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ACIDS. INORGANIC. NEC. DRY (CORROSIVE SOLID, 4930212 N.O.S.) CORROSIVE MATERIAL ACIDIC UN1759 Acids, inorganic nec. dry are various soiid matenals that have the property of being corrosive to tissue. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding Quantities as fog Cool all affected containers with flooding quantities of water Apply water from as tar a distance as possible ft material not involved in fire Build dikes to contain flow as necessary Neutralize spilled matenal with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts of water or soap and water If contact with the matenal anticipated, wear full protective clothing ACIDS. INORGANIC. NEC. LIQUID (ACIDS. LIQUID. 4930201 N.O.S.) CORROSIVE MATERIAL. ACIDIC NA1760 Acids, inorganic, nec. liquid are materials which have the property of being corrosive to metals and or tissue. They are generally heavier than water and soluble in water. They are generally noncombustible. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Matenal itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involvad In Are Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled matenal with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the matenal Wear full protective clothing Do not handle broken packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts of water or soap and water ACIDS. LIQUID, N.O.S. (ACIDS. NEC. LIQUID, 4931404 ORGANIC) CORROSIVE MATERIAL ACIDIC NA1760 Acids, nec. liquid, organic are materials which have the property of being corrosive to metals and/or tissue. If material on Are or involvad In Are Use water in flooding quantities as fog Solid streams of water may be ineffective Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Use water spray to absorb vapors If material not on Are and not Involved in Are Keep sparks, flames, and other sources of ignition sway Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash, or lime April 1991 Personnel protection Avoid breathing vapors Keeo upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts of water or soap and water If contact with the matenal anticipated, wear full protective clothing ACROLEIN. INHIBITED 4909410 FLAMMABLE LIQUID, POISONOUS UN1092 POLYMERIZABLE ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Acrolein is a colorless to yellow colored volatile liquid with a pungent odor, it is used to make other chemicals, plastics, and as a herbicide. It has a flash point of less than 0. deg. F. It is initially irritating to the eyes and mucous membranes: prolonged exposure may lead to death. The material is subject to polymerization if its containers are subject to heat or if it becomes contaminated. It is soluble in water and it is lighter than water. The vapors are heavier than air. It weighs 7.0 pounds per gallon. If material on Are or Involved In Are Do not extinguish fire unless flow can be stooped Use watar in flooding quantities as fog Solid streams of watar may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Usa "alcohol" foam, carbon dioxide or dry chemical If material not on Are and not involved In Are Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear sell-contained breathing apparatus Avoid bodily contact with the material Wear lull protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of watar or soap and water Evacuation If Are becomes uncontrollable or container is exposed to direct flame evacuate for a radius of 5000 feet if material leaking (not on Are), downwind evacuation must be considered Environmental considerations--lend spill Dig a pit. pond, lagoon, holding area to contain liquid or solid matenal Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Neutralize with sodium bisulfate (nahso4) Apply Auorocarbon-water foam to diminish vapor and fire hazard Environmental considerations water spill Use natural barriers or oil Spiff control booms to limit spill motion Add sodium bisulfate If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental coweklerattone air spill Apply water spray or mist to knock down vapors Combustion products include corrosive or toxic vapors 7 MCD 000009748 ACRYLAMIDE SOLUTION (COMBUSTIBLE LIQUfO. 4913187 N.O.S.) COMBUSTIBLE LIQUID NA1993 Acrylamide solution is the colorless crystalline solid dissolved in a solvent it is used tor sewage and waste treatment, to make dyes, ad hesives. and tor many other uses. The flash point of the material depends on the solvent used, but is between 100 and 199 deg. F. It is lighter than water and is soluble in water. Its vapors are heavier than air. Toxic oxides of nitrogen are produced during combustion of this matenal. If material on fire or involved in fire Do not extinguish fire unless flow can be stooped Use water in flooding quantities as tog Solid streams of water may be ineffective Cool an affected containers with Hooding quantities of water Apply water from as far a distance as possible Use alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pods of liquid Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material if contact with the matenal anticipated, wear full protective clothing ACRYLAMIOE SOLUTION (FLAMMABLE UOUID. 4909183 N.O.S.) FLAMMABLE LIQUID UN1993 Acrylamide solution is the colorless crystalline solid dissolved in a solvent. It is used for sewage and waste treatment, to make dyes, ad hesives . and for many other uses. The flash point of the material depends on the solvent used, but is less than 100 deg. F. It is tighter than water and is soluble in water. Its vapors are heavier than air. Toxic oxides of nitrogen are produced during combustion of this material. If materiel on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol" foam, carbon dioxide or dry chemical If material not on fire end not involved In fire Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gioves. and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing 6 MOD 000009749 ACRYLIC ACID 4931405 CORROSIVE MATERIAL ACIDIC. COMBUSTIBLE UN221S Acrylic acid is a colorless Isauid. It is combustible and it has a flash point of 130 deg. F. It is soluble in water. It is corrosive to metals and tissue. Prolonged exoosure to fire or heat can cause me material to polymenze. If polymerization takes Diace in a container violent rupture may occur. if materiel on fire or involved in fire Do not extinguish fire unless flow can be stooped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding Quantities of water Apply water from as far a distance as possible Use alcohol' foam, carbon dioxide or dry cnemicai Use water spray to absorb vapors H material not on fire end not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled matenal with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts of water or soap and water If contact with the materia! anticipated, wear full protective clothing Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet ACRYLONITRILE 4906420 FLAMMABLE LIOUID. POISONOUS UNI 093 POLYMERIZABLE ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-IOO'45.4) Acrytomthte is a clear colorless liquid with a strong pungent odor. It is used in insecticides and to make plastics, fibers and other chemicals It has a flash point of 32 deg. F. It may polymerize if contaminated with strong bases or if the container is subject to heat as in fire conditions Prolonged exposure to the vapors or skin contact may result in death It is lighter then water and is soluble in water. Its vapors are heavier then air. Toxic oxides of nitrogen are produced during combustion of this material. It weighs 6.7 pounds per gallon. If material on fire or Involved m fire Do not extinguish fire unless flow can be stopped Use water In flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Uae "alcohol" foam, carbon dioxide or dry chemical tf materia! not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources end sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1981 Evacuation If firs becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet If material leaking (not on fire), downwind evacuation must be considered Environmental consideration*--lend spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Aosorb bulk liquid with fly ash. cement powder, sawdust, or com mercial sorbents Apply universal gelling agent to immobilize spill Environmental considerations--water spill Use natural barriers or oil spill control booms to limit spill motion Use surface active agent (e g. detergent, soaps, alcohols) to com press and thicken spilled material Inject universal' gelling agent to solidify encircled so<H and increase effectiveness of booms Add calcium hypochlorite If dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Combustion products include corrosive or toxic vapors ACTIVE PRIMARY AMYL ALCOHOL (ALCOHOL. 4913106 N.O.S.) COMBUSTIBLE LIQUID UN1987 Active primary amyt alcohol is a clear colorless liquid. It has a Mash point of 115 deg. F. It is lighter than water and slightly soluble in water. Its vapors are heavier than air. If materiel on fire or Involved in firs Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In firs Keep sparks, flames, and other sources of ignition away Keep materiel out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ACTIVE SEC-AMYL ALCOHOL (ALCOHOL. N.O.S.) 4909106 FLAMMABLE LIQUID UNI 987 Active sec-amyl alcohol is a dear colorless liquid. It has a flash point of 89 deg. F. It is lighter than water and slightly soluble in water. Its vapors are heavier than air. If material on firs or Involved in fire Do not extinguish firs unless flow can be stopped Use water in flooding quantities as log Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol" foam, carbon dioxide or dry chemical April 1981 MCD 000009750 If materiel not on fire and not involved in fire Keeo sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle Oroken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ACTUATING CARTRIDGE. EXPLOSIVE (FIRE 4903305 EXTINGUISHER OR VALVE) CLASS C EXPLOSIVE Actuating cartridge, explosive is a small metal or fiber housing con- lainmg a small amount of explosive and is used to activate remotely controlled fire extinguishers and other apparatus. If material on fire or involved in fire Flood with water Apply water from as far a distance as possible if materiel not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear seif-contained breathing apparatus when fighting fires involv ing this matenal Evacuation if fire becomes uncontrollable--evacuate for a radius of 1500 feet ADDITIVES. FUEL OIL, GASOLINE OR LUBRICATING 4910S3S OIL, CONTAINING LESS THAN 50% BY WEIGHT PETROLEUM OIL (FLAMMABLE UQUID, N.O.S.) FLAMMABLE UQUID UN1993 Additives, fuel oil. gasoline or lubricating oil are various colored liquids having a petroleum-like odor. Their flash point is below 100 deg. F. They are lighter than water and insoluble in water. Their vapors are heavier than air. If matarial on fire or involved In fire Do not extinguish fira unless flow can be stopped Use water in flooding quantities as tog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical H material not on fira and not Involved In fira Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 9 MCD 000009751 ADOfTIVES. FUEL OIL. GASOLINE OR LUBRICATING OIL. CONTAINING LESS THAN 50% BY WEIGHT 4915535 OF PETROLEUM (COMBUSTIBLE LIQUID, N.O.S.) COMBUSTIBLE LIQUID NA1993 Additives, fuel oil. gasoline or lubricating oil. are various colored liquids having a petroleum-like odor. They have a flash point between 100 and 200 deg. F. They are lighter than water and insoluble in water. Their vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not nandle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ADHESIVE. N.O.S. 4910504 FLAMMABLE LIQUID NA1133 Adhesive, n.o.s. is the solution of various gums and resins in various solvents. The liquids are quite thick and range from a clear colorless to a black "tarThe Hash point will depend on the solvent used, but it will be below 100 deg. F. The hazard of this material is flammability. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep matenai out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ADHESIVE. N.O.S. 4915504 COMBUSTIBLE UOUIO NA1133 Adhesive, n.o.s. is the solution of various gums and resins in various solvents. The liquids are quite thick and range from a dear colorless to a black "tar". The flash point will depend on the solvent used, but H will be between 100 and 199 deg. F. The hazard of this material is combustibility. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective 10 Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol foam, carbon dioxide or dry cnemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers 8uild dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenai which may have contacted the body with copious amounts of water or soap and water ADIPIC ACID 4966110 ORM-E NA9077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Adipic acid is a white crystalline solid. It is used to make plastics and foams and for other uses. It is insoluble in water. It will burn though it may take some effort to ignite. If material on fira or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use "alcohol foam, carbon dioxide or dry chemical If material not on fira and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors or dusts Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soao and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates AFTER SHAVE LOTIONS (COMBUSTIBLE LIQUID, 4915424 N.O.S.) COMBUSTIBLE UOUIO NA1993 After shave lotions may contain significant amounts o< alcohol. Their flash point is between 100 and 199 dag. F. They are lighter than water and soluble in water. Their vapors are heavier than air. if material on fire or involved In fire Do not extinguish fire unless flow can be slopped Use water in flooding quantities as tog Solid streams of water may be ineffective Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical April 19b MCD 000009752 If material not on fire and not involved in fire Keep sparks, flames, ana other sources of ignition away Keep material out of water sources ana sewers Build dikes to contain flow as necessary Use water spray to disperse vapors and dilute standing pools of llQUld Personnel protection Avoid Breathing vaoors Keep upwind Wear Poots. protective gloves, ana goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water AFTER SHAVE LOTIONS (FLAMMABLE LIQUID. 4910424 N.O.S.) FLAMMABLE LIQUID UN1993 After shave lotions may contain significant amounts of alcohol. Their flash point is below 100 deg. F. They are lighter than water and soluble m water. Their vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol" foam, carbon dioxide or dry chemical If material not on fice and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water A(R CONDITIONING MACHINE, FLAMMABLE GAS (See REFRIG ERATING MACHINE, FLAMMABLE GAS 4905867) AIR CONDITIONING MACHINE, FLAMMABLE LIQUID (See REFRIG ERATING MACHINE. FLAMMABLE LIQUID 4910167) AIR CONDITIONING MACHINE, NONFLAMMABLE GAS (See RE FRIGERATING MACHINE, NONFLAMMABLE GAS 4904667) AIR. COMPRESSED 4904501 NONFLAMMABLE GAS UN1002 Air. compressed is ordinary air. compressed and shipped in cylinders under pressure, tf material involved In fire Extinguish fire using agent suitable for type of Surrounding fire (Material itself does not bum or bums with difficulty.) Coot ail affected containers with flooding quantities oi water Apply water from as far a distance as possible if materiel not involved in fire Keep sparks, flames, and other sources of ignition away Attempt to stop leak if without hazard Personnel protection Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution April 1981 AIRCRAFT ROCKET ENGINE (COMMERCIAL) 4917405 FLAMMABLE SOLID NA2791 Aircraft rocket engine (commercial) consists of a solid metal case containing a solid composite fuel--not classed as an explosive, and containing no explosive material or element. If material on fire or involved in fire Flood with water Cool all affected containers with flooding quantities of water If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing fumes from burning material Evacuation If fire is prolonged and material is confined in the container--evac uate for a radius of 5000 feet If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet AIRCRAFT ROCKET ENGINE IGNITER (COMMERCIAL) 4917410 FLAMMABLE SOLID UN2792 Aircraft rocket engine igniter(commercial) are devices containing a small quantity of ignition matenal. They must be packaged m sealed metal containers. If material on fire or involved in fire Flood with water Cool all affected containers with flooding quantities of water If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away ALCOHOL DISTILLATES. SYNTHETIC (ALCOHOL. 4915401 N.O.S.) COMBUSTIBLE UQUIO UN1987 Alcohol distillates, synthetic are matenals having a closed cup flash point between too and 199 deg. F. The hazard is combustibility. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Coot all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical if material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ALCOHOL DISTILLATES. SYNTHETIC (ALCOHOL, 4910401 N.O.S.) FLAMMABLE UQUIO UN196? Alcohol distillates, synthetic are materials having a closed cup flash point of less than 100 deg. F. The hazard is flammability. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Continued on nmxt peg* 11 o v0> If material not on fire end not involved In fire Keeo soarks. names, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of iiQUld Personnel protection Avoid breathing vapors Keeo upwind Wear boots, protective gloves, and goggles Do not nandie broken packages without protective eouipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ALCOHOL IN BOND. FREE OF INTERNAL REVENUE 4910102 TAX (ALCOHIC BEVERAGE) FLAMMABLE LIQUID UN1170 Alcohol in bond is a clear colorless to amber colored liquid with a characteristic odor.lt has a flash point of less than 100 deg. F It is lighter than water and soluble m water. Its vapors are heavier than air. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool alt affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol ' foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ALCOHOL IN BOND, FREE OF INTERNAL REVENUE 4915102 TAX (ALCOHIC BEVERAGE) COMBUSTIBLE LIQUID UN1170 Alcohol in bond ii a dear colorless to amber colored liquid with a characteristic odor. It has a flash point between 100 and 199 deg. F. It is lighter than water and soluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol" foam, carbon dioxide or dry chemical If materiel not on fire and not involved Hi fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to disperse vapors and dilute standing pools of liquid 12 Personnel protection Avoid breathing vapors - Keep upwind Wear boots, protective gloves, and goggies Do not handle broken packages without orotective eauioment Wash away any material which may nave contacted the body with copious amounts of water or soap ana water ALCOHOL OR SPIRITS. FRUIT. EXCEPT GRAPE. 4915104 NEUTRAL, IN BONO (ALCOHOLIC BEVERAGE) COMBUSTIBLE LIQUID UN1170 Alcohol or spirits, fruit, except grape, neural is a c:ear coioness to variable colored liquid with a characteristic odor it has a flash point of between 100 and 199 deg. F. It is lighter than water and soluble m water Its vapors are heavier than air. If material on fire or involved in fire Oo not extinguish fire unless flow can be stopped Use water n Hooding quantities as tog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use 'alcohol1' foam, carbon dioxide or dry chemical If material not on fire end not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to disperse vapors and dilute standing pools ol liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap ana water ALCOHOL OR SPIRITS, FRUIT,EXCEPT GRAPE, 4910104 NEUTRAL, IN BOND (ALCOHOLIC BEVERAGE) FLAMMABLE LIQUID UN1170 Alcohol or spmts. fruit, except grape, neutral is a clear colorless to variable colored liquid with a characteristic odor. It has a flash point of less than 100 deg. F. It is lighter than water and soluble in water Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams ol water may be ineffective Cod all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'' loam, carbon dioxide or dry chemical tf materiel not on fire and not Involved In fire Keep sparks, llamas, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggies Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ooo^54 MCt> 0 April 198 ALCOHOL OR SPIRITS. GRAPE. NEUTRAL IN BONO 4910103 (ALCOHOLIC BEVERAGE) FLAMMABLE LIQUID UN1170 Alcohol or spirits. grape, neutral is a dear colorless to variable colored liquid with a characteristic odor. It has a Hash point of less than 100 deg. r It is lighter than water and soluble in water, its vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in Hooding quantities as tog Solid streams of water may Oe ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol foam, carbon dioxide or dry chemical It material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out ol water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ALCOHOL OR SPIRITS. GRAPE. NEUTRAL IN BONO (ALCOHOUC BEVERAGE) 4915103 COMBUSTIBLE LIQUID UN1170 Alcohol or spirits, grape, neutral is a dear colortess to variable colored liquid with a characteristic odor. It has a flash point between 100 end 199 deg. F. It is lighter than water and soluble in water. Its vapors are eavier than air. ft materiel on fire or Involved In fire Do not extinguish tire unless How can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, end goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ALCOHOL. CONTAMINATED, SUITABLE FOB ONLY 4910501 BLENDING OR REDISTILLING PURPOSES (ALCOHOL, N.O.S.) FLAMMABLE LIQUID UN19B7 Alcohol, contaminated, suitable only for blending or redistilling pur* poses is a clear colorless to dark colored liquid, it has a flash point of less than 100 deg. F. ft is lighter than water and generally is soluble in water. Its vapors are heavier than air. aril 1961 0ooos?55 if material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers 8uild dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ALCOHOL. CONTAMINATED. SUITABLE ONLY FOR BLENOING OR REDISTILLING PURPOSES 4915501 (ALCOHOL, N.O.S.) COMBUSTIBLE LIQUID NA1993 Alcohol, contaminated, suitable only for blending or redistilling pur poses is a dear colortess to dark colored liauid. It has a flash point between 100 and 199 deg. F. It is lighter than water and generally is soluble in water. Its vapors are heavier than ar. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If materiel not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ALCOHOL, N.O.S. 4913103 COMBUSTIBLE UQUIO UN1987 Alcohol, n.o.s. is the proper shipping name for the family of organic chemicals called "alcohols". Those classed as combustible liquid have a flash point between 100 and 199 deg. F. Most alcohols, n.o.s. are soluble in water. Their vapors are heavier than air. If material on five or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Continued Off next page 13 If material not on lira and not Involvod In fir* Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear coots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and watar ALCOHOUN.O.S. 4909105 FLAMMABLE LIQUID UNI 997 Alcohol, n.o.s. is the proper shipping name for the family of organic chemicals caliad "alcohols". Their flash point is less than 100 deg. F. Most alcohols, n.o.s. are soluble in water. Their vapors are heavier than air. Thair main hazard is flammability. If material on fire or Involvod In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool ail affected containers with flooding quantities of water Apply water from aa far a distance aa possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on Are and not involved In Are Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow aa necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and watar ALCOHOLS, FATTY OR CYCLIC, ETHOXYLATED 4915109 (ALCOHOUN.O.S.) COMBUSTIBLE LIQUID NA1993 Alcohols, fatty or cyclic, athoxyfated are deer colorless liquids, their flash point is between 100 an 199 dag. F. They are lighter then water and are generally insoluble in water. Their vapors arc heavier than air. tf material on Are or Involved in Are Do not extinguish fire unless fiow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers wllh flooding quantities of water Apply water from as ter a distance aa possible Use "alcohol" teem, carbon dioxide or dry chemical tf materiel not on fire end not Involvod In Are Keep sparks, flames, end other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow aa necessary Attempt to stop leak If without hazard Use watar spray lo disperse vapors and dilute standing pools of liquid 14 Personnel protection Avoid breathing vapors ' Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ALCOHOLS, FATTY OR CYCUC, ETHOXYLATED 4910111 (ALCOHOUN.O.S.) FLAMMABLE LIQUID UN1997 Alcohols, fatty or cyclic, ethoxylated are clear colorless liquids, their flash point is less than 100 deg. F. They are lighter than water and are generally insoluble in water. Their vapors are heavier than air. tf material on Are or involved in Are Do not extinguish fire unless flow can be stooped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on Are and not involved In Are Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body wit copious amounts of water or soap and water ALDOL (COMBUSTIBLE LIQUID. N.O.S.) 4913105 COMBUSTIBLE L1QUB NA1993 Aldd is a clear colorless to pate yellow syrupy liquid. It has a flash point of 150 dog. F. It is heavier than water and soluble in water. Its vapors are heavier than air. H material on Are or Involved in Are Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be tneffactiv# Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical H material net on Are end not involved In Are Keep sparks, flames, and other sources ol ignition away Keep material out ol water sources and sewers Build dikes to contain flow as necessary Use water spray to disperse vapors and dilute standing pods ot liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1991 MOD 000009756 ALORIN 4921403 POISON 8 NA2761 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-VO.454) Aldrm is a drown to white crystalline solid. It is insoluble in water and is non-combustible. It is toxic by mnaiation and skin absorption. In case of damage to, or leaking from containers of this matenai contact the pesticide safety team network. Telephone: 800-424-9300 If material involved in fire Extinguisn fire using agent suitable for tyoe of surrounding fire (Material itself does not burn or burns with difficulty.) Coot ail affected containers with flooding quantities of water If material not involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing vapors or dusts Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective eautpment Wash away any matenai which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in ram or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom if dissolved, apply activated carbon at ten times the spilled amount m region of tOppm or greater concentration Remove trapped matenai with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates ALORIN MIXTURE. DRY (WITH MORE THAN 65% ALDRIN) 4921407 POISON B NA2761 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Aldrm mixture, dry is a white to brown crystalline solid. Aldrin itself is non-combustible and insoluble in water. The other material in the mixture may or may not be combustible or water soluble. It is toxic by inhalation (dusts, etc) and by skin absorption, in case of damage to. or leaking from containers of this matenai contact the pesticide safety team net work. Telephone: 800-424-9300 If material involved in fira Extinguish fira using agent suitable for type of surrounding lire (Matenai itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use alcohol" foam, carbon dioxide or dry chemical If material not involvad In fire Keep material out of water sources and sewers Personnel protection Avoid breathing vapors or dusts Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid matenai Cover solids with a plastic sheet to prevent dissolving in rain or fire lighting water April 1981 MCD 000009757 Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sanq bag barriers to trap matenai at bottom if dissolved, apply activated carbon at ten times the spilled amount in region of lOopm or greater concentration Remove traoDed material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates ALDRIN MIXTURE, DRY. WITH 65% OR LESS ALDRIN 4941109 ORM-A NA2761 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1 .454) Aldrin mixture, dry. is a white to brown colored solid. It is used as an insecticide. Aldnn. itself, is noncombustible and insoluble in water. The other material in the mixture may or maybe combustible or water soluble. It may cause sickness due to inhalation of dust or by skin absorption. In case of damage to. or leaking from containers of this matenai contact the pesticide safety team network. Telephone- 800-424-9300. If material involved in fira Extinguish fire using agent suitable for type of surrounding fire (Matenai itself does not bum or bums with difficulty.) if material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving m rain or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove traooed materia) with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates ALORIN MIXTURE, LIQUID (WITH MORE THAN 60% 4921406 ALORIN) POISON B NA2762 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Aldrin mixture, liquid is a colorless to brown colored liquids. Aldrin itself is a non-combustible solid but the liquid mixture may be flammable combustible or non-combustible depending on the flammable property of the solvent. Its vapors are heavier than air. It is toxic by inhalation and skin absorption. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone: 800-424-9300 H materia) on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Solid streams of water may be ineffective Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Continued on next page 15 If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective eauioment Wash away any material which may have contacted the boay with copious amounts of water or soap and water Evacuation If material leaking (not on tire), downwind evacuation must be considered Environmental considerations---land spill Dig a pit. pond, lagoon, holding area to contain iiguid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with My ash or cement powder Environmental considerations'--water spill Use natural barriers or oil spill control booms to limit spill motion Use surface active agent (e.g. detergent, soaps, alcohols) to com press and thicken spilled material Inject universal'' gelling agent to solidify encircled spill and increase effectiveness of booms If dissolved, apply activated carbon at ten times the spilled amount m region of tOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates ALORIN MIXTURE. LIQUID. WITH 60% OR LESS . ALORIN 4941108 ORM-A NA2762 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-1 0.454) Aldhn mixture, liquid is a colorless to brown colored liquid. It is used as an insecticide. Aldnn itself is a noncombustible solid, but the liquid may be combustible or noncombustibie depending upon the flammable property of the liquid. Its vapors are heavier than air. It can cause sick ness due to inhalation of the vapors or by skin absorption. In case of damage to. or leaking from containers of this material contact the pes ticide network. Telephone- 800-424-9300. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considsrations--water spill Use natural barriers or oil spill control booms to limit spill motion Use surface active agent (e.g. detergent, soaps, alcohols) to com press and thicken spilled material Inject universal ' gelling agent to solidify encircied spill and increase effectiveness of booms If dissolved, apply activated carbon at ten times the spilled amount m region of 10ppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates 16 ALDRIN. CAST SOLID 4941107 ORM-A NA2761 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-1 0.454) Aldnn. cast solid is a brown to white sol'd, it is used as an insecticide If the large pieces are broken up or powdered, it is toxic by inhalation and skin absorption, it is insoluble in water and noncombustible. In case of damage to. or leaking from containers of this material contact the pesticide safety team network Teleonone- 800-424-9300. If material involved in fire Extinguish fire using agent suitaDie for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in ram or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barners to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount m region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates ALKAUNE CORROSIVE BATTERY FLUID 4935210 CORROSIVE MATERIAL. BASIC UN2797 Alkaline corrosive battery fluid consists of a water solution of potar. slum hydroxide, it is corrosive to metals and tissue. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing ALKAUNE CORROSIVE BATTERY FLUID PACKED 493656S WITH BATTERY CHARGER, RADIO CURRENT SUPPLY DEVICE OR ELECTRONIC EQUIPMENT AND ACTUATING DEVICES CORROSIVE MATERIAL BASIC NA2797 Alkaline corrosive battery fluid packed with battery charger, radio cur rent supply device or electronic equipment and actuating devices consist of containers of alkaline corrosive battery fluid. Packed in the same outside shipping container with battery charger, radio current supply device or electronic equipment and actuating devices. The alkaline cor rosive battery fluid is soluble in water with evolution of heat, it is corrosive to metals and tissue. April 196. WCD 00000975a If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water m flooding Quantities as fog Aoply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid bodily contact with the material Wear ooots. protective gloves, and goggles Do not hanole broken packages wunout protective eouipment Wash away any material wmch may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing mis material if contact with the material anticioated. wear full protective clothing ALKALINE CORROSIVE BATTERY FLUID WITH 4935215 EMPTY STORAGE BATTERY CORROSIVE MATERIAL, BASIC UN2797 Alkaline corrosive battery fluid with empty storage battery is the stor age battery packed together with containers ol the battery fluid. The fluid is a water solution of potassium hydroxide. It is corrosive to metais and tissue. If material involved in fire Extinguish fire using agent suitable tor type of surrounding tire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing ALKALINE CORROSIVE UOUIO, N.O.S. 4935220 CORROSIVE MATERIAL BASIC NA1719 Alkaline corrosive liquid, n.o.s. are materials having the property of being corrosive 10 metals ana or tissue. Most of these materials are water soluble. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Matenal itself does not bum or bums with difficulty.) Use water in Hooding quantities as fog Cool ali affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved in fire Keep matenal out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water II contact with the matenal anticipated, wear full protective clothing April 1981 00009759 MCD 0 ALKANESULFONIC ACID 4931406 CORROSIVE MATERIAL. ACIDIC UN2584 . Aikanesuifomc acid is a mixture of methane ethane, and propane sulfonic acids which is a colorless to amber colored liquid. It is soluble in water with release of heat, it is corrosive to metais ana tissue. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool ail affected containers with flooding quantities ol water Apply water from as far a distance as possible Use aicohol ' foam, carbon dioxide or dry cnemical Use water spray to absorb vaoors if material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled matenal with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective glaves. and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water if contact with the material anticipated, wear full protective clothing ALL FREIGHT RATE SHIPMENTS, NEC (TOFC) 4950150 Consult the shipping papers for the exact contents of the car. con tainer. or trailer. ALLYL ALCOHOL 4907425 FLAMMABLE LIQUID. POISONOUS UN1098 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100/4S.4) Altyi alcohol is a clear colorless liquid with a mustard-like odor. It has a flash point of 70 deg. P. It is toxic by inhalation and ingestion. It is lighter than water and soluble in water. Its vapors are heavier than air. It weighs 7.1 pounds per gallon. If material on fire or involved In fire Do not extinguish (ire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol ' foam, carbon dioxide or dry chemical ft materiel not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the matenal Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water * Continued on next page 17 Evacuation If fire becomes uncontroiiaole or container is exposed to direct flame--evacuate for a radius of 1500 feet If matenal leaking (not on fire). downwind evacuation must be considered Environmental consideration*--land spill Dig a pit. pond, lagoon, holding area to contain liauid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash. cement powder, sawdust, or com mercial sorbents Apply ' universal ' gelling agent to immobilize spill Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount m region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors ALLYL BROMIOE 4907410 FLAMMABLE LIQUID, POISONOUS UN1099 Ally! bromide is a clear colorless to tight yellow liquid with an irritating, unpleasant odor. It has a flash point of 30 deg. F. It is an eye. skin, and respiratory irritant. Prolonged exposure o< the skin to allyi bromide may result in toxic amounts of the material being absorped. It is heavier than water and slightly soluble in water. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keap material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Evacuation if fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered ALLYL CHLORIDE 4907412 FLAMMABLE UQUIO, POISONOUS UN1100 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-IOOO/454) Allyi chloride is a dear colorless liquid with an unpleasant pungent odor. It has a flash point of -20 deg. F. Vapor is irritating to skin, eyes and mucous membranes. Prolonged exposure to the liquid or vapor can result in death by inhalation or skin absorption, tl is lighter than water and slightly soluble in water, its vapors are heavier thap air. It weighs 7.8 pounds per gallon. 