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From lha dask ot PAULA CLINE, THE ARCHIVES OFFICE First Printing 1942 see "Monsanto Magazine" June, 1942 - last page 0683738 LEXOLDMONOQ5668 0683740 LEXOLDMON005670 MONSANTO CHEMICALS 0683741 LEXOLDMON005671 District Office' \kUoN.o|||<> Jm.I National Building Telephone: 11 l\ml< rk <> l *> I I < >S V NGLI.IS. <. \[ If . \\ et < )|\ mpie Bl\ i|. Telephone: Michigan OUK IHBMINGII \\I. VI.V. Ki-.>wn \l ar\ Budding Telephone: 7-nKTT MoNTKE VI.. C \\ VI) V I7H St. Paul Street W et 'Telephone: \( Vrket 12 in \\< >SToN. \| \. I \ iTi-it Station I elrphone; I . \ I-.r** t *>f I III NEW AoRk. \. 1 . hi Rockefeller Pla/a I elcphone: ( |rele 7 <. I h charlotte. v c Johnston ItmMins Telephone: J..U.U ST. l.iH IS. Ml). 1700 South Second Mreei Telephone; ( T.ntral 02 I i CHICAGO, ILL. Tribune Tower Telephone: \X Hltehall 677)0 DETROIT, MICH. 127 Fisher Building Telephone: TRinit 2->72K LONDON, ENGLAND Victoria Station House SVN FRANCISCO. ( VI IK. !') Mil'll Street Telephone: DOuglas HJO TORONTO. (JAN A I) V I8A Front Street Kat Telephone: WAverU llti MELBOURNE. Al STB VI I V Somerville Road Braybrook ^. 19 M ANCHESTER. ENGLAND king's House king's Street West If ork*. ANNISTON, ALA B AM A CARONDELET. MISSOLRI CAMDEN, NEW JERSEY DAYTON. OHIO EVERETT, MASS. KARNACK, TEXAS MONSANTO, ILLINOIS MONSANTO, TENNESSEE NITRO, WEST VIRGIN A NORFOLK. \ I KOI NI V TEXAS CITY. TEX VS TRENTON. MICHIG VN SPRINGFIELD. MASS. st. Louis, Missouri MONTREAL, C AN ADA RUABON, N. WALES SUNDERLAND. ENGLAND MELBOURNE. AUSTR VI I V 0683742 LEXOLDMONOQ5672 Divisions and Associated Companies MERRIMAC DIVISION. Everett Station, Boston, Mass. ORGANIC CHEMICALS DIVISION. 1700 S. Second St., St. Louis. Mo. PHOSPHATE DIVISION, 1700 S. Second St., St. Louis, Mo. PLASTICS DIVISION, Springfield. Mass. TEXAS DIVISION. Karnack. Texas. RUBBER SERVICE DEPARTMENT, 2nd National Building, Akron, Ohio. CENTRAL RESEARCH DEPARTMENT, Dayton, Ohio. NEW ENGLAND ALCOHOL COMPANY, Everett Station. Boston, Mass. SHAWINIGAN RESINS CORPORATION, Springfield, Mass. MONSANTO (CANADA), LTD., 378 St. Paul St. West. Montreal. Quebec. MONSANTO CHEMICALS LTD., Victoria Station House, Victoria St., London, S. W. 1, England. MONSANTO (AUSTRALIA) PTY. LTD., Somerville Road, Bravbrook W. 19, Melbourne, N. S. W., Australia. Cable Address "Monsanto" St. Louis Codes: ABC, 6th and 7th Acme, Bentley's and Bentley's Second 26TH EDITION Page 3 0683743 LEXOLDMONOQ5673 CONTENTS Mow To Lse This Hook................................................................... ,"> A Word About Containers................................................................ ", Monsanto--The Organization......................................................... 7 Industries Served by Monsanto......................................................11 Monsanto Products ....................................................................... IT Monsanto Literature.....................................................................145 General Data.................................................................................... 149 Testing Liquids With the Hydrometer......................................149 Dilution and Concentration of Liquids....................................151 Sulfuric Acid Tables...................................................................152 Hydrochloric Acid Tables......................................................... 154 Nitric Acid Tables.....................................................................156 Acetic Acid Tables ...................................................................158 Aqua Ammonia Tables.............................................................159 Anhydrous Ammonia Tables................................................... 161 Aluminum Chloride Tables ..................................................... 162 Aluminum Sulfate Tables ....................................................... 163 Sodium Bisulfite Tables........................................................... 165 Merclor Tables............................................................................ 166 Weights Per Gallon...................................................................167 Conversion Tables for Volume and Weight.............................. 168 0663744 LEXOLDMONOQ5674 HOW TO USE THIS BOOK This is an entirely new book, designed to bring together in the most convenient and useful form possible, sufficient information on all Monsanto products to serve as a buying guide and to enable users of chemicals to determine whether a material unfamiliar to them is of sufficient interest to merit further consideration. Those desiring more detailed information on specific products are referred to the Mon santo literature listed on page 14o or to their nearest Monsanto dis trict office. Locations of these offices are given on page 2. Alt products are listed alphabetical^ in the main section of the book according to their common chemical names or Monsanto trade names. Where a product has more than one common name, or both a trade name and a chemical name, it has been attempted to list all of these along with proper cross references, thus making the book self indexing and eliminating the trouble of referring to an index first and then to a given page number. To assist users of chemicals in acquainting themselves with the Monsanto products applicable in their particular industrv, a classi fication of products according to industries is given on page 11. This classification should not be considered final or complete. New uses for Monsanto chemicals and plat-tics are opening up dailv, some in fields entirely unsuspected a snort time before. Likewise, no product should be considered as limited to the uses mentioned in this book. The general data section beginning on page 149 contains a variety of physical and chemical information which will be useful in connec tion with certain products described in the alphabetical section. Specific reference to this data is made under products to which any of it applies. If as you use this book suggestions come to mind as to how it might be made more helpful we w ould appreciate your passing them along to us. In this way we will be able to make our next edition even more useful to you and the many other users of Monsanto products. A WORD ABOUT CONTAINERS Because of the rapid changes taking place in the availability of con tainers at the time this book was compiled, no attempt was made to include container data of any kind. Users of Monsanto products may rest assured, however, that at all times their orders will be shipped in the highest quality and most satisfactory containers available. For current container information write your nearest Monsanto district office. *** CAUTION: The products described in this book are primarily for manufacturing use. They should not be used on the human body, either internailv or externally, until their safety for the use intended is clearly established, and then not unless under competent direction. 26TH EDITION Page 5 06837*6 LEXOLDMON005676 MONSANTO -- The Organization Monsanto Chemical Company, founded in 1901 by John Francis Queenv and given his wife s maiden name, today is one of the major American producers of chemicals and plastics. Stemming from broadly diversified chemical raw materials such as coal tar. petroleum, phos phorus. cellulose, salt and sulfur. Monsanto products number in the hundreds and find use in virtually every branch of manufacturing industrv. The company's five divisions and Canadian affiliate operate four teen plants in North America, and subsidiary companies operate three overseas. Four government plants are in operation or under construction. ORGANIC CHEMICALS DIVISION The Organic Chemicals Division is the lineal descendent of the original Monsanto works. To considerable extent, the division's products, too, derive from the research program begun in the first days. The original Monsanto product, saccharin, is now one of manv made and sold by the division. Others fall in a wide varietv of classi fications including pharmaceuticals, drug intermediates, dve inter mediates, petroleum additives, flavorings, plasticizers, resins, insect icides and neavy chemicals. The division's largest plant is on the site of the original works at St. Louis. Here are manufactured the fine chemicals, many derived from coal tar, that established Monsanto's early reputation, as well as numerous other classes of products. Across the Mississippi River from St. Louis, in Monsanto, Illinois, the Organic Chemicals Division operates a large plant producing heavy chemicals and organic inter mediates. At Norfolk, Virginia, the division operates a plant manufacturing intermediates. Rubber Service Department Monsanto's Rubber Service Department, part of the Organic Chem icals Division, specializes in supplying the needs of one industrv. It provides the rubber industry with many chemicals sucb as accelera tors, antioxidants, mold lubricants, pigments, colors, preservatives, softeners and plasticizers. A modern laboratory is maintained for solving compounding problems. The facilities of this laboratory and the help of its trained and experienced staff is available without cost to users of Rubber Service materials. The Rubber Service headquarters are at Akron, Ohio, in the 26TH BDITtON Page 7 0683747 LEXOLDMONOQ5677 heart of the rubber manufacturing district. The plant is at Xitro, West Virginia. MERRIMAC DIVISION Monsanto's Merrimac Division, headquartered at Everett Station, Boston, manufactures a diversified line of heavy and industrial chem icals. Included among its products are acids, lacquers, alcohol, sol vents, intermediates, tanning chemicals, commercial gases and lampblack. The division operates thne plants, the largest being at Everett Station, Boston. Adjoining this are the facilities of the .New England Alcohol Company, a partly owned subsidiary of Monsanto. At Camden, New Jersey, Monsanto lampblack is manufactured. Some of the products of the Merrimac Division duplicate those made at other plants of the company and thus provide an eastern source of supply for Monsanto customers. PHOSPHATE DIVISION The phosphates and other compounds of phosphorus are, as a class, increasing in importance. They are finding use in such varied fields as medicinals, water treatment, dentifrices, soaps, metal treatment, and foods. Operations of Monsanto's Phosphate Division are based on the production of elemental phosphorus at Monsanto, Tennessee. At this location, phosphate earth ts dug from large open pit mines and charged into huge electric furnaces where the phosphorus is freed in elemental form. From elemental phosphorus comes phosphoric acid, the parent of the large family of phospnates which are made in the division's other plants at Anniston, Alabama, Carondelet, Missouri, and Trenton, Michigan. At Anniston, in addition to phosphates, those products of the division not derived from phosphorus, such as diphenyl, Aroclors, Santowax, calcium carbide and aluminous abrasives are made. Head quarters for the division are at St. Louis. PLASTICS DIVISION Monsanto's Plastics Division has attained a leading position in the new and growing plastics industry. The development of new plastics and their application is a continuing and accelerating process, a fact Page 8 MONSANTO CHEMICALS 0683746 LEXOLDMON005678 Monsanto, Tennessee, phosphorus furnace plant at night which guides the policies of the division from research through pro duction to sales and advertising. Monsanto's plastics operations are consolidated at Springfield, Massachusetts. As a result ol a construction program begun in 1938 there have been several major additions at Springfield, including a plant for the production of Resinox phenol-formaldehyde resins and molding materials, and the plant of the Shawinigan Resins Corpora tion, a Monsanto affiliate manufacturing vinyl resins. TEXAS DIVISION In 1941 Monsanto was requested by the Rubber Reserve Company, a government agency, to design, construct and operate a plant to manufacture an important raw material for synthetic rubber. The same year, at the request of the Ordnance Department of the United States Army, the company contracted to operate a major plant for the manufacture of munitions. The Texas Division was created to operate these two plants. The division makes no products for general sale. CENTRAL RESEARCH DEPARTMENT Research at Monsanto is both a divisional and a centralized function. Each division maintains its own research laboratories--Organic 26TH EDITION |agf 9 0683749 LEXOLDMON005679 Chemicals Division at St. Louis and Nitro, Phosphate Division at Anniston and Carondelet, Plastics Division at Springfield, and Merrimac Division at Everett. In each, the ceasearch function is kept separate from other laboratory operations, such as analytical control and testing. The work of the divisional research laboratories is supplemented ami augmented by the Central Research Department at Davton, Ohio. It is here that much of the fundamental research of the com pany is carried out. The Central Research laboratories are equipped with the latest t\pe of research aids, including such equipment as the electron microscope and X-ray, The department carries on special investigations in cooperation with the operating divisions ami also carries out studies of an exploratory nature that may not he related to the company's present products. TECHNICAL SERVICE Each of the Monsanto divisions maintains a technical service staff comprised of qualified personnel who are experienced in the chemical problems and requirements of a wide variety of industries. Industrial users of chemicals are invited to make use of these men. Their func tion is to provide sound technical counsel on problems relating to the use of chemicals. Plant of the Shawinigan Resins Corporation, a Monsanto affiliate 0683750 SOME INDUSTRIES SERVED BY MONSANTO AND PRODUCTS SUPPLIED AGRICLLTl R U>ra<ives Calcium Phnsp|lulf.. |)i r.,lri,,ni Sulfate I' I'rrir (Jiloride I >Tn>|>ln)*(ihnniK Lacquers Muriatic Arid Nitre Cake N ilric Acid Phosilage Phosphoric Acid Plastics Sodium Sulfate Sulfur Sulfuric Acid W citing Agents (Santomerse) APPLIANCES \brasives Cresol Ferric Chloride lacquers Lampblack Maleic Anhydride Muriatic Acid Nitric Acid Phosphoric Acid Phthalic Anhydride Plastics Solvents Sulfuric Acid AUTOMOTIVE Abrasives Acetic Acid Alcohol Aluminum Sulfate Amyl Acetate Aroclors (Chlorinated Diphenyl) Battery Acid Benzene Butyl Acetate Butyl Alcohol Caustic Soda Chlorine Cresol Diacetone Alcohol Dibutyl Phthalate Diethyl Phthalate Ethyl Acetate Ferric Chloride Ferrophosphorus Lacquers Muriatic Acid Nitric Acid Phenol Plioiph >ric Arid Phlhali Anhvdride Plastics ' Hitbber Accelerators Bone Ash Muriatic Acid Phosphoric Ar id Salt Cake Sodium Pv rophosphate, Tetra Sulfuric Acid Wetting Agent Rubber Anti-Oxidants Santiri?er ') (Suntortierse) Sodium Acetate Sodium Phosphates CHEMICAL Sodium Sulfate Sulfur Sulfuric Acid Tanning Chemicals Thinner* Trirresv l Phosphate AVIATION PROCESS Acetic Acid para-Ace tv I- \ in inn-Ben- zenesulfonechloride Alcohol Aluminum Sulfate Ammonia, Aqua Abrasives Amyl Acetate Alcohol ortho-Anisidine \myl Acetate Butyl Acetate Butyl Acetate Calcium Pyrophosphate Ethyl Acetate Caustic Soda Finishes Chlorine Lacquers meta-Cresol Phosphoric Acid ortho-Cresol Plastics para-Cresol Primers Cresylic Acid Solvents Diacetone Alcohol Sulfuric Acid Dinitrochlorobenzenc Surfaces* Ethyl Acetate Thinnen Mersol (Solvent) Methvl Salicylate CARPET and RUGS Mixed Acid Acetic Acid Monochlorobenzene Aluminum Sulfate Glauber's Salt Monsanto Salt Muriatic Acid Lacquert Nitric Acid Latex A< celerators Nitre Cake ortho-Xitroaniline para-Nitroaniline Sodium ftisulfite. ortho-Nitroanisole Anhydrous Nitrocellulose Solution Sodium phosphate, Tri ortho-Nitrochlorobenzene Sodium Pyrophosphate, Tetra Sodium Sulfate, Anhydrous para-Nit rochlorobenzenr para-Phenetidin Phenol Phosphoric Acid Sulfuric Acid Phosphorus Oxychloride Wetting Agent Phosphorus Trichloride (Santomerse) Phthalic Anhydride CERAMICS Abrasives Piperidine Pyridine Salicylic Acid 2 6TH EOtTlON Page 11 Salt Cake N"lmm Mmiiinaie Sodium Bisulfite Sodium Pyrophosphate, Tetra Sodium Sulfite Solvents Sulfuric Acid Sulfuryl (lliloride Thiourea Trirresv I Phosphate (ira I <>|tiem'*idfonjmide jMrU'Toluenc'ulfon. chloride Calcium Pvrophosnhate CnsJhd ' Metfn I Salicylate Plastics Phosphoric Acid Saccharin Sodium Benzoate DYESTUFF MAM FACTURE Acetic \r d Muminum Sulfate ortho. Minnndiphenvl VnilineOd ` Sodium Bi-ulfite Sodium Sidfate Sulfurx I Chloride Thiourea para-Toluencsulfonamide para-Toluenesulfon- chloride para-Toluenesulfonic Acid Wetting and Spreading Agent* ( \rekap. \resket, \rosklene. Santomerse) % c-i ting Agent* COSMETICS AND PERFUMES \l< oliol Benzoic Acid Benzyl Chloride (idlcium Phosphate, Di Calcium Phosphate, Tri (lunatic Soda ortho-\niidinr nuru- \iiisidine Benzotrtcldoride Benzov l ( hloride Benzvl ( Monde nriho-Chli'roaniline ineta-Chloroaniline para-Chloi oaniline para-Chloio.meta-Creso] orlho-Chlurophenol ELECTRICAL \nxlors Cable Dope Lacquers Lampblack Nitric Acid Phosphoric Acid Plastics Sulfuric Acid (.oumarin meia-Cresol Dicthv I Phthalate Manicure Lacquer Manicure Lacquer Remover Methyl Salicylate Phosphoric Acid Phthalic Anhydride para-Chloi ophenol Chlorostdfonic Acid ortho-Chloro-para- Toluene Soclium Sulfon ate (Monsanto Salt) ortho Cresol para-Creso1 Cyclohexylamine Dichloroaniiine engraving Acetic Acid Nitric Acid Perchloride of Iron Plastics Sulfuric Acid W ptiing Agent (Santomerse) Potassium Pyrophosphate, ortho-Dich'orobenzene , Tetra ' Dichlorophenol Salicylic Acid DinitroaniLne FLORISTS AND FRUITGROWERS \uepak Dinitrochlorobenzene Ammonia, Anhydrous W et ting Agent Glauber's Salt ortho-Dichlorobenzene H Acid DAIRY PRODUCTS Mixed Acid para-Dichlorobenzene Muriatic Acid Ammonia. Anhydrous Monochlorobenzene Sodium Phosphate, Tri Ammonium Phosphate, Mono Monsanto Salt Nitre Cake Vuepak Wetting Agent Coumarin Kthavan Merclor (Sodium Hypo chlorite) ' Santamine Sodium Acid Pyro phosphate Sodium Phosphate, Di Sodium Phosphate, Tri Sodium Pyrophosphate, Tetra Sulfuric Acid V anillin DENTAL PRODUCTS Alcohol Benzoic Acid Calcium Phosphate, Di Calcium Phosphate, Tri ortho-Nitroaniiine (Santomerse) para-Nitroaniline ortho-Nitrosnisole FOOD ortho- Nitrochlorobenzene Ammonium Benzoate meta-Xitro< hlorobcnzene Benzoic Acid L . S. P. para-Nitrochlorobenzene Calcium Phosphates Nitrodichlotobenzene Calcium Pyrophosphate ortho-Nitrophenol para-Nitrophenol Oil of Vitriol Calcium Sulfate Coumarin Monsanto Dry Ice ortho-Phenttidin Etnavan para-Pheneiidin Phenol Phosphoric Void Ferric Phosphate Methyl Salicylate Muriatic Acid Phosphorus Oxvchloride Phosphoric Acid Phosphorus Trichloride Phosphoric Acid Paste Phthalic Anhydride Sodium Acei ate Sodium Acid Pvrophosphate Saccharin Monsanto Sodium Acid Pvro- phosphate Sodium Benzoate L.S.P. Page 12 MONSANTO CHEMICU.S 0683752 Sodium Bisulfate Sodtum Phosphate, Di Sodium Phosphate, Mono Sodium Phosphate, Tri Vanillin Monsanto GLASS AND VIT REOUS WARE Abrasives Done Ash Chlorine Muriatic Acid Plastics Salt Cake Wetting Agent (Santomerse) INSECTICIDES Cresol Dibutyl Pbtbalate ortho Dichlorobenzene nara-Dichlorobenzene Methyl Salicylate Sulfur Trichlorobenzene Wetting Agent (Santomerse) LAUNDRY Chloramine T Chlorine Merclor (Sodium Hypochlorite) Sodium Bisulfate Sodium Bisulfite Sodium phosphate, Tri Sodium pyrophosphate, Tetra Wetting Agent (Santomeree) Sodium Sulfide Sulfuric Acid Wetting and Spreading Agents, (Areskap, Aresket, Aresklene, Santomerse) LUMBER LEATHER AND Lacquers TANNING Permasan Santobrite Aluminum Sulfate Santophen 20 Ammonia, Aqua Belt Cement METALS Caustic ftoda Abrasives para-Chloro-meta-Cresol Ammonia, Aqua para-Chloro-meia-Xylenol Bone Ash ortho*Dicblorobenzene C. P. Acids Dopes Caustic Soda Glauber's Salt Cresylic Acid Lacquers Fernsul (Ferric Sulfate) Lampblack Ferropboaphonis Merclor (Sodium Hibitito Hypochlorite) Inhibited Acids Mertanok (Syntan) Mixed Acid Muriatic Acid Muriatic Acid Permanol Nitric Acid Phenol Phosphoric Acid Salicylic Acid Sodium Pboapbate, Di Santotan (Baaic Chrome Sodium Phosphate, Tri Sulfatt) Sodium Pyrophosphate, Sodium pisulfate Tetra Sodium pisulfite. Sulfuric Acid Anhydrous Wetting Agent Sodium phosphate, Di (Santomerse) Sodium Sulfhydrate Zinc Chloride Solutions 0683753 LEXOLDMONOQ5683 Inspecting safety valves on the electrolytic chlorine cells at Monsanto, Illinois. MINING Abrasives Hone Ash C. P. Acids Flotation Agents (Xanthates) Nitre Cake Sodium Sulfide Sodium Sulfite - OIL REFINING Caustic Soda Chlorine Cresols Muriatic Acid Phenol Phosphoric Acid Santolubes Santopoid Santopour Sulfuric Acid PACKAGING Cast Phenolic Resin Cellulose Acetate Cellulose Nitrate Lacquers Polystyrene Santicfzer-8 V'uepak PAINT, VARNISH AND LACQUER Amyl Acetate Antioxidants Benzoic Acid Butyl Acetate Cotton Solutions Diacetone Alcohol Dibutyl Pbtl.alate Diethyl Phtbalate Dimethyl Phtbalate Ethyl Acetate Lampblack Maleic Anhydride Mertec (Chlorinated' Rubber Base Paint) Monochlorobenzene Paint Anti-Skinning Materials Phenol Phthalic Anhydride Resins Santicizers (Phthalyl Glycollates and other Plasticizers) Santoiites (Resins) Santomask (Deodorant) Solvent Alcohol (Mersol) Thinners Tricresyl Phosphate Triphenyl Phosphate PAPER Alcohol Aluminum Sulfate, Com mercial and Iron Free Ammonia, Anhydrous Ammonia, Aqua Benzoic Acid Bone Ash C. P. Acids Chlorine Coumarin Dibutyl Phthalate Ferric Sulfate Ferrisul Lacquers Muriatic Acid Page 14 MONSANTO CHEMICALS 0683754 LEXOLDMONOQ5684 Sail Cake Santicizers (Specialty Sulfuric Acid Sanlicizers plasticizers) Wetting Agent Santobrite Santolite* (Synthetic (Santomerse) Santolites resins) Santosite Thiourea TEXTILES Sodium Aluminate Tricresyl Phosphate Acetic Acid Sodium Bisulfale Triphenyl Phosphate Alcohol Sodium Bisulfite. Vuepak Aluminum Chloride Sodium Hypochlorite Sodium Phosphate, Tri Sodium Sulftae POWER AND Ammonium Phosphate, POWER PLANTS Mono Ammonia Sodium Sulfite Vlumimim Sulfate \myl Acetate Sulfuric Acid Chlorine Butyl Acetate Tricresy I Phosphate Wetting Agents ortho-Dichlorobenzene Ferrisul Calcium Phosphate, Tri Calcium Sulfate PHARMA Santobrile Caustic Soda CEUTICAL Acetanilid L. S. P. Aoetophenelidin L. S. P. Acetyl Salicylic Acid (Aspirin) Benzoic Acid U. S. P. Caffeine U. S. P. Calcium Phosphate, Di Santophen Santosite Sodium Agminate Sodium Phosphates Sodium Sulfate PRINTING INKS Muminum Chloride Aluminum Sulfate Chlorine Cresol Dibntyl Phthalate Ethyl Acetate Ferric Sulfate Glauber's Salt Lacquers Merclor Chloral Hydrate V. S. P. Antioxidants Chloramine-T l'. S. P. Anti-Skinning Agents Mixed Acid Nitrate of Iron Dichloramine-T N. F. Glycerophosphates Magnesium Phosphates. Aroclors Coumarin Lampblack Nitre Cake Oil of Vitriol Plasticizers Mrihvl Salirvlate U.S.P. Phenol V. S. P. Phenolphthalein U. S. P. Methyl Salicylate Nitrate of Iron Phenol Potassium Pyrophos phate. Tetra Santobrite Phosphoric Acid Potassium Ammonium Phosphate Santocel Santomask Sodium Aluminate Santophen 20 Sodium Acetate Sodium Acid Pyro Potassium Phosphate, Mono Saccharin U. S. P. Salicylates Salol Sodium Benzoate U. S. P. Sulfanilamide U. S. P. PLASTICS AND SYNTHETIC RUBBER Accelerators Antioxidants Caustic Spda Cycline Oil Piperidine Santobrite Sodium Sulfite Softeners phosphate Sodium Bisulfite Sodium Phosphate, Di Sodium Phosphate, Tri Sodium Pyrophosphate, Tetra Sodium Sulfate Sodium Sulfite Sopet Sulfuric Acid RESINS Ammonia, Aqua Benzoic Acid, Technical Sulfur Sulfuric Acid SOAPS AND Tricresyl Phosphate Wetting Agent (Santomerse) Cast Phenolic Resin Cellulose Acetate DETERGENTS Antioxidants WATER Cellulose Nitrate C. P. Acids TREATMENT Cresole Calcium Sulfate Aluminum Sulfate Dibutyl Phthalate Caustic S(ida Ammonia, Aqua Diethyl Phthalate Chlorosnllonic Acid Chlorine Dimethyl Phthalate Maleic Anhydride Coumarin Cresol Ferrisul (Ferric Sulfate) Santobrite Monsanto Plastics Phenol Santosite (Reducing Phenol Soda Ash Agent) Phthalic Anhydride Sodium Phosphate, Di Sodium Aluminate Polystyrene Sodium Phosphate, Tri Sodium Hypochlorite Polyvinyl Acetals Sodium Pyrophosphate, Sodium Phosphate, Di Resinox (Phenol* Tetra Sodium Phosphate, Tri Formaldehyde) Sopanox Sodium Sulfate 26TH EDITION Page 15 0683756 LEXOLDMON005686 ACCELERATORS- MONSANTO PRODUCTS ABRASIVES (See Aluminum Oxide Abrasive Grain). ACCELERATORS* RUBBER.................................................. ><< iihIinxIii.iI accelerators below for specification* ami properties. K.K. Classification: Rubber Accelerators NOlHN. Available l.iteraturei "Monsanto Chemicals for (he Rubber Industry," 12 pages. "Latex Compounding." 36 page*. "Rubber Compounding for the Wire Indusiry,'* 18 pages. "Santocnre-- Vn Accelerator for Rubber \ ulcanizalion," 32 pages. *A-10"___________ Specifications: Condensation product of aniline and formaldehyde. It is neither meihvlene dianilide nor formaldehyde aniline, but probably a mixture in which the latter product predominates. White or yellowish tinted powder; 95 per cent through 200 mesh and 99 per cent through 100 mesh; loss on beating less than 5.0 per cent when heated for two hours at 105'C.; m.p., begins to soften at 1204C.: p. g. 1.17; uncombineil reagents, no excess of free aniline and not more than truces of formaldehyde. ** A-19" Specifications: Formaldehyde derivative of a condensation product of aniline and acetaldehyde, of complex chemical composition. Brown resinous powder; m.p. between 75'C. and 85C.; sp. g 1.17. Specifications: Reaction product of butyraldehyde and butylidene aniline. The chemical structure of such products is necessarily complex. Red yellow to orange brown oily liquid, slightly turbid when cold; sp. g. 0.98; flash point 80C.; soluble in benzene, chloroform, acetone and solvent naphtha. Specifications: Light tan powder; constant composition blend of Santocure and HI Sixty. ! 6 T H B n I TIO > Page 17 0683757 LEXOLDMONOQ5687 ACCELERATORS "A-77M Specifications! Condensation product of acetaldehyde and aniline by a special Monsanto process. Such product s, known as aldeh\de derivaiives of SchifTs bj>es, are of complex chemical composition. Free flowing reddish brown liquid; p. g. I.HI: fla*h point 5.VC.: soluble in benzene, chloroform and acetone; partly oinlile in alcohol ami gasoline. Specifications! Aldehyde derivative of a Si-liiffs base made with the use of both liutyruldehyde and uceialdei >de. Dark reddish brown oily liquid; sp. g. 1.01: flash point Bo'C.; soluble in benzene, cliloroforin, acetone and solvent naphtha. `BL'TASAN" (Zinc Salt of Dibutyl Dithiocarbamic Acid)____ Specifications: Cream colored powder; sp.g., 1.2 U melting point, 106C.; cur* at temperatures below lOO^C. General Information: 0.5% to 1 % on rubber weight used in latex, cements, for dipped goods, adhesives, coatings, etc. DPG (Diphenylguanuline) Specifications: White powder, not darker than the approved color standard: no residue on 100 mesh screen; m. p. not less than 146C.; sp. g. 1.19; strength, 99.0% min. of DPG by acidimetric titration; soluble in alcohol, benzene, chloro form and ether; very slightly soluble in water. "EL SIXTY" (Dibenzothiazyldimethvithiol urea) Specifications! A light cream colored powder; 99.5% min. through 200 mesh, no coarse particles; m.p. 220C. min.; sp. g. 1.29; very slightly soluble in acetone, alcohol and chloroform; slightly soluble in hot pyridine or orthodichlorbenzene. "ETHASAN" (Zinc Salt of Diethyl Dithiocarbamic Acid)___ Specifications: White powder; sp.g , 1.5; melting point, 173C. General Information: 0.5% to 1% on rubber weight used in latex. Page 18 MONSANTO CHEMICALS 0683758 LEXOLDMONOQ5688 ACCELERATORS "GLANTAL" Specifications: Ester formed by reacting two molecules of diphenylguanidine and one molecule of pluhalic acid; contains one-half mole of water of crystalliza tion. White powder ranging from blue white to faint gray; 99.5% min. through 201) mesh, no coarse particles; m. p 178C. min.; sp. g. 1.20; soluble in alcohol; insoluble in benzene and gasoline. "METHASAN" (Zinc Salt of Dimethyl Dithiocarbamic Acid) .Specifications; White powder; sj .g., 2.00; melting point, 249C.; cures at temperatures below 100C. General Information: 0.5 to 1% on rubber weight used in latex and cements. PIP-PIP (Piperidine-pentamethylene Dithiocarbamate) _____ Specifications: Fluffy, cream colored powder; 98.0% min. through 200 mesh and 99.5 per cent through 100 mesh; m.p. over 160C. at time of shipment. Decomposes slowly in the presence of water and during storage with a corre sponding drop in melting point. Sp. g. 1.13; soluble in alcohol and solvents con* taining water. "R-2" CRYSTALS Specifications! Reaction product of carbon bisulfide with methylenedipiperi* dine. Light brown coarse crystallint solid; sp. g. 1.11; m. p. between 50C. and 60C. "SANTOCURE"_________ ___________________________________ Specifications: Condensation product of mercaptobenzothiazole with cyclo* hexylamine. Light tan or buff colored powder; 99.5% min. through 200 mesh; m.p. 90C. min.; sp. g. 1.27. Available Literature: 52-page booklet, "Santocure--An Accelerator for Rubber Vulcanization.** "TACKOL" Specifications: Standardized, uniform blend of resins and oils. Viscous brown liquid. Odor is distinctive coumarone-like; sp. g. 1.05; flash point 160C. 26TR EDITION Page 19 0683759 LEXOLDMON005689 AC C h'l F.RATORS General Information: l sed as a softener or tack producer in rubber. Available Literature: 42-page booklet: "Monsanto Chemicals for the Rubber Industry," THIOCAKBANIUDE Specifications: While powder, not darker than the approved color Miindard; o uiin. ilirougli l()U mesh, noooirse particles: m. p. not |es than II8 C.: sp. g. I..12: insoluble in water and many other common *o|vents soluble in alcohol. THIl'RAD" (Tetramethyl Thiuram Disulfide) Specifications: Sp.g., 1.29; melting point, 116-1 tC.; color, white: odor, none; soluble in carbon bisulfide, benzene a^d chloroform; insoluble in water, dilute caustic and gasoline. "UREKA" Specifications: Constant composition blend of diphenylguanidine and 2, tdinilrophenyl tliiobenzolhiazole. Uniform light yellow powder; 99.5% min. through 200 mesh, no coarse particles; m. p. between 117C. and 127C.; sp. g. 1,25; soluble in alcohol and chloroform. "I REKA BLEND B" Specifications! A blend similar to "l reka" with a portion of the "DPG" re placed by "Guamal." Yellow to brownish powder; 99.5% min. through 200 mesh, no coarse particles; m.p. 130C. min.; sp. g. 1.33. "UREKA C" (Benzothiazylthiobenzoate) Specifications: An acyl-thiazole powder in which (he acidic hydrogen atom of niercaptobenzothiazole has been replaced by a benzoyl group. A pale ivory or yellowish powder; 100 per cent through 30 mesh: m.p. not less than 1159C.; __ sp. g. 1.43; soluble in chloroform and benzene; slightly soluble in alcohol. ACETAMLID, U.S.P. NHCOCH* Mol. Wt. 135.16 Page 20 {Continued) MONSANTO CHEMICALS 0683760 Specification*! White crystal* or powder; ash 0.05% mas.; conforms to I'.S.P. test9 for carbonizable impurities ami heavy metal*; solubility in ethvl alcohol 05%, complete; m.p. II l.0cC. min.; no crystals retained on 11 mesh; 3.0% mat. ponder retained on 80 mesh. II.K. Classification: Wetaniliri. Generul Information! Pharmai eutical product. ACETIC ACID - CHjCOOH Gradest 56% CjHjQj: *p-g. 1.067; freezing point --8.0F. 70% QlIjOj: sp.g. 1.074; freezing point -f-0.6F. 80% QH^Oj: sp.g. 1.076; freezing point + 17. tF. 81% CjHjOj: *p.g. 1.075; freezing point 4-27.3F. Glacial: 99% CjHjOj; sp g. 1.0576; freezing point +58.3F. H.K. Classification i Acetic Acid. General Information! Used in dyeing where a weak acid is required in (he dye bath; in the manufacture of acetate solvent*; manufacture of cellulose acetate; and in the formation of oi her acetates, such as aluminum, lead, sodium, and ammonium acetate. Also used in manufacture of fish glue; as an antichlor: coagulation of rubber latex; destrurlion of fungi; disinfectant in gelatine: pickling foodstuffs; giving added detergency and firmness to soap; stabilizing olive oil; protecting seedlings from injury due to root rot and damping off; hardening and developing solutions for photographic films. (See table in general data section) ACETONE C. P. Typical Analysis: Water white liquid; non-volatile matter, not more than 0.001 gram when 100 cc. are evaporated and heated to constant weight at 100C. to 110C.; water solubility, miscible with distilled water in all proportions; dryness, no turbidity when one volume is mixed with 19 volumes of 609B6. gasoline at 20C.; sp. g., 0.791 to 0.793 at 20C./208C.; rcidity, less than 0.002%, calculated as COj.; purity, 99-100% dimethyl ketone; potassium permanganate test, color of added potassium permanganate retained at least two hours when 1 cc. of a 0.1% solution is added to 100 cc. of Acetone; chlorides, none; iron, none; odor, mild--non-residual; flash point, -- 1880. (--0.48F.): w t. per U.S. gal., 6.59 lbs. at 68F. R.H. Classificationi Acetone. General Information! Acetone is faster drying than ethyl acetate and a more active solvent. It is an important constituent of quick-drying water proof ce ments; an active solvent for cellul<>*e acetate; a good dye solvent; resin solvent used extensively in paint removt rs and cleaners and for various extraction, processes. 26T H It D IT IO N Page 21 0683761 ACETOPHENETIDIN, U.S.P NHCOCHj Mol. Wi. 179.11 Standard Forms: Crystals: powder. Spccifications:White crystals or crystalline powder; Solubility in ethvl alcohol ''i'o (1:15), complete: m.p. 135.0C. min.; ash .05% max. No crystals retained <>n 11 mesh screen; 5% powder retained on 100 mesb. K.R. Classfication: Chemicals NOIftN. General Information: Pharmaceutical product. paro-ACETYL-AMINO-BENZENESULFONECHLOR IDE_____ NHCOCH, 0 so,a Mol. Wt. 233.59 Standard Forms Crystals. Characteristics: Light tan to browi-ish powder or fine crystals; assay, 97.5% min. K.R. Classification: Chemicals NOI8N. General Informations Used as an intermediate in the manufacture of sulfa drugs. ACETYL SALICYLIC ACID, U.S.P. (Also known as Aspirin) COOH 0OCOCHi Mol. Wt. 180.06 Standard Forms: Crystals, 20 mesh Crystals, 40 mesb Powder, 80 mesh Specifications t White crystals or poyder; assay 99.5% min.; solubility in ethyl alcohol 95% (1:5), complete; solubility in 10% NajCOj(l:20), complete; ash, 0.05% max.; conforms to U.S.P. test for heavy metals, carbooizable impurities, resinous products, chloride, sulfate. apd free salicylic acid. (Continued) Page 22 MONSANTO CHEMICALS 0683762 Ml.SH: Retained oil-- JO mciiti screen 30 mesh screen 10 mesh screen 15 mesh screen 50 mesh screen 60 mesh screen HO mesh screen Thru-- 100 mesh screen 140 mesh screen 20-mesh iO-mesh 80-mesh Trace mas. 5.0% min. 10.0% min. 45.0% min. 60.0% max. 70.0% mm. 85.0% max. Trace max. 10.0% min. 20.0% mat. 20.0% mat. 15.0% min. 60.0% mat. none 10.0% mat. 25.0% max. R.R. Classification! Acetyl Salicylic Acid. General Information! Pharmaceutical product. ACETYL SALICYLIC ACID, Starch Granulations Standard Format 10%., 12*50 mesh, white 16%, 12*50 mesh, white 20%, 12*50 mesh, white 10%, 12*50 mesh, pink 10%, 20 mesh, pink 10%, 12*50 mesh, green 10%, 20 mesh, green Specifications! (Made with Acetyl Salicylic Acid U.S.P.) White, pink or green granules. Assay: starch granulation 10%, 90.0% min. 91.0% mat.; starch granulation 16%, 84.0% min. 85.0% max.; starch granulation 20%, 80.0% min. 81.0% max. Free salicylic acid conforms to U.S.P. test on Acetyl Salicylic \oid. UF.SH: Retained on-- 12 mesh screen 14 mesh screen 16 raesh screen 20 mesh screen Thru-- 40 mesh screen TH EDITION 12`50 mesh Trace, max. 5.0% min. 15.0% max. 20.0% min. H5.0% max. 60.0% min. 5.0% max. k0.0% max. (Continued) 20-mesh Trace, max 0683763 LEXOLDMONOQ5693 K.IL Classification; Acetyl Salicylic Acid. General Information: Pharmaceutical product. ACID CALCIl'M PHOSPHATE (See CaMum Phosphate. Mono). VIRCRAFT FINISHES __ Commercial Finishes: \ircraft finishes include protective and decorative coatings for every part of the aircraft structure, such as fabric dopes (clear and colors) for wings, control sur. faces and fusilage; primers, surfacers and lacquers for aluminum and dural sheet; llume-proof dopes for interiors, thinners, cleaning solvents. Properties of the com mercial finishes in application conform to the best modern plant practice, and properties in service meet the severe requirements of resistance to stress, sea water corrosion, weather, gas and oil. .Monsanto finishes have for years been accepted as standard bv manufacturers and airlines. CMDK NO. TYPE OF PRODUCT For Fabric--Dopes L-.'Jdul L-1031 L-2194 L-760 L-3193 L-3195 I.