Document y54Qebnx65pxavBk0RXzMyE

Refining. North America (conoc Conoco Inc. PO Bo* 37 Westlake, LA 70669 (318) 491-5211 June 29, 1990 Louisiana Emergency Response Commission Office Of State Police Hazardous Substance Control Section Right-To-Know Unit P. 0. Box 66614 Baton Rouge, LA 70896 SUBMITTAL OF MSDS UPDATES - SECOND QUARTER 1990 Dear Sir: Enclosed you will find Material Safety Data Sheet Updates for the second quarter of 1990, for the Conoco Refinery, Westlake, Louisiana. This information is being provided to you in accordance with the update requirements of Section 311 of Community Right-To-Know Act. If you have any questions concerning this submittal, please contact Dave Tinker at 318-491-5543. Lake Charles Refinery am att cc w/o att: W. 0. Lukens (Conoco) P. B. Butler (Conoco) D. L. Tinker (Conoco y*"" DLT: MSDS.DOC SAL 000006346 >'RT: 92180 PRODUCT NAME: PREMIER ETP CUTTING FLUID AERO PAQE OF ********* SECTION VIII - SAFE HANDLING AND PROTECTION INFORMATION RESPIRATORY PROTECTION: USE ONLY IN WELL VENTILATED AREAS. ILATION-LOCAL: RECOMMENDED SPECIAL:N/A CS580 MECHANICAL: REQUIRED OTHER: N/A PROTECTIVE GLOVES: SOLVENT RESISTANT OTHER PROTECTIVE EQUIPMENT: EYE PROTECTION: SAFETY GOGGLES IF VENTILATION IS INADEQUATE* WEAR APPROVED RESPIRATORY EQUIPMENT. ESTIMATED LDSO. MG/KG: YES ORAL RAT 13000iDERMAL RABBIT 2000. ESTIMATED LC50, PPM: YES INHALATION MAN 10000 SENSITIZATION: NO IRRITANT: NO SYNERGISTIC AGENTS: NO ******************* SECTION IX - SPECIAL PRECAUTIONS ************************ PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: KEEP IN A COOL PLACE. KEEP AWAY FROM HEAT. SPARKS. FLAMES, OR SOURCES OF IGNITION. AVOID PROLONGED OR REPEATED BREATHING OF GAS, FUMES, VAPOR OR SPRAY MIST. AVOID PROLONGED OR REPEATED CONTACT WITH SKIN. WASH THOROUGHLY AFTER USING. OTHER PRECAUTIONS: DO NOT PUNCTURE, INCINERATE (OR BURN) CONTAINERS. KEEP OUT OF REACH OF CHILDREN. ALWAYS READ AND FOLLOW DIRECTIONS ON PRODUCT LABEL. IN CASE OF ACCIDENT OR ILLNESS, SEEK PHYSICIAN IMMEDIATELY, SHOW LABEL OR MSDS. ADDITIONAL TECHNICAL DATA SHEETS AND/OR MATERIAL SAFETY DATA SHEETS (MSDS) ARE AVAILABLE UPON REQUEST. FOR PROFESSIONAL AND INDUSTRIAL USE ONLY. THE INFORMATION AND RECOMMENDATIONS PROVIDED HEREIN ARE BELIEVED TO BE ACCURATE AS OF THE DATE HEREOF. HOWEVER, SUCH INFORMATION AND RECOMMENDATIONS ARE F IDED WITHOUT WARRANTY OF ANY KIND AND PREMIER INDUSTRIAL CORPORATION DECLAIMS ANY AND ALL LIABILITY OR LEGAL RESPONSIBILITY FOR USE OR RELIANCE UPON SAME. SAL 000006399 Vendor Information r0ge Purchase Requisition Of Priority RLOC Department REB Refining Ship To 1 Shaded Areas RO Loc Requisition No. for Purchasing I Dept, Use Only 316 257738 Ship1 date fleq'o at Dest Order Previous f vu Type KORMAL Tagging Instruction* C T EHGUEERUG F.O.B. Point Freight Te Attn: PAUL 318-988-24*1 Requisitioner Date BACHELU 3/8/90 Tax Status Special Instructions Charge Exempt 6% Conoco Inc. Refinery Warehouse Old Spanish Trail P.O. Box 37 Westlake, LA 70669 Cerner Project ID Clauses Payment Terms APE Reportir Distribution Charge 7411-3-1240-152-14-4103 TMr * con WCoOntrol MO 2S773B! 3/8/90 k*103 T#n* Trm UM tail Star NO CM ST 44 1003 80S 152 C*f0 Sroet No b>w ><*iwi ETP Cuttlne Fluid 1 1 APPROVED: D t BECK)SSARD ------ i------------------- i _ L .... ... On* IWbuiub 7411-3-li$0-152-14-4103 tlftrr Ouanttty No Or0*r*d Pnc 1 12 i i | | On -mjtc i i i COSTUMED ORDER TO C T EXGIXEE2TSG it DO SOT HOP li i j------------------------------------------------------------------------------------------------ - _________ 1 ' h ! 1 Opetyti^Q P>e* .- .. 1 i .1 AptrwV fvre*4ir* Oh. _____J................ .. . !........... j s-w xr H4ii SAL 000006400 I C p 0 88 05-Feb-90 Page 1 Conoco Material Safety Data Sheet SCI hay i is*) MATERIAL IDENTIFICATION NUMBER NAME : GASC0059 : CONOCO XP-14W SOLVENT CHEMICAL FAMILY : Mixed Petroleum Hydrocarbons TRADE NAMES / SYNONYMS s Paraf f mic/Naphthenic Solvent CAS NUMBER NFPA RATING WHMIS CLASSIFICATION Not Applicable. : 64742-47-8 : Health: 0 Flammability: 2 Reactivity: 0 : MANUFACTURER/DISTRIBUTOR: Conoco Inc. P.O. Box 2197 Houston, TX 77252 GENERAL INFORMATION PHONE : 1 -(713)293-5550 TRANSPORTATION EMERGENCY PHONE : 1-<800)424-9300 MEDICAL EMERGENCY PHONE : 1-(800)441 -3637 ************************++*********#***##*#*********** + -***************** OSHA HAZARD DETERMINATION Hazardous Ingredients CAS Number `1 Paraffinic & Naphthenic Hydrocarbons Mixture 100*/ Hazardous Physical Properties: Class 111A Combustible Liquid, NFPA 30-1987. The material is hazardous as defined by OSHA's Hazard Communication Standard 29 CFR 1910.1200. Refer to the Regulatory Information Section of this MSDS for federal state regulatory information. and *** ****-****** *********** ******* **#***#****#*#**#*# ****#* ********** ******** PHYSICAL DATA Boiling Point Vapor Pressure Vapor Density `/ Volatiles Evaporation Rate Solubility in Water do r Form Color Specific Gravity 350 to 460 deg F 2 mm Hg at 100 deg 6.2 (Air = 1.0) Nil Not Applicable Insoluble Hydrocarbon Liquid Clear, colorless (H20=l) 0.80-0.81 F SAL 000006401 05-Feb-90 Conoco Material Safety Data Snaet Page 2 MSDS No: GASC'j'jj^ HAZARDOUS REACTIVITY Instability : Stable. Hazardous Composition Products: Combustion products will include carbon dioxide and possibly carbon monoxide. Conditions to Avoid: materia Is. Excessive heat, flame and oxidizing Hazardous Polymerization: Will not occur. *******^*********^*************-*****Ht**Ht**-^***--fr- + -fr*-**-4--ft<*-ft-***- FIRE AND EXPLOSION DATA Flash Point : 140 deg F Method : TCC Flammable Limits in Air, X by Vol. LEL : 1.0 UEL : 6.0 FIRE AND EXPLOSION HAZARDS Class IIIA Combustible Liquid (NFPA). EXTINGUISHING MEDIA Water Spray. Dry Chemical. C02. Foam. SPECIAL FIRE FIGHTING INSTRUCTIONS Special Fire Fighting Procedures: Water or foam may cause frothing. Use water to keep fire-exposed containers cool. Water spray may be used to flush spills away from exposures. Unusual Fire and Explosion Hazards: Products of combustion may contain carbon monoxide, carbon dioxide and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. + **-******************+******+*****************************#*****+-****** HEALTH HAZARD INFORMATION Primary Route(s) of Exposure/Entry: Skin, inhalation. Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: Extreme exposure or aspiration into the lungs may cause pneumonia. Overexposure may cause weakness, headache, nausea, confusion, blurred vision, drowsiness and other nervous system effects; greater exposure may cause SAL 000006402 05-Feb-90 Conoco Material Safety Data Sheet (HEALTH HAZARD INFORMATION - CONTINUED) Page 3 MSDS No: GASC005 C P 0 38 dizziness, slurred speech, flushed face, unconsciousness or convulsions. The product contains petroleum hydrocarbons and, as with many petroleum products, it may cause irritation to the eyes lungs or skin after prolonged or repeated exposure. Studies with mice or rats have shown that some petroleum distillates have caused either damage or tumors of the kidneys or tumors of the liver. However, kidney effects were not seen in similar studies involving guinea pigs, dogs or monkeys. Also, the significance of the liver tumors in rodents is highly speculative. Carcinogenicity None of the components in this chemical is listed by IARC, NTP, OSHA, or ACGIH as a carcinogen. Exposure Limits for CONOCO XP-14W SOLVENT TLV PEL Other (ACGIH) (OSHA) : None Established : None Estab1ished : PEL: Petroleum Distill ates 400 ppm; 1600 mg/ m3 * TLV is a registere d trademark. Safety Precautions Wash thoroughly after handling. ***##******* +***#****+** **********************+************** ********** FIRST AID INHALATION If inhaled, remove to fresh air. If not respiration. If breathing is difficult, physician. breathing, give artificial give oxygen. Call a SKIN CONTACT In case of contact, immediately wash skin with soap and plenty of water. If irritation develops, consult a physician. EYE CONTACT In case of contact, immediately flush eyes with plenty of water fo at least 15 minutes. Call a physician. INGESTION If swallowed, do not induce vomiting. Give large quantities of water. Never give anything by mouth to an unconscious person. Call a physician. SAL 000006403 05-Feb-90 Conoco Material Safety Data Sneet (FIRST AID - CONTINUED) Page 4 MSDS Nos GA3C005C CP038 NOTES TQ PHYSICIAN Gastric lavage by qualifed medical personnel may be considered, depending on quantity of material ingested. PROTECTION INFORMATION Generally Applicable Control Measures and Procedures Ventilations adequate. General mechanical ventilation normally Personal Protective Equipment Respiratory Protection: Select appropriate NIOSHapproved respiratory protection where necessary to maintain exposures below the acceptable limits in the Health Hazard Information Section. Proper respiratory selection should be determined by adequately trained personnel and based on the contaminant(s), the degree of potential exposure, and published respiratory protection factors. Protective gloves: Should be worn when any potential exists for skin contact. NBR or neoprene recommended. Eye Protection: Chemical splash goggles or face shield recommended where splashing can occur. Other Protective Equipment: Sufficient to minimize skin exposure. Coveralls with long sleeves if splashing is probable. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. SPILL, LEAK AND DISPOSAL INFORMATION Spill, Leak, or Release NOTE: Review FIRE AND EXPLOSION HAZARDS and SAFETY PRECAUTIONS before proceeding with clean up. Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clean up. In Case of Spill or Leak: All sparks, flames and ignition sources must be restricted from the area. Contain spill immediately in smallest possible area. Recover as much of the product as possible by such methods as vacuuming, followed by recovering residual fluids using absorbent materials. Nonrecoverable product, contaminated soil, debris and other materials should be placed in proper containers for ultimate disposal. Avoid washing, draining or directing material to storm or sanitary sewers. SAL 000006404- 05-Feb-90 Conoco Material Safety Data Sheet Page 5 MSDS No: GA5C005 (SPILL, LEAK AND DISPOSAL INFORMATION C P 0 38CONTINUED) Waste Disposal Treatment, storage, transportation and disposal must be in accordance with applicable Federal, State/Provincia 1, and Local regu1 at ions. Recycle as much of the recoverable product as possible. ***-* + ** + ******************* + ************ + **************** + *- SHIPPING INFORMATI ON DOT Proper Shipping Name Petroleum Disti Hazard Class UN/NA No. DOT Label(s) DOT Placard late : : : : Combustible UN 1268 None Combustible Liquid *#+***+***#***#**+#*************+*****#**************+*+*********** STORAGE CONDITIONS Store in accordance with National Fire Protection Assn regulations. **********-****** +******************* ************************************** REGULATORY INFORMATION FEDERAL REGULATIONS CERCLA, 40 CFR 302 The material does not to the Act. contain ingredient(s) subject SUPERFUND AMENDMENTS AND REAUTHOR 1ZATION ACT OF 1986, TITLE III - SECTIONS 302, 304, 311, 312, 313 SECTION 302/304 - Extremely Hazardous Substances, 40 CFR 355 The material does not contain extremely hazardous substances at greater than l.OX concentration; however, it is possible that this material may contain extremely hazardous substances at a lower concentration so that a large enough spill could warrant an Emergency Release Report under Section 304. SECTION 311/312 - MSDS and Chemical Inventory Reporting Requirements, 40 CFR 370 The material should be reported under the following EPA hazard categories: x Immediate (Acute Health Hazard) Delayed (Chronic Health Hazard) x Fire Sudden Release of Pressure SAL 000006405 05-Feb-90 Conoco Material Safety Data Sheet Page 6 MSDS No: GA5C005C (REGULATORY INFORMATION - CONTINUED) C PO 38 Reactive Not Applicable Note: See the Hazard Determination Section for the concentration of any ingredients classified as hazardous by OSHA. SECTION 313 - List of Toxic Chemicals, 40 CFR 372 The material does not contain chemica1(s) at a level of l.OX or greater (0.1X for carcinogens) on the list of Toxic Chemicals and subject to toxic chemical release reporting requirements. TOXIC SUBSTANCES CONTROL ACT (TSCA), 40 CFR 710 The material is in the TSCA Inventory of Chemical Substances (40 CFR 710) and/or is otherwise in compliance with TSCA. RESOURCE CONSERVATION AND RECOVERY ACT (RCRA), 40 CFR 261, SUBPART C AND D The material, when discarded or disposed of, is not specifically listed as a hazardous waste in Federal regulations; however, it could be considered hazardous if it meets criteria for being toxic, corrosive, ignitable or reactive according to U.S. EPA definitions (40 CFR 261). Additionally, it could be designated as hazardous according to state regulations. This material could also become a hazardous waste if it is mixed with or comes in contact with a listed hazardous waste. If such contact or mixing occurs, check 40 CFR 261 to determine whether it is a hazardous waste. If it is a hazardous waste, regulations 40 CFR 262, 263, 264 and 268 may apply. FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 116, Section 311 The material contains the following ingredient(s) which is considered hazardous if spilled in navigable waters. Ingredient Petroleum Hydrocarbon Reportable Quantity Film or sheen upon or discoloration of the water surface or adjoining shoreline HAZARDOUS MATERIALS TRANSPORTATION REGULATIONS, 49 CFR 171-170 The material does not contain mgredient(s) subject to the Regulations. STATE REGULATIONS CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT SAL 000006406 05-F eb-90 Conoco Material Safety Data Sheet Page 7 MSDS No: GASC005 (REGULATORY INFORMATION - CONTINUED) C p 0 38 OF 1986 ("PROPOSITION 65") The material does not contain ingredient(s) subject to the Act. PENNSYLVANIA WORKER AND COMMUNITY RIGHT TO KNOW ACT To the best of our knowledge the material is not sold or produced m Pennsylvania. Please notify Conoco at the telephone number noted below if the material results m PennsyIvanla commerce. ************#***#***#4**t****##***t**4*#4*4 The above data are based on tests, experience, and other information which Conoco believes reliable and are supplied for informational purposes only. However, some ingredients may have been purchased or obtained from third-party manufactures. In these instances, Conoco, i good faith, relies on information provided by those third parties. Since conditions of use are outside our control, CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM USE OF THE ABOVE DATA. NOTHING CONTAINED HEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, TH MATERIAL DESCRIBED, OR ITS USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. Date of latest Revision Responsibility for MSDS : 89/12/07 : Env. & Occ. Health Services Conoco Inc. PO Box 2197 Houston, TX 77252 713-293-5550 SAL 000006407 distributed by MATERIAL SAFETY DATA 7558 NFPADe.iwSSpai?FlCEBOX MONOSOOIUM PHOSPHATE M0N0S0R8 (R) M0N0S03IUM PHOSPHATE XP-4 ( R) FEED SUPPLEMENT NEW ORLEANS. LA. DEGREE o/TJ&SPHONE 504 7 EMERGENCY TELEPHONES: EXTREME HIGH MODERATE SLIGHT INSIGNFICANT PLANTS: (913) 749-8103 LAWRENCE/ KS (231) 541-4171 CARTERET/ NJ CHEMTREC: (8333 424-9303 TRANSPORTATION MEDICAL': (3D3) 595-9048 ROCKY MTN (REDI S228 REACTIVITY (YELLOW) REVISION: 2 EFFECTIVE: 05727/87 PRINTED: 10/12/87 PREPARED FOR USE BY....... AUTO CHLOR 2801 PEACH STREET NEW ORLEANS LA ........ .................... ........ IDENTIFICATION INFORMATION PROVIDES BY..: FMC CORPORATION 2030 MARKET STREET PHILADELPHIA/ PA 19103 70185 ..................... .......................... ; ^HTPPTMG NAHF - DOT......: TATI; IMC3.. F n 9 Mil 1 1 - - ........ ..................... ! rucurrn famti v- SODIUM PHOSPHATE/ MONOBASIC; MONOSOOIUM PHOSPHATE MONOSOOIUM PHOSPHATE MONOSODIUM PHOSPHATE NAH2P04 PHOSPHATE MSP PRECAUTIONARY INFORMATION PRECAUTIONARY STATEMENT..: (PLEASE USE THIS STATEMENT TO SATISFY THE IN-PLANT LABELING REQUIREMENTS OF THE OSHA HAZARD COMMUNICATIONS STANDARD 29CFR 191 3.1 2033 NO PRECAUTIONARY STATEMENT REQUIRED. MONOSOOIUM PHOSPHATE/ HONOSORB <R)/ AND XP-4 (R) WERE NOT FOUND TO BE HAZARDOUS OSHA CRITERIA. BY r c h aud rnuDnu;ur. .... PERCENT CASA : 100 : 7558-80-7 -------1 :8 a I a :S a a a ja a a rN a a t ra )a :E j a >a SAL 000006*08 PAGE 31 CS228 -FMC MATERIAL SAFETY DATA 7558 30 7 NFPA Designation 704 MONOS 00IUM PHOSPHATE M0N0S0RB (R> MONOSDDIUM PHOSPHATE XP-A <R> FEEO SJPPLEHENT degree of hazard EMERGENCY TELEPHONES : 4 = EXTREME 3 = HIGH 2 = MODERATE i = Slight 0 = INSIGNFICANT PLANTS: (913) 749-8193 LAWRENCE/ KS <201) 5*1-4171 CARTERET/ NJ CHEMTREC: (630) 424-9300. TRANSPORTATION MEDICAU: (303) 595-9048 ROCKY MTN FLAMMABILITY (RED> REACTIVITY IYELLOW1 SPECIAL HAZARD REVISION: 2 EFFECTIVE: 05/27/87 PRINTED: 10/12/87 PHYSICAL- DATA ------------------. MFI ITT M Z PH T NT . - _____ BOILING POINT...-...................... : VAPOR PRESSUR: VAPOR DENSITY (AIR 1>..: ROOM TEMPERATURE APPEARANCE AND STATE: ODOR. . . ............... ... SPECIFIC GRAVITY (H20 -1 > : SOLUBILITY IN H20 X BY WT: X VOLATILES BY VOLUME....: EVAPORATION RATE (BUTYL ACETATE * 1 ).: PH (AS IS)............ .. .......................... PH (IX SOLUTION)............................ H20/1 80C NOT APPLICABLE NON-VOLATILE NON-VOLATILE WHITE GRANULES OR POWDER NONE BULK DENSITY 1.3 G/ML 48 9 25C NON-VOLATILE NON-VOLATILE NOT APPLICABLE 4.5 .............. FIRE#- EXPLOSION AND REACTIVITY DATA ------ FLASH POINT............................... AUT01GNITION TEMPERATURE.: FLAMMA9LE LIMITS UPPER..: (AIR) LOWER: EXTINGUISHING MEDIA................ .. SPECIAL' FIREFIGHTING.............: PROCEDURES OEGREE OF FIRE AND EXPLOSION HAZARD STABILITY......................................... ... HAZAR03U5 POLYMERIZATION.: CONDITIONS TO AVOID......: MAJOR CONTAMINANTS THAT..: CONTRIBUTE TO INSTABILITY INCOMPATIBILITY.......................... HAZARDOUS DECOMPOSITION..: PRODUCTS NON NON NOT NOT NOT NOT COMBUSTIBLE COMBUSTIBLE APPLICABLE APPLICABLE APPLICABLE APPLICABLE NONE STABLE WILL NOT NONE NONE OCCUR NONE NONE S*L 000006409 PAGE 02 S225 -FMC MATERIAL SAFETY DATA 7 558 50 7 NFPA Designation 704 H0M0S0DIUM PHOSPHATE M0M0S0RB (R) M0M0S0DIUM PHOSPHATE XP-A (R> FEE0 SUPPLEMENT 6 ME RGENCY TELEPHONES: 4 = EXTREME 3 = HIGH 2 - MODERATE l = SLIGHT 0 = INStGNFTCANT PLANTS: (915) 749-8103. LAWRENCEs KS (231) 541-4171 CARTERET/ NJ CHEHTREC: (8333 424-9303 TRANSPORTATION MEDICAL*: (333) 5 ? 5-9 048 ROC K V MTN HEALTH (BLUE) < FLAMMABILITY (RED) 00 SPECIAL HAZARD REACTIVITY . (YELLOW) REVISION EFFECTIVE: 05/27/87 PRINTED: 10/12/87 ROUTES OF EXPOSURE EYE CONTACT SKIN CONTACT. SKIN ABSORPTION INHALATION............. INGESTION................ MINIMAL IRRITANT TO UNWASHED EYES; PRACTICALLY NON-IRRITATING TO WASHEO EYES (RABBIT). SOURCE: FHC STUDY 186-923 DATE: 1986 NO PUBLISHED DATA NQ PUBLISHED DATA NO PUBLISHED OATA NO SIGNIFICANT HAZARD EXPECTED. SOURCE: FED. REG. 44(244): 74854 DATE: 1979 'EXPOSURE LIMITS NONE PROMULGATED * EFFECTS OF OVEREXPOSURE ACUTE EXPOSURE............................ NO HUMAN DATA AVAILABLE. ANIMAL EYE IRRITATION STUDIES NOTE THIS MATERIAL IS A MINIMAL IRRITANT TO UNWASHED EYES AND NON-IRRITANT TO WASHEO EYES. CHRONIC EXPOSURE.... ...HUMAN INDUSTRIAL EXPERIENCE HAS SHOWN NO SIGNIFICANT INHALATION HAZARD OR SKIN IRRITATION WHEN GOOD PERSONAL HYGIENE PRACTICES ARE FOLLOWEO. EHERCENCV AMO FIRST AID PROCEDURES EYES................ SKIN................ INHALATION INGESTION. DECONTAMINATION PROCEDURE: FLUSH THOROUGHLY WITH WATER. IF IRRITATION OCCURS AND PERSISTS* OBTAIN MEDICAL ATTENTION. WASH OFF WITH WATER. REMOVE FROM EXPOSURE. RINSE MOUTH WITH WATER. GIVE WATER TO CAUSE OCCURS/ OBTAIN MEDICAL ATTENTION. ................. WASH WITH WATER. SAL 0000064-1 PAGE 33 GS 2 28 -FMC MATERIAL SAFETY OATA 7 55 3 33 7 NFPA Designation 704 MONOS ODIUM PHOSPHATE HONOSORB (R) M0N0S0DIUM PHOSPHATE XP-A (R* FEED SJPPLEHENT EMERGENCY TELEPHONES: DEGREE OF HAZARD 4 = EXTREME 3 = HIGH 2 = MODERATE 1 r SLIGHT O = INSIGNFICANT HEALTH (SLUE) PLANTS: (915) 749-8103 LAWRENCE/ KS (201) 511*4171 CARTERET/ NJ CHEHTREC <8330 424-9300 TRANSPORTATION MEDICAL': (335) 595-9048 ROC K Y MTN FLAMMA8ILITV (REOt o^ 3 SPECIAL HAZARD REACTIVITY . (YELLOW) REVISION: 2 EFFECTIVE: 05/27/87 PRINTED: 10/12/87 naiiBBauBaisnaMana- EMERGENCY AND FIRST AZO PROCEDURES NOTES TO PHYSICIAN................... .. INGESTION OF LARGE DOSE (E.G. 20G) MAY CAUSE NAUSEA AND VOMITING. IF VOMITING IS NOT SPONTANEOUS/ 00 NOT INOUCE. PHOSPHATES ARE LAXATIVES. TREATMENT IS SYMPTOMATIC AND SUPPORTIVE. ----- --------------- SPECIAL PROTECTION VENTILATION REQJIRENENTS.: RECOMMENDED PERSO NALL .: PROTECTIVE EQJIPHENT RESPIRATORY................... ... EYES.................................... GLOVES....................... ... SPECIAL CLOTHING..: AND EQUIPMENT NO SPECIAL REQUIREMENT NO SPECIAL REQUIREMENT USE NIOSH/HSHA APPROVED RESPIRATORY PROTECTION WHEN AIRBORNE DUST IS EXPECTED. WEAR CHEMICAL GOGGLES/ WHEN AIRBORNE IS EXPECTED. NO SPECIAL REQUIREMENT NO SPECIAL REQUIREMENT DUST T--- R S a a a a ia a a a iI aj STORAGE AND HANDLING - (PLEASE USE THIS STATEMENT TO SATISTY THE IN-PLANT LABELING REQUIREMENTS OF THE 0SHA HAIARD COMMUNICATIONS STANDARD 29CFR 1913.12033 USE NIOSH/MSHA APPROVED RESPIRATORY PROTECTION WHEN AIRBORNE OUST IS EXPECTED. STORE IN DRY AREA/ FOR PRODUCT QUALITY ASSURANCE. ea>n.auaammananubbb DISPOSAL# SPILL (SR R.EM PROCEDURES PROCEDURE FOR RELEASE....: OR SPILL WASTE DISPOSAL METHOD....: MATERIAL SHOULD BE SWEPT UP FOR SALVAGE OR 01S P OS AL IF MATERIAL CAN NOT BE SALVAGED/ A METHOD OF DISPOSAL IS IN A LANDFILL IN ACCORDANCE WITH ALL LOCAL/ STATE/ ANO FEDERAL REGULATIONS. SAL 000006411 PAGE 34 ** -FMC MATERIAL SAFETY DATA 7 558 30 7 NFPA Designation HOMOSODIUM PHOSPHATE MONOSORB (R) H0M0S00ZUM PHOSPHATE XP-A {R > FEED SJPPLEHEN f DEGREE Of HAZARO EMERGENCY TELEPHONES: * - EXTREME 3 - HIGH 2 - MOOERATE t ` SLIGHT 0 = INSIGHFICANT PLANTS: (913) 749-B 103 LAWRENCE/ KS (201) 541-4 171 CARTERET/ NJ CHEMTREC: <630* 424-9 303. TRANSPORTATION MEDIC ALU (3D3) 5?5-9 048 ROCKY MTN flammability (RED) HAZARO REVISION: 2 EFFECTIVE: 05/27/87 PRINTED: 1 0/1 2/87 TRANSPORTATION DATA DOT PROPER SHIPPING NAME.: DOT CLASSIFICATION.......: DOT LABELS............................... ... DOT MARKING................. .. DOT PLACARD................................... .. UN NUMBER.................................... HAZARDOUS SU8ST4NCE/RQ. 49 STCC NUMBER.....: EMERGENCY ACCIDENT PRECAUTIONS AND PROCEDURE: PRECAUTIONS TO 3E TAKEN..: IN TRANSPORTATION CMA CHEHCARO NUMBER............... TYPE PACKAGES.................. ................. OTHER SHIPPING IDS.................. MONOSODIUM PHOSPHATE NOT REGULATED NOT REQUIRED NOT REQUIRED NOT REQUIRED NONE NOT LIST60 NONE NOT HAZARDOUS BY OSHA CRITERIA; ABOVE FOR RELEASE OR SPILL. NONE NONE MULTIWALL PAPER BAGS. NONE SEE INSTRUCTIONS ADDITIONAL REGULATORY INFORM ATI DM MATERIAL IS REPORTED IN EPA T SCA INVENTORY LIST? YES MATERIAL IS LISTED AS A CARCINOGEN/POTENTIAL CARCINOGEN IN FOLLOWING NTP ANNUAL REPORT... ? NO I ARC MONOGRAPHS..... ? NO OSHA 29CFR PART 1910 SUBPART Z ? NO FDA GRAS LIST; PERMITTED IN FOOD. USDA PERMITTED IN MEATS. SAL 000006412 PAGE 05 ri^S BETZ PROCESS |W| CHEMICALS, INC P.0. BOX 4300 The Woodlands, Texas 77367 (713) 367-2442 MATERIAL SAFETY DATA SHEET (PAGE 2 OF 3) ^ S 3 64 PRODUCT: PHILMPLUS 5K10 SECTION 4-------------------------------- HEALTH HAZARD EFFECTS------------------ ------------------ -............ ACUTE SKIN EFFECTS *** PRIMARY ROUTE OF EXPOSURE MODERATELY IRRITATING TO THE SKIN,MAY CAUSE DERMATITIS. ACUTE EYE EFFECTS *** SEVERE IRRITANT TO THE EYES ACUTE RESPIRATORY EFFECTS *** PRIMARY ROUTE OF EXPOSURE VAPORS,GASES,MISTS OR AEROSOLS MAY CAUSE IRRITATION TO UPPER RESPIRATORY TRACT.PROLONGED EXPOSURE MAY CAUSE DIZZINESS AND HEADACHE. CHRONIC EFFECTS OF OVEREXPOSURE*** PROLONGED OR REPEATED EXPOSURE MAY CAUSE CNS DEPRESSION; MAY CAUSE DEFATTING-TYPE DERMATITIS. MEDICAL CONDITIONS AGGRAVATED *** NOT KNOWN SYMPTOMS OF EXPOSURE *** EXCESSIVE DERMAL EXPOSURE CAUSES DEFATTING AND DRYING OF SKIN;EXCESSIVE INHALATION OF VAPORS CAUSES DIZZINESS.HEADACHE AND NAUSEA. SECTION 5----------------------------------FIRST AID INSTRUCTIONS----------------------------------- ---------- SKIN CONTACT*** REMOVE CONTAMINATED CLOTHING.WASH EXPOSED AREA WITH A LARGE QUANTITY OF SOAP SOLUTION OR WATER FOR 15 MINUTES EYE CONTACT*** IMMEDIATELY FLUSH EYES WITH WATER FOR 15 MINUTES.IMMEDIATELY CONTACT A PHYSICIAN FOR ADDITIONAL TREATMENT INHALATION EXPOSURE*** REMOVE VICTIM FROM CONTAMINATED AREA TO FRESH AIR.APPLY APPROPRIATE FIRST AID TREATMENT AS NECESSARY INGESTION*** DO NOT FEED ANYTHING BY MOUTH TO AN UNCONSCIOUS OR CONVULSIVE VICTIM DO NOT INDUCE VOMITING.IMMED,CONTACT PHYSICIAN.DILUTE CONTENTS OF STOMACH USING 3-4 GLASSES MILK OR WATER --------- SECTION 6---------------------- SPILL,DISPOSAL AND FIRE INSTRUCTIONS------------------ SPILL INSTRUCTIONS*** VENTILATE AREA,USE SPECIFIED PROTECTIVE EQUIPMENT.CONTAIN AND ABSORB ON ABSORBENT MATERIAL.PLACE IN WASTE DISPOSAL CONTAINER. THE WASTE CHARACTERISTICS OF THE ABSORBED MATERIAL,OR ANY CONTAMINATED SOIL, SHOULD BE DETERMINED IN ACCORDANCE WITH RCRA REGULATIONS. REMOVE IGNITION SOURCES.FLUSH AREA WITH WATER.SPREAD SAND/GRIT. DISPOSAL INSTRUCTIONS*** WATER CONTAMINATED WITH THIS PRODUCT MAY BE SENT TO A SANITARY SEWER TREATMENT FACILITY,IN ACCORDANCE WITH ANY LOCAL AGREEMENT,A PERMITTED WASTE TREATMENT FACILITY OR DISCHARGED UNDER A NPDES PERMIT PRODUCTCAS IS)INCINERATE OR BURY IN APPROVED LANDFILL FIRE EXTINGUISHING INSTRUCTIONS*** FIREFIGHTERS SHOULD WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS(FULL FACE-PIECE TYPE).PROPER FIRE EXTINGUISHING MEDIA: DRY CHEMICAL,CARBON DIOXIDE,FOAM OR WATER $4l 00064i3 mS BETZ PROCESS |w| CHEMICALS, INC P.0. BOX 4300 The Woodlands, Texas 77387 (713) 367-2442 NFPA/HMIS : HEALTH - MATERIAL SAFETY DATA SHEET 24 HOUR EMERGENCY TELEPHONE (HEALTH OR ACCIDENT) (215) 355-3300 65364 DISTRIBUTED: APR-17-1990 PRODUCT : PHILMPLUS 5K10 (PAGE 1 OF 3) EFFECTIVE DATE 05-18-89 PRINTED: 10-Apr-1990 REVISIONS TO SECTIONS: 3 PRODUCT APPLICATION : A BLEND OF FILMING INHIBITORS IN HEAVY AROMATIC NAPTHA. --------- SECTION 1---------------------- HAZARDOUS INGREDIENTS................. ................... INFORMATION ON PHYSICAL HAZARDS, HEALTH HAZARDS, PEL'S AND TLV'S FOR SPECIFIC PRODUCT INGREDIENTS AS REQUIRED BY THE OSHA HAZARD COMMUNICATIONS STANDARD ARE LISTED. REFER TO SECTION 4 (PAGE 2) FOR OUR ASSESSMENT OF THE POTENTIAL ACUTE AND CHRONIC HAZARDS OF THIS FORMULATION. HEAVY AROMATIC NAPHTHA;***CAS#64742-06-9:COMBUSTIBLE LIQUID;IRRITANT(EYE): MANUFACTURERS SUGGESTED EXPOSURE LIMIT:100PPM;PEL:NONE;TLV:NONE. TRADE SECRET INGREDIENT(021);IRRITANT;PEL/TLV:25PPM-C. TSRN 125438 - 5179P TRADE SECRET INGREDIENT(E082);EYE IRRITANT;PEL:NONE;TLV:NONE.THIS CHEMICAL IS NOT ON ANY STATE RIGHT-TO-KNOW LIST. TSRN 125438 - 5065P --------- SECTION 2--------------------- TYPICAL PHYSICAL DATA............... ............................................ - PH: 50% EXTRACT (APPROX.) 9.5 ODOR: AROMATIC FL.PT.(DEG.F): 152 SETA(CC) SP.GR.(70F)OR DENSITY: 7.5LBS/GAL VAPOR PRESSURE(mmHG): ND VAPOR DENSITY(AIR-1): ND VISC cps70F: 11 %SOLUBILITY(WATER): 0 EVAP.RATE: ND WATER-1 APPEARANCE: AMBER-GREEN PHYSICAL STATE: LIQUID FREEZE P0INT(DEG.F): <-30 --------- SECTION 3--------------------- REACTIVITY DATA--------------------- ---------- ---------------------- -------- STABLE.MAY REACT WITH STRONG OXIDIZERS.DO NOT CONTAMINATE.BETZ TANK CLEAN-OUT CATEGORY 'B' THERMAL DECOMPOSITION (DESTRUCTIVE FIRES) YIELDS ELEMENTAL OXIDES. SAL 000006414 ntS BETZ PROCESS |w| CHEMICALS, INC P.0. BOX 4300 The Woodlands, Texas 77387 (713) 367-2442 MATERIAL SAFETY DATA SHEET (PAGE 3 OF 3) 364 PRODUCT: PHILMPLUS 5KL0 --------- SECTION 7---------------------- SPECIAL PROTECTIVE EQUIPMENT---------------- -----------------USE PROTECTIVE EQUIPMENT IN ACCORDANCE WITH 29CFR SECTION 1910.132-134. USE RESPIRATORS WITHIN USE LIMITATIONS OR ELSE USE SUPPLIED AIR RESPIRATORS. VENTILATION PROTECTION*** ADEQUATE VENTILATION TO MAINTAIN AIR CONTAMINANTS BELOW EXPOSURE LIMITS RECOMMENDED RESPIRATORY PROTECTION*** IF VENTILATION IS INADEQUATE OR SIGNIFICANT PRODUCT EXPOSURE IS LIKELY, USE A RESPIRATOR WITH ORGANIC VAPOR CARTRIDGES. RECOMMENDED SKIN PROTECTION*** NEOPRENE GLOVES WASH OFF AFTER EACH USE.REPLACE AS NECESSARY RECOMMENDED EYE PROTECTION*** SPLASH PROOF CHEMICAL GOGGLES ........... SECTION 8...........................STORAGE AND HANDLING PRECAUTIONS STORAGE INSTRUCTIONS*** KEEP DRUMS & PAILS CLOSED WHEN NOT IN USE. KEEP AWAY FROM FLAMES OR SPARKS HANDLING INSTRUCTIONS*** COMBUSTIBLE THIS MSDS COMPLIES WITH THE OSHA HAZARD COMMUNICATION STANDARD HAROLD M. HERSH (ENVIRONMENTAL INF9RMATION COORDINATOR) APPENDIX: REGULATORY INFORMATION THE CONTENT OF THIS APPENDIX REPRESENTS INFORMATION KNOWN TO BETZ ON THE EFFECTIVE DATE OF THIS MSDS. THIS INFORMATION IS BELIEVED TO BE ACCURATE. ANY CHANGES IN REGULATIONS WILL RESULT IN UPDATED VERSIONS OF THIS DOCUMENT. ...TSCA: ALL COMPONENTS OF THIS PRODUCT ARE LISTED IN THE TSCA INVENTORY ...REPORTABLE QUANTITY(RQ) FOR UNDILUTED PRODUCT: TREAT AS OIL SPILL . . . RCRA: IF THIS PRODUCT IS DISCARDED AS A WASTE, THE RCRA HAZARDOUS WASTE IDENTIFICATION NUMBER IS: NOT APPLICABLE ...DOT HAZARD/UN#/ER GUIDE# IS: COMBUSTIBLE LIQUID NAl993/#27 ...THIS PRODUCT CONTAINS THESE CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER OR REPRODUCTIVE TOXICITY: NONE PRESENT IN SIGNIFICANT AMOUNTS ...SARA SECTION 313 CHEMICALS: NONE PRESENT IN SIGNIFICANT AMOUNTS ...SARA SECTION 312 HAZARD CLASS: IMMEDIATE(ACUTE),DELAYED(CHRONIC) AND FIRE ...MICHIGAN CRITICAL MATERIALS: NONE PRESENT IN SIGNIFICANT AMOUNTS NFPA/HMIS : HEALTH - 2 ; FIRE - 2 j REACTIVITY - 0 ; SPECIAL - NONE ; PE - B SAL 000006415 BETZ PROCESS CHEMICALS, INC. P.O. BOX 4300 The Woodlands, Texas 77387 (713) 367-2442 NFPA/HMIS : HEALTH - MATERIAL SAFETY DATA SHEET 24 HOUR EMERGENCY TELEPHONE (HEALTH OR ACCIDENT) PRODUCT : PROCHEM 4H3 (215) 355-3300 GS 365 DISTRIBUTED: APR-17-1990 (PAGE 1 OF 3) EFFECTIVE DATE 01-05-90 PRINTED: 10-Apr-1990 PRODUCT APPLICATION : A BLEND OF NEUTRALIZING AMINES IN WATER. ........... SECTION 1---------------------- HAZARDOUS INGREDIENTS.................................. INFORMATION ON PHYSICAL HAZARDS, HEALTH HAZARDS, PEL'S AND TLV'S FOR SPECIFIC PRODUCT INGREDIENTS AS REQUIRED BY THE OSHA HAZARD COMMUNICATIONS STANDARD ARE LISTED, REFER TO SECTION 4 (PAGE 2) FOR OUR ASSESSMENT OF THE POTENTIAL ACUTE AND CHP.ONIC HAZARDS OF THIS FORMULATION. TRADE SECRET INGREDIENT(018);COMBUSTIBLE:CORROSIVE;IRRITANT; PEL/TLV:3PPM(6PPM-STEL). TSRN 125438 - 5177P TRADE SECRET INGREDIENT(071);COMBUSTIBLE;CORROSIVE;SKIN AND RESPIRATORY SENSITIZER;POTENTIAL LIVER,KIDNEY AND LUNG TOXIN;PEL:10 PPM;TLV:10 PPM. TSRN 125438 - 5196P SECTION 2-------------------------------- TYPICAL PHYSICAL DATA.............................................................. PH: AS IS (APPROX.) 12.7 FL.PT.(DEG.F): >200 SETA(CC) VAPOR PRESSURE(mmHG): ND VISC cps70F: 7.5 EVAP.RATE: <1 ETHER-1 PHYSICAL STATE: LIQUID ODOR: AMINE SP.GR.(70F)0R DENSITY: 8.4LBS/GAL VAPOR DENSITY(AIR=1): ND %SOLUBILITY(WATER): 100 APPEARANCE: COLORLESS TO YELLOW FREEZE POINT(DEG.F): -6 ........... SECTION 3---.............. --REACTIVITY DATA.......................................................................... STABLE.MAY REACT WITH STRONG OXIDIZERS.DO NOT CONTAMINATE.BETZ TANK CLEAN-OUT CATEGORY 'B1 THERMAL DECOMPOSITION (DESTRUCTIVE FIRES) YIELDS ELEMENTAL OXIDES. SAL 000006416 BETZ PROCESS CHEMICALS, INC. P.O. BOX 4300 The Woodlands, Texas 77387 (713) 307-2442 MATERIAL SAFETY DATA SHEET (PAGE 2 OF 3) 6S365 PRODUCT: PROCHEM 4H3 --------- SECTION 4---------------------- HEALTH HAZARD EFFECTS------------ ---------------- --------------------ACUTE SKIN EFFECTS *** PRIMARY ROUTE OF EXPOSURE SEVERE IRRITANT TO THE SKIN.ABSORBED BY SKIN.SKIN SENSITIZER. ACUTE EYE EFFECTS *** CORROSIVE TO THE EYES ACUTE RESPIRATORY EFFECTS *** PRIMARY ROUTE OF EXPOSURE VAPORS.GASES,MISTS AND/OR AEROSOLS CAUSE IRRITATION TO UPPER RESPIRATORY TRACT CHRONIC EFFECTS OF OVEREXPOSURE*** PROLONGED OR REPEATED EXPOSURES MAY CAUSE LIVER AND KIDNEY TOXICITY AND MAY CAUSE LUNG DAMAGE. MEDICAL CONDITIONS AGGRAVATED *** NOT KNOWN SYMPTOMS OF EXPOSURE *** INHALATION MAY CAUSE EYE,NOSE,THROAT AND LUNG IRRITATION AND POSSIBLE RESPIRATORY SENSITIZATION OR ASTHMA;SKIN CONTACT MAY CAUSE MODERATE IRRITATION TO SEVERE BURNS AND SENSITIZATION OR ALLERGIC REPONSE (RASH). PRECAUTIONARY STATEMENT BASED ON TESTING RESULTS *** MAY BE TOXIC IF ABSORBED THROUGH SKIN. --------- SECTION 5-................ ......... FIRST AID INSTRUCTIONS................... -................................ SKIN CONTACT*** REMOVE CLOTHING.WASH AREA WITH LARGE AMOUNTS OF SOAP SOLUTION OR WATER FOR 15 MIN.IMMEDIATELY CONTACT PHYSICIAN EYE CONTACT*** IMMEDIATELY FLUSH EYES WITH WATER FOR 15 MINUTES.IMMEDIATELY CONTACT A PHYSICIAN FOR ADDITIONAL TREATMENT INHALATION EXPOSURE*** REMOVE VICTIM FROM CONTAMINATED AREA.APPLY NECESSARY FIRST AID TREATMENT.IMMEDIATELY CONTACT A PHYSICIAN. INGESTION*** DO NOT FEED ANYTHING BY MOUTH TO AN UNCONSCIOUS OR CONVULSIVE VICTIM DO NOT INDUCE VOMITING.IMMED.CONTACT PHYSICIAN.DILUTE CONTENTS OF STOMACH USING 3-4 GLASSES MILK OR WATER --------- SECTION 6................... ---SPILL,DISPOSAL AND FIRE INSTRUCTIONS------------------SPILL INSTRUCTIONS*** VENTILATE AREA,USE SPECIFIED PROTECTIVE EQUIPMENT.CONTAIN AND ABSORB ON ABSORBENT MATERIAL.PLACE IN WASTE DISPOSAL CONTAINER. THE WASTE CHARACTERISTICS OF THE ABSORBED MATERIAL,OR ANY CONTAMINATED SOIL, SHOULD BE DETERMINED IN ACCORDANCE WITH RCRA REGULATIONS, FLUSH AREA WITH WATER. WET AREA MAY BE SLIPPERY. SPREAD SAND/GRIT. DISPOSAL INSTRUCTIONS*** WATER CONTAMINATED WITH THIS PRODUCT MAY BE SENT TO A SANITARY SEWER TREATMENT FACILITY,IN ACCORDANCE WITH ANY LOCAL AGREEMENT,A PERMITTED WASTE TREATMENT FACILITY OR DISCHARGED UNDER A NPDES PERMIT PRODUCT(AS IS)INCINERATE OR BURY IN APPROVED LANDFILL FIRE EXTINGUISHING INSTRUCTIONS*** FIREFIGHTERS SHOULD WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS(FULL FACE-PIECE TYPE).PROPER FIRE EXTINGUISHING MEDIA: DRY CHEMICAL,CARBON DIOXIDE,FOAM OR WATER i V. S4L 00064I7 'titjSI BETZ PROCESS CHEMICALS, INC P.O. BOX 4300 The Woodlands, Texas 77387 (713) 367-2442 MATERIAL SAFETY DATA SHEET (PAGE 3 OF 3) GS 3 65 PRODUCT: PROCHEM 4H3 --------- SECTION 7................ ..........SPECIAL PROTECTIVE EQUIPMENT.............. -........................ USE PROTECTIVE EQUIPMENT IN ACCORDANCE WITH 29CFR SECTION 1910.132-134. USE RESPIRATORS WITHIN USE LIMITATIONS OR ELSE USE SUPPLIED AIR RESPIRATORS. VENTILATION PROTECTION*** ADEQUATE VENTILATION TO MAINTAIN AIR CONTAMINANTS BELOW EXPOSURE LIMITS RECOMMENDED RESPIRATORY PROTECTION*** IF VENTILATION IS INADEQUATE OR SIGNIFICANT PRODUCT EXPOSURE IS LIKELY, USE A RESPIRATOR WITH ORGANIC VAPOR CARTRIDGES. RECOMMENDED SKIN PROTECTION*** GAUNTLET-TYPE RUBBER GLOVES,CHEMICAL RESISTANT APRON WASH OFF AFTER EACH USE.REPLACE AS NECESSARY RECOMMENDED EYE PROTECTION*** SPLASH PROOF CHEMICAL GOGGLES.FACE SHIELD ........... SECTION 8.......................... STORAGE AND HANDLING PRECAUTIONS................................ STORAGE INSTRUCTIONS*** KEEP DRUMS & PAILS CLOSED WHEN NOT IN USE. PROTECT FROM FREEZING HANDLING INSTRUCTIONS*** ALKALINE. CORROSIVE(EYES) .DO NOT MIX WITH ACIDIC MATERIAL. THIS MSDS COMPLIES WITH THE OSHA HAZARD COMMUNICATION STANDARD HAROLD M. HERSH (ENVIRONMENTAL INFORMATION COORDINATOR)............................................. APPENDIX: REGULATORY INFORMATION THE CONTENT OF THIS APPENDIX REPRESENTS INFORMATION KNOWN TO BETZ ON THE EFFECTIVE DATE OF THIS MSDS. THIS INFORMATION IS BELIEVED TO BE ACCURATE. ANY CHANGES IN REGULATIONS WILL RESULT IN UPDATED VERSIONS OF THIS DOCUMENT. ...TSCA: ALL COMPONENTS OF THIS PRODUCT ARE LISTED IN THE TSCA INVENTORY ...REPORTABLE QUANTITY(RQ) FOR UNDILUTED PRODUCT: 1,082 GALLONS DUE TO ETHYLENE DIAMINE ...RCRA: IF THIS PRODUCT IS DISCARDED AS A WASTE,THE RCRA HAZARDOUS WASTE IDENTIFICATION NUMBER IS: D002-CORROSIVE (PH) ...DOT HAZARD/UN#/ER GUIDE# IS: ORM-E(WHEN CONTAINER > RQ) NA9188/#3i ...THIS PRODUCT CONTAINS THESE CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER OR REPRODUCTIVE TOXICITY: NONE PRESENT IN SIGNIFICANT AMOUNTS ...SARA SECTION 313 CHEMICALS: NONE PRESENT IN SIGNIFICANT AMOUNTS ...SARA SECTION 312 HAZARD CLASS: IMMEDIATE(ACUTE) AND DELAYED(CHRONIC) ...MICHIGAN CRITICAL MATERIALS: NONE PRESENT IN SIGNIFICANT AMOUNTS NFPA/HMIS : HEALTH - 3 ; FIRE - 1 ; REACTIVITY - 0 ; SPECIAL - ALK ; PE - D SAL 000Q06418 SAL 000006419 14Vt* msds mui i/i*/ CHANGE NO.I II7( MATERIAL SAFETY DATA Ftf C6At#*tl ___ victory Affair* Oept. HACN COMPANY ro Bex 1*7 Ami. |A 5*\t PO MM tar tSMI M4________________________________ A*S, U Will SHEET * POt! Ilt-LPA 2ST1S4 HA04 Mnl IMH4 E**r*ney Telephone * CS4` K**k)r Mountain PiltM Ctr7 C9B3) i23-7l* I. PRODUCT IDENTIFICATION CATALOG MO. I UM CAS MO. I MA FORMULA! Mat MfUeibli PRODUCT MAHEt DPD Total Chief In* R*< CHEMICAL HAACl Net *P*llC*bl* CHEMICAL FAMILY! M*t applicable Aval* prelangtd #r repaatad eentaet with akin. Da net brepth* duet. Math thereuphly after handling. PROTECTIVE EQUIPMENT i adoauata xent I letlen, aafety flatiat, dlapeaabl lev** II. INGREDIENTS VII. FIRST AID Offanlc Salt CTrad# Mont) PCTi <5* CAS NO.i CenfIdentlalSARA! MOT LISTED TLVi Nat aatabllahad PELt Nat aatabllahad HAZARD! Taalalty unknown Sodlua Fheaphata, Olbatle, Anhydrout PCTi <S CAS NO.l 7SSS-79--4 SARA! NOT LISTED TLVi Nat aatabllahad -- PEL! Net aatabtlahed HAZARD! Madarataly texlai aay eeua* irrltatlan Poteaalea ledlda PCTi <91 CAS NO.1 701-I1'I TLVi Hat aatabllahad HAZARD! Hay aawta Irrltatlan SARA! HOT LISTED PEli Hat aatabllahad EYE AND SKIN CONTACT! laaedletely fluah eye* with water for IS alnwt* phyalelen. Reaeve eentaalnated elathln*. Hath akin with ae*p and Pi watar. IMOESTIQNt Dive l#r* auantltla* af witar er aiik. Call physician laaedletely. INHALATIONS Reaeve te freth air. VIII. SPILL AHD DISPOSAL PROCEDURES 1M CASE OF SPILL OR RELEASE! Sweep up pewder. Aveld Prcsthlnf aeterli DItaelv* In water. Fluah dawn the drain with aseea# water. DISPOSE OF IN ACCORDANCE WITH ALL FEDERAL. STATE. AMD LOCAL REOULATIO. XX. TRANSPORTATION DATA DPD Salt (Trada Saaratl PCTi <S CAS MO.i CanfldantlalSARAi HOT LISTED TLVi Mat aataallahad PCLt Mat aatabllahad HAZARD! Madarataly tealei aay eauae ekln aeneltliatlen Other eeapenent PCIt <| CAS MO.I MA TLVi Net applicable HAZARDi Mat ipplleabla SARA! HOT LISTED PEL! Nat applicable Any caapenant *f thlt alature net eeeelfleally llate* <*. "ether Mpen*nt*"l 1* net eeneidered t* preaent a eerelneypn hazard. III. PHYSICAL DATA STATE! aell* APPEARANCE! Wilt! ta pal* Pink powder ODORl Man# SOL UPILI TV IN! NATERi Salable ACIDi Soluble OTTCRi Nat dateralnad bOILSMO POINT! MA *ITIN0 PT.i NO SPEC ORAVlTVi LC pHi Hat deteralned VAPOR PRESSURE! Mat applicable VAPOR DENSITY <#lrl)t MA EVAPORATION RATE! MA *TAl CORROSIVITY - ALUMINUM! HD STEELt NO STABILITY! StPbl* STORAQE PRECAUTIONS! Star* In a eeel, dry. dark laa*. D.O.T. PROPER SHIPPING MAtCi Nat Currently Reavlated HAZARO CLASS! Hat applicable IDi MA I.C.A.O. PROPER SHIPPING MAHEi Nat Currently Refulated HAZARD CLASS! NA ID! NA GROUP! NA I.M.O. PROPER SHIPPING NA*! Net Currently Reavlated HAZARD CLASS! HA IDi NA GROUP! NA X. REFERENCES l> TLV'e Threshold Halt Value* and Blelefleel Ezpeaura tndlca* far I Its*. Aa*rlean Cenrerenee ef Oevariuuntal Induatrtal HyalsMat*. I' Z) Air Centaalnant*. Federel Resteter, Vel. 5d. Ne. 12, Thursday, jam. it, tass. p*. mi-mi. SI ln-h*w*e infaraatlan ) Teehnleal ]udaant SPECIAL MOTEi This product aey enly be used ** an analytical raatant fc datarainptlan ef ehlarlne In watar du* t* reavlraaenta ef tha Taxi* Subetanes* Central Aat (TSCAI. IV. FIRE, EXPLOSION HAZARD AND REACTIVITY DATA w FLASH PT.i Hat applicable METHOD! NA FLAW4ABILITY LIMITS - LOWER! NA UPPER I NA SUSCEPTIBILITY TO SPONTA1COUS VFATIMOl Men* SHOCK SENSITIVITY! Hen* AUTOtQMlTION PT.i NO CXT1HBUISHIN9 MEDIA! water, dry ehealcal, alcehel fees er cerben dioxide FIRE/EXPLOSIOM HAZARDS! Hey ealt tesla fuaee Jn fir* HAZARDOUS DECOMF. PRODUCTS! May bait toxle fuaee af pheipheru* azide*, ledlne, ledin* eeapeunda In fir* OXIDIZER! Ha MTPA Cede*! Health! 1 FIewwebllItyi I Reactivity! b CONDITIONS TO AVOID! Estraa# temperature*. exeea* aelature, exposurs t# 1 IfhtV. V. HEALTH HAZARO DATA THIS PRODUCT MAY BCi irrltatln* te eye* and raaplratary tract, and aay eauae allarfla ekln raaetlan. ACUTE TOXICITY! Madarataly taxi* ROUTES OF eXFOSURei Infaatlan, Inhalattan TARGET ORGANSi Hat detaralnad CHRONIC TOXICITY! Hat detaralned tOUTES OF EXPOSURE! Iniaatlan, Inhalation TARGET ORGANSi Hat detaralnad CANCER INFORMATION! Net deteralned ROUTES OF EXPOSURE! Net deteralned TARGET ORGAASt Hat deteralned OVEREXPOSUtEi Centact aey eeua* Irritation, akin aanaltlzatlen. May eauae ehrente "ledlaa"! akin raah, eeMunetivltl*. runny neae, aneezins, brenehltla, heedaeha, fever, Irritation ef auoaua aeabrenea. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE! All*r*y er aeneltlvlty t* selte of M,M-Dl*thyl-P-Phenyl*n*dlaa|n* VI. PRECAUTIONARY MEASURES SAL 000006420 Avoid eentaet with eye*. THE 1 WOPHAT 1 OH CONTAINED HERE IM IS BASED OH DATA CONSIDERED TO BC ACCURATE. HOWEVER, 1HO WARRANTY IS EXPRESSED OR IMPLIED PtCAPDTW'- THE ACCUP4CV Of THFSE DATA OP TMf prei'IT* -O AF ORTj.wrp rsfl" tht i--r 'tfcrv 1C' HACH CO. 11*9 MATERIAL SAFETY DATA SHEET RUST BLOCK AEROSOL GS516 PAGE : 01 t (045039-0444M -EO016293-SOS1 )jOATE OF ISSUE ! 03/08/90< | SUPERSEDES j 03/08/90 SECTION 1 - GENERAL INFORMATION CHEMICAL NAME 6 SYNONYMS N/A TRADE NAME & SYNONYMS RUST BLOCK AER05OL CHEMICAL FAMILY RUST PREVENTIVE - HEAVY DUTY ^--MIXTURE MANUFACTURERS NAME: NATIONAL CHEMSEARCH DIV. OF NCH CORP. ADDRESS (NUMBER. STREET. CITY, STATE 6 ZIP CODE) BOX 152170 IRVING. TEXAS 75015 PREPARED BY: KELLY SEAL5/T.S.CHEMIST ! PRODUCT CODE NUMBER ! EMERGENCY TELEPHONE NUMBER 5081 214-438-1381 SECTION II- HAZARDOUS INGREOIENTS THE HAZARDS PRESENTED BELOW ARE THOSE OF THE INDIVIDUAL COMPONENTS AS THE PROOUCT MIXTURE HAS NOT BEEN TESTEO AS A WHOLE. CHEMICAL NAME (INGREDIENTS) [ ALIPHATIC PETROLEUM DISTILLATE 1.1.1-TRICHLOROETHANE PROPANE ISOBUTANE HAZARD COMBUST. IRRITANT ASPHYXIANT FLAMM. | TLV* lOOPPM 3SOPPM N/E N/E 1 ! PEL" 5O0PPM 1 350PPM 100OPPM N/E ! CASA 8052-32-41 71-55-6 74-98-6 75-28-5 SECTION IIA - NON'-HAZARDOUS INGREDIENTS NON-HAZARDOUS INGREDIENT NAMES AND CAS NUMBERS ARE PROTECTED UNDER NO TRADE (CONTINUED) SECRET REGISTRY A RUST BLOCK AEROSOL SECTION IIA - NON-HAZARDOUS INGREDIENTS 409363-5283P SECTION III - PHYSICAL DATA BOILING PT.(FAHRENHEIT) j 160 | SPEC GRAVITY (H20-1) :1.010 VAPOR PRES5URE (MM HG). ! lOO | COLOR BLUE-BROWN VAPOR DENSITY (AIR-O [4.2 [ ODOR CHLOR. HYDROCARB PH 9 100% [N/A | CLARITY HAZY PERCENT. VOLATILE BY VOLUME (%) SOLUBILITY IN WATER l77 < [ EVAPORATION RATE J (BU AC 1 ) | NEGLIGIBLE '.0.75 [ VISCOSITY [ VISCOUS PAGE : 02 SECTION IV - FIRE AND EXPLOSION HAZARD FLASH POINT (METHOD USEO) 150 F. T.C.C. FLAMMABLE LIMITS LEL N/A EXTINGUISHING MEDIA `ALCOHOL " X<--FOAM <--FDAM X<--CC2 DRY X<-- CHEMl CAL <--SWPARTAEYR SPECIAL FIRE FIGHTING PROCEDURES AS WITH ALL FIRES INVOLVING CHEMICALS. USE SELF-COMNTAINED BREATHING APPARATUS AND FULL PROTECTIVE GEAR. UEL Jn/A <--OTHER UNUSUAL FIRE 4 EXPLOSION HAZARDS SPRAY AEROSOL CONTAINERS WITH WATER TO COOL THEM AND PREVENT RUPTURING UNDER SPECIFIC CONDITIONS PHOSGENE CAN FORM. FLAME EXTENTION: 12* BURNBACK : NONE LEVEL 2 AEROSOL (NFPA SOB) NFPA HAZARD RATING (0INSIGNIFICANT.1 *SL IGHT;2"MODERATE:3HIGH4aEXTREME) 3 <--HEALTH 2 <--FLAMMABILITY O <--fiEAtTIVITY <--SPECIAL SECTION V - HEALTH HAZARO DATA SAL 000006421 f* 6S516 (CCpTINUtO) EU5T BLOCK AEROSOL SECTION V - HEALTH HAZARD DATA PAGE : 09 THRESHOLD LIMIT VALUE : NOT ESTABLISHED FOR MIXTURE. SEE SECTION II. EFFECTS OF OVEREXPOSURE . 4CUTE . ,5,,0RT T,,,, ex,osu(ie) 8aSg5?gaKESSh*B8uKS,HIS,it D?Wmh through SKIN IS NOT A SIGNIFICANT ROUTE OF EXPOSURE - Ml LDLV IRRITATING ON CONTACT. INGESTION IS AN UNLIKELY ROUTE OF EXPOSURE BECAUSE THE PRODUCT IS AN AEROSOL. INGESTION OF SMALL QUANTITIES IS NOT LIKELY TO BE TOXIC. OVEREXPOSURE TO EYES CAN CAUSE MILD IRRITATION. BUT NOT CORNEAL INJURY LIKELY. _ CHRONIC . (LONG TERM EXPOSURE) INHALATION If THE MAJOR ROUTE OF EXPOSURE - LOW SYSTEMIC TOXICITY: ACUTE EXPOSURES IN THE 1000 PPM RANGE CAUSE NARCOSIS. PROLONGED 6R REPEATED SKIN CONTACT CAN CAUSE DERMATITIS THROUGH DEFATTING OF SKIN. XN EVES. OVEREXPOSURE MAY CAUSE CONJUNCTIVITIS. PRIMARy"r0UTE OF ENTRY: X<-- INHALATION <-- INGESTION <-* ABSORPTION EMERGENCY A FIRST AID PROCEDURES MOVE TO* FRESH^A?R AND TREAT SYMPTOMATICALLY. IS 01FF1 CULT. GIVE ARTIFICIAL RESPIRATION IF GET MEDICAL HELP. GIVE OXYGEN IF BREATHING BREATHING STOPS. FLUSH WITH WATERCh6l0ING EYELIDS APART FOR 15 MINUTESIF IRRITATION PERSISTS. SEE A PHYSICIAN REMOVE CONTAMINATED CLOTHING AND FLUSH EXPOSED AREAS WITH WATER FOR 5 TO lO MINUTES. ...................................................................................................................... ....................... ........... IF SWALLo5IT,0D0'N0T INDUCE VOMITING. GIVE LARGE QUANTITIES OF WATER OR CITRUS JUICE IF AVAILABLE. SEEK MEDICAL ATTENTION IMMEDIATELY. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. "'"'NOTES TO PHYSICIAN : BECAUSE RAPID ABSORPTION MAY OCCUR THROUGH LUNGS. THE OECISION OF WHETHER TO INDUCE VOMITING OR NOT SHOULD BE MAOE BY A PHYSICIAN. IF LAVAGE IS PERFORMED. SUGGEST ENDOTRACHEAL AND/OR ESOPHAGEAL CONTROL. DANGER MUST BE WEIGHED AGAINST TOXICITY. NO SPECIFIC ANTIOOTE. SUPPORTIVE CARE. TREATMENT BASED ON JUDGMENT OF THE PHYSICIAN IN RESPONSE TO REACTIONS OF THE PATIENT. SECT I ON VI - TOXICITY INFORMATION PRODUCT CONTAINS CHEMICAL LISTED AS CARCINOGEN OR POTENTIAL CARCINOGEN BY: IARC <--YES NTP <-- YES DSHA <--VES ACGIH <--YS OTHER <--YES X<--NC X<--NO X<--NC X<--NO X<--NO (CONTINUED) RUST BLOCK AEROSOL SECTION VI - TOXICITY INFORMATION PAGE : 04 1.1.1 TRICHLOROETHANE OftL-HMN TOLO: 670MG/KG TFX: CN 3. IHL-HMN TCLO: 920PPM/MG TFX: CSN 3. ORL-RAT LDSO: 10.300 MG/KG 3. ALIPHATIC PETROLEUM DISTILLATE EYE-HMN 470PPM/15 MINUTES 3. UNK-HMN TCLO: 1470MG/KG 3. IPR-RAT LOLO: 056OMG/KG 3. THIS INGREDIENT MAY CONTAIN CONTAMINENTS WHICH ARE LISTED BY CALIFORNIA PROPOSITION 65 AS CARCINOGENS. SECTION VII - REACTIVITY DATA STABILITY lX<--STABLE <--UNSTABL CONDIDTIONS TO AVOID AVOID OPEN FLAMES OR OTHER HIGH TEMPERATURE SOURCES WHICH INDUCE THERMAL DECOMPOSITION. XNCOMPATIBILITV (MATERIALS TO AVOID) N/A hazardous decomposition products CAN AT DECOMPOSITION AND TEMPERATURES CARBON MONOXIDE, HYDROGEN CHLORIDE. PHOSGENE. HAZARDOUS WILL NOT j X <--OCCUR MAY <--OCCUR CONDITIONS TO AVOID polymerization! SECTION VIII - SPILL OR LEAK PROCEDURES STEPS TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED REMOVE ALL SOURCES OF IGNITION. PREVENT FROM ENTERING SEWER OR WATER SOURCES. VENTILATE ENCLOSED SPACE. WEAR RESPIRATOR. CLEANUP (ANY ELECTRIC CLEANING EOUIPMENT - MUST BE EXPLOSION PROOF) OR SOAK UP WITH SAND. COTTON WASTE OR OTHER ABSCRBANT MATERIAL. WASTE DISPOSAL METHOD WRAP EMPTY AEROSOL CANS WITH SEVERAL LAYERS OF NEWSPAPER AND DISCARD IN TRASH. NEUTRALIZING AGENT N/A SAL 000006422 rr ( SECTION IX BUST BLOCK AEROSOL SPECIAL PROTECTION INPORMATIOPAOE : 05 516" RE0U1RED VENTILATION GENERAL EXHAUST IS MORE THAN ADEOU ATE TO PROTECT WORKER PROM EXPOSURE TO LEVELS ABOVE PERMISSIBLE EXPOSURE LIMITS. RESPIRATORY PROTECTION t APPROVED ORGANIC VAPOR-TYPE RE5PIRAT0R REQUIRED IN ABSENCE OF PROPER ENVIRONMENTAL CONTROL. FOR EMERGENCIES. A POSITIVE-PRESSURE BREATHING APPARATUS FOR A FULL-FACE RESPIRATOR WITH AN APPROVED ORGANIC VAPOR CONISTER IS RECOMMENDED. DUE TO AEROSOL PACKAGING. NEED FOR ABOVE IS HIGHLY UNLIKELY. PROTECTIVE GLOVES VITRDNG. NEOPRENE. OR POLYVINYL ALCOHOL (FOR FREOUENT OR PROLONGED CONTACT) EYE PROTECTION SAFETY GLASSES. IT IS RECOMMENDED THAN AN EYE-WASH STATION BE AVAILABLE. OTHER PROTECTION APRON DEPENDING UPON THE EXTENT AND SEVERITY OF EXPOSURE LIKELY . SECTION X - STORAGE AND HANDLING INFORMATION STORAGE TEMPERATURE j INDOOR 120 F . < --MAX 30 F.< --MIN \ X jHEATED | PRECAUTIONS TO BE TAKEN IN HANDLING & 5TORJNG FOLLOW LABEL DIRECTIONS. OTHER PRECAUTIONS KEEP OUT OF REACH OF CHILDREN. |REFRIGERATEC | OUTDOOR [\ SECTION XI - REGULATORY INFORMATION CHEMICAL NAME C.A.S. NUMBER UPPER X LIMIT 1 . 1 .1-TRICHLORDEThANE 71-55-6 50 THOSE INGREDIENTS LISTED ABOVE ARE SUBJECT TO THE REPORTING REQUIREMENTS OF 313 OF TITLE III OF THE SUPERFUNO AMENDMENTS AND REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372. iF UE (USE EXEMPTION) APPEARS UNOER UPPER X LIMIT. END USERS ARE EXEMPT FROM NOTIFICATION BECAUSE THE PROOUCT IS USED AND LABELED FOR ROUTINE JANITORIAL WORK, OR THE PRODUCT IS USED ANC LABELED FOR FACILITY GROUNDS MAINTENANCE (SUCH AS FERTILIZERS AND HERBICIDES). OR THE PRODUCT IS USED AND / V RUST BLOCK AEROSOL (CONTINUED) SECTION XI - REGULATORY INFORMATION PAGE : 06 LABELED FOR MAINTAINING MOTOR VEHICLES. SECTION XII - TRANSPORTATION * (FOR FUTURE USE) APPLICABLE REGULATIONS <--49 CFR <--IMCO SHIPPING NAME HAZARO CLASS LABELS UNIT CONTAINER OCT SS CONTAINER AEROSOL PROPELLANT< S i <--TAR!FF 6 D <--IATA <--MILlTARY AIR (AFR 71-4) | ID NUMBER ) REPORT OTY ! LIMITED OTY ! NET EXPLOSIVE WT. 5ECTI0N XIII - REFERENCES 1 . VENDOR'S MSDS. 2. THRESHOLD LIMIT VALUE FOR CHEMICAL SUBSTANCES IN THE WORK ENVIRONMENT. 2ND EDITION. ACGIH. 1985. 3. NICSH REGISTRY OF TOXIC EFFECTS DF CHEMICAL SUBSTANCES 1982. THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CCNSIDEREC ACCURATE IN LIGHT OF CURRENT FORMULATION. HOWEVER. NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THIS DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF. NATIONAL CHEMSEARCH DIV. OF NCH COR. ASSUMES NC RESPONSIBILITY FOR PERSONAL INJURY OR PROPERTY DAMAGE CAUSED BY THE USE . STORAGE : OR DISPOSAL OF THE PRODUCT IN A MANNER NCT RECOMMENDED ON THE K PRODUCT LABEL - USERS ASSUME ALL RISKS ASSOCIATED WITH SUCH UNRECOMMENDED USE. STORAGE. OR DISPOSAL OF THE PRODUCT. SAL 000006423 BETZ PROCESS CHEMICALS, INC P.O. BOX 4300 The Woodlands, Texas 77387 (713) 367-2442 NFPA/HMIS : HEALTH - MATERIAL SAFETY DATA SHEET 24 HOUR EMERGENCY TELEPHONE (HEALTH OR ACCIDENT) (215) 355-3300 C 5? 5 0 5 DISTRIBUTED: APR-17-1990 PRODUCT : EMBREAK 2W122 (PAGE 1 OF 3) EFFECTIVE DATE 12-13-89 PRINTED: 10-Apr-1990 REVISIONS TO SECTIONS: APPENDIX/9 PRODUCT APPLICATION : AN OIL BASED EMULSION BREAKER. SECTION 1 HAZARDOUS INGREDIENTS INFORMATION ON PHYSICAL HAZARDS, HEALTH HAZARDS, PEL'S AND TLV'S FOR SPECIFIC PRODUCT INGREDIENTS AS REQUIRED BY THE OSHA HAZARD COMMUNICATIONS STANDARD ARE LISTED. REFER TO SECTION 4 (PAGE 2) FOR OUR ASSESSMENT OF THE POTENTIAL ACUTE AND CHRONIC HAZARDS OF THIS FORMULATION. HEAVY AROMATIC NAPHTHA;***CAS#64742-06-9:COMBUSTIBLE LIQUID;IRRITANT(EYE) ; MANUFACTURERS SUGGESTED EXPOSURE LIMIT:100PPM;PEL:NONE;TLV:NONE. TRADE SECRET INGREDIENT<162);FLAMMABLE LIQUID;IRRITANT;CNS DEPRESSANT; PEL/TLV:50PPM-C(SKIN). TSRN 125438 - 5224P TRADE SECRET INGRDIENT(372);POTENTIAL EYE,SKIN AND INHALATION IRRITANT ; PEL:400 PPM;TLV:NONE. TSRN 125438 - 5252P --------- SECTION 2---------------------- TYPICAL PHYSICAL DATA......... ...................................-............... PH: 5% EMULSION (APPROX.) FL.PT.(DEG.F): 118 P-M(CC) VAPOR PRESSURE(mmHG): <10 VISC cps70F: 23 EVAP.RATE: ND WATER-1 PHYSICAL STATE: LIQUID 10.7 ODOR: HYDROCARBON SP.GR.(70F)OR DENSITY: 7.8 LBS/GAL VAPOR DENSITY(AIR=1): >1 %SOLUBILITY(WATER): 0 APPEARANCE: AMBER FREEZE POINT(DEG.F): <-30 --------- SECTION 3---------------------- REACTIVITY DATA-------------------------------------------------------------- STABLE.MAY REACT WITH STRONG OXIDIZERS.DO NOT CONTAMINATE.BETZ TANK CLEAN-OUT CATEGORY 'B' THERMAL DECOMPOSITION (DESTRUCTIVE FIRES) YIELDS ELEMENTAL OXIDES. oooo*a4 jtXS BETZ PROCESS CHEMICALS, INC P.O. BOX 4300 The Woodlands, Texas 77387 (713) 367-2442 MATERIAL SAFETY DATA SHEET (PAGE 2 OF 3) PRODUCT: EMBREAK 2WI22 --------- SECTION 4......................--HEALTH HAZARD EFFECTS--............... ---............ ACUTE SKIN EFFECTS *** PRIMARY ROUTE OF EXPOSURE MODERATELY IRRITATING TO THE SKIN.MAY CAUSE DERMATITIS. ACUTE EYE EFFECTS *** SEVERE IRRITANT TO THE EYES ACUTE RESPIRATORY EFFECTS *** PRIMARY ROUTE OF EXPOSURE VAPORS,GASES,MISTS OR AEROSOLS MAY CAUSE IRRITATION TO UPPER RESPIRATORY TRACT.PROLONGED EXPOSURE MAY CAUSE DIZZINESS AND HEADACHE. CHRONIC EFFECTS OF OVEREXPOSURE*** PROLONGED OR REPEATED EXPOSURES MAY CAUSE LIVER AND KIDNEY TOXICITY,MAY CAUSE CNS DEPRESSION,OR MAY CAUSE DEFATTING-TYPE DERMATITIS. MEDICAL CONDITIONS AGGRAVATED *** NOT KNOWN SYMPTOMS OF EXPOSURE *** EXCESSIVE DERMAL EXPOSURE CAUSES DEFATTING AND DRYING OF SKIN;EXCESSIVE INHALATION OF VAPORS CAUSES DIZZINESS .HEADACHE AND NAUSEA. --------- SECTION 5---.................--FIRST AID INSTRUCTIONS-................................ .................... SKIN CONTACT*** REMOVE CONTAMINATED CLOTHING.WASH EXPOSED AREA WITH A LARGE QUANTITY OF SOAP SOLUTION OR WATER FOR 15 MINUTES EYE CONTACT*** IMMEDIATELY FLUSH EYES WITH WATER FOR 15 MINUTES.IMMEDIATELY CONTACT A PHYSICIAN FOR ADDITIONAL TREATMENT INHALATION EXPOSURE*** REMOVE VICTIM FROM CONTAMINATED AREA TO FRESH AIR.APPLY APPROPRIATE FIRST AID TREATMENT AS NECESSARY INGESTION*** DO NOT FEED ANYTHING BY MOUTH TO AN UNCONSCIOUS OR CONVULSIVE VICTIM DO NOT INDUCE VOMITING . IMMED. CONTACT PHYSICIAN. DILUTE CONTENTS OF STOMACH USING 3-4 GLASSES MILK OR WATER --------- SECTION 6---------------------- SPILL, DISPOSAL AND FIRE INSTRUCTIONS...................... SPILL INSTRUCTIONS*** VENTILATE AREA,USE SPECIFIED PROTECTIVE EQUIPMENT.CONTAIN AND ABSORB ON ABSORBENT MATERIAL.PLACE IN WASTE DISPOSAL CONTAINER. THE WASTE CHARACTERISTICS OF THE ABSORBED MATERIAL,OR ANY CONTAMINATED SOIL, SHOULD BE DETERMINED IN ACCORDANCE WITH RCRA REGULATIONS. REMOVE IGNITION SOURCES.FLUSH AREA WITH WATER.SPREAD SAND/GRIT. DISPOSAL INSTRUCTIONS*** WATER CONTAMINATED WITH THIS PRODUCT MAY BE SENT TO A SANITARY SEWER TREATMENT FACILITY,IN ACCORDANCE WITH ANY LOCAL AGREEMENT,A PERMITTED WASTE TREATMENT FACILITY OR DISCHARGED UNDER A NPDES PERMIT PRODUCT(AS IS)- INCINERATE OR BURY IN APPROVED LANDFILL FIRE EXTINGUISHING INSTRUCTIONS*** FIREFIGHTERS SHOULD WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS(FULL FACE-PIECE TYPE).PROPER FIRE EXTINGUISHING MEDIA: DRY CHEMICAL,CARBON DIOXIDE,FOAM OR WATER SAL 000006425 f/S BETZ PROCESS |W| CHEMICALS, INC P.0. BOX 4300 The Woodlands, Texas 77387 (713) 367-2442 MATERIAL SAFETY DATA SHEET (PAGE 3 OF 3) 6S59S PRODUCT: EMBREAK 2W122 --------- SECTION 7---------------------- SPECIAL PROTECTIVE EQUIPMENT----------------------------------USE PROTECTIVE EQUIPMENT IN ACCORDANCE WITH 29CFR SECTION 1910.132-134, USE RESPIRATORS WITHIN USE LIMITATIONS OR ELSE USE SUPPLIED AIR RESPIRATORS. VENTILATION PROTECTION*** ADEQUATE VENTILATION TO MAINTAIN AIR CONTAMINANTS BELOW EXPOSURE LIMITS RECOMMENDED RESPIRATORY PROTECTION*** IF VENTILATION IS INADEQUATE OR SIGNIFICANT PRODUCT EXPOSURE IS LIKELY, USE A RESPIRATOR WITH ORGANIC VAPOR CARTRIDGES. RECOMMENDED SKIN PROTECTION*** NEOPRENE GLOVES WASH OFF AFTER EACH USE.REPLACE AS NECESSARY RECOMMENDED EYE PROTECTION*** SPLASH PROOF CHEMICAL GOGGLES --------- SECTION 8------------ ---------- STORAGE AND HANDLING PRECAUTIONS.......................... -STORAGE INSTRUCTIONS*** KEEP DRUMS & PAILS CLOSED WHEN NOT IN USE. STORE IN COOL VENTILATED LOCATION.STORE AWAY FROM OXIDIZERS HANDLING INSTRUCTIONS*** COMBUSTIBLE. DO NOT USE AROUND SPARKS OR FLAMES. BOND CONTAINERS DURING FILLING OR DISCHARGE WHEN PERFORMED AT TEMPERATURES AT OR ABOVE THE PRODUCT FLASH POINT. THIS MSDS COMPLIES WITH THE OSHA HAZARD COMMUNICATION STANDARD HAROLD M. HERSH (ENVIRONMENTAL INFORMATION COORDINATOR) Vi*T^'*^^,fr'frVr,fr'ftTV'ft*'ft**************'***************************'***A'************* APPENDIX: REGULATORY INFORMATION THE CONTENT OF THIS APPENDIX REPRESENTS INFORMATION KNOWN TO BETZ ON THE EFFECTIVE DATE OF THIS MSDS. THIS INFORMATION IS BELIEVED TO BE ACCURATE. ANY CHANGES IN REGULATIONS WILL RESULT IN UPDATED VERSIONS OF THIS DOCUMENT. ...TSCA: ALL COMPONENTS OF THIS PRODUCT ARE LISTED IN THE TSCA INVENTORY ...REPORTABLE QUANTITY(RQ) FOR UNDILUTED PRODUCT: TREAT AS OIL SPILL ...RCRA: IF THIS PRODUCT IS DISCARDED AS A WASTE,THE RCRA HAZARDOUS WASTE IDENTIFICATION NUMBER IS: D001=IGNITABLE ...DOT HAZARD/UN#/ER GUIDE# IS: COMBUSTIBLE LIQUID NA1993/#27 ...THIS PRODUCT CONTAINS THESE CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER OR REPRODUCTIVE TOXICITY: NONE PRESENT IN SIGNIFICANT AMOUNTS ...SARA SECTION 313 CHEMICALS: TRADE SECRETC162)--ALIPHATIC ALCOHOL , 2.0-5.0% ...SARA SECTION 312 HAZARD CLASS: IMMEDIATE(ACUTE),DELAYED(CHRONIC) AND FIRE ...MICHIGAN CRITICAL MATERIALS: TRADE SECRET(162)--ALIPHATIC ALCOHOL ; NFPA/HMIS : HEALTH - 2 ; FIRE - 2 ; REACTIVITY - 0 ; SPECIAL - NONE ; PE - B ; sal 00006*26 ftXS BETZ PROCESS CHEMICALS, INC. P.O. BOX 4300 The Woodlands, Texas 77387 (713) 367-2442 NFPA/HMIS : HEALTH - MATERIAL SAFETY DATA SHEET 24 HOUR EMERGENCY TELEPHONE (HEALTH OR ACCIDENT) (215) 355-3300 G ft S 9 7 DISTRIBUTED; APR-17-1990 PRODUCT : EMBREAK 2W154 (PAGE 1 OF 3) EFFECTIVE DATE 12-12-89 PRINTED: 10-Apr-1990 REVISIONS TO SECTIONS: APPENDIX/9 PRODUCT APPLICATION : AN OIL BASED EMULSION BREAKER. --------- SECTION 1---------------------- HAZARDOUS INGREDIENTS............................... .. INFORMATION ON PHYSICAL HAZARDS, HEALTH HAZARDS, PEL'S AND TLV'S FOR SPECIFIC PRODUCT INGREDIENTS AS REQUIRED BY THE OSHA HAZARD COMMUNICATIONS STANDARD ARE LISTED. REFER TO SECTION 4 (PAGE 2) FOR OUR ASSESSMENT OF THE POTENTIAL ACUTE AND CHRONIC HAZARDS OF THIS FORMULATION. HEAVY AROMATIC NAPHTHA;***CAS#64742-06-9;COMBUSTIBLE LIQUID;IRRITANT(EYE): MANUFACTURERS SUGGESTED EXPOSURE LIMIT:100PPM;PEL;NONE;TLV:NONE. TRADE SECRET INGREDIENT(028);COMBUSTIBLE;POTENTIAL TOXIN TO BLOOD,LIVER,KIDNEY AND REPRODUCTIVE SYSTEM;PEL:25PFM(SKIN);TLV:5PPM(SKIN). TSRN 125438 - 5182P TRADE SECRET INGREDIENT(078);FLAMMABLE;POTENTIAL LIVER AND KIDNEY TOXIN: CNS DEPRESSANT;PEL/TLV:100 PPM(150PPM-STEL). TSRN 125438 - 5200P TRADE SECRET INGREDIENT(002);COMBUSTIBLE;POTENTIAL BLOOD TOXIN,LIVER TOXIN OR KIDNEY TOXIN;TOXIC(INHALATION);PEL:50PPM(SKIN);TLV:25PPM(SKIN). TSRN 125438 - 5173P SECTION 2----------------------TYPICAL PHYSICAL DATA PH: 50% DISP. (APPROX.) 10.2 FL.PT.(DEG.F): 116 SETA(CC) VAPOR PRESSURE(mraHG): ND VISC cps70F: 20.0 EVAP.RATE: <1 ETHER=1 PHYSICAL STATE: LIQUID ODOR: HYDROCARBON SP.GR.(70F)OR DENSITY: 7.9 LBS/GAL VAPOR DENSITY(AIR=1): ND %SOLUBILITY(WATER): 0 APPEARANCE: AMBER FREEZE POINT(DEG.F): <-30 --------- SECTION 3---------------------- REACTIVITY DATA-------------- ----------------------------------- STABLE.MAY REACT WITH STRONG OXIDIZERS.DO NOT CONTAMINATE.BETZ TANK CLEAN-OUT CATEGORY 'B' THERMAL DECOMPOSITION (DESTRUCTIVE FIRES) YIELDS ELEMENTAL OXIDES. 00006A2T SAL 0 jtAS BETZ PROCESS CHEMICALS, INC P.O. BOX 4300 The Woodlands, Texas 773B7 (713) 367-2442 MATERIAL SAFETY DATA SHEET (PAGE 2 OF 3) PRODUCT: EMBREAK 2W154 --------- SECTION 4-........................ HEALTH HAZARD EFFECTS........................................ ACUTE SKIN EFFECTS *** PRIMARY ROUTE OF EXPOSURE MODERATELY IRRITATING TO THE SKIN.MAY CAUSE DERMATITIS. ACUTE EYE EFFECTS *** SEVERE IRRITANT TO THE EYES ACUTE RESPIRATORY EFFECTS *** PRIMARY ROUTE OF EXPOSURE VAPORS,GASES,MISTS AND/OR AEROSOLS CAUSE IRRITATION TO UPPER RESPIRATORY TRACT. PROLONGED EXPOSURE MAY CAUSE DIZZINESS AND HEADACHE. CHRONIC EFFECTS OF OVEREXPOSURE*** PROLONGED OR REPEATED EXPOSURES MAY CAUSE LIVER AND KIDNEY TOXICITY,MAY CAUSE BLOOD CELL DAMAGE OR IMPAIRMENT OF FUNCTION,MAY CAUSE REPRODUCTIVE SYSTEM TOXICITY,OR MAY CAUSE DEFATTING-TYPE DERMATITIS. MEDICAL CONDITIONS AGGRAVATED *** NOT KNOWN SYMPTOMS OF EXPOSURE *** EXCESSIVE DERMAL EXPOSURE CAUSES DEFATTING AND DRYING OF SKIN;EXCESSIVE INHALATION OF VAPORS CAUSES DIZZINESS,HEADACHE AND NAUSEA. PRECAUTIONARY STATEMENT BASED ON TESTING RESULTS *** MAY BE TOXIC IF ABSORBED THROUGH SKIN OR INHALED. --------- SECTION 5------------------------ FIRST AID INSTRUCTIONS.................................................. SKIN CONTACT*** REMOVE CONTAMINATED CLOTHING.WASH EXPOSED AREA WITH A LARGE QUANTITY OF SOAP SOLUTION OR WATER FOR 15 MINUTES EYE CONTACT*** IMMEDIATELY FLUSH EYES WITH WATER FOR 15 MINUTES.IMMEDIATELY CONTACT A PHYSICIAN FOR ADDITIONAL TREATMENT INHALATION EXPOSURE*** REMOVE VICTIM FROM CONTAMINATED AREA TO FRESH AIR.APPLY APPROPRIATE FIRST AID TREATMENT AS NECESSARY INGESTION*** DO NOT FEED ANYTHING BY MOUTH TO AN UNCONSCIOUS OR CONVULSIVE VICTIM DO NOT INDUCE VOMITING.IMMED.CONTACT PHYSICIAN.DILUTE CONTENTS OF STOMACH USING 3-4 GLASSES MILK OR WATER ........... SECTION 6...........................SPILL, DISPOSAL AND FIRE INSTRUCTIONS...................... SPILL INSTRUCTIONS*** VENTILATE AREA,USE SPECIFIED PROTECTIVE EQUIPMENT.CONTAIN AND ABSORB ON ABSORBENT MATERIAL.PLACE IN WASTE DISPOSAL CONTAINER. THE WASTE CHARACTERISTICS OF THE ABSORBED MATERIAL,OR ANY CONTAMINATED SOIL, SHOULD BE DETERMINED IN ACCORDANCE WITH RCRA REGULATIONS. REMOVE IGNITION SOURCES.FLUSH AREA WITH WATER.SPREAD SAND/GRIT. DISPOSAL INSTRUCTIONS*** WATER CONTAMINATED WITH THIS PRODUCT MAY BE SENT TO A SANITARY SEWER TREATMENT FACILITY,IN ACCORDANCE WITH ANY LOCAL AGREEMENT,A PERMITTED WASTE TREATMENT FACILITY OR DISCHARGED UNDER A NPDES PERMIT PRODUCT(AS IS)- INCINERATE OR BURY IN APPROVED LANDFILL FIRE EXTINGUISHING INSTRUCTIONS*** FIREFIGHTERS SHOULD WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS(FULL FACE-PIECE TYPE).PROPER FIRE EXTINGUISHING MEDIA: DRY CHEMICAL/C02/F0AM OR WATER. SLIPPERY CONDITION. USE SAND/GRIT sal 000642s BETZ PROCESS CHEMICALS, INC. P.O. BOX 4300 The Woodlands, Texas 77387 (713) 367-2442 MATERIAL SAFETY DATA SHEET (PAGE 3 OF 3) CS597 PRODUCT: EMBREAK 2W154 SECTION 7............................... ---SPECIAL PROTECTIVE EQUIPMENT.......................................... USE PROTECTIVE EQUIPMENT IN ACCORDANCE WITH 29CFR SECTION 1910.132-134. USE RESPIRATORS WITHIN USE LIMITATIONS OR ELSE USE SUPPLIED AIR RESPIRATORS. VENTILATION PROTECTION*** ADEQUATE VENTILATION TO MAINTAIN AIR CONTAMINANTS BELOW EXPOSURE LIMITS RECOMMENDED RESPIRATORY PROTECTION*** IF VENTILATION IS INADEQUATE OR SIGNIFICANT PRODUCT EXPOSURE IS LIKELY, USE A RESPIRATOR WITH ORGANIC VAPOR CARTRIDGES. RECOMMENDED SKIN PROTECTION*** NITRILE GLOVES WASH OFF AFTER EACH USE.REPLACE AS NECESSARY RECOMMENDED EYE PROTECTION*** SPLASH PROOF CHEMICAL GOGGLES SECTION 8-------------------------------- STORAGE AND HANDLING PRECAUTIONS................................ STORAGE INSTRUCTIONS*** KEEP DRUMS & PAILS CLOSED WHEN NOT IN USE. STORE IN COOL VENTILATED LOCATION.STORE AWAY FROM OXIDIZERS HANDLING INSTRUCTIONS*** COMBUSTIBLE. DO NOT USE AROUND SPARKS OR FLAMES. BOND CONTAINERS DURING FILLING OR DISCHARGE WHEN PERFORMED AT TEMPERATURES AT OR ABOVE THE PRODUCT FLASH POINT, Vr^**'^****>Wt#***#***************************************^ THIS MSDS COMPLIES WITH THE OSHA HAZARD COMMUNICATION STANDARD HAROLD M. HERSH (ENVIRONMENTAL INFORMATION COORDINATOR) *TW^***^*******Vr*n*)nnllrftVrft,**^i^^ APPENDIX: REGULATORY INFORMATION THE CONTENT OF THIS APPENDIX REPRESENTS INFORMATION KNOWN TO BETZ ON THE EFFECTIVE DATE OF THIS MSDS. THIS INFORMATION IS BELIEVED TO BE ACCURATE. ANY CHANGES IN REGULATIONS WILL RESULT IN UPDATED VERSIONS OF THIS DOCUMENT. ...TSCA: ALL COMPONENTS OF THIS PRODUCT ARE LISTED IN THE TSCA INVENTORY ...REPORTABLE QUANTITY(RQ) FOR UNDILUTED PRODUCT: TREAT AS OIL SPILL . . . RCRA: IF THIS PRODUCT IS DISCARDED AS A WASTE,THE RCRA HAZARDOUS WASTE IDENTIFICATION NUMBER IS: D001-IGNITABLE ...DOT HAZARD/UN#/ER GUIDE# IS: COMBUSTIBLE LIQUID NAl993/#27 ...THIS PRODUCT CONTAINS THESE CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER OR REPRODUCTIVE TOXICITY: NONE PRESENT IN SIGNIFICANT AMOUNTS ...SARA SECTION 313 CHEMICALS: TRADE SECRET(028)--GLYCOL ETHER , 6.0-10.0% ; TRADE SECRET(078)--ALKYL AROMATIC , 2.0-5.0% ; TRADE SECRET(002)--GLYCOL ETHER 2.0-5.0% ; ...SARA SECTION 312 HAZARD CLASS: IMMEDIATE(ACUTE),DELAYED(CHRONIC) AND FIRE ...MICHIGAN CRITICAL MATERIALS: TRADE SECRET(078)--ALKYL AROMATIC ; NFPA/HMIS : HEALTH - 2 ; FIRE - 2 ; REACTIVITY - 0 ; SPECIAL - NONE ; PE - B , SAL 00006429 UNION CARBIDE CHEMICALS AND PLASTICS COMPANY INC. Solvents & Coatings Materials Division MATERIAL SAFETY DATA SHEET EFFECTIVE DATE: 08/03/89 CSS Oft UniCarbide arfii each easterner er recipient o( this MSDS to study it carefully to become aware of and understand the hazards associated with the product. The reader should consider consulting reference works or individuals who are experts in ventilation, texicelegy, and fire prevention, as necessary er appropriate to nse and understand the data contained in this MSDS. To promote safe handling, each customer or recipient should: (1) notify its employees, agents, contractors and others whom it knows or believes will use this material of the information in this MSDS and any other information regarding hazards or safety; (2) furnish this same information te each of its customers for the product; and (3) request its customers to notify their employees, customers, and other users of the product of this information. I. IDENTIFICATION PRODUCT NAME: ANHYDROL SOLVENT SPECIAL, PM-4081. i 90 Proof CHEMICAL NAME: Denatured Ethanol CHEMICAL FAMILY: Alcohols FORMULA: N/A (mixture) MOLECULAR WEIGHT: N/A (mixture) SYNONYMS: Special Industrial Solvent, Government Formula Al CAS NAME: N/A (mixture) II. PHYSICAL DATA BOILING POINT, 760 mm Hg: 79CC174F) FREEZING POINT: -90C(-130F) SPECIFIC GRAVITY(H20 =1): 0.8090 at 20/20 C V VAPOR PRESSURE AT 20'C: 30 mm Hg VAPOR DENSITY (air = 1): 1.4 SOLUBILITY IN WATER by wt: Complete at 20 C EVAPORATION RATE (Butyl Acetate = 1): 2.2 APPEARANCE AND ODOR: Water-wr.ite liquid; nonresidual odor PERCENT VOLATILES (BY VOLUME): 100 Copyright 19*5,1989 Union Carbide Chemicals & Plastics Tech. Cerp. UNION CARBIDE is a trademark of Union Carbide Corporation % ANHYDROL is a trademark of Union Carbide Chemicals & Plastics Tech. Corp. EMERGENCY PHONE NUMBER: 1-SOO-LCC-HELP (Number available at all times) UNION CARBIDE CHEMICALS AND PLASTICS COMPANY INC. Solvents Sc Coatings Materials Division A9 Old Rirfgebury Road^Danbury, CT. 06817-0001 \ SAL 000006430 5 g 6 0 Product name: ANHYDROL SOLVENT SPECIAL, PM-4081, 190 Proof III. INGREDIENTS MATERIAL Ethanol (CAS# 64-17-5) % 82 EXPOSURE LIMITS See Section V HAZARD Flammable Methanol (CAS #67-56-1) 4 See Section V Toxic, flammable Methyl Isobutyl Ketone (CAS #108-10-1) Water (CAS# 7732-1 6-5) 1 4 See Section V None Harmful if inhaled, irritant None Isopropanol (CAS # 67-63-0) 9 See Section V Flammable PAGE 2 IV. FIRE AND EXPLOSION HAZARD DATA FLASH POINT: 61 F(16C),Tag Closed Cup; 74 F (23 C), Tag Open Cup FLAMMABLE LIMITS IN AIR, % by volume: LOWER: 3.3 (Ethyl Alcohol) UPPER: 19.0 (Ethyl Alcohol) EXTINGUISHING MEDIA: Use water spray, carbon dioxide, dry chemical, alcohol-type, or universal-type foams applied by manufacturers' recommended techniques. SPECIAL FIRE FIGHTING PROCEDURES: Use water spray to cool fire exposed containers and structures. Use selfcontained breathing apparatus, and protective clothing. UNUSUAL FIRE AND EXPLOSION HAZARDS: Vapors form from this product and may travel or be moved by air currents and ignited by pilot lights, other flames, sparks, heaters, electrical equipment, static discharges or other ignition sources at locations distant from product handling point. V. HEALTH HAZARD DATA TLV AND SOURCE: Ethanol, 1000 ppm TWA OSHA & ACGIH Isopropanol, 400 ppm TWA OSHA & ACGIH 500 ppm STEl OSHA & ACG'H Methyl isobutyl Ketone. 50 ppm TWA OSHA & ACGIH 75 ppm STEL OSHA S ACGiH Methanol, 200 ppm TWA skin OSHA & ACGIH 250 ppm STEL skin OSHA & ACGIH Values from OSHA 29 CFR 1 91C.10C0 Table Z-1 -A & ACGIH 1 989-90 EFFECTS OF ACUTE OVEREXPOSURE: SWALLOWING: Causes di77'ress, drowsiness, decreased react on, euphoria, nausea, vomiting, staggering cait. and coma. SKIN ABSORPTION: No evidence of adverse effects from available information. INHALATION: May cause dizziness, drows.ness, nausea, and vomiting. SAL 000006431 PRODUCT NAME: ANHYDROL SOLVENT SPECIAL, PM-4081, 190 Proof PA$E 3 ---------------------------------------------------------------------------------------------------------------------------------------------- gj g SKIN CONTACT: No evidence of adverse effects from available information. EYE CONTACT: Minor irritation. EFFECTS OF REPEATED OVEREXPOSURE: No evidence of adverse effects from available information. