN ARE FOR GENERALINFORMATIONALPURPOSESONLY.PLEASE REFERTOTHE VISTA CHEMICAL COMPANY MATE RIAL SAFETY DATA SHEET FORSPECIFIC, COMPLETE INFORMATION REGARDINGTH1SPRODUCT. Storage and Transfer: Store Vista vinyl chloride in steel tanks, cither under refrigeration or under pressure at atmospheric temperatures. Do not use vessels or fittings made ofcopper or aluminum ortheiralloys. Blanket storage tanks with inert gas, and nc ver allow air toentcr the tanks* In the presence ofwatcr,VCM accelerates thecorrosionofironorsteel. Availability: Uninhibited or inhibited grades ofVista vinyl chloride are shipped as a liquid in pressurized tankcars from Westlake, Louisiana. Product can be made available in bulk vessels, for barge orvcssel liftings. Contact Vista Chem ical Company for information regarding water shipment. Vina ualraJtmarttfVuuChfmifalCnmpairj. The above dita ire based on tests and eapenence which Visu Chemical Company believes reliable, and are supplied far informational purposes only. VutaChcniicaJ Company and its subsidiary, Vista Polymers Inc,, disclaim any liability for damage or injury which results from the use of the above dm and nothingcontained therein shall constitute aeuiraniec. warranty or representation (including freedom from patent liability)by Vista Chemical Companyot Vista Polymers Inc. with respect to the data, the pruduct described or their use for any specific purpose, even if that purpose isknown to^ isu ChemicalComparsyor Vrsulhdyrncn Inc. Fordetailed informa tion regardingthese products, please refer to the respective Vista Chemical Company or Vata Polymen Inc. Material Safety Data Sheet. ISOIBMII |4-l I/H4-IM VIS1A VRD 0002022222 TLV e a c ts w ith Cu a n d Al "0 I "< (/> 70 3 Qo 3> 3 nP` '* Q a; (D oi o Q u T> "t TJ TJ 0 w 333 0 01 00 iQ CD a. 3 0 c 0* "1 I m > r H I H 5 < O CO > T r -< > an vr t A CHEMICAL MANUFACTURERS ASSOCIATION June 10, 1992 TO EXECUTIVE CONTACTS OF CMA MEMBER COMPANIES Dear Executive contact: As part of its increasing use of economic arguments in its advocacy, CMA has developed leaflets and brochures that have made an impact in recent debates on "toxic use reduction** bills and other issues. Depending on the topic covered, some of these "handouts" may be useful to you in communicating with various audiences, for example: customers, suppliers, current and retired employees, plant visitors, local community groups and officials, federal and state legislators, and potential employees contacted during college recruitment visits. Samples of the currently available materials are enclosed. The leaflet "The U.S. Chemical Industry: Keystone of U.5. Manufacturing" can be oriented to any of 24 individual states by inserting that state's "Industry Fact Sheet." An example state fact sheet--all the state fact sheets are similar in format--is included in the enclosed sample materials. Color 35 mm slides are also available for the "U.S. chemical Industry" and "Protecting the Environment" leaflets, should you want to present these materials in oral briefings. Each of the leaflets was transmitted to our printer in computerized, electronic form. Should you wish to do your own printing of any of the leaflets, substituting your logo for CMA's logo, we can make our electronic version available to you. We intend to develop similar materials on other topics of interest to the industry. The items currently available have been priced to encourage mass distribution. A price list and ordering information is attached. cc: CMA Key Contacts oc2501 M Street NW. wash.ngton 20037 202.887.1100 Panalax 202-887-1237 Te<e* 3961 7 (CMA WSH PRICE LIST FOR NEW ADVOCACY ITEMS Description Price The u.S. .Chemical Industry $7.00 /100 --State--Industry Inserts for--Above: Alabama California Connecticut Delaware Florida Georgia Illinois Indiana Kentucky Louisiana ' Maryland $2.00 /100 IV ft M IV ft Vff II II VI If Massachusetts Michigan Minnesota Missouri It VI If II New Jersey New York North Carolina Ohio Pennsylvania South Carolina Tennessee Virginia West Virginia II If If M VI It If M II U.S. Chemical Industry 35mm Slide set $75.00 Ea Chemicals, Manufacturing and Cars $8.00 /100 Protecting the Environment 35 mm Slide Set $7.00 /100 $75.00 Ea Facts About Toxic Use Reduction (TUR) Legislation 3.00 Ea RD 0002024898 < Facts About Toxic Use Reduction (TUR) Legislation H.R. 2880 H.R. 3865 S. 2123 S.1081 S. 761 S. 976 Chemical Manufacturers Association Washington, D.C. June, 1992 3 fe/F.k 1.10 VRD<ff0m24H Table of Contents Facts About Toxic Use Reduction Legislation Toxic Use Reduction (TUR): What's It All About? Toxic Chemical Data Elements The impact Of TUR On Chemical Manufacturing What Is Chemistry? Foundations of Inorganic Chemistry Organic Chemicals Organic Chemical Chain Benzene Chain Ethylene Chain Propylene Chain Xylene Chain Toluene Chain Butadiene Chain Methane Chain Butylenes Chain Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Uses Of "Toxic" Chemicals "Toxic" Chemicals In Paper Recycling "Toxic" Chemicals In Steel Production "Toxic" Chemicals In Electronics "Toxic" Chemicals In Aerospace "Toxic" Chemicals In Recreation "Toxic" Chemicals In Pharmaceuticals "Toxic" Chemicals In Textile Production "Toxic" Chemicals In Construction "Toxic" Chemicals In Furniture "Toxic" Chemicals In Printing "Toxic" Chemicals In Food Processing No Cars Without Chemicals: Auto Industry Examples of Eliminating Toxic Chemicals No Cars Without Chemicals: Examples of Chemical Based Components Other Laws Regulating Chemicals Key Conclusions Appendix Page 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 VRD 0002024900 < Toxic Use Reduction (TUR): What's It All About? Current legislative proposals would mandate detailed reporting on the use in manufacturing and chemical processing of over I ,000 chemicals characterized as toxic and the elimination or reduction in use of these chemicals. The more than 1,000 chemicals affected would range from unprocessed elements of the earth and basic building block organic chemicals to highly specialized chemicals created by many stages of chemical processing. These more than 1,000 chemicals have been characterized as "toxic" without systematic reference to risks on the basis of exposure, concentration, dosage, or other relevant criteria. It is not possible to reduce the production and use of over 1,000 key chemicals by using benign, ntm-toxic substitutes. A mandate to reduce the use of over 1,000 key chemicals would be a mandate to reduce the production of U.S. chemicals and the output of all U.S. manufacturing. Detailed reporting on the use of over 1,000 chemicals in individual processes would also markedly increase consumer costs and divert resources from more productive uses -- both economic and environmental. i In addition, toxic use reporting would give foreign competitors vital intelligence on how U.S. high-tech chemical products that are vital ingredients for other U.S. manufacturers are made. I VRD 0002024901 * Toxic Chemical Data Elements (Current and Proposed) Millions of Data Elements Current Reporting 1993 Per Pollution Prevention Act Laulenberg Or SIKorskl Bills Under existing toxic release inventory requirements, EPA currently collects and manages about 5 million data elements. That number will rise to 8-9 million by 1993 under the terms of the Pollution Prevention Act of 1990. New legislation would require huge increases in reporting by individual facilities. New reports on chemical uses and throughputs - not just emissions - would be required at the production unit level. Some facilities have tens or hundreds of production units and processes. A significant diversion of resources from more productive uses to recording and reporting would be required. Requiring 225,000 facilities to report on 1000 chemicals and creating a huge - possibly unmanageable -- data base would at best be an incredibly expensive way to approach a perceived but ill-defined problem. Most likely, it would be counterproductive. EPA estimates that the Laulenberg and Sikorski Bills (S. 2123 and H.R. 2880) would raise the pieces of information collected each year to 100 million, a twenty-fold increase from current levels, adding billions of dollars to industry's costs. U The costs of expensive mishandling of perceived problems - including the costs of detailed data collection ~ in the end are borne not by businesses, but by individuals. These costs are a regressive tax on every person in the U.S. economy. _l Every person in the U.S. economy has a stake in intelligent, cost-effective decisions on toxic chemicals. VfiD 0882824902 < The Impact of TUR On Chemical Manufacturing Toxic use reduction legislation would require the reduction in the manufacture and use and/or the detailed reporting on the use in chemical and other manufacturing processes of over 1,000 chemicals characterized as "toxic" by the legislation. The pages that follow illustrate the potential effects of the legislation on the chemical industry and U.S. manufacturing by showing the role in chemical processing and manufacturing of only about 60 of the more than 1,000 chemicals that would be affected by the legislation. 