-2391 Clear Nitrate Dope (high solids) Clear Nitrate Dope (medium solids) Clear Nitrate Dope (comm, grade) Fully Pigmented Dopes--all colors; non-bleeding reds: matt, resist ance to fading and chalking. Interior Fire-Resistant Clear Dope Interior Fire-Resistant Pigmented Dopes--all colors. Finish Reclaimer (Rejuvent tor) for Nitrate Dope For Metal--Primers, Surfacers, and Lacquers R-4017 Yellow 728 Zinc Chromate--Fa*t Drying. R-4063 Gray 578 Synthetic Primer Surfaces--Slow Drying. R-3552 Gray 423 Lacquer and Dope Snrfacer. L-2939 Clear Aluminum Vehicle. R-3785 Fully Pigmented Lacquers--all colors (except light shades); non bleeding reds; max. resistance to fading. 1.-1518 L-1087 L-2680 L-3196 L-1034 Page 24 Thinners (Reducers)--AU Types Standard lacquer and dope thinner. Retarder (anti-blush) Brush wash for general cleaning. For fire-resistant (acetate). Wax-free remover (dope and lacquer). (Continued) MONSANTO CHEMICALS 068376* LEXOLDMONOQ5694 I . S. Vrmy and Nuy Specification Finishes; .............tlage finishes f<r ......that aircraft were added in the Monsanto line eurlv in the Defense Program. These finishes are in addition to the original l\ S. Armv and l. S. Navy specification materials of which Monsanto has long been an approved supplier. Finishes under the new combined Ar. / and Navy specifica tion* (WTT) are now available. W-l r-|,.t,.>6 V \ -1 l -l . * 1 W-TT-D-SSl I Iln.S M IK.> \ \Utal Surfaces Zinc Chromate Primer. (/loss Lanpicr Odor*. (dear Alnniimnn Bronze Vehicle. Armv Camniifhigc Colored Lacquers. Navy Catuoulbvge Colored Lacquers. Fuhric Surfaces A\-TT-D.51 l \\-TT-l)..V6 VN-TT.D.554 I 1106 M-198 Clear Dope. Seim-Pigmented Colored Dopes. Fiillyd'igmemed Colored Dopes. Army Camnullege Colored Dopes. Navy Camouflage Colored Dopes. Thin/ters AN-TT-T-256 For use with above lacquers. AN-TT-T-258 Blush Retarder for above lacquers. ICR. Classification: Lacquer. ALCOHOL (See Ethyl Alcohol). ALKYL PHOSPHORIC ACIDS Properties: Amyl Phosphoric Acid (from PentasoJ): fluorescent reddish amber liquid; sp.g., 1.33 at 25C.; alky I acid content, approx. 99%.* n-Butyl Phosphoric Acidi fluorescent reddish amber liquid; sp.g., 1.24 at 253C.: alkyl acid content, approx. 99%.* Ethyl Phosphoric Acid: pale straw colored liquid; *p,g., 1.33 at 25C.; alkyl acid content, apptox. 97%.* Methyl Phosphoric Acidi pale straw colored liquid; p.g. 1.439 at 25C.; alkyl acid content, apptox. 97%.* n-Propyl Phosphoric Acid: reddish amber liquid; sp.g., 1.30 at 25C.; alkyl acid content, approx. 97%.* * Balance of assay is ortho-phospboric acid and unconverted alcohoL R.K. Classification: Phosphoric Acid. (Continued) 2<STH edition Page 25 0683765 LEXOLDMON005695 General Information: The Alkyl Phosphoric Acids are mobile liquids which ran be neutralized with alkalis and amines with resultant water-soluble salts. The methyl, ethvl and propyl phosphoric acids are water-9oluble, but the butyl and amyl acids are not. The salts of all are water-soluble. The methyl and ethyl phosphoric acids and their salts a^e very hygroscopic (amine, sodium and potassium sails) whereas the propyl, bt lyl anil amyl acids are not hygroscopic and their sails <mlv slightly so. Alkyl Phosphoric Acids are used in textile and paper processing compounds: a- I'uiaK -is in urea resin formation: as polymerizing agents for resins and oils. ALUM (See Aluminum Sulfate). ALUMINUM CHLORIDE AljCU Mol. Wi. 266.7 Standard Forma: Liquid. 32a B., 56% ALC1 +12 H.O approx.; crystals,* 97% Al.-Clt +12H:0 approx. Typical Analysis: Neutral salt, low in nron content. Solutions have an acid re* action but contain no free acid. Typical analysis as follows: Crystal Liquid ALCI* 12 H-O 97.2% 50.3% ALO, 20.5 10.6 Cl 42.7 22.1 Fe .003-.005 .005 K.R. Classifications: Aluminum Chloride Dry or Aluminum Chloride Liquid. General Information: Used in carbonizing fine wool such as piece goods, raw stock or shoddy, resulting in an exceptionally white, lofty wool. Also in car bonizing colored goods where it has vety little stripping action. Used in soap manufacture for treatment of glycerin lyes where chloride of alumina is more desirable than sulphate. (See table in gemral data section) Crystals: Resale product. ALUMINUM OXIDE ABRASIVE GRAIN (Also known as fused aluminum oxide; artificial corundum.) Specifications: Fused aluminum oxide containing 95-99% AljOj; hardness 9.6, Moh's scale. R.K. Classifications: Abrasive flour or grain. General Information: Coarse to flour grades are available for grinding wheels, polishing, refractory purposes, and for anti-slip or tread use. Page 26 Monsanto chemicals 0663766 ALUMINUM SULFATE, COMMERCIAL Alj(S04)j. 14.5 HjO Standard Forms Fine to lump. Typical Analysis* AljOj, 17.2%; FeO, 0.35%; FejOj, 0.01%. K.K. Classifications Aluminum Sulfate. General Informations Used in paper sizing and water treatment. Monsanto also provides a slab form (6'x6**18') for stock solutions; this form contains 15.5 16.0% AljOj. (See foWe in general data section) ALUMINUM SULFATE, IRON FREE AI*<S04),. 14.5 HjO Standard Forms Fine to lump. Typical Analysias AljOj, 17.2%; FejOj, 0.01%. R.R. Classifications Aluminum Sulfate. General Informations Used in sizing fine papers; manufacture of satin white and dry colors; tanning white leathers; dyeing operations. ort/io-AMINODIPHENYL, TECHNICAL (Also known as 2<aminobipbenyl.) NH, Mol. Wt. 169.10 Standard Forms Fused solid. ' Specifications! Purplish crystalline mass; crystallizing point 47,0eC. min.; assay 94.5% min. Distillation range: first drop, 29S.0eC. min.; 95% (1-96 ml), 8.0C. mix.; dry point, 310.0C. mas. R.R. Classification! Dye Intermediate- General Informations Used as in intermediate in dyestuff synthesis; in the production of resins; in the production of varnishes; in the synthesis of rubber products; as a solvent. CAUTION: THU product is toxic. Avoid breathing its vapors and avoid contact with the skin, 26TH EDITION Page 27 0683767 LEXOLDMON005697 para-AMINODIPHENYL, TECHNICAL (Alto known as 4-aminnbipbenyl.) 0 0- TM Mol. Wt. 169.10 Standard Forms Fused solid. Specifications: Yellowish brown crystalline mass; crystallizing point 50.5*0. min. Distillation range: First drop, 325.0*0. min.; 95% (1 -96 ml), 8.0*0. max.; dry point, 340*0. max. K.K. Classifications Dye Intermediate. General Informations Used as an intermediate in dyestuff synthesis; in the production of resins; in the production of varnishes; as a solvent. CAUTION: Thi$ product is toxic. Avoid breathing its vaport and avoid contact with the tkin. 2-AMINOTHIAZOLE. HC-------- S II I HC C -- NH. Mol. Wt. 100.14 Standard Forms Crystals Characteristics! Light brown crystals. R.R. Classificationt Chemicals NOIBN. General Informations Used as an intermediate in organic synthesis. AMMONIA, ANHYDROUS _ Properties! At normal temperatures and pressures Ammonia Anhydrous is a colorless gas, 0.597 times as heavy as air. It is readily condensed by the ap plication of pressure below 268eF. to a colorless liquid weighing 5.33 lbs. per gal., and having a boiling point of -- 28F. R.R. Classifications Anhydrous Ammonia. General Information* Ammonia Anhydrous is used in refrigeration; as a con densing agent in the formation of pbeoolformaldebyde resins; in water treatment in connection with chlorine; partial neutralisation of phosphate fertiliser; in vulcanization of rubber; nitriding of steel; as a neutralising agent after carbon izing; neutralizing excess carbon dioxide in water supplies; neutralising and deodorising rubber goods which hav# been cured with sulfur chloride; neutral izing petroleum stocks before crackling; as a relatively inexpensive aouroe of hydrogen or nitrogen; and as a solvent. (See table in general data section) Available Literatures Leaflet: "Monsanto Ammonia for Refrigeration." Page 28 Monsanto chemicals 0683766 AMMONIA, AQUA NHiOH Mol. Wt. 3S.0S Standard Forms: Commercial Aqua Ammonia 16, 18% 20% 26 BA Properties: Pungent, water white liquid; wt. per gal. 7.48 lbs. (26s). K.R. Classification! Ammonia Aqoa. General Information! Uses--1. Partial neutralization of phosphate fertilizers. 2. General household cleaning purposes. 3. As a condensing agent in the forma* tion of phenol*formaldebyde resins. 4. As an antichlor. 5. After carbonizing, as a neutralizing agent. 6. Neutralization of excess carbon dioxide in water supplies. 7. Neutralizing and deodorizing rubber goods which have been cured with sulphur chloride. 8. Neutralizing goods w!>ich have been dyed with aniline black. 9. Pre serving rubber latex. 10. Neutralizing oil before cracking. 11. Silk degumming. 12. Manufacture of cuprammoniqm silk. 13. As a solvent. 14. As a debarring agent for bides. 15. For reeling silk. 16. As a penetrant in wetting back crusted tanned leather. 17. As a penetrant for driving in fat liquor in leather making. (See table in general data tection) AMMONIUM BENZOATE Mol. Wt. 139.1S Standard Form i Powder. Specifications! Fine white crystalline powder; assay 98.0% min.; solution in water (1:10) clear. R.R. Classification! Chemicals NOIBN. General Information! Used as *> preservative. AMMONIUM ETHYL PHOSPHATE (Mixture of mono* and diethyl ammonium phosphates). Standard Formi 75% solution is water. Properties: Water-white to yellow-tinged liquid of ammoniacal odor; sp. g. 1.23 at 25'C.; wt. per gal. 10.37 lbs.; pH 75% sol.; 7.0 * 7.2; viscosity at 25C., 60 centipoises. Chemical constitution: 67% mono ethyl ammonium phoepbate; (Continued) 26TB EDITION Page 29 0683769 33% di ethyl Ammonium phosphate. In thin film is liquid at relative humidities above 40%; not stable to heat; when subjected to elevated temperatures for any length of time as a solution or while on any article, will liberate ammonia with a reduction in pH; at temperatures below 1SC. crystals will form in tbe solution and will dissolve with a rise in temperature or on dilution. R.R- Classification t Ammonium Phosphate. General Informations Used as flame proofing agent for paper, textiles, wood ami other combustible materials. AMMONIUM HYDROXIDE C. P. NHOH Mol. Wt. 35.06 specifications* Colorless liquid, free from suspended matter; strength (N'Hj) 28.0% min.; nonvolatile matter 0.005% max.; carbon dioxide (COj) 0.i">2% max.; total sulphur (as SO4) 0.0003% max.; chloride (Cl) 0.00005% max.: pyri dine, to pass A.C.S. test; substances (educing (KMnO), to pass A.C.S. test; iron 0.0001% max.; heavy metals (as had) 0.0005%. R.R. Classification: Chemicals, Ammonia. General Information: Laboratory reagent. AMMONIUM PHOSPHATE, Dl (Also known as diammonium hydrogen phosphate, secondary ammonium phos phate, and ammonium phosphate di-basic.) (NH4),HP04 Mol. Wt. 132.068 Grades: Food (meets sU U. S. Pure Food Law requirements); special grades supplied on request. Properties: White crystalline material, stable in air and very soluble in water: pH value of 1% solution, 7.75. At temperatures above 70C. aqueous solutions lose ammonia readily. Dissociation Pressure: According to Britake and Dumajew (Gmelin's Handbuch der anorganiscbe Chemie, Ammoniak, p.423) and Warren (JACS 49, 1904,1927): Temp. C. 98 111 125 135 147 p NHj in mm. Hg. 3.2 10.7 26.0 55.2 123.4 R.R. Claaaificatlom Phosphate of Ammonia. General Information: Used as a fire retardant in fire-proofing and as a yeast food by yeast producers and breweries. Page 30 NTO CHEMICALS 0663770 7= 5 iH illSefait/'fv ef PitmmiK'um PhottioH .<1 ? s > 3 v> V1L%., 'ii I p/VMofMixfmufrf $ ofOP'ohmomtpoAt 3L H-43 \ s s V-77f Ptntrrr OAP-OtM,^ HPC, IOC 90 tO 10 60 SO 40 SO 10 !0 0 Ptntnt MAP'NHtWQ, AMMONIUM PHOSPHATE, MONO (Also known as ammonium aciti phosphate, primary ammonium phosphate, ammonium dihydrogen phosphate, ammonium phosphate mono-basic, am monium biphosphate). NH4HjP04 Mol. Wt. 115.04 Gradesi Food grade meets all U.S. Pure Food Law requirements. Special grades will be supplied on request. Properties! A white crystalline material, stable in air and soluble in hot and cold water; pH of 1% solution, 4 7. R.R. Classificationt Phosphate of Ammonia. General Information! Used as a retardant in fireproofing and paper special ties, for special medicinal purposes, in the production of woven belting, and as a yeast food. AMMONIUM SALICYLATE N.F. (See Salicylates). AMYL ACETATE_______ ____________________________________ Typical Analysis! Water white liquid; odor, no residual; sp. g. 0.865 0.870 at 15.5C.; shipping wt, per gal., 7.?0 lbs.; acidity, less than 0.01% as free acetic acid; dryness, mixes with petroleum benzine in all proportions without turbidity. Boiling range: below 110C., none above 130C., less than 50%; above 1S0C-. none. Ester content, 85-90%. (Continued) 16TH EDITION Page 31 0683771 LEXOLDMON005701 R,R, Classification: Amyl Acetate. General Information! Used as a nitrocellulose solvent. It is less active than ethyl or butyl acetate and more resistant to moisture. Blends of all three with appropriate diluents such as alcohols (ethyl, butyl, and amyl) yield thinners and solvent mixtures of excellent cutting power, moisture resistance, good flow ar.d leveling, and compatability with various resins and oils. Used in the artificial leather industry and in formulating lacquer finishes for wood, metals, textiles, und paper. A AH L PHOSPHORIC ACID (See Alkyl Phosphoric Acids). ANILINE OIL_______________________________________________ (\lnn known as aminobenzene), NH* Mol. Wt. 93.13 Specifications) Slightly yellowish liquid; purity, 99.5% min.; distillation range, 95% within 0.5C.; distillation limits, 182.0 to 185.0C. (dry point); crystallizing point, --6.2C. min.; moisture, 0.10% max.; solution in HCI, complete; nitro* benzene, none. R.R. Classifications Aniline. "Poison" label required. General Informations A basic intermediate in the dyestuff industry. It also finds application in the production of rubber accelerators, as a constituent of resins and in the manufacture of explosives. CAUTION: This product is toxic. Avoid breathing its vapors. Avoid contact with the skin. ortho-ANISIDINE__________ (Also known as ortho*metboxyantliae, ordio-amtnoaniaole, and l-amino-2-me- ihnxvbenzene.) OCH, > NH, Mot. Wt. 123.15 Standard Forms Liquid Specifications! Reddish brown to amber liquid; crystallizing point 5.3C. min. Distillation range: first drop 223.0aC. min.; 95%, 1.2C. max.; dry point, 226.0C. max. Solution in HCI, clear. R.R. Classifications Dye Intermediate. General Information s Used as a coioponent of azo dyes and in the manufacture (Continued) Page 32 wonsanto chemicals 0683772 of dyestuff intermediates. CAUTION: This product is toxic. Avoid breathing its capon and amid contact uith the skin. para-ANISIDINE---------------------------------------------------------------------------------(Also known as pora-metboxyanilioe, pora-aminoanisole, and 1-amino-4.meth- oiy benzene.) OCH, Mol. Wt. 123.15 MI. Standard Form: Fused solid Specifications: Fused, crystalline mass; crystallizing point 57.2C. min. Distilla tion range: first drop 240.0C. min.; 95% 2.0C. max.: dry point 243.09C. max. Solution in HCI clear, darkens on ageing. K.R. Classification: Dye Intermediate. General Information: Used as a component of various azo dyestuffs and as an intermediate in chemical synthesis. CAUTION: This product is toxic. Avoid breathing its vapors. Aioid contact u ith the skin. ANTI-OXIDANTS, OIL (S<-e Santolube). i-- ANTIOXIDANTS, RUBBER See individual antioxidants below for specifications. R.R. Classificationt Chemicals MOIBN. Available Literature: "Monsanto Chemicals for the Rubber Industry," 42 pages. "Latex Compounding," 36 pages. "Rubber Compounding for the Wire Industry," 48 pages. "FLECTOL H" Specifications: Condensation product of acetone and aniline. Light colored powder: 99.5% min. through 200 mesh, no coarse particles: m. p. 120C. min.; sp. g. 1.08; antioxidant value equal to that of the accepted standard in vulcan ized rubber, both in oxygen bomb and standard flexing tests; solubility approx. 10% in benzene, alcohol and gasoline: insoluble in water. "FLECTOL WHITE"_____ Specifications: Light colored powder, not darker than the approved color (Continued) 26TH edition Page 33 A N T IO X ID A N T S 0663773 standard; 99.5% min. through 200 ursh, no coarse particles; m. p. 145C. nun.; sp. g. 1.25; antioxidant value equ * io that of the accepted standard in ultra violet light tests; soluble in alcohoi. very slightly soluble in water and benzene, insoluble in gasoline. "OXYNONE" (2, 4-Diamino Diphenylamine) Specifications: Brown crystalline powder; 99.5 per cent through 100 mesh and 95 per cent throush 200 mesh, no coarte particles; m. p. not less than 123C,.; sp. g. 1.25; soluble in alcohoi, chloroform and benzol; very slightly soluble in cold water and gasoline. ANTIO XIDANTS "SANTOFLEX B" Specifications: Reaction product of acetone and para-aminodipbenyl. Waxy, dark gray, lumpy solid; crystallizing point about 80C.; sp. g. 1.045. "SANTOFLEX BX" Specifications! Constant composition blend of Santoflex B and diphenyl-para, phenylene diamine. Waxy, dark gray, lumpy solid; sp. g. 1.11, "SANTOVAR A" Specifications: Alkylated polybydroxy phenol. Nearly white crystalline powder, no darker than the accepted standard; m. p. not less than 165C.; sp. g. 1.049; completely soluble in twice its weight of acetone. General Information! Used as a varnish anti>skinning agent; as an antioxidant in oils, paints, and rubber. ANTISEPTICS AND GERMICIDES Chloramine-T L'.S.P. (See under C). pora-Chloro-meto-Cresol (See under C). para-Ch)ro-meta-Xylenol (See under C). Dichloramine-7 N.F. (See under D). Phenol U.S.P. (See under P). "Santamine" (See under S). "Santopben" (See under S). ARESKAP (Monobutyl Phenylphenol Sodium Monosulfonate) Standard Format Liquid and dry powder. (Continued) Page34 Monsanto chbmicals 0683774 K.R. Classification! Washing Compound NOIBN General Information: Wetting, penetrating and spreading agent; used as spreading agent in insecticidal compositions, in embalming fluids and in metal pickling. AHESKET (Monobutyl Diphenyl Sodium Monosulfonate)___ Standard Forms: Liquid and dry powder. It.It. Classification: Washing Compound NOIBN. General Information t W'etting, penetrating and spreading ageot. AKESKLENE (Dibutyl Phenylphenol Sodium Disulfonate)__ Standard Forms: Crystals and g>auboids. Typical Analysis: 43% NajSO* available. Dry AreBklene-400: Tan hygroscopic powder, slightly aromatic; sulfates, trace; chlorides, trace; m. p. about 160C.; pH, approx. 7.5 for 1% solution of dry material at 25C.; soluble (10 parts to 90 parts solvent) in alcohol, acetone, dibutyl tartrate, ethylene glycol, ethyl acetate and butyl cellosolve. Aresklene-375: Light brown paste, slightly aromatic; sulfates, trace; chlorides, (Continued) A laboratory in the new rubber chemicals research building at Nitro, W. Va, 0683775 LEXOLDMON005705 trace; m. p., decomposes at about 175 C.; not soluble in solvents which are immiscible with water. R.H. Classification: Washing Compound, NOIBX. (General Information: Wetting, penetrating and spreading agent used in kicrhoiling, scouring and dying textiles, in industrial cleaners, in deodorant preparations, in insecticidal formulations, in metal cleaning and as a stabilizer .md wetting agent in latex used to treat tord or other fabrics. "AROCLORS" Specifications: The Aroclors are chlorinated hydrocarbons which varv from water-white mobile liquids and pale yellow viscous oils to light amber resins and opaque crystalline solids. Non-flammability: The viscous Aroclor oils and resins do not support combustion when heated alone even at their boiling points-- temperatures above 360C. Most of the Aroclors flux readily with resinous and pitch-like materials to give a product hat ing a decreased fire hazard. Electrical properties: The Aroclors have excellent electrical characteristics, high dielectric strength and resistivity, low power factor. Certain of the liquid Aroclors have a high dielectric constant as compared with that of mineral oils. Solubility: The Aroclor oils and resins are easily soluble in most of the common organic solvents and drying oils. The hard crystalline materials are in general less soluble than the oils of resins. AH Aroclors are insoluble in water, Adhesiveness: The more viscous Aroclor and Aroclor resins have excellent adhesive properties. Thermoplasticitv: The Aroclors are thermoplastic, and apparently undergo no further condensation or hardening upon repeated melting and cooling. Non-drying properties: The Aroclors are non-drying, and when they are exposed to the air no noticeable oxidation or hardening takes place. Vaporisation loss: The clear resins have rather low vaporization losses. At 65.8`C. (150F.) these losges are less than 0.04 g. per square inch of surface per month. Odor and taste: The Aroclor viscous oils and resins are almost without odor and taste at ordinary temper atures. Refractive indices: The refractne indices of these materials are above 1.6125. Stability: The Aroclors in general are stable on long heating at 150C. and are not affected by boiling with sodium hydroxide solution. Tbe light oils ran be distilled at atmospheric pressure without appreciable decomposition and the viscous oils and resins distill readily under vacuum. Corrosiveness: The Aroclors have practically no corrosive action when applied to metallic surfaces. General Information: Uses: Lacquer, paint and varnish: Aroclors impart resistance to moisture, gas, acids, alkalies, end ultra violet light and improve electrical insulating properties and durability. They function as both plasticizers and resins in nitrocellulose and ethyl cellulose lacquers. Sealing Waxes: Where a moisture proof, non-flammable wax or one with good electrical insulating properties is desired. Adhesives: Aroclors in adhesive application have tbe desirable qualities of being non-crystalline, insoluble in water, thermoplastic, light in color, practically odorless, non-drying, and soluble in most organic sol vents. They provide excellent adhesion even to lacquered or varnished surfaces. Impregnation: Aroclors are used in impregnation of materials and articles to give them resistance to moisture, flamet alkalies and acids, and to improve electrical insulating properties. Corresponding to each clear Aroclor there is also a black Aroclor of similar properties. F/ameproo/ing; Aroclors are used in combination with many other materials to reduce tbe flammability of those materials. Rubber and rubber substitutes: The liquid Aroclors have a solvent (Continued) Page 36 Monsanto chemicals 0683776 action on rubber and act as plasticizer. The solid Aroclors impart flame resist ance. Plastics: The Aroclors are compatible with nitrocellulose, ethyl cellulose and vinyl resins. In ground powder form is an excellent organic pigment. Available Literature: 20-page Utoklet "The Aroclors--Physical Pro|>orties and Suggested Applications." ASPIRIN (See Acetyl Salicylic Acid). BATTERY ACID (Electrolyte) Typical Analysis: Practically colorless liquid; HjSOt, 93.2% min.; iron, 0.005% max.; nitrogen compounds (as HNOj), 0.001% max; sp. g. 1.210-1.835. (Acids of tower strengths should be calculated in proportion to above specification on H}SO| content.) R.R. Classification: Sulfuric Aci<>. Ceneral Information: Electrolyte is sulfuric acid, especially adapted to tbe needs of the storage battery trade Various strengths can be furnished to meet the needs of the individual purchaser. BELT CEMENT Ceneral Information: Nitrocellulose base cements for cementing ply belting and taps. Characterized by strength, flexibility, rapid drying properties, and resistance to water. Specially adapted to power belting. More flexible types are ofTered for wool combing aprons and paper machine dryer felts. R.R. Classification: Lacquers. BENZENE SULFONAMIDE, TECHNICAL O Mol. Wt. 157.18 O Characteristics: A brownish crystalline solid, crystallizing at 150 I52C. R.K. Classificationt Lacquer Solvents, NOIBN. Ceneral Informations This product is tbe tecbincal form of Santicixer 129. It may be used in orgsnic syothes<, production of dyestuffs or as a plasticizer in resinous compositions where col is not a factor; is analogous to Monsanto's pars-Toluenesulionamide and can probably be used as a substitute in most applications. 26TH EDITION Page 37 066377? T BENZENE SULFONIC ACID, TECHNICAL 0 Mol. Wt. 158.17 SOjH Characteristics! Greenish black viscous liquid or crystalline mass; crystallizing point. 25.8C. (approx.); HjSO,, 24.0 - 25.0%; benzene sulfonic acid. 70,6.71.0%; ap.g. 25/I5.5,C., 1.45 (approx.). K.R. Ossification: Chemicals. NOIBN. General Information! Used as an intermediate in organic synthesis and as a catalyst in certain condensation reactions. BENZOATE OF SODA (See Sodium Benzoate). BENZOIC ACID Mol.Wt. 122.12 Grades! U.S.P. and Technical. Specifications of U.S.P. Grades White crystalline needles or fine powder; assay 99.S min. (dry basis); m.p. 122.5eC. min.; solution in alcohol (1:2.5) and in 10% sodium carbonate (1:6), clear and colorless; meets U.S.P. test for carboaisable impurities; 5% max. powder retained on 100 mesh screen. Specifications of Technical Grade t White to yellowish white granules or powder; assay, 99.25% min.; odor, characteristic; solution in 10% NajCOj (1:6), slightly turbid or opalescent and practically colorless; approx. 10-20% retained on 20 mesh; approx. 100% retained on 100 mesh. R.R. Classification! Of U.S.P. Grade--Food Preserving Compound; of Tech nical Grade--Chemicals, NOIBN. General Information! U.S.P. Grade used in medicinal preparations and as a preservative in foodstuffs. Technical Grade used in the manufacture of ben zoates and benzoyl compounds; as an intermediate in the manufacture of dyes; as a mordant in calico printing; as a modifying agent in alkyd resins; as a color stabiliser in baking varnishes; as a dispersing agent in the grinding of pigments. P.,.M MONSANTO CHEMICALS 0663776 LEXOLDMON005708 BENZOTRICHLORIDE _ CCI. Mol. Wt. 195.48 Standard Form: Liquid. Specifications: Colorless to light green or yellow liquid: crystallizing point 6.0C. min. Distillation range: fkst drop, 218.0C. min.; 95% (1-96 ml), 2.0C. max.: dry point, 223.0C. max. K.R. Classification: Chemicals N'OIBN. General Information: Used as an intermediate in dyestuff synthesis. (At T10\: Irritating to the skin, f apors are highly irritating to the eyes. Avoid breathing vapors. A void contact with the shin. BENZYL CHLORIDE Mol. Wt. 126.59 Standard Forms: Liquid, anhydrous; liquid with 10% NajCOj solution. Specifications: For anhydrous liquid and material recovered from 10% solution belon: Colorless to light green to brown liquid; sp. g. at 15.5/15.5'C.. I. 104 1.108. Distillation range: first drop, 177.5C. min.; 95% (1*96), 3.0C. max.; dry point, 185.0C. max. Liquid with 10% NajCOj: NatCO,, in water solution, 9.0 11.0%. Note: 23 lbs. of 10% NajCOj solution are add'd to 450 lbs. of benzyl chloride contained in 55 gal. black iron drums. The wet material is a milky white emulsion, from uhich water may separate into a definite layer at either the bottom or top de pending on the temperature and tl*e concentration of NajCOj. The concentration of \a2COi slowly decreases on standing. II. II. Classification: Chemicals NOIBN. General Information: Used in the production of the following: Dyestuffs; perfume bases such as benzyl alcohol, acetates, benzoate and phenyl ethyl al* cohol; plasticizers; resins; wetting agents; rubber accelerators; gasoline gum inhibitors; benzyl cellulose; various pharmaceuticals. CAUTION: This product is irritating to the skin. Vapors are highly irritating to the eyes. Avoid contact with the skin. Avoid breathing vapors. BISULFATE OF SODA (See Nitre Cake) BISULFITE OF SODA (Sec Sodium Bisulfite). UTH coition Page 39 0683779 BLEACH (See Merrlor). BONE ASH,, General Informations Mold wash grade for coating molds used in casting copj>er wire bats, ingots and slabs. A suptrior mold coating for certain steel casting operations. This product is also used in producing opal and other translucent glasses. It.lt. Clarification' Hone Ash. BONE BLACK Grades: Twelve grades are available which vary in fineness, top tone, undertone, tinting strength, and color in oil. Specifications: In general, bone blacks when compared with lampblack or carbon black have greater hardness and lower oil absorption. They mix easily with water, shellacs and lacquer, and are relativ able to sunlight. Specifics- ions for the various standard grades are as foil Grade No. 45 % of Moisture 4.10 % PA 33.50 150 4.10 33.50 250 4.94 33.05 350 4.07 30. IS 439 4.78 32.05 439 Spec. 4.78 31.73 450 & 450-CT. 4.86 34.50 650 4.28 34.00 841 4.02 32.95 8S0 3.82 34.60 Ceco 4.95 32.30 *Lbs. oil per 100 lbs. pigment. **No. 450, 99.00; No. 450-CT., 99.67 % Care".: 9.20 9.20 9.75 13.84 14.57 15.12 9.30 8.75 8.90 8.37 9.70 Oil Absorption* 46.2 46.2 43.9 43.9 50.2 50.5 42.7 43.9 46.2 43.9 46.3 % thru 325 Screen 99.89 99.90 99.40 99.85 99.95 99.90 ** 99.73 99.90 99.90 99.95 R.R. Classification' Animal Charcoal, Other Than Spent. General Information: Chief use is as a pigment in leather finishes, artificial leather, paints, lacquers, japans, inks and wall paper. Bone black has good jetnesa and is easy to wet, whereas lampblack wets only with difficulty and has much less jetness. BRONZING LIQUIDS General Information: Clear lacque: base mediums for aluminum and bronze [towders. Several types offered for metal, wood, fabric, and paper. Applied by spray or machine coating. Many are inhibited to retard gelling. ll.R. Classification: Bronzing Liquids. Rage 40 MONSANTO CHEMICALS 0683780 "BUTASAN" (See Accelerat<<rs, Rubber). BUTYL ACETATE Typical Analysisi Water white liquid: sp. g. 0.872 0.877 at 29'205C.: 7.3 lb*, per gal.: ester content, 88-90%. Roiling range: below 1 l.VC., none: below 122C.. iif-t over 10%; below I25*C., a: least 90%; below 130 C., 100%. Drvnes*. inixes with 19 vol*. 60 Be. gasoline. I.ess than 0.01% as free acetic acid. K.B. Classification: Butyl Acetate. General Information: Ised as a nitrocellulose solvent. Is intermediate in activity between ethyl acetate and amyl acetate. Blends of all three with ap propriate diluents such as alcohols (ethyl, butyl, and amyl) yield thinner* and advent mixtures of excellent cutting power and moisture resistance, good flow and leveling, and compatability with various resins and oils. Used in the artificial leather industry and in formulating lacquer finishes for wood, metals, textiles, and paper. BUTYL BENZENE SULFONAMIDE (See Santiciter 127). H-BUTYL PHOSPHORIC ACID (See Alkyl Phosphoric Acids). BUTYL PHTHALATE (Se< Dibutyl Phthalate). BUTYL PHTHALYL BUTYL GLYCOLLATE (See Samicixer B-16) CABLE LACQUERS General Information! Manufactured in clear, black and colors for application by gasket, for high tension automotive cables and primary wires. Special types are available that are flameproof resistant to hot oil, and have high beat test ratings: also non-inflammable type sleeving lacquer of high dielectric strength. Ml types build well, giving a tough, glossy, flexible finish. R.R. Classification: Lacquers. 26TH bd>tion Page 41 0683781 CAFFEINE, U.S.P. CH, I N -- C =0 o = d: i I ^CH, C-N . RiO ^CH C -N i CII, Mol. Wt. 212.21 Standard Format Powder, anhydrous pi>wder, hydrated. Specifications: White powder. Loss on drying at 80C: anhvdrous pnw.irr 0.25% max.; hydrated flakes 5.75 6.50%. M.p. 235C. min.; meets U.S.P. test for rarbonizable impurities. MESH Retained on-- 20 mesh screen 35 meah screen 45 mesh screen 100 mesh screen 200 mesh screen Hydrated Trace max. 12 0% max. 18 0% max. R.R. Clasaficatloni Chemicals NOIBN. Anhydrous None 2.5% max. General Information! Pharmaceutical product. CAFFEINE, CITRATED, U.S.P.____ CH, 2 1 O II o 11 .CH, O C C-N< 1 II ^CH N--C--N^ | CH, (Caffeine) H,C --COOH + HO --C-COOH 1 HsC-COOH (Citric Acid) Equal quantities by weight Standard Form t Powder. Specifications! White powder; assay 48.0-52.0% anhydrous caffeine; loss on dry ing at 80*0., 0.2% max.; solubility in watet (1*4). complete; conforms to U.S.P. tests for sulfate and heavy metals; 15.0% max. retained oo 100 mesh screen. R.R. Classification! Chemicals NOIBN. General Informations Pharmaceutical product. Page 42 MONSANTO CHEMICALS 0683782 LEXOLDMONOQ5712 CALCIUM GLYCEROPHOSPHATE N.F. (See Glycerophosphates). CALCIUM NITRATE Ca(N03)2.3 II20 Standard Forms: White crystals; 7>% water solution. Typical Analysis: Ca(.\Oj)2 3 IIjO Heavy Metals Iron RA Water White Crystals Solution 98.95% 71.21% none none none none none none none 25% Balance to make up 100' is probably magnesium nitrate. R.R. Classification: Calcium Nitrate. (General Information: Used as a coagulant in latex dipping processes. CALCIUM PHOSPHATE, MONO (\lso known as primary calcium phosphate, calcium di-hydrogen phosphate, mono-basic calcium phosphate, calcium acid phosphate, and acid phosphate of Grades: Regular for phosphated and self-rising flour and baking powder. Granular for baking powder. All grades meet U.S. Pure Food Law requirements. Special grades will be supplied on request. The following mixtures are carried in stock: ,\eut. Strength 52 50 50 45 45 45 Constituents Regular, Starch and 15% Calcium Sulfate. Regular and Starch Granular a(id Starch Regular, Starch and 18% Calcium Sulfate. Regular, Starch and 30% Calcium Sulfate. Regular and Starch. Properties: A white stable material, soluble in water, giving an acid reaction. R.R. Classification: Calcium Phosphate. General Information: Used in baktries for leavening purposes and to prevent the formation of "rope'' in bread; as a leavening agent in biscuits and crackers and as an acid leavening agent in pancakes; as sole acid agent or mixed with sodium aluminum sulfate or sodium acid pyrophosphate in baking powders: in making self-rising, phosphated plain flour and prepared flours; to control pH of solution in malt. 76TH EDITION 0663783 CALCIUM PHOSPHATE, DL (Also known as phosphate of lime, precipitated bone, secondary phosphate of lime, dicalcium ort/io>phosphate and bibasic calcium phosphate.) Anhydrous CailPOi Dihydrate CaHP0j.2II}0 Mol. Wi. 136.068 Mol. Wi. 172.084 Standard Forms: Anhydrous; dihydrate. Properties: Insoluble in alcohol; soluble in dilute citric acid solution. Solubility in CO} free water in grams per liter: Anhydrous: CaO PA Dihydrate: CaO PA 30C. .0414 .0866 .0954 .2066 50C. .667 .1630 .2617 .6182 68C. .0985 .2234 .3409 .3245 loo.rc. .1046 .2461 .3109 .7591 Grades: Medicinal; food; dentifrice. ' R.R. Classification: Calcium Phosphate. General Information: Used as a mineral supplement in diets that are deficient in calcium and phosphorus; as polishing agent in tooth pastes and powders. Anniston, Alabama, plant of the Phosphate Division. 