Document yk2EzNQxv1EOJJ29YE14XknB4
AR226 -- OE HS
ACUTE TOXICITY TO AQUATIC INVERTEBRATES (ACARTIA TONSA) TEST SUBSTANCE
Identity:
A mixture containing perfluorooctanesulfonate, which may also be referred to as PFOS, FC-95, or as a component of FC-602. (1Octanesulfonic acid) (CAS # 2795-393).
Remarks: The 3M production lot number was not noted. The test sample
is FC-602. Current information indicates it is a mixture of 1% PFOS, 12%
diethylene glycol butyl ether, 61.05% water, 20% ethylene glycol, 2% Sultone
foamer, 1% sodium octyl sulfate, 1% sodium decyl sulfate, 1% magnesium
sulfate, 0.7% xanthan gum, 0.1% starch, 0.1% n-(3-chloroallyl)hexaminium
chloride, and 0.05% tolytriazole.
-
The following summary applies to a mixture with incompletely characterized concentrations of impurities. Data may not accurately reflect the toxicityofthe fluorochemical component of the test sample.
METHOD:
Method: ISO/DIS 14669-1997: Water qualit--y Determinationofacute lethal toxicity to marine copepods (Copepoda, Crustacea).
Type: Acute static
GLP: No
Year completed: 2000
Species: Acartia tonsa Supplier: Test organisms cultivated from eggs, supplied by Marine Biological
Laboratory, Universityof Copenhagen, Denmark. Analytical monitoring: Dissolved oxygen, and pH
Exposure period: 48-hours
Test organism age: Large copepodites and adults.
Statistical method: LCs values calculated by PROBIT Analysis, National Swedish Environmental Protection Board (Version 2.3, 1990). Calculation of NOEC is by single factor ANOVA followed by Bonferronis procedure. Test conditions:
Dilution water: Filtered natural seawater
unpolluted site in Byfiord, Norway.
(34
ppt
salinity)
from
an
Dilution water chemistry: Not given.
Lighting: A daily photoperiod of 16 hours light and 8 hours dark was
maintained throughout the testing period.
or
Stock and test solution preparation: A 1000 mg/L primary stock solution
was prepared by diluting 0.9998 gof test substance in 1 Lofwater. Aliquots
were then added directly to water in test vessels to create test solutions.
Exposure vessels: 28 mL rolled rim vials containing 25 mLoftest solution
002125
NNuummbbeerr ooff roerpglaincaitsemss: p4er replicate: 5
Number of concentrations: five plus a blank control
Water cphHemriasntgrey(d0u4r8inhgoutrhse):study: 8.28.2 (control exposure)
Temper8a.tu0re8.r2a(n1g0e0:0 2m0g/+L1expCosure) Dissolved oxygen range (0-48 hours):
75.3.7.74~mmgg/7/LL(.(1c0o4n0t0romlge/xLpoesxuproes)ure)
RESULTS
NReofmeirneanlcecosnucbesnttarnacteio(n3,s5:-dBikchcloonrtoroplh,en1o0l,)
32, at
11.000m,g3/L2.0,
and
1000
mg/L.
Element values: 24-hour LCso = 350 (25-0 490) mg/L 48-hour LCs = 200 (140 -- 270) mg/L. 48-hour NOEC = 100 mg/L.
Element values based on nominal concentrations.
Remarks: Substance
TReesmtianrgkwsafsielcdo.nTduhcetveadlouensarmeipxotrutreed
as described apply to that
in the Test mixture and
not
the fiuorochemical proportion alone.
CONCLUSIONS
___
TcohnefiFdCe-n6c0e2in4t8e-rhvaolurofL1C4s0o wtoas27d0etmegr/mLi.neTdheto4b8e-h2o0u0r mNgo/OLbwsiethrvae9d5E%ffect Concentration (NOEC) was 100 mg/L.
Validity criteria fulfiled. Reference substance in normal range.
Submitter: 3M Company, Environmental Laboratory, P.O. Box 33331, St.
Paul, Minnesota, 55133
DATA QUALITY
Reliability: Klimisch ranking = 2. This study meets the criteria for quality taensdtinigt .lacHkoswaenvaelryt,ictahlecsotnufdiyrmlaatcikosnionffotrhmeaatmioonuonnt opufrfiltyuoofrtochheemtiecsatlspurbosptoarntcieon ~
in the solution.
REFERENCES
002126
rTeeqsutewsatsofc3onMduNcotregde,byLaRbFreRfoegraelnacnednuRemsbeearrc9h9,31o2f-S3t,a2v0a0n0g.er, Norway at the
ower
000000
Last changed: 6/26/00
002127
.
5L9ar51)2-n30..
page 1of 31
fii odio R2ENANE
"FC-602 Light Water Brand ATCplus"
Toxicity tests
Report RF-2000/003
[Fee Lab. rola 983123 No.of pages: 3
Glni(s): 3M Norge
VersionNo. ate: Vers. 1/07.01 2000 Research Program:
----
Samar:
The folowing est resus were obtained with "FC-602 Light Water Brand ATC plus':
Toxcty: Skeletonema costatum Acarta tonsa
72h EG, 48hLc,
(mon: 78 (mon: 200
Corophium volutator 10dLC, (mdrygwehighgt): 53070
The results elateto the product as supplied by Novatech.
Rey worde:
Toxicity, Skelstonema costatum, Acarta tons, Corophium volutator.
opacitybe opro0ud ary om wihtpersion i wgbyFE Rep ese
IngearrLsicsoarAndersen Prof lrHor 15,20.ox203Uo,401Soc
oKarre-NeRotgaarladnd Asear(ch 128 Norco Bl:147517500, 75187570.nmembes5008100.
.
9La9b3.1r2e:f3no.:
Page20f31
CONTENTS:
1 PREFACE css 3
2. TEST FOR TOXICITY WITH SKELETONEMA COSTAccToUM
4
3. TEST FOR TOXICITY WITH ACARTIATONSA cress, 10
4. TEST FOR TOXICITY WITH COROPHIUM VOLUTATOR cvs 15
5+ DATA SHEET(S).covvenrssrssssssmmssssmsmmmsssssssmsssmsmsosesmsmsmsnsnsoso 20
002129
.
