Document x5dwXwvoNab1889QLV0v20eNJ

ARX-OW BIODEGRADATION TEST SUBSTANCE Identity: Perfluorooctanesulfonylamido(ethyl)acetate; may also be referred to as PFOSAA, FC-128 or as the major component of FC-127, FC-129, FC-109, orFC-109-X. (Glycine, N-ethyl-N[(heptadecafluorooctyl)sulfonyl]-, potassium salt, CAS # 2 9 9 1 51-7) Remarks: The test sample is FC-109-X. Current information indicates it is a mixture of 19-23% test substance, 61% water, 12% 2methoxymethylethoxypropanol, 2% ethanol, and 2-6% C 4 -C 7 fluoroalkyl carboxylate compounds. Test sample was from 3M production lot 2. The following summary is abbreviated because the test sample is a mixture of the test substance in a water/organic solvent solution. Data will not accurately relate biodegradation of the test sample with that of the test substance. METHOD: Method: Not noted. Type: Aerobic Carbonaceous BOD with Dichromate reflux determination of COD GLP: No Year completed: 1987 Contact time: 20 days Innoculum: Not noted RESULTS Chemical Oxygen Demand: 375,000 mg O2 / kg product Biochemical Oxygen Demand: 5-Day: 31,000 mg/L 10-Day: 61,000 mg/L 20-Day: 69,000 mg/L Remarks: The BOD and COD values are expected to be the result of biodegradation of the organic solvent components of the test sample. These values are not expected to be representative of the Perfluorooctanesulfonylamido(ethyl)acetate. CONCLUSIONS OOO 2,30 This testing indicated that some portion of the test sample biodegraded in aerobic environments capable of supporting biodegradation. Submitter: 3M Company, Environmental Laboratory, P.O. Box 33331, St. Paul, Minnesota, 55133 DATA QUALITY Reliability: Klimisch ranking 3. This study lacks information on the methodology, characterization of the test substance purity and analytical measurement of test concentrations. Testing cannot conclude what portions of the test sample were responsible for the apparent biodegradation values. REFERENCES This study was conducted by Pace Incorporated of Minneapolis, MN at the request of 3M Company, Lab Request number E2113,12/31/87. OTHER Last changed: 5/18/00 000231 05/17/2000 ENVIRONMENTAL LABORATORY ARCHIVED FINAL REPORT 1 LAB REQUEST NO. E2113 REQUESTOR NAME: EAR/MTE DEPARTMENT: 0535 PROJECT NO: 9970013000 DATE RECEIVED: 09/15/1987 DESC: FC-109-X ENVIRONMENTAL SCREENS CONTRACT LAB(S): PACE EXP COMP DATE: 12/31/1987 DATE COMPLETED: 12/31/1987 PROJECT LEAD: SA BEACH PHONE NO: 651-778-7452 3M FAX NO: 651-778-6176 41-2601-0414-0 LOT 2 SAMPLE(S) SENT TO ABC LABS FOR FISH AND DAPHNIA WORK * SEE LR# E2566. SAMPLE DATE CODE DESCRIPTION RESULT MDL or (95% C.I.) 1 FC-109-X ......... PACE PACE PACE PACE PACE 96-HR-LC50 FISH ACUTE TEST - 96 HOUR C-BOD-05 *BOD-05 (CARBONACEOUS) C-BOD-10 *BOD-10 (CARBONACEOUS) C-BOD-20 *BOD-20 (CARBONACEOUS) COD-RFX *COD (DICHROMATE REFLUX) MICROTOX MICROTOX - EC50 REP-INORG *INORGANIC TESTS REPORT SLUDG-RESP SLUDGE RESPIRATION - EC50 2 DUP OF #1 PACE COD-RFX *COD (DICHROMATE REFLUX) SEE COMMENT ABOVE 31000 MG/KG 61000 MG/KG 69000 MG/KG 360000 MG/KG COMPLETE SEE ATTACHED REPORT COMPLETE 390000 MG/KG 0(30232