068378V LEXOLDMON005714 CALCIUM PHOSPHATE, TRI __ (Also known as (ri-basic calcium phosphate, normal calcium phosphate, neutral calcium phosphate, tertiary calcium pnospbate.). Standard Forms White powder. Grades) Dentifrice, conditioner (salt, sugar, etc.), and medicinal. All material conforms to requirements of the I .S. Pure Food Laws. Properties! White amorphous p.jwder, odorless and tasteless; practically in soluble in water. K.R. Classification! Calcium Phosphate. General Information! Used as a mineral supplement to supply calcium and phosphorus; at a tooth paste base or polishing agent in tooth powder, as an in gredient in making milk glasses: as an antacid: aa a conditioner to prevent caking in salt, sugar, talc and other powdered material. CALCIUM PHOSPHATE, X-C Generallnformationi Extra rich in calcium. Used as a mineral supplement to supply calcium and phosphorus, especially in enriched flours: to control pH of baked products in order to reduce losa of Thiamin (Bj) in baking process; in phosphating plain floure. CALCIUM PYROPHOSPHATE Ca2P207 Mol. Wt 254.12 Properties! A finely subdivided powder; contains 43.8% CaO and 55.5% P205. General Information! Used in food fortification as a mineral supplement. CALCIUM SALICYLATE (See Salicylates). CALCIUM SULFATE (See Crysalba). CARBOLIC ACID (See Phenol). CARBON DIOXIDE GAS____________________________________ CO* Typical Analysis! 100% CO* apptox.; sp. g. of liquefied gas, 1.057. 'Continued) 26TH EDITION Page 45 0683785 K.R. Classification: Liquefied Carbon Dioxide. General Information: Monsanto carbon dioxide is liberated from pure soda ash. It is purified, dried and compressed to 400 lbs. per sq. in. in a multi-stage compressor, then condensed or liquefied and placed in steel cylinders. Thus pre pared, it is entirely free from odors and tastes and is widely used in carbonating beverages. It is also used as a non-oxidizing atmosphere, in rubber vulcanizing, in dry cleaning, in preserving foods, or wherever an inert oxygen-free medium is required. Liquefied Carbon Dioxtde is the cheapest source of high pressure which is portable and without fire hazard. CARBON DIOXIDE, SOLID (Dry Ice) Standard Formt Blocks, 10'xl0'x)0', weighing 50 to 55 lbs. K.R. Classification: Dry Ice. General Information: A product of molasses fermentation in tbe manufacture of alcobol. Carbon dioxide thus produced as compared with the gas from other sources permits higher yield and a purer product, requiring less processing for purification prior to liquefying and solidifying. Used for low temperature refrig eration. CAST PHENOLIC (See Plastics, Opalon). CATECHOL (See Pyrocatecbol). CAUSTIC SODA (Also known as sodium hydroxide) Na OH Mol. Wt. 40.00 Standard Form: Solution 50%. Specifications: Practically clear, colorless or slight yellowish or greenish tinge; sodium hydroxide 48.5% min., 50.$% max.; sodium carbonate 0.20% max.; sodium chloride 1.25% max.; sodiuni chlorate 0.04% max.; iron 0.007% max.; sodium sulfate 0.04% max.; copper 0.0005% max. R.R. Classification: Caustic Soda. General Information: Used in petroleum refining, vegetable oil refining, tanning, aoap making, textile manufacture (rayon), rubber reclaiming. CELLULOSE ACETATE (See Plastics, Fibestoa). CELLULOSE NITRATE (See Plastics, Nitron). Page 46 IONSANTO CRlMtCALS 0683766 CEMENTS General Information! Rapid-drying waterproof cement in various soluble cellulose and resin bases; also heat sealing cements. A complete line of cements is offered for adhering wood, metalK paper and fabric to various plastic materials; also cements for packaging in collapsible metal tubes, such as household cement, model airplane cement, and library cement. R.R. Classification! Lacquer. CHLORAL HYDRATE, U.S.P., CCIjCU(OH), Mol. Wt. 165.39 Standard Formi Crystals. Specifications! Colorless, dry transparent crystals; assay 99.5% min,; solubility in water (1:1), complete; water solution neutral to litmus; comforms to U.S.P. test for carbonizable impurities and chlorides. R.R. Classification! Chemicals NOIBN. General Information! Used in pharmaceatical preparations and veterinary medicines. CHLORAMINE-B--_________________________ (Also known as N.N-sodium chlorobenzene sulfonamide) . iy2 ho so, Mol. Wt. 240.63 N.^N''C1 Standard Formi Crystalline powder. Specification#! Nearly white crystals or crystalline powder; soluble in water; active chlorine 14.45% min. General Information! Chloramine-B is a water-soluble, chlorine-bearing pow der used as a germicide, disinfectant and deodorant. CHLORAMINE-T, U.S.P. . o oH,C Na / S-N 3HtO U \' 0 Cl Standard Formi Crystalline powder. Mol. Wt. 281.70 Specifications! White or faintly yellow powder or granules; solubility in water (2:15), complete; free alkali (as N*OH), 0.07 0.15%; loaa on drying (3 hrs. at {Continued) 26TH EDITION Page 47 068378? 97C.), 18.U 20.0%; active chlorine 12.25 - 12.60%; assay 97.3% min. MESH Retained on 10 mesh screen--Trace max. Retained on 35 mesh screen--1.0% min. R.R. Classification! Disinfectant other than medicinal. General Informations Chloraraine-T is a water-soluble, chlorine-bearing powiler used as a germicide, disinfectant and deodorant. CHLORCOSANE (Chlorinated Paraffin, N.F.) __ Specifications! Light yellow oil; odorless and tasteless; sp. g. 1.00 to 1.07 at 25'C.; combined chlorine content 27% to 30%; reaction of water extract to lit mus. neutral; chlorides (as HCI) 0.004% max.; free chlorine, none; unchlorinated paraffin, negative (N.F. test). K.R. Classifications Chemicals NOIRN. General Informations A solvent for dichloramine-T. For uses where a product with fire-resistant, insulating and solvtnt properties are indicated. CHLORINATED DIPHENYL (See Aroclors). CHLORINATED PARAFFIN, N.F. (See Chlorcosine). CHLORINE Specifications! Ctear, amber colored hquid; about \Vi times as heavy as water; conforms with American Water Works Association specifications. R.R. Classification! Chlorine. General Information! Used for municipal water purification, sewage treatment and swimming pool sterilization, for slime control, in pulp and textile bleaching, metallurgy, bleaching and processing of flour, organic synthesis, and in the manufacture of metallic chlorides and hypochlorites. CAUTION: Chlorine it toxic and highly irritating. Avoid contact with the thin and breathing the vapors. Available Literature! 20-page booklet "Monsanto Chlorine" paro-CHLORO-mefa-CRESOL, white transparent crystals; used as a disinfectant inteneifier; made by Monsanto Chemicals Limited. ortho-CHLORO-paro-TOLUENE-SODIUM SULFONATE (See Monsanto Salt). para-CHLORO-metd-XYLENOL, white crystals; used as a disinfect. (Continued) Page 48 MONSANTO CHEMICALS nt intensifier and as a preservative and preventive against mold and mildew; made by Monsanto Chemicals Limited. ortho-CHLOROAMLINE_______________________________ (Also known as orf/so-aminochlorjbenzene and l-araino-2-cblorobenzene.) NH, Mol. Wt. 127.58 Standard Forms Liquid Specifications! Discolors readily on exposure to air: crystallizing point --2.3C. min. Distillation range: first drop, 208.0C. min.: 95% (1-96 ml), 1.0C. max.; dry point, 210.0C. max; Solution in HCI, very slightly opalescent max. R.R. Classifications Dye Intermediate. General Informations Used as an intermediate in the production of dyestuffs. CAUTION: This product is toxic Avoid breathing its vapors and avoid contact with the skin. meto-CHLOROANILINE ______________________________ (Also known as meto-aminocblorobenzene and l-amino-3-chlorobenzene.) Mol. Wt. 127.58 Standard Forms Fused solid Specifications s Clear, fight yellow liquid; crystallizing point approx. --10.0CC. Distillation range: first drop, 228.0. min.; 95% (1-96 ml), 1.0C. max.; dry point, 231. 0C. max. R.R. Classifications Dye Intermediate. General Informations Used as an intermediate in the manufacture of azo dyestuffs. CAUTION: This product is toxic. Avoid breathing Us vapors. Avoid contact with the skin. pora-CHLOROANILINE ________________________________ (Also known as Poro-aminocblorobenzene and 1-amino-4-chlorobenzene,) NH, Mol. Wt. 127.58 Cl 20TB XDITION Standard Forms Fused solid. (Continued) Page 49 0683769 .Specifications: Yellowish, white solid; crystallizing point 69.5*C. ruin. Distilla tion range: first drop, 229.0JG. min.: 05% (1-96 ml), 1.5C, max.; dry point, 233.0C. max. Solution in HCI, slight opalescence max. K.R. Classification: Dye Intermediate. General Information: l sed as an intermediate in the production of dyestuffs. CAUTION: This product is toxic. Avoid breathing its vapors and avoid contact u ith the skin. CHLOROBENZENE Cl Mol. Vi. 112.56 V Standard Forms Liquid. Specifications: Clear, almost colorless liquid. Distillation range: first drop, 131.5C. min.; 95% (1*96 ml), 0.5*C. max.; dry point. 133.5C. max. R.R. Classification: Monochlorobenzene. General Information: Major use is as an intermediate in the preparation of the various substituted chlorobenzenes which are in turn intermediates for the preparation of dyestuffs, explosives, and various other organic chemicals. Also used as an organic solvent. ortho-CHLOROPHENOL, TECHNICAL (Also known as rth*bydroxycblorobei*ene and l-cbloro-2-hydroxybenzene. OH Mol. Vt. 128.56 () Standard Form: Liquid. Specifications: Clear yellow to brown liquid; monochloropbenol (from Cl con. tent), 95.0% min. Distillation range: first drop, 173.0C. min.; 95% (1*96 ml.), 2.0C. max.; dry point, 178.0C. max. R.R. Classification: Dye Intermediate. General Information: Used as an intermediate in the production of dyestuffs and varioua other organic products. CAUTION: This product is toxic. Avoid breathing its vapors. Avoid contact with th# skin. pora-CHLOROPHENOL (Also known as pora-hydroxychlocobeniene and l-chloco-4-hvdroxybenzene,) fr*Mil.1 MI.mC Page 50 MONSANTO CHSMICALS 0683790 OH Mol. Wt. 128.56 Standard Forms Fused solid. Cl Specifications) Yellow to brown crystalline mass; crystallizing point 42.5C. min.; sp.g. at 45.0/15.59C., 1.256-1.262. 11.11. Classifications Dye Intermediate. Ceneral Informations Used as an intermediate in the production of dyestuffs, as a germicide and in the synthesis of pharmaceuticals. C.4 VTION: Care should In- exercised in handling this product. Avoid contact with the skin. CHLOROSULFONIC ACID (Also known as sulfuric cblorohydrin.) CISOjOH Mol. Wt. 116.53 Standard Forms Liquid. Specifications; Heavy mobile liquid; assay 98.5% min. R.R. Classifications Acid. General Informations Used in chlorosuifonation reactions. CAUTION: Chlo rosulfonic acid reacts violently with water, forming hydrochloric and sulfuric acids. CHROME SULFATE (See Santotan). CITRATED CAFFEINE, U.S.P. (See Caffeine, Citrated). CONTACT MASS (See Vanadium Catalyst). COPPERAS NITRATE OF IRON (See Nitrate of Iron C). COTTON SOLUTIONS General Informations Made from RS (regular soluble) cotton of any desired viscosity. Viscosity, solid content, and solvent composition can be regulated to meet customer requirements. Used in manufacture of lacquers, leather dopes, fabric coatings, artificial leather finishes, etc. Composition of standard base solutions follow: (Continued) 26TB EDITION Page 51 0683791 Formula Number R-1202 R-4683 R-2816 R-1205 RI204 L-4692 Standard Nitrocellulose Solutions Viscosity Wt. NC Percent f to 1 gal. .\itrocel. Nitrocellulose Solvents dry Active Solvent* Seconds 64 o*. 33.9 Butyl Acetate Y% " 64 " 6 " 45 " 36.5 28.1 Ethyl Acetate Butyl Acetate 15-20 " 28 " 19.5 Butyl Acetate 15-20 " 28 " 19.5 Ethyl Acetate 250-400 " 16 " 13.0 Ethyl Acetate Weight one gallon 8.71 lbs 8.54 " 8.53 " 7.99 " 8.1 " 7.24 " * Usual added diluents: Toluol, xylol, naphthas (varying aromaticity), alcohols (ethyl, butyl, amyl). K.K. Classification i Lacquers. "COUMARIN MONSANTO" 'Coumarin N. F.) Mol. Wt. 146.14 Standard Format Crystals, fine: crystals, large--4 mesh. Specifications! Fine or large white crystals: melt (liquid), clear and colorless: m.p. 68.8C. min.; solubility in ethyl alcohol (1:10), complete; loss on drying 0.03% max.: ash 0.05% max.; conforms to N.F. test for acetanilid; 5.0% max. retained on 4 mesh screen; 95.0% min. retained on 8 mesh screen. R.R. Classification t Coumarin. General Information! Coumarin is a flavor and odor principle used separately and in conjunction with vanillin. It is used in perfumes, soaps, tobacco, ink*, foods and other products where flavoring or aromatic ingredients are required. Available Literature! Folder, "Coumarin Monsanto". CREAMERY ACID (See Sulfuric Acid). meta-CRESOL, colorless liquid, assay 98*100%, crystallizes at 10.5 12C.; used in the manufacture of synthetic perfumes and nitro*derivatives; made by Monsanto Cbemicab Limited. ort/lO-CRESOL* white crystalline mass, crystallizes 30 31C.; used in the manufacture of and as a dye intermediate; made by Monsanto Chem icals Limited. Page 52 MONSANTO CHEMICALS 0683792 para-CRESOL, loose white crystals, crystallizes 34.5C.; dye imennediate: made by Monsanto Chemicals Limited. CRESOL-CRESYLIC ACID, duty-free grades; used as a flotation agent and gasoline antioxidant and in tin manufacture of soaps, disinfectants, paint removers, textile chemicals, resins and dyestuffs; made by Monsanto Chemicals Limited. CRESYLIC ACID (See Cretol), "CRYSALBA" CaSO Mol. Wt. 136.14 Properties! Extremely fine, white powder composed of minute particles of crystalline-shaped anhydrous calcium sulfate, standardized and specially pre pared for use as a dentifrice base (paste or powder). R.R. Classification! Calcium Sulfaie. Principal Uses; Used as a tooth paste base or polishing agent. Suitable for preparation of neutral, acid, basic, soap, or magnesia type dentifrice. "CURODEX" A complete line of reodorants for the rubber trade; not manufactured by us but furnished for the convenience of our customers. "CYCLINE" OIL Specifications! Blend of mineral and vegetable oils. Clear, yellow oil with pale blue-green fluorescence; sp. g. 0.89; Bash point, 185C.; viscosity, between 105 and 115 Saybolt viscosimeter at 37.5C.; soluble in benzene, gasoline, dry al cohols, ethers and acetone. R.R. Clasaificatiom Petroleum Oil, NOIBN. General Information! Used as a rubber softener. Available Literature! 42-page booklet "Monosanto Chemicals for the Rubber Industry." 26TH EDITION Page 53 0663793 O.YCLOHEXYLAMI.NE___ (Also known as hexahydroaniline.) NH, |1 CH /\... IttC CH, |1 1 1 II,C CH. \/ CHi Mol. Wt. 99.17 Standard Formi Liquid. Specifications i Clear, practically colorless; sp. g. at 15.5/15.5C., 0.870.0.874. Distillation range: first drop, 132.0'C. min.: 95% (1-96 ml.), 4.0C. max.; dry point, 137.5*0, max. R.R. Classification! Chemicals NOIBN. General Information t Used as a dyestuff intermediate; as an intermediate or ingredient for insecticidal compositions; as a component of conosion inhibitors; in organic synthesis. CA UTION: Thi* product it toxic. Avoid breathing its vaport and avoid contact with the skin. DETERGENTS (See Areskap, Aresket, Aresklene, Santomerse), DIACETONE, TECHNICAL _ Typical Analysis! Nearly water white liquid; acidity, neutral; odor, no residual; p. g. 0.918 at 15.5C.; shipping wt. per gal., 7.60 lbs.; diacetone content, 85%; boiling range, theoretical b.p. 164*0. (decomposes at 130* 140C.); dryness, mixes with 5 vols. of petroleum naptha without turbidity. K.K. Classification! Diacetone. General Information! Diacetone is one of the most active high boiling solvents for nitrocellulose. It is a good solvent for cellulose acetate and many resins, waxes and dyes. Diacetone is miscible and has a high tolerance for nearly all lacquer diluents. Higher percentages of water are tolerated than with most solvents. DIAMMONIUM PHOSPHATE (See Ammonium Phosphate, Di). "D.P. SOLUTION 4519*'___________ Standard Formi 40% sol. in ethyl alcohol. 0Continued) Page 54 MONSANTO CHEMICALS 0663794 Properties: Pale straw colored litfuid; 8.2 lbs. per gal. R.K. Classification: Chemicals NOIBN. Genera) Information: Used as an anti-corrosion agent in lacquers and cotton solutions, and as an agent to prevent tbe settling of Santocel in fiat lacquer formulations. 1MBITYL PIITHALATE 0 -C -0-C4H, 0-C -0-C,H, o Mol. Wt. 278.17 Specifications: Clear, oily, liquid, color (APHA) 10 max.; odor, slight; aciditv (as phtbalic acid) 0.01% max.; ep. g. at 20/209C., 1.0480.00l; refrac. index at 25C., 1.-19050.001; assay (ester content) 99% min.: sulfur (copper strip test), negative. R.K. Classification: Dibutyl Phthalate. General Information: Dibutyl Phthalate is one of the most widely used plasticizers for nitrocellulose. It is miscible with all the common organic solvents and with oils but is soluble in water only to the extent of 0.001% at 30C. It has excellent light stability which permits its use in colorless, white or delicately tinted produets. Tbe stability of Dibutyl Phthalate and its high solvent power for most plastic materials make it one of the most acceptable plasticizers for general use. Available Literature: 40 Page booklet ''Plasticizers and Resina". DICALCIUM PHOSPHATE (See Calcium Phosphate, Di). DICHLORAMINE-T, N.F O y-------. II H,C <( } S-NCIs Mol. Wt. 240.11 O Standard Form: Crystalline powder. Specifications: Yellowish white crystalline powder; crystallizing point 80.5*C. min.; assay (available chlorine) 29.S5%. R.R. Classification! Chemicals NOIBN. (Continued) J6TH SDITION Page 55 0683795 General Information: Dichlorqmine-T i9 a water soluble, active chlorioe bearing product. It must be stored away from light and in a cool place. > 2,5-DICHLOROAMLlNE_________ (Also known as l-aroino.2,5-dichloiobenzene) Cl l > Mol. Wt. 162.03 Standard Form: Fused crystalline mass. Characteristics! Light brown crystalline mass; crystallizing point, 48.6C. min. Distillation range: start, 247C. min.: 95%, within l.S#C. R.R. Classification! Dye Intermediate. General Information! Used as an intermediate in the preparation of azo dye* stuffs. C.-f L TION: This product is toxic. Avoid breathing its vapors. Avoid contact uith the skin. "Poison'' label requited. DICHLOROBENZENE (See Santocblor and ortho.Dichlorobeozene) pora-DICHLOROBENZENE (See Santochlor). orfho-DICHLOROBENZENE, TECHNICAL. (Also known as 1, 2-dichlorobenaeoe) Cl Mol. Wt. 147.00 Standard Forint Liquid. Characteristics: Colorless to slightly yellow liquid; crystallizing point, 7.0C. max.: 100% (1st drop, dry point), 14.09C. max. Sp.g. 15.5/15.5, 1.305.1.313: composition, 75 85% ortho-dieblorobenzene, 15 25% psra-dichlorobenxene. R.R. CSasaificattotis Ortho-dichlorobenzene. General Informations Used as a dyestuff intermediate; solvent; ingredient in cleaning preparations; and as an insecticide and fungicide. Page 56 MONSANTO CHEMICALS 0663796 2, 4-DICHLOROPHENOL ______________ (Also known as 1.3*<Ucb]oro4>hy<ij oxybenzene.) Mol. Wt. 163.00 Standard Formt Fused solid. Specifications! Yellow to brown crystalline mass: crystallizing point 42.0C. min. Distillation range: first drop, 21i.5C. min.; 95% (1-96 ml.), 2.0C. mu. R.R. Classification] Dye Intermediate. General Information! Used as an intermediate in the production of dyestuffs and as a germicide. CA UT10,V: Core should be exercised in handling this material. Avoid contact with the skin. Avoid breathing its vapors. DICYCLOHEXYLAMINE . \-H / Mol. Wt. 181.32 Standard Formi Liquid. Characteristics] Clear, practically colorless liquid: sp.g. 15.5V1S.5C., 0.916 0.920. Distilling range: first drop, i!52.0C. min. Flash point ("Tag'* open cup), above 200F. R.R. Classification) Chemicals NOIBN. General Information! Used as an intermediate in the manufacture of oil additives and insecticides. CA UTfOJV: Thu product is toxic. Avoid breathing its vapors. Avoid contact with the skin. DIETHYL PHTHALATE _ o -C-O-C.H, 0-C-O-C.H, II o Mol. Wt. 222.11 Specifications] Clear, water-wbitt oily liquid; color (APHA), not darker than 10; odor, very slightly aromatic; acidity (aa pbthalic acid) 0.01% max.; sp. g. at 20o/20C., 1.1230.005; refrwe. index at 2QC., 1.5030 0.001, sulfur (copper-strip test), negative. (Continued) 26TB bdition Page 57 0663797 R.R. Classification! Diethyl Phtbalate. General Informations Diethyl Phtbalate is a colorless liquid plasticizer gen* erally used in mixture with dimethyl pbtha ate as a plasticizer for cellulose acetate. It is miscible with all the common organic solvents and diluents. Evap* oration rate of Diethyl Phtbalate is too high for successful use as a regular nitro cellulose plasticizer and it is not a solvent for cellulose acetate. Thus its range of usefulness is somewhat restricted. Mixtures of Diethyl and Dimethyl Pbthaiates usually give better results than can be obtained by either one alone. Boiling point is 295C.; weight per gal., 9.35 lbs. Available Literature! 40 Page booklet "Plasticizers and Resins". 2, 3-DIMETHOXY BENZALDEHYDE, TECHNICAL (Also known as ortta-veratraldehyde). /,, OCH, Mol. Wt. 166.0 0OCH, Characteristics i Yellowish brown fused crystalline mass; solubility in sodium bisulfite, nearly complete; crystallizing point, 4?.5C. min.; sp.g. at 60C., 1.117; wt. per gal., 9.3 lbs. approx. R.R. Classification i Chemicals NOIBN. General Information! Used as a perfume fixative and as an intermediate in chemical synthesis. DIMETHYL PHTHALATE . O /X 11 | j -- C ---0 -- CHi l J-c -- O -- CH V II Mol. Wt. 194.08 Specifications! Clear, water-white oily liquid; color (APHA), not darker than 10; odor, not more than slightly aromatic; acidity (as phthalic acid) 0.01% max.; ap. g. at 15.6/1S.6*C., 1.1964:0.001; refrac. index at 20C., l.S1550.001; sulfur (copper atrip teat), negative. R.R. Classification! Dimethyl Phtbalate. General Information! Dimethyl Phtbalate is a solvent plasticiser for cellulose acetate. It is miscible with all common organic solvents and with oils (except (Continued) Page 58 Monsanto chbmicals 0683790 petroleum oils) and has a solubility io water of 0.4% at 32C. It bas excellent light stability. Dimethyl Phthalate is much used but cannot be ssid to meet very rigid plasticizer requirements. Its use is restricted almost entirely to the cellulose acetate field, and there, as a general rule, it is used in combination with diethyl phthalate or some other plasticizer. Dimethyl Phthalate has a boiling point of 282C., a crystallizing point of 0JC., and weighs 10 lbs, per gallon. Available Literature! 40 Page booklet ' Plasticizers and Resina." 2, 4-DIMTROANILINE___________ (Also known as l-dmmn*2, 4-dinitrobenzene.) NH, NO, Standard Formi Powder. Specifications) Bright yellow powder; m. p. 177.5C. min.; chlorides (total) 0.15% max. R.R. Classification! Dye Intermediate. General Information! Used as an intermediate in the preparation of dyestuffs. CAUTION: This product is toxic. Aioid breathing its dust. Avoid contact with the skin. 2, 4-DINITROCHLOROBKNZENE, TECHNICAL (Also known as l*chloro-2,4-dinit:robenzene.) Cl Mol. Wt. 202.56 NO, Standard Formi Fused crystalline solid. Gradeat 3 grades of fused crystalline solids with crystallizing points of 48.0C., 46.5'C., and 44.0C. Approximate Analysis! 2:4 dinitio* chlorobenzene 48.0C. 46.5C. 95% Approx. 90% S 44.0*C. 85% " isomeric dinitro* chlorobenzenes 5% Approx. 10% " I1S5O%. " Page 59 0663W General Information! Used in the production of explosives, photographic chemicals, and dinitrophenol, and as an intermediate in the preparation of dyestuffs. CAUTION: This product if toxic. Aioid breathing Us vapors. Avoid contact with the skin. DIPHENYL_________________________ (Also known as biphenyl; phenyl benzene). o-o Mol. Wt. 154.2 Properties! Technical diphenyl is a light yellow crystalline solid. Boiling point 254.98C, freezing point 68.5C. to 68.91' C. R.R. Classification! Diphenyl. General Information! Used as a high temperature, low pressure heat transfer medium. It is also the starting point for many derivatives such as Aroclors (chlorinated diphenyl) and the suifonio acid, nitro, amino and hydroxy com* pounds. DIPHENYL PHTHALATE Mol. Wt. 318.31 Specification#! Essentially white fused solid; melt, clear and light yellow color: free acid (as phthalic) 0.20% max., free phenol 0.25% max. R.R. Classification! Lacquer Solvent. General Information! Diphenyl Phthalate has a crystallizing point of about 69C. and is readily soluble in ketones, esters and chlorinated hydrocarbons. Its solubility in alcohols, turpentine afcd linseed oil is rather low, approx. 5.0 grams per 100 c.c. of solvent at 25SC. Diphenyl Phthalate is compatible with nitrocellulose and with the sulfonamide, phenolic, polystyrene and vinyl types of synthetic resins. In nitrocellulose lacquers it produces hard coatings that have excellent gloss retention and weather resistance. Mixtures of Diphenyl Phthalate with either Santolite MS or Santolite MHP are excellent plasticizers for nitro* cellulose in odorless, flexible, adhesive coatings. Diphenyl Phthalate is completely insoluble in water and gives increased water resistance to all compositions in which it is used. It is especially recommended for vinyl resins, polystyrene, ethyl cellulose, and some of the natural resins such as Damar. Available Literature! 40 Page booklet "Plasticizers and Resins'*. Page 60 MONSANTO CHIMICALS DIPHENYLGUANIDINE (See DPG under Accelerator*, Rubber). DIPPING LACQUERS (Set Lacquer*). DISINFECTANT INTENSIFIERS (See Santophen, Are*kap). DISODIUM PHOSPHATE (See Sodium Phosphate, Di). DISPERSING AGENTS (See Areskap, Aresket, Areskleoe, Saotomerte). DRY ICE (See Carbon Dioxidf Solid). **EL SIXTY" (See Accelerators, Rubber). ELECTROLYTE (See Battery Acid). EMULSIFYING AGENTS (See Areskap, Aresket, Aresklene, Santomene). ENAMELS (See Lacquer* and Resin*). "ETHASAN" (See Acceleratois, Rubber). "ETHAVAN" (Ethyl Vanillin)-------------------------------------------------- OH Mol. Wt. 166.17 C=0 Standard Form! Needles. Specifications! Fine white crystalline needles; completely soluble in ethyl alco hol 95% (1:2); ash 0.05% mu.; n..p. 76.5C. min. R.R. Classification! Chemicals NOIBN. {Continued) 26TB EDITION Page 61 0683601 LEXOLDMONOQ5731 General Information! Etbavan is ud as a flavoring and aromatic, and has a flavor similar to that of Vanillin but not identical with it. Tbe relative flavoring strength of Etbavan approximates three times that of Vanillin. Available Literature! Leaflet, ''Etbavan.** ETHYL ACETATE Typical Analysis: Water white liquid; sp. g., 0.895 at 15.5C.; 7.40 lbs. per gal.; ester content, 85-90%. Boiling range: 7(>C. 80C. Dryness, mixes with not less than 10 vols. of petroleum benzine without turbidity. Less than 0.02% as free acetic acid. H.K. Classification! Ethyl Acetate. General Information! Used as a nitrocellulose solvent. It is a more active solvent than either butyl or amyl acetate, evaporating the fastest, and having the least resistance to moisture blush. Blends of all three with appropriate diluents such as alcohols (ethyl, butyl, and amyl) yield thinners and solvent mixtures of excellent cutting power and moisture resistance, good flow and leveling, and com patibility with various resins and oils. Used in the artificial leather industry and in formulating lacquers and finishes foi wood, metals, textiles, and paper. ETHYL ALCOHOL--190 Proof QHjOH (Also see Mersol, a proprietary solvent type alcohol, and Nealco Anti-Frme.) Grade* i 1. Tax Free: 190 proof pure Ethyl Alcohol (95% by volume). May be withdrawn Under Regulations and Provisions by the U. S. or any governmental agency thereof, or by tbe several states and territories, or any municipal subdivision thereof, or by the District of Columbia, or for the use of any scientific university or college of learning, any laboratory foi use exclusively in scientific research, or use in any hospital, or sanitarium, or for the use of any clinic operated for charity and not for profit, including use in tbe compounding of bona fide medicines for treatment outside of such clinics of patients thereof, but not for sale. 2. Tax Paid: 190 proof pure Ethyl Alcohol (95% by volume), (a) May be pur chased by manufacturers and other* for non-beverage use without Federal Permit or bond, but such users must sign affidavit that tbe alcohol so purchased is for industrial use only, as defined by Federal Alcohol Administration Regula tion 2. (b) May be purchased by blenders and rectifier*, (c) Subject to Federal Government Tax. Individual state regulations apply on tbe purchase and use of pure Tax Paid Alcohol. 3. Specially Denatured Alcohol: May be withdrawn for use in a great number of specialised art* and industries. The character of the denaturant or denaturanta employed ia such that Specially Denatured Alcohol may be aold, possesaed and used only pursuant to permit and bond approved by Internal Revenue Depart ment, Alcohol Tax Division. All application forms covering the withdrawal of (Continued) Page 62 Monsanto chemical* 0663802 Molasses storage tanka of the New England Alcohol Company. Specially Denatured Alcohol may be obtained from the office of the District Supervisor, Internal Revenue Department, Alcohol Tax Division of the district in which the purchaser's plant is located. 4. Completely Denatured Alcohol: 188 proof. May be withdrawn without permit or (ax, but buyer must comply with certain Federal and State regulations govern* ing records and storage. R.R. Classification! Alcohol NOIl*N or Denatured Alcohol. General Informationi Nealco ethyl alcohol is manufactured by the fermenta tion of molasses. It is offered in its pure state and in all formulas of Specially Denatured and Completely Denatured Alcohol as authorized by Federal Law under the provisions of Title III of the National Prohibition Act. It is of high uniform quality complying with the exacting specifications of the National Kormulary VI and U.S.P. XI. Available Literature! 68-page booklet "Nealco Industrial Alcohol." ETHYL BENZENE SULFONAMIDE (See Santicixer 128). ETHYL PHOSPHATE (See Triethyl Phosphate). 26TH KIMTION Page 63 0683803 ETHYL PHOSPHORIC ACID (Se Alkyl Phosphoric Acids). ETHYL PHTHALYL ETHYL GLYCOLLATE (See Samicizer E-15). ETHYL TRIETHANOLAMINE PHOSPHATE_______________ Properties! Medium straw colored liquid of slightly alcoholic odor: sp. g. 1.19 at 25`C.; w t. per gal. 9.9 tbs,; liquid at all ranges of relative humidity but very viscous when anhydrous; pH 7.0 7.4; strength, 60% solution in water. 11.R. Classifications. Chemicals NOIBN. (General Information: Used as a plasticizer for water soluble materials and as a humectant. ETHYL VANILLIN (See Ethavan). FERRIC CHLORIDE SOLUTION (Iron Perchloride)______ FeCI, Standard Formt Liquid. Grades. 37B.; 40B.; 426B*. Typical Analysis. Ferric Chloride 42B.: total FejOj, 20.3%; FeO. 1.0%; combined Fe*Oj, 19.2%; FeClj, 39.0%. R.R. Classification. Iron Chloride Liquid. General Information! Used as an acid oxidizing agent in etching, photoengrav> ing, and in the manufacture of textile printing rolls and brass signs. It is used in water and sewage treatment for its iron content. FERRIC GLYCEROPHOSPHATE (See Glycerophosphates). FERRIC NITRATE* LIQUID (Trut Nitrate of Iron) WQjJj Grades. 47Bf,, 16.0% FejOj R.R. Classification. Iron Nitrate. Genera) Information. A source of ferric hydroxide for mineral tan and buff colors on cotton; brown papers; logwood blacks on silk; shoe stains and inks. FERRIC PHOSPHATE-_____________________ Sodium Ferric Pyrophosphate NagFe,|(Pj07)s.XHt0 (Continue*') Page 64 MONSANTO CHEMICALS 068380A Ferric Orthophosphate Ferric Pyrophosphate Ferric Acid Pyrophosphate General Informations Used in food and pharmaceutical fortification as a mineral supplement. FERRIC SULFATE (See Feirisul). FERRIC SULFATE, LIQUID (Copperas Nitrate of Iron) ____ FerfSO* Gradeat 40B4., 13.6% Fe,0, 47B6., 15.7% Fe,Os Containerss Carboys; barrels. General Informations A strong solution of ferric sulfate, containing no nitric acid. Used as a source of ferric hydroxide for mineral tan and buff colors on cotton, brown papers, logwood blacks on silk, shoe stains and inks. "FERRISUL"(Anhydrous Ferric Sulfate) FejfSO*)* Standard Forms Pellets 4*40 mesh. Typical Analysiss 90% min. Fe^SO*)*. R.R. Classifications Dry Ferric Sulfate. General Informations An effective coagulant for the treatment of water supplies, sewage, and industrial waste. In solution, it is a mild oxidising agent and can be used for pickling certain alloys such as the stainless steels, brass and other copper alloys. It is alao used in various organic reactions Available Literatures Booklets, "Ferrisul for Treatment of Water, Sewage and Industrial Wastes'* and "Ferrisul for Metal Treating." FERROPHOSPHORUS (Iron Phosphide) Standard Format Chill cast lumps, egg sixe; powder. Contains 23 26% pbospborua. R.R. Ossifications Ferropbospborus. General Informatlont An alloy of iron and phospborua. Used in iron and steel castings to increase fluidity; in sheet steel to prevent sticking of sheets in final rolling; in wire to give stiffness and better surface for drawing. Available Literatures Phoaphorn*`Iron Alloys Bulletin No. 1. A report of (Continued) 26TB EDITION Page 65 0663005 LEXOLDMONOQ5735 ueneral exploratory research upon the influence of phosphorus in low carbon, low alloy steels, 36 pages. Bulletin No. 2. A report of experimental research investigation upon corrosion jnd mechanical influences of alloying elements in low alloy steels. 62 pages plus harts. Bulletin No. 3. Abstracts of U.S. patents relating to phosphorus as an alloying lenient in steel and list of iron and steel patents, 54 pages. Bulletin No. 4. Re|>orts of experimental research investigation upon influence <>( phosphorus in steels in elevated temperature service and in Ct.Mo steels, 20 pages. "FIBESTOS" (See Plastics). FLECTOL" H snd WHITE (See under Antioxidants). I LOTATION AGENTS (See Xanthates). FUNGICIDES (See Santobrite and Santophen 20). GERMICIDES (See Antiseptics snd Germicides). GLAUBER'S SALT (Sodium Sulfate) NajSC>4+ 10 HjO Standard Format Crystals and Glatiboid*. Typical Analyalai 43% NatSO< available. R.R. Classification! Glauber's Salt. General Information! Used principally as a leveler in dyeing wool and silk; for the precipitation of barium sulfate or blanc fixe; neutralising of sulfonated oils; treating softened boiler feed Mater to prevent caustic embrittlement; salting skins. GLYCEROPHOSPHATES___ Specifications! See individual glycerophosphates below. General Information! The Glycerophosphates are a group ofproducts contain* (Continued) Page 66 MONSANTO CHEMICALS 0663606 ing the glycerophosphate radical and oiay be used advantageously to carry such important elements as calcium, iron, magnesium, manganese, potassium, and sodium in the formulation of pharmaceutical preparations. In the case of the less soluble salts, such as calcium, iron, magnesium, and manganese, the solubility of these products may be materially increased if they are formulated with Clycero* phosphoric Acid or certain accepted food acids, such as lactic, citric and tartaric. GLYCEROPHOSPHATE, CALCIUM, N.F. CaCiH(OH)jPO Mol. Wt. 210.15 Standard Form i Powder, 80 mesh. Specifications! Fine white powder; assay (dry basis) 98.0% min.; sp. g. 0.42 0.50; loss on drying at 130C., 12.0% max.; solubility in water (1:50),complete; chloride (as CaCI.) 0.1% max.; sulfate (as CaSO<) 0.50% max.; free phosphate (as PtO) 0.02% max.; conforms to N.F. test for heavy metals; 3.0% max. re tained on 80 mesh screen; 5.0%, max. on 100 mesh screen. R.R. Classification! Chemicals NOIBN. GLYCEROPHOSPHATE, FERRIC, N.F. Fet(CjH(OH)sPO] Mol. Wt. 621.90 Standard Form! Powder. Specifications! Buff or yellowish green powder; assay (dry basis), 17-0% Fe min.; moisture, 10.0% max.; chloride (as FeCIi), 0.10% max.; sulfate (as Fe;(SO<)i), 0.10% max.; free phosphate (as PjO), 0.20% max.; 2.0% mu. re tained on 60 mesh screen, 10.0% max. on 150 mesh screen, 30.0% mu. on 250 mesh screen. R.R. Classification! Chemicals NOIBN. GLYCEROPHOSPHATE, MAGNESIUM MgCHi(OH)jPO Mol. Wt. 194.39 Standard Forms Powder, 80-taesh. Specifications! White powder: assay, 97.0% mb.; moisture, 12.5% mu.; calcium (as CaO), negative; chlotide (aa MgCI-), 0.10% mu.; sulfate (as MgSO), 0.10% max.; free phosphate (as PiO), 0.20% max.; conforms to N.F, test for heavy metals; 2.0% mu, retabed on 60 mesh screen, 4.0% mu. on 80 mesh screen, 10.0% mu. on 100 mesh screen. R.R. Classifications Chemical! NOIBN. 