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ii O 9 045625 r LABORATORY WASTE DISPOSAL MANUAL MANUFACTURING CHEMISTS ASSOCIATION 1825 CONNECTICUT AVENUE, N. W. WASHINGTON, D. C. 20009 The information and recommendations contained in this Laboratory Waste Disposal Manual have been compiled from sources believed to be reliable and to represent the best opinion on the subject as of 1969. However, no warranty, guarantee, or representation is made by the Manufacturing Chemists Association as to the correctness or sufficiency of any infor mation or recommendation herein, and the Association assumes no responsibility in connection therewith; nor can it be assumed that all necessary hazard warnings and precautionary measures are contained in this manual, or that other or additional information or measures may not be required or desirable because of particular or exceptional conditions or circumstances, or because of applicable federal, state, or local law. Copyright 1969 by Manufacturing Chemists' Association, Inc. Library of Congress Catalog Card No. 72-87285 Printed in the USA FIRST PRINTING, JUNE t969--3,000 CMA 045627 TABLE OF CONTENTS Section I. INTRODUCTION____________________________ 4 section II. HOW TO USE THE MANUAL ____ 5 ^section III. CHART HEADINGS DEFINED _______________ 6 Election IV. ABBREVIATIONS ___ 8 ^^ection V. REFERENCE CHARTS (alphabetical listing of chemical substances)_______ ____ 9 Section VI. WASTE DISPOSAL PROCEDURES__ ____ 121 No. la Organic Acid Halides _______________________ 123 No. 1b Inorganic Halides _____ 124 No. 2 Aldehydes ______________________ 125 No. 3 Alkali and Alkaline Earth Metals, Metal Alkyls, and Alkoxides _____ 126 No. 4a Chlorohydrins and Nitroparaffins 127 No. 4b Organic Halogen and Related Compounds ____ 128,129 No. 4c Substituted Organic Acids ____ ______ __ ____ 130 No. 5 Aromatic Amines ___________________________ 131 No. 6 Aromatic Halogenated Amines and Nitro Compounds 132,133 No. 7a Aliphatic Amines ______ ______ ____ __________ 134 No. 7b Organic Phosphates and Related Compounds 135 No. 8 Azides and Azo Compounds 136 No. 9 Carbon Disulfide ___ 137 No. 10 Caustic Alkali and Ammonia_________ 138 No. 11 Inorganic Salts_____ ________________________ 139 No. 12a Oxidizing Agents__ ____________ 140 No. 12b Reducing Substances_______ 141 No. 13 Mercaptans and Organic Sulfides_______ 142 No. 14 Cyanides and Nitriles ~__ 143,144 No. 15 Ethers ___ 145 No. 16 Hydrazines ________ 146 No. 17 Hydrides .__________________________ 147 Waste Disposal Procedures (continued) No. 18 Hydrocarbons, Alcohols, Ketones and Esters__________________ ______ 148,149 No. 19 Inorganic Amides and Derivatives____ _____ 150 No. 20 Organic Amides__________________ _________ 151 No. 21 Inter-Nonmetallic Compounds.............. 152 No. 22a Peroxides, Inorganic_________________ _____ 153 No. 22b Peroxides, Organic________________________ 154 No. 23 Sulfides, Inorganic_________ 155 No. 24a Acids, Organic (Limited to C, H and O Compositions).... 156 No. 24b Acids, Inorganic___________________________ 157 No. 25 Carbides __ 158 No. 26 Wastes to be dumped into land-fill or released to the air____________________ _ 159 No. 27a Recovery - Scrap Metals 160 No. 27b Recovery - Mercury _______________ ___ ____ . 161 No. 27c Recovery - Phosphorous (Yellow andRed) .... 162 No. 27d Recovery - Arsenic, Antimony, Bismuth.._ 163 No. 27e Recovery-Selenium and Tellurium ..... ......... 164 No. 27f Recovery - Lead and Cadmium Compounds ... 165 No. 27g Recovery - Beryllium Compounds ____ 166 No. 27h Recovery - Strontium and Barium Compounds 167 No. 27i Recovery - Vanadium Compounds 168 No. 27j Recovery - Carbon Tetrachloride, Carbon Tetrabromide and Phosgene 169 No. 27k Recovery - Miscellaneous_________ ___ ______ 170 No. 28 Deep Burial 171 No. 29 Direct Burning .... .......................... 172 SECTION VII. DISPOSAL MATERIALS--MINIMUM REQUIREMENTS ....... ____............ 173 SECTION VIII. BIBLIOGRAPHY ..... ...................................... 175 PAGE 3 CMA 045628 SECTION I. Introduction This manual is published as a service of the Safety and Fire Protection Committee of the Manufacturing Chemists Association. Its purpose is to assist laboratory personnel in developing an awareness of chemical hazards and in fulfilling their responsibilities to dispose of chemical wastes without personal injury, without hazardous adul teration of drains, and without excessive contamination of ground, air or water. Some 1200 chemicals are specifically listed in the manual. Therefore, because of the vast number not in cluded, this publication should be considered preliminary in nature. However, categorization of disposal procedures by chemical classes (See VI) offers a means by which information can be obtained on the disposal of chemicals not specifically listed. In addition to the normal fire and explosion hazards of flammable liquids and their vapors and the expected hazards of toxic materials, certain other hazards must be anticipated in waste disposal handling. Some materials are corrosive to drainage piping. Some react violently with water or with other chemicals. And others, though possibly relatively nonhazardous in themselves, adversely affect sewage disposal systems. Chemicals poured down the drain should be non-toxic or in concentrations below the threshold limit. The con centrations which may be transferred to the drain in any given location are controlled by water pollution standards. Copies of such standards can be obtained from the water pollution control agency in the state or interstate region. PAGE 4 In this manual recommendations for treatment of hazard ous chemical wastes, prior to disposal, are presented in basic outline. Detail is neither possible nor desirable, but all recommendations are directed towards the elimination or adequate reduction of the hazard potential. Some organic wastes can be converted to the non-toxic naturallyoccurring forms. For example, a high valence chromium compound (chromate) can be reduced to a harmless trivalent hydroxide. Certain other inorganic elements and their compounds are highly toxic in any soluble form. Therefore, it is recommended that these be recovered for re-use. Contaminated mercury is an example of this class of material. Recovered material can be shipped to the supplier for reprocessing. Toxic cyanides can be converted to less toxic cyanates or into complex iron cyanides. Very active chemicals, such as SnCI4 can be made less active by mixing with inert materials such as sand, kaolin or vermiculite, and then converted to less harmful forms which can be safely discharged to the drain. Certain materials can be safely destroyed by burning. The burning process for slow-burning compounds may be speeded up by dissolving in flammable solvents. Some incinerators are equipped to reduce carbon and carbon monoxide by means of afterburners, and to remove by products such as S02 and NO with scrubbers. The manual stresses safe procedures for on-site waste disposal from small laboratories, especially those in small communities not possessing sophisticated equipment. \ ; ' i ' ' ji 1 CMA 045629 SECTION II.------------------------------------------------------------------------------How to Use the Manual To obtain information on the hazards of a specific chemical substance and recommendations for its disposal as a laboratory waste, proceed as follows: (a) Find the chemical substance in the alphabetical listing in Section V. (If the substance is not listed, refer to the chemical class listings under Section VI in the TABLE OF CONTENTS. The substance will fall into one of these categories and the associated disposal procedure can be used.) (b) Note the information given in Section V on the health, fire and reac tivity hazards of the substance. Note other pertinent physical prop erties and consult the recommended references for more detailed information. (c) A waste disposal procedure number is given in Section V. Refer to this procedure in Section VI and proceed accordingly. NOTE: For emergency handling of spills and as a matter of good operational policy it is recommended that disposal equipment and materials be readily available and that all who may have to use them know where they are stored. Section VII lists essential equipment and materials and suggests minimum quantities required. CMA 045630 SECTION III. CHART HEADINGS DEFINED Substance/Formula Substances are listed alphabetically by "common" names. Substances which are crossreferenced (e.g. Acetal, see 1,1-Diethoxyethane) are not included in the sequence numbering. Waste Disposal Procedure (See VI) The number con tained in this column indicates the recommended waste disposal procedure as correspondingly numbered in Section VI. TLV (ACGIH) PPM (mg/M3) This column lists Threshold Limit Values as recommended by the American Confer ence of Governmental Industrial Hygienists. TLV's are given in parts of vapor or gas per million parts of air by volume at 25 C. and 760 mm. Hg pressure or (in paren theses) in milligrams of particulate per cubic meter of air. A threshold limit value refers to air-borne concentrations of substances and represents conditions under which it is believed that nearly all workers may be repeatedly exposed, day after day, without adverse effect. The ACGIH advises that threshold limits should be used as guides in the control of health hazards and should not be regarded as fine lines between safe and dangerous concentrations. For further information contact ACGIH at 1014 Broadway, Cincinnati, Ohio 45202. N.F.P.A. The three columns, Health, Fire and Reactivity refer, in most cases, to a numerical system for the Identi fication of the Fire Hazards of Materials (NFPA No. 704M) developed by the National Fire Protection Asso ciation. The numbers given in these columns can be found in NFPA No. 49 Hazardous Chemicals Data and NFPA No. 325M, Properties of Flammable Liquids, Gases, Solids. In a few cases another source is indicated, e.g., a numeral followed by a subscript S refers to Dangerous Properties of Industrial Materials by N. Irving Sax. Sp. Gr. (Specific Gravity). Specific gravity is expressed in grams per milliliter, or density relative to water. Vap. Dens. (Vapor density). Vapor density is the relative density of a vapor or gas compared with air expressed as 1.0. FI. Pt. (Flash Point). The flash point of a liquid is the tem perature at which it gives off vapor sufficient to form an PAGE 6 CMA 045631 CHART HEADINGS DEFINED--Continued ignitible mixture with the air near the surface of the liquid. The flash point figures in the chart represent closed cup tests except where the open cup flash point is designated by the initials "oc" following the figure. ignit- Temp. (Ignition Temperature). The ignition tempera ture of a substance, whether solid, liquid, or gaseous, is the minimum temperature required to initiate or cause self-sustained combustion independent of the source of heat. Flam. Limits % (Flammable or Explosive Limits in air). In the case of gases or vapors from flammable mixtures with air or oxygen, there is a minimum concentration of vapor in air or oxygen below which propagation of flame does not occur on contact with a source of ignition, and also a maximum concentration above which propagation of flame does not occur. The concentrations (expressed in % by volume) between which propagation can occur are known as the lower and upper flammable (or explo sive) limits. B.P- (Boiling Point). The boiling point of a liquid is the temperature of the liquid at which its vapor pressure equals the atmospheric pressure. M.P. (Melting Point), Expressed as C and (F). Sol. in H^O g/IOOg (Solubility of the substance in grams when dissolved in 100 grams water at room tempera ture). The statement "insol." is used for zero solubility, e.g. cuprous cyanide and calcium carbide. "si. sol." means less than 5 grams soluble in 100 grams water, e.g., bromine and benzoic acid. "sol" means 5 to 50 grams soluble in 100 grams water, e.g., ethylene and barium nitrate. "v. sol." means over 50 grams soluble in 100 grams water, e.g., potassium carbonate and ethyl fluoride. "so" means soluble in all proportions, e.g., sulfuric acid and acetone. Superscripts indicate the centigrade temperature at which the amount stated (in grams) is soluble in 100 grams of water. For example, .52ir' indicates that .52 grams of this substance will dissolve in 100 grams of water at 15C. Misc. Ref. See bibliography (Section VIII). CMA 045632 SECTION IV. Abbreviations Note: The "Misc. Ref." columns in the charts (see Section V) list sources of information. For explanations of these abbreviations and names of publications, see Section VIII. Other abbreviations used in charts ace. -- acetone ale. -- ethyl alcohol atm. -- atmospheres of pressure bz. -- benzene CCI4 -- carbon tetrachloride CAR -- carcinogenic--Only chemicals listed in 1968 as carcinogenic by the Department of Health of the State of Pennsylvania are marked CAR. chi. -- chloroform CS2 -- carbon disulfide dec. -- decomposes exp. -- explodes h -- hot insol. -- insoluble iso. -- isomeric m. -- meta MeOH -- methyl alcohol Misc. Ref. -- Miscellaneous References mm -- millimeters of mercury n -- normal o -- ortho org, sol. -- organic solvents Dr -- para sec -- secondary subl. -- sublimes sol. si. sol. tert. -- soluble -- slightly soluble -- tertiary v. sol. CO -- very soluble "" soluble in all proportions < -- less than > -- greater than a m-- alpha p -- beta y -- gamma PAGE 8 CMA 045633 SECTION V. REFERENCE CHARTS Alphabetical Index of Chemical Substances substance/formula ^j^^Aean*phttwn Ci2Hl0 Waste Dis posal Pro cedure (See VI) TLV (ACGIH) PPM (mo/M3) N. F. P. A. Health Fire React. 18 - Acetal see 1,1 Diethoxyethene Sp. Gr. 1.02 Vap. Dens. (Air=1 > FI. At. C <F| Ignit. Temp, C (FI Flam. Limits % B.P. C lF) - 278 (532) M.P. cC lF) 96 (205) Sol. in HjO 9/IOOg Insol, Other Solvents bz. chi. Misc, Raf. 2 Acetaldehyde ` CH3CHO 3 Acetic Acid ' CH3COOH 4 Acetic Anhydrida (CH3C0)2O 5, Acetone CH3COCH3 6 Acetone Cyanohydrin ' |CH3>2CtOH)CN 7. Acetonitrile CH3CN Acetyl Acetone, see 2,4-Pentanedione g. Acetyl Bromide CH3COBr 9. Acetyl Chloride CH3COCI 10. Acetylene c2h2 Acetylene Dichloride, ^MCe 1,2 - Dichjoroethylene 2 200 2 4 2 .78 1.52 -38 185 4-57 21 -124 ce ale., bz. BDH, MCA (--36) (365) (69) (-19D 24a 10 2 2 1 1.05 2.1 43 (109) 426 (800) 4-16 118 (244) 17 (61) 00 org. solv. MCA, AIA, NSC, NTTC. BDH, 24a 52 2 1 1.08 3.5 54 (129) 380 (716) 3-10 140 (284) -73 (-99) a ale., chi. MCA,SDH 18 1000 3 0 .79 2.0 -18 538 3-13 56 -94 MCA, AIA, (0) (1000) (133) (-1371 00 ale., bz. NSC, BDH, NTTC 14 10 4 1 2 .93 2.9 74 688 (165) (1270) 82 (180) -19 (--2.2) v.sol org. solv. BDH, MC8, MCA 14 40 3 3 3 .79 1.4 6 524 80 -41 BDH, (43) (975) 4-16 (176) (-42) 00 ale., chi. MCB, MCA la 5 3 3 2 la 5 3 3 2 IS (.1) 1 43 1,6 1.1 2.7 .91 .9 - 77 -96 (170) 1-141) dec. bz., chi. BDH, MCB 4 390 (40) (734) 51 (124) -112 (-170) dec. ace., bz. chf, BOH,MCB 335 (635) 3-82 -83 (-118) sub!. s|. sol. ace., bz, MGB, NSC PAGE 11 CMA 045635 SUBSTANCE/FORMULA k Acetylene Tetrabromide, 1 see Tetrabromoethane Acetylene Tetrachloride, see Tetrachloroethane Acetylene Trichloride, see Trichloroethylene 11. Acetyl Peroxide {CM3C01202 Acid Chromate Solution, see Cleaning Solution 12 Acridine C13H9N 13 Acrolein CH2=CHCH0 14. Acrolein Dimer (CH2=CHCHO)2 IB Acrylic Acid CH2bCHC00H 16 Acrylonitrile ch2=chcn 17 Adipic Acid COOH (CH2)4C00H Waste Dis posal Pro cedure (See VI} TLV (ACGIH) PPM Img/M'3} N. F. P. A, Health Fire r React. 1 Sp. G, Vap. Dens. (Air=1) FI, Pt. 6C (F) i^ ; '1 ' ill; 1!1 1! 1! 1 i i 22b | 1 2 4 i 1,2 4.07 i1 !! 1S Ignit. Temp. *C (F) Flam, Limits % 8.P. C (F) 63 exp (145) 1 M.P. C <F) Sol. m H2O g/IOOg Other [ Solvents Misc, Ret 30 (86) si. sol. 1 CCI4, ale. j MCB I 5 1 *s _______ 1I_______ 2 .1 3 3 2 3\ 2 24a - 3 j 2! 1 14 20 4| 3j 24a Is ! 's - 1 1.005 | 3 .84 1.9 -26 278 (-15) (532) 1 1.1 i 48 ; (118) 2 1.05 2.5 52oc! 429 (126) | (804) _____ _L_____ ^ 2 .81 1.8 Ooc 481 (32) (898) 1.4 191 422 (376) (792) 345 (653) 110 (230) si. SOI. ale., bz., CS2 53 -87 3-31 (127) (-125) v sol ale 151 (304) 142 (288) 12 (54) <w ale. 3-17 77 (171) -83 sol. (-117) ale. 267 (513) 153 (307) si. sol. ale. MCA. BDH, AIA,NSC BDH MCA. BDH, AIA. MCB, NTTC AIA 18. Adipomtrile CN(CH2)4CN 14 3S 2S .97 93 (199) 295 (563) 2.3 (36) si. sol. ale,, chi. Aerozine 50, see Hydrazine "AGE 12 CMA 045636 SUBSTANCE/FORMULA ,9. Aldrin Ci2Hsc|6 20. Alizarin Oyts C14H8O4 21 Allene CH2'C"CH2 2?, Ally! Acetate CH3CQ2CH2CHCH2 23. Allyl Alcohol ch2=chcnzoh 24 Allyl Amine ch2chch2nh2 25 Allyl Bromide CH2CHCH2Br 26. Allyl Chloride CH2CHCH2CI 27 Allyl Chloroformate CH20HCH2CO2Cl Allylene, see propyne 28. Allyl Glycidyl Ether C6h10C>2 29. Allyl Iodide CH2CHCH2I Waste Dis* posai Pro* cedure (See VI) TCV (ACGIHI PPM Img/M3) N. F, P. A. Health Fire React. Igmt. Vap. FI. Ft. Temp. Flam, B.P, Sp. Dens. C C Limits C Gr. (Ar=1) (F> |F) % (F) M.P. C (F) Sol. in HjO g/100g Other Solvents Misc. Ref. 4b (.25) 3 18 "s 18 18 % 18 2 3 7a 3 4b 3 4b 1 3 4b .1 3 10 - *St 31 31 31 31 31 66 (150) 104 (219) insol ale., bz,, ace. 1.8 .93 .85 2.0 .76 2.0 1.4 4.2 2loc, 374 (70) (705) 21 378 (70) (713) 3*18 -29 (-20) 374 (705) 2*22 -1 295 (30) (563) 4-7 .94 2.6 -32 (-26) 392 (738) 3-11 1.1 4.2 31 (88) 430 (806) 289 (562) sl. sol. bz., CS2/ ale. -34 -136 (-30) (-213) _ 103 (217) 1 sl sol. ! ale. MGB SDH 97 -129 (207) (-200) " | ale. SDH, MCA 58 (136) ^ \ a(c,,chl. MCB 70 -119 tnsol (158) (-182) ale., chi. CS2, CCI4 BDH, MCB 45 (113) -136 insol. (-213) ale., ace., bz. BDH, AIA, MCB. MCA 110 (230) MCB 16 10 % 4b 2 3s 2s .97 1.8 57 (135) 5.8S 154 (309) -100 sol. (-148) ace. 102 (216) -99 insol. (-1461 ale., chi. MCB PAGE 13 CMA 045637 SUBSTANCE/FORMULA ' 30. Ally1 Propyl Disulfide C3H5S2C3H7 31. Alum KA!(S04>2 12H20 32. Aluminum A) Waste Dis posal Pro cedure (See VI) TLV (ACGIH) PPM Imfl/M3) N. F. P. A. Health Fire React 13 2 % 2S 11 Is 27e 0 1 1 33. Aluminum Alkyls RALX 3 34. Aluminum Borohydride Al (8H4)3 17 3S 35- Aluminum Bromide Al Br3 1b 36. Aluminum Carbide AI4C3 37. Aluminum Chloride AICI3 25 1b 30 2 38. Aluminum Ethoxide (C2H5)3AI03 3 Aluminum Lithium Hydride, see Lithium Aluminum Hydride 39. Aluminum Nitrate AI|NO3)3.9H20 11 2S 2S 40. 2-Amino-Diphenylene Oxide C12H9NO 6 CAR Ignit. Vep. FI. Pt. Temp. Flam. S.P. Sp. Dens. C *C Limits c Or. |Air=1) (F> (F) % (F) M.P. "C <F) Sol. in H2O g/IOOg Other Solvents Mise. Ref. MCB 1.7 2.7 - .8 <0 32l 2.4 2.4 200 (392) 92.5 (198) 11.420 2056 (3733) 660 (1220) insol. NTTC Al A 45 (113) -65 (-85) Al A, NSC 263 (505) 98 dec. (208) ale., ace., CS2 BDH, MCB dec. 1400 dec. (2552) 183 (361) 194 (381) at 5 atm 69.915 ale., CCI4 205 (401) 134 dec. (273) si. sol. MCA, BDH, NSC, 150dec. 70 (302) (158) 63.725 CS2 ale., ace 94 (201) PAGE 14 CMA 045638 substance/formula ^^^H*Amtnoathanol, Ethanolamine 41, Aminoethyltthanol Amina ' NH2(CH2)2NH(CH2J2OH 42- 2-AminOpyridin* CgHgNj 42. Ammonia, Anhydrous NH3 44 Ammonia, AQUA IMH4OH 45 Ammonium Dichromite (NH4)2Cr207 4$. Ammonium Fluoride nh4f Ammonium Hydroxide, see Ammonia, Aqua 47, Ammonium Nitrate NH4NO3 48, Ammonium Perchorate NH4CIO4 49, Ammonium Persulfate (NH4)2S20g 50. Ammonium Sulfamate NH4OSO2NH2 Waste Dis posal Pro cedure (See VI) TLV (ACGIH) PPM (mg/M3) N. F, P. A. Health Fire React. Ignit Vap. FI. Ft. Tamp. Flam. B.P. Sp. Dens. C *C Limits "c Gr. (Air=1) (F) (F) % <F) M.P. "C <F> Sol. in HjO g/lOOg Other Solvents Misc. Ref. 7a 5 .5 10 50 10 50 12e ui 11 2 1 0 1.03 3.65 129 368 (265) (695) 244 (471) v, sot. ale, NTTC % 3 1 0 .77 .59 2S *S 2.2 204 (399) 58 (136) 651 (1204) 16-25 -33 --78 (-28) (-108) 16-25 -72 (-98) sol. org.solv. 89.9 org. solv, sol. MCA, NSC, AIA, NTTC, MGB MCA, BDH, 3s 2S iSOdec 15 (356) 31 ale. MCA % 1.0 - subl. 100 ate. 11 2 1 3 1.7 12a 2 1 4 1.9 12a is 2s 19 (15) is 's 19 exp. 210dec. 169 (410) (336) 118 ale., ace., MeOH NSC,NTTC - dec. 10.70 aca MCB - 120dec. 58.2 dec. (248) h2o' 160dec. 125 (320) (257) 16610 PAGE 15 CMA 045639 SUBSTANCE/FORMULA ^r51. Ammonium Sulfide (NH4)2S Waste Dis posal Pro cedure (See VI) TLV (ACGlHl PPM (mg/M^) N. F. P. A. Health Fire React. 23 2S 52. Ammonium Thiocyanate NH4CNS 11 'St 53. Ammonium Vanadate NH4VO3 27i 54. n-Amyl Acetate CH3COO(CH2)4CH3 18 100 1 3 0 55. i$o-Amyl Acetate 18 200 1 3 0 CH3COO{CH2)2CH(CH3)2 56. sec-Amyl Acetate CH3C02CH2CHCH3C2H5 18 125 1 3 0 57. n-Amyl Alcohol CH3(CH2}4OH 18 100 1 3 0 58 iso-Amyl Alcohol (CH3}2CH(CH2>20H 59. Amyl Alcohol CH3CH2C{CH3)OHCH3 18 100 1 1 2 !118 100 3 0 0 60. Amylamine CgH-|iNH2 7a 33 0 61. Amyl Bromide CgHiiBr 4b 13 0 62. Amylene CgH-IQ 1_____________________________________1 18 i4 0 Ignit. Vap. FI. Pt, Temp. Flam. B.P. Sp. Dens. C C Limits C Gr. (Airsl) (F) <*F) % lFI M.P. C tFI Sol. in h2 g/IOOg 1 1 Other Solvents Misc. Ref dec. v. sol. ale., dec BDH h2o1Q0 1.3 I70dec. 150 128 ale., ace (338) (302) 2.3 200dec. ,5215 dec. (392) HjO100 88 4.5 25 379 1-7.5 148 -79 sl. sol. ale. (77) (714) (298) (-110) BDH,NSC .88 4.5 23 380 1-7.5Q 142 (73) (715) @212 F (288) ale. BOH,NSC .86 4.5 32 (89) 1-7.5 121 (250) ale NSC .82 3.0 33 300 1-10 137 -79 insol. ale. (91) (572) (279) (-110) BDH,NSC 81 3.0 43 347 '-9o 132 (109) (657) @212 F (270) aic. BDH .81 3.03 19 437 1-9 102 -12 sl. sol. ale. (66) (819) (216) (10) BDH .8 3,0 7oc. (45) 103 (217) -55 (-67) QQ ale. 1.22 32 (90) -54 (130) -95 (-139) insol. ale .66 2.4 --2 273 1.5-9 30 -165 insol. ale. (28) (523) (86) (-265) BDH PAGE 16 CMA 045640 substance/formula Ether ^^Bci()H220 64 iso-Amyl formats ' hcooCshh 65, Amyl Mercaptan CH3(CH2>4sh 66 iso-Amyl Nitrate C5HHNO3 67. Amyl Nitrite CH3(CH2UN02 68, Aniline C6H5-NH2 69. o-Art>saWehyde C8h82 70 o-Amsidine CH3OC6H4NH2 71 p-Anisdine ch3oc6h4nh2 72. Amsole C6h5OCH3 73. Anthracene C6H4(CH)2CeH4 74. 2'Anthramine C14H11N Waste D* posal Pro* cedure (See VI) TLV (ACGIH) PPM (mg/M3) N. F. P. A. Health Fire React. 15 2 0 Sp. Gr. .74 Vap. Dens. <Aip=1) FI. Ft. C <F) 5,46 57 (135) Ignit. Temp. C lF) Flam. Limits % 171 (340) 8.P. C <F> 190 (374) j! M.P. C tF) H2O g/100g Other 1 Solvents 1 Misc. Ref -70 (-94) msol. ale. IS 1 3 0 .89 4.0 26 (79) 131 -74 si. sol. (267) (-10D ale BDH 13 20 2 3 0 .84 1.1NFPA 18 (65) 4a 1 2 2 .99 52 (125) 127 (261) -76 (-105) insol. 152-7 (306-15) si sol ale, | t-- ale. BDH 4a 1 2S 2 .85 10 209 104 si. sol ale. BDH (50) (408) (220) 55 3 2 0 1.02 3.22 70oc 770 184 -6 sol. alc.r bz NTTC, (158) (1418) 1.3 (3631 (21) MCA. BDH 2 2 1 0 1.12 118 |244)oc 250 (482) 2.5 insol. (36) ale 5 (.5) 2S 224 (435) si. sol ale. BDH 5 (.5) 2S 243 (469) si. sol. ale. BDH 15 1 2 0 .995 3.72 52oc. - 154 -37 insol. ale. (126) (3091 (-35) 18 2S 1.25 6.15$ 121 540 340 217 insol. bz (250) (1004) .6- (644) (423) 5 car 236 (457) insoi. ale. PAGE 17 CMA, 045641 SUBSTANCE/FORMULA " 75. Antraquinone C6H4(CO)2C6H4 Waste Dis posal Pro cedure (See VI) TLV (ACGIH) PPM (mg/M3) N, F. P. A. Health Fire React. 18 's TS Ignit. Vap. FI. Pt. Temp. Flam. B.P. Sp. Dens. C C Limits c Gr. (Air=1) (F) <F) % <F) M.P. C (yF) Sol. in H2O g/IOOg Other Solvents 1.44 7.16s 185 (365) 380 (716) 286 (547) insol. ale. <sl. sol.) Misc. Ref 76. Antimony Sb 27a (.5) 2s 6.68 1380 (2516) 630 (1166) insol. 77 Antimony Hydride, see Stibine 77 Antimony Pentachloride SbCIs 27d (.5) 3S 2.34 140 28 dec. (284) (37) CHCI3 BDH 78. Antimony Pentasuifide Sb2S5 27d (.5) 3 1 1 75dec. insol. (167) 79 Antimony Trichloride SbCl3 27d (.5) 3s 3,14 223 (433) 73 (163) 6020 ale., bz., ace., chi. BOH,MCA 80. Antimony Trioxide Sb203 81. Argon Ar 27d (.5) 26 3S 5.2 1.8 - 1550 656 si. sol. (2822) (1213) -186 -189 (-303) (-308) 4 MGB 82. Arsenic A$4 27d (.51 3S 2S 5.7 615subl insol. (1139) NSC 83 (7-Arsenic Acid H3As04y3H20 27d (.5) 3s ~2 160dec 35.5 (320) (95.7) 16.7 ale. BDH 84. Arsenic Trichloride ASCI3 27d (.5) 3s 2.16 6.25s 63 (145) -9 (15.8) dec. ale. BDH,NSC 85. Arsenic Trioxide As;03 27d (.5) i_____________________ 3AGE 18 3s 3.74 193subl 1.22 (379) ale. BDH, MCA, NSC CMA 045642 SUBSTANCE/FORMULA Waste Dis posal Pro cedure (Sea VI) TLV (ACGIH) PPM (mg/M3) N. F. P. A. Haalth Fire React. Ignit, Vap. FI. Pt. Temp. Flam. B.P. Sp. Dans, C C Limits C Gr. (Air=1) (F) <F) % tF) M.P. C lF) Sol. in HjO g/lOOg Other Solvents Misc. Ret Arylem, Savin 87. AphH gg, Auramine [|CH3)2NC6H4]C:NHCI ~2T p-Lv 5 0 0 1.1 204+ (400) 485 (905) >371 >700 267 si. sol. (513) ale., chi NTTC gg, Azindina (CH2)2nh gO. 2,2'-Azonaphthalene Cioh7N:NC10h7 91. Axoxybenzene C6HS(NON)C6H5 5 .5 3 3 3 .83 1.5 -11 322 3.6*46 56 -72 oe org. solv, (121 (612) (133) I--98) 2Q8solv, insol. hot bz. 3 (408) 8 !S 1.16 87 (189) 36 insol. (97) ale. 92. Barium 0a 93. Barium Chlorate Ba(CI03>2-H20 27h (.5) 2S 2S 3.5 12a 1,5) 1st St 'St 1140 725 (2084) (1337) 120 (248) dec. 27 40 ale. ace , ale. 94. Barium Chloride BeCl2 27h (.5) 2S os 2.8 1560 925 (2840) (1697) 37,526 95. Barium Hydroxide 8a(0H)2'8H20 96. Barium Nitrate Ba(NC>3)2 27h (.5) 27h (.5) 2S 1 0 3.18 1 3.2 780 78 (1436) 1172) 6.6'5 ale. - 592dec. 8.720 (1098) 97. Barium Peroxide 27h (.5) 1 0 1 4.98 ------------------------------------------- 800 (1472) 450 (342) sl. sol. PAGE 19 i j CMA 045643 SUBSTANCE/FORMULA ^ 98. Batteries, Dry Celb 99. Batnrlts. Wat Call] 100. Banzai Chloride c6h5chci2 101. Benzaldehyde C5H5CH0 102. 1,2-Benzanthracene Ci8H14 103. Benzene c6h6 Benzene Monochloride, see Chlorobenzene 104. Benzene Sulfonic Acid c6h5so3h 105. Benzene Sulfonyl Chloride CgHgSC^CI 106. Benzidine (C6H4)2(NH2)2 107. Benzoic Acid C6H5COOH 108 Benzonitrile C6H5CN 2,3'Benzophenanthrene, . see 1.2-Benzanthracene PAGE 20 Waste Dis posal Pro* cedure (See VI) TLV (ACGIH) PPM (mg/M3) N, F. P. A. Health Fire React, 26 27a 4b 2 220 18 car 18 25 2 3 0 Ignit. Vap. FI. Pt. Temp, Flam. B.P. Sp. Dens. C C Limits C Gr. (Air=1) (F> <F) % (F) M.P. "C (F) Sol. in H2O g/IOOg Other Solvents Mise. Ret. 1.26 1.04 3.7 .88 2.8 64 (147) 192 (378) -11 562 (12) (1044) 1.4-8 NSC 205 (401) -- 16 (3.2) insol. ale. BDH 178 (352) -56 (-69) si. sol. ale. BDH 435 (815) 162 (324) insol. bz. 80 (176) 5.4 si. sol. ale., ace. (41) Al A, BDH, NTTC, MCA 4c 1. 