18 If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as log Solid streams of water may spread fire Cool ail affected containers with flooding Quantities of water Apply water from as far a distance as possible Use alcohol' foam, carbon dioxide or Cry chemical If material not on fire end not involved in fire Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equloment Wash away any matenal which may have contacted the body with copious amounts of water or soap and water If contact with the matenal anticipated, wear full protective clothing Evacuation If tire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on tire), downwind evacuation must be considered Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash. cement powder, sawdust, or com mercial sorbents Apply universal" gelling agent to immobilize spill Environmental considerations--water spill Use natural barriers or oil spill control booms to limit spill motion Use surface active agent (e.g. detergent, soaps, alcohols) to com press and thicken spilled matenal Inject "universal" gelling agent to solidify encircled spill and increase effectiveness of booms If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Combustion products include corrosive or toxic vapors ALLYL CHLOROFORMATE (OR) ALLYL 4907807 CHLOROCARBONATE FLAMMABLE LIQUID, CORROSIVE UNI 722 Allyi chtoroformate is a colorless liquid with a pungent odor. It has a flash point of 88 deg. F. It is corrosive to metals and tissue. It is de composed by water to give hydrochloric acid, a corrosive materiai.with evolution of heat. Its vapors are heavier than air. If material on fire or Involved In Are Do not extinguish fire unless flow can be stopped Use "alcohol" foam, carbon dioxide or dry chemical Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Do not use water on materia) rtseff if large quantities of combustibles ere involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors April 1981 000009760 MCD K material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak il without hazard Use water spray to knock-down vapors Oo not use water on material itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking {not on fire), downwind evacuation must be considered If material not on fire and not Involved in fire Do not use water Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the matenal Wear full protective clothing Do not handle broken packages without protective equipment Wash away any matenal which may have contactea the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered ALLYL TRICHLOROSILANE 4934205 CORROSIVE MATERIAL, ACIDIC. FLAMMABLE UN1724 Ailyl tnchlorosilane is a colorless liquid with a pungent odor. It is flammable and has a flash point of 95 deg. F. It is readily decomposed by moisture or water to hydrochloric acid with evolution of heat. It is corrosive to metals and tissue. If material on fire or involved in fire Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool ail affected containers with flooding quantities of water Aopty water from as far a distance as possible tf material not on fire and not involved in fire Keep sparks, flames, and other sources Of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the materia) Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water if contact with the material anticipated, wear full protective clothing ALUMINUM ALKYL 4906011 FLAMMABLE LIQUID UN2B45 Aluminum alkyl is a clear colorless liquid. It is used to make other chemicals. It ignites spontaneously on contact with air. It reacts violently with water and most chemicals, tf material on fire or involved In fire Do not extinguish fire unless flow can be stopped Do not use water Use graphite, soda ash or powdered sodium chloride April 1961 ALUMINUM BROMIDE. ANHYDROUS. SOLIO 4932301 CORROSIVE MATERIAL. ACIDIC UN1725 Aluminum bromide, anhydrous solid is a white to yellowish-red lumpy soiid with a pungent odor. It reacts with water to form hydrobromic acid and aluminum hydroxide with release of heat. It is corrosive to metals and tissue. If material involved In fire Do not use water on material itself If large quantities of combustibles are involved, use water in Hooding quantities as spray and fog Use water spray to absorb vapors If material not involvad In fire Keep material out of water sources and sewers Oo not use water on material itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnet protection Avoid breathing vapors Avoid bodily contact with the material Wear boots, protective gloves, and goggles Oo not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear satf-contained breathing apparatus when fighting lires involv ing this material If contact with the material anticipated, wear full protective clothing ALUMINUM CHLORIDE. DRY (CORROSIVE SOUD. 4932302 N.O.S.) CORROSIVE MATERIAL. ACIDIC UN17S9 Aluminum chloride, dry is a white to grey powder with a pungent odor. It reacts with water to form hydrochloric add and aluminum hydroxide with release of heat, ft is corrosive to tissue. H material Involvad In On Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors If material not involved In Are Keep material out of water sources and sewers Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash. or lime Continued on next page 19 MCD 000009761 Personnel protection Avoid breathing vapors Avoid bodily contact with the material Wear doois. protective gloves, and goggles Do not handle broKen packages without protective eouipment Wash away any material which may have contacted the body with cooious amounts of water or soap ana water Wear self-contained breathing apparatus when fighting fires involv ing this material if contact with the material anticipated, wear full protective clothing If material not on fire and not invoived in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Do not attempt to sweep up dry material Personnel protection Wear boots, protective gloves, and goggles Wash away any material which may have contacted the oocy with copious amounts of water or soao ana water Avoid breathing dusts ALUMINUM HYDRIDE 4916403 FLAMMABLE SOLID UN2463 WATER REACTIVE Aluminum hydride is a colorless to white solid. It reacts with water to form aluminum hydroxide and hydrogen, a flammable gas. The heat of this reaction may be sufficient to ignite the hydrogen. Prolonged ex posure of aluminum hydride to heat may result in its spontaneous de- compostion. It may react violently with oxidizers. If material on fire or involved in fire Do not use water Use graphite, soda ash or powdered sodium chloride If material not on fir# and not involved in tire Do not use water Keep sparks, flames, and other sources of ignition away Keep matenai out of water sources and sewers Keep material dry Personnel protection Avoid breathing dusts, and fumes from burning material Wear boots, protective gtoves. and goggles Do not handle broken packages without protective equipment Wash away any matenai which may have contacted the body with copious amounts of water or soap and water ALUMINUM LIQUIO (OR PAINT) 4910101 FLAMMABLE LIQUID UN1263 Aluminum liquid or paint is a silvery colored liquid. II has a flash point of less than 100 deg. F. It is generally insoluble in water and its vapors are heavier than air. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as tar a distance as possible Use alcohol" foam, carbon dioxide or dry chemical if material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gtoves. and goggles Do not handle broken packages without protective equipment Wash away any matenai which may have contacted the body with copious amounts oi water or soap and water ALUMINUM METALLIC POWDER (POWDER. NEC. 4916706 ALUMINUM) FLAMMABLE SOUD UN1396 Aluminum, metallic powder is a light grey or silvery colored powdered metal. It is easily ignited and bums with an intense flame. If materiel on lire or involved in fire Do not use water Use suitable dry powder 20 ALUMINUM NITRATE 4918701 OXIOIZER UNI 438 Aluminum nitrate is a white crystalline solid, it is used m petroleum refining, in dyetng. in leather tanning, and for many other uses, it absorbs moisture from the air and dissolves m it. The material is soluble m water It is non combustible but it will accelerate the burning of combustible materials. If large quantities are involved or the combustible material is finely divided an explosion may result. Prolonged exoosure of the ma terial to fire or heat may result in an explosion. Toxic oxides of nitrogen are produced in fires involving this material. If material on fire or involved in fire Flood with water Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective eouipment Wash away any matenai which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when lighting fires mvoK ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet ALUMINUM PHOSPHATE SOLUTION 4932304 CORROSIVE MATERIAL. ACIDIC NA1760 Aluminum phosphate solution is the crystalline solid dissolved m phos phoric acid. Aluminum phosphate itself is insoluble in water, tt is cor rosive to metals and tissue. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as tog Solid streams of water may be ineffective Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Avoid bodily contact with die material Wear boots, protective gloves, and goggles Oo not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the matenai anticipated, wear full protective clothing April 1981 MCD 000009762 ALUMINUM PHOSPHIDE 4916305 FLAMMABLE SOLID. POISONOUS UN1397 WATER REACTIVE Aluminum DhosDhide is a dark grey or dry yellow crystalline solid. It reacts with moisture to give phosphine, a flammable poisonous gas Normally the ohosohme will spontaneously ignite m contact with air tf ihere is an excess of water, this fire of phosphine will not normally ignite surrounding combustible material. If material on fire or involved in fire Do not use water Use dry chemical or carbon dioxide If material not on fire and not involved in fire Do not use water Keep sparks, (lames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Personnel protection Avoid breathing dusts, and fumes from burning material Keep uowind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing ALUMINUM SULFATE 4963303 ORM-E NA9078 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Aluminum sulfate is a white crystalline solid. It is used in paper making, m fire-fighting foams, in sewage treatment and water purification, and for many other uses. It is soluble in water. It is non-combustible. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty ) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental conaideratkms--land epUl Oig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agncultural lime (slaked lime), crushed limestone, or sodium bicarbonate Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates ALUMINUM SULFATE SOLUTION 4944165 ORM-B NA1760 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Aluminum sulfate solution is the white crystatine solid dissolved m water. It is used in paper making, in tire fighting foams, as a fire proofing agent, in sewage treatment and water punfication, and for many other uses. It is non-combustible. It is corrosive to aluminum. It weighs 10.9 pounds per gallon. If material involved in fir* Extinguish fire using agent suitable for type of surrounding fire (Matenal itself does not bum or bums with difficulty.) II material not involved In tire Keep matenal out of water sources and sewers Build dikes to contain flow as necessary Personnel protaction Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface (low using soil, sand bags, foamed oolyurethane. or foamed concrete Absorb bulk liquid with fly ash. cement powder, sawdust, or com mercial sorbents Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates ALUMINUM SULPHATE FLUOSULPHATE MIXTURE. 4963304 FLUORINE CONTENT NOT TO EXCEED 25% (ALUMINUM SULFATE) ORM-E NA9078 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Aluminum sulphate fluosulphate mixture is a white solid. It is soluble in water. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Matenal itself does not burn or burns with difficulty.) If material not involved in fire Keep matenal out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any matenal which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid matenal Cover solids with a plastic sheet lo prevent dissolving tn ram or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates ALUMINUM SULPHATE, NOT MORE THAN 5% 4963305 ACTIVATED CARBON (ALUMINUM SULFATE) ORM-E NA9076 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Aluminum sulphate, not more than 5% activated carbon is a light grey solid. It is used to make ethane. Only the aluminum sulphate is soluble in water. It is non-combustible. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itsalf does not bum or bums with difficulty.) If material not involved In fire Keep matenal out of water sources and sewers Build dikes to contain flow as necessary Continued on next page Apnt 1981 ,,ooo^63 21 Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap ano water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liauid or solid material Cover solids witn a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime isiaked lime), crushed limestone, or sodium bicarbonate Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates ALUMINUM. METALLIC, POWDER (POWDERS, ALUMINUM) 4916707 FLAMMABLE SOLID UN1396 Aluminum, metallic, powder is a light grey or silvery colored powdered metal. It is easily ignited and burns with an intense (lame. If material on fire or involved in fire Do not use water Use suitable dry powder If material not on fire end not involved in tire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Do not attempt to sweep up dry material Personnel protection Wear boots, protective gloves, and goggles Wash away any matenal which may have contacted the body with copious amounts of water or soap and water Avoid breathing dusts 2-42-AMINOETHOXY) ETHANOL 493560S CORROSIVE MATERIAL, BASIC NA1760 2-(2-ammoethoxy) ethanol is colorless liquid with a faint fish like odor. It may bum though it may require some effort to ignite, it is soluble in water. It is corrosive to metals and tissue. Toxic oxides of nitrogen are produced during combustion of this matenal. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the matenal anticipated, wear full protective clothing N>AMINOETHYL PIPERAZINE 4935610 CORROSIVE MATERIAL, BASIC. COMBUSTIBLE UN2615 N-aminoethyl piperazine is a colorless liquid with a faint ftsh-like oar it is combustible and has a flash point of 199 deg. F it is soluble water. It is corrosive to metals and tissue. Toxic oxides of nitrogen are produced dunng combustion of this matenal. if material on fire or involved in fire Do not extinguish fire unless flow can oe stopped Use water m flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use "alcohol ' foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective eauipment Wash away any matenal which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this matenal If contact with the material anticipated, wear full protective clothing AMINOETHYLETHANOLAMINE (CORROSIVE LIQUID, 4935674 N.O.S.) CORROSIVE MATERIAL UN1760 Aminoethylethanoiamme is a clear colorless liquid having an am monia-like odor. It is used to make other chemicals. It is corrosive to metals and tissue, it will bum though it may require some effort to ignit- it is lighter than water and soluble in water, its vapors are heavier th air. Toxic oxides of nitrogen are produced during comoustion of this material. H material on Are or involved in fire Do not extinguish lire unless flow can be stopped Use water in flooding quantities as fog Coot all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use "alcohol" foam, carbon dioxide or dry chemical If material not on Are and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the matenal anticipated, wear full protective clothing N-AMINOPROPYL MORPHOLINE 4935620 CORROSIVE MATERIAL, BASIC NA1760 N-aminopropyimorphoiine is a colorless liquid with a faint fish-like odor. It may bum though it may require some effort to ignite. It is soluble in water, it is corrosive to metals and tissue. Toxic oxides of nitrogen are produced during combustion of this matenal. 22 April 1981 000009764 MCD If material on fire or involved in fire Do not extinguish lire unless flow can be stooped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Aooly water from as far a distance as oossibie Solid streams of water may oe ineffective Use alcohol' foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keeo sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material wnich may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this matenal If contact with the material anticipated, wear full protective clothing BIS-(AMINOPROPYL) PIPERAZINE 493562S CORROSIVE MATERIAL. BASIC NA1760 Bis-faminopropyH piperazine is a colorless liquid with a faint fish like odor. It solidities at 59 deg. F ft may burn though it may require some effort to ignite. It is soluble in water. It is corrosive to metals and tissue. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Coot all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use alcohol'' foam, carbon dioxide or dry chemical If material not on firt and not Involved in fira Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid Oreathing vapors Keep upwind Avoid bodily contact with the matenal Wear Doots. protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this matenal If contact with the material anticipated, wear full protective clothing AMINOPROPYLOIETHANOL AMINE 4935615 CORROSIVE MATERIAL, BASIC NA1760 Ammopropyldiethanol amine is a colorless liquid with a faint fishlike odor. It may bum though it may require some effort to ignite, it is soluble in water. It is corrosive to metals and tissue. Toxic oxides of nitrogen are produced during combustion of this matenal. If materiel on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use alcohol" foam, carbon dioxide or dry chemical April 1981 If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts Of water or soap ana water Wear self-contained breathing apparatus when fighting fires involv ing this matenal If contact with the material anticipated, wear full protective clothing AMMONIA SOLUTION (CONTAINING MORE THAN 44% 4904220 AMMONIA) NONFLAMMABLE GAS. CORROSIVE UN2073 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Ammonia solution is ammonia gas dissolved in water. It has the char acteristic ammonia odor, The solution is corrosive to metals and tissue. Although ammonia is lighter than air. the vapors from a leak will initially hug the ground. It weighs 7.3 pounds per gallon. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use water spray Ip absorb vapors N material not Involved in tire Keep matenal out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and gas tight goggles Do not handle broken packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Evacuation If matarial leaking (not on tire), downwind evacuation must be considered Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with vinegar or other dilute add Environmental considerations--water spill Neutralize with dilute add or removable strong add If dissolved, apply activated carbon at tan times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--sir spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked tor containment 23 MCD 000009765 AMMONIACAL LIQUOR (COMPRESSED GAS, N.O.S.) 4904221 NONFLAMMABLE GAS. CORROSIVE UN19S6 Ammomacal liquor is the solution in water of various ammonium salts and ammonia gas. It has so much ammonia in it that there is oressure m excess of 40 osi at 70 deg. F. The solution is corrosive. Although ammonia is lighter than air. the vapors from a leak initially hug the ground. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Cool ail affected containers with flooding Quantities of water Aooiy water from as far a distance as possible Use water spray to absoro vapors If material not involved in fire Keeo material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and gas tight goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Evacuation If material leaking (not on fire), downwind evacuation must be considered AMMONIUM ACETATE 4966708 ORM-E NA9079 ENVIRONMENTALLY HAZAROOUS SUBSTANCE (RQ-5000/2270) Ammonium acetate is a white crystalline solid. It is used in chemical analysis, in pharmaceuticals, in preserving foods, and for other uses. It is soluble in water. It is non-combustibfe. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid matenal Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with dilute add or removable strong add if dissolved, apply activated carbon at ten times the spilled amount in region of fOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates AMMONIUM ARSENATE, SOUD 4923201 POISON B UNI 546 Ammonium arsenate, solid is a white crystalline solid. It is soluble in water and toxic by ingestion. 24 If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with Difficulty ) Use water m flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and tumes from burning material Keeo UQwmo Avoid bodily contact with the material W%ar full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when hooting fires involv ing this matenal AMMONIUM BENZOATE 4966304 ORM-E NA9080 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RG-5000 2270) Ammonium benzoate is a white crystalline solid. It is used m medicine and as a food preservative. It is soluble in water it is non-combustible If materiel involved in fire Extinguish fire using agent suitable for type ot surrounding fire (Matenal itself does not bum or bums with difficulty i If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--lend split Dig a pit. pond, lagoon, holding area to contain liouid or solid material Cover solids with a plastic sheet to prevent dissolving in ram or fire fighting water Environmental considerations--water spill Neutralize with dilute acid or removable strong acid If dissolved, apply activated carbon at ten times the soilied amount in region of 10ppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates AMMONIUM BICARBONATE 4966308 ORM-E NA9081 ENVIRONMENTALLY HAZAROOUS SUBSTANCE (RQ-5000/2270) Ammonium bicarbonate is a white crystalline solid having the odor ol ammonia. It is used to make other ammonium compounds, in food processing, and for other uses. It is soluble in water. It is non- combustible. tt material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itseif does not bum or bums with difficulty.) If materiel not involved In fire Keep matenal out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water April i98i Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liauid or solid matenal Cover solids with a piasnc sheet to prevent dissolving m ram or fire lighting water Environmental considerations--water spill Neutralize with dilute acid or removable strong acid AMMONIUM BISULFITE SOLUTION 4932348 CORROSIVE MATERIAL NA2693 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Ammonium bisulfite solution is the white crystalline solid dissolved in water having an odor of burning sulfur, tt is corrosive to metals and tissue If material involved in fire Extinguish fire using agent suitable tor type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water m flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Keep matenal out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled matenal with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Avoid bodily contact with the material Wear boots, protective gloves, ana goggles Do not handle broken packages without protective eouipment Wash away any material which may have contacted the body with cooious amounts of water or soap and water Wear self'Contained breathing apparatus when fighting fires involv ing this matenal if contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid matenal Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Apply fluorocarbon-water foam to diminish vapor and fire hazard Environmental consideration*--water spill Add calcium hypochlorite Neutralize with dilute acid or removable strong acid If dissolved, appty activated carbon at ten times the spilled amount m region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental consideration*--air spill Apply water spray or mist to knock down vapors AMMONIUM BISULFITE, SOUD 4944142 ORM-B NA2693 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Ammonium bisulfite, solid is a colorless crystalline solid. It is used in the manufacture of other chemicals. It is soluble in water. It is non* combustible, it is corrosive to aluminum. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) If material not involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1981 MCI) 00009767 Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid matenal - Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Add calcium hypochtonte Neutralize with dilute acid or removable strong acid Adjust ph to neutral (ph-7) AMMONIUM CARBAMATE 4941145 ORM-A NA9083 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Ammonium carbamate is a white crystaline solid. It is used as a fertilizer. It is soluble in water. If material Involved in fire Extinguish tire using agent suitable for type o< surrounding tire (Matenal itself does not burn or bums with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any matenal which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Oig a pit. pond, lagoon, holding area to contain liquid or solid matenal Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with dilute acid or removable strong acid Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment AMMONIUM CARBONATE 4941149 ORM-A NA9084 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Ammonium carbonate is a colorless crystaline solid or a white powder with a strong odor of ammonia. It is used to make other ammonium compounds, in phapharmaceuticais, in food processing, and for many other uses. It is non-combustible. It is soluble in water, if material Involved in fire Extinguish fire using agent suitable tor type of surrounding (ire (Material itself does not bum or bums with difficulty.) If material not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gioves, and goggles Avoid breathing vapors or dusts Wash away any matenal which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land apill Oig a pit, pond, lagoon, holding area to contain liquid or solid material Cwer solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental conalderattona water apill Neutralize with dilute acid or removable strong acid Environmental considerations - air apiH Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment 25 AMMONIUM CHLORIDE 4966316 ORM-E NA9085 ENVIRONMENTALLY HA2ARDOUS SUBSTANCE (RQ-5000/2270) Ammonium chionde is a white crystalline solid, it is used to make other ammonium compounds, as a soldering flux, as a fertilizer, and for many other uses. It is soluble in water. It is non-combustible. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Buiid dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with dilute acid or removable strong acid AMMONIUM CHROMATE 4963302 ORM*E NA9066 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-IOOO/454) Ammonium chromate is a yellow crystalline solid. It is used in dyeing, photography, chemical analysis, and as a corrosion inhibitor. It is soluble in water. It is non-combustible. If material involved In firs Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) If material not involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental conaideratlone--land epiU Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Add sodium bisulfite Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates If material not involved in fire Keep material out ol water sources and sewers . Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any matenai which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill v0 Dig a pit. pond, lagoon, holding area to contain liquid or solid material 66Cover solids with a plastic sheet to prevent dissolving m ram or fire fighting water Environmental considerations--water spill Neutralize with dilute acid or removable strong acid If dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates AMMONIUM DICHROMATE (AMMONIUM 4916701 BICHROMATE) FLAMMABLE SOUD. OXIDIZING UN1439 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Ammonium dichromate is a bright orange red crystalline solid. It is readily ignited and bums producing a voluminous green residue. If heated in a closed container, the container may rupture due to the decomposition of the matenai. It may also act as a strong oxidizing agent if mixed with or contaminated with combustible matenai. It is soluble in water. If material on fire or involved in fire Flood with water If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--lend apifi Dig a pit pond, lagoon, holding area to contain liquid or solid matenai Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental conaidtcatlona water spill Add sodium bisulfite Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Use mechanical dredges or lifts to remove immobilized masses ol poHutants and precipitates AMMONIUM CTTRATE. DIBASIC 4668320 ORM-E NA9067 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-6000/2270) Ammonium citrate is a white granular solid. It is used in pharma ceuticals and in chemical analysis. It is soluble in water. It is non- combustible. ft material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) 26 AMMONIUM FLUOSORATE 4944128 ORM-B NA9088 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-S00Q/2270) Ammonium fluoborate is a white solid. It is used in metal plating and finishing, it is corrosive to aluminum. If material Involved in fire Extinguish fire using agent suitable for type of surrounding lire (Material itself does not bum or bums with difficulty.) If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary April 198 ttCD 00097ss Personnel protection Keep upwind Wear bools, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any matenat which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving m rain or fire fighting water AMMONIUM FLUORIDE 4944105 ORM-8 UN2505 ENVIRONMENTALLY HA2AROOUS SUBSTANCE (RQ-5000/2270) Ammoumium ituonde is a white crystalline solid. It is used tn chemical analysis, in brewing, and as a preservative for wood. It is soluble in water. It is non-combustible. It is corrosive to aluminum. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gioves. and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area tocontain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in ram or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates AMMONIUM HYDROGEN FLUORIDE SOLUTION 4932307 CORROSIVE MATERIAL. ACIDIC UN2817 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Ammonium hydrogen fluoride solution is the white crystalline solid dissolved in water. It is corrosive to metals and tissue. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Matenai itself does not bum or bums with difficulty.) Use water in flooding quantities a9 log Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved In Are Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled matenai with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear seif-contained breathing apparatus Avoid bodily contact with the matenai Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenai which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing April 1981 MCE 000009769 Environmental considerations--land spill Dig a pit. pond, lagoon, holding area tocontain liquid or solid matenai Dike surlace flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agncultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spiii Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment AMMONIUM HYDROGEN FLUORIDE. SOLID 4932303 CORROSIVE MATERIAL UN1727 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Ammonium hydrogen fluoride, solid is a white crystalline solid. It is used to stenlize food processing equipment, in chemical analysis, for electroplating and for many other uses. It is soluble in water. It is cor rosive to tissue. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Matenai itself does not bum or burns with difficulty.) Use water in flooding quantities as tog Cool all affected containers with ftooding quantities of water Apply water from as far a distance as possible H material not involved in fire Keep matenai out of water sources and sewers Build dikes to contain (low as necessary Neutralize spilled matenai with crushed limestone, soda ash. or lime Personnel protection Wear boots, protective gioves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts o< water or soap and water Avoid breathing fumes from burning material if contact with the matenai anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid matenai Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations enter spill Neutralize with agncultural lime (slaked lime), crushed limestone, or sodium bicarbonate Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates AMMONIUM HYDROXIDE (CONTAINING LESS THAN 4940347 12% AMMONIA) ORM-A NA2672 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Ammonium hydroxide is a colorless to milky colored liquid with an odor of ammonia, it is used in cleaning compounds, to make other chemicals, and for many other uses. It is non-combustible and soluble in water with release of heat It is corrosive to aluminum. It weighs 7.3 pounds per gallon, if materiel involved In fire Extinguish firs using agent suitable for type of surrounding tire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Apply water from as far a distance as possible Use water spray to absorb vapors Continued on nest pogo 27 If material net involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, ano goggles Do not handle broken packages without protective eauipmem Wash away any material which may have contacted the body with copious amounts of water or soaD and water If contact with the material anticioated. wear full protective clothing Environmental considerations---land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liauid with fly ash or cement powder Neutralize with vinegar or other dilute acid Environmental considerations--water spill Neutralize with dilute acid or removable strong acid Environmental considerations--air spill Apply water sQray or mist to knock down vapors AMMONIUM NITRATE (NO ORGANIC COATING) 4918311 OXIDIZER. THERMALLY UNSTABLE UN1942 Ammonium nitrate <s a white crystalline solid. It is used to make ter- tilizers and explosives, and as a nutrient m producing annoiotics and yeast. It is soluble m water. The matenal itself does not readily burn bul will do so >f contaminated by combustible material, it will accelerate the burning of combustible material. Toxic oxides of nitrogen are produced during combustion. If material on fire or involved in fire Flood with water Cool all affected containers with flooding quantities of water Aiply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the booy with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this matenal Approach fire with caution Evacuation if fire becomes uncontrollable--evacuate for a radius of 5000 feet AMMONIUM HYDROXIDE (CONTAINING NOT LESS THAN 12% BUT NOT MORE THAN 44% 4935280 AMMONIA) CORROSIVE MATERIAL NA2672 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Ammonium hydroxide is a colorless to milky colored liquid with an odor of ammonia, it is used in cleaning compounds, to make other chemicals, and for many other uses, it is non-comousttble and soluble m water with release of heat. It is corrosive to metals and tissue. It weighs 7.3 pounds per gallon. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Materia! itself does not bum or burns with difficulty.) Use water in flooding quantities as fog Apply water from as far a distance as possible Use water spray to absorb vapors If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the matenal Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spilt Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with vinegar or other dilute acid Environmental considerations--water spill Neutralize with dilute acid or removable strong acid Environmental considerations--air spill Apply water spray or mist to knock down vapors 28 AMMONIUM NITRATE (ORGANIC COATING) 4918312 OXIDIZER NA1942 THERMALLY UNSTABLE Ammonium nitrate (organic coating) is a white crystalline solid. The individual pieces of the material are coated with some substance in order to make the material more free flowing. It is soluble in water The material itself will not bum but will readily do so if contaminated by combustible material. It will accelerate the burning of combustible material. Toxic oxides of nitrogen are produced dunng combustion of this matenal. If material on fire or involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Approach fire with caution Evacuation If fire becomes uncontrollable--evacuate for a radius of 5000 feet AMMONIUM NITRATE FERTILIZER (CONTAINING NO 4918310 MORE THAN 0.2% CARBON) OXIDIZER UN2067 THERMALLY UNSTABLE Ammonium nitrate fertilizer is a greyish white solid in the form of pnlls. It is soluble in water. The matenal itself does not readily bum but will readily do so if contaminated by combustible material. It will accelerate the burning of combustible material. Toxic oxides of nitrogen are pro duced dunng combustion of this matenal. tf material on fire or invotved In fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible April 1981 MCD 000009770 If material not on fire and not Involved in fire Keep soarks. flames, and otner sources of ignition away Keep material out of water sources and sewers Personnel protection Wear coots, protective gloves, and goggles Do not candle broken packages without protective eauipment Wash away any material which may have contacted the body with copious amounts of water or soao ana water Wear seif-comamed breathing aoparatus when fighting fires involv ing this material Approach tire with caution Evacuation If fire oecomes uncontrollable--evacuate for a radius o* 5000 feet AMMONIUM NITRATE MIXED FERTILIZER 491B705 OXIDIZER UN2069 Ammonium nitrate mixed fertilizer is a variable colored granular solid. The material is soluble in water. It is noncombustible but it will accelerate the burning of combustible materials. If large quantities of the material are involved in the fire or the combustible material is finely divided an explosion may result. Prolonged exposure of the material to fire or heat may result in an exoiosion. Toxic oxides of nitrogen are produced in fires involving this material. If material on fire or involved In fire Flood with water Cool all affected containers with flooding quantities of waier Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Approach (ire with caution Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet AMMONIUM NITRATE-CARBONATE MIXTURE 4918734 OXIDIZER UN208S Ammonium nitrate-carbonate is a greyish white granular solid. It is the mixture of ammonium nitrate and calcium carbonate, i.e. limestone. The ammonium nitrate is soluble in water: the calcium carbonate is not. The material itself is noncombustible, but it will accelerate the burning of combustible materials. Toxic oxides of nitrogen are produced in tires involving this matenal. If material on fire or Involved In fire Flood with water Apply water from as far a distance as possible if materiel not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out ol water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts ol water or soap and water Wear self-contained breathing apparatus when fighting tires involv ing this matenal April 1981 AMMONIUM NITRATE-FUEL OIL MIXTURE (CONTAINING ONLY PRILLED AMMONIUM NITRATE ANO FUEL OIL) BLASTING AGENT 4902910 Ammonium nitrate-fuel oil mixture is a browmsh-btack granular solid, it is used for blasting rock and in some types ol mining, it will accelerate the burning ol combustible materials. The ammonium nitrate is soluble in water, it large quantities of this material are involved in a fire, it may explode. If material on fire or involved in fire Low order exolosive potential Do not fight fires in a cargo of blasting agents Evacuate area and let bum If material not on fire end not Involved in fire Keep sparks, tlames. and other sources of ignition away Keep spilled material wet Wet spilled material before picking it up Do not attempt to sweep up dry material Personnel protection Avoid breathing dusts, and fumes from burning matenal Wear protective gloves and goggles Do not handle broken packages without protective eauipment Wash away any material which may have contacted the body with copious amounts of water or soaD and water Wear self-contained breathing apparatus when fighting fires involv ing this matenal Evacuation II the matenal is on fire or involved in lire evacuate for a radius of 2500 feet AMMONIUM NITRATE-PHOSPHATE 4918704 OXIDIZER UN2070 Ammonium nitrate-phosphate is a white granular solid, it is used as a fertilizer, it is soluble in water. It is noncombustibie but it will accelerate the burning of combustible materials. If large quantities of the material are involved in the fire or the combustible material is finely divided an explosion may result. Prolonged exposure of the matenal to fire or heat may result in an explosion. Toxic oxides of nitrogen are produced in fires involving this material. If material on Are or involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on Are end not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet 29 ooooo^71 AMMONIUM NITRATE. MAGNESIA AND PULP 4918703 MIXTURE (OXIDIZING MATERIAL. N.O.S OXIDIZER UN1479 Ammonium nitrate, magnesia and pulo mixture is a white to tight yellow granular solid. The material is soluDie in water. It is non-comoustibie Out it wilt accelerate the burning o< combustible materials. If large Quantities of the material are involved in the fire or the combustible material is finely divided an exo'osion may result. Prolonged exposure of the ma terial to fire or heat may result in an explosion. Toxic oxides of nitrogen are produced in fires involving this material. If material on fire or involved in fire Flood with water Coot all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet AMMONIUM NITRATE. SODIUM NITRATE MIXTURE 4918702 (OXIOIZING MATERIAL. N.O.SJ OXIDIZER UNI 479 Ammonium nitrate, sodium nitrate mixture is a white to light greyish granular solid. The material is soluble m water. It is non-combustible but it will accelerate the burning of combustible materials, if large quantities of the material are involved in the fire or the combustible matenal Is finely divided an explosion may result. Prolonged exposure of the ma tenal to fire or heat may result in an explosion. Toxic oxides of nitrogen are produced in fires involving this material. If material on fire or Involved in fire Flood with water Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Approach fire with caution Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet AMMONIUM NITRATE, SOLUTION (CONTAINING NOT 4918774 LESS THAN 15% WATER) OXIOIZER UN2426 Ammonium nitrate solution is the white crystals dissolved in water. It is used to make fertilizers and explosives. Though the material itself is noncombusbbie it will accelerate the burning of combustible materials. Toxic oxides of nitrogen are produced in fires involving this matenal. If materiel on fire or involved In Are Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers 30 o Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective eauipment Wash away any material which may have contacted the body wit1 copious amounts of water or soap and water Wear self-contained breathing apparatus wnen lighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a racius of 2500 feet AMMONIUM OXALATE 4940350 ORM-A NA2449 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000'2270) Ammonium oxalate is a colorless crystalline soud it is used as a reagent in chemical analysis, for rust and scaie removai. and for many other uses. It is soluble in water, it is non-combustible. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) if material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap ana water Environmental consideration#--land spill Dig a pit. pond, lagoon, holding area to contain iiauid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or tire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses / pollutants and precipitates AMMONIUM PERCHLORATE 4901550 CLASS A EXPLOSIVE Ammonium perchlorate is a white crystalline solid It is used in making certain solid rocket propellants. It is smaller than 15 micron size or larger sized material that has been dried oi its water of crystallization. The material itself does not readily bum, but will do so if contaminated by combustible material. Fires involving ammonium percniorate an a com bustible matenal may result in an explosion. H materiel on fire or involved In fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let bum If material not on fire and not involved in fire Keep sparks, flamas. and other sources of ignition away Keep spilled material wet Wat spilled material before picking it up Do not attempt to sweep up dry material Keep material out ol water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Wear protective gloves and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or so^> and water Wear self-contained breathing apparatus when fighting fires involv ing this matenal Evacuation If the material is on fire or involved in fire evacuate for a radius of 5000 feet April 198 AMMONIUM PERCHLORATE 4918320 OXIDIZER. THERMALLY UNSTABLE UN1442 Ammonium perchlorate is a white crystalline solid that is soluble in water. It is used to make rocket propellants, explosives and for other uses. Ammonium oerchiorate that <$ smaller than 15 micron size or larger sized material that has been dried of its water of crystallization is classed as a class a explosive. The material itself does not readily burn, but will do so if contaminated by combustible material. Fires in volving ammonium perchlorate and combustible material may result m an explosion. Prolonged exposure of ammonium perchlorate and or its containers to heat or tire may result m an explosion. If materiel on fire or involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as tar a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate tor a radius of 5000 feet AMMONIUM PERMANGANATE 4918322 OXIOIZER, THERMALLY UNSTABLE NA9190 Ammonium permanganate is a violet brown or dark purple crystalline solid. It is soluble in water. The material itself does not.bum. It accel erates the burning of combustible materials. Contamination by some combustible matenals may result in spontaneous ignition. Prolonged exposure of ammonium permanganate and or its containers to fire or heat may result in an explosion. If material on fira or Invoivad In fira Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fira and not invoivad in fira Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matehai which may have contacted the body with copious amounts of water or soap and water Evacuation if fire becomes uncontrollable--evacuate for a radius of 2500 feet AMMONIUM PICRATE, WET (WITH 10% OR MORE 4917125 WATER) FLAMMABLE SOUO UN1310 Ammonium picrate. wet is a slurry or sludge of yellow crystals. Am monium picrate dry is a high explosive, dry 8 is easily ignited and bums vigorously. If large quantities are involved an explosion may result. The wet material will bum. though it may require some effort to ignite. Toxic oxides of nitrogen are produced during combustion. If material on fire or Involved In fire Dangerously explosive Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible April 1981 If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers - Keep spilled matehai wet Oo not attempt to sweep up dry matenal Personnel protection Wear boots, protective gloves, and goggles Do not handle broxen packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this matenal Evacuation If fire becomes uncontrollable--evacuate for a radius of 5000 feet AMMONIUM S1LICOFLUORIDE 4944135 ORM-A UN2854 ENVIRONMENTALLY HAZAROOUS SUBSTANCE (RO-1000/454) Ammonium silicofluoride is a white crystaline solid. It is used as a disentectant. in etching glass, metal casting, and electroplating. It is soluble in water, it is non-combustible. It is corrosive to aluminum. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Matenal itself does not burn or burns with difficulty.) If material not Invoivad in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any matenal which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water AMMONIUM SULFAMATE 4986732 ORM-E NA9089 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RG-5000/2270) Ammonium sulfamate is a white crystalline solid. II is used to flame proof fabrics and papers, in weed or brush killing products, and for other uses, it is soluble in water. It is non-combustible. If material involved In fire Extinguish fira using agent suitable for type of surrounding fire (Material itsatf does not bum or bums with difficulty.) If material not Invoivad In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any matehai which may have contacted the body with copious amounts of water or soap and water Environmental considerations land spill Dig a pit pond, lagoon, holding area to contain liquid or solid matehai Cmer solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations- water spill Add calcium hypochlorita Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates 31 HCT) 00009773 AMMONIUM SULFIDE SOLUTION FLAMMABLE LIQUID UN2683 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Ammonium sulfide solution is tne yellow crystalline material dissolved m a liquid, usually water It has the odor of rotten eggs. Ammonium suifide is slowly decomposed Oy moisture giving off hydrogen sulfide, a `lammaOie gas. it weighs 9.0 pounds oer gallon, tf material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may oe ineffective Cooi all affected containers with flooding quantities of water Apoly water from as far a distance as possible Use alcohol" foam, carbon dioxide or dry chemical if material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop teak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid matenal Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill Add calcium hypochlorite Adjust ph to neutral (ph*7) Environmental considerations--air spill Apply water spray or mist to knock down vapors Evolves flammable hydrogen sulfide gas on contact with acids AMMONIUM SULFITE 4966332 ORM-E NA9090 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Ammonium sulfite is a colorless crystaline solid. It is used in the manufacture of other chemicals, in medicine, and photography. It is soluble in water. It is non-combustible. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) If maferial not involved in fire Keep matenal out of water sources and sewers Build dikes to contain flow as necessary Personnet protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any matenal which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Add calcium hypochlorite Adjust ph to neutral (ph-7) Environmental considerations--air spill Evolves flammable hydrogen sulfide gas on contact with acids MCI) 000009774 AMMONIUM TARTRATE 4966336 ORM-E NA9091 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000 2270} Ammonium tartrate is a white crystalline solid. it is usea to manufacture `abrics and in medicine, it is soluble in water It is non-comoustibie. If material involved in fire Extinguish fre using agent suitable for type of sumourdina fire (Material itself does not bum or burns with difficulty > If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwinq Wear boots, orotective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the Dody with codious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain hautd or solid material Cover solids with a plastic sheet to prevent dissolving in ram or fire fighting water Environmental considerations--water spill Neutralize with dilute acid or removable strong acid If dissolved, apply activated carbon at ten times the spilled amount m region of iQopm or greater concentration Use mechanical dredges or lifts to remove immopdized masses of pollutants and precipitates AMMONIUM THIOCYANATE CRYSTALS (AMMONIUM 4966738 THIOCYANATE) ORM-E NA9092 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Ammonium thiocyanate is a colorless crystalline solid, it is used in chemical analysis, in photography, as a fertilizer, and for many other uses. It is soluble in water. It is non-combustible. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.} If material not involved in fire Keep matenal out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--watar spill Neutralize with dilute acid or removable strong acid Add calcium hypochlorite Use mechanical dredges or lifts to remove immobilized masses ol pollutants and precipitates AMMONIUM THIOCYANATE UOUOR (AMMONIUM 4966744 THIOCYANATE) ORM-E NA9092 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Ammonium thiocyanate liquor is the colorless crystalline solid dis solved m water. It is used to make other chemicals, fertilizer, and lor many other uses. It is non-combustible. If materiel involved in fire Extinguish fire using agent suitable for type of surrounding fire (Mafenai itself does not bum or bums with difficulty.) April 1981 If material not involved in fire Keep material out of water sources ana sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear ooots. protective gloves, and goggles Avoid breathing vaoors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, tagoon. noidmg area 10 contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill Neutralize with dilute acid or removable strong acid Add calcium hypochlortte Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates AMMONIUM THIOSULFATE 4966750 ORM-E NA9093 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Ammonium thiosulfate is a white crystalline solid. It is used in pho tography. in chemical analysis, and for many other uses. It is soluble in water It is non-comOustiDle. If materiel involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) If material not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear ooots. protective gloves, and goggles Avoid breathing vapors or dusts Wash away any matenal which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid matenal Cover solids with a plastic sheet to prevent dissolving in ram or fire fighting water Environmental consideration*--water spill Neutralize with dilute acid or removable strong add if dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates AMMONIUM THIOSULFATE SOLUTION (AMMONIUM 4966756 THIOSULFATE) ORM-E NA9093 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Ammonium thiosulfate solution is (tie white crystalline solid dissoived in water, it is used in photography and for many other usee. It is non- combustible. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any matenal which may have contacted the body with copious amounts of water or soap and water April 1981 Environmental consideration*--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill Neutralize with dilute acid or removaDle strong acid If dissolved, apply activated carOon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates AMMUNITION FOR CANNON WITH EMPTY 4902110 PROJECTILE CLASS B EXPLOSIVE Ammunition for cannon with empty projectile is fixed ammunition which is an assembled unit consisting of the cartndge case containing the propelling charge and primer with empty projectiles. Under prolonged exposure to fire or heat the material can explode. If material on tire or involved in fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let burn If materiel not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus wnen fighting tires involv ing this material Evacuation If the matenal is on fire or invotved in fire evacuate for a radius of 2500 feet AMMUNITION FOR CANNON WITH EXPLOSIVE PROJECTILE CLASS A EXPLOSIVE 4901105 Ammunition for cannon with explosive projectile is fixed ammunition which is an assembled unit consisting of a cartndge case containing the propelling charge and primer and explosive projectile containing a high explosive. It may be shipped either fuzed or unfuzed. The fuzed am munition may be sensitive to shock or mechanical impact. Under pro longed exposure to heat or fire it can explode, tl material on fire or Involved in fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let bum If materiel not on fire and not involved In fire Keep sparks. Ilames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning matenal Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the matenal is on fire or involved in fire evacuate for a radius of 5000 feet AMMUNITION FOR CANNON WITH GAS PROJECTILE 4901110 CLASS A EXPLOSIVE Ammunition for cannon with gas projectile is fixed ammunition which is an assembled unit consisting ot a cartridge case containing the pro pelling charge and primer, and a projectile containing a gas and a burster. It may ba shipped either fuzed or unfuzed. The fuzed ammunition may be sensitive to shock or mechanical impact. Under prolonged exposure to fire or heat it can explode. Continued on nmxi page <16 33 It material on fire or involved in fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let burn If material not on fire and not involved in fire Keeo soarks. flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear seif-contameo breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved m fire evacuate for a radius of 5000 feet AMMUNITION FOR CANNON WITH ILLUMINATING 4901115 PROJECTILE CLASS A EXPLOSIVE Ammunition for cannon with illuminating projectile is fixed ammunition which is an assembled unit consisting of a cartridge case containing the propelling charge and primer, and a proiectile containing a pyrotechnic composition and burster. It may be either shipped fuzed or unfuzed. The fuzed ammunition may be sensitive to shock or mechanical impact. Under prolonged exposure to fire or heat it can explode. If material on fire or involved in fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let bum If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate lor a radius of 5000 feet AMMUNITION FOR CANNON WITH INERT LOADED 4902120 PROJECTILE CLASS B EXPLOSIVE Ammunition for cannon with inert loaded projectile is fixed ammunition which is an assembled unit consisting of the cartridge case containing the propelling charge and pnmer with inert-loaded projectile. Under pro longed exposure to fire or heat the material can explode. If material on fira or involved in fire Dangerously explosive Do not tight fires in a cargo of explosives Evacuate area and let bum If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this matenal Evacuation if the material is on fire or involved in tire evacuate for a radius of 2500 feet AMMUNITION FOR CANNON WITH SMOKE 4901125 PROJECTILE CLASS A EXPLOSIVE Ammunition for cannon with smoke projectile is fixed ammunition con sisting of a cartridge case containing a propelling charge and primer, and a projectile containing a smoke producing composition and a burster It may either be shipped fuzed or unfuzed. The fuzed ammunition may be sensitive to shock or mechanical impact. Under prolonged exposure to heat or fire it can explode. H material on fire or involved in fire Dangerously explosive Do not tight fires in a cargo of explosives Evacuate area and let burn It material not on fira and not Involved in fire Keep sparks, (lames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing (his matenal Evacuation If the material is on fire or involved in fire evacuate for a radius of 5000 feet AMMUNITION FOR CANNON WITH INCENDIARY 4901120 PROJECTILE CLASS A EXPLOSIVE Ammunition for cannon with incendiary projectile is fixed ammunition consisting of a cartridge case containing a propelling charge and a pnmer and a projectile containing a pyrotechnic composition and a burster. It may be shipped fuzed or unfuzed. The fuzed ammunition may be sen sitive to shock or mechanical impact Under prolonged exposure to heat or fire it can explode. If material on fire or Involved in Are Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let bum If material not on fira and not Involved in fira Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning matenal Wear self-contained breathing apparatus when fighting fires involv ing this matenal Evacuation If the matenal is on fire or involved in fire evacuate for a radius of 5000 feet 34 0^ OO'o & AMMUNITION FOR CANNON WITH SOUO 4902130 PROJECTILE CLASS B EXPLOSIVE Ammunition for cannon with solid projectile is fixed ammunition which is an assembled unit consisting of the cartridge case containing the propelling charge and primer with solid projectile. Under prolonged ex posure to fire or heat the material can explode. If material on fire or Involved in fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let bum If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear seif-contained breathing apparatus when fighting tires involv ing this matenal Evacuation If the matenal is on fire or involved in fire evacuate for a radius of 2500 feet April 1961 AMMUNITION FOR CANNON WITH TEAR GAS 490212? PROJECTILE CLASS B EXPLOSIVE Ammunition for cannon with tear gas projectile is fixed ammunition which is an assembled unit consisting of a cartridge case containing the orooelimg charge and onmer. and a projectile containing the tear gas ana a burster. It may be shipped either fuzed or unfuzed. The fuzed ammunition may be sensitive to shock or mechanical impact. Under prolonged exposure to fire or heat it can explode and release tear gas. If material on fire or involved in fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let burn If materiel not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning matenal Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved m fire evacuate for a radius of 2500 feet AMMUNITION FOR SMALL ARMS WITH EXPLOSIVE PROJECTILE 4901130 CLASS A EXPLOSIVE Ammunition for small arms with explosive projectile is fixed ammu nition of less than 20 mm which consists of a cartridge case containing a propelling charge and primer, and a projectile containing a high ex plosive. It may De shipped either fuzed or unfuzed. The fuzed ammunition may be sensitive to shock or mechanical impact. Under prolonged ex posure to fire it can exDiode. if materiel on fire or involved In fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let burn If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this matenat Evacuation if the material is on fire or involved in fire evacuate tor a radius o< 5000 feet AMMUNITION FOR CANNON WITH TEAR GAS 4901127 PROJECTILE CLASS A EXPLOSIVE Ammunition for cannon with tear gas projectile is fixed ammunition which is an assembled unit consisting ol a cartridge case containing tear gas and a burster, ft may be shipped either Iu2ed or unfuzed. The fuzed ammunition may be sensitive to shock or mechanical impact. Under prolonged exposure to fire or heat it can explode and release tear gas. it material on tire or involved In tire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let bum If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting tires involv ing this material Evacuation If the material is on fire or involved in fire evacuate tor a radius ol 5000 feet AMMUNITION FOR SMALL-ARMS WITH INCENOIARY 4901135 PROJECTILE CLASS A EXPLOSIVE Ammunition for small-arms with incendiary projectile is fixed ammu nition of less than 20mm consisting of a cartridge case containing a propelling charge and primer, and a projectile containing a pyrotechnic charge, it may De either shipped fuzed or unfuzed. The fuzed ammunition may be sensitive to shock or mechanical impact. Under prolonged ex posure to heat or fire it can explode, if material on fire or involved In fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let bum If materiel not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this matenal Evacuation If the material is on fire or involved in fire evacuate for a radius of 5000 feet AMMUNITION FOR CANNON WITHOUT PROJECTILE 4902140 CLASS B EXPLOSIVE Ammunition for cannon without projectile is fixed ammunition which is a unit consisting of the cartridge case containing the propelling charge and primer without projectile. Under prolonged exposure to fire or heat the matenal can explode. If material on tire or involved In fire Dangerously explosive Do not tight fires m a cargo of explosives Evacuate area and let bum If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning matsrial Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet AMMUNITION, CHEMICAL EXPLOSIVE, WITH 4901167 IRRITANT CLASS A EXPLOSIVE Ammunition, chemical, explosive, with irritant may be any type of projectile, bomb, grenade, etc. It contains a matenat classified as an irritant and a burster. Under prolonged exposure to heat or fire it can explode. The irritant causes discomforting effects such as tearing of me eyes or a choking sensation of the respiratory system horn inhalation or contact with small quantities. The irritant may or may not be combustible. K material on fire or Involved In fire Dangerously explosive Do not tight tires in a cargo of explosives Evacuate area and let bum If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Continued on next pege April 1981 q0 oo 35 Personnel protection Avoid breatnmg dusts, and fumes from burning material Wear self-contained breathing aooaratus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 5000 feet AMMUNITION. CHEMICAL. EXPLOSIVE. WITH POISON 4901165 A MATERIAL CLASS A EXPLOSIVE Ammunition, chemical, exolosive. with poison a material may be any tyoe of oroiectile bomb, grenade, etc. It contains a material classified as ooison a and a burster. Under prolonged exposure to heat or fire it can explode. The poison a material may cause death by inhalation or skin absorption of very small quantities. The poison a material may or may not be combustible. If material on fire or involved In fire Dangerously explosive Do not fight tires in a cargo of explosives Evacuate area and let burn If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting tires involv ing this material Evacuation If the material ts on fire or involved in fire evacuate for a radius of 5000 feet AMMUNITION. CHEMICAL. EXPLOSIVE, WITH POISON 4901166 B MATERIAL CLASS A EXPLOSIVE Ammunition, chemical, explosive, with poison b material may be any type of projectile, bomb, grenade, etc. It contains a material classified as ooison b and a burster. Under prolonged exposure to heat or fire it can explode. The poison b matenal may cause death by inhalation, skin absorption, or ingestion of small quantities. The poison b material may not be combustible. If material on fire or involved in fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let burn If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning matenal Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the matenal is on fire or involved in fire evacuate for a radius of 5000 feet AMYL ACETATE 4909111 FLAMMABLE LIQUID UN1104 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Amyl acetate is a clear colorless liquid having a banana like odor. The flash point may vary from 65 deg. F. to 95 deg. F. It is lighter than water and slightly soluble in water. The vapors are heavier than air. it weighs 7 2 pounds per gallon. If material on fire or involved In Ore Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective 36 009 oo Cool ail affected containers with flooding Quantities of water Aoply water from as far a distance as possible "Use alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep SDarks. flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vaoors and dilute standing pools of liquid Personnel protection ACoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liouid or soiid material Oike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash. cement powder, sawdust, or com mercial sorbents Apply fluorocarbon-water foam to dimmish vapor and tire hazard Environmental considerations--water spill Use natural barriers or oil spill control booms to limit spill motion Use surface active agent (eg. detergent, soaps, alcohols) to com press and thicken spiiled matenal Inject universal ' gelling agent to solidify encircled spill and increase effectiveness of booms If dissolved, apply activated carbon at ten times the spilled amount m region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental consideration*--air spill Apply water spray or mist to knock down vapors AMYL ACID PHOSPHATE 4933360 CORROSIVE MATERIAL UN2819 Amyl acid phosphate is a colorless liquid. It is used as a curing agent in paints and plastics and is used in the manufacture of synthetic fibers. It will bum though it may take some effort to ignite. It is heavier than water and is insoluble in water. It is corrosive to metals and tissue. Its vapors are heavier than air. If material on fire or involved in fire Use dry chemical, carbon dioxide, or dry sand Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors If material not on fir* and not involved in fir* Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any malarial which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing April 1961 TERT-AMYL ALCOHOL (ALCOHOL, N.O.S.) 4909112 FLAMMABLE LlQUIO UN1987 Tert-amyi aicohoi is a dear colorless liquid with a camphor like odor. II has a flash point of 67 deg. F It is lighter than water and slightly soiupie in water. Its vaoors are heavier than air. if material on tire or involved in fire Do not extinguish fire unless flow can be stopped Use water m flooding Quantities as tog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apoiy water from as far a distance as possible Use alcohol foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparxs. flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water soray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective eauipmeni Wash away any material which may have contacted the body with copious amounts ot water or soap ana water N-SEC-AMYL ALCOHOL (ALCOHOL. N.O.S.) 4909107 FLAMMABLE LIQUID UN1967 N-sec-amyl alcohol is a clear colorless fiauid. It has a flash point of 94 deg. F. It is lighter than water and slightly soluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts of water or soap and water AMYL CHLORIDE 4909115 FLAMMABLE LIQUID UN1107 Amyl chtonde is a clear, cotorlesa liquid. The flash point may vary from 35 deg. F. to 54 deg. F. It is lighter than water and insoluble tn water. Its vapors are heavier than air. If material on firs or involved tn fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as tog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers April 1961 Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep ubwmd Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material AMYL FORMATE 4909310 FLAMMABLE LlQUIO UN1109 Amyl formate is a clear colorless liquid with a plum like odor. It has a flash point of 79 deg. F. It is lighter than water and insoluble m water. Its vaoors are heavier than air. If materiel on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water AMYL MERCAPTAN 4909119 FLAMMABLE LIQUID UNI 111 Amyl mercaptan is s clear, colorless to light yellow liquid with an offensive odor. It has a flash point of 65 deg. F. It is lighter than water and insoluble in water, its vapors are lighter than water. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool aH affected containers with flooding quantities of water Apply water from as far a distance as possible Use ' alcohol" foam, carbon dioxide or dry chemical If materiel not on fire end not involved in fire Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting tires involv ing this matenal 000009779 MCD 37 AMYL NITRATE (COMBUSTIBLE LIQUID, N.O.S.) 4913107 COMBUSTIBLE LIQUID, OXIDYZING NA1993 Amyi nitrate is a clear colorless liauid with an ether-like odor, it is used as an aaditive tor diesel fuels. It has a flash ooint of f 18 deg. F. It will accelerate the Ournmg of comoustible materials. It weighs about the same as water and is insoluble in water. Its vapors are heavier than air. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as tog Solid streams of water may be ineffective Cool all affected containers with flooding Quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire end not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenal which may have contacted the body with cooious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material TERT-AMYL PEROXY-2-ETHYLHEXANOATE. 4919108 (TECHNICALLY PURE) ORGANIC PEROXIDE UN2899 Tert-amyl peroxy-2-ethylhexanoate. (technically Dure) is a colorless to pale yellow liquid. It is used to manufacture paints, olastics. and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite: but once ignited, it will burn with increasing rapidity as the fire progresses If spilled on combustible materials, spontaneous ignition of the matenal may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burn ing of combustible materials. Under prolonged exposure to fire or heat containers of the material may expiooe. if material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If materiel not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled matenal before picking it uo Personnel protection Avoid breathing Ousts, and fumes from burning material Avoid bodily Contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet AMYL NITRITE 4909121 FLAMMABLE LIQUID UN1113 Amyl nitrite is a clear colorless to yellowish liquid with an ethereal, fruity odor. It is used in medicine and to make other chemicals. It has a flash ooint of 50 deg. F. It is lighter than water and slightly soluble in water. Its vapors are heavier than air. Toxic oxides of nitrogen are produced during combustion of this material, if material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cod ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical if material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avdd breathing vapors Keep upwind Wear boots, protective gloves, and gogglee Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus whan fighting fires invdv- ing this material 38 AMYL PHENOL (CORROSIVE LIQUID, N.O.S.) 4935827 CORROSIVE MATERIAL, BASIC UNI 760 Amyi phenol is a colorless to straw colored liquid, it is slightly soluble in water. It may bum though it may require some effort to ignite. It is corrosive to tissue. It material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use "alcohol'1 foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the matenal Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any malarial which may hava contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting tires involv ing this material If contact with the material anticipated, wear full protective clothing April 198. MCD 000009780 Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain iiguld or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with vinegar or other dilute acid Environmental considerations--water spill Neutralize with dilute acid or removable strong acid if dissolved, aopfy activated carbon at ten times the spilled amount m region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knocxoown water ts corrosive or toxic and should be diked for containment ANILINE OIL. LIQUID 4921410 POISON B. COMBUSTIBLE UN1547 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-IOOO/454) Aniline on. liquid is a colorless to brown oily liquid with a characteristic odor. It is used to manufacture other chemicals, especially dyes, pho tographic chemicals, agricultural chemicals and others. It has a flash oomt of 158 deg. F. It can react with toluene diisocyanate with the reaction leading to possible ignition. It is heavier than water and slightly soluble in water and its vapors are heavier than air. It 15 toxic by skin absorption and inhalation. Toxic oxides of nitrogen are produced during combustion of this material. It weighs 8.5 pounds per gallon. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire end not involved In fire Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If matenal leaking (not on fire), downwind evacuation must be considered Environmental consideration*--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid matenal Oike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fty ash or cement powder Apply "universal" gelling agent to imrnobiHze spill Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom if dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Remove trapped matenal with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates 40 *Qt, o0 Environmental considerations--air spill Apply waier spray or mist to knock down vaoors Combustion products include corrosive or toxic vaoors ANILINE OIL. LIQUID (ANILINE SLUDGE FOR 4921492 FURNACE USE) POISON B UN1547 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000 454) Aniline sludge is a thick brown liquid with a characteristic odor it is comoOstibie though it may require some effort to ignite it is very slightly soluble in water. It is toxic by inhalation ana by skin absorption It weighs 8.5 pounds per gallon. If material on fire or involved in fire Do not extinguish fire unless flow can be stooped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding Quantities of water Apply water from as far a distance as possipie Use foam, carbon dioxide or dry chemical Use water spray to absorb vapors If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective eauioment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If matenal leaking (not on fire), downwind evacuation must be considered Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain houid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers lo trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount m region of lOppm or greater concentration Remove trapped matenal with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors ANIMAL OR POULTRY DIP. NEC. UOUIO 4923905 (POISONOUS LIQUID, N.O.S.) POISON B NA2S10 Animal or poultry dip. nec liquid is vanable colored liquid. It is soluble in water and is toxic by ingestion. If material on firs or involved In Are Use water in flooding quantities as log Cool all affected containers with flooding quantities of water Use foam, carbon dioxide or dry chemical If material not on fire end not involved in fire Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers Build dikes to contain flow as necessary April 1981 AMYL TRICHLOROSILANE 4934210 CORROSIVE MATERIAL. ACIDIC. COMBUSTIBLE UNI 729 Amyl trtchiorosilane is a colorless to yellow liquid with a pungent odor, it is combustible and has a flash pome of 145 deg. F. it is readily de* composed oy water to hydrochloric acid with evolution of heat. It is corrosive to metals and tissue. If material on fire or Involved in fire Use dry chemical, caroon dioxide, or dry sand Do not use water on material itself If large quantities of comoustioles are involved, use water m flooding quantities as spray and fog Use water spray to aosoro vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knockdown vapors Do not use water on matenal itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing AMYLENE 4909109 FLAMMABLE LIQUID UN1109 Amytenes are clear colorless liquids with a petroteum-iike odor. The are volatile liquids having tiash points of below 0 deg. F. They are iigtite than water and insoluble in water. Their vapors are heavier than air. If materiel on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If materiel not on fire and not involved In fire Keep matenal out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any malarial which may have contacted the body with copious amounts of water or soap and water Evacuation If tire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet if matenal leaking (not on tire), downwind evacuation must be considered AMYLAMINE 4909195 FLAMMABLE LIQUID UN1106 Amylamine is a clear colorless liquid with an ammonia-like odor, it is used as a corrosion inhibitor, solvent, flotation agent and in the manu facture of additional chemicals. It has a flash point of 30 deg. F. It is irritating to the eyes and resoiratory system. It is lighter than water and soluble m water. Its vapors are heavier than air. Toxic oxides Of nitrogen are produced during combustion of this matenal. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in Hooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol" foam, carbon dioxide or dry chemical if material not on Are and not Involved In Are Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts of water or soap and water Wear seif-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective dothing April 1961 ANHYDROUS AMMONIA 4904210 NONFLAMMABLE GAS. CORROSIVE UN1005 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100/45.4) Anhydrous ammonia is a clear colorless gas with a characteristic odor It is used as a fertilizer, as a refrigerant, and in the manufacture of other chemicals. Although it is classed as a nonflammable gas, it will burn within certain vapor concentration limits, and the fire hazard will increase in the presence of oil or other combustible materials, its combustibility" is definitely not a common problem in the event of leakage. It is shipped as a liquid under pressure. Contact with the liquid can cause frostbite. It is soluble in water forming a corrosive liquid. Although ammonia is lighter than air, the vapors from a leak inrtiaity hug the ground. It weighs 5.7 pounds per gallon, tf material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use water spray to absorb vapors If matenal not involved In Are Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear seif-contained breathing apparatus Avoid bodily contact with the material Waar boots, protective gloves, and gas tight goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the matenal anticipated, wear full protective clothing Evacuation If material leaking (not on fire), downwind evacuation must be considered MCD 000009781 on next page 39 Personnel protection Avoid breathing vapors Keep uowind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gioves, and goggles Do not handle broKen packages without protective equipment Wash away any material which may have contacted the oody with copious amounts of water or soao and water If contact with the material anticipated, wear full protective clothing ANIMAL OR POULTRY OIP. NEC. OTHER THAN 4923906 LIQUID (POISONOUS SOLID. N.O.S.) POISON B NA2B11 Animal or poultry dip. nec. other than liquid is a variable colored solid. It is soluble in water. It is toxic by ingestion, and by inhalation of dusts. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Materia* itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved In fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when lighting fires involv ing this material It contact with the material anticipated, wear full protective clothing ANIMAL OR POULTRY FEED CHARCOAL. CRUSHED 4917386 OR GROUND. (FLAMMABLE SOLID. N.O.S.) FLAMMABLE SOLID UNI 325 Animal or poultry feed charcoal, crushed or ground i$ a granular black solid. It is fairly easily ignited. The main hazard in transportation is that of spontaneous heating if the charcoal has not been properly cooled after manufacture or if it becomes wet. If material on fire or involved in fire Remove burning material from load if safe and practicable to do so Use dry chemical or carbon dioxide Use water only if flooding quantities are available If material not on fire and not involved in fire Keep sparks, llames. and other sources of ignition away Keep material dry ANISOYL CHLORIDE 4931710 CORROSIVE MATERIAL. ACIDIC UN1729 Anisoyi chloride is an amber colored crystalline solid becoming a liquid at 72 deg. F. The liquid fumes in air. It is decomposed by water to give hydrochloric acid and inaotubte anisic acid with release of heat, tt is corrosive to metals and skin, if material on fire or involved in fire Use dry chemical or carbon dioxide Do not use water on matenal itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with Hooding quantities of water Apply water from as far a distance as possible April 1981 If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources ana sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on matenal itself Neutralize spilled matenal with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the matenal Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts o< water or soap and water It contact with the material anticipated, wear full protective clothing ANTI-FREEZE ALCOHOLS (ALCOHOL, N.O.S.) 4910402 FLAMMABLE LIQUID UNI 987 Anti-freeze aicohols are materials containing a solvent having a closed cup flash point of less than 100 deg. F. The hazard is flammability. If material on fire or involved in fire Do not extinguish tire unless flow can be stopped Use water m flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with Hooding Quantities o( water Apply water from as far a distance as possible Use `alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ANTI-FREEZE ALCOHOLS (ALCOHOL, N.O.S.) 4915402 COMBUSTIBLE UQUIO UNI 987 Anti-freeze alcohols are materials containing a solvent having a closed cup flash point between 100 and 199 deg. F. They are generally lighter than water and soluble in water. If material on fira or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'' foam, carbon dioxide or dry chemical If material not on fire end not Involved in Are Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to disperse vapors and dilute standing pools of liquid Continued on next page mcd 000009783 Personnel protection Avoid breathing vapors Keep upwind Wear ooots. protective gloves, and goggles Dc not handle broken packages without protective equipment V. isn away any material which may have contacted the body with copious amounts of water or soap and water ANTI-FREEZE COMPOUND. LIQUID 4910105 FLAMMA8LE LIQUID NA1142 Anti-freeze compounds, liquid have Hash points of less than 100 deg. F. They are water soluble and their vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Jf material not on fire end not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear Ooots. protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ANTI-FREEZE PREPARATION. LIQUID 4910106 FLAMMABLE LIQUID NA1142 Anti-freeze preparation, liquid have flash points of less than 100 deg. F. It is soluble m water. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers Build dikes to contain How as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Oo not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ANTIFREEZE COMPOUND LIQUID 491S10S COMBUSTIBLE LIQUID NA1142 Anti-freeze compounds, liquid which are classed as combustible liquid have flash points between 1X and 199 deg. F. They are soluble in waier and their vapors are heavier than air. if materiel on fire or involved in fire Do not extinguish fire unless How can be stopped Use water in flooding quantities as fog 42 A* O.0.'0.' 0,0>9 Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources Of ignition away Keep matenal out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Use water spray 10 disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ANTIFREEZE PREPARATION. LIQUID 4915106 COMBUSTIBLE LIQUID NA1142 Anti-freeze preparation, liquid which are classed as combustible liquid have flash points between 100 and 199 deg. F. It is soluble in water and its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in Hooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as tar a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ANTIMINOUS CHLORIDE (See ANTIMONY TRICHLORIDE 4932316) ANTIMONY PENTACHLORIOE 4932310 CORROSIVE MATERIAL. ACUNC UNI 730 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Antimony pentachioride is a reddish-yeiiow fuming liquid with a pun gent odor, it is used to make other chemicals, and in chemical analysis, its fumes are irritating to the eyes and mucous membranes, it is de composed by water to hydrochloric add with release of heat. It solidifies at 37 deg. F. It is corrosive to metals and tissue. If materiel involved in Are Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cooi ail affected containers with flooding quantities of water Apply water from as far a distance as possible April 1b. II material nol Involved In fire Keeo material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid Breathing vapors Keep upwind Wear self-contained Breathing apparatus Avoid bodily contact with the material Wear Boots, protective gloves, and goggles Do not handle broKen packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water if contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorp bulk liquid with fly ash or cement powder Neutralize with agricultural lime tslaked limei, crushed limestone, or sodium bicarbonate Environmental considerations--water spill Add caustic soda if dissolved, apply sodium sulfide solution to precipitate heavy metals Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Add soda ash Allow to aerate Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment ANTIMONY PENTACHLORIOE SOLUTION 4932312 CORROSIVE MATERIAL, ACIDIC UNI 731 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-IOOO/454) Antimony pentachtoride solution is a reddish-yellow solution of anti mony pentachloride in hydrochloric acid. H has a pungent odor and its fumes are irritating to the eyes and mucous membranes, it is decom posed by water into more hydrochlonc acid with release of heat It is corrosive to metals and tissue. If material involved in fire Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing <pril 1981 Environmental considerations--lend spill Dig a pit. Dona, lagoon, holding area to contain liquid or solid matenai Dike surface flow using soil, sand bags, foameo polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agricultural lime (slaked limei, crushed limestone, or sodium bicarbonate Environmental considerations--water spill Add caustic soda If dissolved, apply sodium sulfide solution to precipitate heavy metals Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Add soaa ash Allow to aerate Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment ANTIMONY PENTAFLUORIDE 4932005 CORROSIVE MATERIAL, ACIDIC, POISONOUS UN1732 Antimony oentafluortde is a colorless oily liquid, it is used to make other chemicals and as a catalyst in the manufacture of other chemicals. It is decomposed by water to hydrofluoric acid and other materials with release of heat. Its fumes are irritating to the eyes and mucous mem branes. it is corrosive to metals and tissue. Hydrofluoric acid causes severe painful skin burns. The material may only be shipped in cylinders Prolonged exposure of the cylinders to tire or heat may result in their violent rupturing and rocketing, if material involved In fire Use dry chemical, carbon dioxide, or dry sand Do not use water on matenai itself If large quantities of combustibles are involved, use water in flooding quantities as spray and tog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved in fire Keep matenai out of water sources and sewers Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing ANTIMONY POTASSIUM TARTRATE SOUD 4941114 ORM-A UNI 551 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Antimony potassium tartrate solid is a colorless crystaline solid or a white powder. It is used in textile and leather processing and as an insectide. it is soluble in water, if materiel involved In fire Extinguish tire using agent suitable lor type of surrounding fire (Material itself does not bum or bums with difficulty.) Continued on next page 43 9rr&6 0 OOOO If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid Breathing vapors or dusts Wash away any materia) which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain iiauid or solid material Cover solids with a plastic sheet to prevent dissolving m ram or fire lighting water Environmental considerations--water spill Add caustic soda If dissolved, apply sodium sulfide solution to precipitate heavy metals Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Adjust pn to neutral (ph-7) Allow to aerate ANTIMONY TRIBROMIDE, SOLID 4932319 CORROSIVE MATERIAL NA1549 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Antimony tribromide, solid is the yellow crystalline solid. It is used to make other antimony compounds, in chemical analysis, and in dyeing. If is decomposed by water giving an antimony oxide and hydrobromic acid. It is corrosive to tissue. If material involved in fire Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If targe quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knockdown vapors Do not use water on materia! itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material if contact with the material anticipated, wear full protective clothing Environmental considerations--lend spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spiH Add caustic soda If dissolved, apply sodium sulfide solution to precipitate heavy metals Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Add soda ash Allow to aerate 44 000009^87 ANTIMONY TRIBROMIDE. SOLUTION 4932317 CORROSIVE MATERIAL ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000'454) Antimony tnbromtde. solution is the yellow crystalline solid dissolved in hydrobromic acid. It is used to make other antimony compounds, ir chemical analysis, ana in dyeing. It is decomposed Dy water giving an antimony oxide and hydrobromic acid It is corrosive to metals and tissue. If material involved in fire Use dry chemical, carbon dioxide, or ary sana Do not use water on material itself If large quantities of combustibles are involved, use water m flooding Quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible H materiel not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective eouipment Wash away any material which may have contacted tne body with copious amounts of water or soap and water Avoid breathing dusts Environmental consideration*--land spill Dig a pit. pond, lagoon, holding area to contain iiauid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agncultural lime (slaked limei. crushed limestone, or sodium bicarbonate Environmental considerations--water spill Add caustic soda If dissolved, apply sodium sulfide solution to precipitate heavy metals Use mechanical dredges or lifts to remove immobilized masses of pollutants and precrpitates Add soda ash Allow to aerate Environmental considerations--air spill Apply water spray or mist to knock down vaoors Vapor knockdown water is corrosive or toxic and should be diked for containment ANTIMONY TRICHLORIDE SOLUTION 4932318 CORROSIVE MATERIAL ACIDIC UN1733 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-1000/454) Antimony trichloride solution is a colorless liquid with a pungent odor. The solution is antimony trichloride dissolved in hydrochloric acid. The antimony trichloride is decomposed by water to hydrochloric acid and antimony oxychloride with release of heat, (the antimony oxychloride is soluble in hdyrochlonc acid and insoluble in water). The solution is corrosive to metais and tissue. If material involved In fire Use dry chemical, carbon dioxide, or dry sand Do not usa water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Usa water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible April If material not involved in fire Keep material out of water sources ana sewers Build dikes to contain flow as necessary Use water spray to Knock-down vaoors Do not use water on material itself Neutralize spilled material with crusned limestone, soda ash. or 'ime Personnel protection Avoia Dreathmg vapors Keep upwind Wear self-contained preathing apparatus Avoid Oodity contact with the materia' Wear boots, protective gloves, ana goggles Do not handle broKen pacKages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absoro bulk liquid with fly ash or cement powder Neutralize with agricultural lime (slaked limet. crushed limestone, or sodium bicarbonate Environmental considerations--water spill Add caustic soda If dissolved, apply sodium sulfide solution to precipitate heavy metals Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Add soda ash Allow to aerate Environmental considerations--air spill Appty water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment ANTIMONY TRICHLORIDE. SOLID 4932316 CORROSIVE MATERIAL. ACIDIC UNI 733 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RGMOOO/4S4) Antimony trichloride, solid is a colorless crystalline mass. It is decom posed by water to hydrochloric acid and antimony oxychloride, -antimony oxychloride is soluble in hydrochloric acid but insoluble in water), It is corrosive to metals and tissue. If materiel Involved in fire Use dry chemical, carbon dioxide, or dry sand Do not use water on matenal itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible if material not involved in Are Keep matenal out of water sources and sewers Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled matenal with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Avoid bodily contact with the matenal Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts o< water or soap and water April 1981 Wear self-contained breathing apparatus when fighting fires involv ing this material - If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain pr fire fighting water Neutralize with agncuitural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations---water spill Add caustic soda If dissolved, apply sodium sulfide solution to precipitate heavy metals Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Add soda ash Allow to aerate Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment ANTIMONY TRIFLUORIOE SOLUTION 4932305 CORROSIVE MATERIAL NA1549 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-IOOO/454) Antimony triffuonde solution is the white to grey crystalline solid dis solved in water. It is used in ceramics and to make other chemicals. It is corrosive to metals and tissue. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Matenal itsetf does not burn or bums with difficulty.) Use water in Hooding quantities as fog Cool all affected containers with Hooding quantities of water Apply water from as far a distance as possible H material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled matenal with crushed limestone, soda ash. or lime Personnel protection Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash awav any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting (ires involv ing this material If contact with the material anticipated, wear full protective clothing Environmental considerations--land spin Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash. cement powder, sawdust, or com mercial sorbents Apply universal'' gelling agent to immobilize spill Environmental considerations--water spill Add caustic soda If dissolved, apply sodium sulfide solution to precipitate heavy metals Adjust ph to neutral (ph-7) Usa mechanical dredges or lifts to remove immobilized messes of pollutants and precipitates Environmental considerations -sir spill Appty water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment 45 MOD 000009788 ANTIMONY TRIFLUORIDE. SOLID 4932335 CORROSIVE MATERIAL NA1549 ENVIRONMENTALLY HAZAROOUS SUBSTANCE (RO-1000/454) Antimony trifluoride, solid is a while 10 grey crystalline solid. It is used m ceramics and to make other chemicals. It is corrosive to tissue. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid bodily contact with the material Wear boots, protective gloves, and goggies Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the matenal anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in ram or tire fighting water Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Add caustic soda If dissolved, apply sodium sulfide solution to precipitate heavy metals Use mechanical dredges or tifts to remove immobilized masses of pollutants and precipitates Add soda ash Allow to aerate Environmental considerationa--air apill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment ANTIMONY TRIOXIDE (ANTIMONY OXIDE) 4968905 ORM-E NA9201 ENVIRONMENTALLY HAZAROOUS SUBSTANCE (RQ*5000/2270) Antimony thoxlde is a white crystalline solid. It is used to fireproof fabrics, paper and plastics, as a paint pigment and for many other uses, it is insoluble in water, ft is non-combustible. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Matenal itself does not bum or bums with difficulty.) H material not Involved in fire Keep matenal out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any matenal which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land apdl Dig a pit. pond, lagoon, holding area to contain liquid or sokd matenal Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Add caustic soda If dissolved, apply sodium sulfide solution to precipitate heavy metals 46 AOd sooa ash Allow to aerate Use mechanical dredges or lifts to remove immobilized masses r pollutants and precipitates AQUA AMMONIA SOLUTION (CONTAINING 44% OR LESS AMMONIA) (See AMMONIUM HYDROXIDE 493S280) ARGON 4904502 NONFLAMMABLE GAS UN1006 Argon is a colorless odorless noncombustibie gas. It is heavier than air and can asphyxiate by displacement of air Tt may be shipped in cylinders or special tank cars. If material Involved in fire Extinguish lire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Attemot to stop leak if without hazard Peraonnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggies Do not handle broken packages without protective equipment ARGON--OXYGEN GAS MIXTURE (COMPRESSED 4904410 GAS. N.O.S.) NONFLAMMABLE GAS UNI 956 Argon--oxygen gas mixture is a colorless odorless gas. Both argon and oxygen are noncombustibie; however, oxygen can accelerate the burning of a fire, it may only be shipped m cylinders. if material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Matenal itself does not bum or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible ff material not involved in fire Keep sparks, flames, and other sources of ignition away Attempt to stop leak if without hazard Peraonnel protection Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution ARGON PRESSURIZED LIQUID 4904503 NONFLAMMABLE GAS UNI 951 Argon pressurized liquid is a colorless noncombustibie liquid. Contact with the liquid will cause frostbite. The gas is heavier than air and can asphyxiate by displacement of air. tt may only be shipped in cylinders. If material involved In fire Extinguish lire using agent suitable for type of surrounding fire (Matenal itself does not bum or bums with difficulty.) Cool ail affected containers with flooding quantities of water Do not use water on material itseri Apply water from as far a distance as possible ff material not involved in fire Attempt to stop leak if without hazard Do not use water on material itself Peraonnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggies Do not handle broken packages without protective eouipment April 1981 MCD 000009789 ARGON-CARBON DIOXIDE GAS MIXTURE 4904504 (COMPRESSEO GAS, N.O.S.) NONFLAMMABLE GAS UNI 956 Argon-carbon dioxide gas mixture is a colorless odorless gas. Both argon and carbon dioxide are noncombustible. The mixture can as phyxiate by the displacement of air. It may only be shipped in cylinders. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire [Material itself does not burn or burns with difficulty I Cool all affected containers with flooding Quantities of water Apply water from as far a distance as possible If material not involved in fire Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective eauioment ARGON-HYDROGEN GAS MIXTURE (COMPRESSED 4905805 GAS, N.O.S.) FLAMMABLE GAS UNI 954 Argon-hydrogen gas mixture is a colorless odorless gas. It is easily ignited. It may only be shipped m cylinders. Argon is nontiammabie and heavier than air: hydrogen is flammable and lighter than air. A flame may flash back to the source of leak very easily. It may asphyxiate by the displacement of air. Under tire conditions cylinders may violently rupture and rocket. If material on fira or involved in fire Do not extinguish tire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered ARGON-HYDROGEN GAS MIXTURE (COMPRESSED 4904505 GAS. N.O.S.) NONFLAMMABLE GAS UN1956 Argon-hydrogen gas mixture is a colorless odorless gas. Argon is noncombustibie whereas hydrogen is a flammable gas. The mixture can separate with the hydrogen rising in the air. The mixture can asphyxiate by the displacement of air. It may only be shipped in cylinders. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Matenal itself does not bum or bums with difficulty.) Cool all affected containers with flooding quantities ot water Apply water from as far a distance as possible If material not involved in fire Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment ARGON-METHANE GAS MIXTURE (COMPRESSED 4905810 GAS, N.O.S.) FLAMMABLE GAS UNI 954 Argon-methane gas mixture is a colorless odorless gas. It is easily ignited and may only be shipped in cylinders. Argon is noncombustible and heavier than air. methane is flammable and lighter man air A flame can flash back to the source of teak very easily. It may asphyxiate by the displacement of air. Under fire conditions cylinders may violently rupture and rocket. If material on fire or involved in fire Do not extinguish fire unless flow can be slopped Use water m flooding Quantities as tog Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible if material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution Evacuation If fire becomes uncontrollable or container ts exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on firei. downwind evacuation must be considered ARGON-METHANE GAS MIXTURE (COMPRESSEO 4904506 GAS. N.O.S.) NONFLAMMABLE GAS UNI 956 Argon-methane gas mixture is an odorless colorless gas. Argon is noncombustibie; methane is a flammable gas. Argon is heavier than air. Methane is lighter than air. The mixture can separate into its two com ponents. It can asphyxiate by the displacement of air. It may only be shipped in cylinders. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Matenal itself does not bum or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible tf material not involved in fire Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment ARGON-NITROGEN GAS MIXTURE (COMPRESSED 4904507 GAS. N.O.S.) NONFLAMMABLE GAS UN1956 Argon-nitrogen gas mixture is a colorless odorless gas. Both argon and nitrogen are noncombustibie. The mixture can asphyxiate by the displacement of air. It may only be shipped in cylinders. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Matenal itself does not bum or bums with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved in fire Attempt lo stop leak if without hazard Continued on next page April 1981 CO*181 q0 47 Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment AROMATIC CONCENTRATES. SUITABLE ONLY FOR 4915490 FURTHER PROCESSING (COMBUSTIBLE LIQUID. N.O.S.) COMBUSTIBLE LIQUID NA1993 Aromatic concentrates suitable only for further processing are ma terials having a closed cup flash point between 100 and 199 deg. F The hazard of these materials is combustibility. If material on fire or involved In fire Do not extinguish fire unless flow can be slopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding Quantities of water Apply water from as far a distance as possible Use alcohol" foam, carbon dioxide or dry chemical It material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water AROMATIC CONCENTRATES. SUITABLE ONLY FOR 4910490 FURTHER PROCESSING (FLAMMABLE LIQUID. N.O.S.) FLAMMABLE LIQUID UN1993 Aromatic concentrates suitable only for further processing are ma terials having a closed cup flash point of less than 100 deg. F. The hazard of these materials is flammability. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding Quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ARSENIC ACID SOLUTION (ARSENIC ACID OTHER 492310S THAN FUSED) POISON B CORROSIVE UNI 554 Arsenic acid solution is a clear colorless liquid, it is soluble in water and non combustible. It is corrosive to metals and is toxic by ingestion. 48 if material involved in fire Extinguish fire using agent suitable for type of surrounding tire I Material itself does not Durn or Durns with difficulty I Use water in flooding quantities as tog Use foam, carbon dioxide or dry chemical If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Atiemot to stop leak if without hazard Neutralize sDiileo material with crushed limestone, sooa asn. or lime Personnel protection A9oid creaming ousts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the Oody with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material ARSENIC ACID. SOLID (ARSENIC ACID FUSED) 4923106 POISON B. CORROSIVE UN1553 Arsenic acid, solid is a white crystalline solid. It is soluble in water and non combustible. It is corrosive to metals m the presence of moisture and is toxic by ingestion. It material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved In fire Keep material out of water sources and sewers Neutralize spiiled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the matenai Wear full protective clothing Do not handle broken packages without protective equipment Wash away any materiai which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this matenai ARSENIC BROMIOE, SOUD 4923202 POISON B UNI 555 Arsenic bromide, solid is a yellowish white crystalline solid melting at 90 deg. F. It absorbs moisture from the air. It is decomposed by water to form arsenic acid and hydrobromic acid, a corrosive matenai. It is toxic by inhalation and ingestion. If materiai involved in fire Extinguish fire using agent suitable lor type of surrounding fire (Matenai itself does not bum or bums with difficulty.) Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors If material not Involved In fire Keep material out of water sources and sewers Use water spray to knock-down vapors Do not use water on material itself Neutralize spiiled material with crushed limestone, soda ash. or lime April 1981 MCD 000009792 Personnel protection Avoid breathing dusts, and fumes from burning matenal Keep upwind Avoid bodily contact with the matenal Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material ARSENIC CHLORIDE. LIQUID 4923203 POISON B UN1560 Arsenic chloride is a colorless to yellow oily fuming liquid, it is used to make other arsenic containing compounds. It is decomposed by water to give arsenic acid and hydrochloric acid, a corrosive matenal. It is irritating to the skin eyes and mucous membranes. It is toxic by inhalation and ingestion. II material involved in fire Extinguish fire using agent suitable tor type of surrounding fire (Matenal itself does not bum or bums with difficulty.! Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors If material not involved in fire Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Do not use water on material itself Neutralize spitted matenal with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact wiih the matenal Wear full protective clothing Do not handle broken packages without protective equipment Wash away any matenai which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered Wear full protective clothing Do not handle broken packages without protective equipment Wash away any matenai which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this matenal ARSENIC PENTOXIDE, SOLID 4923112 POISON B. CORROSIVE UN1S59 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Arsenic pentoxide. solid is a white crystalline solid. It is soluble in water to form arsenic acid. It is corrosive to metals in the presence of moisture and is non combustible. It is toxic by ingestion. A material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Matenal itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not Involved In fire Keep matenal out of water sources and sewers Neutralize spilled matenal with crushed limestone, soda ash. or lime Personnel protection Avoid breathing dusts, and fumes from burning matenal Keep upwind Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Environmental eonslderattona--lend spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in ram or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Add ferric chloride (feciS) Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates ARSENIC DISULFIDE (See ARSENIC SULFIDE 4923203) ARSENIC IODIDE, SOUD 4923205 POISON B NA1S57 Arsenic iodide is an orange-red crystalline solid, it is used in medicine and in chemical analysis, it is decomposed by water to form arsenic acid and hydriodic acid, a corrosive matenal. It is toxic by ingestion. If material Involved In Are Extinguish fire using agent suitable for type of surrounding fire (Matenal itself does not bum or bums with difficulty.) Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors If materiel not involved in Are Use water spray to knock-down vapors Use water spray to knock-down vapors Do not use water on matenal itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material ARSENIC SULFIDE, SOUD 4923203 POISON B NA1SS7 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Arsenic sulfide is a yellow or red crystalline solid or powder. It is insoluble in water and it is combustible. It is toxic by inhalation (dust) and by ingestion. A material on Are or Involved in Are Uss water in flooding quantities as fog Use foam, carbon dioxide or dty chemical A material not on Are and not involved in Are Keep sparks, flames, and other sources of ignition away Keep matenai out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear sett-contained breathing apparatus when fighting fires involv ing this material tf contact with the material anticipated, wear full protective clothing Conttnuod on mxt pege April 1961 *tcz> o<o09?93 49 Environmental considerations--land spill Dig a pit. pona. lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom Adiusi oh to neutral (pn-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates ARSENIC TRICHLORIDE 4923209 POISON B UN1560 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-SOOO 2270) Arsenic trichloride is a colorless to yellow oily fuming liquid, it is de composed by water to give arsenic acid and hydrochloric acid, a cor rosive material. It is irritating to the skin eyes and mucous membranes, it is toxic by inhalation and ingestion. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.! Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as soray and fog Use water spray to absorb vapors If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material ith crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted (he body with copious amounts of water or soap and water Evacuation If matenal leaking (not on fire), downwind evacuation must be considered Environmental considerations--land spilt Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerationa--water spill Adjust ph to neutral <ph-7) Add calcium hypochlorite Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Add ferric chloride (feci3) Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment 50 ARSENIC TRIOXIDE. SOLID (ARSENIC. WHITE. SOLID 4923115 ARSENOUS ACID. SOLID) POISON B. CORROSIVE UN1561 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000 2270) Arsenic trioxide, solid is a white amorphous powder, it is slightly sol uble in water and is non combustible. It is corrosive to metals m the presence of moisture and is toxic by ingestion. If material involved in fire Extinguish fire using agent suitable tor type of surrounding lire (Material itself does not burn or burns with difficulty.) Use water m flooding quantities as tog Use foam, caroon dioxide or dry chemical If material not involved in fire Keep material out of water sources and sewers Neutralize spilled matenal with crushed limestone, soda ash. or lime Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when lighting fires involv ing this material Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in ram or fire fighting water Environmental considerations--water spill Add calcium hypochlorite Neutralize with agricultural lime (slaked lime), crushed timestone. or sodium bicarbonate Add ferric chloride (fec<3) Ad|ust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates ARSENIC TRISULFIOE 4923222 POISON B NA1557 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Arsenic trisulfide is a yellow crystalline solid, it is used as a pigment and for other uses. It is insoluble in water. It is noncombustsble. H material on fire or involved In fire Use water in flooding quantities as tog Use loam, carbon dioxide or dry chemical ff materiel not on fire end not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this matenal If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in ram or fire fighting water April 198. MCD 000009794 Environmental consideration*--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom Adjust ph to neutral (ph-7) Add feme chloride (fecl3) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates ARSENIC WHITE. SOLID (See ARSENIC TRIOXIDE, SOUO 4923115) ARSENIC. CRUDE (POISONOUS SOLID, N.O.S.) 4923204 POISON B NA2S11 Arsenic, crude, is a greyish metallic solid. It is insoluble in water. It is toxic by ingestion. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire {Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keeo upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing ARSENIC. SOLID (ARSENIC METALLIC) 4923207 POISON B UN1SS0 Arsenic, solid is a greyish metallic solid turning black on the exposure to air It is insoluble in water. It is toxic by ingestion. If material Involved in fire Extinguish fire using agent suitable for type Of surrounding fire (Matenai itself does not burn or bums with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved in fire Keep matenai out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning matenai Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material if contact with the material anticipated, wear full protective clothing ARSENICAL COMPOUND, N.O.S. (OR) ARSENICAL 4923210 MIXTURE. N.O.S. LIQUID POISON B UNI 556 Arsenical compound, n o.s. or arsenical mixture, n.o.s.. liquid are liquid matenais or solutions of solid matenais containing arsenic. H is toxic by ingestion, April 1981 If material Involved in fire Extinguish fire using agent suitable for type ot surrounding fire (Matenai itself does not burn or bums with difficulty, i Use water m flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full orotective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ARSENICAL COMPOUND. N.O.S.. SOLID. (OR) 4923211 ARSENICAL MIXTURE. N.O.S. SOLID POISON B UN1557 Arsenical compound, n o s., solid, (or) arsenical mixture, n.o.s. Solid are vanous colored solid matenais containing arsenic. Material generally is not soluble in water. It is toxic by inhalation idust) and by ingestion, tf material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Matenai itself does not bum or bums with difficulty.) Use water in flooding quantities as tog Use foam, carbon dioxide or dry chemical If materiel not involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the matenai Wear full protective clothing Do not handle broken packages without protective equipment Wash away any matenai which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this matenai ARSENICAL DIP, LIQUID (SHEEP OIP) 4923212 POISON B NA1SS7 Arsenical dip. liquid is a solution of an arsenic compound. It is soluble in water and is toxic by ingestion. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as tog Use foam, carbon dioxide or dry chemical K material not Involved In fire Keeo matenai out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 51 000009795 MCt> ARSENICAL DUST 4923213 POISON B UN1562 Arsenical dust is a greyish colored powder. It is insoluble in water It is toxic by inhalation (dust) and by ingestion. II material involved In fire Extinguish fire using agent suitable lor type of surrounding lire (Material itself does not burn or burns with difficulty.) Use water in flooding ouanttties as fog Use foam, carbon dioxide or dry chemical If material not involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material ARSENICAL ORE. CRUOE (POISONOUS SOLID. 4923395 N.O.S.) POISON B NA2811 Arsenical ore. crude is a variable colored solid., it is insoluble in water, it is toxic by ingestion. If material on fira or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning matenal Keep upwind Avoid bodily contact with the matenal Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the matenal anticipated, wear full protective clothing ARSENICAL PESTICIDE. LIQUID. N.O.S. 4923301 (COMPOUNDS ANO PREPARATIONS) (AGRICULTURAL INSECTICIDES. NEC, LIQUID) POISON B UN2759 Arsenical pesticide is a liquid or solid dissolved in a liquid carrier. The earner is water emulsitiable. The earner may bum though it may require some effort to ignite. It is toxic by inhalation, skin absorption, and or ingestion. In case of damage to. or leaking from containers of this ma terial contact the pesticide safety team network. Telephone: BOO-424- 9300. If material Involvad In fira Extinguish fire using agent suitable for type of surrounding fire (Matenal itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not Involved In fira Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind 52 ^Cq o0 0q ?9e Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without orotective equipment Wash away any material which may nave contacted the body with copious amounts of water or soap ana water ARSENICAL PESTICIDE. LIQUID. N.O.S. 4923303 (COMPOUNDS AND PREPARATIONS) (INSECTICIDES. OTHER THAN AGRICULTURAL. NEC) POISON B UN2759 Arsenical pesticide is a liquid or solid dissolved m a liquid carrier. The carrier is water emulsifiabie. The carrier may burn though it may require some effort to ignite It is toxic by inhalation, skin absorption, and or ingestion. In case of damage to. or leaking from containers of this ma terial contact the pesticide safety team network. Telephone: 800-424- 9300. If material involved in fire Extinguish fire using agent suitable for tyoe of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not Involved in fire Keep material out of water sources ano sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the matenal Wear full protective clothing Do not handle broken packages without protective equipment Wash away any matenal which may have contacted Ihe body with copious amounts of water or soap and water ARSENICAL PESTICIDE. LIQUID, N.O.S. 4910557 (COMPOUNDS AND PREPARATIONS) (INSECTICIDES. OTHER THAN AGRICULTURAL, NEC) FLAMMABLE LIQUID UN2760 Arsenical pestieide is a liquid or solid dissolved in a liquid earner. The earner is water emulsifiabie. The primary hazard of this material is the flammability of the carrier. It has a flash point below 100 deg. F. ft can cause illness by inhalation. $km absorption and or ingestion. In case of damage to. or leaking from containers of this matenal contact the pes ticide safety team network. Telephone: 800-424-9300. If material on fira or Involvad in fira Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use 'alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective eauipment Wear self-contained breathing apparatus when fighting fires involv ing this material April 1981 ARSENICAL PESTICIDE. LiQUIO. N.O.S. 491055B (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES. NEC. LIQUID) FLAMMABLE LIQUID UN2760 Arsenical pesticide is a liquid ar solid dissolved in a liquid carrier. The carrier is water emuisifiabie The primary hazard of this material is the flammability of the carrier. It has a flash point below tOO deg. F. it can cause illness by inhalation skin absorption and or ingestion. In case ol damage to. or leaking from containers of this material contact the pes ticide safety team network. Telephone. 800-424-9300- If material on fire or involved in fire Do not extinguish tire unless flow can be stopped Use water in flooding quantities as fog Sol'd streams of water may pe ineffective Cool all affected containers with flooding Quantities of water Apply water from as tar a distance as possible Use alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keeo upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wear self-contained breathing apparatus when fighting fires involv ing this material ARSENICAL PESTICIDE. SOLID. N.O.S. (COMPOUNDS 4923304 ANO PREPARATIONS) (INSECTICIDES. OTHER THAN AGRICUTURAL. NEC) POISON B UN2759 Arsenical pesticide is a solid or a liquid absorbed on a dry earner. It is a wettable powder. It is toxic by inhalation, skin absorption, and or ingestion. In case of damage to. or leaking from containers of this ma terial contact the pesticide safety team network. Telephone; 800-424- 9300 If material on fire or involved in fire Extinguish tire using agent suitable for type oi surrounding fire (Material itsell does not burn or bums with difficulty.) Use water in Hooding quantities as fog Use alcohol' foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material oui of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenai which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting lires involv ing this matenai If contact with the material anticipated, wear full protective clothing ARSENICAL PESTICIDE. SOLID, N.O.S. (COMPOUNDS 4923302 AND PREPARATIONS) (AGRICULTURAL INSECTICIDES. NEC. OTHERTHAN LIQUID) POISON B UN27S9 Arsenical pesticide is a solid or a liquid absorbed on a dry carrier. It is a wettable powder. It is toxic by inhalation, skin absorption, and or ingestion. In case ol damage to. or leaking from containers of this ma terial contact the pesticide safety team network. Telephone; 800-4249300. April 1981 If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Matenai itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, (lames, and other sources of ignition away Keep matenai out ot water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing ARSENOUS ACID. SOLIO (See ARSENIC TRIOXIDE. SOLIO 4923115) ARSENOUS ANO MERCURIC IOD10E SOLUTION 492321$ POISON B NA2810 Arsenous and mercuric iodide solution is arsenous iodide and mercuric iodide dissolved in water and is red or yellow in color. It is toxic by ingestion. If material involved in fire Extinguish lire using agent suitable for type of surrounding fire (Matenai itself does not burn or burns with difficulty.) Use water in flooding quantities as tog Use foam, carbon dioxide or dry chemical If material not involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear lull protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ARSINE 4920135 POISON A. FLAMMABLE UN2168 Arsine is a colorless gas with a disagreeable garlic-tike odor. K is llammabie. The gas is heavier than air and a (lame can flash back to the source of leak very easily. It is toxic by inhalation. It may only be shipped in cylinders which may have to be overpacked in wooden or metal containers. Prolonged exposure of the cylinders to fire or heat may result in the cylinders violent ruptunng and rocketing, ff material on fire or involved in lire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as lar a distance as possible Solid streams of water may be ineffective Use alcohol" foam, carbon dioxide or dry chemical If material not on Are end not involved in fire Keep sparks. Itames. and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Continued on next pogm 53 00 0q7 97 ng apparatus e material I ages without protective equipment uch may have contacted the body with r or soap and water ftrei. downwind evacuation must be RIPPING (CORROSIVE 4936543 UNI 760 is a various colored liquid. It is corrosive turn though it may require some effort d In fire suitable for type of surrounding fire urn or burns with difficulty.) ties as tog stance as possible t involved in fire her sources of ignition away iources and sewers s necessary t material is. and goggles ges without protective equipment ich may have contacted the body with or soap and water g apparatus when fighting fires involv- iticipated. wear full protective clothing :e SEALER. ASPHALT. 4915302 >M BASE .O.S.) NA1993 er. asphatt. coal tar or petroleum base like odor. It has a flash point between ly heavier than water and is insoluble lan air. I in fire flow can be Mopped ies as fog oe ineffective vith flooding quantities of water itance as possible dry chemical t Involved In fire ier sources of ignition away Durces and sewers i necessary wn vapors s. and goggles jes without protective equipment :h may have contacted the body with or soap and water ASPHALT PAVEMENT SURFACE SEALER. ASPHALT. 4910302 COAL TAR OR PETROLEUM BASE (FLAMMABLE ' LIQUID, N.O.S.) FLAMMABLE LIQUID UN1993 Asphalt pavement surface sealer, asphalt, coal tar or petroleum base is a black liquid with a petroleum like odor It has a Hash point of less than tOO deg. F. It is generally heavier than water and is insoluble m water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stooped Use water m flooding quantities as fog Solid streams of water may be Ineffective Cool alt affected containers with Hooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap ano water ASPHALT TILE. PLASTICIZER (COMBUSTIBLE 4915408 LIQUID,N.O.S.) COMBUSTIBLE LIQUID NA1993 Asphalt tile, plasticizer is a material containing a solvent having a closed cup flash point between 100 and 199 deg. F. The hazard is combustibility. if material on fire or Involved In fire Do not extinguish fire unless flow can/ Use water in flooding quantities as fc Solid streams of water may be inefft Cool all affected containers with floodl Apply water from as far a distance as Use "alcohol" foam, carbon dioxide or' If material not on fire and not Involved1 Keep sparks, flames, and other sources Keep material out of water sources and sc Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ASPHALT TILE. PLASTICIZER (FLAMMABLE LIQUID. 4910408 N.O.S.) FLAMMABLE LIQUID UN1993 Asphalt tile, plasticizer is a material containing a solvent having a closed cup flash point of less than 100 deg. F. The hazard is tlammability. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "atachoT foam, carbon dioxide or dry chemical April 1981 Hcd 000 9798 If material not on fire and not Involved in fire Keep sparks, flames, and other sources oi ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective eouioment Wash away any material which may have contacted the body with copious amounts of water or soap and water ASPHALT. CUT BACK 4910220 FLAMMABLE LIQUIO NA1999 Asphalt, cut back is a thick black liquid with a characteristic "tar'' odor. It has a flash point of less than 100 deg. F. It is generally heavier than water and insoluble m water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams ot water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ASPHALT. CUT BACK (ASPHALT PETROLEUM, 4915320 LIQUID AND TALL OIL PITCH. MIXED COMBUSTIBLE LIQUIO NA1999 Asphalt, cut back is a thick black liquid with a characteristic tar' odor. It has a Hash oomt between 100 and 199 deg. F. It is generally heavier than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved in Are Do not extinguish lire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool ali affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical if material not on fira and not Involved in lira Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to Knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1961 ASPHALTUM OR COAL TAR PAINT (PAINT) 4915252 COMBUSTIBLE LIQUID UN1263 Asphaltum or coal tar paint may contain a combustible solvent, its flash oomt is between 100 and 199 deg. F. The hazard is combustibility, if material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ASPHALTUM OR COAL TAR VARNISH (VARNISH) 4915253 COMBUSTIBLE LIQUID UNI 263 Asphaltum or coal tar varnish may contain a combustible solvent, its flash point is between 100 and 199 deg. F. The hazard is combustibility. II material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Soiid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water A2NPHOS METHYL (OR) GUTHION (AGRICULTURAL 4921526 INSECTiaOES, NEC, LIQUID) POISON B NA2783 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1 0.454) Azinphos methyl is a brown waxy solid dissolved in a liquid carrier. It is used as a pesticide. It is a water emutsifiable liquid. It is toxic by inhalation, skin absorption, and/or ingestion, in case ot damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone: 600-424-9300. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use 'alcohol" foam, carbon dioxide or dry chemical Continued on next page MCD 000009799 55 ff material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep matenai out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep unwind Wear self-contained breathing apparatus Avoid bodily contact with the matenai Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid matenai Dike surface flow using soil, sand Dags, foamed polyurethane, or foamed concrete Absorb bulk HquiO with fly ash or cement powder Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spilt Apply water spray or mist to knock down vapors AZINPHOS METHYL (OR) GUTHION (AGRICULTURAL 4921527 INSECTICIOES, NEC, OTHER THAN LIQUID) POISON B NA2783 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Azinphos methyl is a brown waxy solid. It is used as a pesticide. It is a wettabie powder. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to, or leaking from containers of this ma terial contact the pesticide safety team network. Telephone: 800-424- 9300. If material on fire or involved In fire Extinguish fire using agent suitable for type of surrounding fire (Matenai itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical If materiel not on fire and not involved in Are Keep sparks, flames, and other sources ol ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the matenai Wear boots, protective gloves, and goggtee Do not handle broken packages without protective equipment Wash away any matenai which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this matenai If contact with the material anticipated, wear fuN protective clothing Environmental conaidarallona- land spM Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental conaidarallona water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap matenai at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates 56 AZINPHOS METHYL (OR) GUTHION (INSECTICIDES, 4921520 OTHER THAN AGRICULTURAL. NEC) POISON B NA2783 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Azinphos methyl is a brown waxy solid or the solid dissolved in liquid earner. It is used as a pesticide. It is toxic-by inhalation, ski. absorption. and'Of ingestion. It is a wettabie powder or water emuisifiable liquid. In case of damage to. or leaking from containers of this matenai contact the pesticide safety team network. Telephone: 800-424-9300. If materiel on Are or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol'' foam, carbon dioxide or dry chemical If materiel not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep matenai out of water sources and sewers Build dikes to contain flow as necessary Attempt to Stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any matenai which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses o- poilutants and precipitates Environmental considerations--sir spill Apply water spray or mist to knock down vapors AZINPHOS METHYL MIXTURE, LIQUID (OR) GUTHION 4921529 MIXTURE, LIQUID (AGRICULTURAL INSECTICIDES, NEC, LIQUID) POISON B NA2783 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Azinphos methyl mixture, liquid is a brown waxy solid dissolved in a liquid earner. It is used as a pesticide. It is a water emuisifiable liquid. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to, or leaking from containers of this material contact the pes ticide safety team network. Telephone: 800-424-9300. If material on Are or Involved in Are Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical H material not on Are and not Involved In Are Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak K without hazard Use water spray to knock-down vapors April 19: 0q 0q',qOq Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken oackages without orotective equipment Wash away any material which may have contacted the body with cooious amounts of water or soao and water Environmental considerations--land spill Dig a ok. oond. *agoon. holding area to contain liauid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Aosorb bulk liauid with fly ash or cement powder Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount m region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors BAGS. SODIUM NITRATE EMPTY ANO UNWASHED 4917301 FLAMMABLE SOLID UN1359 Bags, sodium nitrate, empty and unwashed are burlap bags that have been used to ship sodium nitrate and are still contaminated by it. The bags are easily ignited and burn Quite fiercely due to the oxidizing prop* edies of sodium nitrate. The sodium nitrate is soluble in water. Toxic oxides of nitrogen are produced during combustion of this material. It material on fire or involved in fire Flood with water If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing fumes from burning material BARIUM AZIDE. WET (50% OR MORE WATER) 4917110 FLAMMABLE SOLIO UN1571 Barium azide, wet is a slurry of white crystals. The dhed matenal is a high explosive. Dry it is easily ignited and bums very vigorously. It is soluble m water. Toxic oxides of nitrogen are produced dunng combus tion of this material. If material on fire or Involved In fire Dangerously explosive Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire end not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Do not attempt to sweep up dry material Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts oi water or soap and water Wear self-contained breathing apparatus whan fighting liras involv ing this material Evacuation if fire becomes uncontrollable--evacuate tor a radius of 5000 feet April 1961 BARIUM CHLORATE 4918706 OXIDIZER UN1445 Banum chlorate is a white crystalline solid, it is used in explosives and pyrotechnics, in dyeing textiles, and to make other chlorates The ma terial is soluble in water, it forms a very flammable mixture with com- oustibie materials and this mixture may be explosive if the combustible material is very finely divided. The mixture can be ignited by friction. Contact with strong sulfuric acid can cause fires or explosions. When mixed with ammonium salts, spontaneous decomposition and ignition may result. Prolonged exposure of the material to fire or heat can result in an explosion. if material on fire or involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting tires involv ing this matenal Approach fire with caution Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet BARIUM CHLORATE, WET 4918605 OXIDIZER NA1445 Barium chlorate, wet is a water slurry or sludge of white crystals. It is used in explosives and pyrotechnics, in dyeing textiles, and to make other chlorates. The material is soluble in water, tt forms a very flam mable mixture with combustible materials and this mixture may be ex plosive if the combustible material is very finely divided. The mixture can be ignited by friction. Contact with strong suifuric acid can cause fires or explosions. When mixed with ammonium salts, spontaneous decom position and ignition may result. Prolonged exposure of the material to fire or heat can result in an explosion. If material on fire or Involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If materiel not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep materiel out of water sources and 3ewers Personnel protection Wear bools, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Approach fire with caution Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet BARIUM CYANIDE, SOLID 4923410 POISON B UNI 565 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-10/4.54) Barium cyanide, solid is a while crystalline solid, it is soluble in water and gradually decomposed by water and very rapidly decomposed by acids to give off hydrogen cyanide, a flammable poison gas. It is toxic by skin absorption through open wounds, by ingestion, and by inhalation of hydrogen cyanide from the decomposition of the material. Toxic oxides of nitrogen are produced in fires involving this material. Contlnvd on r*xt pag* 57 MOD 000009801 If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use foam, carbon dioxide or dry chemical Oo not use water on matenal itself If large quantities of comoustibies are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors If material not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources ana sewers Use water spray to knock-down vapors Do not use water on material itself Personnel protection Avoid breathing vapors or dusts Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Oo not handle broken packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Environmental considerations--land split Oig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water split Add caustic soda Add calcium hypochlorite Add sodium sulfate (na2so4) Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates BARIUM HYDROXIDE MONOHYDRATE (CORROSIVE 4935238 SOLIO. N.O.S.) CORROSIVE MATERIAL UNI 780 Barium hydroxide monohydrate is a white powder, it is used in water purification, to make lubricating and oil additives, to make barium con taining chemicals and for many other uses. It is slightly soluble in water. It is corrosive to metals and tissue. Tissue. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Matenal itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Apply water from as far a distance as possible If material not involved In fire Keep material out of water sources and sewers Personnel protection Avoid bodily contact with the material Wear boots, protective gtoves. and goggles Do not handle broken packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts of water or soap and water BARIUM NITRATE 4918709 OXIDIZER UNI 448 Barium nitrate is a white crystalline solid. The material is soluble in water, it is non-combustible but it will accelerate the burning of com bustible materials, if large quantities of the material are involved in the fire or the combustible material is finely divided an explosion may result. Prolonged exposure of the material to fire or heat may result in an explosion. Toxic oxides of nitrogen are produced in fires involving this material. 58 oooo 0 It material on fire or involved In tire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers Personnel protection Wear boots, orotective gloves, ana goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear seif-contained breathing apparatus when fighting fires involv ing this matenal Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet BARIUM PERCHLORATE 4918710 OXIDIZER UN1447 Banum perchlorate is a white crystalline solid, it is used to make explosives. It is soluble in water. It is noncombustibie but it will accelerate the burning of combustible materials. If large quantities of the material are involved in the fire or the combustible material is finely divided an explosion may result. Prolonged exposure of the material to tire or heat may result in an explosion, if material on fire or involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Approach tire with caution Evacuation If fire becomes uncontrollable--evacuate tor a radius of 2500 feet BARIUM PERMANGANATE 4918711 OXIDIZER UNI 448 Barium permanganate is a purplish colored crystalline solid, it is used as a disinfectant and to make other permanganates, it is soluble in water. The material itsetf is noncombustible but it wilt accelerate the burning of combustible material, if the combustible matenal is finely divided the mixture may be explosive. Contact with liquid combustible materials may result in spontaneous ignition. Contact with sulfuric aod may result in fires or explosions. If material on lira or Involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on Are and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers April 19t Personnel protection Avoid breathing dusts Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation if fire becomes uncontrollable--evacuate for a radius of 2500 feet BARIUM PEROXIDE 4918712 OXIDIZER UN 1449 Barium peroxide is a greyish white granular solid. It is insoluble in water and is slowly decomposed by water. It is non-combustible but it will accelerate the burning of combustible material, if the combustible material is finely divided the mixture may be explosive. Mixtures of combustible material and the peroxide can be ignited by friction or con tact with moisture. If material on fire or involved in fire Flood with water Cool ail affected containers with flooding Quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep soarks. (lames, and other sources of ignition away Keep matenal out of water sources and sewers Personnel protection Avoid breathing dusts Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation if fire becomes uncontrollable--evacuate for a radius of 2500 feet BLASTING CHLORATE {CHLORATE, N.O.S.) 4918707 OXIDIZER UN1461 Blasting chlorate is- a crystalline solid. It is soluble in water. It forms a very flammable mixture with combustible materials and this mixture may be explosive if the combustible material is finely divided. The mixture can be ignited by friction. Contact with strong sulfuric add can cause fires or explosions. When mixed with ammonium salts, spontaneous decomposition and ignition may result. Prolonged exposure to fire or heat can result in an explosion. If material on fire or involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If materiel not on fire end not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet April 1981 BATTERIES. ELECTRIC STORAGE. WET. WITH 4936502 AUTOMOBILE AUTO PARTS. ENGINE CORROSIVE MATERIAL NA2794 Batteries, eiectnc storage, wet. with automobile auto parts engine consist of the wet electric storage battery and mechanic equipment in the same carload or trailer load. There are two possible hazards m transportation. First that the battery may be short circuited and resulting sparks may cause a fire. The second is that the battery may be turned over and the electrolyte spilled. The electrolyte is corrosive to metals and tissue. It is water soluble with evolution of heat. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.I Use water m flooding quantities as tog Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the matenal anticipated, wear full protective clothing BATTERY BOX COMPOUNDS {COMBUSTIBLE LIQUID. 4915550 N.O.S.) COMBUSTIBLE LIQUID NA1993 Battery box compounds are various colored liquids. They have a flash point between 100 and 199 deg. F. They are generally heavier than water and insoluble in water. Their vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless How can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol ' foam, carbon dioxide or dry chemical If material not on fire and not Involved In flra Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain How as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear bools, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water BATTERY BOX COMPOUNDS {FLAMMABLE LIOUIO, 4910550 N.O.S.) FLAMMABLE UOUID UN1993 Battery box compounds are various colored liquids. They have a Hash point of less than 100 deg. F. They are generally heavier than water and insoluble in water, their vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless How can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cod all affected containers with flooding quantities of water Appiy water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Continued on next pogo 59 ,,CO 0000098 If material not on fire and not Involved In fire Keep sparks, flames, and other sources of Ignition away Keep material out of water sources ana sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keeo upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water BATTERY CHARGER WITH ELECTROLYTE (ACIO) 4936567 CORROSIVE MATERIAL. ACIDIC NA2794 Battery charger with electrolyte (acid) consists of a package containing a battery charger and container <s) of electrolyte (acid). The electrolyte is a sulfuric acid-water solution, ft is a colorless odorless liquid and is soluble in water with evolution of heat. It is corrosive to metals and tissue. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Apply water from as far a distance as possible If material not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this materiai If contact with the matenal anticipated, wear full protective clothing BATTERY CHARGER WITH ELECTROLYTE 4936568 (ALKALINE BATTERY FLUID) CORROSIVE MATERIAL. BASIC NA2794 Battery charger with electrolyte (alkaline battery fluid) consists of a package containing a battery charger and container (s) of electrolyte (alkaline battery fluid). The electrolyte is water solution of potassium or sodium hydroxide. It is a colorless odorless liquid and is soluble in water with release of heat. It is corrosive to metals and tissue. If materiel involved in tire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Apply water from as far a distance as possible if materiai not Involved in fire Keep matenal out of water sources and sewers Build dikes (o contain flow as necessary Personnel protection Avoid bodily contact with the materiai Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing 60 BATTERY SETS FOR WET BATTERIES (CORROSIVE 4936503 SOLID, N.O.S.) CORROSIVE MATERIAL. BASIC UN1759 Battery sets for wet batteries have containers of potassium or sodium hydroxide in the same package with other non-reguiated items. Potas sium or sodium hydroxide are white solids. They are soluble in water with release of heat. They are corrosive to metals and tissue. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as tog Afcply water from as far a distance as possible If material not involved in fire Keep matenal out of water sources and sewers Personnel protection Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water BATTERY SETS IN BATTERY BOXES (CORROSIVE 4936504 SOLID. N.O.S.) CORROSIVE MATERIAL, BASIC UN1759 Battery sets m battery boxes have containers of potassium or sodium hydroxide in the same package with other non-reguiated items. Potas sium and sodium hydroxide are white solids. They are soluble in water with release oi heat. They are corrosive to metals and tissue. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Materiai itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Apply water from as far a distance as possible H material not invoivad In fira Keep material out of water sources and sewers Personnel protection Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any materiai which may have contacted the body with copious amounts of water or soap and water BATTERY, ELECTRIC STORAGE. WET 4936556 CORROSIVE MATERIAL NA2794 Battery, electric storage, wet is the battery containing either electrolyte (acid) or alkaline corrosive battery fluid. The batteries are continuously evolving hydrogen, a flammable gas. The fluids are soluble in water with evolution of heat. They are corrosive to metals and tissue. It material Involved In tire Extinguish fire using agent suitable for type of surrounding fire (Materiai itsetf does not bum or bums with difficulty.) Use water in flooding quantities as fog Apply water from as far a distance as possible If material not involved in lire Keep material out oi water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing 000 C# VIC'D April 196t BATTERY, ELECTRIC STORAGE. WET. WITH 4936557 CONTAINERS OF CORROSIVE BATTERY FLUID CORROSIVE MATERIAL NA2794 Battery. electric storage, wet. with containers of corrosive battery fluid consist of the batteries packed in the same outside shipping container with battery fluid. The fluid is usually sulfuric acid or sodium potassium nydroxide solutions. The fluid is soluble in water with evolution of heat, it is corrosive to metals and tissues. If material involved in fire Extinguish fire using agent suitable tor type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding Quantities as fog Aopfy water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid bodily contact wiih the material Wear boots, protective gloves, and goggles Oo not handle broken packages without protective equipment Wash away any material wnich may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material if contact with the material anticipated, wear full protective clothing BAY RUM (COMBUSTIBLE LIQUID. N.O.S.) 4915420 COMBUSTIBLE LIQUID NA1993 Bay rum is a clear colorless to variable colored liquid with a pleasant odor. It has a flash point between 100 and 199 deg. F. It is lighter than water and soluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol" foam, carbon dioxide or dry chemicat If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to disperse vapors and dilute standing pools oi liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts oi water or soap and water BAY RUM (FLAMMABLE LIQUID, N.O.S.) 4910420 FLAMMABLE LIQUID UN1993 Bay rum is a clear colorless to variable colored liquid with a pleasant odor. It has a flash point of less than 100 deg. F. It is lighter than water and soluble m water. Its vapors are heavier than air. H material on fira or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol'' foam, carbon dioxide or dry chemical if material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers April 1981 Build dikes to contain flow as necessary Use water spray to disperse vapors and dilute standing pools of liauid 'Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water BELT DRESSING (COMBUSTIBLE LIQUID. N.O.S.) 4915416 COMBUSTIBLE LIQUIO NA1993 Belt dressing is a material containing a solvent having a closed cup flash point between 100 and 199 deg. F. The hazard is combustibility. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as tog Solid streams of water may be ineffective Cool alt affected containers with flooding Quantities of water Apply water from as far a distance as possible Use 'alcohol ' foam, carbon dioxide or dry cnemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers Build dikes to contain flow as necessary Use water spray lo knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts of water or soap and water BELT DRESSING^FLAMMABLE LIQUID, N.O.S.) 4910416 FLAMMABLE LIQUID UNI 993 Belt dressing is a material containing a solvent having a closed cup flash point of less than 100 deg. F. The hazard is flammability. If material on fire or involved In fire Oo not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'' foam, carbon dioxide or dry chemical If materM not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water B6NZALDEHYDE 4913111 COMBUSTIBLE LIQUID NA1999 Benzaklehyde is a dear colorless to yellowish liquid with an atmondlike odor. It has a Hash point of 146 deg. F. It is heavier than water and insoluble in water. Its vapors are heavier than air. Continued on next pogo ooooo005 61 tt material on fire or involved in fire Do not extinguish fire unless ttow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keeo material out of water sources and sewers Build dikes to contain flow as necessary Use water soray to Knock-down vapors Personnel protection Avoid breathing vapors KeeD upwind Wear boots, protective gloves, and goggies Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water BENZENE 4908110 FLAMMABLE LIQUID UN1114 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Benzene is a clear colorless liquid with a characteristic aromatic odor. It is used to make other chemicals, as a solvent, and as a gasoline additive, ft has a flash point of 12 deg. F.. and solidifies at 42 deg. F. it is fighter than water and insoluble in water. Its vapors are heavier than air. It weighs 7.3 pounds per gallon. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with Hooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggies Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If matenai leaking (not on fire), downwind evacuation must be considered Environmental considerations--land apiU Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash. cement powder, sawdust or com mercial sorbents Apply fluorocarbon-water foam to diminish vapor and fire hazard Environmental considerations--water spHI Use natural barriers or oil spill control booms to limit spiR motion Use surface active agent (e.g. detergent, soaps, alcohols) to com press and thicken spilled material Inject "universal" gelling agent to solidify encircled spill and increase effectiveness of booms If dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration 62 Remove trapped matenai with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mtst to knock down vapors BENZENE PHOSPHORUS DICHLORIOE 4931715 CORROSIVE MATERIAL. ACIDIC UN2798 Benzene phosphorus dichioride is a colorless fuming liquid. It is de composed by water to give hydrochloric acid with release of heat. It is corrosive to metals and tissue, if material on fire or involved in fire Use dry chemical or carbon dioxide Do not use water on material itself if large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with Hooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled matenai with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breaming apparatus Avoid bodily contact with the matenai Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenai which may have contacted the body with copious amounts of water or soap and water If contact with the matenai anticipated, wear full protective clothing BENZENE PHOSPHORUS THIODICHLORIDE 4931720 CORROSIVE MATERIAL ACIDIC UN2799 Benzene phosphorus thiodichlonde is a colorless fuming liquid. H is decomposed by water to give hydrochloric acid with release of heat, it is corrosive to metals and tissue H material on firs or Involved In firs Use dry chemical or carbon dioxide Do not use water on material itself If large quantities of combustibles are involved, use water in Hooding quantities as spray and fog Use water spray to absorb vapors Cod all affected containers with Hooding quantities of water Apply water from as far a distance as possible H material not on fire and not Involved in firs Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itsaH Neutralize spilled material with crushed limestone, soda ash. or time Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the matenai Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing April 196 MCD 000009806 BENZIDINE 4921503 POISON B UN1865 Benzidine is a greyish yellow to greyish red crystalline solid. It is used 10 make other chemicals, and in chemical and biological analysis, it is soluble in hot water, it is toxic by ingestion, inhalation, and skin ao- sorotion. Toxic oxides of nitrogen are produced during the combustion of this material. If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water m flooding Quantities as fog Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks. Names, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective eouipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material BENZINE 4906112 FLAMMABLE LIQUID UN1115 Benzine is a dear colorless liouid with a petroleum-like odor, tt has a flash point of less than 0 deg. F. It is lighter than water and insoluble m water, its vapors are heavier than air. if material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical if material not on fire and not involvad In fira Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle Droken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If matenal leaking (not on lire), downwind evacuation must be considered BENZOIC ACID 4964340 ORM-E NA9094 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Benzoic add is a white crystalline solid. It is used to make other chemicals, as a food preservative, and for other uses. It is slightly soluble in water, it will bum though it may take some effort to ignite. If materiel on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as tog Cool all affected containers with flooding quantities of water Apply water from as tar a distance as possible Solid streams of water may be ineffective Use "alcohol" foam, carbon dioxide or ory chemical If material not on fire and not involvad in fire Keep sparks, flames, ana other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors or dusts Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain itauid or solid material Cover solids with a plastic sheet to prevent dissolving in ram or fire fighting water Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Remove trapped matenal with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates BENZOIC DERIVATIVE PESTICIDE, LIQUID, N.O.S 4910507 (COUMPOUNDS AND PREPARATIONS) (INSECTICIDES. OTHER THAN AGRICULTURAL. NEC) FLAMMABLE UQUID UN277Q Benzoic derivative pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emulsifiable. The primary hazard of this material is the flammability of the carrier. It has a flash point below 100 deg. F. It can cause illness by inhalation, skin absorption and or inges tion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone: 600-424-9300. If material on fira or involvad in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cod all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical if material not on Bra and not involvad In fira Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wear self-contained breathing apparatus when fighting fires involv ing this material BENZOIC DERIVATIVE PESTICIDE, UQUIO, N.O.S. 4921609 (COUMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES, NEC, UQUID) POISON B UN2789 Benzoic derivative pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emuisifiabie. The carrier may bum though it may require some effort to ignite, it is toxic by inhalation, skin ab sorption, and/or ingestion, in case of damage to. or leaking from con tainers of this material contact the pesticide safety team network. Tele phone: 800-424-9300. Continued on next page Apnl 1981 MCD 000009807 63 If material on fire or involved in fire Do not extinguish fire unless flow can be stoooed Use water in flooding quantities as fog Solid streams of water may be ineffective Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possiDie Use alcohol' foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water BENZOIC DERIVATIVE PESTICIDE. LIQUID. N.O.S. 4910508 (COUMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES. NEC. LIQUID) FLAMMABLE LIQUID UN2770 Benzoic derivative pesticide is a liquid or solid dissolved in a liquid carrier. The liquid is water emuisifiabie. The primary hazard of this ma terial is the flammability of the earner. It has a flash point below 100 deg. F. It can cause illness by inhalation, skin absorption and or inges tion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone: 800-424-9300. If material on fire or involved in fira Do not extinguish fire unless flow can be stopped Use water m flooding quantities as fog Solid streams of water may be ineffective Cool an affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical. If material not on fira and not involved in fira Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wear self-contained breathing apparatus when fighting fires involv ing this material BENZOIC DERIVATIVE PESTICIDE. SOUD. N.O.S. 4921611 (COMPOUNDS AND PREPARATION (AGRICULTURAL INSECTICIDES, NEC, OTHER THAN LIQUID) POISON B UN2769 Benzoic derivative pesticide is a solid or a liquid absorbed on a dry earner. It is a wettabie powder. It is toxic by inhalation, skin absorption, andor ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone: 800- 424-9300. If materiel on fire or Involved In fira Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use alcohol" foam, carbon dioxide or dry chemical 64 If material not on fire and not involved in fire Keeo sparxs. flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning materia' Keep upwind Avoid oodiiy contact with the material Wear ooots. protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with codious amounts of water or soao ana water Wfear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing BENZOIC DERIVATIVE PESTICIDE. SOLID. N.O.S. 4921610 (COMPOUNDS ANO PREPARATION (INSECTICIOES. NEC, OTHER THAN AGRICULTURAL) POISON B UN2769 Benzoic derivative pesticide is a solid or a liauid absorbed on a dry earner. It is a wettabie powder. It is toxic by inhalation, skin absorption, andor ingestion, fn case of damage to. or leaking from containers of this matenai contact the oesticide safety team network. Telephone: 800- 424-9300. If material on fire or involved fn fire Extinguish fire using agent suitable for type of surrounding fire (Matenai itself does not burn or burns with difficulty.) Use water in flooding quantities as tog Use alcohol" foam, carbon dioxide or dry chemical If materiel not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep matenai out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear seif-contained breathing apparatus when fighting tires involv ing this material If contact with the material anticipated, wear full protective clothing BENZOIC DERIVITTVE PESTICIDE,LIQUID, N.O.S. 4921608 (COUMPOUNDS AND PREPARATIONS) (INSECTtCtOES, OTHER THAN AGRICULTURAL, NEC) POISON B UN2769 Benzoic derivative pesticide is a liquid or solid dissolved in a liquid earner. The carrier is water emuisifiabie. The carrier may bum though it may require some effort to ignite. It is toxic by inhalation, skin ab sorption. and/or ingestion. In case of damage to. or leaking from con tainers of this matenai contact the pesticide safety team network. Tele phone: 800-424-9300. if materiel on Are or Involved in fire Oo not extinguish (ire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol" foam, carbon dioxide or dry chemical April 1961 MCD 000009808 If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attemot to stop leak if without hazard Use water spray to Knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid Dodiiy contact with the material Wear full protective clothing Do not nanaie broken packages without protective equipment Wash away any material wntch may have contacted the body with copious amounts of water or soap and water BENZOL FORERUNNINGS, CRUOE. NOT BENZOL 4910204 (FLAMMABLE LIQUID. N.O.S.) FLAMMABLE LIQUID UN1993 Benzol forerunnings, crude, not benzol are clear colorless liquids with a petroleum like odor. They have a flash point of less than 100 deg. F. They are lighter than water and insoluble m water. Their vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical if material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water BENZONITR1LE 4919134 COMBUSTIBLE LIQUID UN2224 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-1000/454) Benzonitriie is a clear colorless liquid having an almond-like odor. 11 is used as a specialty solvent, and to make other chemicals. It has a flash point of 161 deg. F. It is heavier than water and slightly soluble in water. It weighs 8.4 pounds per gallon. 11 material on fire or involved in fire Do not extinguish tire unless flow can be stopped Use water in flooding quantities as tog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distanca as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in Are Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the matenal Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the oody with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered Environmental considerations--land spill Oig a pit. pond, lagoon, holding area to contain liouid or solid material Dike surface flow using soit, sand bags, foameo polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with caustic soda or soda ash Environmental considerations--water epill Use natural deep water pockets, excavated lagoons, or sand bag barners to trap material at bottom Add caustic soda If dissolved, apply activated carbon at ten times the spilled amount in region of fOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Combustion products include corrosive or toxic vapors BENZOYL CHLORIDE 4931725 CORROSIVE MATERIAL, ACIDIC, COMBUSTIBLE UN1736 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-IOOO/454) Benzoyl chloride is a colorless fuming liquid having a pungent odor. It is used in medicine, and in the manufacture of other chemicals. It is combustible and has a flash point of 162 deg. F. Its fumes are irritating to the eyes and mucous membranes. It is decomoosed by water to hydrochloric add and water insoluble benzoic add with release of heat. It is corrosive to metals and tissue. It weighs 10.2 pounds per gallon. H material on fire or involved In fire Use dry chemical or carbon dioxide Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on Are and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Wear seif-contamed breathing apparatus Avoid bodily contact with tha material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with tha material anticipated, wear full protective clothing Contfnuod on next page April 1981 MCD 000009809 65 Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liauid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agricultural Irme (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Neutralize with agricultural lime isiaked limei. crusned limestone, or sodium bicarbonate it dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses ol pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors BENZOYL PEROXIDE (BENZOYL PEROXIDE 4919115 CRYSTALS, GRANULES OR POWDERS. WET WITH NOT LESS THAN 30% WATER) ORGANIC PEROXIDE NA20S5 Benzoyl peroxide is a white granular solid. It is easily ignited and burns very rapidly. It strpngly supports the burning of combustible ma terials. Contact with many materials may result in ignition Under pro longed exposure to fire or neat, containers of the peroxide can explode. As the peroxide dries out it becomes more susceptible to ignition and decomposition. if material on fire or involved In fire Use water in flooding Quantities as fog Solid streams of water may be ineffective Coot ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this matenal if contact with the matenal anticipated, wear full protective clothing Approach fire with caution Evacuation If the matenal is on fire or involved in fire evacuate for a radius of 2500 feet BENZOYL PEROXIOE (BENZOYL PEROXID&DRY OR 4919110 WET WITH LESS THAN 30% WATER) ORGANIC PEROXIOE NA2085 Benzoyl peroxide is a white granular solid. It is easily ignited and bums very rapidly. It strongly supports the burning of combustible ma terials. Contact with many materials may result in ignition. Under pro longed exposure to fire or heat containers of the peroxide can explode. As the peroxide dries out it becomes more susceptible to ignition and decomposition. 66 if material on fire or involved in fire Burns with explosive violence, if it becomes ignited, it cannot be extinguished Use water in Hooding quantities as foa Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol" foam, carbon dioxide or dry chemical Dangerously explosive if material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the matenal Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting tires involv ing this material If contact with the matenal anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet BENZOYL PEROXIDE. (MORE THAN 77% BUT LESS 491911S THAN 95% WITH WATER) ORGANIC PEROXIDE UN208? Benzoyl peroxide, (more than 77% but less than 95% with water) i. a white solid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. It is easily ignited and bums with increasing rapidity as the fire progresses. It can form explosive mixtures with finely divided combustible matenals. it supports the burning of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or Involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Oangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wei spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning matenal Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted (he body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet April 19fc MCD 000009810 BENZOYL PEROXIDE. (NOT LESS THAN 30% BUT 4919117 NOT MORE 52% WITH INERT SOLIO) ORGANIC PEROXIDE UN2089 Benzoyl oeroxide. mot less than 30% but not more 52% with men solid) is a white solid. It is used to manufacture paints, plastics, and rubber, tt is msotuDte m water. It is easily ignited and burns with increas ing rapidity as the tire progresses. It can form explosive mixtures with finely divided combustible materials. It supports the burning o< combus tible materials. Under prolonged exposure to fire or neat containers of the material may explode. If material on fire or involved in fire Use water m flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities at water Apply water from as far a distance as possiple Use ' alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, names, and other sources of ignition away Keep material out of water sources and sewers Keep spilled materia) wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle Droken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2S00 feet BENZOYL PEROXIOE. (NOT MORE THAN 72% AS A 4919116 PASTE) ORGANIC PEROXIDE UN2087 Benzoyl peroxide, (not more than 72% as a paste) is a white solid, it is used to manufacture paints, plastics, and rubber. It is insoluble in water. It is easily ignited and bums with increasing rapidity as the fire progresses. It can form explosive mixtures with finely divided combus tible materials. It supports the burning of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or involved In fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol " loam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the matenal Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1961 Wear seif-containea oreathmg apparatus when fighting fires involv ing this material if contact with the material anticipated, wear full protective clothing Approacn fire with caution Evacuation If the matenal is on tire or involved in fire evacuate for a radius of 2500 feet BENZOYL PEROXIDE. (NOT MORE THAN 77% WITH 4919114 WATER) ORGANIC PEROXIDE UN2090 Benzoyl peroxide, (not more than 77% with water) is a white solid. It is used to manufacture paints, plastics, and ruooer. It is insoluble in water. It is easily ignited and bums with increasing rapidity as the tire progresses. It can form explosive mixtures with finely divided combus tible materials. It supports the burning of combustible materials. Under prolonged exposure to fire or heat containers of the materia) may explode. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol " foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning matenal Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this matenal If contact with the material anticipated, wear full protective clothing Approacn fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet BENZOYL PEROXIDE, (TECHNICALLY PURE OR) 4919113 BENZOYL PEROXIDE. (MORE THAN 52% WITH INERT SOLID) ORGANIC PEROXIDE UN2065 Benzoyl peroxide, (technically pure or) benzoyl peroxide, (more than 52% with inert solid) is a white solid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. It is easily ignited and bums with increasing rapidity as the fire progresses. It can form explosive mixtures with finely divided combustible materials. It supports the burning of combustible materials. Under prolonged exposure to fire or heat con tainers of the material may explode. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive Continued on next page WOW*'1 67 If material not on fire and not involved in fire Keep sparks, flames, ana other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle proken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soao and water Wear self-contained breathing apparatus wnen fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet BENZYL BROMIDE (BROMOTOLUENE, ALPHA) 4936010 CORROSIVE MATERIAL. POISONOUS UNI 737 Benzyl bromide is a colorless liquid with an agreeable odor it is toxic by inhalation and by skin absorption. It is slightly soluble m water and is heavier than water. It is corrosive to metals and tissue. If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Soiid streams of water may be ineffective Use alcohol'' foam, carbon dioxide or dry chemical If material not on fire end not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggies Oo not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soao and water If contact with the matenal anticipated, wear full protective clothing BENZYL CHLORIDE 4936012 CORROSIVE MATERIAL. POISONOUS, COMBUSTIBLE UN1738 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-IOO/45.4) Benzyl chlonde is a colorless liquid with an irritating odor, it is toxic by inhalation and skin absorption. It is combustible and has a flash point of f53 deg. F. It is slightly soluble in water. It is corrosive to metals and tissue. it weighs 9.2 pounds per gallon. If material on fire or involved In fire Use water in flooding quantities as fog Cool ail affected containers with flooding quantities of water Apoly water from as far a distance as possible Soiid streams of water may be ineffective Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors 68 Personnel protection Avoid breathing vapors Keeo upwind ' Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without Drotective equipment Wash away any matenal which may have contacted the body with copious amounts of water or soao and water If contact with the material anticipated, wear tull protective clothing Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain hauid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Apply universal' gelling agent to immobilize soill Environmental considerations--water spill Use natural deeo water pockets, excavated lagoons, or sand bag Darners to trap material at bottom Remove trapped material with suction hoses If dissolved, apply activated carbon at ten times the spilled amount m region of tOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment BENZYL CHLOROFORMATE 4933010 CORROSIVE MATERIAL. ACIDIC. POISONOUS UN1739 Benzyl chloroformate is a colorless liquid with an acrid odor. It is decomposed by water to give hydrochloric acid with evolution of heat. Its vapors are irritating to eyes and mucous membranes, ft is corrosive to metals and tissue. If material on fire or involved in fire Use dry chemical, carbon dioxide, or dry sand Do not use water on matenal itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cooi all affected containers with flooding quantities of water Apply water from as far a distance as possible ff material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Oo not use water on matenal itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water if contact with the material anticipated, wear full protective clothing BERYLLIUM CHLORIDE 4923305 POISON B UNI 566 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Beryllium chloride is a white to yetiow crystalline mass. It absorbs water from the air and dissolves in it. It is toxic by ingestion. April 198. 000009812 MCD If material Involved in fire Extinguish lire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.! Use water in flooding quantities as fog Use foam, carbon oioxide or ary chemical If material not involved in fire <eeo material out of water sources ana sewers Personnel protection Avo'fl breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, ana goggles Do not hanale broken pacnages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agncultural time (slaked lime). crushed limestone. or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates BERYLLIUM COMPOUND, N.O.S. 4923216 POISON B UNI 566 Beryllium compounds, n o s. are generally white crystalline or pow dered material containing beryllium. They are generally soluble in water. They are toxic by inhalation and by ingestion. If material involved in fire Extinguish fire using agent suitable for type of surrounding tire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the matenal Wear full protective clothing Do not handle broken packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material BERYLLIUM FLUORIDE 4923310 POISON B NAt 566 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-S000/2270) Beryllium fluoride is a colorless crystalline mass. It is soluble in water. It is toxic by ingestion. If materiel involved In fire Extinguish fire using agent suitable lor type ol surrounding fire (Matenal itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved In fire Keep matenal out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind April 1981 MCD 000009B13 Avoid bodily contact with the matenal Wear boots, protective gloves, and goggles Do not handle broken packages without protective eauipment Wash away any material which may have contacted the body with copious amounts of water or soap ana water Wear self-contained breathing apparatus when fighting fires involv ing this matenal If contact with the materia! anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain hauid or solid matenal Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agncultural lime (slaked iimei. crushed limestone. or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates BERYLLIUM HYDROXIDE (BERYLLIUM COMPOUND. 4923315 N.O.S.) POISONS UNI 566 Beryllium hydroxide is a white powder. It is insoluble in water. It is toxic by inhalation (dust, etc.) and by ingestion. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not Involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning matenal Keep upwind Avoid bodiiy contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any materia) which may have contaciea the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing BERYLLIUM NITRATE 4919759 OXIDIZER UN2464 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Beryllium nitrate is a white to pale yellow crystalline solid. It is used in chemical analysis. It is soluble in water. It is noncombustible, but it will accelerate die burning of combustible materials. II larga quantities of the matenal are involved or the material is finely divided, an explosion may resulL Prolonged exposure to tire or heat may result in an explosion. Toxic oxides of nitrogen are produced in fires involving this material. If materiel involved in fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on Are and not Involved in fire Keep material out of water sources and sewers Personnel protection Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Environmental considerations land spill Oig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Contfnuod on next pegs 69 Environmental consideration*--water spill Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium Bicarbonate Adjust oh to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates BERYLLIUM PHOSPHATE (BERYLLIUM COMPOUND. 4923325 N.O.S.) POISON B UNI 566 Beryllium ohosphate is a white crystalline powder. It is insoiuoie m water. It is toxic By inhalation (dust, etc.) and by ingestion. If material involved in lire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the matenal anticipated, wear full protective clothing BERYLLIUM SULFATE (BERYLLIUM COMPOUNO. 4923330 N.O.S.) POISON B UNI 566 Beryllium sulfate is a colorless crystalline solid. It is soluble in water. It is toxic by ingestion. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not Involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and watar Wear self-contained breathing apparatus when fighting fires involv ing this matenal If contact with the material anticipated. wear full protective clothing BETA-PROPIOLACTONE (COMBUSTIBLE UOUIO. 4913110 N.O.S.) COMBUSTIBLE UOUIO NA1993 Beta-propiolactone is a clear colorless liquid with a pungent odor. It has a flash point of 167 deg. F. It is heavier than water and sokjbla in water. Its vapors ars heavier than air. if materiel on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as log Solid streams of watar may be ineffective 70 000009814 WCD Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use 'alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keeo upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with cooious amounts of water or soap and water BIPHENYL (DIPHENYL) (COMBUSTIBLE LIQUID. 4913108 N.O.S.) COMBUSTIBLE LIQUID NA1993 Biphenyl is a clear colorless liquid with a pleasant odor. It is used to manufacture other chemicals and as a fungicide. It has a flash point of 180 deg.f. and is insoluble in water. Its vapors are heavier than air H material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 81PYR10IUUM PESTICIDE. UQUtD, N.O.S. 4910521 (COMPOUNDS AND PREPARATIONS) (INSECTICIDES. OTHER THAN AGRICULTURAL. NEC) FLAMMABLE UQUID UN2782 Bipyndilium pesticide is a liquid or solid dissolved in a liquid earner. The carrier is water emuisiliabte. The primary hazard of this material is the flammability of the carrier, tt has a flash point below 100 deg. F. It can cause illness by inhalation, skin absorption and'or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone: 800-424-9300. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical ft material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors April 19c 8IPYRIDILIUM PESTICIDE.LIQUID. N.O.S. 4921615 (COMPOUNDS ANO PREPARATIONS) (INSECTICIDES. OTHER THAN AGRICULTURAL, NEC) POISON B UN2781 Bipyndilium pesticide is a liquid or solid dissolved in a liquid earner. Tne carrier is water emulsifiable. The carrier may burn though it may require some effort to ignite. It is toxic by inhalation. sKin absorption, ardor ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone: 800- 424-9300. If material on fire or involved in fire Do not extinguish tire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use 'alcohol" foam, carbon dioxide or dry chemical If materiel not on fire end not involved in fire KeeD sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the matenai Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water SLACK POWDER 4901710 CLASS A EXPLOSIVE Black powder is a black granular solid consisting of charcoal potas sium nitrate and sulfur. It is easily ignited and once ignited bums very rapidly. Under prolonged exposure to firs or heat containers of the ma terial can explode. If material on fire or involved in Are Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let bum K material not on Are and not Involved In Are Keep sparks, flames, and other sources of ignition away Keep spilled material wet Wet spilled material before picking it up Do not attempt to sweep up dry material Personnel protection Avoid breathing dusts, and fumes from burning material Wear protective gloves and safety glasses Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 5000 feet 72 BLACK POWDER IGNITER WITH EMPTY CARTRIDGE 4903110 BAG CLASS C EXPLOSIVE Black powder igniter with empty cartndge bag consists of emoty car tridge bags with an igniter composed of black powder attached to it. It materiel on fire or Involved in Are Dangerously explosive Flood with water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep spams, flames, and other sources of ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this matenai Evacuation If fire becomes uncontrollable--evacuate for a radius of ^ 500 feet BLASTING AGENT. N.O.S. 490291S BLASTING AGENT Blasting agent. N.O.S. is the proper shipping name for those materials used for blasting that can not be detonated with an electric blasting cap, and will not explode when subject to friction, or impact: or when the largest single package is subject to fire. However if large quantities of this material are involved in a fire, it may explode. If material on fire or Involved in fire Low order explosive potential Do not fight fires in a cargo of blasting agents Evacuate area and let bum If material not on fire end not involved in Are Keep sparks, flames, and other sources of ignition away Keep spilled material wet Wet spilled material before picking it up Do not attempt to sweep up dry material Personnel Protection Avoid breathing dusts, and fumes from burning material Wear protective gloves and goggles Do not handle broken packages without protective equipment Wash away any material which rriay have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when lighting fires involv ing this material Evacuation Ifthe material ta on fire or involved in fire evacuate for a radius of 2500 feet BOILER COMPOUNDS* LIQUID 4936505 CORROSIVE MATERIAL NA1760 Boiler compounds, liquid are various colored liquids. They are water soluble and are corrosive to metals and/or tissue. If materiel on Are or Involved In Are Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from aa far a distance as possible Solid streams of water may be ineffective Use "alcohol*' foam, carbon dioxide or dry chemical Continued on noxt page April 1981 Personnel protection Avoid breathing vapors Keep uowrnd Wear boots, protective gtoves. and goggles Do not handle broken packages without protective equipment Wear self-contained breathing apparatus when figntmg tires involv ing this material BIPYRIDILIUM PESTICIDE. LIQUID. N.O.S. 4910522 (COMPOUNDS ANO PREPARATIONS) (AGRICULTURAL INSECTICIOES. NEC. LlQUIO) FLAMMABLE LIQUID UN2782 Bipyridilium pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emuisitiabie. The primary hazard of this material is the flammability of the carrier, it has a flash point below 100 deg. F it can cause illness by inhalation, skin absorption and or ingestion, in case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone: 800-424-9300. If material on fira or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol foam, carbon dioxide or dry chemical If material not on fira and not involved in fire Keep sparks, flames, and other sources of ignition away Keep malenal out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective eauipment Wear self-contained breathing apparatus when fighting (ires involv ing this material BIPYRIDILIUM PESTICIDE. SOLID. N.O.S. 4921618 (COMPOUNDS ANO PREPARATIONS) (AGRICULTURAL INSECTICIDES. NEC, OTHER THAN LIQUID) POISON B UN2781 Bipyridilium pesticide is a solid or a liquid absorbed on a dry earner, it is a wettable powder. It is toxic by inhalation, skin absorption, and'or ingestion. In case of damage to. or leaking from containers of this ma lenal contact the pesticide safety team network. Telephone: 800-424- 9300. If material on fire or involved in fire Extinguish fire using agent suitable lor type of surrounding fire (Matenai itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use ` alcohol" foam, carbon dioxide or dry chemical If material not on fire end not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewera Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing (his matenai If contact with the matenai anticipated, wear full protective clothing BIPYRIDILIUM PESTICIDE. SOLID, N.O.S. 4921617 (COMPOUNDS ANO PREPARATIONS) (INSECTICIDES, OTHER THAN AGRICULTURAL, NEC) POISON B UN2781 Bipyndilium pesticide is a solid or a liquid absorbed on a dry carrier. The earner is water emuisifiable. tt is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to. or leaking from containers ot this matenai contact the pesticide safety team network. Teieohone: 800424-9300, If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep matenai out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning matenai Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenai which may have contacted the body with copious amounts of water or soap ana water Wear self-contained breathing apparatus when fighting fires involv ing this material if contact with the material anticipated, wear full protective clothing BIPYRtDIUUM PEST1CI0E.UQUI0. N.O.S. 4921616 (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES, NEC, LIQUID) POISON B UN2781 Bipyridilium pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emuisifiable. The carrier may bum though it may require some effort to ignite. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone; 800- 424-9300. H material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If materiel not on fire end not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Buiid dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective dothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1981 000009816 71 If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material if contact with the material anticipated, wear full protective clothing BOND BREAKING COMPOUND. CONSISTING OF 4915144 NAPHTHA PETROLEUM RESINS ANO VEGETABLE OIL (COMBUSTIBLE LIQUID. N.O.S.) COMBUSTIBLE LIQUID NA1993 Bond breaking compound is a various colored liquid. It has a flash point between 100 and 200 deg. F. It is lighter than water and insoluble m water, its vapors are heavier than air. if materiel on fire or involved In fire Do not extinguish tire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol" foam, carbon dioxide or dry cherhical If material not on fire end not Involved in fire Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water BONO BREAKING COMPOUNO. CONSISTING OF 491014$ NAPHTHA. PETROLEUM RESINS AND VEGETABLE OILS (FLAMMABLE LIQUID. N.O.S.) FLAMMABLE LIQUID UNI 993 Bond breaking compound is a various colored liquid, it has a flash point of less than 100 deg. F. It is lighter then water and msotude in water. Itsvapors are heavier than air. if material on fire or involved in fire Do not extinguish fire unless flow can be Mopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use 'alcohol'' foam, carbon dioxide or dry chemical If materiel not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water BOOSTER (EXPLOSIVE) (COMMERCIAL) 4901310 CLASS A EXPLOSIVE Booster (explosive) consists of a casing containing a high explosive. It is used to intensify the explosion of a detonator If material on fire or involved in fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let burn If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 5000 feet BOOSTER, (EXPLOSIVEXMILITARY) 490121$ CLASS A EXPLOSIVE Booster (explosive) consists of a casing containing a high explosive. It is used to intensify the explosion of a detonator or detonating fu2e. If the casing is metal the booster wiil explode under fire conditions. If the casing is nonmetailic the the booster may or may not explode under fire conditions. If material on lira or Involved In fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area avid let bum If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear sell-contained breathing apparatus when fighting fires involv ing this material Evacuation If tha material is on fire or involved in fire evacuate for a radius of 5000 feet BORDEAU ARSENITE. UQUID 4923420 POISON B NA27S9 Bordeau arsenite. liquid is arsenic and copper compounds. They are dark in color and are used as an insecticide. They are toxic by ingestion and inhalation. If material Involved In fire Extinguish fire using agent suitable tor type of surrounding fire (Matenat itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Usa foam, carbon dioxide or dry chemical H material not involved in fire Keep material out of water sources and sewers Continued on next page April 1981 .0* .00,' 0' O' e> 73 Personnel protection Avoid breathing busts, ana fumes from burning material Keep uowmd Avoid bodily contact with the material Wear boots, protective gloves; and goggles Do not handle broken packages without protective eauipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material It contact with the material anticipated, wear full protective ciothmg BORDEAUX ARSENITE, SOLID 4923415 POISON B NA2759 Bordeaux arsemte. solid is an arsenic and copper compound. It is a black crystalline solid, and is used as an insecticide. It is toxic by inges tion and by inhalation (dusts, etc). It is generally soluble in water. If material involved in fire Extinguish tire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding Quantities as fog Use foam, carbon dioxide or dry cnemical If material not involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gioves. and goggles Oo not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water * Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing BORON TRIBROMIDE 4932010 CORROSIVE MATERIAL. ACIDIC. POISONOUS UN2692 Boron tribromide is a colorless, fuming liquid with a pungent odor. Its fumes are irritating to the eyes and mucous membranes. It is decom posed by water to hydrobromic and boric acids with release of heat. II is corrosive to metals and tissue, if material involved in Are Use dry chemical, carbon dioxide, or dry sand Do not use water on matenal itself If large quantities of combustibles are involved, use water in flooding Quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved In fire Keep matenal out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled matenal with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts of water or soap and water tf contact with the matenal anticipated, wear full protective clothing 74 90^ oo BORON TRICHLORIDE 4932011 CORROSIVE MATERIAL. POISONOUS. ACIDIC UN1741 Boron trichloride is a colorless fuming Iiquio with a Dungent odor, li is used as a cataryst m chemical manufacture, in soldering fluxes, ana for many other uses. Its fumes are irritating to the eyes ana mucous membranes. It is decomposed by water to boric and hydrochloric acids with release of heat, it is corrosive to metals and tissue. If material invoived in tire Use dry chemical, carbon dioxide, or dry sand Do not use water on matenal itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Coof alt affected containers with flooding auantities of water Apply water from as far a distance as oossioie If material not involved in fire Keep matenal out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on matenal itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily oontact with the matenal Wear boots, protective gtoves. and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the matenal anticipated, wear full protective clothing BORON TRIFLUORIDE 4904110 NONFLAMMABLE GAS. POISONOUS UN1008 Boron tnfluohde is a colorless gas with a pungent odor. It is toxic by inhalation. It is soluble in water and slowly hydrolyzed by cold water to give hydrofluoric acid, a corrosive material. Its vapors are heavier than air. it may only be shipped m cylinders. If material involved In lira Extinguish fire using agent suitable for type of surrounding fire (Matenal itself does not burn or burns with difficulty.) Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Usa watar spray to absorb vapors H material not Involved in fire Keep material out of water sources and sewers Attempt to stop leak if without hazard Usa watar spray to knock-down vapors Do not usa water on material itself Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protactive clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fira). downwind evacuation must be considered April 1981 BORON TRIFLUORIDE-ACETIC ACIO COMPLEX 4930202 CORROSIVE MATERIAL. ACIDIC UNI 742 Boron influoride-acetic acid complex is a colorless liquid with a Den- etrating odor. It is soluDle m water. It is corrosive to metals and tissue. If material on fire or involved in fire Do not use water on material itself Use aiconoi foam, carport dioxide or dry chemical Cool an affected containers with flooding quantities of water Aooiy water from as far a distance as possible If material not on fire and not involved in fire Keeo material out of water sources ano sewers Build dikes lo contain flow as necessary Use water spray to knock-aown vapors Neutralize spilled material with crusned limestone, soda ash. or lime Personnel protection Avoid Dreathmg vapors Keep upwind Wear seif-contained Breathing apparatus Avoid oodiiy contact with the material Wear Boots, protective gloves, and goggles Do not handle Broken packages without arotective eouipment Wash away any material which may have contacted the Body with codious amounts of water or soap and water H contact with the material anticipated, wear full protective clothing BOX TOE GUM 4910109 FLAMMABLE LIQUID UN2059 Box toe gum is the solution of a gum m a ftammaoie solvent. It has a flash point of less than 100 deg. F If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams ol water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol' foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain (low as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water BOX TOE GUM 491S109 COMBUSTIBLE LIQUID UN2060 Box toe gum is the solution of a gum in a flammable solvent. It has a flash point between 100 and 199 deg. F. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol" loam, carbon dioxide or dry chemical April 1981 WCP 000009818 If matarial not on fire and not involved In fire Keep sparks. flames, and other sources of ignition away Keeo material out of water sources ano sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid Breathing vapors Keeo uowind Wear Boots, protective gloves, and goggles Do not handle Broken packages without protective eauioment Wash away any material which may nave contacted the body witn copious amounts of water or soap and water BRAKE OR SHOCK ABSORBER FLUIO OR 4915543 HYDRAULIC SYSTEM FLUID OTHER THAN PETROLEUM (COMBUSTIBLE LiQUIO, N.O.S.) COMBUSTIBLE LIQUIO NA1993 Brake or shock absorber fluid or hydraulic system fluid other lhan petroleum is a various colored liquid, it has a flash point of between 100 and 200 deg. F. it is lighter than water and insoluble in water, its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in hooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks. Ilames. and other sources of ignition away Keep matenal out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water BRANDY, ALCOHOLIC (ALCOHOLIC BEVERAGE) 4910107 FLAMMABLE UOUIO UN1170 Brandy, alcoholic is clear colorless to variable colored liquid with a charactetistic odor. It has a flash point of less than 100 deg. F. It is lighter than water and soluble in water. Its vapors are heavier than air. H material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire end not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Continued on next page 75 Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Oo not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap ana water BRANDY, ALCOHOLIC (ALCOHOLIC BEVERAGE) 491S107 COMBUSTIBLE LIQUID UN1170 Brandy, alcoholic is clear colorless to variable colored liquid with a characteristic odor. It has a flash point between lOG and 199 deg. F It is lighter than water and soluble m water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water m flooding Quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep materia! out of water sources and sewers Build dikes to contain flow as necessary Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water BROMBENZYL CYANIDE, LIQUIO (IRRITATING 4925210 AGENT. N.O.S.) IRRITATING MATERIAL NA1893 Brombenzyl cyanide is a pale yellow crystalline solid melting at 77 deg. F. to a brown oily liquid. The vapors are extremely irritating to the eyes and mucous membranes. Exposure to high concentrations may be fatal. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or involved In fire Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical Cool all affected containers with flooding quantities of water Use water spray to absorb vapors If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Oo not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing 76 BROMINE CORROSIVE MATERIAL. POISONOUS. OXIDIZING 4936110 UN1744 - Bromine ts a reddish brown turning liquid with a pungent odor, its vapors are irritating to the eyes and mucous membranes. It is toxic r inhalation. It is heavier than water and slightly soluble in water, it a celerates the burning of combustible material. It is corrosive to metaia and tissue. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty ! Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use water spray to absorb vapors If material not involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear lull protective clothing Do not handle broken packages without protedive equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire) evacuate for a radius of 2500 feet BROMINE PENTAFLUORIOE 4918505 OXIDIZER, CORROSIVE UN174' Bromine pentafluoride is a colorless fuming liquid with a pungent odv it is use to make other chemicals and in rockets. It is decomposed by water to hydrofluoric acid and other materials with release of heat. Its vapors are irritating to the eyes and mucous membranes. It is corrosive to metals and tissue. It will accelerate the burning of combustible ma terial. It may only be shipped in cylinders without any safety relief device. If cylinders are involved in fire they may violently rupture and rocket. If material Involved in fire Do not use water on material itseif Use dry chemical or carbon dioxide Cool all affected containers with flooding quantities of water If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors If materiel net Involved in fire Do not use water on material itself Keep material out of water sources and sewers Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the matenai Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered Apnl 19t MCD 000009819 8R0MINE TRIFLUORIDE 4918507 OXIDIZER. CORROSIVE UN1746 Bromine trifluonde is a colorless to yellow fuming nauid with a oungent odor it solidifies at 48 deg. F. It is decomposed by water to hydrofluoric acid and other materials with release of heat, it is corrosive to metals and tissue. It will accelerate the burning of combustible material. It may only be shipped m cylinder without any safety relief device. If the cyinders are involved m fire they may violently rupture and rocKet. If material involved in fire Do not use water on material itself Use dry cnemicai or caroon d>o*iae Cool all affected containers with Hooding quantities of water If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors If material not involved in fire Do not use water on material itself Keep material out o' water sources and sewers Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Oo not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct liame---evacuate for a radius of 1500 feet if material leaking (not on fire), downwind evacuation must be considered 9ROMOACET1C ACIO SOLUTION 4931411 CORROSIVE MATERIAL. ACIDIC UN1938 Bromoacetic acid solution is the colorless crystalline material dis solved m water. It is corrosive to metals and tissue. If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire end not involved in fire Keep matenal out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled matenal with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the matenal Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the matenal anticipated, wear full protective clothing BROMOACETIC ACIO. SOUD 4931410 CORROSIVE MATERIAL UN1938 Bromoacetic acid, solid is a colorless crystalline matenal. It absorbs moisture from the air and forms a syrup, it is soluble in water. It is corrosive to metals and tissue. pnl 1981 HCD 000009820 If material on fire or involved In fire Use water m flooding quantities as fog Cool all affected containers with flooding quantities oi water Apply water from as far a distance as possible Use "alcohol" foam, caroon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers Neutralize spilled matenal with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Oo not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this matenai if contact with the matenal anticipated, wear full protective clothing BROMOACETONE, LIQUID 4930101 POISON A. FLAMMABLE UN1569 Bromoacetone is a dear colorless liquid turning violet in the absence of air and further decomposing to a black resinous mass on long stand ing. In low concentrations it is very irritating to the eyes and in higher concentrations or prolonged exposure to low concentration it is toxic by inhalation. Contact with the liquid will cause very painful bums. The matenal may only be shipped in cylinders or bottles or cans packed in wooden boxes. The material will burn. Prolonged exposure of the cyl inders to heat or fire may result in the violent rupturing and rocketing of the cylinders. If material on fire or involved in fire Do not extinguish fire unless flow can be stooped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, llamas, and other sources of ignition away Keep matenai out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Pereonnei protection Avoid breathing vapors Keep upwind Wear seif-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered BROMOBENZENE 4913112 COMBUSTIBLE LIQUID UN2S14 Bromobenzene ia a dear colorless liquid with a pleasant odor. It has a flash point of 124 deg. F. It is heavier than water and insoluble in water. Its vapors are heavier than air. Continued on next page 77 If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparns. flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vaoors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material BRUCINE. SOLID (DIMETHYL STRYCHNINE) 4921411 POISON B UN 1570 Brucine, solid is a white crystalline solid. It is very slightly soiuDle in water. It is combustible though it may require some effort to ignite It is ioxjc by inhalation (vapor, dust, etc.) If material on fire or Involved in fire Extinguish fire using agent suitable tor type of surrounding fire (Material itself does not burn or bums with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not on fire and not invoivad in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing vapors or dusts Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts of water or soap and water BURSTER (EXPLOSIVE) CLASS A EXPLOSIVE 4901220 ' Burster (explosive) consists of a casing containing a high exoiosive It is used to rupture a bomo or projectile to release the contents. Unc tire conditions they will explode. If material on fire or involved In fire Dangerously explosive Do not fight tires in a cargo of exDlosives Evacuate area and let burn If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fightina fires involv ing this material Evacuation If the material is on fire or involved m fire evacuate for a radius ot 5000 feet BUTADIENE, INHIBITED (BUTAOIENE FROM 4905705 ALCOHOL) FLAMMABLE GAS UN1010 Butadiene, inhibited is a colorless gas with an aromatic odor, it is used to make synthetic rubber and plastics, and to make other chemicals It is shipped as a liquefied gas under its vapor pressure. Contact with the liquid can cause frostbite, it must be shipped inhibited as it is liable to polymerization If polymerization were to take place in a cylinder or tank car. the cylinder or tank car may violently rupture. It is easily ignited. Its vapor is heavier than air and a flame can flash back to the source of leak very easily it can asphyxiate by the displacement of air Under fire conditions the cylinders or tank cars may violently rupture and rocket. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities oi water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective eouipment Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet If matenal leaking (not on fire), downwind evacuation must be considered BURNT COTTON. NOT REPICKED (COTTON, NEC, IN 4917304 BALES COMPRESSED) FLAMMABLE SOLID NA1325 Burnt cotton, not repicked is cotton fibre that has been on fire and the burned portion has not been removed. The hazard is that once cotton has been on fire, the tire may persist in the interior of the bale for a long time. The regulations require that burnt cotton be held for ten days after the last evidence of fire, before it is offered for transportation. If material on fire or involved in fire Flood with water If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away BUTADIENE, INHIBITED (BUTADIENE FROM 4905704 PETROLEUM) FLAMMABLE GAS UN1010 Butadiene, inhibited is a colorless gas with an aromatic odor. It is used to make synthetic rubber and plastics, and to make other chemicals. It is shipped as a liquefied gas under its vapor pressure. Contact with the liquid can cause frostbite. It must be shipped inhibited as butadiene is liable to polymerization. If polymenzation occurs in a cylinder or tank car. the cylinder or tank car may violently rupture, it is easily ignited, its vapors are heavier than air and a flame can (lash back to the source of leak very easily. It can asphyxiate by the displacement of air. Under fire conditions the cylinders or tank cars may violently rupture and rocket 78 MCD 000009821 April 19bi If material on fir* or involved In fire Do not extinguish fire unless flow can be stooped Use water in flooding Quantities as fog Cool all affected containers with flooding quantities of water Apply water From as far a distance as possible If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keeo material out of water sources ana sewers Attempt to stop teak if without hazard Use water spray 10 knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach tire with caution Evacuation II fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 leet If material leaking (not on fire), downwind evacuation must be considered If materiel on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible if material not on fire end not Involved In fire Keep sparks, flames, and other sources of ignition away Keep matenai out of water sources and sewers Attempt to stop leak tf without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet if material leaking (not on fire), downwind evacuation must be considered BUTADIENE. INHIBITED (BUTADIENE, IMPURE, FOR 4905703 FURTHER REFINING) FLAMMABLE GAS UN1010 Butadiene, inhibited is a colorless gas with an aromatic odor. It is shipped as a liquefied gas under its vapor pressure. Contact with the liquid can cause frostbite. II must be shipped inhibited as butadiene is liable to polymerization. If polymerization were to take place in a cylinder or tank car. the cylinder or tank car may violently rupture, it is easily ignited, its vapor is heavier than air and a flame can Hash back to the source of leak very easily. It can asohyxiate by the displacement of air. Under fire conditions the cylinders or lank cars may violently rupture and rocket. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggies Do not handle broken packages without protective equipment Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet If material leaking (not on fire), downwind evacuation must be considered BUTANE (BUTANE, IMPURE. FOR FURTHER 4905702 REFINING) FLAMMABLE GAS UNI 075 Butane is a colorless gas with a faint petroleum like odor. It is shipped as a liquefied gas under its vapor pressure. Contact with the liquid can cause frostbite. It is easily ignited. Its vapors are heavier than air and a flame can flash back to the source of leak very easily. The leak can be either a liquid or vapor leak. Under fire conditions the cylinders or tank cars may violently rupture and rocket, tf material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool alt affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggies Do not handle broken packages without protective equipment Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet If material leaking (not on fire), downwind evacuation must be considered BUTANE 49057M FLAMMABLE GAS UN1075 Butane is a colorless gas with a faint petroleum like odor. It is used as a fuel, an aerosol propellant, in cigarette lighters, and to make other chemicals. For transportation it may be stanched. It if shipped as a liquefied gas under its vapor pressure. Contact with the liquid can cause frostbite. It is easily ignited. Its vapors are heavier than air and a flame can flash back to the source of leak vary easily. The leak can be either a liquid or vapor leak. Under fire conditions the cylinders or tank cars may violently rupture and rocket. April 1981 mCD 000009822 2-BUTANOL (BUTYL ALCOHOL) 4909129 FLAMMABLE LIQUID NA1120 2-butanol is a dear, cotodesa liquid with a pleasant odor. It is used to make other chemicals and as a solvent. It has a flash point of 75 deg. F. It is lighter than water and soluble in water. Its vapors are heavier than air. ContlnuKl on noxt pogo 79 If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Aooiy water from as far a distance as possible Use alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparxs. (lames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain Itow as necessary Attempt to sioo leak if without hazard Use water spray to disperse vapors and dilute standing pools of iiauid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water BUTENE GAS. LIQUEFIED (LIQUEFIED PETROLEUM 4905707 GAS) FLAMMABLE GAS UN1075 Butene gas. liquefied is colorless gas with a faint petroleum tike odor. For transportation it may be stenched. it is shipped as a liquefied gas under its own vapor pressure. Contact with the liquid can cause frostbite. It is easily ignited. Its vapor is heavier than air. and a flame can flash back to the source of the leak very easily. The leak can either be a liquid or vapor leak. It can asphyxiate by the displacement of air. Under fire conditions the cylinders or tank cars may violently rupture and rocket. If material on fire or involved in fira Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fira and not involved in fira Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution Evacuation if fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet If material leaking (not on fire), downwind evacuation must be considered BUTYL ACETATE 4909128 FLAMMABLE UQUID UN1123 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Butyl acetate is a clear, colorless liquid with a fruity odor. It has a flash point in the range of 72 deg. F. to 88 deg. F. It is lighter than water and very slightly soluble in water. Its vapors are heavier than air. It weighs 7.4 pounds per gallon. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in hooding quantities as fog Solid streams of water may spread fire 80 Cool an affected containers with flooding quantities of water Aopiy water from as far a distance as possible - Use alcohol' foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear ooots. protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Apply fluorocarbon-water foam to dimmish vapor and fire hazard Environmental considerations--water spill Use natural barriers or oil spill control booms io limit spill motion Use surface active agent ie.g. detergent, soaps, afconois) to com press and thicken spilled material Inject universal' gelling agent to solidify encircled spill ana increase effectiveness of booms If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove.trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors N-BUTYL ACIO PHOSPHATE 4933315 CORROSIVE MATERIAL, ACIDIC UN1718 N-butyl acid phosphate is a colorless liquid. It is insoluble in water. It is corrosive to metals and tissue. If materiel on fire or Involved in fire Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities Of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool ail affected containers with flooding quantities of water Apply water from as tar a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled matenal with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when lighting fires involv ing this material If contact with the material anticipated, wear full protective clothing April 1981 MCD 000009823 BUTYL ACRYLATE (COMBUSTIBLE LIQUID, N.O.S.) 4912215 COMBUSTTBILE LIQUID NA1993 Butyl acrylate is a clear colorless liquid. it is used to make paints and plastics. It has a flash point of 120 deg.f. It is lighter than water and insoluble in water, tts vapors are heavier than air. If material on fire or involved in fire Do not extinguish tire unless flow can be stopped Use water in flooding quantities as tog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apoty water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Invotved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation II fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet N-BUTYL ALCOHOL (BUTYL ALCOHOL) 4909117 FLAMMABLE LIQUID NA1120 N-butyl alcohol is a clear colorless liquid, it is used to make other chemicals. It has a flash point of 95 deg. F. It is lighter than water and slightly soluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless Mow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If materiel not on fire end not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water H material on fire or Involved In fire Do not extinguish fire unless flow can be stopoed Use water in flooding quantities as fog Solid streams of water may be ineffective Cool alt affected containers with flooding quantities of water Appty water from as far a distance as possible Use alcohol" foam, carbon dioxide or dry chemical If material not on fire end not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do nol handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water BUTYL BROMIDE (NORMAL) 4909127 FLAMMABLE LIQUID UN1126 Butyl bromide (normal) is a clear colorless liquid. It has a flash point of 65 deg. F. It is heavier than water and insoluble in water, its vapors are heavier than air. tt materiel on fire or Invotved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool aU affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If materiel not on fire and not involved in fire Keep sparks, (lames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain How as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material TERT-BUTYL ALCOHOL (BUTYL ALCOHOL) 4909130 FLAMMABLE LIQUID NA1120 Tert-butyl alcohol is a clear, cotortess liquid with a camphor lika odor. It has a flash point of 52 deg. F. and a melting point of 77 deg. F. It is lighter than water and soluble in water. Its vapors are heavier than air. BUTYL CHLORIDE 4906115 FLAMMABLE UOUtO UN1127 Butyl chloride is a dev colorless liquid, it has a flash point of 15 deg. F. It is lighter than water and insolubla in water. Its vapors are heavier than air. Continued on next page April 1981 & O.' 0.0,0,'0& 81 M material on fire or involved in fire Oo riot extinguish fire unless flow can be stooped Use water in flooding quantities as tog Solid streams of water may spread fire Cool all affected containers with flooding Quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Invotved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Suild dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on tire), downwind evacuation must be considered BUTYL ETHER FLAMMABLE LIQUID 4909125 UN1149 Butyl ether is a clear colorless with an ethereal odor, it has a flash point of 77 deg. F. It is lighter than water and insoluble m water. IL vapors are heavier than air. It material on fire or involved in fire Do not extinguish fire unless flow can be stooped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected cotamers with flooding Quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts of water or soap and water TERT-BUTYL CUMYL PEROXIOE. (TECHNICALLY 4919135 PURE OR) TERT-BUTYL CUMENE PEROXIDE. (TECHNICALLY PURE) ORGANIC PEROXIDE UN2091 Tert-butyl cumyl peroxide, (technically pure or) tert-butyi cumene per oxide, (technically pure) is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite: but once ignited, it will bum with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burning of combustible materials. Un der prolonged exposure to fire or heat containers of the material may explode. If material on fire or invotved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol' foam, carbon dioxide or dry chemical Dangerously explosive if materiel not on fire end not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv- ing this material if contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet 82 BUTYL FORMATE 4909128 FLAMMABLE LIQUID UN112B Butyl formate is a clear colorless liquid, ft has a Hash point of 77 deg. F. It is lighter than water and soluble in water. Its vapors are heavier than air. If material on fir* or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol ' foam, carbon dioxide or dry chemical H material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water TERT-BUTYL HYDROPEROXIDE. (MORE THAN 72% 4919136 BUT NOT MORE THAN 90% WITH WATER) ORGANIC PEROXIOE UN2094 Tert-butyl hydroperoxide, (more than 72% but not more than 90% with water) is a colorless to pale yellow liquid. It is used to manufacture paints, plasties, and rubber. It is soluble in water. The liquid or solution may require some effort to ignite: but once ignited, it will bum with increasing rapidity as the tire progresses. If spilled on combustible ma terials. spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burning of combustible materials. Under prolonged ex posure to fire or heat containers of the material may explode. April 1981 MCD 000009825 If material on fire or involved in fire Use waier in flooding quantities as fog Solid streams of water may De ineffective Cool an affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved In fire Keeo sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the matenai Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts ot water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material if contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of *2500 feet TERT-BUTYL HYDROPEROXIDE. (NOT MORE THAN 4919137 72% WITH WATER) ORGANIC PEROXIOE UN2093 Tert-butyi hydroperoxide, (not more than 72% with water) is a colorless to pale yellow liquid, it is used to manufacture paints, plastics, and rubber. It is soluble in water. The liquid or solution may require some effort to ignite: but once ignited, it will bum with increasing rapidity as the fire progresses, if spilled on combustible matenals. spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burn ing of combustible materials. Under prolonged exposure to fire or heat containers of the matenai may explode. It material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol" foam, carbon dioxide or dry chemical Dangerously explosive H material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep matenai out of water sources and sewers Keep spilled matenai wet Wet spilled matenai before picking rt up Personnel protection Avoid breathing dusts, and fumes from burning matenai Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material if contact with the matenai anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet April 1981 TERT-BUTYL HYDROPEROXIDE. (NOT MORE THAN 80% IN DI-TERT-BUTYL PEROXIOE AND 4919139 SOLVENT) ORGANIC PEROXIDE UN2092 Tert-butyi hydroperoxide. <not more than 80% in dt-tert-butyl peroxide and solvent) is a colorless to pale yellow liquid, it is used to manufacture paints, plastics, and rubber. It is soluble in water. The iiouid or solution may require some effort to ignite: but once ignited, it will burn with increasing rapidity as the fire progresses. If spilled on combustible ma tenals. spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burning of combustible materials. Under prolonged ex posure to fire or heat containers ot the material may explode. If material on fire or involved In fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive if material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep matenai out of water sources and sewers Keep spilled material wet Wet spilled matenai before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the matenai Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this matenai If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the matenai Is on fire or involved in fire evacuate for a radius of 2500 feet N-BUTYL ISOCYANATE 4907415 FLAMMABLE LIQUID. POISONOUS UN2485 N-butyt isocyanate is a clear colorless liquid. It has a flash point of 70 deg. F. In low concentrations its vapors are imtating to the eyes and mucous membranes, in higher concentrations it is toxic by inhalation. It is lighter than water and insoluble in water. It is very slowly decom posed by water. Its vapors are heavier than air. Toxic oxides of nitrogen are produced during combustion of this matenai. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and net Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers 8gild dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Continued on next page 83 Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear lull protective ctothing Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius ol 1500 feet If matenat leaking (not on fire), downwind evacuation must be considered TERT-BUTYL ISOPROPYL BENZENE 4919590 HYOROPEROXIOE ORGANIC PEROXIDE NA2091 Tertiary butyl isopropyl benzene hydroperoxide is a white crystalline solid, it must be shipped as a solution in a non-volatile solvent of not more than 60% concentration. At times this may appear as a slurry or sludge of white crystals. The solution may take some effort to ignite but once Ignited, it bums with increasing rapidity as the fire progresses. The dried matenat is more easily ignited. Contamination of the solution with many chemicals can cause a violent chemical reaction. The maienal supports the burning of combustible material. Under prolonged exposure to heat or fire containers of the material can explode. If material on fire or involved In fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use 'alcohol'' foam, carbon dioxide or dry chemical Oangerousty explosive ft material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have confected the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear tuft protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet BUTYL LACTATE (COMBUSTIBLE LIQUID, N.O.S.) 4913151 COMBUSTIBLE UQUIO NA1993 Butyl lactate is a clear colorless liquid with a mild odor. It is used as a solvent, and in the making of other chemicals. It has a flash point of ^ 66 deg. F. it is lighter than water and insoluble in water. Its vapors are heavier than air. 84 MOD 000009827 If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol ' foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keec sparks, flames, and other sources of ignition away Keep matenat out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water BUTYL MERCAPTAN 4909133 FLAMMABLE UQUIO UN2347 Butyl mercaptan is a clear, colorless liquid with a strong skunk-tike odor. It has a flash point in the range of *15 deg. F. to 35 deg. F. It is lighter than water and slightly soluble in water. Its vapors are heavier than air. H materiel on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool ali affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Usa water spray to disperse vapors and dilute standing pools of Hquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any malarial which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material TERT-BUTYL PEROXY-2-ETHYLHEXANOATE. (NOT 4919142 MORE THAN 30%) WITH 24-DHTERT- BUTYLPEROXY) BUTANE, (NOT MORE THAN 35% WITH NOT LESS THAN 38% PHLEGMAT1ZER) OftOAMC PEROXIOC UN28S6 Tert-butyt peroxy-2-ethythexmnoate. (not more than 30%) with 2.2-di- (tert-butyiperoxy) butane, (not more than 35% with not less than 35% phlegmattzer) is a whits solid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water, It is easily ignited and bums with increasing rapidity as the fire progresses. It can form explosive mixtures with finely divided combustible materials. It supports the burning of com bustible materials. Under prolonged exposure to fire or heat containers of the material may explode. The phiegmatizer is a material added to make the peroxide less readtive. April 1961 II material on tire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol' foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparxs. flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picning it uo Personnel protection Avoid breathing dusts, and fumes from burning material Avoid boaiiy contact with the material Wear boots, oroteccive gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soao and water Wear self-contained breathing apparatus when figntmg fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation if the material is on fire or involved m fire evacuate for a radius of 2500 leet TERT-BUTYL PEROXY-2-ETHYLHEXANOATE. {NOT 4919144 MORE THAN 50% WITH PHLEGMAT1ZER) ORGANIC PEROXIDE UN2B89 Tert-butyl peroxy-2-ethyihexanoate, (not more than 50% with phleg- matizer) is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite: but once ignited, it will bum with increasing rapidity as the tire progresses. If spilled on combustible ma- lenais. spontaneous ignition at the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burning of combustible materials. Under prolonged ex posure to fire or heat containers of the material may explode. The phleg- matizer is a material added to make the peroxide less reacilive. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out ol water sources and sewers Keep spilled matenal wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the matenat Wear boots, protective gloves, and goggies Do not handle broken packages without protective equipment Wash away any material which may have contacted (he body with copious amounts of wafer or soap and water Wear self-contained breathing apparatus when fighting fires involv ing (his material If contact with the matenal anticipated, wear full protective clothing Approach fire with caution Evacuation if the matenal is on tire or involved In fire evacuate for a radius of 2500 feet TERT-BUTYL PEROXY-2-ETHYLHEXANOATE, {TECHNICALLY PURE) 4919141 ORGANIC PEROXIDE UN2143 Ten-butyl peroxy-2-ethylhexanoate. (technically pure) is a clear col orless liquid, it is used to manufacture paints, olastics. and rubber. It is insoluble m water. The liquid or solution may require some effort to ignite: but once ignited, it will burn with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burning of com bustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If materiai on fire or involved in fire Use water m flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with Hooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Oangerousiy- explosive If materiai not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers Keep spilled material wet Wet spilled matenal before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the matenal Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the matenal is on fire or involved in tire evacuate for a radius of 2500 feet TERT-BUTYL PEROXY-2-ETHYLHEXANOATE* NOT 4919143 MORE 12%) WITH 2,2-OKTERT* BUTYLPEROXY)BUTANE. (NOT MORE THAN 14% WITH NOT LESS THAN 14% PHLEGMATIZER ANO 60% INERT INORGANIC SOLID) ORGANIC PEROXIDE UN2867 Tert-butyf peroxy-2-ethylhexanoate. not more 12%) with 2.2-di-(terl- butylperoxy)butane. (not more than 14% with not less than 14% phleg- matizer and 60% inert inorganic solid) is a white solid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite: but once ignited, it wiU bum with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the matenal may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burning of combustible materials. Un der prolonged exposure to fire or heat containers of the matenal may explode. The phlegmatizer is a material added to make the peroxide less reacitive. Continued on next page April 1981 000009828 MCD 85 H material on fire or Involved In fir* Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol'' foam, carbon dioxide or dry chemical Dangerously explosive tf material not on fire and not Involved in fire Keep sparks. flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled matenai wet Wet spilled matenai before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material if contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation tf the matenai is on fire or involved in tire evacuate for a radius of 2500 feet 3-TERT-BUTYL PEROXV-3-PHENYLPHTHALIDE. 