26TB COITION Page 67 0683607 GLYCEROPHOSPHATE, MANGANESE, N.F_____________ ___ MoCiHj(OH)jPO, Mol. Wt. 225.00 Standard Formt Powder, 80-mesh. Specifications) Pinkish white powder; assay (dry basis), 98.0% min.; solubility ' in 25% citric acid solution (1:5), complete; moisture, 10.0% max.; chloride (as MnCI:), 0.15% max.; sulfate (as MnSO,), 0.03% max.; free phosphate (as P.0,), 0.20% max.; conforms to N.F. test for heavy metals; 2.0% max. retained on 60 mesh screen, 4.0% max on 80 mesh screen, 10.0% max. oo 150 mesb screen. K.R. Classification! Chemicals NOIBN. GLYCEROPHOSPHATE, POTASSIUM (Solution) KjCjH*(OH)jPO< Standard Formt Solution 75%. Specifications! Clear, colorless or slightly yellowish solution; assay, 61.6 63.2% anhydrous salt; carbonate (as K,:COj), 0.50 % max.; chloride (as KCI), 0.10% max.; sulfate (as K?SO), 0.10% max.; free phosphate (as PjO*), 0.20% max.; conforms to N.F. test for heavy metals. R.R. Classification! Chemicals NOIBN. GLYCEROPHOSPHATE, SODIUM, N.F Na,C,H,(OH),PO,. 5V$HaO Mol. Wt. 315.15 Standard Formal Crystals, 10-80 mefcb; powder. Specifications! White crystals; assay, 68.0 72.0% anhydrous salt (equivalent to 96.35 104.9% hydrated salt); solubility in water (1:10), complete; chloride (as NaCI), 0.05% max.; free phosphate (as P,Oi), 0.02% max.; conforms to N.F. test for heavy metals and sulfate (as Na,SO,); no crystals retained on 10 mesh screen, 40.0% min. crystals on 80 mesb screen. R.R, Classification! Chemicals NOIBN. GLYCEROPHOSPHATE, SODIUM (Solution) NatCiH,(OH)tP04 Standard Forms Solution 75%. Specificationsi Clear, colorless or slightly yellow solution; sassy 50.0 52.0% (Continued) Page 68 Monsanto chemicals 0663806 LEXOLDMON005738 T anhydrous salt; carbonate (as NajCOj) 0.5% max.; chloride (as NaCI) 0.10% max.; sulfate (as NajSO,) 0.10% max.; free phosphate (as PjO) 0.15% max.; conforms to N.F. test for heavy metals. R.R. Classification] Chemicals NOIBN. GLYCEROPHOSPHORIC ACID (Solution) HiCH(OH):PO Mol. Wt. 172 Standard Formt Solution 35%. Specifications] Clear, colorless liquid, APHA 20 max.; assay 35.0 36.0%; chloride (as CaClj), 0.10% max.; sulfate (as CaSO*), 0.20% max.; calcium (aa CaO), 0.25% max.; free phosphate (as PjOj), 0.35% max.; conforms to N.F. test for heavy metals. R.R. Classification! Chemicals NOIBN. ``GUANTAL" (See Accelerators, Rubber). H ACID (Mono8odium-l-Amino-8-Naphthol-3,6-Disulfonate) OH NH* NaSOj SOsH Mol. Wt. 341.29 Typical Analysis! White powdet; 86-88% monosodium salt; trace of NaCI sod NajSO*; solubility in water, complete. R.R. Classification] Dye Interxiaediate NOIBN. General Information! Used as so intermediate in the manufacture of dyestuffs. "HIBITITE"_____________________________________________ Standard Format Hibitite; Hibitite A, s commercial blend baring half the strength of regular Hibitite. Properties! Derivative of an organic base; reddish brown powder; soluble in concentrated sulfuric and muriatic acids. R.R. Classifications Iron or Steel Cleaning NOIBN. (Continued) 26TB BDtTION Page 69 0683809 LEXOLDMONOQ5739 General Informations Hibitite is widely employed in acids used for pickling and cleaning ferrous metals. It protects the metal by inhibiting the attack of the acid and by reducing the possibility of embrittlement caused by hvdrogen peoe> (ration. Hibitite A is similar in act>on to Hibitite with the exception that it is more readily dispersed than Hibitite in making up tbe acid solutions. Sulfuric acid containing Hibitite is used for pickling tin plate, wire, alloy steels, sheets for galvanizing; for cleaning steel drums and sand filters: for pre paring articles for vitreous enameling; for removing metal coatings. Muriatic acid containing Hibitite is used for cleaning boilers, economizers, heat exchangers, pipe lines, condensers, tanks, tuixs, coils, screens, pans, drums and similar equipment. For steel pickling acid containing Hibitite, see Inhibited Acid. Available Literature: 4-page raimtograpbed leaflet, "Hibitite and Its Uses." HYDROCHLORIC ACID, C. P HCI Mol. Wt. 36.46 Specifications! Colorless liquid free from suspended matter; strength 37.0 to 38.5%; non-volatile matter 0.0005% max.; sulphate 0.0002% max.; free chlorine 0.0002% max.; sulphite 0.003% max.; arsenic 0.00001% max.; iron 0.0001% max.; heavy metals (as lead) 0.0005% max. R.R. Classification: Muriatic Acid General Information: Laboratory reagent. HYDROCHLORIC ACID (See Muriatic Acid). 2-HYDROXY-3-METHOXY BENZALDEHYDE, TECHNICAL (Also known ss ortho-vanillin.) O C--H /\OH Mol. Wt. 152.1 ^OCH. Characteristics: Yellowish crystalline solid; crystallising point, 40.0C. min.; density, 1.20 at 60C.; wt. per gal., 10.0 lbs. R.R. Classification; Chemicals NO) BN. General Information t Used ss sn antioxidant and as an intermediate in chem ical synthesis. Psge 70 MONSANTO CHEMICALS 0683610 INHIBITED ACIDS Grades: These acids are snlutioiis of Hibitite in Monsanto's commercial grades of 60CB. sulfuric acid, 66B. sulfuric acid. 18B#. muriatic acid and 20B. muriatic acid. General Information: Addition of Hibitite to sulfuric and muriatic acids results in a decreased rate of attack of the acid on metal hut does not retard the action of the ocid on surface scab on the metal. Inhibited sulfuric acid is used for pickling tin plate stock, pickling sheets for galvanizing, preparing articles fov vitreous enamel, pickling Hire, pickling high carbon steel, removing metal coatings, cleaning steel drums and cleaning sand lilters. Inhibited muriatic acid is ui-ed for pickling alloy wire and cleaning boiler tubes, condensers, pipes, heater coils and drums. INHIBITORS (See Hibitite). INKS, LACQUER BASE General Information t Lacquer hnks are rapid drying, waterproof, greaseproof, adherent, flexible, and resistant to abrasion. Colors are light, fast and opaque, glossy or dull. Adapted for printing or coating cellophane, glassine, foil and other wrapper stock. Application is by intaglio photo engraved roll printing only, print roll being cleared by doctor blade. R.R. Classification: Lacquers. INSECTICIDES ortbo-Dlchlorobenzene (See under D). "Santochlor" (See under S). IRON CHLORIDE (See Fenic Chloride). IRON GLYCEROPHOSPHATE (See Glycerophosphate, Ferric). IRON NITRATE (See Feme Nitrate). IRON PHOSPHATE (See Fmc Phosphate). IRON PHOSPHIDE (See FetTopboepborus). IRON GLYCEROPHOSPHATE N.F. (See Glycerophosphates). IRON SULFATE (See Ferric Sulfate and Ferrisul). 26TB edition Pace 71 0683611 LEXOLDMONOQ5741 IACQUERS________________ ___________ _____________ For information on special lacquers and related products offered by Monsanto see tbe following listings elsewhere in this catalog: Acetone: Aircraft Finishes; Amyl Acetate; Belt Cement; Bronzing Liquids; Butyl Acetate; Butyl Alcohol; Cable Lacquers: Cements; Cotton Solutions; Diacetone; Ethyl Acetate; Inks. Lacquer Base; Leather Dopes; Manicure Lacquers; Mersol (Solvent Alcohol); Mertec; Textile Lacquers; Textile Printing Lacquers; Thinners. General Information! Tbe Lacquer and Solvent Department of Monsanto has been engaged for twenty years in th< development and manufacture of a wide variety of nitrocellulose base coalings for industrial use. At tbe present time Monsanto finishes for textiles, leathei, paper, rubber, wood and metal are being used in practically all classes of industry. Specific information available on re quest. K.R, Classification! Lacquers. LACQUER COTTON (See Cotton Solutions). LACQUER EMULSIFYING AGENTS (See AreekJene and Santomerse). LAMPBLACK Grades! Ten grades are available which vary in free carbon, density, and oil absorption. Specifications! Grad* Ordinary Black Lampblack Bear Germantown Commercial Black Lampblack No. 10 Lampblack B-5 Lampblack B-16 Lampblack BTA Lampblack S-100 Lampblack No. 8 Lampblack AA Fret Carbon 88.0% 9;\20% 88.05% 99.11% 9?.20% 98.38% 98.23% 91.70% 91.03% 9(-.34% R.R. Classification! Lampblack NOIBN. Apparent Density Lb, per Cu, Ft, 25.4 7.76 25.4 12.11 7.76 6.75 6.30 5.72 5.15 4.77 Beniol Extract % 1.65 -- .20 1.65 .7 .6 .6 .65 .85 General Information! Used as pigment in paints, varnishes, enamels, inks, leather finishes, stencils, crayons, polishes; in pressed forms as electrical conduc tors and electrodes. Available Literature! Booklet, "Monsanto Lampblack." LATEX PENETRANTS (See Areeklene and Santomerse). LATEX STABILIZERS (See Acesklene and Santomerse). Page 72 MONSANTO CBBMICALS 0663812 LEATHER DOPES General Information! Nitrocellulose solutions specially formulated for the incorporation of plasticizer and pigment for use in finishing split, patent, and artificial leathers. R.R. Classification! Lacquers. LITHIUM SALICYLATE N.F. (See Salicylate#). "LUSTRON" (See Plastics). MAGNESIUM AMMONIUM PHOSPHATE (Also known as magnesium ammonium ortho phosphate.) _______________ MgNH4P0.6H,0. Mol. Wt. 245.44 Standard Form: White powder. Properties! Insoluble in water and soluble in acids. Decomposes on beating. Gradet Technical. R.R. Classification! Chemicals NOIBN. Principal Use#! As an ingredient in fire retarding paints for theatre scenery and curtains. General Information! A hexahydrate and a monohydrate form exist. At ordinary temperatures disassociajion of the hexabydrate to the monohydrate takes place without appreciable loss of ammonia. Above 60C. the monobydrate loses NHj forming MgHP04.H20. MAGNESIUM GLYCEROPHOSPHATE (See Glycerophosphates). MAGNESIUM PHOSPHA'l'E, MONO (Also known as magnesium phosphate, monobasic; acid magnesium phosphate; magnesium tetrahydrogen phosphate; magnesium biphosphate.) MgH^PO,), Mol. Wt. 218.31 Standard Forrai White crystals. Gradei Technical. 26TB EDITION (Continued) Page 73 0663613 LEXOLDMONOQ5743 Rotary kilo at Camden, New Jersey, plant. R.R. Classifications Chemicals NOIBN. Principal Uaest Used in pharmaceutical preparations. MAGNESIUM PHOSPHATE, TRI______________ ____________ (Also known as neutral magnesium phosphate.) Mgj(POt)t Mol. Wt. 262.88 Standard Form t White crystalline powder. Grades Technical. R.R. Classificationt Chemicals NOIBN. General Informations Used In pharmaceutical products as an antacid. Page 74 MONSANTO CHEMICALS 0683B14 LEXOLDMON005744 MAGNESIUM SALICYLATES (See SaltyUm). MALEIC ANHYDRIDE Mol. Wt. 98.06 Standard Form: Fused solid. Specifications! White crystalline mass; crystallizing point 52.09C. min.; water solution (4 grams in 10 nil.), clear and colorless; glyceromaleate resin, clear with slight amber color; iron 0.0005% mt*. H.R. Classification! Chemicals NOIBN. General (nformationi Used alono or in combination with other acids in the manufacture of alk>d type resins. MANGANESE GLYCEROPHOSPHATE (See Glycerophosphates). MANICURE LACQUERS (See Lacquers). MANICURE LACQUERS and REMOVERS________________ General Information! Manicure lacquers are offered in two types -- frans. parent and creme. The dyes used in the transparent type are selected for stability to light, soapy water and ag*ng. The bottle appearance of the creme type lacquers is unusually good. There is no objectionable separation due to settling, and tbe lacquer applies without streaking. The bottle color matches the applied lacquer very closely. Colors and shades are provided according to the suggestions and specifications of the customer, and the opportunity to assist in development of new shades is welcomed. For those who prefer to select from standard shades, the following are offered in Manicure Lacquer R-4Q40 Creme and Transparent: Reddish Creme Shades Natural Robin Red Rose Tulip Sunrose Burgundy Old Rose Garnet Brotmish Creme Shades Thistle Suntan Rust Chestnut Bluish Creme Shades Lilac Windsor Grape Heather (Continued) Transparent Natural Rose Garnet 26TR BDtTION Page 75 0683815 Manicure Lacquer Remover R-2522 is an active solvent and has an agreeable odor. Container** Cana, S gal.; drums, 55 gal. Available Literature! Color chip folder, ''Monsanto Manicure Lacquer*." "MERCLOR" (Sodium Hypochlorite)_________________ NaOCl Standard Formi Liquid. Typical Analysis! 22B6.; 12% available chlorine by volume R.R. Classification! Sodium Hypochlorite Solution. General Information! Merclor is used as an oxidizing agent for bleaching cf vegetable fibers and as a chlorinating agent for water, organic compounds and wool. (See table in general data section) "MERSOL" Typical Analysis! Water white liquid: sp. g. 0.80 0.82 at 15.6C.; odor, mild, non*residual; distillation range, 74s 80s C.; acidity, less than 0.005% a* acetic acid. Composition! Alcohol, Special Denatured No. 1 Methyl isobutyl ketone Ethyl acetate, denatured withmethyl isobutyl ketone Gasoline 100 gals. 1 gaL 1 gat. 1 gal. R.R. Classification! Denatured Alcohol Solvent Containing Not Less Than 90% Denatured Alcohol. General Information! Mersol, a proprietary solvent alcohol, is formulated to have the advantages of Special Denatured Alcohol No. 1 without the necessity and burden of purchasing and operating under a government permit. It has the mild odor of alcohol and no residual Mersol may be used for most industrial purposes where SDA No. 1 is indicated, as a solvent for shellac and soft manila gums, in lacquer thinners, cleaners, removers, polishes, dressings, inks, adhesives, celluloid, softeners, brighteners, and as a fuel and dye and stain solvent. Available Literatures 68 page booklet "Nealco Industrial Alcohol." "MERTANOL" Grade*! Mertanol SS; Mertanol L; Mertanol 7L; Mertanol D; Mertanol 7D. (Gmtinued) Page 76 MONSANTO CHEMICALS 0683816 Typical Analyses: Mertanol SS Mertanol L Mertanol 71 Tannin Acidity equivalent to Sp. Gr. Inorganic Salts 12% 19-20% 19-20% .64 .66 normal 1.22 1.26 normal neutral 2.66 2.74% HjSO* approx. 4.74% HjSOt pH 6- 8 1.176 - 1.178 1.205 - 1.212 1.214 - 1.225 8.2% Na,SO, 11.4% (NH,),SO 18.8% (NH*)0 Tannin Acidity equivalent to Sp. Gr. Inorganic Salta Mertanol D 19 - 20% 1.22 1.26 normal approx. 4.74% H^SO* I.22 1.23 II.4% (NH^SO, Mertanol 7D 19 - 20% neutral pH 6-8 1.23 - 1.24 18.8%(NH4),SO Inorganic salt crystallizes out at temperatures below 40 F. K.K. Classification! Liquid Tanning Extract NOIBN. General Information! Mertanol is a synthetic tanning agent consisting of a naptbalene sulfonic acid condensation product in liquid form. The free sulfuric acid acidity has been completely neutralized and the sulfonic acidity neutralized to a definite acidity. L'sed in the manufacture of leather for bleaching of chrome tanned leather, bleaching base stock for making pastel leathers, for pre-tanning pickled stock before regular tan in order to maintain a lighter colored leather throughout the tannage, in vegetable tanning as an *id to penetration of the extracts and solubil ization of non-tans, in dyeing to give even dyeing and increased penetration of the dye, and as a mordant to hasten dyeing of chrome tanned and untanned leathers. "AIERTEC" (Corrosion-Resistant Paint) Mertec is a corrosion-resistant paint designed for use as a protective finish under severe acid and alkaline conditions. It is formulated on a chemically inert base and gives remarkable protection against acid fumes and caustic alkali attack. Mertec is primarily for use on metal, but the inert base makes it a practical finish for concrete. It may also be used on wood surfaces. It gives a tough, glossy, oil and water resistant finish. Fire resistance is excellent; the paint does not support flame travel. Heat resistance in continuous service is good up to about 200*F. Mertec is supplied in gray, rust, black, white and clear. Coverage is about 300 aq. ft. per gal. Pigmented Mertec R-3311 Gray 859 has the most desirable general properties. It is flexible and adheres well to almost any reasonably clean surface. It should cover satisfactorily in one coat, particularly the gray color which is recom mended for general mill use on exposed metal. Clear Mertec R-3300 is inferior to the pigmented type in weather resistance. It is also slightly less effective as a protective coating, and is recommended only where a pigmented finish is impractical. In using Clear Mertec R-3300 as a vehicle for aluminum, use about 1% pounds Aluminum Powder per gal. A (Continued) 26TR EDITION Page 77 06B3817 ready mixed product, Aluminum Met tec R-3457, can be supplied. For outside exposure a prime coat of R-3137 Gray 326 is recommended. Clear Mertec Topcoat R-3311 is a special type for application over ordinary painted surfaces to give resistance to corrosion. Clear Mertec Topcoat also im> parts greater resistance to corrosion when used over the Pigmented Mertec, and is especially recommended for use over Clear Mertec R-3300. Pigmented Mertec R-3799 is a special type for concrete floors. No priming coats or special preparation of the surface is necessary other than cleaning off loose grit and dirt and any accumulation of oil and grease. The surface should preferably be dry but damp surface* can be successfully finished. From the standpoint of durability under traffic the concrete surface should be smooth. K.R. Classification! Lacquers. Available Literaturei Leaflet, "Maintenance Paint*.'' META-CHLOROANILINE (See meta*Chloroaniline under C). META-CRESOL (See metaCreao1 under C.) META-NITROCHLOROBEN/ENE (See meta*Nitrocblorobenzene under N). "METHASAN" (See Accelerators, Rubber). METHYL PHOSPHORIC ACID (See Alkyl Phosphoric Acids). METHYL PHTHALYL ETHYI, GLYCOLATE(SeeSantici*erM.17). METHYL SALICYLATE U.S.P. (See Salicylates). MIXED ACID (See Nitrating Acid). MOLDING COMPOUNDS (Seo plastics). MOLD PASTE ______ ______ ____ Specifications! Several materials blended to give a satisfactory combination of the properties necessary for use on molds for vulcanizing rubber. Light brown colored paste; sp. gr., 1.54. (Continued) Page 78 Monsanto chemicals 0683816 R.R. Classification: Chemicals NOIBN. Available Literature: 42-page booklet "Monsanto Chemicals for the Rubber Industry". MONOAMMONIUM PHOSPHATE(See Ammonium Phosphate, Mono). MONOCALCIUM PHOSPHATE (See Calcium Phosphate, Mono). MONOCHLOROBENZENE (See Chlorobenzene). MONOMAGNESIUM PHOSPHATE (See Magnesium Phosphate, Mono). MONSANTO PLASTICS (S,* Plastics). "MONSANTO SALT" (orf/io-Chloro-para-ToIuene Sodium Sulfonate) ,___________________ ___ (Also known as 3<hloro-4*methyI benzene sodiumsulfonate). CHi Mol. Wt. 228.63 Characteristics: Light gray to light tan powder; asaay (from Cl content), 97.0 100.5%; NaCI, 0.5% max.; n,<oiature (HjO), 1.0% max. R.R. Classification: Dye Intermediate. General Information: Used in dyestuff synthesis. MURIATIC ACID (Hydroch(oric)_______________ HC1 Grades: 18 B<; 20 B; 22 BU Typical Analysis! 18 B*.. 27.9% HC1.; 20 B5., 31.5% HCI.; 22 B*., 35.2% HCI. R.R. Classification: Muriatic Acid General Information: Used extensively in the starch, glucose, steel, galvaniz ing, paper, leather and glaas industries. (See table in general data section) 26th edition Page 19 0683819 `NEALCO" ANTI-FREEZE General Informations A completely denatured ethyl alcohol type anti-freeze Huid for automobile, airplane and oiher gasoline engine cooling systems. Will not corrode the radiator, form rust, sludge or sediment; will not cause leaks nor attack hose connections. K.R. Classifications Anti-freeze Alcohol. NITRATE OF IRON, COPPERAS (Se. Ferric Sulfate). NITRATE OF IRON* TRUE (See Ferric Nitrate). N1 ATING ACID (Mu. ' Acid) -- Typ- <1 Analysis! Nitric Acid (HNOj) Sulphuric Acid (H*SO<) Oxides of Nitrogen (NjOj) 80-15 80.0% 15.0% 0.25% 85-12 85.0% 12.0% 0.25% J8 60.0% 38.0% 0.25% 45-53 45.0% 53.0% 0.25% R.R. Classifications Nitrating Acid General Information: Mixed acid is used for nitrating in the chemical industry, particularly in the manufacture of explosives and dyestuffs. Special mixtures can be furnished to meet individual requirements. (See table in general data section) NITRE CAKE (Sodium Bisulfate) Standard Format Bulk; ground; globular. Typical Analysis! 35% HjSOj available. R.R. Classification! Nitric Cske. General Information! Used to replsce either sulfuric scid or combinstion of sulfuric scid snd Glsuber's sslt. One hundred lbs. of Nitre Cske is spproxixnstely equivalent to 35 lbs. of o6 sulfuric acid snd 141 lbs. of Glauber's salt. Used principally in viscose rayon spinning baths; dyeing woolen goods; re fining nickel ores; manufacture of sulfate pulp; in tanneries for pickling, deliming snd making one bath tan solutions; as an acid scour for household use; in agri culture for disinfecting soil; as a bowl cleaner in sanitary trade. Page 80 MONSANTO CHEMICALS 0683820 T NITRIC ACID HNOj Standard Forms! 36 B., 38 Bt*., 40 Be., and 12 Bi. Typical Analysis! %HNOj: 36Btf.. 52.3: 388B.. 56.5: 408B#,, 61.4: 428B., 67.2. Sp. g. will not vary mors than 0.,5* terms of B. HjSO* 0.1% max.; HCI 0.1% max. For higher strengths refer to Merrimac Division Sales Office. R.R. Classification! Nitric Acid. General Information! Used in the manufacture of insecticides, dyestuffs, drugs, pharmaceuticals, explosive^, photo engravings, nitrates and other nitro products. (See table in general data section) NITRIC ACID C. P. UNO* Mol. Wt. 63.01 Typical Analysis! Colorless Iquid, free from suspended matter; strength(HNOs), 70.0 to 71.5%; non-volatile matter, 0.0005% max.; sulphate (S04) 0.0002% max.; chloride (Cl), 0.00007% piax.: arsenic (As), 0.000003% max.; heavy metals (as lead), 0.0005% max.; heavy metals (as iron), 0.0001% max. R.R. Classification! Nitric Acid. General Information t Laboratoi-y reagent. l-NITRO-2, 5-DICHLOROBENZENE (Also known as 2, 5-dichloroQitrobenzene.) Mol. Wt. 192.01 Cl Standard Formi Fused solid. Specifications! Light yellow to light brown crystalline solid; crystallising point, 52.5C. min. R.R. Classification! Dye Intermediate. General Information! Used as ai> intermediate in the preparation of dyestuffs. CAUTION: This produet it toxic. Amid breathing it* vapors and amid contact with the skin. 2ATH EDITION Page 81 0683821 LEXOLDMONOQ5751 orf/io-NITROANILINE _ (Also known as ort/iu.aminonitrobenzene and I-aminn>2>nitrobenzene.) NH, Standard Forms: Powder; powder with 0.5% tricalcium phosphate. Specifications) Yellow Jo nrangi powder; m. p. ?0.0C. min. Assay: powder. min.; powder wiih triraMum phosphate, 98.50% min. Ash: powder, 0.25% max.; powder with tncalriom phosphate, 0.75% max. K.K. Classification: I))e Intermediate. General Information) ortho.Ndroaniline powder has a tendency to "set up" in tumps on standing. It is recommended that it be milled to proper fineness just before using. The addition of 0.5% tricalcium phosphate reduces the caking tendency. ortho-Nitroaniline is used as an intermediate in the preparation of dyestuffs. CA UTION: This product is toxic. Avoid breathing its dust and avoid contact with the skin. para-NITROANILINE NH* Mol. Wt. 138.12 NO* Standard'^ormi Powder. Characteristics) Bright yellow crystalline powder; soluble in BC); in. p. 148C. min.; assay 99% min. R.H. Classification) Dye Intermediate. "Poison" label required. General Information) Intermediate in dyestuff syntheses. CAUTION: This product is toxic. Avoid contact with tdcin. Avoid inhaling vapors. ortho- NITROANISOLE (Also known as ortho-aminoaniaole, ortAo-nitrophenylmetbylether and l-me* thnxy ^.nitrobenzene. OCHi Mol. Wt. 153.14 Page 82 Standard Formi Liquid (( ontinued) MONSANTO CBS MIC A LS 0683822 Specifications! Light reddish or light amber liquid; crystallizing point, 9.6C. min., dry basis. Distillation range: first drop 270.0C. min.; 95% 2.0C. max.; dry point 273.0C. max. Nitropbetiol 0.05% max. R.R. Classification! Dye Intermediate. General Information i rtAo-NitroanisoIe is used in the production of such dye intermediates as oriho-anisidine apd dianisidiae. It is also used in various or ganic syntheses. CAUTION: This product is toxic. Avoid breathing its vapors and avoid contact with the skin. NITROCELLULOSE SOLUTIONS (See Cotton Solutions). meta-NITROCHLOROBENZENE ____________________ (Also known as me*a-chloronitrobeneene and 1 chloro-3-nitrobenzene.) NO Mol. Wt. 157.50 Standard Form i Fused solid Specifications! Greenish yellow crystalline mass; clear when melted; crystalliz ing point 43.9'C. min. R.R. Claaaificatiom Dye Intermediate. General Information! Used for tonversion into various dyestuff intermediates, cbloroanilinea and chlorobenzidines. CAUTION: This product is toxic. Avoid breathing its vapors. Avoid contact with the skin. ort/io-NITROCHLOROBENZENE _____________________ (Also known as ortAo-chlorooitrobenzene and 1-chioro-2-nitrobenzene.) Cl MoL Wt. 157.50 Standard Formi Fused solid Specifications! Greenish yellow crystalline mass; crystallizing point 31.7#C. (on sample as received). R.R. Classificationi Dye InteruMtdiate. General Information! Used in the preparation of dyestuff intermediates. CAUTION} This material is toxic Avoid breathing its vapors. Avoid contact uziA the skin. 2ATH EDITION Page 83 0683823 para-MTROCH LOROBENZENE (Also known as para-chloronitrnbenzene and l-r'hloro.4>nitrobenzene.) NO, 0 Mol. Wt. 157.56 Cl Standard Forms Fused solid Specifications: Light greenish yellow solid; crystallising point 82.5C. min. K.R. Classification: Dye Intermediate. General Information: para-Nitrotxnzene is used in the preparation of dyestuff intermediates. CriCT/O.V: This ptoducl is toxic. Avoid breathing Us vaport and avoid contact with the skin. ort/io-NITRODIPHENYL, TECHNICAL NO, Mol. Wt. 199 Characteristics: Light yellow to reddish crystalline solid; crystallising point 34.5C. min. R.R. Classification: Dye Intermediate NOIBN. General Information: Used as an intermediate in chemical synthesis where it is useful in some applications as an alternate for substituted nitrobenzene,. Msy be partially reduced and rearranged to give 2,2'*dipbenyl benzidine NITRON" (See Plastics). tro-NITROPHENOL so known ss paro*bydroxynitroben;ene and 1-hydroxy*4-nitrobenene.) OH Mol. Wt. 139.11 NO, Standard Form t Granules Specifications! Brown granular mast; m. p. (dry basis) 112.0C. min.; assay, 96.5% min.; water insoluble material 0.20% max.; alcohol insoluble material 0.20% max. (CotUinued) Page 84 MONSANTO CSKMICALS 068382** R.R. Classification: Dye Intermediate. General Information: /wro-Nitrophenol has the following uses: as ao inter* mediate in the production of dyestuffs and photographic chemicals such as para* aminophenol and methyl pora-aminophenol; as a fungicide to prevent mold growth on chrome tanned leather. C.4LTI0N: This product is toxic. Avoid breathing ils dust or rnpors and avoid contact with the skin. OIL ANTIOXIDANTS (See Stntolube). OIL OF VITRIOL (See Sulfuric Acid). OLEUM (See Sulfuric Acid). "OPALON" (See Plastics). ORTHO-AMINODIPHENYL (See ortho-Aminodiphenyl under A). ORTHO-ANISIDINE (See ortho'Anisidine under A). ORTHO-CHLOROANILINE (See ortho-Chloroaniline under C). ORTHO-CHLORO-PARA-TOLUENE-SODIUM-SULFONATE (See Monsanto Salt.). ORTHO-CHLOROPHENOL (See ortho.Chloropbenol under C). ORTHO-CRESOL (See ortbo-Cwvol under C). ORTHO-DICHLOROBENZENE TECHNICAL (See ortho-Dichlom* beaeeoe Technical under D). ORTHO-NITROANILINE (See ortbo-Nitroaniline under N). ORTHO-NITROANISOLE (See ortbo-Nttroanieole under N). 26TB IDITION Page SS 0683825 LEXOLDMON005755 ORTHO-NITROCHLOROBENZENE (See ortbo-Nitrochloiobenxene under N). ORTHO-NITRODIPHENYL (See ortbo-N'itrodiphenyl under N). ORTHO-PHENETIDIN (See ortboPbenetidin under P). "OXYNONE" (See Antioxidants Rubber). PAINT, acid and alkali resistant (or plant maintenance; (See Mertec). PAINT ANTISKINNING MATERIALS, available to fit varied trade requirements; (See Santovar A). PAPER LACQUERS (See Lacquers). PARA-AMINODIPHENY L (See para-Aminodiphenyl under A). PARA-ANISIDINE (See para*Anisidine under A). PARA-CHLOROANILINE (See para-Chloroaniline under C). PARA-CHLORO-META-CRESOL (See para-Chloro-meta-Cresol under C). PARA-CHLORO-META-XY LENOL (See para-Chloro-meta-Xylenol under C). PARA-CHLOROPHENOL (See para-Cbloropbenol under C). PARA-CRESOL (See para-Cres>1 under C). PARA-NITROANILINE (See para-Nitroaniline under N). Page86 Monsanto chemicals 0683626 LEXOLDMON005756 PARA-XITROCHLOROBEXZKXE (See para*i\itrochlorobenzene under N). PARA-XITROPHEXOL (See para>Nitrophenol under N). PARA-PHEXETIDIX (See para-Phenetidin under P). PARA-TOLLEXESLLFOXAMIDE (See pura-Tnluenesulfonamide under PARA-TOLL EXESULFOXCHLORIDE (See para-Toluenesulforw chloride under T). PEXETRATIXG AGEXTS (See Areskap, Aresket, Aresklene, Santoraeese). PEXTACHLOROPHEXOL (Se< Santophen 20 and PermasanJ. PERCHLORIDE OF IRON (S< Ferric Chloride Solution). PERMAXOL" Gradeet Pertnanol; Permanol 7. Propertieei Viacoua liquid. Inorganic fait crystallize* out at temperatures below 40 F. R.R. Classification! Liquid Tanning Extract NOIBN. General Information! Permanol is *. synthetic tanning agent in liquid form. It has the special property of being extremely lightfast. Information on uses for Mertanol applies. See Mertanol. "PERMASAN" Characteristics! Consists of S% p<ntachloroptaenol, min., 5% non-volatile solvent and 90% petroleum distillate; light amber color, less than 4.5 NPAS; characteristic petroleum odor; flash point, 140F. min. by Tagliabue closed cup method; ap.g. approx. 0.8785 at 1S.5C.; wt. per gal., 7.2 lbs. (Continued) 26TB COITION Page 87 0663827 R.R. Classification: Liquid Wood Preservative NOIBN. General Information: Used for preservation of wood against termites, Lyttus (powder-post) beetles, decay, and a wide range of other wood-attacking insects and organisms. Does not adversely affect the feel and appearance of wood, and surfaces properly treated may be satisfactorily glazed, painted or otherwise fin ished. Permasan conforms with th specifications of the Western Pine Associa tion's Bulletin No. 6 (revised) and is accepted by the National Door Manufact urers Association. Permasan is irritating to the skit! and mucous membranes if sufficient contact is permitted. The precautions for handling given in literature listed below should be observed. Available Literature: 6-page Monsanto Technical Bulletin 0-20, "Permasan for the Preservation of Seasoned Wood." 5-page Monsanto Technical Bulletin 0-14, "Permasan for Lyctus (Powdec-Post) Beetle Control." "PERMASAN 116" Characteristics: Consists of 5% pentachlorophenol, min., and 95% mixture of water repellents, organic solvents and diluents; light amber color, less than 4.5 NPAS; mild, not unpleasant odor; flash point, 1009F. min, by Tagliabue closed cup method; sp. g. approx. 0,855 at 15.5C.; wt. per gal., 7.13 lbs. R.R. Classification: Liquid Wood Preservative NOIBN. General Information: Used same as ordinary Permasan (see above) except gives added advantages of water repellency. Conforms with specifications of Western Pine Association's Bulleti:- No. 6 (revised). Permasan is irritating to the skip and mucous membranes if sufficient contact is permitted. The precautions for handling given in literature listed below should be observed. Available Literature: 8-page Monsanto Technical Bulletin 0-21, "Permasan 116 A Water-Repelleot Preservative for Wood." PETROLEUM CHEMICALS* (See Santolene, Santolubes, Santopoid, Santopour). PHENACETIN (See Acetopheuetidin). orf/io-PHENETIDIN _____ (Also known as ortAo-aminophenyU thylether, ort/to-aminophenetole, and 1-amino-2-etboxybetuene. (Continued) Page 88 MONSANTO CBBMICALS OCiH* ^ NH* Mol. Wt. 137.18 Standard Form! Liquid Specifications! Dark red liquid: crystallizing point (as received) --4.09C. min. Distillation range: first drop 231.0'C. min.; 95% (1-96 ml.), 2.0C. max.; dry point. 234.0C. min. Solubility in IICI, complete. It.K. Classification: Dye Inlermtdiate. General Information! trt/io*Phnetidin is used as an intermediate in the production of dyestuffs. CAUTION: This product ts toxic. Avoid treat/ling its tnpors and contact with the skin. para-PHENETIDIN _____ ____________ _ (Also known as para*aminophenyletbylether.para-aminopbenetole, and l>amino*4 dhoxybenzene.) OCH Mol. Wt. 137.18 NHi Standard Formi Liquid Specificationst Dark red liquid; crystallizing point (as received) 4.09C. min. Distillation range: first drop 248.0C. min.; 95% (1*96 ml.), 2.09C. max.; dry point 25l.09C. max. Solution in HO, opalescent. R.R. Classification: Dye Intermediate. General Information! pora-Phepetidin is used as an intermediate in the pro* ductton of dyestuffs and pharmaceuticals. CAUTION: This product is toxic. Avoid breathing its vapors and contact with the skin. PHENOL-FORMALDEHYDE RESIN (See Plastics. Resinox). PHENOLIC RESIN. CAST (See Plastics, Opatoo). PHENOL _______________ _____________ (Also known as carbolic acid and hydroxybenzene.) Mol. Wt. 94.11 26TH EDITION (Continued) Page 89 0683829 Standard Format Crystalline solid, U.S.P.: '`quid 85%; liquid 88%. Specifications of Crystalline Solid, U.S.P.: White crystalline solid; melt, colorless mobile liquid: solution in water (1:15), clear and colorless; non-volatile residue (100C.). 0.04% mas.; crystallising point 40.0C. min. Distilling range: first drop, 180.0C. min.; 100% (first drop to dry point), 2.0C. max.; 50% to dry |M>int, 0.2C. max. Specifications of Liquids: Colorless mobile liquids. Assay: liquid 85%, 85.08(1.0%; liquid 88%. 88.0 - 80.0%. R.R. Classification: Phenol. General Information: Used as an intermediate for the production of dyestuffs; in production of resins for molding and in the preparation of varnishes, enamels, lacquers and paints; as a selective solvent in the manufacture of lubricating oils; as a disinfectant; in textile printing; in the production of explosives, synthetic tanning materials, pharmaceuticals and medicinals, antiseptics, germicides and preservatives, deodorants, soaps, embalming fluid, vermin exterminators, rubber compounds, and photographic chemicals. PHENOLPHTHALEIN, U.S.P. OH OH Mol. Wt. 318.31 Standard Form: Powder. O Specifications: White powder; m.p. 259.0C. min.; solubility in alcohol (1:15), complete; acidity (cc's N/1000 NaOU/2 g. sample), 3.0 cc. max.; ash 0.05% max.; arsenic 0.001% max.; conforms to U.S.P. test for fluorine and heavy metals; trace max. retained on 100 mesh screen; 21.0% max. on 325 mesh screen. R.R. Classification: Chemicals NOIBN. General Information: Used in pharmaceutical preparations. PHENOLPHTHALEIN, YEI LOW, Not U.S.P. Standard Form: Powder. Speclficationai Yellow powder; m.p. 2$7.0C. min.; loss on drying, 0.50% max.; ash, 0.10% max-; acidity (cc*s N/1000 sodium hydroxide per 2 gm. sample). 5.0 cc max.; solution in ethyl alcohol 95% (1:15), clear; sp. g. (apparent) 0.500 0.600; none retained on 20 mesh screen. (Continued) Page 90 MONSANTO CHEMICALS 0663630 K.K. Classification: Chemicals .NOIBN. (General Information: Used in pharmaceutical preparations. PHENOL-FORMALDEHYDE (See Plastics, Resino* Molding Com* .......mis). PHENYL SALICYLATE (See Salicylates). PHOSPHATES (See Ammonium Phosphate, Calcium Phosphate, Magnesium Phosphate, Potassium Phosphate, Sodium Phosphate) PHOSPHOLEUM (See Tetraphoephoric Acid). PHOSPHORIC ACID (Orthophosphoric Acid) HPO Mol. t. 98.004 Standard Forma: 50%, 75% and 85% HjPO^ Other concentrations supplied <m request. Specifications: Clear, water-white liquid miscible with water in all proportions. Grades: U.S.P.; food, meets all U.S- Pure Food Law requirements: commercial, clear water white liquid: Phoailage, meets ail U.S. Food Law requirements: special. U.K. Classification: Phosphoric Acid. General Information: Principal uses -- Ceramics; To increase translucency and improve the color of porcelain*; as a vitrifying agent and flux. Chemicals and Intermediates: In manufacture of sodium phosphates, calcium phos phates, and other phosphates: in manufacture of ethylene gas: in making albumen derivatives. As a drying agent in th<? synthesis of various intermediate chemicals. Dyes: As a drying agent in the synthesis of various dyes. Engraving: In pro cess engraving and litho trades. 