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: None currently known. EMERGENCY AND FIRST AID PROCEDURES: SWALLOWING: Give two glasses of water and induce vomiting. Get medical help. SKIN: Flush with water. INHALATION: Remove to fresh air. Call a physician. EYES: immediately flush eyes with plenty of water for at least 15 minutes. Call a physician. NOTES TO PHYSICIAN: Ingestion of a large quantity of this material will result in methyl alcohol poisoning. In such a case. Treatment should include the following: hemodialysis; the intravenous administration of ethanol (10 ml per hour) to interfere with the metabolism of methyl alcohol; and the administration of sodium bicarbonate to correct acidosis. VI. REACTIVITY DATA STABILITY: Stable CONDITIONS TO AVOID: Heat, sparks, flames INCOMPATIBILITY (materials to avoid): None HAZARDOUS COMBUSTION OR DECOMPOSITION PRODUCTS: Burning can produce carbon monoxide and/or carbon dioxide. Carbon monoxide is highly toxic if inhaled; carbon dioxide m sufficient concentrations can act as an asphyxiant. HAZARDOUS POLYMERIZATION: Will Not Occur CONDITIONS TO AVOID: NoneVII. VII. SPILL OR LEAK PROCEDURES V. PRODUCT NAME: ANHYDROL SOLVENT SPECIAL. PM-4081, 190 Proof PAGE 4 STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Extinguish and do not turn on any ignition source untH area is determined to be tree from explosion or fire hazards. Collect large spills for disposal. Flush small spills with water. WASTE DISPOSAL METHOD: Incinerate in a furnace where permitted under appropriate Federal. State and local regulations. VIII. SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION: Self-contained breathing apparatus in high concentrations. VENTILATION: This product should be confined within closed equipment, in which case general (mechanical) room ventilation should be satisfactory. Special, local ventilation is needed at points where vapors are expected to escape to the workplace air. PROTECTIVE GLOVES: Neoprene EYE PROTECTION: Safety glasses OTHER PROTECTIVE EQUIPMENT: Eye bath, safety shower IX. SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Do not take internally. Keep away from heat, sparks, and (lame. Keep container closed. Use with adequate ventilation. Wash thoroughly after handling. Avoid breathing vapors. FOR INDUSTRY USE ONLY OTHER PRECAUTIONS: WARNING: Hot organic chemical vapors or mists are susceptible to sudden spontaneous combustion when mixed with air. Ignition may occur at lemperatures below those published in the literature as "autoignition" or "ignition" temperatures. Ignition temperatures decrease with increasing vapor volume and vapor/air contact time, and are influenced by pressure changes. Ignition may occur at typical elevated-temperature process conditions, especially in processes operating under vacuum if subjected to sudden ingress of air, or outside process equipment operating under elevated pressure if sudden escape of vapors or mists to the atmosphere occurs. Any proposed use of this product in elevated-temperature processes should be thoroughly evaluated to assure that safe operating conditions are established and maintained. X. REGULATORY INFORMATION STATUS ON SUBSTANCE LISTS: 1 he concentrations shown are maximum or ceiling levels (weight %) to be used for calculations for regulations. T-ade Secrets ere indicatec by "TS". FEDERAL EPA SAL 000006433 PRODUCT NAME: ANHYDROL SOLVENT SPECIAL, PM-4081 . 190 Proof PAGE 5 6 00 Comprehensive Environmenlal Response, Compensation, and Liability Act of 1 980 (CERCLA) requires notification of the National Response Center of release of quantities of Hazardous Substances equal to or greater than the reportable quantities (RQs) in 4-0 CFR 302.4. Components present in this product at a level which could require reporting under the statute are: CHEMICAL UPPER BOUND CAS NUMBER CONCENTRATION % To be determined Superfund Amendments and Reauthorization Act of 1986 (SARA) Title III requires emergency planning based on Threshold Planning Quantities (TPQs) and release reporting based on Reportable Quantities (RQs) in 40 CFR 355 (used for SARA 302, 304. 31 1 and 31 2). Components present in this product at a level which could require reporting under the statute are: UPPER BOUND CHEMICAL CAS NUMBER CONCENTRATION % To be determined Superfund Amendments and Reauthorization Act of 1986 (SARA) Title III requires submission of annual reports of release of toxic chemicals that appear in 40 CFR 372 (for SARA 313). This information must be included in all MSDSs that are copied and distributed for this material. Components present in this product at a level which could require reporting under the statute are: UPPER BOUND CHEMICAL CAS NUMBER CONCENTRATION % Methyl Isobutyl Ketone 108-10-1 1 Methanol 67-56-t 4 STATE RIGHT-TO-KNOW CALIFORNIA Proposition 65 None MASSACHUSETTS Right-To-Know, Substance List (MSL) Hazardous Substances and Extraordinarily Hazardous Substances on the MSL must be identified when present in products. Components present in this product at a level which could require reporting under the statute are: EXTRAORDINARILY HAZARDOUS SUBSTANCES ( => 0.0001/,) UPPER BOUND CHEMICAL CAS NUMBER CONCENTRATION % To be determined HAZARDOUS SUBSTANCES ( => 1%) UPPER BOUND CHEMICAL CAS NUM8ER CONCENTRATION % To be determined PENNSYLVANIA Right-To-Know, Hazardous Substance List Hazardous Substances and Special Hazardous Substances on the List must be identified when present in products. Components present in this product at a level which could require reportmo under the statute 2re: SPECIAL HAZARDOUS SUBSTANCES (=>0.01%) UPPER BOUND CHEMICAL CAS NUMBER CONCENTRATION % To be determined HAZARDOUS SUBSTANCES ( => 1%) UPPER BOUND CHEMICAL CAS NUMBER CONCENTRATION % To be determined SAL 000006434 Q S 6 00. PRODUCT NAME: ANHYDROL SOLVENT SPECIAL, PM-4081, 190 Proof PAGE 6 Toxic Substances Control Act(TSCA) STATUS: The ingredients of this product are on the TSCA inventory. CALIFORNIA SCAQMD RULE 443.1 VOC'S: VOC 801 g/l; Vapor pressure 30 mm Hg <3> 20 C OTHER REGULATORY INFORMATION: NEW YORK STATE BULK STORAGE REGULATIONS (GNYSRR Parts 595-599) This product is covered by GNYSRR for Bulk Storage and Release Reporting and Response. Technical guidance and recommended practices are as follows: MATERIALS OF CONSTRUCTION Suitable materials of construction are: Steel, stainless steel, baked phenolic lined steel, galvanized steel, copper, and copper alloy. Materials not to be used: Aluminum. Plastics are not recommended for flammable liquids. STORAGE SYSTEM DESIGN Design should comply with applicable industry. Federal, and local codes for a Class IB Flammable liquid with regards to mechanical, electrical, safety and health components. Should also comply with NYS/DEC Chemical Bulk Storage proposed regulations Parts 589.3 to 589.6 (for existing tanks) or Parts 599.2 and 599.7 <1or new or substantially moditied tanks). CONDITIONS FOR STORAGE Store at normal ambient temperatures. INSPECTION AND MAINTENANCE A lesting/inspeclion program which ensures structural integrity and proper system operation should be established. Inspection and maintenance procedures and testing of equipment should comply with NYS/DEC proposed regulations Parts 598.7 to 598.10. TRANSFER AND UNLOADING NOTE-------- These operations should comply with NYS/DEC proposed regulations, Part 598.5. The opinions expressed herein are those of qualified experts within Union Carbide Chemicals and Plastics Company. We believe that the information contained herein is current as of the date of this Material Safety Data Sheet. Since the use of this information and of these opinions and the conditions of the use of the product are not within the control of Union Carbide Chemicals and Plastics Company, it is the user's obligation to determine the conditions of safe use of the product. REVISED SECTIONS: Section IX: VAPOR IGNITION HAZARD warning PC: 32688 F NUMBER: C0052A 0000643s V tfAS BETZ PROCESS |W| CHEMICALS, INC P.O. BOX 4300 The Woodlands, Texas 77387 (713) 367*2442 MATERIAL SAFETY DATA SHEET (PAGE 3 OF 3) GS601 PRODUCT: EMBREAK 2W157 --------- SECTION 7................. ......... SPECIAL PROTECTIVE EQUIPMENT.......................................... USE PROTECTIVE EQUIPMENT IN ACCORDANCE WITH 29CFR SECTION 1910.132-134, USE RESPIRATORS WITHIN USE LIMITATIONS OR ELSE USE SUPPLIED AIR RESPIRATORS. VENTILATION PROTECTION*** ADEQUATE VENTILATION TO MAINTAIN AIR CONTAMINANTS BELOW EXPOSURE LIMITS RECOMMENDED RESPIRATORY PROTECTION*** IF VENTILATION IS INADEQUATE OR SIGNIFICANT PRODUCT EXPOSURE IS LIKELY, USE A RESPIRATOR WITH ORGANIC VAPOR CARTRIDGES. RECOMMENDED SKIN PROTECTION*** NEOPRENE GLOVES WASH OFF AFTER EACH USE.REPLACE AS NECESSARY RECOMMENDED EYE PROTECTION*** SPLASH PROOF CHEMICAL GOGGLES --------- SECTION 8...........................STORAGE AND HANDLING PRECAUTIONS-------------------------- STORAGE INSTRUCTIONS*** KEEP DRUMS & PAILS CLOSED WHEN NOT IN USE. STORE IN COOL VENTILATED LOCATION.STORE AWAY FROM OXIDIZERS HANDLING INSTRUCTIONS*** COMBUSTIBLE. DO NOT USE AROUND SPARKS OR FLAMES. BOND CONTAINERS DURING FILLING OR DISCHARGE WHEN PERFORMED AT TEMPERATURES AT OR ABOVE THE PRODyCT FLASH POINT. THIS MSDS COMPLIES WITH THE OSHA HAZARD COMMUNICATION STANDARD HAROLD M. HERSH (ENVIRONMENTAL INFORMATION COORDINATOR) ^fr******T^*****>Vfr************<^**ft********ft'ft~*frft******Tir*^^ APPENDIX: REGULATORY INFORMATION THE CONTENT OF THIS APPENDIX REPRESENTS INFORMATION KNOWN TO BETZ ON THE EFFECTIVE DATE OF THIS MSDS. THIS INFORMATION IS BELIEVED TO BE ACCURATE. ANY CHANGES IN REGULATIONS WILL RESULT IN UPDATED VERSIONS OF THIS DOCUMENT. . . .TSCA: ALL COMPONENTS OF THIS PRODUCT ARE LISTED IN THE TSCA INVENTORY ...REPORTABLE QUANTITY(RQ) FOR UNDILUTED PRODUCT: 12,500 GALLONS DUE TO N-BUTYL ALCOHOL;TREAT AS OIL SPILL ...RCRA: IF THIS PRODUCT IS DISCARDED AS A WASTE.THE RCRA HAZARDOUS WASTE IDENTIFICATION NUMBER IS: D001=IGNITABLE . . .DOT HAZARD/UN#/ER GUIDE# IS: COMBUSTIBLE LIQUID NA1993/#27 ...THIS PRODUCT CONTAINS THESE CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER OR REPRODUCTIVE TOXICITY: NONE PRESENT IN SIGNIFICANT AMOUNTS ...SARA SECTION 313 CHEMICALS: BUTYL ALCOHOL(71-36-3) , 2.0-5.0% ; ...SARA SECTION 312 HAZARD CLASS: IMMEDIATE(ACUTE),DELAYED(CHRONIC) AND FIRE ,..MICHIGAN CRITICAL MATERIALS: BUTYL ALCOHOL(71-36-3) ; NFPA/HMIS : HEALTH - 2 ; FIRE - 2 ; REACTIVITY - 0 ; SPECIAL - NONE ; PE - B SAL 0000064-36 BETZ PROCESS CHEMICALS, INC. P.O. BOX 4300 The Woodlands, Texas 77387 (713) 367-2442 NFFA/HMIS : HEALTH - MATERIAL SAFETY DATA SHEET 24 HOUR EMERGENCY TELEPHONE (HEALTH OR ACCIDENT) (215) 355-3300 csoot DISTRIBUTED: APR-17-1990 PRODUCT : EMBREAK 2W157 (PAGE 1 OF 3) EFFECTIVE DATE 03-26-90 PRINTED: 10-Apr-1990 REVISIONS TO SECTIONS: 1,4,APPENDIX/9 PRODUCT APPLICATION : AN OIL BASED EMULSION BREAKER. --------- SECTION 1--........... ..........HAZARDOUS INGREDIENTS------------------------------ INFORMATION ON PHYSICAL HAZARDS, HEALTH HAZARDS, PEL'S AND TLV'S FOR SPECIFIC PRODUCT INGREDIENTS AS REQUIRED BY THE OSHA HAZARD COMMUNICATIONS STANDARD ARE LISTED. REFER TO SECTION 4 (PAGE 2) FOR OUR ASSESSMENT OF THE POTENTIAL ACUTE AND CHRONIC HAZARDS OF THIS FORMULATION. HEAVY AROMATIC NAPHTHA;***CAS#64?42-06-9;COMBUSTIBLE LIQUID;IRRITANT(EYE); MANUFACTURERS SUGGESTED EXPOSURE LIMIT:100PPM;PEL:NONE;TLV:NONE. TRADE SECRET INGREDIENT(E076);EYE IRRITANT;PEL:NONE;TLV:NONE.THIS CHEMICAL IS NOT ON ANY STATE RIGHT-TO-KNOW LIST. TSRN 125438 - 5059P N-BUTYL ALCOHOL***(1-BUTANOL);CAS#71-36-3;FLAMMABLE LIQUID;IRRITANT;CNS DEPRESSANT;PEL/TLV:50PPM-C(SKIN). TRADE SECRET INGREDIENT(E038);EYE AND SKIN IRRITANT;TOXIC(ORAL INGESTION); PEL:NONE:TLV:NONE.THIS CHEMICAL IS NOT ON ANY STATE RIGHT-TO-KNOW LIST. TSRN 125438 - 5026P PETROLEUM DISTILLATES***(NAPHTHA);CAS#8002-05-9;POTENTIAL EYE,SKIN AND INHALATION IRRITANT;COMBUSTIBLE LIQUID;PEL:400 PPM;TLV:NONE. SECTION 2--------------------- TYPICAL PHYSICAL DATA FH: 5% DISP. (APPROX.) FL.PT.(DEG.F): 111 P-M(CC) VAPOR PRESSURE(mmHG): <10 VISC cps70F: 73 EVAP.RATE: ND VATER=1 PHYSICAL STATE: LIQUID 3.0 ODOR: HYDROCARBON SP.GR.(70F)OR DENSITY: 8.0 LBS/GAL VAPOR DENSITY(AIR=1): >1 %SOLUBILITY(WATER): 0 APPEARANCE: AMBER FREEZE POINT(DEG.F): <-30 SECTION 3.......................... REACTIVITY DATA STABLE.MAY REACT WITH STRONG OXIDIZERS.DO NOT CONTAMINATE.BETZ TANK CLEAN-OUT CATEGORY 'B* THERMAL DECOMPOSITION (DESTRUCTIVE FIRES) YIELDS ELEMENTAL OXIDES. fjXS BETZ PROCESS CHEMICALS, INC P.O. BOX 4300 The Woodlands, Texas 77387 (713) 367-2442 MATERIAL SAFETY DATA SHEET (PAGE 2 OF 3) f^ Cg 6 01 PRODUCT: EMBREAK 2W157 ^ 17 v v 1 ........... SECTION 4...........................HEALTH HAZARD EFFECTS............................................................ ACUTE SKIN EFFECTS *** PRIMARY ROUTE OF EXPOSURE MODERATELY IRRITATING TO THE SKIN.MAY CAUSE DERMATITIS. ACUTE EYE EFFECTS *** SEVERE IRRITANT TO THE EYES ACUTE RESPIRATORY EFFECTS *** PRIMARY ROUTE OF EXPOSURE VAPORS,GASES,MISTS OR AEROSOLS MAY CAUSE IRRITATION TO UPPER RESPIRATORY TRACT.PROLONGED EXPOSURE MAY CAUSE DIZZINESS AND HEADACHE. CHRONIC EFFECTS OF OVEREXPOSURE*** PROLONGED OR REPEATED EXPOSURES MAY CAUSE LIVER AND KIDNEY TOXICITY,MAY CAUSE CNS DEPRESSION,OR MAY CAUSE DEFATTING-TYPE DERMATITIS. MEDICAL CONDITIONS AGGRAVATED *** NOT KNOWN SYMPTOMS OF EXPOSURE *** EXCESSIVE DERMAL EXPOSURE CAUSES DEFATTING AND DRYING OF SKIN;EXCESSIVE INHALATION OF VAPORS CAUSES DIZZINESS,HEADACHE AND NAUSEA. PRECAUTIONARY STATEMENT BASED ON TESTING RESULTS *** MAY BE TOXIC IF ORALLY INGESTED OR INHALED. --------- SECTION 5------------------------ FIRST AID INSTRUCTIONS---------------- ------------ ----------------- SKIN CONTACT*** REMOVE CONTAMINATED CLOTHING.WASH EXPOSED AREA WITH A LARGE QUANTITY OF SOAP SOLUTION OR WATER FOR 15 MINUTES EYE CONTACT*** IMMEDIATELY FLUSH EYES WITH WATER FOR 15 MINUTES.IMMEDIATELY CONTACT A PHYSICIAN FOR ADDITIONAL TREATMENT INHALATION EXPOSURE*** REMOVE VICTIM FROM CONTAMINATED AREA TO FRESH AIR.APPLY APPROPRIATE FIRST AID TREATMENT AS NECESSARY INGESTION*** DO NOT FEED ANYTHING BY MOUTH TO AN UNCONSCIOUS OR CONVULSIVE VICTIM DO NOT INDUCE VOMITING.IMMED.CONTACT PHYSICIAN.DILUTE CONTENTS OF STOMACH USING 3-4 GLASSES MILK OR WATER ........... SECTION 6---------------------- SPILL,DISPOSAL AND FIRE INSTRUCTIONS---.............. SPILL INSTRUCTIONS*** VENTILATE AREA,USE SPECIFIED PROTECTIVE EQUIPMENT.CONTAIN AND ABSORB ON ABSORBENT MATERIAL.PLACE IN WASTE DISPOSAL CONTAINER. THE WASTE CHARACTERISTICS OF THE ABSORBED MATERIAL,OR ANY CONTAMINATED SOIL, SHOULD BE DETERMINED IN ACCORDANCE WITH RCRA REGULATIONS. REMOVE IGNITION SOURCES.FLUSH AREA WITH WATER.SPREAD SAND/GRIT. DISPOSAL INSTRUCTIONS*** WATER CONTAMINATED WITH THIS PRODUCT MAY BE SENT TO A SANITARY SEWER TREATMENT FACILITY,IN ACCORDANCE WITH ANY LOCAL AGREEMENT,A PERMITTED WASTE TREATMENT FACILITY OR DISCHARGED UNDER A NPDES PERMIT PRODUCT(AS IS)INCINERATE OR BURY IN APPROVED LANDFILL FIRE EXTINGUISHING INSTRUCTIONS*** FIREFIGHTERS SHOULD WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS(FULL FACE-PIECE TYPE).PROPER FIRE EXTINGUISHING MEDIA: DRY CHEMICAL,CARBON DIOXIDE,FOAM OR WATER 0006*38 S*L 00 MSTERIAC SAFETY' DATA SHEET CS021 ALPHA CHEMICAL COMPANY PO box iO'I ia*1 ChablES l* '0C 3'S/Ub tsx SECTION I - PRODUCT IDENTIFICATION Since J96J date: revised u/20/8v OCfilCA.. NAME MP SYNONYMS! TRADE Hf#t AND SYNONYMS! At-PmCHOi 2063 DEGREASE?: CHFH1CAL FAMILY: r0RMULA; PROPRIETARY SECTION II - HAZARDOUS INGREDIENTS PAINTS, PRESERVATIVES, (. SOLVENTS ] X I TLV (Units) | 0T>?FJ< INGREDIENTS Solvents 1! I HAZARDOUS MIXTURES OF OTHER LIQUIDS; SOLIDS, OF: GASES 1Xi TLV (Units) iI I % i TLV (Units; LEAVY AROMATIC NAPTHA LIGHT AROMTIC SOLVENT NAFtlTHA SOLVENT NAPHTHA (PETROLEUM) HEAVY AROMATIC 1 25 pp ! i 50 I NOT ESTABLISH ii SECTION III - PHYSICAL DATA BOILING POINT <F> APPROX. 212 Decrees F VAPOR PRESSURE (a* Hy.)! UNK. VWW DENSITY (AIR=i) UNK. J SPECIFIC GRAVITY (K20=l>: I I PERCENT . VOLATILE I BY VOLIHE <X> .966 LMv. SOLUBILITY IN HATER! MISCIBLE AF*PEARANCE AND ODOR! LIBIT AMBER LIQUID tilth HYDROCARBON ODOR, } FVAKftATION RATE I <_____________=1) 1 SECTION IV - FIRE tffD EXPLOSION LttZttD DATA UNK. FLASH POINT (Hsthod Used)! NONE AT B.P. OF 212 Degrees F (FMCC) EXTINGUISHING MEDIA! HATER SPRAY, FOAM, DRY CHEMICAL, C02, Let! FLAMMABLE LIMITS Ueli SPECIAL FIRE FIGHTING PROCEWRES! AIR SUPPLIED RESCUE EQUIPMENT. COa EXPOSED CONTAINERS WITH HATER. UNUSUAL FIRE AND EXPLOSION HAZARDS* It) NOT STORE OR MIX WITH STRONG OXIDANTS-. SAL 000006439 MATERIAL SAFETY DATA SHEET Cr S 0 21 Since 1961 ALPHA CHEMICAL COMPANY i>0 BOX lot* L*KtCH*i.es la ttxos sii/us-rssc SECTION V - HEALTH HAZARD DATA NJWOCH 2063 BCGREASER HtfESHOUi LIMIT VALUE UNDETERMINED (SEE SECTION II) EFFECTS Of OVEREXFOSURE! EYES! IRRITANT, SKIN! MODERATE IRRITANT. MAY CAUSE DRYING. INGESTION! MAY WM TOXIC EFFECTS IF SWALLOWED. INHALATION! CENTRAL NERVOUS SYSTEM MALAWCTION. POSSIBLY COWAJLSIONS- EMERGENCY AND FIRST AIT* PROCXIWRESt EYES! FLUSH WITH WATER FW 15 MINUTES- GET MEDICAL ATTENTION. SKIN' WASH WITH SOAP AND WATER. IF IRRITATION PERSISTS CALL PHYSICIAN. INGESTION! DO MOT INDUCE SITING MAY GIVE OLIVE OIL TO RETARD ABSORPTION. KEEF WARM AND QUIET, GET IMMEDIATE MEDICAL ATTENTION. IMHALAT1 REMOVE FROM EXPOSURE. GIVE OXYGEN OR ARTIFICIAL RESPIRATION IF NEEDED. GET MEDICAl ATTENTION. SECTION VI - REACTIVITY DATA STABILITY I UNSTABLE ! f CONDITIONS TO AVOID; FEAT. SPARKS. OPEN n_AMF ! STABLE i XXX I INCOMPATIBILITY Otetei iats U- avoid); STRONG OXIDIZING AGENTS. STRONG ALKALI OR CAUSTIC HAZARDOUS OFXOf'FliSniQK PRODUCTS! CfttBOK MONOXIEt, AMMONIA, OXIDES Of NITROGEN. SULFUR DIOXIDE, HYDROGEN SULFIDE, HAZARDOUS POLYMERIZATIOH ! MAY OCCUR jj !------------------------------------------!------------- ! i will not ocaJR | XXX f CONDITIONS TO AVOID SECTION VII - SPILL OR LEAK PROCEDURES BTE*B TO I TAKEN IN CASE HATP3AL IS RELEASED OR SPILLED! ELIMINATE IGNITION SOURCES. EVACUATE ALL PERSC MOT EQUIPPED WITH PROTECTIVE GEAR FROM SPIU.AGE AREA, STOP SPILL AT SOURCE AND DIKE TO PREVENT SPREADING PUMP LIQUID TO SALVAGE TAWS. ABSORB THE REMAINDER WITH INERT ABSORBENT. WASTE DISPOSAL ffiTHOD! DISPOSE OF IN APPROVED INCINERATOR OR LWflOFILL IN ACCORDANCE WITH LOCAL. STATE. ANI FEDERAL REGULATIONS. SECTION VIII - SPECIAL PROTECTION ItFORMTION RESPIRATORY PROTECTION (Specify type)? NIGSH/HESA AFPROVED RESPIRATOR VENTILATION I LXAL DQWJS7 RECOMMENDED 1 SPECIAL. | MECHANICAL (General) EXPLOSION-PROOF | VENTILATION EQUIPMENT I OTTER l NO OPEN FLttES IWTECTIVE GLOVES! RUBBER GLOVES i EYE PROTECTION! COMICAL GOGfiXS OR FULL FACE SHIELD imEfTpROTECTIV^" EQUIPMENT! IMPERVIOUS CLOTHING AND BOOTS TO PREVENT SKIN CONTACT. SECTION IX - SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING Mffi STORING! STORE IN CLOSED CONTAINERS IN WELL VENTILATED AREAS AWAY FROM EXTREME HEAT OR OPEN FLAMES. AVOID BREATHING VAPORS. AVOID CONTACT WITH EYES AND SKIN. PG NOT INGE OTHER PRECAUTIONS? REPEATED CONTACT OF SIMILAR MATERIALS ON LABORATORY ANIMALS HAS RESULTED IN THE. INDUCTION OF TUMORS. SAL 000006440 APR 0 3 PRODUCT NAME MATERIAL SAFETY DATA SHEET Cable Clean (Aerosol) #02069 MANUFACTURED BY: CRC Industries, Inc. 885 LOUIS DRIVE. WARMINSTER, PA. 18974 1. INGREDIENTS 1,1,1 Trichloroethane CAS n 71-55-6 1,3 Dioxolane k 2-Butanol 646-06-0 78-92-2 ACGIH TLV 350 NA 100 S 1 37 #MSDSO 2069 Phone (215)674-4300 OSHA PEL 350 NA 100 Other Limits % 91-0 3. n 2.0 Carbon Dioxide 124-38-9 ` 5000 10000 4.0 These chemicals are listed i i the Toxic Chemical Lis ; found in Section J13 of th 3 Emergency Planning and Comma lity-Right-To-Knov Act SARA Titl 5 111) an 1 are sub ject to release inventory reporting uider that act. 2, PHYSICAL DATA (does not include carbon dioxide propellent) Specific Gravity 1.293 (70p) Vapor Pressure 100 mm % 20C % Volatile 100* Soiling Point 164P Evaporation Rate Rapid Freezing Point N/A Vapor Density 4.55 (air = 1) Appearance and Odor Colorless liquid - irritating odor at high concentrations SolubilitySlight solubility In water - good solvent for many organic materials 3. FIRE AND EXPLOSION DATA Flashooint None Method TCC, C0C. TOC Extinguishing Media Water, fog Flammable Limits LEL 6 UEL 16.7 Unusual Hazards Aerosol cans say explode if their temperature exceeds 130 P 4. REACTIVITY AND STABILITY Stability Good - avoid exposures to open flames, arcs, and high temperatures. Hazardous decomposition products Thermal - Hydrogen chloride, chlorine and some phosgene Materials to avoid Avoid storage in aluminum containers or contact with aluminum and/or _____ ____________zinc powder. ___ _____ 5. PROTECTION INFORMATION Ventilation Maintain vapor concentration below TLV - Use mechanical means if necessary. Respiratory Above TLV use self contained breathing appratus (air mask or vapor mask). Gloves solvent resistant Eye & Face safety glasses Other Protective Equipment Hot normally required for aerosol product usage. SAL 000006441 $S 1 37 USDS 00 2069_________________________________________________________________________ 6. HEALTH HAZARD DATA Primary Routes of Entry Inhalation and akin contact Signs and Symptoms of Exposure 1 Acute Overexposure inhalation - headaches, dizziness, anesthesia, unconsciousness. Eyes - causes pain and some irritation. Skin - irritation on repeated exposures. 2. Chrome Overexposure Repeated overexposures Bay cause liver and kidney effects. Medical Conditions Generally Aggravated by Exposure High levels (8000 ppm + ) of vapor nay cause cardiac arrbythnias Chemical Listed as Carcinogen National Toncology YeQ SflC Ye* ' OSHA w Potential Carcinogen_____________ProgramNo tXX Monograph*No XX__________________________________________________ Ye* C No XX Emergency and First Aid Procedures (if symptoms persist, call a physician) 1 Inhalation j^oove to fresh air, apply artificial respiration if necessary. 2 Eyes Plush for 15 ainutes with large amounts of water. 3. Skin Remove contaminated clothing, wash exposed area with soap and water. 4 Ingestion do NOT induce vomiting - call physician 7. SPILL OR LEAK PROCEDURES Precautions to be taken m Handling anti Storage Store in a cool, dry place. Steos to be taken m case Materials is released or spilled Usually not a problem with aerosols. Area should be ventilated and absorbent used to pick up excess material. Waste Disposal Discarded full cans or partially filled cans are considered Hazardous Waste - Dispose of in conformance with Local, State and Federal regulation 8. SPECIAL PRECAUTIONS AND USE DIRECTIONS Avoid skin contact or breathing of vapors. Since vapors are heavier than air, aerosols should not be used in confined areas or low spots without adequate ventilation. If vapors are suspected in a low area, do not enter unless special breathing apparatus is used and an observer is present for assistance. Keep aerosols away from heat. PREPARED BY: Allen EL Reed ORIGINAL DATE OR DATE OF REVISION 3'90 SAL 000006442 MATERIAL SAFETY DATA SHEET si VI PRODUCT NAME Fleetrieal Ouallfcv Silicon* MANUFACTURED BY: CRC CHEMICALS fA*rnr>lt #2094 # MEDS002094 Phone (215)674-4300 | 885 LOUIS DRIVE. WARMINSTER. PA. 18974 1. INGREDIENTS CAS# Dimethyl polvslloxane 63148-62-9 **1.1,1 Trichloroethane 71-55-6 Petroleum Nanhtha Carbon dioxide 64742-89-8 124-38-9 ACGIH TLV NA 350 NA 5000 OSHA PEL MA 350 500 1QQ00 Other Limits 100 % 3 51 42 4 Carbon dioxide functions as propellent for t his pro< net* aerosol is 85 psier at 7C F. P ressure of **This chemical found on t le Toxic Chemical Li; it found in Sect Emergency Planning and Comm jnity Right-To-Know i ict, (SAR A Title subject to release inventor r reporting under thi A. on 313 5 f the III) an i is 2. PHYSICAL DATA (Propellent not included) Specific Gravity 0*9268 Vaoor Pressure NA % Volatile 97 soiling Point 152 F (Initial Evaporation Rate Rapid Freezing Point NA Vapor Oensity Heavier than air Appearance and Odor Clear water white liquid - solvent odor Solubility Not soluble in water 3. FIRE AND EXPLOSION DATA Flashpoint ^20I Method TCC Flammable Limits Extinguishing Media Foam, Carbon iioxide. Drv chemicals LEL UEL Unusual Hazards Aerosol cans ray exnlode when heated above 130F. MA 4. REACTIVITY AND STABILITY Stability______ Stable Hazardous decomposition products Therral (Carbon monoxide, hydrogen chloride, and posgih Materials to avoid strong oxidizers,phosaene 5. PROTECTION INFORMATION emilation Reouired In a confined area to maintain vapor below TLV Respiratory Self contained breathing apparatus Gloves Solvent resistant Eye & Face Safety Connies Other Protective Equipment Mot normally required for aerosol nao SAL 000006443 Gsi4f. MFDP002094 6. HEALTH HAZARD DATA________________________________________________ _______________ Primary Routes o* Entry Inhalation and Skin Signs and Symptoms of Exposure ______ 1. Acute Overexposes inhalation - Headache, dizziness, nausea, anesthesia & unconsciousness, Fyes - may be irritating to eves, Pfcin - mav be irritating to akin, 2. Chronic Overexposurs - Prolonged high levels of the petroleum naphtha may damaee tissue - high levels of 11*_1 trichloroethane may affect 11vt- and kidney* Medical Conditions Generally Aggravated by Exposure . Usud m CarcMiegan iy Potfiril Cjfonoq^n NttionM Toncotogy Program _______ VhG *S29L I>A>A.C* __ YnQ *> to OSHA ym G ----------- fe-to. Emergency and First Aid Procedures (if symptoms persist, call a physician) 1 Inhalation Remove to fresh air - apply artificial respiration if needed. 2. Eyes plush with larae amounts of water. 3. Skin wash with soap and water - Remove contaminated clothing, 4 Ingestion no^ induce vomiting.___________________________________ ________________ 7. SPILL OR LEAK PROCEDURES P'wunon* to tM tMfl * ,,_ Hai>3hnqstery -tore in a cool dry area. $i#o* 10 M tkn ifi ciu Remove sources of ignition, ventilate area. Ahgnrh liguid and put in a vapor tight container._________________________________________ Waste Disposal Partially used and unused aerosols are hazardous waste if discarded. Dispose in conformance with Federal. State * lnr*l rpouhfiork 8. SPECIAL PRECAUTIONS AND USE DIRECTIONS Aerosols may explode if exposed to temperatures over 130F. PREPARED BY: a.R. Reed ORIGINAL DATE OR DATE OF REVISION 3-90 SAL 000006444 Material Safety Data Sheet met*Mav to aeed ic mralr with OSHA't Haterd Communication Standard. 1910-1900 Standard MMt to oononhort hr *ocUk niuiinny VILE NO. 920:405-S22WA-3 . WICK nDfTinEH #1000 Green Concentrate _ . 8.1 t SECTION 1 Kidtowf'i H* Meriam Instruments City. State, vd ZIP 10920 Madison Ave. Cleveland/ Ohio 44102 Afaatveaf Pweon Kee|eun1lili for FnpiniNB (Optioul) SECTION 2 - HAZARDOUS INGREDIENTS/IDENTITY ^t216) ,281-1100 CUb (216) 281-1100 Date 2-23-90 Hazardous Componenti*) (chemical A i--r*-- name(e)) Butyl Cellosolve (CAS#lll-76-2) Ethylene Giycol (CASI107-21-1) Water (CASI7732-18-5) 0SHA PEL 5oppcn (air) N.A. ACG1H TLV Other tiMwt LmuU 50pg*n -(air)-- 1L.& lOOppm (vatwL) N.A, % tftiOMll 3.7 10.3 25.7 CAS NO. APrnsni trr somrion icasii//-! i-/t Sodium Bicarbonate (CAS#144-55-8) T\ N.A. N.A.. N.A. Trace Green Dve (CAS#518-47-8) Green Dye (CAS#19381-50-l) N.A* N.A. N.A. N.A. N.A. N.A. Trace SECTION 3 - PHYSICAL & CHEMICAL CHARACTERISTICS SSf* 310F Vapor Density (Air ll ^^ Solubility feweier' Completely miscible Appearance sdOdor Green# odorless teedto Gravity (H.O-11 1.0 Reactivity in Water Melti&f hint Nil SECTION 4 - FIRE & EXPLOSION DATA Flash NOn *** Flashinq Aute-lfnition Temperature .. - Method v~* Special Tin Ftfnti&i Pmedurw Estinfuiiher Media Flammable Limit* LEL to Air 1 by Volume Lower CO,,, Dry Chem. N.A. Vapor Pleasure tom Hr* 20 DEL u--r N.a Unusual Fire and Esploaioa Hxxkrdt None SAL 000006445 6ECTI0N ft- PHYSICALHAZARDS {REACTIVITY DATA) N-A. " ^Mnatof^di Oxidizing agents and alkalies_________ Hazardous Decccywitki hsdsrtl N.A. Hazardous May Occur 1D Conditirese Friy--riiatif Will Net Occur c3 Avoid N.A. *8 1-8 1 SECTION 6 - HEALTH HAZARDS Headaches/ nausea/ narcosis SftygjnapsLcaea&ds ofExposure R Chitoe N.A. a MAe|d|riciavlmConj bdiytioSaaspGoer/oreeraBy N.A. Chemical Listed m Carctoofsa cr Poteotial CardDOfen ZtMtftnn iod First Aid Preeeduree National Toxicology Y-- Q rrofram No 0 LAAC. Vee O Nooofrapha No B OSHA Yea D No I. lohalaUon ROUTES OF ENTRY 2. Eyes 2. Skifi 4. Ingestion Remove to fresh air. consult Dhvsician. Flush with water/ consult physician. Wssh with uafer Drink large quantity's of water, induce vomiting, consult nhvsigj SECTION 7 - SPECIAL PRECAUTIONS AND SPILL/LEAK PROCEDURES Precautions to bt Taken te Handlingand Swage__________ Keep container closed. Other Precautions Steps lo be Taken in Case Materia] is biassed Spilled______ Flush with water, clean up with absorbent. Wane Disposal Methods (Consult federal, state, and local regulations) Incineration SECTION 8 - 6PECIAL PROTECTION INFORMATION/CONTROL MEASURES Respiratory Protection fSpeofy T>pe) None Ventilation Yes Local Eaheust Protective" Cloves Rubber gloves Other Protective Clothing or Equipment K-A. Varkti/puut Practices N. A. Mechanical Special IGanarali N.A. N.A. |r* Protection Safety glasses Other N.A. SAL 000006446 IMPORTANT Do sot leave any blank epacea. If required information U unavailable, unknown, or does not apply, ao Indicate. C0FlR Printed by Labefmester, Dtvinon of American LaSelmartt Company Inc Chicago, IL 60&464719 1 -8004214606 (321) 476-0900 fl A 4 1 111 tk'F'Mi'H t hit?: A!-. r: ?1 rn ,n i'i.l i i- 'j ; n A T F k I! A t BAFtlY UA l A SH b F:! I bii l Fi h V I. H !. (J M U f s 0 t - O 4-9 0 *8226 I`u IS i .{_ ; ! : ill i;) /.i <A VI \ '-`AM If i 1- i '1 j ` A 1 'Y i.H MHJ YAK ! : , ;i. j .. ,:i ,'j ; ' H ) --O / i ) n A;..' !. t'tf; I-.:!M I ' Y A A ! A T ,N I .!-. !! r! VIJ L A r!A .... H !; M I.LR Lb L ALL CM L!'! ! * I- < 'J 0 0 ') 4 M 4-9 AHA ------ --- -.....-........--------- ---------- ------- i- ! sK l-'kLUiimH ! i a Ml. F.S | Hi- Hl\(Th-> I ! MM-------- --- ------ ---------------------- - -.....! ' !! A: V'MM Li A I ! ' A y A A' 'MAKA KAMI ' i ; !i-S JHH. I I ! I ! ':. !! > " A II `; !- I-'! ' 1 . f !!''!'!!!!! 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V0 11 iMK I I !!-1!' : Ml i" 1! " 'mi 1 u,-` Cl H F ! A M- r i .1 l-.'l- i i !' .. 'livi. '' K' : .1 ' I. i:.l A:. .a:, a ' l i- ! i ! i Ilf-! . i l J AM 1 I" Ml) I I. AI-1 -.A ! 111-:a:.l Y AM ! ! i ' !!:!-! . i M'-l L! If! i' I M l.ti- ! I i M N .1 N ii ''' ' A I M A I : *! 01 '' :.! I.:;.: 4 6 i M)S SAL 000006447 pi 241 $226 MIWHM. TMF MATERIAL SAFETY IfATA SHEO PG REVISION UK*01-04- L! A i k !-nw I0. M t NU I r;.B . REMOVE L'tlMI'AMI HA VELD CLOTHING AMO SHOfc.8; WASH Cl i ii HIMC-i Hi- y OKH PLUSH. PXSCAPn COM'I AMiNA'JLO Lfc'A'I HEP ARTICLtb. Gfc. I root- ii i;a n::; m::u !'cal a i n- h rion. if- ! I IIUI- ns HO Mt a JNOUCL U0M3 1 ING. jF CONSCIOUS, GIVE LUlii UF UA I >". c.O.S,, LSI rMrtKJl ' A I'f. HI-. MJCAL fii fTl'IfiGN. W) NO f GtVL AH'! i HJ.NC F Y O' M ! ! H 1 ft (-ii-! I !N! ! IMPS ; f)i )S >i K !N 001., S !. NO PERSON .......................................... -......... - ------- Jit- At fo HA,-: AKH ! MCOST1!A I 1 ON------------------------ ----- ----- ------------ I > !..> ; (f! ,C, ( ' F I.VsosOHi-s SK'in fip F Yh CUMlACI, ]NHA! Ai 3UN, SWALLOWS Ni- !'.!!: I ! 1 '-NS I M- X U. ' ; ut`2 VafOPO AMU NiSiS ARL EXlPLOLl. t CUPKf ;S i Vf- iU 1 Hi- MOSi- i !-f t1 O'H'OUH- MPPANLH ,, ftKUMP-li. I'[S, PULMtJM AK r OOP i H: !- i i 0 ON ! t O- NAT OCCUR . 'i KK I I A'f ION, COUCH.I NO, CHfcCl PAIN, A Is i i pvt- o t ri ! NO NAT OCCUR 01 fH P'\ i' f> P Xi-'OSUh'F. WH.I.Lh PPOLUMbf: 0 iso k`- Sin V : M PlfUft! H ! STOKPANCES, miKi; SfcObiKt IKS'} I A l ION ANo SPIN n~J 1 NO 1-1.1 f.l ri i fONC!;; 0 i'KA f .! OHS OAT KHGUL Ph A fH FTP COM I AC) S . i-f- i H .. OK ' N- KKM-P COM | AC l 1.0 'K! i; t iNt.,!- U OljH CAi nv HI 1M00I-SH,. VAPORS, }-. IC-fUID, A Mil M.iSTS AKb fc.XTRhPlfc.LY CUKKuSIVfc. )u CUMfACf OK fHK VAPORS URL HP SHVfcKLL Y .1. KK 1 ( A f I HU . ! HF. L I ON j U OK MIS IS WILL SEVERELY HANAGE i Hfc. EYIr.S ANT NAY CAUSE Ph.KMANLN V fcYfc INJURY WHICH OAt PL FULLOWfci* .OR ! HP .) > CON'I ACT NAY i ANSI- PUkMS. PRIM. ONUfc i! CON i AC i !vVT HF AbP i k' H K j.1 I Hh'OUL'H ! ML h-YCt.N c!N f t Cf-'iUSK ! (..(/. KU1A1 i :1 t VAPliP?'> - I'HbR;. AMlt L. 1 f..'U .1 H APh F.X I KKHLLY CC'NKUS 1 Of; i 0 ;'!!! MtXi'AlC. ? WAi. !. OW I. N-i (HE LiULUi.i CUKMS ! Hfc I I.PPULb, CAl.ISfk : P- ;-!!! i !!';; im A i. PC 1 M , NAUSf.-. A., VOC11 JHO. A NO CO!.LAPSE. SWALl.OWi.MU > C'k-,' [" AIM *. : i'r'S I Ac! OAOSt- i.lF A f H ,, PHk'OPC. PH-H.lH 0) t ''PU'-XJPF " HO SPECIF JC j.MFUKOAilON A VA ] L. A HLC, HO l ON:-.!- :< v!-'!!';;iiKh HAS f.AU'if O KOiNt.Y A N.ii LIVCK HAMAOt J. N C>: pa-K1 riii.N ! AL AN HAi.S .. i- ! :> !N;i ; i 'j OM til-.M!- PA!. ! AOi-fkAVA I 1.11 HY < PUSUKK NUNC KLPOki Hi. I OX rci. t Y HA ! A opals HU NAN !. H!j; - Su PC/KG f.f *- kNAls; HkiHh! i I ! r;.o X 0 4 PS/' G`-i M.-HA! A'! M !!:: PA! ! OK'"' r- OL'OO PhN/S HP r r f.;).:; K;H;: r-! ; i' f ) r " i :! [;.; o A !>>.:!. A!. I:.; Pol (G'lMs 1. hup! u !ii Hi. a hhhc 1 NU!.> M Y i HI' :`A' ii'Ms i 0>S' KOI .OGY PPOCPAN, THI- '! M l )- SNA I ' GOAL AGLNCY M.!p A.-.'; >! iiri i. AH;/":/ Ok :Hi. of :CUpa !'i OH AL sAi-: ( t ANli Hfc.Ai. m aisMlM l.S I PA I j i ! MKK HA'I AS Si. R Vi. SOPS'! JTO.'LO N--N.I ! PUii AM 1 Mi: f;, KNOWN ill PH PiJiHNl ! i HfH: t; OS . ITS HK -R/n;.: U Of-.' 0 ; P }. S PKOlUJl'T COOPS IN CVNlACf W I ! H KfO:; ACiP - OOKGAM .( 1AMli OcoAH)f: r!X '! P j i PSOP A S NOSPHFKFS W1IH H i ! iM O t ;!0.!0 ; 'OOCIH I OA !.! ) 'MS . OSH MilKflfc / r-U i - 'A I !:. !:: H liaiKk h'h-o 1 :: Apo;-one. soi.iii oc. ( '. ft:p! Hi- (. HAM t ft} F LHAOST VI- !-ri .( !.. Ai .1 ON CftPftH!..fc Of- ns.! 0' *: ,J \ ` ' 1 * 01 o'- OGF. Pi0..uu ; HP PEL. ; 111 i: : ! i ip ;; ; L ' ,/ I ; i r.. ( J k. ; ! Or.: ! Hf OA: T ! - ;!'!, ! I ';! i'i ft' ! i :-0;.0 OS1; ' ' ::0` ' f oNp. i:l MIHaIL VAPPP'-: {ts- ni S l P , 1 ; M-'K ! A j ;.!); ! ! j:- j: i; *;/ ; i.h/ './ Si f* : PL! i Al,i: I-'J L Cl A'I p-I-' Ok. I T'fOG CT.K i !: ! I 01 fiAi-SM f`l! t)!!-.. .. (!! >. A Slji-'l-'LJ i-.P-A P PFSPiOAsn; i// .-(Mii !'!!! ! > AiO.Si-1! LLP ' /, 0. f.':- H O, - ' ' A 0SO;C:' : H/1J ; r|: ; O 1 , >;.>L- \ 000006448 SAL fc' 1.241 MORPHOLINE MATERIAL SAFETY OATA SHEE f 68226 kfc.M3.SUJN 01- S03-04-V0 I-Ai'fc fc'Ifc'OF RESPIRATOR IS ALSO WORN- 3T IS Gfc.NE.RAU. Y RtCUGM 1ZLU THAI' I 0N ' Af. i iWNHfc'B SHOO!. 0 NO f BE WORN WHEN WORKING Wl I'H CHh.m.GAL.fc) # CAUSE. I. fc NRt.fi MAY CON I R J BUI fc! HI THfc SFVbRl TY 01- AN EYE 3NJUKY. 5 > r r : ut Li I) f H 1 Nii" I. OMii - BL l::. fc.Vh.JLi SHIRT ? ! ROUSE NS . kUt'TL. KURtfLK HRU ! U, i-Mt'Ti k uluvl.s, piNii kUiri rusher apron. .I l- ;:o,'l-!'T III S-M . I7!!- AS URLS s RfcAOY FOR US!" , fc. Y h WASH AMU SUFLir -:i'Un-.K UhL ' t.`!. .U Hfc. ANI! fc XHi US I (iN .!. Nfc (IWMA I !- 00 H I . H r.:`! > I" ' II."| : :: !l! USfcJ!: LUG X ' i ;.(i.;i1.1 ->! ; Mb ML! I I. A S ! : 1 1:' . : ). fX r: P:I- :. !Ti I. LUWfc H 2 l . 'c. ,H"1 `I;: K i! 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EJH 100 1 T I H OR.n:A I JOO. \ -x- -x -x EN j i.i f-i S ii : -x-x-a-x- sal 000064SO MATERIAL SAFETY DATA SHEET NALCO PRODUCT NALCO 19 PULV OXYGEN SCAVENGE Emergency Telephone Number Medical (708) 920-1510 (24 hours) SECTION 1 PRODUCT IDENTIFICATION TRADE NAME: NALCO 19 PULV OXYGEN SCAVENGER * DESCRIPTION: A blend of sodium metabisulfite, sodium sulfite and cobalt sulfate* NFPA 704M/HMIS RATING: 1/1 HEALTH 0/0 FLAMMABILITY 0/0 REACTIVITY 0=lnsignificant l=Slight 2=Moderate 3=High 4=Extreme 0 OTHER* SECTION 2 HAZARDOUS INGREDIENTS Our hazard evaluation has identified the following chemical ingredient(s) as hazardous under OSHA's Hazard Communication Rule, 29 CFR 1910.1200. Consult Section 14 for the nature of the hazard(s). INGREDIENT(S) CAS # APPROX.% Sodium metabisulfite 7681-57-4 1-5 SECTION 3 PRECAUTIONARY LABEL INFORMATION * * * * * * * CAUTION: May cause irritation to skin and eyes. Avoid contact with eyes. Avoid prolonged or repeated contact with skin. Avoid breathing dust. Do not take internally. * * Empty containers may contain residual product. Do not reuse container unless properly reconditioned. * * SECTION 4 FIRST AID INFORMATION EYES: SKIN: INGESTION: INHALATION: Flush with water for 15 minutes. Call a physician. Flush with water for 15 minutes. Induce vomiting. Give water. Call a physician. Remove to fresh air. Treat symptoms. Call a physician. NOTE TO PHYSICIAN: No specific antidote is known. Based on the individual reactions of the patient, the physician's judgment should be used to control symptoms and clinical condition. CAUTION: If unconscious, having trouble breathing or in convulsions, do not induce vomiting or give water. SECTION 5 HEALTH EFFECTS INFORMATION PRIMARY ROUTE(S) OF EXPOSURE: Eye, Skin, Inhalation EYE CONTACT: Can cause transient irritation. PAGE 1 OF 7 SAL 00064SI NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1198 MATERIAL SAFETY DATA SHEET N ALGO 0S*28 PRODUCT nalco 19 pulv oxygen scavenge] Emergency Telephone Number Medical (708) 920-1510 (24 hours) SECTION 5 HEALTH EFFECTS INFORMATION ( CONTINUED ) SKIN CONTACT: INGESTION: INHALATION: May cause irritation with prolonged contact. Can be harmful. May cause irritation to the respiratory tract and lungs. SYMPTOMS OF EXPOSURE: Sodium sulfite. Ingestion is believed to cause an asthmatic, allergic reaction in susceptible individuals. AGGRAVATION OF EXISTING CONDITIONS: A review of available data does not identify any worsening of existing conditions. SECTION 6 TOXICOLOGY INFORMATION ACUTE TOXICITY STUDIES: Acute toxicity studies have not been conducted on this product, but toxicity studies of the ingredient(s) in Section 2 have been reviewed. The results are shown below. ACUTE ORAL TOXICITY (ALBINO RATS): Sodium bisulfite LDS0 = 2,000 mg/kg OTHER TOXICITY RESULTS: Sodium bisulfite. Intraperitoneal LDS0 (rat) = 650 mg/kg SECTION 7 PHYSICAL AND CHEMICAL PROPERTIES COLOR: Tan/grey BULK DENSITY: SOLUBILITY IN WATER: pH (AT 5%) = FLASH POINT: FORM: Powder 90 lbs/ftJ Completely 7.6 - 8.2 None ODOR: Sw ASTM E-70 NOTE: These physical properties are typical values for this product. SECTION 8 FIRE AND EXPLOSION INFORMATION FLASH POINT: None EXTINGUISHING MEDIA: Not applicable UNUSUAL FIRE AND EXPLOSION HAZARD: May evolve SOx under fire conditions. SECTION 9 REACTIVITY INFORMATION INCOMPATIBILITY: Avoid contact with strong oxidizers (eg. chlorine, peroxides,* chromates, nitric acid, perchlorates, concentrated oxygen, permanganates) which* PAGE 2 OF 7 SAL 000006452 iMM NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 6D5G3-119B MATERIAL SAFETY DATA SHEET NALCO PRODUCT NALCO 19 PULV OXYGEN SCAVENGE: Emergency Telephone Number Medical (708) 9201510(24 hours) g SECTION 9 REACTIVITY INFORMATION ( CONTINUED ) can generate heat, fires, explosions and the release of toxic fumes. * * Avoid contact with strong acids (eg. sulfuric, phosphoric, nitric, hydrochloric, chromic, sulfonic) which can generate heat, splattering or boiling and the release of toxic fumes. * * * THERMAL DECOMPOSITION PRODUCTS: In the event of combustion SOx may be formed. * Do not breathe smoke or fumes. Wear suitable protective equipment. * SECTION 10 PERSONAL PROTECTION EQUIPMENT RESPIRATORY PROTECTION: Respiratory protection not normally needed. If significant dusting occurs, wear a NIOSH approved or equivalent dust respirator, (ANSI Z 88.2, 1980 for requirements and selection). For large spills, entry into large tanks, vessels or enclosed small spaces with inadequate ventilation, a pressure-demand, self-contained breathing apparatus is recommended. VENTILATION: If significant dusting occurs, local exhaust ventilation is recommended. PROTECTIVE EQUIPMENT: No special precautions. Avoid eye and skin contact, and inhalation of dust. If clothing is contaminated, remove clothing and thoroughly wash the affected area. Launder contaminated clothing before reuse. SECTION 11 SPILL AND DISPOSAL INFORMATION IN CASE OF TRANSPORTATION ACCIDENTS, CALL THE FOLLOWING 24-HOUR TELEPHONE NUMBER (708-920-1510) SPILL CONTROL AND RECOVERY: Solid spills: Sweep or vacuum up and reclaim into recovery or salvage drums for disposal. Wear the protective equipment specified in Section 10. Refer to CERCLA in Section 14. DISPOSAL: If this product becomes a waste, it does not meet the criteria of a hazardous waste as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261, since it does not have the characteristics of Subpart C, (i.e. D001 through D017) nor is it listed under Subpart D. * * * * * * * * * * * PAGE 3 OF 7 SAL 0000064-53 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1190 ar^a 7oe-305-,nnn MATERIAL SAFETY DATA SHEET NALCO G S 2 28 PRODUCT NALCO 19 PULV OXYGEN SCAVENGE! Emergency Telephone Number Medical (708) 920*1510 (24 hours) SECTION 11 SPILL AND DISPOSAL INFORMATION ( CONTINUED ) As a non-hazardous solid waste, it can be disposed of in an industrial waste landfill in accordance with local, state, and federal regulations. SECTION 12 ENVIRONMENTAL INFORMATION AQUATIC DATA: 96 hour static acute LCS0 to Bluegill Sunfish = Greater than 10 ppm, less than 100 ppm (1% solution) 96 hour static acute LCS0 to Rainbow Trout - Greater than 100 ppm (1% solution) If released into the environment, see CERCLA in Section 14. SECTION 13 TRANSPORTATION INFORMATION DOT PROPER SHIPPING NAME/HAZARD CODE - PRODUCT IS NOT REGULATED DURING TRANSPORTATION SECTION 14 REGULATORY INFORMATION The following regulations apply to this product. FEDERAL REGULATIONS: OSHA'S HAZARD COMMUNICATION RULE, 29 CFR 1910.1200: Based on our hazard evaluation, the following ingredient in this product is hazardous and the reason is shown below. Sodium metabisulfite = TWA 5 mg/m3 ACGIH/TLV Sodium metabisulfite s TWA 5 mg/m3 OSHA/PEL CERCLA, 40 CFR 117, 302: Notification of spills of this product is not required. SARA/SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (TITLE III) - SECTIONS 302, 311, 312 AND 313: * * * * * * * * * * * SECTION 302 - EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355): This product does not contain ingredients listed in Appendix A and B as an Extremely Hazardous Substance. * * * PAGE 4 OF 7 sal 0000064-54- NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 6Q563-1198 MATERIAL SAFETY DATA SHEET NALCO PRODUCT NALCO 19 PULV OXYGEN SCAVENGE Emergency Telephone Number Medical (708) 920-1510(24 hours) S228 SECTION 14 REGULATORY INFORMATION ( CONTINUED ) SECTIONS 311 and 312 - MATERIAL SAFETY DATA SHEET REQUIREMENTS (40 CFR 370): Our hazard evaluation has found this product to be hazardous. The product should be reported under the following EPA hazard categories: ** * * XX Immediate (acute) -- Delayed (chronic) -- Fire hazard -- Sudden release of -- Reactive hazard health hazard health hazard pressure hazard * * * * * Under Section 311, submittal of MSDS's or a list of product names to the local * emergency planning commission, state emergency response commission and local * fire department is required after October 17, 1987 if you have: * nr -- 10,000 pounds or more of a hazardous substance, or -- 500 pounds or the threshold planning quantity, whichever is less, of an extremely hazardous substance. * * * SECTION 313 - LIST OF TOXIC CHEMICALS (40 CFR 372): This product does not contain ingredients (at a level of 1% or greater) on the * List of Toxic Chemicals. * * TOXIC SUBSTANCES CONTROL ACT (TSCA): The chemical ingredients in this product are on the 8(b) Inventory List (40 CFR 710). * * * * FOOD AND DRUG ADMINISTRATION (FDA): Federal Food, Drug and Cosmetic Act: When use situations necessitate compliance with FDA regulations, this product is acceptable under 21 CFR 173.310 Boiler Water Additive. * * * * * RESOURCE CONSERVATION AND RECOVERY ACT (RCRA), 40 CFR 261 SUBPART C & D: If this product becomes a waste, it does not meet the criteria of a hazardous waste. * * it FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 401.15 (formerly Sec. 307), 40 CFR 116 (formerly Sec. 311): None of the ingredients are specifically listed. * * * * CLEAN AIR ACT, 40 CFR 60, SECTION 111, 40 CFR 61, SECTION 112: This product does not contain ingredients covered by the Clean Air Act. * * STATE REGULATIONS: * PAGE 5 OF 7 SAL 000006455 NALCO CHEMICAL COMPANY ONE NALCD CENTER NAPERVILLE. ILLINOIS 60563-1190 6 S 228 IMALCO MATERIAL SAFETY DATA SHEET PRODUCT NALCO 19 PULV OXYGEN SCAVENGE! Emergency Telephone Number Medical (708) 920-1510 (24 hours) SECTION 14 REGULATORY INFORMATION ( CONTINUED ) CALIFORNIA PROPOSITION 65: None of the chemicals on the current Proposition 65 list are known to be present in this product. MICHIGAN CRITICAL MATERIALS: This product contains the following substance(s) identified on the Michigan Critical Materials Register: Cobalt sulfate STATE RIGHT TO KNOW LAWS: The following ingredients shown are disclosed for compliance with State Right To Know Laws: * * * * * * * * * * * * * Cobalt sulfate Sodium metabisulfite Sodium sulfite 10124-43-3 7681-57-4 7757-83-7 INTERNATIONAL REGULATIONS: This is a WHMIS controlled product under The House of Commons of Canada Bill C-70. The product contains the following substance(s), from the Ingredient Disclosure List or has been evaluated based on its toxicological properties, to contain the following hazardous ingredient(s): Chemical Name CAS # % Concentration Range Sodium metabisulfite 7681-57-4 SECTION 15 ADDITIONAL INFORMATION 1-5 None SECTION 16 USER'S RESPONSIBILITY This product material safety data sheet provides health and safety information. The product is to be used in applications consistent with our product literature. Individuals handling this product should be informed of the recommended safety precautions and should have access to this information. For any other uses, exposures should be evaluated so that appropriate handling practices and training programs can be established to ensure safe workplace operations. Please consult your local sales representative for any further information. PAGE 6 OF 7 SAL 000006456 m NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1198 MATERIAL SAFETY DATA SHEET NALCO PRODUCT NALCO 19 PULV OXYGEN SCAVENGE Emergency Telephone Number Medical (708) 920-1510(24 hour*) SECTION 17 BIBLIOGRAPHY ANNUAL REPORT ON CARCINOGENS, U.S. Department of Health and Human Services, Public Health Service, PB 33-135855, 1983. CASARETT AND DOULL'S TOXICOLOGY, THE BASIC SCIENCE OF POISONS, Doull, J., Klaassen, C. D., and Admur, M. 0., eds., Macmillian Publishing Company, Inc., N. Y., 2nd edition, 1980. CHEMICAL HAZARDS OF THE WORKPLACE, Proctor, N. H., and Hughes, J. P., eds., J. P. Lipincott Company, N.Y., 1981. DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS, Sax, N. Irving, ed., Van Nostrand Reinhold Company, N.Y., 6th edition, 1984. IARC MONOGRAPHS ON THE EVALUATION OF THE CARCINOGENIC RISK OF CHEMICALS TO MAN, Geneva: World Health Organization, International Agency for Research on Cancer, 1972-1977. PATTY'S INDUSTRIAL HYGIENE AND TOXICOLOGY, Clayton, G. D., Clayton, F. E., eds., John Wiley and Sons, N. Y., 3rd edition, Vol. 2 A-C, 1981. REGISTRY OF TOXIC EFFECTS ON CHEMICAL SUBSTANCES, U.S. Department of Health and Human Services, Public Health Service, Center for Disease Control, National Institute for Occupational Safety and Health, 1983 supplement of 1981-1982 edition, Vol. 1-3, OH, 1984. Title 29 Code of Federal Regulations Part 1910, Subpart Z, Toxic and Hazardous Substances, Occupational Safety and Health Administration (OSHA). THRESHOLD LIMIT VALUES FOR CHEMICAL SUBSTANCES AND PHYSICAL AGENTS IN THE WORKROOM ENVIRONMENT WITH INTENDED CHANGES, American Conference of Governmental Industrial Hygienists, OH. Information on this MSDS has changed. The changes are indicated by asterisks on the right side of only the changed sections. This is an updated MSDS as required by OHSA's Hazard Communication Rule 29 CFR 1910.1200. PREPARED BY: Ricky A. Stackhouse PhD., Toxicologist DATE CHANGED: 02/22/90 DATE PRINTED: 04/28/90 PAGE 7 OF 7 SAL 000006457 NALCO CHEMICAL COMPANY ONJE NALCO CENTER NAPERVILLE, ILLINOIS 60563-1193 NALCO MATERIAL SAFETY DATA SHEET PRODUCT Emergency Telephone Number Medical (708) 920-1510 (24 hours) SAL 0000064-58 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-11 SB MATERIAL SAFETY DATA SHEET PRODUCT NALCO 5163 CORROSION INHIBITOI NALCO OPR 0 8 gn Emergency Telephone Number Medical (708) 920-1510 (24 hours) CS287 SECTION 1 PRODUCT IDENTIFICATION TRADE NAME: NALCO 5163 CORROSION INHIBITOR DESCRIPTION: An alkyl amine condensate in a hydrocarbon solvent NFPA 704M/HMIS RATING: 2/2 HEALTH 2/2 FLAMMABILITY 0/0 REACTIVITY 0=lnsignificant l=Slight 2=Moderate 3*High 4=Extreme SECTION 2 HAZARDOUS INGREDIENTS Our hazard evaluation has identified the following chemical ingredient(s) as hazardous under OSHA 's Hazard Communication Rule, 29 CFR 1910.1200. Consult Section 14 for the nature of the hazard(s). INGREDIENT(S) CAS # APPROX.% Ethylbenzene Naphthalene Xylene Heavy aromatic naphtha 100-41-4 91-20-3 1330-20-7 68603-08-7 10-20 1-5 5-10 40-70 0 OTHER * * * * * * * * SECTION 3 PRECAUTIONARY LABEL INFORMATION WARNING: Causes irritation to skin and eyes. Combustible. Prolonged inhalation of vapor may be harmful. Do not get in eyesr on skin or on clothing. Wear goggles and face shield when handling. Avoid prolonged or repeated breathing of vapor. Use with adequate ventilation. Do not take internally. Keep away from heat and open flame. Keep container closed when not in use. Empty containers may contain residual product. Do not reuse container unless properly reconditioned. SECTION 4 FIRST AID INFORMATION EYES: SKIN: INGESTION: INHALATION: Immediately flush with water for at least 15 minutes while holding eyelids open. Call a physician at once. Wash thoroughly with soap and rinse with water. Call a physician. Do not induce vomiting. Give water. Call a physician. Remove to fresh air. Treat symptoms. Call a physician. NOTE TO PHYSICIAN: No specific antidote is known. Based on the individual reactions of the patient, the physician's judgment should be used to control symptoms and clinical condition. # # * PAGE 1 OF 9 ooooofc459 SA'- NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS BQ563-1 190 & 6S28T NALCO MATERIAL SAFETY DATA SHEET PRODUCT NALCO 5163 CORROSION INHIBITOI Emergency Telephone Number Medical (708) 920-1510 (24 hours) SECTION 4 FIRST AID INFORMATION ( CONTINUED ) CAUTION: If unconscious, having trouble breathing or in convulsions, do not induce vomiting or give water. SECTION 5 HEALTH EFFECTS INFORMATION PRIMARY ROUTE(S) OF EXPOSURE: Eye, Skin, Inhalation * * EYE CONTACT: SKIN CONTACT: INHALATION: May cause moderate irritation. May cause moderate irritation. Prolonged inhalation of vapor may be harmful. * * * * SYMPTOMS OF EXPOSURE: ACUTE: Inhalation of high concentrations of product can cause nausea, dizziness, vomiting, stupor or unconsciousness. * * it CHRONIC: Prolonged skin contact with product can cause dry skin and defatting * resulting in irritation and dermatitis. * AGGRAVATION OF EXISTING CONDITIONS: A review of available data does not identify any worsening of existing conditions. * SECTION 6 TOXICOLOGY INFORMATION ACUTE TOXICITY STUDIES: No toxicity studies have been conducted on this product. SECTION 7 PHYSICAL AND CHEMICAL PROPERTIES COLOR: Opaque dark amber FORM: Liquid DENSITY: 7.7 lbs/gal. SOLUBILITY IN WATER: Insoluble SPECIFIC GRAVITY: 0.92 8 60 Degrees F FLASH POINT: Minimum 120 Degrees F (PMCC) ODOR: Hydrocarbon ASTM D-1298 ASTM D-93 NOTE: These physical properties are typical values for this product. # it it * # SECTION 8 FIRE AND EXPLOSION INFORMATION FLASH POINT: Minimum 120 Degrees F (PMCC) ASTM D-93 * EXTINGUISHING MEDIA: Based on the NFPA guide, use dry chemical, alcohol foam, * carbon dioxide or other extinguishing agent suitable for Class B fires. Use * water to cool containers exposed to fire. For large fires, use water spray or * fog, thoroughly drenching the burning material. * PAGE 2 OF 9 sM. 000006460 a NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 6D563-119B ** MATERIAL SAFETY DATA SHEET NALCQ PRODUCT NALCO 5163 CORROSION INHIBITOR Emergency Telephone Number *S i 37Medical (706) 920-1510 (24 hours) SECTION 8 FIRE AND EXPLOSION INFORMATION ( CONTINUED ) UNUSUAL FIRE AND EXPLOSION HAZARD: May evolve NOx under fire conditions. Containers exposed in a fire should be cooled with water to prevent vapor pressure buildup leading to a rupture. SECTION 9 REACTIVITY INFORMATION INCOMPATIBILITY: Avoid contact with strong oxidizers (eg. chlorine, peroxides, chromates, nitric acid, perchlorates, concentrated oxygen, permanganates) which can generate heat, fires, explosions and the release of toxic fumes. * * * * THERMAL DECOMPOSITION PRODUCTS: In the event of combustion CO, C02, NOx may * be formed. Do not breathe smoke or fumes. Wear suitable protective equipment.* SECTION 10 PERSONAL PROTECTION EQUIPMENT RESPIRATORY PROTECTION: Respiratory protection is not normally needed since the volatility and toxicity are low. If significant vapors, mists or aerosols are generated, wear a NIOSH approved or equivalent respirator, (ANSI Z 88.2, 1980 for requirements and selection). For large spills, entry into large tanks, vessels or enclosed small spaces with inadequate ventilation, a pressure-demand, self-contained breathing apparatus is recommended. VENTILATION: General ventilation is recommended. PROTECTIVE EQUIPMENT: Wear gloves, boots, apron and a face shield with chemical splash goggles (ANSI Z 87.1 requirements and selection of gloves, goggles, shoes, etc.). A full slicker suit is recommended if gross exposure is possible. The availability of an eye wash fountain and safety shower is recommended. If clothing is contaminated, remove clothing and thoroughly wash the affected area. Launder contaminated clothing before reuse. SECTION 11 SPILL AND DISPOSAL INFORMATION IN CASE OF TRANSPORTATION ACCIDENTS, CALL THE FOLLOWING 24-HOUR TELEPHONE NUMBER (708-920-1510) SPILL CONTROL AND RECOVERY: PAGE 3 OF 9 06 NALCQ CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1 19B GS237 NALCQ MATERIAL SAFETY DATA SHEET PRODUCT NALCO 5163 CORROSION 1NHIBIT01 Emergency Telephone Number Medical (708) 820-1510 (24 hours) SECTION 11 SPILL AND DISPOSAL INFORMATION ( CONTINUED ) Small liquid spills: Contain with absorbent material, such as clay/ soil or any commercially available absorbent. Shovel reclaimed liquid and absorbent into recovery or salvage drums for disposal. Refer to CERCLA in Section 14. Large liquid spills: Dike to prevent further movement and reclaim into recovery or salvage drums or tank truck for disposal. Refer to CERCLA in Section 14. For large indoor spills, evacuate employees and ventilate area. responsible for control and recovery should wear the protective equipment specified in Section 10. Those Keep the spill away from heat, sparks, flames and welding operations. Ventilate area and evacuate employees from exposure if the airborne concentration exceeds the TLV. Refer to Section 14. DISPOSAL: If this product becomes a waste, it meets the criteria of a hazardous waste as defined under the Resources Conservation and Recovery Act (RCRA) 40 CFR 261. Hazardous Waste D001. As a hazardous liquid waste, it must be solidified with stabilizing agents (such as sand, fly ash, or cement) so that no free liquid remains before disposal to a licensed industrial waste landfill (Hazardous Waste Treatment, Storage and Disposal facility). A hazardous liquid waste can also be incinerated in accordance with local, state, and federal regulations. SECTION 12 ENVIRONMENTAL INFORMATION If released into the environment, see CERCLA in Section 14. SECTION 13 TRANSPORTATION INFORMATION DOT PROPER SHIPPING NAME/HAZARD CODE - COMBUSTIBLE LIQUID, N.O.S. COMBUSTIBLE LIQUID NA 1993 CONTAINS - XYLENE, NAPHTHALENE SECTION 14 REGULATORY INFORMATION The following regulations apply to this product. FEDERAL REGULATIONS: OSHA'S HAZARD COMMUNICATION RULE, 29 CFR 1910.1200: PAGE 4 OF 9 SAL 000006462 MALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1*00 V M NALCO MATERIAL SAFETY DATA SHEET PRODUCT NALCO 5163 CORROSION INHIBITO Emergency Telephone Number G S 2 3 7Medical (708) 920-1510 (24 hours) SECTION 14 REGULATORY INFORMATION ( CONTINUED ) Based on our hazard evaluation, the following ingredients in this product are hazardous and the reasons are shown below. Heavy aromatic naptha - Skin irritant, Ethylbenzene - Eye irritant Naphthalene - Eye irritant Xylene - Eye irritant combustible Ethylbenzene = TWA 100 ppm, STEL 125 ppm ACGIH/TLV 434 mg/m3, 543 mg/m3 ACGIH/TLV Naphthalene = TWA 10 ppm, STEL 15 ppm ACGIH/TLV 52 mg/ra3, 79 mg/ra3 ACGIH/TLV Xylene = TWA 100 ppm, STEL 150 ppm ACGIH/TLV 434 mg/m3, 651 mg/m3 ACGIH/TLV Ethylbenzene = TWA 100 ppm, STEL 125 ppm OSHA/PEL 435 mg/m3, 545 mg/m3 OSHA/PEL Naphthalene = TWA 10 ppm, STEL 15 ppm OSHA/PEL 50 mg/m3, 75 mg/m3 OSHA/PEL Xylene = TWA 100 ppm, STEL 150 ppm OSHA/PEL 435 mg/m3, 655 rag/ra3 OSHA/PEL Heavy aromatic naptha ** 100 ppm TLV Manufacturer's recommendation CERCLA, 40 CFR 117, 302: This product contains naphthalene, a Reportable Quantity (RQ) substance and if 2,300 pounds of product are released, it requires notification to the NATIONAL RESPONSE CENTER, WASHINGTON, D. C. (1-800-424-8802). SARA/SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (TITLE III) - SECTIONS 302, 311, 312 AND 313: SECTION 302 - EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355): This product does not contain ingredients listed in Appendix A and B as an Extremely Hazardous Substance. * * * * * * * * * * SECTIONS 311 and 312 - MATERIAL SAFETY DATA SHEET REQUIREMENTS (40 CFR 370): Our hazard evaluation has found this product to be hazardous. The product should be reported under the following EPA hazard categories: * * * XX Immediate (acute) health hazard -- Delayed (chronic) health hazard XX Fire hazard PAGE 5 OF 9 SAL 0000064-63 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1108 M S23T NALCO ' MATERIAL SAFETY DATA SHEET PRODUCT NALCO 5163 CORROSION INHIBITOf Emergency Telephone Number Medical (708) 920-1510(24 hours) SECTION 14 REGULATORY INFORMATION ( CONTINUED ) -- Sudden release of pressure hazard -- Reactive hazard * * * Under Section 311, submittal of MSDS's or a list of product names to the local emergency planning commission, state emergency response commission and local * fire department is required after October 17, 1987 if you have: * - 10,000 pounds or more of a hazardous substance, or - 500 pounds or the threshold planning quantity, whichever is less, of an extremely hazardous substance. * -* * SECTION 313 - LIST OF TOXIC CHEMICALS <40 CFR 372): This product contains the following ingredient(s), (with CAS # and % range) which appear(s) on the List of Toxic Chemicals. * * * Ethylbenzene Naphthalene Xylene 100-41-4 91-20-3 1330-20-7 10-20 1-5 5-10 * * * * TOXIC SUBSTANCES CONTROL ACT (TSCA): The chemical ingredients in this product are on the 8(b) Inventory List (40 CFR 710). * * it RESOURCE CONSERVATION AND RECOVERY ACT (RCRA), 40 CFR 261 SUBPART C & D: If this product becomes a waste, it does meet the criteria of a hazardous waste as defined under RCRA 40 CFR 261 (consult Section 11). * * * * FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 401.15/ formerly Sec. 307, 40 CFR 116/formerly Sec. 311: * This product contains the following ingredients covered by the Clean Water Act:* Naphthalene - Section 307, 311 Ethylbenzene - Section 307, 311 Xylene - Section 311 CLEAN AIR ACT, 40 CFR 60, SECTION 111, 40 CFR 61, SECTION 112: This product contains the following ingredients covered by the Clean Air Act: Ethylbenzene - Section 111 Xylene - Section 111 STATE REGULATIONS: * * it * * * * * * * PAGE 6 OF 9 _ AL 0006464 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINO;S 60563-1 19S MATERIAL SAFETY DATA SHEET NALCO PRODUCT HALCO 5163 CORROSION INHIBITO Emergency Telephone Number Medical (708) 920-1510 (24 hours) <*8237 SECTION 14 REGULATORY INFORMATION ( CONTINUED ) CALIFORNIA PROPOSITION 65: Substances known to the State of California to cause cancer may be present as an impurity or residue. MICHIGAN CRITICAL MATERIALS: This product contains the following substance(s) identified on the Michigan Critical Materials Register: Naphthalene, Xylene STATE RIGHT TO KNOW LAWS: The following ingredient(s) are disclosed for compliance with State Right To Know Laws: Alkylamide condensate Ethylbenzene Heavy aromatic naphtha Naphthalene Xylene 100-41-4 68603-08-7 91-20-3 1330-20-7 * * INTERNATIONAL REGULATIONS: This is a WHMIS controlled product under The House of Commons of Canada Bill C-70. The product contains the following substance(s), from the Ingredient Disclosure List or has been evaluated based on its toxicological properties, to contain the following hazardous ingredient(s): Chemical Name CAS # % Concentration Range * * * * Ethylbenzene Naphthalene Xylene Heavy aromatic naphtha 100-41-4 91-20-3 1330-20-7 68603-08-7 10-20 1-5 5-10 40-70 * * SECTION 15 ADDITIONAL INFORMATION F 302662 if SECTION 16 USER'S RESPONSIBILITY This product material safety data sheet provides health and safety information. The product is to be used in applications consistent with our product literature. Individuals handling this product should be informed of the recommended safety precautions and should have access PAGE 7 OF 9 $AL 0ooo 65 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1190 M |23T NALCQ MATERIAL SAFETY DATA SHEET PRODUCT NALCO 5163 CORROSION INHIBITOI Emergency Telephone Number Medical (708) 920-1510 (24 hours) SECTION 16 USER'S RESPONSIBILITY ( CONTINUED ) to this information. For any other uses, exposures should be evaluated so that appropriate handling practices and training programs can be established to ensure safe workplace operations. Please consult your local sales representative for any further information. SECTION 17 BIBLIOGRAPHY* I ANNUAL REPORT ON CARCINOGENS, U.S. Department of Health and Human Services, Public Health Service, PB 33-135855, 1983. CASARETT AND DOULL'S TOXICOLOGY, THE BASIC SCIENCE OF POISONS, Doull, J., Klaassen, C. D., and Admur, M. 0., eds., Macmillian Publishing Company, Inc., N. Y., 2nd edition, 1980. CHEMICAL HAZARDS OF THE WORKPLACE, Proctor, N. H., and Hughes, J. P., eds., J. P. Lipincott Company, N.Y., 1981. DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS, Sax, N. Irving, ed., Van Nostrand Reinhold Company, N.Y., 6th edition, 1984. IARC MONOGRAPHS ON THE EVALUATION OF THE CARCINOGENIC RISK OF CHEMICALS TO MAN, Geneva: World Health Organization, International Agency for Research on Cancer, 1972-1977. PATTY'S INDUSTRIAL HYGIENE AND TOXICOLOGY, Clayton, G. D., Clayton, F. E.( eds., John Wiley and Sons, N. Y., 3rd edition, Vol. 2 A-C, 1981. REGISTRY OF TOXIC EFFECTS ON CHEMICAL SUBSTANCES, U.S. Department of Health and Human Services, Public Health Service, Center for Disease Control, National Institute for Occupational Safety and Health, 1983 supplement of 1981-1982 edition, Vol. 1-3, OH, 1984. Title 29 Code of Federal Regulations Part 1910, Subpart Z, Toxic and Hazardous Substances, Occupational Safety and Health Administration (OSHA). THRESHOLD LIMIT VALUES FOR CHEMICAL SUBSTANCES AND PHYSICAL AGENTS IN THE WORKROOM ENVIRONMENT WITH INTENDED CHANGES, American Conference of Governmental Industrial Hygienists, OH. PAGE 8 OF 9 SAL 000006466 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE, U LINOIS 60563-1 19E 4 N NALCO SECTION 17 BIBLIOGRAPHY MATERIAL SAFETY DATA SHEET PRODUCT NALCO 5163 CORROSION INHIBITOI Emergency Telephone Number Medical (708) 920-1510 (24 hour*) o o* * 7 ( CONTINUED ) Information on this MSDS has changed. The changes are indicated by asterisks on the right side of only the changed sections. This is an updated MSDS as required by OHSA's Hazard Communication Rule 29 CFR 1910.1200. PREPARED BY: Ricky A. Stackhouse PhD., Toxicologist DATE CHANGED: 03/12/90 DATE PRINTED: 03/24/90 PAGE 9 OF 9 SAL 000006^7 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-'ll SB NALCO MATERIAL SAFETY DATA SHEET PRODUCT Emergency Telephone Number Medical (706) 920-1510 (24 hours) SAL 000006^68 NALCO CHEMICAL COMPANY ONE NALCO CENTER * NAPERVILLE. ILLINOIS 60563-1 190 IMALCO MATERIAL SAFETY DATA SHEET PRODUCT ELIMINOX OXYGEN SCAVENGER Emergency Telephone Number Medical (70S) 920-1510 {24 hour#) g *8248 SECTION 1 PRODUCT IDENTIFICATION TRADE NAME: ELIMINOX OXYGEN SCAVENGER DESCRIPTION: An aqueous solution of a modified amino compound NFPA 704M/HMIS RATING: 1/1 HEALTH 0/0 FLAMMABILITY 0/0 REACTIVITY 0=lnsignificant 1-Slight 2=Moderate 3=High 4=Extreme * * * 0 OTHER * * SECTION 2 HAZARDOUS INGREDIENTS Our hazard evaluation of the ingredient(s) under OSHA's Hazard Communication Rule, 29 CFR 1910.1200 has found none of the ingredient(s) hazardous. * * SECTION 3 PRECAUTIONARY LABEL INFORMATION CAUTION: May cause skin irritation. Avoid contact with skin and clothing. Avoid prolonged or repeated breathing of vapor. Use with adequate ventilation. Do not take internally. Empty containers may contain residual product. Do not reuse container unless properly reconditioned. SECTION 4 FIRST AID INFORMATION EYES: SKIN: INGESTION: Flush with water for 15 minutes. Flush with water for 15 minutes. Induce vomiting. Give water. Call a physician. NOTE TO PHYSICIAN: No specific antidote is known. Based on the individual reactions of the patient, the physician's judgment should be used to control symptoms and clinical condition. CAUTION: If unconscious, having trouble breathing or in convulsions, do not induce vomiting or give water. * * * * * * * * * * SECTION 5 HEALTH EFFECTS INFORMATION PRIMARY ROUTE(S) OF EXPOSURE: Eye, Skin EYE CONTACT: SKIN CONTACT: Non-irritating. Can cause transient irritation. SYMPTOMS OF EXPOSURE: A review of available data does not identify any symptoms from exposure. AGGRAVATION OF EXISTING CONDITIONS: A review of available data does PAGE 1 OF 7 SAL 000006469 NALCO CHEMICAL COMPANY ONE NALCO CENTER * NAPERVILLE. ILLINOIS 60563-1 19B * MALCO 6 S 2 48 MATERIAL SAFETY DATA SHEET PRODUCT eliminox oxygen scavenger Emergency Telephone Number Medical (708) 920-1510 (24 hours) SECTION 5 HEALTH EFFECTS INFORMATION ( CONTINUED ) not identify any worsening of existing conditions. SECTION 6 TOXICOLOGY INFORMATION ACUTE TOXICITY STUDIES: Acute toxicity studies have been conducted on this product. The results are shown below. ACUTE ORAL TOXICITY (ALBINO RATS): LDS0 * Greater than 5 g/kg ACUTE DERMAL TOXICITY (ALBINO RABBITS): LD50 = Greater than 2 g/kg PRIMARY SKIN IRRITATION TEST (ALBINO RABBITS): SKIN IRRITATION INDEX DRAIZE RATING: 0.23/8.0 Minimal irritation PRIMARY EYE IRRITATION TEST (ALBINO RABBITS): EYE IRRITATION INDEX DRAIZE RATING: 0.33/110.0 Practically non-irritating * * * * * * * * * * * SECTION 7 PHYSICAL AND CHEMICAL PROPERTIES COLOR: Colorless DENSITY: SOLUBILITY IN WATER: SPECIFIC GRAVITY: pH (NEAT) = VISCOSITY: FREEZE POINT: FLASH POINT: FORM: Liquid 8.5 lbs/gal. Completely 1.02 8 60 Degrees F 7.3 pH (at 1%) 3 cps 8 60 Degrees F 28 Degrees F None (PMCC) 6.7 ASTM D-1298 ASTM E-70 ASTM D-2983 ASTM D-1177 ASTM D-93 NOTE: These physical properties are typical values for this product. SECTION 8 FIRE AND EXPLOSION INFORMATION FLASH POINT: None (PMCC) ASTM D-93 EXTINGUISHING MEDIA: Not applicable UNUSUAL FIRE AND EXPLOSION HAZARD: May evolve NOx under fire conditions. Containers exposed in a fire should be cooled with water to prevent vapor pressure buildup leading to a rupture. SECTION 9 REACTIVITY INFORMATION INCOMPATIBILITY: Avoid mineral acids and nitrites. PAGE 2 OF 7 S4L 0006470 r: NALCO CHEMICAL COMPANY ONE NALGD CENTER NAPERVI!___E. ILLINOIS 60563-1 19S MATERIAL SAFETY DATA SHEET NALCO PRODUCT eliminox oxygen scavenger Emergency Telephone Number Medical (706) 920-1510 (24 hours) *8248 SECTION 9 REACTIVITY INFORMATION ( CONTINUED ) Avoid contact with strong oxidizers (eg. chlorine, peroxides, chromates, nitric* acid, perchlorates, concentrated oxygen, permanganates) which can generate * heat, fires, explosions and the release of toxic fumes. * * THERMAL DECOMPOSITION PRODUCTS: In the event of combustion CO, C03, NOx may be formed. Do not breathe smoke or fumes. Wear suitable protective equipment.