Document x1qEnrOEd6gNaBLvzaqOB004E
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VM f:-* S B U -ll tU &n B
(Approved by U. S. Department of Labor. "Essentially Similar" to Form LSB-OOS-4J
FOR METAL CASTING SUPPLIES
N./A - Not applicable
UNK - Unknown
SECTION 1 - SOURCE AND NOMENCLATURE
UFACTU9ERS NAME
EMERGENCY TELEPHONE NO.
he- Hill and.Griffith Ccmpany
MESS [huhnii, stnkct, city, state, ZIP CODE)
262 State Avenue, Cincinnati, Ohio
45204
Area Code
513 Number 921--1075
CODE NO,, TRADE NAME, SYNONYMS
Zircon #1 Corg & Mold Wash
K.CALNAME AND SYNONYMS
I TI CMJI 4
R11g65S:1i1U1
MOCLoEmCUpLlAeRxFORMULA
HDCD USES [check khpkwhiaTK hksJ:
Binders (Curing)
Binders (Non-Curing)
Castables and Exothermics
Additives
Partings
Facings
others Refractory Coating
Metal Additives
EASR.1ACLOONRTAIIMNKGHREDIE_N_T"IN'P.RODUCT:
i
SECTION 2 - HAZARDOUS INGREDIENTS
.. OTESLSHVTAA(.BoSUT.SATNH)DEEABTRCB.
LD
ORAL.
SKIN
*-c,, INHALATION
SPECIES TESTED
i tAL (ONLY DUR1N6 US*):
oduct shipped in plastic or putty form.-
-t-csr lisp wf 11 be converted to- dry powier
rm. Consider refractories in same
assification as nuisance dust.
lOng/M-*
"
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SECTION 3 - PHYSICAL DATA
1 Point (F.) 3 Point (P.) (Give Method) c Gravity (Water = 1)
ENTIRE PRODUCT
2i2^F
>1
OR INGREDIENT (nAMS)
Water 32F - Water
ity in Water (Product) inks) ance (Product) Product)
100& water miscible
White/Soft DUttV Earthy/ sweet
Vapor Pressure (ramHgl
N/A
Vapor Density (Air = 1)
h/A
Evaporation Rate (
=1)
Volatile
% Vol.
Negligible (3 70F
Other:
fj/A % Wt.
SECTION 4 - FIRE AND EXPLOSION HAZARD DATA
757n?
d)
N/A
3f.
.CUISH1NG media:
FLAMMABLE EXPLOSIVE LIMITS
-C. Name: Entire product
None required in existing form.
L. nE FIGHTING PROCEDURES:
e required in existing form.
nv
-,i-=r
UNK
UHX
PLAINTIFF'S EXHIBIT
AL FIFE AND EXPLOSION HAZARDS!
2 recuired '_i sx-isr-i-no- -Fotti
II&G-2S
/-.re., KC>(*IRATOhT
Possible eye, skin & respiratory
NAMS TOXIC I.NCREDieNrs
Possible fumes from acrylic resin
OSSlBt- SYMPTOMS OF OVEREXPOSURE: (cxfiMICAt. NAME AND CO<*eS^ONOINC SVMrTOMs]
harmful if ingested
HRONIC effects:
JNK
MERGENCY AND FIRST AID PROCEDURES;
'
.
inhalation: Rarove from exposure area to fresh airJftgestion; Call physician.
Skin Contact: Soap and water "Wash
Other:;
Eye Contact: Flush with-copius quantities of -water - call physician
SECTION 6 - REACTIVITY DATA
A0ILITV (chck 0Mt| CONDITIONS TO AVOIO:
Stable X
Unstable__________________'^;'
...
\, ___________________^
COMPATABILITY (MA-rcj.lA.ui to avoua):
n case of' fire in or near storage area steam generation is possible.
.
\ZARDOUS DECOMPOSITION PRODUCTS:
ISK - Incomplete combustion might yield carbon monoxide.