9La9b3r1e7f3no.;
Page 3of31
PREFACE:
NsEocolovuttaoitxoein.ccohlToTeghsiescaswlaetmrepesltcseowinesdrueccptoeendcreifnntoarrcacmtoeeortdndhaa"ntFcCne.o8rw0mi2athlLlihgyhetwiW"laHltaberermuoBsrneainddinATaC39p%lAsF"FiFn-a3g6re9emgej.nt wit
Notification Format" (OSPARCOM 1995 / SFT 1998).
sed Offshore Chemgont
Theproject wascarried out at RF- Rogaland Researchfor 3M Norge. Al he tests were
performed byRF -Miljslab. Study director was Senior Engineer Inger Lisa Andersen.
bTyheNotvesattercehs.uls arepresented in separate sections. The results relate to theprodict assupplied
eTTqhhuiesiaptcmecsertnertdeaipnaodtritwooinsriskstisauntegedpbrtoyacteatdlhuaerbeloasrbafotororartayolalrcytchmreeeetdetisstttemhdeebtyNhNoAodrsrewcqeugiiraenmeAnctcsrecdointcaetrinoinngc4o)m.petence,
ci[entrtatelirkfnoiaesldaqrtueeaflseirttehynacctoetnhterollabsocrhaetmoersy,hpaasrtaicsiaptaitsifoanctionryinqtuearlliatyboarsasotunotrrayaincncoeemdpsiaynrsitteshmoe,naswc,hcriaecndhdiaitthmieaonwgo.eesof
materialsand secondary reference materials,
The testsperformed are covered by the accreditation.
This tet report may not be writing by RF-Miljalab.
reproduced
in
anform
other
than
inul,
without
hepermission
in
002130
}
Se
pe
|
TEST FOR TOXICITY
i
.
Marine alga: Skeletonema costatum
{
002131
.
9L9o3b1r3e3f,
Pagseofsi
TEST REPORT
GROWTH INHIBITION TEST WITHTHEMARINE
ALGA Skeletonema costatum
a Iii
wFoLos RROPGAAALRACNRD
TEST SUBSTANCE: "FC-602 Light Water Brand ATC plus"
] TEST RESULT:
.
is
| The 72 hours ECswascalculatot~e7d8 mg/l.
5
The test substance was supplied by Novatech, and the test results relate to thisproduct. pp
TEST DETAILS: Fg
METHOD:
|
a NS-EN ISO 10253, 1998: Water quality - Marine algal growth inhibition te ge
with Skeletonema costatum and|Phaeodactylum tricornutum.
TEST ORGANISM: SotelretongiesmkaecaopsttanattRumFi,-sRts oragianlNmaInVdAReBseAaCrch1., A stock culture ofthe tet
i
Eo
PREPARATIONS:
He Natural seawater (salinity: 34 %) from an unpolluted sie in Byford was used
`aausntdbrabesrniitsSfesfoalarycthcheoaertdgeirdnog1w01t0ahb1mSoeutdi17u05m25.C3`,pTrahineowdratrtoeeucrsoemw.maeTsnhdfeailtstieeoraenwdsafttrherroomwuatgshheeanPGraFirc/ihsCedfiwlIti'etr,h g
INCUBATION:
mmTgee/sdltiuswomal.sutpiOrotenhpseawrreecrdobencypernsettpriaarrtreiindognfs0r.wo1em0r2ae4spgtrroecapkmasrsoeoldfuttfhiroeonm.pArtohidssutcsottcoikcnks1osloluliturtieiooonfno.gfro10w2i.n4 Toerenbsitetaclulstahubarkoeeusrot,f23050r0e0pmlcilecawlteelrssefoifrnoecmaucbahanctoeienxcpdneonn1te0rn0atmtiiiaolnl.fylaTgter-sobtwoitcuntlogtmuierdneosfclsuaeslksusemocJnupleatanrue-.
`tTuhbeesteosfut nwiavserrsuanlunnadteurraclonwthiintuoeuysp.el,igahtta(>te5m0peurEa/tmu're"osefk)2f0r+om2fCl.uorescent
t`Thheetteessttfwlaassksrcuancfhordaabyofuotr 7g2rhoowutrhsm,aeansdurseumbesnatmsp.leAslgoalf5grmolwwtehrweatsakmeenasfurroemd
by fluorescence. pH measurements were performed as indicated on data sheet.
RAANGER:ProfessorOlovHonssan 15,PO B 2
002132
L5o9b3r1e2f3o.:
Page ofl
i DATA ANALYs]s:
1 |
CALCULATIONS: VGerroswutshtirmaet,esawsedreesccrailbceudlaitneNd Sb-yElNogIlSinOea1r0r2e5g3r.ession on biomass (fluorescence)
b
1
ECs! cTohneceinnthriabtiitoornyoeffafepcrtoodnuctthegigvrionwgth5o0f%Skreedluecttoinoenmoafgcrooswtatthumraitse e(xEpCrse)ss.edThaissthe
i
e1f0f2e.ct4mcgoAn.c.entration was calculated by interpolation between 32mg/l and
NOEC: cfCoaacnltccoeurnlAtartNaitoOnioVonfAmNefOaonEllCwoiw(tehNdotbhyOebBcsooennrftverreolrdomEnefiafsencp.troCcoendcuernetrfaotricoon)mpiasrdionngecbaychsingle-
TESTRESULTS:
COMMENTS: VALIDATION:
EosT T--a_ble 1. EC and NOEe C values obtained witm h Skeletonemaccootsaartua mi,:
ToTetstmsbuebswtasneces 0EEcCoe
EECCos
EEeCue
FC-602 Light Water
-
_--
5
>1024
NoEC: 32
GYYrevolpeuhsspiaenrddeinccaoatlerecuo0lnaceibnerydaiinotnerspgoloantigon.10N%O3C0a96raendca0l5oitbtbidyiowngof ogreocwtohmaptaespUrnnisimnmta
Td(hsueereitngegrsowuwhltishcahcruetrbhvaeessg)er.dowotnhgrisowcotnhsiadteersedfotrothbee eixmpeonsepntainal0 i-n7t2hbe,ctohnetproelricouldtures
cTehlledveanlisdiittyyicnrcirteeraisaedgibvyean ifnatcthoertoefstmporroetotchoalnar1e6 fiunlftihleletde,tinpetrhiatodthe control (V3a,cr5y-bodiyrcmhroloerreospphttehonoaonanl1gdw,0ruaionswinitntghstdhrueartrieoanngfgtemhoneroertemtsathlaalnnyd0f,ot9uhden"d7).2, hthoeurcsonttersolrpesHultdsidwintoht
Lab ref. no:
TSeasmtppleeriroedc:eived.: Report date:
993123
222250..1019..9999 07.01.2000
Enclosed: Data sheets
BN
EEnligniHnoerevre Adalytical technician
7Hider ng
SeniAorgeReMsoelavrecrhsSmcyierntist Quality Assurance
a Le Tormey
002133
La3b.1resfno,:
Page 7of31
PRIMARY DATA: Growth Inhibition test with Skeletonema costatum Test substance; ~Fc.602 Light Water Brand ATC plus"
Lab. rel: 993123
CSotnaret.duantiet:: 2m2g.11.99
Measurement:The biomass was measuredbyfluorescence; values in fluorescence units
Conantatenfe 1320 | [oom To 22.11.99] 23.11.99] 24.11.99] 25.11.99
rate | Corre-|atstart| atend
Teds | | dager | | re] i
0
006 | 032 [ 15 82
0
0.06 023
17
161 | 0.999
i
0
006 | ods 3
93
1
11.7616|| 00.999s9
i)A
0o
00.0077 | o0s4s6 | 211s5 n9
11.5696|| 00.999997
012 | ox | 23 | us 150| 0999 032
007 042
032
009 | oss
15 [7| 168| 0998
125
162| 0.998
1
032
007
05
12
1.69| 0.996
|i
00 | os | 27 | is 008
066
34
145
007 064
3
13
1.71 | 0.993
11.6722 |( 00.99991
i|
000.000998 ||"0o05s%8s|| 230345
111.667332||[ 0oo.9s9oe9s
!