3 VRD 0602024903 K What Is Chemistry? Chemistry combines organic and inorganic materials from the earth with heat, air, and water to make products useful in modern civilization. U Organic chemicals begin with raw materials containing hydrocarbons such as oil, natural gas, and coal. I U Inorganic chemicals do not contain carbon but are made from ores. They are listed in the "Periodic Table of Elements". VRD 8802824984 Foundations of Inorganic Chemistry i Periodic table of the elements is Oreup IA VfllA 2 H 1.0079 HA uilon rvvloui | -CAS*iriion - 13 14 IS IS 17 IIIB IVB Vfl VIS VIIB He - ---- fllA IVA VA VIA VI1A 4 00260 34 $ 6 7 1 10 LI Be 1.941 1.013II B 10 It N (4.0047 om 15 9994 foSF 2N0 1e79 11 12 2 4 S 6 7 9 10 11 12 Na Mg IBA-JMVA VA VIA VHA VIKA 22 MU J4.309 m 1VI -vo via viib |------ vni ---j ib im 21S.00i55 16 IB s ra) 32.00 nfk#V Ar 39.941 19 20 21 22 nKmi C40 aM 44SMcSI Tl 47.U 26 5F51e47 31 32 Ga Ge 1972 72 59 34 S71 eK 36 Kr II 00 37 39 39 40 41 42 & STr Y II H lx ii aa Nb II 9014 Mo IS 94 43 Tc l) 44 Ru 101 07 rIi 102 904 46 Pd 104 42 mm mC.tsos 7J 73 74 75 7* 77 76 79 Lai I3I.9M k1H714f1 Ta 110.141 w tu.is Re 114.207 Otoos.i lr 192 22 Pt 11500 Au 194 947 49 SO 1I14n.12 Sn 111.71 Te 127 40 3 94 20B0 Mi 0 Po (2W) 53 1 (24 995 IS .AHOt) 54 Xe l 29 66 Rn <2221 7 19 1 104a 10$ . 106 A 107 - Fr |223| mRwas Ac fUnq 727.0711 |)lp Unp |HJ)r Unh (71J| Uns" |K7| Lanthanide series 58 St 60 Ce Pr Nd >40.12 141904 144 24 61 62 Pm Sm |HI) 154 31 63 Eu 15194 dd ft 16 Dy 67 Ho 66 Er 69 70 Tm Yb 71 Lu 157 25 151125 1(2.50 114 930 117 21 141.9)4 17) 04 <74 947 Actinide series 90 1 92 93 94 9$ 96 97 91 99 too 101 102 >03 Th Pa u Np Pu Am Cm Bk 332 031 231.034 210.821 2)7 040 (244) Il3) (247) <K7) Cl (251) Es Fm Md No I252| (252) >251] <2591 Lr 1710) Elements Regulated Because of Toxicity: Aluminum Bromine Antimony Cadmium Arsenic Chlorine Barium Chromium Cobalt Copper Fluorine Lead Manganese Mercury Nickel Phosphorus Silver Thallium Vanadium Zinc U The "Periodic Table" lists the 107 elements that are the basic building blocks of the earth. These elements include the elements that are the foundation of inorganic chemistry. Nearly 20% of the earth's elements are characterized as "toxic" in current bills before Congress. These elements are ` indicated by a symbol. U There are NO substitutes for elements. new elements will be discovered in large quantities. U The 20 toxic elements Illustrate that the popular notion that "natural" is better than "synthetic" is not necessarily trc _VRtK\ 000 20 2 4 5 0 5 Organic Chemicals Organic Chemicals are about three-fourths of total U.S. chemical production. The following charts illustrate the widespread --and essential-- production and use of "toxic" chemicals at critical stages in processing chains. In interpreting these diagrams: And x = termed "toxic" by proposed legislation. - vertical lines in bold face indicate "breaks" in the chemical processing chains that would be caused by toxic use reduction. fi Organic Chemical Chain 0Bcpzene See Benzene Chain (Page 8) 0Ethylen See Elhylene Chain (Page 9) 0Propylen<CX10Xylcne 0Toluene See Propylene Chain (Page !0) See Xylene Chain (Page I!) See Toluene Chain (Page 12) 0Butadien Methane See Butadiene Chain (Page 13) y See Methane Chain (Page 14) Butylene See Butylene Chain (Page 15) The initial chemical processing of organic inputs - oil, natural gas, and coal - creates eight major basic "building block" chemicals. These eight major chemicals are essential inputs to creation ol all the downstream products in the organic chemical chain. Six ol these eight major organic chemical building blocks are characterized as "toxic" in current legislative proposals. (J These six "toxic" building blocks account for 80% of U.S. sales of all organic chemical building blocks. U Chemistry -* creating new materials -* depends on the reactions o( inputs with one another. Often, properties that make a chemical reactive also make it toxic. j Benign substitutes will not be found lor 6 of Ihe 8 basic building t s ol organic chemistry. VRD 8002824921 0 Elhylcnc ___ Benzene Chain <s> jEthyl -------- -*1 Styrene Acrylunilrilcj--------------------------------------- ^j.Scc Propylene Chain (Page 10) Benzene _aj Acrylonitrile Buladicne Styrene jSec Propylene Chain (Page llvT Styrene -0 Polystyrene ~^j Slyrc nc Butadiene l-alex ->|loodPackaging. Medical ft Denial Products, Electronics. Fumilure. Housewares j~^|.Sce Bulatlienc Chain (Page 13) r&i Propylcn 01Maleic Anhydride ]SMA Resins >|l,atcx Paints. Moor Polish. Pigment Dispersant jPreservatives Po/pals A Oils. Agricultural Chem,, Oil Add, ^ Unsaturated Polyester Resins -----------------------^[.Sce Xylene Chain (Pngell7"| 0 Cyclohexane * Alkyd Resins ^ Cyclohexanone --------------------------------- J Caprnhclam j|.Src Xylene Chain tPagel l)~| ^S7ropy^ne^^In|jPa^T^J 1| * Nylon 6 pom^/rap^AutoPartOliiherCoatingsJ Disinfectant. Resins. Plywood Adhesives^ ------------------------------ ? Phenol ,,nJS> ---- ) `""7 Acetone --------- 5 flame Retardent. Engineering nasties, Epoxy Resins Polycarbonates (Auto Part* A Transparent Plastic) Methyl Isobutyl ^Nitrocellulose & Vinyl Solvents. Inks, Adhesives, Magnetic Tape 0Ketone Hydrogen Cyanide ft Methanol -*f>ce Methane Chain (Page M)| G Methyl Methacrylate 0 Polymclhyl Methacrylate Aircraft & Police Car Windows. Storm Doors Medical A Dental Parts. Dottles ^jpharmaceutk'als^Adhesivcs. Paint Thinne r/Cleancr, Solvent | u Although benzene and its derivatives are "toxic", downstream - end-use -- products are typically not toxic. 8 VRD 8882824988 Ethylene Chain Pol yrlhylene Alpha Olefins Packaging Film, Milk Bodies. Fuel Tanks. Insulation, Toys, Housewares, Oil Cans. Plastic Bags Synthetic Lubes, Detergent. Wax Substitute, Oil Field. 9 Chem. Mold Release. Plasticizer. Leather <s> Ethylene Oxide y Elhanolaminej > 9 Ethylene Glycol Cosmetics, Detergent. Algicide, Corrosion Inhibiter Non ionic Surfactant. Fumigant. Pbarm., Sterilizing Agent, l.atex Paints rnAntifreeze, Polyester, Brake A llydrolic Fluid, Solvent e '.thylcnc $Acetaldehyde Ethyl Alcohol Ethyl Alcohol rfluty! Alcohol --|sce Piopylene Chain (Page jOj f 6U--J Acetic Acetic Acid Anhydride m Carboxyl Chlotoacetic Acid Methyl Cellulose Acetate Bstcn Cosmetics, Toiletries, Medical. Gnsnhot. Mouthwash Aspirin. Fragrance, Pharmaceutical Solvents, Taints Plastics Pharmaceuticals Drilling Mud, Detergents f-------------- >| Vinyl Vinyl Acetate Polyvinyl Acetate Polyvinyl Alcohol Textile A Paper Size. Adhesive Safely Glass. Architectural Glass Acetic Acitl\^Q Ethylbenzene ------------JseHlenzenc Chain ^Pag^^ (?) ! Polyvinyl Chloride Packaging, Wood Glue, Paints, Textile Finishing Paints, Food Wrap, House Siding Garbage Bags. Bodies. Records. Roofing Pipes A Appliance Parts Several Key derivatives processed from ethylene are also characterized as "toxic" by the proposed legislation. VRD 0002024909 <S> FROPYLBNE Propylene Chain $1isopropyl \||rubwno alcohol,niARMArnuTH'Ais.Coatingsoi.v^t.itrsonai.cari;products.alrosals" | ALCOHOI I1 1 .. ..... ............. --- ................ ..... I PO.YTFOPYLENB ICARPBTINO, BRUSHES. ROPE. TATE. TOYS. RI M. PI ASTIC BOTTLES. APPLIANCE PARTS. BOXES HYDROOEN A CARBON MONOXIDE 2 ETHYL1IEXANOL PROTECTIVE CCATINOS IN IATEX PAIN IS PI ASTIC ITER S, ADI1151VES BUTYRALMHrYYDDBB f- o j ACRYLONITJUL > BUTYL Vj 1 AI.COIIOL I ADIPONURli E A NITRILE RUBBER BUTYL ACETATE EXT. SU.VENT FOR DRUGS. OILS PERFUME, rt ASTICS.PAPI-R EEF. BUTADIENE CHAIN (PAtiE I J# ACRYLIC FIBERS STYRENE ACRYLONITRILE AITAREI., CARPET. DRAPES.IIOME FURNISHINUS. PAINT ROLLERS MEDICAL DISPOSABLES, HOUSEWARES, ArVLIANCE 4 AUTOIARTS ACRYLONITRILE BUTADIENE STYRENE i PIPE A F1TTINOS.1EI JifllONES. TOYS. I.IKIOAOE, FURNITURE _J || PROPYLENE OI.YTOL SUNTAN IXmoN.PHARMACF.mKAlS. rosMpms. lubricant. presm vattve PROPYLENlV^fl I V r rn------- rr OXIDE J |____ JPOOO FFUUMMfrOOANIT. DETERGENTS. POLYURETHANE FOAM. DETERGENTS, SURFAO'ANT ACRYLIC* ACm A AC.RYIATIiS PAINTS. (XJATINOS. FLOOR POLISHES. TEXTILES.PAPER, CEMENI DISIOSABLK DIAPERS Similarly, several of the key derivatives of propylene are characterized as "toxic". 