* SECTION 10 PERSONAL PROTECTION EQUIPMENT RESPIRATORY PROTECTION: Respiratory protection is not normally needed since the volatility and toxicity are low. If significant vapors, mists or aerosols are generated, wear a NIOSH approved or equivalent respirator. * * For large spills, entry into large tanks, vessels or enclosed small spaces with inadequate ventilation, a pressure-demand, self-contained breathing apparatus is recommended. * * * * VENTILATION: General ventilation is recommended. * * PROTECTIVE EQUIPMENT: Use impermeable gloves and chemical splash goggles when attaching feeding equipment or doing maintenance. * * If clothing is contaminated, remove clothing and thoroughly wash the affected area. Launder contaminated clothing before reuse. * SECTION 11 SPILL AND DISPOSAL INFORMATION IN CASE OF TRANSPORTATION ACCIDENTS, CALL THE FOLLOWING 24-HOUR TELEPHONE NUMBER (708-920-1510) * * * SPILL CONTROL AND RECOVERY: * * Small liquid spills: Contain with absorbent material, such as clay, soil or any commercially available absorbent. Shovel reclaimed liquid and absorbent into recovery or salvage drums for disposal. Refer to CERCLA in Section 14. * * * * Large liquid spills: Dike to prevent further movement and reclaim into recovery* or salvage drums or tank truck for disposal. Refer to CERCLA in Section 14. * * DISPOSAL: If this product becomes a waste, it does not meet the criteria of a hazardous waste as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261, since it does not have the characteristics of Subpart C, (i.e. D001 through D017) nor is it listed under Subpart D. * * * * PAGE 3 OF 7 SAL 0000064-71 IMALCO CHEMICAL COMPANY ONE NIALCO CENTER NAPERVILLE. ILLINOIS 60563-1198 * GS2 4 NALCO MATERIAL SAFETY DATA SHEET PRODUCT eliminox oxygen scavenger Emergency Telephone Number Medical (708) 820-1510 (24 hours) SECTION 11 SPILL AND DISPOSAL INFORMATION ( CONTINUED ) As a non-hazardous liquid waste, it should be solidified with stabilizing agents (such as sand, fly ash, or cement) so that no free liquid remains before disposal to an industrial waste landfill. A non-hazardous liquid waste can also be deep-well injected in accordance with local, state and federal regulations. * * * SECTION 12 ENVIRONMENTAL INFORMATION AQUATIC DATA: 96 hour static acute LC50 to Bluegill Sunfish = 190 ppm 48 hour static acute LC50 to Bluegill Sunfish = 520 ppm 24 hour static acute LCsc to Bluegill Sunfish = 750 ppm 96 hour static acute LCS0 to Rainbow Trout = 360 ppm 48 hour static acute LCS0 to Rainbow Trout = 700 ppm 24 hour static acute LCS# to Rainbow Trout = Greater than 1,000 ppm If released into the environment, see CERCLA in Section 14. SECTION 13 TRANSPORTATION INFORMATION DOT PROPER SHIPPING NAME/HAZARD CODE - PRODUCT IS NOT REGULATED DURING TRANSPORTATION SECTION 14 REGULATORY INFORMATION The following regulations apply to this product. FEDERAL REGULATIONS: OSHA'S HAZARD COMMUNICATION RULE, 29 CFR 1910.1200: Based on our hazard evaluation, this product is not hazardous. CERCLA, 40 CFR 117, 302: Notification of spills of this product is not required. SARA/SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (TITLE III) - SECTIONS 302, 311, 312 AND 313: SECTION 302 - EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355): This product does not contain ingredients listed in Appendix A and B as an Extremely Hazardous Substance. * * * * * * * * llf * * * * * PAGE 4 OF 7 SAL 0000064-72 IMALCO CHEMICAL COMPANY ONE NALCO CENTER * NAPERVILLE. ILLINOIS 60563-1136 NALCO MATERIAL SAFETY DATA SHEET PRODUCT ELIMINOX OXYGEN SCAVENGER Emergency Telephone Number Medical (708) 920-1510 (24 hours) *S248 SECTION 14 REGULATORY INFORMATION ( CONTINUED ) SECTIONS 311 and 312 - MATERIAL SAFETY DATA SHEET REQUIREMENTS <40 CFR 370): Our hazard evaluation has found that this product is not hazardous under 29 CFR 1910.1200. * Under Section 311, submittal of MSDS's or a list of product names to the local emergency planning commission, state emergency response commission and local fire department is required after October 17, 1987 if you have: * * - 10,000 pounds or more of a hazardous substance, or - 500 pounds or the threshold planning quantity, whichever is less, of an extremely hazardous substance. * * SECTION 313 - LIST OF TOXIC CHEMICALS (40 CFR 372): This product does not contain ingredients (at a level of 1% or greater) on the List of Toxic Chemicals. * * TOXIC SUBSTANCES CONTROL ACT (TSCA): The chemical ingredients in this product are on the 8(b) Inventory List (40 CFR 710). * * RESOURCE CONSERVATION AND RECOVERY ACT (RCRA), 40 If this product becomes a waste, it does not meet hazardous waste. CFR 261 SUBPARTC the criteria of a & D: * * FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 401.15 (formerly Sec. 307), 40 CFR 116 (formerly Sec. 311): None of the ingredients are specifically listed. * * CLEAN AIR ACT, 40 CFR 60, SECTION 111, 40 CFR 61, SECTION 112: This product does not contain ingredients covered by the CleanAir Act. STATE REGULATIONS: * * CALIFORNIA PROPOSITION 65: None of the chemicals on the current Proposition 65 list are known to be present in this product. MICHIGAN CRITICAL MATERIALS: This product does not contain ingredients listed on the Michigan Critical Materials Register. STATE RIGHT TO KNOW LAWS: The following ingredient(s) are disclosed for compliance with State Right To PAGE 5 OF 7 SAL 000006473 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE, ILLINOIS 60563-11 SB MATERIAL SAFETY DATA SHEET GS248 NALCO PRODUCT eliminox oxygen scavenger Emergency Telephone Number Medical (708) 920-1510 (24 hours) SECTION 14 REGULATORY INFORMATION ( CONTINUED ) Know Laws: Carbohydrazide Water 497-18-7 7732-18-5 INTERNATIONAL REGULATIONS: This is not a WHMIS controlled product under The House of Commons of Canada Bill C-70. SECTION 15 ADDITIONAL INFORMATION None SECTION 16 USER'S RESPONSIBILITY This product material safety data sheet provides health and safety information. The product is to be used in applications consistent with our product literature. Individuals handling this product should be informed of the recommended safety precautions and should have access to this information. For any other uses, exposures should be evaluated so that appropriate handling practices and training programs can be established to ensure safe workplace operations. Please consult your local sales representative for any further information. SECTION 17 BIBLIOGRAPHY* I ANNUAL REPORT ON CARCINOGENS, U.S. Department of Health and Human Services, Public Health Service, PB 33-135855, 1983. CASARETT AND DOULL'S TOXICOLOGY, THE BASIC SCIENCE OF POISONS, Doull, J., Klaassen, C. D., and Admur, M. 0., eds., Macmillian Publishing Company, Inc., N. Y., 2nd edition, 1980. CHEMICAL HAZARDS OF THE WORKPLACE, Proctor, N. H., and Hughes, J. P., eds., J, P. Lipincott Company, N.Y., 1981. DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS, Sax, N. Irving, ed., Van Nostrand Reinhold Company, N.Y., 6th edition, 1984. IARC MONOGRAPHS ON THE EVALUATION OF THE CARCINOGENIC RISK OF CHEMICALS TO MAN, Geneva: World Health Organization, International Agency for Research on Cancer, 1972-1977. PAGE 6 OF 7 SAL 000006474 NALCO CHEMICAL COMPANY CNE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1 19B MATERIAL SAFETY DATA SHEET NALCO PRODUCT ELIMINOX OXYGEN SCAVENGER Emergency Telephone Number Medical (708) 920-1510 (24 hours) hours) Gg2 48 SECTION 17 BIBLIOGRAPHY ( CONTINUED ) PATTY'S INDUSTRIAL HYGIENE AND TOXICOLOGY, Clayton, G. D., Clayton, F. E., edSs, John Wiley and Sons, N. Y., 3rd edition, Vol 2 A-C, 1981. REGISTRY OF TOXIC EFFECTS ON CHEMICAL SUBSTANCES, U.S. Department of Health and Human Services, Public Health Service, Center for Disease Control, National Institute for Occupational Safety and Health, 1983 supplement of 1981-1982 edition, Vol. 1-3, OH, 1984. Title 29 Code of Federal Regulations Part 1910, Subpart Z, Toxic and Hazardous Substances, Occupational Safety and Health Administration (OSHA). THRESHOLD LIMIT VALUES FOR CHEMICAL SUBSTANCES AND PHYSICAL AGENTS IN THE WORKROOM ENVIRONMENT WITH INTENDED CHANGES, American Conference of Governmental Industrial Hygienists, OH. Information on this MSDS has changed. The changes are indicated by asterisks on the right side of only the changed sections. This is an updated MSDS as required by OHSA's Hazard Communication Rule 29 CFR 1910.1200. PREPARED BY: Ricky A. Stackhouse PhD., Toxicologist DATE CHANGED: 05/02/90 DATE PRINTED: 05/12/90 PAGE 7 OF 7 SAL 000006475 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1198 N NALCO MATERIAL SAFETY DATA SHEET PRODUCT Emergency Telephone Number Medical (708) 920-1510(24 hours) SAL 000006476 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS SG563-1198 ! J. A A 4i> !... xl;; HA T 4 i Al SAid i V Uh I A Hlt f PS X KlAUS I OH 05' 201-16-90 ''Lui : : 4 .,44 ' -: .4 ;. CS299 h:j S -4_ " ->-: l . : !.'i'.-L. `J' v . `'44 . '.. . .. 4 Li U X - 4 ; 1 i...L . do .!. 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SAL 000006478 r f A f'h'K 1AL UAI- b I Y DATA SHLLT OG U 'A ASH Li OH KLOiSiOH UK =01-16-90 rc OUL Ml-.''!-- h V LUH I AiNKKU AND Li RUCl UK: LA LXoUSLO ; u ii-.'L .. i i '`Z Of-! .../i'L.Uo .1. UM H A/ A\<UL " -.< I 1 i"!GUi. UH A . L i":.. :i.> t tuUK' *S299 ri:.,, J...,m "., .: u: _ j? ooo: OVA ; ;; / iji-'Kii- L. A i'll.- 0 UlLDIHO hKl:S. OK Uihs-..- K.,uM . I.H , i.OOA.'Ki::. i hi. 0''A,... 01 i-L x-J ! .. J ` Z iJ'-i Z"'j; ' ;0M L.; IK i 3 |; HAY O ' i;Di.-..Oi- LULL.Utv: ,, !'L l / K/.-'L1--' 0 L'< 'J,~:i i i.... Y MO' "DJ 0 0!: L. L A i ; 0 " M-.AX OKU ti' M L ..--O .00 MU I .MO- X i.-_. Ov,, I'UDJ.f A O 0 N A D A V-.U" -LUM A i K:;; D L -v, UO i U -UK XKLSUUHL DLHAHD lUJnL CO A S U a u L 1L D - A . I 0z 0 *' i l.L 0 i! l -.j. mk 1 0 : i'ihLi_. .. A i U!_ o " al. L . i -- 0 !_. "( l i :; 1 i.f i L Mr SI-'iKA ( UK LUUU'KLK Uif H OAK l iCULATt. M.L.U..U6 O.O'i DL j i-1 1-I { OV:".N ,, ALX AY U LOAK L. l'L DUU I -_L i 1.'J,--! j r UA Ir\f-x. L. 'I MK AND l.i ! Si-'UY;|- LK J.N LiUl -hKF'KU'-'LD UASVL CU:m ! A.1. OLK'o. *- o h: i U mU MUKKUM D VJ A f L CON ! A i 0-: k:_.. MU:' . ..i'J' i .l\ UfVILHU. AND SOIL.,, j -' n : i'/: ' 00 - lU UUH fOOl Oh UD K K I.J D Li ,-UD O'-10 O'-.- LLAK 0 IN A Kf'1-iHi-..K A1 f-` is U '11-. 'J rO ;iU, HA : i-.-' : r ..'MO OJKAL KKOCLDUK;!: 0 ." 1 i ' ;S : A ... >' -.0 CA.'i KA'.'L H L 0 1 D U 0 0 .. OAOLb -'OD '... - r -KJ O ! : UAO'IL Vi OK'UOA!.... AS? ADOUL- - ............. ... O'LOiAL. t:'KLLAU TiONO-..........--........ ........................... .- i!1 I 10 i " ONJKK SO A 0 ... ,: . _ iO-1-. U- : j;-;: j'AM-iKK T i OK 111 Y " CLUULi.i' t-H iOK MU': . US'.-.O Li i_- ' L.< : u i ' I r-t j ; -i T . \ ^ i-ic. ..AiO.iu ...L . O' i'i 0:f:. OK ON CLU I l-i 1 N'U ,. YOJi'l K'O:. K.O'tO-i '. HUOi... "I HA'l SOUL tit. JUM a'` OM'o' A 0. :!' ''I.L'Y liOOb 1~Ul.k'1"'.................... ................... - -'OK i; ij i. X UHAL ^ HO'OKK A I iO.>:...................* i'OODO: OOKj, 0 0:. ( !A'f 0I-: - DAN i-IA`i l-i-'L S KL;UO 1'ij OKS Y-LK'O i.OL.'rOO, :.0 i i.OO,. v -J- -0 0 / -0 - ....................... O...0!j;..A'iuRV UKKA .00- --......... i-o. o-o: jl,o l.-U i ho ni la.... o- lO-o.,;0 10,'o.is...; .... i./iOOl'i.'l-: O.1; ' ;'.i ! 'SOLO i 0 0.0'' ! 'N i: L .i O. LIT -i 0000:0-:-0 .-i0- 01Cu. SAL 0000064-79 <n S 2 99 H L. r T>! i ( ft A'I ILR1AL SAfL'lY DA'l A SiWt'l Kb L'v'ioiu'-i or -ui j. ........-- - - - - -.... - ................. ; iu r iLti-................. -- ................................ . . . -*!!-. s-:<j <; PLifjLK'J INC;,. < " V' i e;*. f- " ) LYM-M:: YUl. Y lUbCLAINb Ai. .(I UiAKr'V !"3 0i:' U i ' ;-i ! i; 'II !M KH bi-1I TfJ TIM- l-'i'U!".. I r i . > .1 1 11-' M , "A , Li.': A r '! ri I '! X ''ill !" ^'Ub NLCUUK, ij' l y: i iu a-:: r.cci. V ?.j| ' -;U! I" U .1 L i i L .. ' . I . 111 !1 i I.'i b.1 :' ! I Ni.i DM l.11 ; : .. i U lit 1 Y , i. '_!H! < i * iv r.-K". i'7'!:.. !-| AM i iT T NU ANU D 1 b`; AL. Ur !,M. 1 1 Lj i' LJ L i U-.b. CY- O:-' !' CLIAYl'l .1 ,v YbAj-, ; j. L; - i r ; fji-! J-M- 1 U!!LY 1 fj 1 I `! '!_(i.lt !>_,'< \J r,,. bu N< I Y U i;i.. . l !- , Hh 1 \ >\L .l I . ANY liJ.'Y Jj b': ,-!ul-iV Pi -------- : I. Y... Y ' UN - c. : i L1 Ui bD SAL ooo0a^an 1954 USDS DATE! 3/14/10 CHANGE HO.I 7557 Haifa 3,5 i5 MATERIAL For Agtlstance, Contact: Regulatory Affairs Dept. PO Dx *07 An**, IA 5l (8*0) 277-4224 SAFETY DATA HACH COMPAMY PO BOX **7 AMES, |A 5*0 I 0 Ptti 3ULPAZS9815 KACH ORDER*I (85437 SHEET ,84 Emergency Telephene Rocky Mountain Poison Ctr. < 3*3) 423-571* 11 I. PRODUCT IDENTIFICATION CATALOG HO. I 1*34 PRODUCT NAME; Amino Ac!* Reagent for Phosphite and Silica CAS MO.: HA FORMULA: Net applicable CHEMICAL NAME: Hot applicable CHEMICAL FAMILY: Hot applicabla keep container closed. Use only with edeouate ventilation. PROTECTIVE EQUIPMENT: 1*6 trade legates, vent lletion, lab ceat natural rubber gloves, sdeauate VII. FIRST AID II. INGREDIENTS Sodluia Motabisulf 11a PCT: <10 CAS HO.I 7(81-57-4 TLVi 5 mg/M3 HAZARD) Corrosive whan wat; allargan SARA: HOT LISTED PEL: S lag/MS Sodluai Sulflta PCT: <5 CAS MO.: 7757-83-7 TLV: Hot astabl ishad HAZARD: Modarataly toxic; oll*rgan SARA: HOT LISTED PEL: Mot established Organic Solvent (Trade Secrati PCT: <S0 CAS HO.: Confidant lelSARA: HOT LISTED TLV: 10 ppm (skin) PEL: 10 pea (tkinl HAZARD: Hay be tmbryotoxip Eye AND SKIN CONTACT: Immediately flush eye* and skin with water for IS minutes. Remove contaminated clothing. Call physician. INGESTION: Give t slurry of powdered activated charcoal, induce vomiting sticking finger down throat. Never give anything by mouth to sn unconscious person. Call physlelan. ivptAL at ion ? Remove to fresh air. Give artificial respiration if necessary Call physician. VIII. SPILL AND DISPOSAL PROCEDURES IN CASE OF SPILL OH RELEASE: Remove all sources of Ignition. Absorb spill with non-raaetive absorbent. Do net breathe fumaa. tnelnarata materia) In an EPA-approved facility. DISPOSE OF IN ACCORDANCE WITH ALL FEDERAL, STATE, AND LOCAL REGULATIONS. IX. TRANSPORTATION DATA Other eoaponant PCT: <1 CAS MO.I MA TLV: Hot applicable HAZARD: Mot applicable SARA: HOT LISTED PEL: Hot applicabla Demineralized Hater PCT: to 100 CAS MO.: 7732-18-5 TLV: Nat applicable HAZARD: Mona SARA: NOT LISTED PEL: Not appllcbble Any eoaponant of this alxtura not specifically listed It*, "other components") la not considered to present a carcinogen hazard. III. PHYSICAL DATA STATE: llould APPEARANCE: Clear, yellow solution ODOR: Faint, amine SOLUBILITY IN: WATER; Soluble ACID: Not determined OTHER: Hot detaralno* BOILING POINT; 102 C MELTING PT.r HA SPEC GRAVITY: 1.065 pH: 5.8 VAPOR PRESSURE: Not determined VAPOR DENSITY falr*l): HD EVAPORATION RATE: #.S* METAL CORROSIVITY - ALUMINUM: ND STEEL: HD STABILITY! Stable STORAGE PRECAUTIONS: Store In a cool, dry piece twey from oxidizers. tIV. FIRE EXPLOSION HAZARD AND REACTIVITY DATA D.D.T. PROPER SHIPPING NAME: Net Currently Regulated HAZARD CLASS: Not applicable ID! MA I.C.A.O. proper SHIPPING NAME: Hot Currently Regulated HAZARD CLASS: HA ID: NA GROUP: NA l.M.0. PROPER SHIPPING NAME: Not Currently Regulated HAZARD CLASS! MA ID: NA GROUP: MA X. REFERENCES I) TLV's Threshold Limit Values and Biological Exposure Indloes for 1*881*8*. American Conference of Governmental Industrial Hygienists, 1*88. 7) 2* CFR 1*08 - 1*10 fCod# of Federal Regulations - labor) 51 In-house Information 4) Technical Judgment 51 Outside testing. SPECIAL note: In Inboratory tests, application of an Ingredient In thl* substance to the skin of oragnent rats caused fatal deaths when the dosages were close to the lethal dose level for the mother. Avoid Inhalation end contact with this product. FLASH PT,: >212F| >100C METHOD: Closed cup FLAhtfABILlTY LIMITS - LOWER: NA UPPER! NA SUSCEPTIBILITY TO SPONTANEOUS HEATING: None SHOCK SENSITIVITY: Nona AUTOIGNITION PT.! P445C EXTINGUISHING MEDIA: dry chemical, alcohol foam or carbon dioxide FIRE/EXPLOSION HAZARDS: Hoy emit toxic fumes In fir# HAZARDOUS DECOHP. PRODUCTS: Hay omit toxic fumes ef dlmethylamlno, carbon monoxide In fire OXIDIZER: No NFPA Cedes: Health: 1 Flammability: 2 Reactivity: * CONDITIONS TO AVOID: Oxidizing materials, halogeneted hydrocarbons, and Inorganic nitrates; extreme heat or Mamas. V. HEALTH HAZARD DATA IN]S PRODUCT HAY BE: Irritating to ayes, skin and respiratory tract. ACUTE TOXICITY: Oral rat LD50 > 5019 mg/Kf = Slightly toxic ROUTES OF EXPOSURE: Ingestion, Inhalation, contact, skin absorption TARGET ORGANS: liver, kidneys, fetus CHRONIC TOXICITY: Not determined ROUTES OF EXPOSURE: Inhalation, skin absorption TARGET ORGANS: liver, kidneys, fetus CANCER INFORMATION: Hot dstermlnsd ROUTES OF EXPOSURE: Hot determined TARGET ORGANS: Net determined OVEREXPOSURE: Hay cause liver problems, nausea, abdominal pain, increased blood pressure. May be embryotoxle. MEDICAL CONDITIONS AGGRAVATED BV EXPOSURE: None reported VI. PRECAUTIONARY MEASURES Hath thoroughly after handling. Avoid contact with aye*, skin end clothing. Do not breathe chemicals. SAL 000006481 THE INFORMATION CONTAlD HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE. HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEPf Cr. (C> HACH CO. 1*9# moor Information Conoco Inc. Page Purchase Requisition Of Priority RLOC Department REB ^tefining Shaded Areas RQ Loc Requisition No. 259815A for Purchasing Dept. Use Only 316 A Ship Date Req'd at Dest. Order Previous P.O Via Type Normal CO Shif^T Tagging Instructions HACH tn: CATHY iquisitioner 800-525-5940 Date Conoco Inc. Refinery Warehouse Old Spanish Trail P.O. Box 37 Westlake, LA 70669 Distribution Charge F.O.B. Point ' Freight Terms Carrier - -. :. :.. f- Project ID Clauses ^ xo.- i-v r : fsr Payment Terms . . AFE Reporting \Jt - ' RACHELLE Tax Status /ge Exempt 6% 3t 4/20/90 Special Instructions 7411-3-0-37-03-30 ,/ Control Data wo. 4/20/90 S037 Equip. No. Tima Tima Unit tnlt. Stat. Ordared Raqd Coda LB 11|1418 NOW nj Stock No. DaaCriptlOn Amino Aids 1934 Data Required 7411-3-0-37-NSX-03-30 Itam Quantity No Ordared Unit* of itaut Prtca 1 4 each 87.40 Oty. laauad APPROVED: D GOLEN CONFIRMED ORDER TO KHHACH DO NOT DUP c i Operating Dapt. tfls xs. ties Approval - Purchasing Dept. i- $al 'ooo6J2 APR 0 3 ecu MATERIAL SAFETY DATA SHEET SS427 PRODUCT NAME Zinc Re-Nu (Aerosol^ *03074 # MFDSOO 3074 MANUFACTURED SY: CRC CHEMICALS Phone (2151674-4300 | 885 LOUIS DRIVE. WARMINSTER. PA. 18974 1. INGREDIENTS Emergency phone # sara e as above. CAS# ACGIH TLV OSHA PEL Other Limits Zinc Dust 7440-66-6 NA NA Fpoxy Eater Resin NA NA Xylene 1330-20-7 100 100 % 36,0 4.0 10.0 Methyl Ethyl Ketone 78-93-3 200 200 35.0 Propane 74-98-6 NA 1000 15.0 These chemicals listed n Section 31.3 nf sai A III an l subiec t to release inventory repori ing._______________________ * * The propane functions as a proc ellent f ar this product .. . 2. PHYSICAL DATA Specific Gravity NA (Without propellent) Vapor Pressure % Volatile Boiling Point NA Evaporation Rate Dries in 2C-30 minutes Freezing Point NA Vapor Density Heavier than air Appearance and Odor Gray, viscous liquid - solvent ocor Solubility__ Soluble in most organic solvents 60 3. FIRE AND EXPLOSION DATA Flashpoint ^20F Method TCC Flammable Limits NA Extinguishing Media CO*# Foam# Dry Chemical LEL UEL Unusual Hazards Material reacts with water - Aerosol cans may explode if heated above 13Qg^_-_ 4. REACTIVITY AND STABILITY Stability Stable___________________________________________________________________________ Hazardous decomposition products Carbon nonoxide and carbon dioxide. Materials to avoid water, acids# strong acids_____________________________________ 5. PROTECTION INFORMATION________________________________________________ Ventilation Mechanical required if sprayed in a confined area. ______ Respiratory self contained breathing apparatus if vapora_ exceed TLV# Gloves _golvent resistant, _1 Eye & Face safety goggles-______________ Other Protective Equipment nauallv nQt, require* for _____ SAL OOnnnxAo* G S 4 27 MSDSOO 3074 6, HEALTH HAZARD OATA__________ ___________________________ _________________________ Primary Routes of Entry inhalation and Skin_________ ___________________________________________________ Signs and Symptoms of Exposure ____________________ 1 Acute Overexposure inhalation Headaches, dizziness, nausea and Fves - Will cause eve irritation,___ Skifl_- Will cause drying and irritju-irm of akin._________ ---- 2. Chronic Overexposure May cause contact dermatitis -------- -- . _______ - Could have effect. __________ liver and kidney. Medical Conditions Generally Aggravated by Exposure Breathing diff icultlea Chwnoiu*3mCaroneeei Of Potfitt C*rgoogo _ Nkkvii Tojuco4ow r**Q lAAC OSHA yt Z Proqfam Mpoognph*No yv Emergency and First Aid Procedures (xf symptoms persist, call a doctor) 1 inhalation Remove to fresh air * apply artificial reaplration if necessary. 2 Flush with water for at least 15 minuteal' _______________ ____________ 3 Skin yjaah with soap and water - Use skin cream.____________________________ ________ 4 Ingestion^ Po nQt induce vomiting - Tall.a phvaician. ---- --------- 7. SPILL OR LEAK PROCEDURES B'#ciution* 10 6* t*n >n ^ . ,, , -andt'fiq ana StorageStore 11"! a COOi dry Place.___________________________________________________ Sie to be t*n in C4M i> fBieaxd of absorb liquid Not normally a problem with aerosols - Ventilate and Remove sources of ignition._______________________________________ Waste Disposal Partially used or filled aerosols are Hazardous Waste if discarded - Dispose of in conformance to Federal. State & local regulations 8. SPECIAL PRECAUTIONS AND USE DIRECTIONS Aeroaol container* may explode if exposed to temperatures in excess of 130r. Due to the high density of the metallic zinc, the aerosol must be thoroughly agitated before use* PREPARED BY: b. Reed ___________________________________________________________ ORIGINAL DATE OR OATE OF REVISION 9-89 SAL 000006484 BETZ INDUSTRIAL DIV. 1 QUALITY WAY, TREVOSE, PA.19047 6 S 4 70 W BETZ MATERIAL SAFETY DATA SHEET (PAGE 1 OF 3) 24 HOUR EMERGENCY TELEPHONE NO.(215)355-3300 PRODUCT: FOAM-TROL CT REVISIONS TO SECTIONS: 1 PRINTED: 05-15-90 PRODUCT APPLICATION : ANTIFOAM. ----------- SECTION 1-------------------------- HAZARDOUS INGREDIENTS------------------------------------ INFORMATION ON PHYSICAL HAZARDS, HEALTH HAZARDS, PEL'S AND TLV'S FOR SPECIFIC PRODUCT INGREDIENTS AS REQUIRED BY THE OSHA HAZARD COMMUNICATIONS STANDARD ARE AND CHRONIC HAZARDS OF THIS FORMULATION. MINERAL OIL(MILDLY SOLVENT-REFINED OR HYDROTREATED OILS)***CAS#64742-30-9; POTENTIAL SKIN TUMORIGEN(BASED ON CHRONIC ANIMAL SKIN PAINTING STUDIES); PEL:5MG/M3;TLV:5MG/M3 . / ----------- SECTION 2-------------------------- TYPICAL PHYSICAL DATA-------------------------------------------- PH: 50% SOL. (APPROX.) FL.PT.(DEG.F): >200 SETA(CC) VAPOR PRESSURE (irunHG) : <10 Vise cps70F: 30 EVAP.RATE: <1 ETHER=1 PHYSICAL STATE: LIQUID 6.8 ODOR: MILD SP.GR.(70F)OR DENSITY: 0.841 VAPOR DENSITY (AIR=1) : >1 %SOLUBILITY(WATER): 0 APPEARANCE: OFF WHITE TO AMBER FREEZE POINT(DEG.F): ND ----------- SECTION 3-------------------------- REACTIVITY DATA---------------------------------------------------------- STABLE.MAY REACT WITH STRONG OXIDIZERS.DO NOT CONTAMINATE.BETZ TANK CLEAN-OUT CATEGORY 'B' THERMAL DECOMPOSITION (DESTRUCTIVE FIRES) YIELDS ELEMENTAL OXIDES. SAL 000006485 S 4 70 BETZ MATERIAL SAFETY DATA SHEET (PAGE 2 OF 3) PRODUCT: FOAM-TROL CT -------- SECTION 4-------------------------- HEALTH HAZARD EFFECTS------------------------ rtCUTE SKIN EFFECTS *** PRIMARY ROUTE OF EXPOSURE SLIGHTLY IRRITATING TO THE SKIN.MAY CAUSE DERMATITIS. ACUTE EYE EFFECTS *** MODERATELY IRRITATING TO THE EYES ACUTE RESPIRATORY EFFECTS *** VAPORS,GASES,MISTS AND/OR AEROSOLS MAY CAUSE IRRITATION TO UPPER RESPIRATORY TRACT CHRONIC EFFECTS OF OVEREXPOSURE*** PROLONGED OR REPEATED EXPOSURES MAY CAUSE DEFATTING-TYPE DERMATITIS; LIFETIME SKIN PAINTING STUDIES IN MICE HAVE PRODUCED SKIN TUMORS. MEDICAL CONDITIONS AGGRAVATED *** NOT KNOWN SYMPTOMS OF EXPOSURE *** PROLONGED EXPOSURE MAY CAUSE DRYING AND CRACKING OF SKIN. ----------- SECTION 5-----------------------------FIRST AID INSTRUCTIONS-----------------------------------------------------''KIN CONTACT*** REMOVE CONTAMINATED CLOTHING.WASH EXPOSED AREA WITH A LARGE QUANTITY OF SOAP SOLUTION OR WATER FOR 15 MINUTES EYE CONTACT*** IMMEDIATELY FLUSH EYES WITH WATER FOR 15 MINUTES.IMMEDIATELY CONTACT A PHYSICIAN FOR ADDITIONAL TREATMENT INHALATION EXPOSURE*** REMOVE VICTIM FROM CONTAMINATED AREA TO FRESH AIR.APPLY APPROPRIATE FIRST AID TREATMENT AS NECESSARY INGESTION*** DO NOT FEED ANYTHING BY MOUTH TO AN UNCONSCIOUS OR CONVULSIVE VICTIM DO NOT INDUCE VOMITING. IMMED. CONTACT PHYSICIAN . DILUTE CONTENTS OF STOMACH USING 3-4 GLASSES MILK OR WATER ----------- SECTION 6-------------------------- SPILL, DISPOSAL AND FIRE INSTRUCTIONS---------------------SPILL INSTRUCTIONS*** VENTILATE AREA,USE SPECIFIED PROTECTIVE EQUIPMENT.CONTAIN AND ABSORB ON ABSORBENT MATERIAL.PLACE IN WASTE DISPOSAL CONTAINER. THE WASTE CHARACTERISTICS OF THE ABSORBED MATERIAL,OR ANY CONTAMINATED SOIL, SHOULD BE DETERMINED IN ACCORDANCE WITH RCRA REGULATIONS. FLUSH AREA WITH WATER. WET AREA MAY BE SLIPPERY. SPREAD SAND/GRIT. DISPOSAL INSTRUCTIONS*** WATER CONTAMINATED WITH THIS PRODUCT MAY BE SENT TO A SANITARY SEWER TREATMENT FACILITY, IN ACCORDANCE WITH ANY LOCAL AGREEMENT,A PERMITTED WASTE TREATMENT FACILITY OR DISCHARGED UNDER A NPDES PERMIT PRODUCT(AS IS)- INCINERATE OR BURY IN APPROVED LANDFILL /IRE EXTINGUISHING INSTRUCTIONS*** FIREFIGHTERS SHOULD WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS(FULL FACE-PIECE TYPE).PROPER FIRE EXTINGUISHING MEDIA: DRY CHEMICAL/C02/FOAM OR WATER. SLIPPERY CONDITION. USE SAND/GRIT SAL 000006486 6S 470 BETZ MATERIAL SAFETY DATA SHEET (PAGE 3 OF 3) tKODUCT: FOAM-TROL CT ----------- SECTION 7-------------------------- SPECIAL PROTECTIVE EQUIPMENT------------------------------------------ USE PROTECTIVE EQUIPMENT IN ACCORDANCE WITH 29CFR SECTION 1910.132-134. USE RESPIRATORS WITHIN USE LIMITATIONS OR ELSE USE SUPPLIED AIR RESPIRATORS. VENTILATION PROTECTION*** ADEQUATE VENTILATION TO MAINTAIN AIR CONTAMINANTS BELOW EXPOSURE LIMITS RECOMMENDED RESPIRATORY PROTECTION*** IF VENTILATION IS INADEQUATE OR SIGNIFICANT PRODUCT EXPOSURE IS LIKELY, USE A RESPIRATOR WITH ORGANIC VAPOR CARTRIDGES. RECOMMENDED SKIN PROTECTION*** NEOPRENE GLOVES WASH OFF AFTER EACH USE.REPLACE AS NECESSARY RECOMMENDED EYE PROTECTION*** SPLASH PROOF CHEMICAL GOGGLES ----------- SECTION 8-------------------------- STORAGE AND HANDLING PRECAUTIONS-------------------------------STORAGE INSTRUCTIONS*** KEEP DRUMS & PAILS CLOSED WHEN NOT IN USE. STORE IN COOL VENTILATED LOCATION.STORE AWAY FROM OXIDIZERS HANDLING INSTRUCTIONS*** NORMAL CHEMICAL HANDLING ************************************************************************** THIS MSDS COMPLIES WITH THE OSHA HAZARD COMMUNICATION STANDARD AROLD M. HERSH (ENVIRONMENTAL INFORMATION COORDINATOR) X************************************************************************* APPENDIX: REGULATORY INFORMATION THE CONTENT OF THIS APPENDIX REPRESENTS INFORMATION KNOWN TO BETZ ON THE EFFECTIVE DATE OF THIS MSDS. THIS INFORMATION IS BELIEVED TO BE ACCURATE. ANY CHANGES IN REGULATIONS WILL RESULT IN UPDATED VERSIONS OF THIS DOCUMENT. . . . TSCA: ALL COMPONENTS OF THIS PRODUCT ARE LISTED IN THE TSCA INVENTORY TREAT AS OIL SPILL ...RCRA: IF THIS PRODUCT IS DISCARDED AS A WASTE,THE RCRA HAZARDOUS WASTE IDENTIFICATION NUMBER IS: NOT APPLICABLE ...DOT HAZARD/UN#fER GUIDE# IS: NOT APPLICABLE ...THIS PRODUCT CONTAINS THESE CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER OR REPRODUCTIVE TOXICITY: MINERAL OIL(64742-30-9) ...SARA SECTION 302 CHEMICALS: NONE PRESENT IN SIGNIFICANT AMOUNTS ...SARA SECTION 313 CHEMICALS: NONE PRESENT IN SIGNIFICANT AMOUNTS ...SARA SECTION 312 HAZARD CLASS: DELAYED(CHRONIC) ...MICHIGAN CRITICAL MATERIALS: NONE PRESENT IN SIGNIFICANT AMOUNTS NFPA/HMIS : HEALTH - 1 ; FIRE - 1 ; REACTIVITY - 0 ; SPECIAL - NONE ; PE - B SAL 000006487 The Water Management Division of Betz Laboratories. Inc. MAY 15, 1990 CONOCO INC. LAKE CHAS. REFY-WHSE OLD SPANISH TRAIL WESTLAKE, LA 70669 ATTN: PURCHASING DEPARTMENT RE: FOAM-TROL CT 1 Quality Way Trevose, PA 19047-6783 215-355-3300 Telex: 173-148 Fax: 215-355-2869 Dear Customer: Thank you for your recent order of a Betz Product(s). The OSHA HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200) requires that all manufacturers/suppliers of chemicals, send material safety data sheets (MSDS) to their customers with or prior to the receipt of those chemicals by the user. In compliance with this standard you will find enclosed, MSDS for the Betz product(s) you recently ordered. The standard requires that personnel who may come into contact with these products(s) be appraised of any hazards that may be associated with the product(s), therefore please route this information to the correct areas within your organization. Should you have any questions about the contents of these MSDS, please contact Hal Hersh at 215-953-2491. Betz is fully committed to the stewardship of its many product lines and to full disclosure of any health or environmental hazards they may contain. The protection of health and safety in the workplace and surrounding community, and the protection of the environment in which we all live and work requires dedication and team effort. Betz appreciates being part of your team and will ever strive to be equal to the trust you have placed in us. Very Truly Yours, F. S. Spoerle Vice President Engineering SAL 000006488 M NALCO MATERIAL SAFETY DATA SHEET PRODUCT TRANSPORT-PLUS 7205 LIQUID Emergency Telephone Number ^ ktMedical (70S) 920-1510 (24 hours) $ O 23 SECTION 1 PRODUCT IDENTIFICATION TRADE NAME:. TRANSPORT-PLUS 7205 LIQUID DESCRIPTION: An aqueous solution of a polycarboxylic acid NFPA 704M/HMIS RATING 1/1 HEALTH 0/0 FLAMMABILITY 0/0 REACTIVITY 0*lnsignificant l=Slight 2-Moderate 3=High 4=Extreme 0 OTHER * * SECTION 2 HAZARDOUS INGREDIENTS Our hazard evaluation of the ingredient(s) under OSHA's Hazard Communication Rule, 29 CFR 1910.1200 has found none of the ingredient(s) hazardous. * * SECTION 3 PRECAUTIONARY LABEL INFORMATION CAUTION: May cause irritation to skin and eyes. Avoid contact with skin, eyes and clothing. Do not take internally. Empty containers may contain residual product. Do not reuse container unless properly reconditioned. * dp * * SECTION 4 FIRST AID INFORMATION EYES: SKIN: INGESTION: INHALATION: Flush with water for 15 minutes. Call a physician. Wash thoroughly with soap and rinse with water. Call a physician. Do not induce vomiting. Give water. Call a physician. Remove to fresh air. Treat symptoms. Call a physician. NOTE TO PHYSICIAN: No specific antidote is known. Based on the individual reactions of the patient, the physician's judgment should be used to control symptoms and clinical condition. CAUTION: If unconscious, having trouble breathing or in convulsions, do not induce vomiting or give water. SECTION 5 HEALTH EFFECTS INFORMATION PRIMARY ROUTE(S) OF EXPOSURE: Eye, Skin EYE CONTACT: SKIN CONTACT: May cause irritation with prolonged contact. May cause irritation with prolonged contact. SYMPTOMS OF EXPOSURE: A review of available data does not identify any symptoms from exposure. PAGE 1 OF 6 0006 +69 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1138 MATERIAL SAFETY DATA SHEET NALCO G S 5 23 PRODUCT TRANSPORT-PLUS 7205 LIQUID Emergency Telephone Number Medical (708) 920-151 O (24 hours) SECTION 5 HEALTH EFFECTS INFORMATION ( CONTINUED ) AGGRAVATION OF EXISTING CONDITIONS: A review of available data does not identify any worsening >of existing conditions. * * SECTION 6 TOXICOLOGY INFORMATION ACUTE TOXICITY STUDIES: No toxicity studies have been conducted on this product. * * SECTION 7 PHYSICAL AND CHEMICAL PROPERTIES COLOR: Clear yellow DENSITY: SPECIFIC GRAVITY: pH (NEAT) = VISCOSITY: FREEZE POINT: BOILING POINT: FLASH POINT: FORM: Liquid 8.7 lbs/gal. 1.05 @ 73 Degrees F 9.9 7 cps @ 73 Degrees F 31 Degrees F 212 Degrees F 760 mm Hg Greater than 200 Degrees F (PMCC) ASTM D-1298 ASTM E-70 ASTM D-2983 ASTM D-1177 ASTM D-86 ASTM D-93 NOTE: These physical properties are typical values for this product. * IT * * * * * it SECTION 8 FIRE AND EXPLOSION INFORMATION FLASH POINT: Greater than 200 Degrees F (PMCC) ASTM D-93 it EXTINGUISHING MEDIA: Not applicable it SECTION 9 REACTIVITY INFORMATION INCOMPATIBILITY: None known * SECTION 10 PERSONAL PROTECTION EQUIPMENT RESPIRATORY PROTECTION: Respiratory protection is not normally needed since the volatility and toxicity are low. For large spills, entry into large tanks, vessels or enclosed small spaces with inadequate ventilation, a pressure-demand, self-contained breathing apparatus is recommended. VENTILATION: General ventilation is recommended. PROTECTIVE EQUIPMENT: Use impermeable gloves and chemical splash goggles (ANSI 2 87.1 requirements and selection of gloves, goggles, shoes, etc.; when * * it * * * * * * * * PAGE 2 OF 6 0000** jm NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE, ILLINOIS 60563-1133 N NALCO MATERIAL SAFETY DATA SHEET PRODUCT TRANSPORT-PLUS 7205 LIQUID Emergency Telephone Number Medical (708) 920-1510(24 hours) 523 SECTION 10 PERSONAL PROTECTION EQUIPMENT ( CONTINUED ) attaching feeding equipment, doing maintenance or handling product. If clothing is contaminated, remove clothing and thoroughly wash the affected area. Launder contaminated clothing before reuse. * * * * SECTION 11 SPILL AND DISPOSAL INFORMATION IN CASE OF TRANSPORTATIONACCIDENTS, CALL THE FOLLOWING 24-HOUR TELEPHONE NUMBER (708-920-1510) SPILL CONTROL AND RECOVERY: Small liquid spills: Contain with absorbent material, such as clay, soil or any commercially available absorbent. Shovel reclaimed liquid and absorbent into recovery or salvage drums for disposal. Refer to CERCLA in Section 14. Large liquid spills: Dike to prevent further movement and reclaim into recovery or salvage drums or tank truck for disposal. Refer to CERCLA in Section 14. * * * * * * * * * * * * DISPOSAL: If this product becomes a waste, it does not meet the criteria of a hazardous waste as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261, since it does not have the characteristics of Subpart C, (i.e. D001 through D017) nor is it listed under Subpart D. * * * * * As a non-hazardous liquid waste, it should be solidified before disposal in a * sanitary landfill . Can be deep-well injected in accordance with local, state * and federal regulations. * SECTION 12 ENVIRONMENTAL INFORMATION If released into the environment, see CERCLA in Section 14. * SECTION 13 TRANSPORTATION INFORMATION DOT PROPER SHIPPING NAME/HAZARD CODE - PRODUCT IS NOT REGULATED DURING TRANSPORTATION SECTION 14 REGULATORY INFORMATION The following regulations apply to this product. FEDERAL REGULATIONS: * * PAGE 3 OF 6 SAL 000006491 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE, ILLINOIS 60563-1 198 MATERIAL SAFETY DATA SHEET NALCO $S523 PRODUCT TRANSPORT-PLUS 7205 LIQUID Emergency Telephone Number Medical (708) 920-1510 (24 hours) SECTION 14 REGULATORY INFORMATION { CONTINUED ) OSHA HAZARD COMMUNICATION RULE, 29 CFR 1910.1200: Based on our hazard evaluation, this product is not hazardous. CERCLA/SUPERFUND, 40 CFR 117, 302: Notification of spills of this product is not required. SARA/SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (TITLE III) - SECTIONS 302, 311, 312 AND 313: SECTION 302 - EXTREMELY HAZARDOUS SUBSTANCES {40 CFR 355): This product does not contain ingredients listed in Appendix A and B as an Extremely Hazardous Substance. SECTIONS 311 and 312 - MATERIAL SAFETY DATA SHEET REQUIREMENTS (40 CFR 370): Our hazard evaluation has found that this product is not hazardous under 29 CFR 1910.1200. Under Section 311, submittal of MSDS's or a list of product names to the local emergency planning commission, state emergency response commission and local fire department is required after October 17, 1987 if you have: - 10,000 pounds or more of a hazardous substance, or - 500 pounds or the threshold planning quantity, whichever is less, of an extremely hazardous substance. ** * * Hr * * * * * * * * * * * * * * SECTION 313 - LIST OF TOXIC CHEMICALS (40 CFR 372): This product does not contain ingredients (at a level of 1% or greater) on the List of Toxic Chemicals. TOXIC SUBSTANCES CONTROL ACT (TSCA): The chemical ingredients in this product are on the 8(b) Inventory List (40 CFR 710). FOOD AND DRUG ADMINISTRATION (FDA): Federal Food, Drug and Cosmetic Act: When use situations necessitate compliance with FDA regulations, this product is acceptable under 21 CFR 173.310 Boiler Water Additives. U. S. DEPARTMENT OF AGRICULTURE (USDA): USDA Inspection and Grading Programs - Food Safety and Inspection Service: This product is authorized by USDA for use in federally inspected meat and poultry plants. Authorized use is under category G6. PAGE 4 OF 6 000006492 NALCO CHEMICAL CO IMPAMY GNE NALCO CENTER NAPERVILLE. ILLINOIS BQ563-1 15B N NALCO MATERIAL SAFETY DATA SHEET PRODUCT TRANSPORT-PLUS 7205 LIQUID Emorgency Telephone Number Medical (708) 920-1510 (24 hours) (is 5 28 SECTION 14 REGULATORY INFORMATION ( CONTINUED ) RESOURCE CONSERVATION AND RECOVERY ACT (RCRA) , 40 CFR 261 SUBPART C S. Ds If this product becomes a waste, it does not meet the criteria of a hazardous waste. * * * FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 401.15/ formerly Sec. 307, 40 CFR 116/formerly Sec. 311: None of the ingredients are specifically listed. CLEAN AIR ACT, 40 CFR 60, SECTION 111, 40 CFR 61, SECTION 112: This product does not contain ingredients covered by the Clean Air Act. STATE REGULATIONS: * * * * * * * * CALIFORNIA PROPOSITION 65: None of the chemicals on the current Proposition 65 list are known to be present in this product. MICHIGAN CRITICAL MATERIALS: This product does not contain ingredients listed on the Michigan Critical Materials Register. STATE RIGHT TO KNOW LAWS: The following ingredient(s) are disclosed for compliance with State Right To Know Laws: Sodium polymethyacrylate Water 25086-62-8 7732-18-5 * * V * * * * * * * SECTION 15 ADDITIONAL INFORMATION None * SECTION 16 USER'S RESPONSIBILITY This product material safety data sheet provides health and safety information. The product is to be used in applications consistent with our product literature. Individuals handling this product should be informed of the recommended safety precautions and should have access to this information. For any other uses, exposures should be evaluated so that appropriate handling practices and training programs can be established to ensure safe workplace operations. Please consult your local sales representative for any further information. PAGE 5 OF 6 SAL 000006493 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE, ILLINOIS SC563-1 198 MATERIAL SAFETY DATA SHEET NALCO 6 S 5 23 PRODUCT TRANSPORT-PLUS 7205 LIQUID Emergency Telephone Number Medical (708) 920-1510 (24 hours) SECTION 17 BIBLIOGRAPHY ANNUAL REPORT ON CARCINOGENS, U.S. Department of Health and Human Services, Public Health Service, PB 33-135855, 1983. CASARETT AND DOULl'S TOXICOLOGY, THE BASIC SCIENCE OF POISONS, Doull, J., Klaassen, C. D,, and Admur, M. 0., eds., Macmillian Publishing Company, Inc., N. Y., 2nd edition, 1980. CHEMICAL HAZARDS OF THE WORKPLACE, Proctor, N. H., and Hughes, J. P., eds., J. P. Lipincott Company, N.Y., 1981. DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS, Sax, N. Irving, ed., Van Nostrand Reinhold Company, N.Y., 6th edition, 1984. IARC MONOGRAPHS ON THE EVALUATION OF THE CARCINOGENIC RISK OF CHEMICALS TO MAN, Geneva: World Health Organization, International Agency for Research on Cancer, 1972-1977. PATTY'S INDUSTRIAL HYGIENE AND TOXICOLOGY, Clayton, G. D., Clayton, F. E., eds., John Wiley and Sons, N. Y., 3rd edition, Vol. 2 A-C, 1981. REGISTRY OF TOXIC EFFECTS ON CHEMICAL SUBSTANCES, U.S. Department of Health and Human Services, Public Health Service, Center for Disease Control, National Institute for Occupational Safety and Health, 1983 supplement of 1981-1982 edition, Vol. 1-3, OH, 1984. Title 29 Code of Federal Regulations Part 1910, Subpart Z, Toxic and Hazardous Substances, Occupational Safety and Health Administration (OSHA). THRESHOLD LIMIT VALUES FOR CHEMICAL SUBSTANCES AND PHYSICAL AGENTS IN THE WORKROOM ENVIRONMENT WITH INTENDED CHANGES, American Conference of Governmental Industrial Hygienists, OH. Information on this MSDS has changed. The changes are indicated by asterisks on the right side of only the changed sections. This is an updated MSDS as required by OHSA's Hazard Communication Rule 29 CFR 1910.1200. PREPARED BY: Ricky A. Stackhouse PhD., Toxicologist DATE CHANGED J 03/08/90 DATE PRINTED: 04/13/90 PAGE 6 OF 6 sal 0000064-94- NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 6C563-1 190 MATERIAL SAFETY DATA SHEET NALCO S5 82 PRODUCT TRI-ACT 1800 INHIBITOR emergency Telephone Number Medical (708) 920-1510 (24 hours) SECTION 4 FIRST AID INFORMATION ( CONTINUED ) CAUTION: If unconscious, having trouble breathing or in convulsions, do not induce vomiting or give water, NOTE TO PHYSICIAN: Probable mucosal damage may contraindicate the use of gastric lavage. Measures against circulatory shock, respiratory depression and convulsions may be needed. SECTION 5 HEALTH EFFECTS INFORMATION PRIMARY ROUTE(S) OF EXPOSURE: Eye, Skin, Inhalation EYE CONTACT: SKIN CONTACT: INGESTION: INHALATION: Corrosive to the eyes with possible permanent damage depending on the length of exposure and on the first aid action given. Corrosive to the skin, possibly resulting in third degree burns depending on the length of exposure and on the first aid action given. Can cause allergic contact dermatitis in susceptible individuals. Can be harmful or fatal. Can be corrosive to the mucous membranes and the lungs. Can cause an allergic reaction in susceptible individuals. SYMPTOMS OF EXPOSURE: A review of available data does not identify any symptoms from exposure. AGGRAVATION OF EXISTING CONDITIONS: A review of available data does not identify any worsening of existing conditions. SECTION 6 TOXICOLOGY INFORMATION ACUTE TOXICITY STUDIES: Acute toxicity studies have been conducted on this product along with acute toxicity studies on the hazardous ingredient(s) in Section 2. The results are shown below. ACUTE ORAL TOXICITY (ALBINO RATS): LDS0 = 1267 mg/kg 95% Confidence Limit - 1,047 to 1,532 mg/kg COMMENTS: Excessive salivation, squinting of the eyes, loss of muscular coordination, prostration and irregular breathing were observed. ACUTE DERMAL TOXICITY (ALBINO RABBITS): PAGE 2 OF 9 00006< 96 it Hr * * NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1 1SQ AT NALCO MATERIAL SAFETY DATA SHEET PRODUCT TRI-ACT 1800 INHIBITOR* Emergency Telephone Number G S 5 82Medical (708) 920-1510 (24 hours) SECTION 6 TOXICOLOGY INFORMATION ( CONTINUED ) LDS0 = Greater than 2,000 mg/kg COMMENTS: Redness, swelling, and blanching of the skin were noted. Scab formation was due to the corrosive action of the product. However, no systemic signs of toxicity were observed. SKIN SENSITIZATION: Cyclohexylamine can cause sensitization in susceptible individuals. PRIMARY EYE IRRITATION TEST (ALBINO RABBITS): EYE IRRITATION INDEX DRAIZE RATING: Corrosive COMMENTS: Severe redness, swelling, and blistering of the conjunctiva were observed. Opacification of the cornea was also noted. Due to the extreme corosive action of the test material, no Draize index rating could be assigned. OTHER TOXICITY RESULTS: Cyclohexylamine. A battery of tests including the Ames test, sister chromatid exchange, cell transformation, mouse lymphoma and rat hepatocyte/DNA repair provided inconclusive evidence of mutagenic activity. SECTION 7 PHYSICAL AND CHEMICAL PROPERTIES COLOR: Colorless DENSITY: SOLUBILITY IN WATER: SPECIFIC GRAVITY: pH (NEAT) = VISCOSITY: FREEZE POINT: FLASH POINT: FORM: Liquid 8.2 lbs/gal. Completely 0.99 @ 77 Degrees F 12.6 pH (at 1%) 11.2 5 cps @ 77 Degrees F 8 Degrees F 135 Degrees F (PMCC) ODOR: Amine ASTM D-1298 ASTM E-70 ASTM D-2983 ASTM D-1177 ASTM D-93 NOTE: These physical properties are typical values for this product. SECTION 8 FIRE AND EXPLOSION INFORMATION FLASH POINT: 135 Degrees F (PMCC) ASTM D-93 * * EXTINGUISHING MEDIA: Based on the NFPA guide, use dry chemical, alcohol foam, * carbon dioxide or other extinguishing agent suitable for Class B fires. Use * water to cool containers exposed to fire. For large fires, use water spray or * fog, thoroughly drenching the burning material. * l PAGE 3 OF 9 SAL 000006497 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1 19B crrr*. "7pcn -c -- ci; - nni MATERIAL SAFETY DATA SHEET NALCO <rS 5 82 PRODUCT TRI-ACT 1800 INHIBITOR Emergency Telephone Number Medical (708) 920-1510 (24 hours) SECTION 8 FIRE AND EXPLOSION INFORMATION ( CONTINUED ) UNUSUAL FIRE AND EXPLOSION HAZARD: May evolve NOx under fire conditions. SECTION 9 REACTIVITY INFORMATION INCOMPATIBILITY: N-nitrosamines, many are cancer causing agents to laboratory animals, may be formed when certain amines are mixed with nitrous acid, organic or inorganic nitrites or atmospheres with high nitrous oxide concentrations. * * * * * Avoid contact with strong acids (eg, sulfuric, phosphoric, nitric, hydrochloric, chromic, sulfonic) which can generate heat, splattering or boiling and the release of toxic fumes. * * it THERMAL DECOMPOSITION PRODUCTS: In the event of combustion CO, CO,, NOx may * be formed. Do not breathe smoke or fumes. Wear suitable protective equipment. * SECTION 10 PERSONAL PROTECTION EQUIPMENT RESPIRATORY PROTECTION: If it is possible to generate significant levels of vapors or mists, a NIOSH approved or equivalent respirator is recommended. For large spills, entry into large tanks, vessels or enclosed small spaces with inadequate ventilation, a pressure-demand, self-contained breathing apparatus is recommended. VENTILATION: General ventilation is recommended. Additionally, local exhaust ventilation is recommended where vapors or mists may be released. PROTECTIVE EQUIPMENT: Wear gloves, boots, apron and a face shield with chemical splash goggles (ANSI Z 87.1 requirements and selection of gloves, goggles, shoes, etc.). A full slicker suit is recommended if gross exposure is possible. The availability of an eye wash fountain and safety shower is recommended. If clothing is contaminated, remove clothing and thoroughly wash the affected area. Launder contaminated clothing before reuse. * * it * * * * * * * * * * * * it * * SECTION 11 SPILL AND DISPOSAL INFORMATION IN CASE OF TRANSPORTATION ACCIDENTS, CALL THE FOLLOWING 24-HOUR TELEPHONE NUMBER (708-920-1510) PAGE 4 OF 9 SAl 00000 6498 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1109 VvK 1\ MATERIAL SAFETY DATA SHEET N ALGO Emergency Telephone Number Medical (70S) 920-1510(24 hours) (j g > g SECTION 11 SPILL AND DISPOSAL INFORMATION ( CONTINUED ) SPILL CONTROL AND RECOVERY: Small liquid spills: Contain with absorbent material, such as clay, soil or any commercially available absorbent. Shovel reclaimed liquid and absorbent into recovery or salvage drums for disposal. Refer to CERCLA in Section 14. Large liquid spills: Dike to prevent further movement and reclaim into recovery or salvage drums or tank truck for disposal. Refer to CERCLA in Section 14. For large indoor spills, evacuate employees and ventilate area, responsible for control and recovery should wear the protective equipment specified in Section 10. Those DISPOSAL: If this product becomes a waste, it meets the criteria of a hazardous waste as defined under the Resources Conservation and Recovery Act (RCRA) 40 CFR 261. Hazardous Waste D001 & D002. As a hazardous liquid waste, it must be solidified with stabilizing agents (such as sand, fly ash, or cement) so that no free liquid remains before disposal to a licensed industrial waste landfill (Hazardous Waste Treatment, Storage and Disposal facility). A hazardous liquid waste can also be incinerated in accordance with local, state, and federal regulations. SECTION 12 ENVIRONMENTAL INFORMATION If released into the environment, see CERCLA in Section 14. SECTION 13 TRANSPORTATION INFORMATION DOT PROPER SHIPPING NAME/HAZARD CODE - CORROSIVE LIQUID, N.O.S, CORROSIVE MATERIAL UN 1760 CONTAINS - CYCLOHEXYLAMINE SECTION 14 REGULATORY INFORMATION * * * The following regulations apply to this product. FEDERAL REGULATIONS: OSHA'S HAZARD COMMUNICATION RULE, 29 CFR 1910.1200: Based on our hazard evaluation, the following ingredients in this product are hazardous and the reasons are shown below. PAGE 5 OF 9 SAL 000006499 NALCO CHEMICAL COMPANY ONE NALCO CENTER * NAPERVILLE, ILLINOIS 60563-1-1 90 MATERIAL SAFETY DATA SHEET NALCO 6 s 5 82 PRODUCT TRI-ACT 1800 INHIBITOR Emergency Telephone Number Medical (708) 920-1 51 O (24 hours) SECTION 14 REGULATORY INFORMATION ( CONTINUED ) Cyclohexylamine - Corrosive, combustible Ethanolamine - Corrosive, combustible Methoxypropylamine - Corrosive, combustible Cyclohexylamine - TWA 10 ppm, 41 mg/m3 ACGIH/TLV Ethanolamine = TWA 3 ppm, STEL 6 ppm ACGIH/TLV 7.5 mg/m3 15 rag/ra3 ACGIH/TLV Cyclohexylamine ** TWA 10 ppm, 40 mg/m3 OSHA/PEL Ethanolamine = TWA 3 ppm, STEL 6 ppm OSHA/PEL 8 mg/ra3 15 mg/m3 OSHA/PEL Methoxypropylamine = TWA 10 ppm, 20 ppm (15 minute exposure) TLV Weel Guidelines CERCLA/SUPERFUND, 40 CFR 117, 302: Notification of spills of this product is not required. SARA/SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (TITLE III) - SECTIONS 302, 311, 312 AND 313: SECTION 302 - EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355): This product contains cyclohexylamine, which is listed in Appendix A and B as an Extremely Hazardous Substance. The statuatory threshold planning quantity for this substance is 10,000 pounds. A release of 10 pounds of product will require a notification to your State Emergency Response Commission. You may also be required to notify the NATIONAL RESPONSE CENTER - See CERCLA/SUPERFUND, above. SECTIONS 311 and 312 - MATERIAL SAFETY DATA SHEET REQUIREMENTS (40 CFR 370): Our hazard evaluation has found this product to be hazardous. The product should be reported under the following EPA hazard categories: XX Immediate (acute)health hazard -- Delayed (chronic) health hazard XX Fire hazard -- Sudden release of pressure hazard -- Reactive hazard * * * * * * * * * * * * * * * * * * * * Under Section 311, submittal of MSDS's or a list of product names to the local * emergency planning commission, state emergency response commission and local * PAGE 6 OF 9 SAL 000006500 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1'03 N NALCO MATERIAL SAFETY DATA SHEET PRODUCT TRI-ACT 1800 INHIBITOR Emergency Telephone Number Medical (708) 920-1510(24 hours) G $ t5 8 2 SECTION 14 REGULATORY INFORMATION ( CONTINUED ) fire department is required after October 17, 1987 if you have: * - 10,000 pounds or more of a hazardous substance, or - 500 pounds or the threshold planning quantity, whichever is less, of an extremely hazardous substance. * * * * * SECTION 313 - LIST OF TOXIC CHEMICALS (40 CFR 372): * This product does not contain ingredients (at a level of 1% or greater) on the * List of Toxic Chemicals. * * TOXIC SUBSTANCES CONTROL ACT (TSCA): The chemical ingredients in this product are on the 8(b) Inventory List (40 CFR 710). * * * * RESOURCE CONSERVATION AND RECOVERY ACT (RCRA), 40 CFR 261 SUBPART C & D: If this product becomes a waste, it does meet the criteria of a hazardous waste as defined under RCRA 40 CFR 261 (consult Section 11). * * FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 401.15 (formerly Sec. 307), 40 CFR 116 (formerly Sec. 311): None of the ingredients are specifically listed. CLEAN AIR ACT, 40 CFR 60, SECTION 111, 40 CFR 61, SECTION 112: This product contains the following ingredients covered by the Clean Air Act: Ethanolaraine - Section 111 Cyclohexylamine - Section 111 STATE REGULATIONS: * * * * * * it * * it * CALIFORNIA PROPOSITION 65: None of the chemicals on the current Proposition 65 list are known to be present in this product. MICHIGAN CRITICAL MATERIALS: This product does not contain ingredients listed on the Michigan Critical Materials Register. STATE RIGHT TO KNOW LAWS: The following ingredient(s) are disclosed for compliance with State Right To Know Laws: Cyclohexylamine 108-91-8 * SAL 000006501 PAGE 7 OF 9 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1 19B 7nn-^nF--' MATERIAL SAFETY DATA SHEET NALCO G S 5 82 * PRODUCT TRI-ACT 1800 INHIBITOR Emergency Telephone Number Medical (708) 920*1510 (24 hours) SECTION 14 REGULATORY INFORMATION ( CONTINUED ) Ethanolamine Methoxypropylamine Water 141-43-5 5332-73-0 7732-18-5 SECTION 15 ADDITIONAL INFORMATION None SECTION 16 USER'S RESPONSIBILITY This product material safety data sheet provides health and safety information. The product is to be used in applications consistent with our product literature. Individuals handling this product should be informed of the recommended safety precautions and should have access to this information. For any other uses, exposures should be evaluated so that appropriate handling practices and training programs can be established to ensure safe workplace operations. Please consult your local sales representative for any further information. SECTION 17 BIBLIOGRAPHY* I ANNUAL REPORT ON CARCINOGENS, U.S. Department of Health and Human Services, Public Health Service, PB 33-135855, 1983. CASARETT AND DOULL'S TOXICOLOGY, THE BASIC SCIENCE OF POISONS, Doull, J., Klaassen, C. D., and Admur, M. O., eds., Macmillian Publishing Company, Inc., N. Y., 2nd edition, 1980. CHEMICAL HAZARDS OF THE WORKPLACE, Proctor, N. H., and Hughes, J. P., eds., J. P. Lipincott Company, N.Y., 1981. DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS, Sax, N. Irving, ed., Van Nostrand Reinhold Company, N.Y., 6th edition, 1984. I ARC MONOGRAPHS ON THE EVALUATION OF THE CARCINOGENIC RISK OF CHEMICALS TO MAN, Geneva: World Health Organization, International Agency for Research on Cancer, 1972-1977. PATTY'S INDUSTRIAL HYGIENE AND TOXICOLOGY, Clayton, G. D.r Clayton, F. E., eds., John Wiley and Sons, N. Y., 3rd edition, Vol. 2 A-C, 1981. REGISTRY OF TOXIC EFFECTS ON CHEMICAL SUBSTANCES, U.S. Department of Health and Human Services, Public Health Service, Center for Disease Control, National Institute for Occupational Safety and Health, 1983 SAL 000006502 PAGE 8 OF 9 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE, ILLINOIS BQ563-1 19B MATERIAL SAFETY DATA SHEET NALCO PRODUCT TRI-ACT 1800 INHIBITOR Emergency Telephone Number Medical (708) 920-1510 (24 hour*) GS5 82 SECTION 17 BIBLIOGRAPHY ( CONTINUED ) supplement of 1981-1982 edition, Vol. 1-3, OH, 1984. Title 29 Code of Federal Regulations Part 1910, Subpart Z, Toxic and Hazardous Substances, Occupational Safety and Health Administration (0SHA). THRESHOLD LIMIT VALUES FOR CHEMICAL SUBSTANCES AND PHYSICAL AGENTS IN THE WORKROOM ENVIRONMENT WITH INTENDED CHANGES, American Conference of Governmental Industrial Hygienists, OH. Information on this MSDS has changed. The changes are indicated by asterisks on the right side of only the changed sections. This is an updated MSDS as required by OHSA's Hazard Communication Rule 29 CFR 1910.1200. PREPARED BY: Ricky A. Stackhouse PhD., Toxicologist DATE CHANGED: 04/03/90 DATE PRINTED: 04/13/90 PAGE 9 OF 9 SAL 000006503 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE, ILLINOIS 60563-1 19B NALCO G S 5 82 MATERIAL SAFETY DATA SHEET % PRODUCT Emergency Telephone Number Medical (708) 920-1510(24 hours) SAV- NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 6G563-1 19B W3LCHEM' MATERIAL SAFETY DATA SHEET in *1 m MANUFACTURER/SUPPLIER: Welchem, Inc. P. 0. Box 920941 Houston, Texas 77292-0941 TEL. (713) 462-4783 H-9290-9 Refinery coker water clarifier MSDS NO: 05007909 6 S6 24 EMERGENCY HEALTH INFORMATION: (800) 447-8735 EMERGENCY SPILL INFORMATION: (800) 424-9300 CHEMTREC, U.S.A. OTHER PRODUCT SAFETY INFORMATION: (312) 856-3516 IMPORTANT COMPONENTS: Hydrophyllic polyacrylate: trade secret Polymerized polyol: trade secret. No exposure limit established. WARNING STATEMENT: Danger* Causes eye damage and skin irritation. Can cause respiratory irritation. Causes severe irritation of the mouth, throat, and esophagus. HMIS/NFPA CODES:(HEALTH;3)(FLAMMABILITY;1)(REACTIVITY; 1) APPEARANCE AND ODOR: Clear, viscous solution. HEALTH HAZARD INFORMATION EYE EFFECT: Causes eye damage. FIRST AID: Immediately flush eyes with plenty of water for at least 15 minutes, then get immediate medical attention. PROTECTION: Do not get in eyes. Wear chemical goggles. SKIN EFFECT: Causes skin irritation. FIRST AID: Wash exposed skin with soap and water. thoroughly clean and dry before reuse. irritation develops. Remove contaminated clothing and Get medical attention if PROTECTION: Do not get on skin or clothing. Wear protective clothing and gloves. INHALATION EFFECT: Can cause respiratory irritation. FIRST AID: If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. Get prompt medical attention. PROTECTION: Use with adequate ventilation. If ventilation is inadequate, use NIOSH/MSHA certified respirator which will protect against organic vapor/acid mist. SAL 000006505 H-9290-9 MSDS NO: 05007909 PAGE 02 OF 03 Cr S 6 24 ___________________________ HEALTH HAZARD INFORMATION - CONTINUED _______________________ INGESTION EFFECT: Causes severe irritation of the mouth, throat and esophagus. FIRST AID: If swallowed, drink plenty of water, do NOT induce vomiting. Get immediate medical attention. __ FIRE AND EXPLOSION INFORMATION ______________________________________________________ FLASHPOINT: Above 200F (93C) ASTM D56 EXTINGUISHING MEDIA: Agents approved for Class B hazards (e.g., dry chemical, carbon dioxide, halogenated agents, foam, steam) or water fog. UNUSUAL FIRE AND EXPLOSION HAZARDS: Toxic vapors are given off when heated. REACTIVITY INFORMATION DANGEROUS REACTIONS: Mixing with bases can evolve heat and cause spattering. HAZARDOUS DECOMPOSITION: Can form toxic gases if exposed to open flame or high heat. Incomplete burning can produce carbon monoxide, carbon dioxide, and other harmful products. STABILITY: Stable. ___ CHEMICAL AND PHYSICAL PROPERTIES ______________________________________________________________________ BOILING POINT: Above 95F (35C) pH: 10.4 SOLUBILITY IN WATER: Totally soluble. SPECIFIC GRAVITY (WATER = 1): 0.971 VISCOSITY: 1613 cP @ 25C POUR POINT: 25F (4C) ASTM D97 ____ STORAGE AND ENVIRONMENTAL PROTECTION STORAGE REQUIREMENTS: No special requirements. SPILLS AND LEAKS: Remove mechanically or contain on an absorbent material. WASTE DISPOSAL: Disposal must be in accordance with applicable federal, state, or local regulations. Enclosed-controlled incineration is recommended unless directed otherwise by applicable ordinances. Do not landfill. Residues and spilled material are hazardous waste due to corrosivity. EMPTY CONTAINERS: Since the emptied containers retain product residue, follow label warnings even after container is emptied. SAL 000006506 H-9290-9 MSDS NO: 05007909 __TOXICOLOGICAL INFORMATION _ PAGE 03 OF 03 G S6 24 Specific toxicity tests have not been conducted on this product. Our hazard evaluation is based on information from similar products, the ingredients, technical literature, and/or professional experience. No component of this product present at levels greater than 0.1% is identified as a carcinogen by NTP, IARC or OSHA. REGULATORY INFORMATION CERCLA REPORTABLE QUANTITY: This product is not reportable under 40 CFR Part 302.4. DOT PROPER SHIPPING NAME: Corrosive Liquid, N.O.S., UN1760. OSHA HAZARD COMMUNICATION STANDARD: Corrosive. RCRA STATUS: This product is not subject to the 40 CFR Part 268.30 land ban on the disposal of certain hazardous wastes. SARA STATUS: This product is regulated under the following section(s) of SARA Title III, 42 USC 9601. Spills or releases of the product may be reportable as determined by the information given below: SECTIONS 311 AND 312 OF SARA AND 40 CFR PART 370: This product is defined as hazardous by OSHA under 29 CFR Part 1910.1200(d). TSCA STATUS: All of the components of this product are listed on the TSCA Inventory. ISSUE INFORMATION BY: R. G. Farmer, Director, Product Safety & Toxicology ISSUED: March 01, 1990 SUPERSEDES: February 23, 1990 This material safety data sheet and the information it contains is offered to you in good faith as accurate. We have reviewed any information contained in this data sheet which we received from sources outside our company. We believe that information to be correct but cannot guarantee its accuracy or completeness. Health and safety precautions in this data sheet may not be adequate for all individuals and/or situations. It is the user's obligation to evaluate and use this product safely and to comply with all applicable lavs and regulations. No statement made in this data sheet shall be construed as a permission or recommendation for the use of any product in a manner that might infringe existing patents. No warranty is made, either express or implied. SAL 000006507 6 s 6 24 SAL 000006508 APR 0 3 get MATERIAL SAFETY DATA SHEET PRODUCT NAME Urethane Seal Coat CAerosol) #2044 MANUFACTURED BY: CRC CHEMICALS P C0 22 * NSDS002044 Phone <215) 674-4300 885 LOUIS DRIVE, WARMINSTER, PA 18974 1. INGREDIENTS CAS n ACGIH TLV OSHA PEL *ASTM Tvne I Dolvurethan 3 NA_______________________ --NA_ NA **Yvlene **Arpfone Mineral Sm'rits Tron oxide niement *1 1 1 Trirhloroethane PrnnsnF 11330-20-7____________ 100 100 67-64-1_________________ 750 750 64742-88-7____________ -NA________ NA NA_________________________ NA NA 71 - 5 5-6 350 350 74-38-6_________________ NA 1000 T flohufane , 75-28-5_________________ NA NA Other Limits NA 200 800 % 13.5 13.5 26.0 1.0 3.5 14.5 14.0 .o *Note - resin contains n 3 free isocyanate. Propane ind isol utane f jnction as propellents - pressur a is 55 psig at 70F . **The *e chem cals fo und in SARA Title III and subje :t to release invent ory repo `ting. 2. PHYSICAL DATA Specific Gravity 1*128 Vapor Pressure NA % Volatile 82 Boilinq Point NA Evaporation Rate NA Freezing Point NA Vapor Density Heavier than air Appearance and Odor Red brown liquid, pleasant odor, faintly aromatic Solubility Negligible in water. 3. FIRE AND EXPLOSION DATA Flashooint^noF Method TCf! Extinguishing Media C0^, Foam, Dry chemical Flammable Limits NA LEL NA UEL NA Unusual Hazards Aerosol containers may explode when heated above 130F *nng ro hydrocarbon propellant. 4. REACTIVITY AND STABILITY Stability Stable Hazardous decomposition products Thermal ('Hydrogen chloride, chlorine, carbon monoxide, Materials to avoid Srrnnf, nY1'rii7Prapossibly phosgene 5. PROTECTION INFORMATION Ventilation Mechanical ventilation to maintain vapor cone, below TLV. _____________ Respiratory <;Pi f contained hrpafh inp apparatus if vapor rnne. is above TT.V. ^*veS__ Solvent rpninranr-------------- Eye & Face Safety goggles Other Protective Equipment - Not normally required for aerosol packages SAL OOOnnARn PCO 22 #2044 6. HEALTH HAZARD DATA Primary Routes of EntryInhalation and skin Signs and Symptoms of Exposure _______________________________________________ ___ 1 Acute Overexposure Inhalation - headache, nausea, anesthetic effects and unconciou9ness. Skin - drying and defatting. Eyes - Burning and irritation, 2. Chrome Overexposure Dermatitis - May have liver and kidney effects, Medical Conditions Generally Aggravated by Exposure Breathing problems_________ _____________________ Owmcai Listed is Carcinogen or Potential Carcinogen National Toxicology Program Yaa No g IARC Monographs Yaa No g OSHA res ~ No X Emergency and First Aid Procedures (xf symptoms persist, call a physician) 1 Inhalation Remove to fresh air - Apply artificial respiration if necessary, 2 Eyes p^us^ with water for 15 min. Do not rub, 3 Skin yasfr wjth soap and water, __________________________________________________________ 4 Ingestion po not induce VQmiting. 7. SPILL OR LEAK PROCEDURES( Precautions to be takan m Handling and Storage _, Store in 8 COOl dry STfiS Stecs to oa taken m case Materials .s released or >p.iied -- , .. Not normally an aerosol problem. Ventilate area, remove sources of ignition, absorb on inert material and place in a closed container. _____ Waste Disposal Discarded filled or partially used aerosols are hazardous waste and mustJhe_dispQagd_Qf in conformance with regulations. 8. SPECIAL PRECAUTIONS AND USE DIRECTIONS Aerosol containers may explode when heated above 130F. The solvent vapors are heavier than air and will collect in low confined areas. Make sure ventilation is adequate for location being used. PREPARED BY: A . B . Read ORIGINAL DATE OR DATE OF REVISION SAL 000006510 x/90_______________________________________________ MATERIAL SAFETY DATA SHEET P-O-W AEROSOL (HEW) PAGE : 01 (045039-0444M -E0016293-50O5 ) jDATE OF ISSUE | 12/13/89 ! SUPERSEDES | 09/01/89 SECTION I GENERAL INFORMATION CHEMICAL NAME & SYNONYMS N/A TRADE NAME 8 SYNONYMS P-O-W AEROSOL (NEW) CHEMICAL FAMILY AEROSOL PYRETHRUM/BAYGON INSECTICIDE MANUFACTURERS NAME: NATIONAL CHEMSEARCH OIV. OF NCH CORP. FORMULA XC--MIXTURE ADDRESS < NUMBER. STREET. CITY. 5TATE & ZIP CODE) BOX 152170 IRVING. TEXAS 75015 PREPARED BY : KEVIN UHL/T.S. CHEMIST ! PRODUCT CODE NUMBER :! EMERGENCY TELEPHONE NUMBER 5005 214-438-1381 SECTION II- HAZARDOUS INGREDIENTS THE HAZARDS PRESENTED BELOW ARE THOSE OF THE INDIVIDUAL COMPONENTS AS THE PRODUCT MIXTURE HAS NOT BEEN TESTED AS A WHOLE. CHEMICAL NAME (INGREDIENTS) i HAZARD | TLV- PERCHLORCETHYLENE SUSP CARC 50PPM ALIPHATIC PETROLEUM DISTILLATE CDM8 . NA NONYLPHENOL 2-(1-METHYLETHOXY) PHENYL EYE IRR. NOT EST. METHYL CARBAMATE MUT . .5MG/M3 CARBON DICXIDE ASPHYXIANT 5000PPM i PEL25PPM 1OOPPM NOT EST. ! CAS* 127-18-4 8030-30-6 25154-52-3 . SMG/M3 lO.OOOPPM 1 14-26-1 124-28-9 GS4 2ft P-O-W AEROSOL (NEw> SECTION I IA - NON-HAZARDDUS INGREDIENTS =AGE : 02 NON-HAZARDOUS INGREDIENT NAMES ANO CAS NUMBERS ARE PROTECTED UNDER NJ TRADE SECRET REGISTRY * 409363-E041P SECTION III * PHYSICAL OATA BOILING PT.(FAHRENHEIT) VAPOR PRESSURE (MM H6). VAPOR DENSITY < AIR-1> PH 10014 PERCENT. VOLATILE BY VOLUME (%> SOLUBILITY IN WATER ! 250 ! 13 ! 5.5 | N/A {99 i 1 t SPEC GRAVITY (H2D-1) :1.380 )1 COLOR LIGHT YELLOW ( ( ODOR PYRETHRIN/SOLVENT (r CLARITY TRANSPARENT i EVAPORATION RATE i (BU AC - 1 ) |2.0 | | APPRECIABLE VISCOSITY | NON- VISCOUS SECTION IV - FIRE AND EXPLOSION HAZARD FLASH POINT (METHOO USED ) NON-FLAM ] FLAMMABLE LIMITS I LEL f N/A ! UEL iN/A EXTINGUISHING MEDIA -ALCCHCL* X< -- FOAM < - - FOAM X<--C02 DRY X<--CHEM1CAL WATER x<-- spray < - -OTHE R SPECIAL FIRE FIGHTING PROCEDURES USE WATER IN FINE 5 = RAY TO COOL UNBROKEN CONTAINERS TC PREVENT BURSTING FROM EXCESSIVE PRESSURE. SELF-CONTAINED BREATHING APPARATUS AND RUBBER PROTECTIVE CLOTHING SHOULD BE WORN. CIKE AREA TO PREVENT RUNOFF. UNUSUAL FIRE & EXPLOSION HAZARDS FIRE FIGHTING SHOULD BE DONE FROM UPWIND TO MINIMI2E POSSIBILITY OF EXPOSURE TC PESTICIDE. SMOKE AND FUMES. EVACUATE PE OPLE DOWNWIND AS APPROPRIATE. SEE HAZARDOUS DECOMPOSITION PRODUCTS. LEVEL 1 AEROSOL (NFPA 30B) NFPA HAZARD RATING (0-INSIGNIFICANT: 1-SLIGHT;2-MODE RATE:3-H1GH;4-EXTREME) : 3 <--HEALTH 0 --FLAMMABILITY O <--REACTIVITY <--SPE6iaL SAL 000006511 C S 4 2$ P-O-M AEROSOL (NEW) SECTION V - HEALTH HA2AM0 OATA PAQE : 03 THRESHOLD LIMIT VALUE : NOT,ESTABLISHED FOR MIXTURE. SEE SECTION II. EFFECTS OF OVEREXPOSURE - ACUTE - (SHORT TERM EXPOSURE) IRRITATING TO SKIN EYES AND MUCOUS MEMBRANES. SKIN EXPOSURE - LOCAL IRRITATION POSSIBLE FOLLOWED BY TOXIC EFFECTS. INHALATION - EUPHORIA. HEADACHE. BURNING SEN5ATI0N IN THE CHEST. INGESTION - IRRITATION OF MOUTH. THROAT AND ESOPHAGUS; TOXIC EFFECTS OF NAUSEA, RAPID 8REATHING, DROWSINESS. EYE EXPOSURE - BURNING SENSATION AND IRRITATION. PROLONGED SKIN CONTACT CAUSES IRRITATION, REDOENING. DRYING AND CAN LEAD TO DERMATITIS. CONSTANT EXPOSURE TO EYES CAUSES MARKED IRRITATION. INHALATION FOR A PROLONGED PERIOD CAN LEAD TO CENTRAL NERVOUS SYSTEM DEPRESSION. HEADACHES. AND NAUSEA. - CHRONIC - (LONG TERM EXPOSURE) SYSTEMIC & OTHER EFFECTS: PERCHLOROETHVLENE HAS CAUSED LIVER AND KIDNEY TOXIC EFFECTS IN CHRONICALLY OVEREXPOSED EXPERIMENTAL ANIMALS. CARCINOGENICITY: THREE STUDIES HAVE BEEN CONDUCTED TO ASSESS THE CARCINOGENIC POTENTIAL OF PERCHLOROETHVLENE IN LABORATORY ANIMALS. IN ONE STUDY. RATS AND MICE WERE EXPOSED BY GAVAGE (FORCE-FED) AT LEVELS OF 500 AND 1000 MG/KG/DAY. INCREASED INCIDENCE OF LIVER TUMORS WERE OBSERVED IN MICE. THE RESULTS OF THE RAT STUDY WERE INCONCLUSIVE DUE TO AN EXCESS IN ANIMAL DEATHS. THE SECOND STUDY INVOLVED RATS EXPOSED TO CONCENTRATIONS UP TO 600 PPM VIA INHALATION. SIX HOURS PER DAY, S DAYS PER WEEK FOR ONE YEAR. THE ANIMALS WERE OBSERVED UNTIL THE TIME OF DEATH OR UNTIL THE 31ST MONTH ANO STUDIES INDICATE NO STATISTICALLY SIGNIFICANT INCREASE IN TUMORS. SEE SECTION VI --TOXICITY INFORMATION PRIMARY ROUTE OF ENTRY: X<-- INHALATION INGESTION X<-- ABSORPTION EMERGENCY 6 FIRST AID PROCEDURES INHALATION : GET PERSON OUT OF CONTAMINATED AREA TO FRESH AIR. IF BREATHING HAS STOPPED. ARTIFICIAL RESPIRATION SHOULD BE STARTED. OXYGEN MAY BE ADMINISTERED, IF READILY AVAILABLE. SEEK MEOICAL ATTENTION IMMEDIATELY. EYE CONTACT: IMMEDIATELY FLUSH EYES WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES HOLDING EYELIDS APART TO INSURE FLUSHING OF THE EYE SURFACE. SEEK MEDICAL ATTENTION IMMEDIATELY^ SKIN CONTACT: IMMEDIATELY WASH CONTAMINATED SKIN WITH PLENTY OF SOAP AND WATER. IRRITATION PERSISTS. SEEK MEDICAL ATTENTION IMMEDIATELY. IF INGESTION : CALL A PHYSICIAN CR POISON CONTROL CENTER IMMEDIATELY. DC NOT INDUCE VOMITING OR GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. GET MEDICAL ATTENTION IMMEDIATELY. JF VICTIM IS CONSCIOUS. GIVE LARGE AMOUNTS OF WATER TO DILUTE STOMACH CONTENTS. NOTES TO PHYSICIAN : ATROPINE SULFATE IS ANTIDOTAL. P-O-W AEROSOL 1 NEW 1 SECTION VI - TOXICITY INFORMATION PAGE : 04 PRODUCT CONTAINS CHEMICAL LISTED AS CARCINOGEN OR POTENTIAL CARCINOGEN BY: IARC X<--YES NTP <--YES OSHA <--YS ACGIH <--YES OTHER <--Y$ <--NO X<--NO X<--NO X<--NO X<--NO PERCHLOROETHVLENE TERET0GEN1S1&: IHL-RAT: 300PPM/7H/D 1. CARCINOGENISIS ORL-MUS TDLO: 195GM/KG/50W-I:CAR IHL-HMN TCLO: 96sM/7H:SYS 1. IHL-MAN TCLO: 280=PM/2H:EYE 1. ORL-RAT LD50: 8850MG/KG 1. NONYLPHENOL ORL-RAT LD50: 1620MG/KG SKN-RBT LD50: 2140MG/KG 1 1 2-(1-METHYLETHOXY) PHENYL METHYLCARBAMATE ORL-RAT LD50: 83MG/KG 1. SKN-RAT LD50: SOOMG/KG 1. NMO-SAT 250NG/PLATE 1. ALIPHATIC PETROLEUM OISTILLATE SYSTEMIC 8. OTHER EFFECTS: (CONT.) UNK-MAN LDLO; 1176MG/KG 2. THE SIGNIFICANCE OF THE SECOND ORL-RAT LD50: 28G/KG 2. STUDY HAS BEEN QUESTIONED. SINCE EXPOSURE LASTED FOR ONLY ONE YEAR. A THIRD STUDY CONDUCTED FOR THE NATIONAL TOXICOLOGY PROGRAM (NTP) INVOLVED EXPOSURE OF MICE TC 1O0 OR 200 PPM AND RATS TO 200 AND 400 PPM FOR SIX HOURS PER DAY, E DA YS PER WEEK FCR 2 YEARS. SEE SEC. X --SPEC. PRECAUTION SECT ICN VII - REACTIVITY DATA STABILITY j X<- - STAB LE <--UNS TAB L \ CONDIOTIONS TC AVOID N/A INCOMPATIBILITY (MATERIALS TO AVOID) ALKALINE MATERIALS, STRONG OXIDANTS. HAZARDOUS DECOMPOSITION PRODUCTS WHEN HEATED TO DECOMPOSITION EMITS ACRID SMOKE.FUMES 6 PHOSGENE. HAZARDOUS ! WILL NOT \ X <--OCCUR POLYMERIZATION] n/a MAY j CONDITIONS TC AVOIC <--OCCUR j SECTION VIII - SPILL OR LEAK PROCEDURES STEPS TAKEN IN CASE MATERIAL IS RELEASED OR SPILLEO THE PRODUCT IS IN AN AEROSOL SO A SPILL IS UNLIKELY. IN CASE OF LEAKAGE. CONTAIN SPILL, PICK UP WITH AN ABSORBANT. 