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KARST INFLUENCE IN THE CREATION OF A PFC MEGAPLUME
VMiinrngeisnoitaaDYeipnargtlmienngt of Health, 625 Robert Src . St. Paul, MN. 55155, USA, virginia yingling@sate nn us
Abstract cPehrefmliucoarlosuhsneidcatlosp(rPoFduCc)ereafwuildley ruaonigenaotfedinccrugsainacl aanndd mcoombmielrciianlthperoednuvcitrso.nmTehnetiranedxinreeamrsly puebrisqiusitteonucse pcroensceenmces irnegahrudmianngs thaenidr wenivlidroenmehnatsalraiasnedd sheurimoauns wceareldliess.poIonfihsneteh1rd9e4e0u3nl0in1e9d70as,nPdFCs-bienarWiansghiwnagstleosn Comny, Mimnesot. The resuling co-mingled PFC p2l5u0mKeisncroefatgerdouand"wmaetgearplaunmde"foutrhamtajcoorntdarmiinnkaitnegdwaotveerr aaqnudifetrsh:ouascantdisn ofcigphrtivmateuwnellis.wcatSieitrepsuaipnplsltyigsaytsitoenmss rdeuveaClheidenthaGtroKuarpt (fOeaPtDuCr)es,, pnardticuglraorlwyndiwnattehre-sPurraiiciec mwiagtreartiionnt.eractions played a critical fle in conminant Introduction PoregrafnliucorcohcehmeimciaclaslsthPaEtChsa)veabreeeacnhussseodftoflpl-rflouodraiunwaciideeed range of industrial and commercial products, Their neexarrelymeupbiequritosusipsraetnsdeemncnbe ciinethuimntahneseannvdirwoinlmdleinfte ahnads isd serious concems regarding thei environmental aal.nd2h0e0a3;lthAeTfSfDeRt.s (2G00i9e)y. aAnsdaKeansnlan,in2020020:6,OtbheenE,PoAf. amounced it would sek the phasing out of production and mostusesof two PECs, prflvoro-octane sulfonate (PFOS) and peluarooctanare acid (PFOA). SM Corporation (3M) researched and produced PthFeCs1i9n4C0ostt1a0ge1G97r0osv,e, PMFCN-bseianrceintghew1a9s4i0se.s Fwreorme disposed ofa the 3M Cotiage Grove facility and in t(hArTeeSDuRn,li2n0e0d8)l.anAdlflilolsftihnesWeassihtiensgwieorne Cionuvnetsyti,gaMteNd for industrial solvent contamination in the 1980s aopnedraihiangd. acItnive200g3r.ou3ndMwatneotrifieexdtratchteionMinsnyesstoetmas Pollution Control Agency (MPCA) that PFCs had been detceied in the drinking and production water at the Cottage Grove plant.
"The MPCA and Mimesoa DepartmenofHeall (DH) bfoergaPnFCesstiinng 2W0a0s3h.inTghtiosnwCoorukntcyvenpuuballilcynddelpriicvaatteewtehlrlese 2ma5j0orknc?o-omfinggrloeudndPwFaCterplinufsourthmaajcoornadmriinnkaiingd-voavteerr aaqnudiftehrosusaafnfdecstoifnpgrciivgahttewmeulnisc(iYpianvglaiinegr. suaplpl2y0s1y)s.icms nliimiatled,grdoiusncdreweatterPFfClowplmuomdeeslin(gBurprredEincgtiednermionr,e g20r0o5)u.nd1wwaatseralsdiovideatshstubmiesdectthsattha cnoourntthy-swouotuhldtraegnedilnyg HliomwietvePrF,C fcurolnhaemriinnavteisotnigattoiontherevweeasletd.ofgrtohuenddwiavtideer sfueraftaucrees wiantaerkeiyntbreadcrioocnksaqaunidferthcereiantfelduewnncaenioifpakatresdt patiwaysfo contaminant migration. CHoyudnrtoygeology