1,'nveiopes: As a penetrant to aid in the ab sorption of the gum. Fertilizers: In manufacture of double and triple super phosphates; in manufacture of ammonium phosphate. Gelatin: In manufacture of gelatin. Glass: As opacifier. Jelly and Preserves: As a substitute for tar taric and citric acids. Metals: For pickling and cleaning. Pharmaceuticals: In manufacture of certain pharmaceutical chemicals; in making dental cements; in manufacture and purification of hydrogen peroxide; in manufacture of glycero phosphates. Rope and Twine: For brightening the finish. Rubber: As a coagulant of rubber latex. Rust Proofing: In the manufacture of rust proofing compounds. Silage: For silage pteservation. Soft drinks: As a substitute for (Continued) 26TB EDITION Page 91 tartaric and citric acids. Sugar: As a defecating and clarifying agent. Textiles: In brightening the color of silk; in the dyeing of cotton; in calico printing. (Taler treatment: In water softening and correction of alkalinity. 15C. Density and Composition of water solutions of Orthophosphoric Acid (S' ~j-;-- Density g./cc. Decrease per 19C. %HjPO %PA %P MOO 1.150 1.200 1.250 1.300 1.339 1.350 1.400 1.450 1.500 1.550 1.581 1.600 1.650 0.00030 0.00035 0.00045 0.00050 0.00055 0.000S5 0.00060 0.00060 0.00060 0.00065 0.00070 0.00077 0.00075 0.00075 17.52 25.25 32.52 39.22 45.51 50.00 51.22 56.85 62.27 67.35 72.11 75.00 76.75 81.30 12.69 18.29 23.55 28.41 32.96 36.21 37.10 41.17 45.10 48.78 52.23 54.32 55.59 58.88 5.54 7.98 10.28 12.40 14.39 15.81 16.19 17.97 19.68 21.29 22,79 23.71 2 4.26 25.70 1.693 0.00080 85.00 61.56 26.87 1.700 1.750 1.800 0.00080 0.00080 0.00080 85.63 89.88 94.15 62.02 65.10 68.19 27.07 28.41 29.76 1.850 0.00080 98.13 71.07 31.02 1.874 0.00080 100.00 72.43 31.61 The density of more concentrated acids increases approximately linearly (within the range 72.44% to 85% PjO*) with the excess PjOj over 72.44% according to the equation: 1.874 + 0.0171 (%P,0, -- 72.43). PHOSPHORIC ANHYDRIDE (See Phosphorus Pentoxide). PHOSPHORUS, ELEMENTAL (Also known as yellow phosphorus and white phosphorus) Cradeat Monsanto process of manufacture provides over 99.9% purity. Properties! Light yellow, wax-like, semi-transparent solid; burns spontaneously in air to form PjOs; m.p. 44.1C.; insoluble in water but very soluble in carbon bisulphide. R.R. Classification! Phosphorus, Yellow. General Information! Used in manufacture of phosphorus alloys, phosphoric anhydride, phosphorus compounds, phosphoric acid, rodent poisons, flares, smokescreens, etc. PHOSPHORUS OXYCHLORIDE __________ (Also known as phosphoryl chloride). POCU Mol. Wt. 153.35 (Continued) Page 92 MONSANTO CHEMICALS 0683832 Standard Forms Liquid. Specifications: Water-white to yeilow liquid; crystallizing point 0.8*C. min.; assay 99.0% min. Distillation range: first drop, 106.0C. min,; 95% (1-96 ml.), l.5C. max.; dry point, 108.5C. max. PCIj, 0.20% max.; PClj, trace max.; HjPCV 0.30% max.; HCI, 0.50% max.; free chlorine, trace max.; iron, 0.0005% max. R.R. Classification: Phosphorus Oxychloride. General Information: Used as a chlorinating agent and catalyst in the prep aration of various intermediates end dyestuffs and as a reagent in the prepara tion of acetic anhydride and organic phosphates. CALT10X: Care must be ex ercised in handling this product. Avoid breathing its vapors; avoid contort with the skin. It reacts ivith water with explosive violence. PHOSPHORUS PENTOXIDE.._____________ (Also known as phosphoric anhydride; phosphoric oxide; solid P,0,.) P,0, Mol. Wt. 141.96 Standard Formt White amorphous powder. Characteristics: Vapor Pressures: (after J. C. Southard and R. A. Nelson--J.A.C.S. 59. 911 (1937) p = vapor pressure in cm. of mercury. T absolute Temperature). A (low temperature form) Logiof = 9.792--(5000/T) B (high temperature form) Logtop ** 11.113--(7930/7') L (liquid) Logiop = 6.809--(4320/7") Atmospheric sublimation temperat ure: 358.9C. Heat of vaporization: A--22,800 calories per gm. molecule. B--36,200 calories per gm. molecule. L--19,700 calories per gm. molecule. Heat of fusion: 16,500 calories pet gm. molecule. Probable molecular formula of va]or: PfOja. R.R. Classification: Phosphoric Anhydride. General Information: Used in the manufacture of organic and phosphorus compounds and as a cayalyst. It Is a vigorous drying and dehydrating agent. PHOSPHORUS TRICHLORIDE PCI, Mol. Wt. 137.35 Standard Form: Liquid. Specifications! Water white liquid: sp. g. at 15.5/15.59C., 1.582-1.587. Dis> (Continued) 26TB EDITION Page 93 0663833 tilling range; first drop .Tl.S'C. min.; d*y point, 79,0C. man.; total range. 3.0C. K.K. Classification] Phosphorous Trichloride. General Information! Used as a chlorinating agent and catalyst in the prep* aration of various intermediates and dvestuffs: as a reagent in the preparation >f acetic anhydride and organic phosphates; in the manufacture of phosphorus oxychloride and phosphorus pentachlotide; and in producing iridescent metallic deposits. C.ALTtO V; Care must be etprctsed in handling this product. Reacts with miter, -hold breathing its vapors; avoid contact with the skin. PHTHALIC ANHYDRIDE Gradest Three grades with crystallizing points of 131.2C., 131.0C., and 130.7*0 respectively. Specifications: White flakes; solution in benzene (1:20) clear: ash 0.03% max. Maleic acid; 131.2C., 0.10% mn.; 131.0C., 0.15% max.; 130.7X., 0.15% max. R.R. Classification! Phthalic Anhydride. General Information: Uses: As an intermediate in the production of dyestuffs, perfume bases, alcohol denaturants, pharmaceutical products, plasticizers--such as dibutyl phthalate, dimethyl pbthalate, diethyl pbthalate, phtbalyl glycollates --and alkyd resins. PHTHALYL CHLORIDE Mol. Wt. 203.03 Standard Forms Liquid. Characteristics] Yellowish liquid; assay, 95.0% min.; crystallizing point, 7.5C. R.R. Classifications Chemicals NOIBN. Corrosive liquid (white label required). General Information! Used in the manufacture of plasticizers and resins. PICKLER'S ACID (See Inhibited Acid). Page 94 MONSANTO C0BMICAL9 068363A PIPERIDINE______________ (Also known as hfxalivdropvridme). Mol. Wt. 85.14 Standard Form: Liquid Specifications: Clear, water-white liquid of characteristic odor; assay, 98% min.; pyridine, 1.0% max.; sp. g. 25V25'C., 0.860 0.003. Distillation range: 104.0CC. min. start; 107.0C. max. dry point. K.U. Classification: Chemicals NOIBN. General Information: Used as an intermediate in the manufacture of phar maceuticals, wetting agents, and getmicides. "PIP-PIP" (See Accelerators, Rubber). PLASTICIZERS (See Santicizrrs, Dibutyl Phthalate, Diethyl Phtbalate, Dimethyl Phthalate, Diphenyl Phtbalate, Tricreeyl Phosphate, Triphenyl Phosphate). PLASTICS (See individual materials below.) -- CAST PHENOLIC (See Plastics, Opalon). CELLULOSE ACETATE (See Plastics, Fibestoa). CELLULOSE NITRATE (See Plastics, Nitron). "FIBESTOS"* (Cellulose Acetate) The most widely-used thermoplastic, cellulose acetate, is distinguished by a flexible range of properties and formulations. In the form of molding compounds, Fibestos is adapted to either compression or injection molding. Sheets, rods, tubes and continuous length rolls ate other forms in which it is produced hy Monsanto. Mechanical Properties > Specific gravity...........................................................................1.27 1.37 Specific volume, cubic inches per pound.......................20.2 21.8 (Continued) 26TH EDITION Page 95 P L A S T IC S 0683835 LEXOLDMONOQ5765 P L A S T IC S llefractive index ,\[> ............................................................. 1.17 1.50 Tensile strength, lbs., sq.in....................... . 3,500.11.000 I'.lnngatiort, percent ................................................ 5-55 llursling slreniilh (rupture) lbs. q.in., mil.. . .18-35 Modulus of rlaticity, lb.. q.in x 105.......................... I -3.5 Impact strength, I/nd, fi. lbs..'in. of nolcl (V.S.T.M.) ................................................................... 0.7- 4.2 Itriiudl hardness, 2.5 nun. ball 10 kg. load . . . .0 15 Kockuclt hardness ....................................................................M25 - M55 Machining qualities...................................................................(bind Molding Properties: 1 ype.................................................................................................Thermoplastic Molding qualities................................................................. I.xccllent Molding Tempera lure F. ( aiiiipression.................................................................. 210 - 350 Injection..........................................................................300 - 110 Molding Pressure lbs. sq. in. Compression....................................... .......................... 500 - 5000 Injection................................................. . . .8000 - 30000 Preformin'!.............................................................. . Very pond Tendency toroid Don ............................................ .Slight Processing cellulose at Springfield plant fur manufacture of Monsanto plastics. 0683836 LEXOLDMON005766 w Molding methods applicable................................................Compression, injection, trusion, sh aging Mold shrinkage, inches/nch: Povtive............................ 002 .003 Sepii-positive................ 005 .007 Flash................................. 008 .009 Extruding quality.......................................................................Excellent ei* Thermal Properties: Horning rate, in. min. (.060') ..........................................1.5 2.0 Slow burning Thermal conductivity, 10--* calo'ies/sec,/sq.cm./ C. cm............................................................................ 4.5 7.8 Specific heat, calories/C. 'gram.........................................0.3 0.4 Thermal expansion, 10--} C.............................................. 10 16 Resistance to heat, F. (continuous).............................. 140 250 Softening point. F....................................................................140 260 Effect of heat, dry ................................................................ Little or none moist................................................................Slight swelling Heat distortion, F. (A.S.T.M.)........................................122 212 Electrical Properties: \ nlume resistivitv, ohms-cms. (59%R.H. and 25C.). . .'.......................................................... Breakdown voltage, 60 eyries volts mil............ Dielectric constant, 60 cycles................................. 'A 10* cycles................................. Power factor, 60 cycles.............................................. 10 cycles............................................ V) Chemical and Physical Propet ties: Odor................................................................. ................... a. Taste............................................................................... Effect of age..................................................................... Effect of sunlight ........................................................ Effect of ultraviolet light.......................................... Effect of metal inserts................................................ Effect of weak mineral acids................................... Effect of strong acids.................................................. Effect of weak alkalis ................................................ Effect of strong alkalis ............................................. Water absorption 24 hours...................................... Solubility: Softens in-- ........................................ Swells in-- .......................................... Insoluble in--.......................................... (0.7 1.4)xl0>* 600 1.800 3.5 7.5 2.0 5.0 0.007 0.07 0.007 0.03 None to mild aromatic None Slight Gradually become brittle-- some colors fade Gradually become brittle-- some colors fade. None Fair resistance Decomposes Slight Decomposes 1.5-3% Alcohols, esters Chlorinated hydrocarbons Aromatic and aliphatic hy drocarbons, animal, mineral, and vegetable oils, ethers Colon Available in an extremely wide variety of transparent, translucent, pastel and opaque colors, at well as in many mottles, pearls and decorative configurations. Forms: Sheets, rods, tubes and molding compounds. Trade Mark Reg. U. S. Pat. Ofl. 26TH EDITION Page 97 0663837 LEXOLDMON005767 PLASTICS- "LUSTRON"* (Polystyrene Molding Compounds) Lustron is Monsanto's formulation of polystyrene molding compound. Tbe rapid expansion of uses for Lustron since its introduction in 1939 is excellent proof of its versatility and broad range of useful properties. It is unexcelled among thermoplastics for electrical characteristics, chemical resistance, low moisture absorption and dimensional stability as the following table of properties indicates. Molding quality ....................................................................... Excellent CouiproMon molding temperature, F....................... 275 350 Compression molding pressure, Ibs./sq.in..................... 1000 5000 Injection molding temperature, F...................................300 500 Injection molding pressure, Ibs./sq.in............................. 10.000 and up Compression ratio................................................................... 2.0 2.3 Mold shrinkage...........................................................................Compression 0.002 0.005 in. per in. Injection 0.002 0.008 in. per in. Specific gravity ...................................................................1.054 * 1.070 Specific volume, cu.in./lb.................................................... 26.3 25.9 Refractive index ...................................................................1.59 Tensile strength, lbs., sq. in..................................................5000 9000 Elongation, %.........................................................................2*5 Modulus of elasticity, in tension, Ibs./sq in...............1.7 2.6 x 10s Compressive strength, lbs. sq. in...................................... 11.500 13.500 Flexural strength, Ibs./sq. in............................................... 14,000 19,000 Impact strength, Izod, ft. Ibs./in. of not< h (A.S.T. M.).................................................... .................0.35 0.50 ft.Ibs./in. of notch Brinell hardness (2.5mm bail, 25kg. load).................. 20 30 Rockwell hardness.....................................................................M87 M90 Light transmission, % ....................................................88*90 Thermal conductivity, cal./sec./sq.cm./C./cm. 1.9 x 10--4 Specific heat, cal./"C./gram ..........................................0.32 Thermal expansion, C...................................................... .(6 8) x 10-* Softening point, F.................................................................... 190 230 Distortion under beat, F. (A.S.T.M.) .................... 170 180 Tendency to cold flow ...................................................... Slight Volume resistivity, ohm*cms. (50% R. H. and 25C.)..................................................................................... 10*t . iota Dieletric strength, short time, V3 in. thickness volts/mil..........................................................................500 700 Dielectric constant, 60 cycles...................................... .. 2.5 2.6 Dielectric constant, 10s cycles........................................... 2.5* 2.6 Dielectric constant, 10* cycles........................................... 2.5 2.6 Power factor 60 cycles............................................................ 0.0001 0.0002 Power factor 10* cycles......................................................... 0.0001 0.0002 Power factor 10* cycles......................................................... 0.0001 0.0004 Water absorption, immersion 24 brs............................... 0.00 Burning rate................................................................................ Moderate Effect of age................................................................................. Very slight Effect of sunlight..................................................................... Yellows slightly Effect of weak acida and strong acids............................None Effect of weak alkalia andatrongalkalis......................None Effect of organic solvents......................................................Soluble in aromatic and chlorinated hydrocarbons Machining qualities..................................................................Fair to good (Continued) Page 98 MONSANTO CHE MIC A I r 0663638 P L A S T IC S Color possibilities Effect od metal inserts Unlimited .None Available Literature: 16-page booklet "Lustron--A Monsanto Plastic." Trade Mark Reg. U. S. Pat. Off. "NITRON"* (Cellulose Nitrate Sheets, Rods, Tubes)_______ Nitron is a cellulose nitrate plas;:ic which continues as the most suitable material for many exacting uses such as drawing instruments, fountain pens, tool bandies, tooth brush handles, heel coverings, watch and instrument crystals. The raoge of colors and special effects obtainable in Nitron plastics is unlimited. It is easy to fabricate and can be molded, drawn, or blown. Mechanical Properties! Specific gravity.......................................................................... 1.3S 1.40 Specific volume, cu.in./lb......................................................19.8 20.5 Refractive index No ..............................................................1.50 Ultimate tensile strength, lbs./sq. in...............................5,000 10,000 Elongation, %............................................................................ 10 * 40 Modulus of elasticity, in tension lbs./sq. in................ 200,000 400,000 Impact strength, Charpy, ft. lbs /in. of notch (A.S.T.M.)..................................................................... 3-12 Brinell hardness, 2.5 m.m. ball, 10 kg. load................8*11 Rockwell hardness.................................................................. M25 M60 Machining qualities.................................................................Very good Molding Properties! Type.............................................................................. Molding quality....................................................... Compression molding temperature................. Compression molding pressure, lbs./sq. in. Preforming................................................................. Tendency to cold flow........................................... Molding methods applicable.............................. . Thermoplastic . Good . 185 * 250F. .100.500 . Very good . Slight . Swaging, shearing, blowing-- All very good Thermal Properties! Burning rate...................................................... .........................Rapid Thermal conductivity, B.T.U./br./sq. ft./F. temp. diff./in. thickness........................................................0.90-1.48 Specific beat, calories/C./gram............. .........................0.34.0.38 Thermal expansion, 10--&/F.................... .........................6.5-8.9 Resistance to heat, F. (continuous).. ......................... Approximately 140 Softening point, (A.S.T.M.) ............... .........................160 195F. Decomposes at 272F. in 30 minutes Effect of best, dry ....................................... .........................Discolors on continued heat ing at 212F. Electrical Properties! Volume resistivity ohms-cms. (50% R. H, and 25*C.) ................................................................ (2-30) xl0* Dielectric strength, 60 cycles, volta/mil........................600 1,200 (Continued) 26TH BDITION Page 99 0683839 -PLASTICS- Dielectric constant, 60 cycles.................. Dielectric constant, 10 cycles................ Power factor, 60 cycles................................ Power factor, 10 cycles............................. Chemical and Physical Properties! ()dor...................................................................... Taste..................................................................... Effect of age.................................................... Effect of sunlight......................................... I .fleet of ultraviolet tight......................... (''fleet of weak mineral acids.................. Effect of strong acids................................. Effect of weak alkalis................................ Effect of strong alkalis.............................. Water absorption 24 hours immersion Effect of hot water........................................ Effect of cold water....................................... Effect on metal inserts................................ Solubility! Soluble in................................ Insoluble in 6.T 7.3 6.2 0.06 0.15 .0.07 0.10 . None or camphorous .Tasteless to slight .Slight hardening . Discolors and becomes brittle . Yellows and decomposes on extended exposure . Good resistance . Poor resistance, decomposes . Very slowly decomposes Decomposes .0.6 -2.0% Softens, slight shrinkage None . None . Alcohols, ketones, esters Aromatic and aliphatic hydrocarbons, mineral, animal and vegetable oils. Colon Available in an extremely widt variety of transparent, crystal, translu cent, pastel and opaque colors,, as well as in many mottles, pearls and ornamental configurations. Format Available in sheets, rods, tubps and special shapes. Trade Mark Reg. U. S. Pat. Off. "OPALON"* (Cast Phenol-Foi raaldehyde) A cast phenol-formaldehyde resin. Oplon is noted for its beauty and the ease with which it can be fabricated, together with the ability to take a bigh and lasting polish. Special shapes and castings can be produced with low investment in molds. The size of casting ranges front handles for brushes and razors to large parts for coin machine housings, and complete radio cabinets. Restrictions on raw materials now limit the use of Opalon to essential civilian needa and to military applications. Mechanical Properties! Specific gravity........................................................................... 1.27 1.32 Specific volume, cu. in./lb..................................................... 20.0 21.8 Refractive Index Np...................................................1.5 1.7 Tensile strength, Ibs./sq.in....................................................5,000 12,000 Elongation..................................................................................... Very Slight Modulus of elasticity, )bs./sq.in.xl0*.............................5-15 Compressive strength, lbs./sq.in........................................15,000 30,000 Impact strength, Izod ft. Ibs./in. of notch (A.S.T.M.) ....................................................................... 0.1 0.4 Brinell hardness, 2.5 mm. ball, 25 kg. load...............30-45 (Continued) Page 100 MONSANTO C8BMICALS 0683640 Rockwell hardness...................................................................M80 M130 Machining qualities.................................................................. Excellent Shrinkage, % ............................................................................. 0*1 Molding Properties: Tvpe.................................................................................................Thermosetting, non-moldable Thermal Properties: Burning rate............................................................................... Will not support combustion Thermal conductivity, 10""4 calorie^/second/sq.cm C. cm............................................................................ 3*5 Specific heat, calories/C./gram................. ......................0.3 0.4 Thermal expansion, 10-5/C.............................................. 2.8 Resistance to heat, F. (continous)................................. 160 Effect of heat, dry .................................................................. Hardens slowly moist......................................................... .. Whitens Heat distortion........................................................................... Above normal temperatures Electrical Properties: \ olume resistivity, obms-cms. ($0% R.H. and 25C)..................................................................................10 - 10i Dielectric constant, 60 cycles.............................................. 5-10 10 cycles...........................................5.0 7.0 Power factor, 60 cycles.........................................................0.025 0.20 105 cycles...................................................... 0.005 0.08 10 cycles...................................................... 0.01 -0.045 Chemical and Physical Properties! Odor....................................................................... Taste..................................................................... EfTect of age...................................................... Effect of sunlight........................................... Effect of ultraviolet light........................... Effect of weak acids...................................... Effect of strong acids................................... Effect of weak alkalis................................... Effect of strong alkalis................................ Water absorption, 24 hours immersion Effect of hot water........................................ Effect of cold water...................................... Effect on metal inserts................................. Solubility: Insoluble in-- .......... .. . None None . Hardens slightly . Yellows slightly on exposure Some colored materials fade .Yellows slightly on exposure Some colored materials fade . None or slight . Decomposed by oxidizing acids. Reducing and organic acids have less effect .Slight to marked, depending on alkalinity . Decomposes .0.01 -0.5 . Softens and whitens . None .Inert . Most organic solvents, alco* hols, ketones, esters, aro matic and aliphatic hydro* carbons, mineral, animal and vegetable oils Color: Available in an extremely wide variety of transparent, crystal, trans* lucent, pastel and opaque colors, as well as in many mottle# and orna mental configurations. Form: Available in sheets, rods, tubes and a very extensive variety of cast shape# and objects. Trade Mark Reg. VS. Pat. Off 26TB EDITION Page 101 0663841 LEXOLDMON005771 PLASTICS- "RESINOX"* (Phenol Formaldehyde Molding Compounds.). Over a period of years the range of Resinox molding materials has grown to encompass almost every important industrial demand. Shortages of metals and the extremely exacting requirements of the natioo's armed forces have stimulated the development of new types of Resinox materials having particularly high impact strengths. Since fillers vary I be properties of Resinox, the following table gives the range attained by the most common fillers of wood flour, cut fabric, cotton flock, mica and asbestos. Molding quality......................................................................... Fair-excellent Compression molding temperature, "F........................... 290 400 Compression molding pressure, Ibs./sq.in.......... 2000 4500 Compression ratio (bulk factor)........................................ 2.02 10.0 Mold shrinkage, inches per inch.......................................... 004 - .010 Specific gravity........................................................................... 1.34-1.75 Specific volume, cu. in./lb..................................................... 13.3 . 22.2 Tensile strength, Ibs./sq. in.................................................. 4200 9500 Modulus of elasticity, Ibs./sq. in x 10*......................... 8 45 Compressive strength, Ibs./sq.in........................................ 20,000 35,000 Flexural strength Ibs./sq. in................................................. 8,000 - 15,000 Impact strength, ft. lbs./in. of notch, Izod (A.S.T.M.)..................................................................... 0.26-4.00 Rockwell hardness..................................................................... M85 M125 Thermal conductivity, 10~ cal./sec./sq.cm./C./ cm........................................................................................ 3-20 Specific heat, cal/C./gram................................................. 0.25 0.36 Thermal expansion, 10-- */C.......................................... 2.0 7.5 Resistance to heat F. (continuous)................................ 225 450 Softening point, F....................................................................None Distortion under heat F....................................................... 240 285 Tendency to cold flow............................................................ None Volume resistivity, ohm-cms. (50% R. H. and 25C.)........................................... 10 - 10> * Dielectric strength, short time, volts/mil, in. thickness............................................................ 250 500 Dielectric strength, step-by-step, volts/mil, Vi in. thickness............................................................ 200 - 400 Dielectric constant, 60 cycles............................................. 5-20 Dielectric constant, 10* cycles........................................... 4-20 Dielectric constant, 10* cycles........................................... 4.5-20 Power factor 60 cycles............................................................ 0. 04- 0.30 Power factor 10* cycles..........................................................0.04 0.20 Power factor 10* cycles..........................................................0.005 0.10 Water absorption, immersion 48 hours (%)............... 0. 01 1.5 Burning rate.................................................................................Very low Effect of age................................................................................. None Effect of sunlight....................................................................... Light shades discolor Effect of weak acids.................................................................. None to slight Effect of strong acids...............................................................Decomposedby oxidising acids Effect of weak alkalis ............................................................Slight to marked Effect of strong alkalis.................................................... Decomposes Effect of organic solvents...................................................... None on bleed-proof materials (Continued) Page 102 Monsanto chemicals LEXOLDMONOQ5772 P L A S T IC S Machining qualities.................................................................Fair Color range......................................................................... Limited Available Literature: 12-page booklet "Resinox--A Monsanto Plastic." Trade Mark Reg. U. S. Pat. Off. "SAFLEX"* (Laminating Plastic) __ Saflex is a polyvinyl acetal sheet plastic used as the interlayer in making "HiTest" laminated safety glass. The Saflex plastic 6heet, .01$ gauge, acts as the bonding agent holding the two sheets of glass firmly together and prevents scattering of the glass in case one or both surfaces of the glass are broken. The tough, elastic Saflex interlayer gives full protection at all temperature ranges encountered in winter or summer driv ing. For military vehicles and aircraft, multiple-layer laminations of Saflex and glass give protection against small-caliber bullets, bomb or shell fragments and flying debris. Trade Mark Reg. U. S. Pat. Off "VUELITE"* (Embossed Fluorescent Lighting Shields)_______ Vuelite is the trade name for embossed cellulose acetate, developed by Monsanto to serve as diffusing panels for fluorescent lighting fixtures. Glare and brightness are eliminated by a suitable design that spreads the light evenly. Tbe excellent light transmission factor of tbe material assures highly efficient light distribution. Although a fluorescent fixture may be large in size, tbe addition of a Vuelite diffusing panel adds very little to its weight thereby allowing the design of a lowweight fixture. Tbe danger of breakage of Vuelite as compared with glass of tbe same size is very small. Vuelite is easily formed to shape Fixtures that require more than a six-inch radius are fitted with diffusing panels by slipping flat sheets into position. Smaller sizes and intricate shapes are formed without expensive molds or tools while punching, drilling aod cutting opeiations are carried out with ordinary tools. Vuelite sheets are 20'x SO' in size, available in tbe following designs: Number 4B 6B 8B 9B 20B 27B 42B 44B Name "H'* Line Whipcord Silk Cobra Large Cube Mesh Axtee Glow Worm Limiting Gauge Not Under .050* ,040' .030' .050' .030' .030' .040' .040' (Continued) Direction of Size Design 20x47 Lengthwise 20x47 Lengthwise 20x49 Lengthwise 20x47 Lengthwise 20x47 Both ways 20x49 Lengthwise 20x49 Crosswise 20x49 Lengthwise 26TB EDITION Page 103 0683843 PLASTICS 54B 55B 65B Sahara No. 5174 Large Crackle .0W)* .050* .040* Trade Mark Reg. t. S. Pat. Off. 20x47 20x47 20x49 Both wavs Both ways Both ways "VUEPAK"* (Rigid Transparent Packaging Material) Vuepak is produced as a clear transparent sheet plastic in continuous length rolls HI'o inches v>idr. It is extensively used in the manufacture of durable rigid transparent containers, packages and displays for all types of consumer goods products. Originally used chiefly for luxury items. Vuepak containers have now become a successful packaging medium for food products, candies, household appliances, beverages and dry bulk products of all types. An im* portent contributing factor to the broader use of Vuepak containers has been the improved efficiency of fabricating equipment and techniques in the plants of the more than two hundred firms now established as Vuepak fabricators. The properties of Vuepak are covered by the properties of Fibestos cellulose acetate materials in the preceding table. Standard gauges of Vuepak are .005", .0075*, .010*, .0125*. .015* and .020*. In addition to continuous length rolls, Vuepak is sold in standard size sheets or in pieces cut to order. Vuepak can be drawn, scored, beaded, folded or stitched. With suitable inks the surface of Vuepak can be readily piinted in one or more colors. For special requirements Vuepak containers can be made with metal bottoms and lids or in combinations with box-board, paper, wire frames or wood. -- `Trade Mark Reg. U. S. Pat. Off. POLYSTYRENE (See Plastics, Lustron). POLYVINYL ACETAL SHllET (See Plastics, Salfei). POTASSIUM AMMONIUM PHOSPHATE (Also known as potassium ammonium phosphate; ammonium potassium phos phate.) KNH4H4(P04), Mol. Wt. 251.128 Standard Formt White crystals. Grade i Technical crystals. Page 104 (Cohtinued) Monsanto chemicals 06838^ R.R. Classification: Potassium Salts NOIBN. General Information: Used in pharmaceutical products for special medicinal purposes, and in the fermentatioi of *ines. POTASSIUM AMYL XANTHATE It.It. Classifiestion: Potassium \amhate. General Information: Flotation agent used principally in the mining industry. POTASSIUM ETHYL XANTHATE R.R. Classification: Potassium Xantbate. General Information: Flotation agent used principally in the mining industry. POTASSIUM GLYCEROPHOSPHATE (75% SOLUTION) (See Glycerophosphates). POTASSIUM PHOSPHATE, DI _ KiHPO, Mol. Wt. 171.18 Standard Form: 60% solution in water. Typical Analysis: Bluish, odorless liquid: sp.g. 1.7 at 25C.; 14.6 lbs. per gal.; pH 9.9 10.3: viscosity 33 centipoises at 25C.; water solubility 71 grams per 100 gms. solution. R.R. Classification: Chemicals, NOIBN. General Information: Used as a.a antistatic agent for wool and in fermentation and nutrient solutions. POTASSIUM PHOSPHATE, MONO (Also known as potassium diphosphate and potassium bipbosphate). KH,P04 Mol. Wt. 136.09 Standard Form: White crystals. Grades: Technical containing about 0.50% SOj; sulfate*free containing about 0.01% SO,. (Continued) 26TB EDITION Page 105 0663645 LEXOLDMONOQ5775 K.R. Classificationi Potassium Salts. General Information: Used to control pH of culture media and for special medicinal purposes. POTASSIUM PYROPHOSPHATE, TETRA K4P20, Mol. Wi. 330.34 Properties: White powder, hygroscopic in air: pH value in 1% solution at 25 '( 10.6: solubility. 