5 car 24a 14 % 3$ Is is 3S - - 525dac. sol. ale. BDH (977) - - - 252 14.5 insol. hot ale. BDH (485) (58) 1.25 402 (756) 128 (262) si. sol. ale. 1.32 "Zs 121 574 (250) (1065) 249 (480) 122 (252) si. sol. ale,, bz. 1.01 exp. -13 al. sol. ale. BDH (376) (8.6) CMA 045644 SUBSTANCE/FORMULA ^^^^Bepzoqutnone, Quinone 109 eamOtricMorida ' C6H6CCl3 no Benzotrrfluoride C6H5Cf3 111 Benzoyl Chloride c6h5coci H2 Benzoyl Peroxide ' (C6HsC0)202 3,4-Benzophenanthrene see 1,2-Benzanthracene 113, Benzvl Acetate CH3CO2CH2C6H5 114. Benzyl Alcohol C6H5CH2OH 115, Benzyl Amine C6H5CH2NH2 116. Benzyl Benzoate C6H6C02CH2C6H5 117. Benzyl Bromide C6H5CH2Br 118. Benzyl Chloride c6H5c h2ci Waste Dis posal Pro cedure (See VI) TLV (ACGIH) PPM (mg/M3) N. F. P. A. Health Fire React. Ignit. Vap. FI. Pt. Temp. Flam. B.P, Sp. Dens. C C Limits C Gr. (Air=1) <FI (F) % (F) M,P. C (F> Sol. tn H2O 9/IOOg Other Solvents Misc. Ret 4b 2S 4b 4 3 la 3 2 22b (5) 1 4 1.38 6.8S 0 1.19 5,04 12 (54) 1 1.22 4.88 72 (162) 4 1.33 80 (176) 214 (417) -5 insol. (23) ale., bz. 101 (214) -29 (-20) insol. ale. 197 (387) -.5 (31) dec. bz,, CS2 ex. 106 $[. sol. bz.. ace. (223) SDH BDH BDH BDH, MCA. NFPA 18 1 1 0 1.06 5.is 102 461 214 -51.5 si. sol. ale. (216) (862) (4171 (-61) 18 2 1 0 1,04 3.7S 101 436 206 -15.3 4 ale., ace., (213) (817) (403) (4) chi. S% ,98 63 (145) 185 (365) m ale. BDH 18 1 1 0 1,11 2.3s 148 481 323 21 insol. ale., ace., (298) (898) (614) (70) bz., chi. 4b 3S 1.44 5.8s 198 (388) -4 insol. ale. (25) BDH 4b 2 2 1 1,10 4.36 67 585 1.1- 179 -39 insol. ale., chi. BDH, MCA (153) (1085) (354) (-38) PAGE 21 CMA 045645 SUBSTANCE/FORMULA 119. Benzyl Chloroformate CICO2CH2C6H5 120. 8enzyl Cyanide C6H5CH2CN Waste Dis posal Pro cedure (See VI) TLV (ACGIH) PPM (mg/M3) N. F. P. A. Health Fire React. 4b 2S 14 3s Ignit, Vap. FI. Ft. Temp. Flam. B.P. Sp. Dens. C C Limits C Gr. (Air=1) <F) (F) % (F) M.P. C (F) Sol. m HjO g/lOOg Other Solvents Misc. Ret 103 (217) dec. dec., ale. 0DH 1.02 234 (453) -24 (-31) insol. ale. SDH Benzal Chloride see Benzylidene Chloride 121. Benzyl Mercaptan C6H5CH2SH 13 1 122. Beryllium Be 123. Beryllium Salts -Mb' ^CL, (.002) 28g (.002) 124. Biphenyl <C6H5>2 125. N-4-Biphenylacetohydroxamic Acid 18 5 .2 126. 2'Biphenylemine C6H5C6H4NH2 5 2S 41 St 21 2 1,06 *-3s 70 (158) 194 (381) insol. ale., CS2 1 1.86 2970 (5378) 1278 (2332) insol. AIA, NSC AIA. BDH 0 1.2 6.3s 113 540 6-5*80 256 70 insol. ale. (235) 11004) @232 F (493) (158) 171 (340) 0 1.16 5.8 452 (846) 299 49 (570) (120) insol. ale., bz. Biphenyl, 4,4'Diamino, see Benzidine 127. Bismuth Chloride BICI3 128. Borax, Anhydrous N32B407 129. Boric Acid H3BO3 PAGE 22 fill 3S - 4,75 - - 441 230 dec. ale., ace. (826) (446) 11 2S 3s - 1.72 - 1575 741 1.06 (2867) (1366) AIA 25b (15) 2S - 2.46 - - 1860 169 6.330 ale., MeOH AIA (3380) (336) CMA 045646 substance/formula ^^10h170H Waite Oiv posal Pro cedure (See VI) TLV (ACGIHI PPM <mo/M3) N. F. P. A. Health Fire React. 18 2 2 0 131. Boron B 26 2S 2S <32 Boron Fluorida-Ethyl Ethar Complex C4HlO0F3<) 21 1 3s. 2St Ost Boron Hydrid, see Di-,Penta-, or Deca-Boranes Vap. FI. Pt. Sp. Dent. C Gr. (Ain=1) TF> 1.01 5-31 s 66 i (15T) l9ht Temp. C ( F) Flam, Limits % B.F. C (F) M.P. C <F) Sol. in g/IOOg Other Solvents 212subl insol. (413) ale., ac, Mtsc. Ret 3.33 2550 2300 (4622) (4172) insol. AIA 1.1 64oc. (147) -110 -128 (-166) (--198) so). Al A 133. Boron Oxide B2O3 24b 15 2S 134 Boron Tribromide BBr3 21 2s 135 Boron Trichloride ' BCI3 21 2S 136. Boron Trifluoride bf3 21 1 3 0 1 137. Boron Trifluoride Complexes with Acetic Acid end Mentanol 21 % 2.46 2.65 1.35 4.03s 2.99 I860 13380) 460 (860) sol. 92 (196) -45 (-49) dec. - 12.5 -107 dec. (54) (-161) -99 (-146) -127 (-197) 106 AIA a)c., CCI4 AIA ale. AIA BOH, MGB ale AIA, MGB AtA, BDM 138. Bromic Acid HBr03 139. Bromine B<2 140. Bromine Pentafluoride BrFs 12e 12* .1 4 21 3 3S (MGB) 2St 3.19 0 1 3.1 5.5 - 4Rb 2.48 6.05S lOOdec V. sol. (212) BDH - 59 (138) -7 (19) 4.20 ale., CS^ chi. AIA, BDH. NTTC, MCA, NSC 40 -61 (104) (-78) dec, MGB PAGE 23 CMA 045647 SUBSTANCE/FORMULA | M41. Bromine Trrfluoride BrF3 142. Bromo-Acetic Acid CH3BrC00H 143. Bromobenzene C6H5Br 1-Bromobutene, see Butyl Bromide 144. Bromochloromethane CH2BrCI 145. Bromoethene CH3CH2Br 146. Bromoethylena CH2CHBr 147 Bromoform CHBr3 Bromomethane, see Methyl Bromide Bromopentane, see Amyl Bromide Bromopropane, e Propyl Bromide 3-Bromopropene, see Ally 1 Bromide Waste Dis posal Pro cedure (See VI) TLV IACGIHI PPM (mg/M3) N. F. P, A. Health Fire React. Z1 1 % 4Rft Sp. Gr. 2.84 Vap. Dens, (Air=1) FI. Ft. C (F) Igmt. Temp. c (F) Flam. 1 mits % B.P. C <F) - 127 (261) M.F. C <F| Sol. in H2O g/IOOg Other Solvents Misc. Ret 8.8 (48) dec. MGB 4c 2St 1.93 208 (406) 49 (120) 00 ale. BOH 4b 2 2 0 1.52 5.4 51 566 155 -31 msol, ale., bz., BDH 1124) (1051) (311) (-24) chi., CCI4 26 200 1.99 4.46s 4b 200 2 3 0 1.46 3.76 4b 500 2S (MGS) 26 .5 2s % - 1.49 - 2.89 69 (156) -88 insol. (-126) org. sot. 511 (952) 6.7-11.3 38 (100) -119 si. so). (-182) ale. - 15.8 -138 insol. ale. (60) (-216) 150 (302) -6 (21) si. sol. ale., bz., chi. BDH BDH PAGE 24 CMA 045648 SUBSTANCi/FORMULA 3.0romopyn, se Prooargyl Bromide 14g Q-Bromotolune CH3C6H4Br 149 Bromotrifluoromethana ` CBrF3 150. Bronze Alloy 151. Brucine C23H26N204 152- 1,3-Butadiene CH2=ICH)2s*CH2 153. n-Butane C4H10 154. 190`Butane CH(CH3)3 n-8utanol see n-Butyl Alcohol Butanone, see Methyl Ethyl Ketone 155. 1-Butene CH3CH2CH=CH2 156. 2-Butene CH3CH'CHCH3 2-Butoxyethanol, see Butyl Cellosolve Waite Dis posal Pro cedure (See VI) TLV (ACGIH) PPM (mg/M3) N. F. P. A, Health Fire React. Jgnit. Vap. PI. Pt. Temp. Flam. B.P. Sp. Dens. C C Limits C Gr. (Airs=1) (F) (F> % (F) M.P. C <F> Sol. in H2O ftfIDOg Other Solvents Misc. Ret. 4b 2 2 26 1000 - 27a 6 (.03) 0 3s 18 1000 2 0 4 18 1 4 18 1 4 0 1.42 5.9 79 (174) 181 (358) -27 (-17) insol. ale., bz. -59 (-74) -168 (--270) si. sol. chi. 1 - 178 si.(. ale., chi. (352) 2 1.88 1.97 <-7 429 2-11.5 -4.7 -109 insol. org. sof. MCA (NFPA) (<20) (804) (23) (-164) 0 ,60 2.04 -60 405 1.9-8.5 -.5 -138 v. sol. ale., chi. NTTC (-76) (761) (31) (-216) 0 .56 2.01 462 (864) 1.8-8.4 --12 (10.4) -160 (-256) sol. ale. 18 1 40 1.9 384 1.6-9.3 -6.1 insol. ale. (723) (21) 18 1 40 1.9 - 324 1.8-9.7 1.1 - insoi. ale. (615) (34) CMA 045649 SUBSTANCE/FORMULA | 157. n-Butyl Acetate CH3COOC4H9 158. iso-Butyl Acetate CH3COOCH2CH<CH3)CH3 159. sec-Butyl Acetate CH3COOCH(CH3)CH2CH3 160. tert'Butyl Acetate CH3COOC(CH3)3 161. n-Butyl Alcohol CH3CH2CH2CH2OH 162. iso'Butyl Alcohol CH3CH{CH3)CH2OH 163. sec-Sutyl Alcohol CH3CH2CH(OM)CH3 164. tert-Butyf Alcohol (CH3)3COH 165. Butylamine C4H9NH2 166. tert-Butylamine (CH3)3CNH2 167- iao-Butylamine (CH3)2CHCH2NH2 168. n-Butyl Bromida CH3(CH2)3Br 1 PAGE 26 Waste Dis posal Pro- cedure (See VII TLV (ACG1H) PPM (mg/M3) N. F. P. A. Health Fire React. 18 150 1 30 18 150 1 30 18 200 1 3 0 18 200 18 100 1 3 0 18 100 1 30 18 50 1 3 0 18 100 1 3 0 7a 5 3 3 0 7a 5 3 4 0 7a 3 3 0 4b 2 3 0 Ignit Vap. F|. Ft. Temp, Flam. B.P. Sp. Dens. C C Limits C Gr. (Airsl) (FI (F) % (F) M.P. C <F) Sol. in H2O g/IOOg Other Solvents Mtsc. Rat. .38 4.0 27 399 1.4-7.6 125 -76 si. sol. ale. (81) (750) (257) (-105) SDH .87 4.0 18 423 1.3-7.5 117 (64) (793) (243) -99 si. sol. (146) ale. BDH .86 4.0 31 (88)oc 1,7- 112 (234) insol. ale. .87 95 insol. ale. MCA (203) .81 2.55 29 365 1.4-11 118 -89 sol. ale. (84) (689) (244) 1-128) .81 2.55 28 427 1.7-10.9 107 -- 108 10'5 ale. (82) (800) @212 F (225) (-162) .81 2.55 24 406 1.7-9J3 99.5 -115 12.5 ale. (75) (763) @212 F (211) (-175) .78 2.55 10 478 2.4-6 83 25 ale. (50) (892) (181) (77) BDH,MCA BDH BDH, MCA BDH, MCA .76 2.5 -12 312 1,7-9.8 78 -50 00 ale. (10) (594) (172) (-58) BDH .70 2.5 1-7-8$ 45 @212 F (113) -67 (-89) ale. BDH .73 2.5 -9 378 (16) (712) 66 -86 ale. (151) (-123) BDH 1.28 4.7 18 (64) 265 (509) 2-6.6 0 101 @212 F (214) -112 (-170) .06 ale. 8DH CMA 045650 SUBSTANCE/FORMULA Callosolvii C4H9OCH2CN2OH Waste Dis posal Pro cedure (See VI) TLV (ACGIH) PPM ImgW3) N. F. P. A. Health Fire React. 18 50 2S 2S i-tn n-Butyl Chloride CH3(CH2)3CI 4b 23 0 171 tert-Butyl Chloride 4b 23 0 (CH3)3CCI 172. tert*8utyl Chromate CgHigCr04 12a (.1) 3S Butyl Ether, see Dibutyl Ether 173. n-Butyl Formate HCOOC4H9 18 2 3 0 174. iso-Butyt Formate HCOOCH2CH(CH3|2 18 - 175. n-Butyl Glycioyl Ether C4H9-0*CH2-CH^O-CH2 15 50 176. Butyl Hydroperoxide (CH3)3CQOH 22b 1 44 177. n-Butyllithium in Hydrocarbon solvents 177a,b,c, CH3(CH2)3Li 3 177a. In Heptane 3 500 - 177b. In Hexane 3 500 ` Ignit. Vap. FI. Pt. Tdmp. Flam. B.P. Sp. Dens. C Gr. (Airsl) (F) C I'F) Limits % C (F> M.P. C (FI Other Solvents .91 4.1g 61 (142) 1.1-12.7 171 (3401 -40 (-40) 00 ale. .88 3,2 7 471 1.9-10.1 78 -123 .07 (45) (880) (172) (-189) ale. .85 3.2 <21 (<70) 51 (124) -27 (-17) si. sol. ale. Misc. Ret. BDH BDH .91 3.5 18 322 1.7-8 (64) (612) .89 <21 (< 70) .91 - .86 21S solvent 27 (80) 107 --90 (225) (-130) 98 -95 (208) (-139) 164 (327) dec. 6 (43) si. sol. ale. 1.122 ale. sol. ale., chi. BDH MCA .68 -4 223 1.2-6.7 98 - (25) (433) (209) .69 -22 234 1.2-7.5 69 (-7) (453) (156) org. sotv. MCA org. solv. MCA PAGE 27 CMA 045651 SUBSTANCE/FORMULA ^^7c. In Pentane 178. Butyl Mercaptan CH3(CH2)3SH Waste Dis posal Pro cedure (See VI) TLV (ACGIH) PPM (mg/M3) N. F. P. A. Health Fire React. 3 1000 13 10 2 3 0 IgniL Vap. n. Pt. Temp. Sp. Dens. c C Gr. (Airs^l) ("FI <F> a |il U. 8.P. c (F) M.P. C (F) Sol. in H7O g/IOOg Other Solvents Misc. Ref .70 -40 309 1.5-7.8 36 (-40) (588) (97) org,$olv. MCA .84 3.1 2 (36) 98 (208) -116 si. sol. (-117) ale. 179. Butyl Methacrylate CH2C(CH3)COOC4H9 18 2 2 0 .89 4,8 52 (126)oc 163 (325) insol. ale. NTTC 180. Iiobutyl Methyl Ketone CH3C0C4H9 18 100 2 3 0 3.5 17 460 1.2-8 126 -57 (63) (860) (259) (-71) 181. tert'Butyl Peracetate CH3C03C(CH3)3 22b 25 2 3 1 .93 27 (80) 182. tert-Butyl Perbenzoate C6H5C03C(CH3)3 22b 1 3 4 1.0 107 (225) 113dec. (235) 183. Butyl Peroxypivalate (in 75% sol. of Mineral Spirits) (CH3)3C02C0C(CH3)3 22b 034 >68 (>166) -19 (-2) ale. BDH Butyl Peroxytrimethyl Acetate, see Butyl Peroxypiualate 184. di-Butyl Phosphate (C4H90)2P0(0H) 185. tri-Butyl Phosphate (C4H9O3PO 186. p-tert-Butyl Toluene CH3C6H4C4H9 187. Butyl Vinyl Ether C4H9OCH-CH2 7b 1 7b 18 10 15 % 2S 23 .97 .85 2 .77 3-S --9 (16)oc ale., ace. 289dec. <-ao .6 (552) (<-112) ale., ace. 193 (379) -52 (-62) insol. ace., bz., chi. 94 (201) -92 (-134) insol. org. sol. PAGE 28 CMA 045652 SUBSTANCE/FORMULA Bigs. 1-Butyne W chcch2ch3 ,89 n~ButyfiM*hy6e CH3CH2CN2CHO 140 iso*Butyreldehyde (CH3)2CHCHO <91 n-Butyric Acid CH3(CH2)2COOH 192 iso-Butyric Acid (CH3)2CHCOOH 193. n-8utyrie Anhydride [CH3(CH2)2CO)20 194 T-Butyrolactone CH2CH2CH2COO 105. n-Butyronitriie CH3(CH2)3CN 196. Butyryl Chloride C3H7COCI 197. Cadmium Cd 198. Cadmium Chlorida CdC|2 199. Cadmium Oxide CdO Waste Dis posal Procedura (See V)) TLV (ACGIH) PPM (mg/M3) N. F. P. A. Health Fire React. IB 2S ignit Vap. FI. Pt. Temp. Flam. B.P. Sp. Dans. C C Limits C Gr. (Air=1) (F) (Fl % (F) M.P. "C (SF| Sol. in H2O g/IOOg Other Solvents .67 8.1 -127 insol. ale. (46) (-197) Misc. Ref, 2 2 3 1 .82 2.5 -6.7 230 2.5- 76 -89 4 ale. BDH, MCA (20) (4461 (169) (-146) 2 23 .79 2.5 -40 254 1.6-10.6 64 -66 4 ale. BDH, MCA (-40) (490) (147) (-87) 24a 2 2 0 .96 3.0 66 452 2-10 164 -7,9 00 ale. BDH (151) (846) (327) (17,5) 24a 'S 2S .95 3.0 62 502 154 -47 2020 ale., ch|. BDH (144) (935) (309) (-53) 24a 3 2 1 .97 5.4 88 307 198 -73 dec. dec., ale. (190) (585) (388) (-99) 18 2s 1.05 3.0s 98 (209) 206 (403) -44 (-47) 00 ale. 14 5 .8 26 (79) 117 (243) -112 si. sol. (-170) ale., bz. BDH la 1.03 3.7S <21 107 -89 dec, ale. BOH 70) (225) (-128) 27a (.02) 3g 2s 8.6 767 (1413) 321 (610) insol. 27f (.2) % 4,0 960 (1054) 568 (760) 14020 si. sol., aic. 27f (.1) 3s 8.2 * 1559 900 insol. (2838) (1652) PAGE 29 CMA 045653 SUBSTANCE/FORMULA do. Calcium W Ca Waste Dis posal Pro cedure (See VI) TLV (ACGIH) PPM (mg/M3) N. F. P. A. Health Fire React. 3 (51 1 1 2 201. Calcium Arsenate Ca{As04>2 202. Calcium Carbide CaC2 27d 0) 25 % 14 2 203. Calcium Carbonate CaC03 26 204. Calcium Chlorate Ca(Cl03)'2H20 12a 2S 2S 205. Calcium Chloride CaCl2 206. Calcium Cyanide Ca(CN)2 207. Calcium Hydride CaH2 11 14 10 2 00 17 3S 208. Calcium Hydroxide Ca(OH)2 209. Calcium Hypochlorite Ca(CIOJ2 210. Calcium Oxide CaO 26 Zs 12a 2 26 (5) 0 2 211. Camphor Cl0H16 18 (2) 2 2 0 fc_____________________________________ FAGE 30 Ignit. Vap. FI. Pt. Temp, Flam. B.P. Sp. Dens. C C Limits C Gr. (Air=1) (F) (F) % (F| M.P. C (F) Sol. in HtO g/lOOg Other Solvents Misc. Ref. 1.5 1240 842 dec. si. sol., SDH (1548) (2264) ale. 3.6 1.45 .01325 (34.5) 2.2 2300 447 dec. BDH,MCA (4172) (837) 2.7 899 825 si sol. (1650) (1517) 2.71 2.15 100 (212) 178^ ale., ace. AIA <1600 772 K2912) (1422) 7520 ale., ace. NTTC 350dec. dec. (662) BDH, MCA, MCB 1.8 816 dec. dec., ale. BDH (1501) 2.5 dec. 580 .180 (1076) 2.35 lOOdec. dec. (212) 3.25 - 2850 (5162) 2580 (4676) .1310 BDH .99 5.24 66 466 .6-3.5 209 175 si. sol. ace., ale., (151) (871) (408) (347) bz,, chi. CMA 045654 SUBSTANCE/FORMULA Caproic Acid C5H11COOH Capryl Alcohol, see 2-Octanol 213 Capryieldhehyde CH3(CH2)6CHO Caprylic Acid, see Octanoic Acid Caprylic Alcohol, see 1-Octanol 214. Carbazole CqHANHCqH4 Carbitol, see Diethylene Glycol Monoethyl Ether Carbolic Acid, see Phenol 215. Carbon, Black C 216. Carbon Disulfide CS2 217, Carbon Monoxide CO Carbon Oxysulfide, see Carbonyl Sulfide Waste Dis posal Pro cedure <Sm VI) TLV (ACGIH) PPM (mg/M3) N. F. P. A. Health Fire React. -36a" 210 Ignit. Vap. FI. Pt. Temp. Flam, B.P. Sp. Dens. C C Limits 6C Gr. (Air=1) (F) (F) % (F) M.P. C (FI Sot. in H^O g/IOOg Other Solvents .93 4.0S 102 (2l5)oc 205 (401) -5.4 (22) 1.120 etc. Mijc. Ref 2 22 0 .8 4.5 52 - 168 (125) (335) org. solv. 6 's >s MO - - 355 245 Insol. alc,, (6711 (473) hot bz. 26 (3.5) is is ~2 - - * -4200 -- 3680 insol. (-7592) (-6656) 9 20 2 3 0 1.26 2.6 -30 100 1-44 46 -112 .2 ale., ch|. AIA, BDH, (-22) (212) (115) (-169) MCA, NSC 18 50 2 4 0 1 .97 - 609 12.5-74 -192 -207 .004 ale., b2. (1128) (-314) (-341) PAGE 31 CMA 045655 substance/formula ) 218. Carbon Tetrabromide CBr4 219. Carbon Tetrachloride CC14 220. Carbon Tetrafluoride cf4 Carbonyl Chloride see Phosgene 221. Carbonyl Fluoride COF2 222. Carbonyl Sulfide COS Carvene, see Dipentene 223, Caustic Potash KOH 224. Caustic Soda NaOH 22S. Celloeofve CH2OHCH2OC2H5 226. Cellosolve Acetate CH3COOCH2CH2OC2H5 227. Cellulose Nitrate Ci2Hi7{0N02)307 Waste Dis posal Pro- cedure (See VI) TLV (ACGIH) PPM (mg/M3) N. F. P. A. Health Fire React. 27j 3st Ost 27j 10 0s S Z7i - 2S - Ignit. v*p. FI. Pt. Temp. Flam. B.P. Sp. Dent C C Limits C Gr. !Air=1) iF) (F) % m M.P. C (F| Sol. in H20 9/1009 Other Solvents Misc. Ref. 3.4 1.58 5.3s none 3.42 - 190 90 insol. sic., eh|. (374) (194) none 77 (171) -23 , Insol, (-9.4) ale., &z., chi. AIA, BOH, MCA. NTTC, NSC - -127 -184 si. sol. (-197) (-299) - 21 1 2S 3S - 1.14 - 13 - 3 4 1 1.07 2.1 - -83 -114 dec. (-117) (-173) dec., ale. MGB - 12*29 -50 -138 so14 ale. (-58) (-216) MGB 10 3 0 1 2.04 none 10 (2) 3 0 1 2.13 - none none 1320 (2408) 360 (680) 10715 ale. none 1390 (2534) 315 (599) 42 ale. BDH, MCA BDH, NTTC. MCA 18 200 2S 2S - .93 3.10 94 (202) - 1.7-15.6 135 (275) - OO ace., ale., BDH chi. 18 100 2S 2s - .97 -.7S 55 (131) 382 (720) 1,2-12.7 156 (313) -62 v, sol. (-80) org.solv. 28 2 3 3 1.66 13 (55) insol. ace,, MeOH PAGE 32 CMA 045656 substance/formula Lower Nitrates of ^^^Jllulose and Camphor oo cMoral 2 CCI3CHO 730 Chtortt Hydraw 2 CC!3CH(OH)2 731, Chlordane ClOH6Cl8 732, Chloric Acid HCI03'7H20 233. Chlorinl Cl2 234 Chlorine Dioxide ` CI02 235. Chlorine Trrfluorfde ' CIF3 236 Chforoecetaldehyde CH3C1CH0 237. Chloroacetamide CH2CICONH2 238. Chloroacetic Acid CH2CICOOH 239. Chloroecetonitrite ch2cicn Waste Dis posal Pro cedure (See VII TLV (ACGIHI PPM (mfl/M3) N. F. F, A. Health Fire React, 28 2S Ignit Vap. FI. Pt. Temp. Flam. B.P, Sp. Dens, C C Limits *C Gr. (Air=1) (eF) (F> % tQF) --* M.P. C (F> Sol. m H2O S/IOOg Other Solvents - Mjsc. Ref. 2- 24b 1.5) 12a 12a 1 12a .1 21 .1 21 ^r<U> 4C - 14 % - 1,51 5.1s none - 98 -58 V, sol. hot a/c. (208) (-72) 2S Is - 1,64 - - - 96 52 47417 ale., ch|., (205) (126) cs2 3s - - ''"1.6 56 (133) - 175 (347) % 3S 3s 1.28 - 40dec. (104) --20 v. sol. ("4) BDH 3 0 1 2.48 2-99s 3s 3S 3.09 2-3s 3s % 3St 1.77 3.1S 100 (212) -34 (--29) -101 (-150) 1.4 AlA, MCA, MGB, NSC 9.9 -59 dec. (50) (-74) expl. with compounds of carbon. 12 -83 dec. (54) (-117) MCA, MGB, NASA % 2S 1.19 2-3S 88 (190) 85 (185) -16 13.2) 225 (437) 120 (248) 1024 ale. 2S 2s 3s 1.40 3,3s - 1.19 189 63 (372) (146) v. sol. ale., D2., chl,,CS2 BDH ' 123 (253) PAGE 33 CMA 045657 SUBSTANCE/FORMULA 240. Chloracetophenone C6H5CQCH2CI 241 Chloroacetyl Chloride ch2cicoci 242 m-Chloroamline C6H4NH2CI 243 o-Chloroamlme CGH4NH2CI 244. p-Chloroamltne C6H4NH2CI Chlorobenzaldehyde, see Benzoyl Chloride 245 Chlorobenzene C6H5C! 246. o-Chlorobenzoyl Chloride CIC6H4COCI 247. Chlorobromomethane CH2CIBr Chlorobutadiene, see Chloroprene 248 p-Chloro-m-crasol C6H3CH3OHCI 249. Chlorodiethylalummum CI-AI-{C2H5)2 Waste Dis posal Pro cedure (See VI) TLV (ACGIH) PPM (mg/M3) N. F, P. A. Health Fire React. 4b 05 3S Ignit. Vap FI, Pt. Temp. Flam. B.P. Sp Dens. C C Limits C Gr. (Air--1) (FI <F) % (F) M.P. C (R Sol. in HjO g/IOOg Other Solvents 1 19 5.2S 247 (477) 59 (138) insol dee., ale., bz., CS2 Misc. Ret la 3S 1.42 108 (226) -23 (-9) dec dee , ale. BDH 5 3S 1 22 299 (444) -10 (14) msol, Org, SOlv, BDH 5 3S 1 21 209 (408) -14 (6 8) msol org solv BDH 5 3S 1.43 231 (448) 70 sol (hot) org. solv. (158) BDH 4b 75 2 3 0 1.11 3.9 29 638 1.3-7,1 132 -56 msol. ale., bz . AIA, (84) (1180) (270) (-69) chi., CS2 BDH,NTTC 1 iv 2S 2S 225 (437) -10 dec (14) dec. ale 26 200 2S 1.93 4.5S 68 (154) -88 (-126) insol. org. solv. 4b 3S 3 3$t 3St St <-1 30) 235 (455) 66 (151) si, sol. ale. 208 (406) -50 (-58) BDH CMA 045658 substance/formula ^ 1 ,Chloro-1,1 -Difluoroethane W C23ctF2 gt l-ChlorO'Z.^Qimtrobenzenv ' C6H3CIIN02)2 52. Cblorodiphenyls Ci2HxC*v 1.Chioro-2,3*Epoxypropane< $t>e fipiehlorohydrin Waste Dis posal Pro cedure (See VI) tlv (ACGIH) PPM lmg/MJ) N. F. P. A. Health Fire React. 26 H os Igmt. Vap. FI. Ft. Temp. Flam. B.P, 5p. Dens, C C Limits C Gr. (Airsl) (F) (F) % (F) 1.12 632 9-14.8 (1170) -9.2 (15) M.P. C (F) So), in H2O 9/IOOg Other Solvents Misc. Ref. 6 31 4 1.50 194 432 2-22 316 43 insol. bz., CS2 BDH (381) (810) (599) (109) 4b 1.05) % ~1.4 176-80 (394-50) oc 340-75 (644-707) Chloroethane, see Ethyl Chloride Cbloroethanol, see Ethylene Chlorohydrln 53 Chloroform CHCI3 -27 3r(f 50 3 0 1.49 -'S none none 61 (142) --64 (-83) si. sol, ale., bz. Al A BOH. NTTC, MCA Chloromethane, see Methyl Chloride 54. Chloromethyl Ether CICH2OCH3 5S. 2-Chloro-2-Methyl Propene CICH2-C{CH3)CH2 56. Chloronaphthalena Cioh7ci 15 4b 4b % 1.07 .93 1.14 5.6 132 558 (270) (1036) 59 (1381 -103 dec. (-153) ale. 71 (160) 256 (493) -20 insol. (-4) ale. CS2, chi., ale., bz. BDH PAGE 35 CMA 045659 SUBSTANCE/FORMULA 257. Chloronaphthylamme c10h8cin 258. Chloronitroanilines NO2CIC6H3NH2 259. Chloronitrobenzenes C6H4CINO2 260. 1-Chloro*1*Nitropropane C2H5CHCINO2 261. Chloropentaftuoroethane c2cif5 262. m-Chlorophenol C6H4CIOH 263. o-Chlorophenoi C6H4CIOH 264. p-Chiorophenol C6H4CIOH 265. o-Chlorophenyl Diphenyl Phosphate CIC6H40<C6H50)2PO 266. Chloropicrin CCI3N02 267. Chloroprene CH2CHCCICH2 Chloropropane, see n-Propyl Chloride PAGE 36 Wait* Dis posal Pro cedure (See VI) TLV (ACGIH) PPM (mg/M3) N. F. P, A. Health Fire React. 6 car. Igmt, Vap. FI. Ft. Temp. Flam. B.P. Sp. Dens. C C Limits C Gr. (Airs=1) <F) <F) % (F) M.P. C ("Ft Sol. in H2O fl/IOOg Other Solvents 60 (140) ale. Misc. Ref. 6 3s 108-16 (226-41) ale., ace. SDH 6 in 4a 20 3St ''st 1 St 1.37 127 (261) 3S 2 3 1.21 4,3 62 (144) 242 (468) 32-46 insol. (90-115) ate., bz. 142 (288) si. sol. ale. 80H 26 1000 0 0 1.26 6 3S 2S 1.24 -39 (-38) --106 (-159) insol. ale. 214 (417) 32.5 sol.(hot) ale., bz. 00.5) BDH 6 2s 1.24 85 (185) 6 3S 2S 1.24 121 1250) 7b 1s 215 (419) 175 7 v. sol. bz. (347) (45) 220 (428) 43 (109) sol. ale., bz. 240*55 <0 (464-91) 32) BDH BDH 4a 1 4b 25 40 3S 1 1.66 S.7S .95 3.0 -20 (-4) 4-20 712 (234) -64 (-83) $1. sol. ale., bz. 59 (138) si. sol. org. sol. BDH CMA 045560 substance/formula ^^Hbhloro-Proptoniy Chloride ^PICHjCHsCOCI 269 Chlorosulfonic Acid ` H0SO2CI 970 Chlorotrifluoroethylene ` FCCI=CF2 271. Chromates ICrOn") and Dichromates (Cr207*l 272. Chromc Salts (soluble) Cr+-H- 273. Chromum Cr 274. Chromium Trioxide Cr03 275. Chromous Salts (soluble) Cr^ 276. Chromyl Chloride Cr02Cl2 277. Cinnamaldehyde C6H5CH^CHCHO 278. Citraconic Anhydride C5H403 Citrene, see Dipentene 279- Citric Acid ^^(OH)(COOH)3 Waste Dis posal Pro* cedure (See VI) TLV (ACG1H) PPM (mg/M3) N. F. P, A. Health Fire React. 1> Ignit, Vap. FI, Pt. Temp. Flam. B.P, Sp. Dans, C C Limits *C Gr. <Air=1) <F) (FI % (F) 1.33 143 (289) M.P. C l*F) Sol. in H2O g/IOOg Other Solvents si. sol. ale., chi. Misc. Ref. SDH lb 10 3 0 2 1.79 4.0S none none 152 (306) -80 dec. (-112) dec. ale. BDH, MCA, NSC 26 20 3 4 2 1.31 3,4-39 -28 -158 (-18) (-252) 12a l.i; 11 (.5) sol. 26 (1) 12a (.11 12b (.5) S 2S 10 3S 7.2 1 2.70 2480 (4496) 1800 (3434) insol dec. 196 62 (385) sol. ale. 8DH, MCA 12a 3S 2 24a 1,19 1.06 1.25 49 (120) 116 -96 (241) (-141) dec. org. sol, BDH 253 (487) --7.5 (18) si, sol. ale., chi. 213 7--8 (416) (45-6) dec. ate. 24a 'S 'S 1.54 - - dec. 153 v. sol. ale. (307) PAGE 37  SUBSTANCE/FORMULA 280. Cleaning Solution 281. Cobalt Co 282. Cobaltous Nitrate Co{N03)2'6H20 283. Collodion 284. Copper Cu 285. Copper Nitrate Cu<N03)2-6H20 286. Crag 974 C5H10N2S2 287. m-Cresol CH3C6H4OH 288. o-Crasol CH3C6H4OH 289. p-Cresol CH3C6H4OH 290. Creosote 1 Mixed Phenols) Cresylic Acid, see o-Cresol Waite Dis posal Procedure (See VI) TLV (ACGIH) PPM (mg/M3) N. F, P. A. Health Fire React. 12a Ignit. Vap. Ft. Ft. Temp. Flam. B.P. Sp. Dens. C C Limits C Gr. |Air=1) I'F) (F) % )F) M.P. C (F) Sol. m HtO g/lOOg Othar Solvents Misc. R*f 27a (.5) 11 2S 1 0 8.9 1 1.87 2900 (52521 1495 (2723) insol. 55dec. 134 (131) ale., ace. 28 1 4 0 <-18 0I -We- id n 2S 1 0 8.9 1 2.07 2595 (4703) 1083 (1981) Insol, 198dec. 26 244 (388) (79) ale 13 1.15) 2S 18 s 2 1 5.6s - 106 (223) 0 1.03 3.7S 86 559 1.06-1.35 203 12 sol. org, sol. GDH, MCA (187) (1038) @302 F (397) (54) 18 5 2 2 0 1.05 3.7S 81 599 1.35- 191 31 sol (hot) org. sol. BOH, MCA (178) (1110) (376) (88) 18 5 2 1 0 1.04 3-7s 86 559 1.06-1.4 202 35 sol. (hot) org, sol. BDH, MCA (187) (1038) @302F (396) (95) 18 2 2 0 1.07 74-82 336 200-50 (165-80) (637) (392-482) NTTC PAGE 38 CMA 045662 substance/foamula Al CrOtonaldshyds W ' ch3chchcho 292, Croton iQ3 Crotononitrile CH3CH=CHCN 904 Crotonyl Chloride ' CH3CH-CHCH2CI 295, Crude Oil (Petroleum) 296. Cumene C6risCH(CH3)2 297 Cumene Hydroperoxide ' C6HgCICH3>200H 298. Cuprous Chloride ` CuCI 299. Cuprous Cyanide CuCN 300- Cyenamide h2ncn 301, Cyanides CN` 302. Cyanoacetamlde CNCH2CONH2 Waste Dtv posai Pro* cedure /See V/) TLV (ACGIH) PPM (mg/M3) N. F. P. A. Health Fire React. 2 2 3St 3St ZSt Igmt. Vap. FI. Ft. Temp. Flam. B.F. Sp. Dens. C C Limits "C Gr. (Air=1) (F) (F) % (F> M.P. C lF) Sol. in H2O g/IOOg Other Solvents .87 2-OS 7 207 2 1*15.5 104 -76 v. sol. ale., bz. (45) (405) (219) (-105) Misc. Ref BDH 18 !S 14 -83 2.3 <100 122 -52 l<212) 1252) 1-62) la 1st 1.09 124 (255) dec. 18 =S 2S ,78-.79 <27 80) <-46 --501 MTTC 18 50 0 2 0 .86 4.1 44 424 .9*6.5 152 -96 insol. ale., bz. BDH (111) (795) (306) (-141) 22b 1 2 4 1.05 79 (174) 153 (307) NFPA 11 3S 4.14 1490 (2714) 422 (792) si. sol. 14 3S 2.92 dec. 473 (883) insol, 14 14 (SI 2S is 1.07 1.45S 141 (286) 3s 2S - 140 (284) @19mm. 42 (108) v. sol. die., bz. - AIA. 8DH 14 3S 2S dec. 118 (244) 15 si. sol. ale. PAGE 39 CMA 045663 SUBSTANCE/FORMULA 303. Cyanogen (CN)2 304. Cyanogen Chloride CNCI 305. Cycloheptanone ceH12co 306. Cyclohexane C6h12 307. Cyclohexanol C5HTQCHOH 308 Cyclohexanone c6h10co 309, Cyclohexane C6Hiq 310. Cyctohexylamine c6Hhnh2 311. Cyclohexylbenzene C6HllC6H5 312. Cyclonite-RDX C3H6N6O6 313. Cycfopentadiene C5H6 314. Cyciopentane CgHlo PAGE 40 Waste Dis posal Pro cedure (See VI) TLV (ACGIH) PPM (mg/M3) N. F. P. A. Health Fire React. 14 10 4 4 2 Ignit. Vap. FI. Pt. Temp. Flam. B.P. Sp. Dens. C c Limits C Gr. (Air=1) (F) (F) % (F) M.P. C (F> Sol. in H2O g/IOOg Other Solvents Misc. Ref. .95 1 8NFPA 6-32 -21 (-5.8) -34 (-29) 45020 ale MGB 14 .5 3s 1.2 1 % 13 -6.5 si. sol. ale. (55) (20) Je ff 2S .96 178 (352) insol ale. 18 300 3St St .77 2.91 --20 260 1.3-8.4 80 4.1 insol ale., ace., BDH, MCA (-4) (5001 (176) (39) bz. 18 50 1 2 0 .96 3.45 68 300 (154) (572) 161 25 3.6 CS3, bz. (322) (77) 18 50 1 2 0 .99 3.4 44 420 1,1-8.1 156 -- 16 si. sol. ale. (111) (788) (313) (3.2) BDH 18 300 1 3 0 .81 2.8 --6 (21) 83 (181) -104 insol. (-1651 ale., ace., bz. BDH 7a 22 2 3 0 .87 3.4 32 293 (90) (560) 135 (275) -18 (-.4) sol. org. sol BDH 18 2 1 0 .95 99 104 238 7.5 insol. ale. (210) OC (220) (460) (45) 4a 2S 2S 1.8 202 (396) ace. 18 75 2S .80 42 -97 (108) (-143) insol. ale., bz. 18 1 3 0 .75 2.42 -7 20) 49 -94 insol. (120) (-137) aic, CMA 045664 SUBSTANCE/FORMULA cydopentanorts ^ ' C4H8C0 31 g Cyclopropane C3h6 -117 p-cymene 3 CH3C6H4CH(CH3)Z 2]g Decaborane BiflHia 719. Decahydronaphthalene c 1 oH 1 s 320. iso-Decaldehyde CgHigCHO Deoalin, see Decahydronaphthalene 321, n-Decane CH3(CH2}sCH3 322. m-Decyl Alcohol CH3(CH2)3CH2OH Dematon, see Systox 323, Deuterium 2 324. Discetona Alcohol CH3COCH2C(OH)(CH3)2 Oiaminoethan, see Ethylene Diamine Waste Dis posal Pro cedure (See VI) TLV (ACGIH) PPM (mg/M3) 18 N. F. P. A. Health Fire React. 