10 'WD 000 2 024910 Xylene Chain XYLENE I1 VRD 0002 0 2 4 9 1 I Toluene Chain ----------- > SOLVENT. HIGH OCTANE GASOLINE COMPONENT. EXPLOSIVES TOLUENE DIAMINE 12 FOAM FOR REDDING, - CUSHIONS. CAR SEATS. INSULATORS. REFRIGERATORS, COSTINGS A VARNISHES s CD co *< 3 IT CD o' c ac*r CD w oo 3 cn 3o CaD. o 3 cO' 5T Q. U1 CD' 3 CD 0) o x <V O ZT CD 3 o' 03_ D CD 3 O o' A C3 e=j ess S3 f-O S3 NJ -f=- VRD 0002024913 Methane Chain U ' 'owever, Its two major derivatives - methyl alcohol and carbon tetrachloride - are considered "toxic" in proposed lev-elation. VRD 0002024914 u Butylene Is the second of the eight basic organic building blocks that is not considered "toxic". i However, it is produced as a coproduct from refinery gas, along with many "toxic" chemicals. ^o 2. J o 13 P-- =CPT CP 3 03 OC ?B ~ 5* o (TO o"S> *o c. c CP ST e Vi CP Cl cr '-C S* CP O o 3 V) c 3 CP 9 g_p sr o S cb < CP 3" D CB 3 C-Pn n . Vi 3 Op 3 mm cp 3 FT 5c 3 3-- 5f 3 <* CL "O n o Cl CP 23 o 3 n !--I CB OP 'C 3 Q_ CL CB * B o e cb sc/a CB O -n 93 O x i?|o s3- 3^0 g ere c o " |S.E! - Vi ^ 7T B" sr o_ 99 CD :;33o 3B3" CP 99 3 O -a e P C/9 =cr Vi 2g_* e =r 2 o 2. * s era ^ 3. c "3 99 23 ca* 2 ~ o 2CB o2. 99 C w o "3 o on 3 CoBs 05 3 5" era a* 2 cn ~ -y Si g cb 3. 3* 2 & 3 3p p era 2, * 3 s =3 o cb 3 82L S. 09 cb 2 --. --i --` 5 5* 3 & CB o 3 -9 i liD 3^^ 9 3 N, !- ft gafa c3 3- IST o o ST CB oa c 2. p cb ' 3& ig. o sr 2 2era 2 9. 3 3 cb 2 cb E,0* 3. ^ 21 3* s on pr Vi cr CB 00 a. p 09 s 23* Xo i =a o 00 s "1 2 *o--i 3=* cb 0 T3 c rt 3 09 CB 3^ CL 3 03 . CL 1 w. CB *T3 O CL Q C0-3-P 03 03* --BJ * C 3* o o< 00 3 o' 3 o P4 3* O o 1 3 a. CP T? D o oc. sHr a cp ~3 03 09 o 2 o osr cb 3 o E3L n o 3 cb 3 5* < s w *<* C<P CP <3 3 p 3 C^3 Po CP- a. nsr CP 3 m* o & 03 CP C0P9 03 CP 3 P* 3 O CL CP 3 3 P 3 3 ST a 00 Uses of " Toxic" Chemicals Ai *5 C= c& *es=> ro <55 rsS <o VRD 0002624916 VIToxic" Chemicals in Paper Recycling Sail Water -- Q Chlorine Elcclriciiy Caustic Soda (NaOH) Paper Bleaching Paper For Recycling 'ZJlTZ -J Dc-inking 1 T" ^^Ethylene | 0 Ethylene Oxide Methane I Ethylene Glycol G Methanol Ethylene diamine V <aFormaldehyde Sodium Cyanide ZJ Elhylcncdiammclciraacelic Acid ~ZZ ]Remove Heavy Metals I T----------- i -J'- Paper Bleaching I i ~~T~~ Hydrogen Peroxide 1 ^ Hydroquinone 1 Oxygen 0_ 1Quinuiic ------- 7F----- 0> Aniline T Nitrobenzene , 7 0 Bcn/enc RD 8 0 0 2 0 2 4 317 S' "Toxic" Chemicals In Steel Production s 18 VRD 0002024-91S "Toxic" Chemicals In Electronics 1 VRD 8862024919 VV Toxic" Chemicals In Aerospace QAntimony Chloride Coke <Chlorine * Silicon Tetrachloride Silicon Semiconductors Computer Chips 20 VRD 0062624920 " Toxic" Chemicals In Recreation Butadiene '' Polyhuladiene %f Styrene 11 Butadienc^^^ i______ Slyrcnc-Butadicne Lalcx 2' VRD 2002024 9 2 1 "Toxic" Chemicals In Pharmaceuticals ajYRD 000207 4 9 2 2 "Toxic" Chemical Use In Textile Production 0 Benzene o Cyclohexane Caprolactam __* _ Nylon '. Synthetic Fibers [^=0 VRD 0002024923 "Toxic" Chemicals In Construction I Polytetrafluoroethylene t Tetrafluoroethylene --------------- *--------------- J^VCPi^J ] Polyurethane i Toluene Dilsoeyanate i Toluene Diamine <s>Dinitmtolucne QToluene f'RD 00020 2 4 9 2 4 " Toxic" Chemicals In Furniture O Benzene oiCyclohexane Caprolactam Nylon Upholstery ZTZ Aniline Nitrobenzene ----------*------- Benzene Protective Coalings IM,Tt Polyurethane --------- *--------- O Toluene Diisocyanate ------------ *------------ Toluene Diamine ------------ *----------- Dinitrololucnc > <S>l Toluene VRD 00 0 2 0 2 4 9 2 5 "Toxic" Chemicals In Printing <32 Methanol Methyl Methacrylate Paper Coating 2 Chlorine > Pulp Calcium Hypochlorite 1 ~T~ I White Paper i n-Bulylcne | ' /^^\Melhyl Ethyl Ketone 1r Nitrocellulose Pri lling 1 ik Carbon Black 26 y& 060 2 0 2 4 926 "Toxic" Chemicals In Food Processing ]Glucose Hydrogen =F= Sorbitol zx_: Nickel Catalyst --------- 1 Q^Elhyl<^T| (^Sulfuric Acid] | Fat || _________ ' '_________ Ethylene 0 Oxide '' Stearic Acid ^ Benzene I Vitamin C Polyoxyethylene sorbitan monostearate Prevents Separation Preservative Ethylenediaminetetraacetic acid -------------------- ----------------------- J Formaldehyde P ^ Methanol Methane Ethylene diamine 4. Ethylene Glycol^^ t Ethylene Oxide(Sj ------- ------ ;;--------- Ethylen 27 Peeling Fruits & Vegetables Machinery Disinfectants Sodium Hydroxide J Electricity Salt Water  VRD 000 2 0 2 4-9 2 7 No Cars Without Chemicals: Auto Industry Examples of Eliminating Toxic Chemicals From the Production Chain Coatings and Preservatives Plastics: Interior, Exterior, Under the Hood Dtrnipujene ToJufinetHamlne ToluenafiAcyanate Polyurethane Fon^yde P Acetal Resins Polyefriytene Polypropylene Dash EoaqL Bod^Panels. pietdPUTTrpcap Fuel ft Methane:;: Mett^C^ohol MethtfUfcflary - ^ &- ' < dim (h ft***;-- V\ Antl>razBJba*ff and Truaftlsmtlyld Ethy^grjfycof EI4I0MI. Polyurethane Methylert{jn}ocyanate Fluids i.' __y ^npea.Hoee^ CApaUJobettfery, Nylon Styrene Butadiene Rubber ne Ct^SHstectam Ci Plastics: Interior Foem 0 - Legislation Prop< Synthetic Rubber Mandated Elimlnation/Redudion Fibers VKD 000 2 0 2 4928 < No Cars Without Chemicals: Examples of Chemical-Based Components FLUIDS u Gasoline (Including additives) U Brake Fluid U Automatic Transmission Fluid Motor Oil a Grease (wheel bearings, etc.) a Radiator Coolant RUBBER Tires Fuel Hose^g** 1 . Door Seali^tr- ># ./ Windshield Wlpdra Grommet&Txishibgs, gaskets, and washdrs fibers;: f Cbt|M ^ ^ Upholstery Tires U Seat Belts Convertible Tops PLASTICS - Interior Q Upholstery (foam padding) Trim (door liners, etc.) Dashboard Instrument Panel Console U Steering Wheel Cover Heating and Air-Conditioning Outlets U Steering Column Shroud Turn Signal Lever U Sun Visors Seal Frames u Head-Rest Frames Plastics - Exterior U Fuel Tank U Bumpers - Front and Rear u Headlight Shells and Lenses U Mirror Housings U Radiator Grille Tail Light Lenses U Hub Caps U Door Handles Body Side Moldings PiDc - Under the Hood Air Filter Housing p Heater Housing d Air-Conditioner Housing Fuse Box Fans **'*' Distributor Cap * Battery Case 5 i. a Heatif^Alr-Cbnd|rionlng Ductal b Fan Shroud rtocker Anri CbverS v Radiator Oversow Tank Electrical Wiring Insulation Sound Insulation Cl Air Inlet Manifold Paint Anti-Corrosive Coalings Ll Body Panel Finish Color Matched Finish on Plastic Components (dashboard, etc.) Adhesives Bonding of Various Components U Brake Linings 29 yRD 882 28 2 4 9 2 9 Other Laws Regulating Chemicals Controlling And Reporting "Use" Is Not An Effective Means Of Achieving Environmental Gains Other Laws Regulating Chemicals Focus On Risk, Exposure and Pollution Abatement and Control: Pollution Prevention Act of 1990 Comprehensive Environmental Response, Compensation, And Liability Act (Superfund) Emergency Planning and Community Right-To-Know Act Toxic Substances Control Act Clean Air Act Safe Drinking Water Act Clean Water Act Consumer Product Safety Act Federal Hazardous Substances Act Resource Conservation And Recovery Act Federal Insecticide, Fungicide, And Rodenticide Act Occupational Safely and Health Act Hazardous Materials Transportation Act Marine Protection and Sanctuaries Act Federal Food, Drug, and Cosmetic Act Poison Prevention Packaging Act Flammable Fabrics Act Surface Mining Control and Reclamation Act Federal Mine Safety and Health Act 30 ^RD 0002024930 Key Conclusions Because effective substitutes cannot be found for many "toxic" chemicals that occur early in chemical production chains, a mandated reduction in "toxic" chemical production and use would force a reduction in total U.S. chemicals and manufacturing output, lowering U.S. living standards. Moreover, mandating a reduction in the production and use of a large number of chemicals characterized as "toxic" would not be an effective means of risk reduction because there is no meaningful correlation between the production and use of these "toxic" chemicals in producing goods -- most of which are themselves non-toxic -- and whatever risks the use of these chemicals may pose to individuals and the environment. a Toxic use reporting -- generating data on the quantities of over 1,000 "toxic" chemicals used in many thousands of production processes in 225,000 facilities -- would generate over 90 million data points annually. These data would serve no useful purpose but would be gathered at a high cost both in terms of dollars and the diversion of resources from other uses more effective in reducing risks to individuals and the environment. a The dollar costs of toxic use reporting -- like other costs of regulation - are not borne by "businesses" but are ultimately passed on to individuals, to everyone in the economy. The costs of regulation are the equivalent of a tax -- a regressive tax -- on all members of the economy. Just as with other forms of regulation and spending, everyone has a stake in the amount and efficiency of environmental regulations and spending. ji IE 6 tm 0 0 0 G*M A > "O "U cd 3 Q. X VRD 0002 0 2 4 m Chemicals Subject To Toxic Use Reduction Legislation The following tables show the specific chemicals subject to toxic use reduction under each of several legislative proposals. The Community Right-To-Know More bills (H.R. 2880, S. 2123) would subject over 1,077 chemicals to toxic use reduction, including many