____________________
VZARDOUS POLYMERIZATION (chkck ons): NO.T.ONS TO avoid:
XWill Not O___c__c__ur
----------------------------------
M. ightO,,ccur
SECTION 7 - SPILL OR LEAK PROCEDURES
:ps to be taken if material is releases or spilled:~
""
'--
roduct is shipped in plastic form. If spill occurs in use form (cut back with water
slurry form) dike spill area with inert material such =, oar>^
STS DISPOSAL, method:
move- waste collection to approved land rill.
i SECTION 8 - SPECIAL PROTECTION INFORMATION
ITTLATION REQUIREMENTS:
PROTECTIVE EQUIPMENT (sfecirr Ttres):
bI Exhaust
Reccomended.
Eye Safety goggles or face' shield
honical Exhaust rial
Reccomended for pouroff & ----------- :------- ------------------------- --
shake out areas.
Gloves Rubber or neoprene reccamenaea. Respiratory NiUSH approved in Douroft 6c stake out ---------------------- ------------------------------------------------=---------------------------------areas
sr Protective Equipment
ijGllC required.
SECTION 9 - SPECIAL PRECAUTIONS
CAUTIONS TO BE TAKEN IN HANDLING AND STORAGE:
intain storage area above freezing.
R PRECAUTIONS:
ne required.
j. ~l-/
=ftr-
\V\jQ
information contai-ned^ uherein Ic rnrro~ rt to the^bessutgogfeosut rthkantoywoleudegvea. lTuahtee rtehceosemrmeecondmamtioennsdaotriosnusgagnesdtisoungsgceosntiotanisneindyinouthrisowdantalasbhoereatuare m'>a
tout guarantee or representat
. h of warranty negligence or otherwise is limited to the purchase price of the.
Our responsibility for claims arising ro b h
V. ^3 9ate[i;entconta;ned hsrdn. WITBREGARD TO THE MATErt.A
fPR /^^ES^^^WA^fL^TT OF^NY* K ND WHATEVER, EXPRESS 9RTMPUED. AND ALL IMPLIED WARRANTIES OF MERCHAN"
PURPOSE AREHEREaY DISCLAIMED BJ^SELLER,-------------------------------------------
5/28/S5
signature:
1
Victor S. LaFay
/
TITLE
STAFF CHEMIST
\
MATERIAL SAFETY DATa SHEET
/**sx is?\ /&:, r
May be used to comply with OSHA's Hazard Coimnunication^t'andard, 29 CFR 1910.1200. Standard must be consulted ior specixic requirements.
H.A. = NOT APPLICABLE
N.E. = NOT ESTABLISHED
I. PRODUCT IDENTIFICATION
PRODUCT NAME (s):#l Zircon Core & Mold Wash
Manufacturer:_Hill and Griffith Co. Address: 1262 State Avenue Cincinnati, Ohio 45204
TELEPHONE: (800) 543-0425 Hours: 8:00 A-M. - 5:00 1J. M. Fax: 513-921-9180
II. HAZARDOUS MATERIAL IDENTIFICATION SYSTEM
CATEGORY Flammability Health Reactivity Personal Protection
RATING 0 1 0 B
LEGEND 0=Minimal Hazara l=Slight Hazard 0=Minimal Hazard B=Glasses and Gloves
III. HAZARDOUS INGREDIENTS
HAZARDOUS INGREDIENTS
ACGIH THRESHOLD CAS. NO "' ` LIMIT VALUE
% RANGE
OSHA PERMISSaBLE EXPOSURE LIMIT
Zircon
7440-67-2
5 mg/m3
70-80
5 mg/m3
* As respirable dust @ This material contains Silicon Dioxide in some form.
IaRC Monographs or
the evaluation of the Carcinogenic Risk of Chemicals to Humans (Volume 42,
1987) concludes that there is sufficient evidence for the carcinogenicity oi
crystalline silica to experimental animals, and that there is limited
evidence of the.carcinogenicity of crystalline silica to humans.
Classified by the IARC as 2A
PRINTED IN U.S. A.
FOR CHEMICAL EMERGENCY, SPILL, LEAK, EXPOSURE OR ACCIDENT CALL CHEMTREC DAY OR NIGHT AT
1-poO-474-q^OO
Product Name:#l Zircon Core & Mold Wash IV. PHYSICAL/CllEitICAL PROPERTIES
Page 2
Appearance and Odor: White-soft putty. Earthy-sweet smell.
Water Solubility: 100% misc.