230 18 400 40 218 7 0 17 .05 3 2 18 2St St Ost 2 Ignit Vap. FI. Pt. Temp. Flam. Sp. Dens. C C Limits Gr. (Air=1) <F) (F) % .95 2,3 26 (79) B,P. "C (F) 131 (268) M.P. C <F) Sol. m H2O g/IOOg Other Solvents -58 (-72) insol. ale., MeQH Misc, Ref. ,72 1.45 498 2,4-10.4 -33 -127 (928) (-27) (-197) si. sol. ale. .86 4.62 47 436 .7-5.6 177 -68 msoi. ale,, chi. SDH (117) (817) (351) (-90) .94 80 149 (176) (300) 213 (415) 100 (212) si. sol. ale., oz., CS2 AIA, NFPA. NSC .87 4.76 57 250 .7-4.9 186 -45 insol. ale,, chi. BDH (135) (482) (367) (-49) .8 5.4 85 (186) 197 (387) 18 0 2 0 ,73 4.90 46 208 .8-5.4 174 -30 insot. ale. (115) (406) (345) (-22) 18 2S .83 5.3 82oc 229 7 insol. ale., ace., (180) (444) (45) bz., chi. 2?j 0 4 0 .18 5-75 -250 -255 (-418) 1-427) si. sol. @>121mm 18 50 1 2 0 4.0 64 603 1.8-6.9 168 -50 00 (147) 11117) (334) (-58) atc. SDH PAGE 41 CMA 045665 SUBSTANCE/FORMULA | Diatomaceou* Earth, see Silica Waste Dis posal Pro cedure (See VI) TLV (ACGIH) PPM (mg/M3) N. F. P. A. Health Fire React. Ignit. V1. F|, Ft, Temp. Flam. B.P. Sp. Dens. C C Limits C 0r- (Air^l) (F) TF> % (^1 M.P. c (F1 Sol. in H9O g/IOOg Other Solvents 325. Diazomethane ch2n2 8 .2 3s 1.45 lOOexp, (212) -23 -145 dec. (-9.4) (-229) hot ale. 326. 1,2,5,6-Dibenzacridina C21H15N 5 327. 1,2,7,8-Dibenzacridine C21H15N 328 1,2,5,6-Qibenzanthracene C22H14 5 18 268 (514) insol. ace., bz., CS2 329. 1,2,5.6-Dibenzcarbazole C20H17N 5 330. 3,4,5,6-Dibenzcarbazole C2oH,7M 5 331. 1,2,5,6-Dibenzofluorene C21HI8 332. 1,2.3,4-Dibenzophenanthrene C22h18 Dibanzopyrrola, see Carbazole 18 18 280 (S36) @ .3mm 174 (345) bz. 333. 3,4,8,9'Dtbenzpyrene C24h17 18 334. Dibenzylamme HN(CH2C6H5)2 i______________________________________ 5 PAGE 42 3S 1.03 300dec. -26 l. (572) (-15) ale. Mtsc. Ref, CMA 045666 SUBSTANCE/FORMULA ^^W?iboran ^^^B2h6 Waste Dis posal Pro cedure (See VO tlv (ACGIH) PPM (mg/M3) N. F, P. A. Health Fire Reect. 17 .1 3 4 3 DibrOtT', see Dtmethyl-1,2* Oibromo-2,2'Dichloroethvlphos Ignit Vp. FI. Pt. Temp. Flam. B.P. Sp. Dens. C *C Limits C Gr. (Ami) (F> (F| % (F) M.P. "C Tf) Sol. in MjO gVIOOg Other Solvents Misc. Ref. .46 .96NFPA -90 (-130) 145 (293) .9-98 -93 -165 dec. (-135) (-265) dec., ale. Al A, MCA. NSC 336. 2. 6-Dibromo-N-Chlorop-Benio-Qumanimine C6H2Br2CINO 1,2-Dibromoethane see Ethylene Dibromide 6 .1 85 (185) insol. 737 1,2,-Dibromotetrafluoromethane 26 100MGB (Freon-114B2) C2Br2F4 st 2.72 24.5 (76) -142 (-224) 338. Dibutylamme (C4H9^NH 7b 32 0 .50 4.46 52 (126)oc 1*9 (318) -51 sol. (-60) ale. 339. Dibutyldichlorotfn |C4Hg)2 SnCl2 4b 3s 's 1.36 10.5S 355 (671) 135 (275) @ 10mm 43 (109) dec. ale., bz. 340 Di-m-Butvl Ether ' [CH3<CH2>3]2 15 23 0 .77 4.5 25 194 1.5-7.6 141 -98 insol. ale. BDH (77) (381) (286) (-144) 341. Dibutyl Oxalate (C4H9^2c24 342 Dibutyl Peroxide ' (CH3)3COOClCH3)3 18 22b 1000 3$ 1 23 0 1.01 7.0g 104 (220) 4 .79 5.0s 18 (65) 246 (475) 111 (232) -30 insol. (--22) ale. -40 insol. (-40) ace. NFPA 343 Dibutyl Phosphite (C4HgO)2POH 7b 1 32 0 .97 6.7S 49 (120) 115 (239) @ 10mm CMA 045667 SUBSTANCE/FORMULA H}44 Dibutyl Phthalate w C6H4{COO)2(C4H9)2 345. DibutyJ Tin Dileurafe (CH3<CH2)10COO)2 Sn(C4Hg)2 Waste Dis posal Pro cedure (See VI) TLV (ACGIH) PPM (mg/M3) n. e. p. a. Health Fire React. 18 (5) 0 1 0 18 1S 346. Dichloroacetic Acid CHCljCOOH 4c % 347. Dichloroacetyl Chloride CHCI2COCI la 321 343. 2,5'Dichloroaniline CI2C6H3NH2 349 o-Oichlorobenzane C6H4CI2 6 3 10 6 50 2 2 0 350. 3,3'-OichlorobenXldme CIMH2CeH3C6H3NH2CI 6 car 35 T. 1,4-Dichlorobutane CH2CI(CH2)3CI 4b 2 2 0 352. 1 ,3*Dichloro-2`Butene CH2C!CHCC!CH3 4b 2 30 353. DiChiorodifliioromathane CC!2F2 26 1000 - 354. 1,3*Dlchloro*5,5*Dimethylhydantoin C5HgCI2N202 6 (.2) % 355. 1,1-Dichloroethana CH3CHCI2 4b 100 2 3 0 Igmt. Vap. FI. Pt. Temp, Flam. B.P. Sp. Dens. C QC Limits C Gr. (Air=l) (F) (F) % (F) M P. C (F) Sol. in < | H2O Other g/lOOg ' Solvents ] Misc. Ref 1.04 9.65 157 (315) 403 (757) 340 (644) -35 (-31) insol bz,, ace., ale 1.05 2i.8S 235 (455) 27 insol, ace., bz. (81) 1.56 4.45s 192 (378) 9.7 150) ale. BDH 1.53 1.30 5.1 66 (151) 5.6s 166 (331) 5.07 66 (151) 648 (1198) 2-9 107 (225) 251 ! 50 1484) 1122) 180 (356) -18 (-.4) dec 1 z , ale. BDH ' si sol. , ale,, bz insol ale. BDH AIA, BDH, NTTC, MCA 8.7S dec. 132 insol bz,, ace., (270) ale. 1.1 4.4 52 (126) 162 (324} -39 (-38) msoi. chi 4.3 27 (81) 123 (253) insol. org, sol 1.30 4.2MGB -29 -158 (--20) (-252) sol. ale. 1.5 6.8$ 132 (270) 1 .IS 3.4s -6 458 5.6-11.4 +57 -97 .70 (21) (856) (+135) (-143) ale. BDH 3AGE 44 CMA 045668 substance/formula ,2-0ichl<aro8thane. Ethylene Dichloride Waste Dis posal Pro cedure fSee VI) TLV (ACGIH) PPM Img/M3) N. F. P. A, Health Fire React. ignit. Vap. F|, Pt. Temp. Flam. 8.P. Sp. Dans. C C Limits C Gr. (Air=1) (aF) (aF) % (F) M.P, C <F) Sol. in HjO a/100g Other Solvents Mtsc. Ref. 1 (i -Dichloroethylftne, see Vinylidene Chloride rg i 2-Dich|<?roethylen* ' CICH=CHCI 4b 200 2 3 2 1.3 3.3 2-4 (36-9) 9.7-12.8 48-60 -80 (118-40) (-112) s). so). aJc, AJ A, BDH, MCB ,,e7 2 Z'-Dichloroethyl Ether J (C|C2H4)20 758 Dichloromethane ' CH2Cl2 -vf-o Dichloromonotluoromethane CH CI2F 760 1 1-Dichloro-1-Nitroethane ' H3C(N02)CCl2 36) 2 4-DicMorophenol C6H3OHCI2 IS 15 2 26 500 2 26 1000 4* 10 3S G 2 0 2 0 1.22 4.9 55 369 1131) (696) 178 (352) -24 (-11) insol.' org. sol. AIA, BDH MCB 0 1.34 2.93 1.48 3.8S 662 15.5-66 (12241 in 02 40 (104) -97 (-143) 220 ale. 652 (1026) 9 -135 insol. ale (48) (-211) BDH, NTTC, AIA, MCA 3 1.42 4.97 76 (168) 0 ^ 1.38 5.% 114 (237) 124 (255) 210 (410) .520 45 (113) $1. sol ale , bz., chi. BDH 362 Dichlorophenyiphosphine ` C6H5PCl2 363 1,2-Dichloropropane H2CCICHCICH3 364 1,3*D ichlpropropene c3h4ci2 jb 7\> % 1.3 6.2S 225 (437) dec. bz., CS2 4b 75 2 3 0 1.16 3.9 16 557 3.4-14.5 97 -100 si. sol. ale. (61) (1035) (207) (-148) AIA, NTTC 4b % 2S 1.23 3S 35 (95) 104 (219) insol. chi. 365 Dichlorotetrafluoraathane CCI2P-CF3 26 1000 1S st 1.44 3.6 -94 (38) (-137) insol. ate. PAGE 45 CMA 045669 substance/formula 1 W 366. Picyeiohexylamme (CeHuhNH Waste Dis posal Pro cedure (See VI) TLV (ACGIH) PPM (mg/M3) 7a N, F. P. A. Health Fire React. 2$ Ignit Vap. FI. Pt. Temp. Flam. So. Dens. C C Limits Gr. (Airs=1) (F> (F) % .93 6.3S 99qc (210) B.P. C |F) 256 (493) M.P. C (F> -.1 (32) Sol. in HjO &/100g Other Solvents .1628 ale., bz. 367. Dicydopentadiane C10H12 18 1 3 1 .93 4.55S 35 (95) 170 (338) 33 (91) ale. 368. Dieidrin c12h10c,6 4b (.25) 1.75 13.2S - 175 (347) insol. ace., bz. 369. Diethanolamine {HOCH2CM2)2NH 7a 1 0 1.09 3.6 152 662 <306)oc (1224) 270 28 v. sol. (518) (82) ale. 370. 1,1-Oiethoxyethane CH3CH(OC2H5)2 371. Diethyladipate C2H500C(CH2)4C00C2H5 15 18 2 3 0 .83 4.08 -20 230 1.7-10.4 102 -100 2120 ale. (-5) (446) (216) (--148) 1.01 240-5 --21 .4330 ale. (464-73) (-5.8) 372. Diethylaluminum Chloride (C2H5)3AICI 4b 333 Ignites in air 208 (406) -50 (-58) 373. Diethylamine (C2Hg)2NH 7a 25 3 3 0 .71 2.5 <-26 312 1.8-10.1 56 -48 v. sol. ale. (<--15) (594) (133) (-54) 374. 2-Diethyl-Amino*Ethanol (C2H5)2NCH2CH20H 375. N, N-Oiethylaniline C6H5N|C2H5)2 376. Diethyleerbonata ic2hs)2co3 7a 70 3 2 0 .88 4.03 60 (140)oc 5 3 2 0 .94 5.15 85 332 (185) (630) 18 25 =s 3 .98 4.07 25 (77) - 163 (325) 216 (421) O0 -38 (-36) ,412 126 (259) -43 (--45) insoi. ace., ale., bz. ale. ale. 377. Diethylena Glycol CH20HCH2OCH2CH20H 18 0 1.12 3.66s 124 229 2- (255) (444) 245 1473) -8 I+1B) sol. ale. Misc. Ref NTTC BDH NFPA BDHr MCA BDH, NTTC BDH BDH PAGE 46 f CMA 045670 SUBSTANCE/FORMULA Piethylene GlycolMonoethyl Ether C2H50(CH2)20(CH2>20H 179. Diethylenetriamin* |NH2C2H4)2NH Diethyl Ether, see Ethyl Ether 380 Diethyl Ethyl Phosphonate (C2H5)2PO,OC2H5) 381 Diethyl Ketone (C2H5(2CO 382. Diethyl Malonate CH2(C02C2H5)2 383 o-Diethyl Phthalete (C6H4)(COOC2H5)2 384 p-Diethyl Phthalete (C6H4l(CQOC2H5)2 385. Diethyl Sulfate {C2H50)2S02 386. Diethyl Zine Zn(C2H5)2 387. Diglycidyl Ether ((CH2*CHCH2>0]20 Diglycol, see Diethylene Glycol Waste Dis posal Pro cedure (See VI) TLV (ACGIH) PPM (mg/M3) N, F. P. A. Health Fire React. Sp. Gr. 15 11 0 1.11 -1.23 Vap. Dens. (Air=1) FI, Pt. C <F) 4.6s 96 1206) Ignit. Temp. C <F| Flam. Limits % 204 (400) 1.2- B.P, C (F> 202 (396) M.P. C (F) Sot. m HjO g/IOOg Other Solvents -10 (--14) QQ org. sol. Misc. Ref 7a 31 0 .95 3.6S 102 399 207 -39 W ale. NTTC, MCA (216)oc (750) (405) (-38) 7b 18 18 18 18 4b 5 3 (5) 15 .5 41 13 01 01 01 31 03 % 0 1.03 5.7S 105 (221) 83 (181) @11 mm sl. sol. ale. 0 82 2.96 t3 452 (55)oc (846) 101 (214) -42 (-44) 4,720 ale. 0 1.06 5.5g 93 (200)oc 199 -50 2.120 ale. (390) (-58) 0 1.23 117 (2431 302 (576) --40 (-40) insol. ale., bz. 0 1.23 7.7S 163 (325) 296 (565) -5 insoi. ale,, bz. 123) 1 1.18 5.3s 104 436 - 208 -25 insol. ale. (219) (817) (406) (-13) BDH 3 1.18 Ignites in air 124 (255) 28 dec. (82) dec,, ale. - 1.25 - 260 (500) PAGE 47 CMA 045671 SUBSTANCE/FORMULA 1,2*Oihydroxyanthraquinone, see Alizarin Dyes Waste Dis posal Pro cedure (See Vt) TLV (ACGIH) PPM (mg/M3) N, F. P. A. Health Fire React. Igmt. Vap- FI. Pt. Temp. Flam. B.P, Sp. Dens. c *C Limits C Gr. (Air^l) (F) (F) % (eF> M.P. C <F) Sol. in H2O g/IOOg Other Solvents Misc. Ref 388. 3,4'Dihydro-2H`Pyrn c5h8o 18 3 389. Diisobutyl Ketone [(CH3)2CHCH2]2CO 18 50 1 2 390. Diisopropyl Amine [{CH3)2CH}2NH 7a 5 3 3 391. Diisopropyl Ether (CH3)2CHOCH(CH3)2 15 500 2 3 392, Diisopropyl Fluorophosphate C6H14FPO3 7b % 0 .92 2.9S -18 (0) 86 (187) sol. ale. 0 .81 4,9 60 (140) ,8*6.2 @212F 168 (334) insol ale. 0 ,72 3.5 -1 (30)oc -84 83 (181) -61 (-78) si, so!. 1 .72 3.5S -28 443 1,4'7.9 69 -86 si. sol. [ ale. (-18) (829) (155) (-123) ~1.1 5.2s 46 (115) @5mm -82 (-116) BDH 393. Diisopropylperoxydicarbonate (CH3)2HOC>OC-OC>0-CH (CH3>2 00 394. 3P3'-Dimathoxybenzidine (NH2{OCH3)C6H3]2 22b 5 395. Oimethoxyethane (ch3o)2c2h4 15 396. Dimathoxymethane (CH30)2CH2 15 1000 0 car 2 4 2 3 4 ` 8.5$ 206 (403) 0 .85 3-1S 40 (104) 2 .86 2.63s -18 237 (Q)oc (459) 12exp. (53) NFPA 137 (279) insol. bz , ace , ale. 65 -113 sol. (149) (-171) ale , chi. BDH 46 -105 ale. (115) (-157) 33 397. Dimethoxypropane (CH30)2C3H6 15 - 2S. .85 3.6s -7 (19) - 95 (203) 398. N,N'Drmethyi Acetamide CH3CON(CH3)2 20 10 2s Is .94 3.0s 77 354 1.8-13.8 165 -20 (171) (669) (329) (-4) 00 ale., bz. PAGE 48 CMA 045672 SUBSTANCE/FORMULA OimdthyUmilW C2H7N jOO oimathylam<noazobenzBn#-2^ Naphthalan* C78H19N3 Waste Dis posal Pro cedure (See VI) TLV (ACGJH) PPM (mg/M3) N, Fa P. A. Health Fire React. 7a 10 3 4 0 8 Car. 401 2->im*thVlan'r,of:^'n " Ci5H15N 6 car. d02 N N-Oimethylaniline ' C6H5N(CH3)2 55 32 0 03 2 3-Dimethyla*obenzene ' (CH3)2C6H3N2C6H5 8 - car. Ignit. Vap. FI. Pt. Temp. Flam. B.P. Sp. Dens. C 6C Limits C Gr. (Air=1) (F> (F) % (F) M.P, C (F| Sol, m H2O g/IOOg Other Solvents Misc. Rel .68 1.65 <-18 430 2,8-14,4 7,4 -92 v. sol. ale. nfpa (0) (806) (45) (-134) BDH, MCA, MG8 1.08 174 (345) hot bz .95 4.17 63 371 (145) (700) 193 (379) - 2.5 si. so). ale,, bz (36) AlA, 8DH 404. 9,10''Dimethyl-1,2* Benzanthracene (CHjI^CigHiQ G Dimethylbenzylhydroperoxide, sea Cumene Hydroperoxide car. 122 (252) insol. CS2, bz, 405 N,N-Dimethyl-4-Biphenylamine ` (CH3)2(CgH4J2NH 6 car. 406 2,2-Dimethy! Butane (CH3)3CCH2CH3 407. Dimethyl Carbonate OCIOCH3)2 408. 1,2-Dinwthyl Chrytene (CH3)2Cl8^10 409. DimethyM,2-Dibromo-2,2pichloroethyf Phosphate (CH2Br)2C2H3Cl2P04 IB 1 3 18 3 18 car. 7b (3) 0 .65 3,00 --48 425 1.2-7.0 50 -98 insol. ale. 1--54) (797) (122) (-144) 1 1.1 3.1 19 (66)oc - 90 .5 insol. ale. (194) (32) BDH - 448 250 insol. si. sol., bz. (838) (482) ^200 392) PAGE 49 SUBSTANCE/FORMULA 1 Dimethyl Ether, " see Methyl Ether Waste Dis posal Pro* cedure (See VI) TLV (ACGIH) PPM (mg/M3) N. F. P. A. Health Fire React. 410. Dimvthyiformsmitfe (CH3)2NCHO 20 10 20 411. Dimethyl Fumarete (CHCOOCH3)2 18 2,6-Dimethyl-4-Heptanone, see Diisobutyl Ketone 1,1 -Dimethylhydrezine, see Unsymmetrical DimethylHydrazine 412. 1,4-Dimethylnaphthalene Cl0H6(CH3]2 18 Dimethyl nitrosoamine, see N-Nitrosodimethylamine 413. Dimethyl Phthalate C6H4ICO2CH3I2 414. 2,2-Dimethyl Propane <CH3)4C 18 IS) 0 1 0 18 1000 MGB 40 415. Dimethyl Sulfate <CH3)2SC>4 4b 1 42 0 416. Dimethyl Sulfide |CH3)2S 13 4 4 0 417. Dimethyl Sulfoxide ICH3)2SO 4b 1 1 0 Ignit b-STl > < FI. Ft. Tamp, Flam. B.P. M.P. Sol. in Sp. C C Limita C C H?0 Other Gr. PF) (F) % (F) <F) g/IOOg Solvents Misc. Ref. .94 2,51 58 445 2.2-15.2 153 -61 oc ale., bz. BDH (136) (833) (307) (-78) 192 (378) 102 (216) ch|. 1,02 - 262 (504) -18 (0) insol. ale. 1.19 6.7g 146 556 (295) (1032) - 288 (550) insoi. ale., bz. .61 2.48 <-7 450 1.4-7.5 9.5 (<20) (842) (49) --18 (0) insol. ale. 1,33 4.35 83 (181) - 189dec. -31 sol. (372) (-24) ale., bz. A|A, BDH, NTTC, MCA .8 2.INFRA <-18 206 2.2-19.7 37 -83 insol. ale., 0> (403) (99) (-117) MeOH 1.01 95 - 2.6-28,5 189 18 sol. ale., ace. (203)oc (372) (65) PAGE 50 CMA 045674 SUBSTANCE/FORMULA 430. Dipentene CiOH16 Dipentene Dioxide, see p-Mentha-1,8-Diene Waste Dis posal Pro cedure (See VI) TLV (ACGIH) PPM (mg/M3) N. F, P. A. Health Fire React. 18 2S 2 0 431. Dipentene Monoxide Cl0H140 432. Diphenylamme <C6H5)2^H 18 1 5 310 433. Diphenylmethane (CgH5)2CH2 434. Diphenyisuifide (C6Hg)2S 18 1 1 0 13 435. Dipropytene Glycol Methyl Ether CH30C3H60C3H60H 15 100 2S 436. m-Dodecane Cl 2^26 437. Dodecyl Sodium Sulfate Ci2H25NaS04 18 4b 0 \ is 2 0 438. Elon (H0C6H4NHCH3)2H2S04 439. Endrtn c12h8oci6 6 6 (.1) 3 1 0 440. Epichiorohydrin c3h5cio 4b 5 3 3 2 Ignit, Vap. FI. Pt. Temp, Flam. B.P. Sp. Dens. C C Limits C Gr. (Air=1) <F) lF) % (F| M.P, C ("FI Sol. in HjO g/IOOg Other Solvents Muc. Ref. .85 4.66 45 237 7-6,10 178 -97 insol. ale. (113) (458) @302F 1362) (-143) BDH .93 4.45s 67 (152) 1.16 5.8s 153 (307) 634 (1173) 1.01 5.8S 130 436 (266) (907) 1.12 .95 5.1s 85 (185)oc 75 5.96 74 (165) 204 (399) ,6- - - 1.18 27 (80) 3.29 41 (106)oc 75 (167) <--6 (21) 302 (576) 53 (127) insol. ale., bz., CS2 266 (511) 26 insol. (79) ale., chi. 296 (565) <-40 insol. K--40) bz.. CS2 189 (372) 216 (421) -12 (10) insol. ale., ace., CS2 260dec 425 ale. (500) 200 (392) 117 -48 <5 ale., bz. (243) (-54) BDH, MCA PAGE 52 CMA 045676 SUSSTANCE/FORMULA ^TTepn ^H^Ci4Hl405NPS Watte Dis posal Pro cedure (See VI) TLV (ACGIH) PPM (mg/M3) N, F. P. A, Health Fire React, 4a (.5) 3S 2 1,2-Epoxy-3-Phenoxypropane ` H2COCHCH2OC6H5 15 to Ignit Vap, FI. Ft. Temp, Flam, Sp. Dens, C C Limits Gr. (A.r=1) lFI (F) % 1.27 B.P. C (F) M.P. C <F) Sol. m H2O g/lOOg 1 Other i Solvents Misc. Ret 36 m$ol. (97) ale., bz 1.11 4.4s 245 (473) 3.5 (38) i43 1,2'Epoxv-Propao* h3c-choch2 15 100 2 4 2 .83 2.0 -37 (-35) 2.1-21.5 34 -104 v, sol. ale. (93) (-155) BDH 444. Epoxy Resin System* 445. Erbium Er 26 27k 2s 9,05 2900 (5252) 1497 (2727) insol. A|A,NSC 446. Ethane C2h6 Ethanediol, see Ethylene Glycol 18 4 0 .57 1.04 - 515 3-12.5 --89 -183 insol. | ale. (959) (-128) (-297) i ! 447. Ethanethiol C2H5SH^ 13 10 2 4 0 .84 2.14 <27 299 2,8-18 37 -144 1.5 ale. 81) (570) (99) (-227) BDH Ethanoic Acid, see Acetic Acid 44fi. Ethanol CH3CH2OH 449. Ethanolamine nhjchjch^oh 18 1000 0 3 0 .79 1.59 12 423 3,3-19 79 -- 114 W ace. (54) (7931 (174) (-173) 7# 3 2 2 0 1.02 2.11 85 (185) 170 (338) 11 (52) oe ale. BOH,NTTC, MCA NTTC.MCB 450- Ethoxy Acetylene C2H5OCCH 16 .79 <-7 lOOexp. !<19) (212) 50 (122) insol. ale. 2-Ethoxy Ethanol, see Cellosolve PAGE 53 CMA 045677 SUBSTANCE/FORMULA 2-Ethoxy Ethylecetate, see Cellosolve Acetate Waste Di* posai Pro cedure (See VI) TLV (ACGIH) PPM (rog/M3) N, F. P. A. Health Fire React. 451. 4-Ethoxy-2-Nitro-Aniiine C2H5OC6H3NO2NH2 452. Ethyl Acetanilide CH3CON(C2H5)(C6H5) 6 20 020 453. Ethyl Acetate CH3COOC2H5 18 400 1 30 454. Ethyl Acetoacetate CH3COCH2COOC2H5 18 220 455. Ethyl Acrylate CH2CHCOOC2H5 18 25 2 3 2 Ethyl Alcohol, see Ethanol Ethyl Aldehyde, see Acetaldehyde 456. Ethylamine C2H5NH2 7a 10 3 4 0 457. Ethyl sec-Amyl Ketone CH3CH2CHCH3CH2COCH2CH3 18 25 458. N-Ethyl Aniline c2h5nh(c6h5i 5 320 459. Ethyl Benzene C6H5C2H5 18 100 2 3 0 Ignit. Vap. FI. Ft. Temp. Flam. B.P. Sp. Dens. C C Limits C Gr. (Air=1) (F) (F) % (F) M.P. C <F) Sol. in HjO g/IOOg Other Solvents Mtsc. Ref. 113 (235) chi. .94 5.62 52 (1261 258 (496) 54 (129) insol. ale. .90 3.04s -4.4 427 2.18-9 77 --84 7.520 ale. (24) (800) (171) (-119) 1.03 4.48 84 (183)oc 181 <-80 1317 (358) K-112) ale., bz. .92 3.5 16 273 1,8(60) (524) 100 <-72 sol. (212) K-98) aic. BDH, NTTC, MCA. SDS BDH BDH, NTTC, MCA .80 1.56 <-18 384 3.5-14 17 -81 00 ale. (0) (723) (63) (-114) .85 57 (135)oc 161 (322) Insol. ale. ,96 4.18 85 (185)oc 205 (401) -64 (-83) insol. ale. ,9 3.7 15 432 1-6.7 136 -95 .01'5 ale. (59) (810) (277) (-139) BDH, NTTC, MGB BDH BDH PAGE 54 CMA 045678 substance/formula ^^Kthyl Benzoete ^K6H5COOC2H5 Ethyl Bromide Bromoethane tBi Ethyl BromoiCniti CH2BrC02C2H5 462 Ethyl Butyl Ketone C2H5COC4H9 463. Ethyl Butyrate C3H7CO2C2H5 464. Ethyl Chloride CH3CH2CI 465 Ethyl Chloroacetats ' CICH2COOC2H5 466 Ethyl Chloroformett CIC02C2H6 467 Ethyl Crotonate 'CH3CHCHCO2C2H5 468. Ethyl Cyenoeeetete CNCH2CO2C2H6 Ethyl Cyanide, see Propionitrile 469. Ethylene H2C=CH2 Watte Dis posal Pro* cedure (See Vi) TLV IACGIH) PPM (mp/M3) N. F. P. A. Health Fire React. 18 1 2 0 Ignit Vap. FI. Pt. Temp. Flam. B.P. Sp. Dans. C C Limits C . Gr. (Air=l) (FI (F) % (F| -3o 0o^S Sol. in HjO 8/IOO9 Other Solvents 1.15 5.17s 96 (205) 213 (416) -35 insol. (-31) ale. Mix. Ret. 4b 18 50 3S 12 18 2 3 4b 1000 2 4 4b 2 2 4b 3s 3 18 2 3 14 3s 1 1.51 5.8S 48 (118) 159 (318) <-20 (<--4} insol. ale. 0 .82 3.93 46 (115)oc 148 (298) -37 (-35) insol. ale. 0 .88 4.0 26 463 (79) (865) 121 -97 (250) (-143) .6826 ale- BOH 0 .92 2.2 -50 519 3.6-15.4 12 -139 .450 ale. NFPA (-58) (966) (54) (-218) BOH, MCA 0 1.26 4.3 66 (150) 144 (291) -27 (-17) insol. ale. BDH 1 1.36 3.74 16 (61) 95 -81 (203) (-114) dec. bz., dec. ale. BDH 0 .92 3.93 2 (36) - 143-7 45 insol. ale. (289-96) (113) 0 1.06 3.9S 110 (230) 206 (403) -23 (-9.4) 225 ale. BDH 18 5500 1 4 2 .001 1.0 450 (842) 3.1-32 --104 -169 260 (-155) (-272) si. sol., ale. PAGE 55 CMA 045679 SUBSTANCE/FORMULA 470. Ethylene Chlorohydrin CH2OHCH2CI 471. Ethylene Diamine NH2CH2CH2NH2 472. Ethylene Dibromide BrCH2CH2Br 473. Ethylene Dichloride CICH2CH2CI 474. Ethylenedinitriie Tetracettc Acid Dipotenium Salt (EDTA) K2C10O9N2H19 47S. Ethylene Glycol CH2OHCH2OH Waste Dis posal Pro cedure (See VII TLV (ACGIH) PPM (mg/M3) N. F. P. A. Health Fire React. 4a 5 3 2 0 Ignit. Vap. FI. Ft, Temp. Flam. B,P. Sp. Dens. C C Limits C Gr. (Ain^l) lF) (F) % <F> M.P. C (F) Sol. in H2O g/IOOg Other Solvents 1.21 2.78 60 425 4.9-15,9 128 -69 (140)oc (797) (262) (-92) ale. Misc. Ref, Al A, BDH, MCB 7a 10 3 2 0 .90 2.07 43 1110) 117 8.5 v. sol. ale. (243) (47) BDH NTTC 4b 25 4b 50 4c 3s 23 2,18 6.48S 131 (268) 9.3 (48) si. sol, ale. 0 1.26 3.4s 13 413 6.2-15.9 83 -36 si. sol. ale. (55) (775) (182) (-32) -- BDH BDH, Al A, NTTC, MCA CED 18 ,2 1 1 0 1.11 3.14s 111 413 3.2- 198 -13 so ale., ace. BDH, NTTC (232) (775) (388) (8.6) Ethylene Glycol Monobutyl Ether, see Butyl Cellosolve Ethylene Glycol Monoethyl Ether, see Cellosolve Ethylene Glycol Monomethyl Ether, see Methyl Cellosolve Ethylenimine, see Azirjdlne 476, Ethylene Nitrate C2H4(0N02)2 477. Ethylene Oxide (CH2)20 4a .2 15 50 % 2S - 1.49 5.25s - 114exp. -20 (237) (-4) insol. ale. 2 4 3 .87 1.49 <-18 429 3-100 11 -111 sol. ale., bz. AIA, MCA NFPA o> (804) (51) (-168) PAGE 56 CMA 045680 1 SUBSTANCE/FQRMULA ^^Apthyl Ether ^^R2H5oc2H5 Ethyl Ethynyl Ether, see Ethoxyacetylene mg. Ethyl Fluoride CH3CH2F abO Ethyl Fluoroacetate FCH2COOC3Hg 481. Ethyl Formate HCOOC2H5 482 2*Ethyl Hefcanol ' C4H9CH(C2H5)CH2OH 483. Ethyl lodida C2H5I 484 Ethyl Lactate ' CH3CN0HC02C2H5 Ethyl Malonete, see Diethyl Malonate Ethyl Mercaptan, see Ethanethiol 485. N-Ethylmorpholine C6Hi3NO 486. Ethyl Nitrite Q2H5ONO Waste Dis* pottl Pro cedure (See VI) TLV (ACGIH) PPM (mg/M3) N, F, P. A. Health Fire React. 15 400 2 4 1 Ignit. Vap. FI. Ft. Temp. Flam. B.P. Sp. Dens. C C Limits c Gc. (Air=1) (F> tP) % lFl M.P. c lF) Sol. in H2O g/lQOg Other Solvents Misc. Ret. .71 2.55 --45 180 1.85-48 34 -123 7.62 bz. NFPA (-49) (356) (94) (-189) AIA BDH, MCA 4b 4b Ifi 100 18 4b 18 *5 -^t 23 22 2S 2S 22 .82 1.665 -38 (-36) -143 19814 elc. (--225) 3-7$ 116 (241) 0 .95 2,55 -20 455 2.7-13.5 54 -79 1118 ale. (-4) (851) (129) (-110) 0 .83 4.49 84 (184) 1.95 5.4g 180-5 <-76 insol. (356-65) (-105) ale. 72 (162) -105 420 (-157) ale. 0 1.04 4.07 46 400 1.5-30 154 (115) (752) @212SF (309) 00 ale. BDH BDH BDH BDH 5 20 2 3 0 .92 4.00 32 (90)oc 138 (280) 4a 5 2 4 4 30 2.59 -35 90 4.1-50 17 (-30) (194) (63) ee ale. dec. ale. PAGE 57 CMA 045681 SUBSTANCE/FORMULA Waste Dis posal Pro cedure (See VI) TLV (ACGIH) PPM Img/M3) N. F. P. A. Health Fire React. 487. N-Ethyl-N-Nitroso-N-Butylamina C6H4N2 488. N-Ethyl-N-Nitrosovinylamine C4H8N2O 7a 7a car. car. 489. Ethyl Oxalate (COOC2H5)2 18 3S 2 0 Ignit. Vap. FI. Pt. Temp. Flam. 8.P. Sp. Dens. C c Limits C Gr. (Air=?1) (F> lF) % <F) M.P, c <F) Sol. in HtO g/IOOg Other Solvents 1.08 5.04 76 (168) 186 (367) -41 (-42) si. sol. ale. Misc, Ret 490 p-Ethyl Phenol CH3CH2C6H4OH 18 1 0 1.0 104 (219) 219 (426) 45 (113) si. sol. ale., bz,r CSj 491. 2*Ethyl*3*Propyl Acrolein CH3{CH2)2CHC(C2H5)CHO 2 2 2 1 .85 4.35 68 (155) 163 <100 insol. (325) K2121 ale. 492. Ethyl Silicate <c2HS)4Si4 493. Ethyl Vinyl Ether CH2CHOC2H5 18 100 2 2 0 .93 7.22 52 (125) HOsubl. dec. (230) si. sol., bz. BDH 15 2 4 2 .75 2.46 <-46 202 1.7-28 36 -115 si, sol. ale. (<-501 (395) (97) (-175) 494. Excelsior 29 495. Fatty Acids 24a NTTC 496. Ferbam Fe[CH3)2NCS2)3 497. Ferric Chloride (60%) FeCl3 13 (15) 1b 2S ]s 2.80 - dec. 306dec. 740 (583) ale., MbOH 498. Ferrosilicon Fe + Si 26 2S 5,4 - - insol. NSC 499 Ferrous Ammonium Sulfate FeN2HgS208'6H20 11 1.86 100-10 26.920 dec. (212-30) PAGE 58 CMA 045682 SUBSTANCE/FORMULA Ferrous Chloride ^MFeCl2 Waste Dis posal Pro* cedure (See VI) 11 cm Ferrous Sulfate &U ' FeS04-H20 11 502 Ferrovanadium Dust ' FeV cn3 N-2-Fluorenylacetamide C15H13N0 2G 6 504. Fluorine F2 505 FJuoroacettc Acid ` CH2FCOOH 12a 4c 505. Fluoro-Boric Acid HBF4 507- 4-Fluoro-4*Biphenylamine Ci2Ht0NF Fluoroethane, see Ethyl Fluoride 24b 6 508. Fluoroethylene C2H3F 4b Fluorohydric Acid, see Hydrofluoric Acid 509. 2'-Fluoro-4-Phenylactanilide C14H1 2nof 6 1 t o h; 1 N. F, P. A. Health Fite React. Is !S (i) % car. 2s ,1 4 0 3 2S % car. 2St car. 'St Sp. Gr. 3.16 Van. Dens. (Airsl) FI. Ft. C (F) Ignit. Tamp. C (F) Flam. Limits % B.P. C <F) 1026 (1879) M.P. 'C (FI Sol. m HtO g/lOOg Other Solvents 670 64.410 ale. (1238) 2.97 - sl. sol, Misc. Ref. 1.1 >-'s - 192 insol. ale. (378) -188 -218 dec. (-307) (-360) 165 (329) 33 so! h (91) I30dec, (266) 00 ale. ale. AlA, MCA, MGB, NASA BDH - 2.6-21.7 -51 -160 insol. ale., bi. (-60) (-256) CMA 045683 SUBSTANCE/FORMULA 510. 2'*F|uoro-4'*Phenylacetanilide Cl4H12N(^F Waste Dis posal Pro cedure (See VI) TLV (ACGIH) PPM (mg/M3) N. F. P. A. Health Fire React. 6 car. Ignit. Vap, FI. Ft. Temp. Flam. B.P. Sp. Dens. C C Limits 6C Gr. <Air=1) <F) (F) % lF) M.P. "C (F> Sol. in H2O g/lOOg Other Solvents Misc. Ret 511. 4"'-Fluoro-4'-Phenylacetanilide Ci4H12NOF 512 Fluoro-Silicic Acid h2sif6 6 24b car. % - dec. sol. SDH 513. Fluorotnchloromethane CCI3F 514. Formaldehyde HCHO 515. Formalin (39% Formaldehyde Methanol Free) 516. Formalin (37% Formaldehyde15% Methanol) 517 Formamide HCONH2 26 1000 1.49 24 -Ill insol. ale. (75) (-168) 2 5 2 4 0 .82 1.08 430 7,0*73 (806) -19 --92 sol. 1-3) (-134) ale. 2 5 2 2 0 .82 85 (185) 101 (214) 25 2 50 (122) 101 (214) 20 2S 2S - 1.13 155 (310) 21 Idee. 2.6 (412) (36) 00 ale. BDH, NTTC, MCA, NSC Form-Oimathyiarnide, see Dlmethylformamide 518. Formic Acid HCOOH 519. Fumartc Acid HOOCCH-CHCOOH 24a 5 24a 3 2 0 1.22 1.59 69 601 18-57 101 8.2 oa ale. (156) 11114) (213) (47) Is is 1.64 290subl. sl. sol. (554) ale. BDH 520. Furan C4H4O 18 10 1 4 1 .94 2.35 <0 32) 32 -86 insol. (90) (-123) ale. PAGE 60 CMA 045684 SUBSTANCE/FORMULA furfural ^^C4H3OCHO c22 Furfuryl Alcohol C4H3OCH2OH 523, Gadolinium ' Gd r?4 Gallic Acid C6H2(0h>3C00h 525. Gallium Ga 526 Garments, Contaminated 527, Gasoline C5H12 t0 C9H2^ 528- Germane Ge H4 5^9- Germanium Ge 530. Germanium Dioxide Ge02 531. Germanium Hydride Ge2H6 532 Germanium Tetrachloride GeCl4 Waste Dis posal Pro- eedure (See VI) TLV (ACGIH) PPM (mg/M3) N. F. P, A. Health Fire React, 25 1 2 1 78 50 1 2 1 Sp. Gr. 1.16 1.13 Vap, Dens. (Air=1) FI. Ft. C lF) Ignit. Temp. C lF) Flam, Limits % B.P. c (F) 3 31 60 316 2,1- (140) (600) 162 (324) 3,37 75 491 1.8-16 3 (167)oc (916) 171 (340) M,P. C (F) -37 (-35) -31 (-24) Sol. in HzO 9/IOOg 9113 Cw 1 i Other I Solvents 1 Mise Ret ale | BDH NTTC 1 1------------------------ale CED 27k 79 -3000 1312 insol. (- 5432) (2394) 24a 1.69 253dec. (487) 1 13 ale . ace. 27k TS 5.90 2403 30 msol. (43571 (86) 29 IS -500 1 ' 3 0 S 3 0-4.0 -43 280-456 1.4-7.6 38-204 (-45) (536-853: (100-400) NTTC 26 3S 3S 3.43 27k 2S 2S 5.35 ! 27k 2S 6.24 -90 (-130) -165 (-265) 2700 958 (4892) (1756) insol. noo (2012) insol. AIA AIA 17 6.74 1.5S 29 -109 dec. AIA (84) (-164) 1b 5 3s 1.88 86 (187) -50 (-57) dec. ale. AIA CMA 045685 SUBSTANCE/FORMULA 533. Glutaraldehyde OCH(CH2)3CHO 534. Glutaric Anhydride C5H603 53$. Glycerol CH2OHCHOHCH2OH 536. Glycido! C3H6O2 537 Glycolic Acid HOCH2COOH 538. Glyoxal OCHCHO 539. Grain Fumigants {Agricultural Insecticides) 54Q. Greases 541. Guaiacoi HOC6H4OCH3 542. Hafnium Hf 543. Helium He 544 Heptachlor C10H5CI7 Waste Disposal Pro cedure (See VI) TLV (ACGIH) PPM (mg/M3) N. F. P. A. Health Fire React. 2 Igmt. Vap. FI. Ft. Temp, Flam. B.P. Sp. Dens. C C Limits c Gr. (Air=1) (F) (F) % lFI M.P. C lF) Sol. in H2O g/IOOg Other Solvents .72 3.4s I88dec. (370) ale. Misc. Ref. 24a 303 (577) 18 1 1 15 50 % 0 1.26 3.17S 160 393 (320) (739) 1.12 2.15s 29Gdec. (554) 18 (64) 160dec. (320) ao ale , CS2 MTTC QO ale., b*. 