190 grams in 100 grrms water at 25C. R.K. Classification: Cleaning Com|<ound. General Information: t'sed for incorporation in textile oils and soapa to increase emulsifying values and to prevent formation of insoluble bard water soaps; as clarifying agent and to improve cleansing action of soaps. POTASSIUM SALICYLATE (See Salicylatee). n-PROPYL PHOSPHORIC ACID (See Alkyl Phosphoric Acids). PYRIDINE, pure waterwhite liquid; used as a solvent and chemical reagent; as a denaturant for alcohol, and in special medicinals; made by Monsanto Chem* irals Limited. PYROXYLIN CEMENTS (Set Celluloid Cements and Belt Cements). PYROCATECHOL __________ __________ ___________________ (Also known as brenzcatechin, catecbol or 1, 2*dthydroxy benzene). OH Mol. Wt. 114.1 Specifications: Fine white needle* (may contain a few dark specks); assay, 99.5% min.: odor, practically none; crystallizing point, 104.0C. min. Solution in cold water, (1:10): color, APHA 40,, max.; turbidity, essentially clear. Solution in alcohol (1:10): color, APHA 40, mac. K.R. Classification: Chemicals NOIBN. General Information: Used aa a developer in fur dyes, antioxidant in printing inks, and as intermediate in chemical synthesis. Page 106 MONSANTO CHBMICALS 06838*6 "R-2" CRYSTALS (See Accelerators, Rubber), REODORANTS, RUBBER Monsanto provides, but does not manufacture, the following type* of rubber reodorants for the convenience of its customers. Curodex No. 19--Pale yellow liquid; deodorizes: percent used in 100 lbs. of rubber, 0.15 - 0.20; standard package, 5 lb. bottle. Curodex No. 188--Pale yellow liquid: odor, lily; percent used in 100 lbs. of rubber, 0.20 0.50; standard package, 5 lb. bottle. (.urodex No. 198--Pale yellow liquid; odor, musk; percent used in 100 lbs. of rubber, 0.20 0.50; standard package, 5 lb. bottle. RESIN'S (See Santolites and Plastics). "RESINOX" (See under Plastics). RUBBER LACQUERS (See Lacquers). "SACCHARIN MONSANTO" Saccharin Monsanto is available in the so-called insoluble form (complies with L.S.P. requirements for Saccharin) and in the soluble or sodium form (complies with L.S.P. requirements for Saccharin, Sodium). Descriptions of both forms are given below. SACCHARIN, U.S.P_______ ___________________________________________ (Also known as saccharin insoluble; ortho-sulfobenzimide). O-L NH V 0, Standard Form t Powder Mol. Wt. 183.11 Specifications: Vhite crystalline powder: assay 98% min.; m.p. 227.0C. min.; loss of drying 0.50% max., solubility in 10% NajCOj(l:5) complete. R.R. Classification i Chemicals NOIBN. General Information Saccharin has approximately 500 times the sweetening power of sugar. Used as a sweetener in tooth pastes, mouth washes, and phar maceutical preparations, and in beverages and foodstuffs in place of sugar for diabetics. 2ATR EDITION Page 107 0683847 SACCHARIN. SODR.M, U.S.P. (Also known as soluble saccharin; sodium ortho-sulfobenzimide). [ '-C^NN,2H,0 v-f,r Mol. Wi. 211.13 Standard Format Crystals; powder. Specifications! %hite crystals or j-owder; solubility in water (1:8), complete. Loss on drying at I25C.: crystals U.0% rain. --14.35% max.; powder. 5.3% min. --5.8% max. K.K. Classification! Chemicals NOIBN. General Information! See under Saccharin, U.S.P. "SAFLEX" (See Plastics). SALICYLATE, AMMONIUM _ COONH* OH Mol. Wt. 155.08 Standard Formt Powder, 80 mesh. Specifications! White crystalline powder; assay, 98.0% min.; solubility in water (1:5), complete, colorless; solubility in etbyl alcohol 95% (1:15), complete; con* forms to N. F. test for heavy metals. No powder retained on 80 mesh screen. R.R. Classification! Chemicals NOIBN. General Information! Pharmaceutical product. SALICYLATE, CALCIUM _______________________________________ Mol. Wt. 314.16 Standard Formt Powder. Specificationsi Fine white powder; solubility in water (1:50), complete, colorless; free salicylic acid. 0.25% max.; conforms to U.S.P. test for heavy metals, R.R. Classification! Chemicals NOIBN. General Information! Pharmaceutical product. Page 108 Monsanto chemicals 0663848 LEXOLDMONOQ5778 Pilot plant operation at St. Louis plant. SALICYLATE, LITHIUM, N.F. COO Li OH Mol. Wt. 143.98 Standard Forms Powder. Specifications! White or slightly grayish powder; assay 98.5% mm.; solubility in water (1:20), complete, colorless; conforms to N.F. test for heavy metals. R.R. Classifications Chemicals NOI8N. General Information! Pharmaceutital product. SALICYLATE, MAGNESIUM Mg Mol. Wt. 298.54 Standard Form 2 Powder. Specifications! Fine white powder; solubility in water (1:10), complete; con forms to L'.S.P. test for heavy metals. R.K. Classification! Chemicals NOIBN. Ceneral Information! Pharmaceutict-1 product. 26TR EDITION Page 109 06838<i9 LEXOLDMONOQ5779 SALICYLATE, METHYL, U.S.P. COOCH, 0OH Mol. Wt. 152.14 Standard Form: Liquid. Specifications: Clear, colorless liquid, assay 98.0% min.; solubility in 70% ethyl alrohol (1:7), complete; solubility in N KOH (1:10), complete; sp. g. 25/2S9C., 1.180 1.185; free phenols, 0.010% max.; conforms to U.S.P. test for heavy metals. II.R. Classification: Oil of Wintergreen. General Information: Used as a pharmaceutical product, as a flavoring agent in foodstuffs and beverages, and as at) odorant in printing inks and insecticides SALICYLATE, PHENYL, U.S.P. (Salol) Mol. Wt. 214.21 Standard Forms: Crystals; powder, 80-mesh. Specifications: White crystals or powder; solubility in ethyl alcohol 95% (1:6), complete; m.p. 41.0C. min.; conform* to U.S.P. tests for chloride, sulfate, free acid, free phenol, and free salicylic acid . 1.0% max. retained on 80 mesh screen. H.R. Classification: Chemicals NOWN. General Information: Pharmaceutical product. SALICYLATE, POTASSIUM. COOK nOH Mol. Wt. 176.21 Standard Form: Powder. Specifications: White or very slightly pinkish powder; assay (dry basis), 99.0% min.; solubility in water (1:10), complete; conforms to U.S.P. test for heavy metals; free alkali, negative. K.R. Classification: Chemicals NOIHN. General Information: Pharmaceutical product. Page 110 MONSANTO CHEMICALS 0683850 SALICYLATE, SODIUM, U.S.P. COONa OOH Mo). Wt. 160.11 Standard Forms: Powder, crystals. Specifications: White powder or crystals: assay (as received) 99.5% min.: solubility in \ater (10:100), complete, APHA 15 max.: solubility in ethyl alcohol q5% (1:10), complete, colorless; conforms to U.S.P. tests for heavy metals and rarbonizable impurities: trace max. ponder retained on 60 mesh screen, 1.0% on 80 mesh screen, 2.0% on 100 tnesb screen. R.R. Classification i Sodium Salts. General Information: Pharmaceutical product. SALICYLATE STRONTIUM, N.F.-____________________ Sr . 2H.0 Md. W,. 397.74 Standard Form: Powder. Specifications: White crystalline powder; assay (as dihydrate), 99.0% min.: solution in water (1:20), complete; conforms to N.F. test for heavy metals and barium. R.R. Clasaificatlons Chemicals NOIBN. SALICYLIC ACID, (Ortho-Hydroxybenzoic Acid). COOH OH Mol. Wt. 138.05 Grades: U.S.P. and Grade. Specifications of U.S.P. Grade* White needles or powder, 100-mesh; assay 99.5% min.; m.p. 158.0eC. min.; conforms to U.S.P. test for carbonizsble sub stances; asb 0.05% max.; powder trace, max. retained on 100-mesh screen. Specifications of "B** Grade: White needles; assay 98.75% min.; m.p. 158.0C. at start. (Continued) 26TB EDITION Page 111 0683851 H.R. Classification; Salicylic Acid. General Information: Ised in the manufacture of medicinals and dyestuffs, as an industrial preservative and as an intermediate in many organic syntheses. SALOL (See Salicylate, Phenyl). SALT CAKE (Sodium Sulfate, Technical) . Na,S04 Typical Analysis! 94 95% Naj$04 available. R.R. Classification t Salt Cake. General Information: Used in (he manufacture of sulfate pulp, glass, sodium sulfide, and for treatment of boilei feedwaters. "SANTAMINE"___________________________________________ _ Characteristics: White powder, readily soluble in water, will not decompose oo standing if kept in clean dry place. R.R. Claaaificationt Disinfectant Other Than Medicinal NOIBN. General Information: Santamitte is a sterilizing and deodorizing agent de veloped especially for the dairy industry, where it is used in water solution for washing utensils, equipment and bottles as well as the udders and teats of the cows. It also finds use in other industries where an efficient chemical sterilizing agent is required. It contains no poison or acid and will not barm rubber or metal. "SANTICIZER 8"________ _____________________ (Mixture of ortho* and para.toluenp ethyl sulfonamides). /--------\ 0H NI Mol. Wt. 199.26 Specifications! Light yellow, viscous liquid; odor, slight, characteristic; free amide, 9% to 13%; acidity (at acetic acid) 0.1 % max. R.R. Classification! Lacquer Solvents NOIBN. General Information! This plasticizer is readily miscible with all common organic solvents except the petroleum hydrocarbons in which it is only very 'Continued) Page 112 MONSANTO CHEMICALS 0663652 blightlv soluble. It is soluble in castor oil. slightly soluble in china wood oil and insoluble in linseed oil. In watet it id soluble to the extent of about 0.13% at 23C. and 0.21% at 48C. Its solubility in water is decreased by the presence of ammonia but is increased by other alkalies. Its retentivity in acetyl cellulose is about 90 parts by weight to 100 of acetate, and it imparts a high degree of plasticity. It is a solvent for both nitrocellulose and acetyl cellulose. Santirizer ti is an excellent plasticizer for cellulose acetate, giving a brilliance and polish not obtainable with other plasticizers. This product, being practically insoluble in petroleum hydrocarbons, is a valuable plasticiser for coatings designed to withstand gasoline and related products. Santicizer 8 has some plasticizing action on such protein compounds as casein, glue, soybean protein and corn protein. It may be used alone or in conjunction with other materials such as glycerine or similar compounds. Santicizer 8 greatly increases the flexibility of isheilac, having at the same time a considerable softening effect. Available Literatures 40page bmklet, "Plasticizers and Resins'*. "SANTICIZER 9" _______ ____________ (Mixture of ortho and para-tolueaesulfonamides) OH HI -- S-N--H OO Mol. Wt. 171.16 Specifications: Fine granular particles; m. p. 105C. min.; melt, clear and light vellow; aciditv, pH 4.6 min. in dilute acetone (2 gram sample in IS cc A. R. Acetone and 35 cc of COj free distilled water). R.R. Classification: Lacquer Solvent NOIBN. General Information: Solubility of this plasticizer is quite low in coal-tar hydrocarbons and negligible in p<troleum hydrocarbons. It is readily soluble in most other solvents, and in hot linseed, china wood, and caster oils. It is soluble in water to the extent of only about 1.0% at 3-lC., but this is increased by the presence of alkali. It is the least soluble of the Monsanto plasticizers in ethylene dichloride and in benzene, its solubility in ethylene dicbloride being about 4% at 30C. and in benzene about 1.5% at 30C. Santicizer 9 differs greatly from other plasticizers in its action. Relatively small amounts impart a gloss to polished articles and give smooth working and uniform curing of molded products. It blends readily with most synthetic resins and does not impart the softening action of liquid plasticizers. It is particularly valuable to tbe makers of molding compositions. In some phenol-aldehyde resins it appears to act not only as a lubricant but also as a promoter, giving more uniform and thorough curing. In amounts of about 20 parts per 100, it has a temporary plasticizing action on protein compounds such as com protein and soybean protein. Available Literature: 40-page booklet, "Plasticizers and Resins'*. 26TH EDITION Page 113 0683053 "SANTICIZER E-15" (Ethyl Phthalyl Ethyl Glycollate)_____ o0 /X II 11 j 1 ~ C ~~ O CH* C 0 C,H* )l --C --O --CjH* ^ II u Mol. Wt. 280.13 Specification#: Color, (APHA), 20 max.; sp. g. at 25P/2S'C., 1.1800.005; refrac. index at 25C., 1.498 0,002; acidity (as acetic acid) 0.02% max.; odor, slight; sulfur (copper strip test), negative. It.lt. Classificationi Lacquer Solvert NOIBN. General Information! This plasticizer is miscible with the common organic solvents except the petroleum hydroc arbons. It is miscible with vegetable oils when heated but partially separates oih cooling. Its solubility in water is 0.0175% at 30C. Santicizer E-15 is a solvent for both nitrocellulose and acetyl cellulose md for most resins. It is lightest, and does not evaporate even from the thin* nest films. With both acetyl and nitrocellulose it gives clear, tough, flexible films which have greatly increased (esistance to moisture penetration. It is highly recommended for use with cellulose acetate and vinyl resins. Available Literature: 40-page booklet, "Plasticizers and Resins'*. "SANTICIZER B-16" (Butyl Phthalyl Butyl Glycollate)____ O -- CHj --C -- 0*-C*H -C --O--C(H* II o Mol. Wt. 336.19 Specifications: Color (APHA), 45 max.; sp. g. at 25/25C.. 1.0970.005; refrac. index at 25C., 1.490 0.002; acidity (as acetic acid) 0.02% max.; odor, essentially odorless; sulfur (copper strip test), negative. R.R. Classification: Lacquer Solved NOIBN. General Information: Santicizer B-16 is a practically colorless liquid plastic izer which boils at 219C. at 5 mm. a(td does not crystallize at temperatures as low as --35C. Its water solubility i(* 0.0012% at 30eC. It is extremely lightstable. It darkena upon heating abov< 290C. Sancticizer B-16 is a solvent for nitrocellulose and is compatible with most resins, imparting good flexibility. It probably embodies more desirable properties (Continued) Page 114 MONSANTO CHEMICALS 0683854 than any other single nitrocellulose plasticizers, lire retarding action being about the only property it does not have. Santicizer B-16 ia a solvent for and imparts plasticity to many resins both synthetic and natural. It has especially interesting properties when used with resins of the glycerol-pbthalate and phenol-aldehyde tvpes in which is may be incorporated at various stages of resin formation. It is miscible with castor, linseed and china wood oils and somewhat retards gel formation in the latter on heating, it swells crepe rubber but appears to have no effect on vulcanized rubber. It is an excellent plasticizer for chlorinated rubber, from 10 to 25 parts per 100 usually being required. It is an exceptionally good plasticizer for polystyrene. Mixtures of Santicizer B-16 and Santoiite resins may he used to plasticize casein and coi'n protein. Vtailahle Literature: 40-page booklet, "Plasticizers and Resins". "SANTICIZER M-17" (Methyl Phthalyl Ethyl Glycollate) _ oo II H 'I--C-O-CHi-C - 0-C,H -C-0-CH* Mol. Wt. 266.11 O Specifications: Color, (APHA) JO max.; sp. g. at 25/25C., 1.2200.005; refrac. index at 25C., 1.5040.001'; acidity (as acetic acid) 0.02% max.; odor, slight characteristic; sulfur (coppet strip test), negative. K.R. Classification; Lacquer Sohent NOIBN. General Information: Santicizer M-17 is a solvent for both nitrocellulose and acetyl cellulose. It imparts a high degree of plasticity which is maintained undinmhed even in extremely thin films exposed to air currents for a long time. It is very light stable and may be used in transparent or tinted articles without danger of yellowing. This product is not miscible with castor, linseed, or china wood oils or with petroleum hydrocarbons but is readily miscible with other organic solvents. Its solubility in water is 0.09% at 30C. but it imparts a con siderable degree of resistance to moisture penetration to both nitrocellulose and acetyl cellulose films. Santicizer M-17 is probably the best cellulose acetate plasticizer available. It dissolves Santoiite resins, and as both are very resistant to petroleum products and compatible with so many film-forming materials, they make an excellent combination for producing gasoline resistant coatings. Available Literature: 40 page booklet, ''Plasticizers and Resina". "SANTICIZER 127" (Butyl Benzene Sulfonamide). OH HI O0 26TB EDITION Mol. Wt. 213.29 Continued) Page 115 Characteristics: Essentially colorless, oily liquid; crystallizing point --20C. (approx.); sp. g. 1.146 at 25V25C.; refrac. index 1.522 at 25eC. R.R. Classification: Lacquer Solvents NOIBN. Ceneral Information: This plasticizer is almost identical in characteristics with Santicizer 8 for which it may be substituted in most formulations. It has slightly less solvent action, lower compatibility, and is less soluble in water (0.003% at 31C.). When used with small amounts of active solvent plasticizers it produces hard but flexible and tough compositions. "SANTICIZER 128" (Ethyl Benzene Sulfonamide). 0H I! I O Mol. Wt. 185.25 CharacterUticst White crystalline solid; m. p. 51.9C.; sp.g., 1.208 at 60C. R.R. Classifications: Lacquer Solvents NOIBN. Ceneral Information i The plasticising properties of this product are of the same general character as Sancticizer It bos less compatibility and should not be used in amounts greater than 50 parts by weight to 100 parts of base plastic. Its chief value is aa an auxiliary plasticizer to be used with others in order to extend the supplies of less available materials and at the same time impart the properties of gloss, workability, etc., < haracteristtc of the sulfonamide plasticizers. "SANTICIZER 129" (Benzene Sulfonamide) O Mol. Wt. 1S7.18 O Characteristics: White crystalline solid; crystallizing point 152C. R.R. Classification: Lacquer Solvents NOIBN. General Information: Santicizer 129 is similar in properties to its toluene analog, Santicizer 9. The principal difference ia a slightly lower compatibility with most plastic materials. Sea Benzene Sulfonamide Technical for use where color is not a factor. "SANTOBRITE" (Sodium Pentachlorophenate Technical)__ Standard Forms: Powder; 1-oz. briquettes. (Continued) Page 116 MONSANTO CHEMICALS 0683856 Characteristics: Brownish gray powder; non-volatile at ordinary temperatures; practically odorless; noa-hvgros<opic under ordinary atmospheric conditions. Solubilities in water are: 4C. (39;F.) 20.8% by weight; 25C. (77F.) 26,1% by weight; 33'C. (95T.) 28.0% by weight. Santobrite is a stable, relatively un. reactive chemical and is not spent on organic matter. Its water solutions do not attack metals and under ordinary conditions do not decompose to form acid materials. It can be supplied as substantially neutral material containing from 0.2 to 0.6% free alkali or as a more alkaline product containing 3 4% alkali. (Conversion to pentachlorphenol occurs at pH's below 6.8. H.IC Classification: Agricultura Insecticide or Fungicide N'OIBN. General Information: A water-soluble industrial preservative and fungicide. I ed lor manufacture of termite-resistant cellulose insulating board and for control of microbiological activity m paper, paperboard, leather, adhesives, latex and cold water paints; for control of sap stain in green lumber; and for control of slime and algae in water systems where the water is not used for drinking or bathing. Santobrite and its solutions are irritating to the skins and mucous membranes of many individuals and are somtwbat toxic to man and the higher animals. For detailed information on uses end methods of handling, write for literature listed below. Available Literature: Technical Bulletin No. 0-1, "Santobrite for the Preservation of Adhesives." Technical Bulletin No. 0-2, "Santobrite and Santophen 20 for Paint Preser vation." Technical Bulletin No. 0-5, "Santobrite for Microorganism Control in the Pulp and Paper Industry". Technical Bulletin No. 0-15, "Santobrite for the Control of Slime and Algae." Technical Bulletin No. 0-17, "Santobrite for the Preservation of Rubber Latex." Technical Bulletin No. 0-19, "Santobrite in the Tanning Industry." Technical Bulletin No. 0-22, "Santobrite--Methods of Handling and Applica tion." "Sap Stain Control by Monsanto" (24 page booklet). "Preservation of Cellulose Insulating Materials by Monsanto" (24 page booklet). "Instructions for Handling Santobrite." "SANTOCEL" Standard Form: Light weight porous solid. Properties: Santocel is silica gel frc-m which the water has been removed by a process which does not destroy the original gel structure. Apparent density 7.5 jbs. per cubic foot; bulking value in liquid 17.1 lbs. per gal. Typical Analysis: 26TB EDITION SiO, Volatile Sodium Sulfate FejOj and AljOj 90% 5.5% 3.5 1. {Continued) Page 117 Types: (1) Santocel 45, high oil absorbing. (2) Santocel 58, low oil absorbing. (3) Santocel "O", designed lor use as a thermal insulator. All b<ut Santocel "O" are vthite and translucent. rades: The three types are each available in 1two grades. Fine and All Size. Thru 20 40 60 80 100 200 Fine APPROXIMATE MESH On 20 m.?sh 7% Thru 40 60 80 100 200 6% 12% H% 9% 28% 3 6 10 20 40 2?% 60 100 All Size On 3 mesh 20.7% 6 20.7% 10 17.2% 20 H.7% 40 13.0% 60 4.2% 80 2-5% 7.0% K.R. Classificationi Insulating Material NOIBN. General Informations Santocel 45 and Santocel 58 are used principally as (1) Flatting agents for paints, varnishes and lacquers. (2) Thickening :ents for volatile and nonvolatile liquids; particularly useful in printing ink >) Anti* caking agents. (4) Dry dispersing agent for pigments and dyestuffs. (5 >uroe of highly reactive silica. (6) Stiffening agent in crepe rubber. Santocel "O'* is designed for use as a thermal insulation material. "SANTOCHLOR" (para-Diohlorobenzene) (Also known as 1, 4-dichlorobenzene) Cl Mol. Wt. 147.00 Cl Characteristics: White crystals; crj stallizing point, 52.8C. min. Standard Crystal Sices: No. 2. (large)--For shaker top cans. No. 5 (small)--For peach tree borers and for insecticide and miscellaneous uses. No. 34 (medium)--A combination of two uniformly sized crystals. For shaker top cans and for compressing into cakes. K.R. Classification: Paradichlorobettzene. General Information: Para-dichlorobenzene is used as an intermediate in the production of dyestuffs; as a deodorant; mothicide, larvacide, and in control of peach tree borers. (Co/Uinued) Page 118 MONSANTO CHEMICALS 0683858 Available Literature: 3 page Technical Bulletin No. 0*18, "Santochlor for the Control of Peach Tree and Stone Fruit Borers." 'SANTOCURE" (See under Accelerators) 'SANTOFLEX B*' (See under Antioxidants, Rubber), S.WTOFLEX BX" (See under Antioxidants. Rubber). "SANTOLITE BA" almost identical in properties with Santolite MS. of w hich it is the benzene analog. SANTOLITE BH," almost identical in properties with Santolite MHP, of which it is the benzene analog. "SANTOLITE BK," almost identical in properties with Santolite K, of which it is the benzene analog. "SANTOLITE BK5M almost identical in properties with Santolite K5, of which it is tbe benzene analog. "SANTOLITE K" Specifications! Clear, light yellow sticky resin; color, not more than No. 2.5 by Monsanto Santolite K Standard (comparable in depth of color but not in shade to No. 5 of the Gardner 1933 staodard); acid number, 10 max.; refractive index at 50C., 1.5330 to 1.5390. R.R. Classification! Synthetic Resin. General Information! Santolite K is a resinous condensation product of toluene sulfonamide, formaldehyde, and alkyd resins. It is a soft sticky resin with the qualities of both tbe sulfonamide and alkyd types. It is compatible with cellulose esters sod ethers. Santolite K hae plasticizing properties itself but for most purposes additional plasticiser is desirable and Santiciser M*17 is recom* mended, although others may be ysed advantageously. Santolits & ia soluble in practically all common organic solvents except the petroleum hydrocarbons. It is not compatible with drying oils so cannot be used in oil Tarnishes. Santolite K hae a better light stability than the other Ssntolites and ia of special value for increasing the resistance to moisture penetration of cellulose ester compositions. Available Literature! 40>page b;x>klet, "Plasticizers and Resina." 26TB EDITION Page 119 0683859 SANTOLITE K5"___ General Information: A moderation f yaniolite K having the same general rhararteristics except that it is harder. "SANTOLITE MHP" Specifications: Hard, practically colorless resin; refractive index (25 grams in "> jirarns normal Hntyl Acetate), (.4280 to 1.4310; penetration, (200 gram load for 5 seconds at 25C.) 2.0 mm. max. H.H. Classification: Synthetic ftesin. General Information) SantoliU MHP is an aryl sulfonamide-formaldehyde resin and is similar to Santolite VIS in characteristics, except that it is much harder, softening at about 628C. and being brittle at normal temperatures. It is nearly colorless and is well adapted to specialty lacquers, fabric coatings, molding compositions and the like. Being incompatible with drying oils it cannot be used as a varnish material. Exceptional features of this resin are the ease with which it may be worked into practically any formula using a cellulose ester and the wide variation of properties obtained by its use. Its bigb degree of solubility makes very concen(rated solutions possible, and its extreme compatibility with plasticizers and cellulose esters removes much of the danger of blushing, sweating and separation. Santolite MHP cao be used in tpvaying, dipping or brushing lacquers to make clear, colorless, odorless coatings of good gloss and adhesion. It does not material ly increase the viscosity of the solution and permits the building up of a high solids content in the lacquer. It ia compatible with all the common plasticizer*. Available Literature: 40-page booklet. "Plasticizers and Resins". "SANTOLITE MS" Standard Forma: Viscous Resin; Solution T.B. Specifications of Viscous Resin: Pale yellow viscous resin; solution in benzene (1:5), clear; solution in benzene (4:6), no crystalline deposit in 24 hrt.; refractive index at 508C., 1.5690 1,5720; color of benzene solution (25 gma. in 50 cc.). APHA 70 maximum. Specifications of Solution TBi Light colored, viscous liquid, free flowing at temperatures above 20*C. Composition: 85% Santolite MS; 15% solvent (95% toluene and 5% butyl acetate), tolerance from 14 to 16% solvents; refractive index at 2SeC., 1.563 0.002. R.R. Classification: Synthetic Retin. General Information: Santolite MS is a soft, practically colorless reain made (Continued) Page 120 ions:xto chkuicals Looking down an aisle in one of the Monsanto warehouses. by the condensation of formaldehyde with aromatic sulfonamides. Like all the Santolites it is compatible with Doth nitrocellulose and acetyl cellulose and, being a solvent for both, it can b< used in any proportion. It forms brittle com. positions with both these esters but the addition of a plasticizer makes such combinations permanently Bexible. It is readily miscible with all the common organic solvents and thinners except petroleum hydrocarbons. It is not miscible with varnish and paint oils. Santolite MS is excellent for water-white lacquers which will not be exposed to extreme weather conditions, its high gloss and lack of color being unusual in the resit: field. Available Literature! 40-page b>oklet, "Plasticizers and Resins." "SANTOMASK" Specifications! Clear, light yellow liquid; faint vanilla.like odor; sp. g. at 2572SC., 1.04. 1.06. Additional Properties! Flash point, 210F. (by Cleveland open cup method); flow point, below 0C.; lbs. per gal-, 8.7. (Continued) 2 6TH EDITION Page 121 0683661 K.R. Classification: Chemicals NOIIjN, General Information! Odor-masking ingredient for interior paints, printing nks and similar products having objectionable natural odors. In addition to masking odors, may reduce or eliminate irritation to eyes, nose and throat caused by volatile components of some interior paints. Will not affect drying time, color durability and other characteristics of paints and inks. "SANTOMERSE" Standard Format The Santomerses are highly efficient surface active wetting agents and detergents. The Santomerse series consists of six products. Each is distinctive in character and has been developed to meet a certain industrial need. Santomerse D--neutral powder. SantomerseS--30% aqueous solution of Santomerse D. Santomerse No, 1--neutral flakes. Santomerse No. 2--alkaline flakes. Santomerse No. 3--neutral powder. Santomerse No. 3--paste (75% Santomerse No. 3 in water). R.R. Classification] Washing Compound NOIBN. General Information! The Santomerses are the salts of a homologous aeries of substituted aromatic sulfonic acids. They are used as wetting, spreading, pene trating, emulsifying agents and detergents in the following industries: textile, paper, leather, adhesive, rubber, insecticide, dust collection, soap, cosmetic, ceramic, detergent, metal cleaning, plating, emulsions, dyes, pharmaceutical, embalming fluid, laundry, steel, paint, cement, glue, felt and color, etc. Available Literature! 32 page booklet 'Santomerse". , "SANTOPHEN 7" (ortho and para-Benzyl Phenol.)________ Standard Forrai Fused solid. Specifications! Light yellow, semi-crystalline mass; faint phenolic odor; sp. g., 1.088 1.098 (55C./S5C.); refrac. index, 1.579 1.589 (55C.); crystallizing point, 40C. min. R.R. Classification! Agricultural Insecticides. General Information! Santophen 7 is used as the active ingredient in disin fectants and antiseptic formulations; as an industrial preservative and as an enhancing agent for coal tar and cresylic acid disinfectants. It is highly toxic to bacteria. CAUTION: This product istoxic. Avoid contact with the skin. Available Literature! Monsanto Technical Bulletin 0-3, "Santophen 7--A Germicide and Industrial Preservative." Page 122 MONSANTO CHEMICALS 0683862 "SANTOPHEN' 20" (Peutachlorophenol) Characteristics: Dark grayith brown flakes; chlorphenolic odor; crystallizing point, 1?5M80C.; bulking value, 45.45 lbs. per cu. ft.; dispersible in soaps and sulfonated oils. R.R. Classification i Agricultural Insecticides Other Than Liquid NOIBN. General Information: Santophen 20 is highly toxic to fungi and many bac teria and is used industrially where such growths must be prevented or con trolled. Frequently used in oil solution (See Permasan) or as the sodium salt (see Santobrite). SOLUBILITY DATA Solub; lities expressed as per cent Santophen on weight of solution Water Pine Oil 95% Ethyl Alcohol (Ethanol) 100% Ethyl Alcohol Methyl Alcohol (Methanol) Orthodichlorbenzene Stoddard Solvent No. 9 Refined Oil Gas Oil Diesel Oil Carbitol Ethylene Glycol Diethylene Glycol Benzol Cellosolve Butyl Carbitol Dioxan Diethyl Ether U.S.P. Acetone U.S.P. Linseed Oil (Raw) Tung Oil Dipentene Turpentine Carbon Disulfide Carbon Tetrachloride Glycerin 0 C. 0.00049 24.5 39.0 46.0 40.5 20 C. 0.0014 32.0 47.5 53.0 57.0 5.5 8.5 1.5 0.4 1.1 0.3 2.4 1.9 3.1 30.0 6.0 27.5 11.0 8.0 27.0 34.5 48.0 11.5 52.9 21.5 13.9 11.2 8.4 3.0 3.0 2.0 0.1 at 35C. 40 C. 0.0025 39.0 56.5 60.0 72.0 15.5 3.5 2.5 5.2 5.7 51.0 21.0 62.0 19.5 50.0 62.0 22.0 60 C. 0.0053 46.5 65.5 67.0 77.5 26.0 7.5 5.6 9.3 11.3 38.5 ii.s 65.0 37.5 Santophen 20 tod its solutions and formulations are irritating to the skin and mucous membranes and are somewhat toxic to man and the higher animals. Precautions suggested in "Instructions for Handling Santophen 20" should be observed. Available Literature: 3-page mimeographed bulletin "Santophen 20." Mimeographed bulletin "Instt-uctions for Handling Santophen 20." 26TK EDITION Page 123 0663663 "SAMOPOID S" Standard Forms Oily, homogeneous liquid Specifications: Dark brown liquid; ?p. g. 1.20 1.30; flash, (open cup method), 250T. min.; fire, (open cup method), 290 - 300F. min.; pour, below --35F, viscosity, S.U. at 1U0F.. 134.5 - 112.5 seconds. R.K. Classification: Chemicals NOIBN. General Informations Used up to 10% mixed with mineral oil to form extreme pressure lubricants for hypoid and other gears. "SANTOPOLR" Specifications: Gravity, 26.7A.P.l.; flash, 485F.; pour, 10F.: viscosity, S.U. at 210F., 156.4; carbon residue, 1.4; color, NPA (85 and 15), 6; neutralization number, 1.20. R.R. Classifications Petroleum Lubricating Oil. General Information! An improved pour point depressant for lubricating oils. Lowers tbe pour point of wax-bearing oils as much as SOT. Stable under extreme service conditions. Available Literatures Application Data Bulletin No. 120, "Santopour." "SANTOSITE" (Sodium Sulphite Anhydrous* Technical)____ Specifications! Tan to slightly pink crystalline powder; assay (NajSOj) 93.0% min.; foreign odor, very faint, max.; solution, filtrate from a 10% solution in water is not darker than APHA ISO max. R.R. Claaaiflcationt Sodium Sulphite Anhydrous. Technical. General Informations Used as a depressant in ore flotation and rubber, paper and cordage manufacture, and as a reducing agent for removing oxygen from boiler feed water. "SANTOTAN-KR" (Basic Chrome Sulfate) Containa approx. 50% of Crj(SO<)j(OH)i Standard Form: Crystals. Specifications! Dark green crystal^; solution in water (5:500), clear; baaicity (CriOs/SOj), 101-105; baaicity (Schorlemtner), 37.3%-39.7%; chromium aa CrjOj, 23.9% min. (Continued) Page 124 MONSANTO CHEMICALS 0683864 R.R. Classification: Dry Tanning Extract NOIBN. General Information: Used in chrome tanning of calf, cow, and borse bides and sheepskins. Available Literature: 16 page b.x>klet "Chemicals for the Tanning Industry." "SANTOVAR A" (See under Antioxidants, Rubber). SANTOWAX, REGULAR____________________________ ____ Standard Form: Yellow waxy solid. Properties: Boiling range: first drop, 365eC.; 80%, 402C. Freezing point: primary hold point, 140C.; secondary bold point, 56C. Apparent sp.g., 1.10 (approx.) at 2SC. Slightly soluble in alcohol and more soluble in benzene. R.R. Classification: Coal Tar Resin. General Information: Used in compounding polishes and waxes when a high melting wax is desirable. Also a plasticizer and resin. "SANTOWAX M" Standard Form: Yellow waxy solid. Properties! Micro-crystalline hydrocarbon wax of unsual stability toward heat: melting point, 83 85C.; flash point, 207C.; hardness (ASTM D-5-25) 250 gm. load, 0.23 mm. R.R. Classification! Coal Tar Resin. General Information i Used as att opactfier for paraffin candles and as a partial substitute for Carnauba wax. "SANTOWAX O" Properties! Oily, crystalline hydrocarbon; hold point, less than 50C.; flash point, 171C.; flame point, 193C. Hardness (ASTM D-5-25): 50 gm. load, 0.13 mm.; 150 gm. load, 0.40 mm.; 250 gm. load, 1.07 mm. R.R. Classification! Coal Tar Resin. General Information! Semisolid plasticizer for soft wax or resin compositions. 26TB EDITION Page 125 0683865 T "SANTOWAX P" Standard Forms Flaky crystals. Properties: Nearly white, crystalline high-melting hydrocarbon: first crystals, 209 213C.; flash point, 207C.: flame point. 238C.: hardness (ASTM D-5-25) 250 gm. load, 0.33 mm. It.K. Classifications Coal Tar Resns. General Information t Used to raise softening point and hardness of other w axes and resins. SODIUM ACETATE CHjCOONa CHjCOONa. 