of Southern Washington eSdoguetoifetmheWTawsihniCnigtiiaens CBaosuinntayndiissluoncdaetreldaoinnbhyehecalsoiweemr Palooiesedimentary seqtypiucaloefthneHolclandeale gElmacbiaalymderinft, acnodvearleldovbiyom3 (--Fig3u0rem1)o.f Ruenaccotnisvoaltiiodnateodf Proterozoic fulssometime aftr the MiddleOrdovician rbleoscukfeadultinswliatrghe-vsecratliec,alodrihseplaasc-esmoenwtiwoefsutp ttore4n5dinmg andsssociated subperpenadndiscubupalraallrljoining (Figure 2: Mosler and Bloomgren. 1990; Mossler and Tipping. 2009. Four major aquifers provide the majority of drinking wSia.tePretfeorr Scaonmdsmtuonniety(OaSnTdP),priPvraatieriewellas CihnietnheGraorucp (OPDC), Jordan Sandstone (CJDN), and Tun City sGerpoaurpate(dCTbCyG;lowfeorrmeprelnymeatbhieltFyranlcaoyneiras).orAl"tlheoakusg"h abqeutiween (thae iCnItDheNcaasned oCfhTCeG),Si. bLedarworckiefau(lCsSTanLd vtheemsiecalayejrosi,ntpsarilcuelarlcyomipnrtohmeisseoduhtehem aindmciaseronf mst portions of the coun. Thi, in pan, ccounis for hydraulic communication betwee the quer.
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figure 1. Generalied stofigraphic column or
Stofipstihheroegrrno.oundRdwuantkeierlfnltowsl.vwpi2t0hle0in70)t3hepoaOrmPtieDddCe booTcnrcsursostoamalet odolmueisiacnlwealglsedntehdediingyplofaLneakFeacEltmso ftnhatht iOPrDcC 1W0h1e0skri(d19o9 roipiOPeDCapein asseo.mlbwerveMceess owp cToopiwnigeotnal.Mi(n2n0s06o)tsepofoiveedrtbeaslhews wopbwseerrvdatFioornms tFhoenCuIsiDoNnatnodwdaorwndwsaHrTdZf,lowwilfhroomuthne dupp(elroSwhaiklopleee aaquwi at Ftarbor,on. wUpawsarTd ToGw ToSmothrIeON mWaosnhoirnigtnognwCeolulsnyai(oWeesoofn StohlutPioEnCs, dIinsg.po0s0al7)s.s in aTsiiofpestaolpo20n0ie6)rrnepogrFtchinucrassewdhepreeiuerShsackonpede
Fomatonis buriedess than60 mers late 0 tose in
WAreesnxtetiwpnogrkhodopofwCndosuptnoltyyth,eiMCiiIsssNeooattnooposvballlyeys,enwhlie ne`monomlrseagdeydepmlytbuurreisTea(dacreesad,sn.eItpcia)snaewlsoaeoxrpebgecustbedgsdtthatyasnodlutmaiaornneCcToL imn sommebupeletnsw,eipnrocvpideanratqteusiimsiocSonTf FpOiPDlCe, bouidontaalyt(heRruonskeielnl.w2e00s, of he row brid
CIDR. The valleys were once buts to. Uh oMissuissiippi,River, wSh.iCchrobounRdivstehr,ecwouinhtybotheosnosw1h0atnhd NPeFrCyPl2.u00m0epDubelli.inepartviio.n and. mniring wel cosisTfoorsveothvWrasrdetihngCfooorwnsrounddvarteer dacnorr. sinveso2u0t0,h WparsoviinnggondCeoawds saitvse! baeedn tseammppolreed S(oFhiggr2uounKdwwateerkendtClar,u1g990s, es ts coun dofelnetPiEnCsodftteeePdFCis pphearmlsa.crTohbeuamooisct awiidd,esPpFreBaAd Karst fats, partial in the OPDC, futher (foFifsgscx2.tePeFyBAoiwcsnwoaftlhee maosrtpmieobinlecPEcCs odus aclalnsdeorgrotaml d(v2a01t3e)r o1pd.r hceonOanmcionranFormomvaemnentth,e