products not generally considered environmental problems, such as alcoholic beverages, tobacco and human adrenalin (epinephrine). Note that some of the items listed, such as antimony compounds or polychlorinated biphenyls (PCB's) are chemical categories . The totals provided at the end of the listing count each of these categories - which may include ten or more individual chemicals -- as only one chemical. Itemizing chemicals covered in these compound categories would considerably expand the list and number of chemicals covered by the legislation. Also, S. 976, with the Senator Lautenberg and Durenberger amendments, would mandate that EPA add 250 unspecified chemicals to the list, even though EPA currently has the discretionary authority to add chemicals to the toxic release inventory, an action which would also result in their inclusion in the chemicals covered by most TUR proposals. RD 0002024933 How Chemicals Subject To Toxic Use Reduction Legislation Were Selected CJ Current toxic use reduction legislation selects the chemicals to be regulated primarily by relying on references to various lists ol chemicals incorporated in earlier legislation, regulations, or studies. In many cases, this "tist-of-lists" approach to defining "toxic" chemicals is an inappropriate means ol selecting Hems for reporting and control. H R. 2880 and S. 2123 would mandate the reduction in use of chemicals and other substances which appear in: (1) the toxic release inventory (section 313 of the Emergency Planning and Community Right -To -Know Act), (2) priority pollutants listed under regulations relating to steam electric power point source pollutants under the Federal Water Pollution Control Act, (3) wastes under the Solid Waste Disposal Act, (4) Hazardous Air Pollutants and Class I and II Ozone-Depleling substances under the Clean Air Act, (5) Any pesticide that has been denied registration, that is undergoing Special or administrative review, or that is classified a restricted use pesticide, (6) regulations under the Safe Drinking Water Act, (7) chemicals Identified as known or probable carcinogens by the Carcinogen Assessment Group (EPA). International Agency lor Research on Cancer, or the National Toxicology Program, (8) Extremely Hazardous Substances listed under the Emergency Planning and Communrty Righl-To-Know Act of 1986, (9) reproductive toxins listed under California's Proposition 65 The Community Right-To-Know More amendment to H.R. 3865, offered by Mr. Sikorski and Mr. Rinaldo. would apply toxic use reduction to: (1) the toxic release inventory (section 313 of the Emergency Planning and Community Right -To -Know Act), (2) wastes under the Solid Waste Disposal Act, (3) at teast 200 additional chemicals which EPA must select and add. S. 976, with amendments from Senators Lautenberg and Durenberger, would apply toxic use reduction to: (1) the toxic release inventory (section 313 of the Emergency Planning and Community Right -To -Know Act), (2) Class I and II Ozone-Depleting substances under the Clean Air Act, (3) 250 chemicals which EPA must propose by July 1,1994 or the list under S. 2t23 will be added. S. 761 would apply toxic use reduction to chemicals in the toxic release inventory (section 313 of the Emergency Planning and Community Right-To-Know Act). U S. 1081 would apply toxic use reduction to nine chemicals. In addition, H would mandate that EPA "prohibit the discharge of highly toxic or highly bioaccumulative pollutants". A highly toxic pollutant is defined as any pollutant with a level of ''toxicity equivalent to or greater" than that of the original nine pollutants. V, *VRD 0002024934 Chemicals Subject To Toxic Use Reduction Legislation CAS# Chemical Name 250 Addltlonal C hemlcals to be named 200 Additional Chemicals 1o be named HR. 2880 Legislation H.R S. *s. 3865 2123 9?6 Yes Yes S. 761 S. 1081 83-32-9 208-96 8 7507 0 75 87-6 60 35 5 546-88 3 67-64 1 75-86 5 1752-30-3 75-05-8 98-86 2 75-36 5 591-08 2 53-96-3 107-02-8 79-06-1 79-10 7 107-13-1 014-68-6 111 69 3 23214 92 8 15972 60 8 116-06-3 1646 88 4 164687-3 309-00-2 107 10 6 107-05-1 107-11-9 28981 97-7 7429 90-5 1344 28 1 20859-73-8 39831-55-5 82 28 0 117-79-3 60-09-3 97-56-3 1 92-67-1 Acenaphlhene Acenaphthylene Acetaldehyde Acetaldehyde, txfchfero Acetamide Acetohydroxamic acid Acetone Acetone cyanohydrin Acetone Thiosemicarbazfde Acetonitrile Acetophenone Acetyl chloride (C.R.T) t- Acety!-2-thiorea 2- AcetylaminoHuorene Acrolein Acrylamide Acrylic acid Acrylonitrile Acrylyl chloride Adiponltrile Adriamycin Aflatoxtns Alacbor Aldicarb AMicerb suilone Aldicarb sulloxida Aldrfn ADyl alcohol Aflyl chloride AHylamine Alprazolam Aluminum (fume or dual) Aluminum oxide (fibrous forms) Aluminum phosphide Amikacin Sullate 1- Amino-2-methylanthraquinone 2- Aminoanlhraquinone . 4- Aminoazobenzene o- Aminoarotoulene 4- Aminoblphenyl Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes CAS# 125-84 8 2763 96-4 54 62 6 78-53 5 3734-97-2 33089 61-1 61-82 5 7664-41-7 6484 52 2 131-74 8 7783-20-2 7603-55-6 300-62-9 62-53 3 88 05-1 90 04 0 104-94 9 134 29-2 120-12-7 7440-36-0 7783-70-2 1397-94-0 86 88-4 140-57-8 7440-38-2 7778-39-4 130328-2 1327 53-3 1327-53-3 7784 42-1 1332 21 4 50-78 2 1912-24 9 115 02-6 446-86-6 2642-71-9 7440-39-3 542-62-1 17804-35-2 3 Chemical Name H.R. 2B6Q Aminogfulethimide Yes 5- Aminomethyl)-3-isoxazolol Yes Aminopterin Amiton Amiton oxalate Amrtraz Amitrole Ammonia Ammonium nitrate (solution) Ammonium plcrate Ammonium sullate (solution) Ammonium vanadate Amphetamine Anabolic steroids Aniline Aniline. 2.4.6-trimethyl0- Anisidine P- Anisidine 0- Anisidine hydrochloride Anthracene Antimony Antimony compounds Antimony pentafluoride Antimycin A Anlu (Thiourea. 1-napbthalenyl Aramite Arsenic Arsenic acid Arsenic compounds Arsenic pentoxide Arsenic trioxide Arsenous oxide Arsine Asbestos (triable) Aspirin Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Atfazirm Azaserine Azathioprine Azinphos-ethyl Barium Barium compounds Barium cyanide Benomyl Yes Yes Yes Yes Yes Yes Yes Yes Le gfslaHon H.R. s. **s. S. s. 3663 2123 -76_ 761 , 1P81 Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes . Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes *RD 0002024-935 Chemicals Subject To Toxic Use Reduction Legislation CAS# 225-51-4 56 97-6 98-87-3 5521 0 23950 58 5 98 16 8 71-43-2 9687-3 100-14-1 98 05-5 122 09-8 98-09-9 92 87-5 3615 21 2 205 99 2 50 32-8 205-99-2 205 82-3 207 08-9 98 07-7 191-24-2 98 88 4 94 36 0 5411 22-3 10044-7 140 29-4 7440-41-7 319 84 6 319 85-7 319 86 8 15271 41-7 92 52 4 534-07-6 154 93 8 4044-65-9 10294-34-5 7637 07-2 353 42-4 28772-56-7 7726 95-6 598 31-2 Chemical Name HR. 2880 Benz(c)aeridine Yes Benz[a]anthracene Yes Benzal chloride Yes Benzamide Yes Benzamide, 3,5.-dichloro-N(1.1-din Yes Benzenamine, 3-(trifluoromethyl}- Yes Benzene Yes Benzene, (dichloromethyl)- Yes benzene, 1-(chloromethyf)-4-nitro- Yes Benzenearsonic acid Yes Benzeneethanamlne, alpha.alpha-d Yes Benzenesullonic acid chloride (C.R) Yes Benzidine Yes Benzimidazole, 4,5-dichloro-2-(lriflu Yes benzo (b) fluoranthene (3,4-Benzol Yes Benzoja] pyrene Yes Benzo|b)riiioranthene Yes Benzo(i)lluoran1hene Yes Benzo[k]fluoranthene Yes Benzoic trichloride (Benzotrichloride Yes 1.12- benzoperylene (benzo9ghi) perylen Yes Benzoyl chloride Yes Benzoyl peroxide Yes Benzphetamine hydrochloride Yes Benzyl chloride Yes Benzyl cyanide Yes Beryllium Yes Beryllium Compounds Yes alpha- BHC Yes Bela- BHC Yes Della- BHC (PCB-polychlorinated biphenyl Yes Bieyck>[2.2.1]heptane-2-carbonitrile Yes Biphenyl Yes Bis(chloromethyl) ketone Yes BiscNoroethyl nitrosourea (BCNU) Yes Bitoscanale Yes Bool and Shoe Manufacture and Re Yes Boron trichloride Yes Boron trifluoride Yes Boron trifluoride compound with me Yes Bromadiokme Yes i Bromine Yes Bromoacetone Yes Leglsla lion HR. S. " s. 3865 2123 976 Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes S. 761 Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes S. 1081 Yes CAS# 124-48-1 74 25 2 75-25-2 74-83-9 101-55-3 1689 84 5 357-57-3 106-99 0 55-98-1 141-32-2 71-36-3 78-92-2 75-65-0 85-68-7 25013-16-5 106-88-7 123-72-8 2602-46-2 4680-78-8 569-64-2 989-38-8 2832-40 8 3761-53-3 569-61-9 16071-86-6 1937-37-7 81-68 9 3118-97-6 842 07-9 97-56-3 492-80 B 128-66-5 75-60-5 7440 43-9 1306-19-0 2223-93 0 13765-19 0 156-62-7 592-01-8 56-25-7 105-60 2 2425-06-1 Chemical Name HR. 2880 Bromodichloromethane Yes Bromoform Yes Bromoform (thbromomethane) Yes Bromomethane (methyl bromid Yes 4 Bromophenyl phenyl ether Yes Bromoxynil Yes Brucine Yes 1.3- Butadiene Yes 1.4 Bulanediol cfimelhanesutphona Yes Butyl acryble Yes n- Butyl alcohol Yes sec- Butyl alcohol Yes tert- Butyl alcohol Yes Butyl benzyl phthslale Yes Butyfated Hydroxyanisole Yes 1.2 Butylene oxide Yes Butyrafdehyde Yes C. i .Direct Blue 6' Yes C. 1. Acid Green 3* Yes C. 1. Bask Green4* Yes