3HjO Mol. Wt. 82.02 Mol. Wt. 136.07 Standard Formas Crystals, 60%, >. F.: anhydrous (not N.F.) Specifications of N.F. Grades White crystals or granules: assay (as trihy drate), 99.5 104.0% solubility in w^ter (1:2), complete: alkalinity (as NajCOj), 0.025% max., conforms to N.F. te*t for heavy metals; no crystals retained on 10 mesh. Specifications of Anhydrous (not N.F.): White or grayish crystalline ma terial: assay, 99.0% min.: solubility in water (1:2), complete; carbonate (as NajCOj), 0.5% max. R.R. Classification! Sodium Acetate. General Informations Used in tbt manufacture of dyestuffs as a condensing component and buffing agent in coupling reactions; in dyeing operations as a mordant: in the manufacture of pharmaceuticals; in the soap and tanning indus tries; and as a photographic chemical. SODIUM ACID PYROPHOSPHATE (Also known as disodium dihydrogtn pyrophosphate and acid sodium pyro phosphate). NajHjPjOj Mol. Wt. 221.97 Gradeas Food and commercial. Fot>d grade meets all U. S. Pure Food Law requirements. Properties: White powder, soluble in water and having min. neutralizing value of 74; pH of 1% solution, 4.2. (Continued) Page 126 Monsanto chemicals 0663666 LEXOLDMONOQ5796 R.R. Classification: Sodium Phosphate. General Information: Used in oil well drilling muds and as a leavening agent in baking powder and flour. SODIUM ALUMINATE NaAUO, Mol. Wt. 164.2 Standard Form: White soluble powder; contains 90% soluble sodium aluminate. Properties: Readily soluble in water and extremely low in iron and insoluble material. Stable for at least 24 hours in 10% solutions although comains a max. of only 5% free caustic soda. R.R. Classification: Sodium Alumioite. General Information: Used in papermaking; With aluminum sulfate for sizing at higher pH's. Also to help se| color and filler and to improve paper formation. In treatment of municipal and industrial water: With aluminum sulfate as a coagulant. In the lime*soda soft<ning process for silica removal and floe formation. Miscellaneous: As an alkaline source of alumina in the manufacture of certain pigments, catalysts and casein paints; in processing glycerin lyes; in chrome tanning; in cleaning solutions; to aid set of the frit in vitreous enameling. SODIUM AMMONIUM PHOSPHATE (Also known as microcosmic salt; sodium ammonium hydrogen phosphate; salt of phosphorus; phosphorous salt; fusible salt of urine.) NaNHHPQ|.4H0 Mol. Wt. 209.09 Standard Formi Crystals. Properties: Transparent, white, efflorescent, monoclinic crystals. Gives off water and ammonia on heating, leaving NaPOs; contains above 32% PjOj, 7.5% NH, and 14% Na,0. Grades Commercial. R.R. Classification: Disodium Phosphate. Principal Uses: Used principally in analytics! laboratories for staodardizing uranium solution; determination of Mg and Mn; as reagent in blow pipe analysis. SODIUM BENZOATE. Mol. Wt. 144.11 26TH EDITION 'Continued) Page 127 068386? Grades) U.S.P. and Technical. Specifications of U.S.P. Grade: Thin white flakes or white powder; solubility in water (1.0:1.8 at 25C.), complete solubility in 90% etbvi alcohol (1:50), com plete; N/10 alkali or acid per 2 grain sample, 0.2 cc max.; pH 6.8 - 10.4: loss on drying at 110C., 0.50% max.; assay, 99.0% min.: chlorides (as NaCI), 0.05% max.: organic chlorine, none; sulfates (as NajSQj), 0.05% max.; nitro compounds, none. Specifications of Technical Grade: White or slightly tinted powder; assav, 99.0% min. (dry basis); solution in v, a ter (1:1.8), essentially complete but slightjv inferior to U.S.P. quality; chlorides (as NaCI), 0.6% max.; sulfates (as NajS04j, 0.6% max.: phthaiic acid, 0.1% max.; heavy metals, none. R.R. Classification: Pood Preserving Compound. General Information: Used for preserving foods, tobacco and medicinal pre parations. SODIUM BISULFATE (See Nitre Cake). SODIUM BISULFITE_____ Standard Forms: Liquid--33 B$. containing approx. 21% SOj; wt. per gal., 10.78 lbs. Anhydrous (Sodium Metabisulfite)--66% SO] (approx.) Typical Analysis: SO] NajS04 Fe Liquid 21.5% 3.00 .006 Anhydrous 66% 1.5 .002 R.R. Classification: Sodium Bisulfite Dry or Sodium Bisulfite Liquid. General Informatlont Used in dy< manufacture,as source of SO] for reducing sodium bichromate to basic chrome ^ulphate in tanning, bleaching of vegetable tan extracts, production of hydrosulfite for vat dyeing, antichlor in bleaching of groundwool, bleaching dyes out of wo:>den coloring drums used for dyeing leather, anttcblor in pulp bleaching, antichlor in laundries, bleaching of straw, rabbit fur, sugar syrups, glue, glucose. (See lablf in general data section) SODIUM FERRIC PYROPHOSPHATE NagFe.fPjO,)* . XH,0 Properties: A finely subdivided powder, insoluble in water, soluble in hydro chloric acid; contains min. of 15.5% iron. General Information: Used in foot* fortification as a mineral supplement. Page 128 Monsanto crbmicals 0683868 SODIUM GLYCEROPHOSPHATE (Sec Glycerophosphate*). SODIUM HYDROXIDE (See Caustic Soda). SODIUM HYPOCHLORITE (See Merclor). SODIUM PENTACHLOKOPHENATE (See Santobrite). SODIUM PHOSPHATE, DI (Also known as phosphate of soc'a; sodium phosphate di-bastc; secondary sodium phosphate; exsiccated sodium phosphate). NfljHPO* Mol. Wt. 141.982 Properties! Soluble in water, insoluble in alcohol. On exposure to air will absorb 2 to 7 molt HjO depending on humidity and temperature. Loses molecular water at 2408C. forming tetrasodium pyrophosphate. pH of 1% solution at 25*C.. 8.8. Onelb. anhydrousproductisequivaient to 2.5 lbs. of crystalline (dodecahydrate)* Oradest Technical, Food (Regi-lar, Granular, Powdered), Medicinal, U.S.P. R.R. Classification! Disodium Phosphate. General Information! Used in making glazes for potteries, porcelains and china ware; as an emulsifier in Making process cheese; in various chemical pro. cesses; in manufacture of dyestuffs such as Scheduler's green; in the preparation of enamels; in tinning and soldering; in leather tanning; as a bath ingredient in galvanoplastic work; in the manufacture of pigments such as cobalt phosphate; in the weighting of silk and impregnating of textiles in dyeing and calico printing; in the adjustment of condensed milk; conditioning boiler water; medicinal. DENSITY OF MONOSODIUM PHOSPHATE SOLUTIONS 2ATH EDITION Page 129 0683669 SODIUM PHOSPHATE, MONO ___ (Also known as sodium phosphate, monobasic; sodium dihydrogen phosphate; sodium biphosphate; monosodium ortho phosphate; acid sodium phosphate.) NaH,PO< Mol. Wt. 119.993 Standard Form: White powder. Properties: Contains not less than 1)8% PjOj; pH value of 1% solution, 4.5. tirades: Food: commercial. ICR. Classification: Sodium Phosphate. General Information: Used for conditioning boiler water and in electroplating. dSisuVOW-- MneUwf 0663670 LEXOLDMON005800 SODIUM PHOSPHATE, TRI ( VU<> known as normal sodium phosphate; sodium phosphate, tri-basic; tertiary sodium phosphate: T.S.P.) NajPOj. 12H}0 Mol. Wt. 380.16 Specifications! White crystalline irTaterial. uniformly sized: quickly soluble in water giving an alkaline reaction: p11 value of 1 % solution, 11.8. R.R. Classification: Trisodium Pnosphate. General Information: Used principally in cleaners and detergents for both household and industrial use. Fruit Cleaning: To remove insecticide sprays and inhibit grow th of fruit mold. Watet Treatment: For softening and conditioning water. SODIUM PHOSPHATE, TRI, MONOHYDRATE Na3PCVH20 Mol. Wt. 181.99 Standard Form: White powder. Properties- Soluble in water: one Kb. is equivalent in NajPC>4 content to 2.10 lbs. of tris<- iin phosphate crystalline. Grade: Commercial. R.R. Classification: Trisodium Phosphate. Principal Uses: Used for the same purposes as crystalline T.S.P.: in the manu* facture of compounds containing caustic soda it permits the production of dry mixtures. SODIUM POTASSIUM AMYL PHOSPHATE (Mixture of sodium and potassium salts of the amyl phosphoric acids). Standard Form: 60% solution in water. Properties: Straw colored liquid with slight Pentasol odor; sp. g. 1.339; wt. per gal. 11.2 lbs.; pH 7.0 7.3; slightly hygroscopic; anhydrous form gelatinous. 11.11. Classification: Chemicals XOIBN. General Information: Used as ingredient in vat printing pastes and as a spin ning agent for wool. SODIUM PYROPHOSPHATE, TETRA (Also known as sodium pyrophosphate, pyrophosphate of soda, normal pyro- sodium phosphate, alkaline sodium pyrophosphate and TSPP.). Grades: Crystalline and Anhydrout. Properties: White crystalline material and white granular or powder; pH value of 1% solution, 10.2. R.R. Classification: Sodium Phosphate. (Continued) 26TH EDITION Page 131 0683871 Entrance to office and laboratory building at Trenton, Michigan, plant. General Informations Used in bleaching, especially for straw, and as an ink eradicator; in manufacture of iron pyrophosphate and other pyrophosphates; household and industrial cleaner and detergent; in dye bath for putting certain types of dye in complete solution; electroplating; metal cleaning; electrolytic separation of various metals; oil drilling muds; as emulsifier in process cheese manufacture; soap builder; dtgummin); textiles. SODIUM SALICYLATE (See Salicylates). SODIUM SULFATE, ANHYDROUS NsjSO, Mol. Wt. 142.05 Typical Analysist White granular crystals; 99% Na*SO< available. For crude Sodium Sulfate, see Salt Cake. II.K. Classification! Sodium Sulfate. General Information! Differs from Glauber's salt only in sodium sulfate con tent. Glauber's salt contains 43% sodium sulfate and 56% water of crystalliza tion. Anhydrous sodium sulfate contains 99% sodium sulfate and no water of (Continued) Page 132 Monsanto chemicals 0663872 LEXOLDMON005802 crystallizaiion. I sed for diluting dry dyestuffs and in tanning. Other uses same as for Glauber s salt. For crude Sodium Sulfate, see Salt Cake. SODIUM SULFHYDRATE* NaHS Mol. Wt. 56.06 Standard Form: 33!2% NaHS, liquid. It.It. Classification: Sodium Su fhydrate. General Information: Sodium Sulfhydrate is chemically similar to sodium sulfide. Where a sulfide witb a lower caustic content is desirable Sodium Sulfhv. irate may be used. The main application for Sodium Sulfhydrate is in dehairing leather where its lower caustic alkalinity makes it more desirable than sodium sulfide for certain leathers. A lower caustic alkalinity causes less swelling of the hides or skins, thus producing leather with a finer, smoother grain. It can be said that Sodium Sulfhydrate affords a means of controlling plumping (swelling). I alike sodium sulfide. Sodium Sulfhydrate will not dehair by itself. Lime must be used with it to give a sufficiently high pH for dehairing. * Not manufactured by us, but furnished for the convenience of our customers. SODIUM SULFIDE Standard Forms: Crystals (\ajS.9HjO): concentrated--flakes.* (NatS.nHtO); liquid (20% NajS solution). Typical Analysts: Crystals, 31% Na*S; concentrated, 60-62% NajS; liquid, 20% Na,S. H.R. Classification: Sodium Sulfide. General Information: Sodium Sulfide is a salt of the weak acid, hydrogen sulfide, and the strong alkali, caustic soda, and consequently its solutions are strongly alkaline. Reacts with mtal salts to form metal sulfides, nearly all of which are colored. Reacts with aci<tv precipitating sulfur and liberating hydrogen sulfide. Ia a reducing agent, and aoiutions are ready solvents of sulfur to form polysulfides. Principal use is in tanning, to remove hair from calfskins and cowhides, and from sheepskins from which the w ool has already been removed. Other usee are in the manufacture and application of sulfur dyes, degumming of silk, denitrat ing of nitrocellulose rayon, sodium polysuifide solutions, leaching gold ore tailings, dissolving cresola from coal tar oils, boiling out linen, and depositing mineral pigments on cotton. Not manufactured by us but furbished for the convenience of our customers. SODIUM SULFITE (See Saitoeite) SOLVENTS (See Ethyl, Butyl and Amyl Acetates, Diacetone Alcohol). 26TB EDITION Page 133 0683673 SOPANOX" General Information: Sopanox is an amino compound, effective in minute quantities in restraining the oxidation of soap and the resulting rancidity, dis* coloration and other adverse qualities, all of which must be avoided in pro* dvicing a product of highest grade, Our experience shows that Sopanox satisfies the exacting demands of manufacturers of soaps produced from animal or vege* (able oils, filled or unfilled. It is particularly valuable in preventing discoloration of refined toilet soaps. K.li. Classification: Chemicals !\OIBX. Available Literature: Technical bulletin "Sopanox." "SOPET" (Sodium Potassium Ethyl Phosphate Solution)___ Mixture of sodium and potassium salts of the ethyl phosphoric acids. Standard Form: 60% solution in water. Properties: Water white liquid with slight ester odor; 11.41b. per gal.; sp. g. 1.37 at 25C.; pH 7.0 7.4 in 60% solution; viscosity, 128 centipoises at 25C. R.R. Classification: Chemicals NOIBN. General Information: Used as fiber lubricant in spinning of wool. Being water soluble* is easily removed from yarn or cloth without soap scouring. SPRAY LACQUERS (See Lacquers). SPREADING AGENTS (See Areskap, Aresket, Aresklene, Santomerse). STEEL PICKLING INHIBITORS (See Hibitite). STRONTIUM SALICYLATE N.F. (See Salicylate.)- SULFANILAMIDE, U.S.P. (para-Aminobenzene Sulfonamide) NH, Mol. Wt. 172.20 NH, Page 134 Standard Forma: Crystals, 30-mesh; powder, 100>mesh. (Continued) MONSANTO CHEMICALS 0683874 LEXOLDMON005804 Specifications: White crystals or powder; assay (dry basis) 99.5% min.; m.j>. 165.0C. min.; solution in N/2H.CI (2;30) clear; asb 6.05% max.; chlorides (as HC1) 0.011% max.; sulfate (as EUSO<) 0.04% max.; conforms to li.S.P. test for heavy metals. MESH: Retained on-- 30 mesh screen 40 mesh screen 60 mesh screen 80 mesh screen 100 mesh screen 110 mesh screen 200 mesh screen 30-mesh Trace max. 40.0% min. 75.0% min. 90.0% min. 11.H. Classification: Chemicals N01BN. 100-mesh 0.8% max. 10.0% max. 25.0% max. 20.0% min. 40.0% max. General Information: Used in pharmaceutical preparations and veterinary medicines. CALT10.\: Sulfanilamide should be administered only under super vision of a competent physician. SULFATE OF IRON (See Ferric Sulfate and Ferrisul). SULFUR 99.5% pure sulfur. Grades: Commercial rtibbermaker*. commercial flour, 90% through 80 mesh; dusting, 93*95% through 325 mesh. R.P. Classification: Sulfur. Genera] Information: Sulfur is a brilliant yellow crystalline substance, ap proximately twice as beavy as water and melting at about 248 F. This ready fusibility permits casting into various shapes. It is highly acid resisting and is a j>oor conductor of heat and electricity. It combines with rubber to form polysullides. Sulfur is used as a source of sulfur vapor for manufacture of carbon bisulfide and sublimed sulfur; as a source of sulfur dioxide for fumigation, bleaching and manufacture of sulfuric acid\ sulfiu and bisulfite for paper manufacturing; in formation of sulfides and polysulfidps for oil refining, vulcanization of rubber, smelting, and manufacture of calcium sulfide and sodium polysulfide; as an acid-resistant bonding material for brick-lined acid tanks; as a water-resistant materia) for water pipe joints; as a non-conductor for the manufacture of insu lators; as a fungicide; in manufacture of fireworks and railway signals; in grain mixtures (or poultry; as a soil disinfectant. 26TH EDITION Page 135 0683825 Converters used in manufacture of sulfuric acid at Everett. Mass, plant. SULFURIC ACID II2S04 Standard Strengths! 58 B6; 60 B6.; 66 Be.; 98% I12S0<; Oleum. Typical Analyslsi 58 B: 74.36% HjSO|j freezing point, below --40F. 60 B.: 77.67% min. HjSO^ freezing point. +12.6 F. approx. 66 B6.: 93.2% min. HjSO<; freezing point, --29 F. approx. 98%: 98.0% min. HjSO^ freezing poipt, 38 F. approx. Oleum--20% SOj: 104.50% min. HjSO<; freezing point, 22.8F. 25% SO3: 105.6% min. H2S04; freezing point, 48.7F. 35% SOj: 107.88% min. HjSO,; freezing point, 83.5F. 40% SOj: 109.00% min. HjSOi; freezing point, 91.5F. 65% SO;: 114.6% HjSO*; freezing point, 38.0 F. Oleum freetinj point data bawd on Matufactuiinj Chemists Association curve, 1941 R.R. Classification! Sulfuric Acid, General Information! Used extensively in steel mills, enameling works, oil refineries, pigment works, by-product ghs plants, fertilizer plants, tanneries, and many other industries. (See tables in general data section) Page 136 MONSANTO CHEMICALS 0683876 LEXOLDMON005806 SULFURIC ACID C.P___ HjSOt Mol. Wt. 98.07 Specifications: Colorless liquid; assay, 95.5 97.0%; non-volatile material. 0.0005% mat.; chloride (Cl), 0.(K)006% max.: nitrate (NOj), 0.0002% max.; ammonium (NH<), 0.0003% mat.; SOj, 0.0005% max.; arsenic, 0.000003% max.: heavy metals (as Pb), 0.0005% max.; heavy metals (as Fe), 0.0001% max. R.R. Classificationi Sulfuric Ac>d. Corrosive liquid (white label required). Central Informations Lsed as a laboratory reagent and where an extremely pure material is required. SULFURIC COISTACT CATALYST (See Vanadium Catalyst). SULFURYL CHLORIDE SOjCI, Mol. Wt. 134.97 Standard Form: Liquid. Characteristics! Light yellow liquid (may deposit precipitate on standing); sp.g. 15.5/15.5C., 1.67 1.71. Distilling range: first drop, 50.0C. min.; dry point, 70.0C.; 20% 100% range, 2.0C. max.; total condensation, 95% min. R.R. Classification: Chemicals NOIBN. Corrosive liquid (white label required). General Informations Used as a chlorinating and condensing agent. SYNTANS (See Mertanol). TETRAPHOSPHORIC ACID (Phospholeum) Properties: Clear, water white viscous liquid: PjOj content 83 84%; does not crystallize at --50C. Sp. g.: 2.060 at 20C.; 1.983 at lOO^C.; 1.960 at ^S^C. R.R. Classifications Phosphoric Acid. General Informations Lsed for industrial applications where a high strength phosphoric acid is desired and as t drying agent. TETRAPOTASSIUM PYROPHOSPHATE (See Potassium Pyropbos. phate, Tetra). (Continued) 26TH EDITION Page 137 0683677 TETRASODIL'.M PYROPHOSPHATE (See Sodium Pyrophosphate, Tesra). TEXTILE LACQUERS General Information t Clear and pigmented for waterproofing garment fabrics, raincoats, shower curtains, duck and balloon cloth. Can be supplied in cellulose nitrate, acetate, aceto butyrate, ethyl cellulose, and chlorinated rubber base. Applied by machine coating. R.R. Classification: Lacquers. TEXTILE PRINTING LACQLERS _ General Information: Pigmented lacquers for engraved roll and stencil print* ing on finished fabrics, cotton, silk, cilanese, rayon taffetas, crepes, and voiles. R.R. Classification: Lacquers. THINNERS General Information > Thinners are supplied for reducing all lacquer products to required viscosity for spraying, dipping, and machine coating. Can be adjusted to meet special requirements for flow out, drying time, moisture resistance, and solvent power. Retarding tbinners, cleaning thinners, stripping thinners, re movers, resins and dye solvents are also available. R.R. Classification* Lacquer Thinning Compound. THIOCARBANILIDE (See uod( Accelerators). THIOUREA_______________ _______________________________ (Also known as tbiocarbamide, sulfoearbamide, and sulfourea.) NHi.CS.NH, Mol. Wt. 76.12 Standard Form: Crystals. Specifications* White. (ree*flowing crystals; moisture 0.50% max.; ash 0.05% max.; solution (10% water at 25C.) turbid. R.R. Classification* Chemcials NOIBN. General Information* Used as an intermediate in the production of dyestuffs and pharmaceutical**, in the manufacture of vulcanization accelerators; as an (Contuui#*'1 Page 158 Monsanto cbbmicals 0683678 ingredient of insecticidal compositions; moth-proofing agent in treating furs, feathers, skins and fabrics; and as an intermediate in the production of resins and waxes. 'THILRAD" (See Accelerators) TOLUENE ETHYL SULFONAMIDE (See Santicizer 8). para-TOLUENESULFONAMIDE (Also known as poro-toluenesulfonic acid amide, para-sulfonamidotoluene, and 4-sulfonamidotoluene.) CH* Mol. Wt. 171.21 SO NH Standard Formi Crystalline powder Specifications! Light brownish, crystalline powder; crystallizing point (dried material) 135.0C. min.; ash 0.60% max.; alcohol insoluble material, 0.60% max.; loss on drying, 0.50% max. R.R. Classification! Chemicals NOIBN. General Information! Used as an intermediate in the production of active chlorine bearing compounds, as an intermediate in the production of dyestuffs, as a plasticizer, and as a base iti the production of plasticizers and resins. Also see Santicizer 9, a mixture of ortho and para*toluenesulfonatnides. para-TOLUENESULFONCHLORIDE CHi Standard Form! Crystals Characteristics> White or yellowish crystals; assay, 95% min.; crystallizing point, 65.5C. min. R.R, Classification! Chemical* NOIBN. General Information! Used at a condensing agent and an intermediate in dyestuff synthesis. 26TH EDITION Page 139 0683679 TOLIE.NESU.FOMC ACID, TECHNICAL CH, 0 Mol. Wt. 172.19 SOjH Standard Forms Fused crystsdlint mass. Characteristics: Brown to black crystalline solids toluenesulfonic acid. 85.0% min.; HjSOj, 8.0% max. Composition: approx. 85.0% para and 15.0% ortho; contains up to 14.0% water; may contain 1.0 2.0% toluene. R.R. Classification} Chemicals NOIBN. General Information: Used in tle manufacture of dyestuff intermediates and as a catalyst in certain organic reactions. TRICALCIUM PHOSPHATE (See Calcium Phosphate. Tri). TRICHLOROBENZENE, TECHNICAL _____________ C*HClj Mixture of 1, 2. 3* and 1, 2, 4-tricblorobenzene Mol. Wt. 181.45 Standard Formi Liquid. Characteristics: Practically cle*r, colorless to light yellow liquid; sp.g. 15.5e/15.5C., 1.460 1.477; acidity as HC1, 0.01% max.; crystallizing point, 1Q.0C. max. Distilling range; first drop, 20S.OC. min.; 50%, 213,0C. min.; 90%, 216.0C. min.; dry point, 250.0C. max. R.R. Classificationj Trichlorobensene. General Information! Used in orgmic synthesis, as a solvent, and as an insect icide. TRICRESYL PHOSPHATE. cn.-<^ Page 140 'y-p/ (Continued) MONSANTO CHSMICAIS- 0683880 LEXOLDMON005810 Specifications; Clear practically colorless liquid; sp. g. at20/20C., 1.1620.005; acidity (as HsPO*) 0.01% max.i free phenols (permanganate test), a distinct purple color to be present after 3') minutes. R.R, Classificationt Lacquer Solvents NOIBN. General Information; Tricresyl Phosphate is used principally as a plasticizer. It has a high boiling point and is relatively non-volatile, the evaporation loss ia 100 hours at I00"C. being less than 0.10%. The refractive index is abo\it 1.556 at 2<)C. Viscosity increases rapidly at temperatures below normal until at about --35 X. the product is a solid transparent mass without crystalline structure. It is miscible with alt the common solvents and thinners, and with linseed, china wood, and castor oils. Its solubility in water is less than 0.002% at 85C. and it imparts good moisture resistance to nitrocellulose films. Being a solvent for nitrocellulose, it has a high retentivity and can be used in large proportions without danger of sweating or separation. Tricresyl Phosphate is the standard fire retarding plasticizer for nitrocellulose. It is compatible with most lacquer resins and gives firm, tough, flexible films of excellent weathering qualities. The ortho isomer, which is reputed to he the toxic element in normal Tricresyl Phospbate, has been virtually eliminated from Tricresyl Phosphate Monsanto, there by reducing toxicity dangers to a minimum and making the product more suit able for many applications. Elimination of the ortho isomer causes no impairment in plasticizing qualities. Available Literatures 40-page booklet, "Plasticizers and Resins". TRIETHYL PHOSPHATE (CjHjDiOjPO Standard Forms Liquid. Mol. Wt. 182.2 Characteristics; Water white liquid; acidity (cc. ti/100 NaOH per 5 cc.), 3.0 cc. max.; moisture, 0.20% max. Distilling range: first drop, 2009C. min.; dry point, 220X. max. R.R. Classifications Chemicals NOIBN. General Informations Used as a solvent plasticizer and as a catalyst in chem ical syntheses. Available Literatures 40-page booklet: "Plasticizers and Resins." TRIMAGNESRJM PHOSPHATE (See Magnesium Phosphate, Tri). 46TB EDITION Page 141 0663661 TRIPHENYL PHOSPHATE. Mol. Wt. 326.31 Specifications! White flakes, faintly aromatic; m. p. 48.5C. min. start; solution in alcohol (10 gms. in 50 cc), not more than faintly opalescent; permanganate test, distinct purple color to be present after 30 minutes; acidity (as HjPOj) 0.003% max. II.R. Classification! Lacquer Solvents NOIBN. General Information! The chief uses of Tripbenyl Phosphate are as a plastic izer and fire retarder. It is miscible with the common solvents and thinners and with vegetable oils. Its solubility it. water is 0.001% at 34C. and 0.002% at 54C. and it imparts some moisture resistance to cellulose acetate films. Its retentivity in cast cellulose acetate films is nearly 80%; that is, it can be incorporated in the proportion of 8 parts to 10 of acetate without causing separation and blooming. It imparts good flexibility and gives clear, tough compositions without tendency toward tackiness. Triphenyl Phosphatfe is toxic and should not be used in articles such as foil, which are to come in oontact with foodstuffs. One of the most valu able properties of Triphenyl Phosphate is that of fire retarding. When used alone in cellulose Acetate films an amount of Tripbenyl Phosphate equal to 20% of the cellulose acetate weight produces films which will not support combustion. Available Literature? 40-page booklet "Plasticizers and Resins" TRIPHENYL PHOSPHITE Mol. Wt. 310.31 Specifications! A crystalline soli<$ at slightly below room temperature; at higher temperatures is an oily liquid weighing 9.85 lbs. per gal. R.R. Classificationi Chemicals NOIBN. General Information! Used as s plasticizer and as a fire retarder for nitro cellulose. Page 142 Monsanto chemicals 0663882 TRISODIUM PHOSPHATE (See Sodium Phosphate, Tri). "I'REKA". "LREKA BLEND B") "UREKA C" (See under Accele rators, Rubber). VANADIUM SULFURIC ACID CATALYST General Information: Used in manufacture of sulfuric acid by contact process. (Not suitable for other purposes). VANILLIN, ETHYL (See Eth,,van). "VANILLIN MONSANTO" (Vanillin, U.S.P.) CHO 0cH' Mol. Wt. 152.14 OH Standard Form: Fine Crystals. Specifications: Fine, white crystalline needles: m.p. 81.5C. min.: no foreign flavor (in sugar solution): loss on dr) ing, 0.03% max.; solubility in alcohol (1:2), complete. R.K. Classification: Chemicals NOIBN. General Information! Used as a flavoring agent in foodstuffa and beverages. Available Literature: Leaflet "Vanillin Monsanto." VARNISH ANTISKINNING AGENTS (See Santovar A). "VUELITE" (See Plastics). "VUEPAK" (See Plastics). WATER-TREATING CHEMICALS (See Aluminum Sulfate. Ammonia, Chlorine, Ferrisul, Hypochlorite of Soda, Santobrite. Santosite, Sodium Alum- inate, Sodium Sulfate). 26TH COITION Page 143 0663683 LEXOLDMONOQ5813 WETTING AGENTS (See Are(.kap, Aresket, Aresklene, Santotnerse). XANTHATES, (See Potassium Amyl Xanthate and Potassium Ethyl Xan* (hate). ZINC CHLORIDE________________ (rudest 25s He. and 52 B6. solutions. It.lt. Classification! Zinc Chloride liquid. General Information! I'sed as a flux in galvanizing and soldering since it has the acid properties of muriatic acid without being volatile at the temperature used. The following products are made by Monsanto Chemicals Limited* London* England* <md are not at present available for sale bv Monsanto in the United States: "ACROSYL" ANTHRACENE OIL AURINE BENZENE BENZENE ABSORBING OIL COCMARONE RESIN CREOSOTE NAPHTHA, HIGH FLASH NAPHTHA, SOLVENT NAPHTHALENE PITCH PYRIDINE BASES TAR ACID OIL TOLUENE Page 144 MONSANTO caiMICALS 068388-. LEXOLDMONOQ5814 MONSANTO LITERATURE Accelerators, Rubber. "Santocure." 52-page file size booklet giving proper ties, uses and comparative data. Alcohol. "Nealco Industrial Alcohol." 70.page booklet giving chemical and physical data on ethyl alcohol, completely denatured alcohol, anti-freeze, and specially denatured alcohols. Abo includes government regulations pertaining to alcohols. Ammonia. "Monsanto Ammoiiia for Refrigeration." 12-page reference book let for operators of refrigerating machines. Contains property tables for an hydrous ammonia and calcium chloride and instructions for handling ammonia and ammonia cylinders. Aroclors. "The Arociors." 20-page file size booklet covering physical and chemical properties, uses, and applications. Chlorine. "Monsanto Chlorine. * 20-page file size, illustrated booklet, giving properties of chlorine and information on containers, care of equipment and safe handling. Coumarin. "Coumarin Monsanto." 4-page pocket size folder, giving proper ties and uses. Ethavan. "Ethavan (Pure Etbyl Vanillin)." 4-page pocket size folder, giving properties and uses. Ferrisul. "Ferrisul for Metal Treatment." 12-page file size booklet, giving properties and directions for use of Ferrisul for pickling stainless steel and copper and for etching metal articles preparatory to galvanizing. Ferrisul. "Ferrisul for Treatment of Water, Sewage and Industrial Wastes." 16-page file size booklet, giving properties and directions for use of Ferrisul for treatment of municipal water supplies, sewage and industrial wastes and for other industrial uses. Ferropbospborus. "Phosphorus-Iron Alloys, Bulletin No. 1." 36-psge file size booklet, containing a report of general exploratory research upon influence of phosphorus in low carbon, low Uoy steel. Based on work done at Battelle Memorial Institute. Ferropbospborus. "Phosphorus-Iron Alloys, Bulletin No. 2." 64-page file size booklet. A report of experimental research investigation on corrosion and mechanical influences on alloying elements in low alloy steel. Ferrophosphorus. Phosphorus-Iron Alloys, Bulletin No. 3." 56-page file size booklet in two parts. Part one: Digest of U.S. Patents relating to phosphorus as an alloying element. Part two-: Lial of U.S. Patenta relating to steel production and treatment. Ferropbospborus. "Phosphorus-Iron Alloys, Bulletin No. 4." 20-page file size booklet containing reports of experimental investigation on the influence of phosphorous in Cr.*Mo steels and steels in high temperature service. Hibitite. "Hibitite and Its Uses." 4-page mimeographed bulletin. Lacquers. "Saflei Lacquers." 4-page mimeographed bulletin on Saflex fabric coatings. 26TH EDITION Page 145 0683865 LEXOLDMON005I MONSANTO LITERATURE__Continued Lampblack. "Monsanto Bear Lampblack. Properties and Principal Uses." 12-page pocket size booklet, giving description and analyses of the various grades of Monsanto Lampblack. Latex. "Latex Compounding." 36-page file size illustrated booklet containing comprehensive discussion of latex compounding methods and technique, com pounding materials and various test data. Manicure Lacquera. "Monsanto Manicure Lacquer." Pocket size color card folder, containing sample chips of the standard creme shades of Monsanto man icure lacquers. .Mertec. "Maintenance Paints." Mimeographed bulletin. Methyl Salicylate. "Methyl Salcylate Monsanto." -l-page pocket size folder giving specifications and uses. Permasan. "Chemicals for Termite Control." Monsanto Technical Bulletin No. 0-13, August 22, 1940. 4-page file size bulletin describing recommended chemicals for treatment of soil and wood. Permaaan 116. "Permasan 116, A Water Repellent Preservative for Wood." Monsanto Technical Bulletin No. 0-21. February 1.3. 1911. 8-page file size bulletin giving properties and application dats. Phosilage. "Grass Silage for Mor<< Profitable Livestock Farming--How to Make It and How to Feed It." 32-page pocket size booklet, describing procedure for making and feeding grass silage in which Phosilage is used as the preser vative. Plasticizers and Resina. "Plasticisers and Resina, Specifications and Applica tion Data." Revised May, 1940. 40-page file size booklet, giving comprehensive data on properties and applications of Monsanto plasticizers and resins, which include the Santicizers, phthalatea, phosphates, Santolitet, and Aroclora. Plaatica. "Resinox, A Monsanto Plastic." 12-page illustrated booklet describ ing properties, manufacture, molding, and uses of Resinox phenol-formaldehyde plastic. Plastics. "Lustron, A Monsanto Plastic." 16-page illustrated booklet describ ing properties, manufacture, molding, ana uses of Lustron, Monsanto poly styrene. Plaatica. "A Wartime Guide to Monsanto Plastics." 13-page file size booklet describing the main groups of Monsanto Plastics and some of their wartime applications. Potassium Pyrophosphate, Tetra. "Tetrapotassium Pyrophosphate." Mon santo Technical Bulletin No. P-23. January 1. 1941. 4-page file aize bulletin. Rubber Chemicals. "Monsanto Chemicals for the Rubber Industry." 44-page file size booklet giving properties and general characteristics and uses of Mon santo accelerators, antioxidants, softeners and miscellaneous materials for the rubber industry. Page 116 MONSANTO CHEMICALS MONSANTO L[TEKATLRE_Xontinued Rubber Compounding. "Rubber Compounding for the Wire Industry." 17-page file size booklet giving specification* and testing and compounding data on rubber * ire coatings. Santobrite. "Santobrite for the Preservation of Adhesives." Monsanto Tech nical Bulletin No, 0-1, June I. 1940. 6-page file size bulletin. Santobrite. "Santobrite and Santophen 20 for Paint Preservation," Mon santo Technical bulletin 0-2. 2-paee tile size bulletin. Santobrite. "Santobrite for Microorganism Control in the Pulp and Paper Industry," Monsanto Technical Bulletin No. 0-5. April 1, 1940. 8-page file size bulletin. Santobrite. "Santobrite for the Control of Slime and Algae," Monsanto Technical bulletin No. 0-15, March 25, 1940. 6-page file size bulletin, describ ing Santobrite for the control of ah me and algae in industrial cooling water systems. Santobrite. "Santobrite for the Preservation of Rubber Late*," Monsanto Technical bulletin No. 0-17. September 29, 1939. 8-page file size bulletin des cribing (he use of Santobrite for preventing biological deterioration of raw latex and latex products. Santobrite. "Santobrite in the Tanning Industry," Monsanto Technical bulletin No. 0-19, June 20, 1940. 6-,page file size bulletin describing the use of Santobrite for preserving hides, tanned leather, and tanning materials from mold and biological deterioration. Santobrite. "Santobrite--Methods of Handling and Application," Monsanto Technical bulletin No. 0-22. 8-page file size bulletin. Santobrite. "Preservation of Cellulose Insulating Materials by Monsanto." 24-page file size booklet describing the use of Santobrite for protecting cellulose insulating materiala and fibre boards from attack by decay and termites. Contains much investigational and field data. Illustrated. Santobrite. "Sap Stain Control by Monsanto." Revised August, 1940. 24page illustrated file size booklet, describing the use of Santobrite for controlling sap stain and mold in green lumber. Santoehlor. "Santoehlor for the Control of Peach Tree and Stone Fruit borers." Monsanto Technical Rullelin No. 0-18, December 1. 1939. 3-page file size bulletin. Santolube. "Santolubea--Corrosioi, Inhibitors for Lubricating Oils." 20-page file size booklet giving properties and results of operating and laboratory tests. Santomask. "Santomask for After-Odor Control of Interior Paint, Printing Inks and Some Other Odoriferous Formulations," Monsanto Technical Buelltin No. 0-16, July 26, 1940. 2-page file sfce bulletin, giving properties and directions for use. 26TH EDITION Page 147 MONSANTO LITERATURE--Continued Santomerse. "Santomerse.32-page file size booklet, giving physical ami chemical properties and applications of Sanioinerse as a detergent and wetting, spreading, penetrating, cleaning and dispersing agent. Santophcn T. "Santophcn 7, A Germicide and Industrial Preservative." Monsanto Technical bulletin No. 0-3. August 15, 1941. 7-page file size bulletin giv ing properties and application dat<>. Suntopour. "Santopour. A Pour-Point Depressant for Lubricating Oils." 10-pagc file size booklet describing properties, method of application, and test and field service results. Sopanox. "Sopanox--An Antioxidant for Soaps." Monsanto Technical Bulle tin No. P-100, May 1, 1939. 3-page file size bulletin giving properties and direc tions for use of Sopanox, also methods of testing soap for oxidation and rancidity. Vanillin. "Vanillin Monsanto." 