Document xz5gLGGLa52JDZdyQL8NZZOJ

BIODEGRADATION (BOD/COD) TEST SUBSTANCE Identity:Perfluorooctanoiaccid,ammonium salt;may alsobe referredto as PFOA ammonium saltA,mmonium perfluorooctanoateP,FO, FC116, FC-126, FC-169, or FC-143. (Octanoicacid,pentadecafluoro,ammonium salt,CAS # 3825-26-1) Remarks: The 3M productionlotnumber was 37. The testsample isFC143. It'psuritywas notsufficientclhyaracterizedt,hough currentinformation indicatesitisa mixtureof96.5 - 100% testsubstance and 0 - 3.5% C6,C7, and Cg perfluoroanalogue compounds. METHOD: Method: Not noted. Type: Aerobic GLP: No Year completed: 1980 Contact time:20 days lnoculum: Sewage taken from thetreatmentsystem at3M Cottage Grove, MN.. Chemolite, RESULTS Chemical Oxygen Demand (COD): BiochemicalOxygen Demand (BOD): 5-Day: 1O-Day: 20-Day: 570 -870 mg/kg* <38 mg/kg <38 mg/kg <38 mg/kg Two testswere conducted. The raw data sheets are notavailable.The summary sheet states"afractioonfthesample went up intothe condenser each time,so the resultsare notconsistentwhen run induplicate". CONCLUSIONS No reliablceonclusionscan be derivedfrom thisstudy. Submitter: 3M Company, EnvironmentalLaboratory,P.O. Box 33331, St. Paul,Minnesota,55133 DATA QUALITY ReliabilitKyl:imischranking3. Study lacksdescriptioannd recordsofthe method followed.The inoculumisnot properlycharacterized.There isno analyticamleasurement ofthe testsubstance inthe solutions.Test substance was not characterizefdorpurity. REFERENCES The COD and BOD studieswere conducted the 3M Company, Environmental Laboratory,St.Paul,MN, Lab Request number 5625S, 1980. OTHER Last changed: 5/24/00 Form 10620-5-PWO cei LA.8 R&QUEST BOOK - 42-SW PRODUCT R3j: ENVIR. ASSESS. l@!0, REQUEST @OZO/ I PRODUCT: C14e-pl-@ DIVISION I-qt -3-/ C-C Yo'4-@5 ECOLOGICAL ASSESSMENT FOR LABORATORY WORK 3.M lkcUarrZODPaper LAB REQUEST No. 5,6,;?!Srs REQUESTER Name: Eri ou IrLt,-- Phone No. Request Date: ProjectNo.: Code No.: fko Prob.No. Sample Date: Descriptionoo:'rc y 3 Date Needed: 40-@- 3 7 Purpose of Tests: 1;7n v c-#,,-,eri 4 4b C;;, 6-0'7Y LABORATORY Date Received Analyst: Mt. Date Completed: f4 -,2 rAT,6=-UtA5 . HoursSpent: Mp-!l y B'- -r -p r'Z7IIR- PleasCeallRequesterIfDelaysAre Encounterel-_,@A PHYSICAL & CHEMICAL PROPERTIES Ci 31 Heatof Combustion Cal/G IBTU/Lb.) 37 Density Ash Other WATER POLLUTION 'P4+- Coh COD BOD 5 W&A:l -T70 . /,g, BOD, Ultimate TOC GC -taxisi@ll&i!)64- e Oxygen Uptake Dehydrogenase Activity (TTC) Other BIOASSAY 6 Specify Organism and Method: TSCI rafhui LEACHATE FROM LEACHING pH COD BOD 5 BOD, Ultimate TOC GC Bioassay O,her TEST 76 tfq3-rM,I) OTHER Bioaccumulation Persistence Degradation Products i2ko oor JF White - Return to Requester Canary -Environmental Engrg. office File tin-k- Environmental Engrg. Lob Goldenrod - Return to Reau@ter ubwomy ,$Iskhkot00*9# RequeNsot. MM@" Dlude-n PW gotoNoo. 0.0. iall ;wdW ONutm motdo No. wow ma (Gpdww) INNW D.O. OCII BODRunNo. An"Gi r7 DayBODReadinos 4A2) @F, 0 9-ti p .0m.t 0.0. (C2) (Al -A2) o,50 o.o. Dooetion (Cl -C2) AftruDp.O. DepWtion (Ai -A2) 0,5 AvereW 0.0Depletion S,.d COi*Cll gotoo swnpio ske 0 InitiaDlA). Pfawnt D.O. (B2) D.O. Depletion (Bi -62) 0.70 0, 5 Gluem -CiluamicAGM SufW Wd . Bowe No. SO"%" $its initial0.0. IDII 3,0 prowt D,O. 102 7 PomWum 10 Hydropn Phtheigis S.MW&rd (OPDOW) got"o No. li-sin itotm 0.0. IDI) prownt D.O. ID2) Total 0.0. Cmplotion IDI -D2) Total D.O. Depletion IDI - D21 -Day -ever C?7 Depletion Due Day To Standard -SOD Day SOD For m 19755 PWO t /0,/970 *4t, 'talL*"&*NV shwt -tiorks, ww stwodwdl RequestNo.