i;
01 | oss
00017 || ooaa3
1s 165| 0987
11445 11.6734|| 00590s09
ii
}
@= | 0o0m6:|| oosss|| o21r
2 00s| 043|
i1s627| 0[o5s%e
|
|
wes
| 01 |
os |
29
oz
1024 007 | 008 | ois
163| 0999
04| 0970
wes | oo | or | 45
006509|| 0o9o7n1
83
BeteriTessnmcmogo1srubs|tanceo[o(0354r ||dcho00rs1]p8ha|nol:o0s%s smo | or | ois | ose
ze | oos | of Mean values: 0 032 1 3102
32
007 04
008
05
0.08 oe
000099 | 04
0.09
05
(Referencesubst 000|036 | 04
1 77]
05%| Tosoe ooo| ooo
83| 82
TT
162 [0999
166| 0.987
168| 0.995
116676|| 00.999998| reeofr
01.5654|| 00.69949||si wubostnan'ces(5.3% omy"002134
is
Page 8of31
|f
TGeRstOsWubTstHanCceU:RV*ECS6:02GLrioghwttWhatIenrhiBbriatnidonATtGesptluwsi"th
Skeletonema costatum
Labret: Snr
l
| De 2s
~
! i | i 1 i
|
s
]
4
Hy
i
i
g
i'
|
=
vom
Lat
-=
1
3
oat dation Pees)
i
I test duration(hours)
-
i 1 mgt
--
3 i
5
Ii =oF
i
le {
5s
| bl
Fa
ments
' 32 mg
rl
yisap
on
oF nsmonm
|ss;
|| I
i
ha [Rion
Lii
3 testduration(hours)
Se |
af
|
||
i
|
ha
esto mse)
002135
L9a9b3re1f2n3o
Papgaediodf3l
wSiTthEabition of the growth of skeletonems costatum 9/1 (FC602 Light Water Brand ATC plus)
Experimental data:
I cFCo-n6c0e2ntLriagthitonWaitner BrT and ATCI plus T
cCoonnttrrooll Control
12 3
CCoonnttrrooll 5
Control 6
Control mean :
00.3322 032
1.1l0000 100
33.12200 320
1100..0000 10.00
33220.0000 32000
1100220.4400 102130
116661
l1e7s ils
-
150
1.62
11.6628 16
Ca1m72 162
1176:32 ile
11.665 1m
11.6627 16s
00..4680 06s
iInnhpiebritcieonnt
-: --o 00.10 00 00.00 01 l0.o0 00 00.00 00 00.10 oo 7603.00 EX
| 002136
gia; 2
j
i
Page 100f31
|
ERORY
ii
vi
How i
TEST FOR ToxICITY
Marine herbivore: Acartia tonsa
|
.
{
002137
5La9b3r1e2f3ino
Page 11of31
i
TEST REPORT
i ACUTE TOXICITY TEST WITH THE
i MARINE COPEPOD Acartia tonsa
a iil
wee>irime RR2SLEANCR
ii TEST SUBSTANCE: "FC-602 Light Water Brand ATC plus"
3 TEST RESULT: -
: The 48 hours LCso was calculated to 200 mg. Cg The test substance was supplied by Novatech, and the test results relate to thisproduct.
4
TEST DETAILS:
2 METHOD: i
ISO/DIS to marine
1c4o6p6e9po-d1s99(7C:opWeaptoedra,quCarluisttya-ceDae)t.erminationof
acute
lethal
toxicity
3
TEST
ORGANISM:
Acartia tonsa (Dana), supplied UniversityofCopenhagen.
by
the
Marine.
Biological
Laboratory,
CULTIVATION: avTnihtdehattdehusetlto"srPawgraeinrsieCsumossmemwdieisrnsetihsoeunptpe-lsRti.iedngasTeesgtgsP,roatnodcowle"re(VcKuIl)t.ivaLtaerdgiencaocpcoerpdoadnicee.s
3
PREPARATIONS: p2Nrsaitbouarrsatiols usfseoera.wtahteedril(usatliionnitwya:t3er4.%oT)hefrwoamtearnwuanspoflillutteereddstihteroiungBhyfajGoFr/dCw.afs eused
i
m`wTaget/seltr.swoalsutpiroenspawreerdebpyrsetpiarrreindgf0r.o9m99a8sgtrocakmssoolfuttihoen.prAoduscttocikns|olluittrieoonfoif 1l00u0
INCUBATION:
Other concentrations were prepared from this stock solution.