24a 2S dec. 79 (174) sol. ale. 2 2S 'S 1.14 50 (122) 15 v. sol. ale. (59) BDH 7h 122-140 (50-60) oc 18 15 2S 2S 1.13 82 (180) 205) (401) 28 1.715 ale. (82) NTTC NTTC 27k (.5) 13.31 20 5400 2150 insol. (68) (9752) (3902) 26 'S .13 -269 -272 (-452) (-458) @26atm. .9 4b (.5) 3S 1.58 95 (203) insol. aic. PAGE 62 CMA 045686 SUBSTANCE/FORMULA Heptane CH3(CH2)5ch3 2-Heptanone. Methyl Amyl Ketone 3>Heptenona,, see Ethyl Butyl Ketone K4S. n-Heptylamine c7h16nh3 647 Hwuchlorobenim cgcie HexacMorocyelohexane, see Lindane 548, Hchloroth,r CI3CCCI3 549, Hexachloronaphthalene ClOH2cl6 550 Hexafluoroethene G2F6 55I Hexamethy/sne Tetrtmine <CH2)6N4 552. Hmn CH3{CH2l4CH3 553. 1,6-Hexanediemine NH2(CH2)6nh2 Watte Dis posal Pro cedure (Sae VI) TLV (ACGIH) PPM Img/M^) N. F, P. A, Health Fire React. is 500 30 Ignit. Vap. FI. Pt. Temp. Flam. B.P. $p. Dens, C C Limits C Gr. (Ar=1) (F) (F) % (F) M.P. C <F| Sol. in H2O g/IQOg Other Solvents Misc. Ref. .68 3,45 -4 223 i .2-6.7 98 -91 insol. ale. (25) (433) (208) (-132) BDH 7a 2 2 0 .77 4,0 54 158 -23 si. so). ale. (129)oc (316) (-7.6) 4b 's 1.57 9.8S 242 (468) - 322 (612) 230 (446) insol. b2. 26 4b (.2) 26 2S 3s 7a 18 500 2S 1 7a 2S Ost s 30 Is 2.09 186 (367) insol. ale. 1.59 - 1.33 - .66 237 -79 -94 (-110) (-137) insol. $1. sol., ale. 250 (482) - - 280subJ, v. sol. ale., ace. (536) -22 (-7) 261 (502) 1,1-7.5 68 (154) -96 (-141) insol. ale. SDH,NTTC 204 (399) 42 1108) v, sol. ale., bz. PAGE 63 CMA 045687 SUBSTANCE/FORMULA Hexanedioic Acid, see Adipic Acid Waste Dis posal Pro cedure (See VI) TLV (ACGIH) PPM |mg/M3) N. F. P. A. Health Fire React, Ignit. Vap. FI. Ft. Temp. Flam. B.P. Sp. Dens. c *C Limits c Gr. lAr=1) ("FI (F) % (FI M.P. C (F) Sol. m HjO 0/1 OOg Other Solvents Misc. Ret. Hexanoic Acid, see Caproic Acid 554, m-Hexanol CH3<CH2)4CH20H 2-Hexanona, see Methyl Butyl Ketone 555, 1-Hexene H2C=CH(CH2)3CH3 556. 2-Hexene CH3CH=CHCH2CH2CH3 IS 1 2 0 .81 3.52 60 293 158 -45 si. sol. ale,, bz. BDH (140) (559) (316) (-49) 18 500 18 1 1 3 0 .7 2.97 <-7 20) 3 0 .68 2.92S <-7 20) 1.2-6.9 63 (145) -139 insol. (-218) ale. 69 (156) -146 insol. (-231) ale. Hexone, see iso-Butyl Methyl Ketone 557. sec-Hexyl Acetate 18 50 1 2 0 .86 4.97 45 (CH3)2CHCH2CH2CH200CCH3 (113) 141 (286) --64 insol. (-83) ale. Hexyl Alcohol, see m-Hexanol 558. Hexyl Amina c6h13nh2 559. Holmium Ho 560. Hydracrylic Acid-0-Lactone C3H4O2 7i 2 3 27k 24a car. st 2 0 .76 3,49 29 (84)oc 8-80 1.15 2.5 74 (165) 129 (264) -19 si. sol. (-2,2) ale. 2600 1461 in$oi. (4712) (2662) 2.9- 155 -33 dec. chi. (311) (-27) PAGE 64 CMA 045688 SUBSTANCE/FORMULA Hydrazine HjNNHj Waste Dis posal Pro cedure (See VI) tlv (ACGIH) PPM (mg/M3) N. F. P. A, Health Fire React. 16 1 333 562 Hydrazaie AchJ ' HN3 81 % 563 Hydrazine Saltt and Solutions 16 1 % 2S 564. Hydnodic Acid HI 24b 5MGB % 565 Hydrobromic Acid HBr 566 Hydrochloric Acid HCI 567 Hydrocyanic Acid HCN 568. Hydrofluoric Acid HF 569. Hydrogen H2 Hydrogen Bromide, see Hydrobromic Acid 24b 3 24b 5 14 10 24b 3 .2? % 30 44 40 04 0 2 0 Igmt Vap. FI. Pt. Temp. Flam, B.F. Sp. Dens, C C Limits C Gr. (Air=1) (F> tFI % (F) 1 01 UNFPA 38 (100) Varies with Surface 4.7-100 113 (236) (74- 5186F) 1.09 exp. 37 (99) M.P. C (F) Sol. in H2O g/IOOg Other Solvents 1.4 v. sol. ale. (34) -80 Op aic. (-112) Misc. Ref. Al A, SDH, MCA, MCB. NASA - 0OH, MCA 5.66 3.50 -35 (-31) @4 atm -51 42,5<> (-60) -67 -87 221 (-89) (-125) ale. ale. 1.19 1-3S none -85 (--121) -115 830 (-175) ale., bz. .69 .93NFPA -18 538 6-41 (0) (1000) 26 -14 QC ale. (79) (6.8) 1.0 71s none 20 -83 (68) (-117) 90 .09 .069 585 4-75 (1085) -253 -259 2.10 (--423) (--434) ale. BDH BDH, MGS Al A, BDH, NTTC MCA, MG0 BDH, MCA AIA, BDH, MCA.SDS, MGB. NSC MCA, NASA Hydrogen Chloride, see Hydrochloric Acid Hydrogen Cyanide, see Hydrocyanic Acid PAGE 65 CMA 045689 SUBSTANCE/FORMULA Hydrogen Fluoride, see Hydrofluoric Add West* Dll' potel Pro cedure (See VI) TLV (ACGIH) PPM (mg/M3) N, F. P, A. Health Fire React. Ignit Vap. FI. Pt. Temp. Flam. B.P, Sp, Dana. C C Limits C Gr. (Air=l) (F> (Ft % (F) M.P. C (F) Sol, in H2O g/100g Other Solvents Mix. Ref. Hydrogen Iodide, eee Hydrlodic Acid 570. Hydrogen Peroxide H202 (90%) 22a 1 2 0 3 1.39 - 140 (284) 00 ale. MCA 571. Hydrogen Peroxide (27-52%) 572. Hydrogen Selenide H25e 573. Hydrogen Sulfide H2S 22a 1 2 0 1 1.39 27* .05 23 10 3S 3s 2,00 2.8S 3 4 0 1.19 1.2NFPA * 107 -11 Ob ale. SDH, MCA 1225) (12) for 35% -42 (--44} -64 (-83) 3774 cs2 260 4,3-46 (500) -60 -83 (-76) (-117) 437 ale., CS2 AIA, MCA, MGB. NSC 574. p-Hydroquinone C6H4(OH)2 18 (2) 2S Is - 1.33 3.85 165 (329) - 285 171 sol. ale. (545) (340) 575. Hydroqulnone Monomethyl Ether CH3QCQH4OH 576. Hydroxydimethylersine Oxide ICH3)2AsOOH 15 7b 2S Is 3s 1.55 - 131 (268) 421 (790) - 246 54 sol. (475) (129) ale,, bz. - -- 200 v. sol. ale. (392) 577. Hydroxylemine NH2OH 7a 1 3 3 1.20 - I29exp. (264) 56 (133) 34 sol. (93) ale., MeOH 578. Hydroxylemine Hydrochloride nh2oh.hci 7a 2S 3s 1.67 - - dec. 153 83*7 ale., MeOH (307) Hypo, see Sodium Thiosulfate PAGE 66 CMA 045690 SUBSTANCE/FORMULA Waste Dis posal Pro cedure (See VI) TLV (ACGIH) PPM (mg/M3) N. F. P. A. Health Fire React. Ignit, Vap, FI. Pt. Temp. Flam. B.P. $0. Dens. C C Limits C Gr. <Air=1l (F) (F) % (FJ M.P. C <F) Sot. m H2O g/IOOg Other Solvents Mise. Ref ^ Diethanolamine 579, 5-lndinol C9H10O 58O. In cgt, industrial Gas (Liquefied Hydrocarbon Gas) 18 27 k 18 3S 2S 255 (491) 55 (131) *1. SO). ale. 7.3 - 2000 165 insol. (3632) (311) -108 (-162) NTTC 582. Iodic Acid HIO3 24b 3s 2$ 4.63 -- HOdec. 28B'8 ale. (230) 583. Iodine '2 584 Iodine Chloride tci 585 Iodine Pentefluoride IF5 588 Iodine Trichloride ICI3 12a .1 21 21 3 21 3S 3S 2S 3s 3$ 's - 4.93 3.18 3S 3.75 3.12 - - 184 113 .0320 ale., bz., BDH, NSC (363) (235) cs2 97 14-27 dec. (207) (57-81) ale. BDH 98 (208) 9.6 dec. (49) MGB 77dec. 101 (171) (214) dec. @16 atm. ale., bz, BDH 587. lodoecetic Acid C2H3102 4c !st dec. 82 sol. (180) ale. lodoethene, see Ethyl Iodide todomettone, see Methyl iodide CMA 045691 SUBSTANCE/FORMULA 3-lodopropenc, see Allyl Iodide 588. Isoprene CH2C(CH3)CHCH2 Isothiocyanic Acid, see Methyl Isothiocyanate 589a Jet Fuel JP-1 589b Jet Fuel JP-4 589c Jet Fuel JP-5 589d Jet Fuel JP-6 590. Kerosene 591. Ketene ch2co 592. Laetonitrile CH3CH|OH)CN 593. Lamps, Fluorescent 594. Lanthanum La Waste Dis posal Pro cedure (See VI) TLV IACGIH) PPM (mg/M3) N. F. P. A. Health Fir* React. Ignit. Vap. FI. Pt. Temp. Flam. B.P. Sp. Dens. C C Limits C Gr. |Ain=l) (6F) ("FI % (F) M.P. C (F> Sol. in HjO g/IQOg Other Solvents Misc. Ret, 18 2 4 1 68 2.35 -54 220 34 -147 insol ale (-65) (428) (93) (-233) 18 18 18 18 18 18 .5 14 26 27k 020 35-63 228 (95-145) (442) <-46 (<--501 NTTC 1 30 -23-1 (-10-30) 242 (468) <-46 {<--50) NTTC 020 35-63 246 (95-145) (475) <-46 --50) NTTC .8 <i 38 224 .6-3.7 121 <-46 (100) (435) (250) --50) NTTC 0 2 0 .81 4.5S 38-66 229 .7-5 170-300 <-46 (100-150) (444) (338-572) (<--50) NTTC 3s 1.45S -56 -151 (-69) (-240) dec. dec., ale. % 3S .99 3.45s 77 (171) 182dec. -40 (360) (-40) Op cs2 is 3S 6.15 3470 920 (6278) (1688) dec. PAGE 68 CMA 045692 substance/formula ftks. Lacquer Oiluent 596. U* no? Laurie Acid 0 CH3lCH2)ioCOOH 598 UurOyl Peroxide (ChH23CO)22 599. Lead Pb 600. Lead Acetate Pb(C2 ^02)2-2 H20 601, Lead Arsenate PbHAs04 g02. Lead Carbonate {PbC03)2 Pb(OH)2 603. Lead Nitrate Pb(N03)2 604. Lead Oxide PbO 605. Lead Thiocyanate Pb(SCN)3 606. Ligroin Waste Dis posal Pro* cedure (See VI) TLV (ACGIH) PPM (mg/M3) N. F. P. A. Health Fire React. 18 3 0 Ignit. V#p. FI. Pt. Temp. Flam. B.P. Sp. Deni. 6C C Limits C Cr. (Air=*1) (F) (FI % (F) M.P. 6C lF> Sol. in Other Solvents .7 -11 232-88 1.2-6 88-107 (12) (450-550 (190-225 Mik. Ref, 26 24# 22b 2S 'S .87 02 3 299 (570) 48 (118) insol. ale., bz. 49 (120) insol. NTTC NFPA 27a 1.2) 27f - 3$ 2$ 3$ 11.3 3.25 1744 (3171) 327 (621) insol. 75 (167) 4420 27cJ (.15) 3$ 7,80 720dec. insol. (1328) 27f 3S - 61.4 27f 1 0 1 4.53 400dec. insol. (752) 470dec. 38 (878) ale. 27f (.15) H H ~9.5 888 insol. (1630) BDH, MCA 27f 1 i 1 3.82 190dec. Insol. (374) 18 <22 72) BDH PAGE 69 CMA 045693 SUBSTANCE/FORMULA Umonant, am Dipentene sea p-Moutha-1,8-Diene 607. lindane CeHgCle 608. liquefied Petroleum Gas (LPG) 609. Lithium Li 610. Lithium Aluminum Hydride UAIH4 611. Lithium Borohydride L1BH4 612. Lithium Carbonate L12CO3 613. Lithium Hydride LIH 614. Lutecium Lu 615. 2,6-Lutidine (CH3)2C5H3N 616. Magnesium Mg 617. Magnesium Chlorate Mg(CI03)2.6H20 Waste Dispossi Pro cedure (See VI) TLV (ACGIH) PPM (mg/M3) N. F. P. A. Health Fire React. Ignil Vsp. FI. Ft. Temp. Flam, B.P. Sp. Dens. C C Limits "C Gr. (Air=1) (F) (F) % l"F) M.P. C (F) Sol. in H2O g/IOOg Other Solvents Misc. Ref, 4b (.5) 3$ 1.87 - 288 (550) 113 insol. (235) ace., bz. 18 1000 3S <-46 K--50) - NTTC 3 1 1 2 .53 - 1337 179 dec. (2437) (354) AIA, BDH,NSC 17 3 1 2 32 125dec. dec. (257) BDH, NSC 17 2S - .66 284 (543) 279 dec. 1534) BDH,NSC 11 2.11 17 (.025) 1 4 2 .82 27k 2S 9.84 - May Ignite Spontan eously 1310dec 723 $1. sol. (2390) (1333) - 680 dec. (1256) 3327 1652 (6020) (3006) BDH 7a - .92 3.7S 38-46 - 144 --6.6 si. sol,, ale. BDH (100-15) (291) (20) 27a 0 1 2 1.74 - 1107 651 dec.100 (2025) (1204) 12a * 2S 3S - 1.80 * 120dec. 35 12910 ale. (248) (95) AIA PAGE 70 CMA 045694 substance/formula Btgig Magnesium Chloride VigCi? ci9 Magnesium Nitrate Mg<N03)2'2H2^0 620 Magnesium Oxide MgO 621 Magnesium Perchlorate MglCI04)2 622 Malathion CiOH196PS2 623 Malaic Acid HOOC(CHI2COOH 624 Maleic Anhydride (C0CHI20 625- Manganese Mn 626 Manganese Sulfate MnS04 627 p-Mentha-1, 8-Diene Ciqh16 Mercaptoacetic Acid, see Thioglyeohc Acid 628 2`Mercaptoethanol HSCH2CH2OH Waste Dis posal Pro cedure (See VI) TLV (ACGIH) PPM (mg/M3) N. F. P, A. Health Fire React. 11 2S SpGr. 2 32 Vap. Dens. (Air=1) FI. Pt. C (F) Igmt. Temp, C lF) Flam, Limits % B.P. C ("FI M.P. C (FI Sol. in H2O g/IOOg 1412 708 5420 (2574) (1306) i Other Solvents Mim:, Ret. ale 11 1 0 26 (15) 2S 1 2 03 3 65 330dec (626) 129 (264) sol 3600 --2600 si sol (6512) (4712) ate, --T--------------- 12a 1 0 1 2 2 7b (15) 3S 24a 2S Is 1 23 1.59 4 0S 25ldee (484) SO2 5 ate j 156 (313) Q? 7mm 29 (37) 135dec, (275) si sol ale., bz 1 v sol. | ale . ace 124a m 3 0 9 3.4s 102 477 1,4-7 1 202 53 dec ace (216) (890) (396) (127) AIA, MCA 27a (5) 7S 2S 7 20 2030 1260 (3686) (23001 dec 11 2S 3 25 850dec (1562) 700 (1292) 526 ale 18 1 2 0 3.84 7 4S 45 237 .7-6.1 170 <60 insol (113) (458) (338) (<140) 13 22 1 14 2 69 74qc (165) 157 (315) sol ale PAGE 71 CMA 045695 I SUBSTANCe/FORMULA 629 Mercuric Chloride M9CI2 630 Mercury Hg 631 Mercury Compounds (Organic! 632 Mercury Fulminate HgC2N202 633 Mesityl Oxide CgHioO 634 a-Methacrylie Acid CH2C(CH3>COOH Waste Dis posal Pro cedure (See VI) TLV (ACGIH) PPM (mg/M3) N. F. P. A. Health Ftr* React. 27b 3S Sp. Gr. 5 44 Vap. Dens. (Air=1) FI. Ft. C ("FI Ignit. Temp. C (F) Flam. Limits % B.P. C (F) 304 (579) M.P. C (F) 277 (531) Sol. in H2O g/lOOg 69=0 Other Solvents ale 27b 01 3S 13 6 357 (674) -39 (-38) msol 27b ( 01) 3S 27b 18 25 24a 3S 3S 4 42 330 86 35 31 344 (88) (652) 3 2 2 1,02 77oc (171) exp si 501, ' ale 108 (226) -59 (-74) sol 158 (316) 16 sol (61) ale ale 63B Methane ch4 636 Methanesulfonic Acid CH4O3S 18 4c 1 4 0 42 6 1 48 537 (999) 5-15 -161 -183 si sol, (-258) (-297) 167 (333) 20 v. sol (68) b? ale, Methanethioi, see Methyl Mercaptan 637 MethoxychlOr (DMDT) (CH30C6H4)2CHCC(3 4b (15) 12S 94 insol org.sol (201) 2-Methoxyphenol, see Guaiaco! 4-Methoxy Phenol, see Hydroqumone Monomethyl Ether Misc, Hef. AIA, BDH, NSC BDH NSC BDH PAGE 72 CMA 045696 CMA 045697 SUBSTANCE/FORMULA Waste Dll' poial Pro cedure (See Vl) TLV (ACGIH) PPM <mg/M3| N. F, P. A. Health Fire React. 644 10-Methyl-1, 2-Benzanthracan# ClSHnCH3 18 Car Ignit. Vap. FI. Pt. Temp. Flam. B.P. Sp, Dens. C C Limits C Gr. (Air=1> (F) l6F) % lF) M,P, C (F) Sol. in HjO g/IOOg ! j Other Solvents Misc. Ret 141 (286) insol die ace , CSj 645 Methyl Benzoate 18 0 2 0 1 09 4 69 83 CGH5CQ2CH3 1181) 200 (392) -13 18 6) inSOl ale . MfOH 646 frMethylbenzyl Alcohol C6H5CH(CH3)QH 18 1 1 0 1 02 421s 96 (205) '203 (397) 21 170) 647 Methyl Bromide CH30r 4b 20 3 1 0 1 73 3.27 537 (999) 10-16 4 (401 -95 (-139) si sol. ale CS2 AIA, BDH MCA MGB 648 2-MethyM-Butene C5H1Q 18 4 0 66 2 4 <-7 (<--20) 39 (102) -134 (-209) 649 2-Methyl-2-Butene CSH10 650 3-Methyl-1-Butene CgHlO 651 N-Methylbutylarmne CH3(CH2)3NHCH3 18 3 0 67 2 4 <-7 (< 20) 18 1000 2S 4 0 67 2,42 <--7 K20) 7a 74 3.0 13oc (55) 38 (100) -123 ( 189) 1 6-7 7 20 (68) -68 (-90) insol ale _______ msol ale 91 (196) 652. Methyl Butyl Ketone CH3OC(CH2)3CH3 18 100 2 3 0 81 3.45 35oc 533 1 2-fi 126 -57 (95) (9911 (259) (-711 ale 653. Methyl Butyrate CH3COOC3H7 18 2S 3 0 90 3.53 14 (57) 102 (216) <-97 si sol K -143) ale 654 Methyl Ceilosolve H3C-0'CH2-CH20H 18 25 2S 2S .97 2 62 46 288 2,3-24 5 125 -87 <x> bz (115) (551) (257) (-125) BDH 655 Methyl Ceilosolve Acetate CH3C00CH2CH20CH3 18 25 3S 2S 1.01 4 07S 49 394 1.5-12 3 145 -70 sol (120) (740) (293) (-94) PAGE 74 CMA 045698 SUBSTANCE/FOflMULA Hg Methyl Chloride W CH3C1 Methyl Chloroform, see 1,1, 1-Tnchloroethane Waste Dis posal Procedure {See VI) TLV (ACGIH) PPM (mg/M3) N. F. P. A. Health Fire React. 4b 100 2 4 0 Ignit. Vap. FI. Pt. Temp. Flam. B.P, Sp. Dens. C C Limits C Gr. {Ain=1) (F) <F) % (eF) M.P Sol, irt C H2O Other (FI g/l00g Solvents 1 4 1 SNFPA 632 10,7-17 4 -24 -98 (1170) (-11) (-144) !>Ol ale Misc. Ref MCA, MGB 5? Methyl Chloroformate CICOOCH3 658 3-Methyl Cholanthrene C21H16 Methyl Cyamda, see Acetonitrile 4b 18 3S car 1 24 1 28 3 26s 12 504 (54) (940) 71 (160) 280 (536) @80mm 180 (356) dec ale , bz | BDH 659. Methyl Cyclohexane C0HhCH3 18 ggO (j-Methyl Cyelohexanol ` CH3C6H10OH 18 661 2-Methyl Cyclohexanone CH3C5H9CO 18 062 4-Methyl Cyclohexene C6H9CH3 18 663 3-Methyl-4*DimethylemmoazoBenzene C15H17N3 8 664 Methylene-Bi-Phenyhsocyanate OCNC6H4CH2C6H4NCO 6 Methylene Chloride, see Dichloromethane 500 7$ 100 3S 100 car 02 3 2 2 3 0 77 3,39 -4 285 1.2- 100 -126 insol ale (25) (645) (212) (-195) 0 92 343 296 (565) 165 (329) -20 (--4) si sol ale 0 92 3.86 59 (138) 165 (329) insol ale. 0 80 3.34 -- loc (30) 103 (217) -116 (-177) insol ale 1.19 194-9 (381-90 @ 5mm 37 (99) 8DH BDH BDH PAGE 75 CMA 045699 SUBSTANCE/FORMULA Methylene Chlorobromide, see Bromochloromethane Methylene Di-p-Phenylene Isocyanate, see Methylene Biphenyl Isocyanate 665 Methyl Ether CH3OCH3 Waste Dis posal Pro* cedure (See VI) TLV (ACGIH) PPM N. F. P. A, Health Fire React. 15 %4 0 Ignit vp. FI. Pt. Temp. Flam, B.P. Sp. Dens. C Dr. |Air=1) l-F) C Limits c laF) % |F) ! M.P. *C (F) Sol. m H2O g/lOOg Other Solvents Misc, Ref 66 1.56 -41 350 34-18 -24 -139 sol (-42) (662) (-11) (-218) ale, MCA 666 Methyl Ethyl Ether CH3OC2H5 15 400 2 4 1 73 2 07 -37 190 2-10,1 11 (-35) (374) (52) sol. ale. 667, Methyl Ethyl Ketone CH3COCH2CH3 IS 200 1 30 81 2 5S -7 515 (201 (960) 2-10 80 -87 (175) (-124) V sol die bz AIA BDH, NTTC. MCA 668 Methyl Ethyl Ketone Peroxide CH3CO2C2H5 22b 224 52-93 1125-200) 1 lOexp, sol (230) ale infra 669 Methyl Ethyinitrosocarbamaie C4H8N2O3 4a Car 670 Methyl Formate HCOOCH3 18 100 2 4 - 0 ,99 21NFPA -19 456 5,9-20 32 -100 V, sol ale. (-2) (853) (90) (-148) BDH 671 2-Methyl Furan c5h6o 18 2S 3 92 zss -30 (--22) 63 -89 (145) (-128) msol ale 5-Methyl-3>Heptanone, see Ethyl Amyl Ketone 672 Methyl Hydrazine CH3NHNH2 673. Methyl Iodide CH3I 16 2 4b 5 3S 9 2.28 1 6 <27 {<80) 4.89$ 87 <-80 sol (189) K-112) ale. 43 (109) -67 $1 sol. (-89) ale MCA BDH PAGE 76 CMA 045700 1 SUBSTANCE/FORMULA ^^74 Methyl Isobutyl Ketone CH3COCH2CH(CH3)2 Waste Otsposal Pro cedure (See VI) TLV (ACGIH) PPM (mg/M3) N. F. P. A. Health Fire React. 18 100 2 3 0 Ignit. Vap. FI. Pt. Temp. Flam. B.P. sp. Oens, C c Limits C Gr. (Air=1) lF) ("FI % (FI M.P. C (F) Sol. in HjO g/IOOg Other Solvents 80 3,5S 23 460 1 4-7.5 117 -85 si sol. ale,, b2 (73) (860) (243) (-121) Miie. Ref. MCA 675 Methyl Isobutyrate (CH3I2CHCQ2CH3 18 86 3.5s 13oc 482 (55) (900) 92 4198) -84 1-119) si. sol ale 676 Methyl Isocyanate CH3N=-C=0 077 Methyl Isothiocyanate CH3NCS 18 ,02 9 3S 97 1 67 44 (111) 119 (246) 36 si, sol (97) ale 2 M Ethyllactomtnle. see Acetone Cyanohydrin 073 Methyl Mercaptan CH3SH 13 10 2 4 0 ,87 1 66 <-18 0) 3 9-21.8 76 (451 -123 si sol. (-1891 ale MGB 079, Methyl Methacrylate CH2C(CH3)COOCH3 680 1-Methylnaphthalene C10H7CH3 18 100 2 3 2 94 3.6 10 421 2 M2.5 100 -50 si. sol ate (50) (790) (212) (-58) 18 2 2 0 1.03 528 (982) 240-3 -22 (464-9) (-7,6) msof ale, BDH, MCA 081 l-Methyl-2'Naphthylamme CH3C10H6NH2 682 N-Mathyl-N-Nitrosoacetarmde C3H6N202 5 6 Car Car 51 (124) org. sols/ 683 N-Methyl-N-N>trosoallylamine C4HgN20 6 Car 584 N-Methyl-N-Nitrosoanilin# CeH5NINO)CH3 G Car 1,13 255dec. (491) 15 (59) insol, ale. PAGE 77 CMA 045701 SUBSTANCE/FORMULA 685 N-Methyl-N-Nitrosobenzyla* mine C3H10N2Q Waste DiS* posal Pro cedure (See VI) TLV (ACGIM) PPM (mg/M3) N. F. P, A. Health Fire React. G car 686 1-Methyl* 1'Nitrosourea H2NCQN<NO)CH3 6 car Ignit. Vap. FI. Pt. Temp, Flam. B.P, Sp. Dens. C C Limits C Gr. |Air=1) (F) ("FI % <F> M.P. C (F> Sol. m HzO g/lOOg 1 | Other Solvents Misc. Ref 123dec (253) insol ak bz 687 N'Methyi'N'Nitrosovmyla' mine C3H5N2Q 688 Methyl Parathion (Xylene solution) c10Hi0no5ps 2-Methyl-2-Propanethiol, see t-Butyl Mercaptan 6 car. 7b 1 11 4 3 3- 46 (115) 689 Methyl-n* Propyl Ketone CH3CO(CH2)2CH3 690, 1-Methylpyrrole CH3C4H4N 691 Methyl Salicylate HOC6H4COOCH3 692. a-Methyl Styrene C8H7CH3 693 m.'P'Methyl Styrene CH2CHC6H4CH3 IS 200 2 3 0 81 30 7 505 1 6-8 2 102 -78 si sol ) ale (46) (941) (216) (-108) BDH 6 3 91 2.8 16 115 insol i hIl ___ L___(61) (239) 18 1 0 1.18 E24S 101 454 (214) (850) 223 (433) -8.3 (18) Sl sol ale IS 100 1 2 1 92 4 08g 54 574 1 9*6 1 167-70 -23 msol ak (129) (1065) (333*8) ("9.4) 18 100 2 2 0 .89 4 08 57 494 9 170 -83 (134) (921) (338) 1-1171 NTTC Methyl Sulfate, see Dimethyl Sulfate Methyl Sulfide, see Dimethyl Sulfide PAGE 78 CMA 045702 substance/formula Methyl Sulfoxide, see Qimeihyl Sulfoxide Wane Dis posal Pro cedure (See VI) TLV (ACGIH) PPM (mg/M3) N. F. P. A. Health Fire React. Ignit. vap. FI. Pt. Tamp. Flam. B.P, $p, Dans. aC Gr. (Airsi) lF) C Limits C (F) % (F) M.P. C lF) Sol. m H?o g/IOOg Other Solvents Misc. Ref 694 N-Methyl*N-2,4,6*Tetrenitro- 6 (1.5) 2S 3S aniline C7H5N5O8 695 Methyl-p-Toluene$ulfonate CH3C6H4S03CH3 18 cos Methyl Vinyl Ether ' h?C=CH-0-CH3 g97 Mixed Acids (HNO3+H2SO4) 15 24b 242 4 1.57 1 23 6 45S 77 2 0 -51 (-60) None 187exp 130 (369) (266) msol. si. sol 27 insol bz , ale (81) 8 -122 (46) (-188) si sol Qrq Sotv None Vanes Vanes MCA 698 Molybdenum Mo 699. Molybdenum Compounds (insoluble) 27a 2S 26 (15) *S 10 2 5660 2622 (10040) (4751) i i , 700. Molybdenum Compounds (Soluble) 11 (5) 'S 701 Monochloroamine NH2CI 19 -66 (-87) sol ek Monochlorobenzene, see Chlorobenzene 702 Monomethylamme CH3NH2 703. Morpholine C4H9NO 7a 10 3 4 0 1 1NFPA -10 (14) 430 4 9-20 8 -6-3 (806) (21) -94 (-137) v sol. ale BDH, MCA. MGB 5 20 2 3 0 .99 3.00 38oc 310 (100) (590) 128 (262) -4,9 (23) CjO org, solv. PAGE 79 CMA 045703 SUBSTANCE/FORMULA Motor Fuel Antiknock Com pounds, see Tetraethyl Lead Waste Dis posal Pro cedure (See VI) TLV (ACGIH) PPM (mg/M3) N. F. P, A, Health Fire React. Muriatic Acid, see Hydrochloric Acid Mylone, see Crag 974 Ignit. Vap. FI. Pt. Temp, Flam. 8.P. Sp. Dens. *C C Limits C Gr. (Air=1) (F) (F) % (SF) M.P, C <F) Sol. in H2O g/IOOg Other Solvents Misc. Ref, 704 Naphtha (Coal Tar) 18 200 2 2 0 87 42 (107) 277 (531) 149*216 (300-421) NTTC Naphtha (Petroleum), see Petroleum Ether | 705 Naphtha, Varnish Makers and 18 500 1 Painters, 50Flash 3 0 <1 4 1 10 232 9-6 7 116-43 j (50) (450) (241-89) 7Q6 Naphtha, Varnish Makers and Painters, High Flash 18 500 1 3 0 <1 4 3 29 232 1-6 139-77 (85) (450) (282-351) 707 Naphtha. Varnish Makers and Painters, Regular 18 500 1 3 0 <1 -2 232 (28) (450) .9-6 100-60 (212*320) 708, Naphthalene CioHe 18 10 2 2 0 1 15 4.42 79 526 .9-5.9 210 80 msol, CS2 MCA (174) (979) (410) (176) ale., bz- Naphthalene Ethylene, see Acenaphthene 709 1-Naphthol CtoHyQH 710. 2-Naphtho! C10H7OH 18 18 2S 2S is 1.10 1,22 4 97S 153 (307) 288 (550) 96 (205) 295 (563) 123 (253) msol, ale , bz msol. ale., bz PAGE 80 CMA 045704 CMA 045705 SUBSTANCE/FORMULA Waste Dis posal Pro cedure (See VI) TLV (ACGIH) PPM (mg/M3) N. F. P. A. Health Fire React. 722a Nitrate'Nitrite Salt Baths (53% KNO3/40%NaNO2,7%N3N03) 11 Ignit. Vap. FI. Pt. Temp. Flam. B.P. Sp. Dens. C C Limits C Or. (Air=1) (F) (F) % (F) M.P. C (aF) Sol. in HzO g/100g Other Solvents Mise. Ref 140 (285) NSC 722b Nitrate-Nitrite Salt Baths (50%KNQ3,5Q%NaNO2> 11 220 (428) NSC Nitrating Acid, see Mixed Acids 723 Nitric Acid HNO3 724 Nitric Oxide NO 24b 2 25 >/ 20 3S 1 1 50 3S 1 34 1 04S 86 (187) -42 <-44| dec ale -153 -164 (-243) ( 263) 7 3 ale A1A BOH. NTTC MCA AIA, MGB 2,2',2"-Nitrilotriethanol, see Triethanolamine 1 725 3-Nitroacetophanone NO2C6H4COCH3 726 m-Nitroamlme NO2C6H4NH2 727. o> Nitroanilme NO2C6H4NH2 6 6 6 3st 'St 'St 1.18 3St 'st 'St 1 44 168oc 521 (335) (970) 202 (396) 81 <1781 V 501 | die 306 (583) 114 (237) si sol ale . bz MeOH 284 (5431 71 (160) Sl sol hIc , bz BOH 8Dh 728 p-Nitroamhne NO2C6H4NH2 61 3 1 44 199 (390) 336 (637) 146 (295) m$o! die , MeOH BDH,MCA 729 Nitrobenzene C6H5NO2 730 o-Nitrobiphenyl C6H5C5H4N02 61 32 0 1 20 4.24 88 482 1 8- 211 5 si. $ol ale., bz AIA (190) (900) @2QQF (412) (41) BDH, MCA 6 Car 2 0 1,44 6.9S 143 180 (290) (356) 330 (626) 35 insol, (95) ale PAGE 82 CMA 045706 substance/formula Nitrochlorobenzene. see chloromtrobenzene 731 Nitroethene CH3CH2NO2 732 2-Nitrofluorene C13H9N02 733, Nitrogen N2 734 Nitrogen Dioxide NO2 735 Nitrogen Fertilizer Solutions Nitrogen Tetroxide, see Nitrogen Dioxide 736, Nitrogen Trifluoride ' NF3 737 Nitrogen Trioxide NO3 738 Nitromethane CH3NO2 739 a-Nitronaphthaiene ' C10H7NO2 740, m-Nitrophenol NO2C6H4OH Waste Difr posal Pro cedure (See VI) TLV (ACGIH) PPM Img/M3) N, F. P. A, Health Fire React. Ignit. Vap. FI. Pt. Temp. Flam. B.P, sp. Dens. C C Limits C Or. (Air=:1) (F) (FI % (F) 1 M.P. C (F) Sol. in HjO 9/100g Other Solvents j 1 j Misc. Ref 4a 100 1 3 6 Car 26 -&WT 5 26 0s 3s 0 3 1 05 2,58 28 415 3 4- 114 -90 $01. ale. (82) (779) (237) (-130) AIA, BDH 160 (320) insol. hot bz 1,25 -196 -210 2 3 j si sol ale MCA (-321) (-346) 1 1.49 1.59S ! 1__________ 1__________ :__________ 20 i 11 (66) ! (12) ! .. dec 1 chl.,CS2 1 - : <-73 ' l-ioo) At A, MCA, MGB. NASA NTTC 12a 10 3s 3s 1.59 -129 -209 (--200) (-344) si. $Ol 26 5 3S 1.45 35 -102 (38) (-152) eth MG8 4a 100 1 3 4 1.14 211S 35 418 7.3- 101 -28 sol. ale. (95) (785) (214) (-18) AIA 6 1 1 0 1.14 5.96s 164 (327) 304 (579) 60 (140) insol ale , CS2 6 3S 1.28 194 (381) @70mm 97 (207) $1. Sol. ale BDH PAGE 83 CMA 045707 SUBSTANCE/FORMULA 741 o-Nitropheno< NQ2C6H4OH 742 p-Nitrophenol NO2C6H4OH 743 1 Nitropropane CH3CH2CH2NO2 744 2 Nitropropane CH3(N02lCHCH3 745 4'Nitroqutnoline-N-Oxide NO2C9H6NO 746 N-Nitrosodiethylamine C4H10N20 747 N-Nitrosodimetbylamme C2HQN2O 748 N-Nitroso-N'Methylamline C6H5N(NO)CH3 749 4-Nitrosomorphohne C4H9N2O3 750 1-Nitrosopiperazme C4H9N2O 751 N-Nitrosopipendme C5H10N2O 752 Nitrosyl Chloride NOCI Waste | Dis- TLV posal i(ACGIH) Pro PPM cedure (mg/M3) (See VI) N, F, P. A, Health Fire React. 6 3S Sp, Gr. 1 48 Vap. Dens. (Air=1) FI. Pt. C (F) Ignit. Temp. *C (F) Flam. Limits % B.P. C (F) 215 (419) M,P, C <F) Sol. in H2O g/IOOfl Other Solvents 45 (113) si. sol. ale 6 3S 1 48 279 (534) 113 (235) si. sol. ale 4a 25 1 2 3 99 3.06 49oc 421 2 6-- 131 -108 si. sol. aic (120) (789) (268) (-162) 4a 25 1 2 3 j 99 3.06 39oc 428 2.6- 120 -93 si sol 1103) (802) (248) (-135) 6 153 (307) 7a Misc. Ref BDH SDH 7a car 6 6 1 01 1 13 152 (306) sol 255dec (491) 15 (59) insot ale. ale. 6 6 12a 3S 1.06 3.0 2.3s 217 1423) -5.8 (21) -64 (-83) sol dec. MGB PAGE 84 CMA 045708 CMA 045709 SUBSTANCE/FORMULA 765. Oil, Cocoanut 766a Oil, Fuel? 1 766b Oil, Fuel ?2 766c Oil, Fuel -4 766d Oil, Fuel -5 766e, Oil, Fuel "6 767. Oil, Lubricating 768 Oil, Mineral Oil Mist 769. Oil, Olive 770 Oil, Peanut 771 Oil. Soybean Oil of Vitroil, see Sulfuric Acid PAGE 86 Waste Dis TLV posal (ACGIH) Pro PPM cedure (mg/M3) (See VI) N. F P. A. Health Fire React. Ignit. Vap. FI, Pt. Temp, Flam. B.P. Sp, Dens. C 6C Limits C Or, (Air=1) (F> pp) % (F) M P, C <F) Sol. in H2O g/IOOg Othei j Solvents Misc. Ret 18 0 1 0 9 216 (420) 23 (72) i 18 0 2 0 <i 3Soc 229 7-5 <-46 [ NTTC (100) (444) (<-50) ____________ l________ 18 0 2 0 <i 38oc 257 (100) (494) <-46 (<- 50) 1 NTTC 1 ; 18 0 2 0 <i 54oc 263 (130) (505) 18 0 2 0 <i 54oc (130) i <-46 i j K-50) j ! <-46 j (<-50> (` NTTC 1 _____________1______________ NTTC 18 0 2 0 <1 71oc 407 (160) (765) <-46 1 (<-501 ! NTTC 18 0 1 0 >149oc 260-371 (>300) (500-700]( 360 <-46 (680) (< 50) . NTTC 18 (5) 0 10 .81 193oc (380) 360 (680) 18 0 1 0 .9 225 343 (437) (650) 18 0 1 0 .9 282 445 (540) (833) 18 0 10 9 282 445 (540) (833) 6 (21) ___ ____ - ^ i 3i (37) ^.................. __ s 22 (72) CMA 045710 CMA 045711 SUBSTANCE/FORMULA 781 Paint 782 Paraffin 783 Paraformaldehyde (HCHQ) x 784 Paraldehyde (CH3CHCM3 785 Parathion C10H14NO5PS 786 Pentaborane b5h9 787 Pentachloroethane CHCl2CC(3 788 Pentachloronaphthalene C10H3CI5 789. Pentachlorophenol c6ci5oh 790 3JpPentane CH3(CH2)3CH3 791 iso-Pentane (CH3)2CHCH2CH3 792 1. 5-PentanediOl CsHiq(OH)2 Waste Dis posal Pro cedure {See VI) TLV (ACGIH) PPM (mg/M3) N. F. P. A, Health Fire React, 26 3S 3s Igmt. Vap. FI. Pt. Temp. Flam. B.P, Sp. Dens. C C Limits C Gr. (Air=1) (F) (F) % (F) M.P. c <F) HjO g/IQQg Other Solvents j Mi$c. R*t, <27 80) -36 (-32) NTTC 18 S TS 199 (390) 245 (4731 >370 42-60 0698) (108-40) 2 5 2St 2St =St 70 (158) 300 (572) 120-170 (248-338) 1 2 3 1 j .99 4 55 36oc 238 1 3- 128 12 v, so) j aJc, 496) (460) (262) (54) BDH,MCA BDH 7b U) 4 1 0 1 26 375 61 insol. ale , ace ! (707) (43) 17 ,005 3 4 3 .66 2 2 30 (86) 4b 3S 2S 1 67 7.0S .4- 58 -47 dec. (136) (-53) 162 (324) -29 1-20) mSOl ale. AIA, MCA, NASA' NSC BDH 4b ( 5) 3S 4b (.5) 3S 18 1000 4 18 1000 4 18 1.98 310 (590) 190 (374) sl. sol ale 0 63 2.48 -49 309 1 4-8 36 -130 V. sol. ale (-56) (588) (97) (-202) 0 62 2.48 -51 420 1 4-7.6 28 -161 msol ale (-60) (788) (82) (-258) 0 99 3 59S 129oc (264) 260 (500) -16 (3 2) sot. ale. AIA. BDH BDH BDH PAGE 88 i CMA 045712 SUBSTANCE/FORMULA 7Q3 2 4-Pentenedione ' CH3C(0)CH2C(0)CH3 n-peptanol. see n-Amyl Alcohol 704 2'PerttanoJ C5HiiOH 2-Pentanne, see Methyl n-Propyl Ketone 3-Pentanone, see Diethyl Ketone Pentene, see Amylene Waste Dis posal Pro cedure (See VI) TLV (ACGIH) PPM (mq/NI3) N, F, P, A Health Fire React. 