Document xzOb6Bydb7JgvEMz35gjo78kG

i Centre Analytical Laboratories, Inc. 0 "504P8honeR:e(s8e1a4r)c2h3D1-i8v0e32 Fax: (814) 23S1-a1t25e3Coolrl(a6g1e4,) 2P3A1-161850810 i EN-5 i Analytical Report i Fluorochemical Characterization of Drinking Water Samples Port St. Lucie, FI (W2363) i Centre Analytical Laboratory Report No. 023-007 i Testing Laboratory Centre Analytical Laboratory, Inc. i 3048 Research Drive State College, PA 16801 3M Environmental Laboratory Contact i KeBnltdgR,. 2L3inEd-s0t9rom P.0. Box 33331 i SPt.hoPnauel:, M(5N51)55717383--53335321 Requester 1 Kris J. Hansen, Ph.D. 3M Environmental Technology & Safety Services Bldg. 2-3E-09 i P.O. Box 33331 St. Paul, MN 55133-3331 ii Pacers 00330 i B 1 Introduction fostoot fre srl of cr ung wrarisovat cores Results are reported for the analysis of a series of drinking water samples received by Centre collected from Port St. Luce, Fl. The Centre study number assigned to the project is 023.007. B (SpecLifiOc fMlurSwoacIhserreViqcuaSelstc)headrfaocrteariszaatmipolnebsy. lAiqouitdachofr1o6msaatmogprlaepshwy/ertearnedceemivmeadsfsorsanpaelcytsriosm.etry 6 Thesampleswerepreparedandanalyzedby LCIMSIMS forthefolowing istoffuorochericals: Pl + Table 1: Target Analysis EB [P[ eruoC roocto eneSm u-- forp ale oundN T[Ape wroosnm m e|| Perluoroociane Sufonyaride [Peruoroocionrcoaan te| i ta gens i ior fis sity vas gurl crag fo USEPA Good Labor anPrdacrtiecseuss(aGrLPeso)n.flTehweitanaCleytnitcraal.mDeatthaopdreusseendtewdahseveelidsatlheedhibgyhCeesnttrqe.uaTyhdeatvaaalvaatiiaobnlperaotttociosl ime. i 2 Sample Receipt The samples were submited in indidual past containers and were nit preserved. Sixteen |] cinodliviicduianl sdaatmepslweecroentnaoitnseurpsplwieerde, rCehcieiavievdo.fcuSsatmopdlyesinwfoerrmeatrieocneiisvperdeosnen0t2e/d15i/n0A0t.iTahcehmseanAmptle 0 3 Holding Times The analytical method used wes validated againsat maximum holdingtmeof 14 days. The `stabilityoftheanalytesofinterestforlongerperiodshasnotbeen determined. a Pace20Fs 00331 i 4 Methods - Analytical and Preparatory B 4411.4 SLaCm/plMeSIPrMepSaration for LCMSIMS Analysis r`eSsaimdpulaelscwhelorreinne.tSloirdeaptheadsweithex2tr0a0ctuilo.nof(2SP5E0)gLwa.ssoucskeudm 1t0hiopsruelfpaatreesothuetosnafmoplreesmofvoer H dTLihCseIcMacrSadIretMdiSdaganendawlyatshises.fSrsPAtEifotcreotduymmwiintlhewra5spmoLrt.thoieofnn4oa0flu%staemmdpewtliheahwnea1ls0nr0a%nwsamiteeetrrhraesnodloutlt.iaon,CAinT5ShmePiEhpacoolrrioteinwcgeoesf K cmoentcheanntorlatiwoansofcotlheecsiaemdpflo esapnrailoyrstiosabnaylyLsOisMSMS. This veatment esuled ir an sghtfod 0 412 Sample Analysis by LOMSMS . cInolHuPmnL.C,Baanseadolnitoqhfeeuaxftorfantcytosftnheectaenda anfdopratshseesdtattrioounagrhypahiaqsueiidn-tphhaesceoclhurommnarleolgartiavpehitoc 0 tHhePlLiCquisdepmaorabtlieon,phEasSeM,Steproavniadeystairarpeitdaianneddfoarccaurcahlaeramcetaenrsisfo:raamnoaulnyztionfg taimwei.deFrolalnogweinogf organic compounds, including fluorochemicals. Elecirospray isganeralyoperated at relatively H K`mnilodwntefmupeorraotcuhreemsi;camloslaerceuloebssearrveedioaninzdedq,uafnrtaigamteendteadg,aiansntdsdteatnedcatredds.. Ions characteristic of RB aAHneaweisetttPhoacskaamrpdleHPe1x1a0c0tH.PLACnsaysstemwacosuppleeddofromaedMicwrionmgassselUetctemda MreSaIcMiSonwamsonuisoeidnfgo iu a(SnRdMM).SSSampmleetshowdesrueseexdtfroarciaondaloynsi2s2a2n5/d00nasntdumaennatlpyazreadmbeyteMrSsIcMaSnboen f2o/2u6n/d00i.n aTihzechHmPenLtC. D. i 5 Analysis i 51 ACa7l-ipborinatcialobnrationcurvewas analyzedathe begining and endof he analyical sequence. 