The test was run in glass containers (28 mi rolled im vias) eacchontaining
2Y2i50alm1slwoefCrt.eesktpepHstoaulunntddieoornxyaagn1de6n1/ma8enhaismlauilrgshe,um'e4dnarrtekspplwhiecoratteoepsefroirodeaacthactoenmcpeentrraattuiroen.ofThe
data sheet,
performed as indicated on the
Bon cee o
002138
L9a9b3r1e2fr3o.:
Page 12031
- DATA ANALYSIS:
: CALCULATIONS: paTehprertoeedfsutfcectcotnloceetnhnattlrhea10tsiu5or0nvi%wvoeafrlteohfuesAectdaesrfttoiaranciatmloacnulslsaat(iiLsoCnesx0p)r.esTsheedcaosmtbhienceodnmcoernttarlaititoyn of
: i
sPLrtCoaotnoedcavtraidloupnersBoocaaenrdddurt(heVePe9rRs5Oi%BonIco2Tn3fA,inda1el9yn9sc0ie)s.l,iNmiattiwoenrae.l cSaTwlheceduli2ast4hehdEonbuvyrisrvoaimnnmdgae4tn8hteahlous
i
concentrations lethal to 10% and 90%ofTthihseptreostgarnaimmmalesa.lso caleulage sos
3 : i
NOEC: fcCaoacnltccoeurnltAartNaitoOinooVnfAmNefOaonlElCwoiwt(ehNdotbhyOebBcsooennrtfvreoerldrmoEefnfiaenpc.troCcoendcuernetrfaotricoon)mpiasrdionngeebayrsingle-
i oe { TESTRESULTS: Table1. LC 104 NOEC values obtained with "FC-602 Light Watar Brand ATC,plus
i
seAcarm tia te onsa
i
Ley
M24bhous
s4h8 heourss
i
tc
120 (56-190)
330 @s0-490)
87 (12-130)
200 (10-270
1
Lew
970 (650-2200)
450 (320-900)
:: i
te haelceosmpiundtbied cryaptPerRo1Og0Br%IaTd m5amn0ea%Glryasanipds5h,0an%dI9cn5hS%oaslco1on0fnrc2e4ainedt4saurrsiUtre2imNgsE.Coolusesaoeneetdy
3 2
VALIDATION: OTxhyegveanlicdointcyecnrtirteartiiaongiavtetnheinetnhdeofttehteprtoetsocol are fulfilled, i that the dissolved
|
LthCespeorfc3e,n5t-adgiecmhloorrtoaplheiintonyl t(hreefceornetnrcoel)swwaatsswialnesstgshreteharatanenrg1te0hn%ao,nramonardleltqyhuefaol4u8tnodh.4onmegs/l,
i
: 4
LSaabm.plreef.renco.c;ived.:
2909.3091.2939
4 Test period:
22251199
#
Report date:
07.01.2000
: Enclosed: Data sheets
QEliln HorVveoru Engineer
Analytical technician
Hl SeniAorgeReMsoelavrecrhsSmcyierntist
Quality Assurance -- --
}5 3
Tohmot onte edbb epbosn seidbyNorwegin Accrdiaion A.Trp To pommy mi rodveed mn"
i
002139
| La5b5r3e1f3r3o.:
Page 13of31
PRIMARY DATA: Acute toxicity test with Acartia tonsa
Test substance; "FC-602 Light Water Brand ATC plus"
|
|||
Lasbu.nrdeate:: Measurement:
9190.31112938 Numberofdead
|
I
nuTmoubler|| pNrsu.pmevbceeisrmseeolnf
NUMBEROFDEAD _
|
24hours
sohors |
| Concentration | Specimen
F|o
men pr.conc.
AcE
BToDF | Toa
Ace
[TBEDF | Toa |
|
000
000
|
{ |
000 0
|C| li
5555 1010
I
|
|
20
7
LTTT T17 Co
Referencesubstance ep
---
| Theresultwithth rferencesubstance swithintha range normaly foun.
--
%|
002140
|| titrye.
_--_--
|
LSTaeasntodstua:b:stance: ts"soFsrCr-iz6e0as2 Light Water Brand ATC plus" Measurofooxmygeenanntdpsh
| corconv| aon | Oogns T pn |omo een n on m|mommen
/
i
L (mg/)
(mg/)
-
(mg/)
-
(mg/)
=1
e e ee e e t Fo
C|e
eeTT
Ce ee|
RT
$_
_
|
002141
L9ab3r1esfno.:
Page 1531
|
i
TEST FOR TOXICITY
Marine Amphipode: Corophium volutator
|
|
i
i
&
3 aoe
32
+
2#
i
002142
La5b9.3r1e2fn3o.
Page 16 of31
TEST REPORT
a
i
ACUTE TOXICITY SEDIMENT TEST WITH THE MARINE AMPHIPOD Corophium volutator
Q [3 me RESEARCH
TEST SUBSTANCE: "FC-602 Light Water Brand ATC plus"
TEST RESULT:
The 10d LCso was calculated to >3070 mg kg" dry weight sediment.
The test substance was supplied by Novatech, and the test results relate to this product.
TEST DETAILS:
METHOD:
ASTM E1367-
`Toxicity Tests
90, Standard
with Marine
Gui
and
de For Conducting 10
Estuarine Sediments.
day
Static
Se
di
men
t
`TEST ORGANISM: Corophium volutator, from an unpolluted site near Trondheim.
CULTIVATION:
~~
The test organisms aerated seawater at
w1e5rCe.suAppslmiaeldlaasmaoduulnttso(f4n-a8tmurmalisnesaiwzee)eadnwdawseruesehdeflodr
in
feeding.
PREPARATION:
SNattauvraanlgesreawwaasteurse(sdalfionritdyi:lu3t4io%n)waftrero.m aSneduinmpeonlltuctoeldlseictteediantBaynfjuonrpdoelnlouuttesdisdiete awnaaslyusseeddffoorroprrgeapnaircincgontteestntseadnidmepnrtosp.orTtihoensseildtifmoernetaicshatemsut.ddy sand and was dEaacmhptseestdicmoenncetnitnraatpiloanstwiacsbupcrkeepta.re2d0b0ymaldodfisnegatwhaetperrodwuacst aidn d6e0d0agnrdamthseof 4b0uc0kmetiowfassesahwaakteenr fwoa3srahdoduersd.toTehaechs,edainmdetnhtewbaesadkievrisdweedreianetorattheredeobveearkers, tnihgehtd.am1p0 saendiimmaelnstwwearse tahneanlyrsaenddfoomrlwyatseelreccotnetdefnotr,eaancdhablelackoenrc.enAtrastaimopnlsearoef.
calculated as mg kg! sedimentdryweight.
