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o'eafe Mr. X. J, Biellski Films-Packaging Division P. 0. Box I98 Centerville, Iowa 52544 nine 3* 1976 Medical Department Mr. T. K.Bayles Or. C. J.Broun*tein Mr. J. M.Cwikla Mr. J. V.Burkin Mr. V. L.Ketner Mr. X. V. Powell Mr. J. X. Rausch Dr. J. J. Welsh/Dr. K. S. lane Industrialhygiene Survey Centerville Plant, April 29, 1976 BUSINESS CONFIDENTIAL -------------------------------- Dear Mr. Bleliskl: An Industrial hygiene survey was conducted at Centerville on April 29, 1976. Air samples were collected and analyzed for vinyl chloride monomer or total dust content, l&e results of these samples are shown In the attached tables of data. lfce lateness of this report Is due partially to the time required to obtain analytical results and partially to an exceptionally heavy travel schedule the past two weeks. I regret the delay. The air sample collected on the person of the PVC Blender Operator did contain enough vinyl chloride monomer that It could be detected by the existing analytical technique. The 0.08 ppm, representing the exposure of this employee over five hours and three minutes of his work shift, representsthe first positive result this office has ever obtained on any employee at Centerville. This probably relates to the fact that this la the longest term single air sample collected to date on any of these employees. However, this result Is still well below even the existing action level for VCM in workroom air. ycc 062384 Mr. R. J. Bieilskl -2- JUne 3, 197b The air sample*, collected this time os the person of the Powdering- Machine Operator, gave a time-weighted average concentration of 17.7 milligrams of potato starch per cubic meter of workroom air over the k hours and 50 minutes duration of these samples. This result Is above even the present standard for a nuisance-type dust. This 06H& standard is considered as too high for any dust exposure both by the American Conference of Governmental Industrial Hygienists and by this office. The appearance of this Powdering Roam reflected this unusually high Concentration of airborne starch. There was much settled dust visible on all horizontal surfaces. This operation must be tightened to better contain the starch powder. While no air samples were collected this time in the FVC Extrusion Room, it was observed that the Ho. U Extrusion Machine was masking rather heavily. The existing exhaust ventilation system was unable to handle this anoke, and it did accwulate in this area. Experience would indicate that such smoke probably consisted mainly of water vapor and vaporized plasticizer material, and that it would not be highly toxic. However, this is not a normal operating conditi n, and such equipment must be repaired as quickly as possible. The solvent odor was very strong in the Frin|ii% Press Roam. This would suggest that the exhaust ventilation system might need cleaning to restore it to peak efficiency* I greatly appreciate the many courtesies extended to me during my visit. If I can be of further assistance, please let me know. Very truly yours, EGB/eg Enc. E. G. Brown, Industrial Hygienist ucc 062365 rotaj. dust; UfllOH CARBIDE CORPORATION PUma-Packaging Division Centerville, Iova April 29. 1976 Location Fovderlng-Machine Operator Powdering-Machine Operator mg/M3* Total mat 21.1 10.7 Remarks Personal Sample, 04/29/76. A.M. 2 hra., 20 min. Personal Sample, 04/29/76. P.M. 2 hrs., 30 Bln. * Potato atarch, the Baterial used in this operation, la a arterial of low toadcity. As such, the American Conference of Govermental Industrial Hygienist* classifies It as a nuisance particulate. The threshold limit value (TLV) for nuisance dusts is 15 milligrams per cubic meter of workroom air (06HA-1975)* However, both the ACGIH and this office recognize that 10 mg/M3 is a much more tolerable level for the human respiratory system. 062 Vinyl Chloride Moncoer UNION CAKBUE CORPORATION ttl*-Packagii Division Centerville, Iowa April 29. 