18 2 2 0 Ignit. Vap, F|. Pt. Temp, Flam. B.P. Sp. Dens. C c Uimits C Gr. (Air=1) (F) (F> % (F) M.P. C (F) Sol. in HjO g/IOOg Other Solvents 98 345 41oc 1106) 136*40 -23 (277*84) (-9.4) v. sol. ale Misc, R#t. SDH 18 100 tst 2St Ost .81 39 (1031 347 (6571 1,2-9.0 119 (246) , v, sol. etc. n-Pentyl Acetate, see n-Amyl Acetate Mc-Pentyl Acetate, see sec-Amyl Acetate Pentyl Alcohol, see n-Amyl Alcohol Pentyl Amine, see n-Amylamne iso-Pentyl Nitrite, see Amyl Nitrite 795, Peracetic Acid (60% Acetic Acid Solution) CH3COOOH 12a 23 4 1 23 41 1 lOexp. (105) (230) 105 (221) -30 (-22) v. sol. aic. NFPA CMA 045713 SUBSTANCE/FORMULA 796 Perchloric Acid Solution HCIO4-2H20 seePerchloroethylene, Tetrachloroethylene Waste Dis posal Pro cedure (See VI) TLV (ACGIH) PPM (mg/M3) N. F. P, A. Health Fire React, 12a 3 0 3 Ignit. Vap. PL Pt. Temp. Flam. B.P. Sp, Dens. eC C Limits C Gr. (Air=1) (F) (F) % lF) 1.70 203 1397) ! M.P, Sol. in , C H2O Other (F) g/lOOg Solvents Misc. Ref ________________ (0)-18 v sol ale, MCAAlA, BDH NbC | 797 Perchloromethyl Mercaptan CISCCI3 798, Parchloryl Fluoride CIO3F 13 21 ,1 3 799 Petroleum Ethers 18 500 3S 1 70 6.4S 149 (300) 2S 2S 3s 1 1,43 I -47 1 -146 (-53) j (--231) <-73 :1 4 0 6 2.50 -57 288 1-6 30-60 1 (-70) (550) 186-140) 1 K-1011 : MCA BDH 800, Phenanthrene {CsH4CH)2 18 's 1 18 6.14S 340 ! 101 (644) (214) insol ale , CS3 801, 2-Phenanthreneacetamide C16H13NO 20 car 16 13802, 3-Phenanthreneacetamide c h no 20 car, 1 ( 803. Phenol C6H5OH 18 6 3 2 0 1 5-1.07 3.24 79 715 181 40 sol ale , CS2 BDH, (175) (1319) (358) (104) NTTC, MCA 804, Phenyl Acetate CH3CO2C6H5 1 018 2 1.09 4 7 80 (176) 196 si sol ale. (385) Phenyl Acetonitrile, see Benzyl Cyanide 805. l-Phenylazo-2-Naphthol Cl6Hl2N2Q 8 car. 102-4 (216-19) PAGE 90 CMA 045714 SUBSTANCE/FORMULA phenylcyelohexane, see Cyclohexylbenzene 06r p-Phenylenediamme 2 6 4 2H NlC H )NH 7oq phenylethanolamme 6 5 2C H NHCH CH2OH 8on Phenyl Ether 6 5 6 5C H OC H qqq Phenyl Ether Biphenyl Mixture 1 2 3Phenyl Glycidyl Ether, see , - Epoxy- -Phenoxy propane 810 Phenylhydraaine 6 2C HsNHNH 311 Phsnyl Isocyanate 6 5C H NCO 012 Phenyl'B'Naphthylamine 7 6h5Cioh ^hc 013 o-Phenyl Phenol 6 5 6 4C H C H OH 14B Pho'nB ^ 3 3 0CH (CH )C=CHCI ICH- 3 3C(CH >CH 015 iso-Phorone C9H14O Waste Dis posal Pro cedure (See VI) TLV IACGIH) PPM <mg/MJ> N. F. P. A, Health Fire React. Ignite Vap. FL Pt. Temp, Flam. B.P. 5p. Dans. C C Limits C 1Gr. (Air= ) (F) (F) % (F) M.P. 6C (F) 2Sol, <n HO g/IOOg i Other Solvents Misc. Ret, 5 1(. ) 2S 52 15 1 15 1 (311562) 0 1 09 (315025) 1 09 5.86s (9260o5e) (1614965) 1 06 (215254)0C (1611300) . (526173) (218404) sol ale (528455) (9355) 4,620 ale (245986) (8271) i insol j ale , bz, (425974) j -- 16 5 3 2 0 1.09 3?S (18992) (314745) 24(436d9ec) , (2608) sol. ale , bz BDH 18 11 (316259) (--3202) dec, dec., ale. 5 1,20 (470502) (212086) *nsol hot ale, 18 2S 1 0 1 21 124 (255) (258467) (15375) insoi ale , ace, bz. 18 25 2 2 0 .88 4.8 (18855) (319877) 8282( ) sl. sol ale. 18 25 2 1 0 .93 4.77S (926005c) (486624) 8-3.8 (241159) (-186) si. sol SDH PAGE 91 CMA 045715 SUBSTANCE/FORMULA 816. Phoidrin C7H136P Waste Dis posal Pro cedure (See VI) TLV (ACGIH) PPM (mg/M3) N. F. P. A. Health Fire React. 7b (.1) 3S igmt. Vap. FI. Pt. Temp. Flam. B.P. Sp. Dens. C C Limits C Gr. (Air=2l) (F) (F) % (F) M.P. C (F) Sol. m H-zQ g/lOOg Other Solvents 1.23 79oc (175) 107 (225) @1 mm Misc, Ref S17 Phosphine ph3 7b ,3 3S 3s 79 1 15MGH 40-60 >1 -87 -133 (-125) (-20?) si. sol. 818 Phosgene C0CI2 27] 1 3S 1 39 3S 8 -128 (46) (-198) dec. dec . ale MCA MCB, MGB 819 Phosgene Solutions in Benzene 18 1 3S <22 72) BDH 820 Phosphoric Acid H3PQ4 821 Phosphoric Anhydride p20S 24b (.1) 2S 24b 2S 1 69 2.38 260 (500) 42 (108) v sol. ale 300 subl (5721 dec. dec., ale BHD. NTTC BDH.MCA 822. Phosphorous (White & Yellow) P4 823. Phosphorous (Red) P4 824, Phosphorous Oxychloride POC13 27c { 1) 27c ( 1) 3 0 3 1 21 3S 1 1.82 4 42S 1 2,34 4.77s 1.69 5.30s (30) 86 260 (500) 280 (535) 44 (111) sl sol bz. CS2 280 590 (1094) v, sol @43atm ale. 107 (225) 1.2 (34) dec. dec., ale. BDH. MCA. NSC BDH BDH. MCA Phosphorous Pentoxide, see Phosphoric Anhydride 825 Phosphorous Pentschloride PCI5 21 (1) % 2S 4.65 162 subl (324) dec. CS2 BDH PAGE 92 CMA 045716 substance/formula Phosphor011* Pentasfulfide P7S5 g27 phosphorous Sesquisulfide P4S3 g2S Phosphorous Tribromrde ' PBr3 g29 phosphorous Trichloride PCI3 030 phthalic Anhydride ` C6H4lC0)20 831 fi-PicOhne CH3C5H4N 832 4-Picolme CH3C5H4N 833 P'cric Acid <N02)3C6H20H 834 Pimelic Acid HQ0C1CH2)5CQ0H 835 Pindone (Pival) C14H14O3 836 fl-Pinene Ciqh16 837, Piperidine CsHiqNH Waste Dis posal Pro cedure (See VI) TLV (ACGIH) PPM (mg/M3) N, F, P, A. Health Fire React. Ignit. Vap. FI. Ft. Temp, Flam. e,p. Sp. Dens. C C Limits c Gr. (Air^l) !F> lF) (F) M.P, C (F) Sol. in H2O g/IOOg Other Solvents Misc. Ref. 21 m 3 2 2.03 142 (287) 514 (957) 276 (529) insol. si. sol CS2 MCA 21 2 2.03 100 (212) 407 (765) 173 (343) m$ol. bz. CS2 21 0-5 3s 2 35 173 (343) -40 (--40) dec. dec., ale BDH 21 5 30 2 1.59 -75s 75 (167) -112 (-169) dec. bz, CS2 BOH. MCA 24a 2 2 1 0 1,53 S.10S 151 584 1,7-104 284 131 si. sol. ale (304) (1083) (544) (268) Al A. MCA 5 22 0 ,95 3.2 39oc 538 129 -70 v. sol ale BDH (102) (1000) (264) (-94) 5 22 0 96 3,21 57 (134) 143 (289) 4w (39) ale. BDH 6 ( 1) 25a 24 4 1 76 7 9s 150 300 (302) (572) 1 33 >300exp (>572) 122 sol. 272 (522) @100mm 106 (223) si. sol ale. ale. BDH 18 (.1) 109 (228) 18 13 0 .86 4.7 33 I9D 156 (313) -55 (--67) si. sol. ale. 6 23 3 .86 3.0 16 (61) 106 (223) -7 00 (19) ale , bz. PAGE 93 CMA 045717 SUBSTANCE/FORMULA 838. Piperylene Waste Div posal Pro cedure (See Vl) TLV (ACGIH) PPM (mg/M3) N. F, P, A. Health Fire React, 18 Igmt. Vap. FI. Pt. Temp, Flam. B.P. Sp. Dens. C C Limits C Gr. (Air=1) (F) (F) % (F) 1 M.P, C (F) Sol. in H2O g/IOOg Other Solvents Misc, Ref ] 68 42 (108) Rival, sea Rind one 339 Platinum Pt 840. Polytetrafluoroethylene (F2C'CF2)n 841 Polyvinyl Acetate Emulsion 27a ( 0021 4b 18 is 21.5 1.5 842 Potassium K 843 Potassium Acetate CH3COOK 844 Potassium Borohydnde K8H4 845. Potassium Carbonate K2CO3 846. Potassium Chlorate KCIO3 847. Potassium Cyanide KCN 848 Potassium Dichromate K2Cr207 3 11 17 11 12a 14 5 12a 31 'S 2S 2 86 1,57 1 18 2 43 0 2 2 32 2 0 0 1.52 3S 2S 2 68 3827 1774 (6920) (3225) msol -76 -143 (-105) (-225) -36 (-32) msol j i ! NTTC 774 (1425) 64 (147) dec ; dec , hIc BHD 292 25320l ale , MeOH (558) i _________ 1------------------- 5O0dec 1932) 1920 si sol . ale. BDH dec. 891 1122 (1636) 4QOdec. 368 (752) (694) 7.120 ale AIA.BDH 635 (1175) 50 si. sol , ale BDH <500dec 398 (<3321 (748) 4.9 PAGE 94 CMA 045718 SUSSTANCE/FORMULA Et^9 Potassium Ferrocyamde W K4Fe(CN>6 3H20 850 Potassium Fluoride KF qc{ Potassium Hydrogen Piflyoride KHFj Potassium Hydroxide, see Caustic Potash 852 Potassium Nitrate KNO3 853, Potassmm Perchlorate KCIO4 554, Potassium Permanganate KMn04 855, Potassium Persulfate K2S2O8 356 Potassium Peroxide <202 g57 Potassium Sulfide K2S 858, Praseodymium Pr 859 Propane CH3CH2CH3 Waste Dis posal Pro cedure (See VI) TLV (ACGIH) PPM (mg/M3) N. F. P. A. Health Fire React. 11 11 3s 11 Igmt. Vp. FI. Pt. Temp. Flam. 0.P. Sp. Dens. 6C c Limits c Gr. (Airsll 1F) (F) % |F) M.P Sol in C H2O Other i (6F) g/IOOg Solvents ! Misc. Ret, 1 1 85 2 48 . dec, 70 27,812 ace (158) 1505 380 (2741) (1616) v, sol j l 2 37 225dec (437) ! 4121 | i i 6DH 11 1 12a 1 12a 0 12a 1 22a 3 23 2 27k 18 1000 1 0 2 2 11 <AOOdec ! 334 l<752) J (6331 13 J 0 2 2,52 610 (1130) 75 si sol , ale 0 1 2.70 <240dec 464) 6.42 dec , ale, sol., MeOH 0 1 2,48 <1 OOdec 212) 1 750 02 1 0 1 81 dec. 490 (914) dust explosive 840 (1544) sol ale 2S 6.64 3127 935 456611 (1715) dec 4 0 ,58 1.56 -249 468 2.2-9.5 -45 -187 sol ale , bz. NTTC (-1561 (874) (-49) (-305) CMA 0457X9 I SUBSTANCE/FOHMULA 860. 1, 2 - Propanediamine CH3CH(NH2)CH2NH2 861 1,2- Propanediol CH3CHOHCH2OH Waste Div posal Pro cedure (See VI) TLV (ACGIH) PPM (mg/M3) 7a N, F. P. A, Health Fire React. -- 23 0 18 0 1 0 Ignit Vap. FI. Pt. Temp. Flam. B.P. Sp. Dens. C C Limits C Cr. <Air=1> ("FI (F) % PF) M.P. C (F) Sol. in HjO g/100g Other Solvents 86 2,56 24oc (75) 117 (243) -37 (-35) V. sol chi. 1 04 2 62s 99 (210) 415 2 6-12 5 189 (780) (372) w ale n-Propanol, see n-Propyl Aicohol 862 Propargyl Alcohol HCSCCHjOH 18 3S 2S j .96 1.93s 36 (97) 115 (239) -17 (1 4) sol ale. 863 Propargyl Bromide HC^CCHjBr 4b 3S 3S 1.56 6.87S 18 (65) 90 (194) -61 (-78) Propene, see Propylene 364 iso-Propenyl Acetate CH3COOCICH3)CH2 ^-Propiolactone, see Hydracrylic Acid-/3-Lactone 18 23 ,91 3.45 16 (60) 93 -93 (199) (-135) 866. Propionaldehyda C2H5CHO 866 Propionic Acid CH3CH2COOH 867 Propiomtrile CH3CH2CN 868. Propionyl Chloride CH3CH2COCI 2 24a 14 la 2 3 1 .81 1.8 -9-7oc 207 3.7-16 1 48 -81 sol ale nfpa (15-19) (405) (120) (-114) 2 2 0 99 2.56 54 513 (130) (955) 141 (286) -22 (-8) 00 ale. 3S 2S .77 1.9S 97 -99 (207) 1-134) v. sol. ale. 3 3 1 1 06 3-2 12 (54) 80 -94 (176) (-137) dec ale. Misc. Ref NTTC BDH BHD SDH PAGE 96 CMA 045720 SUBSTANCE/FORMULA 9 ,,ea iw-Propyl Acetate 8 CH3COOCH(CH3)2 s70 n-Propyl Acetate 8 CH3COOCH2CH2CH3 fl71 n-Propv1 Alcohol ' CH3CH2CH20H 072 iso-Propyl Alcohol CH3CHOHCH3 073 Propylamine CH3CH2CH2NH2 074, iso'Propylamine (CH3)2CHNH2 875 Propyl Benzene C3H7C6H5 i$o-Propyl Benzene, see Cumene g76. iso-Propyt Benzoate C6H5COOCH(CH3)2 877, Propyl Bromide CH3CH2CH2Br 878 Propyl Chloride CH3CH2CH2CI n-Propyl Cyanide, see Butyrorntrile Waste Dis posal Pro cedure (See VI) TLV (ACGIH) PPM N. F. P. A. Health Fire React. 18 250 1 30 18 200 30 18 200 30 18 400 30 7a 5 3 3 0 7a 5 3 4 0 18 3 0 IgniL Vap. FI. Pt. Temp. Flam. B.P. Sp. Dens. C C Limits C Gr. |Air=1) (F) (F) % (F) M.P. C (F) Sol. in HjO g/IOOg Other Solvents .87 3.52 4 460 1.8-7.8 93 -73 sol. (40) (860) (199) (-99) ale. .89 3.5S 14 450 2-8 (58) (842) 102 -95 (216) (-139) si. sol. ale. 78 2.07 25 371 2.5-13.5 97 -127 v $Oi ale., b2. (77) (700) (207) (-197) .79 2.07 12 399 2.3-12 7 82 -89 06 (53) (750) (180) (-128) ale. ,72 20 -37 318 2.0-10.4 49 -83 sol. ale (-35) (604) (120) (-116) .69 2.03 -37oc 402 2.3-10.4 32 -101 QO (-35) (756) (90) (-150) ale .86 4 14 30 (86) 159 -100 (318) (-148) insol. ale , bz. Misc. Ret. BDH BDH BDH BDH. MCA BDH BDH, NTTC, MCA 18 11 1.01 5.67S 99 (210) 218 (424) -26 (-15) into!. ale 4b %% 1.35 71 (-110 (160) (-166) si. sol. ale. BDH 4b 2 3 0 .89 2.71 -18 2.6-10.5 47 -123 si. sol. ale. BDH (0) (117) (-189) CMA 045721 SUBSTANCE/FORMULA 879 Propylene c3Hfi 880. Propylene Carbonate C3H6CO3 Waste Dis* poial Pro* cedure (See VI) TLV (ACGIH) PPM (mg/M3) N. F. P. A. Health Fire React. 18 4000 1 4 1 18 1 1 0 Propylene Dichloride, see 1,2-Dichloropropane 881 Propylene Disulfate 4b car C3H13S2O8 Propylene Glycol, see 1, 2-Propanediol 882 Propylene (mine C3H6NH 7a 2 2S 2S Propylene Oxide, see 1, 2-EpoxyPropane 883. iso-Propyl Ether [(CH3)2CH!20 884 m-Propyl Formate C3H7OOCH 15 500 18 23 2 *3 1 888 iso-propyl formate <CH3)2CHOOCH 18 2 30 886. iso-propyl glycidyl ether 15 50 3S H3C0CH2CH2-0-HC(CH3i2 887. propyl nitrate CH3CH2CH2NO3 4a 25 2 3 3 Ignit. Vap. FI. Pt. Temp, Flam. B.P. Sp. Dans. 6C C Limits C Gr. (Air=1) (F> (F) % (F) M.P, C (F) Sol. in HjO g/IOOg Othw Solvents .51 1 4NFPA -108 497 (-162) (927) 2-11.1 -48 (-54) -185 (-301) v sol HtL 1,21 135oc (275) 242 (468) -49 (-56) V. sol b2 Misc. Ret MCA 2.0S 1 63 1145) -- 1 72 .91 .97 92 1.06 3.5 -28 443 1.4-21 69 -86 si. sol ale. (-18) (830) (155) (-123) 3.03 -3 465 (27) (851) 81 -93 (178) (-135) si sol. ale. 3.0 -6 485 (22) (905) 68 (154) s(. sol. ale. 4,15s 137 (279) 20 177 2-100 111 (68) (350) (232) si. sol. ale MCA CMA 045722 substance/formula A no-propyl loluPnii B see cymene aS8, PrOpyne hc=cch3 aQQ Propyne-allene mixture ` (MAPP) 090, pyrethrum 891. Pyridine C5H5N 892 Pyrogallic acid C6H3(OH)3 893, Pyrrolidine C4H9N 094 Pyruvic acid CH3COCOOH Quicklime, see Calcium oxide 895. Quinaldme CH3C6H3NCHCHCH 896. Quinoline C6H4NCHCHCH 897 8-qumohnol HOC6H3NCHCHCH we Dis posal Pro cedure (See VI) TtV (ACGIH) PPM (mg/M3) N. F. P. A. Health Fire React. Ignit. Vap, FI. Ft. Tamp. Flam. B.P. Sp. Deni. C C Limits C Gr. (Air=1) lF) (F| % lF) 1 M.P. C <F| Sol. in H2O g/IOOg Other Solvents Misc, Ret. IS 1000 2 4 18 1000 26 (5) 55 24a 7a 24a 23 3S 23 2 1,78 1.38 1.7 -23 -105 (-9) ('157) die. forms expl. with Cu & Ag 'i 1| 11 | j1 0 .99 2.7 20 482 1.8-12 4 115 -42 W ! ale | BDH, 168) (900) (240) (-43) j | NSC 1.45 1 85 2.45 3 (37) 309 (588) ----- -----1 89 (192) 133 (271) -63 (-81) v. sol. (30 ale ale | i 1,23 165 (329) 14 00 (57) ale. 8DH 5 1.51 247 -2 si. sol. ale. (477) (28) 5 2 1 0 1.09 4 45 480 238 -20 sol. ale , CS2 BDH (896) (460) (-4) 5 267 -76 m$ol. ale. (513) (-105) PAGE 99 CMA 045723 SUBSTANCE/FORMULA 898 Quinone OC6H4O Waste Dis posal Procedure (See VI) TLV (ACGIH! PPM (mg/M3) N, F. P. A, Health Fire React. 18 1 3S Ignit. Vap. FI. Pt. Temp. Flam. B.P. Sp. Dens. C C Limits C Gr. (Air=1) <F) ("Ft % lF) M.P. C ("Ft Sol. in H2O g/IOOg Other Solvents 1 32 293 (560) 116subl (241) si. SOI. ale. Misc. Ref, Rad fuming nitric acid, see nitric acid, anhydrous 899 Refrigerant gases 26 900 Resins 26 901 Resorcinol CeM4(OH)2 902 Rhodium Rh 903. Ronnel C8H8C!303PS 904, Rotenone C23H22O6 18 27k (.1) 7b (15) 18 (5) 2S 2S <38 (<1001 ] 1 1,27 12.4 1.27 37% 127 (261) 608 1 4(1126) @392F 281 (538) 110 (230) sol. ale ' 3707 1985 (6705) (3605) msol, 41 (106) 210-20 (410-28) 163 (325) org solv insol. org, solv NTTC -i 905. Rubber (tubing, etc.) 26 906 Rubidium Rb 907, Ruthenium Ru 908. Salicylaldehyde HQC6H4CHO 27k 2S 1.53 Ignites 700 in air (1292) 38 (102) dec. dec. ale. 27k 2S 12.30 4150 2450 (7502) (4442) msol 2 2 0 1.15 78 197 -10 5I. sol ale. (172) (387) (14) CMA 045724 CMA 045725 substance/formula 920 Silica (quartz) $iC>2 921 Silica (amorphous) SiC>2 922. Silica gel H2S1O3 Silicic acid, see silica gel 923 Silicon tetrachloride S1CI4 924 Silicon tetrafluoride SiF4 925. Silver Ag 926 Silver Nitrate AgNC>3 927. Sodium Na 928. Sodium acetate NeOOCCH3 929 Sodium amide NaNH2 930. Sodium azide NaN3 PAGE 102 Waste Oiv posal Pro cedure (See VI) TLV (ACGIH) PPM (mg/M3) N, F. P. A. Health Fire React. 26 250 2S (%Si02+5) 26 706/cc =s 26 Is Vap. FI. Pt. Sp. Dens. C Gr. (Air=l) (F) 2.64 Ignit. Temp. C (F) Flam, Limits % B.P. C (F) 2230 (4046) MP C (F) Sol. in ! HjO ] g/IOOg | Other Solvents ~1 1610 (2930) msol [ ; Misc. Ref. 2.19 2230 (4046) 150dec (302) msol j 1 msol | ; --%a /i- 21 3S 3S 27a ( 01) Is 27k (.01) 1 ' 0 1,48 9.7 remy 4.67 10.5 1 4 35 3 31 2 .97 11 0s 1.53 19 3S 2S 8 3$ 2,85 58 (136) | -70 1 dec, 1 dec ale j BDH (-94) j j -65 -90 dec. ale, ! MGB (-85) (-130) >1810mrTt@1318mrni ' 2212 (4014) 961 (1762) msol. 444dec. (831) 212 (414) >115 (239) spontaneous ignition in dry air 892 (1638) 607 (1125) 98 (208) 324 (615) 1220 dec 119 eth, dec ale si, sol. ale BDH, MCA, NSC 400 (752) 210 (410) dec. BDH dac. 4217 si. sol. ale. BDH CMA 045726 SUBSTANCE/FOHMULA 931 Sodium benzoate NaOOCCgHs 932 Sodium bicarbonate N3HC03 933 Sodium bisulfate ` NaHS04 934 Sodium bisulfite NaHS03 935, Sodium borohydride Na6H4 936, Sodium carbonate Na2C03 937 Sodium chlorate NaCl03 933, Sodium chloride NaCI 939, Sodium chlorite NaCI02 940. Sodium chromate Na2Cr04 94), Sodium cyanide NaCN 942 Sodium dichromate Na2Ct207 Waste Dis posal Pro cedure (See VI) TLV (ACGIH) PPM (mg/M3) N. F. P, A. Health Fire React, 11 S Ignit. Vap, FI. Ft. Temp. Flam. B.P. Sp. Dens. 6C C Limits C Gr. <Air=1) (F) (F) % l'F| M.P. C (F) Soi. in HjO g/IOOg Other Solvents 6620 si. sol, afc Mtsc. Ret. 11 12a 2S 12b 2.16 2 44 1 48 270 (518) 6.9 si, sol. ale >3l5dec, 2926 (599) si sol ale dec v, sol si sol ale. 17 2S 2S 11 2S 12a 1 0 2 11 s 12a 1 1 2 12a 3S 14 (5) 2 0 0 12a 3S 1.07 2.53 2.49 2 17 none none >400 l>752) 5525 ale., MeOH A!A, BDH dec. 851 (1564) 7 1 $> sol. ale. 300dec, 248 (572) (478) 79 ale BDH,MCA 1413 801 (2575) (1474) 36 $1. sol. ale. 175dec. (347) 39'7 792 (1458) sol, MCA 1496 560 (2725) (1040) 48' Si. sol. ale. BDH, MCA 120 (248) sol. MCA PAGE 103 CMA 045727 SUBSTANCE/FORMULA 943. Sodium ethoxide NaOC2H5-2C2H50H 944. Sodium fluoride MaF 945 Sodium fluoroacetate CH2FCOONa Waste Dis posal Pro cedure (See vi) TLV (ACGIH! PPM (mg/M3) N, F. P A. Health Fire React. 3 3S 3S Igmt. Vap. FI. Pt. Temp, Flam. B.P. Sp. Dens. C C Limits 4C Gr. (Airs=1) (aF) iF) % ("FI dec. M.P, C (F) Sol. in H2O g/IOOg 200 (392) dec Other ' Solvents | 1 ale. j Misc, Ret. BDH 11 3s 4b (05) 3s | 2 56 1700 (3092) 9S0-97 < 17961827) 4.218 200 (392) 11125 sl. sol. ale. 946. Sodium formate NdOOCH 947 Sodium hydride NaH 948 Sodium hydrogen difluoride NaF-HF 11 17 U 3S ) 3S Is 1 2S 1 ' '192 : -92 I- 2.08 'j' 253 (487) 9720 $1 sol ale. Explodes with w ater j . j 800dec. dec. 1 j (1472) NSC ! BDH Sodium hydroxide, see caustic soda 949 Sodium hypochlorite NaOCI 950. Sodium iodide Nel 12a 11 1 j =S ! 3.67 dec. BDH 1304 (2379) 651 (1204) 18425 ale., ace. 951. Sodium methoxide NaOCH3-2CH3OH 3 dec. dec. MeOH BDH 952. Sodium nitrate NaNQ3 11 1 0 2 2.26 380dec. (716) 307 (585) 9225 ale.. MeOH 953. Sodium nitrite NaNQ2 12b 3S =S 2.17 538exp. (1000) 320dec. 271 (608) (520) 8119 si. sol. ale. PAGE 104 CMA 045728 SUBSTANCE/FORMULA 54 Sodium pentachlorophenate C6Cl50Na Waste Dtv posal Pro* cedure (See VI) TLV (acgih; PPM (mg/M3) N. F P. A. Health Fire React. 4b ( 5) Ignit. Vap. FI. Pt. Temp. Flam. B.P. Sp. Dens. C C Limits C Gr. <Air=1) (F) <F) % (F) M.P, C (F) Sol. in H2O g/IOOg Other Solvents 955 Sodium perchlorate NaCl04 56, Sodium peroxide Na202 2.02 482dec. (900) 46Qdec, (860) 957 Sodium o-phosphate N32HPQ4-7H20 $58 Sodium-potassium alloys NaK 1.68 48 10440 (118) Ignite m air g59, Sodium propionate NaQQCC2H5 96O Sodium silicate (water glass) Na20.xSi02 Sodium sulfide Na2S g62. Sodium sulfite N32S03 23 12h 2 ! 1 jo 2S NTTC 1180 121561 1510 sl. sol. ale. 12 963 Sodium tetraborate Na2B4C>7 964 Sodium thiocyanate NaSCN 965 Sodium thiosulfate Na2S203 11 11 12b 3S 3S 2.37 1.67 157dec. 741 (2867) (1366) 1.06 287 (549) 13921 ale., ace. 48 U18) 50 CMA 045729 SUBSTANCE/FORMULA 966- Stannic Chloride SnCl4 967. Stearic acid c17h3ScOh 968. Stibine SbH3 969. 4-stilbenamine Ci4Hi4 970. Stoddard solvent 971. Strontium Sr 972. Strontium carbonate SrCC>3 973. Strontium nitrate Sr(N03)2 974. Strontium peroxide Sr02 975, Strychnine c21h22n22 976. Styrene (CeHsCHCH2)n 977. Styrene monomer C5H5CHCH2 PAGE 106 Waste Dis posal TLV (ACGfH) Pro* PPM cedure (mg/M3) (See VI) -------------- 1 n 12) N. Health 3s F. P. Fire Is A. React. 24a 1 1 ! 0 i 27d 1 3s 2S ignit. Vap. FI, Pt. Temp. Flam. B.P. Sp. Dens. C aC Limits C Or. (Air^l) (F) (F) % (F) M,P. C (F) Sol. m H2O g/IOOg Other J Solvents 1 Misc. Ref, 2.23 714 (237) -33 (-27) sol eth. BDH .95 9.8S 196 395 (385) (743) 358-83 69 (676-721) (156) insol CS2 NTTC 5.30 -17 -88 (1.4) (-126) .40 cs2 5 car. 1 90 I (194) 18 500 2S 10 38-43 227-60 8-5 1 220-300 1 (100*10) (441-500) l(428-572lj '( 27h 2S 2S . 2.6 ' 1384 752 (2523) (1386) dec. i 1 ale. 27h 3.7 27h 1 0 1 2.99 1340 (2444) 1497 (2727) @69 atm si sol 645 570 (1193) (1058) 711 s si. sol. ale 27h 1 0 5 (.15) 3s 18 31 2 3 1 4,56 215dec. Si sol (419) aic. 1,36 909 3.6 270 (518) @5mm 268 (514) $1 sol. chi. 31 490 1.1-6.1 146 -33 (88) (914) (295) (-27) insol. ale., CS2 Al A, BDH, NTT 18 100 2 3 2 .905 1.1NFPA 31 490 1.1-6.1 145 -31 insol. ale , CS2 BDH.MTTi (88) (914) (293) (-23) MCA CMA 045730 SUBSTANCE/FORMULA Succinic Acid COOH(CH2)2COOH q^9 Su,n'c Anhydride y C4H4O3 aito Succinomtriie 9& NCCH2CH2CN qg1 Sulfamide S02<NH2)2 932 Sulfur Sg 983. Sulfur Decafluoride S2F10 gg4 Sulfur Dichloride SCI2 9g5 Sulfur Dioxide SO2 QQj?>}eKafiuaride 987 Sulfuric Acid H2SO4 gg8 Sulfur Monochfonde S2CI2 ggg, Sulfur Trioxide so3 WastB J ij- | TLV puMil jfACGlHI Pro* PPM cedure (mg/M3) (s VI) N. F. P. A, Health Fire React. Igmt. Vap. FI. Ft. Temp, Flam. B.P sp. Dens, C C Limits C Gt. (Air=1) lcF) lF) % (F) M.P. "C ("FI Sol. in H2O g/IOOg Qthei Solvents | Misc. Ret 24a 24a 14 19 26 21 025 2S 's 1,57 ` 2S 's 1 10 j 3S Is -- 98 ! 2 76 i 132 (270! ! 1 61 -! -i I.1! 2 0 1 2 07 i j 207 232 !i (405) 1450) ] r------------ j3s 2 08 ' 235dec (455) 261 (502! 266 (511) 185 (365) 120 (248) 58 (136) si sol ale MeQH | 1 msol. ale j j jv sot ale , b/ | 250dec. (482) 92 (198) n1 j 444 | 119 1 (8321 j 1246) sol ale ] insol j CS2 NTTC, MCA,NSC 29 -92 (84) (-134) 21 1 3S 2S 1.62 | 3 6s ' 59dee -78 (138) (-108) bz BDH, MCA 12b 53 0 0 1 4 23s -10 (14) -76 (-105) 230 ale AlA, MCA 21 1000 1 67 6,2S --64sub( si. sol (-83) ale. Z4b (11 3 0 21 1 2 1,84 1 69 2SS None None 338 (640) 10 w (50) dec , ale 118 (245) 234 (453) 136 (277) -80 (-112) dec bz. CS2 A[A BDH.NTTC. MCA BDH. MCA 24b 3S 2.75 45 (113) 17 dec. (63) MCA CMA 045731 ? SUBSTANCE/FORMULA 990 Sulfuryl Chloride SO2CI2 991 Sulfuryl Fluoride SOjF; 992 Systox (C2H50>2PS0C2H4SC2H5 993 Tall Oil (Liquid Rosin) 994 Tallow 995. Tannic Acid C76H526 996 Tantalum Ta 997 Tar, Liquid TEDP, see Tetraethyl Dithionopyrophosphate 998 Tellurium Te 999 Tellurium Hexafluoride TeFg TEPP, see Tetraethyl Pyrophosphate Waste Dis posal Pro cedure (See VI) TLV iacgih; PPM (mg/M3) N, F, P, A. Health Fire React. 21 % Sp. Gr. 1 67 Vap. Dens. (Air=1) FI. Ft. C lF) Ignit. Temp. C (F) Flam. Limits % B.P, C (F) 69 (156) M.P. C lF) Sol. in H7O g/100fl Other Solvents -54 (-65) dec. bi 21 5 % 3 72 -55 -137 (-67) (-215) 109 ale 7b ( 1) 3S 134 (273) 18 182 (360) 18 24a 27a (5) 0 2S 1 0 .895 'S 16.7 265 (509) 199oc. 527 (390) (980) 32 (90) 210dec. sol. (410) ale , ace 5425 2997 (9797) (5300) insol, 26 3s 2S >93 (>2001 49 (120) 27e (.1) 27# .02 2S 2S 6 26 1 18 1390 (2534) 452 (846) insol. 35 -36 dec. (95) (-33) Misc. Ret, BDH NTTC NTTC NTTC PAGE 108 0*S732 SUBST-ANCE/FOBMULA HhoO Terbium Tb Waste Div posal Pro cedure (See VU TLV (ACGlH) PPM (mg/M3) N. F, P. A. Health Fire React. 27k 2S Sp. Gr. 8 77 vap. Dens. (Airs=H FI. Pt. C (F) Igmt Temp. C (6F> Flam, Limits % B,P. C (F) M.P. C (F) So), in H2O g/IOOg Other Solvents 2800 1356 (5072) (2473) insol. Misc, Ref. 1001 m-Terphenyf ClBHl4 18 t 0 1 16 135oc (275) 365 (689) 87 (189) insol, ale,, bz, 1002 o-Terphenyl CiSH14 1003 p-Tsrpbenyl Cl8H14 18 1 IS ) 1 0 1 14 IS 1 ' | 1 Z* ! 163oc (325) - 332 (630) 57 (135) insol bz , MeOH 405 (761) 213 (415) 1004 Tetrabromoethane BrjCHCH Br2 26 1 30 1 2 97 239dec (374) -1 insol (30) ale SDH 1005 lr2,4,5*Tetragbloroben*ene C6H2CI4 4b 1 0 1.86 155 (311) 243 (469) 139 (282) insol bz , CSj 1006 1,2.2.2-TetrachlocO'1,1- 26 500 =s Difluoro Ethane F2CCI CCI3 1 64 7.03S 92 (198) 41 (106) insol ale. 1007 1,1,2,2-Tetrachloro-l ,2. Difluoro Ethane C(2FCCFCl2 26 500 1 64 7.0% 93 (199) 25 insol (77) ale 1008 1,1.2,2 Tetrachloroethane CI2HCCHCI2 4b 5 % 1.59 5.8S None 146 (295) -43 5). sol (-45) ale AlA. BDH, MCA 1009 Tetrachloroethylene CJ2C=CCJ2 1010 Tetrachioronephthalene C10H8CI4 4b 100 6 (2) 3s 2S 1 62 5.8S None 121 (250) -24 1-11) insol 182 (360) ale , bz. AlA, BDH, NTTC. MCA 1011. Tetradecane C14H30 18 !St st .76 6% 100 202 .5-- 254 6 insol ale (212) (396) (489) (43) PAGE 109 CMA 045733 SUBSTANCE/FORMULA 1012 Tetraethyidithionopyrophosphete (C2H50I4P20S2 Tetraethylenepentamine 1UIJ H2N(CH2CH2NH)3 CH2CH2NH2 1014 Tetraethyl Lead Pb(C2H5l4 1015 Tetraethyl Pyrophosphate IC2H50I4P203 1016 Tetrahydrofuren C^HgO 3,4,7,7a*Tetrahydro-4,7Methanomdene, see Dicyclopentadiene Waste Dis TLV posal (ACGIH) Pro PPM cedure (mg/M3} (See VI) N. F. P. A. Health Fire React. 7b (2) % Sp. Gr. 1.19 7a 2 1 0 ,99 4b ( 075) 3 2 3 1.66 7b I 05) % 18 200 7 3 1 1.20 1 j 89 1 Vap. Dens. (Air=1) Fl. Pt. C (F) Igmt. Temp. C (F) Flam, Limits % B.P. C (F) M.P, C <F) Sol. in HjO g/IOOg Other Solvents 138 (280) insol ale. 163oc (325) 333 (631) 8 6 93 (206) I70exp (338) -137 (-215) insol, ale , bz. 155 (311) '00 ! -- 1 * ale , ace i 2.5 -- 14 321 2-11 8 65 --65 v so) org,, sol (6) (610) (151) (-85) ! 1017 Tetrahydronaphthalene c10Hi2 18 20 97 4.55 71 384 .8-5 207 -30 msol, ale (160) (723) @302 F (405) (-22) 1018 Terralin, see Tetrahydronaphthalene N,N.I\r.N'-TetramethYl`3,3'* Oimethoxybenzdine C18H24Q2W2 N,N,N',N'-Tetramethylethy1020 lenediamine (CH3>2NCH CHN(CH3)2 1021. Tetramethyl Lead Pb(CH3)4 6 car. 6 4b ( 075) 3 2S 78 3 3 1.99 6.5 38 (100) 121 (250) 110 (230) sol -28 msol (-18) ale., bz. 1022. Tetramethyl Silane Si(CH3)4 3S .65 27 eth, (81) Misc. Ref. MCA BDH CMA 045734 SUBSTANCE/FORMULA Tetramethyl Succmonitrile W NCCICH3)2C(CH3)3CN Waste Dis posal Pro cedure (See VI) 14 TL V (ACGIH) PPM (mg/M3) 1 5| 1 N. F. P. Health Fire | 3g , i A React. 1 - | Sp. Gr. 1 30 Vap. Dens. (Air=i1) F|. Pt. C (F) Ignit. Temp. C (F) Flam. Limits % B.P. C (F) M.P Sol. m C h2o Other (F) g/IOOg Solvents igOsubl (374) 1 si sol si sol , Jl(,, M*sc. Ret. niA Tetramethylthmram Disulfide 1UZ llh.ram) iH2NCSCH3)4$2 Tetramtromethane 102 CtNQ2>4 13 4a (5) 1 2s j % %j - 13 1.64 j 70 (158) : 1---------- ,------- ------- --------------------;------------------------ - 126 ! 13 I msol ale (259) [ (55) j ! Tetryl. see N-Methyl-N-2, 4,6-Tetranitroamlme 1026 ThaUmm Tl 1027 Thallium, soluble compounds i1 !!1ii 27k ! | 1) | 3S 27k 1,1) ! 3S ^ - ; ,- j 11,9 |- _________ _________ T !; :i . | 1460 : ! (2660) ' ; 304 | (579) , msol i I - ! , : 1028 Thallous Sulfate H2SO4 1029 Thioacetemide CH3CSNH2 1030 2 2'-Thiodiethanol (CH2CH2QH)2S 1031, Thioglycolhc Acid HSCH2'COOH 1032 Thionyl Chloride SOClo 1033, Thionyl Fluoride sqf2 27k ' j 3s | ! 