C. 1. Bask Red I* Yes C. I. Oisperse Yellow 3* Yes C. 1. Food Red 5' Yes C l. Basic Red 9 Monohydrochl Yes C.l. Direct Brown 95* Yes C.l. Direct Black38* Yes C l. Food Red 15* Yes C.l. Solvent Orange 7* Yes C.l. Solvent Yellow 14* Yes C.l. Solvent Yellow 3* Yes C.l. Solvent Yellow 34' (Aurami Yes C.l. Val Yellow 4* Yes Cacodylic acid (Arsinic acid, de Yes Cadmium Yes Cadmium compounds Yes Cadmium oxide Yes Cadmium stearate Yes Calcium chromate Yes Calcium cyanamide Yes Calcium cyanide Yes Cantharkftn Yes Caprolactam Yes Captafof Yes Le glsla lion *H.R. s. M s. 3865 .2123 976 Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes S. _Z1 Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes V4 VRD 0002 0 24-936 Chemicals Subject To Toxic Use Reduction Legislation CAS# 133-06-2 26419 73 0 63 25-2 1563 66 2 75-150 630 08 0 56-23 5 353-504 463-58-1 706-19 6 41575-94-4 120-809 21725 46 2 474-25-9 50-25-3 438 41-5 133 90 4 305-03-3 116-75-2 57-74-9 6164 98 3 115-2B-6 470-90 6 108171-26-2 7782-50-5 10049 04-4 24934 91 6 999 81 5 494 03 1 100-60-1 563 47-3 59 50-7 95-83-0 3165 93 3 107-200 79-11-8 532-27-4 Le gists (Ion Chemical Name H.R. H.R. s. s. Capten 2990 -3B65J 2129 979 Yes Yes Yes Yes Carbamic add, methyl*, o-(((2,4-din Yes Yes Carbaryl Yes Yes Yes Yes Carbofuran Yes Yes Carbon disulfide Yes Yes Yes Yes Carbon Monoxide Yes Yes Carbon tetrachloride Yes Yes Yes Yes Carbonic dilluorida Yes Yes Yes Carbonyl sulfide Yes Yes Yes Yes Carbophenothkm Yes Yes Carboplatin Yes Yes Catechol Yes Yes Yes Yes Cayanazine Yes Yes Chenodiol Yes Yes Chlodiazepoxide Yes Yes Chlodiazepoxkfo hydrochloride Yes Yes ChloiAmben Yes Yes Yes Yes Chlorambucil Yes Yes Yes Chkjranil Yes Yes CHordane Chlordimelorm Yes Yes Yes Yes Yes Yes Chlorendic add Chlorlenvinlos Chlorinated benzenes N.O.S. Yes Yes Yes Yes Yes Yes Yes Chlorinated ethane N.O.S. Chlorinated fluorocarbons N.O.S. Yes Yes Yes Yes Yes Yes Chlorinated naphthalene, N.O.S. Yes Yes Yes Chlorinated Paraffins (C12. 60% Ch Yes Yes Chlorinated Phenol, N.O.S. Chlorine Chlorine dioxide Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Chlormephos Yes Yes Chlormequat Yes Yes Chlornaphazin Yes Yes Yes Bis(2- chloro-1 -methylelhyl) ether 3- Chloro-2-melhylpropene Yes Yes Yes Yes Yes Yes 4- chloro-3-melhyl phenol Yes Yes P* Chloro-m-cresol 4- Chloro-o-phenylerwdiamine Yes Yes Yes Yes Yes 4- Chloro-o-toluidine, hydrochloride Chloroacetaldehyde CWoroaeetic acid 2- Chloroacetoohenone Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes S. 791 Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes CAS# 106-47-9 108 90-7 510-15 6 1620-21-9 124-48-1 75-00-3 107 07-3 111-91-1 627-11-2 110-75-8 111-44-4 13909-09-6 13010-47-4 354-56-3 76 12-0 75 72-9 422 81-1 3182 26 1 1652-74-0 $77-68-9 76-17-5 661-97-2 76 18 6 67-66-3 39638-32 9 74-07-3 107-30 2 542-88-1 91-587 3691-35-8 95-57-0 7005-72 3 126-99-8 542-76 7 1897-45 6 1982-47-4 21923 23 9 10025-73-7 7440-47-3 218-01-9 Chemical Name Chloroalkyl esters N.O.S. P- Chloroaniline Chlorobenzene Chlorobenzilate Chlorocyclizine hydrochloride Chlorodibromomethane Chloroethane Chloroelhanol Bis(2- chloroethoxy) meihane Chloroethyl Chioroformate 2- Chtofoetbyl vinyl ether 8is{2- chloroethyl) ether 1-(2- CWoioe1hyl)-3-|4-niethy1cydoh 1(2- Chloroethyl)-3-cyclohexyM -nitr1 Chlorofluorocarbon-111 (CFCChlorofluorocarbon-112 (CFCChlorofluorocarbon-13 (CFC-t Chlorofluorocarbon-211 (CFC-I Chlorofluorocarbon-212 (CFC-I Chlorofluorocarbon-213 (CFC-I CMoroftuorocarbon-214 (CFC-I CNorofluorocarbon-215 (CFC-I Chlorofluorocarbon-216 (CFC-I Chlorofluorocarbon-217 (CFC-I Chloroform Bis(2(- chloroisopropyl) ether Chlotome thane Chloromethyl methyl ether Bis chloromethyl) ether 2- Chloronaphthatene Chiorophacinone 2- Chlorophenol Chlorophenols 4 chlorophenyl phenyl ether Chloroprene 3- Chloropropionitrile Chlorolhalonil Chloroxuron Chlorthiophos Chromic chloride Chromium Chromium compounds Chrysene H.R. 2880 Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Le glsla Non H.R s. "S. 3965 2123 979 Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes S. 761 Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes /  VR0 0002 0 2 4-937 Chemicals Subject To Toxic Use Reduction Legislation CAS # 15663 27-1 6358 53 B 50-41 9 6007-45-2 7440-464 10210-68-1 $2207-76 5 50 36 2 64-66-6 7440 50-6 544-92-3 5836 29 3 8001-56-9 120-71-8 108 39 4 95 49-7 106 44 5 1319-77-3 535-89-7 123 73-9 4170-30-3 98 82 8 80 15 9 135 20 6 2172546-2 57-12-5 460 19-5 506 68-3 506 77-4 506-78-5 263626 2 675 14-9 14901 08 7 110 82-7 Chemical Name Cisplfltin Citrus Red No. 2 Clomiphene citrate Coal gasification Coal Tar creosote Coal-tar pitches Coal-tars Cobalt Coball carbonyl Coball compounds Cobalt, ((2,2'-( 1,2-ethanediy1bis(nitri Cocaine Coke Oven emissions Coke production Colchicine Conjugated Estrogens Copper Copper compounds Copper cyanide Coumatetrayl Creosote P- Cresidine m- Cresol o- Cresol P- Cresol Cresol (mixed isomers) Crftnidine CronaWehyde, (E)Crotonaldehyde Cumene Cumene hydroperoxide Cuplerron Cyanazine Cyanide compounds cyanides (soluabfe salts and complr cyanogen Cyanogen bromide (CN) Br Cyanogen Chloride Cyanogen iodine Cyanophos Cyamiric fluoride 4 Cycasin Cyclohexane H.R 2860 Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yea Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Le>gislition *H.R. s. * s. 3865 2123 976 Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes S. 761 Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes S. 1081 CAS# 108-94-1 66 61-9 131-89-5 108-91-8 50-18-0 6055-19-2 13121-70 5 147-94-4 94-75-7 4342-03-4 17230-88-5 20830-81-3 23541-50-6 64-73-3 72-54-8 3547-04-4 72-55-9 50-29-3 17702-41-9 1163-19-5 8065 48-3 919-66-8 117-81-7 10311-04 9 2303-16-4 615-05-4 39156 41-7 101 80 4 95-80-7 25376-45-8 439-14-5 333-41 5 334-88 3 53-70-3 226-36 8 189-55-9 224-42-0 192-65-4 189-64-0 189-55-9 191-300 Chemical Name HR. Cyclohexanone (1) 2080 Yes Cycloheximide Yes 2 Cyclohexyl-4,6-0inifrophenol Yes Cyclohexylamine Yes Cyclophosphamide (anhydrous Yes Cyclophosphamide (hydrated) Yes Oyhexatin Yes Cytarabine 2.4- 0 Yes Yes Dacarbazlne Yes Daminozide Yes Danazol Yes Oaunomycin Yes Daunorubicm hydrochloride Yes Daunorubicin hydrochloride (int Yes DBCP Yes ODD. (Benzene. l.r-(2.2-dichli Yes DDE Yes 4.4- DDE (p.p-DDX) Yes DDT Yes Decaborane(M) Yes Decabromodiphenyl oxide Yes Demeton Yes Demeton-S-methyl Yes Di-(2-elhylhexy1) phlhalate (DE Yes Dialifor Yes Diallale Yes 2.4 Diaminoanisole Yes 2.4 Diaminoanisole sutlate 4,4 Diaminodiphenyl ether Yes Yes 2.4- Diaminotoluene Yes Diaminofoluene (mixed isomer; Yes Diazepam Yes Diazinon Yes Diazome thane Yes Dibenz(a.h) anthracene Yes Dibenz|a.h|acridine Yes Dibenz(a,i)pyrene Yes Diberu|a,j)acridine Yes Dibenzo(a.e]pyrene Yes Dibenzo|a.h]pyrene Yes Dibenzo|a.i)pyrene Yes Dibenzo|a,l]pyrene Yes Legisla lion H.R. s. * s. S. 3865 -2123. MS --Zl Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes RD 0882024^38 Chemicals Subject To Toxic Use Reduction Legislation Le gisls Mon CAS# Chemical Name HR H.R. s. - s. S. S. 2680 ?7ff 761 INI 194 59-2 7H- Dibenzo|e.g|carbazole Yes Yes Yes 132-64-9 Dibenzofuran Yes Yes Yes Yes Yes 19Z87-45-7 Diborane Yes Yes 96-12 S 1.2- Dibromo-3-chlofOpropane Yes Yes Yes Yes Yes 106-93-4 04-74-2 1.2- Dibromoethane (ethylene dibromide Yes Yes Yes Yes Yes Dibutyl phthalata Yes Yes Yes Yes Yes 764-41 0 1.4- Dkhloro-Zbutene (I.T) Yes Yes Yes 95 50-1 541 73 1 106-46-7 25321-22-6 91-94-1 75 27-4 1.2- Dkhlorobenzene 1.3- Dichlorobenzene 1.4- Dkhlorobenzene Dichlorobenzene (mixed isomers) 3.3- DicWorobenzWine DicWorobromomethane Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes 110-57-6 farts-1,4 dkhlorobutene Yes Yes 75-71-8 DkMorodifluoromethane Yes Yes Yes 75-34-3 107-06-2 540-59 0 156 60-5 25323-302 1.1- Dichloroethene Yes Yes Yes 1.2- Dlchloroethene (ethylene dkhlorlde Yes Yes Yes Yes Yes 1,2- Dlehloroethylene Yes Yes Yes Yes Yes 1.2- Dichloroethylene Yes Yes Yes Dichbroethylene N.O.S. Yes Yes Yes 75 09 2 149-74 6 Dichloromethane (methylene chloric Yes Yes Yes Yes Yes Dichloromethylphenylsilane Yes Yes 120 83 2 2.4- Dichlorophenol Yes Yes Yes Yes Yes 07 65 0 696-28-6 2.6- Dlchlorophenol OichlorophenylarsinB Yes Yes Yes Yes Yes Yes 70-07-5 26639 19 7 1.2- Oichioropropane Dichloropropane N.O.S. Yes Yes Yes Yes Yes Yes Yes Yes 26545-73 3 79-00 6 26952-23 8 75-99 0 542-75 6 62-73 7 Dichloropropanol N.O.S. 2.3- Dichloropropene Dkhloropropene NO.S. 2.2- Dkhloropropione Acid (Oatapon) 1.3- Dichloropropylene Dichlorvos Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes 115-32 2 Dicofol Yes Yes Yes Yes Yes 141-66 2 60-51-7 1464-53-5 111-42-2 Dicrotophos Dieldrin Diepoxybutane Diethanolamine Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes 014 49 3 84-66-2 64 67-5 311 45 5 Diethyl chforophosphate Diethyl phthalate l Diethyl sulfate Diethyl-p-nitrophenyl phosphate Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes 692 42 2 Diethvlarsine Yes Yes Yes CAS# 1642-54-2 56-53-1 71-63-6 2238 07-5 101-90-6 20830-75-5 94-58-6 115-26-4 60-51-5 119-90 4 68-122 57-14-7 2524-03-0 131-11 3 77-78 1 99-99-9 124-40 3 60-11 7 121 -69 7 57-97-6 119 93 7 79 44-7 75-78 5 540 73 8 105-67-9 513-37-1 644 64-4 534-52-1 99-65-0 528-29 0 100-25-4 25154-54-5 534-52-1 51-28-5 121-14-2 606-20-2 25321-14 6 39300 45-3 89 85-7 1420-07-1 117-84-0 123-91-1 Chemical Name Diethykarbamazine citrate Diethylstibesterol Digitoxin Diglycidy! ether Diglycidyl Resorcinol Ether Digoxin Diguat Dihydrosahole Dimefox dimethoate 3,3- Dimethoxybenzidine Dimethyl Formamide 1,1- Dimethyl hydrazine Dimethyl phosphorochioridothk Dimethyl phthalate Dimethyl sulfate Dimethyl-p-phenylenediamine Dimelhylamfne (1) 4- Dimethylaminoazobenzene N.N- Dimethyianilirte 7.12- Dimethyfbenz (a| anthracene 3.3- Dimelhylbenzidirte (o-Toiidine) Dimethylcarbamyt chloride Dimethyldichlorosilane 1.2- Dimethylhydrazirte 2.4- Dimethylphenol DimethyMnyl Chloride Dimetilan 4.6 Dinitro-o-cresol, and salts m- Dinitrobenzene - Dinitrobenzene R Dinitrobenzene Dinitrobenzene, N.O.S. Dinitrocresof 2.4- Dinitrophenol 2.4- Dinitrololuene 2.6 Dinitrotoluene Dinitrololuene (mixed isomers) Dinocap Dinoseb Dinoterb n- Dioclyl phthalate 1.4 Dioxane Le gfsfa tlon HR H.R s. "S. 2660 Jim. .mi i Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes S. _I1 Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes VRD 00020H939 Chemicals Subject To Toxic Use Reduction Legislation CAS# 70-34 2 02-66-6 122-39 4 57-41-0 122-66-7 152-t6-9 142-84-7 290-04-4 514 73 8 541-53-7 564-25-0 94080-85-4 24390-14-5 17086 28 1 316*42-7 115 29 7 959-98 8 33213 65 9 1031 07 8 145-73-3 2778-04-3 72-20-8 7421-93 4 106-09-6 51-43-4 2104 64-5 136-25 4 50-14 6 379-79-3 12510 42 0 1622 32 0 16752-77-5 10140 07-1 57 63 6 97 63 2 13194 48 4 110-00 5 141-78-6 140-88 5 Chemical Name H.R. 2880 Dioxalhion Yes Diphacinone Yes Dlpbenylemine Yes Dlphenylhydanloln (phanytoin) Yes 1.2- Diphenylhydrazine Yes DiphosphoramWs, octamethyl Yes Oipropylamine (1) Yes OhsuHolon Yes Olthiazanine iodide Yes Dithiobiuret Yes Doxycycline (internal use) Yes Doxyeyetine calcium (internal use) Yes Doxycycline hyclate (internal use) Yes Doxycycline monohydrete (internal < Yes Emetine, dihydrochloride Yes Endosulfan Yes Alpha- endosulfan Yes Bala- endosulfan Yes Endosulfan sulfate Yes Endothall Yes Endothion Yes Endrin Yes Endrin aldehyde Yes Epichlorohydrin Yes Epinephrine Yes EPN Yes Erbon Yes Ergocalcilerol Yes Ergotamine tartrate Yes Erionite Yes Estrogens (Not Conjugated): Estrat Yes Estrogens (Not Conjugated): Elhyir Yes Estrogens (Not Conjugated): Mestr Yes Estrogens (Not Conjugated): Estron Yes Ethanesul fonyf chloride, 2-chloro Yes Ethanimidothroic acid, n-Imethylami Yes Ethanol, 1,2-dichloro-,ac6tate Ye9 Ethinyl estradiol Yes Ethl methacrylate Yes Ethoprophos Yes 2- Ethoxyethanol (Ethylene glycol mon Yes Ethyl acetate Yes Ethyl acrylate Yes Le>gislclUon hr. s. s. 3865 2m 979 Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes S. 781 Yes Yes Yes Yes S. 1001 Yes CAS# 541-41-3 $0-29-7 62-50-0 100 41-4 538 07 8 74-85-1 371-62-0 107-21-1 75-21-8 96-45-7 111-54-6 151-56-4 103-23-1 75-34-3 542-90-5 33419-42-0 54350-48-0 52-85-7 22224-92-6 122-14 7 115-90 2 4301-50-2 2164-17-2 206-44-0 86-73-7 7782-41-4 $40-19-7 M4-490 35906-8 51-21-8 46-43-7 13311-84-7 944 22-9 50-00-0 107-16-4 23422 53-9 64-18-6 2540-82-1 17702-57-7 21548-32-3 Chemical Name H.R. Ethyl Alcohol in alcoholic bever Ethyl ehloroformale Ethyl ether (1) Ethyl methanesuifonate N- Ethyl-N-nitrosourea Ethylbenzene Ethylbis(2-chloroethyl)smioe Ethylene Ethylene biscarbamates Ethylene fluorohydrin Ethylene glycol Ethylene oxide Ethylene thiourea Ethylenebisdithiocarbamlc acid Ethyleneimme Bis(2- elhylhexyl) adipate Ethylidene dichloride (1,1-Diehl ethylthiocyanale Etoposide Etretinate Famphur Fenamiphos Fenitrothlon Fensidfothion Flue netil Fluometuron Fluoranthene Fluorene Fluorine Fluoroacetamide Flucroacelic Acid Fluoroacetyl chloride Fluorouracil Fluoxymesterone Flutamlde Fonofos Formaldehyde Formaldehyde cyanohydrin Formetanate hydrochloride Formic acid (C.T) Formothion Formparanate Fosthietan 2990 Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Le glsla lion 'HR. s. "S. 3965 2123 979 Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes S. 791 Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes B yRO 00020^249-40 Chemicals Subject To Toxic Use Reduction Legislation CASH 76-13.1 3076-19 1 110-00 9 109 99-9 98 01-1 13450 90 3 18883-664 765-34-4 1071 836 70-25-7 23092 17 3 76-44 8 1024 57-3 87-68-3 118 74-1 77-47-4 67-72 1 1335-87-1 70 30 4 1808-71-7 757-S8-4 4835-11-4 680-31-9 822 06-0 110 54-3 302-01-2 10034 93-2 1615 00-1 7647-01-0 76 12-0 354 21-2 306 83 2 2837-89-0 359 28 4 431 06 1 431-07-2 Chemical Name H.R. 2080 Freon 113 Yes Fuberidazole Yes Fursn (1) Yes Furan,te6rahydfo-(1) (tetrahydrofurar Yes Furfural (1) Yes Furniture and cabinet making Yes Gallium trichloride Yes D Glucose, 2-deoxy-2-|[metfiytnitrosoi Yes GlycWylaldehyde Yes Glycol ethers Yes Glyphosate Yes Guanidine, N-methyl-N' nitro-Nniti Yes Halazepam Yes Halomelhenes N.O.S. Yes Heplachlor Yes Heptachlor epoxide (BHC-hexachloi Yes Hepiachlordibenzo-p-dloxins Yes Heptachlorodibenzofurans Yes Mexachlordibenzo-p-dioxins Yes Hexachloro-1,3-buiadiene Yes Hexachlorobenzene Yes Hexachlorocyclopenladiene Yes Hexachlorodibenzofurans Yes Hexachtoroelhane Yes Hexachloronaphthaiene Yes Hexachlorophene Yes Hexachloropropene Yes Hexaethyl letr.apbospbate Yes Hexamelhylenediamine, N. N'-dibut Yes Hexamethylphosphoramide Yes Hexamrthylene-1,6-diisocyanate Yes Hexane Yes Hydrazine Yes Hydrazine sullale Yes Hydrazine, 1,2-dielhyl- Yes Hydrochloric acid Yes Hydrochlorof!uofocarbon-12f (HCF1 Yes Hydrochlorofluofocarbon-122 (HCF Yes HydrochlorolloofOcarbon-123 (HCF' Yes Hydrochlorofluorocarbon-124 (HCF' Yes Hydrochlorofluorocarbon-131 (HCF1 Yes 1 HydrochloioRuorocarbon-132 (HCF1 Yes Hydrochlorofluorocaibon-133 (HCF1 Yes Lciglslcilion H.n. s. s. 3065 2123 976 Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes S. 761 Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes S. 1061 CAS H 430-57-9 336-64-7 75 43 4 12754-83-4 7664-39-3 7722-84-1 7783-07-5 7783-064 74-90 8 123-31-9 3778-73-2 193 39-5 24267-56-9 9004-66-4 13463-40-6 297-78-9 78-83-1 7B-842 78-82-0 102-36 3 465-73-6 i Chemical Name Hydrochforofluorocarbon-141 { Hydrochlorofluorocarbon-142 { Hydrochtorofluoroearbon-21 (H Hydrochlorofluorocarbon-221 ( Hydrochlorofluorocarbon-222 ( Hydroehlorofluoroearbon-223 ( Hydrochtorofluorocarbon-224 ( Hydrochlorofluorocarbon-225 ( Hydrochlorofluorocerbon-226 ( Hydrochlorofluorocarbon-231 ( Hydrochlorofluofocarbon-232 ( Hydrochkuofluorocarbon-233 ( Hydrochlorolluorocarbon 234 ( Hydrochlorofluorocarbon-235 (' Hydrochlorofluorocarbon-241 ( HydrochloroRuorocarborr-242 ( Hydrochtorofluorocarbon-243 ( Hydrochlorofluorocarbon-244 ( Hydrochlorofluorocarbon-251 ( Wydrochksrofluorocarbon-252 ( Hydrochlorofluorocarbon-253 ( Hydrochlorofluorocarbon-261 (: Hydrochlorolluorocarbon-262 ( Hydrochlorofluorocarbon-271 (I Hydrochlorofluorocarbon-31 (H Hydrogen fluoride Hydrogen peroxide (Conc > 52 Hydrogen selenide Hydrogen sulfide Hydrogren cyanide Hydroquinone ffoslamlde Indeno (1,2.3-cd) pyrene Iodine-131 Iron and steel founding Iron Dextran Complex Iron, pentacarbonylIsobenzan isobutyl alcohol (l,T) Isobutyraldehyde Isobutyronilrife Isocyanic acid, 3,4-dichlorophe Isodrin HR 2880 Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Le gisla lion *H.R. s. ** s 3665 2123 978 Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes S. 781 Yes Yes Yes Yes 5 1001 ID 0 00 2 0 2 4 m Chemicals Subject To Toxic Use Reduction Legislation CAS# 55 91 4 78 59 1 75 59 1 4098 71 9 67 63 0 108 23 6 119 38 0 120-58-1 4759-48-2 143-50-0 78-97-7 303 34-4 7439-92-1 301-04-2 7446-27-7 1335-32-6 11609-90-5 541 25 3 58-89-9 554-13 2 919-16 4 7580 67-8 846-49-1 80-05-7 108-31-6 123-33 1 109-77-3 2427-30-2 7439-96 5 2108-13-3 71-56 9 595-33-5 148 82-3 9002 60-0 950-10-7 57-53-4 1600 27-7 1908-53-2 7439-97-6 Chemical Name Isofluorphato (diisopropytfluoropho Isophorone Isophorone Isophorone diisocyanate Isopropyl alcohol (strong acid proc< Isopropyl chforolormate IsopropylmethylpyrazoJyf dimethylc Isosafrote Isotretinoin Kepone (Cblordeeone) lactonitrile Lasiocarpine Lead Lead acetate Lead compounds Lead phosphate Lead subacetate Leptophos Lewisite Lindane Lithium Carbonate Lithium Citrate Lithium hydride Lorazepam 4,4- isopropylidenediphenol Magenta, manulacture of Maleic anhydride Maleic hydrazide Malononitrile Maneb Manganese Manganese compounds Manganese, tricarbonyl methylcyci Medioxyprogesterone acetate Megestrol Acetate Melphalan Menotropins Mephoslolan Merceptopurine Mercuric ecetale Mercuric oxide Mercury Mercury compounds RR. 2680 Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Le gists tion RR s. s. 3865 2123 976 Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes S. 761 Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes S, 1081 Yes CASH 628-86-* 72-33-: 10476 95 f 760-93-C 126-98-7 920 46-7 30674-80-7 3963-95-9 10265-92-f 558-25-8 67-56-1 91-80-S 950-37-8 60-56-C 16752-77-5 59 05-2 15475 56 72-43-5 109 86-4 151-38-2 298-81-7 96-33-3 79-22-1 78-93-3 1338 23 4 60-34-4 74-88-4 624 83 9 556-61 6 108-10-1 80 62-6 66-27-3 298-00-0 3735-23-7 676-97-1 1634 04 4 556-64-9 78-94-4 5649-5 3697-24-3 74-95-3 Chemical Name Mercury fulminate Mestranol Methacrotein diacetate Methacrylic anhydride Methacrylonitrite (l,T) Melhacryioyl chloride Methacryfoyloxyethyl isocyana Methacycline hydrchloride Methamidophos Methanesuffonyj fluoride Methanol Methapyrifene Methidathion Methimazole Methomyl Methotrexate Methotrexate sodium Methoxychlor 2- Methoxyethanol (Ethylene glyc Methoxyethylmercuric acetate 8- Methoxypsoralen Methyl acrylate Methyl chlorolormate Methyl ethyl Ketone Methyl ethyl ketone peroxide Methyl hydrazine Methyl iodine Methyl Isocyanate Methyl isothiocyanate Methyl Isobutyl ketone Methyl Mercury Methyl methacrylate Methyl Methanesulfonate Methyl parathion Methyl phenkaplon Methyl phosphonic dichloride Methyl terl-butyl ether Methyl thiocyanate Methyl vinyl ketone N Methyl-N-nitrosourea 3- Methylcholanthrene 5- Methylchrysene Methylene bromide RR. 288C Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Le gisla (Ion RR. 3865 Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yea Yes Yes Yes Yes Yes s. 212: Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes s. Vft Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes s. S. 761 1081 . I Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes i VKD 00020 2 4 9 4 2 Chemicals Subject To Toxic Use Reduction Legislation CAS# 101-14 4 101-68-8 101-61-1 101-77-9 59 IB 4 56 04-2 75-79 6 1129-33-0 443-49 f 90 63-7 74-93-1 502-39-6 9094-8 19467-96 8 13614-98-7 2385-95-5 12015-39 9 50-07-7 '047682-3 1313-27-5 6923 22 4 6923 22 4 150-69-5 2763 96-4 505 60-2 91-20-3 130 15 4 9159 9 134-32-7 16220-42 0 16391-57 2 7440020 3463-39 3 557-19-7 54-11-5 65-30-5 4797-55 9 7697-37-2 0102 43-9 139 13 9 Chemical Name 4,4- Methylenebis (2Methylenebis (phenyBsocyanate) 4.4 Methylenebis(N.N-dimethyl) 4.4- Methylenedlanilfne Methyltestosterone Methylthiouracil Methyltrichlorosilene Metolcarb Metronidazole Metyl 2-ch!oroacryfa1e Metyl mercaptan {Methanethiol (I.T Metylmercuric dlcyanamide Mlchler'e Ketone Midazolam hydrochloride Mineral oils, unhealed and mikfly-h Minocycline hydrochloride (inlernal Mirex Misoprostal Mitomycin C Mitoxantrone hydrochloride Molybobenum trioxide Monocrotopho* Monocrotophous Monuron Muscimol Mustard gas Naphthalene 1,4- Naphthoquinone beta- Naphthylamine alpha- Naphthyfamine Nelarelin acetate Netilmicin sulfate Nickel Nickel carbonyl Nickel compounds Nickel Cyanide Nicotine and salts Nicotine sullale Nitrate Nitric acid Nitric oxide * Nitrilotriacetic acid Nitrile HR 2HQ Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Legislation *H.R. 39M Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Ye9 S. 2123 Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Ye9 Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes S m Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes S. _Z1 Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Le glsla tlon CAS# 99-59 2 99-55-8 100-01-6 99-95-3 92-93 3 1122-60-7 1936-75 5 67-20-9 10102-44-0 51-75-2 55-86-7 Chemical Name 5- Nitro-o-anisidine 5- Nitro-o-toluidine MR *H.R. s. ** s. S. s. ?8Bt 3865 2123 373 761 1081 Yes Yes Yes Yes Yes Yes Yes Yes P- Nitroaniline Nitrobenzene Yes Yes Yes Yes Yes Yes Yes Yes 4- Nitrobiphenyl Yes Yes Yes Yes Yes Nitrocyclohexane Yes Yes Nitrofen Yes Yes Yes Yes Yes Nitrofurantoin Yes Yes Nitrogen dioxide Yes Yes Yes Nitrogen mustard Yes Yes Yes Yes Yes Nitrogen Mustard Hydrochloric Yes Yes 126-85-2 Nitrogen Mustard Hydrochloric Yes Yes Yes Nitrogen Mustard N-Oxide Yes Yes Yes Nitrogen Mustard N-Oxtde hyd Yes Yes Yes 55-63 0 Nitroglycerin Yes Yes Yes Yes Yes 88-75-5 2- Nitrophenol Yes Yes Yes Yes Yes 100-02-7 4 Nitrophenol Yes Yes Yes Yes Yes 79-46-9 2 Nitropropane Yes Yes Yes Yes Yes 35576-91-1 Nitrosamines, N.O.S. Yes Yes Yes 64091-91-4 4-{N- Nitroso methyfamino)-1-)3-pryi Yes Yes 759-73-9 N- NitrosoN-elhylurea Yes Yes Yes Yes Yes 684-93 5 N- Nitroso-N-methylurea Yes Yes Yes Yes Yes 615-53-2 N- Nihoso-N-methylurethane Yes Yes Yes 924-16-3 621-64-7 N- Nitrosodi-n-butyfamine N Nihosodin-propylamine Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes 55-18-5 62-75 9 156-10 5 1116-54-7 10595-95 6 4549-40-0 N Nitrosodiethylamine N- Nitrosodimethylamine P- Nitrosodiphenylamine N Nitrosodithanolamine N Nitrosomethylethylamine N Nitrosomethylvinylamine Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes 59-89 2 16543-55 8 100-754 N Nitrosomorpholine N Nihosonornicotine N- Nitrosopiperidine Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes 930-55-2 n- NitrosopyrroWine Yes Yes Yes 13256-22-9 N Nitrososarcosine Yes Yes Yes 86-30-6 N- Nitrosodiphenylamine Yes Yes Yes Yes Yes 991-42 4 Norbormide Yes Yes 68-22 4 Norethisterone (norethindrone] Yes Yes 51-96 9 Norethisterone acetate (Norett Yes Yes 6533-00-2 Norgestrol Yes Yes 3288-58-2 0.0 -Diethyl S-methyl dithioph Yes Yes Yes 303-47-9 Ochratoxin A Yes Yes i Vl) 0002024-9^43 Chemicals Subject To Toxic Use Reduction Legislation CAS# 2234-13-1 20816-120 20816 12 0 630 60 4 23135 22 0 78-71-7 434-07-1 2497-07-6 79-57-2 2058 46 0 10028 15 6 123-63 7 115-67-3 1910-42-5 2074-50-2 56-38-2 52-67-5 19624 22-7 608 93-5 76 01-7 87-86 5 2570 26-5 504 60-9 57-33 0 79 21-0 72-56-0 63 98 9 62-44-2 85 01-8 576 94 9 136 40-3 10B-95-2 4416 66 0 64-00-6 Lc*gl$teitlon Chemical Name H.R H.H. s. 3. S. S. 2880 3865 2123 676 761 1081 Octachloronaphlhalene Oestrogen replacement theory Yes Yes Yes Yes Yes Yes Yes Oestrogens, nonsteroidal Yes Yes Oeslrogens. Steroidal Yes Yes Oat contraceptives, combined Yes Yes Oral contraceptives, sequential Yes Yes Organorhodium Complex (PMN-B2 Yes Yes Osmium letroxide Yes Yes Yes Yes Yes Osmium letroxide Yes Yes Yes Ouabain Yes Yes Oxamyl Yes Yes Oxetane, 3,3-bte(chloromethyf). Yes Yes Oxydeme Ion-methyl Yes Yes 4.4'- Oxydianifine Yes Yes Oxydisul folon Yes Yes Oxytetracycline (internal use} Yes Yes Oxyletracycllne hydrochloride (inter Yes Yes Ozone Yes Yes Paraldehyde Yes Yes Yes Paremethadione Yes Yes Paraquat Yes Yes Paraquat methosulfate Yes Yes Parathion Yes Yes Yes Yes Yes Penicillamine Yes Yes Pentaborne Yes Yes Pentachlorobenzene Yes Yes Yes Penlachlorodibenzo-pdioxins Yes Yes Yes Pentachtorodibenzolurans Yes Yes Yes Penlachloroethane Yes Yes Yes Pentachforophenol (PCP) Yes Yes Yes Yes Yes Pentadecylamina Yes Yes 1.3 Penladiene (1} Pentobarbital sodium Yes Yes Yes Yes Yes Peracetic acid Yes Yes Yes Yes Yes Perthane Yes Yes Phenacemide Yes Yes Phenacetin Yes Yes Yes Phenanlhrene Yes Yes Phenarsazirte chloride Yes Yes Phenazopyridine Hydrochloride Yes Yes Phenol Yes Yes Yes Yes Yes Phenol, 2.2'-thiobis(4-cHoro-6-meth Yes Yes Phenol. 3-(1-methylethyt)- methyica Yes Yes CAS# 58-366 63-92-3 106-50-3 25265-76-3 59-88-1 62-38-4 90-43-7 2097-19 0 103-85-5 298-02 2 4104-14-7 947-02-4 75 44 5 732-11-6 13171-21-6 7803-51-2 2665-30-7 2703-13-1 50782-69-9 7664-38-2 3254-63-5 2587-90-8 10026-13-8 1314-56-3 7723-14-0 85 44 9 57-47-6 57 64-7 1918 02-1 109 06-8 88 89-1 124-87-8 110-89-4 51-03-6 54 91-1 23505 4M 18378-89-7 1336 36 3 151-50 8 506 61-6 Chemical Name H.H. 2660 Phenoxersine Yes Phenoxybenzamine Hydroehlor Yes P- Phenylenediamine Phenytenediamine Yes Yes Phenyihydrazine hydrochloride Yes Phenylmefcury(ic) acetate Yes 2- Phenylphenol Yes Phenylsilatrate Yes Phenylthiourea Yes Phenytoin Yes Phorate Yes Phosacetim Yes Phoslolan Yes Phosgene Yes Phosmet Yes Phosphamidon Yes Phosphine Yes Phosphonothieic acid. Methyl-. Yes Pbosphonothloic acid, methyl-. Yes Phosphonolhioic acid, methyl-. Yes Phosphoric acid Yes Phosphoric acid, dimethyl 4-(m Yes Phosphorothioic acid, o.odime Yes Phosphorous pentachloride Yes Phosphorous pentoxide Yes Phosphorus (yeUow or white) Yes Phthalic Acid esters NOS Yes Phthalic anhydride Yes Physostigmlne Yes Physostigmine, salicylate (1:1) Yes Pictoram Yes 2- Picoline (2-methylpyridine) Yes Picric acid Yes Picrotoxin Yes Piperidine Yes Piperonyl butoxide Yes Pipobroman Yes Pirimilosethyl Yes Plicamycin Yes Polychlorinated biphenyls (PCE Yes Potycylic Organic Matter Yes Potassium cyanide Yes Potassium Silver Cyanide Yes Le glslalion H.R. 3. - s. 3665 2123 976 Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes S. 761 Yes Yes Yes Yes Yes Yes Yes Yes A-12 ^VRD 00020249-44 Chemicals Subject To Toxic Use Reduction Legislation Legislation CAS# Chemical Name H.n, HR. S. S. $. S. 2880 3865 2123 875 761 1081 366-70-1 Procarbazine