4-page pocket size leaflet giving properties and uses. Vuepak. "How Vuepak Helped 21) Manufacturers to Package for Greater Sales." 30-page file size booklet, giving case studies of sales gains resulting from use of Vuepak. Intermediates are made at the Norfolk, Virginia, plant. Page 148 MONSANTO CHEMICALS 0683888 GENERAL DATA TESTING LIQUIDS WITH THE BALME HYDROMETER Monsanto products, when made to a Bautne specification, may vary 0.2 Be. above but never below the spec(fied strength. The hydrometer used should be of limited range, not more than 10 B., and should be at least 10' in length. Its accuracy should be certified by the manufacturer. Our own hydrometers are tested against standard glasses certified by the U. S. Bureau of Standards, METHOD OF READING THE HYDROMETER* The correct method of reading tl.ie hydrometer is illustrated in Figs. 1 and 2. The sample of liquid is placed in ft clear glass jar or cylinder and the hydrometer carefully immersed in it to a point slightly below that to which it naturally sinks, an.I is then allowed to float freely. The reading should not be taken until the liquid and the hydrometer are free from air bubbles and are at rest. / A/Q.i Method of Reading Baume Hydrometer In taking the reading the eye should be placed slightly below the plane of the surface of the liquid (Fig. 1) and then raised slowly until this surface, seen as an ellipse, becomes a straight line (Fig. 2). Tbe point at which this line cuts the hydrometer scale should be taken as the reading of the instrument (Fig. 2). In case the liquid is not sufficiently clear to allow the reading to be made as above described, it will be necessary to read from above the liquid surface and to estimate as accurately as possible the point to which the liquid rises on the hydro* meter stem. It should be remembered, however, that the instrument is calibrated * U. S. lurseu of Stondordt, Circ. No. 57 26TH edition Page U9 0683669 LEXOLDM to give correct indications "hen lead at the principal surface of the liquid. It will be necessary, therefore, to colrect the reading at the upper meniscus by an amount equal to the height to which the liquid creeps up on the stem of the hydrometer. The amount of this correction may be determined with sufficient accuracy for most purposes by tak*ng a few readings on the upper and the lower meniscus in a sample of the clear liquid and noting the difference. The magnitude of the correction will obviously depend upon the length and value of the subdivisions of the hydrometer scale and must be determined in each case for the particular hydrometer in question. CORRECTING FOR TEMPERATURE The Thermometer must be used along with the hvdrometer in testing any liquid. ' Hydrometers do not indicate the correct strength of a liquid unless read at the exact temperature indicated on the spindle, that is, at 60F. Accurate readings may be obtained by bringing the liquid to this temperature by cooling or warming, but in most instance* a correction can be applied with sufficient accuracy by reference to the following tables. For all liquids listed in this booklet, except Ammonia, the correction is added when the test is made above 60F. and subtracted when made below 60F. For Ammonia the reverse is true. CONVERSION FORMULAE FOR DENSITY SCALES Heavy Liquids Degrees Twaddell = (Sp. Gr. --1)200 Deg. Tw. +200 Sp. Gr. = 200 145 Degrees Bauml = 145- Sp. Gr, Sp. Gr. < 145 145--Deg. B*. Light Liquids 140 Degrees Baumt -------------------------130 Sp. Gr. 140 Sp. Gr. -- ----------------------------- 130 +Deg. B4. Page 150 MONSANTO CHBMICALS 0663890 THE DILUTION AND CONCENTRATION OF LIQU IDS AND MIXTURES RECTANGLE METHOD Tbe figures expressing the percentage concentration of two solutions (or those of one solution, and the figure 0 /or uater, where dilution with water is desired) are written in the two left hand corners of a rectangle, and tbe figure expressing the desired concentration is placed on the intersection of the two diagonals of this rectangle. Now subtract the figures on the diagonals, the smaller from the larger, and write the result at the other end of the respective diago* nal. These figitres then indicate what quantities of the solutions whos< concentration is given on the other end of the respective horizontal line, must be taken to obtain a solution of the desired concentration. For ex* F/G.l ample, to mako a 12% solution, by mixing an 8% and a 15% solution we prepare Fig. 1, which indicates that we have to take 3 parts by weight of the 8% solution, and 4 parts by weight of the 15% solution to obtain (7 parts by weight of) the 12% solution. Again, if we wish to dilute a 25% solution so as to obtain a 9% solution, we place the figure 25 in, for example, the upper left corner of a rectangle and place figure 0 (concentration of ........ .................... 9 the solution in pure water) in the lover left corner, and then place tbe figure 9 (desired concentration) at the point of intersection of the diagonals, and subtracting across the diagonals, we obtain Fig. 2: 9 parts by weight of the 25% solution, if mixed with 16 parts by weight of water, will give 25 parts by weight of a 9% solution. In diluting to a given Bauml strength or Specific Gravity, the percentage composition, corresponding to the B#um6 or Specific Gravity, must be taken from the following tables. For instance, supposing a 32 .........................^0Baum6 Chloride of Alumina solution is to be diluted to 8*Baum6withvater. By reference to table on page 163 6.50 a 32 Baum6 solution contains 27.88% AltCl*, and an 8 // Baun6 solution contains 6.50% AlCl. These percentages q........'}<}"$'" 2/M must ^ U8e<* *n frying the weight# of Chloride of Alumina ' and water to b< mixed by the above method. According to the scheme as outlined above, the percentages are arranged as in Fig. 3 and the subtractions made along the diagonals, the lower from the higher. Thus when 32 Baum6 Chloride of Alumina is mixed with water in the proportion 6.50 pounds to 21.38 pounds, 27.88 pounds of solution will be obtained at 8 BaumL 26tm DITIOK Page 151 SULFURIC ACID* By W. C. Ferguson and H. P. Talbot De grees He Specific Gravity 60760* F. Per Cent H,SO Freezing (Melting) Point Dg. F. De. sr Specific Gravity 60760 F. Per Cent h*so4 Freezing (Melting) Point Deg. F. 0 1.0000 0.00 +32.0 36, 1.3303 42 63 --70.0 37 1 3426 43.99 --60.0 1 1.0069 1.02 2 1.0140 2.08 +31.2 +30.5 38 1.3551 45 35 --53.0 39 1.3679 46 72 --no 3 1.0211 3.13 +29.8 40 1.3810 48.10 --no 4 1.0284 4.21 +28.9 5 1.0357 5.28 +28.1 41 1.3942 49.47 --35.0 42 1.4078 50.87 --31.0 6 1.0432 6 37 +27.2 43 1.1216 52.26 --27.0 7 1.0507 7 45 8 1.0584 8 55 +26.3 +25.1 44 1 6 53.66 --23.0 45 1 55.07 --20.0 9 1.0662 9.66 +24.0 10 1.0741 10.77 +22.8 46 1. 56 48 --14.0 47 1. 57.90 -- 15.0 11 1.0821 11.89 +21.5 48 1. 59.32 -- 18.0 12 1.0902 13.01 +20.0 49 1.5: 60.75 --22.0 13 1.0985 14 13 +18.3 50 1.52 62.18 --27.0 U 1.1069 IS. 25 +16 6 15 1.1154 16.38 +14.7 SI 1.5426 63.36 --33.0 52 1.5591 65 13 --39.0 16 1.1240 17.53 +12.6 S3 1.5761 66.63 --49 0 17 1.1328 18.71 +10.2 54 1.5934 68.13 --59.0 18 1.1417 19.89 +7.7 55 1.1611 69.65 t 19 1.1508 21.07 +4 8 20 1.1600 22.25 +1.6 56 1.6292 71.17 57 1.6477 72.75 {t 21 1.1694 23.43 22 1.1789 24 61 --1.8 --6.0 58 1 6667 74.36 59 1.6860 75.99 T --7.0 23 1.1885 25.81 --11.0 60 1.7059 77.67 +12.6 24 1.1983 27.03 --16 0 25 1.2083 28.28 --23.0 61 1.7262 79.43 +27.3 62 1.7470 81.30 +39.1 26 1.2185 29 53 --30.0 63 1.7683 83 34 +46.1 27 1.2288 30.79 --39.0 64 1.7901 85.66 +46.4 28 1.2393 32.05 --49.0 64 M 1.7957 86.33 +43.6 29 1.2500 S3 33 --61.0 64 1.8012 87.04 +41 1 30 1 2609 34.63 --74 0 64K 1.8068 87.81 +37 9 65 1.8125 88.65 +33 1 31 1.2719 35 93 --82.0 65*4 1.8182 89.55 +24 6 32 1.2832 37 26 --96 0 65 H 1.8239 90.60 +13.4 33 1.2946 38.58 --97.0 65 H 1.8297 91 80 -- 1.0 34 1.3063 39 92 --91.0 35 1.3182 41.27 --81.0 66 1.8354 93.19 --29.0 This table has been approved and adopted as a Standard by the Manufact uring Chemiata' Association of tbe United States. fBelow--40. Specific Gravity determinations veri made at 60 F., compared with water at 60F. (Continued) Page 152 Monsanto chsmicals 0683892 LEXOLDMONOQ5822 SULPHURIC ACID__Continued From the Specific Gravities, the corresponding degrees Bauml were cal culated hy the following formula: Uaume = 145--145/Sp. Gr. ALLOWANCE FOR TEMPERATURE At 10 Be. correctionof .029 B4. or .00023 Sp. G. for every 1F. At 20 B. correctionof .036 Be. or .00034 Sp. G. for every 1F. At 30 Be. correctionof .035 B6. or .00039 Sp. G. for every 1'F. At 10 Be. correctionof .031 Be. or .00041 Sp. G. for every 1F. At 50 B. correctionof .028 Be. or .00045 Sp. G. for every I'F. At 60 B4. correctionof .026 Be. or .00053 Sp. G. for every 1 F. At 63 B. correctionof .026 B. or .00057 Sp. G. for every 1F. At 66 Be. correction of .0235' B. or .00054 Sp. G. for every 1F. For temperatures above 60F.. the correction is added to the observed in dication: below 60F. subtracted. % Oleum OLEUM % Free SO, Equiv. % H:SO, Freezing Point F. 0 0 100.00 50.5 10 10 102.25 32.0 20 20 104.49 22.0 25 25 105.62 47.0 30 30 106.75 66.0 40 40 109.0 91 9 50 50 111.25 91 9 60 60 113.5 62 0 65 65 114.62 38.0 70 70 115.75 56.0 80 80 118 0 78.0 26TB BDITION Page 153 0663893 LEXOLDMONOQ5823 Degrees Baum6 1.00 2.00 3.00 4()0 5 00 5 25 5.50 5.75 6.00 6.25 6.50 6.75 7.00 7.25 7.50 7.75 8.00 8.25 8.50 8.75 9.00 9.25 9.50 9.75 10.00 10.25 10.50 10.75 11.00 11.25 11.50 11.75 12.00 12.25 12.50 12.75 13.00 13.25 13.50 13.75 14.00 14.25 14.50 14.75 15.00 Page 154 hydrochioric acid* (Muriatic Acid) By W. C Ferguson Specific 60760 F. Gravity 1 0069 1.0140 1.0211 1.0284 1.0357 1.0375 1.0394 1.0413 1.0432 1 0450 1 0469 1.0488 1.0507 1.0526 1.0545 1 0564 1.0584 1.0603 1.0623 1.0642 1.0662 1.0681 1,0701 1.0721 1.0741 1.0761 1.0781 1.0801 1.0821 1.0841 1.0861 1 0881 1.0902 1.0922 1.0943 1.0964 1.0985 1.1006 1.1027 1.1048 1.1069 1.1090 1.1111 1.1132 1 1154 Per Cent HCI. Degrees Baum6 1 40 2.82 4.25 5 69 7.15 1S.2S 15.50 15.75 16.0 16.1 7.52 7.89 8.26 8.64 9.02 16.2 16.3 16 4 16 5 16.6 9.40 9.78 10.17 10 55 10.94 17 1' 1 17.1 11.32 11.71 12.09 12.48 12.87 17.2 17.3 17 4 17.5 17.6 13.26 13.65 14.04 14.43 14.83 17.7 17,8 17.9 18.0 18.1 15.22 15.62 16.01 16.41 16.81 18.2 18.3 18.4 18.5 18.6 17.21 17.61 18.01 18.41 18.82 18.7 18.8 18.9 19.0 19.1 19.22 19.63 20.04 20.45 20.86 19,2 19.3 19.4 19.5 19.6 21.27 21.68 22.09 22.50 22.92 19.7 19.8 19.9 20.0 20.1 {Continued) Specific Gravity 60760* F. 1.1176 1 1197 1.1219 1.1240 1.1248 1.1256 1.1265 1 1274 1.1283 1.1292 1.1301 1.1310 1.1319 1.1328 1.1336 1.1345 1.1354 1.1363 1.1372 1.1381 1.1390 1.1399 1.1408 1.1417 1.1426 1.1435 1.1444 1.1453 1.1462 1.1471 1.1480 1.1489 1.1498 1.1508 1.1517 1.1526 1.1535 1 1544 1.1554 1.1563 1.1572 1.1581 1.1590 1.1600 1.1609 Per Cent HCI. 23.33 23.75 24.16 24.57 24.73 24.90 25.06 25.23 25.39 25.56 25 ' 25 26 26 26.,, 26.56 26.73 26.90 27.07 27.24 27.41 27.58 27.75 27.92 28.09 28.26 28.44 28.61 28.78 28.95 29.13 29 30 29.48 29.65 29.83 30.00 30.18 30.35 30.53 30.71 30.90 31.08 31.27 31.45 31.64 MONSANTO CHEMICALS 0683694 LEXOLDMONOQ5824 HYDROCHLORIC ACID_Continued Degrees Baum6 20.2 20.3 20.4 20.5 20.6 20.7 20.8 20.9 21.0 21.1 21.2 21.3 21.4 21.5 21.6 21.7 21.8 21.9 22.0 22.1 22.2 22.3 22.4 22.5 22.6 22.7 22.8 22.9 23.0 23.1 Specific 60 .60 F. Gravity 1 1619 I 1628 1.1637 1.1647 1.1656 1.1666 1.1675 1.1684 1.1694 1.1703 1.1713 1.1722 1.1732 1.1741 1.1751 1.1760 1.1770 1.1779 1.1789 1.1798 1.1808 1.1817 1.1827 1.1836 1.1846 1.1856 1.1866 1.1875 1.1885 1.1895 Per Cent HCI. 31.82 32.01 32.19 32,38 32.56 32.7> 32.9,1 33. 1:2 33 31 33.59 33.69 33.88 34.07 34.26 34.45 34.61 34.81 35.02 35.21 35.4) 35.59 35.78 35.97 36.16 36.3> 36.54 36.78 36.9) 37.14 37.36 Degrees Baume 23.2 23.3 23.4 23.5 23.6 23.7 23.8 23.9 24.0 24.1 24.2 24.3 24.4 24.5 24.6 25.7 24.8 24.9 25,0 25.1 25.2 25.3 25.4 25.5 Specific Gravity 60,60 F. 1.1904 1 1914 1.1924 1.1934 1.1944 1.1953 1.1963 1.1973 1.1983 1.1993 1.2003 1.2013 1.2023 1.2033 1.2043 1.2053 1.2063 1.2073 1.2083 1.2093 1.2103 1.2114 1.2124 1.2134 Per Cent HCI. 37.58 37.80 38 03 38.26 38.49 38.72 38 95 39 18 39.41 39.64 39.86 40.09 40.32 40.55 40.78 41.01 41.24 41.43 41.72 41.99 42.30 42.64 43.01 43.40 This table baa been approved and adopted as a Standard by the Manufact uring Chemists' Association of the tailed States. Specific Gravity determinations were made at 60F., compared with water at 60F. From the Specific Gravities, tbo corresponding degrees Baum6 were calcul ated by the following formula: 145 Bauml =145 ---------------- Sp. G. allowance: for temperature At 10 to 15 B4. At 15 to 22 B6. At 22 to 25 B6. correction of 1/40 B.or .0002 Sp. G. for every 1F. correction of )/30 B6.or .0003 Sp. G. for every 1 F. correction of ] /28 B6.or .00035 Sp. G. for every 1F. 26TH EDITION Page 155 0683895 LEXOLDMONOQ5825 Decrees Baume 10 01) 10 25 10 50 10.75 11.00 11.25 11.50 11.75 12.00 12.25 12.50 12.75 13.00 13.25 13.50 13.75 14.00 14.2S 14.50 14.75 15.00 15.25 15.50 15.75 16.00 16.25 16.50 16.75 17.00 17.25 17.50 17.75 18.00 18.25 18.50 1875 19.00 1925 19 50 19.75 20.00 20.35 20.50 20 75 21 00 Page 156 NITRIC ACID* By W. ('. Ferguson Specific GravUv 60 60s' F. 1.07U 1 0761 1.0781 l (1801 1.0821 1.0841 1.0861 1,0881 1.0902 1.0922 1.0943 1.0964 1.0985 1.1006 1.1027 1.1048 1.1069 1.1090 1.1111 1.1132 1.1154 1.1176 1,1197 1.1219 1.1240 1.1262 1.1284 1.1306 1.1328 1.1350 1.1373 1.1395 1.1417 1.1410 1.1462 1.1485 1.1508 1.1531 1.1554 1.1577 1.1600 1.1624 1.1647 1.1671 1 1694 Per Cent HNOj 12.86 13.18 13.49 13.81 14.13 1 Degrees , 1 Kaume 1 1 21.25 j 21.50 21.75 l 22.00 22.25 Specific Gravity 60760 'F. 1.1718 1.1741 1.1765 1.1789 1.1813 Per Cent HNOj 28.02 28 36 28 72 29.07 29.43 14.44 14.76 15.07 15.41 15.72 22 50 22.75 23.00 23.25 23.50 1.1837 1.1861 1.1885 1.1910 1.1934 29.78 30 14 30.49 30.86 31.21 16.05 16.39 16.72 17.05 17.38 23.75 24.00 24.25 24.50 24.75 1.1959 l.1983 1.2008 1.2033 1.20S8 31.58 31.94 32.31 32.68 33.05 17.71 18.04 18.37 18.70 19.02 25.00 25.25 25.50 2S.75 26.00 1.2083 1.2109 1.2134 1.2160 1.2185 33.42 33.80 34.17 34.56 34.94 19.36 19.70 20.02 20.36 20.69 26.25 26.50 26.75 27.00 27.25 1.2211 1.2236 1.2262 1.2288 1.2314 35.33 35.70 36.09 36.48 36.87 21.03 21.36 21.70 22.04 22.38 27.50 27.75 28.00 28.25 28.50 1.2340 1.2367 1.2393 1.2420 1.2446 37.26 37.67 38.06 38.46 38.85 22.74 23.08 23.42 23.77 24.11 28.75 29.00 29.25 29.50 29.75 1.2473 1.2500 1.2527 1.2554 1.2582 39.25 39.66 40.06 40.47 40.89 24.47 24.82 23.18 25.53 25.88 30.00 30.25 30.50 30.75 31.00 1.2609 1.2637 1.2664 1.2692 1.2719 41.30 41.72 42.14 42.58 43.00 26.24 26.61 26,96 27.33 27.67 31.25 31.50 31.75 32.00 32 25 (Continued') 1.2747 1.2775 1.2804 1.2832 1 2861 43.44 43.89 44 34 44.78 45 24 MONSANTO CHEMICALS 0683696 LEXOLDMONOQ5826 NITRIC ACID--Continued Degrees Bauin6 32.50 32.75 33.00 33 25 33.50 33.75 34.00 34.25 34.50 34.75 35.00 35 25 35.50 35.75 36.00 36.25 36.50 36.75 37.00 37.25 37.50 37.75 38.00 38.25 38.50 38.75 39.00 39.25 39.50 39.75 40.00 40.25 40.50 40.75 41.00 Specific Gravity 60 60 F. 1.2889 1.2918 1.2946 1 2975 l 3004 1.3034 1.3063 1.3093 1.3122 1.3152 1.3182 1.3212 1.3242 1.3273 1.3303 1.3334 1.3364 1.3395 1.3426 1,3457 1.3488 1.3520 1.3551 1.3583 1.3615 1.3647 1.3679 1.3712 1.3744 1.3777 1.3810 1.3843 1.3876 1.3909 1.3942 Per Cent HN'Oj 45.68 46 14 46.58 47 04 47.49 47.95 48.42 48 90 49 35 49.83 50,32 50.81 51.30 51.80 52.30 52.81 53.32 53.84 54.36 54.89 55.43 55.97 56.52 57.08 57.65 58.23 58.82 59.43 60.06 60.71 61.38 62.07 62.77 63.48 64.20 Degrees Baumc 41.25 41 50 41.75 42.00 42.25 42.50 42.75 43.00 43 25 43.50 43.75 44.00 44.25 +4.50 44 75 45 00 45.25 45.50 43 ii> 46 00 46.25 46.50 46.75 47 00 47.25 47.50 47.75 48.00 48.25 48.50 Specific Gravity 60 60F. 1.3976 1.40)0 l.4044 1.4078 1.4112 1.4146 1 4181 1. 4216 1 4251 1.4286 1.4321 1.4356 1 4392 1.4428 1 4464 1 4500 1 4536 1.4573 1. 4610 1.4646 1 4684 1.4721 1.4758 1.4796 1.4834 1.4872 1.4910 1.4948 1.4987 1.5026 Per Cent HNOj 64 93 65 67 66.42 67 18 67.95 68 73 69 52 70 33 71.15 71 98 72.82 73.67 74.53 75.40 76.28 77 17 78.07 79.03 80 04 81.08 82.18 83.33 84.48 85.70 86.98 88.32 89.76 91.35 93.13 95.11 This table has been approved and adopted as a Standard by the Manu/act uring Cbemiata* Association of the United States. Specific Gravity determinations were made at 60* F. compared with water at 60F. From the Specific Gravities, the corresponding degrees Baumfi were calcu lated by the following formula: -- Bautnl = 145 -- 145 -------------------- Sp. G. (Continued) 26TB EDITION Page 157 0663697 LEXOLDMONOQ5827 NITRIC ACID__Continued allowance for temperature At from 10 to 20 B6. correction of 1/30 B6. or .00029 Sp. G. for every 1F. At from 20 to 30 B6. correction of 1/23 B6. or .00044 Sp. G. for every lF. At from 30 to 40 B6. correction of 1/20 B6. or .00060 Sp. G. for every 1F. At from 40 to 43.5 B6. correction ofl/17 B. or .00084 Sp. G. for every 1F. ACETIC ACID 60,60 F. Ouciemanns Specific Gravity 1.0000 1.0016 1.0032 1.0047 1.0062 1.0077 1.0093 1.0108 1.0123 1.0137 1.0152 1.0167 1.0181 1.0195 1.0210 1.0224 1.0238 1,0252 1.0266 1.0280 1.0294 1.0308 1.0321 1.0334 1.0347 1.0360 1.0373 1.0385 1.0398 1.0410 1.0422 1.0434 1.0446 1.0457 Per Cent C,HA 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 Specific Gravity 1.0469 1.0480 1.0491 1.050? 1.051? 1.0523 1.0533 1.0543 1.05S3 1.0562 1.0572 1.0581 1.0590 1.0599 1.060? 1.0617 1.0625 1.0633 1.0641 1.0648 1.0656 1.0663 1.0670 1.0676 1.0683 1.0689 1.0695 1.0701 1.0707 1,0712 1.0717 1.0722 1.0727 1.0731 Per 4Cent C,H o, 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 ! 61 62 . 63 64 65 66 67 : Specific Gravity 1.0735 1.0739 1.0743 1.0747 1.0750 1.0752 1.0754 1.0756 1.0757 1.0758 1.0758 1.0758 1.0758 1.0757 1.0756 1.0754 1.0752 1.0749 1.0746 1.0741 1.736 1.0730 1.0723 1.0715 1.0706 1.0696 1.0684 1.0670 1.0654 1.0635 1.0614 1.0590 1.0563 Per Cent CjH40, 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 100 Pane 158 MONSANTO CBSMICALS 0663696 LEXOLDMONOQ5828 AQUA AMMONIA* By W ('. Ferguson Degrees Baum 10.00 10.25 10.50 10.75 11.00 11.25 11.50 11.75 12.00 12,25 12.50 12.75 13.00 13.25 13,50 13.75 14.00 14.25 14.50 14.75 15.00 15.25 15.50 15.75 16.00 16.25 16.50 16.75 17,00 17.25 17.50 17.75 18.00 18.25 18.50 18.75 19.00 19.25 19.50 19.75 Specific Gravity 607604'. 1.0000 .9982 .9964 .9947 .9929 .9912 .9894 .9876 .9859 .9842 .9825 .9807 .9790 .9773 .9756 .9739 .9722 .9705 .9689 .9672 .9655 .9639 .9622 .9605 .9589 .9573 .9556 .9540 .9524 .9508 .9492 .9475 .9459 .9444 .9428 .9412 .9396 .9380 .9365 .9349 Per Cent NHj j Degrees | Batiml .oo .40 .80 1.21 1.6j: 20.00 20.25 20. 50 20.75 21.00 2.0'? 2.40 2.81: 3.30 3.73 21.25 21.50 21.75 22.00 22.25 4.1( 4.5V 5.0* 5.45 5.81 22.50 22.75 23.00 23.25 23.50 6.3] 6.74 7.17 7.61 8.05 23.75 24.00 24.25 24.50 24.75 8.49 8.93 9.38 9.83 10.28 25.00 25.25 25.50 25.75 26.00 10.73 11.18 11.64 12.10 12.56 26.25 26.50 26.75 27.00 13.02 13.49 13.96 14.43 14.90 27.25 27.50 27.75 28.00 28.25 15.37 15.84 16.32 16.80 17 28 28.50 28.75 29.00 Specific Gravity 60760^. 1 Per Cent NHj .9333 .9318 .9302 .9287 .9272 17.76 18.24 18.72 19.20 19.68 .9256 .9241 .9226 .9211 .9195 20.16 20 64 21.12 21.60 22.08 .9180 .9165 .9150 .9135 .9121 22.56 23.04 23.52 24.01 24.50 .9106 .9091 .9076 .9061 .9047 24.99 25.48 25.97 26.46 26.95 .9032 .9018 .9003 .8989 .8974 27.44 27.93 28.42 28 91 29.40 .8960 .8946 .8931 .8917 29.89 30.38 30.87 31.36 .8903 .8889 .8875 .8861 .8847 .8833 .8819 .8805 31.85 32.34 32.83 33.32 33.81 34.30 34.79 35.28 '"This table has been approved antf adopted as a Standard by the Manufac* luring Chemist#' Association of the l nited States. Specific Gravity determinations wire made at 60F. compared with water at 60F. (Continued) 26TH EDITION Page 159 0663899 LEXOLDMON005829 AQl'A AMMONIA__Continued ] to Raiime ------------------------- -- 130. SP. G. ALLOWANCE FOR TEMPERATl'RE The coefficient of expansion for ai Jinonia solutions varying with the temper* a Hire, correction must be applied according to the following tabic: -- Degrees i itumne J I Corrections to be Added for Each Degree Below 60*F. 40'K. 50CF. ITBe. ]G " 18 " 20" - 26 " ()|5Be. .021 ** .027 " .033 " .039 " .053 ' 0l7Be. .023 " .029 " ,036s " .042 " .057 " Corrections to be Subtracted (or Each Degree Above 60F. 7):F. o::oBe. u:6 " .0}<1 ' .U2T*7 " .043 . Of 7 80F. i 90F. . 022Be. | .028 " .033 - ! .038 " .043 " .059 ' ! 1 . 024Be. .030 " .035 ' .040 " 017 " J00F. ,026'BC .032 " .037 " .042 " Central Research Department Laboratories. Dayton, Ohio Page 160 MONSANTO CHEMICALS 0683900 LEXOLDMON005830 Temp. U.g. -- U> -35 - 30 -J5 --20 -15 -- 10 --5 0 5 10 15 20 25 30 3S 40 45 50 55 60 65 TO 75 80 85 00 95 100 105 110 115 120 125 ANHYDROl'S AMMONIA Pressure Lbs. per Sq. In. Abs. 10.12 11.74 13.56 15.61 17.91 20.46 23.30 26.46 29.95 33.79 38.02 42.67 47.75 53.50 59.39 65.91 73.03 80.75 89.09 98.03 107.7 118.1 129.2 141.1 153.9 167.4 181.8 197.3 213.8 231.2 249.6 269.2 289.9 311.6 Specific V olume <>:' Liquid C;i Ft. per Lb. of Sat. Vapor, Cu. Ft. per Lb. 0.0234 0.0235 9.0236 9.0238 25.45 22.14 19,35 16.95 0.0239 0.0240 0.0241 0.0242 14.89 13.15 11.63 10.32 0.0244 0.0245 0.0246 0.0248 9.19 8.20 7.34 6.583 0.0249 0.0250 0.0252 0.0253 5,920 5 336 4.820 4.364 0,0255 9.0256 0.0258 0.0259 3.959 3.599 3.278 2.992 0.0261 0.0263 0.0264 0.0266 0.0268 0.0270 0.0271 0.0273 2.734 2.503 2.296 2.109 1.940 1.788 1.650 1.524 0.0275 0.0277 9.0280 0.0282 0.0284 0.0286 1.408 1.305 1.210 1.122 1.042 0.970 Meat of \ aporization, B.T.l. 601.9 598.3 594.7 591.1 587.4 583.6 579.9 576.1 572.2 568.3 564.4 560.4 556.3 552.2 548.1 543.9 539.7 535.3 531.0 526.5 522.0 517.5 512.8 508.1 503.4 498.5 493.5 488.5 483.4 478.2 472.9 467.4 461.9 456.3 Sp. G. Liquid 0.6364 at 32F. 26TH EDITION Page 161 0683901 LEXOLDMON005831 ALUMINUM CHLORIDE 60 60 F. Rii-choff S pecific G ra v ity ti B r? kc a a.-e .00 SO 1.00 1.50 2.00 2.50 3.00 3.50 4.00 4.50 5.00 5.50 6.00 6.50 7.00 7.50 8.00 8.50 9.00 9.50 10.00 10.50 11.00 11.50 12.00 12.50 13.00 13.50 14.00 14.50 15.00 15.50 16.00 16.50 17.00 1.0000 1.0035 1.0069 1.0105 1.0140 1.0175 1.0211 1.0247 1.0284 1.0320 1.0357 1.0394 1.0432 1.0469 1.0507 1.0545 1.0584 1.0623 1.0662 1.0701 1.0741 1.0781 1.0821 1.0861 1.0902 1.0943 1.0985 1.1027 1.1069 1.1111 1.1154 1.1197 1.1240 1.1284 1.1328 .00 .35 .75 1.17 1.58 2.00 2.40 2.78 3.16 3.58 4.00 4.38 4.81 5.20 5.63 6.05 6.50 6 92 7.32 7.75 8.13 8.57 9.00 9.46 9.90 10.28 10.70 11.15 11.60 12.05 12.50 12.95 13.37 13.83 14.30 -- 2* IILi h u| jt tty_* X V a.< 00 .038 .113 .178 .242 17.50 18.00 18.50 19 00 19.50 .307 .370 .430 .490 .557 20.00 20.50 21.00 21.50 22.00 .625 .686 .756 .820 .890 22.50 23.00 23.50 24.00 24.50 .962 1.04 1.11 1.18 1.25 25.00 25 50 26 00 26.50 27.00 1.32 1.39 1.47 1.55 1.63 27.50 1 28.00 28.50 29.00 29.50 1.70 1.77 1.85 1 93 2.02 30.00 30.50 31.00 31.50 32.00 2.10 2.19 2.27 2.35 2.44 ! 32.50 ! 33.00 ! 33.50 1 34.00 1 34 50 1.1373 1.1417 1.1462 1.1508 1.1554 1.1600 1.1647 1.1694 1.1741 1.1789 1.1837 1.1885 1.1934 1.1983 1.2033 1.2083 1.2134 1.2185 1.2236 1.2288 1.2340 1.2393 1.2446 1.2500 1.2554 1.2609 1.2664 1.2719 1.2775 1.2832 1.2889 1.2946 1.3004 1.3063 1.3100 14 73 15.16 15.60 16.OS 16.53 16.94 17.43 17.88 18.33 18.78 19.22 19 68 20.13 20.57 21.03 21.50 21.98 22.38 22.82 23.20 23.70 24 13 24.58 25.02 25.53 25.99 26 45 26.92 27.38 27.88 28.33 28.78 29.24 29.68 30.00 _.*C < 2.33 2.60 2 69 2.78 2.88 2.96 3.06 3.15 3.25 3 34 3.43 3 53 3.62 3.72 3.81 3.90 4.02 4.12 4.21 4.30 4 41 4.50 4 61 4.72 4.83 4.94 5 04 5 16 5.27 5.40 5 50 5.62 5 73 5.85 5.92 * AljCI* +12H|0, Chloride of Alumina Crystal. For Chloride of Alumina 32B4. twice the above pound* per gallon of eohition. Page 162 MONSANTO CHBMICALS 0683902 LEXOLDMONOQ5832 ALUMINUM SULFATE 60 60 F. Beveridge h 11,k > '//J 00 50 J.00 1.50 2.0 2.5 3.0 35 4.0 4.5 5.0 5.5 6.0 6.5 7.0 7.5 8.0 8.5 9.0 9.5 10.0 10.5 11.0 11.5 12.0 12.5 13.0 13.5 H.O 14. S 15.0 15.5 16.0 16.5 17.0 17.5 18.0 18.5 19.0 19,5 l 000 1.003S 1.0069 1.0105 1.0140 1.0175 1.0211 1.0247 1.0284 1.0320 1.0357 1.0394 1.0432 1.0469 1.0507 1.0545 1.0584 1.0623 1.0662 1.0701 1.07*1 1.0781 1.0821 1.0861 1.0902 1.0943 1.0985 1.1027 1.1069 1.1111 1.1154 1.1197 1.1240 1.1284 1.1328 1.1373 1.1417 1.1462 1.1508 1.1554 26TH BOITIOK M m A .00 .53 1.07 1.64 2.16 .00 .044 .090 .138 .181 2.70 3.28 3.79 4.40 4.97 .228 .279 .323 .376 .427 5.52 6.10 6.73 7.33 7.98 .476 .528 .585 .638 ,700 8.56 9.18 9.82 10.43 11.OS .751 ,808 .860 .925 .980 11.65 12.26 12.90 13.53 14.13 1.04 1.10 1.16 1.22 1.28 14.71 15.32 15.98 16.60 17.25 1.34 1.40 1.47 1.53 1.59 17.90 18.48 19.13 19.80 20.40 1.66 1.72 1.79 1.86 1.92 21.06 21.73 22.43 23.10 23.78 1.99 2.06 2.14 2.21 2.28 (Continued) -s 3 tl*'<l5l llljS .00 0.6 1.1 1.7 2.3 2.9 3.5 4.1 4.7 5.3 6.0 6.7 7.3 7.9 8.5 9.2 9.8 10.5 11.1 11.8 12.4 13.1 13.8 14.4 15.1 15.7 16.4 17.1 17.7 18.4 19.1 19.9 20.4 21.1 21.8 22.4 23.1 23.7 24.4 25.1 .00 .050 .092 1.95 .246 .298 .350 .403 .456 .518 .581 .635 .690 .745 .809 .865 .931 .988 1.05 i.n 1.18 1.25 1.30 1.37 1.43 1.50 1.57 1.63 1.70 1.77 1.86 1.91 1.99 2.06 2.12 2.20 2.26 2.34 2.42 Ptge 163 0683903 LEXOLDMONOQ5833 ALUMINUM SULFATEL-Continued tl U>3 -i -2 20. u 20.5 21.0 21.5 22 5 23.0 23.5 24.0 24.5 25 0 25.5 26.0 26.5 27.0 27.5 28 0 28.5 29.0 29.5 30.0 30.5 31.0 31.5 32.0 32.5 33.0 33 5 34.0 34.5 35.0 35.5 36 0 36.5 \.1600 1.1647 1.1694 1.1741 1.1789 1.1837 1.1885 1.1934 1.1983 1.2033 1.2083 1.2134 1.2185 1.2236 1.2288 1.2340 1.2393 1.2446 1.2500 1.2554 1.2609 1.2664 1.2719 1.2775 1.2832 1.2889 1.2946 1.3004 1.3063 1.3122 1.3182 1.3242 1.3303 1 3364 S jw cifio G ra vity "i Z 2.5-f CJJ z< j. * < t- 24.38 24.99 25.60 26.22 26.87 27.50 28.16 28.85 29.50 30.18 30.85 31.54 32.24 32.95 33.63 34.35 35.03 35.75 36.46 37.20 37.90 38.58 39.30 40.02 40.73 41.49 42.20 42.96 43.71 44.48 45.20 46.00 46.80 47.58 2.35 2.42 2.49 2.56 2.64 2.71 2 78 2.86 2.94 3.02 3.10 3.18 3.27 3.35 3.44 3.52 3.61 3.70 3.79 3.88 3 98 4.06 4.16 4.25 4.35 4.45 4.54 4.64 4.75 4.86 4.95 5.07 5.18 5.29 v2i ,H.x ~ 1 v ^ # jf^1 1 x_ $ w 5 ^ r'i 25.7 26.4 27.1 27.7 28.4 29.1 29.8 30.3 31.1 31.7 2.49 2.56 2.64 2.71 2.79 2.87 2.95 3.02 3 11 3.18 32.4 33.1 33.8 34.5 35.2 35.9 36.7 37.3 38.1 38.8 39.7 40.3 41.0 41.8 42.5 43.3 44.1 44.9 45.7 46.5 47.4 48.3 49 2 50.1 3.27 3.35 3.44 3.52 3.61 3.70 3.79 3.87 3.97 4.06 4.18 4.26 4.35 4.46 4.55 4.66 4.76 4.87 4.98 5.09 5.21 5.34 5.46 5 59 FREEZING POINTS OF 0.6% "BASIC ALUM SOLUTIONS Baum at 60'P. 5 10 15 20 25 30 35 Freezing Points, degrees F. 31 30 29 27 24 21 38 Page 164 MONSANTO CHEMICALS 0683904 LEXOLDMON005834 SODIUM BISULFITE 6T 60 F. H. B. Bischoff * <Ti ll s ^ =3 2 tl i. z. a.< .00 . 50 1.00 1.50 2.00 2.50 3.00 3.50 4.00 4.50 5.00 5.50 6.00 6.50 7.00 7.50 8.00 8.50 9.00 9.50 10.00 10.50 11.00 11.50 12.00 12.50 13.00 13.50 14.00 14.50 15 00 15.50 16.00 16.50 17.00 17.50 18.00 18.50 19.00 19.50 1 0000 1 0034 l 0069 1 0104 1.0140 1.0175 1.0211 1.0247 1 0284 1.0320 1.0357 1.0394 1.0432 1.0469 1.0507 1.0545 1.0584 1.0623 1.0662 1.0701 1.0741 1.0781 1.0821 1.0861 1.0902 1.0943 1.0985 1.1027 1.1069 1 1111 1.1154 1.1197 1.1240 1.1284 1.1328 1.1372 1.1417 1.1462 1.1508 1.1554 .00 51 1 02 1.53 2.04 2.55 3 06 3.57 4.08 4.59 5.11 5 63 6.15 6 67 7.19 7.71 8.24 8.77 9 30 9.83 10 36 10.89 11.42 11.95 12.48 13.02 13 56 1.410 14.65 15.20 15.75 16.30 16.85 17.40 17.96 18.52 19.08 19.64 20.20 20.76 .00 . 3i. .63 .94 1.20 1.5" 1.88 2.5}* 2.5) 2.8^ 3.1S> 3.4T 3.79 411 4.43 4.75 5.07 5.4* 5.7? 6.OS 6.3* 6.70 7.03 7.36 7.6* 8.02 8.35 8 66 9.02 9.36 9.70 10. oa 10.37 10.71 11.05 11.39 11.74 12.08 12.43 12.77 S5 y &c 5 la If = J3 t. k* 1. < 20.00 20.50 21.00 21.50 22.00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00 30.50 31.00 31.50 32.00 32.50 33.00 33.50 34.00 34.50 35.00 35.50 36.00 36.50 37.00 37.50 38.00 38.50 39.00 39.25 1 1600 1.1647 1.1694 1.1741 1.1789 1 1837 1 1885 1.1934 1.1983 1.2033 1.2083 1.2134 1.2185 1.2236 1.2288 1.2340 1.2393 1.2446 1.2500 1.2554 1.2609 1.2664 1.2719 1.2775 1.2832 1.2889 1.2946 1.3004 1.3063 1.3122 1.3182 1.3242 1.3303 1.3364 1.3426 1.3488 1.3551 1.3615 1.3680 1.3712 21.32 21 88 22.44 23.00 23.57 24.14 24.71 25 28 25.85 26.42 26.99 27.56 28 13 28.70 29.27 29 85 30.43 31.00 31.57 32.14 32.71 33.28 33.86 34.43 35.01 35 62 36.25 36.88 37.51 38.14 38.78 39.42 40.06 40 69 41.30 41.91 42.52 43.12 43.72 44.02 13 13 13.46 13 81 14. 15 14.50 14.85 15.20 15.55 15.91 16.23 16 60 16.96 17.32 17.66 18.01 18.37 18.73 19.08 19 33 19.78 20.13 20.46 20.83 21.19 21.55 21.92 22.30 22.70 23 08 23.47 23.87 24.27 24.65 25.03 25.41 25.79 26.17 26.54 26.91 27.10 26TB EDITION Page 165 0683909 LEXOLDMONOQ5835 B6. .25 ,50 .75 1.00 1,25 1.50 1 75 2,00 2.25 2.50 2.75 3 on 3 25 3.50 3.75 4.00 4.25 4.50 4.75 5.00 5,25 5.50 5.75 6.00 6.25 6.50 6.75 7.00 7.25 7.50 7.75 8.00 8.25 8 50 8.75 Tw.8 .34 .70 1.04 1.38 1.74 2.10 2.44 2.80 3.14 3.50 3.86 4.22 4.58 4.94 5.30 5.68 6.04 6.40 6.76 7.14 7,50 7,88 8.26 8.64 9,00 9.38 9.76 10.14 10.52 10.90 11.30 11.68 12.06 12.46 12.84 MERCLOR Per Cent Available Cl by Volume .11 .21 .32 .43 .54 .65 .76 .87 .98 1.10 1.21 1.32 1.43 1.55 1.66 1.78 1.90 2.01 2.13 2.26 2.38 2.51 2.63 2.75 2.88 3.01 3.13 3.26 3.39 3.52 3.64 3.77 3.90 4.05 4.18 B*. 9.00 9.25 9.50 9.75 10.00 10.50 11.00 11.50 12.00 12 50 13.00 13.50 14.00 14.50 15.00 15.50 16 00 16.50 17.00 17.50 18.00 18.50 19.00 19.50 20.00 20.50 21.00 21.50 22.00 22.50 23.00 23.50 24.00 24.50 25.00 Tw.8 13.24 13.62 14.02 14.42 14.82 15.62 16.42 17.22 18.04 18 86 19.70 20.54 21.38 22.22 23.08 23.94 24.80 25 66 26 56 27.44 28.34 29.24 30.16 31.08 32.00 32.94 33.88 34.82 35.78 36.72 37.70 38.68 39.66 40.66 41.66 Per Cent Available Cl by Volume 4.30 4.43 4.57 4 71 4.84 5.09 5.38 S 65 5.94 6.24 6 52 6.83 7.12 7.41 7.71 8.01 8.31 8.60 8.92 9.23 9.54 9.87 10.19 10.51 10.84 11.18 11.52 11.89 12.23 12.60 12.95 13.33 13.71 14.11 14.50 Page 166 MONSANTO CBBMICALS 0663906 LEXOLDMON005836 WEIGHTS PEK GALLON AT 60 F. Arctic Acid 28% .................................................... Arctic Acid 56% . ................. Acetic Acid Glacial . . .......................................... Aluminum Chloride 32 B6 ............................................ Amyl Acetate.................................................................... Aqua Ammonia 18 B.................................................... Aqua Ammonia 20 B#.................................................... Aqua Ammonia 26 B<......................................................... Battery Acid 1.400........................................................ Butyl Acetate................................................................... Diacetone Alcohol................................................................ Ethyl Acetate.......................................................................... Iron, True Nitrate 47 Bi......................................................... Iron, Copperas Nitrate 47 B................................................. Iron, Perchloride 40 B6............................................................ Merclor........................................................................................ Muriatic Acid 18 Bi..................................................................... Muriatic Acid 20 Be....................................................................... Muriatic Acid 22 B.. .............................................................. Nitric Acid 36 B.............................................................................. Nitric Acid 38 B6. .......................................................................... Nitric Acid 40s B6.............................................................................. Nitric Acid 42 B6....................... Oleum 25% (at 15 C.)............................. ............... Oleum 60% (at 15 C.) ................................................................ Phosphoric Acid 75%..................................................................... Sodium Bisulfite 33 B.................................................................. Sulfuric Acid 66 B<....................................................................... Sulfuric Acid 98%............................................................................ Sulfuric Acid 100% (Monohydrate)........................................ Zinc, Cholride 52 B....................................................................... Zinc, Cholride 72 B<....................................................................... Weight per gallon *= Sp. Gr. x 8.337 1 Cubic Foot s= 7.480 gallons 1 Gallon == 3.785 liters Pounds 8 66 8.90 8.81 10.70 7.2 7 89 7.78 7 18 11.67 7.3 7.6 7.4 12.30 12 30 11.51 9.7 9.67 9.83 11.09 11.30 11.51 11.74 16 12 16 84 13.2 10.78 15.30 15.36 15. 41 13.00 16 56 26th edition Page 167 068390V LEXOLDMONOQ5837 INTERCONVERSION TABLES FOR TO -------- MULTIPLY BY COM ERT To FROM - Cu. In. To Cu. Ft. To Cu. Yd. To FI. Oz. To Pint To Quart T Gallon Cu. In. Cu. Ft. Cu. Yd. FI. Oz. 1.00000 1728.00 46656 0 1.80469 .0,5787 l.00000 27.0000 .001044 0,2143 .037037 1.00000 .03868 .554112 957.505 25852.6 1.00000 .034632 59.8442 1615.79 .062500 .017316 29.9221 807.896 .031250 .004329 7 48052 201 974 .007813 Pint Ou art Callon Crain 28.8750 57.7500 231.000 .003954 .016710 .033420 .133681 .0,2288 .0,6189 .001238 . 0049,51 . 0,8475 16.0000 32.0000 128.000 .002191 1.00000 2.00000 8 00000 .0*1369 .500000 1.00000 4.00000 . 0,6850 .125000 250000 1 00000 .0,1712 Oz. Troy l.b. Troy Oz. Av. Lb. Av. 1.89805 22.7766 1.72999 27.6799 .001098 .013181 .001001 .016018 .0*4008 .0,4882 .0,3708 .0,5933 1.05173 12.6208 .958608 15.3378 .065733 .788800 .059913 .958611 .032867 .394400 .029957 .479306 .008217 .098600 .007489 .119826 CC or Cram Liter or Kg. Cm. M. .061024 61.0237 61023.7 .0,3531 .035315 35 3146 .0,1308 .001308 1.3079S .033814 33.8140 33814.0 .002113 2.11337 2113.37 .001057 1 05669 1056.69 .0,2642 .264172 264.172 NOTE:--The small subnumeral following a zero indicates that tbe zero ia to be taken that number of times, thus .0,1428 is equivalent to .0001428. Values used in constructing table: 1 inch = 2.540001 cm. 1 cu. in. -- 16.587083 cc. = 16.387083 g. H,0 at 48C.(39F.) 1 lb. av. *" 453.5926 g. Page 168 MONSANTO CHEMICALS 0663908 LEXOLDMON005838 UMTS OF VOLUME AND WEIGHT MULTIPLY BY To Crain To Oz. Troy To Lb. Troy To Oz. Av. To Lb. Av. to to CC. or G. Liter Or Kg 252 891 436996 11799(>j 456.390 .526857 910.408 24581.0 .950813 ,043905 75.8674 2048.42 .079234 .5780117 998,848 26968 9 1,043)8 .036127 62.4280 1685.56 .065199 16 3871 28316.9 764556 29.5736 016387 28.3169 764.556 .029573 7302 23 1460 45 58417.9 1.00000 15.2130 30.4260 121.704 .002083 1.26775 2.53550 10.1420 .0,1736 16.6908 33.38 6 133.5?7 .0022w 1.04318 2.08635 8.34541 .0,1428 473.177 946.354 3785.42 064799 .473177 .946354 3.78542 .0,6479 480.000 5760.00 437.500 7000.00 1.00000 12.0000 .911457 14.5833 .083333 1.00000 ,075955 1.21528 1.09714 13.1657 1.00000 16.0000 ,068571 .822857 .062500 1.00000 31.1035 373.342 28.3495 453.593 .031104 373242 .028350 .453593 15.4523 15432.3 154320, .032151 32.1507 32150.7 .002679 2.67923 2679.23 .035274 35.2739 35273.9 .002205 2.20462 2204.62 1.00000 1000 00 1000000 .001000 ! 00000 looo on 1 lb. av. = 27.679886 cu. in H,0 at 4C. (39"F.). 1 lb. av. = 7000 grains 1 gal. = 8.34541 lb. 1 gallon = 58417.87 grains. 231 cu. in. 1 gal. = 3785.4162 g. To Cu. M. .0,1639 .028317 .0,2957 . 0,4732 . 0,9463 .003785 0r6479 .0,3110 .0,3732 . 0,2835 .0,1536 .000001 .001000 1 00000 24TB BOITION Page 169 PRINTED <N U. S. A. 0683909 LEXOLDMON005839 0683910 LEXOLDMON005840 f Monsanto Chemical Company wu one of the Brat to be awarded the INavy "E" and Bureau of Ordnance flag and the All-Nary "E" burgee 'in recognition of production of ordnance materiel vital to our national defeoae.1' It waa alao one of the Brat to be awarded the joint Army-Navy **E" burgee "repreaenting recognition by both the Army and Navy of erpecially meritorioua production of war materials." 0683911 LEXOLDMON005841 0683912 LEXOLDMON005842