13 j - 2s : - :- 6 77 t -1 ![ _________ 1_________ 1_________ _________ _________ -- dec. 632 11170) 1 20 1 49 1 115 (239) v sol ! ale ! 1 1 I ! 13 13 20 21 1 1 % % 0 : 1 18 j 4 2S 160oc. (320) i1 1.35 1 64 28 u oo (82) (12) 105 (221) @11mm 17 00 (1) 76 -105 (169) (-157) dec ale ale bz. BDH BDH 21 2 93 -44 -110 dec. bz , ace, (-47) (*166) SUBSTANCE/FORMULA 1034 Thiophene C4H4S 1035. Thiourea NH2CSNH2 Thirem, see Tetramethyl Thiuram Disulfide 1036, Thorium Th 1037. Thorium Nitrate Th<N03)4 1038 Tin Sn 1039. Tin, Inorganic compounds 1040 Tin, Organic compounds 1041. Titanium Ti 1042. Titanium Dioxide (rutile) T1O2 1043. Titanium Tetrachloride T1CI4 1044 Toluene C6H5CH3 Wane Dis* TLV posal (ACGIH) Pro PPM cedure (mg/M3) (See VI) N. F. P, A. Health Fire React. 13 2S % Sp. Gr. 1.06 Vap. Dens. (Air=1) FI. Pt. C (F) Iqnit. Temp. icF) Flam. Limits % 2.9 -1 (30) B.P. (F| 84 (183) M.P. C (F) Sol. m H2O g/IOOg Other Solvents -38 (-36) org., sol. 13 'S 1.41 dec. 181 sol. ale. (358) Misc, Ref. BDH 27k 2S | - , 117 1( 1 27k 1 I0 1j ' 27a (21 11 (2) r-- 26 Ml | 0S | 1$ 1 - | I 5.75 . . . 1_ _ _ _ _ _ _ _ 1_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ variable, j oxides | toxic % ! ---------------1------------------ 1 - 4500 (8100) 1827 (3321) insol 500dec. 1 v sol. (932) ale 2260 (4100) 232 insol (450) most soluble AIA 27a (15) 26 (15) li> 5 18 200 S 30 23 4.5 4.26 700-800 (13921472) 3262 (5432) 1800 msol (3146) ~27QQ (4890) 1840 msol. (3344) AIA 1 1 73 136 (277) -30 sol. (-22) ale. 8DH. NSC 0 87 3,1 5 (40) 536 1 4-6 7 (997 111 (231) -95 (-139) msol. ale., b2, CS2 AIA BDH,NTTC MCA PAGE 112 CMA 045736  Is " J______ substance/formula Totuene-2,4-diisocyanate CH3C6H3(NCO)2 a-Toluenethiol, se Benzyl Mercaptan Waste Dis posal Procedure (See V0 TLV (ACGIH1 PPM (mg/M3) 6 02 N. F. P A. Health Fire React, I2 1 2 1 _________ 1_________ Sp. Gr. 12 Vap. Dens, (Air=1) FI. Pt. (F) Ignit. Temp, C (F) 132 (27Q)oc .9-9 5 B.P. C lF) 251 (484) M.P, C (F) Sol. in HjO g/IQQg Other Solvents Misc, Ret, 20 j AIA, MCA (68) 1 .nJK 1.o-Tolyllo-2-Nphthol 10 Cl7Hl4N20 Tolylene Diisocyanate, see Toluene-2,4-0iisocyanate o-Tolyl Phosphate, see Trttolyi Phosphate 1047 m-Toluidme CH3-C6H4-NH2 1048 o-Toluldine CH3'C6h4'nh2 1049 p*Toluidine CH3-C6H4-NH2 8 5 5 5 car, 5 32 5 32 5 32 i j ' 0i !1 .99 ; 3.9c 1 se ! 1 (187) 0 1.004 j 3.7S 85 085) I 0 1 046 3% 87 (189) 482 (900) 482 (9001 482 (900) 1 1 1 I 203 -31 (398) (-24) ! I si, sol, ; ale 200 (392) -16 (3) si. sol. ale. 200 44 (392) (111) si sol. ale BDH, MCA BDH, MCA BDH, MCA Toxaphene, see Chlorinated Camphene 1050. Tremolite CasMgsSigOj^Hj 26 '77/cc 1051 Triamylamine iC5Hn)3N 7a 25 2 1 0 .8 7.8S 102 (215) 232 (450) ale., ace Tribromomethane, see Bromoform PAGE 113 CMft. 045737 SUBSTANCE/FORMULA 1052 Tri-n-Butyl Amine (C4Hg)3N 1053. Tributylchlorotin Ci2H27SnCI 1054. Tributyl Phosphate (C4HgO)3 PO 1055. Trichloroacetic Acid C CI3COOH T richloroacetaldehyde, see Chloral 1056 Trichloroacetorutnle CCI3CN Waste Dis posal Pro cedure (See VI) TLV (ACGIH) PPM (mg/M-5) N. F, P. A. Health Fire React. 7a 5NFPA 2 2 0 Ignit. Vap. FI, Pt. Temp. Flam. B.P. Sp, Dens. C C Limits C Gr. (Air=1) (F) (F) % (F) M.P. C (F) Sol. in H2O g/IOOg Other ! Solvents Miac. Ret. .8 6.3S 86 (187) 216 (421) -70 (-94) si. sol. ale. BDH 4b 1.13 174 30 (345) (86) 7b (5) 4c 1 j 2 1j 0 ,97 9.2S 146 (295) 3S 1 63 292 <-80 (558) K--112) sol. ale., b2., "2 198 j 58 (388) ] (136) _________ ________ ^ V sol. ale. BDH 14 1 44 85 -44 (185) (-47) 1057 Trichloroacetyl Chloride concoct 1 3S 1.63 118 (244) dec. dec., ale. 1058. 1,2,4-Tnchlorobeniene CeH3Ci3 1059. 1,1,1-Tnchloroethane CH3CCI3 1060. Trichloroethylene CICHCCI2 T richlorofluoromethane, see Fluorotrichloromethane 4b 2 1 0 1.45 6,3g 99 (210) 214 (417) 17 insol. si sol., ale. (63) 26 350 2S 4b 100 3S 'S 1,34 1.46 4-6S 4.54 none 32 (90) 74 (165) -38 (-36) msol. ale. 410 12,5-90 (770) 87 (188) -88 (--126) si. sol. ale. AIA, NTTC, MCA AIA. BDH, NTTC. MCA. NSC Trichioromethanethiol, see Perchloromethyl Mercaptan CMA 045738 SUBSTANCE/FORMULA Im6l Trichloronaphthalena V ' C10HSCl3 Waste Dis posal Pro cedure (See V)> TLV (ACGIHI PPM (mg/M3) N. F. P. A, Health Fire React. 4b (5) 2S Ignit. Vap. FI, Pt. Temp. Flam. B.P. Sp. Dens. C C Limits C Gr. (Air=1) (F> (FI % (F> | M,P, C Sol. m H2O g/IOOg Other | Solvents j Misc. Ret. 133 (271) a)c.h Tnchloronitromathane, see Chloropicnn 1062- 2,4,5-Trchlorophenoxy Acetic Acid CI3C2H2OCH2COOH 4c 10 ! 157 (315) 1063 1,2,3-Triehloropropane C3H5CI3 4b 50 3 2 0 1.39 5.0 82 304 3,2-12.6 156 -15 st sol. ale. (180}oc (579) (313) (5) 1064 1^1,2'Tnchloeo-1,2,2-TrifJuoro Ethane CI2FCC Cl F2 26 Tncresyl Phosphate, see Tritolyl Phosphate 1000 Is 1,56 680 (1256) 48 (118) -36 (-33) insol. ale., bz. 1065, Tridecanol CH3(CH2)nCH20H 1066. Triethyl Aluminum <C2HSI3AI 1067. Triethyl Amine (C2H5I3N 1068. Triethanolamine (CH2OHCH2)3N 1069. Triethylene Glycol Triethy (CH20CH2CH20H)2 1070, Triethylene-Tetramme H2NCH2(CH2NHCH2l2CH2 nh2 18 3 7s 7a 18 7a .82 3S __ ______ _________ 1 25 2 3 0 ,84 .73 !st *st 'St 1,13 1 1 0 1.13 3 1 0 .98 6.9 121 (250) 274 31 msol. ale. (525) (S8) <-S3 <-53 --63) IC-63) 194 (381) -53 exp.h^O (-63) 3.48 <-7 (<-20)oc 1.2-8,0 89 (192) -115 (-175) sol. ale. 179 (355) 360 (680) 20 0O (68) ale. S.17S 177 371 .9-9.2 276 -4 Qo ale. (350) (700) (529) (25) 135 (275) 338 1640) 267 (513) 12 sol. (54) ale. AIA BOH BDH PAGE 115 CMA 045739 SUBSTANCE/FORMULA 1071 Triethyl o-Formate IC2H50)3CH 1072. Trifluoroacetic Acid cf3cooh 1073. Trifluoromethana chf3 1074. Triisobutyl Aluminum (C4H9)3AI Waste Dis posal Procedure (S#a VI? TLV IACGIH) PPM (mg/M3) N, F. P. A. Health Fire React. 18 % 2S 4c 3S -4b 2S 3 %% Ignit. Vap. FI. Pt, Temp. Flam. 8.P. Sp. Dens. "C C Limits C Gr. (Air=1) ("FI (F) % <F) .89 5.1s 30 <86) 146 (295) M.P. C (F) Sol. in H20 g/IOOg Other Solvents dec ale. 1.54 72 (162) -15 sol. (5) 1.52 -84 (-119) -163 (-261) $1. sol. ale. ,79 <0 <4 (<32) 39) 114 (237) 4 (39) Misc. Ret. BOH BDH A) A 1075. Trimathyl Amine ICH3)3N 7a 10 3 4 0 1076. 5,9,10-Tnmethyl-l,2-Benzan thracene (CH3)3C-]gH-|3 18 car 20NFPA -13- -8 (8-18) 190 (374) 2-11.6 * 4 -117 v sol ale., bz. (39) 1-179) BDH. MCA. MGB 1077. 6,9,1O-Trimethyl-1 ,2-Benzanthraeana (CH3}3CfgHf3 107$. Trimathyl Borat B(OCH3)3 18 18 car 2 3 1 92 3.6 <27 (< 80) 67 (153) -29 (-20) dec. MeOH 3,5,5`Trimethyl*2-Cyclohexenon, see iso-Phorone 1079. 2,2,4-Tnmethyl Pentane (CH3)3C CH2 CH(CH3)2 1080. 2,4,4-Trimethyl-2*Pentene (CH3)2C=CHC(CH3)3 1081 1,3,5-Trinitrobenzene C6H3(N02>3 18 18 6 2S 3 3 24 0 .69 3.9 0 .72 3.9 4 1.69 -12 (10) 418 (784) 1 1-6.0 99 (210) -107 insol. (-161) si. sot., ale. 2 112 -107 insol. (35) (234) (-161) exp. 121 si. sol. ace., bz. (250) BDH CMA 045740 I SUBSTANCE/FORMULA Trinitropheno), see Picric Acid 1082- 2,4,6-Tnmtrotoluane CH3C6H2(N02i3 1083. 1,3,5-Trioxf OCH2OCH2OCH2 1084 Triphenyl Phosphate (CgHsOhPO 1085- Triphenyl Phosphine IC6H5)3P 1086 Tripropylamme (C3H7>3 N 1087- Trisodium Phosphate Na3P04't2H20 Triton, see Trinitrotoluene 1088* Tritolyl Phosphate (CH3C6H4)3P04 1089- Turpentine ClOH16 1090. Unsymmetrieal Dimethyl Hydrazine (CH3)2NNH2 1091 Urenium U Waste Dis posal Procadura (See VI) TLV (ACGIH1 PPM (mg/M3) N. F. P. A, Health Fire React. Ignit. Vap, FI. Pt. Temp. Flam. B.P. Sp, Dans, C C Limits C Gr, (Air=1) <F) (F) % (F) M.P. C (F) Sol. in H2O g/IOOg Othai Solvents Misc. Ret. 6 11.5) 2 4 4 1.65 exp. 240exp 81 (464) 1 (178) insol. ace., bz. 18 7b (3) 7b 7a 2 2 0 1.17 2 1 0 1.21 % 2S 1.19 45 (113)oc 414 (777) 3.6-29 115 (239) 62 1144) 220 1428) 180 (356)oc 245 (4731 @11mm ------- <360 (680) 49 (120) 80 (176) v. Sol. ale., bz. cs2 1 m$ol. j ale.. b2 insol. | ate., bz. I 2 2 0 .75 4.9 41 (106)oc 156 (313) -94 (--137) sl. sol. ale. 11 2S 1.62 74dec. si. sol. (165) 7b 2 18 100 1 16 .5 3 27k (.051 3S 1 3 3 0 1.17 12.7S 225 385 (437) (7251 410 (770) 11 (52) AIA, BDH 0 .87 4.6s 35-39 253 .8- 153-75 (95-102) (487) (307-47) AIA 1 .79 1.94 -15 249 2-95 63 -58 v. sol. ale., MeOH MCA (^5) (480) (145) (-72) 19.05 3818 1130 msol. (6905) (2066) AIA PAGE 117 SUBSTANCE/FORMULA Waste Dis posal Pro cedure (See VI) TLV (ACGIH) PPM (mg/M3) ^^^2, Uranium, Insoluble Compounds 27k 25 N. F, Pr A. Health Fire React. 3s Igmt. Vap. FI. Pt. Temp, Flam. B.P. Sp. Dens. C C Limits C Gr. (Airxsl) lF) (FJ % (F) M.P. C (F) Sol. in H9O g/lOOg Other Solvents insol. 1093. Uranium, Soluble Compounds 27k (.05) 3s 1094. Uranium, Nitrate U02(N03)2`6H20 27k (.05) 1 0 1 2.81 118 (244) 59 (138) sol. W ale., ace. Misc, Ref. 1095. Urea H2NCQNH2 1096. Valeraldehyde CH3CH2CH2CH2CHO 26 2. 0S 1.32 .81 3.0 12 (54) dec. 133 v. sol. ale. 102 (217) -92 (-134) si. sol. ale. NTTC NTTC 1097. Valeric Acid C4H9COOH 24a 'S .94 3.5 96 (205)oc 186 (367) -36 sol. (-31) ale. 1098. Vanadium Dichloride VCI2 27i 3S 3.23 dec. ale. 1099. Vanadium Oxytrichloride VOCI3 27i 3S 1 .S3 127 (261) -77 (-107) dec. ale. 1100. Vanadium Pentoxide V25 1101, Varnish 27i (.1) 18 2S 3.36 30 176-24* 1750dec, 690 (3182) (1274) si. sol. NTTC 1102. Vinyl Acetate CH3COOCHCH2 Vinyl Bromide,, see Bromoethyiene Vinyl Butyl Ether, see Butyl Vinyl Ether 18 2 3 2 ,94 3.0 -8 427 2.6-13.4 73 -100 insol. org, sol. NTTC. MCA (18) (800) (163) (-148) CMA 045742 CMA. 045743 SECTION VI. WASTE DISPOSAL PAGE 121 CMA 045744 SUBSTANCE/FORMULA 1112. Xylidine C6H3(CH3)2NH2 1113 Yttrium Y 1114. Zinc Zn 1115. Zinc Acetate Zn(C2H302)2 1116. Zinc Chlorate Zn{Cl03)2'4H20 1117. Zinc Chloride Zn Cl2 1118. Zinc Oxide ZnO 1119. Zirconium Zr 1120. Zirconium Compounds 1121. Zirconium Hafnium Powder Waste Dis posal Pro cedure (See VI) TLV (ACGIH) PPM (ma/M3) N. F. P. A. Health Fire React. 553 1 0 tgnit Vap. FI. Pt. Temp. Flam. B.P. Sp. Dens, C C Limits C Gr. (Air=1) (F) <F) % (*F) M,P, C (F) Sol. in H2O 9/100g Other Solvents .99 4.2S 97 (206) 224 (435) <-15 5) si sol ale Mi$c. Ref. SDH 26 i.D 2S 4,34 2927 1500 (5300) (2732) si. dec. 27a (15) 0 1 1 7,14 905 (1661) 419 (787) insol. 11 12a 11 ID s 20 2St 1.84 2 2.15 2St 2.91 200dec. 302 (392) ale. 60dec. 26220 (140) ale., ace. 732 (1350) 283 (541) 43225 ale. AIA 26 (5) 3S 5.47 1975 (3587) sol. 26 (5) 1 4 1 6.5 260 (500) 3578 1850 (5252) (3362) inSOl. AIA, NSC 11 (5) 26 (5) Is 14 1 20 (68) insol. MCA,NSC PAGE 120 CMA 045745 _DISPOSAL PROCEDURE ORGANIC ACID HALIDES Rubber gloves, self-contained breathing apparatus (or work in an effective fume hood with full face shield), laboratory coat. Cover with a mixture of soda ash and slaked lime (50-50). Mix thoroughly. Spray gently with 6M-NI-UOH,* Slowly scoop the slurry into large beaker or bucket of water. Neutralize** and slowly pour into drain with large excess of water. Wash site with soap solution containing soda ash. Package lots: (CHOICE OF PROCEDURES) 1 Slowly sift or pour into a large evaporating dish containing a layer of soda ash and lime. Spray with 6M-NH4OH as above. Mix thoroughly and add slowly to a large bucket of water. Neutralize and pour slowly down the drain with a large excess of water. Repeat this procedure until all has been disposed. 2 Dissolve the chloride in a flam mable solvent. Spray into an inciner ator with afterburner and scrubber. Examples: Acetyl bromide Acetyl chloride Benzoyl chloride Butyryl chloride Chrotonyl chloride Chloroacetyl chloride 3-chloropropionyl chloride o-chlorobenzoyl chloride Oxalyl chloride Propionyl chloride * See Section VII, ** If excess of 6M-NH.OH has been used, neutralize with 6M-HCI {use litmus paper indicator). If acidic, neutralize with 6M-NH4OH, CMA 045746 lb INORGANIC HALIDES Wear.- Rubber gloves, self-contained breath ing apparatus (or work in fume hood), laboratory coat. For the more active compounds work from behind a body shield. Spills: Cover with a 50-50 dry mixture of kaolin and soda ash. Mix thoroughly. Spray with 6M-NH4OH. When the smoke of NH^CI has subsided, scoop the slurry into a large beaker or plastic bucket of ice water. Neutralize* the solution and run the suspension down the drain with a large excess of water. Package lots: Sift or pour onto a dry well-mixed layer of 50-50 kaolin and soda ash in a large evaporating dish. After mixing thor oughly spray with 6M-NH4OH while stir ring. Cover with a layer of crushed ice and stir. Continue spraying with 6M-NH4OH. When the smoke of NH4CI has partly subsided add iced water and stir. Dump this slurry into a large con tainer. Repeat until all has been treated. Neutralize* and slowly siphon the suspension into the drain with ex cess running water. Examples: Aluminum bromide, anhydrous Aluminum chloride, anhydrous Ferric chloride, hexahydrate Germanium tetrachloride Silicon tetrachloride Tin tetrachloride Titanium tetrachloride * See la for procedure. CMA 045747 DISPOSAL PROCEDURE Rubber gloves, self-contained breathing apparatus, laboratory coat. Eliminate all sources of ignition and flammables. Small--Absorb on paper towel. Evapo rate in fume hood and burn the paper. Large--Cover with sodium bisulfite (NaHSO;i). Add small amount of water and mix. Scoop into large beaker. After one hour wash down the drain with a large excess of water. Wash site with soap solution. Package lots.- (CHOICE OF PROCEDURES) 1 Absorb on vermiculite. Burn in an open pit or open incinerator. 2 Dissolve in a flammable solvent (such as acetone or benzene). Spray into the fire-box of an incinerator equipped with an afterburner. Examples: Acetaldehyde Acrolein Acrolein dimer Benzaldehyde Butyraldehyde Caprylaldehyde Chloral Chloralhydrate Chloroacetaldehyde Cinnamaldehyde Crotonaldehyde 2-ethyl-3-propylacrolein Formaldehyde Formalin (MeOH free) Formalin (15% MeOH) Furfuraldehyde Glutaraldehyde Glyoxal Paraldehyde Paraformaldehyde Propionaldehyde Salicylaldehyde Valeraldehyde ldehydes t DISPOSAL PROCEDURE 2--PAGE 125 CMA 045748 DISPOSAL PROCEDURE--------------------------------------- ALKALI AND ALKALINE EARTH METALS, METAL ALKYLS, AND ALKOXIDES Wear-. Leather gloves, large face shield, labo ratory coat. (Class D fire extinguisher should be available) SpH/S : Small--Cover with dry soda ash. Mix and add slowly to butyl alcohol. After 24 hours dilute, neutralize* and add to drain with large excess of water. Package lots: OR Large spills--Mix with dry soda ash. Scoop into a dry bucket. In a remote area spread onto a large iron pan. Cover with scrap wood, paper and ignite with an excelsior train. OR--Burn in an open pit incinerator, OR--Direct "dry" steam onto the waste, spread on an iron pan. Beware of splatter. Examples: Alkoxides Aluminum alkyls Aluminum ethoxide n-butyl lithium Calcium Diethyl zinc Lithium Potassium Sodium Sodium ethoxide Sodium methoxide Sodium-potassium alloys Triethyl aluminum Triisobutyl aluminum * Neutralize with 6M-HCI. PAGE 126--DISPOSAL PROCEDURE 3 ALKALI AND ALKALINE EARTH METALS, METAL ALKYLS, AND ALKOXIDES CMA 045749 .DISPOSAL PROCEDURE CHLOROHYDRINS, NITROPARAFFINS Neoprene gloves, plastic laboratory coat, self-contained breathing appara tus. Provide good ventilation. Eliminate all sources of ignition. On skin--Wash immediately with soap solution. Rinse thoroughly. On clothing--Remove clothing immedi ately and place in a fume hood. Wash clothing before wearing again. Shoes are difficult to decontaminate and may have to be discarded and burned. On bench and floor--Cover with soda ash. Mix and spray with water. Scoop into a bucket of water. Let stand two hours. Neutralize* and wash into sewer with large excess of water. Wash site with soap solution. ' Neutralize with 6M-HCI. Package lots: (CHOICE OF PROCEDURES) 1 Pour or sift over soda ash. Mix and wash slowly into large tank. Neu tralize and pass to sewer with excess water. 2 Absorb on vermiculite. Mix and shovel into paper boxes. Drop into incinerator with afterburner and scrubber. OROHYDRINS, NITROPARAFFINS Examples iso-amyl nitrate iso amyl nitrite 1-chloro-l-nitropropane Chloropicrin Cyclonite 1,1-dichloro-l-nitroethane EPN Ethylene chlorohydrin Ethylene nitrate Ethyl nitrate Methyl ethyl nitrocarbamate Nitroethane Nitromethane Nitropropane Propyl nitrate Tetranitromethane DISPOSAL PROCEDURE 4a--PAGE 127 CMA 045750 ORGANIC HALOGEN AND RELATED COMPOUNDS Wear: Rubber gloves, self-contained breath ing apparatus, laboratory coat. Spills : Eliminate all sources of ignition. Ab sorb on paper towels. Place on an iron pan in a hood. Allow to evaporate. Burn the paper. Wash site with soap solution. Package lots: (CHOICE OF PROCEDURES) 1 Pour onto a sand-soda ash mix ture (90-10). (If a fluoride is present, add slaked lime to the mixture.) Mix and shovel into paper boxes. Place in an open incinerator. Cover with scrap wood and paper. Ignite with an excel sior train; stay on upwind side. Or dump into a closed incinerator with afterburner. 2 Dissolve in a flammable solvent. Spray into the fire box of an inciner ator equipped with afterburner and scrubber (alkali). Examples Aldrin Allyl bromide Allyl chloride Allyl chloroformate Allyl iodide Amyl bromide Benzal chloride Benzotrichloride Benzotrifluoride Benzyl bromide Benzyl chloride Benzyl chloroformate Bromobenzene Bromoethane Bromoethylene o-bromotoluene n-butyl bromide m-butyl chlorate t-butyl chloride Chlordane Chloroacetophenone Chlorobenzene Chlorocresols Chlorodiphenyl 3-chloro-2-methyl propene Chloronaphthalene PAGE 128--DISPOSAL PROCEDURE 4b ORGANIC HALOGEN AND RELATED COMPOUNDS CMA 045751 examples--Continued Ithloroprene Chlorotrifluoroethylene Dibuty! dichlorotin j 4-dichlorobutane j'3-dichloro-2-butene j l-dichloroethane 1 2-dichloroethylene ^2-dichloropropane ^ 3-dichloropropene Dieldrin Diethyl aluminum chloride Diethyl sulfate Dimethyl sulfate Dimethyl sulfoxide Dodecyl sodium sulfate Epichlorohydrin Ethyl bromoacetate Ethyl chloride Ethyl chloroacetate Ethyl chloroformate Ethylene dibromide Ethylene dichloride Ethyl fluoride Ethyl fluoroacetate Ethyl iodide Fluoroethylene Heptachlor Hexachlorobenzene Hexachloronaphthalene Lindane Methoxychlor Methyl bromide Methyl chloride Methyl chloroformate Methyl iodide Octachloronaphthalene Octafluoro-2-butene Octafluoropropane 4b Pentachloroethane Pentachloronaphthalene Propargyl bromide Propyl bromide Propyl chloride Propylene disulfate Sodium Pentachlorophenate 1,2, 4, 5-tetrachlorobenzene Tetrachloroethane Tetrachloroethylene Tetraethyl lead Tetramethyl lead Tributyl chlorotin 1,2,4-trichlorobenzene Trichloroethylene Trichloronaphthalene 1,2,3-trichloropropane Vinyl chloride Vinylidene chloride pGANIC HALOGEN AND RELATED COMPOUNDS DISPOSAL PROCEDURE 4b--PAGE 129 CMA 045752 DISPOSAL PROCEDURE----------------------------------SUBSTITUTED ORGANIC ACIDS Rubber gloves, self-contained breathing apparatus or all-purpose canister respirator, laboratory coat. Eliminate all sources of ignition. Turn on the fume hood if acid is volatile. Spray the atmosphere with 6M-NHjOH. Cover the spill on bench and floor with soda ash and slaked lime. Mix and scoop into a large beaker of water. When reaction is complete, neutralize* and pour down the drain, with a large excess of water. Wash site with soap solution. (CHOICE OF PROCEDURES) f m pour 0nto a mixture of soda ash and slaked lime (50-50). Mix and scoop into a bucket. Dump into a 55-gal. drum and fill with water. After 24 hours neutralize and slowly pour into drain with large excess of water. 2 Pour onto vermiculite in an open incinerator. Cover with scrap wood and paper. Pour waste alcohol over all and jgnite with an excelsior train. Stay on upwincj side. 3 Dissolve in a flammable solvent such as waste alcohol. Spray into an incinerator with an afterburner and scrubber. Benzene sulfonic acid Bromoacetic acid Chloroacetic acid Dichloroacetic acid EDTA Fluoroacetic acid lodoacetic acid Trichloroacetic acid 2,4, 5-trichlorophenoxy acetic acid Trifluoroacetic acid * Neutralize the 6M*NHiOH with 6M-CI. PAGE 130--DISPOSAL PROCEDURE 4c SUBSTITUTED ORGANIC ACIDS CMA 045753 DISPOSAL PROCEDURE aromatic AMINES Butyl rubber gloves, plastic laboratory coat, self-contained breathing appara tus. On skin and clothing--Wash skin with strong soap solution immediately. Rinse thoroughly. Contaminated cloth ing should be removed, dried, and washed with strong soap solution--or destroyed. It may be necessary to de stroy shoes by burning. Small spills--Absorb liquids on paper towels. Brush solids onto paper. Place in an iron pan and allow evaporation in the fume hood. Add crumpled paper and burn. Wash site with strong soap solution. Large spills--Cover large spills with sand and soda ash mixture (90-10). Mix and shovel into a cardboard box. Pack with much excess crumpled paper. Burn in an open pit or in an incinerator with afterburners and scrubber. Package lots: (CHOICE OF PROCEDURES) 1 Pour or sift onto a thick layer of sand and soda ash mixture (90-10). Mix and shovel into a heavy paper box with much paper packing. Burn in incinerator. Fire may be augmented by adding excelsior and scrap wood. Stay on upwind side. 2 Waste may be dissolved in flam mable solvent (alcohols, benzene, etc.) and sprayed into fire box of an inciner ator with afterburner and scrubber. Examples: Acridine 2-aminodiphenylene oxide 2-aminopyridine Aniline Anisidines 2-anthramine Auramine Aziridine Benzidine* Benzyl amine N-4-biphenyl acetohydroxamic acid 2-biphenyl amine 1, 2, 5, 6dibenzacridine 1, 2, 7, 8dibenzacridine 1, 2, 5, 6dibenzcarbazole 3, 4, 5, 6dibenzcarbazole Dibenzyl amine N, N-diethyl aniline 3,3'-dimethoxy benzidine* N, N-dimethyl aniline Diphenyl amine N-ethyl aniline Ethyl morpholine 1-methyl- 2-naphthylamine Morpholine 1- naphthylamine 2- naphthylamine* Nicotine p-phenylenediamine Phenylethanolamine Phenyl- 2-napththylamine Pyridine Quinaldine Quinoline 4-stilbenamine Strychnine Toluidines Xylidines * Carcinogenic CMA 045754 JL DISPOSAL PROCEDURE AROMATIC HALOGENATED AMINES and NITRO COMPOUNDS Wear: Butyl rubber gloves, protective labora tory coat, self-contained breathing apparatus, protective shoes. Spills : On skin--Wash with strong soap solu tion immediately. Rinse well. Contaminated gloves, clothing, shoes-- Remove and clean at once or destroy by burning. Small spills on tables or floor--Absorb liquid spills on paper towels; sweep solid spills onto paper. Put on an iron pan in the fume hood and allow to evaporate. Burn the paper in the ab sence of other flammables. Wash the site thoroughly with strong soap solu tion. Large spills--Absorb liquid spill on sand or mix sand with a solid spill. Package this in a paper carton and burn in an open pit. Use fuel such as crumpled paper and wood splinters. Wash site thoroughly as above. Package lots: (CHOICE OF PROCEDURES) 1 Pour or sift onto sand-soda ash mixture (90-10). Mix and package in heavy paper cartons with plenty of paper packing to serve as fuel. Burn in an incinerator. Fire may be aug mented with scrap wood. 2 The packages of # 1 may be burned more effectively in an incinerator with afterburner and scrubber (alkaline). 3 The waste may be mixed with a flammable solvent (alcohol, benzene, etc.) and sprayed into the fire cham ber of an incinerator with afterburners and scrubber. Examples Azoxybenzene Brucine Carbazole 1- chloro-2, 4-dinitrobenzene Chloro-2-naphthylamine Chloro-nitroanilines Chloro-nitrobenzene Chlorophenols 2,6-dibromo-N-chloro-p-benzoquinoneimine 2.5- dichloroaniline Dichlorobenzene 3, 3'-dichlorobenzidine* 1, 3-dichloro 5,5-dirnethylhydantoin 2,4-dichlorophenol 2- dimethylaminefluorene 9,10-dimethyl-l, 2-benzanthrene N, N-dimethyl-4-biphenylamine Dinitroaniline m-dinitrobenzene** o-dinitrobenzene** p-di nitrobenzene** 4.6- dinitro cresol 2, 7-dinitrofluorene 2, 4-dinitrophenol* * Carcinogenic, ** Explosive. Other mtro compounds may also b unstable. PAGE 132--DISPOSAL PROCEDURE 6 AROMATIC HALOGENATED AMINES and NITRO COMPOUNDS CMA 045755 EXAMPLES--Continued . 4-dinitrosopiperazine I 4-dinitrotoluene** Elon Endrin 4-ethoxy-2-n 1 troan 1 line Hj.2-f|uorenylacetamide 4.f|goro4-biphenylamine 2-fluoro-4-phenylacetan i I ide 4-fluoro-4'-pheny lacetani I ide Methylene bis-phenylisocyanate N-methyl'N-nitrosoacetamide N-methyI-N-n itrosoaI lylamine IM-methyl-N-nitrosoaniline N-methyl-N-nitrosobenzylamine DISPOSAL PROCEDURE 1-methyl-l-nitrosourea N*methyl-N-nitrosovinylamine 1- methyl pyrole N-methyl-N-2,4,6-tetranitroaniline 3- nitroacetophenone m, 0-, p-nitroanilines Nitrobenzene Nitrobiphenyl 2- nitrofluorene n-nitronaphthalene Nitrophenols 4- nitroquinoline-N-oxide N-nitroso-N-methylaniline 4-nitrosomorphoiine 1- nitrosopiperazine N-nitrosopiperidine m-r o-, p-nitrotoluenes 2- phenonthreneacetamide Picric acid** N, N, N', N'-tetramethyl-3, 3'-dimethoxybenzidine N, N, N'f N'-tetramethylenediamine Toluene-2,4-di isocyanate Trinitrobenzene** Trinitrotoluene** ** Explosive. Other mtro compounds may also be unstable. CMA 045756 7a ALIPHATIC AMINES Wear.- Butyl rubber gloves, face shield or all purpose canister respirator, laboratory coat. Spills: Liquid or solid--Cover with sodium bi sulfate. Spray with water, neutralize* and wash into drain with large excess of water. * Make a litmus test. Use 6M-HCI or 6M-NH.1OH as required. Package lots: (CHOICE OF PROCEDURES) 1 Add the contaminated amine to a layer of sodium bisulfate in a large evaporating dish. Spray with water. Make neutral and wash into the drain with large excess of water. 