50fo0r,th2endco1m0p0o0unngdlsL o(fppitn)feTrheset.reTshpeoncsaelborfattihoen pqouiannttsiawteornelpornevpearrseudsatthe0,co2n5,cen50i,re1t0i0o,nw25a0,s plotied for each point. Using linear regression with 1/x weighing, the slope, y-nterospt and H `correlation coefficient (r) and coefficieonft determination (') were determined. A calbration `curve is acceifrp>0t .98a 5(*b>0l.97e0). |] `Calibrationstandardsarepreparedusing thesameSPE procuseedfdorsuamrplees. [] Domo ve sensssCove tCarloiubgrahtoiuotn cthheeckasntaalnydsiasrdssewqeureencaen.alyzCeodmppleirainocdeicails (eovbetrayintedrtfeoftihevee ssatamnpdlaerdinjeacntailoyntse) u For the resus reported here, calbration criteria were met. aHu Pacesors 00332 52 BExltaranckiosn extraction bbllaannkkss swheorued pnroetpahraevdeaannyd taanrgaelty zaend awietsh epvreersyenetxattroacrtaiobnovbeattchhe ocf osnacmepnltersa.tTiohenf holowdevel clbreton slandard. Forthesesampis, heexracionblankswerecompliant. E lIenvsetlrcuamlenttatbiloannksstanndatrhde,foarnmd oaffcelrekannomwenthhaingahliasvoellvesnatmwpelrese.alAsgoaainna,ltyhzeedblaafntkrs esvheoryudhingoht- B have any targe analytes present a or above the lowdavel samples presentedherethe instrument blaarencompkliasnt. calbraton standard For the 5 53 SSuumrorgoageastpeiksesarenotacomponentofthe LCIMSIMS analytical method. 54 MaMtatirxisxpiSkpeiskweesrepreparedfor everysamploat aconcentration of 100ngl using al EB `compoofuinnterdesst. Matrix spikerecoveriesaregiven inAtachmentC. B Ficeolmdpsopuinkdesswoferneeraelsst.opFrieepldarspeidkoe rnesceovveerriaelssaamrpellessoatgiavecnonicneAnatrcahtmioennotfC.100ng/L.usingall BE 55 Tn Duplicates Al samples were analyzed in duplicate. Resuls are given along with the sample resus in 56 Laboratory Control Samples HB cMoimlipqowuantderswwearsesbpiektewdewinth70al-l1c3o0%mpioeuacnohdfLiCnSt.erestat 25 and 250 ng. Allrecovefroireasl H 57 SFiaemdpbllaenkRsealmaptleesd cCoonsmismteednotfsempty containers. Forty miliers of type | water fered 0 mraounghnaasethhyrepeorcearrbcsaamrpildesg.ewasadded fotheempl conlainer andanalyzed in thesame " 6 Data Summary " Please seeAttachment Bfor adetalled listingofthe analyticalresults. 0 7 Data/Sample Retention R2H e`lSeacmiprloensicadraetdaisipsoasrecdhoivfeodnoenmroenfrtohvaafbelretmheerdeipaoartndihiassrudecdoupnylersespoorthtesarwriosesstpoerceidfieindd.atAlal foders maintained by Cente. a 0 Pace4ors 00333 Bi 8 Attachments 81 Attachment A: Chain-of-Custody 62 Masmens: Ress, 83 tachmenCt: atx Sik Recoveries (Fld and Laboraey Ses) 84 AtachmentD; LOMRawSAnaMicaSDota 9 Signatures NH Um [Te df Sohn, Faherty, Manager nfostialSonices Group hoe Date | K<oop7 ilPremt 29-onh e o N Obras MerbarsContigoD oH P KarenLSmith -- u 0 racesors 00334 aMm Envi E mentalLaborEatorEy ChaE inofE CustodE y/Reque.E ...rLaE boratorR y AnalE yical E REED E 17133 WEPE hiE c r -------- re meio hy22508 POE ZB won| FaeStele el | H GEr-01% , een] wale i ToShr Lodt it, FL 3 Eas eeee [ Fr Eifeisoematf msem1wp7en7atl T P TRTohe| eamr=e ]l2 e mmme [E FmmcsFohiactiT abaseeev er | t EN p r H Er eo 4 CRFea 5 J 0 A et ct | A 4 Er tr -- ------ ---- pie ume TT TT al HE EE EEEEERSERQDR ER EE E 3M Envi mentalLaboratory Chainof Custody/Reque.,. rLaboratoryAnalytical 17134 BR a ema [ Eamets---- lei bo ( GivF -04R PWoarzti5e4.>Lie, FL Gene en [TTT] fee [cle[dred]| | | | Te fe ae LEE FF[eilcliiniecinuen on sBisiA:O7b60o3p EC RTP f|ui 8A l Afrr0 SES S rp| fC r E r B iA | H J 70 20 H , pH = HH = r [ Yuthyg biacl e TETone =Jr an FES res wm lR l2 ure sens (10336 : Ls ee AN Centre Analytical A 5018 Research Dive,Stata CoLllaagebPAo16r401at614o-23r7-i803e2 sFA,X STEI29nT-c12.87 Hanmer no Mamie entiation | jjroie Heeeesm NEJoE y A ~ew Saamopleneset IoteraPR urea SSSivi]etPnnepmeanpss SSotiirna Si SP a, micse PwROSUO 233 333 23 32 w3mrOsGgl 323 333 [2 3$ o3PoAAmon) 333 323 3 33 " 00337 Ee --