Document yk3wOaMM8p38ZdxaJ59GNn86D
PLASTICS DIVISION
To DivUion
Mr. J. C. Schlichter Union Carbide Corporation Texas city, Texas
Copy lo
Mr. D. Barbieri - BB Mr. J. H. Barrett - TC Mr. J. N. Barton - Chicago Mr. G. P. Bigelow-NY Mr. A. J. Costantin - BB Mr. G. G. Himmler - BB Mr. J. L. Hockersmith - TC Mr. D. E. Richardson - TC Mr. G. C. Shipston - NY Mr. R. N. Wheeler - SC
RIVER ROAD, ROUND BROOK, NEW JFRSEY 0S305
originating Oupt.
April 14, 1967 Applications - R & D
<An*w/7n9 Ltt+r date
Subfact
Proposed specification for
Ethylene-PVC Copolymer Resins for the PVC Bottle Market
The proposed resin specification for QXOL-7 contained in your memorandum of April 5, 1967 does not define a resin of sufficient quality for the clear rigid PVC bottle market. The required resins QSQH, QSQL, and QSQM should meet the following specification:
Property Inherent Viscosity % Ethylene Screen Analysis % thru 40 mesh % thru 200 mesh Particle Size, Clear HRP Dye Respro
17. 5 mil 10 mil ICMT Contamination Dry Flow, sec/400cc Bulk Density, lb/ft**
Heat Loss, % Plasticizer Sorption, %
QSQH 0.76-0.80 0. 90+. 15
100 min. 4 max.
140-200 3 max.
0 max. 50 max. 90 min. 3 max. 4. 0 max. 28 min. 0. 5 max. 80 min.
-QSQL 0. 91-0. 95 0. 90+.15
100 min. 4 max.
140-200 3 max.
0 50 100 3 4.0 28 0.5 80
QSQM 0. 96-1. 00 0. 90+ . 15
100 min. 4 max.
140-200 3 max.
0 50 100 3 4.0 28 0.5 80
These resins are being priced considerably above the competitive resins currently sold in this market. This premium is based not only on the advantages derived by the ethylene comonomer but on a low fisheye level and
excellent powderblend properties. The powderblend approach used by potential
TO: Mr. J. C. Schlichter
2 April 14, 1967
resin customers necessitates low volatiles, low fines content and freedom from hard particles in the resins.
The ethylene content is especially significant because values greater than 1.1% cause haze in clear bottle formulations. This lower ethylene content and tighter specifications are necessary if these resins are to penetrate the clear packaging market.
The resins development effort and recent quality improvements in suspension resin production will be wasted if sufficiently restrictive specifications are not established to demand a premium price for these resins.
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R. J. Ireland
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0/39435