2 Dissolve in a flammable solvent (e.g., waste alcohols). Burn in an open pit by means of an excelsior train. Stay on the upwind side. 3 Solution of #2 may be sprayed into the fire box of an incinerator with afterburner and scrubber. Examples Allyl amine Amyl amine Aminoethylethanola- mine Butyl amine Iso-butyl amine Tert-butyl amine Dibutyl amine Cyclohexylamine Dicyclohexylamine Diethanolamine Diethyl amine 2-diethyl aminoethanol Diethylenetriamine Diisopropylamine Dimethylamine Ethanolamine Ethylamine Ethylene diamine N-ethyl-N-nitrosoN-butylamine N-ethyl-Nnitrosovinylamine n-heptylamine Hexamethylenetetra mine 1-6-hexanediamine Hydroxylamine Hydroxylamine hydrochloride Lutidine N-methylbutylamine Monomethylamine N-nitrosodiethanola- mine N-nitrosodimethylamine* 1, 2-propanediamine Propyl amines Propylene imine Pyrrolidine Tetraethylenepentamine Triamylamine Tri-n-butylamine Tri-ethylamine Triethanolamine Triethylene tetramine Trimethylamine Tri propylamine * Carcinogenic. CMA 045757 .DISPOSAL PROCEDURE 7bORGANIC PHOSPHATES AND RELATED COMPOUNDS Rubber gloves, self-contained breath ing apparatus, laboratory coat. Absorb on paper towels or sweep onto towel. Put on an iron pan in the hood. Add some pulverized limestone and pour onto it a slight amount of benzene. Ignite from behind a body shield with a long torch. Dump residues into a large beaker of water. When settled decant into drain with large excess of water. Wash site thoroughly with soap and water. Package lots: (CHOICE OF PROCEDURES) 1 Take packages to an open incin erator. Stay on upwind side and mix with equal parts of sand and pulverized limestone. Wet down with a flammable solvent (benzene or alcohol). Ignite from a safe distance with an excelsior train. 2 Shovel mixture of #1 into a paper box and drop into an incinerator with an efficient afterburner. Alkaline scrub bing will prevent escape of any oxides of phosphorous and arsenic. Examples 0-chlorophenyl diphenyl phosphate Dibutyl phosphite Diethyl ethyl phosphate Diisopropyl fluorophosphate Dimethyl-1,2-dibromo-2, 2-dichloro-ethyl phosphate Grain fumigants Hydroxy dimethyl arsine oxide Malathion Methyl parathion 1-naphthylisothiocyanate Parathion Phosdrin Ronnel Systox Tetra ethyl dithiono pyrophosphate Tetra ethyl pyrophosphate Tri butyl phosphate Triphenyl phosphate Triphenyl phosphine Tritolyl phosphate CMA 045758 PROCEDURE-------------------------------------- - i AZIDES and AZO-COMPOUNDS I The organic azides and heavy metal azides are explosive. Alkali and alka line earth azides are not considered ex plosive under normal laboratory con ditions. Keep stock of all azides very low. Stamp date and receipt on package. Wear.- Leather gloves, heavy face shield, labo ratory coat. Work from behind a barri cade (body shield or wall). Avoid un necessary heat, friction or impact. Small spills.- Absorb the liquid on paper. If it is a solid, brush onto paper with great care. Deposit on an iron pan in a hood and add some crumpled paper for fuel. Ignite by means of a torch from behind a body shield. OR Sponge up with water, followed by de contamination with a 10% ceric am monium nitrate solution. Large spills or Package lots: (CHOICE OF PROCEDURES) 1 Dissolve alkali or alkaline earth azides in a large volume of water. Wash into drain with a large volume of water. 2 Transfer organic azides and azo compounds, and azides of heavy metals to an open pit, preferably on an iron pan. Add paper and wood for fuel. Ignite by means of a long excelsior train. 3 "Kill" in a grea t e r-t h a n- stoichiometric amount of ceric am monium nitrate solution with agitation sufficient to provide suspension of all solids. Examples: Sodium azide Hydrazoic acid Diazo methane 2,3-dimethyl-azo benzene l-ortho-tolylazo-2-naphthol 3-methyl-4-dimethyl ammo-azobenzene Dimethyl amino azo benzene-2-naphthalene 2,2'-azonaphthalene l-phenylazo-2-naphtho! I I i CMA 045759 CARBON DISULFIDE Rubber gloves, safety glasses, labora tory coat. If hood is not available wear self-contained breathing apparatus. Carbon dioxide fire extinguisher should be available. Eliminate flammables and all sources 0f ignition. Allow to evaporate or absorb with paper towels and evaporate in hood on an iron pan. Burn the paper. Package lots: All equipment or contact surfaces should be grounded to avoid ignition by static charge. Absorb on vermiculite, sand, or ashes and cover with water. Transfer under water in buckets to an open area. Ignite from a distance with an excelsior train. If quantity is large, carbon disulfide may be recovered by distillation and repackaged for use. Iarbon disulfide DISPOSAL PROCEDURE 9-PAGE 137 CMA 045760 r CAUSTIC ALKALI AND AMMONIA Wear.- Rubber gloves, large face shield (wear all-purpose or special canister respira tor for NH(*), Laboratory coat. Package lots: Pour into large tank of water and neu tralize. Transfer to sewer with large excess of water. Spills : Solid--Sweep up, dilute and neutralize with 6M-HCI in a large bucket. Wash down drain with large excess of water. Solution--Neutralize and mop up--or use water-vac. Discharge to sewer with large excess of water. *NH.i or concentrated solution of NH3. Spray atmosphere with 6M-HCI from a stainless steel spray can or its equiva lent--or fog cjown with a water hose. Neutralize and flush to sewer with ex cess of water. Examples: Ammonia, anhyd. Ammonia, aqua Slaked lime Quick lime Caustic soda Caustic potash PAGE 138--DISPOSAL PROCEDURE 10 CMA 045761 DISPOSAL PROCEDURE INORGANIC SALTS Rubber gloves, safety glasses, labora tory coat. 1 Solutions--Cover with soda ash, mix and scoop into a beaker of water. Neutralize with 6M-HCI and wash down drain with excess water. 2 Solids--Collect in a beaker. Dis solve in large amount of water. Add soda ash, mix and treat as above. If spill contains a fluoride, add slaked lime in addition to the above treatment. Package lots; Add slowly to a large container of water. Stir in slight excess of soda ash. If fluoride is present add slaked lime also. Let stand 24 hours. Decant or siphon into another container and neutralize with 6M-HCI before washing down drain with large excess of water. The sludge may be added to land fill. Examples: Alums Aluminum chloride, hydrate Aluminum nitrate, hydrate Aluminum sulfate, hydrate Ammonium fluoride Ammonium nitrate Ammonium thiocyanate Borax Calcium chloride Chromic (III) salts, hydrates Cobaltous nitrate Copper nitrate Ferrous Ammonium sulfate Ferrous chloride Ferrous sulfate Lithium carbonate Magnesium chloride Magnesium nitrate Manganese sulfate Nickel nitrate Nickel sulfate Potassium acetate Potassium carbonate Potassium ferrocyanide Potassium fluoride Potassium hydrogen difluoride Potassium nitrate Sodium acetate Sodium benzoate Sodium bicarbonate Sodium carbonate Sodium chloride Sodium fluoride Sodium formate Sodium hydrogen difluoride Sodium iodide Sodium phosphates Sodium propionate Sodium silicate Sodium tetraborate Stannic chloride, hydrate Zinc acetate Zinc chloride 2GANIC SALTS DISPOSAL PROCEDURE 11--PAGE 139 CMA 045762 OXIDIZING AGENTS Wear: Rubber gloves, face shield, laboratory coat. Body shield should be available for the more active agents. Replace face shield with self-contained breath ing apparatus for such agents as chlo rine and bromine. SpHlS: 1 If a gas leak (e.g., chlorine)--Turn on the fume hood and spray the atmos phere with a high concentration of a reducer such as a solution of hypo, NajS-03, or sodium sulfite.* Attempt to stop leak and return the tank to the supplier. If the leak cannot be stopped, set tank upside down in a drum filled with reducer solution (hypo, sodium sulfite, or ferrous sulfate). Add more reducer as needed until all chlorine is converted to chloride. * After the operation is completed wash down the furniture and floors to remove the salts used and formed. 2 If the oxidizer is a liquid or a solid--Cover with a reducer (hypo, a bisulfite, or a ferrous salt but not car bon, sulfur or strong reducing agents). Mix well and spray with water. A sulfite or a ferrous salt will require addition of some 3M-HjS04 to promote rapid reduction. Scoop slurry into a con tainer of water and neutralize with soda ash. Wash down the drain with excess water. Wash site thoroughly with a soap solution containing some reducer. Package lots: Add to a large volume of concentrated solution of reducer (hypo, a bisulfite or a ferrous salt and acidify with 3M-HoS04). When reduction is com plete add soda ash or dilute hydro chloric acid to neutralize the solution. Wash into drain with large excess of water. Examples: Ammonium dichromate Ammonium perchlorate Ammonium persulfate Bromic acid Bromine Calcium chlorate Calcium hypochlorite Chloric acid Chlorine Chlorine dioxide Cleaning solution (acid dichromate) Chromium oxychloride Iodine Magnesium chlorate Magnesium perchlorate Peracetic acid Perchloric acid Potassium and sodium perchlorates, chlorates, chlorites, hypochlorites, persulfates Zinc chlorate PAGE 140--DISPOSAL PROCEDURE 12a 1 CMA 045763 REDUCING Rubber gloves, safety glasses, labora tory coat. Work in hood or wear a respirator. ous), stir and add more water to form a slurry. Scoop the slurry into a large beaker. Let stand for one hour; dilute and neutralize* the oxidized solution and transfer to the drain with excess water. Eliminate all sources of ignition. If a gas leak* (SOj, etc.), turn on fume hood and spray atmosphere with soda ash solution containing low concentration of calcium hypochlorite. Wash into drain. If spill is a solid cover it with soda ash. Mix and spray with water. If effer vescent wait until reaction is complete. Cautiously add equal volume of calcium hypochlorite (reaction may be vigor- Test with litmus. Neutralize with 6M-HCI or gM-NaOH as required. * if a tank of reducing gas has developed a perma nent leak lower it upside down into a drum filled with water. Add a mixture of soda ash and cal cium hypochlorite. Continue the treatment until the tank is empty and the drum contains a solu tion of stable element or compound. Package lots: If a gas,** bubble into soda ash solu tion. If a solid, mix with equal volume of soda ash and add water to form a slurry in a large container. In either case add calcium hypochlorite. Add more water if necessary and let stand two hours. Neutralize* the oxidized solution. Wash down drain with large excess of water. Sulfur dioxide Chromous salts Sodium sulfite Sodium thiosulfate Sodium bisulfite Sodium nitrite Stannous chloride CMA 045764 13 MERCAPTANS-and organic sulfides Wear: Rubber gloves, self-contained breath ing apparatus, laboratory coat. Spills : Eliminate all sources of ignition. Cover with calcium hypochlorite and mix. Scoop into a large beaker. After 12 hours, neutralize* if necessary. Wash to sewer with excess water. Wash site of spill with strong soap solution to which has been added some hypochlo rite. Package lots: 1 As for spills. 2 Dissolve in waste alcohol or other flammable solvent. Burn in an inciner ator with an afterburner and scrubber to neutralize the S03. Examples. Ally! propyl disulfide Amyl mercaptan Benzyl mercaptan Butyl mercaptan Carbonyl sulfide** Diphenyl sulfide Ethanethiol 2-mercaptoethanol Methyl mercaptan** Perchloromethyl mercaptan Thioacetamide Thioglycolic acid 2,2-thiodiethanol Thiophene Thiourea Tetramethylthiuram disulfide (Thiram) CMA 045765 _DISPOSAL PROCEDURE CYANIDES AND NITRILES Long rubber gloves, self-contained breathing apparatus, laboratory apron 0r coat. Evacuate the laboratory and isolate the area during decontamination. Spills : Eliminate all sources of ignition and flammables. 1 General treatment: (a) Absorb liquid on paper towel (sweep solid onto paper). Place on an iron pan in a hood. Evapo rate and burn paper. (b) On skin--Wash away immediately with much soap and water. 2 Hydrocyanic acid (HCN) leak.-* Turn on fume hood and spray atmos phere with alkaline solution of calcium hypochlorite. Allow gas to leak into a container of sodium hydroxide solu tion while stopping leak. Add excess calcium hypochlorite to the alkali cya nide. Discharge the cyanate into the drain with excess water. * If the leak cannot be stopped set the tank upside down in a drum filled with a strong solution of sodium hydroxide and calcium hypochlorite, Con* tinue the treatment until the tank is empty. 3 Cyanides: (a) Scoop into a larger beaker and make alkaline with sodium hydrox ide solution. Add to the slurry an excess of ferrous sulfate solution. After one hour, flush down the drain with excess water. OR (b) Add excess sulfur to the alkaline slurry of the cyanide. Heat to con vert to thiocyanate. Flush down drain with excess water. Nitriles: Add excess of strong calcium hypochlo rite solution to produce a cyanate. Scoop slurry into a large beaker. After one hour flush down the drain with excess water. Wash site with soap solu tion containing some hypochlorite. (Continued on n xf page) snides and nitriles DISPOSAL PROCEDURE 14--PAGE 143 CMA 045766 14 Package lots: (CHOICE OF PROCEDURES) 1 Add with stirring to strong alkaline solution of calcium hypochlorite. Let stand 24 hours. Flush the cyanate down drain with large excess of water. 2 Liquid nitrile can be mixed with a flamable solvent and sprayed into an incinerator equipped with an after burner and scrubber. Examples Calcium cyanide Cuprous cyanide Cyanamide Cyanogen Cyanogen chloride Hydrocyanic acid Potassium cyanide Sodium cyanide Acetone cyanohydrin Acetonitrile Adiponitrile Benzonitrile Benzyl nitrile Butyl nitrile Chloroacetonitrile Crotononitrile Cyanoacetamide Ethyl cyanoacetate Lactonitrile Propionitrile Sevin Succinonitrile Tetramethyl- succinonitrile Trichloroacetonitrile CYANIDES AND NITRILES CMA 045767 CEDURE 1 5 Rubber gloves, large heavy face shield (if in doubt use body shield also). Selfcontained breathing apparatus. Eliminate all sources of ignition and flammables. Absorb on paper towel. Evaporate from an iron pan in a hood. Allow time for vapors to completely escape the hood vents, then bum the paper. If large spill, absorb on much more paper or vermiculite and allow com plete evaporation from all surfaces. Use same precaution before burning paper. Package lots: 1 Pour on ground in open area. Allow evaporation or ignite from a dis tance by means of a long fuse or excel sior train. 2 Dissolve waste in higher alcohol (e.g., butyl), benzene, or petroleum ether. Incinerate. 3 PEROXIDE FORMATION. (See MCA Data Sheet SD-29 ethyl ether.) Ether of long standing in contact with air and exposed to light may contain peroxides, especially if stored in clear glass. Explosions have occurred when caps or stoppers were turned. (See MCA Accident Case History No. 603.) Transport cans or bottles to an isolated area (e.g., deserted quarry). Each con tainer should be wrapped in padding material or packed in sawdust. At site uncover containers and arrange an ex celsior train. From a safe distance puncture the cans near bottom with rifle fire. Ignite excelsior train. Local regulations must be observed. Examples: Allyl glycidyl ether n-Amyl ether Anisole Butyl vinyl ether Di-n-butyl ether 2.2-dichloroethyl ether Diethylene glycol monoethyl ether Diglycidyl ether Diisopropyl ether Dimethoxy ethane Dimethoxy methane Dimethoxy propane Dipropylene glycol methyl ether 1.2-epoxy-3-phenoxy. propane 1.2-epoxy-propane Ethoxyacetylene Ethyl ether Ethyl vinyl ether Ethylene oxide Glycidol Guaiacol Hydroquinone monomethyl ether Methyl ether Methyl ethyl ether Methyl vinyl ether Phenyl ether Phenyl etherbiphenyl mixture iso-propyl ether iso-propyl glycidyl ether Vinyl ether SHERS DISPOSAL PROCEDURE 15--PAGE 145 CMA 045768 Wear: Rubber gloves, self-contained breath ing apparatus. Impervious clothing recommended. Body shield should be available. S/BillS: Eliminate ail sources of ignition and flammables. 1 On skin or clothing--Wash skin immediately. Remove contaminated clothing at once. 2 Absorb liquid with paper towels. Sweep solids onto paper. Burn the paper on an iron pan in a hood. 3 Large spills--Collect the liquid with an aspirator such as used for re covering spilled mercury. Empty into a large beaker and neutralize with dilute sulfuric acid. Wash to drain with excess water. Wash site with soap and water. Package lots: (CHOICE OF PROCEDURES) 1 Dilute to at least 40% and neu tralize with dilute sulfuric acid. Flush to sewer with excess water. OR 2 Dissolve in large volume of waste alcohol or other flammable solvent and burn in an open pit. Ignite from a dis tance with an excelsior train. PAGE 146--DISPOSAL PROCEDURE 16 HYDRAZINES Examples: Hydrazine Methyl hydrazine Phenyl hydrazine 1,1-dimethyl hydrazine (UDMH) Hydrazine salts HYDRAZINES CMA 045769 HYDRIDES Rubber gloves, fire proof clothing, face shield. Work from behind body shield where possible. Keep available pulver ized dolomite or dry graphite for fire fighting. Eliminate all sources of ignition and flammables. Sweep powder onto dry paper and place on an iron pan in a hood. Spray with dry butyl alcohol. Keep blower on to maintain low gas concentration. Destroy last traces of hydride by spraying with water. Neu tralize and wash to sink with excess water. If hydride powder lands on skin blow it off and flood the skin with excess water. Package lots: (CHOICE OF PROCEDURES) 1 Mix with dry sand to avoid or stop fire. Scoop into bucket and remove to open area. Slowly spray with dry butyl alcohol. Later add water by fogging until last of hydride is destroyed. Scoop the solid into a large container. Neutralize* with 6M-HCI. Let settle. Decant and flush to sewer with excess of water. Send sand residue to land fill. 2 Burn in iron pan or in open pit. * Test with litmus-- neutralize with 6M HCI if necessary. Examples: Decaborane Silane Germanium hydride Lithium borohydride Lithium hydride Sodium hydride Potassium hydride Sodium borohydride Diborane Pentaborane Lithium aluminum hydride Aluminum borohydride HYDRIDES DISPOSAL PROCEDURE 17--PAGE 147 CMA 045770 - PROCEDURE HYDROCARBONS, ALCOHOLS, KETONES, and ESTERS Wear.- Rubber gloves, face shield, laboratory coat Have all-purpose canister mask available. Spills: Eliminate all sources of ignition and flammables. 1 A gas leak from a faulty tank-- Keep concentration of gas below the explosive mixture range by forced ven tilation. Remove tank to an open area and allow dissipation to the atmos phere. Attempt to cap the valve outlet and return tank to the supplier. 2 A liquid--Absorb on paper. Evapo rate on an iron pan in a hood. Burn the paper. 3 A solid--Sweep onto paper and place in an iron pan in the hood. Burn the paper and compound. Package lots.- 1 A gas--Pipe the gas into the incin erator. Or lower into a pit and allow it to burn away. 2 A liquid--Atomize into an incinera tor. Combustion may be improved by mixing with a more flammable solvent. 3 A solid--Make up packages in paper or other flammable material. Burn in the incinerator. Or the solid may be dissolved in a flammable sol vent and sprayed into the fire chamber. Examples Acenaphthene Acetone Acetylene Alizarin dye Allene Allyl acetate Ally! alcohol m-Amyl acetate iso-Amy! acetate sec-Amyl-acetate m-Amyl-alcohol iso-Amyl alcohol tert-Amyl alcohol Amylene iso-Amyl formate Anthracene Anthraquinone 1, 2-Benzanthracene Benzene Benzyl acetate Benzyl alcohol Benzyl benzoate Biphenyl Borneol Butadiene m-Butane iso-Butane 1-Butene 2-Butene m-Butyl acetate iso-Butyl acetate sec-Butyl acetate tert-Butyl acetate m-Butyl alcohol iso-Butyl alcohol sec-Butyl alcohol tert-Butyl alcohol Butyl cellosolve m-Butyl formate iso-Butyl formate Butyl methacrylate iso-Butyl methyl ketone p-tert-Butyl toluene 1-Butyne 2-Butyrolactone Camphor Carbon monoxide Cellosolve Cellosolve acetate Cresols Creosote Croton oil Crude oil Cumene Clycloheptanone Cyclohexane Cyclohexanol Cyclohexanone Cyclohexene Cyclohexyl benzene Cyclopentadiene Cyclopentane Cyclopentanone Cyclopropane p-Cymene PAGE 148--DISPOSAL PROCEDURE 18 HYDROCARBONS, ALCOHOLS, KETONES, and ESTERS CMA 045771 SAMPLES--Continued DISPOSAL necahydronaphthalene m.necane rn-Decyl alcohol piacetone alcohol ' 6-Dibenzanthracene 1 2, 5. ' 6-Dibenzofluorene 1, Z, 3, 4-Dibenzophenanthrene 3 4, 8,9-Dibenzpyrene nib'utyl tin diluarate pibutyl oxalate Dibutyl phthalate picyclopentadiene Diethyl adipate piethyl carbonate piethylene glycol piethyl ketone piethyl matonate piethyl phthalate 3, 4-Dihydropyran Diisobutyl ketone 2r 2-Dimethyl butane Dimethyl carbonate 1 2 Dimethyl chrysene Dimethyl fumarate Dimethyl naphthalene Dimethyl propane Dimethyl phthalate pi-m-octyl phthalate Di-sec-octyl phthalate 1,4-Dioxane Dipentene Dipentene monoxide Diphenyl methane Dodecane Ethane Ethyl acetate Ethyl acetoacetate Ethyl acrylate Ethyl alcohol Ethyl-sec-amyl ketone Ethyl benzene Ethyl benzoate Ethyl butyl ketone Ethyl butyrate Ethyl crotonate Ethylene Ethylene glycol Ethyl formate 2-Ethyl hexanol Ethyl lactate Ethyl oxalate p-Ethyl phenol Ethyl silicate Furan Furfuryl alcohol Gasoline Glycerol Greases Heptane Hexane m-Hexanol 1-Hexene 2-Hexene sec-Hexyl acetate p-Hydroquinone 5-indanol Industrial gases (LHG) Isoprene Jet fuels Kerosene Ketene Lacquer diluent Ligroin Liquefied petroleum gas p-Mentha-1, 8-diene Mesityl oxide Methane Methyl acetate Methyl acrylate Methyl alcohol Methyl amyl alcohol Methyl-m-amyl ketone 6 Methyl-1, 2-benzanthra cene 10 Methyl, 1, 2-benzanthra cene Methyl benzoate Methyl benzyl alcohol 2-Methyl-l-butene 2- Methyl-2-butene 3- Methyl-l-butene Methyl butyl ketone Methyl butyrate Methyl cellosolve Methyl cellosolve acetate 3- Methyl cholanthrene Methyl cyclohexane 2-Methyl cyclohexanol 2-Methyl cyclohexanone 4- Methyl cyclohexene Methyl ethyl ketone Methyl formate 2-Methyl furan Methyl isobutyl ketone Methyl isobutyrate Methyl isocyanate Methyl methacrylate 1-Methyl naphthalene Methyl-m-propyl ketone Methyl salicylate Methyl styrenes Methyl-toluene sulfonate Naphthas Naphthalene 1- Naphthol 2- Naphthol Natural gas Nonyl phenol Octane 1-Octanol dYDROCARBONS, ALCOHOLS, KETONES, and ESTERS 2-Octanol Oil, cocoanut Oil, fuel Oil, lubricating Oil, mineral mist Oil, olive Oil, peanut Oil, soybean Oil, vegetable Paraffin m-Pentane iso-Pentane 1, 5-Pentanediol 2, 4-Pentanedione 2-Pentanol Petroleum ether Phenanthrene Phenol Phenyl acetate Phenyl isocyanate o-Phenyl phenol Phorone iso-Phorone Phosgene solutions in benzene 2-Pinene Piperylene Pival Polyvinyl acetate emulsion Propane 1, 2-Propanediol Propargyl alcohol iso-Propenyl acetate iso-Propyl acetate m-Propyl acetate m-Propyl alcohol iso-Propyl alcohol Propyl benzene iso-Propyl benzoate Propylene Propylene carbonate 18 Propyl formate iso-Propyl formate Propyne Propyne-allene mixture Qumone Resorcinol Rotenone Stoddard solvent Styrene Tall oil Tallow Terphenyls Tetradecane Tetrahydrofuran Tetrahydronaphthalene 1-Tetralone Toluene Tridecanol Triethylene glycol Triethyl-ortho-formate 5, 9,10-Trimethyi-l, 2-benzanthracene 6, 9,10-Trimethyl-l, 2-benzanthracene Trimethyl borate 2, 2, 4-Trimethyl pentane 2, 4, 4-Trimethyl-2-pentane S-trioxane Turpentine Varnish Vinyl acetate Warfarin Xylenes Xylenols DISPOSAL PROCEDURE 18-PAGE 149 CMA 045772 19 INORGANIC AMIDES and Derivatives Wear: Rubber gloves, large face shield, pro tective laboratory coat. A large body shield should be available. SpHlS : Eliminate all sources of ignition. Sweep up solid amide onto dry paper. Cau tiously add to cold water in small por tions with agitation. Neutralize* and discharge into drain with large excess of water. Package lots: Sift slowly into a large container of cold water, with agitation. When all has reacted, neutralize* and pour into drain with large excess of water. Examples Sodium amide Sulfamide Sulfamic acid Ammonium sulfamate Test with litmus. Neutralize with 3M-HCI or 6M-NH*OH as required. PAGE 150--DISPOSAL PROCEDURE 19 INORGANIC AMIDES and DERIVATIVES CMA 04S773 ORGANIC amides Rubber gloves, safety glasses, labora tory coat. Sweep onto a paper towel. Place on an iron pan in a hood. Add alcohol and ignite. If liquid, absorb on a paper towel. Package lots: Add to a flammable solvent (alcohol or benzene). Pour into an iron pan in an open pit. Ignite. OR Spray into an incinerator. Oxides of nitrogen may be scrubbed out with alkaline solution. 20 Examples.- N, N-dimethylacetamide Dimethyl formamide Formamide 2-Phenanthreneacetamide 3-Phenanthreneacetamide CMA 045774 21 INTER NON-METALLIC COMPOUNDS Wear: Long rubber gloves, safety glasses or goggles, self-contained breathing ap paratus, laboratory coat. Recommended that work be done in an effective hood from behind a body shield or in an open barricaded area out of doors. NOTE--Some suppliers will collect unwanted cylinders of com pressed gases on request. Spills : Eliminate all sources of ignition. Gas leak (e.g,, boron trichloride, chlo rine trifluoride). Allow gas to flow into a mixed solution of caustic soda and slaked lime or invert the cylinder in a large container of the solution of main tained concentration. If possible, keep in a hood until cylinder is emptied. Liquid or solid--Cover with mixture of soda ash and slaked lime (50-50). Mix and spray water cautiously from an atomizer. Scoop up and add slowly to a large container of water (if too active continue spraying). When reaction is complete neutralize* and wash down the drain with a large excess of water. Wash site with soap solution. Package lots: Sprinkle or sift onto a thick layer of mixed dry soda ash and slaked lime (50-50) from behind a body shield. Mix and spray water cautiously with an atomizer. Scoop up and sift cautiously into a large volume of water. Neutral ize* and wash down the drain with large excess of water. * Make litmus test Neutralize with 6M-NH4OH or 6M-HCI as required. Examples Boron fluoride-ethyl ether complex Boron tribromide Boron trichloride Boron trifluoride Boron trifluoride complexes with acetic acid and methanol Bromine pentafluoride Bromine trifluoride Carbonyl fluoride Chlorine trifluoride Nitric oxide Phosphorous oxychloride Phosphorous pentachloride Phosphorous pentasulfide Phosphorous sesquisulfide Phosphorous tribromide Phosphorous trichloride Silicon tetrafluoride Sulfur decafluoride Sulfur dichloride Sulfur hexafluoride Sulfur monochloride Sulfuryl chloride Sulfuryl fluoride Thionyl chloride Thionyl fluoride CMA 045775 PEROXIDES, INORGANIC Rubber gloves, large face shield, labo ratory coat. A body shield should be available. Package lots: Use the above method for the encrusted impure peroxide. Repackage any recov ered pure granular peroxide in glass containers with rubber stoppers. 