Melting Point(oF): 32
Boiling Range(oF): 212
Specific Gravity<water=l):>1
Vapor Pressure<mmHg): na
Percent Volatile By Weight: neg
Vapor Density(Air = l) : na TPQ: na
Evaporation Rate<Butyl Acetate=l): na . RQ: na
V. FIRE AND EXPLOSION INFORMATION
Flash Point(C.O.C.)(oF): na
Auto-Ignition Temperature<oF): na
Flammable Limits:
LEL na
UEL na
Extinguishing Media: Product is considered non combustible.
Unusual Fire or Explosion Hazards: None
Special Fire-Fighting Procedures: Use full facepiece with self contained breathing apparatus when fighting fires near this product
VI. CHEMICAL REACTIVITY INFORMATION
Conditions Contributing to Instability: None.
Incompatible Materials: N. E.
Conditions to Avoid: Storage in extreme cold.
Hazardous Decomposition Products: Carbon monoxide and water vapor. May produce oxides of sulfur & nitrogen. PRINTED IN U. S. A.
4*
Product Name: #1 Zircon Core & Mold Wash
VII. HEALTH HAZARDS
A. Summary/Risks
PAGE 3
Signs and Symptons of Overexposure: Overexposure to the skin could result in minor skin irritations including redness or itching.
Medical Conditions Generally Aggravated by Exposure: May aggravate pre existing medical conditions
Primary Route(s) of Entry: Gkin Contact.
Target Organs: Eyes and Skin.
Acute Health Effect: Overexposure could result in mild skin irritations that are reversible. Chronic Health Effect: e
Carcinogenicity: This product is not considered a carcinogen by the ACGIH, NTP, IARC, or OSHA. Notes to Physician: None.
VII. HEALTH HAZARDS B. FIRST AID/EMERGENCY PROCEDURES
Inhalation: It overcome, immediately remove from exposure and seek medical attention
Skin Contact/Absorption: Wash skin thoroughly with soap and water. irritation develops, seek medical attention
If
Eye Contact: Flush with clear flowing water for at least lh minutes. If irritation persists, seek medical attention.
Ingestion: If ingested, DO NOT induce vomiting; call a physician immediately.
VIII. SPILL, LEAK AND WASTE DISPOSAL PROCEDURES
Procedures for clean-up of spills/leaks:on as possible. Scoop up or clea
n up using best means possible. Water may be used to
clean area. Not
ify proper authorities if the need exists.
Contain spill
Waste Disposal: Waste generated during application, demolition, breakage or
spillage are not hazardous wastes as defined by RCRA (40 CFR part 2bl).
Place waste and spillage in closed containers. Dispose of in approved
landfill in accordance with federal, state and local regulations.
PRINTED IN THE U.S.A.
--A
Product Name: #1 Zircon Core & Mold Wash
PACE -4
IX. PROTECTION AND CONTROL INFORMATION
Hygeinic Practices: Minimize breathing vapors, mists, fumes or dusts. Avoid prolonged or repeated contact with skin. Remove contaminated clothes launder before reuse. Remove contaminated shoes; clean before reuse.
Ventilation Requirements: Provide ventilation sufficient to prevent exceeding recommended exposure limits.
Respiratory Protection: respirator
Use NIOSH approved organic cartridge Type 7
Eye Protection: Use safety glasses, splash goggles or face shield when eye
contact may occur
....
-......
Protective Gloves: Use chemical-resistant gloves, if needed, to avoid prolonged or repeated skin contact
Other Clothing and Equipment: As required to prevent contact
Engineering Controls/Work Practices: containers closed when not in use.
Keep containers and storage
Special Considerations for Repair/Maintenance of Contaminated Equipment: Provide adequate respiratory, eye and skin protection.
X. PRECAUTIONS FOR SAFE HANDLING AND USE
Storage Segregation: Always segregate materials by major hazard class.
Special Handling/Storage: Do not transfer contents to unlabeled container<s).
Other: Comply with all federal, state and local regulations.
XI. DOT SHIPPING REQUIREMENTS Shipping Name: Paint Compounds Hazard Class: None. Identification Number: None Label(s) Required: None.
Date Prepared: 04-16-1990 Prepared by: Steve Neltner
Title : Lab Manager
As of the date of preparation of this document, the forgoing information is believed to be accurate and is provided in good faith to comply with applicable federal and state law(s). However, no warranty or representation with respect to such information is intended or given. PRINTED IN U.S. A