evxaesed(sKAs<a0l01.modTehleinxgipnredoifcttiohnsPFofBAthpeapnasnefasx lodwuenrgmtehmbe3rtoofSthmeilOlFoDnC,yowuedreenptoskritiWfcaasiosn (BaeroEunngidnveaereitngd,it2e0,09T,hiscowadsinigsroabseproendainotse FLotrmaptrieocnedKeadridfecpoasiiotinoonfiofbethSeakoovepreleyikngoSotcackuorpeeds _ dsriution other PECs (TSDR, 2008 ulroinvgia n15gmiOllSoTn?y(eVuohlieat,us2p0r0i8or. 10Asdeposeitilon ooff WRhoillleo maolsyt opfeathl cPEoCnscmeaprpnedangdesr- yigphpase0 oVloulncheadrceontdiuotns aevsentl, naldopresrwpeedircuof0wibtedldiin.g -sFoOeSoinstewOdudkeo-Lcikse wEillhofaemssdocdsowowngFruairosn ToefaheheOPcDCoanotpfiepeoSpertoavakideersmnusdhOorfeohes hmemdbelrs 3W.ashLionwtocnoCnocueryrnLsanfdiPmFoOnSitoarrieng.dewreeldaidn Ttee aColdousetiy or 145 bse ene wpe 4P3E1O)S plsaosrtddsiss dobevloew rR,ecHsowvese,s (r0e0s3
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SaonudtehxetrenWtaosfhiPnFgBtAocnoCnotunatmyi.nAarteiaiosnnwithout
shadingindicateno PFC S0MmPies OYE DREN
pSoouitsh"aonfd scoluetahrweedstPiR.OSdcoowncnengtrraatidoniosfn(dh-e)2 sgiel,)otin oprfitvhaetsewe"lhlost wseorte"dehansieadd.istAinkcot,iveth"eFipnlguemreinsg"opuaitsetm (sFiimapwlresc3o.manTiinsantsugagnesstpeodrtabry roebgeironf]acgtorrosunbedsviadters flow wer at work.
GRervoieuwnodfwtahte egrro-uSnudwraitearcseamWpalitnegrdaItantreesrcaacltediotnhsn all PFOS detections in Lake Emo private wells were lionceartemdiesno:usaencdamwesetmeorfRgaelseifgohmCraocsk iFsiguorfewe3t)laTnhdiss nar he 3M-Oskdae Disposal Sie, where high lvls oaftcPaFbOSle(s4i50e0.0 SiunLp)lihnavoef RbaeleeinghdeCtrecctkedinin20t0h6e decid concentaofiPoROnSs, PFOA, wd PFBA wp 10"B8otusnpoer"airn tLahkediEspmosoal(sTieSDanRd.up200053).iTLhecsaurrfatchee wdaeterredconicnenhtreatnieoanrsbycorprrevlaateedwecllolsselcyomtpolPiFeCd ilnevtehles OSa TOPPDC upto 55 miclow growd sufice.
seven 1955 and 1995, groundwater extracted from
thseoWnaoshirnogtnocnmCoounntvyasLaaiadn spar1dt0o2ftfvhetini ydustsl roimael oCviecre.k pTpuriovsiemwaecrlyul2ikmnalmyordisocfhaErgxees tPooiRnalLeaikgeh (3F5igkuereP4F)OMADwHreedsiscturmieosdrmeoathtahnte4ce5r0eckskgdPurFiBnAgatnhids inc (ATSDR, 2006)
r-o10cu proionut eLiaketieasn,d LwahkoereEgmroounardevacchrssrifeecdgaes
and discharge occur in differen parts of the lakes
(Washinglon County, 2014). Groundwater discharges
(0 Eaglo e Poinm t Lake vfevromethesnoorth and wreocharsgeis nbaeck Gouna sso diciures to Like Fino fom the or an rechges back to the groundvaer ear the costandsoueas shorn
oHviesrofrlcowaeld,tdurring soflrooeduosfawgee,tlahEnadgsleto PLoaikne ELlaok,e
on the cast side of the groundwater divide. To control flooding ofLake Elmoa,pipeline was construcied from Eagle Point Lake to Horseshoe Lake.
