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MATERIAL SAFETY DATA SHEET I.____ MATERIAL IDENTIFICATION Name: Clarified Oil, Slurry Oil, Decant Oil Conoco Product Code:1072 Synonyms: Catalytic Cracked Clarified Oil; FCC Decant; FCC Clarified; FCC Slurry; Catalytic Cracked Decant Oil Chemical Family: Petroleum Hydrocarbons Manufacturer: Conoco Inc. Address: P.O. Box 1267, Ponca City, OK 74604 CAS Reg. No.: Mixture; major component is 64741-62-4 Transportation Emergency No.: (800) 424-9300 (Chemtrec) Product Information No.: (405) 767-6000 II. HAZARDOUS INGREDIENTS HAZARD DATA Hazard Determination: Health Effect Properties: Clarified Oil (CAS No. 64741-62-4)/ Polynuclear Aromatic Hydrocarbons (PNAs) Potential animal carcinogen and liver toxin (see section VII). Physical Effect Properties: Product/Mixture: None. Not Applicable. III. PHYSICAL DATA Appearance and Odor: Black, viscous liquid, petroleum odor. Vapor Pressure (PSI), 100 F Nil Specific Gravity (Hso)=1) Vapor Density Air=1) Solubility in Water Not Applicable Nil % Volatile (by volume) Evaporation Rate (Ether=1) Distillation Range 1.03 - 1.12 Nil Nil > 650 F IT. REACTIVITY DATA Stable: Z Unstable: Hazardous Decomposition Products: Oxides of carbon, sulfur, and nitrogen. Conditions To Avoid: Strong oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. ?. FIRE AMD EXPLOSION HAZARD DATA Flash Point (Method used): > 200 F (PM)* * Handle and store in accordance with NFPA procedure for Class III B Combustible Liquid. Extinguishing Media: Use water spray, dry chemical, foam, or carbon dioxide. Special Fire Fighting Procedures: Use water to keep fire-exposed containers cool. If leak or spill has not ignited, use water spray to disperse the vapors and to provide protection for men attempting to stop a leak, Water spray may be used to flush spills away from sources of ignition. MCD 000022986 May 9, 1986/RESC0012 ?. FIRE AMD EIPLOSION HAZARD DATA (continued) Unusual Fire and Explosion Hazards: Do not heat above flash point. Products of combustion may contain carbon monoxide, carbon dioxide, and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Association (NFPA) Health 0 Fire 2 Reactivity 0 HAZARD RATING Least - 0 Slight - 1 Moderate - 2 High - 3 Extreme - 4 VX.TRANSPORTATION AND STORAGE DOT HAZARD CLASS: Not Applicable Precautions To Be Taken In Handling And Storing: Product is Class III B Combustible Liquid per NFPA Code No. 30-1984. Store and handle accordingly. *200 F is a limitation of the application for regulations in this subchapter and should not be construed as indicating that liquids with higher flash points will not burn. Shipping Paper Description: Not D.O.T. Regulated. Placard: Not D.O.T. Regulated. D.O.T. Label: Not Regulated. OSHA Label: CAUTION: Minimize exposure. This product may contain certain hydrocarbons (PNAs) which have caused cancer in laboratory animals. Hash thoroughly with soap and water after contact. VII. HEALTH HAZARD INFORMATION PEL Not Established (refer to the Coal Tar Pitch Volatile Standard; 0.2 mg/m3) TLV Not Established (refer to the Coal Tar Pitch Volatiles; 0.2 mg/n^f " Ceiling Value Not Established AEL Not Established Primary Route(s) of Exposure/Entry: Skin, Inhalation. Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: No adverse health effect In humans has been identified specifically for this product. However, health effect information from animal studies has been included on related materials, even though health experts may disagreekas to the significance of this data. Mouse skin painting studies have shown that petroleum distillates having a boiling point above 700 F, and which are similar to ingredients in this product, caused skin tumors. Rat skin painting 90-day studies have shown a clarified slurry oil to cause liver damage and death at doses as low as 8 mg/kg/day. Carbazole derivatives are thought to be the chemical components causing the liver damage. May 9, 1986/RESC0012 MCD 000022987 VII. HEALTH HAZARD IHFORMATIOM Ccontinued) The product may cause irritation to eyes, lungs or skin after prolonged or repeated contact. Intermittent or occasional skin contact with the material is not expected to have serious health effects as long as good personal hygiene measures, such as those outlined in this material safety data sheet are followed. Listed as Carcinogen or Potential Carcinogen by: NTP No IARC Yes OSHA No Till. EMERGENCY AND FIRST AID PI RES Eyes: Immediately wash with fresh water for at least 15 minutes and get medical attention. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If irritation persists, consult a physician. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. If exposed to hot oil, immediately cool with cold water. Do not attempt to remove oil but continue to cool exposed areas with cold packs and seek medical assistance immediately. Inhalation: If overexposure occurs, remove individual to fresh air. If breathing stops, administer artificial respiration. Ingestion: If large amount of material is swallowed, do not Induce vomiting. If vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. Immediately consult a physician. Do not attempt . to give liquid to an unconscious person. Note to Physician: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. H. SPILL, LEAK AND DISPOSAL PF RCRA HAZARDOUS WASTE: Yes RES No X In Case of Spill or Leak: Contain spill immediately in smallest area possible. Allow hot oil to cool. Use shovel or mechanical means to scoop up spilled material including contaminated soil and place in proper containers for storage and ultimate disposal. Avoid washing, draining or diverting material to storm or sanitary sewers. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of nonrecyclable material by controlled incineration, complying with federal, state and local regulations. Avoid drainage into storm or sanitary sewer. May 9, 1986/RESC0012 MCD 000022988 1. PRECAUTIONARY MEASURES Respiratory Protection: NIOSH-approved particulate respirator where necessary to avoid inhalation of mists or hot fumes. Ventilation: Local Exhaust -- As required to remove vapors and fumes from hot materials. Protective Gloves: Neoprene or NBR recommended (insulated if material is being handled hot). Eye Protection: Face shield if material is being handled hot. Other Precautions: Skin contact should be minimized. Complete protective clothing if material is being handled hot. Launder or discard contaminated clothing. Discard heavily contaminated leather material. * The above data la baaed on testa and experience which Conoco believes reliable and are supplied for informational purposes only. CONOCO DISCLAIMS ANT LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTA TION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, HC PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. May 9, 1986/RESC0012 MCD 000022989