INCUBATION:
sTehdeimteesntt,waasppr.u4n0i0n gmllaosfs csoenatwaaitneerrsan(d60100maln)imeaalcsh,c3onrteapilinciantges20f0orgoeafcthest tcoenmcpeenrtartautrieono.f T15he+b1eaCk.erpsHwearnedkoexpytguenndmereacsounrteimnueonutssaweerraetipoenraftoarmed as indicated on the data sheet.
|
|
|; | | ! -|
. 0brOle 5.0.x2505Un091Scr Nr
145107800
002143
45 87520,Eve mrs 500
9La9b3r1ef2n3o.:
Page 170f31
DATA ANALYSIS:
CALCULATIONS:
mTtorharettiaeolfniftoeycftapeoprnreotsdhteucsctuornlvceitevhnaatllrtaootfi5Co0nor%wooepfrhetihuuesmetdevsoftlouartncaiatmloacrlulsiast(eiLxoCpnsr.)e.sTsheTedha1es0cdtohameybcLioCnnsecpden-
`value and the 95% confidence limit are calculated by using the standard PROBIT Analysis, National Swedish Environmental Protection Board(Version 2.3, 1990). This programme also calculate test concentrations lethal to 10% and 90%ofthe test animals.
NOEC: fCaacltcourlaAtNioOnVofANfOoEllCow(eNdobOybBsoenrfveerrdoEnfifsecptroCcoendcueraetrfaotricoon)mpiasrdionngeebaychsingleconcentration mean with the control mean.
TESTRESULTS: P Table 1. LCl aad NOEC u values obtains ed with FC-6t 02 Light Wate er Brand ATk C pldus"d.
Corophium voutaor
10d
Len
1750
ice
>3070
feCo
--.>.3070
NoEC:
3070
VaGVlraluauepehsspaianrddeiiccantase1tl00%i5y05%PaRnOdBI9T0a%nleycsha.liyaNfeOr E1a0rCdayas. iUniis idbnymtghRecgo"mspetedpirdomrpyeewmecinsgh,tt.
VALIDATION:
`Tohxeygveanlicdointcyecnrtirteartiiaogniavtetnheinetnhdeotfetstheprtoetsotcwolasagrreefautlefritllhead,noinrtehqatuatlheto6di0sso%l,ved
iFtshleufoporeuarnncdteetnoatbeaeg(ewreimftoehrrtieannlcieat)cycweiapnstitehndetlchiomenittrrsaonflogsrewonerorgreamnlaielcslscytofhnoatunennd1t.5b%uTthatenhdesaesidltitemsfetrnawtcittuihsonedis
recommended higher .
Table 2. CharacteisRcs oofthee seTdimeenteusledffoor trsetaege
--OOrgpaniceconnten C(4y) _ 07
siSittffcracitioonn(e4)y, os08
LSaabm.plreef.rneoc.e:ived.:
`Test period:
Report date:
20909391.29.93
03-12.12.99
07.01.2000
SEliNn Hoerve
Engineer
Analytical technician
AFgeeHMoylvrerstmyyr --
Senior Research Scientist
Quality Assurance
Enclosed: Data sheets
To
form
theprtrhnsin
fuell,dwbyiWtothhreperroymiusssietondinewritiNnogbrywReFgn- MAicljrsdlba.ion
OR).Terror
myoevz144 ||
Labrefro.
99312-3
Page Isr31
"e
PRIMARY DATA: Acute toxicity test with Corophium volutator
Test substance: "FC-602 Light Water Brand ATC plus" SLtaabr.tocattse: sna.n1i2z9a0 Measurement: Numobfdeeard
Total | Nsoprecmiamreon
umber| pr. vessel
NOMSEROF DE
7
Says
100s
Concentration | Specimen| A C E | A C E
ACE
(mg dry/wekighgt)| pr.conc. | B D F B DF Total B DF Total
Control
1100 1100 1100
00000 0
|
|[=[s[ [ T~ ]]|
a070
l|
Referencesubstance (tuoranthene_):
_
Tharesulwitthe referancesubstanceiswit th rangenormallyfound.
002145
Lab.refno.
Page 19of31
Lab. ref.:
993123
es s[ n w oe TT ow] Concentration Oxygen
PH
Oxygen
pH
Oxygen
PH
[om [wow ou] |L (mg/kg dryweight)| (%)
:
(%)
-
(%)
-
[=eo [ = w Te ee w lw e = ]ur]
C|-- eI To oT:
002146
993123 DATA SHEETS
002147
993123
HSS-DATASLAD (else, illo 0g Sikkecharsdacamias) DEokvumeenstari 0018-/21807/35.79 Usksegeivtees ut 1 1110//1111//9988 vscearnsion 1 ap 03.0O000 T#e4l5e-fdoant:asl63ade8s4 7o5c u00car/bTeeildeessaxa:v M63ilj84eav1d7e.8l8ingen ved I Norge A/S.
1 IOENTIFIXASION AV KIEMIRALIET 00 ASVARLG FERAL
Tapesser: 34 Norge A/s
-
Sancel2sCn-a2v0n1:a7 LIGET WATER' (TW) 1% APFF (FREEZE PROTECTED)
: Telefo2n5, 5Gif13si0n0fornesjonssencralea:
| ||
|; ;i
Ep ------
|
Informasjon on enkeltkonponenter, faresymbol(er) og risikasetninger !
storm
cAs-nz
2v(-aO(I2E-TBYuLtEovsGaLTYoRROsLYN)O-NZOTARNUOTTLYELR/E)
Twaateass
12-tFtazaewsoyomrboles/zisikosatninger: Xi; R136 Fazesymbotes/zisikosecninges: tn; R122
107-2101
ALRRMYFLOT-ESRULFEALTUSOARLTOENRLKVDEEAANTUIRDE TRIZTAROLAKIN
TTrraaddee SSeecczreerr 102-716
RPEERSFTLERUOARVOAOLRIGLA-NSIUSLFEONFALTU-OSRAKLJTEEMRIKALIER TTrraaddee sSeeccrzeets
VEXT-PROSENT |
3r5.e0 - 3290.00
- 100 154.00 - 1106..00 1.0 Sa3.o0 | Ikke Mint
02148
99312-3
-
FC-201AT LIGHT WATER (TX) 1% AFFE (FREEZE PROTECTED)
3 VIATIGSTE FAREMOMENTER.
Viksigsce skadevickninges
telsetTaRzIe:TERNOE (x1) Irsitees oynene.