Hydrochloride Yes Yes S7 03-0 Progesterone Yes Yes 2631-37-0 23950-50-5 107-10 8 1120-71-4 107-19-7 10696-7 Promecarb pronamide i- Propanamine (i,T) (n ) Propane suitone Propargyl alcohol Propargyl bromide Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes 57 57-8 123-38-6 107 12 0 beta- Propiotaclone Propionaldehyde PropfonibBe (ethyl cyanide) Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes 7069-9 Propiophenone, 4'-amlno Yes Yes 114-26-1 Propoxur Yes Yes Yes Yes Yes 109 61-5 115-07-1 75 56 9 75-55-8 Propyl chforoformaie Propylene Propylene oxide Propyleneimine Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes 51-52-5 2275-18-5 129 00-0 110 86-1 140 76-1 504 24-5 1124-33-0 Propylthiouracil Prothoate Pyrene Pyridine Pyridine, 2-methyl-5-vtnyiPyridine, 4-amino Pyridine, 4-nitro-P 1-oxide Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes 53558 25 1 91-22 5 106 51 4 82 68 8 50 55 5 108 46 3 302 79 4 Pyriminil Yes Yes Quinoline Yes Yes Yes Yes Yes Guinone Yes Yes Yes Yes Yes Quintozene (pentachioronitrobenzei Yes Yes Yes Yes Yes Reserpine Yes Yes Yes Resorcinol (1,3-Benzenediol) Yes Yes Yes Retinoic acid, aK trans Yes Yes Retinoi/relinyl esters (daily dose > 1 Yes Yes 36791 04 5 299 84-3 Ribavirin Ronnel Yes Yes Yes Yes 83 79 4 Rotenone Yes Yes 81 07-2 94-59-7 14167 18 1 107-44-8 7783-00-8 12039 52 0 7782-49-2 1 Rubber industry Saccharin (manufacturing) Safrole Satcomine sarin Selentous acid Selenlous acid, dithaKiumfU) salt Selenium Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes CAS# 7791-23-3 7488-56-4 630-10-4 563-41-7 3037-72-7 7631-36-9 7440-22-4 506-64-9 93-72-1 122-34 9 7778-43 0 26628 22 8 124-65-2 143-33-9 62 74 8 13410-01-0 10102-20 2 900-95-8 3810-74-0 18883-66-4 8001-50-1 57-24 9 60-41-3 100-42-5 96-09-3 9-56-7 3689-24-5 3569-57-1 7446-09-5 1314 60-3 7783-60-0 7446-11-9 7664-93 9 93-76-5 77-81-6 54965 24-1 Legislation Chemical Name Selenium compounds H.n. H.R. S. ** 8. 2880 -3885- Mil. 875 Yes Yes Yes Yes Selenium oxychloride Selenium sulfide Yes Yes Yes Yes Yes Selenourea Yes Yes Yes Semkcarbazide hydrochloride Yes Yes Yes Shale oils Yes Yes Silane, (4-am1nobuty1)diethoxyr Yes Yes Silica, crystalline Silver Yes Yes Yes Yes Yes Yes Silver compounds Silver Cyanide Yes Yes Yes Yes Yes Yes Yes Silvex (2,4,5-TP) Spent Propan Yes Yes Yes Simazine Sodium Arsenite Yes Yes Yes Yes Sodium azide (Na(N3)) Yes Yes Yes Sodium cacodylate Sodium cyanide (Na(CN)) Yes Yes Yes Yes Yes Sodium fluoroacetale (Flouroac Yes Yes Sodium selenate Sodium tellurite Yes Yes Yes Yes Soots Soots, Tars, and Mineral Oils Stannane, acetoxytriphenyiStreptomycin sullate Streptozotoein Stiobane Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes strychnine and salts Strychnine, sulfate Styrene Styrene oxide Sulfallate Yes Yas Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Sulfate Yes Yes Sulfotep Yes Yes Yes Sulfoxide. 3-chloropropyl octyl Yes Yes Sulfur dioxide Yes Yes Sulfur phosphide (R) Yes Yes Yes Sulfur telrafluoride Yes Yes Sulfur trioxide Yes Yes Sulfuric acid Yes Yes Yes Yes 2.4.5- T acid (Acetic acid, 2,4,5-triehk Yes Yes Yes Tabun Yes Yes Talc containing asbestiform Rbr Yes Yes Tamoxifen citrate Yes Yes S. S. .1SL -1M1 Yes Yes Yes Yes Yes Yes M3 < VRD 00020 2 4 9 4-5 Chemicals Subject To Toxic Use Reduction Legislation CAS# Chemical Name HR. 2880 13494-00-9 Tellurium Yes 7783004 Tellurium hexafluoride Yes 646-50-4 Temazepam Yes 107-493 Tapp Tetraethyl pyrophosphate Yes 13071-799 Terbulos Yes 686500 Teibulryn Yes 56-20-8 Testosterone cypkmate Yes 315-37-7 Testosterone enenthate Yes 95 94 3 1.2.4.5 Tetrachlorobenzene Yes 174601 6 2.3,7,8- Tetrachlorodibenzo-p-dioxin Yes Tetrachlorodibenzo-p-dioxlns Yes Telraehlorodibenzofurans Yes 79-34-5 1.1,2.2- Telrachloroethane Yes 630-20 6 1,1.1,2- Telrachloroethane Yes 25322-20-7 Tetrachloroethane N.O.S. Yes 127-18-4 Tetrachloroethylene (perchloroethyl Yes 50-90 2 2,4.3.6- Tetrachlorophenol Yes 961-11-5 Tetrachlorvfnpbos Yes 60-54-8 tetracycline (internal use) Yes 64 75 5 Tetracycline hydrochloride (internal Yes 78-00-2 Tetraethyl lead Yes 3689 24-5 TetraethylditHopyrophosphate Yes 597-64-0 Tetraethyltin Yes 75-74-1 Telremethyllead Yes 509-14 8 Tetranitromathane Yes 50-35-1 Thalidomide Yes 1314-32 5 Thallic oxide Yes 7440-28-0 Thallium Yes 563-68-8 Thallium (1) acetate Yes 6533-73 9 Thallium (1) carbonate Yes 744618-6 Thallium (1) sullate Yes 7791-12 0 Thallium chloride Tlcl Yes Thallium compounds Yes 10102 45 1 Thailium(l) nitrate Yes 2757-18-8 Thaflousmalonate Yes 62 55 5 Thioacetamide Yes 2231-57 4 Thiocarbaztde Yes 139-65-1 4.4- Thiodianiline Yes 39196 18 4 Thiotanox Yes 154-42-7 Thioguanine Yes 297-97 2 108-98-5 Thionazin i TWophenol (Benzenethiol) Yes Yes 79-19-6 Thiosemicarbazide Yes Lc`glsleiUon *H,R. s * s. 3065 2123 976 Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yea Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes S. 761 Yes Yes Yes Yes Yes Yes Yes S. 1H | Yes CAS# 62-56-6 5344-82-1 614-78 8 137-26 8 1314-20-1 7550-45-0 49842-07-1 108-88-3 584-84-9 823 40-5 91-08-7 496-72-0 26471-62-5 95-53-4 106-49 0 636-21-5 8001-35-2 299-75-2 1031-47-6 68-76-8 24017-47-8 28911-01 5 78-48-8 52 68 6 1558-25-4 27137 85 5 76-02-8 120 82 1 71-55-6 79 00 5 79-01-6 115-21-9 75-69 4 327-98 0 95-95 4 88 06 2 98 13 5 96-18-4 25735-29 9 998-30-1 Chemical Name Thiourea Thiourea, (2-chlorophenyl) Thiourea, (2 methylphenyl)Thiram Thorium dioxide Titanium tetrachloride Tobacco products, smokeless Tobacco smoke Tobramycin sullate Toluene ToIuene-2,4-diisocyanale Toluene 2,6-diamine Toluene-2.6-dirsocyana1e Toluene-3,4-diamine Toluenediisocyanate 0- Toluidine P Toluidine o- Toluidine hydrochloride Toxaphene Treosulphan Triamiphos Triaziquone Triazofos Triazolam s.s.s- Tributyl Phosphorotfithioate Tributylins Trichlorfon Trichtero(cHoromethyl)silane Trichloro(dichlorophenyl)silane Trichloroacety! chloride 1.2.4 Trichlorobenzene 1.1.1- Trichloroe thane 1.12- Trichloroethane Trichloroethylene Trichloroethylsilane Trichloromonofluoromethane Trichloronate 2.4,5- Trichlorophenol 2,4.6- Trichlorophenol Trichlorophenylsilane 1.2.3- Trichloropropane Trichloropropane. N.O.S, Triethoxysilane H.R. 2080 Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Le gisla lion HR. s. 3065_ 2123 Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yea Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes * s. 179 Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yea Yea Yes Yea Yea Yes S. 791 Yes Yes Yes Yes Yes Yes Yes Yea Yes Yes Yes Yes Yea Yes Yes Yes Yes Yes s _VRi) 000 2 8 2 4 9 46 ww ______ ___ _ - Chemicals Subject To Toxic Use Reduction Legislation CAS# 126 68 1 121 44 a 1582 09 8 2303 17 5 13647 35-3 127-490 95 63 6 75-77-4 824 11-3 540 84-1 106645-1 99-35-4 639 58-7 76 87-9 126 72-7 52-22-4 52-24 4 555-77-1 72-57-1 50-31-7 66-75-1 51-79-6 26995 91-5 2001-95-8 99 66 1 7440 62-2 1314 62-1 143 67-9 2068-78-2 108 05 4 59360-2 75-01-4 75 35-4 129 06-6 01 81-2 108-38-3 95 47-6 106 42 3 1330 20-7 87 62-7 2834 M3 9 7440 66-6 Chemical Name 0,0,0- Triethyl phosphorothioate Triethylaming Trifktralin Trills 1e Tritostane Trimethadiorte 1.2.4- TrimthyIbentene Trimethylchtorosiiane Trimethylolpropane phosphite 2.24- Trlmelhylpentane Trimefhyftin chloride 1,3,5- Trinilrobenzene (R.T) Triphgnylfin chloride Triphenyltin hydroxide TPTH Tris (2.3-dibromopropyl) phosphate Tris(l-azlridioyl) phosphine suiphldr Tris(1-ailridinyl)pbosphfne sulfide Tris(2.3dtbromopfopyl) phosphate Tris(2-chloroethyl)amine Trypan blue (2.7-Naphthalenedlsuio Trysben Uracil Mustard (2,4-(lH,3H)-Pyrimk Urethane Urofollitropin Velinomycin Valproate (Valproic Acid) Vanadium (fume or dust) Vanadium pentoxide Vinblastine sulfate Vincristine sulfate Vinyl acetate Vinyl bromide Vinyl chloride Vmylidene chloride Warfarin Sodium Warfarin, A salts, whan presint at c< m- Xylene o- Xylene P- Xylene Xylene (mixed isomers) 2.6- Xylidine 1 Xyfyfene dicbhrid& Zinc (lume or dust) H.R. 2880 Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Lcsglsl?illon *H.R. s. ** s. 3865 2123 876 Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes S. 761 Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes S. CAS# 1061 557-21-1 1314-84-7 58270-08-9 12122 67-7 Chemical Name Zinc compounds Zinc Cyanide Zinc phosphide Zn3P2 Zinc, dichloro(4.4-dimethyl-5((( Zineb H.R. 2880 Yes Yes Yes Yes Yes Le gfsla tlon HR. s. s. 396? 2123 376 Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes S. 761 Yes Yes Number of Chemicals Subject 1077 784 1077 To Toxic Use Reduction- 1 (Compound categories that are listed above are counted as 1 chemical even though they mey Include many more Individual chemicals that would be subject lo the legislation) 621 329 1 Analysis her# Is ol lha proposed Community fllght-To-Know More Amendment lo H.R. 3665 offered by Mr. Slkorskl and Mr Rlnafdo 1 * S. 976 as amended by Senators Laufenberg A Durenberger 3. 1061 9 *-15