* sow Type a gowee A conoonvatmm 1 Monooded,Dbuden -W*W bd" D.O. (All 1)4) 9p, /0 seww onuihm-wow ow* D.O. ocil Boo RunNo.6 Analyst 'ME@w m 7 Day BOD Readings at* Pi@.@ Da. tA2) 7,9,S7' D.O.DoOofion (A, - A2) Average 0.0. Depletion (Al-7421 plawl DA. 4C2) q D.O. n p' let -C.21 0160 Awwop 0.0. D@O*lWn 01 -1!21 S"d Convois INMW D.O. (all p 0.0. 182) 04. Dopbti" /,00 :@u 2-(D 17,90 IL 0 Gluco-GsleutmAnciicIdtVA,wd BottNloe. Senmdsein 3,0 5"0 /-T7,o Potassium Hydropn PHOWM InitDi.aOl. (DI) q( I%am t0.0. (D2) '2--5 iLq?o. $Undwd loptionall Tota0l.0. DepWOon (Di -02) DSO&ti".Dum TO Stoluk" @OF- 2.CPS C,;*o sc) -T Day F Battle No. Swnpio $in lnitw D.O. (Oil Present D.O. (D2) Total 0.0. Dspi"on IDI -D21 Doploiion Due To Standwd Day B-dD- vwap. Dav Average Day Bob-- pWo ,oRequm No. ;4z ? 4d Type lbG"fto coomenwow p- Cow *%rod If BOD RunNO. 2-0 va (-30-17 -Day SOD Readings Dote Md" Me. -Wow". bo" a& Promma 0.0. !A2) 17, D.D.Depletion (Al-A21 A"mp D.O. Depletion (Ai -A21 sewcontrok MA I"dWAil fall 9. !z ftemn D.O. IC21 DA. 0""tw el -C21 2,2-0 2, 0 C) 2.2-0 ftuw DA. Avmp D.O. Di"g"iIl.nC2) 2.13 D.O. Dqokdm 12, or Gluom -GkvtmW AOW *W*bd.. 2 S' ft%"km somplean 3,0,- 7,0 "y**W ftOAkU fD,l p 0.0. ID2) 93' 0'YE @ip -a Wp*wA) motileme. 2 -p' IDS) ID2) 0.70 TOW 04. DqAodm IDI -D2) n To 8 6,5a- Tatd D.O. Dspboon 101 D2) IDpo In Dto To go- @m 5-Fo 7 :zC) off Day A Day 19755 PWC) ).gvork"'mS7h'oaoLlte@Zlmoprlyas L-i Req.No.* nalyst Dot* Started BOD Run No.@ AnalVst YO - f)7 Day BOD Readings 3M gmpif,6e*crlption ln,itlD4ilution InitiaDlilutionFoeW Fc- /4/-? of Sample dilutedto ml with D Iwater (Dilutiofnactor I ifundiluted) Botdo NO. Cone.at somplol Swnpb sin2i Initial Prownt D.O.(DI) D.O.(D2) Total0.0. Depletion IDI -D2) DepletionDue To Semple Day SOD Av*rop Day SOD 1717 A 14)W.q zo qE o,25 f,/0 o.,15 50 9,90 IFI'9-0 0,10 Ind Note: 1 Cont.-aConcentrationof sample (miA or mgA) inBOD bottles. 7,1 2. Sample Siis ml org of sample or dilutedsample added to BOD Bottle. Comments t 10-0@/, Form 19766 PWO irkShnt Sompla .,bReq. No. WROV" 25a-W"d SOD Run No.* Ansfyipt YO 17 Day SOD Readings 3M &to W" DN"M lohM,P&J" FMAW Fc-fc,(3 of Saropledilutedto mi with 01 water (Dilutionfactbr I lf'undiluted) anub@ b~ Flow uo, 04. IDI) oo.i%l TOW 0.0. Depbom (DI D"*Ikm olw Tosumple D" oev 900 '70 ILI z 1. Coric. CohMtMtion of sample fmia or rmA) in SOD bottles. 2. Somple Sli* ffiolr a of Umple or dilutedsampleadded to 80() lbottle. Comnonts v A4 sntaLlabmwy )rk$heat-Sompke Ab ftoq.No. 25 Do" ad BOO RunNo.# 2-0 Analyst -DaySOD Roodings ID*te smvfb Dowiption WAM ON*". NOW Dbdm Fedw Fc- 1413 ofSwnpledilutteod mi withD IWater (Dilutifo&nM(W 1 ifundiluted) oo"b cam of 2-0 o@w b*" hom Toed 0.0. DqW@tim DIPINWR Due ant DA).idil DA).4021 (Di D2) To Sow#b BOD 177 (W q 9, Day Note. i.@ cor -PAnomovtim of mnole (adA or nigal in BOD bottin. 2. Sw!!@ $to Mi or q of samot or diluted sonple to SOD Botdo. Comments