22a Examples .* Hydrogen peroxide {3% to 90%) Sodium peroxide Potassium peroxide Potassium superoxide Cover with at least double volume of sand-soda ash mixture (90%-10%). Mix thoroughly and break up any lumps of peroxide. With a plastic scoop add slowly to a large beaker of sodium sul fite solution (3 or 4 liters) with stirring. Neutralize with dilute sulfuric acid. When settled decant the sulfate solu tion into drain with excess water. The sand can be sent to the landfill. CMA 045776 I 22b PEROXIDES, ORGANIC CAUTION: Keep stock low and date each container as received. Never transfer to glass stoppered containers or screw cap bottles which can cause dangerous friction. See Procedure 15. Wear: Rubber gloves, large heavy face shield, laboratory coat. Work from behind heavy body shield in hood. NaOH, Bum the original cartons and bags. 2 Solid peroxide spills should be mixed with a large volume of vermiculite or sand. Cautiously transfer as above and burn. 3 A very small quantity of #1 or #2 may be destroyed by adding 10 vol umes of 20% NaOH. After 24 hours, neutralize* and pass into drain with large excess of water. Examples. Acetyl peroxide Benzoyl peroxide Butyl hydroperoxide Tert.-butyl peracetate Tert.-butyl perbenzoate Butyl peroxy pivalate Cumene hydro peroxide 3,4-dichlorobenzoyl peroxide Dibutyl peroxide Diisopropyl peroxy dicarbonate Lauroyl peroxide Methyl ethyl ketone peroxide Spills: Eliminate all sources of ignition. 1 Liquid peroxide spills may be ab sorbed in large quantity of vermiculite or sand. Using a soft plastic scoop, carefully place the mixture in a plastic container. Spread on a steel pan or in a deep pit. Ignite from a distance with an excelsior train or a long torch. Wash the scoop and container with 20% Package tots: Absorb or mix in small portions on ver miculite or sand. Wet down with 10% NaOH. Scoop up with plastic scoops and take to open-incinerator pit. When dry, ignite from a distance with an ex celsior train. CMA 045777 4ULFIDES, INORGANIC Wear: Package lots: Rubber gloves, safety glasses. Work in hood or wear self-contained breathing apparatus, laboratory coat. Add to a large volume of FeCI3 solution with stirring. Add more FeCI., if neces sary. Add soda ash with stirring until neutral. Scoop up and wash down the drain with excess water. Eliminate all sources of ignition. Add peCIs solution. Stir until FeS formation is complete. Add slight excess of soda aSh. Scoop up and wash into drain with excess water. Wash site with soap solution. Note: If a gas (e.g., H^S), seal the cylin der and return to supplier. If a per manent leak, place the cylinder upside down in a tank of FeCI:j solution and treat as above. 23 Examples Ammonium sulfide Calcium sulfide Hydrogen sulfide Ammonium polysulfide Potassium sulfide Sodium sulfide CMA 045778 24a ACIDS, ORGANIC (Limited to C, H, and 0 Compositions) Wear: Rubber gloves, face shield, laboratory coat. Body shield and self-contained breathing apparatus should be avail able. Spills : Eliminate all sources of ignition. 1 If acid is volatile (e.g., CH3 COOH, etc.) spray atmosphere with 6M-NH4OH. Cover contaminated surfaces with soda ash. Mix and add water if necessary. Scoop up slurry and wash neutral* waste down drain with excess water. Wash site with soda ash solution. 2 If acid is a non-volatile liquid or Package tots: (CHOICE OF PROCEDURES) 1 Liquid acid may be injected at base of incinerator or after mixing with a flammable solvent. Afterburner is suggested for complete combustion. 2 A solid acid may be dissolved in a flammable solvent and burned as above. 3 Solid acid may be packaged in paper or other flammable material and burned in an incinerator. Examples Acetic acid Acetic anhydride Acrylic acid Benzoic acid m-Butyric acid iso-Butyric acid Butyric anhydride Caproic acid Citraconic anhydride Citric acid Formic acid Fumaric acid Gallic acid Glutaric anhydride Glycolic acid Hydracrylic acid-B-lactone* Laurie acid Maleic acid Maleic anhydride Methacrylic acid Octanoic acid Oleic acid Oxalic acid Pimelic acid Propionic acid Pyrogallic acid Pyruvic acid Salicylic acid Stearic acid Succinic acid Succinic anhydride Tannic acid Valeric Acid CMA 045779 ACIDS, inorganic Rubber gloves, self contained breath ing apparatus, laboratory coat. Have body shield available. 1 If a volatile acid (e.g., HCl, HBr, etc.) spray the atmosphere with 6M-NH4OH. Cover the contaminated surface with a soda ash and slaked lime mixture (50-50). Mix and add water if necessary to form a slurry. Scoop up slurry and wash down the drain with excess water. Wash site with soda ash solution. 2 If a non-volatile liquid or solid, cover with a mixture of soda ash and slaked lime. Mix and add water. Scoop up slurry and wash down drain with excess water. Package lots: Add slowly to large volume of agitated solution of soda ash and slaked lime. Add neutralized solution to excess run ning water. As an added precaution, the sink can be lined with protective matting and filled with coarse chipped marble. 24b Examples: Boric acid Boron oxide Fluoroboric acid Fluorosilicic acid Hydriodic acid Hydrobromic acid Hydrochloric acid Hydrofluoric acid Iodic acid Mixed acids Nitric acid Phosphoric acid Phosphoric anhydride Sulfonic acids Sulfuric acid Sulfur trioxide CMA 045780 DISPOSAL PROCEDURE CARBIDES Rubber gloves, safety glasses, labora tory coat. Eliminate all sources of ignition. Sweep onto paper. Place in an iron pan in the hood. Spray slowly with water from an atomizer until the reaction is com pleted. Burn the hydrocarbon gas by using a lighted burner as a pilot flame. Wash the residue down the drain with excess water. Add slowly to a large container of water and burn off the hydrocarbon gas with a pilot flame as above. Allow precipi tate to settle. Siphon off the liquid into the drain with excess water. Transfer the precipitate to the landfill. Aluminum carbide Calcium carbide PAGE 158--DISPOSAL PROCEDURE 25 CARBIDES CMA 045781 DISPOSAL PROCEDURE WASTES to be dumped into landfills or released to air Heavy work gloves, safety glasses. properly assembled waste ready for pick-up trucks may be used as fill in reclaiming low areas or may be dumped into a landfill. Examples; Asphalt Batteries, dry cel) Boron Bromochloromethane Bromoform Calcium carbonate Carbon black Chlorobromomethane Chloroform Crude lime Dichlorodifluoromethane Dichloromethane Ferrosilicon Fluorotrichloromethane Helium Hydrogen Lamp bulbs Latex Molybdenum, insoluble compounds Neon Nitrogen Nitrogen fertilizers Nitrogen trioxide Octafluorocyc lobutane Osmium tetroxide Oxygen Ozone Paint Pyrethrum Resins Rubber Scrap glass Scrap metal Scrap stoneware Silica Sludges Stone, alberine Sulfur Tar Tetrabromoethane 1, 1,1, 2-Tetrachloro-2, 2-difluoroethane 1,1, 2, 2-Tetrachloro-l, 2-difluoroethane Tetramethyl silane Transite Titanium oxide Tremolite 1,1,1-Trichloroethane 1,1, 2-Trichloro-l, 2, 2-trifluoroethane Trifluoromethane Urea Zinc oxide Zirconium-hafnium powders CMA 045782 27a Scrap metal in the f rm f sheets, rods, wire, tubes Wear.- Heavy gloves, safety glasses, laboratory coat. 1 Larger pieces of less expensive metals can be salvaged profitably for use in local shops, or can be sold as scrap metal--e.g., aluminum, copper, brass. 2 The more expensive metals are worth salvaging, even in small pieces-- e.g., platinum wire, silver foil. Metal should be sorted, classified, and placed in boxes, properly labelled. Turnings, shot, cuttings of the cheaper metals may be assigned to landfill. (See 27.) Examples: Sheet, rods, wire, tubes, foil, etc. Aluminum Brass Bronze Cadmium Cobalt Copper Gold Lead Magnesium Manganese Molybdenum Nickel Paladium Platinum Rhodium Silver Steel, carbon Steel, stainless Tantalum Tin Titanium Zinc CMA 045783 .DISPOSAL PROCEDURE RECOVERY*-MERCURY Rubber gloves, self-contained breath ing apparatus, laboratory coat. CAUTION: The toxicity of mercury is such that the element and its com pounds should not be allowed to con taminate air or water. * m procedures 27b to 27m, recovery is essential because of high toxicity of all elements and com pounds--e.g. the American Conference of Govern mental Industrial Hygienists' threshold limit values (1968) expressed as mg/M3 (milligrams per meter cubed) for mercury = 0.1, for arsenic = 0.5, anti mony = 0.5, selenium = 0.2, beryllium 0.002, lead 0.2, cadmium 0.2, barium 0.5, uranium 0.05, vanadium 0.1--as opposed to hydrogen cyanide 11, and hydrogen sulfide 15. Spills and package lots.- Metal--Collect all droplets and pools at once by means of suction pump and aspirator bottle with a long capillary tube. Cover fine droplets in nonaccessible cracks with calcium poly sulfide and excess sulfur. Combine all contaminated mercury in a tightly stoppered bottle. Hold it for purifica tion or sale. Compounds--Dissolve all water soluble contaminated compounds. Convert other contaminated compounds to the soluble nitrates. Adjust the acidity and precipitate as mercuric sulfide. Wash and dry the precipitate. Ship to the supplier. Examples Mercury Mercurous nitrate and chloride Mercuric nitrate, chloride and thiocyanate Organic mercury compounds Mercury fulminate COVERY*--MERCURY DISPOSAL PROCEDURE 27b--PAGE 161 CMA 045784 Wear: Rubber gloves, large face shield. PHOSPHORUS YELLOW AND RED YELLOW PHOSPHORUS Spills : Cover with wet sand. Spray with water to Keep sand wet. Scoop into a bucket of water. After standing overnight, re cover and repackage. OR If quantity is very small (e.g., frag ments of sticks of yellow phosphorus), cover with water and remove to an open area. Pour onto the ground or a steel pan. The water will evaporate and dry yellow phosphorus will ignite spontane ously in air and burn away. RED PHOSPHORUS SpillS: Sweep up and burn on an iron pan in the hood. Defective package: Repackage and return to the shelf--or to the supplier. Defective package: Submerge defective package in a large CMA 045785 --ARSENIC, ANTIMONY AND BISMUTH* Rubber gloves, safety glasses, respira tor, laboratory coat. Work in fume hood. Dissolve in minimum hydrochloric acid (concentrated, reagent). Filter if neces sary. Dilute with water until white pre cipitates form (SbOCI and BiOCI). Add just enough 6M-MCI to redissolve. Saturate with hydrogen sulfide. Filter, wash the precipitate, dry, package and ship to the supplier. OR If the waste is of very little value, use Procedure 11. Examples: Metals (arsenic, antimony and bismuth) Arsenic trichloride Arsenic acid Arsenic trioxide Arsenous acid Calcium arsenate Lead arsenate Nitrates and chlorides of arsenic, antimony and bismuth Antimony pentasulfide Antimony trioxide * Although bismuth is much less toxic than arsenic or antimony it is included here because the recov ery procedure is similar, RECOVERY--ARSENIC, ANTIMONY AND BISMUTH* DISPOSAL PROCEDURE 27d--PAGE 163 CMA 045786 --SELENIUM AND TELLURIUM Wear: Rubber gloves, safety glasses, respira tor (or work in hood), laboratory coat. Spills: Absorb on paper and place in wide mouth stoppered bottle for later recov ery, Wash site with soap solution. Package lots and recovered spills: Liquid or solid--Make a solution strongly acidic with hydrochloric acid. Slowly add sodium sulfite to the cold solution with stirring, thus producing sulfur dioxide, the reducer. Upon heating dark grey selenium and black tellurium form. Let stand over night. Filter and dry. Ship to supplier. Examples: Selenium oxides Selenium tetrachloride Selenium oxychloride Selenium hexafluoride Tellurium oxides Tellurium hexafluoride PAGE 164--DISPOSAL PROCEDURE 27e RECOVERY--SELENIUM AND TELLURIUM CMA 045787 I rECOVERY0LEAD and cadmium compounds 27f tor (or work in hood). 4 Convert to nitrates with a minimum of nitric acid (concentrated, reagent). Evaporate in a fume hood to a thin paste. Add about 500 ml. water and saturate with hydrogen sulfide. Filter, wash, and dry the precipitate. Package and ship to the supplier. OR If the waste is of small volume, use Procedure 11. Lead salts Cadmium oxide Cadmium salts CMA 045788 27g Wear.- Rubber gloves, self-contained respira tor, laboratory coat (wash after each job). Spills: Absorb on paper towels and place in large stoppered wide-mouth bottle. Save for recovery. Wash site with soap solution. BERYLLIUM COMPOUNDS Package lots and recovered spills: Dissolve in minimum of 6M-HCI. Filter and treat filtrate with slight excess of 6M-NH4OH (use litmus). Boil and allow coagulated precipitate to settle for about 12 hours. Filter and dry. Pack age and ship to the supplier. Examples; Beryllium salts F \ \ I I \ ! l I PAGE 166--DISPOSAL PROCEDURE 27g RECOVERY--BERYLLIUM COMPOUNDS CMA 045789 DISPOSAL PROCEDURE RECOVERY-STRONTIUM AND 0BARIUM COMPOUNDS Rubber gloves, safety glasses, labora tory coat. Package lots and recovered spills: Dissolve waste in 6M-HCI and filter. Neutralize the filtrate with 6M-NH4OH (use litmus) and precipitate with ex cess sodium carbonate. Filter, wash, and dry the precipitate. Package and ship to the supplier. OR If the waste is of small volume, use Procedure 11. Examples: Oxides and salts of strontium and barium RECOVERY--STRONTIUM AND BARIUM COMPOUNDS DISPOSAL PROCEDURE 27h--PAGE 167 CMA 045790 -VANADIUM COMPOUNDS Wear: Rubber gloves, large face shield, labo ratory coat. (Wear self-contained respi rator if spill is large.) Spills. Cover with powdered ammonium car bonate. Add a layer of crushed ice and spray with 6M-NH4OH while stirring. Scoop slurry into a wide mouth bottle, save for salvage. Wash site with soap water. Package lots: (Work in a fume hood). Add (e.g,, VOCI3) slowly to a thick layer of powdered ammonium carbo nate in a large evaporating dish. Spray with 6M-NH4OH while stirring. Add a layer of crushed ice and continue stir ring and spraying. Add more 6M-NH4OH if necessary. May add more waste va nadium compound with stirring. Pour into large beaker and let stand over night. Filter off the crude ammonium vanadate, dry and package for shipment Examples. Vanadium oxides Vanadium chlorides Vanadium oxychlorides Vanadium sulfates Sodium vanadate CMA 045791 DISPOSAL PROCEDURE RECOVERY- ^barbon Tetrachloride, Carbon Tetrabromide and Phosgene* Rubber gloves, self-contained respira tor (or work in hood), laboratory coat. Absorb on paper towels and allow to evaporate in the fume hood. Burn the paper. Wash site with soap solution. The toxic liquid compounds concerned here are insoluble in water and cannot be burned. Purify the contaminated liquids by distillation and place the pure distillate back on the shelf. 0R Return to the supplier, Carbon tetrachloride Carbon tetrabromide Phosgene * The phosgene container should be sealed and re turned to the supplier. If the cylinder has devel* oped a permanent leak it may be necessary to dissipate the leak in a strong-draft fume hood. The supplier may be called to cap the cylinder and haul it away. ^^COVERY--CARBON TETRACHLORIDE, CARBON TETRABROMIDE AND PHOSGENE* DISPOSAL PROCEDURE 27j-PAGE 169 CMA 045792 27k The elements and their compounds listed below should be dealt with sepa rately. If the quantity justifies recovery get in touch with the supplier for spe cial instructions. * These materials as well as all other naturally radioactive materials, elements or substances must be disposed of in accordance with regulations of the U.S. Atomic Energy Commission or those of the local or state departments of health. This may usually be done by turning them over to the radiation safety officer or a commercial disposal agency handling radioactive materials. RECOVERY-MISCELLANEOUS Examples: Erbium Gadolinium Gallium Germanium Germanium dioxide Hafnium Holmium Indium Lanthanum Lutecium Niobium Osmium Osmium oxide Praseodymium Radium* Radon* Rubidium Ruthenium Samarium Terbium Thallium Thallous sulfate Thorium* Uranium* PAGE 170--DISPOSAL PROCEDURE--27k RECOVERY--MISCELLANEOUS . > ! CMA 045793 DEEP burial Heavy leather gloves, heavy full-face shield, laboratory coat. Examples Cellulose nitrate Celluloid Collodion Eliminate all sources of ignition. Cover spills with vermiculite and scoop into paper boxes. Transport packaged spills and other package lots to a very deep pit or well (at least 20 feet deep). Cover with a layer of pulverized limestone, followed by earth fill. OR For small quantities use Procedure 29. 28 CMA 045794 ! DIRECT BURNING Wear: Heavy leather gloves, safety glasses. Disposal: Materials should be properly packed for safe handling, and placed in a pre scribed site for daily pick-up. Burning can be done in an open or closed incin erator with afterburners. Examples Materials: Biological wastes--animal remains, bedding, feed wastes Clothing, discarded or contaminated Excelsior Paper wastes, packing boxes, etc. Wood scraps, packing boxes, etc. Bags, paper and cloth CMA 045795 f SECTION VII.------------------------------------------------------------------ j i Disposal Materials--Minimum Requirements { (a) CHEMICALS Acetone, waste (2 gal.) Alcohol, butyl (2 gal.) | Alcohol, denatured (waste) (2 gal.) j `Ammonium hydroxide (concentrated, Reagent) (2 liters) j Ammonium hydroxide (6M) (4 liters) J Ammonium carbonate (2 x 1 lb.) Benzene, waste (2 gal.) 1 Calcium hypochlorite (2 x lb.) i "Calcium polysulfide (2 x 1 liter) * Excelsior (box) Fuels -- scrap wood ( paper ! organic flammable solvents Ferrous sulfate (2 x 1 lb.) Ferrous sulfate, 30% (4x1 liter) {Ferric chloride (2x1 lb.) Graphite powder (5 lb.) Hydrochloric acid (concentrated, Reagent) (2 liters) I "`Hydrochloric acid, (6M) (4 liters) Hydrogen sulfide (small cylinder) * Ice, chipped v Kaolin (2 x 5 lb.) Kaolin -- Soda ash (50-50) (2 x 5 lb.) >i Limestone, pulverized (2x5 lb.) Litmus paper, red and blue (1 doz. vials each) Marble chips (2x5 lb.) Nitric acid (centrated, Reagent) (2 liters) Paper boxes, waste Potassium iodide, 10% (peroxide test) Sand, dry (2x10 lb.) Sand-Soda ash (90-10) (2 x 10 lb.) Slaked lime (2x5 lb.) Soap powder (6x1 lb.) Soda ash (2x5 lb.) Soda ash-Slaked lime (50-50) (2 x 10 lb.) Sodium hydroxide, 10% (4 liters) Sodium hydroxide, 20% (4 liters) Sodium bisulfite (5 lb.) Sodium sulfite (5 lb.) Sodium thiosulfate (hypo) (2x5 lb.) Sulfur, sublimed (2x 1 lb.) Sulfuric acid (concentrated, Reagent) (2 liters) ""Sulfuric acid (3M) (4 liters) Towels, paper (1 doz. rolls) Vermiculite (10 lb.) `Requires approximately 400 ml. of concentrated reagent grade NH4OH per liter of solution. "Saturate one liter of concentrated lime water with hydrogen sulfide. Add excess sublimed sulfur. Shake. Requires 5X6 ml. of concentrated HCI per liter of solution. ****336 ml. of concentrated reagent HSO per liter of solution. (See over for EQUIPMENT listing) CMA 045796 SECTION VII continued Disposal Materials--Minimum Requirements (b) EQUIPMENT Aspirator bottle (mercury collector) (2) Atomizer spray bottle (2) Beakers, 3 or 4 liter size (2) Brush, hand (6) Brush, small paint Bucket, plastic (3 gal.) Burners, Bunsen Condenser, Liebig Dish, evaporating, 12" (2) Extinguisher (Class D fires) (10 lb. size) Extinguisher (CO-) (10 lb. size) Flask, Distilling -- 1 liter (2) Gloves, heavy work Gloves, leather Gloves, neoprene Gloves, butyl rubber Iron pan (for fume hood) (approx. 18" x 24") Laboratory coat, cloth Laboratory coat, plastic Matting, open mesh, rubber, to fit sink Mop and bucket Pipettes 10 ml. (peroxide test) (4) Respirator, canisters (1 of each) Respirator (self-contained breathing apparatus) Safety glasses or goggles (2 prs.) Scoop, plastic Shield, body Shield, face, large and heavy, 0.050", to cover ears and neck Spray jar (insecticide type), stainless steel Suction pump (mercury collector) Tank (oil drum, 55 gal.) Tools -- hammer pliers wrench, crescent screwdrivers Water-vac CMA 045797 SECTION VIII BIBLIOGRAPHY IA--"Nitroparaffins and their hazards," Report #12, and "Chemical Hazards Bulletin," American Insurance Association, 85 John St., New York, N.Y. 10038 ACGIH--"Threshold Limit Values," American Conference of Govern mental Industrial Hygienists, 1014 Broadway, Cincinnati, Ohio 45202 ASTM--"Fire and Explosion Hazards of Peroxy Compounds," Tech, Bui. #394, American Society for Testing and Materials, 1916 Race St,, Philadelphia, Pa. 19103 Audrieth, L. F. & Ogg, B.A.---"The Chemistry of Hydrazine," John Wiley & Sons Inc., 605 3rd Ave., New York, N.Y, 10016 BDH--'"Spillages of Hazardous Chemicals," British Drug Houses Ltd., Poole, Dorset, England. Also available from Gallard-Schlesinger Chemical Mfg, Corp., 584 Mineola Ave., Carle Place, Long Island, New York, N.Y. 11514 or from British Drug Houses (Canada) Ltd., Barclay Ave., Toronto 18, Ontario, Canada Brookes and Alyea--"Poisons," Van Nostrand Reinhold Company, 430 Park Avenue, New York, N.Y. 10022 Campbell, Neil--"Schmidts Organic Chemistry," Oliver and Boyd Ltd., Edinburgh, Scotland CGA--"Safe Handling of Compressed Gases" Pamphlet P-1, Com pressed Gas Association Inc., 500 5th Ave., New York, N.Y. 10036 Cloyd, D. R. & Murphy, W. J.--"Handling Hazardous Materials--N.A.S.A. SP-5032," National Aeronautics and Space Administration, Washing ton, D. C. 20546 Elkins, H. B.--"Chemistry of Industrial Toxicology," 1963, John Wiley & Sons, 605 3rd Ave., New York, N.Y. 10016 Fairhall, L. T.--"Industrial Toxicology," Williams and Wilkins. Balti more, Md. Gaston, p. J.--"The care, handling and disposal of dangerous chem icals," 1965, Institute of Science Technology, Northern Publishers (Aberdeen Ltd.), Aberdeen, Scotland Gonzales, Vance, Helpern--"Legal Medicine and Toxicology," 1940, Appleton-Century Trade Books, 250 Park Ave., New York, N.Y. 10017 Hurd--"Chemistry of Hydrides," 1952, John Wiiey & Sons, Inc., 605 3rd Ave., New York, N.Y. 10016 IBM--"Freon" solvent data book, IBM Corp., Yorktown Heights, New York 10598 Kirk & Othmer--"Encyclopedia of Chemical Technology," Vol. 8, p.489 2nd Ed,, Wiley-lnterscience, 605 3rd Ave., New York, N.Y. 10016 Los Angeles Fire Dept.--"Dangerous Chemicals Code," 1951, Parker & Son, Inc., Los Angeles, Calif. McElroy, F. E.--"Accident Prevention Manual tor Industrial Operations," 5th Ed,, National Safety Council, 425 No. Michigan Ave., Chicago, III. 60611 MCA--"Chemical Safety Data Sheets," "Safety Guides" and "ChemCard Manual," Manufacturing Chemists Association, 1825 Connecti cut Ave., Washington, D. C. 20009 PAGE 175 CMA 045798 MGB-See Matheson. Matheson--"Gas Data Book," The Matheson Co., Inc., P.O. Box 85, East Rutherford, N.J. 07073 Matheson, Coleman & Bell--"Safety Procedures: Laboratory Chemical Catalog," pp. 9-31, Matheson, Coleman & Bell, 2909 Highland Ave., Norwood, Ohio 45212 N.F.P.A.--No. 49, "Hazardous Chemicals Data"; No. 325, "Fire Hazard Properties Of Flammable Liquids, Gases and Volatile Solids"; No. 491, "Manual of Hazardous Chemical Reactions"; No. 704M, "Fire Hazards of Materials," National Fire Protection Association, 60 Batterymarch St., Boston, Mass. 02110 Nat'l Research Council--"Evaluation of the Hazard of Bulk Water Transportation of Industrial Chemicals," 1966, National Academy of Science, 2101 Constitution Ave., N.W., Washington, D. C. 20418 Nicholson, H. Page--"Pesticide Pollution Control," Science 158, 871 (Nov. 17, 1967) Noller, D. C. & Bolton, D. F.--"Safe Handling and Storage of Organic Peroxides in the Laboratory," Anal. Chem. 35, 887 (June 1963). NSC--"Chemical Safety References," National Safety News 97, 47 (Apr. 1968). and "Industrial Safety Data Sheets," National Safety Council, 425 No. Michigan Avenue, Chicago, III. 60611 NTTC--"Commodity and Equipment Data Sheets," National Tank Truck Carriers, Inc., 1616 P St., N.W., Washington, D. C. 20006 O'Brien, Richard D.--"Toxic Phosphorous Esters," 1960, Academic Press Inc., Ill 5th Ave., New York, N.Y. 10003 Patty, Frank A.--"Industrial Hygiene and Toxicology," Vol. II, 1963, Wiley-lnterscience, 605 3rd Ave,, New York, N.Y, 10016 Pennsylvania Department of Health--"Short Term Limits tor Exposure to Airborne Contaminants," "Hygienic Information Guides," "Indus trial Waste Manual," Division of Sanitary Engineering, Harrisburg, Pa. PAGE 176 Pennsylvania Department of Revenue--"Highway Transportation 0f Hazardous Substances," 1968, Hazardous Substances Transportation Board, Harrisburg, Pa. 17127 Remy, H.--"Treatise on Inorganic Chemistry," Vol. I & II, 1956, Ameri. can Elsevier Publishing Co., 52 Vanderbilt Ave., New York, N.Y. 10017 Ross, R. D.--"industrial Waste Disposal," Van Nostrand Reinhold Com. pany, 430 Park Avenue, New York, N.Y. 10022 Sax, N. I.--"Dangerous Properties of Industrial Materials," 1963, Van Nostrand Reinhold Company, 430 Park Avenue, New York, N.Y. 10022 Sidgwick--"Chemical Elements and their Compounds," Vol. I & II, 1955 Oxford University Press, Inc., 200 Madison Ave., New York. N.Y 10016 Sittig, Marshall--"Sodium, its manufacture, properties and uses." 195^ Van Nostrand Reinhold Company, 430 Park Avenue, New York, N.Y 10022 ; Steere, N. V.--"Handbook of Laboratory Safety," Waste disposal pp 34-40, 1967, Chemical Rubber Co., 18901 Cranwood Parkway, Cleve- land, Ohio 44128 f j Voeglein, Joseph F.--"Storage and Disposal of Dangerous Chemicals," J J. Chem. Educ. 43, A151 (Feb. 1966) 'I Walsh, John--"Pollution--The Wake of the Torrey Canyon" (nevs comment), Science 160, 167 (April 12, 1968) | Weast, R. C. & Selby, S. M.--"Handbook of Chemistry and Physics," 1967, Chemical Rubber Co., 18901 Cranwood Parkway, Cleveland 1 Ohio 44128 'I World Health Organization--"Treatment and Disposal of Wastes," WHO * Tech. Report Series No. 367 (1967) | CMA 045799 >1 I i CMA 045800