00 NOT FLUSH TO SEWER. PLACE INTO LABELED CONTAINER AND SEAL. CONTACT YOUR STATE PESTICIDE OR ENVIRONMENTAL CONTROL AGENCY. OR THE HAZARDOUS WASTE REPRESENTATIVE AT THE NEAREST EPA REGIONAL OFFICE FOR GUIDANCE f > (CONTINUED) p-Q-W AEROSOL (NEW) SECTION VIII - SPILL OR LEAK PROCEDURES PAGE : 05 WASTE DISPOSAL METHOD REPLACE THE CAP OH THE AEROSOL CONTAINER IN SEVERAL LAYERS OP INCINERATE OR PUNCTURE. CONTAINER NEWSPAPER AND AND SECURELY WRAP THE DISCARD IN TRASH. ORIGINAL DO NOT NEUTRALIZING AGENT SOAP AND WATER WILL NEUTRALIZE 6S4 23 SECTION IX - SPECIAL PROTECTION INFORMATION REQUIRED VENTILATION THIS PRODUCT IS FOR OUTDOOR USE ONLY. RESPIRATORY PROTECTION TYPICAL USE OF PROOUCT DDES NOT REQUIRE THE USE OF A RESPIRATOR. PROTECTIVE GLOVES PROTECTIVE GLOVES TO MINIMIZE CONTACT INCLUDING PVA, MBR NITRILE. VlTON. NITRILE LATEX EYE PROTECTION SAFETY GOGGLES SHOULD BE WORN DEPENDING ON SEVERITY OF EXPOSURE. CTHER PROTECTION PROTECTIVE CLOTHING SHOULD BE WORN DEPENDING UPON SEVERITY OF EXPOSURE. 5ECTION X - STORAGE AND HANDLING INFORMATION STORAGE TEMPERATURE 120 F.<--MAX 3= F . <--MIN 1 INDOOR JX jHEATED | PRECAUTIONS TO BE TAKEN IN HANDLING 6 STORING KEEP AWAY FROM IGNITION SOURCES. STORE IN A COOL. DRY PLACE. WASH THOROUGHLY AFTER HANDLING. OTHER PRECAUTIONS. AVOID CCNTAVI NAT ING WATER SOURCES. CO NOT ALLOW SDRAV DRIFTS TO CONTACT DESIRABLE PLANTS KEE= CUT D F REACH OF CHILDREN AND ANIMALS. READ ENTIRE LAB E L BEFORE USE. OTHER PRECAUTIONS SYSTEMIC & OTHER EFFECTS: <CCNT.> INCREASED INCIDENCE OF LIVER TUTORS WERE OBSERVED IN MICE. IN RATS AN INCREASE IN A RARE KIDNEY TUMOR WAS OBSERVED IN THE MALE RAT. AND BOTH MALES AND FEMALES HAD AN INCREASED INCIDENCE OF MONONUCLEAR CELL LEUKEMIA. SEE SECTICN XI I--REFEFENCES ]REFRIGERATED! OUTDOOR |] P-O-W AEROSOL (NEW) SECTICN XI - REGULATORY INFORMATION PAGE : 06 CHEMICAL NAME C.A.S. NUMBER UPPER % LIMIT PERCHLOROETHYLENE 127-18-4 UE METHYLCARBAMATE 1 14-26-1 UE TH05E INGREDIENTS LISTED ABOVE ARE SUBJECT TO THE REPORTING REQUIREMENTS OF 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHOR 12AT I ON ACT OF 1986 AND AO CFR PART 372. IF UE 4 USE EXEMPTION) APPEARS UNDER UPER % LIMIT. END USERS ARE EXEMPT FROM NOTIFICATION BECAUSE THE PRODUCT IS USED AND LAEELED FOR ROUTINE JANITORIAL WORK, CR THE PROCUCT IS USED AND LABELED FOR FACILITY GROUNDS MAINTENANCE (SUCH AS FERTILIZERS AND HERBICIDES). OR THE PRODUCT IS USED AND LABELED FOR MAINTAINING MOTCR VEHICLES. SECTION XII - TRANSPORTATION (FOR FUTURE USE) APPLICABLE REGULATIONS <--49 CFR < - - IMCC SHIPPING NAME HAZARD CLASS LABELS UNIT CONTAINER DOT SPS CONTAINER AERCSOL PROPELLANT(S) <--TARJFF 6 C <--IATA <--MlLlTARY AIR (AFR 71-4) 1 jID NUMBER REPORT QTY | LIMITED QTY [ NET EXPLOSIVE WT. SECTICN XU! - REFERENCES 1. DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS. 6TH EDITION. N. IRVING SAX. 2. NIDSH REGISTRY CF TOXIC EFFECTS OF CHEMICAL SUBSTANCES. 1982. 3. NIOSH POCKET GUIDE TC CHEMICAL HAZARDS. 1978. 4. VENDOR'S MSDS. SYSTEMIC & OTHER EFFECTS: (COST.) THE INTERNATIONAL AGENCY FOR CANCER SAL 0000065Z3 ^ S4 23 (CONTINUED) P-O-W AEROSOL (N6W) SECTION XIII - REPCfttNCCS PAGE : 07 RESEARCH CONSIDERS LIVER TUMORS IN MICE AS LIMITED EVIDENCE OP ANIMAL CARCINOGINCITY. EPIDEMIOLOGIC STUDIES HAVE BEEN INCONCLUSIVE IN DETERMINING WHETHER PERCHLOROETHVLENE CAUSES CANCER IN HUMANS. REPRODUCTIVE TOXICITY: STUDIES ON MICE. HATS AND RABBITS HAVE BEEN CONDUCTED TO EVALUATE THE POTENTIAL EFFECTS PERC MAY HAVE ON REPRODUCTION ANO OFFSPRING OF LABORATORY ANIMALS- PERC HAS BEEN FOUND TO BE EMBROYTOXIC AND HAS CAUSED OELAYS IN THE DEVELOPMENT OF FETUSES. PERC HAS NOT CAUSEO TERATOGENIC (BIRTH DEFECT) EFFECTS IN EXPERIMENTAL ANIMALS. THE INFORMATION CONTAINED HEREIN IS BASED ON OATA CONSIDERED ACCURATE IN LIGHT OF CURRENT FORMULATION, HOWEVER. NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THIS DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF. NATIONAL CHEMSEARCH DIV. OF NCH CORP. ASSUMES NO RESPONSIBILITY FOR PERSONAL INJURY OR PROPERTY DAMAGE CAUSEO BY THE USE . STORAGE OR DISPOSAL OF THE PRODUCT IK A MANNER NOT RECOMMENDED ON THE PRODUCT LABEL. USERS ASSUME ALL RISKS ASSOCIATED WITH SUCH UNRECOMMENDEO USE, STORAGE. OR DISPOSAL OF THE PRODUCT. \ SAL 00000651* APR 0 3 CCI MATERIAL SAFETY DATA SHEET PRODUCT NAME LECTRA CLEAN (Aerosol) #20l8,020l8T MANUFACTURED BY: CRC Industries, Inc. 885 LOUIS DRIVE, WARMINSTER, PA. 18974 1. INGREDIENTS * 1,1,1 Trichloroethane CAS # 71-55-6 1,3 Dioxolane k 2-Butanol 646-06-0 78-92-2 ACGIH TLV 350 NA 100 CS2 0 5 # MSDSO ?018 Phone (215) 674-4300 OSHA PEL 350 NA 100 Other Limits % 91.0 3.0 2.0 Carbon Dioxide 124-38-9 * 5000 10000 4.0 These chemicals are listed ii i the Toxic Chemical Lis ; found in Section 313 of th 3 Emergency Planning and Commu: lity-Right-To-Know Act ;SARA Titl i III) an i are sub Ject to release inventory reporting i inder that act. 2. PHYSICAL DATA (does not include carbon dioxide propellent) Specific Gravity 1.293 (70f) Vapor Pressure 100 mm 8 20C % Volatile 100* Boiling Point 164F Evaporation Rate Rapid Freezing Point N/A Vapor Density 4.55 (air = 1) Appearance and Odor Colorless liquid - irritating odor at high concentrations Solubility Slight solubility in water - good solvent for many organic materials 3. FIRE AND EXPLOSION DATA Flashpoint None Method TCC, COC, TOC Flammable Limits Extinguishing Media Water, fog LEL 6 UEL 16.7 Unusual Hazards Aerosol cans nay explode if their temperature exceeds 130 F 4. REACTIVITY AND STABILITY Stability Good - avoid exposures to open flames, arcs, and high temperatures. Hazardous decomposition products Thermal - Hydrogen chloride, chlorine and some phosgene Materials to avoid Avoid storage in aluminum containers or contact with aluminum and/or zinc powder. 5. PROTECTION INFORMATION________________________________________ _____________ Ventilation Maintain vapor concentration below TLV - Use mechanical means if necessary. Respiratory Above TLV use self contained breathing appratus (air mask or vapor mask) Gloves solvent resistant Eye & Face safety glasses Other Protective Equipment fjQt normally required for aerosol product usage. G S 2 0,5 USDS 00 2018 6. HEALTH HAZARD DATA ___________________ Primary Routes of Entry Inhalation and akin contact_____________________ . Signs and Symptoms of Exposure 1 Acute Overexposure inhalation - headaches, dizziness, anesthesia, unconsciousness. Eyes - causes pain and some irritation. Skin - irritation on repeated exposures. 2. Chronic Overexposure Repeated overexposures nay cause liver and kidney effects. Medical Conditions Generally Aggravated fay Exposure High levels (8000 ppm +) of vapor nay cause Chemical Listed as Carcinogen or Potential Carcinogen cardiac arrhythmias Natiorwl Toxieotofly Program YesP Mo XX (ARC Yes MonographsNo XX No XX OSHA Yes G Emergency and First Aid Procedures (If 3rmptoill3 persist, call a physician)_____________ 1 Inhalation Renpyg to fresh air, apply artificial respiration if necessary. 2 Eves________flush for 15 minutes with large amounts of water._____________ 3 ______ Remove contaminated clothing, wash exposed area with soap and water. 4. Ingestion do HOT induce vomiting - call physician 7. SPILL OR LEAK PROCEDURES Precautions to be taken in Handling ano Storage Store in a cool, dry place. Mamr'ai^s'^eieasedofspiiied Usually not a problem with aerosols. Area should be ventilated and absorbent used to pick up excess material. Waste Disposal Discarded full cans or partially filled cans are considered Hazardous Waste - Dispose of In conformance with Local, State and Federal regulation 8. SPECIAL PRECAUTIONS AND USE DIRECTIONS Avoid skin contact or breathing of vapors. Since vapors are heavier than air, aerosols should not be used in confined areas or low spots without adequate ventilation. If vapors are suspected in a low area, do not enter unless special breathing apparatus is used and an observer is present for assistance. Keep aerosols away from heat. PREPARED BY: Allen B. Reed ORIGINAL DATE OR DATE OF REVISION 3-90 S*L 000006516 Apr o 3 ecu MATERIAL SAFETY DATA SHEET PRODUCT NAME CO CQVTACT CLKAMSt (Aeroeol) #2013,2016 MANUFACTURED CV: QIC CHEMICALS 886 LOUIS DRIVE. WAfMNffTBL PA 18974 1. INGREDIENTS Trlchlorotrlfluoroethane Chlorodifluoromethane CASS 76-13-1 75-4! . N ACGIH TLV 1 looo //,/, C$139 # USDS 002015 Phone (215) 674-4300 OSHA PEL 1000 Other Limits 1000 % 75 25 * This chealcal la listed In be Toxic BMrgeocy Planning and Com f1** ~ R1` release Inventory reporting under the / ,,, [ 'J/ iy- 1 ectlon 3 l3 of the tie III) ind are s Abject to 2. PHYSICAL DATA (Does not include Chorodifluoromethane propellent) Specific Gravity 1-57 Vapor Pressure 5.5 psla 70 P % Volatile 100 Soiling Point 117.6 P Evaporation Rate 0*3 (Carbon tet * 1) Freezing Point-35.7 P Vapor Density 6.5 (air *1) Appearance and Odor Colorless liquid Solubility Slight solubility In water - Soluble In eany organic liquids 3, FIRE AND EXPLOSION DATA Fiashooint Hone Method TCC, TOC Flammable Limits Hone Extinguishing Media Hot needed LEL -- UEL -- Unusual Hazards Aerosol containers can explode If contents are heated to more than 130 P 4. REACTIVITY AND STABILITY Stability Very stable "______________________________________________________________ Hazardous decomposition products Halogens, halogen acids, possibility of phosgene (Thermal) Materials to avoid Powdered eetals aucfa as alueinua, aagneslua, calclue, zinc 5. PROTECTION INFORMATION Ventilation Maintain concentration below TLV. Respiratory Self-contained breathing apparatus above TLV* Gloves Keopreoe Eye & Pace Safety goggles Other Protective Equipment protective clothing only if there is repeated contact with liquid. T7T 00000651T G S 1 39 MSDA002015 6. HEALTH HAZARD DATA_________________________________________________ __ ____________ Primary Rout-- of Entry Inhalation and akin___________________________________ Signs and Symptom* of fecpoaura____________________________________ ______________ 1. Acuta Ovraxposur* Inhalation - Drowsiness, llghtheadedneas possible cardiac arrhythslaa at high concentration. Stela * defatting action, may cause dermatitis. gyaa - --j irritate eyas. 2. Chronic Ovaraxpotura May cause akin Irritation with rep--tad akin contact. Medical Conditions Ganarally Aggravatad by Expoaura Impaired cardiovascular function such as cardiac arrhythmias sight be sensitised by InLalatlon. Oamieal Lnd -- Cjrtunogi orPwwwHCj<tjnuo>n Ngoonl Tqacotofy Program (XXYm Q Wo tASC Mancqnpftg Y-- Hots 0$HA thC SokS Emergency and First Aid Procedures (if syeptoea persist call a physician) 1. Inhalation Rang-- to fresh air - apply artificial respiration if necessary 2. Eyas piuah with large aaounta of water______ 3. Skin tfaah with water 4. Ingestion induce vomiting - call a physician 7. SPILL OR LEAK PROCEDURES Prcaufiorw to b* uMn Handling and Sioragg Store in a cool dry area 1 Qua to high volatility Mterlal quietly evaporates.________ Yentilate area, evacuate personnel until concentration la below TLY or use self-contained breathing appratus. Waste Disposal If possible puap into drums for reclamation. 8. SPECIAL PRECAUTIONS AND USE DIRECTIONS Aerosol containers may explode if exposed to temperatures over 130 P. Vapors are vary heavy and will collect in low areas. Oxygen would be displaced and asphyxiation could result. Good ventilation is a auat for low areas and confined spaces. PREPARED BY: Allan B. Reed________________ ORIGINAL DATE OR DATE OF REVISION 1/90 - SAL 000006518 j^Pj HALOOR TOPSOE, INC. CAO 11 TK-711 . MATERIAL SAFETY DATA SHEET revised: May 1989 EMERGENCY HAZARD RATING 4 - Ext ACME 3 - MIOM 7 MOOEBATE i slight 0 INSIGNIFICANT A. (lYo)/0\ HEALTH AEACTIVITY y>y/ SPECIFIC HAZARD Page 1 of 2 1 GENERAL INFORMATION Trade name and synonym: Hydroprocessing Catalyst, TK-711 Chemical family: Oxides of Nickel, Molybdenum, Aluminum Major chemical constituents (CAS No.): N10 (1313-99-1) MoO (1313-27-5) A1 0 (1344-28-1) 6 5 All components of the catalyst appear on the TSCA Inventory. Manufacturer's or Importer's name 4 address: HALOOR TOPSOE, INC. Telephone No.: 17629 El Camlno Real Houston, TX 77058 Emergency Telephone No.: (713) 480-2600 (713) 474-3261 2. HAZARDOUS INGREDIENTS concentration _____ wt % TLV/T^A* mg/m __ N10 2 1 (N1) MoO. 6 5 (Mo) 92 10 (Nuisance Dust) *As adopted by ACGIH Aluminum oxide, molybdenum trioxide, and all compounds containing chromium, cobalt, nickel, copper or zinc are subject to Chemical Release Reporting requirements of SARA Section 313, as codified In 40 CFR Part 372. 3. PHYSICAL DATA Appearance & odor: Yellowish-green cylinders or rings, odorless Bulk density: 31 lbs/cuft (rings) Vapor pressure: Not relevant 38 lbs/cuft (cylinders) Melting point: >1470 F Solubility in water: Negligible ~4. FIRE & EXPLOSION HAZARD DATA Flash Point: Not relevant Flammable Limits: Not relevant Extinguishing Media: Not relevant Special Fire Fighting Procedures: Not relevant, Noncombustible Unusual Fire & Explosion Hazard: None SAt- 0000065! 9 r C A 0 11 5. HFALTH HAZARD DATA TK-711 Pag 2 of 2 Effects of overexposure: Nickel and some nickel compounds have been listed as human carcinogens. In addition, nickel compounds may Irritate the skin and respiratory tract. Some people can develop an allergy towards nickel and therefore should not handle this catalyst. Emergency & first aid procedures: In case of significant Inhalation, seek medical attention. Hash off the skin with soap and water. Irrigate eyes with water. listed as a carcinogen: Yes __X___ No by OSHA ______ IARC X NTP X T. REACTIVITY DATA Stability: Stable Unstable Incompatibility (Materials to avoid): Hater damages catalytic properties. Hazardous decomposition products: N/A ' Hazardous polymerization: may occur ____ will not occur X 7. SPILL AND .WASTE DISPOSAL PROCEDURES Steps to be taken If material is spilled: Collect all spilled material by mechanical means and place In a container. Avoid dust generation. Label container. Waste Disposal Method: In accordance with Federal, state, & local regulations. 8. PERSONAL PROTECTION INFORMATION Respiratory protection: Use approved respirator In confined space. Eye protection: Goggles Ventilation of work place: Outside: Natural Inside reactor: Mechanical Hand protection: Gloves Other protection: Safety shoes recommended when handling drums. 9. SPECIAL PRECAUTIONS During storage: Keep containers dry and tightly closed. When handling containers: Adhere to standard safety procedures. Use mechanical assistance to avoid strain. During loading: Adhere to standard safety procedures. Minimize free fall of material to avoid breakage. During unloading: Adhere to standard safety procedures. Spent catalyst may be pyrophoric in the presence of air. The information and recommendations set forth herein are believed to be correct and presented in good faith as of the date hereof. Haldor Topsoe. Inc. however, makes no representation or warranty as to the completeness thereof and disclaims any liability for damages resulting from reliance thereon. SAL 000006520 v/ CRETM-N MATERIAL safety DATA SHEET MSDS NUMBER : 6153-03 REVIEW DATE : November 14, 1989 24 HOUR EMERGENCY ASSISTANCE 'CRITERION:' 800-777-607 6 (IN USA): ; i: CHENTREC: 800-424-9300 (IN USA) CRITERION: 713-863-3942 (GLOBAL) CANUTEC: 613-996-6666 (CANADA) GENERAL! HSOS: ASSISTANCE CRITERION: 713-874*2600 HEALTH FIRE REACTIVITY 200 HA2ARD RATING : MOOERATE-2 EXTREME-4 For acute and chronic health effects refer to Section IV SECTION I NAME PRODUCT CRITERION TRILOBE 424 CATALYST CHEMICAL NAME C-424 CHEMICAL FAMILY METAL OXIDE CRITERION PROOUCT COOE CRITERION FILE NUMBER 55140 40706211 55150 40706154 55160 40706153 55170 40706155 PROOUCT USE SECTION II-A NO. COMPOSITION REFINERY PROCESSING PRODUCT/INGREDIENT CAS HUMBER PERCENT P CRITERION TRILOBE* 424 CATALYST MIXTURE 100 1 ALUMINUM OXIDE (ALUMINA) - AljOj 2 MOLYBDENUM OXIDE - HoCU 3 NICKEL OXIDE - NiO 4 PHOSPHOROUS OXIDE - P-,0; 1344-23-1 1313-27-5 1313-99-1 1314-56-3 BALANCE 19.5 4 8 SECTION NO. II-B SARA TITLE III AND CERCLA SARA HI EHS RQ (lbs) <*1) SARA III EHS TPO (lbs) (*2) SARA III 311/312 CATEGORIES (*3) INFORMATION SARA III SECTION 313 (*4) CERCLA RQ (lbs) (*5> 1 AUOj 2 MoOj 3 NiO 4 P205 1 H-1 H-1 H-1, H-2 10 YES YES YES, NICKEL COMPOUNDS SPENT C-424 H-1, H-2, P-3 OTES.................... . *1 REPORTABLE OUANTITY OF EXTREMELY HAZARDOUS SUBSTANCE UNDER SECTION 302 *2 THRESHHOU) PLANNING QUANTITY OF EXTREMELY HAZARDOUS SU8STANCE UNDER SECTION 302 *3 HAZARD CATEGORY FOR SECTION 311/312 REPORTING: HEALTH H-1 = IMMEDIATE (ACUTE) HEALTH HAZARD H-2 = DELAYED (CHRONIC) HEALTH HAZARO PHYSICAL P-3 = FIRE HAZARD P-4 = SUDDEN RELEASE OF PRESSURE HAZARD P-5 = REACTIVE HAZARD *4 TOXIC CHEMICAL UNDER SECTION 313, CATEGORY AS REQUIRED UNDER SECTION 313 (40 CFR 372.42). *5 REPORTABLE QUANTITY OF HAZARDOUS SUBSTANCE UNDER CERCLA 1 SAL 000006521 C A042 SECTION II-C NO. ACUTE ORAL LD50 (MO/kg) PRODUCT NAME: CRITERION TRILOBE* 424 CATALYST KSDS NO. 6153-03 ACUTE TOXICITY DATA ACUTE DERMAL LDSO (ng/kg) ACUTE INHALATION LC50 (0/M3) P C-424 2 MoO, L P_0_ NOT AVAIUBLE 12S-180 (RAT) 2090 (RAT) 287 (LC70, RAT -1 hr/30 days) 1217 IRAT - 1 hr) SECTION III NHMIS INFORMATION ACCORDING TO CRITERION'S UNDERSTANDINC, THIS PRODUCT (C-424) IS CLASSIFIED UNDER THE CANADIAN WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM (UHMIS) AS: POISONOUS AND INFECTIOUS CUSS D DIVISION 2, SUBDIVISION A. FOR SPENT CRITERION TRILOBE* 424 CATALYST, THE UHMIS CLASSIFICATION IS: POISONOUS AND INFECTIOUS CLASS D DIVISION 2, SUBDIVISION A. FLAMMABLE AND COMBUSTIBLE CLASS B, DIVISION 6. SECTION IV HEALTH INFORMATION THE HEALTH EFFECTS NOTED 8ELOU ARE CONSISTENT^ WITH REQUIREMENTS UNDER THE OSHA HAZARD COMMUNICATION STANDARD (29 CFR 1910-1200). EYE CONTACT BASED ON ESSENTIALLY SIMILAR PRODUCT TESTING, PRODUCT IS MILDLY IRRITATING TO THE EYES. SKIN CONTACT BASED ON ESSENTIALLY SIMILAR PROOUCT TESTING, PROOUCT IS MINIMALLY IRRITATING TO THE SKIN. INHALATION THIS PROOUCT CONTAINS NICKEL OXIDES UHICH ARE CONSIDERED TOXIC AND MAY BE HARMFUL IF INHALED; MAY PRODUCE LUNG DAMAGE. INGESTION THIS PROOUCT MAY BE SLIGHTLY TOXIC AND HARMFUL IF SWALLOWED. SIGNS AND SYMPTOMS IRRITATION AS NOTEO ABOVE. LUNG DAMAGE MAY BE EVIDENCED BY SHORTNESS OF BREATH, KAY BE ACCOMPANIED BY CHRONIC COUGH. ESPECIALLY ON EXERTION, AND AGGRAVATED MEDICAL CONDITIONS PREEXISTING EYE AND RESPIRATORY DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS PROOUCT. FUNCTION(S) FROM PREEXISTING DISORDERS HAY BE AGGRAVATED BY EXPOSURE TO THIS PROOUCT. IMPAIRED LUNG OTHER HEALTH EFFECTS THE NATIONAL TOXICOLOGY PROGRAM AND INTERNATIONAL AGENCY FOR RESEARCH ON CANCER HAVE DETERMINED THERE IS SUFFICIENT EVIDENCE FOR THE CARCINOGENICITY IN EXPERIMENTAL ANIMALS OF NICKEL OXIDES. THEREFORE, THE HANDLING PROCEDURES AND SAFETY PRECAUTIONS IN THIS HSDS SHOULD BE FOLLOWED TO MINIMIZE EMPLOYEE'S EXPOSURE. SECTION V OCCUPATIONAL EXPOSURE LIMITS MO. OSHA TRANSITIONAL FINAL RUL^ LIHIT/PEL LIMIT/TUA <g/M3 ) (mg/M3) ACG1H TLV/TUA TLV/STEL (mg/M3) (mg/M3) OTHER At23 2 MoO-j 3 NiO 15 5 15 1 10 5 10 5*** 1 10 10 1 TOTAL DUST RESP1RA8LE FRACTION INSOLUBLE COMPOUNDS, TOTAL DUST INSOLUBLE COMPOUNDS, RESPIRABLE FRACTION AS Ni COMPLIANCE WITH TRANSITIONAL LIMITS REQUIRED BY ADMINISTRATIVE OR ENGINNERING CONTROLS ONLY, UNTIL 12/31/92. COMPLIANCE WITH FINAL RULE LIMITS BY ANY COMBINATION OF ENGINEERING CONTROLS, WORK PRACTICES AND PERSONAL PROTECTIVE EQUIPMENT UNTIL 12/31/92. STARTING 1/1/93, THE FINAL RULE LIMITS MUST BE MET BY ADMINISTRATIVE M OR ENGINEERING CONTROLS ONLY. AS NICKEL, CRITERION HAS ESTABLISHED AN INTERNAL STANOARD FOR NICKEL OXIDE, BASED ON 8-12 HOUR TWA AT 300 MICROGRAMS/M3. 2 00000652Z SAL C A042 PRODUCT MANE: CRITERION TRILOBE* 424 CATALYST USDS NO. 6153-03 \ SECTION VI EMERGENCY AND FI3RST AID PROCEDURES EYE CONTACT FLUSH EYES WITH PLENTY OF UATER FOR 15 MINUTES WHILE HOLDING EYELIDS OPEN. GET MEDICAL ATTENTION. SKIN CONTACT REMOVE CONTAMINATED CLOTHING/SHOES AND WIPE EXCESS FROM SKIN. SOAP AND WATER. IF IRRITATION OCCURS, GET MEDICAL ATTENTION. FLUSH SKIN WITH UATER. FOLLOW BY WASHING WITH DO NOT REUSE CLOTHING UNTIL CLEANED. INHALATION REMOVE VICTIM TO FRESH AIR AND PROVIDE OXYGEN IF BREATHING IS DIFFICULT. GET MEDICAL ATTENTION. INGESTION DO NOT GIVE LIQUIDS IF VICTIM IS UNCONSCIOUS OR VERY DROWSY. OTHERWISE, GIVE NO MORE THAN 2 GLASSES OF UATER AND INDUCE VOMITING BY GIVING 30CC (Z TABLESPOONS) SYRUP OF IPECAC. IF IPECAC IS UNAVAILABLE, GIVE 2 GLASSES OF UATER AND INDUCE VOMITING 8Y TOUCHING FINGER TO BACK OF VICTIM'S THROAT. KEEP VICTIM'S HEAD BELOW HIPS WHILE VOMITING. GET MEDICAL ATTENTION. SECTION VII SUPPLEMENTAir HEALTH INFORMATION NO REPORTS OF CANCER HAVE BEEN ASSOCIATED WITH THIS PROOUCT, HOWEVER, EPIDEMIOLOGICAL STUDIES ON WORKERS IN NICKEL REFINERIES HAVE DEMONSTRATED AN EXCESS RISK OF CANCER OF THE NASAL CAVITY AND LUNG. THEREFORE, THE HANDLING PROCEDURES AND SAFETY PRECAUTIONS IN THIS MSDS SHOULD BE FOLLOWED TO MINIHI2E EMPLOYEE'S EXPOSURE. FOR SPENT CATALYST - NICKEL SUBSULFIDE, WHICH MAY BE PRESENT IN THE REDUCED CATALYST, HAS BEEN SHOWN TO PRODUCE A POSITIVE CARCINOGENIC EFFECT IN EXPERIMENTAL ANIMALS VIA INHALATION EXPOSURE. BASED ON THIS INFORMATION CRITERION H^S ESTABLISHED AN INTERNAL STANDARD FOR NICKEL SUBSULFIDE, BASED ON 8-12 HOUR TUA AT 15 HICROGRAMS/M . STUDIES CONDUCTED ON GUINEA PIGS HAVE OETERMINEO THAT SIMILAR CRITERION CATALYSTS TO C-424 ARE NOT SKIN SENSITIZERS. HOWEVER, SOME INDIVIDUALS MAY BE SUSCEPTIBLE TO NICKEL SENSITIZATION. SECTION VIII PHYSICAL DATA BOILING POINT: APPROX. 4000 (DEG F) SPECIFIC GRAVITY: NOT APPLICABLE (H20=1) VAPOR PRESSURE: NOT SIGNIFICANT (MM HG) HELTING POINT: APPROX. 3700 (DEG F) SOLUBILITY: APPROX. 5% (IN UATER) VAPOR DENSITY: NOT APPLICABLE (AIR=1) EVAPORATION RATE (N-BUTYL ACETATE = ): NOT SIGNIFICANT BULK DENSITY = 0.80 g/ec APPEARANCE AND ODOR: YELLOWISH-GREEN, TRI LOBE*-SHAPED EXTRUDATES. NO OOOR SECTION IX FIRE AND EXPLOSION HAZARDS FLASH POINT METHOC: WILL NOT BURN. (SEE BELOW) FLAWABLE LIHITS /% VOLUME IN AIR LOWER: N/AP UPPER: N/AP EXTINGUISHING MEDIA AS PROOUCED, WILL NOT BURN. CHEMICAL OR COj. IF REDUCED (SPENT) CATALYST IS INVOLVED IN A FIRE, USE WATER FOG, FOAM, DRY SPECIAL FIRE FIGHTING PROCEDURES AMD PRECAUTIONS WILL NOT BURN. WEAR FULL PROTECTIVE CLOTHING AND A NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS IF CATALYST IS IN FIRE AREA. UNUSUAL FIRE AMO EXPLOSION HAZARDS MAY FORM NICKEL CARBONYL; A VERY TOXIC, POTENTIALLY LETHAL GAS, ON CONTACT WITH CARBON MONOXIDE. AS PROOUCED, THE CATALYST WILL NOT BURN. HOWEVER, IN USE, THE CATALYST IS REDUCED AND SULFIDED. THE REDUCED FORM, ESPECIALLY WHEN WARM, REACTS WITH OXYGEN ON CONTACT WITH AIR. ENOUGH HEAT CAN BE PROOUCED TO BURN COKE OR RESIDUAL ORGANIC MATERIAL LEFT ON THE CATALYST, AND COULD IGNITE FLAMMABLE MIXTURES WHICH IT MAY CONTACT. TO 3 SAL 000006523 C/U>42 PRODUCT NAME: CRITERION TRILOBE* 424 CATALYST KSDS NO. 6153*03 PROTECT AGAINST THIS POSSIBILITY, SPENT CATALYST SHOULO 8E OXIDIZED AND COOLED BEFORE REMOVING IT FROM THE REACTOR4 OTHER MEASURES, SUCH AS COOLING AND BLANKETING UITH NITROGEN OR UATER WETTING THE CATALYST MAY ALSO BE USED TO RETARD OXIDATION. SECTION X REACTIVITY STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR CONDITIONS AND MATERIALS TO AVOID: CONTACT WITH CARBON MONOXIDE UNDER CERTAIN CONDITIONS CAN FORM VERY TOXIC AND POTENTIALLY LETHAL NICKEL CARBONYL (ACGIH TLV/TWA FOR NICKEL CARBONYL IS 0.05 PPM). HAZARDOUS DECOMPOSITION PRODUCTS SEE ABOVE. SECTION XI EMPLOYEE PROTECTION RESPIRATORY PROTECTION IF EXPOSURE MAY OR DOES EXCEED OCCUPATIONAL EXPOSURE LIMITS (SEC. V) USE A NIOSH-APPROVEO RESPIRATOR TO PREVENT OVEREXPOSURE. IN ACCORD WITH 29 CFR 1910.134 USE EITHER AN ATMOSPHERE-SUPPLYING RESPIRATOR OR AN AIR-PURIFYING RESPIRATOR FOR PARTICULATES. PROTECTIVE CLOTHING AVOID PROLONGED OR REPEATED CONTACT UITH SKIN. WEAR GLOVES AND OTHER CLOTHING AS REQUIRED TQ MINIMIZE CONTACT. ADDITIONAL PROTECTIVE MEASURES USE EXPLOSION-PROOF VENTILATION AS REQUIRED TO CONTROL PARTICULATE CONCENTRATIONS. SECTION: XII^ - ENVIRONMENTAL PROTECTION :^ - SPILL OR LEAK PROCEDURES WEAR NIOSH APPROVED RESPIRATOR WHEN DUST LEVELS EXCEED CCCUPATIONAL EXPOSURE LIMITS. WEAR GLOVES, GOGGLES AND PROTECTIVE CLOTHING TO CONTROL EXPOSURE TO BOOY SURFACES. DO HOT DRY SWEEP OR USE METHODS WHICH INCREASE DUSTING. USE VACUUMING OR SWEEPING COMPOUND FOR CLEAN-UP. DO NOT WASH SPILLS INTO SEWERS OR OTHER PUBLIC WATER SYSTEMS. WASTE DISPOSAL UNDER EPA RCRA (40 CFR 261.21), SPENT UNREGENERATED CATALYST IS A WASTE MATERIAL, IT COULD BE AN IGNITABLE HAZARDOUS WASTE, HAZARDOUS WASTE NUMBER D001. REFER TO LATEST EPA OR STATE REGULATIONS REGARDING PROPER DISPOSAL. ENVIRONMENTAL HAZARDS DO NOT WASH SPILLS INTO SEWERS OR OTHER PUBLIC WATER SYSTEMS. 8ECTION XIII ' ?^ SPECIAL PRECAUTIONS DO NOT EAT, DRINK OR SMOKE IN AREAS WHERE CATALYST IS PRESENT. WASH HANOS THOROUGHLY AFTER HANDLING. KEEP CONTAINERS CLOSED WHEN NOT IN USE. NOTIFY AUTHORITIES IF MATERIAL THREATENS TO ENTER OR ENTERS INTO SEWER OR PUBLIC UATER SYSTEM. ALL PRECAUTIONS GIVEN FOR FRESH CATALYST SHOULD BE OBSERVED FOR SPENT CATALYST AND WASHINGS. BECAUSE OF CHARACTERISTICS NOTED IN SECTIONS IX AND X, SPENT CATALYST HANDLING CAN REQUIRE SPECIAL, MORE RESTRICTIVE, PROCEDURES THAN FRESH CATALYST.* * SECTION XIV__________ TRANSPORTATION REQUIREMENTS________ DEPARTMENT OF TRANSPORTATION CLASSIFICATION: FRESH CATALYST NOT HAZARDOUS BY DOT REG' OTHER REQUIREMENTS: * SPENT CATALYST ONLY - FLAMMABLE SOLID N.O.S. UN1325. 4 SAL 000006524 C A 0 42 PRODUCT NAME: CRITERION TRILOBE* 424 CATALYST USDS HO. 6153-03 SECTION XV OTHER REGULATORY CONTROLS______________ THE COMPONENTS OF THIS PROOUCT ARE LISTED ON THE EPA/TSCA INVENTORY OF CHEMICAL SUBSTANCES. THE INFORMATION CONTAINED HEREIN IS BASED ON THE OATA AVAILABLE TO US AND IS BELIEVED TO BE CORRECT. HOWEVER, CRITERION MAKES NO WARRANTY, EXPRESSED OR IMPLIED, REGARDING THE ACCURACY OF THESE DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF. CRITERION ASSUMES HO RESPONSIBILITY FOR INJURY FROM THE USE OF THE PRODUCT DESCRIBED HEREIN. SECTION XVISUMMARY OF REVISIONS USDS NUMBER 6153-01 6153-02 6153-03 DATE NATURE OF REVISIONIST OCTOBER 30, 1988 ORIGINAL ISSUE MAY 12, 1989 ADD NEW OSHA TRANSITIONAL AND FINAL RULE EXPOSURE LIMITS. ADD SECTION XVI - SUMMARY OF REVISIONS. ADD REVIEW DATE TO TOP OF PAGE 1. November 14, 1989 ADD CERCLA INFORMATION TO SECTIONS I IB AND XII WHERE APPROPRIATE. CHANGE PROOUCT COOE NUMBERS (DROP 93's AND -*S>. REVIEW DATE: November 14, 1989 cwgJ2_cJI . M c CjoJUot^\ DONALD C. MCCULLOCH TECHNICAL OIRECTOR CRITERION CATALYST COMPANY L.P. CRITERION CATALYST COMPANY L.P. TWO GREENSPOINT PLAZA, SUITE 1000, 16825 NORTHCHASE DR., HOUSTON, TEXAS 77060 5 SAL 000006525 SAL 000006526 RITERION CATALYSTS MATERIAL SAFETY DATA SHEET MSDS NUMBER : 6159-04 REVIEW DATE i November 14, 1989 24 HOUR EMERGENCY ASSISTANCE CRITERION: 800-777-6076 (IN USA) CRITERION: 713-863-3942 (GLOBAL) CXEXTREC: 800-424-9300 (IN USA) CANUTEC: 613-996-6666 (CANADA) GENERAL MSDS ASSISTANCE CRITERION: 713-874-2600 HEALTH 2 FIRE 0 REACTIVITY 0 LEAST-0 HAZARD RATING : MODERATE-? EXTREME-4 CA0 43 For scute end chronic health effects refer to Section tv SECTION I NAME PRODUCT CRITERION TRILOBE 444 CATALYST CHEMICAL NAME C-444 CHEMICAL FAMILY METAL OXIDE CRITERION PRODUCT COOE CRITERION FILE NUMBER 55180 40706161 55190 40706160 55200 40706159 55195 product use SECTION II-A MO. COMPOSITION REFINERY PROCESSING PRODUCT/INGREDIENT CAS HUMBER P CRITERION TRR06E* 444 CATALYST MIXTURE 1 ALUMINUM OXIDE (ALUMINA) Al.O, 2 MOLYBDENUM OXIDE - MoO* 3 COBALT OXIOE CoO 1344-28-1 1313-27-5 1307-96-6 PERCENT TOO BALANCE 14.5 4 SECTION MO. II-B SARA TITLE III AND CERCLA SARA 111 EKS M (lbs) (*1> SARA III EHS TPQ (tbs) (*2) SARA HI 311/312 CATEGORIES (3) INFORMATION SARA III SECTION 313 C*4> 1 AUO3 2 MoL 3 CoO H-1 H-1 H-1, H-2 YES YES YES, COBALT COMPOUNDS CERCLA RQ (lbs) (*5) SPENT C-444 H-1, H-2, P-3 *1 REPORTABLE QUANTITY OF EXTREMELY HAZARDOUS SUBSTANCE UNOER SECTION 302 *2 THRE5HHOLD PLANNING QUANTITY OF EXTREMELY HAZARDOUS SUBSTANCE UNOER SECTION 302 *3 HA2ARD CATEGORY FOR SECTION 311/312 REPORTING: HEALTH H-1 * IMMEDIATE (ACUTE) HEALTH HAZARD H-2 = DELAYED (CHRONIC) HEALTH HAZARD PHYSICAL P-3 * FIRE HAZARD P-4 * SlX>OEN RELEASE OF PRESSURE HAZARD P-5 = REACTIVE HAZARD 4 TOXIC CHEMICAL UNDER SECTION 313, CATEGORY AS REQUIRED UNOER SECTION 313 (40 CFR 372.42). *5 REPORTABLE QUANTITY OF HAZARDOUS SUBSTANCE UNDER CERCLA 1 SAL 000006527 C A043 SECTION II-C MO. ACUTE ORAL LD50 (g/fcg) PRODUCT MIC: CRITERION TRUCK* 444 CATALYST USDS NO. 6159-OG ACUTE TOXICITY DATA ACUTE DERMAL LD50 (g/kg) ACUTE IBNALATION LC30 (g/NS) p C-444 >5000 (RAT)* >1000 (RAT)* >748 (RAT 4 )* * BASED ON SIMILAR PROOUCT TESTING. SECTION III WHMIS INFORMATION ACCORDING 70 CRITERION'S UNDERSTANDING, THIS PRODUCT (C-444) IS CLASSIFIED UNDER THE CANADIAN WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM (VIHIS) AS: POISONOUS AND INFECTIOUS CLASS D DIVISION 2, SUBDIVISION 1. FOR SPENT CRITERION TRILOBE***444 CATALYST, THE WHM1S CLASSIFICATION IS: POISONOUS AND INFECTIOUS CLASS D DIVISION 2, SUBDIVISION 6. FLAMMABLE AND COMBUSTIBLE CLASS 8, DIVISION 6. SECTION IV HEALTH INFORMATION THE HEALTH EFFECTS NOTED BELOW ARE CONSISTENT WITH REQUIREMENTS UNDER THE OSHA HAZARD COMMICATICN STANDARD <29 CFR 1910.1200). ETC CONTACT PRODUCT KAY BE MILDLY IRRITATING TO THE EYES. SKIN CONTACT PRODUCT MAY BE MILDLY IRRITATING TO THE SKIN. INHALATION THIS PROOUCT MAY CAUSE IRRITATION TO THE NOSE, THROAT AMD RESPIRATORY TRACT. SENSITIZATION BASED ON COMPONENT 3 (COBALT OXIDE). KAY PROOUCt LUNG DAMAGE AWO/OR INGESTION GENERALLY CONSIDERED TO HAVE A LOU ORDER OF ACUTE ORAL TOXICITY. SIGNS AND SYMPTOMS IRRITATION AS NOTED ABOVE. LUNG DAMAGE KAY 8E EVIDENCED BY SHORTNESS OF BREATH, ESPECIALLY ON EXERTION, AND NAY BE ACCOMPANIED BY CHRONIC COUGH. LUNG SENSITIZATION (E.G. ALLERGY, ASTHMA) KAY BE EVIDENCED BY WHEEZING WITH SHORTNESS OF BREATH AND COUCH. AGGRAVATES MEDICAL CONDITIONS PREEXISTING EYE, SKIN AND RESPIRATORY DISORDERS KAY BE AGGRAVATED BY EXPOSURE TO THIS PROOUCT. IMPAIRED LUNG FUNCTION(S) FROM PREEXISTING DISORDERS KAY BE AGGRAVATED BY EXPOSURE TO THIS PROOUCT. PREEXISTING SKIN OR LUNG ALLERGIES KAY INCREASE THE CHANCE OF DEVELOPING INCREASED ALLERGY SYMPTOMS FROM EXPOSURE TO THIS PROOUCT. OTHER HEALTH EFFECTS NO REPORTS OF HEART TOXICITY HAVE BEEN ASSOCIATED WITH THIS PRODUCT, HOWEVER, COBALT IS KNOWN TO CAUSE HEART TOXICITY (MYOCARDIOPATHY), WHICH MAY BE EVIDENCED BY EDEMA (SWELLING OF THE FEET) AND SHORTNESS OF BREATH ON EXERTION OR WHEN LYING SUPINE (ON THE BACK, WITH FACE UPWARD). SECTION V OCCUPATIONAL EXPOSURE LIMITS QSKA ACSIK MO. TRANSITIONAL FINAL RUlf. TLV/TUA TLV/5TEL LIMIT/PEL LIMIT/TUA (S/KS) <ag/M3) (-3/K3) (9/K3) OTHER 1 AljOj 2 HoOj 3 CoO 15 5 15 5 0.1 10 5 10 5 O.OS 10 10 0.05 TOTAL DUST RESPIRABLE FRACTION INSOLUBLE COMPOUNDS, TOTAL DUST INSOLUBLE COMPOUNDS, RESPIRABLE FRACTION AS Co * COMPLIANCE WITH TRANSITIONAL LIMITS REQUIRED BY ADMINISTRATIVE OR ENGINEERING CONTROLS ONLY. UNTIL 12/31/92. ** COMPLIANCE WITH FINAL RULE LIMITS BY ANY COMBINATION OF ENGINEERING CONTROLS, WORK PRACTICES AND PERSONAL PROTECTIVE EQUIPMENT UNTIL 12/31/92. STARTING 1/1/93, THE FINAL RULE LIMITS MUST BE MET BY ADMINISTRATIVE OR ENGINEERING CONTROLS ONLY. 2 SAL 000006528 PRODUCT MAME: CXITEXICM TilLOBE* 444 CATALTff USDS BO. 6159-04 SECTION VI EMERGENCY AND FIRST AID PROCEDURES EYE CONTACT FLUSH EYES WITH PLENTY OF WATER FOR 15 MINUTES WHILE HOLDING EYELIDS OPEN. GET MEDICAL ATTENTION. SUM CONTACT REMOVE CONTAMINATED CLOTHING/SKOES ANO WIPE EXCESS FROM SKIN. SOAP AND WATER. IF IRRITATION OCCURS, GET MEDICAL ATTENTION. FLUSH SKIN WITH WATER. FOLLOW BT WASHING WITH DO NOT REUSE CLOTHING UNTIL CLEANED. INHALATION REMOVE VICTIM TO FRESH AIR ANO PROVIDE OXYGEN IF BREATHING IS DIFFICULT. GET MEDICAL ATTENTION. INGESTION DO NOT INDUCE VOMITING. DO NOT GIVE LI0U1DS IF VICTIM IS UNCONSCIOUS OR VERY DROWSY. OTHERWISE, GIVE LARGE QUANTITY OF WATER. IF V0M1TTIMG OCCURS, REPEAT LI0U1D ADMINISTRATION. GET MEDICAL ATTENTION 1MEDIATELY. SECTION VII SUPPLEMENTAL HEALTH INFORMATION IN ONE LIFETIME INHALATION STUDY, COBALT-EXPOSED HAMSTERS DEVELOPED PNEUMOCONIOSIS; ADDITIONALLY, THERE WERE NO INCREASES IN TUMORS. STUDIES CONDUCTED ON GUINEA PIGS HAVE DETERMINED THAT SIMILAR CRITERION CATALYSTS TO C-444 ARE NOT SKIN SENSITIZERS. HOWEVER, SOME INDIVIDUALS MAY BE SUSCEPTIBLE TO COBALT SEWSJT12AT10N. SECTION VIII PHYSICAL DATA BOILING POINT: APPROX. 4000 (DEG F) SPECIFIC GRAVITY: NOT APPLICABLE (H20=1) MELTING POINT: APPROX. 37D0 (OEG F) SOLUBILITY: APPROX. 5X (IN WATER) EVAPORATION RATE (H'BUTYL ACETATE 1): NOT SIGNIFICANT APPEARANCE AND ODOR: BLUE, TRILOBE*-SHAPED EXTRUOATES. NO COOR. VAPOR PRESSURE: NOT SIGNIFICANT (MM HG) VAPOR DENSITY: NOT APPLICABLE (AIRS1) BULK DENSITY * 0.S2 G/CC SECTION IF FIRE AND EXPLOSION HAZARDS FLASH POINT METHOD: WILL NOT BURN. (SEE BELOW) FLAFMABLE LIMITS /X VOLLXC IN AIR LOWER: N/AP UPPER: N/AP EXTINGUISHING MEDIA AS PRODUCED, WILL NOT BURN. CHEMICAL OR C02. IF REDUCED (SPENT) CATALYST IS INVOLVED IN A FIRE, USE WATER FOG, FOAM, DRY SPECIAL FIRE FIGHTING PROCEDURES AND PRECAUTIONS WILL NOT BURN. WEAR FULL PROTECTIVE CLOTHING AND A NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS IF CATALYST IS 1H FIRE AREA. UNUSUAL FIRE AND EXPLOSION HAZARDS AS PRODUCED, THE CATALYST WILL NOT BURN. HOWEVER, IN USE, THE CATALYST IS REDUCED AND SULFIDED. THE REDUCED FORM, ESPECIALLY WHEN WARM, REACTS WITH OXYGEN ON CONTACT WITH AIR. EHOUGH HEAT CAN BE PROOUCED TO BURN COKE OR RESIDUAL ORGANIC MATERIAL LEFT ON THE CATALYST, ANO COULD IGNITE FLAMMABLE MIXTURES WHICH IT MAY CONTACT. TO PROTECT AGAINST THIS POSSIBILITY. SPENT CATALYST SHOULD BE OXIDIZED AND COOLED BEFORE REMOVING IT FROM THE REACTOR. OTHER MEASURES, SUCH AS COOLING AND BLANKETING WITH NITROGEN OR WATER WETTING THE CATALYST MAY ALSO BE USED TO RETARD OXIOATION. 3 SAL 000006529 0 43 SECTION X STABILITY: STABLE MOUCT NAME: CRITERION THICK* 444 CATALTST USDS MO. 6159-04 REACTIVITY HAZARDOUS POLYIdlZATlON: WILL NOT OCCUR SECTION XI EMPLOYEE PROTECTION RESPIRATORY PROTECTION USE A NIOSH-APPROVED RESPIRATOR TO PREVENT OVEREXPOSURE. IN ACCORD UITN 29 CFR 1910.134, USE EITHER AN ATMOSPHERE-SUPPLYING RESPIRATOR OR AN AIR-PURIFYING RESPIRATOR FOR PARTICULATES. PROTECTIVE CLOTHING AVOID PROLONGED OR REPEATED CONTACT WITH SKIN. WEAR GLOVES AND OTHER CLOTHING AS REQUIRED TO MINIMIZE CONTACT. ADDITIONAL PROTECTIVE MEASURES USE EXPLOSION-PROOF VENTILATION AS REQUIRED TO CONTROL PARTICULATE CONCENTRATIONS. SECTION XII ENVIRONMENTAL PROTECTION SPILL OR LEAK PROCEDURES WEAR NIOSH APPROVED RESPIRATOR WHEN DUST LEVELS EXCEED OCCUPATIONAL EXPOSURE LIMITS. WEAR GLOVES, GOGGLES AND PROTECTIVE CLOTHING TO CONTROL EXPOSURE TO BODY SURFACES. DO NOT DRY SWEEP OR USE HETHOOS WHICH INCREASE DUSTING. USE VACUUMING OR SWEEPING COMPOUND FOR CLEAN-UP. DO NOT WASH SPILLS INTO SEWERS OR OTHER PUBLIC WATER SYSTEMS. WASTE DISPOSAL UNDER EPA - RCRA (40 CFR 261.21), SPENT UNREGENERATED CATALTST IS A WASTE MATERIAL, IT COULD BE AN IGNITABLE HAZARDOUS WASTE, HAZARDOUS WASTE NUMBER DOOI. REFER TO LATEST EPA OR STATE REGULATIONS REGARDING PROPER DISPOSAL. ENVIRONMENTAL HAZARDS DO HOT WASH SPILLS INTO SEWERS OR OTHER PUBLIC WATER SYSTEMS. SECTION XIII SPECIAL PRECAUTIONS DO NOT EAT, DRINK OR SMOKE IN AREAS WHERE CATALYST IS PRESENT. WASH HANOS THOROUGHLY AFTER HANDLING. KEEP CONTAINERS CLOSED WHEN NOT IN USE. NOTIFY AUTHORITIES IF MATERIAL THREATENS TO ENTER OR ENTERS INTO SEWER OR PUBLIC WATER SYSTEM. ALL PRECAUTIONS GIVEN FOR FRESH CATALYST SHOULD BE OBSERVED FOR SPENT CATALYST ANO WASHINGS. ( SECTION XIV___________TRANSPORTATION REQUIREMENTS_________ DEPARTMENT OF TRANSPORTATION CLASSIFICATION: FRESH CATALTST NOT HAZARDOUS BY DOT REG* OTHER REQUIREMENTS: * SPENT CATALYST ONLY - FLAMMA8LE SOLIO N.O.S. UN1325. 4 SAL 000006530 CA043 PRODUCT NAME: CRITERION TtlLCK* 444 CATALYST USDS HO. 4159*04 SECTION XV OTHER REGULATORY CONTROLS THE COMPONENTS OF THIS PROOUCT ARE LISTED ON THE EPA/TSCA INVENTORY OF CHEMICAL SUBSTANCES. THE INFORMATION CONTAINED HEREIN IS BASED ON THE DATA AVAILABLE TO US AND IS BELIEVED TO BE CORRECT. HOWEVER, CRITERION MAKES NO WARRANTY, EXPRESSED OR IMPLIED, REGARDING THE ACCURACY OF THESE DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF. CRITERION ASSUMES NO RESPONSIBILITY FOR INJURY FROM THE USE OF THE PRODUCT DESCRIBED HEREIN. SECTION XVI SUMMARY OF REVISIONS MSDS NUMBER 6159-01 6159-02 6159-03 6159-04 DATE NATURE OF REVISIONS* DECEMBER 28, 1988 ORIGINAL ISSUE MAY 14, 1989 ADD NEW OSHA TRANSITIONAL AND FINAL RULE EXPOSURE LIMITS. ADD SECTION XVI SUMMARY OF REVISIONS. ADD REVIEW DATE TO TOP OF PAGE 1. CORRECT TYPO IN CAS NUMBER FOR COBALT OXIDE TO 1307-96-6. AUGUST 12, 1989 ADD PROOUCT CCOE NO. 93551-95 TO MSDS. Kovenber 14, 1989 ADD CERCLA INFORMATION TO SECTIONS IIB ANO XII WHERE APPROPRIATE. CHANGE PROOUCT CCOE NUMBERS (DROP 93'$ ANO $). REVIEW DATE: Noveffber 14, 1989 c^a_Q_c$- DONALD C. MCCULLOCH TECHNICAL DIRECTOR CRITERION CATALYST COMPANY L.P. SAL 000006531 CRITERION CATALYST COMPANY L.P. TWO GREENSPOINT PLAZA, SUITE 1000, 16825 NORTHCHASE OR., HOUSTON, TEXAS 77060 5 C AO 43 SAL 000006532 ees9ooooo ivs i novas mono 3oMVissns snoovnvH jo juiurvno 3isYi*od3a s* Ur m vjo o*> Etc no! id as vaonn Q3inc3a sv xyooaivo 'ci Nouoas naan tvougho oixoi * OMVZVH 3AIX3V38 S*d OSVZVH 3anSS3d JO 3SV313V H3000S Vd OVVZVH 3813 = -d TVOISXHd OSVZVH HX1V3H (OINOVHO) O3A\m0 = 2-H QVYZVH HX1V3H (3inOV) 3XYI03WHI * l-H H1TV3H 9NIldOd3ij 2l/U N01101S dOJ A8003iVD OfVZVH * Z0 NOI103S MONO 33NYXS8ftS SDOOVVZVH X13H3VXX3 JO JlXIXNYnO MUUmd GXWHS3HKX 2* 20 Noixoas vaarai BONvisaas snoaavzvH xiawaxxa jo uiixvno 3isvxaod3v u ............................................................ S3X0KX00J................................................................... -d `2-H 'l-H 6E-N XN3dS SONDOdHOO X1VS00 *S3A S3A sax Z-H 'l-H l*H l-H ooo Viv 2 l (s) <*U> N c**> l N0IX03S () S3IW93XV3 ZIE/UE cz*) (N) W1 SH3 a.) (sqj) (Ml SH3 no3om wv5____________ m ms___________m mshi vws *OM NOIXYKHOitfl YI0H3D CIOT III a'lJ.IX TOYS G-XI 1101X039 21 S8 001 XM33H3d 9-96-20EI S-Z2-EIEI V-8Z-**l aanixiH OOO - 301X0 X1V9O0 *00* - 301X0 HnNSOaxiOM Viv (VNimiv) 301x0 HnNiwnv XSX1VXV3 6-N NO1831ISO 2 k d JB8MTM SVD NDlXISOcKJO *0(1 XNaiaaraoKi/xoaaoTO ONISSaDOHd AH3NIJ3H y-ii Noixoas asn xonoovd EZ090ZO? 01SS9 mown 3113 Noiaaxm 3000 lOOOOad N0IH3XIV0 aaixo avxaw X1IMVJ 1V0IN3H3 ee-N 3WVN 1V3IH3H3 XSXIYXYO 6-K NOIYaXIHO XOOOOVd SHYK Al uojox J9J9J S5a X Noxxpas oiuojip pue jno joj ^ V3H3HXX3 Z-31W300M : MIXW 0SV7VB 0*1SV31 0 AXIA1X3V3V 0Z 3813 . HX1V3H 1 [ 0092;fl-LZ -NOllQim | ZWVUISSV SOSH 1VS3KX1 (VMM 9999-966-C19 :33ifWn (VSO 1> OO**TO-O0tf^UIGK3 tiva0T9> Z6C-C98-CT cvsn > 9Z.09-iiZ.-008 =noiif3ino 'r_ hdmyisissv xoNaoHanra kaoh *z 686T '*T qm9AON : axva MaiASH 0-S09 S TOSHON BOSH 133HS viva A133VS1VIU31VIAI t*00 SISATVIVO NOftIBlIdO O A 0 44 SECTION II-C HO* ACUTE ORAL LDSO (B/kg) PRODUCT MICS CtllBUfli CATALYST N9>S MO. 6075-88 ACUTE TOXICITY DATA ACUTE DERMAL LD50 (W/kf) ACUTE MRAUTIOK LC50 (B/K3) > N-39 2 MoO, 5 CoO NOT AVAIUBLE 125-180 (RAT) 1700 (RAT) Z090 (RAT) 287 (LC70, RAT -1 hr/30 day*) SECTION H H . ffHMIS INFORMATION ACCORDING TO CRITERION'S UNDERSTANDING, THIS PRODUCT (H-39) IS CUSSIf IED UNDER THE CANADIAN WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM <UMIS> AS: POISONOUS AW) INFECTIOUS CUSS D DIVISION 2, SUBDIVISION i. ton SPENT CRITERION N-39 CATALYST, THE UNMIS CLASSIFICATION IS: POISONOUS AM) INFECTIOUS CUSS D DIVISION 2, SUBDIVISION B. FLAFKABLE AND COMBUSTIBLE CUSS S, DIVISION 6. SECT ION IV ; HEALTH INFORMATION THE HEALTH EFFECTS NOTED BELOU ARE CONSISTENT WITH REQUIREMENTS UNDER THE OSNA HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200). ETE CONTACT PRCOUCT MAT BE MILDLY IRRITATING TO THE EYES. SKIN CONTACT PROOUCT MAY BE MILDLY IRRITATING TO THE SKIN. INHALATION THIS PRODUCT MAY CAUSE IRRITATION TO THE NOSE, THROAT AND RESPIRATORY TRACT. SENSITIZATION BASED ON COMPONENT 3 (COBALT OXIDE). NAY PRODUCE LUNG DAMAGE AND/OR INGESTION GENERALLY CONSIDERED TO HAVE A LOU ORDER OF ACUTE ORAL TOXICITY. SIGNS AW) SYMPTOMS IRRITATION AS NOTED ABOVE. LUNG DAMAGE KAY BE EVIDENCED BY SHORTNESS OF 8REATN, ESPECIALLY ON EXERTION, AND KAY BE ACCOMPANIED BY CHRONIC COUGH. LUNG SENSITIZATION (E.G. ALLERGY, ASTHMA) MAY BE EVIDENCED BY WHEEZING WITH SHORTNESS OF 8REATH AND COUGH. AGGRAVATED MEDICAL CONDITIONS PREEXISTING EYE, SKIN AND RESPIRATORY DISORDERS KAY BE AGGRAVATED BY EXPOSURE TO THIS PRCOUCT. IMPAIRED LUNG FUNCTION(S) FROM PREEXISTING DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS PRODUCT. PREEXISTING SKIN OR LUNG ALLERGIES MAY INCREASE THE CHANCE OF DEVELOPING INCREASED ALLERGY SYMPTOMS FROM EXPOSURE TO THIS PROOUCT. OTHER HEALTH EFFECTS NO REPORTS OF HEART TOXICITY HAVE BEEN ASSOCIATED WITH THIS PROOUCT, HOWEVER, COBALT IS KNOWN TO CAUSE HEART TOXICITY (MYOCARDIOPATHY), WHICH MAY BE EVIDENCED BY EDEMA (5VELLING OF THE FEET) AND SHORTNESS OF BREATH ON EXERTION OR WHEN LYING SUPINE (ON THE SACK, WITH FACE UPWARD). SECTION V OCCUPATIONAL EXPOSURE LIMITS OSHA ACGIH NO. TRANSITIONAL FINAL RUL| TLV/TUA TLV/STEL LIMIT/PEL LIMIT/TWA (Q/KS) (S/K5) (aa/M3) (*g/K3) OTHER 1 *l23 2 MoOj 3 CoO 15 5 15 5 0.1 10 5 10 5 0.05 10 10 0.05 TOTAL DUST RESPIRABLE FRACTION INSOLUBLE COMPOUNDS, TOTAL DUST INSOLUBLE COMPOUNDS, RESPIRABLE FRACTION AS Co ,, COMPLIANCE WITH TRANSITIONAL LIMITS REQUIRED BY ADMINISTRATIVE OR ENGINNER1NG CONTROLS ONLY, UNTIL 12/31/92. COMPLIANCE WITH FINAL RULE LIMITS BY ANY COMBINATION OF ENGINEERING CONTROLS, WORK PRACTICES AND PERSONAL PROTECTIVE EQUIPMENT UNTIL 12/31/92. STARTING 1/1/93, THE FINAL RULE LIMITS MUST BE MET 8Y ADMINISTRATIVE OR ENGINEERING CONTROLS ONLY. 2 000006534- SAL n C A 0 44 PRODUCT MIC: CXITESIOH 1-99 CATALYST M5DS WO. <075-05 SECTION VI EMERGENCY AMP FIRST AID PROCEDURES_________ j\ EYE CONTACT FLUSH EYES WITH PLENTY OF WATER FOR 15 MINUTES WHILE HOLDING EYELIDS OPEN. GET MEDICAL ATTENTION. SKIN CONTACT REMOVE CONTAMINATED CLOTHING/SHOES AND WIPE EXCESS FROM SKIN. SOAP AND WATER. IF IRRITATION OCCURS, GET MEDICAL ATTENTION. FLUSH SKIN WITH WATER. FOLLOW BY WASHING WITH DO NOT REUSE CLOTHING UNTIL CLEANED. INHALATION REMOVE VICTIM TO FRESH AIR ANO PROVIDE OXYGEN IF BREATHING IS DIFFICULT. GET MEDICAL ATTENTION. INGESTION DO NOT INDUCE VOMITING. DO NOT GIVE LIQUIDS IF VICTIM IS UNCONSCIOUS OR VERY DROWSY. OTHERWISE, GIVE LARGE QUANTITY OF WATER. IF VQMITTING OCCURS, REPEAT LIQUID ADMINISTRATION. GET MEDICAL ATTENTION IMMEDIATELY. SECTION VII i SUPPLEMENTAL HEALTH INFORMATION IN ONE LIFETIME INHALATION STUDY, COBALT-EXPOSED HAMSTERS DEVELOPED PNEUMOCONIOSIS; ADDITIONALLY, THERE WERE HO INCREASES IN TUMORS. STUDIES CONDUCTED ON GUINEA PIGS HAVE DETERMINED THAT SIMILAR CRITERION CATALYSTS TO N-39 ARE NOT SKIN SENSITIZERS. HOWEVER, SCHE INDIVIDUALS KAY BE SUSCEPTIBLE TO COBALT SENSITIZATION. SECTION VIII PHYSICAL DATA BOILING POINT: APPROX. 4000 (DEG F) SPECIFIC GRAVITY: NOT APPLICABLE (H2G=1} MELTING POINT: APPROX. 3700 (DEG F) SOLUBILITY: APPROX. 5X (IN WATER) EVAPORATION RATE (N-BUTYL ACETATE = 1): NOT SIGNIFICANT APPEARANCE ANO OOOR: BLUE, CYLINDER-SHAPED EXTRICATES. NO OOOR. VAPOR PRESSURE: NOT SIGNIFICANT (HH HG) VAPOR DENSITY: NOT APPLICABLE (AIR1> BULK DENSITY = -0.55 G/CC SECTION IX FIRE AND EXPLOSION HAZARDS FLASH POINT METHOD: WILL NOT 8URN. (SEE BELOW) FLAWABLE LIMITS f% VOUiC III AIR LOWER: N/AP UPPER: N/AP EXTINGUISHING MEDIA AS PRODUCED, WILL NOT 8URH. CHEMICAL OR COg. IF REDUCED (SPENT) CATALYST IS INVOLVED IN A FIRE, USE WATER FOG, FOAM, DRY SPECIAL FIRE FIGHTING PROCEDURES AND PRECAUTIONS WILL NOT BURN. WEAR FULL PROTECTIVE CLOTHING ANO A NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS IF CATALYST IS IN FIRE AREA. UNUSUAL FIRE ANO EXPLOSION HAZARDS AS PROOUCED, THE CATALYST WILL NOT BURN. HOWEVER, IN USE, THE CATALYST IS REDUCED AND SULFIDED. THE REDUCED FORM, ESPECIALLY WHEN WARM, REACTS WITH OXYGEN ON CONTACT WITH AIR. ENOUGH HEAT CAN BE PROOUCED TO BURN COKE OR RESIDUAL ORGANIC MATERIAL LEFT ON THE CATALYST, ANO COULD IGNITE FLAMMABLE MIXTURES WHICH IT MAY CONTACT. TO PROTECT AGAINST THIS POSSIBILITY, SPENT CATALYST SHOULD BE OXIDIZED AND COOLED BEFORE REMOVING IT FROM THE REACTOR. OTHER MEASURES, SUCH AS COOLING AND BLANKETING WITH NITROGEN OR WATER WETTING THE CATALYST KAY ALSO BE USED TO RETARD OXIDATION. 3 SAL OOOOO6535 c A 0 44 SECTION X STABILITY: STABLE REACTiyitY PtCDUCT HW: CRITERION *-39 CATALYST MSDS MO. 6075-BS HAZARDOUS P0LYIERIZAT10N: WILL MOT OCCUR SECTION XI EMPLOYEE PROTECTION RESPIRATORY PROTECTION USE A NiOSK- APPROVED RESPIRATOR TO PREVENT OVEREXPOSURE. IN ACCORD WITH 29 CFR 1910.134, USE EITHER AN ATMOSPHERE-SUPPLYINC RESPIRATOR OR AN AIR-PURIFYING RESPIRATOR FOR PARTICULATES. PROTECTIVE CLOTHING AVOID PROLONGED CR REPEATEO CONTACT WITH SICIH. WEAR GLOVES AND OTitER CLOTHING AS REQUIRED TO MINIMIZE CONTACT. ADDITIONAL PROTECTIVE MEASURES USE EXPLOSION-PROOF VENTILATION AS REQUIRED TO CONTROL PARTICULATE CONCENTRATIONS. 8ECTION XII ENVIRONMENTAL PROTECTION SPILL OR LEAN PROCEDURES WEAR NIOSH APPROVED RESPIRATOR WHEN DUST LEVELS EXCEED OCCUPATIONAL EXPOSURE LIMITS. WEAR GLOVES, GOGGLES AND PROTECTIVE CLOTHING TO CONTROL EXPOSURE TO BOOT SURFACES. DO NOT DRY SWEEP OR USE METHOOS WHICH INCREASE DUSTING. USE VACUUMING OR SWEEPING COMPOUND FOR CLEAN-UP. DO NOT WASH SPILLS INTO SEWERS OR OTHER PUBLIC WATER SYSTEMS. WASTE DISPOSAL UNDER EPA - RCRA (40 CFR 261.21), HAZARDOUS WASTE, HAZAROOUS WASTE DISPOSAL. SPENT UNREGENERATED CATALYST IS A WASTE MATERIAL, IT CCULD BE AN IGNITABLE NUMBER D001. REFER TO LATEST EPA OR STATE REGULATIONS REGARDING PROPER ENVIRONMENTAL HAZARDS DO NOT WASH SPILLS INTO SEWERS OR OTHER PUBLIC WATER SYSTEMS. SECTION XIII SPECIAL PRECAUTIONS DO NOT EAT, DRINK OR SMOKE IN AREAS WHERE CATALYST IS PRESENT. WASH HANDS THOROUGHLY AFTER HANDLING. KEEP CONTAINERS CLOSED WHEN NOT IN USE. NOTIFY AUTHORITIES IF MATERIAL THREATENS TO ENTER OR ENTERS INTO SEWER OR PUBLIC WATER SYSTEM. ALL PRECAUTIONS GIVEN FOR FRESH CATALYST SHOULD BE OBSERVED FOR SPENT CATALYST AND WASHINGS. SECTION XIV TRANSPORTATION REQUIREMENTS DEPARTMENT OF TRANSPORTATION CLASSIFICATION: FRESH CATALYST NOT HAZARDOUS 8Y DOT REG** OTHER REQUIREMENTS: * SPENT CATALYST ONLY - FLAMMABLE SOLID N.O.S. UN1325. c 4 SAL 000006536 C AO 44 PRODUCT MIEs CRITERION 1-39 CATALYST USDS NO. 6075-03 SECTION XV______________ OTHER REQUIATORY CONTROLS_______________ THE COMPONENTS OF THIS PROOUCT ARE LISTED ON THE EPA/TSCA INVENTORY OF CHEMICAL SUBSTANCES. THE INFORMATION CONTAINED HEREIN IS BASED ON THE OATA AVAILABLE TO US AND IS BELIEVED TO BE CORRECT. HOWEVER, CRITERION HAKES NO WARRANTY, EXPRESSED OR IMPLIED, REGARDING THE ACCURACY OF THESE DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF. CRITERION ASSUMES NO RESPONSIBILITY FOR INJURY FROM THE USE OF THE PROOUCT DESCRIBED HEREIN. SECTION XVI SUMMARY OF REVISIONS MSDS NLMBER 6075-01 6075-02 DATE NATURE OF REVISIONS DECEMBER 28, 1988 ORIGINAL ISSUE HAT 14, 1989 ADO NEW OSHA TRANSITIONAL AND FINAL RULE EXPOSURE LIMITS. ADD SECTION XVI SUMMARY OF REVISIONS. ADO REVIEW DATE TO TOP OF PAGE 1. CORRECT TYPO IN CAS NUMBER FOR COBALT OXIDE TO 1307-96-6. 6075-03 N overt* r 1989 ADO CERCLA INFORMATION TO SECTIONS 118 ANO XII WHERE APPROPRIATE. CHANGE PROOUCT COOE NUMBERS <DROP 93'fi AND -'s>. REVIEW DATE: November 14, 1989 OvvoJlcS. C * M DONALD C. MCCULLOCH TECHNICAL DIRECTOR CRITERION CATALYST COMPANY L.P. CRITERION CATALYST COMPANY L.P. TWO GREENSPOINT PLAZA, SUITE 1000, 16825 MORTHCKASE DR., HOUSTON, TEXAS 77060 5 SAL 000006537 C A044 SAL 000006533 Refining, North America Conoco Inc. P O. Box 37 Westlake. LA 70669 (318)491-5211 March 31, 1990 Louisiana Emergency Response Commission Office Of State Police Hazardous Substance Control Section Right-To-Know Unit P. 0. Box 66614 Baton Rouge, LA 70896 SUBMITTAL OF MSDS UPDATES - FIRST QUARTER 1990 Dear Sir: Enclosed you will find Material Safety Data Sheet Updates for the first quarter of 1990, for the Conoco Refinery, Westlake, Louisiana. This information is being provided to you in accordance with the update requirements of Section 311 of Community Right-To-Know Act. If you have any questions concerning this submittal, please contact Dave Tinker at 318-491-5543. Lake Charles Refinery am att cc w/o att: W. 0. Lukens (Conoco) P. B. Butler (Conoco) D. L. Tinker (Conoco) DLT: MSDS.DOC SAL U00006539 Ftofining. North America Conoco Inc. P.0. Bok 37 Westlake. LA 70669 (318)491-6211 March 31, 1990 Mr. Samuel H. Russell Calcasieu Parish Local Emergency Planning Committee P. 0. Box 1391 Lake Charles, LA 70602-1391 SUBMITTAL OF MSDS UPDATES - FIRST QUARTER 1990 Dear Sir: Enclosed you will find Material Safety Data Sheet Updates for the first quarter of 1990, for the Conoco Refinery, Westlake, Louisiana. This information is being provided to you in accordance with the update requirements of Section 311 of Community Right-To-Know Act. If you have any questions concerning this submittal, please contact Dave Tinker at 318-491-5543. Plant Manager Lake Charles Refinery am att cc w/o att: W. 0. Lukens (Conoco) P. B. Butler (Conoco) D. L. Tinker (Conoco) DLT: MSDS.DOC SAt- 000006540 Refining, North America Conoco Inc. P.0 Box 37 Westlake. LA 70669 (318)491-5211 March 31, 1990 Fire Chief Westlake Fire Department 2401 Guillory Street Westlake, LA 70669 SUBMITTAL OF MSDS UPDATES - FIRST QUARTER 1990 Dear Sir: Enclosed you will find Material Safety Data Sheet Updates for the first quarter of 1990, for the Conoco Refinery, Westlake, Louisiana. This information is being provided to you in accordance with the update requirements of Section 311 of Community Right-To-Know Act. If you have any questions concerning this submittal, please contact Dave Tinker at 318-491-5543. Sincerely, Lake Charles Refinery am att cc w/o att: W. 0. Lukens (Conoco) P. B. Butler (Conoco) D. L. Tinker (Conoco) DLT: MSDS.DOC SAL 000006541 CHESTERTON MATERIAL SAFETY DATA SHEET 6 S4 9 3 AW. CHESTERTON COMPANY 22S Fallon Road, Mlddloaox Industrial Park Stonaham, MA 02180-3999 U.SJL Emergency Telephone Nos. 617-436-7000 (Day) 617-436-7013 (Night) Section i Data of Prop. October IS, 1989 HAZARDOUS MATERIALS IDENTIFICATION SYSTEM (HMIS) MSDSNo. 192A-4 4 Savers Hazard 3 > Serious Hazard 2 Moderate Hazard HEALTH FLAMMABILITY 1 1 1 - Slight Hazard REACTIVITY 1 Product Name: 655 Abrasion Control Liquid Part A Black, Grey 0 - Minimal Hazard Personal Protection * See Section VIH - Special Protection Information Genera/ Use end Precautionary information CheslertonO Maul Repair System: Repair damage caused by impact, abrasion, erosion or corrosion; rebuild worn areas; fW holes and cracks: provide abrasion resistant surfaces. The safely and health hazards are detailed for Part A and Part 8; separately The final cured product is considered nonhazardous. Upon machining, it can only be categorized as a nuisance dust Section li HAZARDOUS INGREDIENTS fngredlenlafSynonyma CAS No. % Wt. BtspherxH A Diglycidyl Ether Resin 25068-38-6 5-15 OSMA-.fl . acoet-ny . ppm mp/mj ppm mp/mt Vapor Pressure None Initial Bolling Point Section MA - OTHER INGREDIENTS on the EPA UST OF T OXIC CHEMICALS x Material /narked contains or is e loitc chemicel(t). Subject to the reports requements of section 313 of Tide 111 of me Superfund Amendments and Reauthon2iton Act of 1966 and 40 CFR Pan 372 Section III - PHYSICAL DATA N/A Percent Volatile (by volume) < 1 Vapor Density >1 (Air. 1) nosh Point 249*C (480sF) Closed Cup Evaporation Rote <1 (Ether . 1) Weight Per Gallon 16 lbs (1.9 kg/1) Section IV - FIRE AND EXPLOSION DATA LEL Not Determined DOT Shipping Nome Nonhazardous DOT Hazard Class Not Restricted DOT UN/NA 9 N/A Extinguishing Madia Carbon Dioxide, dry chemical, foam or water fog. Unusuaf Ftra and Explosion Hazards Thermal decomposition can form aldehydes, acids or other toxic fumes Special Hra Fighting Procedures Cool exposed containers with water. Recommend Firefighters wear selt-conuined breathing apparatus AW CHESTERTON CO. lM AIR^u PatermO A9 U S Pst atO TJA OB. SAL 000006542 SHEA OlHTlU fa S4 9 8 Product Name: 855 Abrasion Control Liquid Part A Black, Grey Data: October 15. 1989 Section V -- REACTIVITY DATA Stability Stable Hazardous Decomposition Products Carbon Monoxide, aldehydes, acids and other toxic fumes. Conditions to Avoid Heat abovs 300*F (149*C) Hazardous Polymerization Materials to Avoid Stong mineral acids and bases, strong organic bases and strong oxidizers like Squid Chlorine and concentrated Oxygen. May Occur (S Will Not Occur Section VI -- HEALTH HAZARD DATA Primary Route of Exposura Under Normal Usa Skin and eye contact Personnel with preexisting skin or lung aBergios may be aggravated bp exposure. 4cur Enacts Moderate eye and skin irritant May cause skin sensitization as evidenced by rashes or hives. Chronic Effects Although the significance is unknown. Bphenol A Digtycidyl Ether Resin has been shown to be mutagenic in some nvcrobiai tests but has failed to show mutagenicity in others Chromosomal aberrations were observed in cultured rat liver eetls. Based on recent 2-year mice skin painting studies and oher available information, the International Agency <or Research on Cancer (IARC) concluded that they did not have enough information to classify Bisphenoi A Diglycidyl Ether Resin. Emergency and First Aid Procedures Inhalation N/A Eye/Skfn Contact Remove contaminated clothing. Wash skin with soap and water. Flush eyes ter at least 15 minutes with large quantities ol water. Consult physician if irritation develops. Ingestion Do not induce vomiting. Contact physician immediately. Section VII -- SPILL OR RELEASE PROCEDURES Steps to be Taken In Casa Malarial la SpiUad or Released Avoid skin contact Contain spiK to a small area. Pick up with absorbent material (eg., sand, sawdust, day. etc.) and transfer to a suitable container lor disposal. Keep out of sewers, streams and waterways. Weale Disposal Method Landfill sealed containers in an approved area Check local, state and federal regulations Section VIII -- SPECIAL PROTECTION INFORMATION Respiratory Protection Not needed. Protective Gloves Chemical resstant gloves (e g.. Neoprene). Ventilation No special requirements. Eye Protection Safety goggles. Other Impervious doming as necessary to prevent skin cont^x. Precautions In Hsndllng snd Storing Section IX -- SPECIAL PRECAUTIONS Store in cod, dry area. Other Precautions Remove contaminated clothing immediately. Wash clothing before reuse. Contaminated leather including shoes cannot be decontaminated so they should be discarded Th* tnlotmtiOT eootamad Saraln I* baaad on data provided hem auppdari U dta maiariab vnd and not on the mature lux. and m bala'ied to be eorracL hfcn**e. no warranty la aipraaaad or rrpled repardmg the accuracy ol tha data. Sine* Via WormMion eomhad herein may be appied under condkene beyond Our control, tha pwaona noMng * ahl make that own detarmrvaibn 01 Via auiabUy 0* tha produd lor Shafr parSortw pinpnaae 7SS4S 192A-* SAL 000006543 0*<A a cm Parti If Id 12M. ins I 1f17ZS. IflSfO. ISMS* and t*2f UA 441 CUR 21 M CHESTERTON MATERIAL SAFETY DATA SHEET S4 94 AW. CHESTERTON COMPANY 225 Fallon Road, Mkfdlasax Industrial Park S'onoham. MA 02180-2999 U.S.A Section I Emorooncy Telephone Nos. 617-438-7000 (Day) 617-428-7013 (Night) Data ol Prop. October IS. 1989 MSOSNo. 1926-4 Product Nama: 855 Abrasion Control Liquid Part B HAZARDOUS MATERIALS IDENTIFICATION SYSTEM (HMIS) 4 Sever Hazard 3 - Serious Hazard 2 - Moderate Hazard 1 - Slight Hazard 0 - Minimal Hazard HEALTH FLAMMABILITY REACTIVITY Personal Protection 3 1 1 6 > See Secton VIII Specie/ Protsction Inform*ton Ganarai Usa and Precautionary Information Chesterton* Melal Repair System: Repair damage caused by impact, abrasion, erosion or corrosion; rebuild worn areas; fill holes and cracks; provide abrasion resistant surfaces. The safety and health hazards are detailed for Pari A and Part B; separately. The final cured product is considered unhazardous Upon machining, it can only be categorized as a nuisance dusL Benzyl Alcohol Section It - HAZARDOUS INGREDIENTS Ingradlsnts/Synonyma CAS No. % Wl. 100-51-6 40-50 OSHAStL, . ppm mpfmt ACOH-Tiy . ppm mp/mt Vapor Pressure Gisphenol A Initial Boiling Point Section IIA - OTHER INGREDIENTS on the EPA UST OF TOXIC CHEMICALS 60-05-7 1-5 x Material marked contain* or is a toxic chemlceK*). subject to toe reporting require ment* ot section $13 ot Title lit of toe Superfund Amendment* and Reeuthonzation Act of 1986 and 40 CFR Part 372. Section III - PHYSICAL DATA Not Determined Parcsnt Vdatiis (by volume) Negligible Vapor Danslty >1 (Air. 1) Flash Point >93aC t200F} Closed Cup Evaporation Pats <1 (Ethar 1) Wslght Par Gallon 8.3 lbs. (1,0 kgi) Section IV - FIRE ANO EXPLOSION DATA LEL Not Determined DOT Shipping Nama Nunhazardous DOT Hazard Claaa Not Restricted ' DOT UN/NA a N/A Extinguishing Madia Carbon Dioxide, dry chemical or loam. Unusual Fir* and Explosion Hazards Thermal decomposition can lorm Carbon Monoxide, Nitrogen Oxides and other toxic fumes. Special Firs Fighting Procedure* Cool exposed containers with water. Recommend Firefighters wear sell-contained breathing apparatus. CA.W CHCBTtSTON CO, 1MI A* R<yu ng us Pei andT M. oa. d S4t- 000006 544 Stt6A OMtcOR Product Nam*: 855 Abrasion Control Liquid Part 8 S 4 94 Data: October 15, 1999 Stability Stable Hazardous Decomposition Products Hazardous Polymerization Section V -- REACTIVITY DATA Conditions to Avoid Open flames and red hoi surfaces. Carbon Monoxide. Carbon Ok?xide. NOx, aldehydes and other toxic fumes. Materials to Avoid Strong acids, strorg oxidizers like liquid CNorirw and concentrated Oxygen May Occur 9 Will Not Occur Section VI -- HEALTH HAZARD DATA Primary Rouia of Exposure Under Normal Use Inhalation, skin and eye contact Personnel with pre-existing allergies, eczema or stun conditions may be aggravated by exposure. Acute Effects Direct contact will cause severe irritation to skin. eyes, and mucous membranes. High vapor concentrations can cause severe eye and respiratory tract irritation, headache, dizziness, nausea and possibly shortness of breath. Chronic Effects Prolonged or repeated contact may cause asthma, skin sensitization and other allergic reactions As per 29 CFR 1910 1200 (Hazard Communicator!), (here are NO carcinogens in this product as listed in the National Toxicology Program (NTP), the International Agency for Research on Cancer (IARC) or the Occupational Health and Safety Administration (OSHA) Emergency and First Aid Procedures Inhalation Remove to Iresh air If not breathing, administer artificial respiration. Contact physician. Eye'Skin Contact Rood area with water while removing contaminated clothing Wash clothing before reuse. Rush eyes lor at least IS minutes with large amounts of water. Consult physician. ingestion if conscious, do not induce vomiting, dnnk milk, water or vinegar. Contact physician immediately Section VII -- SPILL OR RELEASE PROCEDURES Steps to be Taken In Case Material Is Spilled or Released Evacuate area Provide adequate venblalion Avoid skin contact. Contain spill to a small area. Pick up with absorbent matenal (e g , sand, sawdust, clay, etc.) and iransler to a suitable container lor disposal- Flush final traces ol spil with water Waste Disposal Method Landfill sealed containers m an approved area. Check local, state and federal regulations Section VIII -- SPECIAL PROTECTION INFORMATION Respiratory Protection Not normally needed II necessary, utilize an approved organic vapor respirator. Protective Gloves Chemical resistant gloves (e g , natural rubber or PVC). Ventilation No special requirements. II necessary, provide adequate ventilation Eye Protection Safety goggles. Other Impervious clothing as necessary to prevent sxin contact Precautions in Handling and Storing Section IX -- SPECIAL PRECAUTIONS Store in cool, dry area Avoid breathing rmsi Other Precautions Remove contaminated clothing immediately. Wash clothing before reuse. Contaminated leather including shoes cannot be decontaminated so they should be discarded. Th* inlormaion corduriao nararn * basao on daia (xonOM Irom supptws ol iha malar*s used and not on in* manure asofl. and m bolevoa 10 M cor/eci. Hoar*vr. no ananiy ft aip'oeMd or impfiad lejt'Orq tfa accuracy at ma daia. $mca tha in(ormation conutnod horaUi may t* app<ed under eondnona beyond our control, lha poisons lacarvnj shal rruka thau omn oatarmaxaion & ir tuabli!y d lha produa for thair particular puipoaas. 7SSXS 1926 4 SAL 000006545 03HA 29 Of ft Pans 1910 1300. 1915 99 1917M. 1919 90. 1(99 59 and 193 MA 441 CAM 31 09 CHESTERTON* MATERIAL SAFETY DATA SHEET AW. CHESTERTON COMPANY 225 Fallon Road, Middlesex Industrial Park Stooeham, MA 02160-2090 U.S.A Section Emergency Telephone Nos. 617-436-7000 (Day) 617-436-7013 (Night) Data ol Prep. June i, 1989 HAZARDOUS MATERIALS IDENTIFICATION SYSTEM (HMIS) MSDSNo. 144A-3 4 Saver# Hazard 3 Serious Hazard 2 - Moderate Hazard HEALTH FLAMMABILITY 1 1 1 - Slight Hazard REACTIVITY 1 Product Name: 818 Rapid Cura Steel Putty Plus Part A 0 Minimal Hazard Personal Protection 5m Section VUt - Special Protection Information Genera/ Uoa and Precautionary Information Chesterton* Metal Repair System: Repair damage caused by impact, abrasion, erosion or corrosion; rebufld worn areas; fiR holes and cracks: provide abrasion resistant surfaces. Tbs safety and health hazards are detailed lor Part A and Part B; separately. The final cured product is considered nonhazardous. Upon machining, it can only be categorized as a nuisance dust Section II - HAZARDOUS INGREDIENTS Ingrsdlants/Synonyms CAS Ho. % Wt Bisphenol A Oiglycidyt Ether Resin 25066-36-6 25-35 OSHA+tL . ppm mfimti acoe+ny . ppm mi/ml Vapor Pressure Nons Will Boding Point Section HA OTHER INGREDIENTS on the EPA UST OF TOXIC CHEMICALS X Materid merited contains or is a toxic chemical(s). subject to toe reporting require ments o1 section 319 ol Title IN of toe Supertund Amendments and Reautoorizaton Act of 1666 and 40 CFR Part 372. Section III - PHYSICAL DATA N/A Psresnt VoMils (by volumt) < 1 VsporDsntlty >1 (Air. 1) Evaporation Rsts <i (Ether m if Wight Par Gallon 17 bs. (2,06 Iqyi) Section IV - FIRE AND EXPLOSION DATA Hash Point 249C (460F) Closed Cup LEL Not Determined OOTShipping Namo Nonhazardous DOT Haiord Class Not Restricted DOTUWNAg NM Extinguishing Media Carbon Dioxide, dry chemical, loam or water log. Unusual Firo and Explosion Hazards Thermal decomposition can form aldehydes, acids or her toxic himes. Special Firm Fighting Proctdurss Cool exposed containers with water. Recommend Firefighters wear self-contained breathing apparatus. ) M.W CHESTERTON CO . IMS Al ft^u IWterteo OR U S Par >W T U OS SH/f /</// sal 00006^6 Product Name: 818 Rapid Cure Steel Putty Plus Part A 6 S4 9K Dale: June t. 1989 | i Slability Stable Hazardous Decomposition Products Hazardous Polymerization Section V -- REACTIVITY DATA Conditions to Avoid Non# Carbon Monoxide, aldehydes, acids and other toxic fumes. Materials to Avoid Strong mineral aetds. strong oxidizers like liquid Chlorine and concentrated Oxygen May Occur E Will Not Occur Section VI -- HEALTH HAZARD DATA Primary Rout* ot Exposure Under Normal Us* Skin and eye contact Personnel with pre-existing allergies may be aggravated by exposure Acuta Ellada Moderate eye and skin irntant. May cause skin sensitization as evidenced by rashes or hives. Chronic E/facta Although the significance is unknown. Bisphenol A Diglycidyl Ether Resin has been shown to be mutagenic in some microbial tests but has failed to show mutagenicity in others. Chromosomal aberrations were observed tn cultured rat liver ceils Based on recent 2-year mice skin painting studies and other available information, the International Agency lor Research on Cancer (IARC) concluded that tey did not have enough information to classify Bisphenoi A Digtyddyt Ether Resin Emergency and First Aid Procedures Inhalation N/A Eye/Skin Contact Remove contaminated clothing Wash skin with soap and water. Flush eyes for at least 15 minutes with large quantities of water. Consult physician if irritation persists. Ingestion Do not induce vomiting Contact physician immediately. Section VII -- SPILL OR RELEASE PROCEDURES Steps to be Taken In Case Material Is Spilled or Released Avoid skin contact Scoop up and transfer to a suitable container for disposal ~~ ~ IVsste Disposal Method Landfill sealed containers in an approved area. Check focal, state and federal regulations Section VIII -- SPECIAL PROTECTION INFORMATION Raspiraiory Protection Not needed Profecl/ve Cloves Chemical resistant gloves (e g . Neoprene) ventilation No special requirements. Eye Protection Safety goggles Other impervious clothing as necessary to prevent skin contact Precautions in Handling and Storing Section IX -- SPECIAL PRECAUTIONS Store m cool, dry area. Other Precautions Remove contaminated clothing immediately. Wash dothing before reise. Contaminated leather including shoes cannot be decontaminated so they should be discarded. The intormeion contained herein based on cate fvcnOad hom *^pk*r* & the meter** used ana not on the mature uefl ana rt beteved 10 be cored However. ro wineniy it eipieued or rioted th* eoegreey of the due. Since the mtorrrviiion careened herein may be aopieo under eonotons beyond Out control in* persons receiving n that make the* orn determmaicn o< the tuteMity ef the product lot their penoiter purpoMe. 7?0Ai 144*3 OShA ft Cf Par's '*10 1?00. (BiS n 1*17 21 '*'1 *0. IBM S ino 1*2* CHESTERTON MATERIAL SAFETY DATA SHEET ^ S4 9 6 A.W. CHESTERTON COMPANY 225 Fallon Road, Middlesex Industrial Park Stoneham, MA 021*0-2999 U.S.A. Emergency Telephone Nos. 617-439*7000 (Oay) 617-438-7013 (Night) Section I Date of Prep. June 1.1969 MSDSNo. 1446-3 Product Name: 818 Rapid Cure Steel Putty Plus Part B HAZARDOUS MATERIALS IDENTIFICATION SYSTEM (HMIS) 4 Severe Hazard 3 Serious Hazard 2 - Moderate Hazard 1 - Slight Hazard 0 - Minimal Hazard HEALTH FLAMMABtUTY REACTIVITY Personal Protection 2 1 1 Sea Section VIII Special Protection Information Genera/ Usa and Precautionary information ChestertonS Metal Repair System: Repair damage caused by impact, abrasion, erosion or corrosion: rebuild worn areas: M holes and cracks; provide abrasion resistant surfaces. The safety end health hazards are detailed tor Part A and Part B; separately The final cured product is considered unhazardous. Upon machining, it can only be categorized as a nuisance dust Section It - HAZARDOUS INGREDIENTS Ingredlents/Synonyms CAS No. * Wl. 2,4.6-Tri {dimathylaminomethyl} Phenol 90-72-2 S-10 QSHA-TU. . ppm m 'ml ppm4Cd#ef-taj/yja Vapor Pressure None Initial Boiling Point Section IIA - OTHER INGREDIENTS on the EPA LIST OF TOXIC CHEMICALS X Material marked contain* or is a tonic chemical!