Sikieshes:
.
Hiljotare:
i
+ rexsteasziosTILTAX.
|| Titeax ove: BSiknyvlslcessc.zakKsonseaykn:eselesgerunudmiidgdemlebdasrei.kelSikgyellimnegsgduensdervantnran&spmoirnts.s 13
| TileekSyhule: scraks bude med sipe og rikelige mengdes vann. Fier
||
ctiolyseflo:r dteoyc. brHuvikses siysmipetnomeorg okpapssttitri,lseklotntaskktotelye.ge. Vask tilselt
i
| meisax sackading:
|
Kevxoisnspzoens:eysniplnteggoems.ek:ildoepnp.stiSro,rgbrfionrgfvreidskkomlmuefsn.devbiosr:syfmraptomene vedvares, ||
TiitakKonstvaeklg:inlge:ge
umiddelbazs.
Fremkall
| brekninger
kun
i
samrdd
med
mpeedzsiosni.nsk pzsorell. Gi aldri noe gjennom austen til en bevisssles
5 TILTAX VED BRANNSLURNING.
EgaetPbrroadnukntseltukneringestnibdrdaenln:slukkingsmiddel. Tie egnet brannslukningsaiddel:
Eksponeringszisiko ved brann:
|
:
__
1002149
993123
:
F-20LAF LIGHT WATER (B) 1% APPR (rReEzz PROTECTED)
Fosbzenniagsprodukeer ved brann:
2zosecyres vad siukking av bana:
TILIA VED Urrisixeer Urenzes. PessoSneiisveesaveasrinleisaikltaukn:der andre punkeer i dette fNS-datebladet. TiltaVckbesnvesardibleecsseeinoldnssziikdmeeaerts.eruieSsspilieil.plp:aSpvislrlensseasnleusmiodpdpelbuensisd.deiDveakcs.tilRemmemdyorat
onside: aed vann. Plasseres i en egnc beholder mes tomy FlemmiSengpeanvisKje13n,tkfaelrinesivsaglla:v kjemikalieavtar.
RT--
3ecingelses fos sikker opshevaring:
MBCeLalsiikeuklsel,e:lLaalgsretesesesmiidvieoecmrr.dtdeeLarapgerrhevasotrurveperrdodotuvekemtrpeets0etskuearendekuronmdmeseerls4ii3ukeog.enetspaeokrrtdmed
beholderen tett lukket
Utoranelise maseriatec:
nds
produktet
ikke
er
i
bruk.
VentilOavspjboenv:ar eaba: llasjen pd at godt ventilert seed. Sikkechetssileak for 4 forhindze beana: StkkeTckhkeesbsrteinlnisaakz.for forhindre eksplosjon:
Sikkerhetstiltak for & forhindre statisk elektrisitet:
FoshoHPZloordlrosdkdreuenkgeslsoeebgtsalklvfaaeensdrjleibcnseoueykkt:deiecntkgomflpuokrkkerta.akeReyfkoirnugrenfsonribnugde:avUnsdeebrskbkersukoausvalles SEabilize: ogs reakiviteto,nersiknagdseplriogdeukdieexerspkounnendsaenrn.es. Se poate 3,
oT
002150
L5ao9i3r1eg2-3no.
rugRiny se
FC-201A7 LIGHT WATER (TN) 1% APF (rRzzz PRomecrED)
8 EXSIONIRINGSKONTROLL OG PEASONLIG VERNEUTSTER.
i
oyevezUnn:esh 3 4 dass, vezaebrilles ned
vspnrseiyleerl.ler
thke
L
oyneme.
Bruk
tetce
Hindve3r:nu:k egnede vessehansiker bindcesing av srodukset.
Vavernheehnasniskksesrmesavsisfomlessenedrsiamlaetevseidale(r)
anbefales: Bucylgemni.
AnnetUnhnugdhverhuadkeonnntahxiea.dvesn:
Ancadz2Uen7sngtLdsuvfeicrafnno:drnudzienngsnaivngelsufcibhazrebceidmsaattemrioaslfea.renBavseeirgsesofenkoanvsenftorrapasnjdoenen oSyT2s0a(n2i)skeGoddkajnegresr odgndevdazseksetfaovremring:e hpaaritvimkalsekse: meAd/PIfSiLl.er mec
svetgiag:
fpDeretondduenirdteei:ek.tkteeVrassptihsieunssd,staetsditrneigkkoeonsgrldefelorlrersgpriurssoiydnkiges.smeudndesripsarobgeidvamme.d Vask AnbefasEolvdtiiscvieuentnsstiulgdannsidjneogdnzs:evsesnstvialransiobnenyisktkees.exSetriglscfroerxkeillissc,remxhkelalgsnes
avenaitniilsatsriaotnivseiixroarsmezcamopgk/oenlsleenstrkaosnjtornoelnies:hoslpdreasy eulnldeerr ssigvbee.falte Ad. nomme: for foruzensning i asbeidsatmesfare, Tebrusz 1996: VAN A(n7m7e3z2k-n1i8n-g5e)d: Ingen adm. nos. 2-(2-83-UcTiOnKeSsYsETvOKeSrYa)-pZoTmA:NOL35/ (DISTYLENGLYXOLUONOBUSYLITER) (112-34-5)
A(nTmaegceknninnogzessk: aAaz.esniokramn)s.k grenseverdi asbefalt av produsenten.
1,2-E8T-AtNiDnIeOcLs 8-tiners
(vv1e0er7dd-ii21m-p1ao)m/:mi:-
1(0stev()stov)
TTeakkvveerzddii pmogn/:ml:23- ((ddaammpp))
AMFOTAERnnFeLzUkOnRiOnAgLeK:YLIAnNgIeDn-DaEdRmI.VATnor(mT.rade Secret)
ALKYLA-nSmUeLcFkAnTi-nSgAeLzT:ER In(gTernadeadmS.ecrneotr)m.
i
|i i :
: |i |! }| |
|
|| |
;: i| :
:
; }i
}
Vor : i i
i
1 002151
993173
-
FC-201a LcaT WATER (TM) 13 ATFY (FREEZE PROTECTED)
TTs-6ttiinneerss vveorree:s pmogm/:ml:- 5 PIRTLaU-OcRiOnNecLsYLv-SeUeLlFOmNgT/-aSdA:LT0E,R1 (Trade Secres)
A(sTmaegseknninnogresrk: sAdm.azinkoernms.k grenseverdi ssefalt av produsencen. RISERS-AtVineOrRsGANVIeSrKdEi mFLgU/OmR:KIE0N,1INALGIrZeRnse(vTerzadle aSencbreefta)lt av I.