Lpaekce, yanedr LgaekeceElmnot.heAssawtietsh wRaelreigohf ECxrgeleek,Potihne
glarkoeunwdavtaeerrPsFaCmplceosnfcreormatnoensycOorPcDhCiewdelcllsos(eFliygur0e w3,ellTsabdleown1)g. raPdFiCnsth(avceaaslsotb-esnoodfueHtteocrhtseeedsahinoseOPLaDkCs (ascampolesnGcW-teasnainmditlSaWrr-f)oa. otssidetocetned in Laks Emo
"The PECdaa lutte the ivesgroundwater wsaptieerdefruartthieorntshawnhimcohdehleipngexpprleadiinc,teidn.paFrto,rheoxwamPpElCes PFCs discharge from the groundwater 3 te Onkdale fDilsopwosstaolwaSridethietcoitRyaolfeLiaghkeCrEomcok., Ti hrens,itaisonthsefcrroemcak gaining 10: losin scam ustcast of 1694), cinasg lcion-enairnsgoleicnegowfilPhFtChserPecFhCarggrionugnodwtahteergrpouhndewastoeurracnedd fom the Washingion County Landfill (Figure 4). At 1EoagtlheosPeoidnitsLcahkrei,nPgE1CtfherohmikRealferiognh tChreogcrkoaurnedwaadtedre,d rForuonmdwEaatgelre,PosilniLnikge,insohmee ParFeCasorfecchaorgme a10ntdhe wes south and souhvest of he lk, However, ome
emsmonos comemmct ccaimoons 321
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locations shown on Figure 3
Th romietanrd souo lake. Similarly, PFCs discharge from Horseshoe Lake to
[[ownf[sh 5 o iw s] ] The Role of Karst in PFC Migration
B[ J o o vJe Joroo J] or] GSmraiorrchmvoeernmimoevnvaderonriyndrbacciueotnimnsopoornoeirecoacmFohor
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himedemm eee Poin LakeandLake Elmo is unexpected,given the location hTiheespsarre10 CoPnEcCigaehrise eogcrvallgs, ilobg.isbwlanlhoefQiuhik1 dHepZoswi iAsnpohedOhcP,C
322 NCKHSIMPOHUMS 14THSINKHOLECONFERENCE
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b`eceonncenctorlaitcironesddetected insurface water. Ares without shading indicate no PFC samples have
ihheerdsentshietyShaankdopsespFeorrmatofiosnoisuobunr-iendlnegsedtnea60rms, tpoacelosc,altlyh hdeiaspdliacfertnhcegsraros awpepraredlivirdeetfrcomrn15
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srowdvater divide Figure 9)
ifnrokmarstt,hwghircdhiecnan(aTlilpowinf,or pleorswondalisccomomnucthaeiodni).r
AwSelolbtsheerivgeihdnhayqudifreirtcesctosnduacntdivfiltioewsmmeetesrsinegdininatshae mThiigsratmiaoyn oafloPFaCcscou(nltaotrethto aepplaroennt "swrpogmrnavdiaetne"r
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oairsewohrerfeacttuhreye.saTe hIsnuedpllesoconmceocniopdebayrsa a(rFsiriss03.leAsutgouretgi,onalPrCoSunadrvdatirceTdowfniwnedlil
S10caolcecyur sllons eGbomesoticoknsvbaleleeyse.nwhtihechQpUroIviTdeaabosvse 600m orthoftsbdo aly,
ain gbreliow otfhePOFncCotatoFormtaetioOnF.DTChisvaiallothwesfHoTrZ.piIdn Tphhaemesso(utFhivressr3s4n,i4ngndf)inmgaeyrilke bo easndfb atthieoePnFC
maocowtrnce cmos 323
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nKaersrt eineflduenrcoeuognhsloyn2a40midasnst.rTnhsi,i cTohnese"nTntgewrsi"h Tincament orien spor by Messer a Toping t(n2ee0a0s4p)ir.novIstiodseteeopmnrs-erneelannsiognaeab,plesituo bsaupsfpasoerctPjtoFhiCanttmhisigtgrshaetirionnf.tlhoi|ws STChoueumnmPaRClrsyiamtesitahieonpsoiinn t sofourbohirghlyWaschoimnpglteoxn caonrtalminyant fmoirgraitigonh ppaetrshivsn:inchKeamircaol.quWihisl,e rroouuninvdateerr smaomdpellien.g pbroovridoend unnidearstdanidricnigoanf hfoer
+reqeuxicreeeddsedamMeinnaesredmrionkhisngPFwCast,er sundads and
TCDhoiiosspecrlpauatbiilvimeceatArironsewnase sNuuppmoerrte,d TbSyI.-Lt4h0e5,GraTntator by the Centers for Discse Control and Prvenion a(uCtDhCo)r. aItnscddoonottaerneencseostlseasrliylythererpersepsoennstibitlhietyoofffitcihael vHiuemwasnoSfevthieesC,DC or the Deparment ofHealth and ARleefaendreernCcEe,s Runkel AC, Typing RG, Gesn JA.