*), subject lo the reporting require ments of section 313 of Title III of the Superfund Amendments and Raaulhonzaton Acl of 1986 and 40 CFR Pan 372. Section III - PHYSICAL DATA N/A Percent Volatile (by volume) < 1 Vapor Density >i (Mr* 1) Evaporation Rata <1 (Ether i) Wafght Par Gallon 8 7 lbs (1,04 kg/t) Flash Point 149C (300*F) Open Cup Section IV - FIRE AND EXPLOSION DATA LEL Not Determined DOT Shipping Name Nonhazardous DOT Hazard Class Not Restnctad DOTUN'NAt N/A Extinguishing Media Carbon Dioxide, dry chemical, foam or water log Unusual Fire and Explosion Ha2ards Thermal decomposition can form Hydrogen Sulfide and other toxic fumes Special Fire Fighting Procedures Cool exposed containers wilh water Recommend Firefighters wear self-contained breathing apparatus MW CKSTTRTON CO. IMS A RiqM* A*mm Aaq U S ew and T U O* StiEA OI</b/3 SAL 00000654a Product Name: 818 RftpM CurgltMi PirttyPlua Pert 8 *496 Data; Juna 1.1989 4 mtmitj' States Heserdoue Decomposition Products Hbaeadbuj Potymarlratfon sctJon v--menvrrv data Hydrogen Sulfide, Carton 'Monowde and ofter toxic fumes. Pmwvmm is to-Aroid Nona Materials toAvoid Strong ruriduers fee fiquid CNorine and concartoalad Oxygon. AtoyOcetr '(S' MMNefOccar Section VI -- HEALTH+IAZARD DATA Primary /tout* of Exposure Undo* Normal Uee inhalation, akin and aya contact Personnel with pro existing akin. may.be aggravated by exposure. and lung coniSiono Acute Effects Direct contact causes irritation to skin, eyes and mucousmembranes. Vapors irritation to eyes,. noon and tfvoat 2,4,6'Tri (dmethyteminomethyt) Phenoi may cauea akin sensitization es evidenced by rashaa or fives Chronic Effects Prolonged or repeated skin and eye contact with 2.4.6-Tri (dxnethytarranometfiyQ Phenol can cause buna. VapomAums ot 2,4,6-Tri (dimethylarninomathyt)Phenol can causedalayad tong damage and ehemicai pneumonia. As per 20 CFR 1010.1200 {Hazard Communication), there ere NO carcinogens in Ohs product aa fisted in the Nabonto Toxicology Program (NTF),Jhe International Agency tor Research on Cancer ((ARC) or the Occupational Safety and Health Administration (OSHA). Emergency and RrstAJd Procodurea MrisSon N/A Eye/SkJn Contact Hood area with water wtlie removing corUarNnated dothing. Wad) dothing before teuee. Wash elan with eoap and water. Rush eyes for at teast 30 minutes with large quantities ofwater. Consult physkawv Ingestion Do not induce writing. If conscious, dilute stomach contents with maker water. Contact physician immediately. Section`VII -- SPILL OR RELEASE PROCEDURES Stops to be Taken in Csss Material is 3pBtedor Released Evacuate area. Provide adequate-yentitetion. Spopp up and transfer to a suitable container for disposal. Keep out sewers, streams and waterways. Waste Disposal Method LendSB seated containers in an approved aree.vChsck focal, state and federal regulations. Section VUI -- SPECIAL PROTECTION INFORMATION Respiratory Protection Not normally needed. II necessary, tsa approved air suppted respirator. IVptoctfvs Okvoo Chemical resistant gloves (*9., Neoprene). Ventilation No special requirements. If necessary, provide adequate ventilation. Eye Protection Safety gog^es. Other impervious clothing as necessary to prevent skin contact Precautions in Handling and Storing Section IX--SPECIAL PRECAUTIONS Store in cool, dry area. Other Precautions Remove contaminated ctotNrqj immediately. Wash dothir^j -before reuse. Contaminated leather todudirg shoes cannot be decofSarransfed so-ibey shooed -be -dbpsrded. Tte Morrrwon (wint4 wianty ng'WMfl or p*iMAt ncWIng t that i 77081 14*6-3 to Uwa on eu.pmUM kom ooppiort et So mwWi w no rofMkig We jccwacy ol Wo Sms. Stnoo iho iitowiin eenuhod ewr mi eoiwwwuon.at Sm eteity ci * pmdua fortote pwOoter 0 mkluro IMS. end X hotel'ofl to b* oonoo. lleooiw. no My te ondor condBons teyend m MU, te OSHAtoCStten tstotaoo. tSISJS. ii7Ji, teireo. tsj av tta SAL 000006549 CHESTERTON MATERIAL SAFETY DATA SHEET 6 S4 9 7 A.W. CHESTERTON COMPANY 225 Fallon Road, Middlesex Industrial Park Stoneham, MA 02180-2959 U.S.A. Emergency Telephone Noe. 617-438-7000 (Day) 617-438-7013 (Night) Section 1 Data of Prap. Juno 1. 1989 MSDSNo. 143A-3 Product Name: 810 Steel Putty Plus Part A HAZARDOUS MATERIALS IDENTIFICATION SYSTEM (HMIS) 4 Sever* Hazard 3 Serious Hazard 2 - Moderate Hazard 1 Slight Hazard HEALTH FLAMMABILITY REACTIVITY 1 1 1 0 - Minimal Hazard Personal Protection > See Section VHt Special Protection Information General Use and Precautionary Information CheslartonS MeUt Repair System: Repair damage caused by impact, abrasion, erosion or corrosion: rebuild worn areas: HO holes and cracks; provide sbraskm resistant surfaces. The safety and health hazards are detailed for Part A and Part B. separately The final axed product is considered unhazardous Upon machining, it can only be categorized as a nuisance dust Section II - HAZARDOUS INGREDIENTS Ingredlen ta'Synonyms foir CAS No. % Wt. Bisphenol A D>g!ycidyl Ether Resin 2S068-38-6 35-45 BoOmSMAm+EoLtm}m ACOm^-oTtlfm_l Vapor Pressure None Moat Boiling Point Section HA - OTHER INGREDIENTS on the EPA LIST OF TOXIC CHEMICALS X Materiel medeed contain* or is e toxic chemicals), subject to the reporting require ment* of section 313 of Title tit ol the Superfunp Amendments end Reeuthorixelon Ad of 1966 end 40 CFR Pen 372. Section III - PHYSICAL DATA N/A Percent Volatile (by volume; < 1 Vapor Dan ally >i (Air m 1) Evaporation Rata <\ (Ether - 1) Weight Par Gallon 17 lbs. (2 06 kgl) Section IV - FIRE AND EXPLOSION DATA Flash Point 249eC (4dOeF) Closed Cup LEL Not Determined DOT Shipping Name Nonhazardous DOT Hazard Clasa Not Restricted DOTUN/NA 9 N/A Extinguishing Madia Carbon Dioxide, dry chemical, loam or water og. Unusual Fir* and Explosion Hazards Thermal decomposition can lorm aldehydes, acids or other toxic lumes. Spacial Fire Fighting Procedures Cool exposed containers with water. Recommend Firefighters wear sell-contained breathing apparatus. CAW CHESTERTON CO. i*S* Al Rchu IUwvm A*g u$ PM iitu OI OJV&/Y SAL 000006550 Product Nam*: 810 Steel Putty Plus Part A GS497 Date: June 1, 1989 SltbMJty Stable Hazardous Decomposition Product* Hazardous Patymartzation Sactfon V -- REACTIVITY DATA Condition* to Avoid None Carbon Monoxide, aldehydes. adds and other toxic fumes. Malarial* to Avoid Sfrong mineral adds, strong oxtdaera Eke liquid Chlorine and concentrated Oxygen. MayOcctr (B WW Not Occur Section VI -- HEALTH HAZARD DATA Primary Pouts of Expoaura Undar Normal U*a Skin and eye contact Personnel with pre-existing afiergies may be aggravated by exposure. Acuta El(sets Moderate eye and skin irritant May cause skin sensitization as evidenced by rashes or hives. Chronic Ellacta Although the significance is unknown, BisphenoJ A Dgtycdyl Ether Resin has been shown to be mutagenic in some micro bial tests but has failed to show mutagenicity in others. Chromosomal aberrations ware observed in cultured rat liver cels. Based on recent 2-year mice skin painting studies and other avalabie information, the International Agency for Reseweh on Cancer (LARC) concluded that tiey did not have enough information to classify Bisphenol A Diglyctdyf Ether Resin. Emergency and First Aid Procedures tthataOon N/A Eya/Skln Contact Remove contaminated clothing. Wash stun with soap and water. Flush eyes for at least IS minutes will large quantities of water. Consist physician if irritation persists Ingestion Do not induce vomiting. Contact physician immediately. Section VII -- SPILL OR RELEASE PROCEDURES Steps to be Takan In Cass Material Is SpiUad or Ratsaasd Avoid skin contact Scoop up and transfer to a suitable container lor cfisposal. Wasts Disposal Msthod Landfill sealed containers in an approved area. Check focal, slate and lederal regulations. Section VIII -- SPECIAL PROTECTION INFORMATION Respiratory Protsction Not needed. Protective Ctowi Chemical resistant gloves (e g.. Neoprene). Ventilation No special requirements. Eys Protsction Safety goggles. Other Impervious dotfling as necessary to prevent skin contact Precaution* In Handling and Storing Section IX -- SPECIAL PRECAUTIONS Store in cool, dry area. Othar Precautions Remove contaminated clothing immediaiety. Wash dothing before reuse. Contaminated leather including shoes canncrt be decontaminated so they should be dsearded. Th Mormatnn cmvM herein * ftnrl on data pmdM Irom fc^lin at *n irawitk vud and net on me mactwre *et. uO to teti'd to be coma. Iloweoer, no muiantf fc r~wni1 o* rifled mperdme me eecuttcf tt Ste oa*. Since Vie intormwien corawwt hemm may be J under oondttoni beyond our corwol. me gem mcwvmg I ihtl mUe tee own dotwmnew ot me mitabtey of tho product ter merr pvocvlw pupewe. 77060 - 143A-3 SAL om* zs cm Pifw ieia io. me 1*17 2*. isitao. itoe.se ene i IU 441 CMA 21 0* 00000655x CHESTERTON MATERIAL SAFETY DATA SHEET S4 9 8 A.W. CHESTERTON COMPANY 725 Fallon Rood, Middlesex Industrial Par* Sioneham, MA 02180-2999 U S A Section I___________ Emergency Telephone Noi 617-438-7000 (Dai 617-438-7013 (Nigh __ ____ Date of Prep. June 1, 1989 MSDSNo. 1438-3 Product Name: 810 Steel Putty Plus Part B HAZAROOUS MATERIALS IDENTIFICATION SYSTEM (HMIS) 4 - Severe Hazard 3 - Serious Hazard 2 * Moderate Hazard 1 Slight Hazard HEALTH FLAMMABILITY REACTIVITY 3 2 1 0 > Minimal Hazard Personal Prolection * - See SecUon Vlil Specie! Protection Inlor/naoon General Use and Precautionary Information Chesterton^ MetaJ Repair System Repair damage caused by impact, abrasion, erosion or corrosion, rebuild worn areas; fill holes and cracks; provide abrasion resistant surfaces. The safety and health hazards are detailed lor Part A and Part B: separately. The final cured product is considered nor>hazardous Upon machining, it can only be categorized as a nuisance dusL )iethyfene Triamine 'henot Section II - HAZARDOUS INGREDIENTS tngredientsSynonyma tt0MVX CAS No, % Wt 111 -40-0 <25 z 108-95-2 <2 OSHA-eiL pa>* mo?ml 14 5 (skin) 19 ppmMCCHmTtlrfnmj 1 (skin) 4 S (skin) 19 Vapor Pressure - Jone Initial Bolling Point Section HA - OTHER INGREDIENTS on the EPA LIST OF TOXIC CHEMICALS x Material marked conians o' $ `.arc chemieal(s). subject to m reoortjng require ments of section 313 o' T .re III of me Superfund Amendments and Reeumonzafion Actol 1986 and 40 CFR Pen 37? Section III - PHYSICAL DAT N'A Percent Volatile (by volume) < 1 Vapor Density {Air s I) Ewapcratton Rate < 1 Weight Per Gallon 8 3 cs {Ether a 1) Section IV - FIRE AND EXPLOSION DATA Flash Point 76SC (164*F) Closed Cup LEL Not Determined DOT Shipping Name Corrosive Liquid nos DOT Hazard Class Corrosive DOTUN/NA d UNI 760 Extinguishing Media Carbon Dioxide, dry chemical or foam Unusual Fire and Explosion Hazards Thermal decomposition can lorm Phenol. Amines and other toxic fumes. Special Flra Fighting Proeaduras Cool exposed containers with water Recommend Firefighters wear self-contained breathing apparatus AW CHESTERTON CO. 1U A1 :R4 U S Pit ''d T U Ofl Riwnwl 5t1EA OM&tS 0000065^2 sM- Product Nam*: 810 Steel Putty Plus Part B CS498 Data: June 1. 1989 Stability Stable Hazardous Decomposition Products Hazardous PoTymertzatfon Section V -- REACTIVITY DATA Carbon Monoxide, Phenol. Amines and other toxic fumes Conditions to Avoid Open (lames and red hot surfaces. Materials to Avoid Strong oxidizers Bta liquid Chforine and concentrated Oxygen. Q May Occur B Will Not Occur Section VI -- HEALTH HAZARD DATA Primary Routs ot Exposure Under Normal Use Inhalation, skin and eye contact. Acute Effects Direct contact wiH cause bums to stun, eyes, and mucous membranes. Hgh vapor concentrations can cause severe eye and respiratory tract irritation, nausea and vomiting. Chronic Effects Prolonged or repealed contact may cause asthma, skin sensitization and other aDergic reactions. As per 29 CFR 1910.1200 (Hazard Communication), there are NO carcinogens in this product as fisted in the National Toxicology Program (NTP). the International Agency (or Research on Cancer (IARC) or the Occupational Safety and Health Administration (OSHA). Emergency and First Aid Procedures Inhalation Remove to fresh air. II not breathing, administer artificial respiration. Contact physician. Eya/Sktn Contact Rood area with water while removing contaminated ctolhing Wash clothing before reuse. Rush eyes tor at least 30 minutes with large amounts of water. Consult physician. ingestion if conscious, do not induce vomiting; drink milk, water or vinegar. Contact physician immedalely. Section VII -- SPILL OR RELEASE PROCEDURES Steps to be Taken In Case Material Is Spilled or Released Evacuate area. Provide adequate ventilation. Avoid skin contact Scoop up and fransier to a suitable container for disposal. Waste Disposal Method Landfill sealed containers in an approved area. Check local, state and federal regulations. Section VIII -- SPECIAL PROTECTION INFORMATION Respiratory Protection Not normally needed. If necessary, utilize an approved air supplied respirator. Protective Gloves Chemical resistant gloves (e g., natoral rubber or PVC). Ventilation No special requirements. If necessary, provide adequate ventilation. Eye Protection Safety goggles Other Impervious clothing as necessary to prevent skin contact Precautions In Handling end Storing Section IX -- SPECIAL PRECAUTIONS None Other Precautions Remove contaminated clothing immediately. Wash clothing before reuse. Conteminated leather induing shoes cannot be decontaminated so they shotid be discarded. Th mformiren contifrwti harain * htaad on calm ppvitiati from suppSers ft Che maiam* uud and on ntirtm Uaff. anti la tetovad B be arma. However, no warranty a **pra*aad or Impleti reearorg the accuracy d The Since the Hormauon corxaned hBn may be appM under csnAxxB beywd oca control. Ob parlors moemn* I ahal maM OB* wn deiermnaiBn d the futility d the product Igr the> parttauto piapow. 7700 1438 3 osha z* cntPens lateizDo, tetsi 1817 28. iSll.tO 1*20-50 ant 1*2* UA 441 CMP 21 00 SAL 000006553  MATERIAL SAFETY DATA SHEET PRODUCT NALCO 5209 antifoulant NALCO Emergency Telephone Number Medical (312)920-1510(24 hour*) GS611 *Effective November 11, 1989. the area code will be changed to 708. SECTION 1 PRODUCT IDENTIFICATION TRADE NAME: NALCO 5209 ANTIFOULANT DESCRIPTION: An alkyl aryl diamine in a heavy aromatic naphtha NFPA 704M/HMIS RATING: 1/1 HEALTH 2/2 FLAMMABILITY 0/0 REACTIVITY 0=Insignificant l=Slight 2=Moderate 3=High 4-Extreme 0 OTHER SECTION 2 HAZARDOUS INGREDIENTS Our hazard evaluation has identified the following chemical ingredient(s) as hazardous under OSHA's Hazard Communication Rule, 29 CFR 1910.1200. Consult Section 14 for the nature of the hazard(s). INGREDIENT(S) CAS # APPROX.% Heavy aromatic naphtha Naphthalene 64742-94-5 91-20-3 40+ 1-10 SECTION 3 PRECAUTIONARY LABEL INFORMATION CAUTION: Combustible. May cause irritation to skin and eyes. Prolonged inhalation of vapor may be harmful. Avoid contact with skin, eyes, and clothing. Avoid prolonged or repeated breathing of vapor. Use with adequate ventilation. Do not take internally. Keep away from heat and open flame. Keep container closed when not in use. Empty containers may contain residual product. Do not reuse container unless properly reconditioned. SECTION 4 FIRST AID INFORMATION EYES: SKIN: INGESTION: INHALATION: Flush with water for 15 minutes. Call a physician. Wash thoroughly with soap and rinse with water. Call a physician. Do not induce vomiting. Give water. Call a physician. Remove to fresh air. Treat symptoms. Call a physician. NOTE TO PHYSICIAN: No specific antidote is known. Based on the individual reactions of the patient, the physician's judgment should be used to control symptoms and clinical condition. CAUTION: If unconscious, having trouble breathing or in convulsions, do not induce vomiting or give water. PAGE 1 OF 8 SAL 000006554 ISIALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60566-1034 NALCO MATERIAL SAFETY DATA SHEET GS611 PRODUCT HALCO 5209 ANTIFOULAHT Emergency Telephone Number Medical (312) 920-1510(24 hours)* 'Effective November 11. 1989, the area code will be changed to 708 PRIMARY ROUTE(S) OF EXPOSURE: Eye, Skin, Inhalation EYE CONTACT: SKIN CONTACT: INHALATION: May cause irritation depending on the duration of exposure. Can cause transient to moderate irritation. Prolonged inhalation of vapor may be harmful. SYMPTOMS OF EXPOSURE: ACUTE: Inhalation of high concentrations of heavy aromatic naphtha can cause nausea, dizziness, vomiting, stupor or unconsciousness. CHRONIC: Prolonged skin contact with heavy aromatic naphtha can cause dry skin and defatting resulting in irritation and dermatitis. AGGRAVATION OF EXISTING CONDITIONS: A review of available data does not identify any worsening of existing conditions. SECTION 6 TOXICOLOGY INFORMATION ACUTE TOXICITY STUDIES: Acute toxicity studies have been conducted on this product. The results are shown below. ACUTE ORAL TOXICITY (ALBINO RATS): LD50 = 3.4 g/kg 95% Confidence Limit = 2.6 - 4.4 g/kg ACUTE DERMAL TOXICITY (ALBINO RABBITS): LD5,, = Greater than 2 g/kg COMMENTS: 2.0 g/kg applied to the backs of test animals failed to produce mortality. PRIMARY SKIN IRRITATION TEST (ALBINO RABBITS): SKIN IRRITATION INDEX DRAIZE RATING: 4.2/8.0 COMMENTS: Slight redness was noted at all sites 24 hours after contact. Irritation increased at 72 hours in one-half of the test sites. Swelling increased in intensity from slight to moderate at 72 hours. PRIMARY EYE IRRITATION TEST (ALBINO RABBITS): EYE IRRITATION INDEX DRAIZE RATING: 8/110.0 Minimally irritating COMMENTS: Corneal opacities and iritis were not noted. Only slight conjunctivitis was observed at one hour. By day three, all eyes appeared normal PAGE 2 OF 8 SAL 000006555 TMALCD CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60566-1024 MATERIAL SAFETY DATA SHEET PRODUCT nalco 5209 antifoulant NALCO Emergency Telephone Number Medical (312)920-1510(24 hours)' (rS6 11 'Effective November 11. 989. the area code will Oe changed to 708 SECTION 7 PHYSICAL AND CHEMICAL PROPERTIES COLOR: Dark red DENSITY: SOLUBILITY IN WATER: SPECIFIC GRAVITY: pH (at 20%) = VISCOSITY: POUR POINT: FLASH POINT: PERCENT VOLATILE BY WEIGHT: FORM: Liquid 7.5 - 7.7 lbs/gal. Insoluble 0.91 @ 60 Degrees F 8.7 48 SUS @ 100 Degrees F -10 Degrees F 172 Degrees F (TCC) 1 @ 75 Degrees F ODOR: Hydrocarbon ASTM D-1298 ASTM E-70 ASTM D-2983 ASTM D-97 ASTM D-56 NOTE: These physical properties are typical values for this product. SECTION 8 FIRE AND EXPLOSION INFORMATION FLASH POINT: 172 Degrees F (TCC) ASTM D-56 EXTINGUISHING MEDIA: Based on the NFPA guide, use dry chemical, alcohol foam, carbon dioxide or other extinguishing agent suitable for Class B fires. Use water to cool containers exposed to fire. For large fires, use water spray or fog, thoroughly drenching the burning material. UNUSUAL FIRE AND EXPLOSION HAZARD: May evolve NOx under fire conditions. SECTION 9 REACTIVITY INFORMATION INCOMPATIBILITY: Do not use with rubber, vinyl, polyethylene, PVC, Buna-N, polypropylene, ethylene isopropylene, or polyurethane. Avoid contact with strong oxidizers (eg. chlorine, peroxides, chromates, nitric acid, perchlorates, concentrated oxygen, permanganates) which can generate heat, fires, explosions and the release of toxic fumes. THERMAL DECOMPOSITION PRODUCTS: In the event of combustion CO, C03, NOx may be formed. Do not breathe smoke or fumes. Wear suitable protective equipment. SECTION 10 PERSONAL PROTECTION EQUIPMENT RESPIRATORY PROTECTION: Respiratory protection is not normally needed since the volatility and toxicity are low. If significant vapors, or mists are generated, wear a NIOSH approved or equivalent respirator, (ANSI Z 88.2, 1980 for requirements and selection). For large spills, entry into large tanks, vessels or enclosed small PAGE 3 OF 8 006S56 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE, ILLINOIS 60566-102*3 NALCO MATERIAL SAFETY DATA SHEET GS611 PRODUCT MALC0 5209 amtifoulamt Emergency Telephone Number Medical (312) 920-1510 (24 hours)* Effective November 11. 1989. the area code will be changed to 708. spaces with inadequate ventilation, a pressure-demand, self-contained breathing apparatus is recommended. VENTILATION: General ventilation is recommended. Additionally, local exhaust ventilation is recommended where vapors, mists or aerosols may be released. PROTECTIVE EQUIPMENT: Use impermeable gloves and chemical splash goggles (ANSI Z 67.1 requirements and selection of gloves, goggles, shoes, etc.) when attaching feeding equipment or doing maintenance. If clothing is contaminated, remove clothing and thoroughly wash the affected area. Launder contaminated clothing before reuse. SECTION 11 SPILL AND DISPOSAL INFORMATION IN CASE OF TRANSPORTATION ACCIDENTS, CALL THE FOLLOWING 24-HOUR TELEPHONE NUMBER (708-920-1510) SPILL CONTROL AND RECOVERY: Small liquid spills: Contain with absorbent material, such as clay, soil or any commercially available absorbent. Shovel reclaimed liquid and absorbent into recovery or salvage drums for disposal. Refer to CERCLA in Section 14. Large liquid spills: Dike to prevent further movement and reclaim into recovery or salvage drums or tank truck for disposal. Refer to CERCLA in Section 14. DISPOSAL: If this product becomes a waste, it does not meet the criteria of a hazardous waste as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261, since it does not have the characteristics of Subpart C, (i.e. D001 through D017) nor is it listed under Subpart D. As a non-hazardous liquid waste, it should be solidified with stabilizing agents (such as sand, fly ash, or cement) so that no free liquid remains before disposal to an industrial waste landfill. A non-hazardous liquid waste can also be incinerated in accordance with local, state, and federal regulations. SECTION 12 ENVIRONMENTAL INFORMATION If released into the environment, see CERCLA in Section 14. PAGE 4 OF 8 SAL 000006557 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60566-1024 MATERIAL SAFETY DATA SHEET PRODUCT .NALCO 5209 ANTIFOULANT NALCO Emergency Telephone Number Medical (31 2) 920-1510 (24 hours)* 6S6 11 'Effective November J J, 19S9, (he area code will be changed (o 708 SECTION 13 TRANSPORTATION INFORMATION DOT PROPER SHIPPING NAME/HAZARD CODE - COMBUSTIBLE LIQUID, N.O.S. COMBUSTIBLE LIQUID NA 1993 CONTAINS - AROMATIC HYDROCARBONS, NAPHTHALENE SECTION 14 REGULATORY INFORMATION The following regulations apply to this product. FEDERAL REGULATIONS: OSHA'S HAZARD COMMUNICATION RULE, 29 CFR 1910.1200: Based on our hazard evaluation, the following ingredient in this product is hazardous and the reason is shown below. Heavy aromatic naphtha - Skin irritant, combustible Naphthalene - Irritant Naphthalene = TWA 10 ppm, STEL 15 ppm ACGIH/TLV 52 mg/m3, 79 mg/m3 ACGIH/TLV Naphthalene = TWA 10 ppm, STEL 15 ppm OSHA/PEL 50 mg/m3, 75 mg/m3 OSHA/PEL Heavy aromatic naphtha = 100 ppm TLV Manufacturer's recommendation CERCLA, 40 CFR 117, 302: This product contains naphthalene, a Reportable Quantity (RQ) substance and if 1,400 pounds of product are released, it requires notification to the NATIONAL RESPONSE CENTER, WASHINGTON, D. C. f1-800-424-8802). SARA/SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (TITLE III) - SECTIONS 302, 311, 312 AND 313: SECTION 302 - EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355): This product does not contain ingredients listed in Appendix A and B as an Extremely Hazardous Substance. SECTIONS 311 and 312 - MATERIAL SAFETY DATA SHEET REQUIREMENTS (40 CFR 370): Our hazard evaluation has found this product to be hazardous. The product should be reported under the following EPA hazard categories: PAGE 5 OF 8 SAL 000006558 I^ALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60566-102^ yy MATERIAL SAFETY DATA SHEET g g ^ j IpRODUCT MALC0 5209 antifoulamt NALCO MIL Emergency Telephone Number Medical (312)920-1510(24 hours)' 'Effective November 1 h ? 989. the area code will be changed to 708 ( CONTINUED ) XX Immediate (acute) health hazard -- Delayed (chronic) health hazard XX Fire hazard -- Sudden release of pressure hazard -- Reactive hazard Under Section 311, submittal of MSDS's or a list of product names to the local emergency planning commission, state emergency response commission and local fire department is required after October 17, 1987 if you have: -- 10,000 pounds or more of a hazardous substance, or -- 500 pounds or the threshold planning quantity, whichever is less, of an extremely hazardous substance. SECTION 313 - LIST OF TOXIC CHEMICALS (40 CFR 372): This product contains the following ingredient(s), (with CAS # and % range) which appear(s) on the List of Toxic Chemicals. Naphthalene 91-20-3 1-10 TOXIC SUBSTANCES CONTROL ACT (TSCA): The chemical ingredients in this product are on the 8(b) Inventory List (40 CFR 710). REGISTERED WITH THE U. S. EPA, OFFICE OF FUEL AND FUEL ADDITIVE REGISTRATION, as a fuel additive. RESOURCE CONSERVATION AND RECOVERY ACT (RCRA) , 40 CFR 261 SUBPART C L D: If this product becomes a waste, it does not meet the criteria of a hazardous waste. FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 401.15 (formerly Sec. 307), 40 CFR 116 (formerly Sec. 311): This product contains the following ingredient covered by the Clean Water Act: Naphthalene - Section 307, 311 CLEAN AIR ACT, 40 CFR 60, SECTION 111, 40 CFR 61, SECTION 112: This product does not contain ingredients covered by the Clean Air Act. STATE REGULATIONS: CALIFORNIA PROPOSITION 65: PAGE 6 OF 8 SAL 000006559 NALCO CHEMICAL. COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60566-1024 MATERIAL SAFETY DATA SHEET NALCO PRODUCT NALCO 5209 ANTIFOULANT Emergency Telephone Number Medical (312) 920-1510(24 hours)' $$6 11 *Effective November ii, 1989, the area code will be changed to 708 SECTION 14 REGULATORY INFORMATION ( CONTINUED ) None of the chemicals on the current Proposition 65 list are known to be present in this product. MICHIGAN CRITICAL MATERIALS: This product does not contain ingredients listed on the Michigan Critical Materials Register. STATE RIGHT TO KNOW LAWS: Regulated in those states using the TLV for naphthalene as a criteria for listing. SECTION 15 ADDITIONAL INFORMATION None SECTION 16 USER'S RESPONSIBILITY This product material safety data sheet provides health and safety information. The product is to be used in applications consistent with our product literature. Individuals handling this product should be informed of the recommended safety precautions and should have access to this information. For any other uses, exposures should be evaluated so that appropriate handling practices and training programs can be established to ensure safe workplace operations. Please consult your local sales representative for any further information. SECTION 17 BIBLIOGRAPHY* I ANNUAL REPORT ON CARCINOGENS, U.S. Department of Health and Human Services, Public Health Service, PB 33-135655, 1983. CASARETT AND DOULL'S TOXICOLOGY, THE BASIC SCIENCE OF POISONS, Doull, J,, Klaassen, C. D., and Admur, M. 0., eds., Macmillian Publishing Company, Inc., N. Y., 2nd edition, 1980. CHEMICAL HAZARDS OF THE WORKPLACE, Proctor, N. H., and Hughes, J. J. P. Lipincott Company, N.Y., 1981. eds., DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS, Sax, N. Irving, ed., Van Nostrand Reinhold Company, N.Y., 6th edition, 1984. IARC MONOGRAPHS ON THE EVALUATION OF THE CARCINOGENIC RISK OF CHEMICALS TO MAN, Geneva: World Health Organization, International Agency for Research on Cancer, 1972-1977. PAGE 7 OF 8 SAL 000006560 NALCO CHEMICAL. COMPANY ONE NALCO CENTER # NAPERVILLE. ILLINOIS 60566-1024 MATERIAL SAFETY DATA SHEpT Cr S 6 11 NALCO 5209 ANTIFOULANT product NALCO OCVTTan 7 STBLTwarn Emergency Telephone Number Medical (31 2) 920-1510 (24 hours*' Effective November r i, 1989. the area code will be changed fo 708 ( CONTINUED ) PATTY'S INDUSTRIAL HYGIENE AND TOXICOLOGY, Clayton, G. D., Clayton, F. E., eds., John Wiley and Sons, N. Y., 3rd edition, Vol. 2 A-C, 1981. REGISTRY OF TOXIC EFFECTS ON CHEMICAL SUBSTANCES, U.S. Department of Health and Human Services, Public Health Service, Center for Disease Control, National Institute for Occupational Safety and Health, 1983 supplement of 1981-1982 edition, Vol, 1-3, OH, 1984. Title 29 Code of Federal Regulations Part 1910, Subpart Z, Toxic and Hazardous Substances, Occupational Safety and Health Administration (OSHA). THRESHOLD LIMIT VALUES FOR CHEMICAL SUBSTANCES AND PHYSICAL AGENTS IN THE WORKROOM ENVIRONMENT WITH INTENDED CHANGES, American Conference of Governmental Industrial Hygienists, OH. PREPARED BY: John J. Kasper, MSc., Manager Product Safety DATE CHANGED: 11/29/89 DATE PRINTED: 01/06/90 PAGE 8 OF 8 SAL 000006561 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60566-1024 GS 180 MATERIAL SAFETY DATA SHEET PAGES 1 DOW CHEMICAL U.S.A. MIDLAND MICHIGAN 48640 EMERGENCY PHONE: 517-636-4400 EFFECTIVE DATE: 13 NOV 79 PRODUCT CODE: 3B698 PRODUCT NAME: ^GLYCgIfg^^P___ ____ __ ______ MSDs 0165 INGREDIENTS (TTPICAL VALUES-NOT SPECIFICATIONS) i%: GLYCERINE, MINIMUM s 99.5 : SECTION 1 PHYSICAL DATA BOILING POINT: 554F, 290C : SOL. IN WATER: MISCIBLE VAP PRESS: 1.0 MHHG 9 2DC : SP. GRAVITY: 1.2607 * 25/25 VAP DENSITY (AIR=1): 3.1 : % VOLATILE BY VOL: VERY LOW APPEARANCE AND ORDER; WATER WHITE -- ODORLESS LIQUID. (MIN.) SECTION 2 FIRE AND EXPLOSION HAZARD DATA FLASH POINT: 390F, 199C : FLAMMABLE LIMITS (STP IN AIR) METHOD USED: PENSKY MARTENS C.C. * LFL: NOT DETER. UFL: NOT DETER. EXTINGUISHING MEDIA: WATER FOG, ALCOHOL FOAM, C02, DRY CHEMICAL. SPECIAL FIRE FIGHTING EQUIPMENT AND HAZARDS: NONE. AUTOIGNITION TEMPERATURE 698F, 370C. SECTION 3 REACTIVITY DATA STABILITY: -------INCOMBATIBILITT: OXIDIZING MATERIAL. HAZARDOUS DECOMPOSITION PRODUCTS: ACROLEIN. HAZARDOUS POLYMERIZATION: WILL NOT OCCUR. SECTION 4 SPILL,LEAK,AND DISPOSAL PROCEDURES ACTION TO TAKE FOR SPILLS: SMALL LEAKS ABSORB, SWEEP UP AND BURN. LARGE SPILLS - FLUSH TO SEVER WITH WATER DISPOSAL METHOD: BURN OR DILUTE WITH COPIOUS AMOUNTS OF WATER. SECTION 5 HEALTH HAZARD DATA INGESTION: LOW SINGLE AND REPEATED DOSE TOXICITY. EYE CONTACT: SLIGHT TRANSIENT IRRITATION. SKIN CONTACT: ESSENTIALLY NON-IRRITATING. SKIN ABSORPTION: NOT LIKELY TO BE ABSORBED THROUGH SKIN. INHALATION: ACGIH TLV IS 10 MG/M3 AS A NUISANCE MIST (1979). EFFECTS OF OVEREXPOSURE: IRRITATION. (CONTINUED ON PAGE 2 ) (R) INDICATES A REGISTERED OR TRADEMARK NAME OF THE DOW CHEMICAL COMPANY i S&426 000006562. SAL j2LSS&& GS 180 IH.EBIU SAFETY DATA SHEET PAGE* 2 DOW CHEMICAL U.8.A. MIDLAND MICHIGAN 48640 EMERGENCY PHONE: 517-636-4400 EFFECTIVE DATE: 13 MOV 79 PRODUCT (COKT'D): GLYCERINE, USP, 99.5% PRODUCT CODE: 38698 HSD: 0165 SECTION 6 FIRST AID--NOTE TO PHYSICIAN FIRST AID PROCEDURES: EXES: IRRIGATION OF THE EYE IMMEDIATELY WITH WATER FOR FIVE MINUTES IS GOOD SAFETY PRACTICE. SKIN: WASH OFF IN FLOWING WATER. INHALATION: FAIREMOVE TO FRESH AIR IF EFFECTS OCCUR. CALL PHYSICIAN AND/OR TRANSPORT TO MEDICAL FACILITY. INGESTION: LCW IN TOXICITY. INDUCE VOMITING IF LARGE AMOUNTS ARE INGESTED. NOTE TO PHYSICIAN: EYES: KAY CAUSE MILD IRRITATION. STAIN FOR EVIDENCE OF CORNEAL INJURY. INJURY IS UNLIKELY. SKIM: INJURY IS UNLIKELY. NOT LIKELY TO BE ABSORBED IN ACUTELY TOXIC AMOUNTS. RESPIRATORY: SHOULD AVOID HEATED VAPORS. MAY CAUSE SEVERE IRRI TATION WITH OVEREXPOSURE. ADMINISTER OXYGEN IF AVAILABLE. BRONCBODILATORS, EXPECTORANTS, AND ANTXTUSSIVES MAY BE OF HELP. ORAL: LOW ZM TOXICITY. SYSTEMIC: RAT STUDIES INDICATE THAT KIDNEY IS TARGET ORGAN WITH OVEREXPOSURE. CONSULT STANDARD LITERATURE. NO SPECIFIC ANTIDOTE. TREATMENT BASED ON THE SOUND JUDGMENT OF THE PHYSICIAN AND THE INDIVIDUAL REACTIONS OF THE PATIENT. SECTION 7 SPECIAL HANDLING INFORMATION VENTILATION: RECOMMEND CONTROL OF MIST TO SUGGESTED GUIDE. RESPIRATORY PROTECTION: NONE NORMALLY NEEDED. PROTECTIVE CLOTHING: NONE REQUIRED. EYE PROTECTION: NOT NORMALLY NECESSARY. SECTION 8 SPECIAL PRECAUTIONS AND ADDITIONAL INFORMATION PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: PRACTICE REASONABLE' CARE AND CAUTION. ADDITIONAL INFORMATION: REVISIONS 11/13/79 -- SECTIONS 3, 5, 6, 7. LAST PAGE (R) INDICATES A REGISTERED OR TRADEMARK NAME OF THE DOW CHEMICAL COMPANY THE INFORMATION HEREIN IS GIVEN IN GOOD FAITH, BUT NO WARRANTY, EXPRESS OR IMPLIED, IS MADE. r SAL 000006563 .-S9427 material safety data sheet EM SCIENCE PREPARATION DATE A DIVISION OF EM INDUSTRIES 111 WOOOCREST INFORMATION PHONE NUMBER*: CHERRY HILLt N*J. 08034-0395 (609) 354-9200 CHEMTREC EMERGENCY NUMBER: 1-800-424-9300 OCT 27* *87 I NFPA HAZARD RATINGS I | HEALTH : 3 FLAMMABILITY *: 0 I REACTIVITY : 0 SPECIAL HAZARDS*: N/A CATALOG NUMBER(S): CHEMICAL NAME****: TRADE NAME.................. .. C.A.S* NUMBER**.*: CHEMICAL FAMILY*.: FORMULA............................. MOLECULAR WEIGHT.: DOT SHIPPING NAME: DOT NUMBER**.*...: SECTION I - GENERAL MX0398 MX0400 MERCURY QUICK SILVER 7439-97-6 METALLIC ELEMENT HG 200.59 N/A N/A INFORMATION MX0405 4404 GS 588 SECTION II - HAZARDOUS INGREDIENTS -NONE OTHER THAN SPECIFIED PRODUCT SECTION III- PHYSICAL DATA BOILING POINT (C 760 MM HG)*: 357C MELTING POINT (C)............................. .. -39C SPECIFIC GRAVITY(H*2*0 = 1).*..: 13*55 VAPOR PRESSURE(MM HG)............... .. 0*001 20C PERCENT VOLATILE BY VOL (X).*: 99+ VAPOR DENSITY <AIR*1).................. .. N/A EVAPORATION RATE (BUAC*1)* * *.: N/A SOLUBILITY IN WATER (X)............... .. INSOLUBLE APPEARANCE AND ODOR*: SILVERY-GRAY HEAVY LIQUID SECTION IV - FIRE & EXPLOSION HAZARD DATA FLASH POINT (F).................. .. NONCOMBUSTIBLE FLAMMABLE LIMITS LEL X.: N/A FLAMMABLE LIMITS UEL X.: N/A EXTINGUISHING MEDIA.***: ANY SUITABLE FOR SURROUNDING MATERIALS MSDS-MX0398 PAGE * : 01 SAL 000006564 CS 583 FIRE FIGHTING PROC............ : WEAR SELF-CONTAINED BREATHING FIRE L EXPL. HAZARDS...: -EMITS EXTREMELY TOXIC MERCURY APPARATUS VAPOR AT HIGH TEMPERATURES SECTION V - HEALTH HAZARD DATA (ACUTE AND CHRONIC) ACGIH TLV/OSHA PEL (TWA).: 0.05 MG/CU.M. (TWA) OSHA-PEL: O.I MG/CU.M. (CL) TOXICITY DATA............................. -IHL-MAN TCLO: <?<?*3 MG/M3/9H IHL-RBT LCLO: 29 MG/M3/30H SYMPTOMS OF EXPOSURE ............................ -HIGHLY TOXIC 8Y VAPOR INHALATIONS SYMPTOMS: METALLIC TASTE? NAUSEA? ABOOMINAL PAIN? DIARRHEA? HEADACHE* ALBUMINUREA PROLONGED OR REPEATEO EXPOSURE MAY CAUSE MUSCLE TREMORS* CENTRAL NERVOUS SYSTEM DISTURBANCES? KIDNEY* HEART* LUNG ANO BRAIN damage CAN BE ABSORBED THROUGH SKIN AND Gl TRACT MEDICAL CONO. AGGRAVATED BY EXP: DATA NOT AVAILABLE. ROUTES OF ENTRY........................................... : INHALATION* INGESTION OR SKIN CONTACT. CARCINOGENICITY................................... : SEE COMMENTS* SECTION XJ IF NO INFORM ATION APPEARS? THE MATERIAL IS NOT LISTED AS A CANCER CAUSING AGENT. EMERGENCY FIRST AID................................ SKIN: WASH THOROUGHLY WITH SOAP ANO WATER EYES: FLUSH THOROUGHLY WITH WATER INHALATION: REMOVE TO FRESH AIR * INGESTION: IF CONSCIOUS* INDUCE VOMITING GET MEDICAL ASSISTANCE FOR ALL CASES OF OVEREXPOSURE * (GIVE ARTIFICIAL RESPIRATION IF BREATHING HAS STOPPED) SECTION VI - REACTIVITY OATA STABILITY........................... .. YES CONDITIONS TO AVOID -HEAT MATERIALS TO AVOID. : ( ) WATER ( ) ACIDS ( ) BASES ( ) CORROSIVES ( ) OXIDIZERS (X) OTHER (SPECIFY)- ACETYLENIC COMPOUNDS? AMMONIA* ETHYLENE HAZARDOUS POLYMERIZATION.: DATA NOT AVAILABLE. HAZARDOUS DECOMPOSITION..: -N/A OXIDE c SECTION VII - ENVIRONMENTAL PROTECTION PROCEDURES SPILL RESPONSE: -TAKE UP WITH SUCTION AND CONTAINERIZE FOR RECLAMATION OR PROPER DISPOSAL hASTE DISPOSAL: TO BE PERFORMED IN COMPLIANCE WITH ALL CURRENT STATE AND FEDERAL REGULATIONS. LOCAL* SECTION VIII - SPECIAL PROTECTION INFORMATION VENTILATION* RESPIRATORY PROTECTION* PROTECTIVE CLOTHING? -MATERIAL MUST BE HANDLED OR TRANSFERRED IN AN APPROVEO MSDS-MX0398 EYE PROTECTION: FUME HUGO PAGE ff : 02 $al 006565 OR WITH EQUIVALENT VENTILATION PROTECTIVE GLOVES (NEOPRENE* PVC OR EQUIVALENT) PREVENT SKIN CONTACT SAFETY GLASSES WITH SIDE SHIELDS SHOULD BE WORN SHOULD AT ALL BE WORN TINES TO SECTION IX - SPECIAL PROTECTION INFORMATION HANOLING L STORAGE -KEEP CONTAINER CLOSED AND AWAY FROM HEAT DO NOT BREATHE VAPOR 00 NOT GET IN EYES* ON SKIN OR ON CLOTHING AVOIO PROLONGED OR REPEATED SKIN CONTACT DO NOT TAKE INTERNALLY WASH THOROUGHLY AFTER HANDLING WORK/HYGIENIC PRACTICES: WASH THOROUGHLY AFTER HANOLING* 00 NOT TAKE INTERNALLY. EYE WASH ANO SAFETY EQUIPMENT SHOULD BE REAOILY AVAILABLE. SECTION X - OTHER INFORMATION COMMENTS................................ .. -* (SUBLIMES) TESTS ON LABORATORY ANIMALS INDICATE MATERIAL MAY CAUSE TUMORS AND MAY PRODUCE ADVERSE MUTAGENIC AND REPRODUCTIVE EFFECTS REV. 9/86 REVISION HISTORY........................ : 12/01/81* N/A OCT 27* *87 N/A * NOT AVAILABLE: MSDS-MX0398 PAGE # : 03 SAL 0006566 MATERIAL SAFETY DATA SHEET EASTMAN KODAK COMPANY Date of Revisions 10/5/89 Kodak Accession Number: 927769 PRODUCT INFORMATION Product Name: KODAK PROSTAR Plus Developer Formula: Aqueous Mixture Kodak Catalog Number(s): Cat 102 2990 - 1 Gallon Solution Number: 9879 Kodak Hazard Rating Codes: R:1 S:2 F: 0 6 S 6 08 C: 0 Manufacturer/Supplier: Eastman Kodak Company 393 State Street Rochester/ New York 19650 USA For Emergency Information: (716) 722~5151 For other purposes/ call the Marketing and Distribution Center in your area. COMPONENT INFORMATION Weight Percent CAS Number Accession Number Water Sodium sulfite Potassium sulfite Potassium carbonate XHydroquinoneKX 85-90 1-5 1-5 1-5 2 7732-18-5 7757-83-7 10117-38-1 589-08-7 123-31-9 035290 901198 397367 900909 900356 ^Principal Hazardous Component(s) XXChemical subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments 8 Reauthorization Act of 1986 and 90 CFR Part 372. PHYSICAL DATA Appearance and Odor: Clear/ light yellow solution; Boiling Point: GT 100 C (GT 212 F) Vapor Pressure: ca. 18 mmHg 9 20 C Evaporation Rate (n-butyl acetate = 1): ca. 0.36 Vapor Density (Air = 1): ca. 0.6 Volatile Fraction by Weight: ca. 85 X Specific Gravity (H20 - 1): 1.10 pH: ca. 10.6 Solubility in Water (by Weight): Complete odorless GT * Greater than; LT * Less than C-0112.350D 83-0336 SAL 000006567 6 S 6 OR 2 FIRE AND EXPLOSION HAZARD FLASH POINT: Non, noncombustible EXTINGUISHING MEDIA: Use appropriate agent for surrounding fire. SPECIAL FIRE FIGHTING PROCEDURES: Wear self-contained breathing apparatus and protective clothing. UNUSUAL FIRE AND EXPLOSION HAZARDS: Fire or excessive heat may cause production of hazardous decomposition products. REACTIVITY DATA STABILITY: Stable INCOMPATIBILITY: Mineral acids HAZARDOUS DECOMPOSITION PRODUCTS: Thermal decomposition may produce oxides of sulfur. CONDITIONS CONTRIBUTING TO HAZARDOUS POLYMERIZATION: Will not occur. TOXICOLOGICAL PROPERTIES EXPOSURE LIMITS: Component: Hydroquinone ACGIH TLV: 2 mg/m3-TWA CACGIH 1988-89) OSHA PEL: 2 mg/m3-TWA EXPOSURE EFFECTS: Inhalation: Low hazard for recommended handling. Eyes: Liquid may cause irritation. Skin: Prolonged or repeated skin contact may cause skin irritation. May cause an allergic skin reaction. Ingestion: Expected to be a low ingestion hazard. PROTECTION AND PREVENTIVE MEASURES VENTILATION: Good general ventilation* should be sufficient. ^Typically 10 room volumes per hour is considered good general ventilation: Ventilation rates should be matched to conditions of use. SKIN AND EYE PROTECTION: Safety glasses with side shields are recommended. Impervious gloves should be worn. The routine use of a non-alkaline (acid) type of hand cleaner will help minimize the possibility of allergic skin reaction. STORAGE AND DISPOSAL SPECIAL STORAGE AND HANDLING PRECAUTIONS: Avoid contact with mineral acids. SPILL, LEAK, AND DISPOSAL PROCEDURES: Flush material to an acid-free '-ewer with large amounts of water. Discharge, treatment, or disposal may be subject to federal, state, or local laws. ^ 000656g C-Q112.350D 83-0336 r r GS608 3 FIRST AID Eyes: Immediately flush eyes with plenty of water for at least 15 minutes and get medical attention if any symptoms are present after washing. Skin: Flush skin with plenty of soap and water. If skin irritation or an allergic skin reaction develops, get medical attention. Remove contaminated clothing and shoes. Wash contaminated clothing before reuse. Destroy or thoroughly clean contaminated shoes. Ingestion: Drink 1-2 glasses of water. Seek medical attention. ENVIRONMENTAL EFFECTS DATA This environmental effects summary is written to assist in addressing emergencies created by an accidental spill, which might occur during the shipment of this product, and in general, it is not meant to address discharges to sanitary sewers or publically owned treatment works. Some laboratory test data and published data are available for the major components of this formulation. Although this product, as such, has not been tested for environmental effects, the data, mentioned above, have been used to provide the following estimates of potential environmental impact, in the event of an accidental spill: (1-121 This chemical formulation is a moderately alkaline aqueous solution, and this property may cause adverse environmental effects. It is expected to have a low biological oxygen demand, and it is not expected to cause oxygen depletion in aquatic systems. It is expected to have a high potential to affect aquatic organisms and a moderate potential to affect the germination and growth of some plants. It is expected to have a moderate potential to affect the germination and growth of some plants. The organic components of this chemical formulation are biodegradable and are not expected to persist in the environment. They are not likely to bioconcentrate. The direct instantaneous discharge to a receiving body of water of an amount of this formulation which will rapidly produce, by dilution, a final concentration of 0.25 mg/L, or less, is not expected to cause an adverse environmental effect. After dilution with a large amount of water, followed by secondary waste treatment, the chemicals in this formulation are not expected to have any adverse environmental impact. TRANSPORTATION For Transportation information regarding this product, please phone the Eastman Kodak Distribution Center nearest you: Rochester, NY (716) 588-9293; Oak Brook, IL (312) 954-6000; Chamblee, GA (404) 455-0123; Dallas, TX (214) 241-1611; Whittier, CA (213) 693-5222; Honolulu, HI (808) 833-1661. REFERENCES 1. Unpublished data. Health and Environment Laboratories, Eastman Kodak Company, Rochester, NY. 000006569 SM- C-0112.350D 83-0336 6 08 4 2. Verschueren, K., Handbook of Environmental Data on Organic Chemicals, Second Edition, Van Nostrand Reinhold Company, New York, NY, 1983. 3. Battelle*s Columbus Laboratories, Water Quality Criteria Data Book * Vol. 3 - Effects of Chemicals on Aquatic Life * Selected Data from the Literature Through 1968, for the U.S. Environmental Protection Agency, Project No. 18050 6WV, Contract No. 68-01-0007, Hay 1971. 4. National Association of Photographic Hanufacturers, Inc. and Hydroscience, Inc., Environmental Effects of Photoprocessing Chemicals, National Association of Photographic Manufacturers, Harrison, NY, 1974, 2 Vols. 5. Kodak Publication J-41, B0D5 and COD of Photographic Chemicals, Eastman Kodak Co., 1981. 6. McKee, J.E. and Wolf, H.W., Eds., Water Quality Criteria, State of California, Publication No. 3-A, 1963. 7. Bringmann, G. and Kuehn, R., Z. Wasser Abwasser Forsch., 10(5), 161-6 (1977) (in German). 8. Bringmann, G. and Kuehn, R., Z. Wasser Abwasser Forsch., 15(1), 1-6 (1982) (in German). 9. Juhnke, I. and Luedemann, D., Z. Wasser Abwasser Forsch., 11(5), 161-4 (1978) (in German). 10. Wellens, H., Z. Wasser Abwasser Forsch., 15(2) 49-52 (1982) (in German). 11. DeGraeve, G.H., et al.. Arch. Environ. Contam. Toxicol., 9, 557-68 (1980). 12. Pomona College, Medicinal Chemistry Project, Chemical Parameter Data Base, Leo, A.J. and Hansch, C., Eds., Seaver Chemistry Laboratory, Claremont, CA, June 20, 1987. PREPARATION INFORMATION Health and Environment Laboratories Eastman Kodak Company Rochester, New York 14652-3615 The information contained herein is furnished without warranty of any kind. Users should consider these data only as a supplement to other information gathered by them and must take independent determinations of the suitability and completeness of information from all sources to assure proper use and disposal of these materials and the safety and health of employees and customers. C-0112.350D 83-0336 SAL 000006570 GRAPHITE METALLIZING CORPORATION 1090 Nepperhan Avenue, P.O. Box 110, YONKERS, NY 10702 Tri: $14-968-8400 TELEX: 13-1571 FAX: 914-968-8468 Engineered GRAPHALLOY Products since 1913. MATERIAL SAFETY DATA SHEET section I Chemical name and Synonyms; Impregnated graphite/carbon G S 6 09 Trade name and Synonyms; GRAPHALLOY Chemical Family: Mixture of carbon, graphite, and resin or metal (Normally, only a few of the metals indicated will be present in any one piece of material) SECTION II - INGREDIENTS GRAPHALLOY May contain a combination of these materials: Carbon (C) including natural and synthetic graphite Lead (Pb) (7439-92-1) (See Section V) Antimony (Sb) (7440-36-0) Tin (Sn) (7440-31-5) Copper (Cu) (7440-50-8) as dust Cast Iron (Fe) (7439-89-6) Boron (B) (7440-42-8) Nickel (Ni) (7440-02-0) (See Section V) Chromium (Cr) (7440-47-3) Silver (Ag) (7440-22^) Traces of other metals are possible Resin *OSHA Regulations "ACGIH 1988-89 % 40-60 0-50 0-50 0-5 0-50 0-50 0-2 0-50 0-10 0-50 0-30 "'Nuisance particulate TLV (UNITS) 10.0 mg/M3*" 50.0 ug/M3* 0.5 mg/M3" 2.0 mg/M3" 2.0 mg/M3 5.0 mg/M3"' 10.0 mg/M3"* 1.0 mg/M3** 0.5 mg/M3" 0.1 mg/M3" 10.0 mg/M3*** SECTION III PHYSICAL DATA Boiling Point - Melts (at or above) 475F (Lead Alloys Only) Boils 2900F Specific Gravity (Hp=1) -- 1.8- 3.5 Vapor Pressure (mm Hg) - not applicable Percent Volatile by Volume (%) - not applicable Vapor Density (Air =1 > - not applicable Evaporation Rate - negligible Solubility in Water - negligible Appearance and Order - odorless, various shapes and sizes, black to grey SECTION IV - FIRE AND EXPLOSION HAZARD DATA Rash Point (Method Used) - not applicable Flammable Limits - not applicable Extinguishing Media - normal fire fighting techniques Special Fire Fighting Procedures - normal fire fighting techniques plus approved breathing apparatus and full protective clothing. Unusual Fire and Explosion Hazards - Dust will be electrically conductive and may contribute to fire hazard. Solids and dust may contribute to Fire. Lead, lead oxide, antimony, and tin fumes and dust are hazardous. SAL 000006571 GS6 09 SECTION V - HEALTH HAZARD DATA Threshold Limit Value - See Section II Effects of Overexposure - Ingestion of dust particles or breathing of dust or fumes may lead to metal poisoning. f Refer to OSHA standards and industrial hygiene references. Hexavalent chromium has been listed as a cancer agent by the ACGIH (chromium metal has not been listed). Emergency First Aid Procedures - Remove from exposure; consult physician at once. LEAD Molten lead alloys consisting of tin and antimony do not produce significant quantities of fume below 900F The present U.S. Department of Labor (OSHA) standard limit for occupational exposure to lead as referenced in CFR-Title 29 part 1910.1025 is 50 micrograms (50ug/M3) based on an 8 hour time-weighted average. This standard states that when the air of work-rooms contain regularly not more than 50 ug/M3 of inorganic lead and its inorganic compounds per cubic meter of air, as measured by prescribed methods, cases of lead intoxication will not occur. As a matter of good industrial hygiene, it is recommended that when lead alloys of tin and antimony are melted, adequate local exhaust ventilation be employed. Maintain the threshold limit value (TLV) below 50 ug /M3 for lead equal to 0.05 mg/M3. NICKEL Inhalation: The national Toxicology has listed nickel oxide as possible cancer hazards. The International Agency for Research on Cancer concluded there was sufficient evidence that nickel refining was carcinogenic to humans and limited evidence that nickel and certain nickel compounds were carcinogenic to humans. IARC could not state with certainty which forms of nickel are human carcinogens but said "... metallic nickel seems less likely to be so than nickel subsulphide or nickel oxides." The inhalation of nickel powder has not resulted in an increased incidence of malignant tumors in rodents. Studies of workers exposed to nickel powder and to dust and fume-generated in the production of nickel alloys and stainless steel have not indicated a Respiratory cancer hazard. Inhalation may cause irritation to upper respiratory tract Acute inhalation case LC50 in rats is greater than 10 mg/L Skin: Repeated contact with metallic nickel can cause nickel sensitivity resulting in allergic reaction such as skin rashes. Repeated contact is not likely to cause absorbtion in toxic quantities. Ingestion: Single dose oral toxicity is minimal, amouts ingested in industrial use are unlikely to cause injury. ( Acute oral case LD50 in rats is greater than 500 mg/kg. SECTION VI - REACTIVITY DATA Unstable in Strong oxidizing acids; other strong oxidants. Incompatibility (Materials to Avoid) - Strong oxidizing acids; other strong oxidants. Avoid acetylene, ammonia nitrate, bromates, chlorates, iodates, Cl and F! gas, and hydrogen sulfide. Hazardous Decomposistion Products - CO, CO2, SO2 Hazardous Polymerization /Will not occur. SECTION VII - SPILL OR LEAK PROCEDURES Steps to be taken in case material is released or spilled - Sweep, shovel, vacuum with approved device. Waste Disposal Method - Dispose in accordance with Federal, State and Local regulations. SECTION VIII - SPECIAL PROTECTION INFORMATION Respiratory Protection - Approved respirators if dust generated in excess of PEL. Ventilation /Local Exhaust: Recommended to minimize dust. Special: Not applicable Mechanical (General): Not applicable Other Not applicable Protective Gloves - Recommended Eye Protection - Safety glasses Other Protective Equipment - Full protective clothing when required by fumes or dusts. SECTION IX - SPECIAL PRECAUTIONS SAL 00006572 Precautions to be taken in Handling and Storing - Minimize Dust; minimize accumulation. CAUTION: The dust generated from cutting, grinding, or machining the solid material will be toxic to some degree, depending on the metal and the amount of secondary work. NOTE: This data sheet is supplied for your information only. Graphite Metallizing Corporation makes no warranties either implied or expressed and assumes no responsibility for the accuracy or completeness of the data contained herein. GS609 SECTION V - HEALTH HAZARD DATA Threshold Limit Value - See Section II Effects of Overexposure - Ingestion of dust particles or breathing of dust or fumes may lead to metal poisoning. Refer to OSHA standards and industrial hygiene references. Hexavalent chromium has been listed as a cancer agent by the ACGIH (chromium metal has not been listed). Emergency First Aid Procedures - Remove from exposure; consult physician at once. LEAD Molten lead alloys consisting of tin and antimony do not produce significant quantities of fume below 900F The present U.S. Department of Labor (OSHA) standard limit for occupational exposure to lead as referenced in CFR-Title 29 part 1910.1025 is 50 micrograms (50ug/M3) based on an 8 hour time-weighted average. This standard states that when the air of work-rooms contain regularly not more than 50 ug/M3 of inorganic lead and its inorganic compounds per cubic meter of air, as measured by prescribed methods, cases of lead intoxication will not occur. As a matter of good industrial hygiene, it is recommended that when lead alloys of tin and antimony are melted, adequate local exhaust ventilation be employed. Maintain the threshold limit value (TLV) below 50 ug /M3 for lead equal to 0.05 mg/M3. NICKEL Inhalation: The national Toxicology has listed nickel oxide as possible cancer hazards. The International Agency for Research on Cancer concluded there was sufficient evidence that nickel refining was carcinogenic to humans and limited evidence that nickel and certain nickel compounds were carcinogenic to humans. IARC could not state with certainty which forms of nickel are human carcinogens but said "...metallic nickel seems less likely to be so than nickel subsulphide or nickel oxides." The inhalation of nickel powder has not resulted in an increased incidence of malignant tumors in rodents. Studies of workers exposed to nickel powder and to dust and fume-generated in the production of nickel alloys and stainless steel have not indicated a respiratory cancer hazard. Inhalation may cause irritation to upper respiratory tract Acute inhalation case LC50 in rats is greater than 10 mg/L. Skin: Repeated contact with metallic nickel can cause nickel sensitivity resulting in allergic reaction such as skin rashes. Repeated contact is not likely to cause absorption in toxic quantities. Ingestion: Single dose oral toxicity is minimal, amouts ingested in industrial use are unlikely to cause injury. Acute oral case LD50 in rats is greater than 500 mg/kg. SECTION VI - REACTIVITY DATA Unstable in Strong oxidizing acids; other strong oxidants. incompatibility (Materials to Avoid) - Strong oxidizing acids; other strong oxidants. Avoid acetylene, ammonia nitrate, bromates, chlorates, iodates, Cl and FI gas, and hydrogen sulfide. Hazardous Decomposistion Products - CO, CO2, SO2 Hazardous Polymerization /Will not occur. SECTION VII - SPILL OR LEAK PROCEDURES Steps to be taken in case material is released or spilled - Sweep, shovel, vacuum with approved device. Waste Disposal Method - Dispose in accordance with Federal, State and Local regulations. SECTION VIII - SPECIAL PROTECTION INFORMATION Respiratory Protection - Approved respirators if dust generated in excess of PEL. Ventilation /Local Exhaust: Recommended to minimize dust. Special: Not applicable Mechanical (General): Not applicable Other Not applicable Protective Gloves - Recommended Eye Protection - Safety glasses Other Protective Equipment - Full protective clothing when required by fumes or dusts. SECTION IX - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing - Minimize Dust; minimize accumulation. CAUTION: The dust generated from cutting, grinding, or machining the solid material will be toxic to some degree, depending on the metal and the amount of secondary work. NOTE: This data sheet is supplied for your information only. Graphite Metallizing Corporation makes no warranties either implied or expressed and assumes no responsibility for the accuracy or completeness of the data contained herein. Material Safety Oata Sheet naquifcd under USOl Safer and Heath Refutations for Shipyard Employmenr (29CFR 19tSl 8610 U.S. Department of Labor Occupational Safety ano Health Adm*n>$irat>n October 1939 Section I________________________________________ _______________ Manufacturer i Name ALPHA CHEMICAL COMPANY_____________ _______________ Address (Number. Street. Crty. State, andZIP Code) 4809 E. Napoleon St._____ Sulphur, LA 70663 fraction II - Haiardoue Ingredients Chemical Name and Synonyms Trade Name and Synonyms Chemical Family Emergency Telephone Nyrnbe- 318) 625 7550 EDTA Tlt rant. 0.001-0.20 Molar EDTA , 2Na+ H2O Formula Paints, Preservative*, and Schrenta PignjeritS * TLV (Units) Moyt and MetaWc Costing* Base Metal % TlViUnits Catalyst Alloys Vehicle Solvents Additives MetalBc Coatings Filler Metal Plus Coating or Core Flux Others Others Hazardous Mixtures of Other Ugtrtde. totida or Gees* * TLV (Unit DiSodium EDTA + H*>o Section III - Physical Oata Soiling Point (*F) Vapor Pressure (mm Hg.) Vapor Density (A!R*1) Solubility in Wattr Appearance and Odor _______ Clear Liquid Section IV Fta and Exptoekm Heard Data Flash Point {Method Used) N/A Extinguishing Media N/A Special Fire Fighting Procedures N/A Unusual Fire and Explosion Haiads 10GC Spec/flc Gavitf 14(H20) Percent Volatile by Volume (*) Evaporation Rate 0,7(H20) Soluble Flammable Limas Lei 1.0 96-100% ->1 Uef $AL 000 6573 U "UC l `Of Conoco Material Safety Data Sheet RQ i MATERIAL IDENTIFICATION NUMBER NAME 6ASC0059 CONOCO XP-14W"SOLVENT CP0S8 CHEMICAL FAMIlt Mixed Petroleum Hydrocarbons TRADE NAMES / SYNONYMS : Paraffmic/Naphthenic Solvent CAS NUMBER NFPA RATING WHMIS CLASSIFICATION Not Applicable. 64742-47-8 Health: 0 Flammability: 2 Reactivity: 0 MANUFACTURER/DISTRIBUTOR: Conoco Inc. P,Q. Box 2197 Houston, TX GENERAL INFORMATION PHONE TRANSPORTATION EMERGENCY PHONE MEDICAL EMERGENCY PHONE 77252 1 -(713)293-5550 1-1800)424-9300 1 - (800)441-3637 OSHA HAZARD DETERMINATION Hazardous Ingredients CAS Number X Paraffinic & Naphthenic Hydrocarbons Mixture 1002 Hazardous Physical Properties: Class I 11A Comoustible Liquid, NFPA 30-1987. The material is hazardous as defined by OSHA's Hazard Communication Standard 29 CFR 1910.1200. Refer to the Regulatory Information Section of this MSDS for federal state regulatory information. and PHYSICAL DATA Boiling Point Vapor Pressure Vapor Density X volatiles Evaporation Rate Solubility m water dor Form Color Specific Gravity 350 to 460 deg F 2 mm Hg at 100 deg 6.2 (Air = 1.0) Nil Not Applicable Insoluble Hydrocarbon Liquid Clear, colorless (H20=l) 0.80-0.81 F Sal 000006574, 16-0ct-69 Conoco Material Safety Date Sheet Page 2 MSDS No*i GASCOO* CP 08$ HAZARDOUS REACTIVITY Instability ; Stable. Hazardous Composition Products: Combustion products will include carbon dioxide and possibly carbon monoxide. Conditions to Avoid: Excessive heat, flame and oxidizing materials. Hazardous Polymerization: Will not occur. FIRE AND EXPLOSION DATA Flash Point : 140 deg F Method : TCC Flammable Limits in Air, L E L : 1.0 UEL : 6.0 by Vol. FIRE AND EXPLOSION HAZARDS Class 111A Combustible Liquid (NFPA). EXTINGUISHING MEDIA Water Spray. Dry Chemical. C02. Foam. SPECIAL FIRE FIGHTING INSTRUCTIONS Special Fire Fighting Procedures: Water or foam may cause frothing. Use water to keep fire-exposed containers cool. Water spray may be used to flush spills away from exposures. Unusual Fire and Explosion Hazards: Products of combustion may contain carbon monoxide, carbon dioxide and other toxic materials. Do not enter enclosed or confined space without proper protective equioment including respiratory protection. HEALTH HAZARD INFORMATION Primary Pouters! of Exposure/Entry: Skin, inhalation. Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: Extreme exposure or aspiration into the lunqs may cause pneumonia. Overexposure may cause weakness, headache, nausea, confusion, blurred vision, drowsiness and other nervous system effects; greater exposure may cause SAL 000006575 1d-Gct-89 Conoco nittnal Safety Data Sheet imEhlTH HAZARD INFORMATION - CONTINUED) Page 3 MSDS NoI GASCOOt C PO 88 dizziness, slurred speech, flushed face, unconsciousness or convuIs ions. The proauct contains petroleum hydrocarbons and, as with many petroleum products, it may cause irritation to the eyes lungs or skin after prolonqed or repeated exposure. Studies with mice or rats have shown that some petroleum distillates have caused either damage or tumors of the kidneys or tumors of the liver. However, kidney effects were not seen m similar studies involving guinea pigs, dogs or monkeys. Also, the significance of the liver tumors in rodents is highly speculative. Carcinogenicity None of tne components in this chemical is listed by I ARC, NTP, OSHA, or ACGIH as a carcinogen. Exposure Limits for CONOCO XP-14W SOLVENT TLV PEL Other (ACGIH) (OSHA) None None PEL: Established Established Petroleum Distillates 400 ppm; 1600 mg/m3 * TLV is a registered trademark. Safety Precautions Wash thorougnlv after handling. FIRST AID inhalation If inhaled, remove to fresh air. If not respiration. If breathing is difficult, physic xan. breathing, give artificial give oxygen. Call a SKIN CONTACT In case of contact, immediately wash skin with soap and plenty of water. If irritation develops, consult a physician. EYE CONTACT In case of contact, immediately flush eyes with plenty of water fo at least 15 minutes. Call a physician. INGESTION If swallowed, do not induce vomiting. Give large Quantities of. water. Never give anything by mouth to an unconscious person. Call a physician. SAL 000006576 1 6-Oct -8<? Conoco Material Safety Data Sheet (FIRST AID - CONTINUED) Page 4. MSDS Noi GASC005- CP0 38 r' NOTES TO PHYSICIAN Gastric lavage by Qualifeo medical personnel may be considered, depending on quantity of material ingested. PROTECTION INFORMATION Generally Applicable Control Measures and Procedures Ventilation: General mechanical ventilation normally adequate. Personal Protective Equipment Respiratory Protection: Select appropriate NIOSHapproved respiratory protection where necessary to maintain exposures below the acceptable limits in the Health Hazard Information Section. Proper respiratory selection should be determined by adequately trained personnel and based on the contam inant(s), the degree of potential exposure, and published respiratory protection factors. Protective gloves: Should be worn when any potential exists for skin contact. NBR or neoprene recommended. Eve Protection: Chemical splash goggles or face shield recommended where splashing can occur. Other Protective Equioment: Sufficient to minimize skin exoosure. Coveralls with long sleeves if splashing is probaole. caunder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. SPILL, LEAK AND DISPOSAL INFORMATION Spill, Leak, or Release NOTE: Re view FIRE AND EXPLOSION HAZARDS and SAFETY PRECAUTIONS before p roceeding with clean up . Use appropriate PERSONAL PROTECT I VE EQUIPMENT during cle an up In Case of Soill or Leak: All sparks, flames and ignition sources must oe restricted from the area. Contain spill immediat ely in smallest possibl e area. Recover as much of the prod uct as possible by such methods as vacuuming, f o1 lowed by recovering residual fluids using absorbent material s. Nonrecoverable prod uct, contaminated soil. debris a nd other materials shou Id be placed in proper conta me rs for ultimate disposa 1. Avoid washing, draining or direc ting material to storm or sanitary sewers. sal oooooeirf 16-Oct"09 Conoco Material Safety Data Sheet Pago 9 MSOS NoI GASCOO! i SPILL, LEAK AND DISPOSAL 'INFORMATION CONTINUED) CP038 Maste Disposal Treatment, storage, transportation and disposal must be m accordance with applicable Federal, State/Provincial, and Local regulations. Recycle as much of the recoverable product as possible. SHIPPING INFORMATION 00 T Proper Shipping Name Not DOT regulated IATA/IMO Proper Shipping Name Not restricted STORAGE CONDITIONS Store in accordance with National Fire Protection Assn regulations. REGULATORY INFORMATION FEDERAL REGULATIONS CERCLA, 40 CFR 302 The material does not to the Act. contain ingredient!s) subject SUPERFUND AMENDMENTS AND REAUTHQRI2AT ION ACT OF 1986, TITLE III - SECTIONS 302, 304, 311, 312, 313 SECTION 302/304 - Extremely Hazardous Substances, 40 CFR 355 The material does not contain extremely hazardous substances at greater than 1.0`X concentration; however, it is possible that this material may contain extremely hazardous substances at a lower concentration so that a large enough soill could warrant an Emergency Release Report under Section 304. SECTION 311/312 - MSDS and Chemical Inventory Reporting Requirements, 40 CFR 370 The material should be reported under the following EPA hazard categories: x Immediate (Acute Health Hazard) Delayed (Chronic Health Hazard) x Fire Sudden Release of Pressure Reactive SAL 000006578 ia-Oct-09 Conoco Material Safety Data Sheet Page 6* USDS No I GASCOOS (REGULATORY INFORMATION - CONTINUED) CP0S8 Not Applicable Note: See the Hazard Determination Section for the concentration of any ingredients classified as hazardous by OSHA. SECTION 313 - List of Toxic Chemicals, 40 CFR 372 The material does not contain chemical(s) at a level of l.OK or greater (0.1X for carcinogens) on the list of Toxic Chemicals and subject to toxic chemical release reporting requirements* TOXIC SUBSTANCES CONTROL ACT (TSCA), 40 CFR 710 The material is in the TSCA Inventory of Chemical Substances (40 CFR 710) and/or is otherwise in compliance with TSCA. RESOURCE CONSERVATION AND RECOVERY ACT (RCRA), 40 CFR 261, SUBPART C AND D The material, when discarded or disposed of, is not specifically listed as a hazardous waste in Federal regulations; however, it could be considered hazardous if it meets criteria for being toxic, corrosive, igmtable or reactive according to U.S. EPA definitions (40 CFR 261). Additionally, it could be designated as hazardous according to state regulations. This material could also become a hazardous waste if it is mixed with or comes in contact with a listed hazardous waste. If such contact or mixing occurs, check 40 CFR 261 to determine whether it is a hazardous waste. If it is a hazardous waste, regulations 40 CFR 262, 263, 264 and 268 may apply. FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 116, Section 311 The material contains the following ingredlent(s) which is considered hazardous if spilled in navigable waters. Ingredient Petroleum Hydrocarbon Reportable Quantity Film or sheen upon or discoloration of the water surface or adjoining shore 1 me HAZARDOUS MATERIALS TRANSPORTATION REGULATIONS, 49 CFR 171-178 The material does not contain ingredient(s) subject to the Regulations. STATE REGULATIONS CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1906 (''PROPOSITION 65**) 000006579 S M- lfe-0ct-69 Conoco Material Safety Oata Sheet (REGULATORY INFORMATION - CONTINUED) PQ 7 MSDS No* GASCOO CP038 The material does not contain ingredient(s> subject to the Act * PENNSYLVANIA WORKER AND COMMUNITY RIGHT TO KNOW ACT To the best of our knowledge the material is not sold or produced in Pennsylvania. Please notify Conoco at the telephone number noted below if the material results in Pennsylvania commerce. ADDITIONAL INFORMATION AND REFERENCES Fire and Explosion Section revised. The above data are based on tests, experience, and other information which Conoco believes reliable and are supplied for informational purposes only. However, some ingredients may have been purchased or obtained from third-party manufactures. In these instances, Conoco, good faith, relies on information provided by those third parties. Since conditions of use are outside our control, CONOCO DISCLAIMS AN LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM USE OF THE ABOVE DATA. NOTHING CONTAINED HEREIN SHALL CONSTITUTE A GUARANTEE, WARRANT (INCLUDING WARRANTY OF M6RCHANTABILI TV) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, Tf MATERIAL DESCRIBED, OR ITS USE FOR ANY SPECIFIC PURPOSE, EVEN IF THA PURPOSE IS KNOWN TO CONOCO. Date of latest Revision Responsibility for MSDS 89/10/16 : Env, it Occ. Health Services Conoco Inc. PO Box 2197 Houston, TX 77252 713-293-5550 1 Data Sheet Emergency Medical Telephone (800) 441 -3637 LVT* 200 C P0 37 L MATERIAL IDENTIFICATION Name LVT* 200 CAS Registry Number 64742-46-7 Synonyms Paraffinic/Naphthenic Solvent Transportation Emergency Phone 1-(800) 424-9300 (Chemtrec) Chemical Family Mixed Petroleum Hydrocarbons n. OSIIA HAZARD DETERMINATION The material is hazardous as defined by OSHA's Hazard Communication Standard, 29 CFR 1910.1200. Refer to Section XI of this MSDS for other federal and state regulatory information. Hazardous Ingredients Paraffinic and Naphthenic Hydrocarbons CAS Registry Number Mixture Concentration >99% Hazardous Physical Properties None HI. PHYSICAL DATA Appearance and Odor Clear, colorless liquid; Kerosene-like odor Specific Gravity (H,0 = 1) 0.82 - 0.83 Boiling Point 430 to 550*F % Volatiles Nil Vapor Pressure 0.4 mm Hg @ 10CTF Solubility In Water Insoluble Vapor Density (Air = 1.0) 6.2 Evaporation Rate Not Applicable IV. REACTIVITY DATA Stable: X Unstable: Hazardous Decomposition Materials: Combustion products will include carbon dioxide and possibly carbon monoxide. Conditions to Avoid: Excessive heat, flame and oxidizing materials. Hazardous Polymerization: Will not occur. GASC0192/November 1989 SAL 000006581 Conoco Inc., P.O. Box 2197, Houston, TX 77252 General Information No. (713) 293-5550 C Pn 87 V. FIRE AND EXPLOSION HAZARD DATA LEL: Ui UEL: 60 Flash Point (Method used): 200F fPM) Handle and store In accordance with NFPA procedure for Class HIB Combustible Liquid. Extinguishing Media: Use water spray, dry chemical, CO* alcohol-resistant foam. Special Fire Fighting Procedures: Water or foam may cause frothing. Use water to keep fire-exposed containers cool. Water spray may be used to flush spills away from exposures. Unusual Fire and Explosion Hazards: Products of combustion may contain carbon monoxide, carbon dioxide and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Association (NFPA) Classification Health_Q_ Fire 1 Reactivity 0 VI. TRANSPORTATION AND STORAGE HAZARD RATING Least-0 Slight-1 Moderate-2 High-3 Extreme-4 Storage Conditions: Store in accordance with National Fire Protection Association regulations. Shipping Information: DOT: Not Regulated IATA/IMO: Not Restricted VII. HEALTH HAZARD INFORMATION Exposure Limits for LVT* 200 PEL: None Established TLV: None Established Exposure Limits for Petroleum Distillates PEL: 400 ppm: 1600 mg/m3 Primary Routes of Exposure/Entry; Skin, Inhalation. Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: Extreme overexposure or aspiration into the lungs may cause pneumonia. Overexposure may cause weakness, headache, nausea, confusion, blurred vision, drowsiness and other nervous system effects; greater exposure may cause dizziness, slurred speech, flushed face, unconsciousness or convulsions. The product contains petroleum hydrocarbons, and as with many petroleum products, it may cause irritation to the eyes, lungs or skin after prolonged or repeated exposure. Studies with mice or rats have shown that some petroleum distillates have caused either damage or tumors of the kidneys or tumors of the liver. However, kidney effects were not seen in similar studies involving guinea pigs, dogs or monkeys. Also, the significance of the liver tumors in rodents is highly speculative. Carcinogenicity: This material is not known to contain any chemical listed as a carcinogen or suspected carcinogen by OSHA, IARC, or NTP at a concentration greater than 0.1%. GASC0192/November 1989 2 SAL 000006582 C POST vm. EMERGENCY AND FIRST AID INFORMATION Eyes: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Call a physician. Skin: In case of contact, immediately wash skin with soap and plenty of water. If irritation develops, consult a physician. Inhalation: If Inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a physician. Ingestion: If swallowed, do not induce vomiting. Give large quantities of water. Never give anything by mouth to an unconscious person. Call a physician. Notes to Physician: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. IX. SPILL, LEAK AND DISPOSAL INFORMATION In Case of Spill or Leak: All sparks, flames and ignition sources must be restricted from the area. Contain spill immediately in smallest possible area. Recover as much of the product as possible by such methods as vacuuming, followed by recovering residual fluids by using absorbent materials. Nonrecoverable product, contaminated soil, debris and other materials should be placed in proper containers for ultimate disposal. Avoid washing, draining or directing material to storm or sanitary sewers. NOTE: Review FIRE AND EXPLOSION HAZARDS before proceeding with clean up. Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clean up. Waste Disposal Method: Recycle as much of the recoverable product as possible. Treatment, storage, transportation and disposal must be in accordance with applicable Federal, State/Provincial, and Local regulations. X. PRECAUTIONARY MEASURES Respiratory Protection: Select appropriate NIOSH*approved respiratory protection where necessary to maintain exposures below the acceptable limits in Section VII. Proper respirator selection should be determined by adequately trained personnel and based on the contaminant(s), the degree of potential exposure and published respiratory protection factors. VentUation: General mechanical ventilation normally adequate. Protective Gloves: Should be worn when any potential exists for prolonged or repeated skin contact Neoprene or vinyl recommended. Eye Protection: Chemical splash goggles or face shield recommended where splashing can occur. Other Protective Equipment: Sufficient to minimize skin exposure. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. XI. REGULATORY INFORMATION FEDERAL REGULATIONS CERCLA, 40 CFR 302 Not Applicable GASC0192/November 1989 3 SAL 000006583 CP037 SUPERFUND AMENDMENTS AND REAUTHOR1ZATION ACT OF 1986, TITLE HI SECTIONS 302, 304, 311, 312, 313 SECTION 302/304 - Extremely Hazardous Substances (40 CFR 355) The material does not contain extremely hazardous substances at greater than 1.0% concentration; however, it is possible that this material may contain extremely hazardous substances at a lower concentration so that a large enough spill could warrant an Emergency Release Report under Section 304. SECTION 311/312 - MSDS and Chemical Inventory Reporting Requirements (40 CFR 370) The material should be reported under the following EPA hazard categories: x Immediate (Acute) Health Hazard __ Delayed (Chronic) Health Hazard __ Fire __ Sudden Release of Pressure __ Reactive __ Not Applicable NOTE: See Section II for the concentration of any ingredients classified as hazardous by OSHA. SECTION 313 * List of Toxic Chemicals (40 CFR 372) The material does not contain chemicals at a level of 1.0% or greater (0.1% for carcinogens) on the list of Toxic Chemicals and subject to toxic chemical release reporting requirements. TOXIC SUBSTANCES CONTROL ACT (TSCA), 40 CFR 710 This material is in the TSCA Inventory of Chemical Substances (40 CFR 710) and/or is otherwise in compliance with TSCA RESOURCE CONSERVATION AND RECOVERY ACT (RCRA), 40 CFR 261, SUBPART C AND D The material, when discarded or disposed of, is not specifically listed as a hazardous waste in Federal regulations; however, it coukl be considered hazardous if it meets criteria for being toxic, corrosive, ignitable or reactive according to the U.S. EPA definitions (40 CFR 261). Additionally, it could be designated as hazardous according to state regulations. This material could also become a hazardous waste if it is mixed with or comes in contact with a listed hazardous waste. If such contact or mixing occurs, check 40 CFR 261 to determine whether it is a hazardous waste. If it is a hazardous waste, regulations 40 CFR 262, 263, 264 and 268 may apply. FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 116.4A, SECTION 311 The materia] contains the following ingredients) which is considered hazardous if spilled in navigable waters. Ingredient Petroleum Hydrocarbon Reportable Quantity Film or sheen upon or discoloration of the water surface or adjoining shoreline HAZARDOUS MATERIALS TRANSPORTATION REGULATIONS, 49 CFR 171-178 Not Applicable STATE REGULATIONS CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986 ("PROPOSITION 65*) The material does not contain ingrcdient(s) subject to the Act GASC0192/November 1989 4 0000065SM- CP037 PENNSYLVANIA WORKER AND COMMUNITY RIGHT TO KNOW ACT The material contains the following hazardous substances: Categories: S *= Special Hazardous Substance (2 0.01%) H * Hazardous Substance 1.0%) E = Environmental Hazard ( 1.0%) Ingredient Petroleum Distillates CAS Registry Number Mixture Category H Nonhazardous ingredients) information is withheld as a trade secret in accordance with Section 11 of the Act MSDS Code: GASC0192 DATE OF LATEST REVISION/REVIEW: DEPARTMENT RESPONSIBLE FOR MSDS: PRODUCT INFORMATION CONTACT: 11/89 - Replaces MSDS dated 6/89 Safety, Occupational Health & Environmental Affairs Hazard Communication Analyst Conoco Inc (713) 293-5550 The above data are based on tests, experience, and other information which Conoco believes reliable and are supplied for informational purposes only. However, some ingredients may have been purchased or obtained from third-party manufacturers. In these instances, Conoco, in good faith relies on information provided by those third parties. Since conditions of use are outside our control, CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA. NOTHING CONTAINED HEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE MATERIAL DESCRIBED, OR ITS USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. GASC0192/November 1989 5 SAL 000006585 MATERIAL SAFETY DATA SHEET MEGA OUXCKSTIR HARDNER RAGE : Ol <056873-0362* -50O699O3-0S HROER)|OATE OF ISSUE ! 09/01/69 SUPERSEDES 05/14/67 SECTION I - GENERAL INFORMATION j: :r .A %4 CHEMICAL NAME & SYNONYMS N/A TRADE NAME & SYNONYMS MEGA 0U1CKSTJR HARDNER CHEMICAL FAMILY N/A FORMULA X<--MIXTURE MANUFACTURERS NAME: X-ERGON. A PARTSMASTER CO. DJV OF NCH ADDRESS (NUMBER. STREET. CITY. STATE 6 2IP CODE) BOX 152170 IRVING, TEXAS 75015 PREPARED BY: ROBERT P. RHOME/T.S.CHEM PROOUCT CODE NUMBER OS HRDER EMERGENCY TELEPHONE NUMBER 214-438*1381 CrS6 12 SECTION II- HAZARDOUS INGREDIENTS THE HAZARDS PRESENTED BELOW ARE THOSE OF THE INDIVIDUAL COMPONENTS AS THE PROOUCT MIXTURE HAS NOT BEEN TESTED AS A WHOLE. CHEMICAL NAME (INGREDIENTS) ! HAZARD PHENOL 2.4.6 TRI (CIMETHYLAMINCMETHYL) N/A N/A PHENOL I TLV" 5PPM N/A 1 PEL* 5PPM N/A ! cas* 108-95-2 90-T2-2 SECTION III - PHYSICAL DATA BOILING PT.(FAHRENHEIT) |N/A | SPEC GRAVITY (H20-1) : 1.44 (CONTINUED) MEGA GUICKSTIR HAftDNcR SECTION III - PHYSICAL DATA VAPOR PRESSURE (MM HG). VAPOR DENSITY (AIR-1) PH * 100% PERCENT. VOLATILE BY VOLUME (%) SOLUBILITY IN WATER VISCOSITY {<0.1 |< AIR | COLOR | ODOR N/A N/A {N/A | CLARITY N/A jNIL 1 | t | SLIGHT EVAPORATION RATE (BU AC - 1 ) ! N/A {SLOWER 1 aGE : 02 SECTION IV - FIRE AND EXPLOSION HAZARD FLASH POINT (METHOD USED) >250.0 FTAG ! FLAMMABLE LIMITS *N/A ! LEL |n/a In/a EXTINGUISHING MEDIA ALCOHOL* X< --FOAM <--FOAM X<--C02 DRY X<--CHEMICAL WATER <--sprav <--OTHER SPECIAL FIRE FIGHTING PROCEDURES WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING. USE WATER TO COOL EXPOSED CONTAINERS. WATER STREAM DIRECTED INTO FIRE MAY CAUSE FROTHING WITH SUBSEQUENT SPREAD OF FIRE. UNUSUAL FIRE & EXPLOSION HAZARDS IRRITATING AND/OR TOXIC GASES OR FUMES MAY BE GENERATED BY THERMAL DE COMPOSITION OR C0M8USTI ON. CLOSED CONTAINERS MAY RUPTURE OR EXPLODE (DUE TD PRESSURE BUILD-UP) WHEN EXPOSED TO EXTREME HEAT. NFPt HAZARD RATING (O-1NSIGNIFI CANT: 1-SLI GMT:2-MODCRATE;3-HIGH:4-EXTREME) : 1 <--HEALTH 1 <--FLAMMABILITY 0 <--REatI VITY <--SPECIAL SECTION V - HEALTH HAZARD OATA THRESHOLD LIMIT VALUE N/A EFFECTS OF OVEREXPOSURE - ACUTE - (SHORT TERM EXPOSURE) EYES: SEVERE IRRITANT. MAY CAUSE PERMANENT CORNEAL INJURY. SKIN: SEVERE IRRITANT. CORROSIVE MAY CAUSE CHEMICAL BURNS AND BLISTER REPEATED OR PR0L0N6E0 OVEREXPOSURE May CAUSE SENS IT12AT ION. MAY BE ABSORBED IN HARMFUL AMOUNTS. SAL 000006586 ^ i ! r , \ - . i 111--i Q < CONTINUED) SECTION V HEALTH HAZARD DATA PAGE INHALATION- MAT CAUSE IRRITATION OF RESPIRATORY TRACT. OVEREXPOSURE MAY CAUSE HEAOACHE: NAUSEA? AND VOMITING. MATERIAL ASPIRATED INTO LUNGS MAY CAUSE CHEMICAL PNEUMONITIS. INGESTION: MAY CAUSE IRRITATION/BURNS OF MOUTH, THROAT. AND STOMACH. SYMPTOMS INCLUDE NAUSEA. ABDOMINAL PAIN AND POSSIBLE COLLAPSE. SLIGHTLY TOXIC.PREEXISTING PULMONARY AND DERMATOLOGICAL DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO HAZARDOUS COMPONENTS. - CHRONIC - (LONG TERM EXPOSURE) NONE OTHER THAN THOSE NOTED ON ACUTE. PRIMARY ROUTE OF ENTRY INHALATION <- INGESTION <- ABSORPTION EMERGENCY ft FIRST AIO PROCEDURES INHALATION : REMOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. ADMINISTER ARTIFICIAL RESPIRATION IF NOT BREATHING. OBTAIN MEDICAL ATTENTION. EYE CONTACT: FLUSH WITH PLENTY OF WATER AT LEAST 15 MINUTES. OBTAIN IMMEDIATE MEDICAL ATTENTION. SKIN CONTACT: ,, REMOVE CONTAMINATED CLOTHING. WASH AFFECTED AREA(S) THOROUGHLY WITH SOAP AND WATER. CONSULT A PHYSICIAN. INGESTION : DO NOT INDUCE VOMITTING. GIVE WATER OR MILD IF VICTIM IS CONSCIOUS AND NOT OROWSY. SHOULD VOMITTING OCCUR. BE SURE TO KEEP VICTIM'S HEAD BELOW HIPS TO AVOID ASPIRATION OF VOMITU5 INTO THE LUNGS. OBTAIN IMMEDIATE MEDICAL ATTENTION. N/A NOTES TO PHYSICIAN w SECTION VI - TOXICITY INFORMATION PRODUCT CONTAINS CHEMICAL LISTED AS CARCINOGEN OR POTENTIAL CARCINOGEN BY: IARC <-- YES X < - * NO NTP <-YES OSHA X<--NC <-- YES ACGIH <-- YES OTHER X<-- NO X<--NO <-- YES X<--NO N/A SECTION Vll - REACTIVITY DATA STABILITY Jx<--STABLE <--UNSTAEL i CONDUCTIONS TO AVOIO "sources of IGNITION . (CONTINUED) MESA QU1CKST1R HARDNER SECTION Vtl - REACTIVITY DATA INCOMPATIBILITY (MATERIALS TO AVOID) STRONG BASES OR OXIDANTS. STRON LEWIS OR MINERAL ACIDS. HAZARDOUS DECOMPOSITION PRODUCTS ACRID SMOKE. OXIDES OF CARBON. HAZARDOUS POLYMERIZATION WILL NOT <-*OCCUR MAY <--OCCUR } CONDITIONS TO AVOID PAGE : 04 SECTION VIII - SPILL OR LEAK PROCEDURES STEPS TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED VENTILATE AREA. WEAR APPROPRIATE PROTECTIVE EOUlPMENT DURING CLEANUP. ELIMINATE SOURCES OF IGNITION. SHUT OFF SOURCE OF LEAK IF SAFE TO DO SO. DIKE OR CONTAIN SPILL. ABSORB WITH INERT MATERIAL. SWEEP OR SHOVEL INTO CONTAINERS WITH LIDS. COVER LOOSELY AND STORE IN A WELL-VENTILATED AREA UNTIL DISPOSAL. WASH SPILL AREA WITH SOAP ANO WATER. WASTE DISPOSAL METHOD REVIEW ALL LOCAL. STATE. AND FEDERAL REGULATIONS CONCERNING HEALTH ANO POLLUTION FOR APPROPRIATE DISPOSAL PROCEDURES. NEUTRALIZING AGENT N/A SECTION IX - SPECIAL PROTECTION INFORMATION REQUIRED VENTILATION LOCAL EXHAUST AS NEEDED TO CONTROL VAPOR/DUST LEVELS TO BELOW RECOMMENDED LIMITS. RESPIRATORY PROTECTION IF THE TLV IS EXCEEOEO. IF USE IS PERFORMED IN A POORLY VENTILATED CONFINED SPACE Oft AREA WITH LIMITED VENTILATION. USE N1 OSH-APPROVEO RESPIRATOR IN ACCORDANCE WITH 29 CFR 1910 134 USE N 3 OSH-APPROVED RESPIRATOR FOR OUSTS ANC MISTS WHEN GRINDING OR MACHINING CURED COMPOUND USE SELF-CONTAINED BREATHING APPARATUS IF MATERIAL IS TO BE SPRAYED OR WHEN BURNING OUT CURED EPOXY. PROTECTIVE GLOVES IMPERVIOUS RUBBER. SAL 000006587 (CONTINUED) EYE PROTECTION CHEMICAL SAFETY GOGGLES. SECTION IX 1MEGA QU CKSTIR HABDNER SPECIAL PROTECTION INFORMATIOPAGE : 05 GS6 12 OTHER PROTECTION ACCESSIBLE EYE WASH ANO SAFETY SHOWER. CLEAN PROTECTIVE CLOTHING. SECTION X - STORAGE ANO HANDLING INFORMATION STORAGE TEMPERATURE oooooo< *-MAX oooooo-*min ! INDOOR ! | HEATED PRECAUTIONS TO BE TAKEN IN HANDLING & STORING FOR INDUSTRIAL USE ONLY. DO NOT TAKE INTERNALLY. AVOID CONTACT WITH EYES. SKIN, ANO CLOTHING. AVOID BREATHING VAPOR/DUST/MIST WASH THOROUGHLY AFTER HANOLING TIGHTLY RESEAL ALL PARTIALLY USED CONTAINERS. OTHER PRECAUTIONS |REFRIGERATED j OUTDOOR 1I SECTION XI - REGULATORY INFORMATION CHEMICAL NAME C.A.S. NUMBER UPPER % LIMIT PHENOL 106-95-2 0.004 THOSE INGREDIENTS LISTED ABOVE ARE SUBJECT TO THE REPORTING REQUIREMENTS OF 319 OF TITLE III OF THE SUPERFUNC AMENDMENTS ANO REAUTHOR IZAT1 ON ACT OF 1986 ANO 40 CFR PART 372. IF UE (USE EXEMPTION) APPEARS UNDER UPPER % LIMIT, END USERS ARE EXEMPT FROM NOTIFICATION BECAUSE THE PRODUCT IS USED ANC LABELED FOR ROUTINE JANITORIAL WORK, OR THE PRODUCT IS USEO AND LABELED FOR FACILITY GROUNDS MAINTENANCE (SUCH AS FERTILIZERS AND HERBICIDES). OR THE PRODUCT IS USED AND LABELED FOR MAINTAINING MOTOR VEHICLES. SECTION XII - TRANSPORTATION (FOR FUTURE USE) APPLICABLE REGULATIONS <--49 CFR <--JMCC SHIPPING NAME <--TARIFF 6 D <--IATA <-- MlLITARY AIR (APR 71-4) ( MEGA QUICKSTIR HARDN'gR (CONTINUED) SECTION XII - TRANSPORTATION - (FOR FUTURE USE) PAGE : 06 HAZARD CLASS ! IC NUMBER | REPORT QTY LABELS ! LIMITED QTY UNIT CONTAINER DOT SPS CONTAINER | NET EXPLOSIVE WT . AEROSOL PRQPELLANT(S) N/A SECTION XIII - REFERENCES THE INFORMATION CONTAINED HEREIN IS 8ASED ON DATA CONSIDERED ACCURATE IN LIGHT OF CURRENT FORMULATION. HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THIS DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF. X-ERGON. A PARTSMASTER CO.. DIV OF NCH ASSUMES NO RESPONSIBILITY FOR PERSONAL INJURY OR PROPERTY DAMAGE CAUSED BY THE USE , STORAGE OR CISPOSAL OF THE PRODUCT IN A MANNER NOT RECOMMENDED ON THE PROOUCT LABEL. USERS ASSUME ALL RISKS ASSOCIATED WITH SUCH UNRECOMMENDED USE. STORAGE. OR DISPOSAL OF THE PRODUCT. SAL 000006588 BETZ LABORATORIES,INC. 4636 SOMERTOH ROAD, TREVOSE, PA. 19047 BETZ MATERIAL SAFeA DATA SHEET G S6 18 24 HOUR EMERGENCY TELEPHONE (HEALTH OR ACCIDENT) 215/355-3300 PRODUCT ; POWERLINE 2280 (PAGE 1 OF 3) EFFECTIVE DATE 02-27-89 PRINTED: 23-Mar-1989 REV:SEC.1 PRODUCT APPLICATION : FUEL TREATMENT ---------- SECTION 1------------------------- HAZARDOUS INGREDIENTS----------------------------------INFORMATION ON PHYSICAL HAZARDS, HEALTH HAZARDS, PEL'S AND TLV'S FOR SPECIFIC PRODUCT INGREDIENTS AS REQUIRED BY THE OSHA HAZARD COMMUNICATIONS STANDARD IS LISTED. REFER TO SECTION 4 (PAGE 2) FOR OUR ASSESSMENT OF THE POTENTIAL ACUTE AND CHRONIC HAZARDS OF THIS FORMULATION. MONOETHANOLAMINE(ETHANOIAMINE)***CAS#141-43-5/COMBUSTIBLE/CORROSIVE/ IRRITANT;PEL/TLV:3PPM(6PPM-STEL) TRIETHYLENETETRAMINE** *[1,2-ETHANEDIAMINE,N,N-BIS(2-AMINOETHYL) ] ; CAS#112-24-3;CORROSIVE;POTENTIAL REPRODUCTIVE TOXIN?PEL:NONE?TLV:NONE. SECTION 2------------------------ TYPICAL PHYSICAL DATA PH: AS IS (APPROX.) 12.2 FL.PT.(DEG.F): >200 SETA(CC) VAPOR PRESSURE (irunHG) : 26 Vise cps70F: 6.6 EVAP.RATE: <1 ETHER*1 PHYSICAL STATE: LIQUID ODOR: NONE SP.GR.(70F)OR DENSITY: 1.015 VAPOR DENSITY(AIR"1)J >1 %SOLUBILITY(WATER): 100 APPEARANCE: COLORLESS FREEZE POINT(DEG.F): 5 SECTION 3------------------------ REACTIVITY DATA STABLE THERMAL DECOMPOSITION (DESTRUCTIVE FIRES) YIELDS ELEMENTAL OXIDES. SAL 000006589 BETZ MATKRTAT. SAFETY DATA SHEET (PAGE 2 OF 3) PRODUCT: POWERLINE 2280 EFFECTIVE DATE 02-27-89 -----------SECTION 4------------------------- HEALTH HAZARD EFFECTS--------- ----------------------------------------- ACUTE SKIN EFFECTS *** PRIMARY IJOUTE OF EXPOSURE SEVERE IRRITANT TO THE SKIN.ABSORBED BY *SKIN.SKIN SENSITIZER. ACUTE EYE EFFECTS *** G S6 13 CORROSIVE TO THE EYES ACUTE RESPIRATORY EFFECTS *** PRIMARY ROUTE OF EXPOSURE VAPORS,GASES,MISTS AND/OR AEROSOLS CAUSE IRRITATION TO UPPER RESPIRATORY TRACT CHRONIC EFFECTS OF OVEREXPOSURE* * * PROLONGED OR REPEATED OVEREXPOSURES MAY CAUSE LIVER AND KIDNEY TOXICITY,MAY CAUSE REPRODUCTIVE SYSTEM TOXICITY,OR MAY CAUSE PRIMARY IRRITANT DERMATITIS. MEDICAL CONDITIONS AGGRAVATED *** NOT KNOWN SYMPTOMS OF EXPOSURE *** INHALATION MAY CAUSE IRRITATION OF MUCOUS MEMBRANES AND RESPIRATORY TRACT; SKIN CONTACT CAUSES SEVERE IRRITATION OR BURNS. PRECAUTIONARY STATEMENT BASED ON TESTING RESULTS *** MAY BE TOXIC IF ABSORBED THROUGH SKIN OR INHALED. -----------SECTION 5--------------------------- FIRST AID INSTRUCTIONS------------------------------------------------SKIN CONTACT*** REMOVE CONTAMINATED CLOTHING.WASH EXPOSED AREA WITH A LARGE QUANTITY OF SOAP SOLUTION OR WATER FOR 15 MINUTES EYE CONTACT*** IMMEDIATELY FLUSH EYES WITH WATER FOR 15 MINUTES.IMMEDIATELY CONTACT A PHYSICIAN FOR ADDITIONAL TREATMENT INHALATION EXPOSURE*** REMOVE VICTIM FROM CONTAMINATED AREA TO FRESH AIR.APPLY APPROPRIATE FIRST AID TREATMENT AS NECESSARY INGESTION*** DO NOT FEED ANYTHING BY MOUTH TO AN UNCONSCIOUS OR CONVULSIVE VICTIM DO NOT INDUCE VOMITING.IMMED.CONTACT PHYSICIAN.DILUTE CONTENTS OF STOMACH USING 3-4 GLASSES MILK OR WATER ---------- SECTION 6------------------------- SPILL, DISPOSAL AND FIRE INSTRUCTIONS-------------------SPILL INSTRUCTIONS*** VENTILATE AREA,USE SPECIFIED PROTECTIVE EQUIPMENT.CONTAIN AND ABSORB ON ABSORBENT MATERIAL.PLACE IN WASTE DISPOSAL CONTAINER. THE WASTE CHARACTERISTICS OF THE ABSORBED MATERIAL,OR ANY CONTAMINATED SOIL, SHOULD BE DETERMINED IN ACCORDANCE WITH RCRA REGULATIONS. FLUSH AREA WITH WATER. WET AREA MAY BE SLIPPERY. SPREAD SAND/GRIT. DISPOSAL INSTRUCTIONS*** WATER CONTAMINATED WITH THIS PRODUCT MAY BE SENT TO A SANITARY SEWER TREATMENT FACILITY,IN ACCORDANCE WITH ANY LOCAL AGREEMENT,A PERMITTED WASTE TREATMENT FACILITY OR DISCHARGED UNDER A NPDES PERMIT PRODUCT(AS IS>- INCINERATE OR BURY IN APPROVED LANDFILL FIRE EXTINGUISHING INSTRUCTIONS*** FIREFIGHTERS SHOULD WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS(FULL FACE-PIECE TYPE). DRY CHEMICAL,CARBON DIOXIDE,FOAM OR WATER SAL 000006590 BETZ MATERIAL SAFETY DATA SHEET (PAGE 3 OF 3) PRODUCT: POWERLINE 2280 EFFECTIVE DATE 02-27-89 '---------- SECTION 7------------------------- SPECIAL PROTECTIVE EQUIPMENT--------------------------------------- USE PROTECTIVE EQUIPMENT IN ACCORDANCE WITH 29CFR SECTION 1910.132-134. USE RESPIRATORS WITHIN USE LIMITATIONS OR ELSE -USE SUPPLIED AIR RESPIRATORS. VENTILATION PROTECTION*** ADEQUATE VENTILATION TO MAINTAIN AIR CONTAMINANTS BELOW EXPOSURE LIMITS RECOMMENDED RESPIRATORY PROTECTION*** IF VENTILATION IS INADEQUATE OR SIGNIFICANT PRODUCT EXPOSURE IS LIKELY, USE A RESPIRATOR WITH ORGANIC VAPOR CARTRIDGES. RECOMMENDED SKIN PROTECTION*** GAUNTLET-TYPE NEOPRENE GLOVES,CHEMICAL RESISTANT APRON G S6 18 WASH OFF AFTER EACH USE.REPLACE AS NECESSARY RECOMMENDED EYE PROTECTION*** SPLASH PROOF CHEMICAL GOGGLES.FACE SHIELD ---------- SECTION 8-------------------- --STORAGE AND HANDLING PRECAUTIONS-----------------------------STORAGE INSTRUCTIONS*** KEEP DRUMS & PAILS CLOSED WHEN NOT IN USE. PROTECT FROM FREEZING HANDLING INSTRUCTIONS*** GENERAL-IMMEDIATELY REMOVE CONTAMINATED CLOTHING,WASH BEFORE REUSE SPECIFIC- ALKALINE.CORROSIVE TO EYES.DO NOT MIX WITH ACIDIC MATERIAL. A************************************************************************* THIS MSDS COMPLIES WITH THE OSHA HAZARD COMMUNICATION STANDARD HAROLD M. HERSH (ENVIRONMENTAL INFORMATION COORDINATOR) aaaaaaaaa-aaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaa APPENDIX: REGULATORY INFORMATION THE CONTENT OF THIS APPENDIX REPRESENTS INFORMATION KNOWN TO BETZ ON THE EFFECTIVE DATE OF THIS MSDS. THIS INFORMATION IS BELIEVED TO BE ACCURATE. ANY CHANGES IN REGULATIONS WILL RESULT IN UPDATED VERSIONS OF THIS DOCUMENT. ...TSCA: ALL COMPONENTS OF THIS PRODUCT ARE LISTED IN THE TSCA INVENTORY ...REPORTABLE QUANTITY(RQ) FOR UNDILUTED PRODUCT: NOT APPLICABLE ...RCRA: IF THIS PRODUCT IS DISCARDED AS A WASTE,THE RCRA HAZARDOUS WASTE IDENTIFICATION NUMBER IS: DQ02=CORROSIVE ...DOT HAZARD CLASSIFICATION: NOT APPLICABLE ...DOT SHIPPING DESIGNATION IS: NOT APPLICABLE ...THIS PRODUCT CONTAINS THESE CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER OR REPRODUCTIVE TOXICITY: NONE PRESENT IN SIGNIFICANT AMOUNTS ...SARA SECTION 302 CHEMICALS: NONE PRESENT IN SIGNIFICANT AMOUNTS ...SARA SECTION 313 CHEMICALS: NONE PRESENT IN SIGNIFICANT AMOUNTS ...SARA SECTION 312 HAZARD CLASS: IMMEDIATE(ACUTE) AND DELAYED(CHRONIC) ...MICHIGAN CRITICAL MATERIALS: NONE PRESENT IN SIGNIFICANT AMOUNTS MFPA/HMIS : HEALTH - 3 ,* FIRE - 1 7 REACTIVITY - 0 7 SPECIAL - ALK ; PE - D SAL 00006591 PI348 MATERIAL SAFETY DATA SHEET MONOSOD IUM PHOSPHATE 30* G S 4 22 PC 1 REVISION OF: 12*14-89 MAIL TO: 45000382 CONOCO INC REFINING P O BOX 37 WESTLAKE LA 70669 ORDER NO: 420715751 PROD NO: 04173372 VAN WATERS & ROGERS INC. # SUBSIDIARY OF UNIVAR 1600 NORTON BLDG. SEATTLE, WA 98104-1564 (408) 435-8700 ----------------------------------------------------------- EMERGENCY ASSISTANCE----------------------------------------------------------------- FOR EMERGENCY ASSISTANCE INVOLVING CHEMICALS CALL CHEMTREC <800)424-9300 ------------------------------------------------FOR PRODUCT AND SALES INFORMATION---------------------------------------------- CONTACT YOUR LOCAL VAN WATERS & ROGERS BRANCH OFFICE --------------------------------------------------------- PRODUCT IDENTIFICATION--------------------------------------------------------------- PRODUCT NAME: MONOSODIUM PHOSPHATE COMMON NAMES/SYNQNYMS: SODIUM PHOSPHATE, MONOBASIC. ANHYDROUS; PHOSPHORIC ACID, MONOSODIUM SALT CAS NO.: 7558-80-7 ANHYDROUS 10049-21-5 HYDRATE VW&R CODE: P1348 FORMULA: NA H2 P04 HAZARD RATING (MANUFACTURER) DATE ISSUED: 08/89 SUPERCEDES: 07/89 HEALTH: 0 FIRE: O REACTIVITY: O SPECIAL: NONE HAZARD RATING SCALE; "MINIMAL 3"SERI0US 1"SLIGHT 4"SEVERE 2=MQDERATE -HAZARDOUS INGREDIENTS- COMPONENT CAS NO. MONOSODIUM PHOSPHATE 7558-80-7 EXPOSURE LIMITS, PPM OSHA ACGIH OTHER * PEL TLV LIMIT >99 NONE NONE NONE HAZARD NONE PHYSICAL PROPERTIES- BOILING POINT, DEG F: N/A VAPOR PRESSURE, MM HG/20 DEG C: MELTING POINT, DEG F: LOSES VAPOR DENSITY <AIR"1>: WATER, 356 SPECIFIC GRAVITY (WATER*!): 1.0 WATER SOLUBILITY, X: BULK DENSITY APPEARANCE AND ODOR: NO EVAPORATION RATE (BUTYL ACETATE=1>: ODOR, WHITE GRANULES OR POWDER N/A N/A 48 NIL FIRST AID MEASURES- IF INHALED: REMOVE TO FRESH AIR. GIVE ARTIFICIAL RESPIRATION IF NOT BREATHING. GET IMMEDIATE MEDICAL ATTENTION. IN CASE OF EYE CONTACT: IMMEDIATELY FLUSH EYES WITH LOTS OF RUNNING WATER FOR 15 MINUTES, LIFTING THE UPPER AND LOWER EYELIDS OCCASIONALLY. GET IMMEDIATE MEDICAL ATTENTION. PROD: 04173372 01:29:23 05 JAN 1990 CUST: 45000382 INVOICE: 420715751 SAL 000006592 P1348 MATERIAL SAFETY DATA SHEET MONOSODIUM PHOSPHATE 30X G S4 22 PQ 2 REVISION OF: 12-14-09 IN CASE OF SKIN CONTACT: RINSE WITH WATER. IF SWALLOWED: GIVE WATER TO DILUTE. COMFORT. MEDICAL ATTENTION IN CASE OF DIS ------------------------------------------------------ HEALTH HAZARD INFORMATION---------------------------------------------------------- PRIMARY ROUTES OF EXPOSURE: INHALATION* SKIN OR EYE CONTACT. SIGNS AND SYMPTOMS OF EXPOSURE INHALATION: BREATHING DUST MAY IRRITATE THE NOSE AND THROAT AND CAUSE COUGHING AND CHEST DISCOMFORT. EYE CONTACT: DUSTS MAY IRRITATE THE EYES. SKIN CONTACT: NONE CURRENTLY KNOWN. SWALLOWED: SWALLOWING LARGE QUANTITIES MAY CAUSE NAUSEA AND VOMITING. CHRONIC EFFECTS OF EXPOSURE: NO SPECIFIC INFORMATION AVAILABLE. MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: NONE REPORTED. -------------------------------------------------------------------- TOXICITY DATA------------------------------------------------------------------------- ORAL: RAT LD50 = 7, 100 MG/KG DERMAL: RABBIT > 7*940 MG/KG INHALATION: NO DATA FOUND CARCINOGENICITY: THIS MATERIAL IS NOT CONSIDERED TO BE A CARCINOGEN BY THE NATIONAL TOXICOLOGY PROGRAM, THE INTERNATIONAL AGENCY FOR RESEARCH ON CANCER, OR THE OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION OTHER DATA: NONE -----------------------------------------------------------PERSONAL PROTECTION-------------------------------------------------------------------- VENTILATION: LOCAL MECHANICAL EXHAUST VENTILATION CAPABLE OF MAIN TAINING DUST EMISSIONS AT THE POINT OF USE BELOW THE PEL. RESPIRATORY PROTECTION: A RESPIRATOR IS NORMALLY NOT REQUIRED IF THIS PRODUCT IS USED WITH ADEQUATE VENTILATION. EYE PROTECTION: SAFETY GLASSES WITH SIDE SHIELDS. IT IS GENERALLY RECOGNIZED THAT CONTACT LENSES SHOULD NOT BE WORN WHEN WORKING WITH CHEMICALS BECAUSE CONTACT LENSES MAY CONTRIBUTE TO THE SEVERITY OF AN EYE INJURY. PROTECTIVE CLOTHING: LONG-SLEEVED SHIRT, TROUSERS, SAFETY SHOES, AND GLOVES. OTHER PROTECTIVE MEASURES: AN EYEWASH AND SAFETY SHOWER SHOULD BE NEARBY AND READY FOR USE. -----------------------------------------------FIRE AND EXPLOSION INFORMATION----------------------------------------------------- FLASH POINT, DEG F: N/A FLAMMABLE LIMITS IN AIR, X METHOD USED: N/A LOWER: N/A UPPER: N/A EXTINGUISHING MEDIA: THIS MATERIAL IS NOT COMBUSTIBLE. USE EXTIN GUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE. SPECIAL FIRE FIGHTING PROCEDURES: NONE. UNUSUAL FIRE AND EXPLOSION HAZARDS: NONE. ---------------------------------------------------------- HAZARDOUS REACTIVITY----------------------------------------------------------------- STABILITY: STABLE POLYMERIZATION: WILL NOT OCCUR PROD: 04173372 01:29:23 05 JAN 1990 CUST: 45000382 INVOICE 420715751 *L 000n^ p1348 HATERIAL SAFETY MONOSODIUM PHOSPHATE 30% ` PG 3 REVISION OF:12-14-09 CONDITIONS TO AVOID: NONE MATERIALS TO AVOID: NONE INDICATED. HAZARDOUS DECOMPOSITION PRODUCTS: NONE INDICATED. -----------------------------------------SPILL. LEAK, AND DISPOSAL PROCEDURES---------------------------------------------- ACTION TO TAKE FOR SPILLS OR LEAKS: WEAR PROTECTIVE EQUIPMENT INCLUDING RUBBER BOOTS, RUBBER GLOVES, RUBBER APRON, AND A FULL FACEPIECE OR A HALF MASK AIR-PURIFYING CARTRIDGE RESPIRATOR WITH PARTICULATE FILTERS. WEAR CHEMICAL GOGGLES IF A HALF MASK IS WORN. FOR SMALL SPILLS, SWEEP UP AND DISPOSE OF IN DOT-APPROVED WASTE CONTAINERS. FOR LARGE SPILLS, SHOVEL INTO DOT-APPROVED WASTE CONTAINERS. KEEP OUT OF SEWERS, STORM DRAINS. SURFACE WATERS, AND SOIL. COMPLY WITH ALL APPLICABLE GOVERNMENTAL REGULATIONS ON SPILL REPORTING, AND HANDLING AND DISPOSAL OF WASTE. DISPOSAL METHODS: DISPOSE OF CONTAMINATED PRODUCT AND MATERIALS USED IN CLEANING UP SPILLS OR LEAKS IN A MANNER APPROVED FOR THIS MATERIAL. CONSULT APPROPRIATE FEDERAL. STATE AND LOCAL REGULATORY AGENCIES TO ASCERTAIN PROPER DISPOSAL PROCEDURES. NOTE: EMPTY CONTAINERS CAN HAVE RESIDUES, GASES AND MISTS AND ARE SUBJECT TO PROPER WASTE DISPOSAL, AS ABOVE. ----------------------------------------------------------- SPECIAL PRECAUTIONS------------------------------------------------------------------- STORAGE AND HANDLING PRECAUTIONS: STORE IN A COOL, DRY, WELL-VENTILATED PLACE AWAY FROM INCOMPATIBLE MATERIALS. KEEP BAGS OR FIBER DRUMS DRY AT ALL TIMES. WASH THOROUGHLY AFTER HANDLING. DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING. REPAIR AND MAINTENANCE PRECAUTIONS: NONE. qTHER PRECAUTIONS: CONTAINERS, EVEN THOSE THAT HAVE BEEN EMPTIED, WILL RETAIN PRODUCT RESIDUE AND VAPORS. ALWAYS OBEY HAZARD WARNINGS AND HANDLE EMPTY CONTAINERS AS IF THEY WERE FULL. FOR ADDITIONAL INFORMATION- CONTACT MSDS COORDINATOR, VAN WATERS & ROGERS INC. DURING BUSINESS HOURS, PACIFIC TIME (408)435-8700 -OTHER REGULATORY INFORMATION- THIS PRODUCT CONTAINS THE FOLLOWING CHEMICAL(S) CONSIDERED BY THE STATE OF CALIFORNIA'S SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986 (PROPOSITION 65) AS CAUSING CANCER OR REPRODUCTIVE TOXICITY AND FOR WHICH WARNINGS ARE NOW REQUIRED: CHEMICAL CAS NO. %, WT ARSENIC CADMIUM LEAD NOTICE- 7440-38-2 7440-43-9 7439-92-1 TRACE TRACE TRACE **VAN WATERS & ROGERS INC. <"VW*tR"> EXPRESSLY DISCLAIMS ALL EXPRESS OR IMPLIED WARRANTIES OF MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE, WITH RESPECT TO THE PRODUCT OR INFORMATION PROVIDED HEREIN.** ALL INFORMATION APPEARING HEREIN IS BASED UPON DATA OBTAINED FROM THE MANUFACTURER AND/OR RECOGNIZED TECHNICAL SOURCES. WHILE THE INFORMA TION IS BELIEVED TO BE ACCURATE, VW&R MAKES NO REPRESENTATIONS AS TO ITS ACCURACY OR SUFFICIENCY. CONDITIONS OF USE ARE BEYOND VW&R'S CON TROL AND THEREFORE USERS ARE RESPONSIBLE TO VERIFY THIS DATA UNDER THEIR OWN OPERATING CONDITIONS TO DETERMINE WHETHER THE PRODUCT IS SUITABLE FOR THEIR PARTICULAR PURPOSES AND THEY ASSUME ALL RISKS OF THEIR USE, HANDLING, AND DISPOSAL OF THE PRODUCT, OR FROM THE PUBLICA TION OR USE OF, OR RELIANCE UPON, INFORMATION CONTAINED HEREIN. THIS PROD: 04173372 01:29:23 05 JAN 1990 OUST: 4500031 SAL 000006594 3715751 PI 348 MATERIAL SAFETY DATA SHEET MONOSODIUM PHOSPHATE 30% G S 4 22 PG 4 REVISION OF:12-14-09 INFORMATION RELATES ONLY TO THE PRODUCT DESIGNATED HEREIN* AND DOES NOT RELATE TO ITS USE IN COMBINATION WITH ANY OTHER MATERIAL OR IN ANY OTHER PROCESS. ------------------------------------------------------------------- REVISION------------------------------------------------------------------------------ 12/89: ADDED ANOTHER CAS FOR THE HYDRATE. **** END OF MSDS **** PROD: 04173372 01:29:23 05 JAN 1990 GUST: 45000382 INVOICE: 420713751 oo TEXACO INC. INDUSTRIAL HYGIENE. TOXICOLOGY. AND MATERIAL SAFETY DATA SHEET NOTE NO REPRESENTATION IS MADE AS TO THE ACCURACY OF Th INFORMATION HEREIN. SEE PAGE 7 FOR CONDITIONS UNDER WHICH DATA ARE FURNIShSl- Trsde Name and Synonyms 70203 MORPHOLINE GS226 DISTRIBUTED BY Manufacturer's Name Texaco Chemical Company Emergency Tel (409)>722 S_ JAa wucffa> Address 4800 Fournace Place .0. Box 430 Bellaire. TX 77401 715 PATCH STREET SULPHUR, 1A 700G3 Chemical Name and/or Famify^or Description PHONE: (318) 527-5077 Horohol ine___________** 1----------- ' - * ------------------------------------------------- ------------ 1-000-027-50tt THIS PRODUCT IS CLASSIFIED A$:. * NOT HAZARDOUS: y 1 2459 A HAZARDOUS BY BEFfrJITIf**' - ON ATTACHED EXPLANATION SHEETS WARNING STATEMENT*". - DANGER! FLAMMABLE CAUSES SEVERE EYE L SKIN BURNS & KAY CAUSE BLINDNESS HARMFUL IF SWALLOWED; MAY FORM SUSPECTED CANCER- CAUSING N1TR0SAMINES IF MIXED WITH NITRITES OCCUPATIONAL CONTROL PROCEDURES Protective Equipment (Type) Eyes: Chemical type goggles with face shield must be worn. contact lenses. Do not wear When handling large quantities subject to splashes and spills, impervious suits, gloves and rubber boots must be worn. Inhalation: Ventilation: Supplied air respiratory protection for cleaning large spills or upon entry into tanks, vessels, or other confined spaces. Local exhaust ventilation recommended Permissible Concentrations: Ain 20 ppm (70 mg/cubic meter) 8 hr. TWA (ACGIH 1986*87) ACCIH skin, see Add. Cmts. Pg.6. 20 ppm 0SHA Permissible Exposure Limit (PEL) 'irst Aid Eyes: Skin Ingestion: Flush thoroughly with water for at least fifteen minutes.Get immediate medical attention. If drenched, remove contaminated clothing under safety shower and flood exposed areas with water. Get immediate medical attent on. Wash clothing before reuse. Destroy contaminated shoes. Do NOT induce vomiting. Give large quantities of water. Cal a doctor. Inhalation; Other Instructions: Remove to fresh air; if not breathing apply artificial respira tion.Get medical attention.Keep affected person warm and at rest None. N.D, - Not Determined N.A. - Not Applicable SAL 000006596 ***** @ Effects of Exposure Acute: Eyes: Believed to be extremely irritating with possible permanent eye injury. Vapor may cause transient corneal edema (hazy vision) Skin: Corrosive; expected to cause severe skin damage with burns and blistering. Toxic effects due to skin absorption possible* Respiratory System- Hay cause irritation of upper respiratory tract. Chronic: Two-year inhalation oncogenic study negative in rats. Other. Sensitization Properties: Skim Yes----- No -- Unknown JL Respiratory. Yes ____ No____ Unknown Median Lethal Dose (LDM LC 50 HSpecies) __________________ 1.05 g/ka (rat); moderately toxic Inhalation .... - Dermal ---------------------Other ----------------------- no deaths (rat).12.000 com 8 hr: revers. respiratory tract injury .500 g/ka (rabbit): moderately toxic_____________________________________ N. D. - ____ ____ ______ Irritation Index. Estimation of irritation (Species) Skin _Believed to be 6.6-8.0/8.0 (rabbit): corrosive EyesBelieved to be 80-110/110 (rabbit): extremely irritating Comments Ignition Temp. F: Flammable Limits (%) Lower 1 *8 Flash Point F. (Method) Upper 10.8 95r Products Evolved When Subjected to Heat or Combustion: Ammonia, carbon monoxide, and carbon dioxide may be formed on burning in limited air supply. Recommended Fire Extinguishing Agents And Special Procedures: According to the NFPA Guide 325M, water soluble, flammable liquid fires may be extinguished by dry chemical, foam, or carbon dioxide. Water may be ineffective on flames, but should be used to keep fire-exposed containers cool. If a leak or spill has not ignited, use water spray to disperse the vapors and to provide protection for persons attempting to stop the leak. Unusual or Explosive Hazards: Explosive air-vapor mixtures may form. SAL 000006597 ND. - Not Determined N.A. - Not Applicable 8226 Waste Disposal Method Re-evaluation of the product say be required by the user at the tine of disposal, since the product uses, transformations, mixtures and processes may change classification to non-hazardous * or hazardous for reasons other than, or in addition to ignitability. (See Remarks for Waste Classification.) Procedures in Case of Breakage or Leakage: (Transportation Spills Call CHEMTREC (BOO) 424-9300) Eliminate all ignition sources including internal combustion eng* ines and power tools. Ventilate area. Avoid breathing vapor. Use SCBA or supplied-air mask for lg spills or in confined areas.Con* tain spi11.Remove with inert absorbent.Avoid all personal contact Waste Classification: Product (as presently constituted) has the RCRA characteristic of ignitability and if discarded in its purchased form would have the hazardous waste number D001. PRECAUTIONS DANGER! FLAMMABLE CAUSES SEVERE EYE & SKIN BURNS & MAY CAUSE BLINDNESS HARMFUL IF SWALLOWED; MAY FORM SUSPECTED CANCER CAUSING NlTROSAMINES IF MIXED WfTH NITRITES Do not get in eyes, on skin or clothing, keep away from heat, sparks and flame. Avoid breathing vapor or mist Keep container dosed. Use only in well-ventilated locations. Wash thoroughly after handling. Requirements for Transportation. Handling and Storage: Transport, handle and store in accordance with OSHA Regulation 1910. 106 and applicable DOT regulations. DOT Proper Shipping Name: Morpholine DOT Hazard Class (if applicable): Flammable liq. UN2054/Corros. CHEMICAL AND PHYSICAL PROPERTIES Boiling Point PF) 265 Vapor Pressure...^--. --.......... IMSbI (mmHg) Specific Gravity ,, 1 PQl? (H^Q= 1) Vapor Density--3r Q (Air-1) Appearance and Odor___ c tear , co 1 or 1 es s J.iq. .ammonia odor_____________________________________ pH of undiluted product 11.2 Percent Volatile by Volume 100 Viscosity 2.23 cP 1 20_C Solubility Apprec Evaporation ^ D Other _. ( ----- _ )=1 Hazardous Polymerizations---------------- Occur -2L. - Do not occur The Material Reacts Violently With: (If others is checked below, see additional comments on page 6 for futher details Air Water Heat Strong Oxidizers Others None of These - XX VJ.D. - Not Determined - ] ,,,, Thin N.A. - Not Applicable -- Th,,, n SAL 000006598 GS226 ^ Chemical/Common Name CAS No. Exposure Limit Range in X Morpholine y 110918 20pp ACGIH (SKIN) 20ppa 0SHA (SKIN) 30ppm STEL (SKIN) 100.00 Hazardous according to OSHA (1910.1200) or one or more state Right~To~Know lists. I. Title III Section 302/304 Extremely Hazardous Substance Component CAS No. NONE % RQ (Lbs) TPQ (Lbs) II. CERCLA Section 102(a) Hazardous Substance Component NONE CAS No. % RQ (Lbs) ill. Title Ml Section 311 Hazard Categorization Acute Chrome X IV. Title III Section 313 Toxic Chemicals Component NONE Fire X Pressure CAS No. Reactive % Not Applicable SAL 000006599 Cr 82 26 70203 MORPHOLINE DANGER! FLAMMABLE CAUSES SEVERE EYE & SKIN BURNS & MAY CAUSE BLINDNESS HARMFUL IF SWALLOWED; MAY FORM SUSPECTED CANCERCAUSING NITROSAMINES IF MIXED WITH NITRITES Do not get in eyes, on skin or clothing. Keep away from heat, sparks and flame. Avoid breathing vapor or mist. Keep container closed. Use only in well-ventilated locations. Wash thoroughly after handling. In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Call a doctor. Wash clothing before reuse. Destroy contaminated shoes. If swallowed, DO NOT induce vomiting. Call a doctor. Never give anything by mouth to-an unconscious person. In case of fire use foam, dry chemical or C02. Use water spray to keep containers cool. ! emical/Common Name CAS No. Range in X Morpholine 110918 100.00 y Hazardous according to OSHA (1910.1200) or one or more state Right-To-Know lists. HMIS Health : 3 Reactivity : 0 Flammability: 3 Special :- DOT Proper Shipping Name: Morpholine DOT Hazardous Class : Flammable liq. UN2054/Corros. CAUTION: Misuse of empty containers can be hazardous. Empty containers can be hazardous if used to store toxic, flammable, or reactive materials. Cutting or welding of empty containers might cause fire, explosion or toxic fumes from residues. Do not pressurize or expose to open flame or heat Keep container closed and drum bungs in place. HEALTH EMERGENCY TELEPHONE: (9141 831-3400 (EXT. 204) Texaco Inc. 2000 Westchester Avenue White Plains, New York 10650 For Additional Information Concerning: Fuels/Lubricants/Anti freezes call (914) 631-3400 (EXT.204) Chemicals call IS121 459-6543 Transportation Spills call CHEMTREC (800) 424-9300 000006600 c V 8226 STATE OF MICHIGAN CRITICAL MATERIALS ACT (REVISED 1988) No critical materials present. DO NOT USE sodium nitrite or other nitrosating agents in formulations containing this product. Suspected cancer-causing nitrosamines could be formed. Aquatic toxicity rating: TLM-96 HRS - 100-1000 PPM; practically NON-TOXIC. ACGIH "SKIN" NOTATIONappropriate measures should be taken to prevent cutaneous absorption since the TLV is based on overexposure to the mucous membranes. Like many aliphatic amines,this product is not extensively biodegraded under laboratory conditions of the five day test. Reacts violently with acids. SAL 000006601 To determine applicability or effect of any law or regulation with respect to the product, users should consult his legal advisor or the appropriate government agency. Texaco does not undertake to furnish advice on such matters. F. E. Bentley By - 04-19-88 Date New Title Coordinator of Product Safety Q Revised. Supersedes 10 14 8 7 N.D. Not Determined N.A. - Not Applicable MATERIAL SAFETY OATA SHEET EM SCIENCE PREPARATION DATE ..................... .. A DIVISION OF EM INDUSTRIES HI WOOOCR65T INFORMATION PHCNE NUMBER.: CHERRY HILL* N*J 06034-0395 (609) 354-9200 CHEMTREC EMERGENCY NUMBER: 1-000-424-9300 MAY 26* *66 6S557 J NFPA HAZARD RATINGS I I HEALTH : 2 FLAMMABILITY : 0 I REACTIVITY : 0 SPECIAL HAZAROS.: CATALOG NUMBER(S): 6647 6639 CHEMICAL NAME. TRADE NAME....................: C.A.S. NUMBER....: CHEMICAL FAMILY..: FORMULA. ........................ MOLECULAR WEIGHT.: DOT SHIPPING NAME: DOT NUMBER....................: SECTION I - GENERAL INFORMATION SX0759 SX0760 SX0761 SODIUM SULFATE* ANHYDROUS SALT CAKES OISODIUM SULFATE 7757-82-6 INORGANIC SALT NA2S04 142.04 (NON-REGULATED) (NONE) SX0763 SX0765 SECTION II - HAZARDOUS INGREDIENTS NONE OTHER THAN SPECIFIED PROOUCT. SECTION III- PHYSICAL DATA BOILING POINT (C 760 MM HG).: N/A MELTING POINT (C).............................. : 888C SPECIFIC GRAVITY(H2Q = 1)... 2.671 VAPOR PRESSURE..(MM HG)............. N/A 20C PERCENT VOLATILE BY VOL <%). N/A VAPOR DENSITY <AIR = I)................... N/A EVAPORATION RATE (6UAC=I)... N/A SOLUBILITY IN WATER (%}... 21 APPEARANCE AND ODOR WHITE CRYSTALLINE GRANULES MSDS-SX0759 OR POWDER PAGE U : 01 SAL 000006602 GS5 57 SECTION IV - FIRE C EXPLOSION FLASH POINT ........................... : NONCOHBUST IBLE FLAMMABLE LIMITS LEL N/A FLAMMABLE LIMITS UEL *: N/A EXTINGUISHING MEDIA...*: ANY SUITABLE FOR ADJACENT MATERIAL FIRE FIGHTING PROC.............: WEAR SELF-CONTAINED BREATHING APPARATUS FIRE EXPL. HAZARDS...: EMITS TOXIC FUMES ON THERMAL DECOMPOSITION HAZARD DATA SECTION V - HEALTH HAZARD DATA (ACUTE AND CHRONIC) ACGIH TLV/OSHA PEL (TWA)..................... NONE ESTA8LI SHED TOXICITY DATA................................. ............... ORL-MUS LD50 : 5989 MG/KG SYMPTOMS OF EXPOSURE ............. .....: -MAY BE IRRITATING TO EYES SKIN* NASAL AND RESPIRATORY PASSAGES MAY BE HARMFUL IF SWALLOWED MEDICAL COND. AGGRAVATED BY EXP: DATA NOT AVA ILABLE. ROUTES OF ENTRY. . . .......................... INHALATION* INGESTION CARCINOGENICITY........................................... .. THE MATERIAL IS NOT LISTED AS A CANCER CAU SING AGENT. EMERGENCY FIRST AID........................... : GET MEDICAL ASSISTANCE FOR ALL CASES OF OV EREXPOSURE SKIN: WASH THOROUGHLY WITH SOAP AND WATER EYES: IMMEDIATELY FLUSH THOROUGHLY WITH WA TER FOR AT LEAST 15 MINUTES DUST INHALATION: REMOVE TO FRESH AIR INGESTION: IF CONSCIOUS* INOUCE VOMITING SECTION VI - REACTIVITY STABILITY............................................ .. YES CONDITIONS TO AVOID ............ : NONE INDICATED MATERIALS TO AVOID.................. .. ( ) WATER ( ) BASES ( ) CORROSIVES ( ) OXIDIZERS (X) OTHER: ALUMINUM < HEAT) HAZARDOUS POLYMERIZATION.: DOES NOT OCCUR HAZARDOUS DECOMPOSITION..: SOX* NAZO ( DATA ) ACIDS ( SECTION VII - ENVIRONMENTAL PROTECTION PROCEDURES SPILL RESPONSE: -TAKE UP AND CONTAINERIZE FOR PROPER DISPOSAL FLUSH AREA WITH WATER WASTE DISPOSAL: TO BE PERFORMED IN COMPLIANCE WITH ALL CURRENT STATE AND FEDERAL REGULATIONS. LOCAL* SECTION VIII - SPECIAL PROTECTION INFORMATION MSDS-SX0759 PAGE # : 02 SAL 000006603 e S557 VENTILATION* RESPIRATORY PROTECTION* PROTECTIVE CLOTHING* EYE PROTECTION -MATERIAL SHOULD BE HANDLED OR TRANSFERRED IN AN APPROVED FUME HOOD OR WITH ADEQUATE VENTILATION PROTECTIVE GLOVES (NEOPRENE* PVC OR EQUIVALENT) SHOULO BE MORN TO PREVENT SKIN CONTACT SAFETY GLASSES WITH SIDE SHIELOS SHOULO BE WORN AT ALL TIMES SECTION IX - SPECIAL PROTECTION INFORMATION HANDLING C STORAGE : -KEEP CONTAINER CLOSED STORE AT CONTROLLED ROOM TEMPERATURE 00 NOT BREATHE DUST DO NOT GET IN EYES AVOID PROLONGED OR REPEATED SKIN CONTACT WORK/HYGIENIC PRACTICES: WASH THOROUGHLY AFTER HANDLING* 00 NOT TAKE INTERNALLY. EYE WASH AND SAFETY EQUIPMENT SHOULD BE REAOILY AVAILABLE SECTION X - OTHER INFORMATION COMMENTS........................................ .. TESTS ON LABORATORY ANIMALS INDICATE MATERIAL MAY PRODUCE ADVERSE REPRODUCTIVE EFFECTS REVISION HISTORY........................ : 09/01/81* 2/84* 1/24/87* 10/27/87 N/A * NOT AVAILABLE: MS0S-SX0759 PAGE * : 03 SAL 000006604 IDi 105181960 Page 1 of 4 MATERIAL SAFETY DATA SHEET One Oak Way Issue Date: 11/02/89 Berkeley Heights, NJ 07922-2727 issue Number: 2 Emergency Telephone # (201) 736-6066 Supercedes Date* 07/07/89 Non-Emergency Telephone # (201) 771-4644 Reason for Re-Issue; UPDATE I. PRODUCT IDENTIFICATION. Product Name: FLEXGEL Chemical Name/Synonym* CABLE FILLING COMPOUND Product Code/Comcode: 105181960 HMDS Number: 6671 Label Codes Health* O-NON-TOXIC Fire* 1-MILDLY COMBUSTIBLE Reactivity* 0-NON-REACTIVE II. HAZARDOUS INGREDIENTS. Component: CAS # % TLV(ACGIH) PEL(OSHA) POLYETHYLENE COPOLYMER ------- < 10 N.D. N.D. SEVERELY SOLVENT REFINED HEAVY PARAFFINIC PETROLEUM OIL 64741-88-4 < 90 5 MG/M3 MIST 5 MG/M3 OIL MIST COMMENTS* THE INFORMATION PRESENTED IN THIS MSDS PERTAINS TO ALL CABLE PRODUCTS CONTAINING FLEXGEL. TO IDENTIFY CABLES CONTAINING FLEXGEL SEE CABLE CODES LISTED IN THE PRECAUTIONARY LABEL SPACE OF THIS MSDS UNDER SECTION X SPECIAL PRECAUTIONS. III. PHYSICAL PROPERTIES. Appearance/Odor; YELLOW RUBBER-LIKE MATERIAL WITH NEARLY NO ODOR. Specific Gravity: .87 Vapor Density (Air=l): > 14 Boiling Point* N.D. Melting Points 196 F Vapor-Pressure: NIL mm Hg at 20 C Solubility in Water: INSOLUBLE Evaporation Rate (ET-ETHER55!): .0002pHs N/A % Volatiles by Volume: NONE IV. HEALTH HAZARD SUMMARY, PRIMARY ROUTES OF EXPOSURE. ORAL* SKIN: X EYE: INHALATION: Effects of Overexposure: NONE EXPECTED WHEN EXPOSURE IS BY INHALATION, SKIN, OR INGESTION. EYE CONTACT MAY CAUSE TEMPORARY IRRITATION. NO PERMANENT DAMAGE EXPECTED. SAL 000006605 ato" IDs 105181960 Page 2 of 4 0 6 S 6 07 Listed as a Carcinogen or Potential Carcinogen By the Following Agencies? NTP) NO IARC: NO OSHAi NO Toxicity Study Informations THE TOXICOLOGICAL PROPERTIES OP THIS MATERIAL MAY NOT BE POLLY EVALUATED# PLEXGEL - PRACTICALLY NON-TOXIC WHEN INGESTEDj LD50 > 15 G/KG. V. FIRST AID PROCEDURES. Eyes PLUSH WITH WATER. IP IRRITATION PERSISTS, OBTAIN MEDICAL ATTENTION. Skins NOT EXPECTED TO BE A PROBLEM. WIPE OFF SKIN AND WASH WITH SOAP AND WATER inhalatlon:NOT expected to BE A problem. Ingestions GIVE LIQUIDS AND INDUCE VOMITING UNLESS VICTIM IS UNCONSCIOUS. OBTAIN MEDICAL ASSISTANCE. SMALL AMOUNTS WHICH ACCIDENTALLY ENTER MOUTH SHOULD BE RINSED OUT UNTIL TASTE IS GONE. Notea to Physicians NONE VI. FIRE AND EXPLOSION HAZARD DATA. Flash Points 420 F by Flammable Limits: LEL: N.D. % Autoignition Temps N.D. UELs N.D. t Extinguishing Media: DRY CHEMICAL, CARBON DIOXIDE, FOAM. Special Firefighting Proceduress WEAR SELF CONTAINED BREATHING APPARATUS WHEN FIGHTING FIRE IN CONFINED SPACE. Unusual Fire and Explosion Hazards: NONE VII. REACTIVITY DATA. stability: STABLE Conditions to Avoids OPEN FLAMES, EXPOSURE TO EXCESSIVE HEAT OR OTHER IGNITION SOURCES * Incompatibility (Materials to Avoid): NONE Hazardous Decomposition Products: THERMAL DECOMPOSITION MAY PRODUCE CARBON MONOXIDE, CARBON DIOXIDE. SAL 000006606 ART ID: 105161960 Page 3 of 4 Hazardous Polymerisations WILL NOT OCCUR Conditions to Avoids NONE Cr S 6 0 7 VIII. SPECIAL PROTECTION INFORMATION. Ventilations GENERAL VENTILATION SHOULD BE ADEQUATE. Respiratory Protections RESPIRATORS ARE NOT REQUIRED. Protective Gloves: GLOVES ARE NOT REQUIRED, Eye Protections SAFETY GLASSES ARE RECOMMENDED. Other Clothing and/or Equipments NONE NORMALLY REQUIRED. IX. ENVIRONMENTAL INFORMATION. Steps to be Taken in Case Material is Released or Spilled: ABSORB WITH VERMICULITE, CLAY, OR SIMILAR MATERIAL. PICK UP MATERIAL AND PLACE IN CONTAINER FOR DISPOSAL. Waste Disposal Method: DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE LOCAL, STATE, AND FEDERAL RULES AND REGULATIONS. INCINERATION MAY BE BEST METHOD OF DISPOSAL, TSCA Status: ALL COMPONENTS APPEAR ON THE TSCA CHEMICAL SUBSTANCE INVENTORY X. SPECIAL PRECAUTIONS. Storage and Handling Requirements: USE GOOD PERSONAL HYGIENE WHEN WORKING WITH THIS MATERIAL, Precautionary Label CABLES WITH THE FOLLOWING CABLE CODES CONTAIN FLEXGEL: CODES WITH PREFIXES KA, KG, WG, AND WA FOLLOWED BY 2JR, 4JR, 9JR, 2WR, 4WR, 9WR, 2AR, 4AR, 9AR AND PREFIXES WG AND WA FOLLOWED BY 6JR, 6WR, AND 6AR. PREFIX BDW FOLLOWED BY 3/22-C, 2/19-C, 2/19-FCC, 3/19-GRF, 2/22-GRF, 3/22-FCC, SEB-2/22, 2/19-GRF, AND PREFIX BSW FOLLOWED BY 2/22-FCC, 5/22-FCC, 2/22-C, 5/22-C. ALL CABLE CODES WITH THE FOLLOWING PREFIXES CONTAIN FLEXGEL: AFAW, AFAWUM, AFAY, AFBW, AFBWUM, AFMW, AFMWUM, AFMY, AFTW, AFTWUM, MFMWUM, AFTY, KFAW, KFAWUM, KGAW, KGAWUM, MFMW, MFMWUM, CGAW, CGAWUM. v1 IDs 105181960 Page 4 of 4 6 S 6 07 ND. Not Determined*N/A = Not Applicable. While information in this fact sheet has been compiled from reference materials and other sources believed.to be relia ble, its accuracy and completeness is not guaranteed, nor is any responsibility assumed or implied for any loss or damage resulting from inaccuracies or ommlssions. Any specific evaluation will involve professional judgement by the user's industrial hygiene personnel. SAL 000006608 UnitedCatalysts Inc. Girdler and CCt Cata-ysts Pott Offic# Box 32370 Louisville. Kentucky 40252 Telephone 502-634-7200 Tetex 204190.204239 Facsimile 502-637-3732 MATERIAL SAFETY DATA SHEET NN--239 SECTION Z PRODUCT IDENTIFICATION Trade Name and Synonyms Chemical Family Inorganic N-239 Formula AlaOi+CoO+LazOa+MoOs SECTION II HAZARDOUS INGREDIENTS Hazardous Components in the Solid Mixture COMPONENT CAS No. % Aluminum oxide Cobalt oxide Lanthanum oxide Molybdenum trioxide 1344-28-1 1304-96-6 1312-81-8 1313-27-5 80-90 1-5 1-5 10-15 OSHA/PEL ACGIH/TLV 10.0 mg/m3 0.05 mg/m3 *NIA 10.0 mg/m 0.05 mg/m *NIA 10.0 mg/m3 10.0 mg/m SECTION III PHYSICAL DATA Appearance and Odor: Blue extrusions. No odor. Melting Point: Greater than 800C, greater than 1450F. Solubility in Water: Insoluble. Bulk Density: 37 lbs./cu. ft. Percent Volatile by Weight at 1000*F: Less than 5%. 8ECTION IV FIRE EXPLOSION DATA Fire and Explosion Hazard Negligible fire and explosion hazard when exposed to heat or flame by reaction with incompatible substances. SAL 000006609 Updated: September 6, 1989 Page 1 UnitedCatalysts Inc. Girdter end CCI Catalysis CAO 47 MATERIAL SAFETY DATA SHEET Flash Point Nonflammable. Firefighting Media Dry chemical, water spray, or foam* For larger fires, use water spray fog or foam. Firefighting Nonflammable solids, liquids or gases: Cool containers that are exposed to flames with water from the side until well, after fire is out. For massive fire in enclosed area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. Withdraw immediately in case of rising sound from venting safety device or any discoloration of the tank due to fire. SECTION V HEALTH HAZARD DATA Health hazards may arise from inhalation, ingestion, and/or contact with the skin and/or eyes. Alumina particles deposited in the eye may cause necrosis of the cornea. Ingestion may cause stomach and intestinal distress. Salts of alumina may cause dermatoses, eczema, conjunctivitis, and irritation of the mucous membranes of the upper respiratory tract. Prolonged inhalation of alumina dust may result in pneumoconiosis. Lung damage (Shaver/s Disease) may result from inhalation of finely divided aluminum oxide particles; it is complicated by silica and oxides of iron in the inhaled air. Excessive inhalation of cobalt may cause irritation of the respiratory tract; asthma-like symptoms with cough, dyspnea, chest tightness and wheezing? lung damage; and pneumoconiosis. Ingestion may produce nausea and vomiting, diarrhea, and sensation of hotness. Chronic ingestion may cause blood abnormalities (polycythemia), increased clotting time, hyperplasia of the bone marrow and thyroid gland, cardiomyopathy, and damage to the pancreas in sensitive individuals, prolonged or repeated contact with the skin, in the . absence of proper hygienic practices may result in dryness, irritation and/or an allergic dermatitis. Contact with the eye may cause redness, irritation, and/or conjunctivitis. Research data on cobalt and cobalt compounds based on animal injection studies indicates that cobalt may be a possible carcinogen SAL 000006610 Updated: September 6, 1989 Page 2 4| UnitedCatalysts Inc. Girdtor and CCI Catalysts _ _^ C A 0 47 MATERIAL SAFETY DATA SHEET N2$a9 Cobalt oxide reacts violently with hydrogen peroxide. Lanthanum dust is a serious fire hazard when exposed to flame; it can react vigorously with oxidizing materials. Reacts violently with nitric acid, phosphorus (above 400*C), air, and halogens. Dust is moderately explosive when exposed to flame or by chemical reaction. Incompatible with Ha, C, N, B, Se, si, and S. Molybdenum trioxide explodes on contact with molten magnesium. Reacts violently with interhalogens (e.g., bromine pentafluoride, chlorine trifluoride). Incandescent reaction with hot sodium, potassium, or lithium. Emits toxic fumes of molybdenum when heated to decomposition. ` SECTION VII SPILL OR LEAK PROCEDURES Notify safety personnel of spills or leaks. Clean-up personnel need protection against inhalation of dusts or fumes. Eye protection is required. Vacuuming and/or wet methods of cleanup are preferred. Place in appropriate containers for disposal, keeping airborne particulates at a minimum. Disposal Consult applicable local, state, and federal regulations to select the method of disposal. Recover metal components by reprocessing whenever possible. SECTION VIII SPECIAL PROTECTION INFORMATION Respiratory Protection Provide a NIOSH/MSHA jointly approved respirator in the absence of proper environmental control. Contact your safety equipment supplier for proper mask type. Ventilation Provide general and/or local exhaust ventilation to keep exposures below the TLV. Ventilation used must be designed to prevent spots of dust accumulation or recycling of dusts. Protective clothing Wear protective clothing, including long sleeves and gloves, to prevent repeated or prolonged skin contact. Eye Protection Chemical splash goggles designed in compliance with OSHA regulations are recommended. Consult your safety equipment supplier. SAL 000006612 % IMedCatalysts Inc. Ginger and CCI Catalysts 0 A 0 47 MATERIAL C'FETY DATA SHEET Prolonged excessive inhalation of lanthanum may result in pneumonitis or granuloma of the lung. Lanthanum may cause delayed blood clotting, leading to hemorrhages. Overexposure may lead to hemoglobineraia. Symptoms of exposure are chills, fever, headache, muscle pains, abdominal cramps, nausea, malaise, and hemobloginurea. Skin contact, in the absence of proper hygienic practices, may result in irritation and skin granulomas. Eye contact may cause irritation and/or conjunctivitis. Molybdenum trioxide may cause irritation of the eyes and mucous membranes. Prolonged, excessive inhalation may affect the liver, kidneys, and red blood cells; cause hypothyroidism; and/or produce molybdenum-induced gout. Ingestion of excessive amounts may produce signs of copper deficiency. First Aid (Inhalation) Remove to fresh air immediately. If breathing has artificial respiration. Keep affected person warm medical attention immediately. stopped, give and at rest. Get First Aid (Ingestion) If large amounts have been ingested, give emetics to cause vomiting. Stomach siphon may be applied as well. Milk and fatty acids should be avoided. Get medical attention immediately. First Aid (Eyes) Wash eyes immediately and carefully for 30 minutes with running water, lifting upper and lower eyelids occasionally. Get prompt medical attention. First Aid (Skin) To avoid repeated or prolonged contact with this chemical, use good hygienic practices. Wash with soap and a large amount of water. Get medical attention if irritation or inflammation develops. SECTION VI REACTIVITY DATA - Reactivity Is stable under normal temperatures and pressures in sealed containers. Hazardous polymerization will not occur. Finely divided particles may result in fire or explosion. Aluminum oxide is incompatible with hot chlorinated rubber. Exothermic reaction above 200C with halocarbon vapors produces toxic HCl and phosgene. 0q 06 TT owKnr C. 1 QUO  UnitedCatalysts Inc. Girdler and CCI Catalyst* _ C A 0 47 MATERIAL SAFETY DATA SHEET N- 239 IARC Monographs on the Evaluation of Carcinogenic Risks to Humans: Silica and Some silicates. Volume 42, Lyon, World Health Organization, International Agency for Research on Cancer, 1987. Kentucky Occupational Safety and Health Standards for General Industry, 29 CFR Part 910 as adopted by 803 KAR 2:020 with Amendments as of July 31, 1986, Promulgated by Occupational Safety and Health Administration, U.S. Department of Labor, Kentucky. Occupational Safety and. Health Program, Kentucky Labor^Cabinet, Commerce Clearing House, Inc., Chicago 1986. Occupational Diseases, A Guide to their Recognition, 0. S. Department of Health, Education, and -Welfare, Public Health Service, Center for Disease Control, NIOSH, Revised Edition, 1977. June Patty's Industrial Hygiene and Toxicology, Clayton, G.D., Clayton, F.E., eds., John Wiley and Sons, New York, 3rd Edition, Volume 2, A-C, 1981. TLVsR Threshold Limit Values and Biological Exposure Indices for 1988-1989, American Conference of Governmental Industrial Hygienists, Cincinnati, OH, 1988. MSDS's from Suppliers of Raw Materials. SECTION XI The information presented herein is believed to be accurate but is not warranted. Recipients are advised to confirm in advance that the information is current and applicable to meet their circumstances. * No Information Available Doc. 115 SAL 000006614- UnitedCatalysis Inc. Girdier and CCt Catalysts _ C A 0 47 MATERIAL SAFETY DATA SHEET n N-239 SECTION IX REGULATORY INFORMATION This product contains substances which appear on lists of the indicated act or agency. XX American Conference of Governmental Industrial Hygienists (ACGIH) Threshold Limit Values for Chemical Substances in the Work Environment ___ California Proposition 65 ___ Clean Air Act 40 CFR 61 ___ Clean Water Act 40 CFR 116 ___ Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA) 40 CFR 302 ___ International Agency for Research on Cancer (IARC) Monographs on the Evaluation of Carcinogenic Risks to Humans Volumes 1-42. ___ NTP Annual Report on Carcinogens XX Occupational Safety and Health Administration (OSHA) 29 CFR 1910 ___ Resource Conservation and Recovery Act (RCRA) 40 CFR 261 Subpart C XX Superfund Amendments and Reauthorization Act of 1986' (SARA) Title III Section 313 40 CFR 372 XX Toxic Substances Control Act (TSCA) 40 CFR 700 SECTION X BIBLIOGRAPHY -Clinical Toxicology of Commercial Products, Fifth Edition-, Gosselin, Smith, Hodge, Williams and Wilkins, Baltimore, 1984. Dangerous Properties of Industrial Materials, Sax, N. Irving, ed.. Van Nostrand Reinhold Company, New York, 7th Edition, 1989. IARC Monographs on the Evaluation of Carcinogenic Risks to Humans, Overall Evaluations of Carcinogenicity; An Updating of IARC Monographs, Volumes 1-42, Lyon: World Health Organization, International Agency for Research on Cancer, 1987. SAL 000006613 Confcwhor . 1989 Page 5 28-5ep-89 Conoco Material Safety Data Sheet C I 04 5 Page 1 MATERIAL IDENTIFICATION NUMBER NAME : IPBC0020 : CASINGHEAD GASOLINE CHEMICAL FAMILY : Petroleum Hydrocarbons TRADE NAMES / SYNONYMS i Straight Run Gasoline NFPA RATING WHMIS CLASSIFICATION Not Applicable. : Health: 1 Flammability: 3 Reactivity: O : MANUFACTURER/DISTRIBUTOR: Conoco Inc. P.O. Box 2197 Houston, TX 77252 GENERAL INFORMATION PHONE : 1 -(713)293-5550 TRANSPORTATION EMERGENCY PHONE : 1-(BuO)424-9300 MEDICAL EMERGENCY PHONE : 1-(800)441-3637 **4*****t*******'*t#**********t**444**t**4t***4***** OSHA HAZARD DETERMINATION Hazardous Ingredients CAS Number Hydrocarbons (Aromatic & Paraffinic) Benzene 71*43-2 Regulated as a toxic chemical under section 313 of Title III of The Superfund Amendments and Reauthor 12 ation Act of 1986 and 40 CFR part 372. Hazardous Physical Properties: Class IA Flammable Liquid per NFPA Code No. 30-1987. The material is hazardous as defined by QSHA's Hazard Communication Standard, 29 CFR 1910.1200. **444*444*<**444#*t>*44*ft*t444***t****4f*4**444* PHYSICAL DATA Vapor Pressure Vapor Density Solubility in Water F o rm Color APi G rav11y Distillation Range : 15-20 PSI (? 100 deg F : Not Applicable : Slightly soluble : Liquid : Colorless : 70-90 : 70-300 deg F 000006615 SM- C I 04 5 L'O Sep Lot-oco MaUnal Safety Data Sheet Page 2 MSDS No: IPbCo.*fc HAZARDOUS REACTIVITY Instability : Stable. Hazardous Decomposition Products: Oxides of carbon, incomplete combustion may produce carbon monoxide. Conditions to Avoid: Oxidizing materials* neat, flame. Hazardous Polymerizat ion: Will not occur. FIRE AND EXPLOSION DATA Flash Point: Less than ambient FIRE AND EXPLOSION HAZARDS Class IA Flammable Liquid (NFPA). EXTINGUISHING MEDIA Dry Chemical. C02. Foam. SPECIAL FIRE FIGHTING INSTRUCTIONS Special Fire Fighting Procedures: Water may be ineffective, but water should be used to keep fire-exposed-containers cool. If a leak or spill has not ignited, use water spray to disperse the vapors and to protect personnel attempting to stop a leak. Water spray may be used to flush spills away from exposures. Unusual Fire and Explosion Hazards: Highly flammable. Products of combustion may contain carbon monoxide, carbon dioxide and other toxic materials. Do not enter enclosed or confined space without proper protective eauipment including respiratory protection. ***ft#t4*****44***ft*t#****4*44*ft**t4*#***4*ft*ft*4444* HEALTH HAZARD INFORMATION Primary Routes of Exposure/Entry: Skin, Inhalation. Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: Studies with mice or rats have shown that some petroleum distillates have caused either damage or tumors of the kidneys or tumors ofthe liver. However, kidney effects were not seen in similar studies involving gu in"~ dogs, or monkeys. Also, the significance of tF SAL UU v Ks 28-Sep-89 Conoco Material Safety Data Sheet 04 5 Page 3 MSDS No: IPBC0020 (HEALTH HAZARD INFORMATION - CONTINUED) tumors in rodents is highly speculative. Mouse skin painting studies have shown that petroleum middle distillates (boiling range of 100-700 deg F; naphtha, jet fuel, diesel fuel, kerosene, etc.) can cause skin cancer when repeatedly applied and never washed from the animal's skin. The relative significance of this to human health is uncertain since the petroleum distillates were not washed from the skin and resulting skin effects (irritation, cell damage, etc.) may play a role in the tumorigemc response. A few studies have shown that washing the animal's skin with soap and water between treatments greatly reduces the carcinogenic effect of some petroleum oils. The product contains petroleum hydrocarbons which may cause irritation to eyes, skin, and lungs after prolonged or repeated exposure. Extreme exposure or aspiration into the lungs may cause pneumonia. Overexposure may cause weakness, headache, nausea, confusion, blurred vision, drowsiness, and other nervous system effects; greater exposure may cause dizziness, slurred speech, flushed face, unconsciousness, or convulsions. A few studies have indicated that workers exposed to nigh concentrations of benzene have a slightly incidence of leukemia. Benzene can also be toxic Dlood and blood-forming tissues. many years higher to the Carcinogenicity The following components are listed by IARC, NTP, OSHA, or ACGIH as carcinogens. A 'P' indicates a Proposed Carcinogen. Chemical IAR NTP OSH ACG Benz ene XX X X DuPont controls the following chemicals as potential carcinogens : Benzene . Exposure Limits for CASINGHEAD GASOLINE TLV ** (ACGIH) PEL (USHA) IJ t l tc r None Established None Established Lxpo'.iirt* l i in it tor I'l'lniln un PEL: 400 ppm, 1600 rng/mJ 11 i . t i 1 J . t . Other Applicable Exposure Limits: Exposure Limits for Benzene SAL 000006617 C I 04 5 28-Sep-89 Connco Material Safety Data Sheet Page A MSDS No: IPBCO'j.. (HEALTH HAZARD INFORMATION - CONTINUED) AEL (DuPont) TLV ** (ACGIH) PEL (OSHA) l ppm 5 ppm 10 ppm, 1 ppm 5 ppm 0.5 ppm 8 & 12 Hr. TWA 15 Min. TWA 30 mg/m3 (A2) - 8 Hr. TWA - (Short term exposure - Action level limit) AEL is DuPont's Acceptable Exposure Limit. ** TLV is a registered trademark. Safety Precautions Avoid breathing vapors or mist. Avoid contact with eyes. Avoid contact with skin. Wash thoroughly after handling. Wash clothing after use. ****#**** + #********************************'************* + ***-****-*** FIRST AID INHALATION If inhaled, remove to fresh air. If not respiration. If breathing is difficult, physician. breathing, give artifif give oxygen. Call a / i SKIN CONTACT In case of contact, immediately wash skin with soap and plenty of water. If irritation develops, consult a physician. EYE CONTACT In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Call a physician. INGESTION If swallowed, do not induce vomiting. Give large quantities of water. Never give anything by mouth to an unconscious person. Call a physician. NOTES TO PHYSICIAN Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. ..***l*.**t4***t>***ft*t4tt***tt*t.tttt*fr4***4fr4**4****t- PROTECTION INFORMATION Generally Applicable Control Measures and Procedures Ventilation: Sufficient ventilation to maintain atmospneric concentrations below permissible exposure limits. SAL 000006618 Personal Protective Equipment Respiratory Protection: Select appropriate NIOSH- approved 28-Sep-09 Conoco Material Safety Data Sheet C I 04 5 i-'aqe 5 MSDS No: IPBC0020 (PROTECTION INFORMATION - CONTINUED) respiratory protection equipment where atmospheric concentrat ions exceed permissible exposure limit. Protective Gloves: Neoprene or NBR recommended. Eye Protection: Where the possibility of splashing exists, a face shield is recommended. Other Protective Equipment: Sufficient protective apparel should be worn to minimize potential skin contact with this material. SPIlL, LEAK AND DISPOSAL INFORMATION Spill, Leak, or Release NOTE: Review FIRE AND EXPLOSION HAZARDS and SAFETY PRECAUTIONS before proceeding with clean up. Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clean up. Remove source of heat, sparks, flame, impact, friction or electricity. Dike spill. Prevent liquid from entering sewers, waterways or low areas. Recover free liquid for reuse or reclamation. Soak up with sawdust, sand, oil dry or other absorbent mater la 1. Nonrecoverable material, contaminated soil, and debris should be placed in proper containers for ultimate disposal. waste Disposal Treatment, storage, transportation and disposal must be in accordance with applicable Federal, State/Provincia 1, and Local regulations. shipping information dot Proper Shipping Gasoline Hazard Class UN/NA No. DOT L abel(s) DOT Placard Name Flammable UN 1203 Flammable F lammable liquid liquid STORAGE CONDITIONS Store in accordance with National Fire Protection Assn regulations. SAL 000006&19 28-Sep-89 Conoco Material Safety Data Sheet Page 6 MSDS No: lPBCOO^, Tne above data are based on tests, experience, and other information which Conoco believes reliable and are supplied for informational purposes only. However, some ingredients may have been purchased or obtained from third-party manufactures. In these instances, Conoco, in good faith, relies on information provided by those third parties. Since conditions of use are outside our control, CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM USE OF THE ABOVE DATA. NOTHING CONTAINED HEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE MATERIAL DESCRIBED, OR ITS USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. Date of latest Revision Responsibility for MSD5 89/09/28 Env. it Occ. Health Conoco Inc . PQ Box 2197 Houston, TX 77252 713-293-5550 Services ( SAL 000006620 28-SCP-69 Conoco Material Safety Data Sheet CI04 6 Page 1 MATERIAL identification NUMBER NAME : IPBC0080 : STA8ILI2ER OVERHEAD LIQUID CHEMICAL FAMILY CAS NUMBER NFPA RATING WHMIS CLASSIFICATION Not Applicable. Petroleum Hydrocarbons Mixture Health: 1 Flammability: 3 Reactivity: 0 MANUFACTURER/DISTRIBUTOR: Conoco Inc. P.0. Box Houston, GENERAL INFORMATION PHONE TRANSPORTATION EMERGENCY PHONE MEDICAL EMERGENCY PHONE 2197 TX 77252 : 1-(713)293-5550 : I -(800)424-9300 : 1 -(800)441 -3637 ****#*******#******#*#t###*4**##**###t##**ft****t#******#**#*###*##### OSHA HAZARD DETERMINATION Hazardous Ingredients Hydrocarbons (Aromatic & Paraffinic) Benzene Hydrogen Sulfide CAS Number Mixture 71-43-2 7783-06-4 Regulated as a toxic chemical under section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR part 372. Hazardous Physical Properties: Class IA Flammable Liquid per NFPA Code No. 30-1987. The material is hazardous as defined by OSHA's Hazard Communication Standard, 29 CFR 1910.1200. PHYSICAL DATA Vapor Pressure Vapor Density Solubility in Water Form Color Specific Gravity API Gravity Distillation Range 15-200 PSI e 100 deg F > 1 (Air = 1.0) Slightly soluble Llquid Colo rless (H20 = 1) 0.5 - 0.7 70-140 -125 - +400 deg F (Includes traces of hydrocarbons, hexanes, and higher molecular weight.) SAL 000006621 CI04 6 ^a-Sep-bV Lonoco Material Safety Data Sheet Page 2 USDS No: 1PBCOO HAZARDOUS REACT1V11V Instability : Stable Hazardous Decomposition Products: Oxides of carbon and sulfur. Incomplete combustion may produce carbon monoxide. Conditions to Avoid: It is flammable. Reactive with oxidizing agents. Corrosive to many materials whem moist. Hazardous Polymerization: Will not occur. FIRE AND EXPLOSION DATA Flash Point: Below ambient. FIRE AND EXPLOSION HAZARDS Class IA Flammable Liquid (NFPA). EXTINGUISHING MEDIA Dry Chemical. C02. F o am. SPECIAL FIRE FIGHTING INSTRUCTIONS Special Fire Fighting Procedures: Water may be ineffective, but water should be used to keep fire-exposed containers cool. If a leak or spill has not ignited, use-water spray to disperse the vapors and to protect personnel attempting to stop a leak. Water spray may be used to flush spills away from exposures. Unusual Fire and Explosion Hazards: Highly flammable. Products of combustion may contain carbon monoxide, carbon dioxide and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. ****#******** ************************************************* ***** health hazard information Primary Routes of Exposure/Entry: Skin, Inhalation. Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: Studies witn mice or rats have shown that some petroleum distillates have caused either damage or tumors of the kidneys or tumors of the liver. However, kidney effects were not seen in similar studies involving guinea pigs. SAL 000006622 26-Sep-89 Conoco Material Safety Data Sheet C I 04 6 Page 3 MSDS No: 1PBC0080 (HEALTH HAZARD INFORMATION - CONTINUED) dogs, or monkeys. Also, the significance of the liver tumors in rodents is highly speculative. Mouse skin painting studies have shown that petroleum miodle distillates (boiling range of 100-700 deg r; naphtha, jet fuel, diesel fuel, kerosene, etc.) can cause skm cancer when repeatedly applied and never washed from the animal's skin, The relative significance of this to human health is uncertain since the petroleum distillates were not washed from the skin and resulting skin effects iirritation, cell damage, etc.) may play a role m the tumorigenic response. A few studies have shown that washing the animal's skin with soap and water between treatments greatly reduces the carcinogenic effect of some petroleum D 1 iS . The product contains petroleum hydrocarbons which may cause irritation to eyes, skin, and lungs after prolonged or repeated exposure. Extreme exposure or aspiration into the lungs may cause pneumonia. Overexposure may cause weakness, headache, nausea, confusion, blurred vision, drowsiness, and other nervous system effects; greater exposure may cause dizziness, slurred speech, flushed face, unconsciousness, or convuIs ions. hydrogen sulfide can be irritating at low concentrations to the eyes, skin, ana respiratory tract. At higher concentrations, loss of ability to smell hydrogen sulfide, respiratory paralysis, and death may occur. A few studies have indicated that workers exposed to high concentrations of benzene have a slightly incidence of leukemia. Benzene can also be toxic Dlood and blood-forming tissues. many years higher to the Carcinogenicity The following components are listed by IARC, NTP, OSHA, or ACGIH as carcinogens. A 'P' indicates a Proposed Carcinogen. emical IAR NTP OSH ACG nzene XX X X DuPont controls the following chemicals as potential carcinogens : Benzene . exposure Limits for STABILIZER OVERHEAD LIQUID TLV ** (ACGIH) : None Established PEL (OSHA) : None Established 000006623 SAL CI04 6 28-Sep-09 Conoco material Safety Data Sheet Page 4 MSDS No: IPBCOO.^ (HEALTH HAZARD INFORMATION - CONTINUED) Other : Exposure Limits for Petroleum Distillate PEL: 400 ppm, 1600 mg/m3 Other Applicable Exposure Limits: Exposure Limits for Benzene AEL (DuPont): 1 ppm - 0 St 12 Hr. TWA 5 ppm - 15 Min. TWA TLV ** (ACGIH) : 10 ppm, 30 mg/m3 (A2) PEL (OSHA) : 1 ppm- S Hr. TWA 5 ppm - (Short term exposure limit) 0.5 ppm - Action level Exposure Limits for Hydrogen Sulfide AEL TLV ** PEL (DuPont): 10 ppm - S & 12 Hr. TWA (ACGIH) : 10 ppm, 14 mg/m3 STEL 15 ppm, 21 mg/m3 (OSHA) : 10 ppm, 14 mg/m3 STEL 15 ppm, 21 mg/m3 AEL is DuPont's Acceptable Exposure Limit. ** TLV is a registered trademark. Safety Precautions Do not breatne vapor or mist. Avoid contact with eyes. Avoid contact with skin. Wash thoroughly after handling. Wash clothing after use. FIRST AID oKIN CONTACT In case of contact, immediately wash skin with soap and plenty of water. If irritation develops, consult a physician. EYE CONTACT In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Call a physician. INGESTION If swallowed, do not induce vomiting. Give large quantities of water. Never give anything by mouth to an unconscious person. Call a physiclan. INHALA fION it hydrogen sulfide is present, the following applies: Rescue personnel must use good judgment to minimize their risk. Because hydrogen sulfide can cause death, rescuers must wear positive pressure full facepiece, self-contained or supplied-air NIOSH approved resoirators before attempting the resc* SAL 000006624 28-Sep-89 Conoco Material Safety Data Sheet C I 04 6 Page 5 MSDS No: IPBCO080 (FIRST AID - CONTINUED) Remove victim to fresh air breathing, give artificial is difficult, give oxygen. a physician. immediately. If not respiration. If breathing Keep warm and at rest. Call NOTES TO PHYSICIAN Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. PROTECTION INFORMATION Generally Applicable Control Measures and Procedures Ventilation: Sufficient ventilation to maintain atmospheric concentrations below permissible exposure limits. Personal Protective Equipment Respiratory Protection: Select appropriate NIOSH-approved respiratory protection equipment where atmospheric concentrations exceed permissible exposure limit. Protective Gloves: Neoprene or NBR recommended. Eye Protection: Where the possibility of splashing exists, a face shield is recommended. Other Protective Equipment: Sufficient protective apparel should be worn to minimize potential skin contact with this material. SPILL, LEAK AND DISPOSAL INFORMATION Spill, Leak, or Release NOTE: Review FIRE AND EXPLOSION HAZARDS and SAFETY PRECAUTIONS before proceeding with clean up. Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clean up. Remove source of heat, sparks, flame, impact, friction or electricity. Dike spill. Prevent liquid from entering sewers, waterways or low areas. Recover free liquid lor reuse cu red am a t l on . Soak up w 11 h sawdust, sand, oil dry or other absorbent mat e ria 1. Nonrecoverab1e material, contaminated soil, and debris should be placed in proper containers for ultimate disposal. u/aste Disposal SAL 000006625 CI04 6 28-Sep-89 Conoco Material Safety Data Sheet Page 6 MSDS No: IPBCOO (SPILL, LEAK AND DISPOSAL INFORMATION - CONTINUED) Treatment, storage, transportation and disposal must De m accordance with applicable Federal, State/Provincial, ana Local requlations. Recycle as much of the recoverable material as possible. SHIPPING INFORMATION DOT Proper Shipping Name : Petroleum distillate Hazard Class : UN/NA No. : DOT Labe Its) : DOT Placard : Flammable UN 1268 Flammable Flammable 1iquid liquid ******#******************************************-* STORAGE CONDITIONS Store in accordance with National Fire Protection Assn regulations. The above data are based on tests, experience, and other informatic which Conoco believes reliable and are supplied for informational purposes only. However, some ingredients may have been purchased or obtained from third-party manufactures. In these instances, Conoco, in good faith, relies on information provided by those third parties. Since conditions of use are outside our control, CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM USE OF THE ABOVE DATA. NOTHING CONTAINED HEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE MATERIAL DESCRIBED, OR ITS USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. Date of latest Revision Responsibility for MSDS 89/09/28 Env. & Occ. Health Conoco Inc. PO Box 2197 Houston, TX 77252 713-293-5550 Services SAL 000006626 28-Sep-09 C I 04 7 Conoco Material Safety Data Sheet Page 1 MATERIAL IDENTIFICATION NUMBER NAME I T AI1090 PROPANE INTERMEDIATE STREAM CmEMICAL FAMILY s Paraffin Hydrocarbons TRADE NAMES / SYNONYMS : Mixture of oropane and propylene Cat Poly Propane Casinghead or PBC Propane Alky Propane GRP P-P FCC P-P CAS NUMBER NFPA RATING WHMIS CLASSIFICATION Not Applicable. 74-9d-fc Health: 1 Flammability: 4 Reactivity: 0 MANUFACTURER/DISTRIBUTOR: Conoco Inc. P.0. Box 2197 Houston, TX GENERAL INFORMATION PHONE TRANSPORTATION EMERGENCY PHONE MEDICAL emergency PHONE 77252 l-<713)293-5550 1 - (800)424-9300 1-(800)441-Jfc37 ObMH HAZARD DETERMINATION Hazardous Ingredients CAS Number Hyorogen Sulfide Hydrocarbons (gaseous alkanes) 7783-06-4 Mixture Hazardous Physical Properties: Compressed Gas, Flammable. The material is hazardous as defined by OShA's Hazard Communication Standard, 29 CFP 1910.1200. r r 1 CAL DATA Boi 11 ng Point Vapor Pressure V a d o r Dens itv X Vo 1 a 11les So lub i1ltv in Water F orm Color Spec l fic Gravity Odor -54 to -44 deg F : Approx. 10,000 mmHq or 200 : 1.56 (Air r 1.0) : (by vo1ume} 100 : Insoluble Gas (liquid under pressure ! Color less : Gas; Liquid 0.5-0.6 (H2U $ Propane sold tor use as fu contains mercaotan odorant SAL 00000662? S-lEA con c Io4 7 28- Sep -89 Conoco Material Safety Data Sheet Page 2 M5DS Nc: ITAIlO1 HAZARDOUS REACTIVITY JnstaDility : Staple. Hazardous Decomposition Products: and sulf ur. Oxides OT carbon Conditions to Avoid: Strong oxidizing materials. Hazardous Polymerization: Will not occur. HIRE AND EXPLOSION DATA Method : TCC Flammable Limits in lEL : 2.2 UfcL : 9.5 Flash Point: Below Air, X by Vol. ambient or approximately -156 deg F HIKE AND EXPLOSION HAZARDS Handle and store m accordance with NFPA procedure for Compressed Gas, Flammable. LX 1 INGUISH2NG MEDIA If gas nas ignited, do not extinguish. Allow to ourn out. Stop gas flow. SPECIAL FIRE FIGHTiNG INSTRUCTIONS Do not fignt fire. Shut off source of fuel, it possiDle risK. Cool tank/container with water spray. If a leak or spill has not ignited, use water spray to disperse the gas and to protect personnel attempting to stop a leak. and without Unusual Fire and Explosion Hazards: Highly flammable. Products of combustion may contain carbon monoxide, carDon dioxide and otner toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. tlF.Ai.1H HAZARD INtURMAEION primary Route of Exposure/Entry: Inhalation: Signs ana Symptoms of Exposure/Medical Conditions Aggravated by Exposure: 000006628 SAL 20-Sep-89 Conoco Material Safety Data Sheet C I 04 7 Page 3 MSDS No: II AIL 090 (HEALTH HAZARD INFORMATION - CONTINUED) Overexposure may cause central nervous system depression, targe concentrations in ambient air can cause asphyxiation oue to oxygen displacement. Contact with liquified gas may cause f rostbite. If hydrogen sulfide is present, low concentrations are irritating to the eyes, skin, and respiratory tract. At higner concentrations, respiratory paralysis and loss of ability to smell hydrogen sulfide may occur. Carcinogenicity None of the components in this chemical is listed by I ARC, NTP, OSHA, or ACGIH as a carcinogen. Exposure Limits for PROPANE INTERMEDIATE STREAM AEl * (DuPont): None Estaolished TLV ** (ACGIH) : Simple Asphyxiant PEl (DSmh; : 1,000 ppm, 1,800 mg/m3 Other Applicable Exposure Limits: Exposure Limits for Hydrogen Sulfide AEl * TLV ** PEL (DuPont): (ACGiH) : (OSHA) : 10 ppm - 8 t 12 Hr. TWA 10 ppm, 14 mg/m3 STEL lt> ppm, 21 mg/m3 10 ppm, 14 mg/m3 STEL 15 ppm, 21 mg/m3 AEL is DuPont's Acceptable Exposure Limit. ** TLV is a registered trademark. Safety Precautions Do not breathe vapor or mist. Avoid contact with eyes. Avoid contact with skin. Wash thoroughly after handling. Wash clothing after use. R5T AID SKIN CONTACT Immediately consult a physician for possible frostbite. EYE CONTACT Immediately consult a physician for possible frostbite. INHALATION If hydrogen sulfide is present, the following applies: Rescue personnel must use good judgment to minimize CI047 28-Sep-89 Conoco Material Safety Data Sheet Page 4 MSDS No: ITAIlO^ (FIRST AID - CONTINUED) their risk. Because hydrogen sulfide can cause death, rescuers must wear pos1t1ve-pressure, fu11-faceplece. self-contained or supp1led-alr, NI OSH-approved respirators before attempting the rescue. Remove victim to fresh air immediately. If not breathing give artificial respiration. If breathing is difficult, give oxyoen. Keep warm and at rest. Call a physician. PROTECTION INFORMATION Generally Applicable Control Measures and Procedures Ventilation: ventilated. areas. Storage and use areas should be well Fans or blowers should be used m enclosed Personal Protective Equipment Respiratory Protection: Personnel should never enter high concentrations except for rescue. Self-containeo respiratory equipment should be used. Protective Gloves: Should be used to prevent frostbite which can be caused by rabid evaporation. Eye Protection: Chemical goggles or face shield when changing valves, hoses, etc. Use full facepiece where respiratory protection is required. SPILL, LEAK AND DISPOSAL INFORMATION Spill, Leak, or Release NOTE: Review FIRE AND EXPLOSION HAZARDS and SAFETY PRECAUTIONS before proceeding with clean up. Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clean up. Evacuate personnel, thoroughly ventilate area, use self-contained breathing aoparatus. Remove source of heat, sparks, flame, impact, friction or electricity. Keep upwind of leak - evacuate until gas has dispersed. Dissipate vapor with water spray. Haste Disposa 1 If spilled as a liquid, this product will evaporate completely. Vapors should be dispersed mechanically, possible. if SAL 000006630 28-Seo-89 Conoco Material Safety Data Sheet C I 04 7 Page 5 USDS No: ITAIL090 SHIPPING I NFQRtlAT ION DOT Proper Shipping Name Liquified Petroleum Hazard Class UN/NA No. DOT Label(s) L*UT Piacaro Gas F1ammable UN 1075 F1ammab1e F-1 ammab le gas g as ST DRAGE CONDIT IONS Store in well ventilated area. Store in accordance with National Fire Protection Assn regulations. .^..**.-***-** + -*'*-*'********'**-*'*-* + *'*******-*********'*******-*****#**-##**#.#.*.*#. Tre above aata are basea on tests, experience, ana other information ,r i:n Conoco oelieves reliable ana are supplied for informational Purposes only. However, some ingredients may have been purchased or obtained Trom third-party manufactures, in these instances, Conoco, in gcoc faith, relies on information provided by those third parties. 5i-.ce conditions of use are outside our control. CONOCO DISCLAIMS ANY LlABillTV FOB DAMAGc OB iNJuRY WHICH RESULTS FROM USE OF IHE ABOVE OATH. NOTHING CONTAINED HEREIN SHALL CONSTITUTE A GUARANItt, WARRANTY (INCLUDING WARRANTY OF MERLhAnTAB1L I TY ) DR REPRESENTATION (INCLUDING FREEDOM CROM PATENT LIABILITY ) BY CONOCO WITH RESPECT iO THE DATA, THE NAtERIAl DcS^hIBcD, OB ITS Ubfc FOR ANY SPECIFIC PURPOSE, EVEN JF THAT OijRPQSt iS KNOWN TO CONOCO. Date of latest Revision Responsibility tor MSDS : 89/09/28 : Env. it Occ. Health Services Conoco Inc. PO Box 2197 Houston, TX 77252 713-292-5550 000006631 SAL reoufsrsto for* CiJMOCQ CNC r 0 jinx sj w./. LAFAYETTE -LA /osoh G S1 2 0 ORMK NUt i^QQ NU: 040999/2 VAN UM'I'lili * RUUFRJCINC..,; SlIRSnOARY 01* UNHVAR 1400. NORTON PLUG. SEATTLEWA 98104-1564 (403 V 4-55-8/00 ..............- - - -................................. I MtRCI HCY ACCIMAHCl........----- ---- ------------- OR EMERGENCY ASSISTANCE INVOLVING CHEW(CALS CALL CHEMfREC <300)424-9*00 .................................................... i nk ikomicr anh sai fs ini'iiknayuin------ ----------------- ------------------ contact your local van waters & Rogers branch office ............................. ---IRtiHUCY- j Ji! 'NT IF) CAT) (*N--------------------------------- ------------ kunucr name:. chlorine CfiNMUN NAMI 'C/CYHUNYMH ' CHMiKlMF -FA REG. NO. 550-1// ' cas no. : //82-50-5 VW&R C(f)t|: s F10J1 M'WM a*. n y /ARH RAT TNG <NsrPA HI'AI Tl I r FIRE: O Rl ACT i V'l > Y: (% SPEC CAL : o:<y 49) UATF iSSUFli: OC/SV SUPSRCEOES: 07/09 HA/ARl* KATINS SCALF: O-MINIMAL ^SERIOUS J St.HiHT 4^HFVI RF 2-l'IOOEtvA f UA/AKWiUS 1 NCRI ID FHTS---------- - COMPONENT (:(II UK J Nl % VV.5 EXPOSURE L CHITS. WH OSHA ACUllI UlliER PEL TLV LIU C f 0.5 1 .1.0- CEILING HAZARO TOXIC* COKknSiVFS COMPRESSED GAS ------------------------- --------- PHYSICAL PROPERT CES -- ------------------------------- ---- -------- -------- i!fi>i )hh I'lm-rr. dfc it /v varur prcssurf, mm h/?<> uku cs 4U<>o MELTING POINT. OEG K* -150 VAPOR DENSITY <AIRl)l 2.5 ITOI tr: CRAVTYY (WATERS): J.41 (U(UDH) WAlTR SOI UHILITY, X:, 6./ APPEARANCE AND ODOR: EVAPORATION RATE -(BUTYL ACE TATE =l)s N/A Ski I N) UM--YI I l OM NAS OR MUUIli, SUFFOCATING. PUNGENT OOOR ................................... ........... --- FIRST' ADI MFASURFC~------ -----*-'*--- CP INHALED2 REMOVE TO FRESH AIR. GCVE ARTIFICIAL'RESPIRATION IF NOT ):I;t A VI P NC. CFT 1 MPil Jll AYF Ml IDCAI AI YI'NYIUN- IN CASE OF EYE CONTACT:' CMMEOCAfELY FLUSH EYES WITH LOTS OF RUNNING WAtlk FUR 1 ? * MINlTlFS. I HYING IHF URFI k ANH 1.&WFR EYFI IHC UCCACltlNAI l.Y. JET IMMEDIATE MEDICAL ATTENTION. iN CACF Ul SKIN CONTACT: TRFAY hUR TNHAI/iYION KXfOSUKF FIRST. : ^MEDIATELY FLUSH SKTN WITH LOTS OF RUNNING WATER FOR 15 MINUTES. MUVF CUNTAM) NATFH CIOVHINO AN)* CHUFSs. WASH HtMlRI KFUST . OFT PROi'i 040999/2 14:10:0/ 05 .JAN 1990 CIJSfs 450/96:56 INVOICE! S*L 000006632 SH6^ 013300 moi j natlkiai safety hat a om i t MLGR INC liquified 13AS k, G $1 20 REVISION OF:12-29-OV immediate medical artention. h **iai t owns ucj hut. ipower vcmrnNo. n conscious^. give lots of matu< OR wtl - GET IMMEDIATE Pie 01 CAL AT TEN f tUN. 00 NOT GIVE ANYTHING Y MOUTH 'I Cl AM UNCONSCIOUS OK CONVUt V HO I'! KHUN. ..............------------------------------------------HEALTH HAZARD CNFORMA r ION------------------------------------------------------ i*i:jhacy nmrrrn or exposure*. jnhaiaoon A H3NS ANO SYMPTOMS OF EXPOSURE - ^ ^ HUAI ATI OHS VAPUKU ANU MTOTf; Alii: EXYkEMI'l V CUCCUSTVI TO THI NOLI . THROAT, AHO HUCOUS MEKDRANES. ASiONCH C f IS., PULMONARY EDEMA, AND f :t!l Ml LAI CNI UMON) ilk MAY OCCUR. rlilill AT) OWvCOUOinm.. Olll.iiT PAIN. AND DIFFICULTY IN AREA THING MAT - OCCUR UI rH DRIFF exposure:. WHILE PROLONGED exposure may cioui t jn moke t*vfci iccnATTUN anh utii.UK tiapaoi . AREA fH CHG HtGH CONCENTRA LIONS MAY KStSULf IN >OeA l`H- I VI * C< INTACT: VAI'UkG. I 1 HUlli AHO Pi i Kid Alii FXTkl NFt Y CUCUOO j Ml- TO THE EYES. .GRIEF CON TAC r OF THE VAPORS U ILL AC SEVERELY IRRITATING, ocm contact nt iiir mouth octncto uni i oi Vfki ly HAPiAbE rnr fyio anu .>;?>! ONGED COM TACT MAY CAUSE PERMANEN T . EYE INJURY WHU)H HAY DE FOLLOW; 0 :Y >:l UTHNI <;K!N CONTACT: MOMH CtllUIONI Will HUCH 'HU' SIC j N - - U! OH CONCENTRA IONS OF .GAS WILL IRRITATE THE SKIN ANO MAY FORM BLISTERS. OUAI I OUI in <;WAU OWING 10 UNITKIl.Y ):i CAUOl 00100 HI* 10 A OAK Al NOON TEMPERATURE AND PRESSURE. INGESTION OF LIQUID WOULD CAUSE SEVERE > NTTCNAI iN-WCHO. IICONIC FIIICTO UF I: XPOSUKEt- PIAY CAUOI COCkOClUH OF THE TEETH. SKJN ;'<}'< I I'ATTON * AMO REDUCED RESP IRA TORY CAPACITY. Ml UTCAC COMIOTiONO Ul Nl 'CAl t Y AOUCAVATFU HY I XI`OCUk`L'5 nunl: KFCOKTIli. ------------------------------------------------------------------------TOXICITY DA TA -------------------------------------- ------------------------------ OCAI - NO HATA WUINU HECAHHF CISIOdNl 1C A OAO AT CtWM TI Ptl TK'A TUL'I . DERMAL: MO OA TA FOUND RECAUSE CHLOR INF. IS A GAS AT ROOM TEMPERA TURF. ' NIIAI AT TON: MOHAN I (1 0 Ti/Js PPM/OO NT Ns CAT l COO a >VS H'M/1 Hlis MOUSE LC50 = 107 PPPI/l HK f:AL*C 1 HCiOl 'NT Cl T Y: THIS PIATFR1AI 1C NUT CONCl JUKI M T 0 hi A CAIiCINClOl.N HY THE NATIONAL TOXICOLOGY FKOGKAM* THG INTGKNAfIONAL AGENCY FOK L-l CLAkCH ON CANCCFi. UK Tilt! UCCUPATIUNAI KAI TTY AH)i Ht'Al TH AON) N1 Si CAT ION OTHFK DATA: THE OOOK THKESHHOLO FOK CHLOPCNK GAS IS 0.02-0.2 PPM A! THOMHJ! 01 I LACTOKY LATJUUIr: MAY ULVII III* AITF K CHliUNlC LOW IIWL XPOSUKFS. AT 0.2-0.5 PPM IN AIR THERE ARE NO REPORTED LONG-TERM iinCTC: 1-a h'CPI IklilTATr mr HOST ANO KYLCs 6 CCM lkClTATTS THT nik-UAT; ;:0 F'PPI CAUSES INTENSE COUGHING; 40-60 PPM MAY CAUSE Ss?IOUS DAMAGE; TOO PCM NAY CAUHr l t THAL OAPIASr? 1000 PPM MAY HI FATAL WITH A FI U HITT HREATHS. -PFKSUNAI PkUTICTHiN........-- ----------------- VFN T CLA TION s LOCAL MECHANICAL EXHAUST VENTILATION CAPABLE OF MAIN TAINING FM!001ONS AT THF POINT OF UOF HI LOW THI PI l.. PC0V1HF 0U1T AHIL VENTING FOR LOU LYING AREAS. ki OPI CAVOk'Y Pk-OTFCIJOH; UFAk* A NIUOIP-APPCOVFH k-FOPICATOC APPKUPKI AT F FOR THE VAPOR OR MIST CONCENTRATION AT TNG J'OrNT OF USE. APPROPRIATE CIOPIKATOCO MAY HF A I Ul I IAOFPHCI Uk A IIAI f MASK A) li-PUli) I Y) NO CAC'l IOGE RESPIRATOR EGUIPPEO FOR ACID GASES/MISTS, A SELF-CONTAINED .krATHINO APPACATIIO TN Till' PliFSOURF UtPiANU PiOHF, UK A OUPPI .11 H-Al li RESPIRATOR. nr pcuTi cnoN: cim nioai soooi t o anu i ui.i t alt oini i h uni t:so a flu i SAL 000006633 PROD: 040999/2 M:l0:0/ 05 JAN 1990 COST: 450/9636 INVOICE: r i;1 < j i MATFU1 Al ILORfNE I.tOUlFESO >3AS KAFFVY HAT A KMH'T PU 3 ; 1 2 0REVISION OFsl2-29-s4r-:S acfp cece respirator is also worn. ir is generally recognised that < :OHYA(:'l IFNOFS SHUUl H NUT Fit: WORN WHFH WURKINU WI TH CHIMH:AI.S BECAUSE CONTACT LENSES MAY CONTRIBUTE TO THE SEVERITY OK AN EYE INJURY. iliiri'ICiiUi M fiTIUNU: I dN(i SI I LVIH SM'i UY. TUUUSI RS. SAFETY SHOPS, RUUHLK Ot.OVF3- AN ft RUBBER APRON. Mlilll K l lvd'H ("nvr Ml ASURFS: AN FYLWASH ARM SAFETY SIIUWIU SHOW II HF NEARBY ANH READY FOR USE. .........- ........"K'i l-'l ` AH)i t XI*1 US`j UN ) Nt TiKMA'I1 UN--------------------------------------------------- LASH POINT. UEG Ft NONE Nl'THUH USIUs N/A '< T INljU CSH ING MEDIA: THIS UtiLinWH MI 111 A Al'I'RUl-in ATI 'OMBUSriON. NA TERCAL IS NOT FOR SlIRRUUNHi NU FLAMMABLE LIMITS IN AIR. Z lUWLFc: N/A llITTh'S N/A COMBUSTIBLE. USE EX TINF1UF. CIIIURJNI Will SUPPORT <lt(.iAl I Ilvl t i.UtrnHO PUUPLMlUFK: F1UF FlCnTFRS SHUULU Wl Ak sm - I'UHTAlNLH BREATHING APPARATUS AN IT PULL PROTECTIVE CLOTHING. USE WATER CPUAY in CMOI WFAUUY CUNTAJHI US ANH SI RUCYUM !S LXPUSIU TU F1KF. YANKS ANA CYLINDERS WILL RELEASE CHLOSUNE WHEN FUSIBLE METAL SAFETY PLU13S MELT at iso i /.ii inw-i r. UNIISUAI I MvF ANli I XI 'I OKI ON HA/AUUS: CUIOKilNI Will. SUPPORT THF. HORNING -IF COMBUSTIBLE MATERIALS JUST AS OXYGEN GOES. FLAMMABLE GASES ANO vapors fan rouii fxpiusjvi mi>riurl:s wmt chiukjnl. l.iuuju chlouinf can TON I IE SOL to METALS SUCH AS ALUMINUM, CARBON STEEL, AND FINELY iiUMtlli i POM. ........................................ -- .............. - --IIA/AUHOUS Ul ACTIVITY---------------- -;---------------------------- ------------------------ ABILITY: STABLE . POLYMER I NATION: WILL NOT OCCUR Nin i i fill*; TO AVI11 )is J NTI NKF I.SOAP HI'AT MATERIALS 10 A VO 10: REDUCING AGENTS, COMBUSTIBLE MATERIALS, ORGANIC .:l!imr:AI l i Nl I Y U'JVjniH Mi l AlS ANU WATIk. HAZARDOUS DECOMPOSITION PRODUCTS: CHLORINE OOFS NOT OECOMPOSE BUT Ll ACTS UiHI WATFR TU FORM HYUKUCHIUIO C AC3H ANH U1TII CARHUN MUHOX1M- III :**0RI1 PHOSGENE. ......................... --.......KPUI, I FAK, ANH UiSPUKAI PkUCrMJRTS------------------------------------- ACTION TO TAKE FOR SPILLS OR LEAKS: ONLY SPECIALLY TRAINED PERSONNEL SIJOUUi A l l I MPT RFPAiRS. WI/AK* ACIU-RHO STANT SI lUKFfi SUIT ANll COMPI.LTP. : R`OTECriVE EUUIPMENT INCLUDING RUBBER GLOVES. RUBBER BOOTS, AND CHEMICAL COHOI FS ANH FACI'SHlFt U. WFAR SFI F-CUHTAINFH BRFATHJNti APPARATUS. STOP THE FLOW OF GAS. IF THE LEAK CANNOT BE STOPPED IN PLACE AND IS IN AN I NCI USIH PI At:l\ MtiVI Till* CUNTAiNFR TU Till: UPFN AIR IF IT IS SAI F TU UU SO. SHIFT THE CONTAINER SO GAS, RATHER THAN LIQUID, LEAKS. REPAIR THE FAK Ul; APPJ Y AN FNFRUFHCY K)Y. NFVFK APPLY WATER TU A CHI UR1NL* LFAK. DISPOSAL METHODS: DISPOSE OF CONTAMINATED PRODUCT AND MATERIALS USED iN CIFAN1NU UP SPHLS UR LEAKS IN AvMANNFR APPROVER FOR THIS MAYITOAI CONSULT APPROPRIATE FEDERAL, STATE ANO LOCAL REGULATORY AGENCIES TO ASCI KTAi N PRUPFK lUSPOSAt PROCFUURI S. MOTE: EMPTY CONTAINERS CAN HAVE RESIDUES, 3ASES AND HCSTS AND ARE !:l.l)i,IICT in PKUPFR WASTE* IHSPOSAl , AS AUUVF. --------------------------------------------------------SPECIAL PRECAUTIONS---------------------------------------------------------------- RAHUL)MU AND STURAUF PRFCAUTHlNSs . S10RF ) H A COW , HUY ARI A OUT OF DIRECT SUNLIGHT ANO PROTECTED FROM MOISTURE. STORE AWAY FROM OTHER CUNPRFSOt *U UAStS, ) MCOMPAT) HI F MATFR1AI S, ANIr CUNHUKVi HLE MATERIAL.S. USE AN APPROVED CHLORINE WRENCH ONLY. PAH; ANH MAI NYI 'WANCF PRFLAUTHlNSs HO NUT CUT. SR] Hli, UI I.U, OK DK1IL uN DR NEAR THIS CONTAINER. UTHFK PUICAUTHiNS: HU NOT ATUMP'I YU MANUll:., STUUF, UR USI CHIUU1NF .ROD: 040`?"??/2 M s 10:0/ 05 JAN l*?VO COST: 450/96:SiA INVOICE: SAL 000006634- Vl<M1 MATIKIAI faAIETY HAVA faH! IT LORINE L r.fJIJ IF CKO GAS Pli 4 REVISION OK: L 2~Z9-:1V *41 THOU r a COMPLETE REVIEW BY ALL PERSONNEL OK THE CHLORINE INSf I TU TE'sC C t :| si OK 1 HI I'iANMAI . AlSU, ATTENDANCE AT A VAN WATERS & CODERS, INC- "r SEMINAR ON CHLORINE HANDLING IS SUGGCS TED. OTHER M`l CAUTIONS: OONTA) Nl Rfa, EVEN THOM lUAV HAVE BMW LMCVIFW, Will ATTAIN PRODUCT RESIDUE AND VAPORS. ALWAYS OBEY HAZARD WARNINGS AND -UAHHI E EMPTY CONTAiWERS AC It THEY WERE EUI I . -------- ?---------------------------------------- FOR ADDITIONAL CNKORNA TION........................... --7----------------------- CONTACT MODS COON)* I NATOR, VAN WATERS & NC.iNt.kti INC. DURING DUS CHESS HOURS* S>ACIEIC HME ( 408)4:5^-8/00 .......................... .................. --other keuim atony ineurmation-........ ---- ~ ................ DO NOT DETACH THIS SECTION FROM THE USDS AND BE SURE TO ;<nci oui line- oecuon winn cucyjno the mods. THIS PRODUCT CS A TOXIC CHEMICAL SUBJECT TO THE REPORTING REQUIREMCN TO fir CICTlOH .':1 Of mtl 111 01 MIE SUPEKI UHD AMENDMENTS AND RtAUlMURl7ATC0N ACT OK 1906 AND 40 CFR PARf -'4/2. . - VAN WATERS * ROGERS INC. r'VW&R11) EXPRESSLY DISCLAIMS ALL EXPRESS -jl-iTI ini WARRANTIES or MERCflANTAHU f TY AND EilHEfaS EUR A PARTiCULAR JRPOGE. WITH RESPECT TO THE PRODUCT OR INFORMA T CON PROVIDED HEREIN.*# Al l j Mr(if-:MAI 1 ON APPEAR! NO HEREIN IS BASED UPON HAVA (JBTAIHI It t RON f HI: MANUFACTURER AND/OR RECOGNIZED TECHNICAL SOURCES. WHILE THE INFORMA1 '{{iN IS REMEUtD TO HI ACCURATE. VUfck MAKES HO RCPUffatNVAT1OHS AO TU S ACCURACY OR SUKEICIENCY. CONDITIQNS OK USE ARE BEYOND VU^R'S CON- 01 AND lIHREfURI' USERS AUK RESPOND)DLETO VERITY THIS BATA UNDER THEIR OWN OPER'A T CNG CONDITIONS TO DC TERM INK WHETHER THE PRODUCT IS `UD 1 ADI l` ICR *1 HI 1R P AC I ICOI AR PURPOSES AND THEY ASSUME Al L. RISKS OE THEIR USE, HANDLING, AND DISPOSAL OK THE PRODUCT, OR KROH THE PUBLICA niON UR Her 01 ,, OR REI iAMCf upon, imeormavhih contained herein, vhis INEORMA T CON RELATES ONLY TO THE PRODUCT DESIGNATED HEREIN, AND DUES NOT REI ATI TO iTC USE IN COMBINATION Willi ANY OTHER MATER 1 Al UK IN ANY 0*11 ILK PROCESS. -------- REVISION---------- -- D//S9S REVISED PEL. AO/OV: CHANGER III ADIWO AND CONTACT INI UKMAT1 ON. **** END OF MS 0S **#* "ROD: A40VVV/P 14:10:0/ OH JAN 1990 COST: 4U0/96SA INVOICE: SAL 000006635 Material Safety Datasheet Emergency Medical Telephone (800) 441-3637 (conoco) DECTOL R.O. OILS 32, 46, *8, 100 G SI 28 I. MATERIAL IDENTIFICATION Name Dectol R.G. Oils 32, 46, 6S, 100 CAS Registry Number Mixture; See Section XI Synonyms Petroleum Lubricating and Hydraulic Oil Product Code 7302/7304/7306/7308 Chemical Family Petroleum Hydrocarbons Transportation Emergency Phone 1-{800) 424-9300 (Cberntrec) II. OSHA HAZARD DETERMINATION The material is not hazardous as defined by OSHA's Hazard Communication Standard, 29 CFR 1910.1200. Refer to Section XI of this MSDS for federal and state regulatory information. Hazardous Ingredients None CAS Registry Number Concentration Hazardous Physical Properties None III. PHYSICAL DATA Appearance and Odor Light brown liquid; Pungent sweet odor Specific Gravity (H,01) 0.87 Boiling Point/Range 650 - 120CPF % Volatiles (by volume) Nil Vapor Pressure Nil Solubility In Water Insoluble Vapor Density (Air = 1.0) >1 Evaporation Rate (Ether 1) Nil IV. REACTIVITY DATA Stable: X Unstable:____ Hazardous Decomposition Materials: Hazardous gases/vapon produced are carbon dioxide. Incomplete combustion may produce carbon monoxide. Conditions to Avoid: Strong oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. HYDC0020/August 1989 SAL 000006636 Conoco Inc., P.O. Box 2197, Houston, TX 77252 <-.> A/\n r- r- t~ r\ 5H4C-0/33<p, DOid&l ootim, 001343 V. FIRE AND EXPLOSION HAZARD DATA Flash Point (Method used): 29CTF fPMCO Autolgnitlon Temperature: 680*F Handle and store In accordance with N7PA procedure for Hiw JUlh Combustible Liquid. Extinguishing Media: Use water spray, dry chemical, CO* foam. Spedal Fire Fighting Procedures: Water or foam may cause frothing. Use water to keep fire-exposed containers cooL Water spray may be used to flush spills away from exposures. Unusual Fire and Explosion Hazards: Products of combustion may contain carbon monoxide, carbon dioxide and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Association (NFPA) Classification Health 0 Fire 1 Reactivity 0 VL TRANSPORTATION AND STORAGE HAZARD RATING Least-0 Slight-1 Moderate-2 High-3 Extreme-4 Storage Conditions: Store in accordance with National Fire Protection Association regulations. Shipping Information: DOT: Not Regulated 1ATA/IMO: Not Restricted VII. HEALTH HAZARD INFORMATION Exposure Limits for Dectol R.O. Oils 32, 46, 68, 100 PEL: None Established TLV: None Established Ceiling Value: None Established Primary Routes of Exposure/Entry: Skin. Signs and Symptoms of Exposurc^Medkal Conditions Aggravated by Exposure: Mouse skin painting studies have shown that highly solvent-refined petroleum distillates, which are similar to ingredients in this product, have not caused skin tumors. The product does not pose a significant health hazard, but as with many petroleum products, poor hygienic practices or inadequate engineering design that allow prolonged or repeated exposure may cause minor skin irritation. Carcinogenic!ty; None of the components in this material are listed as carcinogens by NTT, IARC, or OSHA. VIII. EMERGENCY AND FIRST AID INFORMATION Eyes: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Call a physician. Skin: In case of contact, immediately wash skin with soap and plenty of water. If irritation develops, consult a physician. Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a physician. Ingestion: If swallowed, do not induce vomiting. Give targe quantities of water. Never give anything by mouth to an unconscious person. Call a physician. Notes to Physician: Gastric lavage by qualified personnel may be considered, depending on quantity of material ingested. HYDC0020/August 1989 2 SAL 000006637  SI 28 IX- SPILL, LEAK AND DISPOSAL INFORMATION Io Case of Spill or Leak: Contain spill immediately in smallest possible area. Recover as much of the product as possible by such methods as vacuuming, followed by recovering residual fluids by using absorbent materials. Nonrecoverable product, contaminated soil, debris and other materials should be placed in proper containers for ultimate disposal. Avoid washing, draining or directing material to storm or sanitary sewers. NOTE: Review FIRE AND EXPLOSION HAZARDS before proceeding with dean up. Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clean up. Waste Disposal Method: Recycle as much of the recoverable product as possible. Treatment, storage, transportation and disposal must be in accordance with applicable Federal, State/Provincial, and Local regulations. X. PRECAUTIONARY MEASURES Respiratory Protection: None required except under unusual circumstances such as described in Section V. Ventilation: Normal shop ventilation. Protective Gloves: Should be worn when the potential exists for prolonged or repeated skin exposure. NBR or neoprene recommended. Eye Protection: Safety glasses with side shields; chemical splash goggles if splashing is probable. Other Protective Equipment: Coveralls with long sleeves if splashing is probable. Launder contaminated clothing before reuse. XL REGULATORY INFORMATION FEDERAL REGULATIONS CERCLA, 40 CFR 302 Not Applicable SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986, TITLE HI SECTIONS 302, 304, 311, 312, 313 SECTION 302/304 - Extremely Hazardous Substances (40 CFR 355) The materia! does not contain extremely hazardous substances at greater than 1.0% concentration; however, it is possible that this material may contain extremely hazardous substances at a lower concentration so that a large enough spill could warrant an Emergency Release Report under Section 304. SECTION 311/312 - MSDS and Chemical Inventory Reporting Requirements (40 CFR 370) The material should be reported under the following EPA hazard categories: __ Immediate (Acute) Health Hazard __ Delayed (Chronic) Health Hazard __ Fire __ Sudden Release of Pressure __ Reactive JL_ Not Applicable NOTE: See Section II for the concentration of any ingredients classified as hazardous by OSHA. SECTION 313 - List of Toxk Chemicals (40 CFR 372) The material does not contain chemkal(s) at a level of 1.0% or greater (0.1% for carcinogens) on the list of Toxic Chemicals and subject to toxic chemical release reporting requirements. TOXIC SUBSTANCES CONTROL ACT (TSCA), 40 CFR 710 This material is a mixture as defined by TSCA The chemical ingredients In this material are in Section 8(b) Chemical Substance Inventory and/or are otherwise in compliance with TSCA In the case of ingredients obtained from other manufacturers, Conoco relies on the assurance of responsible third parties in providing this statement. HYDC0020/August 1989 3 SAL 000006638 Si 2 8 RESOURCE CONSERVATION AND RECOVERY ACT (RCRA), 40 CFR 241, SUBPART C AND D Tbe material, when discarded or disposed of, is oot specifically listed as a hazardous waste In Federal regulations; however, it could be considered hazardous If It meets criteria for being toxic, corrosive, ignitable or reactive according to U.S. EPA definitions (40 CFR 261). Additionally, it could be designated as hazardous according to state regulations. This material could also become a hazardous waste if it is mixed with or comes in contact with a listed hazardous waste. If such contact or miring occurs, check 40 CFR 261 to determine whether it is a hazardous waste. If it is a hazardous waste. Regulations 40 CFR 262, 263, 264 and 268 may apply. FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 114, SECTION 311 The material contains the following ingredieot(s) which b considered hazardous if spilled in navigable waters. Ingredient Petroleum Hydrocarbon Reportable Quantity Film or sheen upon or discoloration of the water surface or adjoining shoreline HAZARDOUS MATERIALS TRANSPORTATION REGULATIONS, 49 CFR 171-178 Not Applicable FOREIGN REGULATIONS CANADIAN HAZARDOUS PRODUCTS ACT (WHMIS) The material b not a WHMIS Controlled Product STATE REGULATIONS CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1984 ("PROPOSITION 65") The material does not contain ingredients) subject to the Act PENNSYLVANIA WORKER AND COMMUNITY RIGHT TO KNOW ACT This material does not contain any ingredients) subject to the Act Nonbazardous ingredients) information b withheld as trade secret in accordance with Section 11 of the Act MSDS Code: HYDC0020 DATE OF LATEST REVISION/REVIEW: DEPARTMENT RESPONSIBLE FOR MSDS: PRODUCT INFORMATION CONTACT: 8/89 * Replaces MSDS dated 4/89 Environmental and Occupational Health Services MSDS Analyst Conoco Inc. (713) 293-5550 HYDC0020/August 1989 SAL 000006639 4 KS128 The above data are based on tests, experience, and other information which Conoco believes reliable and are supplied for informational purposes only. However, some ingredients may have been purchased or obtained from third-party manufacturers. In these instances, Conoco, in good faith relies on information provided by those third parties. Since conditions of use are outside our control, CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA. NOTHING CONTAINED HEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA THE MATERIAL DESCRIBED, OR ITS USE FOR ANY SPECIFIC PURPOSE. EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. HYDC0020/August 1989 5 000006640 SAL CHESTERTON MATERIAL SAFETY DATA SHEET G s1 79 A. W. CHESTERTON COMPANY Middlesex Industrial Park/Route 93, Stoneham, MA 02180 Section I emergency leiepnona no. 01/-439-7UQO (Day) 617-438-7013 (Night) Date of Prap. September 1, 1987 MSDSNo. 122-2 Product Name 256 Gel Cleaner HAZARDOUS MATERIALS IDENTIFICATION SYSTEM (HMIS) 4 Severe Hazard 3 Serious Hazard 2 Moderate Hazard HEALTH FLAMMABILITY 2 3 1 Slight Hazard REACTIVITY 1 0 Minimal Hazard Personal Protection - Sm Secton VIM Space! Pmacfon Inlonmtion Genera/ Use end Precautionary Information Removes grease and oil without scrubbing. The principal hazard is from exposure to high vapor concentrations. Vapor build-up wd most frequently occur in poorly ventilated or enclosed areas. Frequent shin contact could defat tw skin. The produet also classified as flammable. Section II - HAZARDOUS INGREDIENTS fngredlents/Synonyma CAS No. % Wt Stoddard Solvent 5052-41 -3 40-45 Potassium Hydroxide 1310-58-3 1-3 Isopropyl Alcohol 67-63-0 5-10 OSW-efl . mfmt 500 2900 jeoffny am mffmt 100 52S Vapor Pressure 10 mm Hg 400 960 (c*iling)2 400 980 90 mm Hg Initial Bolling Point 82*C (180*F) Section III - PHYSICAL DATA Percent Volatile (by volume) 82 Vapor Oenalty >1 (Air. 1) Evaporation Rata <1 (Ether. 1) Weight Par QaBon 7.2 t (0,8 kg/1) Section IV - FIRE AND EXPLOSION DATA Hash Point 32C (90BF) Closed Cup LL 0.9% Extlngutahlng Media Carbon Dioxide, dry chemical, foam or water fog DOT Shipping Name Compounds. Craning, Liquid DOT Hazard Class Flammable Liquid DOT UN/HA a NA1993 Unuaual Eire and Explosion Hazards None Special Fire Fighting Procedures Cool exposed container* with water. Recommenu FWefighlers wear seif-contained breaming apparaka. MW CHESTERTON CO . 17 Ml Rip* fWxrva eAog UIPlMTUOl SAL 000006641 179 Product Name: 256 Got Cleaner Sadion V -- REACTIVITY DATA Data: Saotambar 1 iQft7 Stability Stable Hazardous Decomposition Products Carbon Monoxide, AJdehydes and otiter toxic Conditions to Avoid Open names end red hot surfaces. Hazardous Polymerization Materials to Avoid Strong oxidbers like liquid chlorine and concentrated oxygen. a May Occur D Will Not Occur Section VI -- HEALTH HAZARD DATA Primary Pouts ot Exposure Under Normal Use Inhalation, skin and eye contact Acuta Effects Direct eye contact may result in eye rotation. inhalation ol vapor concentrations m excess of the PE1/TLV may result in eye and respiratory tract irritation and dizziness and headaches. Chronic Effects Prolonged or repeated skin contact may defat the skin and causa skin irritation. Emergency and First Aid Procedures Inhalation Remove to Fresh air. If not breathing, administer artificial respiration. Contact physician. Eye/Skin Contact Wash skin with soap and water. FXah eyes for at least 15 minutes with large amounts of water. Contact physician if initation persist. Ingastlon Do not induce vomiting. Contact physician immediately. Section VH -- SPILL OR RELEASE PROCEDURES Sfeps to be Taken In Case Materiel Is Spilled or Released Evacuate area. Provide adequate ventilation. Contain sp4 to a small area. Flush away from ignition sources with water. Pick up with absorbent material (e g., sand, clay, sawdust, etc.) and frartsler to a suitable container lor disposal. Waste Disposal Method Incinerate absorbed material. Check local, state and federal regulations. Section VIII -- SPECIAL PROTECTION INFORMATION Respiratory Protection Not normally needed. If PEUTLV is exceeded, use approved organic vapor respirator. Ventilation No special requirements. If PEL/TLV is exceeded, provide adequate ventilation. Protective Gloves Chemical resistant gloves (e g., Butyl). Eye Profaction Salary goggles Other None Precautions In Handling and Storing Section IX -- SPECIAL PRECAUTIONS Keep containers dosed when not in use. Other Precautions None SAL 000006642 rh* Warmton conured hwen * bu*C on Oats prodded Horn MppUert ef the menta uw) and net on the mature leaf, end a Belated to M correct However, no rerranty w eipreesed or implied remaning fte aceurocy d the data. 3*ce te Irrlormwbn oonuhad here* mey be eccrted unev cuxlttom beyond our control, die pereone recervrtg t ahaf mate the* own determrudlon at the 9uib*y d the preduet lor the* particular purpoeee. CGHA 29 CPR Parte tiO 1240. till 99. 1917 21. lft I 94. tm S9 and 1959 MA *41 CWfl 21 OS G S3 33 Shell MATERIAL 97367 14 19) 24 HOUR EMERGENCY ASSISTANCE SAFETY DATA SHEET MSOS NUMBER 5.250-4 GENERAL MSDS ASSISTANCE PAGE 1 SHELL: 713-473-9461 CHEMTREC: 800-424-9300 SHELL: 713-241-4819 ACUTE HEALTH Q2 A1 , AEACTivmr 5 HAZARD RATING V * HlCM - 3 EXTREME 4 For acute and chronic health effects refer to the discussion in Section III *1 BE SAFE UM OUM MMMMJCT wen MroMumoM PASS (T OM M<InT SECTION I PRODUCT y TRIETHYLENE GLYCOL NAME CHEMICAL w TEG NAME V CHEMICAL K __ FAMILY V GLYCOL ^CODE 32378 SECTION II-A NO. P TRIETHYLENE GLYCOL 1 DIETHYLENE GLYCOL 2 TRIETHYLENE GLYCOL 3 TETRAETHYLENE GLYCOL PRODUCT/INGREDIENT COMPOSITION CAS NUMBER PERCENT MIXTURE 111-46-6 112-27-6 112-60-7 100 4.2 95 1.6 SECTION II-B NO. ACUTE ORAL LD50 1 14.8 G/KG - RAT 2 >15 G/KG - RAT 3 30.8 ML/KG - RAT ACUTE TOXICITY DATA ACUTE DERMAL LD50 11.9 G/KG - RABBIT NONE 20 ML/KG - RABBIT ACUTE IFttALATION LCSO NONE NONE SATO. AIR-6 HRS-RAT-NO DEATHS SECTION III HEALTH INFORMATION THE HEALTH EFFECTS NOTED BELOW ARE CONSISTENT WITH REQUIREMENTS UNDER THE OSHA HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200). EYE CONTACT PRODUCT IS MILOLY IRRITATING TO THE EYES. SKIN CONTACT PRODUCT IS SLIGHTLY IRRITATING TO THE SKIN. NOT FIND ANY SENSITIZATION TO OCCUR. SKIN SENSITIZATION TESTING IN 25 HUMAN VOLUNTEERS DID INHALATION GENERALLY CONSIDERED TO HAVE A LOW ORDER OF ACUTE INHALATION TOXICITY BUT VAPORS OF COMPONENT 1 MAY BE IRRITATING TO THE LUNGS. INGESTION baseo on Product testing, TOXICITY BUT INGESTION OF FATAL. AND LIVER DAMAGE. product is generally considered to have a low oroer of acute oral COMPONENT 1 MAY PROOUCE CNS DEPRESSION AND KIONEY DAMAGE. WHICH MAY SAL 000006643 BE - 5. -* r*(M4nfMJ PRODUCT NAME: TRIETHYLENE GLYCOL NSOS PAGE 5,2*0-4 2 SIGNS AND SYMPTOMS IRRITATION AS NOTED ABOVE. EARLY TO MODERATE CNS (CENTRAL NERVOUS SYSTEM) DEPRESSION MAY BE EVIDENCED BY GIDDINESS, HEADACHE. DIZZINESS AND NAUSEA; IN EXTREME CASES. UNCONCIOUSNESS AND DEATH MAY OCCUR. KIDNEY DAMAGE MAY BE EVIDENCED BY CHANGES IN URINE OUTPUT. URINE APPEARANCE OR EDEMA (SMELLING FROM FLUID RETENTION). LIVER DAMAGE MAY BE EVIDENCED BY LOSS OF APPETITE. JAUNOICE (YELLOWISH SKIN COLOR) ANO SOMETIMES PAIN IN THE UPPER ABDOMEN ON THE RIGHT SIDE. AGGRAVATED MEDICAL CONDITIONS PREEXISTING SKIN. EYE ANO RESPIRATORY OISQRDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS PROOUCT. IMPAIRED LIVER AND KIDNEY FUNCTIONS FROM PREEXISTING DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS PRODUCT. SECTION IV NO. PCL/TWA OSHA NONE ESTABLISHED- OCCUPATIONAL EXPOSURE LIMITS PEL/CE1LXNQ TLV/TWA ACQIH TLV/STEL OTHER SECTION V EMERGENCY AND FIRST AID PROCEDURES EYE CONTACT FLUSH EYES WITH PLENTY OF WATER FOR 19 MINUTES WHILE HOLDING EYELIOS OPEN. GET MEDICAL ATTENTION. SKIN CONTACT LUSH SKIN WITH WATER. IF IRRITATION OCCURS. GET MEDICAL ATTENTION. INHALATION REMOVE VICTIM TO FRESH AIR AND PROVIOE OXYGEN IF BREATHING IS DIFFICULT. GET MEDICAL ATTENTION. INGESTION DO NOT GIVE LIQUIDS IF VICTIM IS UNCONSCIOUS OR VERY DROWSY. OTHERWISE. GIVE NO MORE THAN 2 GLASSES OF WATER ANO INDUCE VOMITING BY GIVING 30CC (2 TABLESPOONS) SYRUP OF IPECAC.* IF IPECAC UNAVAILABLE. GIVE 2 GLASSES OF WATER AND 1N0UCE VOMITING BY TOUCHING FINGER TO BACK OF VICTIM'S THROAT. KEEP VICTIM'S HEAD 8EL0W HIPS WHILE VOMITING. GET MEDICAL ATTENTION. IS NOTE TO PHYSICIAN IF VICTIM IS A CHILD. GIVE NO MORE THAN 1 GLASS OF WATER ANO 1SCC (1 TABLESPOON) SYRUP OF IPECAC. IF SYMPTOMS SUCH A$ LOSS OF GAG REFLEX, CONVULSIONS OR UNCONSCIOUSNESS OCCUR BEFORE EMESIS, GASTRIC LAVAGE SHOULO BE CONSIDERED FOLLOWING INTUBATION WITH A CUFFED ENDOTRACHEAL TUBE. SECTION VI NONE IDENTIFIED. SUPPLEMENTAL HEALTH INFORMATION iCTXON VII BOILING POINT: 540 (DEG F) PHYSICAL OATA SPECIFIC GRAVITY: 1.1 (H20*1) SAL 000006644 VAPOR PRESSURE: <0.01 * (MM HG) 68 DEG F PRODUCT NAME: TRXETHYLENE GLYCOL MELTING POINT: 19 <DEG FJ SOLUBILITY: (IN WATER) EVAPORATION RATE (N-BUTYL ACETATE 1): 0-001 COMPLETE APPEARANCE ANO ODOR: COLORLESS. SLIGHTLY VISCOUS LIQUID. MILD ODOR. Gj r:; r? 3 3 KSDS PAGE VAPOR DENSITY: 5 <AlR*t) 8,280-4 3 SECTION VIII FIRE AND EXPLOSION HAZARDS FLASH POINT ANO METHOO: 305 OEG F TCC FLAM4ABLE LIMITS /% VOLUME IN AIR LOWER: N/AP UPPER: N/AP EXTINGUISHING MEDIA USE WATER FOG. "ALCOHOL* FOAM. DRY CHEMICAL OR C02. SPECIAL FIRE FIGHTING PROCEDURES AND PRECAUTIONS MATERIAL will not BURN UNLESS PREHEATED. DO NOT ENTER CONFINED FIRE SPACE WITHOUT FULL BUMCER GEAR (HELMET WITH FACE SHIELD, BUNKER COATS, GLOVES AND RUBBER BOOTS), INCLUDING A POSITIVE PRESSURE NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED CONTAINERS WITH WATER. SECTION IX REACTIVITY STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR CONDITIONS AND MATERIALS TO AVOID: AVOID CONTACT WITH STRONG OXIDIZING AGENTS HAZARDOUS DECOMPOSITION PRODUCTS CARBON MONOXIDE ANO UNIDENTIFIED ORGANIC COMPOUNDS MAY BE FORMED DURING COMBUSTION. SECTION X EMPLOYEE PROTECTION RESPIRATORY PROTECTION USE A NIOSH-APPROVED RESPIRATOR AS REOUIREO TO PREVENT OVEREXPOSURE. IN ACCORD WITH 29 CFR 1910.134. USE EITHER AN ATMOSPHERE-SUPPLYING RESPIRATOR OR AN AIR-PURIFYING RESPIRATOR FOR ORGANIC VAPORS. PROTECTIVE CLOTHING AVOIO CONTACT WITH EYES. WEAR CHEMICAL GOGGLES IF THERE IS LIKELIHOOD OF CONTACT WITH EYES. AVOID PROLONGED OR REPEATED CONTACT WITH SKIN. WEAR CHEMICAL-RESISTANT GLOVES AND OTHER CLOTHING AS REQUIRED TO MINIMIZE CONTACT. ADDITIONAL PROTECTIVE MEASURES USE VENTILATION AS REQUIRED TO CONTROL VAPOR CONCENTRATIONS. SHOULD BE AVAILABLE FOR EMERGENCY USE. EYE WASH FOUNTAINS ANO SAFETY SHOWERS SECTION XI ENVIRONMENTAL PROTECTION SPILL OR LEAK PROCEDURES MAY BURN ALTHOUGH NOT READILY IGNITA8LE. USE CAUTIOUS JUDGMENT WHEN CLEANING UP LARGE SPILLS. LARGE SPILLS WEAR RESPIRATOR ANO PROTECTIVE CLOTHING AS APPROPRIATE. SHUT OFF SOURCE OF LEAK IF SAFE TO 00 SO. DIKE ANO CONTAIN. REMOVE WITH VACUUM TRUCKS OR PUMP TO STORAGE/SALVAGE VE5SELS. SOAK UP RESIDUE WITH AN ABSORBENT SUCH AS CLAY, $ANO OR OTHER SUITABLE MATERIAL; DISPOSE OF PROPERLY. FLUSH AREA WITH WATER TO REMOVE TRACE RESIDUE. SMALL SPILLS TAKE UP WITH AN ABSORBENT MATERIAL ANO DISPOSE OF PROPERLY. SAL 000006645 S3 s>c Shell ENVIRONMENTAL DATA SHEET )* U-71 EDS NUMBER 5.250 PAGE 1 PRODUCT ^ TRIETHYLENE GLYCOL PRODUCT CODE P 33376 r SECTION X NO. P TRIETHYLENE GLYCOL 1 DIETHYLENE GLYCOL PRODUCT/CONPOSITXON COMPONENT CAS NUNBEII MIXTURE 111-46"G PERCENT 100 4.2 SECTION IX NO. EHS RQ (LBS) <*1) SARA TITLE III INFORMATION EHS TPQ (LBS) C2) SEC 913 ( "3 ) 313 CATEGORY ( *4 ) 1 311/312 CATEGORIES C5) H- 1 ........................ ------------------- --------- ------------------------------------------------------FOOTNOTES...................-..................... ................................................................................... 1 - REPORTABLE QUANTITY OF EXTREMELY HAZARDOUS SUBSTANCE, SEC.302 2 * THRESHOLD PLANNING QUANTITY, EXTREMELY HAZARDOUS SUBSTANCE. SEC 302 3 TOXIC CHEMICAL. SEC 313 *4 - CATEGORY AS REQUIRED BY SEC 313 <40 CFR 372.65 C). MUST BE USED ON TOXIC RELEASE INVENTORY FORM S HAZARO CATEGORY FOR SARA SEC. 311/312 REPORTING HEALTH H-1 - IMMEDIATE (ACUTE) HEALTH HAZARD H-2 DELAYED (CHRONIC) HEALTH HAZARO PHYSICAL P-3 - FIRE HAZARD P-4 SUDDEN RELEASE OF PRESSURE HAZARO P-5 REACTIVE HAZARO SECTION III ENVIRONMENTAL RELEASE INFORMATION KEEP OUT OF SURFACE WATERS, SEWERS. AND WATERWAYS ENTERING OR LEADING TO SURFACE WATERS. NOTIFY AUTHORITIES IF ANY EXPOSURE TO THE GENERAL PUBLIC OR ENVIRONMENT OCCURS OR IS LIKELY TO OCCUR. SECTION IV RCRA INFORMATION PLACE IN AN APPROPRIATE DISPOSAL FACILITY IN COMPLIANCE WITH LOCAL REGULATIONS. SAL 000006646 ,,388 *. ?f~ UCT NAME: TRIETHYLENE GLYCOL EDS PAGE B.2SO 2 THE INFORMATION CONTAINED HEREIN IS BASED ON THE DATA AVAILABLE TQ US AND IS BELIEVED TO BE CORRECT HOWEVER. SHELL MAKES NO WARRANTY. EXPRESSED OR IMPLIEO REGARDING THE ACCURACY OF THESE OATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF. SHELL ASSUMES NO RESPONSIBILITY FOR INJURY FROM THE USE OF THE PRODUCT DESCRIBED HEREIN. DATE PREPARED:OCTOBER 15. 1997 ....................... .................... SHELL OIL COMPANY ENVIRONMENTAL AFFAIRS P. 0. BOX 4220 HOUSTON. TX 77210 FOR ADDITIONAL INFORMATION ON THIS ENVIRONMENTAL OATA PLEASE CALL (713) 241-2252 FOR EMERGENCY ASSISTANCE PLEASE CALL SHELL: (713) 473-9461 CHEMTREC: (600) 424-9300 c SAL 000006647 ZQ-Sep-89 Conoco Material Safety Data Sheet C I 04 3 Page l material identification number NAME * IPBCOOaO : RICH SPONGE OIL, RICH OIL ChEmICAL FAMI.Y : PetroleumHydrocs^Dorio TRADE NAMES /SYNONYMS S Absorber rJll Absorber Lean Oil CAS NUMBER nF PA RATING WHMIS CLASSIFICATION '.ct Aoblicable. : Mixture : Health: 1 Flammabihtv: 3 Reactivity: O : MANuFACTuRER/D1STRIBUTOR: Conoco Inc. P.O. Box 2197 Houston, TX GENERAL INFORMATION PHONE RAnSPORTAr1UN EMERGENCY PHONE MEDICAL EMERGENCY PHONE 7?252 : 1 -{ 7 I 3 ) 293-555u : 1 - <B00)424-9JUU : 1 -(800)441 -363? CSHA HAZARD determination "lacafL'Ous ingreoients CAS Number ^yoroc arbor. 5 (Aromatic It Paraffinic) Napn tnalene -ydrrqen buJtioe Mixture 91-20-3 / 783-06 -4 * Fiegji3teC as a toxic chemical under section 313 of Title III of the Super!una Amendments and Reauthorization Act of 1986 and 40 CFR part 372. hazardous Physical Properties: Class IA flammable Liauid per NFPA Code No. 30*1907. me material is hazardous as defined by OSHA's Hazard _ ofi.mur. ic a t l or. Standard, 29 CFR 1910.1200. Pr^sICAL DATA vapor Pressure v.iuor Density Solubility in Nater o r :l, Color AC-; Gravity D i s t 111 a 11 or. Range Approximately 2 PS 1 & lOO deg FNot Applicable Sliqhtly soluble L lqu i d Drpnze 15 - 20 100 700 deg F SAL 00000664-8 5/ie^ct'i /t,a , <toi /co CI04 3 .Li 'jcp u 'r oco Material Safety Data Sheet Page J ttSDS No: Iu&COCo. Mi i/nlcDUUS h r 'i I I .' I I r lnstadi 1 i tv : -t able. tia:ardoub Oetompoiltion Products: Oxides of carcon anc sulfur. Incomplete comousticn may produce carbon monoxice. Londxtions to Avcio: Oxidizing materials, neat, flame. Hazardous Pu i vmtr i zat ion: Will not occur. *******tt********4*4*t**4#***t******** FIRE AND EXPLOSION DATh riash k-'omt; Less than ambient h f RE AND EXPLOSION HAZARDS 1. i a' .\> 1 A h 1 in-ir* ib l c Liquid l hi k `A ' . L > i iNOUlSHlNG MEDIA Dry Chemical- C02 . r o am. jPllIhL rlRt EiuHllND iN&TFuC1 I'jwi ,poci.il I ire i Liiiit mp Pri.'i'i'ijur^1. : water may oe iriettective, but wster snoulc oe used to Keep, f i re-e .i posed containers cooi. If a leak or spill nas not ignited, use water spray to disperse the vapors anc to protect personnel attempting to stop a leak. Water spray may be used to T lusn spills away trom exposures. unusual Fire and Explosion ha:jras: Hiqniy tlammaoie. Products ot combustion may contain .:rhon monoxide, carbon dioxide and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. HEAlIH hazard INFORMATION . rinary mcutes of b<.posure/Entry: Skin, inhalation. signs and Symptoms of txposure/Medica1 Conditions Aggravated by Exposure: Studies with mice or rats have snown tnat some petroleum distillates have caused either damage or tumors of the Kidneys or tumors of the liver. However, kidney effects were not seen m similar studies involving guinea pigs, ouqs. or monkeys. Also, the significance of tr.e liver o000066^9 AL rS-Seo-89 Conoco Material Safety Data Sheet C I04 j Page 3 MSDS No: IPBC0060 {HEALTH HAZARD INFORMATION - CONTINUED) tutors in rodents is highly speculative. Mouse skin painting studies have shown that petroleum middle distillates (boiling range of 100-700 deg naphtha, jet fuel, diesel fuel, kerosene, etc.) can cause skin cancer when repeatedly applied and never washed from tne animal's skin. The relative significance of this to rjiT-an neaith is uncertain since the petroleum distillates ere not wasneo from tne skin and resulting skin effects i irritation, :dii aamaqe, etc..' may play a roie in tne tumorigenic response. A few studies have shown that washing tne animai s s*in with soap and water between treatments greatly -educes the carcinogenic effect of some petroleum Tne product contains petroleum hydrocarbons, and as with many petroleum products, it may cause irritation to the eyes, lungs, or skin after prolonged or repeated exposure. E-it-eme exposure or aspiration into the lungs may cause pneumonia. Cverexposure may cause weakness, headache, nausea, confer ion, Dlurre-i w. ion, drowsiness, and other nervous system eftects; greater exposure may cause dizziness, spurred speech, flushed face, unconsciousness, or c or.v u Is 1 ons . Naphthalene is a potential irritant to eyes, skin, and lungs ana may damage the blood, eve, and kidney after prolonged or -epeated exposure. Hydrogen sulfice can be irritating at low concentrations to tne eyes, skm, and respiratory tract. At higher concentrat ions, loss of ability to smell hydrogen sulfide, -esoiratory caraiysis, and death may occur. Carcinogenicity None ot tne components in this chemical is listed by I ARC, nTP, uSHA, or ACGIH as a carcinogen. exposure Limits tor RICH SPUNuE OIL, RICH OIL I lV ** '.hCuIH) ; None Established PEL (OShA) : None Established Other Applicable Exposure Limits: Exposure Limits for Naphthalene AE_ (DuPont): None Established T L v ** (ACGIH) : 10 ppm, 50 mg/m3 STEL 15 ppm, 75 mg/mj SAL 000006650 CXo4 3 :8-ueu bv t_.,' . lto Material Safety Data Sheet Pa(?e * MSDS Nc: IPBC006 tiUAl m HAZARD INf-ORMAT IQN - CONTINUED) kcL iU`jHM| : 10 ppm, 50 mg/m3 STEL 15 ppm, 75 mg/iri3 Exposure Limits for Hydrogen Sulfide AtL r LV PEL iDuPontl ** lACGlH) iUCHA) : 10 ppm : 10 ppm f STEL 15 : 10 ppm, STL 15 8 i 12 Hr. TWA 14 mg/m3 ppm, 21 mg/m3 14 mg/m3 ppm, 21 mg/m3 AtL is DuPont's Acceptaole Exposure Limit. ** T LV is a registered trademark. safety Precautions Do not oreathe vapor or mist. Avoid contact with eyes. Avoid contact with skin. Wash thoroughly after handling. Wash clothing after us e. f- I RSI AID SKIN CONTAlI In case of contact, immediately wash skin with soap anc plenty of water. It irritation develops, consult a physician. EYfc CONTACT In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Call a physician. INGEST ION If swallowed, do not induce vomiting. Give large quantities of water. Never give anything Py mouth to an unconscious person. Call a physiclan. INHALATION If hydrogen sulfide is present, the following applies: Rescue personnel must use good oudgment to minimize their risi- . Because hydrogen sulfide can cause death, rescuers must wear positive-pressure, full-facepiece, self-contained or supp11ed-alr, NIOSH-approved respirators before attempting the rescue. Remove victim to fresh air immediately. If not breathing, give artificial respiration. If breathing difficult, qive oxygen. Keep warm and at rest. Call physiclan. is a MU I ES 10 Pn V = iL AN Gastric lavage by qualified medical personnel may be consicered, depending on cuantity of material ingested. SAL 000006651 2S-Sep-^ Conoco Material Safety Data Sheet CIo4 3 Page N MSDS No: U'UCuO.v' -RQTECTION INFORMATION jererallv Applicable Control Measures and Procedures Ventilation: Sufficient ventilation to maintain a tmospne r i c concen t r a t ions Cielow permissible exposure limits Persona 1 quipnent Respiratory Protection: Select appropriate NlOSH-approved respiratory protection equipment where atmospheric concen t r a t ions exceed pe^rrussiole exposure limit. Protective Gloves: Neoprene or NBfi recommended. Eye Protection: occur. Face shield is recommended it splasning may Other i ve Equlpmen t: None normally required. SPi-L, LEAK AND disposal information Sdi*1, Leix, or Release NOTE: Review FIRE AND EXPLOSION HAZARDS ana SAFETY PRECAUTIONS oefore proceeding with clean up. Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clean up. Remove source of heat* sparks, flame, impact, friction or electricity. Dike spill. Prevent liquid trom entering sewers, waterways or low areas. Recover free liquid for reuse or reclamation. Soak up with sawdust, sand, oil dry or other absorbent ma te r i a 1 . Nonrecoverabie material, contaminated soil, and debris should be placed m proper containers for ultimate disposal. waste Disc os a i Treatment, storage, transportation and disposal must be in accordance witn applicable Federal, State/Provmnal, and Local reguia tions. Recycle as much of the recoverable material as possible. 3-1PCING INFORmATION DOT Proper Shipping Name : Petroleum distillate Hazard Class : i jn.'NA r; i. : Flammable UN 1 260 liquid SAL 000006652 C I 04 3 2B-S ep-69 Lor.oco Material Safety Data Sheet Page 6 MSDS No: IPECOOt, (SHIPPING INFORMATION - CONTINUED) DOT LaoellG) LOT Placard s Flammable liquio : Flammable blUKAGfc LUND I 1 IONS Store in accordance with Notional Fire Protection Assn regulations. i'le above -j a' a are based on tests, experience, ana other mt or7 a 11 :*r hicn Conoco believes reliable and are suDDlied for informational purposes only. However, some ingredients may nave been purcnasea oobtained from tnird-party manufactures. In these instances, Conoco, ;r good faith, relies on information provided by those third oarties. Since conditions of use are outside our control, CONOCO DISCLAIMS ANY LlAbUITY FUR DAMAGE OR INJURY WHICH RESULTS FROM USE OF THE ABOVE DATA. NOTHING CONTAINED HEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE MATERIAL DESCRIBED, OR ITS USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. Date of latest Revision Responsibility for MSDS : 89/09/28 : Env. & Occ. Health Services Conoco 2 nc. PO Box 2197 Houston, TX 77252 713-293-5550 SAL 000006653 20-Sep-89 Conoco Material Safety Data Sheet C I 04 1 Page 1 MATERIAL I DENT IF I CATION NUMBER NAME : ITAIL080 : PBC DEETHANIZER TAIL GAS CHEMICAL FAMILY TRADE NAMES / SYNONYMS Deethanizer OH Gas Alky Deethanizer OH s PetroleumHydrocarbons : Gas CAS NUMBER NFPA RATING WHMIS CLASSIFICATION Not Applicable. : Mixture : Health: 1 Flammability: 4 Reactivity: O : MANUFACTURER/DISTRIBUTOR: Conoco Inc. P.O. Box 2197 Houst on, TX uENtKAL INFORMATION PHONE TRANSPORTATION EMERGENCY PHONE MEDICAL EMERGENCY PHONE **** C5HA mAZARD determination 77252 : 1 - { 7 l J ) 2Vj > : 1-(800)424-9GOu : l-{800)441-303/ ********#** Hazardous Ingredients CAS Number Hydrogen Sulfide Hydrocarbons (Gaseous Alkanes) 7783-06-4 Mixture Hazardous Physical Properties: Compressed Gas, Flammable. The material is hazardous as defined by OSHA`s Hazard Communication Standard, 29 CFR 1910.1200. fl-##**-***-**-*******'#**#####*'#'*#************#*#**-**-*-*'** PHYSICAL data Vapor Pressure Vapor Density Solubility in Water F orm Color Specific Gravity Distillation Range 100 - 200 PS I > 1 (Air = 1.0) Slightly soluble Gas Colorless Not Applicable -128 to +30 deg F (contains pthinr through butane**.) SAL 000006654 (,f" I? 3 CI04 1 JU- Sep-89 Conoco Material Safety Data Sheet Page 2 MSDS No: ITAIlO. HAZARDOUS Rf ACT 1VI TV Instability : Stable. Hazardous Decomposition Products: Oxides of carbon. May produce carbon monoxide by incomplete combustion. Conditions to Avoid: flammable gas. Reactive with oxidizing agents. Hazardous Polymerization: Will not occur. FIRE AND EXPLOSION DATA flash Point: Below ambient. FIRE AND EXPLOSION HAZARDS Handle and store in accordance with NFPA procedure for Compressed Gas, Flammable. EX I 1NGU1SHING MEDIA If gas has ignited, do not extinguish. Allow to burn out. Stop gas flow. special fire fighting instructions Special Fire Fighting Procedures: Stop flow of gas. Use water to keep fire-exposed containers cool and to protect personnel effecting the shutoff. If a leak or spill has not ignited, use water spray to disperse the gas and to protect personnel attempting to stop a leak. Unusual Fire and Explosion Hazards: Highly flammable. P'roducts of comoustion may contain carbon monoxide, carbon dioxide and other toxic materials. Oo not enter enclosed or confined space without proper protective equipment including respiratory protection. HEALTH HAZARD INFORMATION Primary Route of Exposure/Entry: Inhalation. Signs and Symptoms of Exposure/Medica1 Conditions Aggravated by Exposure: Overexposure may cause weakness, headache, nausea, confusion, blurred vision, drowsiness, and other nervous system effects;, greater exposure may cause dizziness. SAl 000006655 28-Sep-99 Conoco Material Safety Data Sheet C I 04 1 Page 3 MSDS No: ITAIL080 (HEALTH HAZARD INFORMATION - CONTINUED) slurred speech, flushed face, unconsciousness, or convulslone. Hydrogen sulfide can be irritating at low concentrations to the eyes, skin, and respiratory tract. At higher concentrations, loss of ability to smell hydrogen sulfide, respiratory paralysis, and death may occur. Large concentrations m ambient air can cause asphyxiation due to oxygen displacement. May cause frostbite when skin is exposed to compressed air. None of the components in this chemical is listed by I ARC, NTP, OSHA, or ACGIM as a carcinogen. Exposure Limits for PBC DEETHANIZER TAIL GAS TLV ** (ACGIH) : None Established PEL (OSHA) : None Established Other Applicable Exposure Limits: Exposure Limits for Hydrogen Sulfide AEL TLV PEL (DuPont): ** (ACGIH) : (OSHA) : 10 ppm - 8 & 12 Hr. TWA 10 ppm, 14 mg/m3 STEL 15 ppm, 22 mg/n>3 10 ppm, 14 mg/m3 STEL 15 ppm, 21 mg/m3 * AEL is DuPont's Acceptable Exposure Limit. * * TLV is a registered trademark. Safety Precautions Do not breathe vapor or mist. Avoid contact with eyes. Avoid contact with skin. Wash thoroughly after handling. Wash clothing after use. ****'***#*#******#*************#*******#***#*****###****#*******# FIRST AID SKIN CONTACT In case of contact, immediately wash skin with soap and plenty of water. If irritation develops, consult a physician. EVE CONTACT In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Call a physician. 000006656 SAL C I 04 1 28-Sep-89 Conoco Material Safety Data Sheet Page 4 USDS No: ITAILO (FIRST AID - CONTINUED) INHALATION If hydrogen sulfide is present, the following applies: Rescue personnel must use good judgment to minimize their risk. Because hydrogen sulfide can cause death, rescuers must wear positive-pressure, fu11-facepiece, self-contained or supp1led-air, NlOSH-approved before attempting the rescue Remove victim to fresh aiirr immediately. If breathing stops, beqin resuscitation. If breathing is difficult, give oxygen. Keep victim warm and at rest. Seek medical attention. PROTECTION INFORMATION Generally Applicable Control Measures and Procedures Ventilation: Sufficient ventilation to maintain atmospheric concentrations below permissible exposure limits Personal Protective Equipment Respiratory Protection: Select appropriate NIOSH-approved respiratory protection equipment where atmospheric concentrations exceed permissible exposure limit. Protective Gloves: None required. Eye Protection: Use a full facepiece with the when the atmospheric concentration of hydrogen exceeds the permissible exposure limit. respirator sulfide Other Protective Equipment: None normally required. SPILL, LEAK AND DISPOSAL INFORMATION Spill, Leak, or Release NOTE: Review FIRE AND EXPLOSION HAZARDS and SAFETY PRECAUTIONS before proceeding with clean up. Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clean up. Evacuate personnel, thoroughly ventilate area, use self-contained breathing apparatus. Remove source of heat, sparks, flame, impact, friction or electricity. Keep upwind of leak - evacuate until gas has dispersed. Haste Disposal When feasible, vapors should be dispersed mechanically. SAL 000006657 2d-Sep-8V Conoco Material Safety Data Sheet CI 04 1 Page 5 MSDS No: ITAIL080 SHIPPING INFORMATION Not to be transported by truck, rail, air, or water. STORAGE CONDITIONS Store in accordance with National Fire Protection Assn regulations. The above data are based on tests, experience, and other ir.formation which Conoco believes reliable and are supplied for informational purposes only. However, some ingredients may have been purchased or oDtained from third-party manufactures. In these instances, Conoco, in good faith, relies on information provided by those third parties. Since conditions of use are outside our control, CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM USE OF THE ABOVE DATA. NOTHING CONTAINED HEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FRDM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE MATERIAL DESCRIBED, OR ITS USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAI PURPOSE 15 KNOWN TO CONOCO. Date of latest Revision Responsibility for MSDS 89/09/28 Env. &. Occ. Health Conoco Inc. PO Box 2197 Houston, TX 77252 713-293-5550 Services 000006658 C I 04 0 28-Sep-89 Conoco Material Safety Data Sheet Page 1 MATERIAL IDENTIFICATION NUMBER NAME : ITAIL097 s SOUR WATER STRIPPER ACID GAS CHEMICAL FAMILY TRADE NAMES / SYNONYMS Sour Water Stripper Sour Water Stripper : Petroleum Hydrocarbons 4 Overhead Gas Gas CAS NUMBER NFPA RATING WHMIS CLASSIFICATION Not Applicable. : Mixture : Health: 1 Flammability: 4 Reactivity: O : MANUFACTURER/DISTRIBUTOR: Conoco Inc. P.O. Box 2197 Houston, TX GENERAL INFORMATION PHONE TRANSPORTATION EMERGENCY PHONE MEDICAL EMERGENCY PHONE 77252 : 1-(713)293-5550 : 1-(800)424-9300 : 1 -<800)441-3637 QSHA HAZARD DETERMINATION Hazardous Ingredients CAS Number Hydrogen Sulfide 1 Hydrocarbons (Gaseous Alkanes) 7703-06-4 Mixture Hazardous Physical Properties: Compressed Gas, Flammable. The material is hazardous as defined by OSHA's Hazard Communication Standard, 29 CFR 1910.1200. PHYSICAL DATA Vapor Pressure Vapor Density Solub Llity in Water F o rm Color D 15 t 1 . 1 ation Range 50 - 150 PSI 9 100 deg F > 1 (Air = 1 0) Very soluble Gas Colo r less -258 to +100 deg F (cont a ins methane through pentanes) o0oO SM- c.,lH A CO/7 3/ C I 04 0 2Q-Sep-99 Conoco Material Safety Data Sheet Page 2 MSDS No: ITAiv HAZARDOUS REACTIVITY Instability : Stable. Hazardous Decomposition Products: Oxides of carbon, nitrogen and sulfur; sulfur if burned in oxygen-deficient a tmosphere. Conditions to Avoid: Flammable gas. Reactive with oxidizing agents. Heat can be generated if reacted with alkaline materials. Wet gas is corrosive. Hazardous Polymerization; Will not occur. Flftt AND EXPLOSION DATA Flash Point: Less than ambient. I IKE AND EXPLOSION HAZARDS Handle and store in accordance with NFPA procedure for Compressed Gas, Flammable. EX I INGUISHING MEDIA If gas has ignited, do not extinguish. Allow to burn out. Stop gas flow. SPECIAL FIRE FIGHTING INSTRUCTIONS Special Fire Fighting Procedures: Stop flow of gas. Use water to keep fire-exposed containers cool and to protect personnel etfecting the shutoff. If a leak or spill has not ignited, use water spray to disperse the gas or vapor and to protect personnel attempting to stop a leak. u nus u.i I 1ire and E xplos 1 on Haz a p rod ucts of c omb us tion m ay con t a iox 1 de and 0 the r toxic ma 1ten a c onf ined spa c e w ithout P roper 0 r esp iratior y P rot ection. ds: Highly flammable, in carbon monoxide, carbon s. Do not enter enclosed or otective equipment including HEALTH HAZARD INFORMATION Primary Route of Exposure/Entry: Inhalation. 000006660 Signs and Symptoms of Exposure/Medical Conditions Aggravated by E xoosure: Overexposure may cause weakness, headache, nausea, 28-Sep-09 Conoco Material Safety Data Sheet C104 0 Page 3 MSDS No: ITAIL097 (HEALTH HAZARD INFORMATION - CONTINUED) confusion, blurred vision, drowsiness, and other nervous system effects; greater exposure may cause dizziness, slurred speech, flushed face, unconsciousness, or convuIs ions. Hydrogen sulfide can be irritating at low concentrations to the eyes, skin, and respiratory tract. At higher concentrations, loss of ability to smell hydrogen sulfide, respiratory paralysis, and death may occur. Large concentrations in ambient air can cause asphyxiation due to oxygen displacement. May cause frostbite when skin is exposed to compressed gas. Carcinogenicity None of the components in this chemical is listed by 1ARC, NTP, QSHA, or ACGIH as a carcinogen. Exposure Limits for SOUR WATER STRIPPER ACID GAS TLV PEL (ACGIH) (OSHA) None Established None Established Otner Applicable Exposure Limits: Exposure Limits for Hydrogen Sulfide AtL (DuPont) TLV ** (ACGIH) PEL (OSHA) 10 ppm 10 ppm, STEL 15 10 ppm, STEL 15 0 &. 12 Hr. TWA 14 mg/m3 ppm, 21 mg/m3 14 mg/m3 ppm, 21 mg/m3 AEL is DuPont's Acceptable Exposure Limit, *# TLV is a registered trademark. Saf e ty P re cau 11 ons Do not bre athe vapor or mist. Avoid contact with eyes. Avoid contact wi th skin. Wash thoroughly after handling. Wash clothing after use. ** **************************+**** h 1 AST A ID SKIN CONTACT In case of contact, immediately wash skin with soap water. If irritation develops, consult a physician. for possible frostbite. and See plenty of physiclan EYE CONTACT ooooo^61 CI04 0 2S-Sep-09 Conoco Material Safety Data Sheet Page 4 MSDS No: ITAILC (FIRST AID - CONTINUED) In case of contact, immediately flush eyes with plenty of water * at least 15 minutes. Call a physician. See physician for possible frostbite. INHALATION If hydrogen sulfide is present, the following applies: Rescue personnel must use good audgment to minimize their risk. Because hydrogen sulfide can cause death, rescuers must wear posltive-pressure, full-facepiece, self-contained or supplied-air, N10SH-approved respirators before attempting the rescue. Remove victim to fresh air immediately. If not breathing, give artificial respiration. If breathing difficult, give oxygen. Keep warm and at rest. Call physlclan. is a PROTECTION INFORMATION Generally Applicable Control Measures and Procedures Ventilation: Sufficient ventilation to maintain atmospheric concentrations below permissible exposure limits Personal Protective Equipment Respiratory Protection: Select appropriate NIOSH-approved respiratory protection equipment where atmospheric concentrations exceed permissible exposure limits. Protective Gloves: None required. Eye Protection: Use a full facepiece with the respirator when the atmospheric concentration of hydrogen sulfide exceeds the permissible exposure limit. Other Protective Equipment: None normally required. SPILL, LEAK AND DISPOSAL INFORMATION Spill, Leak, or Release NOTE: Review FIRE AND EXPLOSION HAZARDS and SAFETY PRECAUTIONS before proceeding with clean up. Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clean up. Evacuate personnel, thoroughly ventilate area, use self-contame breathing apparatus. Remove source of heat, sparks, flame, impac* friction or electricity. Keep upwind of leak - evacuate until gas has dispersed. Dissipate vapor with water spray. SAL 000006662 28-Sep-09 Conoco Material Safety Data Sheet CI 04 0 Page 5 MSDS No: ITA1L097 (SPILL, LEAK AND DISPOSAL INFORMATION - CONTINUED) Waste Disposal Treatment, storage, transportation and disposal must be in accordance with applicable Federal, State/Provincla 1, and Local regulations. When feasible, vapors should be dispersed mechanically. SHIPPING INFORMATION Not to be transported by truck, rail, air, or water. STORAGE CONDITIONS Store in accordance with National Fire Prot ection Assn regulations. * *********************************************** **************************** The above data are based on tests, experien ce, and other information which Conoco believes reliable and are supp lied for informational purposes only. However, some ingredients ma y have been purchased or obtained from third-party manufactures. In these instances, Conoco, in good faith, relies on information provided by those third parties, Since conditions of use are outside our con t ro1, CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULT S FROM USE OF THE ABOVE DATA. NOTHING CONTAINED HEREIN SHALL C0NST1 TUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WI TH RESPECT TO THE DATA, THE MATERIAL DESCRIBED, OR ITS USE FOR ANY SPEC IFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. Date of latest Revision Responsibility for MSDS 89/09/28 Env. & Occ. Health Services Conoco Inc. PO Box 2197 Houston, TX 77252 713-293-5550 SAL 000006663 28-Seo-09 Conoco Material Safety Data Sheet CI039 Page 1 4 MATERIAL IDENTIFICATION NUMBER NAME 1TAIL040 CTU OVERHEAD/DEBUTANIZER GAS CHEMICAL FAMILY : Petroleum Hydrocarbons TRADE NAMES / SYNONYMS : Primary Tower Overhead Gas Crude Unit wet Gas LSR Stabilizer Overhead Gas CAS NUMBER NFPA RATING WHMIS CLASSIFICATION Not Applicable. Mix ture Health: l Flammability: 4 Reactivity: o MANUFACTURER/DISTRIBUTOR: Conoco Inc. P.0. Box 2197 Houston, TX GENERAL INFORMATION PHONE TRANSPORTATION EMERGENCY PHONE MEDICAL EMERGENCY PHONE 77252 : l-(713)293-5550 : 1 -(000)424-9300 : 1 -(800)441-3637 D5mA HAZARD DETERMINATION Hazardous Ingredients CAS Number Hydrocarbons (Gaseous alkanes) benzene Hydrogen Sulfide Mixture 71-43-2 7783-06-4 Regulated as a toxic chemical under section 313 of Title III of the Superfund Amendments and Re authorizalion Act of 1986 and 40 CFR part 372. Hazardous Physical Properties: Compressed Gas, Flammable Tne material is hazardous as defined by OSHA's Hazard Communication Standard, 29 CFR 1910.1200. hhySiCAL DATA vapor Pressure Vapor Density Solubility in Water Form C o lor API Gravity Distillation Range % 1O0 - 200 psi : > 1 (Air = 1.0) : Slightly soluble : Gas Colorless Not Applicaple -258 - +400 deg hydrocaroons, he molecular weight traces o t i qhe r SAL 000006664- cnMi cXo3 9 28-Sep-89 Conoco Material Safety Data Sheet (PHYSICAL DATA * CONTINUED) f Page 2 MSDS No: ITAILO- HAZARDOUS REACTIVITY Instability : Stable. Hazardous Decomposition Products: Oxides of carbon and sulfur. May produce carbon monoxide. Conditions to Avoid: Highly flammable gas. Reactive with oxidizing agents. Corrosive to many materials when wet. Hazardous Polymerization: Will not occur, FIRE AND EXPLOSION DATA (-lash Point: Below ambient. FIRE AND EXPLOSION HAZARDS Handle and store in accordance with NFPA procedure for Compressed Gas, Flammable. EXTINGUISHING MEDIA If gas nas ignited, do not extinguish. qjs. Allow to burn out. Stop flow of SPECIAL FIRE FIGHTING INSTRUCTIONS Special Fire Fighting Procedures: Stop flow of gas. Use water to keep fire exposed containers cool and to protect personnel effecting the shutoff. If a leak or spill has not ignited, use water spray to disperse the vapors and to protect personnel attempting to stop a leak . Unusual Fire and Explosion Hazards: Highly flammable. Products of combustion may contain carbon monoxide, carbon dioxide and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. HEALTH HAZARD INFORMATION Primary Routes of Exposure/Entryj Inhalation. SAL 000006665 Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: 28-Sep-B9 Conoco Material Safety Data Sheet CI03 9 Page 3 MSDS No: ITAI1040 (HEALTH HAZARD INFORMATION - CONTINUED) The product contains petroleum hydrocarbons which may cause irritation to eyes, skin, and lungs after prolonged or repeated exposure. Extreme exposure or aspiration into the lungs may cause pneumonia. Overexposure may cause weakness, headache, nausea, confusion, blurred vision, drowsiness, and other nervous system effects; greater exposure may cause dizziness, slurred speech, flushed face, unconsciousness, or convulsions. Large concentrations m ambient air can cause asphyxiation due to oxygen displacement. Contact with compressed or liquified gas may cause frostbite. Hydrogen sulfide can be irritating at low concentrations to the eyes, skin, and respiratory tract. At higher concentrations, loss of ability to smell hydrogen sulfide, respiratory paralysis, and death may occur. A few studies have indicated that workers exposed to high concentrations of benzene have a slightly incidence of leukemia. Benzene can also be toxic blood and blood-forming tissues. many years higher to the Carcinogenicity The following components are listed by IARC, NTP, GSHA, or ACGIH as carcinogens. A 'P' indicates a Proposed Carcinogen. Chemical IAR NTP OSH ACG Benzene XX X X DuPont controls the following chemicals as potential carcinogens : Benzene . Exposure Limits for CTU OVERHEAD/DEBUTANIZER GAS TLV ** (ACGIH) PEL (QSHA) Other : None Established : None Established : Exposure Limits for Petroleum Distillate PEL; 400 ppm, 1600 mq/m.) Other Applicable Exposure Limits: Exposure Limits for Benzene AEL T LV ** PEL (DuPont): (ACGIH) : (QSHA) : 1 ppm - 8 & 12 Hr. TWA 5 ppm - 15 Min. TWA 10 ppm. 30 mg/m3 (A2 ) 1 ppm - Q Hr. TWA 5 ppm - (Short term exposure limit) SAL 000006666 C I 03 9 28-Sep-09 Conoco Material Safety Data Sheet Page 5 MSDS No ITAIL040 [PROTECT ION INFORMATION - CONTINUED) Respiratory Protection: Select appropriate NI OSH-approved respiratory protection equipment where atmospheric concentrations exceed permissible exposure limit. Protective Gloves: None required. Eye Protection: Use a full facepiece with the respirator when the atmospheric concentration of hydrogen sulfide exceeds the permissible exposure limit. Other Protective Equipment: None required. SPILL, LEAK AND DISPOSAL INFORMATION Spill, Leak, or Release NOTE: Review FIRE AND EXPLOSION HAZARDS and SAFETY PRECAUTIONS before proceeding with clean up. Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clean up. Evacuate personnel, thoroughly ventilate area, use self-contained Oreathing apparatus. Remove source of heat, sparks, flame, impact, friction or electricity. Keep upwind of leak - evacuate until qas has dispersed. waste Disposal Treatment, storage, transportation and disposal must be m accordance with applicable Federal, State/Provmeia 1, and Local regulations. When feasible, vapors should be dispersed mechanically. * ****- SHIPPING INFORMATION * ** * * Not to be transported by truck, rail, air, or water. STORAGE CONDITIONS Store in accordance with National Fire Protection Assn regulations. 1ne above data are based on tests, experience, and other information wmch Conoco believes reliable and are supplied for informational purposes only. However, some ingredients may have been purchased or obtained from third-party manufactures. In these instances, Conoco, in good faith, relies on information provided by those third parties. Since conditions of use are outside our control, CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM USE OF THE ABOVE DATA. NOTHING CONTAINED HEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING SAL 000006668 28-Sep-89 Conoco Material Safety Data Sheet CI03 7 Page 1 MATERIAL IDENTIFICATION number NAME ITAIL010 ACID GAS/SOUR GAS (SULFUR PLANT) CHEMICAL FAMILY : Petroleum Hydrocarbons TRADE NAMES / SYNONYMS : Acid Gas Regenerator Overhead Gas Sulfur Recovery Unit Tail Gas NFPA RATING WHMIS CLASSIFICATION Not Applicable. : Health: 1 Flammability: 4 Reactivity: 0 : MANUFACTUR6R/DISTRIBUTDR: Conoco Inc. P.0. Box 2197 Houston, TX 77252 GENERAL INFORMATION PHONE : 1-(713)293-5550 TRANSPORTATION EMERGENCY PHONE : 1-(600)424-9300 MEDICAL EMERGENCY PHONE : 1 -(800)441 -3637 ******************************************************************************* OSHA HAZARD DETERMINATION Hazardous Ingredients CAS Number Hydrogen Sulfide Hydrocarbons (Gaseous Alkanes) 7783*06-4 Mixture Hazardous Physical Properties: Compressed Gas, Flammable. The material is hazardous as defined by OSHA's Hazard Communication Standard, 29 CFR 1910.1200. ******************************* *********** ********* *****#**#****#***#***# PHYSICAL DATA Vapor Pressure Vapor Density Solubility in Mater Form Color Specific Gravity Distillation Range 100 - 200 PSI & 100 deg F > 1 (Air = 1 .0) Very Soluble Gas Colorless Not Applicable -258 to +400 deg F (includes traces of hydrocarbons, hexanes, and higher molecular weight) SAL 000006670 She/t coaqq c10a 9 20-Sep-89 Conoco Material Safety Data Sheet f Page 4 MSDS No: ITAIiu-C (HEALTH HAZARD INFORMATION - CONTINUED) 0.5 pom - Action level Exposure Limits for Hydrogen Sulfide AEL * TLV ** PEL (DuPont): (ACGIH) : (OSHA) : 10 ppm - 8 & 12 Hr. TWA 10 ppm, 14 mg/m3 STEL 15 ppm, 21 mg/m3 10 ppm, 14 mg/m3 STEL 15 ppm, 21 mg/m3 * AEL is DuPont's Acceptable Exposure Limit. ** TLV is a registered trademark. Safety Precautions Do not breathe vapor or mist. Avoid contact with eyes. Avoid contact with skin. Wash thoroughly after handling. Wash clothing after use. FIRST AID bMN CONTAC 1 In case of contact, immediately wash skin with soap and plenty of water. If irritation develops, consult a physician. EYE CONTACT In case ot contact, immediately flush eyes with plenty of water for at least 15 minutes. Call a physician. INHALATION If hyarogen sulfide is present, the following applies: Rescue personnel must use good judgment to minimize their risk. Because hydrogen sulfide can cause death, rescuers must wear positive pressure full facepiece, seit-contamed or supplied-air NIOSH approved respirators before attempting the rescue. Remove victim to fresh air immediately. If breathing stops, begin artificial resuscitation. If breathing is difficult, give oxygen. keep victim warm and at rest. Seek medical attention. PROTECTION INFORMATION Generally Applicable Control Measures and Procedures Ventilation: Sufficient ventilation to maintain at concentrations below permissible exposure limits. Personal Protective Equipment 000006667 SAL o 28-Sep-89 Conoco Material Safety Data Sheet C I 03 7 Page 3 MSDS No: ITAILOIO (HEALTH HAZARD INFORMATION - CONTINUED) due to oxygen displacement. exposed to compressed gas. Frostbite may occur when If hydrogen sulfide is present, low concentrations are irritating to the eyes, skin, and respiratory tract. At higher concentrations, respiratory paralysis and loss of ability to smell hydrogen sulfide may occur. The product may contain low concentrations of ammonia and thus enhance the irritant properties of the product. Carcinogenicity None of the components in this chemical is listed by IARC, NTP, OSHA. or ACGIH as a carcinogen. Exposure Limits for ACID GAS/SOUR GAS (SULFUR PLANT) TLV ** (ACGIH) : None Established PEL (OSHA) : None Established Other Applicable Exposure Limits: Exposure Limits for Hydrogen Sulfide AEL (DuPont) TLV ** (ACGIH) PEL (OSHA) 10 ppm - 8 & 12 Hr, TWA 10 ppm, 14 mg/m3 STEL 15 ppm, 21 mg/m3 10 ppm, 14 mg/m3 STEL 15 ppm, 21 mg/m3 AEL is DuPont's Acceptable Exposure Limit. ** TLV is a registered trademark. Safety Precautions Do not breathe vapor or mist. Avoid contact with eyes. Avoid contact with skin. Wash thoroughly after handling. Wash clothing after use. **************************************************** ********************** FIRST AID SKIN CONTACT In case of contact, immediately wash skin with soap water. If irritation develops, consult a physician. for possible frostbite. and See plenty of physician EVE CONTACT In case of contact, at least 15 minutes f ros tbite . immediately flush eyes with plenty of water for Call a physician. Se physician tor possible SAL 000006672 C I03 9 20-Sep-B9 Conoco Material Safety Data Sheet Page 6 MSDS No: IT AI LO<.v I'.IMKnl.l CONDITIONS - CONTINUED) FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA , THE MATERIAL DESCRIBED, OR ITS USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. Date of latest Revision Responsibility for MSDS B9/09/2B Env. Occ. Health Conoco Inc. PO Box 2197 Houston, TX 77252 713-293-5550 Services SAL 000006*^ 4 28-Sep-89 Conoco Material Safety Data Sheet C I 03 7 Page 5 MSDS No: ITAILOIO (SPILL, LEAK AND DISPOSAL INFORMATION - CONTINUED) accordance with applicable Federal, State/Provincial, and Local regulations. When feasible, vapors should be dispersed mechanically. **************** ******** ****************************************** SHIPPING INFORMATION Not to be transported by truck, rail, air, or water. ************************************************************************** STORAGE CONDITIONS Store in accordance with National Fire Protection Assn regulations. ************************************************************************** The above data are based on tests, experience, and other information which Conoco believes reliable and are supplied for informational purposes only. However, some ingredients may have been purchased or obtained from third-party manufactures. In these instances, Conoco, in good faith, relies on information provided by those third parties. Since conditions of use are outside our control, CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM USE OF THE ABOVE DATA. NOTHING CONTAINED HEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE MATERIAL DESCRIBED, OR ITS USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. Date of latest Revision Responsibility for MSDS 89/09/28 Env. St Occ. Health Conoco Inc. PO Box 2197 Houston, TX 77252 713-293-5550 Services sal 000006674- * 28-Sep-89 Conoco Material Safety Data Sheet C I 03 6 Page 1 material IDENTIFICATION NUMBER name : IHYSU140 5 hds stripper overhead gas CHEMICAL FAMILY s PetroleumHydrocarbons TRADE NAMES /SYNONYMS ! HDS Unit Stripper OH Gas CAS NUMBER NFPA RATING WHMIS CLASSIFICATION Not Applicable. : Mixture : Health: 1 Flammability: 4 Reactivity: 0 : MANUFACTURER/DISTRIBUTOR: Conoco Inc. P.O. Box 2197 Houston, TX 77252 GENERAL INFORMATION PHONE : 1-(713)293-5550 TRANSPORTATION EMERGENCY PHONE : 1-(800)424-9300 ***.M*E.*D.I*C*A.#L *.E#ME*RGE*N**C*Y**P*H*O*N*E**********************:**1*-(8**0*0*)*4*4*1**-3**6*37**** * * * OSHA HAZARD DETERMINATION Hazardous Ingredients / Hydrocarbons (Gaseous Alkanes) Hydrogen Sulfide CAS Number Mixture 7783-06-4 Hazardous Physical Properties Compressed Gas, Flammable. The material is hazardous as defined by OSHA's Hazard Communication Standard, 29 CFR 1910.1200. ************************** ********************* *************************** PHYSICAL DATA Vapor Pressure Vapor Density Solubility m Water Form Color Specific Gravity Distillation Range 100 - 1200 PSI & > 1 (Air = 1.0) 51ightly soluble Gas Colorless Not Applicable -420 to +400 deg of hydrocarbons, higher molecular 100 deg F F (includes traces hexanes, and weight) v> SAL 000006675 Cl 0 3 7 28-Sep-89 Conoco Material Safety Data Sheet Page 2 MSD5 No; ITAILt HAZARDOUS REACTIVITY Instability : Stable. Hazardous Decomposition Products: Sulfur dioxide; sulfur if burned in oxygen-deficient atmosphere. Conditions to Avoid: Flammable gas. Reactive with oxidizing agents. Heat can be generated if reacted with alkaline materials. Wet gas is corrosive. Hazardous Polymerization: Will not occur. ************** ************************************************* ******* ***. FIRE AND EXPLOSION DATA Flash Point: Below ambient. FIRE AND EXPLOSION HAZARDS Handle and store in accordance with NFPA procedure for Compressed Gas, Flammable. EXTINGUISHING MEDIA If gas has ignited, do not extinguish. Stop gas flow. Allow to burn out. SPECIAL FIRE FIGHTING INSTRUCTIONS Special Fire Fighting Procedures: Stop flow of gas. Use water to keep fire-exposed containers cool and to protect personnel effecting the shutoff. If a leak or spill has not ignited, use water spray to disperse the gas or vapor and to protect personnel attempting to stop a leak. Unusual Fire and Explosion Hazards: Highly flammable. Products of combustion may contain carbon monoxide, carbon dioxide and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. ********************************************************** HEALTH HAZARD INFORMATION Primary Route of Exposure/Entry: Inhalation. sM_ 000006671 Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: Overexposure may cause central nervous system depression. Large concentrations in ambient air can cause asphyxiation 20-Sep-89 Conoco Material Safety Data Sheet c I 03 6 Page 3 MSDS No: IHYSU140 HEALTH HAZARD INFORMATION Primary Route of Exposure/Entry: Inhalation. Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: Overexposure may cause central nervous system depression. Large concentrations m ambient air can cause asphyxiation due to oxygen displacement. Contact with liquified gas may cause frostbite. If hydrogen sulfide is present, low concentrations are irritating to the eyes, skin, and respiratory tract. At higher concentrations, respiratory paralysis and loss of ability to smell hydrogen sulfide may occur. The product may contain low concentrations of ammonia and thus enhance the irritant properties of the product. Carcinogenicity r None of the components in this chemical is listed by IARC, NTP, OSHA, or ACGIH as a carcinogen. Exposure Limits for HDS STRIPPER OVERHEAD GAS TLV ** (ACGIH) : None Established PEL (OSHA) : None Established Other Applicable Exposure Limits: Exposure Limits for Hydrogen Sulfide AEL TLV ** PEL (DuPont): (ACGIH) : (OSHA) : lO ppm - 8 A 12 Hr. TWA 10 ppm, 14 mg/m3 STEL 15 ppm, 21 mg/m3 10 ppm, 14 mg/m3 STEL 15 ppm, 21 mg/m3 AEL is DuPont's Acceptable Exposure Limit. ** TLV is a registered trademark. Safety Precautions Do not breathe vapor or mist. Avoid contact with eyes. Avoid contact with skin. Wash thoroughly after handling. Wash clothing after use. V. X CI03 7 28-Sep-89 Conoco Material Safety Data Sheet Page 4 MSDS No; ITAIlv (FIRST AID - CONTINUED) INHALATION If hydrogen sulfide is present, the following applies: Rescue personnel must use good judgment to minimize their risk. Because hydrogen sulfide can cause death, rescuers must wear positive-pressure, full- facepiece, self-contained or supplied-air, NIOSH- approved respirators before attempting the rescue. Remove victim to fresh air breathing, give artificial is difficult, give oxygen. a physician. immediately. If not respiration. If breathing Keep warm and at rest. Call *^*************^*****-fr*** it******************-************-********* PROTECTION INFORMATION Generally Applicable Control Measures and Procedures Ventilation: Sufficient ventilation to maintain atmospheric concentrations below permissible exposure limits ( Personal Protective Equipment Respiratory Protection: Select appropriate NlQSH-approved respiratory protection equipment where atmospheric concentrations exceed permissible exposure limit. Protective Gloves: None required. Eye Protection: Use a full facepiece with the respirator when the atmospheric concentration of hydrogen sulfide excees the permissible exposure limit. Other Protective Equipment: None normally required. ***********************************************.*-***. SPILL, LEAK AND DISPOSAL INFORMATION Spill, Leak, or Release NOTE: Review FIRE AND EXPLOSION HAZARDS and SAFETY PRECAUTIONS before proceeding with clean up. Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clean up. Evacuate personnel, thoroughly ventilate area, use self-container1 breathing apparatus. Remove source of heat, sparks, flame, impar friction or electricity. Keep upwind of leak - evacuate until g, has dispersed. Dissipate vapor with water spray. Waste Disposal SAL 000006673 Treatment, storage, transoortation and disposal must be in 28-Sep-89 Conoco Material Safety Data Sheet c I 03 7 Page 5 MSDS No: ITAILOIO (SPILL, LEAK AND DISPOSAL INFORMATION - CONTINUED) accordance with applicable Federal, State/Provincia1, and Local regulations. When feasible, vapors should be dispersed mechanically. a-*#*************************************************-#**************** SHIPP1NG INFORMATION Not to be transported by truck, rail, air, or water. a************************************************************ STORAGE CONDITIONS Store in accordance with National Fire Protection Assn regulations. ************************************************************************ The above data are based on tests, experience, and other information which Conoco believes reliable and are supplied for informational purposes only. However, some ingredients may have been purchased or obtained from third-party manufactures. In these instances, Conoco, m good faith, relies on information provided by those third parties. Since conditions of use are outside our control, CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM USE OF THE ABOVE DATA. NOTHING CONTAINED HEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE MATERIAL DESCRIBED, OR ITS USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. Date of latest Revision Responsibility for MSDS 89/09/28 Env. S< Occ. Health Conoco Inc. PO Box 2197 Houston, TX 77252 713-293-5550 Services V SAL 000006674  28-Sep-69 Conoco Material Safety Data Sheet C I 03 6 Page 1 MATERIAL IDENTIFICATION NUMBER NAME s IHYSU140 s HDS STRIPPER OVERHEAD GAS CHEMICAL FAMILY : Petroleum Hydrocarbons TRADE NAMES / SYNONYMS : HDS Unit Stripper OH Gas CAS NUMBER NFPA RATING WHMIS CLASSIFICATION Not Applicable. Mixture Healths 1 Flammability: 4 Reactivity: 0 MANUFACTURER/DISTRIBUTOR: Conoco Inc. P.O. Box 2197 Houston, TX 77252 GENERAL INFORMATION PHONE l-(713)293-5550 TRANSPORTATION EMERGENCY PHONE 1 -(800)424-9300 MEDICAL EMERGENCY PHONE 1 -(800)441-3637 ***^*^*Hfr*^***** + #-****-****-#******************----**-***** OSHA HAZARD DETERMINATION Hazardous Ingredients / Hydrocarbons (Gaseous Alkanes) Hydrogen Sulfide CAS Number Mixture 7783-06-4 Hazardous Physical Properties: Compressed Gas, Flammable* The material is hazardous as defined by OSHA's Hazard Communication Standard, 29 CFR 1910.1200. ************#***********#*****#*****#*-# + *##-##*****#+****************' PHYSICAL DATA Vapor Pressure Vapor Density Solubility m Water Form Color Specific Gravity Distillation Range : 100 - 1200 PSI @ 100 deg F : > 1 (Air = 1.0) : Slightly soluble : Gas s Colorless : Not Applicable : -420 to +400 deg F (includes traces of hydrocarbons, hexanes, and higher molecular we lght) v> SAL 000006675 C I 03 6 28-Sep-89 Conoco Material Safety Data Sheet Page 2 MSDS No; IHYSUl HAZARDOUS REACTIVITY Instability : Stable Hazardous Decomposition Products: Produces sulfur dioxide when burned in excess air. Normal combustion produces carbon dioxide; incomplete combustion may produce carbon monoxide. Conditions to Avoid: It is a highly flammable gas. Reactive with oxidizing agents. Heat can be generated if reacted with alkaline materials. It is corrosive to many materials when moist Hazardous Polymerization: Will not occur. *******t***4******t**********4******ft**#***ftt4** FIRE AND EXPLOSION DATA Flash Point: Below ambient. FIRE AND EXPLOSION HAZARDS Handle and store in accordance with NFPA procedure for Compressed Gas, Flammable. EXTINGUISHING MEDIA If gas has ignited, do not extinguish. Stop gas flow. Allow to burn out. SPECIAL FIRE FIGHTING INSTRUCTIONS Special Fire Fighting Procedures: Stop flow of gas. Use water to keep fire-exposed containers cool and to protect personnel effecting the shutoff. If a leak or spill has not ignited, use water spray to disperse the gas or vapor and to protect personnel attempting to stop a leak. Unusual Fire and Explosion Hazards: Highly flammable. Products of combustion may contain carbon monoxide, carbon dioxide and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. 000006676 SAL 28-Seo-09 Conoco Material Safety Data Sheet c I 03 6 Page 3 MSDS No: 1HYSU140 HEALTH HAZARD INFORMATION Primary Route of Exposure/Entry: Inhalation. Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: Overexposure may cause central nervous system depression. Large concentrations in ambient air can cause asphyxiation due to oxygen displacement. Contact with liquified gas may cause frostbite. If hydrogen sulfide is present, low concentrations are irritating to the eyes, skin, and respiratory tract. At higher concentrations, respiratory paralysis and loss of ability to smell hydrogen sulfide may occur. The product may contain low concentrations of ammonia and thus enhance the irritant properties of the product. Carcinogenicity None of the components in this chemical is listed by IARC, NTP, OSHA, or ACGIH as a carcinogen. Exposure Limits for HDS STRIPPER OVERHEAD GAS TLV ** (ACGIH) : None Established PEL (OSHA) : None Established Other Applicable Exposure Limits: Exposure Limits for Hydrogen Sulfide AEL TLV ** PEL (DuPont): (ACGIH) : (OSHA) : 10 ppm - 0 (. 12 Hr. TWA 10 ppm, 14 mg/m3 STEL 15 ppm, 21 mg/m3 10 ppm, 14 mg/m3 STEL 15 ppm, 21 mg/m3 AEL is DuPont's Acceptable Exposure Limit. ** TLV is a registered trademark. Safety Precautions Do not breathe vapor or mist. Avoid contact with eyes. Avoid contact with skin. Wash thoroughly after handling. Mash clothing after use. C1 ,36 JH iiep-B9 Conoco Material Safety Data Sheet Page A MSDS No: n IHYSU1 FIRST AID SKIN CONTACT In case of contact, immediately wash skin with soap water. If irritation develops, consult a physician. for possible frostbite. and See plenty of physician EYE CONTACT In case of contact, immediately flush eyes at least 15 minutes. Call a physician. See f rostbite. with plenty of water for physician for possible INHALAfION If hydrogen sulfide is present, the following applies: Rescue personnel must use good judgment to minimize their risk. Because hydrogen sulfide can cause death, rescuers must wear positive-pressure, fu11-facepiece, self-contained or supplied-air, NIOSH-approved respirators before attempting the rescue. Remove victim to fresh air immediately. If not breathing give artificial respiration. If breathing is difficult, give oxygen. Keep warm and at rest. Call a physician. PROTECTION INFORMATION Generally Applicable Control Measures and Procedures Ventilation: Sufficient ventilation to maintain atmospheric concentrations below permissible exposure limits Personal Protective Equipment Respiratory Protection: Select appropriate NIOSH-approved respiratory protection equipment where atmospheric concentration exceeds permissible exposure limit. Protective Gloves: None required. Eye Protection: Use a full facepiece with the respirator when the atmospheric concentration of hydrogen sulfide excees the permissible exposure limit. Other Protective Equipment: None normally required. SAL 000006678 28-Sep-89 Conoco Material Safety Data Sheet C I 03 6 Page 5 MSDS No: 1HYSU140 SPILL, LEAK AND DISPOSAL INFORMATION Spill, Leak, or Release NOTE: Review FIRE AND EXPLOSION HAZARDS and SAFETY PRECAUTIONS oefore proceeding with clean up. Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clean up. Evacuate personnel, thoroughly ventilate area, use self-contained breathing apparatus. Remove source of heat, sparks, flame, impact, friction or electricity. Keep upwind of leak - evacuate until gas has dispersed. Dissipate vapor with water spray. Waste Disposal Treatment, storage, transportat ion and disposal must be in accordance with applicable Federal, State/Provincial, and Local regu1a tions. When feasible, vapors should be dispersed mechanically. ******************************************************************-#**-***** SHIPPING INFORMATION Not to be transported by truck, rail, air, or water. **********************#*****#*****#*********'*+ ********# ****#-*** STORAGE CONDITIONS Store m accordance with National Fire Protection Assn regulations. a**#***********************-**-********** *******#****************#***##* The above data are based on tests, experience, and other information which Conoco believes reliable and are supplied for informational purposes only. However, some ingredients may have been purchased or obtained from third-party manufactures. In these instances, Conoco, in good faith, relies on information provided by those third parties. Since conditions of use are outside our control, CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM USE OF THE ABOVE DATA. NOTHING CONTAINED HEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE MATERIAL DESCRIBED, OR ITS USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. Date of latest Revision Responsibility for MSDS 89/09/27 Env. & Occ. Health Conoco Inc. PO Box 2197 Houston, Tx 77252 713-293-5550 Services SAL 000006679 20-Sep-89 Conoco Material Safety Data Sheet c I os 5 Page l i '- Kj> material identification NUMBER NAME IHYSU120 HDS SEPARATOR GAS CHEMICAL FAMILY CAS NUMBER NFPA RATING WHMIS CLASSIFICATION Not Applicable* Petroleum Hydrocarbons Mixture Health: l Flammability: 4 Reactivity: O MANUFACTURER/DISTRIBUTOR: Conoco Inc. P.O. Box 2197 Houston, TX 77252 GENERAL INFORMATION PHONE : 1-(713)293-5550 TRANSPORTATION EMERGENCYPHONE ; 1-1800)424-9300 MEDICAL EMERGENCY PHONE : 1 -(BOO)441 -3637 ***#****************#**********************-* OSHA HAZARD DETERMINATION Hazardous Ingredients CAS Number Hydrocarbons (Gaseous Alkanes) Hydrogen Sulfide Mixture 7783-06-4 Hazardous Physical Properties: Compressed Gas, Flammable. The material is hazardous as defined by OSHA's Hazard Communication Standard, 29 CFR 1910.1200. *#**#*********#**##****#************##****#*#*# PHYSICAL data Vapor Pressure Vapor Density Solubility m Water Form Co lor Specific Gravity Distillation Range 100 - 1200 PSI <? > 1 (Air r 1 .0) Slightly soluble Gas Colorless Not Applicable -420 to +400 deg of hydrocarbons, higher molecular 100 deg F F (includes traces hexanes, and welght) + *********#**********-*-*-*******************#***-*#*#-***-***###***#**-*******-** HAZARDOUS REACTIVITY Instability : Stable. Hazardous Decomposition Products: Produces sulfur dioxide when burned in excess air. Normal combustion forms carbon dioxide; incomplete combustion may produce carbon monoxide. SAL 000006680 c : 0- 3 5 J6-Sep-8V Conoco Material Safety Data Sheet Page 2 MSDS nos IHYSUl. (HAZARDOUS REACTIVITY - CONTINUED) Conditions to Avoids It is a highly flammable gas. Reactive with oxidizing agents. Heat can be generated if reacted with alkaline materials. It is corrosive to many materials when moist. Hazardous Polymerizations Will not occur, ************************************************************************* FIRE AND EXPLOSION DATA Flash Point: Below ambient. FIRE AND EXPLOSION HAZARDS Handle and store in accordance with NFPA procedure for Compressed Gas, Flammable. EXTINGUISHING MEDIA If gas has ignited, do not extinguish. Allow to burn out. Stop gas flow. SPECIAL FIRE FIGHTING INSTRUCTIONS Special Fire Fighting Procedures: Stop flow of gas. Use water to keep fire-exposed containers cool and to protect personnel effecting the shutoff. If a leak or spill has not ignited, use water spray to disperse the gas or vapor and to protect personnel attempting to stop a leak. Unusual Fire and Explosion Hazards: Highly flammable. Products of combustion may contain carbon monoxide, carbon dioxide and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. ************************************************************************* HEALTH HAZARD INFORMATION Primary Route of Exposure/Entry: Inhalation. Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: Overexposure may cause weakness, headache, nausea, confusion, blurred vision, drowsiness, and other nervous system effects; greater exposure may cause dizziness, slurred speech, flushed face, unconsciousness, or convulsions. SAL 000006681 C I 03 5 2B-Sep-09 Conoco Material Safety Data Sheet Page 3 MSDS No: IHYSU120 {HEALTH HAZARD INFORMATION - CONTINUED) the eyes, skin, and respiratory tract. At higher concentrations, loss of ability to smell hydrogen sulfide, respiratory paralysis, and death may occur. Large concentrations in ambient air can cause asphyxiation due to oxygen displacement. May cause frostbite when skin is exposed to compressed gas. Careinogeniclty None of the components in this chemical is listed by IARC, NTP, OSHA, or ACGIH as a carcinogen. Exposure Limits for HDS SEPARATOR GAS TLV ** (ACGIH) : None Established PEL (OSHA) : None Established Other Applicable Exposure Limits: Exposure Limits for Hydrogen Sulfide AEL TLV ** PEL (DuPont): (ACGIH) : (OSHA) : 10 ppm - 8 t* 12 Hr. TWA 10 ppm, 14 mg/m3 STEL 15 ppm, 21 mg/m3 10 ppm, 14 mg/m3 STEL 15 ppm, 21 mg/m3 AEL is DuPont's Acceptable Exposure Limit. ** TLV is a registered trademark. Safety Precautions Do not breathe vapor or mist. Avoid contact with eyes. Avoid contact with skin. Wash thoroughly after handling. Wash clothing after use. -******#*******' + ***********************'*******************'***- **** + *** FIRST AID SKIN CONTACT In case of contact, immediately wash skin with soap water. If irritation develops, consult a physician. for possible frostbite. and See plenty of physician EYE CONTACT In case of contact, immediately flush eyes at least 15 minutes. Call a physician. See f rostbite. with plenty of water for physician for possible INHALATION If hydrogen sulfide is present, the following applies: SAL 000006682 "c i0 a 5 28-Sep-89 I Conoco Material Safety Data Sheet Page 4 MSDS No: iHYSui (FIRST AID - CONTINUED) Rescue personnel must use good judgment to minimize their risk. Because hydrogen sulfide can cause death, rescuers must wear positive-pressure, ful1-facepiece, self-contained or supplled-air, NIOSH-approved respirators before attempting the rescue. Remove victim to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Keep warm and at rest. Call a physician. PROTECTION INFORMATION Generally Applicable Control Measures and Procedures Ventilation: Sufficient ventilation to maintain atmospheric concentrations below permissible exposure limits Personal Protective Equipment Respiratory Protection; Select appropriate N1OSH-approved respiratory protection equipment where atmospheric concentrations exceed permissible exposure limit. Protective Gloves: None required. Eye Protection: Use a full facepiece with the respirator when the atmospheric concentration of hydrogen sulfide exceeds the permissible exposure limit. Other Protective Equipment: None normally required. *ft*******t****#'#***t***4*#*****#**#**-ft#*******SPILL, LEAK AND DISPOSAL INFORMATION Spill, Leak, or Release NOTE: Review FIRE AND EXPLOSION HAZARDS and SAFETY PRECAUTIONS before proceeding with clean up. Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clean up. Evacuate personnel, thoroughly ventilate area, use self-contained breathing apparatus. Remove source of heat, sparks, flame, impact, friction or electricity. Keep upwind of leak - evacuate until gas has dispersed. Dissipate vapor with water spray. Waste Disposal SAL 000006683 Treatment, storage, transportation and disposal must be in accordance with applicable Federal, State/Provincial, and Local regulations. When feasible, vapors should be dispersed mechanica1ly. 20-Sep-89 Conoco Material Safety Data Sheet SHIPPING INFORMATION Page 5 MSDS No: IHYSU120 Not to be transported by truck, rail, air, or water. STORAGE CONDITIONS Store in accordance with National Fire Protection Assn regulations. * **************************** **************************************** - The above data are based on tests, experience, and other information which Conoco believes reliable and are supplied for informational purposes only. However, some ingredients may have been purchased or obtained from third-party manufactures. In these instances, Conoco, in good faith, relies on information provided by those third parties. Since conditions of use are outside our control, CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM USE OF THE ABOVE DATA. NOTHING CONTAINED HEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY ) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE MATERIAL DESCRIBED, OR ITS USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. Date of latest Revision Responsibility for MSDS 09/09/27 : Env. It Occ. Health Services Conoco Inc. PO Box 2197 Houston, TX 77252 713-293-5550 SAL 000006684 28-Sep-89 C I 02 9 Conoco Material Safety Data Sheet Page i MATERIAL IDENTIFICATION NUMBER NAME : IHYSUOBO : HYDRODESULFURIZED LIGHT ?* HEAVY NAPHTHA CHEMICAL FAMILY j Petroleum Hydrocarbons TRADE NAMES / SYNONYMS : Desulfurized reforming naphthas Sweet Napntha Reformer Feed Desulfurized Cracked Gasoline CAS NAME nfpa rating WHMIS CLASSIFICATION Not Applicable. Naphtha Number: Naphtha Number: Health: (petroleum), hydrodesulfur lzed light 64742-73-0 (petroleum), hydrodesulfuri2ed heavy 64 742-02- 1 1 Flammability: 3 Reactivity: 0 MANUFACTURER/DISTRIBUTOR: Conoco Inc. P.O. Box 2197 Houston, TX GENERAL INFORMATION PHONE TRANSPORTATION EMERGENCY PHONE MEDICAL EMERGENCY PHONE 77252 l -{713)293-5550 1 - (800)424-9300 1 -(800)441-3637 USHA HAZARD DETERMINATION Hazardous Ingredients CAS Number Hydrocarbons (Aromatic & Paraffinic) Benzene Hydrogen Sulfide Mixture 71-43-2 7783-06-4 Regulated as a toxic chemical under section 313 of Title III of the Superfund Amendments and Reauthorizat ion Act of 1986 and 40 CFR part 372. Hazardous Physical Properties: Class IA Flammable Liquid per NFPA Code No. 30-1987. The material is hazardous as defined by OSMh's Hazard Communication Standard, 29 LFK 1910.1200. ^^^a^**^***************************-#******* **#********** + **** physical data Vapor Pressure Vapor Density Solubility in Water Form Color : 2 - 20 PSI <? 100 deg F : > 1 (Air = 1.0) : Nil : Liquid : Clear SAL 000006685 10 2 9 * -s. Jd -Sep- 07 Conoco Material Safety Data Sheet Page 2 MSDS No: iHYSUOu. (PHYSICAL DATA - CONTINUED) API Gravity Distillation Range : 34 - 59 : -4 to *44o deg F HAZARDOUS REACTIVITY Instability : Stable. Hazardous Decomposition Products: Normal combustion forms carbon dioxide: incomplete may produce carbon monoxide. Conditions to Avoid: Strong oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. *"******** ##***#*#*+* + ***-*####**##***#***#####*#*#*##*##-**#***.#* # FIRE AND EXPLOSION DATA TJash Point : ' ambient Flammable Limits in Air, X by Vol. LEL : < 1 UEL : 0 FIRE AND EXPLOSION HAZARDS Class IA Flammable Liquid (NFPA). EXTINGUISHING MEDIA Dry Chemical. C02. F oam. SPECIAL FIRE FIGHTING INSTRUCTIONS 3 P e Cl a 1 Fire F i gh ting Proce dures: W a t er m ay be in et feet ive, b ut water should be us ed to keep f l r e- e X posed CO nt a me rs c o o 1. If a leak or sp 11 1 has not l q n lt e d , use wa te r sp ray to disperse the vapors and to D r o t e c t pers onn e 1 att empt in g to stop a leak. Wa ter spray m a V b e used to f 1 ush spi 1 Is away from exposures. Unusual Fire and Explosion Hazards: Highly flammable. Products of combustion may contain carbon monoxide, carbon dioxide and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. SAL 000006686 C I 02 9 28-Sep-89 Conoco Material Safety Data Sheet Page 3 MSDS Nos IHYSUOBO HEALTH HAZARD INFORMATION Primary Routes of Exposure/Entry: Skin, Inhalation. Signs ana Symptoms of Exposure/Medical Conditions Aggravated by Exposures Studies with mice or rats have shown that some petroleum distillates have caused either damage or tumors of the kidneys or tumors of the liver. However, kidney effects were not seen m similar studies involving guinea pigs, dogs, or monkeys. Also, the significance of the liver tumors in rodents is highly speculative. Mouse skin painting studies have shown that petroleum middle distillates (boiling range of 100-700 deg F; naphtha, jet fuel, diesel fuel, kerosene, etc.) can cause skin cancer when repeatedly applied and never washed from the animal's skin. The relative significance of this to human health is uncertain since the petroleum distillates were not washed from the skin and resulting skin effects (irritation, cell damage, etc.) may play a role in the tumongenic response* A few studies have shown that washing the animal's skin with soap and water between treatments greatly reduces the carcinogenic effect of some petroleum oils. The product contains petroleum hydrocarbons which may cause irritation to eyes, skin, and lungs after prolonged or repeated exposure. Extreme exposure or aspiration into the lungs may cause pneumonia. Overexposure may cause weakness, headache, nausea, confusion, blurred vision, drowsiness, and other nervous system effects; greater exposure may cause di2nness, slurred speech, flushed face, unconsciousness, or convuIs ions. Hydrogen sulfide can be irritating at low concentrations to the eyes, skin, and respiratory tract. At higher concentrations, loss of ability to smell hydrogen sulfide, respiratory paralysis, and death may occur. A few studies have indicated that workers exposed to high concentrations of benzene have a slightly incidence of leukemia. Benzene can also be toxic blood and blood-forming tissues. many years hlghe r to the Carcinogenicity The following components are listed by IARC, NTP, OSHA, or ACGIH as carcinogens. A 'P' indicates a Proposed Carcinogen. Chemical IAR NTP OSH ACC SAL 000006687 1*29 JU Laep - U`y , 1 Conoco Material Safety Data Sheet Page 4 MSDS No: IHYSUO.. (HEALTH HAZARD INFORMATION - CONTINUED) Benzene XX X DuPont controls the following chemicals as potential carcinogens : Benzene . x Exposure Limits for HYDRODESULFURIZED LIGHT & HEAVY NAPHTHA TLV ** (ACGIH) PEL (OSHA) Other None Established None Established Exposure limit for Petroleum PEL* 400 ppm; 1600 mg/m3 Distillate: Other Applicable Exposure Limits; Exposure Limits for Benzene AEL * TLV ** PEL (DuPont): (ACGIH) : (OSHA) : 1 ppm - 8 & 12 Hr* TWA 5 ppm - 15 Min. TWA 10 ppm, 30 mg/m3 (A2) 1 ppm - 8 Hr. TWA 5 ppm - (Short term exposure 0.5 ppm - Action level limit) Exposure Limits for Hydrogen Sulfide AEL TLV ** PEL (DuPont): 10 ppm - 8 fit 12 Hr. TWA (ACGIH) : 10 ppm, 14 mg/m3 STEL 15 ppm, 21 mg/m3 (OSHA) : 10 ppm, 14 mg/m3 STEL 15 ppm, 21 mg/m3 AEL is DuPont's Acceptable Exposure Limit. ** TLV is a registered trademark. Safety Precautions Do not breathe vapor or mist. Avoid contact with eyes, skin, or clothing. Wash thoroughly after handling. Wash clothing after use. FIRST AID SKIN CONTACT In case of contact, immediately wash skin with soap and plenty of water. If irritation develops, consult a physician. EYE CONTACT In case of contact, immediately flush eyes with plenty of water at least 15 minutes. Call a physician. INGESTION I t swa1lowed water. Never SAL 000006633 do not induce vomiting. Give large quantities of give anything bv mouth to an unconscious person. Call C I 02 9 28-Sep-89 Conoco Material Safety Data Sheet Page 5 MSDS No: IHYSU080 (FIRST AID - CONTINUED) a physician. INHALATION If hydrogen sulfide is present, the following applies: Rescue personnel just use good judgment to minimize their risk. Because hydrogen sulfide can cause death, rescuers must wear positive pressure full facepiece, self-contained or supplied-air NIOSH approved resoirators before attempting the rescue. Remove victim to fresh air immediately. stops, begin artificial resuscitation. is difficult, give oxygen. Keep victim rest. Seek medical attention. If breathing If breathing warm and at NOTES TO PHYSICIAN Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. PROTECTION INFORMATION Generally Applicable Control Measures and Procedures Ventilations Sufficient ventilation to maintain atmospheric concentrations below permissible exposure limits. Personal Protective Equipment Respiratory Protection: Select appropriate NIOSH-approved respiratory protection equipment where atmospheric concentrations exceed permissible exposure limit. Protective Gloves: N8R recommended. Eye Protection: Where the possibility of splashing exists, a face shield is recommended. Other Protective Equipment: Sufficient protective apparel should be worn to minimize potential skin contact with this material. **********t*4***t*#*#*#**#t4***4*ft*4***fr***tt** SPILL, LEAK AND DISPOSAL INFORMATION Spill, Leak, or Release NOTE: Review FIRE AND EXPLOSION HAZARDS and SAFETY PRECAUTIONS before proceeding with clean up. Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clean up.Remove source of heat, spares, flame, impact, friction or electricity. Dike spill. Prevent liquid from entering sewers, SAL 000006689 28-Sep-69 Conoco Material Safety Data Sheet Page 6 MSDS No: IHYSUO (SPILL, LEAK AND DISPOSAL INFORMATION - CONTINUED) waterways or low areas. Recover free liquid for reuse or reclamation. Soak up with sawdust, sand, oil dry or other absorbent material. Recover as much of the material as possible by such methods as vacuuming, using explosion-proof equipment. Nonrecoverable material, contaminated soil, and debris should be placed in proper containers for ultimate disposal. Waste Disposal Treatment, storage, transportation and disposal must be in accordance with applicable Federal, State/Provincia1, and Local regulations. #****#**#*##***#####*##****##******#**#*#*********#**#*#*#**#**#***## SHIPPING INFORMATION DOT Proper Shipping Name Petroleum naphtha Hazard Class UN/NA No. DOT L abe1{s) DOT Placard Flammable UN 1255 Flammable Flammable liquid liquid 4*******4*t* + *****ft4*******t*****M*t****#***#**4** STURAG6 CONDITIONS Store in accordance with National Fire Protection Assn regulations. 44*t******ft*****t#****<**t**********44**t*tt*4*4t**t* The above data are based on tests, experience, and other information which Conoco believes reliable and are supplied for informational purposes only. However, some ingredients may have been purchased or obtained from third-party manufactures. In these instances, Conoco, m good faith, relies on information provided by those third parties. Since conditions of use are outside our control, CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM USE OF THE ABOVE DATA. NOTHING CONTAINED HEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE MATERIAL DESCRIBED, OR ITS USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. Date of latest Revision Responsibility for MSDS : 89/09/2B : Env. & Occ. Health Services Conoco Inc. PO Box 2197 Houston, TX 77252 713-293-5550 SAL 000006690 2B -Sep-89 C I 02 2 Conoco Material Safety Data Sheet Page MATERIAL I DENT IF I CAT ION NUMBER NAME : 1THCR060 : LIGHT & HEAVY THERMAL CRACKED NAPHTHA CHEMICAL family : Petroleum TRADE NAMES / S TNONYMS : Coker Gasoline Thermal Cracked Gasoline GRP Gasoline Thermal Gasoline Primary lower bottoms Hydrocarboris CAS NAME NFPA RATING WHMIS CLASSIFICATION Not Appiicaole. : Naphtha (petroleum), 1 lght the rma1 crack ed Number: 64741-74-8 Naphtha lpet ro1eum) , heavy t he rma1 c r a ck ed Number: 6474l-83-9 : Health: 1 F 1amm abl i : 1 y : j Reactivity: 0 MANUFACTURER/DISTRIBUTOR: Conoco Inc. P.O. Box 2197 Houston, TX GENERAL INFORMATION PHONE TRANSPORTATION EMERGENCY PHONE MEDICAL EMERGENCY PHONE 7 /252 : 1-(713)293-5550 : 1 - (800)424-9300 : 1 -(800)441-3637 osha hazard determination Hazardous Ingredients CAS Number HvdrocarDons (Aromatic & Pant time) benzene Hydrogen Sulfide -- Mixture 71-43-2 7783-06-4 Regulated as a toxic chemical under section 313 of Title III of the Supertund Amendments and Reauthori;ation Act of 198b and 40 CFR cart 37'2. Hazardous Physical Properties: Class IA Flammable Liquid per NFPA Code No. 30-1987. The material is hazardous as defined by GSHA's Hazard Communication Standard, 29 CFR 1910.1200. Y _> 11`AL DA r A vapor Pressure Vapor Density Solubility inWater l i. rn, : 4 - 12PSI (? 100 deg F : > 1 (Air = 1.0) : Ni) : Liquid SAL 000006691 Shea cxj^o-7 . cojiwx C I 02 2 -.'U - ti'* Lunoco Material Safetv Data Sheet Page 1 MSDS No; I7HCROsw tPHYSICAL DATA - CONTINUED) I .o 1 i>r - I Gravity Distillation Range Yellow 58 - 6.J 20 - 43d deg F HAZARDOUS REACTIVITY 1 nstabi 1 itv : Stable. Hdzardous Decompositlon Products; Normal carbon dioxide; incomplete combustion may mono); ide . combustion forms produce carbon Conditions to Avoid; f i ame. Strong oxidizng materials, heat, and Hazardous PoiymerizaX lon; Will not occur. f-iKt hNL' EXPLOSION DATA h lammabie Limits in LEL : l l UtL : B Flash Point: Below Air, X by ambient. voi. i [i * /ini^ i AP-tusiuu hazards Class 1A Flammable Liquid inf-A). LX I IN6UISHING MEDIA Dry Chemical. LUC. t- oam. :,n LlrtL rlRt ICjHT I NG INSTRUCTIONS .special Fue righting Procedures: water may oe ineffective, but water should be used to keep Tire*exoosed containers cool. If a leak or spill has not ignited, use water spray to disperse the vapors and to protect personnel attempting to stop a leak. Water spray may be used to flush spills away from exposures. Unusual Fire ana Explosion Hazards: hjrjnly i lammabie. Products of combustion may contain carbon monoxide, carbon Oior ue and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. Z8-Sep-89 C I 02 2 Conoco Material Safety Data Sheet Page 3 MSDS No: ITHCR060 HEALTH HAZARD INFORMATION Primary Routes of Exposure/Entry: Skin, Inhalation. Signs ana Symptoms of Exposure/Medical Conditions Aggravated Dy Exposure: Studies with mice or rats nave shown that some petroleum aistillates have caused either damage or tumors of the xioneys or tumors of the liver. However, kidney effects were not seen in similar studies involving guinea piqs, dogs, or monkeys. Also, the significance of the liver tumors m rodents is highly speculative. Mouse skin painting studies have shown that petroleum middle distillates iDolling range of 100-7O0 deg r; napntna, :et fuel, diesel tuel, kerosene, etc.) can cause skin cancer wnen repeatedly applied and never washed from the animal's skm. The relative significance of this to human nealth is uncertain since the petroleum distillates were not washed from the skin and resulting skin effects (irritation, ceil damage, etc.) may play a role in the tumorigemc response. A few studies have shown that washing the animal's skin with soap and water between treatments greatly reduces the carcinogenic effect of some petroleum oils. The product contains petroleum hydrocarbons which may cause irritation to eyes, skin, and lungs after prolonged or repeated exposure. Extreme exposure or aspiration into the lungs may cause pneumonia. Overexposure may cause weakness, headache, nausea, confusion, blurred vision, drowsiness, and other nervous system effects; greater exposure may cause diz2iness, slurred speech, flushed face, unconsciousness, or convulsions. Hydrogen sulfide can be irritating at low concentrations to the eyes, skm, and respiratory tract. At higher concentrations, loss of ability to smell hydrogen sulfide, respiratory paralysis, and death may occur. A few studies have indicated that workers exposed to high concentrations of benzene have a slightly incidence of leukemia. Benzene can also be toxic blood and blood-forming tissues. many years higher to the Carcinogenicity The following components are listed by IARC, NTP, OSHA, or ACG1H as carcinogens. A 'P' indicates a Proposed Carcinogen. Chemica1 1AR NTP OSH ACG SAL 000006693 02 2 *'lj*Sep S' Conoco Material Safety Data Sheet r Page A MSDS No: ITHCROv (HEALTH HAZARD INFORMATION * CONTINUED) benzene DuPont controls the following chemicals as potential carcinogens : Benzene . Exposure Limits for LIGHT & HEAVY THERMAL CRACKED NAPHTHA TLV ** (ACGIH) PEL (OSHA) Other None Established None Established Exposure Limits for PEL: 400 ppm, 1600 Petroleum mg/m3 Distillate Other Applicable Exposure Limits: Exposure Limits tor Benzene AEL TLV ** PEL (DuPont): (ACGIH (OSHA) 1 ppm - 8 & 12 Hr. TWA 5 ppm - 15 Mm. TWA 10 ppm, 30 mg/m3 (A2) 1 ppm - 8 Hr. TWA 5 ppm - (Short term exposure 0.5 ppm - Action level limit) Exposure Limits for Hydrogen Sulfide AEL TLV PEL (DuPont): ** (ACGIH) : (OSHA) : 10 ppm - 8 4 12 Hr. TWA 10 ppm, 14 mg/m3 STEL 15 ppm, 21 mg/m3 10 ppm, 14 mg/m3 STEL 15 ppm, 21 mg/m3 AEL is DuPont's Acceptable Exposure Limit. ** TLV is a registered trademark. Safety Precautions Do not breathe vapor or mist. Avoid contact with eyes. Avoid contact with skm. Wash thoroughly after handlinq. Wash clothing after use. FJKSf AID SKIN CONTACT In case of contact, immediately wash skin with soao and olenty of water. If irritation develops, consult a physician. EYE CONTACT in case of contact, immediately flush eyes with plenty of water at least 15 minutes. Call a physician. INGESTION It swallowed, do not induce vomiting. Give large quantities of .r SAL OOOnnAAoi 26 -Sep-89 c I 02 2 Conoco Material Safety Data Sheet Page 5 MSDS No: ITHCR060 (FIRST AID - CONTINUED) water. Never give anything by mouth to an unconscious person. Call a physician. INHALATION If hydrogen sulfide is present, the following applies: Rescue personnel must use good audqment to minimize their risk. Because hydrogen sulfide can cause death, rescuers must wear positive pressure full facepiece, self-contained or supplied-air NIOSH approved before attempting the rescue Remove victim to fresh air immediately. If breathing stops, begin artificial resuscitation. If breathing is difficult, give oxygen. Keep victim warm and at rest. Seek medical attention. NOTES TO PHYSICIAN Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. PROTECT ION INFORMAT ION Generally Applicable Control Measures and Procedures Ventilation: Sufficient ventilation to maintain atmospheric concent rat ions below permissible exposure limits* Personal Protective Equipment Respiratory Protection: Select appropriate NI3SH-approved respiratory protection equipment where atmospheric concent rat ions exceed permissible exposure limit. Protective Gloves: NBR recommended. Eye Protection: Where the possibility of splashing exists, a face shield is recommended. Other Protective Equipment: Sufficient protective apparel should be worn to minimize potential skin contact with this material. SPi^u, LEAK AND DISPOSAL INFORMATION Spill, Leak, or Release NOTE: Review FIRE AND EXPLOSION HAZARDS and SAFETY PRECAUTIONS before proceeding with clean up. Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clean up. Remove source of heat, sparks, flame, impact, friction or SAL 000006695 02 2 jB-Sep-e* Loiioco Material Safety Data Sneet Page 6 MSDS No: lTHCRC. (SPILL, LEAK AND DISPOSAL INFORMATION - CONTINUED) electricity. Dike spill. Prevent liquid from entering sewers, waterways or low areas. Recover free liquid for reuse or reclamation, soak up with sawdust, sand, oil dry or other absorbent material, Nonrecoveraole material, contaminated soil, and debris should be placed m proper containers for ultimate disposal. waste Disposal Treatment, storage, transportation and disposal must be in accordance with applicable Federal, State/Provxncia1, and Locai regulations. Do not flush to surface water or sanitary sewer system. Recycle as much of the recoverable material as possible. SHIPPING INFORMATION DOT Proper Shipping Name Petroleum naphtha Hazard Class UN/NA No. DOT L abe1(s) DOT Placard : F1ammab1e liquid : UN 1255 : Flammable liquid : r1ammab1e STORAGE CONDITIONS Store in accordance with National Fire Protection Assn regulations. The above data are based on tests, experience, and other information which Conoco believes reliable and are supplied for informational purposes only. However, some ingredients may have been purchased or obtained from third-party manufactures. In these instances, Conoco, m good faith, relies on information provided by those third Darties. Since conditions of use are outside our control, CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM USE OF THE ABOVE DATA. NOTHING CONTAINED HEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, Th= MATERIAL DESCRIBED, OR ITS USE FOR ANY SPECIFIC PURPOSE, EVEN IF TH-T PURPOSE IS KNOWN TO CONOCO. Date of latest Revision Responsibility for MSDS 89/09/20 Env. fc Occ. Health Conoco Inc. PO Box 2197 Houston, Tx 77252 713-293-5550 Services SAL 000006696 28-Sep-89 Conoco Material Safety Data Sheet CI02 1 Page 1 MATERIAL identification NUMBER NAME : ITHCR100 i COKER BLOWDOWN CHEMICAL FAMILY : Petroleum Hydrocarbons TRADE NAMES /SYNONYMS : Blowdown Slop Oil CAS NUMBER NFPA RATING WHMIS CLASSIFICATION Not Applicable. Mixture Health: 1 Flammability: 3 Reactivity: O manuFACTURER/DISTRIBUTOR: Conoco Inc. P.O. Box 2197 Houston, TX GENERAL INFORMATION PHONE TRANSPORTATION EMERGENCY PHONE MEDICAL EMERGENCY PHONE OSHA HAZARD DETERMINATION 77252 : 1 -(713)293-5550 : 1-(600)424-9300 : 1 - (BOO)441 -3637 Hazardous Ingreoients CAS Number Hydrocarbons (Gaseous Alkanes) Hydrogen Sulfide Mixture 7783-06-4 Hazardous Physical Properties: Class IA Flammable Liquid per NFPA Code 30-1987. The material is hazardous as defined by OSHA's Hazard Communication Standard, 29 CFR 1910.1200. __ physical data Vapor Pressure Vapor Density Solubility in Water F orm Color API Gravity Distillation Range : 0 - 3 PSI 100 deg F : > 1 (Air = 1.0) : Nil : Liquid : Brown : 9.4 - 30.2 : 80 - 1000 deg F HAZARDOUS REACTIVITY Instability : Stable. Hazardous Decomposition Products: Normal carbon dioxide; incomplete combustion may mono xide. combustion forms produce carbon SAL 000006697 5, If A OO/S40 102 1 % 2B-Sep-89 Conoco Material Safety Data Sheet Page 2 USDS No: ITHCR1 (HAZARDOUS REACTIVITY - CONTINUED) Conditions to Avoid: Strong oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. FIRE AND EXPLOSION DATA Flash Point : Below ambient FIRE AND EXPLOSION HAZARDS Class 1A Flammable Liquid (NFPA), EXTINGUISHING MEDIA Dry Chemical. C02. Foam. SPECIAL FIRE FIGHTING INSTRUCTIONS Special Fire Fighting Procedures: Water may be ineffective to extinguish, but water should be used to keep fire-exposed containers cool. If a leak or spill has not ignited, use water spray to disperse the vapors and to protect personnel attempting to stop a leak. Water spray may be used to flush spills away from exposures. Unusual Fire and Explosion Hazards: Highly flammable. Products of combustion may contain carbon monoxide, carbon dioxide and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. HEALTH HAZARD INFORMATION Primary Routes of Exposure/Entry: Skin, Inhalation. Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: Overexposure may cause weakness, headache, nausea, confusion, blurred vision, drowsiness, and other nervous system effects; greater exposure may cause dizziness, slurred speech, flushed face, unconsciousness, or convulsions. Hydrogen sulfide may be irritating at low concentrations to the eyes, skin, and respiratory tract. At higher concentrations, loss of ability to smell hydrogen sulfide, respiratory paralysis, and death may occur. SAL 000006698 28-Sep-89 Conoco Material Safety Data Sheet c I 02 1 Page 3 MSDS Nos ITHCRIOO ^HEALTH HAZARD INFORMATION - CONTINUED) Large concentrations in ambient air can cause asphyxiation oue to oxygen displacement. May cause frostbite when skin is exposed to compressed gas. Carcinogenicity None of the components m this chemical is listed by IARC, NTP, OSHA, or ACG1H as a carcinogen. Exposure Limits for COKER BLOWDOWN TLV ** (ACGIH) i None Established PEL (OSHA) s None Established Other Applicable Exposure Limits: Exposure Limits for Hydrogen Sulfide AEL * TLV ** PEL {DuPont): (ACGIH) : ((OOSSHHAA)) : JO ppm - 8 fc 12 Hr. TWA 10 ppm, 14 mg/m3 STEL 15 ppm, 21 mg/m3 10 ppm, 14 mg/m3 STEL 15 ppm, 21 mg/m3 AEL is DuPont's Acceptable Exposure Limit. ** TLV is a registered trademark. Safety Precautions Do not breathe vapor or mist. Avoid contact with eyes. Avoid contact with skin. Wash thoroughly after handling. Wash clothing after use. FIRST AID SKIN CONTACT In case of contact, immediately wash skin with soap and plenty of water. If irritation develops, consult a physician. EYE CONTACT In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Call a physician. INGESTION If swallowed, do not induce vomiting. Give large quantities of water. Never give anything by mouth to an unconscious person. Call a physician. v. x INHALATION If hydrogen sulfide is present, the following applies: Rescue personnel must use good judgment to minimize SAC 000006699 102 1 28-Sep-89 Conoco Material Safety Data Sheet r^ Page 4 USDS No: ITHCRl . (FIRST AID - CONTINUED) their risk. Because hydrogen sulfide can cause death, rescuers must wear positive pressure full facepiece, self-contained or supplied-air NIOSH approved respirators before attempting the rescue. Remove victim to fresh air immediately. If breathing stops, begin artificial resuscitation. If breathing is difficult, give oxygen. Keep victim warm and at rest. Seek medical attention. NOTES TO PHYSICIAN Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. PROTECTION INFORMATION Generally Applicable Control Measures and Procedures Ventilation: Sufficient ventilation to maintain atmospheric concentrations below permissible exposure limits. C Personal Protective Equipment Respiratory Protection: Select appropriate NIOSH-approved respiratory protection equipment where atmospheric concent rat ions exceed permissible exposure limits. Protective Gloves: NBR recommended. Eye Protection: Where possibility of splashing exists, a face shield is recommended. Other Protective Equipment: Sufficient to minimize potential skin contact with the material. t*****t*4****#**#**********************t****tft******t44 SPILL, LEAK AND DISPOSAL INFORMATION Spill, Leak, or Release NOTE: Review FIRE AND EXPLOSION HAZARDS and SAFETY PRECAUTIONS before proceeding with clean up. Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clean up. Remove source of heat, sparks, flame, impact, friction or electricity. Dike spill. Prevent liquid from entering sewers, waterways or low areas. Recover free liquid for reuse or reclamation. Soak up with sawdust, sand, oil dry or other absorb material. Nonrecoverable material, contaminated soil, and debris should be placed in proper containers for ultimate d isposa1. SAL 000006700 28-Sep-89 Conoco Material Safety Data Sheet CI021 Page b MSDS No: ITHCR100 (SPILL, LEAK AND DISPOSAL INFORMATION - CONTINUED) Waste Disposal Treatment, storage, transportat ion and disposal must be in accordance with applicable Federal, State/Provincla 1, and Local regulations. Do not flush to surface water or sanitary sewer system. Recycle as much of the recoverable material as possible. SHIPPING INFORMATION DOT Proper Shipping Name : Petroleum distillate Hazard Class : UN/NA No. s DOT Label(s) : DOT Placard s Flammable UN 1268 Flammable Flammable liquid liquid STORAGE CONDITIONS Store in accordance with National Fire Protection Assn regulations. ****..#..*##**********#*****##*#**##'************#*##******#*****#*#******* The above data are based on tests, experience, and other information which Conoco believes reliable and are supplied for informational purposes only. However, some ingredients may have been purchased or obtained from third-party manufactures. In these instances, Conoco, m good faith, relies on information provided by those third parties. Since conditions of use are outside our control, CONDCQ DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM USE OF THE ABOVE DATA. NOTHING CONTAINED HEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY iINCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE MATERIAL DESCRIBED, OR ITS USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. Date of latest Revision Responsibility for MSDS 89/09/28 Env. & Occ. Health Conoco Inc. PG Box 219? Houston, IX 7/2t>2 713-293-5550 Services 00Q06701 SAL 0 27-Sep-B9 Conoco Material Safety Data Sheet CI 02 0 Page 1 material identification NUMBER NAME : IPQLY040 : POLYMERIZATION NAPHTHA CHEMICAL FAMILY : PetroleumHydrocarbons TRADE NAMES /SYNONYMS : CAT POLY GASOLINE CAS NAME CAS NUMBER NFPA RATING WHMIS CLASSIFICATION Not Applicable. Naphtha (petroleum), polymn. 64741-72-6 Health: 1 Flammability: 3 Reactivity: 0 MANUFACTURER/DISTRIBUTOR: Conoco Inc. P.O. Box 2197 Houston, TX 77252 GENERAL INFORMATION PHONE : 1-(713)293-5550 TRANSPORTATION EMERGENCY PHONE : 1-(800)424-9300 MEDICAL EMERGENCY PHONE : I-< BOO) 441-3637 ******^**^************ *************#**********#****#***************#*** OSHA HAZARD DETERMINATION Hazardous Ingredients CAS Number Hydrocarbons (Aromatic & Paraffinic) Mixture Hazardous Physical Properties: Class IA Flammable Liquid per NFPA Code No. 30-19B7. The material is hazardous as defined by OSHA's Hazard Communication Standard, 29 CFR 1910.1200. Refer to the Regulatory Information Section of this MSDS for other federal and state regulatory information. -#-* ************ **** ******************* ****#** **#*##****#****#**#*-*#****** PHYSICAL DATA Vapor Pressure Vapor Density Solubility in Water F orm Color API Gravity Distillation Range 6-14 PSI <? 100 > I (Air = 1.0) Nil Liquid Ye1low 58.5 - 72.1 70 - 440 deg F deg F 6^2 000 sM- 10 2 0 27-Sep-89 Conoco Material Safety Data Sheet Page 2 MSDS No: I POLYC HAZARDOUS REACTIVITY Instability : Stable. Hazardous Decomposition Products: Normal carbon dioxide; incomplete combustion may monoxide. combustion forms produce carbon Conditions to Avoid: flame. Strong oxidizing materials, heat, Hazardous Polymerization: Will not occur. #*** ***************** ******** ***********#***#****#*#**** ******* FIRE AND EXPLOSION DATA Flash Point: Less than ambient FIRE AND EXPLOSION HAZARDS Class 1A Flammable Liquid (NFPA). EXTINGUISHING MEDIA Dry Chemical. C02. Foam. SPECIAL FIRE FIGHTING INSTRUCTIONS Special Fire Fighting Procedures: Water may be ineffective, but water should be used to keep fire-exposed containers cool. If a leak or spill has not ignited, use water spray to disperse the vapors and to protect personnel attempting to stop a leak. Water spray may be used to flush spills away from exposures. Unusual Fire and Explosion Hazards: Highly flammable. Products of combustion may contain carbon monoxide, carbon dioxide and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. it******************************************************************* HEALTH HAZARD INFORMATION Primary Routes of Exposure/Entry: Skin, Inhalation. Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposures Studies with mice or rats have shown that some petroleum distillates have caused either damage or tumors of the SAt 000006703 27-Sep-89 Conoco Material Safety Data Sheet 4 c I 02 0 Page 3 MSDS No: 1P0LY040 (HEALTH HAZARD INFORMATION - CONTINUED) kidneys or tumors of the liver. However, kidney effects were not seen in similar studies involving guinea pigs, dogs, or monkeys. Also, the significance of the liver tumors m rodents is highly speculative. Mouse skin painting studies have shown that petroleum middle distillates (boiling range of 100-700 deg F; naphtha, oet fuel, diesel fuel, kerosene, etc.) can cause skin cancer when repeatedly applied and never washed from the animal's skin. The relative significance of this to human health is uncertain since the petroleum distillates were not washed from the skin and resulting skin effects (irritation, cell damage, etc.) may play a role in the tumongenic response. A few studies have shown that washing the animal's skin with soap and water between treatments greatly reduces the carcinogenic elfect of some petroleum oils. The product contains petroleum hydrocarbons which may cause irritation to the eyes, skin, and lungs after prolonged or repeated exposure. Extreme exposure or aspiration into the lungs may cause pneumonia. Overexposure may cause weakness, headache, nausea, confusion, blurred vision, drowsiness, and other nervous system effects; greater exposure may cause dizziness, slurred speedch, flushed face, unconsciousness, or convulsions. Carcinogenicity None of the components m this chemical is listed by IARC, NTP, OSHA, or ACGIH as a carcinogen. Exposure Limits for POLYMERIZATION NAPHTHA TLV PEL Other (ACGIH) (OSHA) None Established None Established Exposure Limits for PEL: 400 ppm, 1600 Petroleum mg/m3 Distillate * TLV is a registered trademark. Safety Precautions Mash clothing after use. #*tt****#*##<Ht<HHHHHI***#******#**#**t#########**##**###*#**4*t****r FIRST AID INHALATION If inhaled, remove to fresh air. If not respiration. If breathing is difficult, physician. breathing, give artificial give oxygen. Call a SAL 000006704