Ven oo romansmememenn,
Tilstandsform, farge, luke:
we Roepe /inservalls Saetcsunke/-inservalls Flemmegunie: Setvenemnelighets Zsslosjonsgranses, nedre: Zsstosjonsgrenses, pre: Daspecyik: Losetighes i vann:
"gtar raviarget vaske.
15-08 100 (3egyanende Kekesinke)
Tice zetevant > 0c (uinielash) Tike selevant Tike zelevant Tie selevait - 16 oma (sellers v/20 ) Biueser
Spesifikk vekt: |
= 1.10 (vann=1)
Samptesthet:
.
-a 10 (efeel) (Kalkulest v/20
Fiykeige organiske forbindelser (VOC): =Pro3d5u9kt9e/sL) SCAU (3/1 av
Fordampningshastighet:
<1 (butylacetacel)
Viskositet:
= 18 centipoise
-
-
002152
La9v3r1a2}3no,
Fuge su on
Fo-2013r Laas ware (7) 14 AFPE (rREEZE mRorzCreD)
10 STA3ILITET OG REAKPIVITET.
Forhold som skal unngls:
|
Eereommenohile os Karbondioksid. Bydcosentiuorid. Giftige dumper,
blanding forventes ikke i representere noen risiko.
enn Stabilitet og FreakEziviettesi:ertsasion vil te foretsme.
i
Eizekter oynes
i
seterecedsarnaeta:hudteisasjon (esses Langrariy alles siesta Koneaks1s
Lanpvasis elie: sjencest sksponesing kan fore its
|
bAolpecoisk hudesksjons symptones Ken vere zadhet, heveise, biomes
AF3 Effekter inndnding:
erhes, sevnighet, manglende koordinasjonsevne, nedsate
reaksjonsevne, bevisstleshet.
sleret
tale, svimmelhet -
og
i
ekstreme
tilfeller
eriettasihonee(neveogLhuptaetvnasiter): sympsenes Kan vase shzhes nase 03
setekcrraeesentesovtepetecgeikdnsgdh:ueteorrtvsiesadsosrgtarnoiksekse fslouocrkefseemnttkaliisrs,rrsnonefineersL
SSReeeknlagapieyemeneedbseikaabeipnpspectoeiete5sSenhsemimeoasetnroeattropsTteensat.sDaecsp.fofemomrneelstssoonneeFsroporneeEneprnetitag,
LI nner nie
I I |
|~
00215.
Laib.resfno..
Pa27gofe31
C-2018F Licer WATER (TW) 10 AFF (FRoEiE PROTECTED)
etitnng,
Svelging kan fore cit
|
Losinen v3 rrv---- Pdvizkaiag av nyrene: symptomesr kan vate redusest urinmengde, blod ! Aspizesjonsoneumons. (Lungebetennelse som skyldes at fremmediegemes Rckoorsmpsmkeea:sto.pn)se:dbsilyomlpuocngogennaLesu.nksaEennsevatalermmsienlnheeossltiigsnoguA,rsKaepknusctvieelrveantsiLhliesvrta,atnrd3ueisnsnvdieen.rd. Intorassson on allersi, overfolsoanes:
Xref:fremkallende egenskaper:
|
Acvestottakadelise egenskesest
|
Reproduksjonsskadelige egeaskapes:
i
Andze skedevizkninges, heise:
i
DonFveleetudrtobereLipyaerntnogtndekiueenkltgtieiseatss,t,ieosntransceoahm(roamleudstleouirnbsoelesninesiqnaeenlkrgal)noeym:oerosfeglonerrrypeloeenrroerssgtsakolnuiimesirklLeeserogemrsesve&dkropven |1|
#fGo4lx7en"dcmeeesscbneraaskskekesarposfnroeamriTsnokgraeigruo.sneesrbeiatngosfoovr1eerlhfieosrrgseorrrdsianesgiidesnkveKeljlefenrdcenecirnnkgej.lesmstsutatteikosres !||
asm arbeiders viser ingen skadelige stfercers i Forekomsten av organiske fluorkjemikalier i blodet til den
1
generelle befolkningen og underpopulasjoner som arbeidere, har vart publisert siden 1970 Arene. 3s epidemiologiske studier av
i |
:
!
12 GPeLySNINGER OM MILTeARE.
;
PezatsbFtelatintoser/kpBerinooidlkuoakgltiiasetk:niesadnobcmehyomsluhdlaeisrsheenetsn:eilklkeero5flnereedborrygieoneirsekeog forbiis 1 |
miljoet (persistente).
i
Andce skedevizkninger, mitje:
|
Nedbrytning:
i
C5Sa0Obz20(0/CchGoeanmgiec=rasl29o(%x3yigoecnhenDeimcaanld)Sry=se1n71D0ena0n0d0)ng=/k4g3;4 000 mg/kg:
;
Acvatiox gistghes:
002154
993123"
"
FC-201AF Loar WATER (TW) 1 APFF (FREEZE PROTECTED)
p$6tyciaess 1050 for fist (Sathead minnow (Pinephales promelas)) =
3a93t;iness 2030 for dapinia (Hater flea (Daphnia magna)) = > 1000
9360 stiinsseisster1scs023f0o,s asl;
Waligcetor=on>
1(0P0h0otmegb/eLc;ieriun
phosshoreun)
=
63
B3atritnes 50, Accivased Sludge Respiration Inhibition = > 1000
Serg for avfallshlrdtering iht. gjeldende forskrifter.
13 FUERNING AY KIENEALTEAVEALE
HetodeSrsesfioarlafvjiearlnli.ngfeavverkjaersfiakisllisssivliaelnl:offentlis sodkent aoteaks- eller behandtingsanless for spesisiaceail.
innsamles,
ARnObVeEfOaRlAsTeEGOaRv:ial07l:sgrAuVpFsAeCsL: FAA ORGANISKE PROSESSER.