ueSnrdametrilioyinnssg,beeadnnrddotchkefinideatrureos, gnrouaannnddodrwenaiootnreern-asutrifoincooeffwaaIrtse,rst,2F0U13MT.EaSDweie.pSDetoivcmategoorrliDaggiion,sonSosf ispninskhhoolert3co,lslcMapioose:nrne,s pafleluatmtue,rse,s,ssTwmhaainssyeraiotdfictahlseidtgorniianfckicicenaragnnwea}itmeprlicwaetVliiocnuostsagafocrdpnutblhiec t'MuNelCiKEdnRigIsicnSiepyelmripinonagrsyinuCdmonE2fPenrorcereneodcoinenlgSsionfIkthmhopleaesc13tatnohd PFC "hot spots" hat were not predict by modeling Ket 2005. Consbad. NA, p 288291
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3592.0006
STATE 02072450
ATSDRP.ru2o0r0o.chPuebnliicalHeClninaAnisnasiotnn Lak Ea nd Ose, Washington Cou isso.
Prepared by the Mimesoia Dept. ofHealth usr
rativaegreementwith the U.S. Department
OA riande man Seo r2ie, ATSDRn .Ang 30, 2008. [Cited 2015 Mar 2]. 173 p. Available online: ATSDRr. 2o09rbr.at TVoixsol20g0i.atCiPreofl0e1a4 Mc
9). 404 p. Available online: www.atsdr.gcodvc toxprofiles 200.pdf.
rca inh Enironmen. Enron Sei
Technol. 147-152.
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`SGweoalnoogincLA, Mely-eWrasaGh,idnisgoorn).CouCnotuyn,tyMAissso. Sruerse,,AUlnsiv:e,rsPofce5s. Mtin.eso1t.a GPaeuoll,oMgiNsl MossGkJeroJSlHo,gSBicloAoamrsenBWAi.sha i1n9g90o,n CBeodruonckMGeeosloogsy.in: SSioeev,e,AUlnaisveCr5s, PoflMsi2.mMesitss.o1. PGaelo,loMgNi.c
Moser Jii,vTaipnpinage2io2m0e0%a Glyiin ppoa rt of
`County. Informal mapsandgrids submited as
odHeelaitvmhe,rabncleessoartcoanhtPreaocMltlibamenotsCweoannDrheleUpAnaigrveemrnesinotnftyd i Watingonm County egos of Public Rea MosViieInres20.08MiRaInGSe:soPslGoersslcgiNnoSmueeyl,aRterpoosrct Ona.flm2e0s08tgaUtonnspSut PbaGul,SAiNa.ysershofeigdh mionepmoirisosnwsiof sosuotnhee(r1n1W2a)ssicnrgaopnpiCnoguncta,tions DeMpiimersmtean.toPfeHepalrteh,bdySt.BrPuace.OMeN, Mimsota OlinLGWu.nCdhJeKr. T2,00M.IKPErJT,orBsuroscaJe.uHalnseen K1J,d aRoldrrcore oatcuhleotd ndoneors,seEanmoofnAHmeerlia Pepect. 11 192-1901
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Nima Wises Gesogis Survey Report
Runkoef AICn:vesMtigoatisones. 6T1i. spin RG. 207 Ths LpSyadekreasEralvmogotrdaoppwhnhococlethlaoegrgtinneg aproiojteocoatnf:rfarioend og ton
Tipping RG, Runkel AC, Alexander EC, Alexander ireenJA. X Evidencefor hydraulic
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