1976 location On person of PVC Blender Operator (O.P.) ppm* VCM 0.08 Remarks Personal 8anple, 04/29/76, A.M, & P.M. 5 hrs., 3 Bin. * The threshold Unit value (TLV) for vinyl chloride Bonaner In workroom air is 1 part per Billion (by volwe) as an 8-hour, tine-weighted, average concentration (06HA-1975) f Mr. R. 1. Blackwell Hone and Automotive Products P. 0. Bax 698 Ottawa, Illinois 61350 May 6, 1976 Medical Department Mr. R. C. Andrevs/W. Clevenger Mr. R. Reward Mr. R. foster Mr. P. McBabb Mr. R. D. Todd Or. J. J. Welsh/Dr. K. 8. Lane Dear Mr. Blackwell: An industrial hygiene survey was nade at Ottawa on February 25-26, 1976. file lateness in this report is due to an extended delay in getting analytical results from the laboratory. The results for vinyl chloride and dust are shown on the attached tables. With regards to vinyl chloride it is recosnended that the Banbury operator on line 5 be rechecked since the level found was essentially at the Unit. In the silo area leakage was noted at the covers, and doors were open so that exhaust ventilation patterns were not noraal. The other locations checked were well below the Unit for vAnyl chloride. Ousts in the vinyl production areas were quite noticeable and house keeping could be considerably improved. The Units for total dust are based on the cristoballte content of the filler materials such as Silver Frost. It Is expected that additional sampling will be performed go ascertain better exposure evaluation to lead and tin duat in air since we were not able to use the data obtained on this survey. In other plant areas, there were sene noise problems noted and current ucc 062388 Mr. R. X. Blackwell May o, 197tJ practices to reduce overall noise levels should be continued since it is probable that 85 dBA will be the limit before the year is out* la extruder areas, if reduced ventilation rates are considered, it should be pointed out that ozone generated tram, treating could be a problem. Also, exhaust gases frem a process area should not be exhausted to another work area. the possible use of catalytic converters on fork trucks to reduce carbon monoxide in building areas was also discussed. The probable restriction of use of various chrome containing compounds as colorants for various products was also discussed. If adequate control were possible, these materials continued to be need. Thanking your., for thecourtesies extended, we remain Very truly yours, X, G. Brown Industrial Hygienist L. J. LaTrance Industrial Hygienist LJ1/S Xnc. Dust Concentrations UHIOH GARBHE CORPORATION Bone and Automotive Products Ottawa, Illinois February 25-26, 1976 Location Banbury operator Line 1 Total Dust n/M3 0.01^ ' " Line 1 1.00 " " Line 5 0.45 Composite Blender Operator 3rd Floor 0.46 Blender Operator 3rd Floor (Rowe) 1.50 Bladder Operator 3rd Floor (Rowe) 1.30 Fedd Operator VO Line Qround Floor 4.74 Fedd Operator VO Line Ground Floor 7.50 Remarks 2/25 Personnel Sanpler 2/26 " ft 2/25 " *1 2/26 " n 2/25 " ft A.M 2/25 " f F.M 2/25 " 2/26 " tt ^ Operating problens were present during this stapling period and very little Material was processed. The Unit for total dusts in this area would be 1.7 ag/M^ based on erlstobalite content. The Halt for tin is 0.10 ag/M^ and for lead 0.15 ag/M^. All of these staples were analysed for lead and tin, but due to apparent laboratory problens, they are not being reported. ucc 062390 Vinyl Chloride in Air TJHIOH CARBIDE CORPCRATIOIi Bone end Automotive Products Ottava, Illinois February 25-86. 1976 Location Calender operator Line 1 Calendar operator Line 5 Banbury operator Line 5 Stationery Saepler Tap of silo Stationery Stapler Airreyor Boon Vinyl Chloride PPBI ^0.0005 c. 0,0005 0.9h 1.60 <_ 0.0005 Remarks 3/25 Personnel Saaple 2/35 Personnel Saaple 2/26 Personnel Saaple 2/25 Pusping resin to silo 2/26 Pooping resin to silo Liaitffor vinyl chloride is 1 pert per million. IJCC 062391