SUSieNnDkgEkiRoeRcrAeiTnIgG07aOnRiI0d6l0e70s3,:05:SdeeAlsvoifgnaetlnealksstjfeoransoPmrSigDad3nliesrakveogfelotKstoessntmmotefdtflieekrr,., og mocertut.
sipe,
vaskevasker
Avtallssoffouames: 7151 Organisk avfall med halogen.
Spesielle koaponentes: fluorforbindelser.
14 orppLtsNINGER ON TRANSPORT.
RoR-kiasses
-
siffer:
-
bokstav:
-
sargnusmer:
-
cerrckore:
-
-numme:
-
Ieno-Klasse:
-
I0G-kLasse:
-
i.
f
0pz15
La9b9.3r1e2fn3o.:
Page 29.iotfed31
FC-201AF LIGHT WATER (TM) 1% ATFF (FREEZE PROTECTED)
1406-3ide:
-
Eus-az.:
-
wraG:
.
ovsigeTiokgeslryasnnsipnogretsf:eslis gods.
15 OPPLYSNINGZR OM LOVER 0G FORSKRIFTZR.
Nerkestikest: -
SymbolE(LeSxI)S:TADELIG (Xa)
Tnneho2l-d(e2r-:butoksyetoksy)-ecanol 19 3 Eeylessiykol 14 3
R-sesninges: Farlig ved svelging. Irriterer oynene.
s-setnUinnngegr:inalnding av camp/sproycetdke. Unngk konzaks med oyrene of i sltarnagkusariGgrunkdoingtamkesdmesdorheudemne.agdFAe:r mveannnsotgoffkeocntaiktsynleengee;. sEktytlelr hudkontaks, vask med shoe og vann. Ved svelging, kontakt lege onglends og vis dexze beholdesen eller etiketten.
ram--00
-
| i
Korr. yrkeshvg. lufthehor:
i
0-30 m/l
ourige opplysninger om meckeetikesten: ovvaernene4vaftiennemecpkhinpgrodeu-kbtaesreretn tpihdtifdrleimgoveerre.meMrekkeifnogresnkrivfitler og vil inidlestid erstattes av folgende merking, som er basert ph revideste merkeforsirifter av Januar 1998.
Symbol: IRRITERENDE (Xi)
~
Tnneholder: 2-(2-buzoksyatoksy)-stanol, 1,2-etandiol
XIornrtiatke=remredoynoeynnse.ne.UsaUgnhnghinnlkanndgivnagrigaveldalmepr/sgpjreonyttaetcthkkeo.nteUkntngmhed
huden. FA man stoffec i oynene; skyll straks grundig med store
mveannng.desVevdansnveolgginkgo,nsedkreikklegteo. glEacstservahundnkoongtakkotn,tavkatsklegmeed sipe og
uniddetbase.
0p215
T9a9v3i1g2-A3o.
suger
FC-201AF LIE ATER (TN) 13 AFEE (FRezzz zRoTECTED)
t0i-grizse: SpestSeSilklEkeeoslThoevisesrEdoatgoanbbleasudtseemmfmboereiisdfeeaslr:aleigeogkjdeimsitkeailbiuersi.on av Kelse-, milse- og |
3k2..anFFmooerrdsstikoczziietftsmioolnmjokKfllaaarssess.iiffiisseerriinngg, ogmermkeirnkginmg.va.v afvarlsitgaetKjseomnlkalier, | 54.. FFoorrsskkeriiffte oonm sstpoefstikaalratvoatlelk.. 6 Eee.
i
16 ANDRZ OPPLYSNINGER AV 3ZTYDNING FOR BARUKZRNES SIXXZR4ZT OG HELSZ.
i
AavendFeillsaedsounesniddees:siumiorsansiat for sing av beam ydzokasonss, ||
VikiiDgsataablkeidldef(ar) iveGdenuezraableiOdfeflisceesn, aSvtH.MSP-adualt,abMliandneets:ste, USA.
:
AsseEBeMtlSiel-ddoaepttaeacbdallteaeddrfeiotnrgs:ekxzirieevri,derfta.stTsialtptasiseJ:anunayre m1e99c8k.e-Eroeg.
i: i
2570 opplysninges:
i
gSIIeknrksfieioeyri0ams%naesijnogpnerseoasntmusovkgpesdsebsedmseettudetnedeodzepHspcfScea-otdmn@maiaSsnla-gebdlaaaftndoegmebhhtloealnededre.sti,Erihakettmeihrsoldbbrruutkkiloavvgiprheriondnduitkveiererisensgdessson || pexeobdruuskeetzenskaonmsbvianra.sjon med andre produkter eelllleerr esnohnvemredssaemreenr pbrriosskesssv ||
i
i
ii. :|
i!i i
0p2157
f9r9i3r1v3t3at
rage io)
FO-2OIAF LiGT WATER (7) 1b APF (FREzzz PRoTzcTED)
FOLGENDE PRODUKTER BEXXES AV DETTE ENS-DATASLADET:
3 Towne.
+ 27-0002-0842-3
F3iMghLtiignhgt wFaoatme,r F1C%-2A0T1F3F7,Fir20e0 L
3M Town.
27-0002-0341-1
3FighLtiignhgt WFoaatme,r F1C3-2A0T1EaF7,F1i0r0e0 L
3M Toonz.
+ XF-0008-0205-g
F3ighLtiignhge WFoaasme,r F13C-2A0F1FaF%,FirBeulk
3 Toone. + X3MF-0L0i0g8h-t02W0a3c-e3: 1% AFFF Fize -
Fighting Foam, FC-201a7,1000 L
3M 10-nz.
X7-0008-0202-5
3FighLtiignhgt WFoaatme,r F1C%-2A0T1FaF%,Fir2e00 1
3 oar.
+ X7-0008-0200-3
.
F3i%ghLtiignhge
Water Fem,
F1C8-2A0F1FaF7,rice20
1
1
!
wr
:
4
RE ~ Rogaland Research
0.80 2503 Ulsnchaug
2
4
4008 Stanger
i
Norway
i
C2o
TTeoleepshone: 2+44775511887755200000
x
E
$be
po
of
al
----
SH
:
i
5008 aren
9
ee &
TNorowaoy n' 753505850 2 s
Teer: +4754538650
Internet: hitp://www.rtno E
3