4919146 (TECHNICALLY PURE) ORGANIC PEROXIOE UN2S96 3-tert-butyl peroxy-3-phenylphthalide. (technically pure) is a white solid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. It is easily ignited and bums with increasing rapidity as the fire progresses. ft can form explosive mixtures with finely divided combus tible materials. It supports the burning of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. if material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep matenai out of water sources end sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, end fumes from burning materiel Avoid bodily contact with the material Wear boots, protective gloves, end goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach tire with caution Evacuation If the material is on tire or involved in fire evacuate for a radius of 2500 feet TERT-BUTYL PEROXY-3.5.5-TRIMETHYLH6XANOATE 4919145 (OR) TERT-8UTYL P6ROXYISONONANOATE. _ (TECHNICALLY PURE) ORGANIC PEROXIOE UN21C Ten-butyl peroxy-3.5.5-tnmethylhexanoate ion ten-butyl peroxyiso nonanoate. (technically pure) is a colorless to pale yellow liquid, it is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite: but once ignited, it will bum with increasing rapidity as the fire orogresses. If soilled on combustible materials, spontaneous ignition of the material may occur Contamination with many chemical substances can cause a violent chemical reaction. It supoorts the burning of combustible materials. Un der prolonged exposure to fire or heat containers of the material may explode. The phlegmatizer is a matenai added to make the peroxide less reacitive. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the matenai Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet TERT-BUTYL PEROXYACETATE, (NOT MORE THAN 4919147 52% IN SOLUTION) ORGANIC PEROXIDE UN2096 Tert-butyt peroxyacetate, (not more than 52% in solution) is a colorless to pale yellow liquid, ft is used to manufacture paints, plastics, and rubber, it is insoluble in water. The liquid or solution may require some effort to ignite: but once ignited, it will bum with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the materiel may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burn ing of combustible materials. Under prolonged exposure to tire or heat containers of the materiel may explode. If material on fir* or Involved In fire Use water in flooding quantities as log Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water horn as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep materiel out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up 66 April 1981 MCD 000009829 Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear coots, protective gloves, and goggles Do not hanole broken packages without protective equipment Wash away any material which may nave contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing thus material if contact with the material anticipated, wear full protective clothing Approach lire with caution Evacuation if the material is on tire or involved m fire evacuate tor a radius of 2500 feet TERT-BUTYL PEROXYACETATE. (NOT MORE THAN 4919148 76% IN SOLUTION) ORGANIC PEROXIDE UN2095 Tert-butyl peroxyacetate. (not more than 76% in solution) is a colorless (o pale yellow liquid. It is used to manufacture paints, plastics, and rubber, it is insoluble in water. The liquid or solution may require some effort to ignite: but once ignited, it wifi burn with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the matenat may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burn ing of combustible materials. Under prolonged exposure to fire or heat containers of the matenat may explode, if material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparKs, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting tires involv ing this matenai If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet TERT-BUTYL PEROXYBEMZOATE (NOT MORE THAN 4919149 50% WITH INERT INORGANIC SOUD) ORGANIC PEROXIDE UN2990 Tert-butyl peroxybenzoate (not more than 50% with inert inorganic solid) is a white solid, ft is used to manufacture paints, plastics, and rubber, it is insoluble in water, it is easily ignited and bums with increas ing rapidity as the fire progresses. It can form explosive mixtures with finely divided combustible materials. H supports the burning of combus tible materials. Under prolonged exposure to fire or heat containers of the material may explode. April 1981 if material on fire or involved In fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Oangerousiy explosive If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources ana sewers Keep spilled matenai wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the matenai Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet TERT-BUTYL PEROXYBENZOATE. (NOT MORE THAN 4919150 75% IN SOLUTION) ORGANIC PEROXIDE UN2098 Tert-butyl peroxybenzoate. (not more than 75% in solution) is a col orless to pale yellow liquid- It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite: but once ignited, it will bum with increasing rapidity as the fire progresses, if spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burn ing of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on Are or involved in Are Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on Are and not Involved in Are Keep sparks, flames, and other sources of ignition away Keep matenai out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning malarial Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash sway any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this materia) If contact with ths materiel anticipated, wear full protective clothing Approach Are with caution Evacuation if the material is on fire or involved in fire evacuate for a radius of 2500 feet 87 MCD 000009830 TERT-BUTYL PEROXYBENZOATE. (TECHNICALLY 4919151 PURE OR) TERT-BUTYL PEROXYBENZOATE, (MORE THAN 75% IN SOLUTION) ORGANIC PEROXIDE UN2097 Tert-butyl peroxybenzoate. (technically pure or) tert-butyl peroxyben zoate. [more than 75% in solution) is a colorless to paie yellow iiquiO it is used to manufacture paints, plastics, and ruboer. It is insoluble m water. The liauid or solution may require some effort to ignite: but once ignited, it will burn with increasing rapidity as the tire progresses If spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burning of combustible ma terials. Under prolonged exposure to fire or neat containers of the ma terial may explode. If material on fire or involved in fire Use water in Hooding quantities as log Solid streams oi water may be ineffective Cool all affected containers with Hooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this matenal If contact with the material anticipated, wear full protective clothing Approach tire with caution Evacuation If the material i9 on fire or involved in tire evacuate for a radius of 2500 feet TERT-BUTYL PEROXYCROTONATE. (NOT MORE 76% 4919152 IN SOLUTION) ORGANIC PEROXIDE UN2183 Tert-butyl peroxycrotonate. (not more 76% in solution) is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite: but once ignited, it will bum with increasing rapidity as the fire progresses. If spiffed on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction, ft supports the burn ing of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or involved In fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material 68 Wear boots, protective gloves, and goggles Do not nanaie broken packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires mvo ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material Is on fire or involved m fire evacuate for a radius of 2500 feet N-BUTYL PEROXYDICARBONATE. (NOT MORE THAN 4919153 27% IN SOLUTION) ORGANIC PEROXIDE UN2170 N-butyl peroxydicarbonate. (not more than 27% in solution) is a col orless to pale yellow liquid. It is used lo manufacture oaints. plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite: but once ignited, it will burn with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It suooons the burn ing of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Coot all affected containers with Hooding quantities of water Apply water from as far a distance as possible Use alcohol" foam, carbon dioxide or dry chemical Dangerously explosive if materiel not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep materia) out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning matenal Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet TERT-BUTYL PEROXYOfETHYLACETATE, 4919156 (TECHNICALLY PURE) ORGANIC PEROXIDE UN2144 Tert-butyl peroxydiathytacetata. (technically pure) is a colorless to pale yellow liquid, it is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite; but once ignited, it wiH bum with increasing rapidity as the fire progresses. It spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can causa a violent chemical reaction. It supports the burning of com bustible materials. Under prolonged exposure to fire or heat containers of the material may explode. April 1961 MCD 000009831 Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the matenat Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material K contact with the matenai anticipated, wear full protective clothing Approach fire with caution Evacuation if the material is on fire or involved in fire evacuate for a radius of 2500 feet TERT-BUTYL PEROXY1SOPROPYL CARBONATE. 4919159 (TECHNICALLY PURE) ORGANIC PEROXIOE UN2103 Tert-butyl peroxyisopropyl carbonate, (technically pure) is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liguid or solution may require some effort to ignite: but once ignited, it will bum with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical suDstances can cause a violent chemical reaction. It supports the burn ing of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or Involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol foam, carbon dioxide or dry chemical Dangerously explosive if material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep matenai out of water sources and sewers Keep spilled matenai wet Wet spilled matenai before picking it up Personnel protection Avoid breathing dusts, and fumes from burning matenai Avoid bodily contact with the matenai Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenai which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this matenai If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet TERT-BUTYL PEROXYMALEATE, (NOT MORE THAN 4919161 55% AS A PASTE) ORGANIC PEROXIDE UN2101 Tert-butyl peroxymaleate. (not more than 55% as a paste) is a white solid. It is used to manufacture paints.p(astics. and rubber. H is insoluble m water. It is easily ignited and bums with increasing rapidity as the fire progresses. It can form explosive mixtures with finely divided combus tible materials. It supports the burning of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. iO 000009633 MOD If material on fire or involved in fire Use water in flooding quantities as log Solid streams of water may be ineffective Coot all affected containers with flooding quantities af water Apply water from as far a distance as possible Use 'alcohol" foam, carbon dioxide or dry chemical Dangerousiys36explosive If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet SDilied material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the matenai Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting tires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the matenai is on fire or involved in fire evacuate for a radius of 2500 feet TERT-BUTYL PEROXYMALEATE. (NOT MORE THAN 4919160 55% IN SOLUTION) ORGANIC PEROXIDE UN2100 Tert-butyl peroxymaleate. (not more than 55% in solution! is a col orless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite: but once ignited, it will bum with increasing rapidity as the fire progresses, h spiffed on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burn ing of combustible matenais. Under prolonged exposure to fire or heat containers of the material may explode. If material on Are or involved in fire Use water in flooding quantities as tog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning matenai Avoid bodity contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the materiel is on tire or involved in fire evacuate for a radius of 2500 feet April 1981 If material on flra or involved In fire Use water in flooding quantities as fog Solid sireams of water may be ineffective Cool all affected containers with flooding quantities of water Aoply water from as far a distance as possible Use alcohol ' foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled matenal wet Wet spilled matenal before picking it up Personnel protection Avoid breathing dusts, and fumes from burning matenal Avoid bodily contact with the matenal Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet TERT-BUTYL PEROXYDIETHYLACETATE. (33% WITH) 4919155 TERT-BUTYL PEROXYBENZOATE. (33%. AND SOLVENT) ORGANIC PEROXIDE UN25S1 Tert-butyl peroxydiethylacetate. (33% with) tert-buty! peroxybenzoate. (33%. and solvent) is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite: but once ignited, it will bum with increasing rapidity as the lire progresses. If spilled on combustible materials, spontaneous ignition of the matenal may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burning of combustible materials. Un der prolonged exposure to fire or heat containers of the material may explode. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If materiel not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any malarial which may hava contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus whan fighting fires involv ing (his material if contact with the material anticipated, wear fun protective clothing Approach fire with caution Evacuation If the matenal is on fire or involved in fire evacuate for a radius of 2500 feet April 1951 TERT-BUTYL PEROXYISOBUTYRATE. (MORE THAN 52% Bl/T NOT MORE THAN 77% IN SOLUTION) 4919157 ORGANIC PEROXIDE UN2142 Tert-butyl peroxyisobutyrate. (more than 52% but not more than 77% in solution) is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite: but once ignited, it will bum with increasing rapidity as the fire progresses. If spilled on combustible ma- tenals. spontaneous ignition of the matenal may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burning of combustible materials. Under prolonged ex posure to fire or heat containers of the material may exolode. if material on fire or Involved In fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet TERT-BUTYL PEROXYISOBUTYRATE, (NOT MORE 4919158 THAN 52% IN SOLUTION) ORGANIC PEROXIDE UN2562 Tert-butyl peroxyisobutyrate. (not more than 52% in solution) is a colorless to pale yellow liquid. H is used to manufacture paints, plastics, ind rubber. It is insoluble in water. The liquid or solution may require some effort to ignite: but once ignited, it will bum with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burn ing of combustible materials. Under prolonged exposure to lire or heat containers ot the material may explode. If material on fire or Involved in flra Use water in Hooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carton dioxide or dry chemical Dangerously explosive If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Continued on next page 632 Ci09 00 69 TERT-BUTYL PEROXYMALEATE. (TECHNICALLY 4919162 PURE) ORGANIC PEROXIOE UN2099 Tert-butyl peroxymaieate. (technically pure) is a white solid. It is used to manufacture paints, plastics, and rubber It is insoluble m water. It is easily ignited and burns with increasing rapidity as the fire progresses, it can form explosive mixtures with finely divided combustible materials, it supports me burning of combustible materials. Under prolonged ex posure to fire or heat containers of the matenal may explode. If material on fir* or involved in fire Use water m flooding quantities as fog Solid streams of water may be ineffective Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning matenal Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soao and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation if the material is on fire or involved >n fire evacuate for a radius of 2500 feel TERT-BUTYL PEROXYNEODECANOATE. (NOT MORE 4919163 THAN 77% IN SOLUTION) ORGANIC PEROXIDE UN2177 Tert-butyl peroxyneodecanoate. (not more than 77% in solution) is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. II is insoluble in water. The liquid or solution may require some effort to ignite: but once ignited, it wilt bum with increasing rapidity as the tire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can causa a violent chemical reaction, ft supports the burn ing of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or Involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantifies of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If materiel not on fire end not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled matenal before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment April 1981 Wash away any matenal which may nave contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this matenal If contact with the matenal anticipated, wear full protective clothing Aooroach fire with caution Evacuation if the material is on fire or involved in fire evacuate tor a radius of 2500 feet TERT-BUTYL PEROXYNEODECANOATE. 4919164 (TECHNICALLY PURE) ORGANIC PEROXIDE UN2594 Tert-butyl peroxyneodecanoate. (technically pure) is a colorless to pale yellow liquid. It is used lo manufacture paints, plastics, and rubber It is insoluble m water. The liquid or solution may require some effort to ignite: but once ignited, it will bum with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burning of com bustible matenais. Under prolonged exposure to fire or heat containers of the material may explode. if materiel on fire or involved In fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire end not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled matenal wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the matenal Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the matenal anticipated, wear full protective clothing Approach fire with caution Evacuation If the matenal is on fire or involved in fire evacuate for a radius of 2500 feet TERT-BUTYL PEROXYPHTHALATE, (TECHNICALLY 4919165 PURE) ORGANIC PEROXIOE UN2105 Tert-butyl peroxyphthaiate. (technically pure) is a white solid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. It is easily ignited and bums with increasing rapidity as the fire progresses. It can form explosive mixtures with finely divided combustible matenais. It supports the burning of combustible materials. Under prolonged ex posure to fire or heat containers of the material may explode. Continued on next page 91 OOOOO^4 tf material on Are or Involvad In fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not Involved in fire Keep sparks. flames, and other sources of ignition away Keep material out o( water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with (he material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts ol water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material It contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation II the material is on fire or involved in fire evacuate for a radius of 2500 feel BUTYL PHENOL (CORROSIVE SOLID, N.O.S.) CORROSIVE MATERIAL, 8ASIC 4935629 UNI 759 .Butyl phenol is a white crystalline solid, it is used to make other chemicals. It is insoluble in water. It may bum (hough u may require some effon to ignite. It is corrosive to metais and tissue. If material on Are or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool alf affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keeo material out ol water sources and sewers dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the materia) Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts ol water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing TERT-BUTYL PEROXYPIVALATE. (NOT MORE THAN 4919166 77% IN SOLUTION) ORGANIC PEROXIDE UN2110 Tert-butyl peroxypivaiate. (not more than 77% in solution) is a col orless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber, it is insoluble in water. The liquid or solution may require some effort to ignite: but once ignited, it will bum with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. K supports the burn ing of combustible materials. Under prolonged exposure to fire or heat containers of (he material may explode. If material on fire or Involved In fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on Are and not Involved in Are Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear lull protective clothing Approach fire with caution Evacuation if the material is on fire or involved in fire evacuate for a radius of 2500 feet 92 CD 000009836 BUTYL PHOSPHORIC ACIO (SEE ACID BUTYL PHOSPHATE 4933318) N-SUTYL PHTHLATE 4962110 OftM-E NA9095 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-IOO/46.4) SUBSTANCE (RO-IOO/45.4) N-butyf phthalate Is a colorless oily liquid. A is used in paints and plastics and as a reaction media tor chemical reactions. It is insoluble in water. It is combustible though It may take some effort to ignite. If material on Are or Involved In Are Do not extinguish Are unless Aow can be stopped Use water in flooding quantities as tog Cool aH affected containers with flooding quantities of water Apply water from as far a distance es possible Solid streams of water may be ineffective Use "alcohol" foam, carbon dioxide or dry chemical If material not on Are and not involved in Are Keep sparks, flames, and other sources of ignition away Keep materia) out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors or dusts Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental conekterettona land spill Dig a pit pond, lagoon, holding area to contain liquid or solid matenai Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder April 1981 Environmental consideration*--water spill Use natural Darners or oil soill control booms to limit spilt motion Use surface active agent fe.g. detergent, soaps, alcohols) to com press and thicken spilled matenai inject universal'' gelling agent to solidify encircled spill and increase effectiveness of booms Remove trapped matenai with suction hoses if dissolved, aooiy activated carbon at ten times the spilled amount m region of tOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors BUTYL TRJCHLOROSILANE 4934215 CORROSIVE MATERIAL, ACIDIC. COMBUSTIBLE UN1747 Butyl tnchiorosilane is a colorless liquid with a pungent odor, it is used to make vanous silicon containing compounds. It is combustible and has a flash point of 126 deg. F. It is readily decomposed by moisture or water to hydrochloric acid with evolution of heat. II is corrosive to metals and tissue. If material on fira or involved in fire Use dry chemical, carbon dioxide, or dry sand Do not use water on matenai itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as tar a distance as possible If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on matenai itself Neutralize spilled matenai with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the matenai Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing N-BUTYL-4.4-DKTERT-BUTYLPEROXY)VALERATE, 4919133 (NOT MORE THAN 52% WITH INERT SOLID) ORGANIC PEROXIOE UN2141 N-butyl-4.4-di-(tert-butylperoxy)valerate. (not more than 52% with inert solid) is a white solid. It is used to manufacture paints, plastics, and rubber. II is insoluble in water. H is easily ignited and bums with increas ing rapidity as the fire progresses. It can form explosive mixtures with finely divided combustible materials. It supports the burning of combus tible materials. Under prolonged exposure to fire or heat containers of the material may explode. April 1961 If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Coot all affected containers with flooding quantities of water Apply water from as tar a distance as possible Use 'alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep matenai out of water sources ana sewers Keep spilled material wet Wet spilled matenai before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenai which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this matenai If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the matenai is on fire or involved in fire evacuate tor a radius of 2500 feet _ N BUTYL-4,4OKTERT.BUTYLPER0XY)VALERATE, 4919134 (TECHNICALLY PURE) ORGANIC PEROXIDE UN2140 N-butyl-4.4-dHtert-butyiperoxy)valerate. (technically pure) is a col orless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite: but once ignited, it will burr with increasing rapidity as the fire progresses, if spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burn ing of combustible matenais. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or involved In fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive ff material not on fire and not involved in fire Keep sparks, (lames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled matenai wet Wet spilled material before picking it up Personnet protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts ol water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet 93 MCD 000009836 BUTYLAMINE FLAMMABLE LIQUID 4909120 UN1125 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-IOOO/454) Butylamine is a clear colorless liquid with an ammonia-tike odor. It has a flash point of 10 deg. F. It is lighter than water and soluble m water. Its vapors are heavier than air. Toxic oxides of nitrogen are produced during combustion of this material. It weighs 6.2 pounds per gallon. If material on firs or involved in fire Oo not extinguish fire unless flow can be stopped Use water in flooding Quantities as fog Solid streams of water may be ineffective Cool ali affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Oo not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Evacuation if fire becomes uncontrollable or container is 'exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash. cement powder, sawdust, or com mercial sorbents Apply fluorocarbon-water foam to diminish vapor and fire hazard Neutralize with sodium bisulfate (nahso4) Environmental considerations--water spill Add sodium bisulfate If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environments! considerations sir spM Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic end should be diked for containment TERT-8UTYLAMINE (BUTYLAMINE) 4909134 FLAMMABLE LIQUID UN1125 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/4S4) Tert-butylamine is a dear, colorless liquid with an ammonia like odor. It has s flash point of 70 deg. f. ft is lighter than water and soluble in water. Its vapors are heavier than air. Toxic oxides of nitrogen are produced during combustion of this mattfial. It weighs 6.2 pounds per gallon. 94 MCD 000009837 if material on fire or Involved In fire Do not extinguish fire unless flow can be stopped - Use water in flooding quantities as fog Solid streams of water may be ineffective Cool ail affected containers with flooding quantities of water Appty water from as far a distance as possible Use alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain tlow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash. cement powder, sawdust, or com mercial sorbents Apply fluorocarbon-water foam to diminish vapor and fire hazard Neutralize with sodium bisulfate (nahso4) Environmental considerations--water spill Add sodium bisulfate If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses pollutants and precipitates Environmental considerationa--air spill Apply water spray or mist to knock down vapors BUTYLENE, IMPURE, FOR FURTHER REFINING 4905711. (LIQUEFIED PETROLEUM GAS) FLAMMABLE GAS UN107S Butylene is a colorless gas with a faint petroleum like odor. It is shipped aa a liquefied gea under its vapor pressure. Contact with the liquid can cause frostbite. It ia easily ignited. Its vapor is heavier than air and a flame can flash back to the source of leek very easily. The teak can either be a liquid or vapor leak. It can asphyxiate by the displacement of air. Under fire conditions the cylinder or tank car may violently rupture and rocket. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool att affected containers with flooding quantities of water Apply water from as far a distance as possible H material not on Era and not Involved in Era Keep sparks, flames, and other sources of ignition away Keep materiel out of water sources and sewers Attempt to stop leek if without hazard Us# water spray to knock-down vapors April 1981 Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Oo not hanole broken packages without protective equipment Aoproach fire with caution Evecuetton if fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet If material leaking (not on tire}, downwind evacuation must be considered BUTYRALDEHYDE 4908119 FLAMMABLE LIQUID UN1129 Butyraldehyde is a clear liquid with a pungent odor. It has a flash point of 10 deg. F It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved in fire Oo not extmguisn fire unless flow can be stopped Use water in flooding quantities as fog Solid streams ot water may spread fire Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" loam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks. Names, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If lire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 fast If material leaking (not on firs), downwind evacuation must be considered BUTYRIC ACID 4931414 CORROSIVE MATERIAL* ACIDIC. COMBUSTIBLE UN2820 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-500Q/2270) Butyric acid is a colorless liquid with an odor of rancid butter, it is combustible and has a flash point of 161 deg. F. It is soluble in water, it is corrosive to metals and tisaue. It weighs 8.0 pounds per gallon. If material on Are or Involved In Are Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Use water spray to absorb vapors April 1981 9038 0000 O If materiel not on Are and not Involved In lira Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-oown vapors Neutralize soiiled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerationa--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface (low using soil, sand bags, loameti polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental conelderatfone--water spill Neutralize with agncultural lime (slaked lime), crushed limestone, or sodium bicarbonate If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment BUTYRONITRILE (FLAMMABLE LIQUID, N.O.S.) 4909241 FLAMMABLE UQUIO UNI 993 Butyronitrile is a dear colorless liquid. It is used in the manufacture of other chemicals. It has a flash point of 76 deg. F. it is lighter than water and slightly soluble in water. Its vapors are heavier man air. Toxic oxides of nitrogen are produced during combustion of this material. It material on Are or Involved In Are Do not extinguish fire unless flow can be stopped Use water in flooding quantities as tog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from aa far a distance as possible Use `alcohol'' foam, carbon dioxide or dry chemical If material not on Are and not Involved In Are Keep sperks. flames, and other sources of ignition away Keep mattriai out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of Hquid Personnel protection Avoid breathing vapor* Keep upwind Wear self-contained breathing apparatus Avoid botfly contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap end water A contact with the material anticipated, wear fuH protective clothing 95 CAOMIUM ACETATE 4962303 ORM-E NA2570 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100/45.4) Cadmium acetate is a colorless crystallite solid. It is used in ceramics and in chemical analysis. It is soluble in water it is non-combustible. If material Involved in fire Extinguish fire using agent suitable tor type ot surrounding tire (Material itself does not burn or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build diKes to contain (low as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in ram or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Add ferric chionde (fect3) Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates CAOMIUM BROMIDE 4962305 ORM-E NA2570 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100/45.4) Cadmium bromide is a white to yellow crystalline solid. (I is used in photography, pnnting. and lithogrphy. It is soluble in water. It is non- combustible. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) If material not involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental conalderatlona--lend epHI Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in ram or fire fighting water Environmental consideration#--water apM Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Add ferric chloride (fed3) Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates CADMIUM CHLORIDE 4962S09 ORM-E NA2570 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RG-HXV45.4) Cadmium chloride is a white crystalline solid. Cadmium chloride is used in photography, in fabric printing, in chemical analysis, and in many other uses. It is soluble in water. It is non-combustible. 96 MCD 000009839 If materiel involved in fire Extinguish fire using agent suitable for type of surrounding fire (Matenal itself does not bum or burns with difficulty.) If material not involved In fire Keep matenal out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any materia) which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Covet solids with a plastic sheet to prevent dissolving in ram or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Add feme chloride (fec!3) Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates CALCIUM ARSENATE AND SULPHUR. DRY (CALCIUM 492321B ARSENATE) POISON B UNI 573 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Calcium or lead, arsenate and sulfur, dry is a yellow white to yeilow powder. It is insoluble in water. It is toxic by inhalation (dust) and by ingestion. (t material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If materiel not involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken package# without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting tires involv ing this matenal If contact with the material anticipated, wear full protective clothing Environmental conalderatlona--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental consideration!" water spill Neutralize with agricultural lima (slaked lime), crushed limestone. or sodium bicarbonate Add ferric chloride (fect3) Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates CALCIUM ARSENATE, SOLID 4923217 POISON B UNI 573 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-IOOO/454) Calcium arsenate solid is a white powder, ft is very slightly soluble in water. It is toxic by inhalation (dust) and by ingestion. April 1961 tr material involved in tire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Use water m flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not Involved in fire Keeo material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this matenai If contact with the matenai anticipated, wear full protective clothing Environmental considerations--land spilt Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in ram or tire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicaroonate Add feme ehtonde <fecl3) Adiust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates CALCIUM BISULFITE SOLUTION (See CALCIUM HYDROGEN SULFITE SOLUTION 4932331) CALCIUM CARBIDE 4916408 FLAMMABLE SOLID UN1402 WATER REACTIVE ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Calcium carbide exists as a greyish-black irregular lumo solid. It is used to make acetylene and in steel manufacture. It reacts with water to form calcium hydroxide and acetylene, a flammable gas. The heat from this reaction may be sufficient to ignite the acetylene. If material on fire or involved in fire Do not use water Use graphite, soda ash. powdered sodium chloride, or suitable dry powder Carbon dioxide may be ineffective If material not on fire and not involved in fire Do not use water Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep matenai dry Personnel protection Avoid breathing dusts, and fumes from burning malarial Wear bools, protectiva glovsa, and goggles Do not handle broken packages without protective equipment Wash away any matenai which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spHI Dig a pit. pond, lagoon, holding area to contain liquid or solid matenai Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate April 1981 CALCIUM CHLORATE 4918713 OXIDIZER UN1452 Calcium chlorate is a white crystalline solid, it is used in photography, m pyrotechnics, and as a herbicide. It is soluble in water. It forms a very flammaDie mixture with combustible materials and thts mixture may be explosive if the combustible material is finely divided. The mixture can be ignited by friction. Contact with strong suifunc acid can cause fires or explosions. When mixed with ammonium salts, spontaneous decom position and ignition may result. Prolonged exposure of the material to fire or heat can result in an explosion. If material on firs or Involved In firs Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If meterial not on fire and not involved in fire Keep sparks, tiames. and other sources of ignition away Keep matenai out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet CALCIUM CHLORITE 4918714 OXIDIZER UN1453 Calcium chlorite is a white granular solid. It is decomposed by water to calcium hydroxide and chlonne dioxide, a nonflammable oxidizing gas. The material itself is non-combustible, but it will accelerate the burning of combustible materials. If the combustible material is finely divided, the mixture may be explosive. Prolonged exposure of the ma terial to fire or heat may result in an explosion and the rupturing of the containers. If material on firs or involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire end not Involved in fire Keep sparks, tiames. and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid -breathing dusts Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation H firs becomes uncontrollable--evacuate for a radius of 2500 leet CALCIUM CHROMATE 4963307 ORM-E NA9096 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-1000/454) Calcium chromate is a yeHow powder. It is slightly soluble in water. It i mhibtor. and for other uses. It is sKghtly soluble in water. It is non- combustibie. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material Itself does not bum or bums with difficulty.) Continued on next pepe 97 0'. 0. *0 If material not Invoivad in fir* Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear Coots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a p't. pond, lagoon, holding area to contain licjuid or solid material Cover solids with a plastic sheet to prevent disspiving in ram or fire fighting water Environmental consideration*--water spill Add sodium bisulfite Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates CALCIUM CYANIDE. SOLIO (OR) CALCIUM CYANIDE 4923223 MIXTURE. SOLID POISON 8 UNI 575 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-10'4.54) Calcium cyanide, solid is a white crystalline powder or crystalline solid. It is slowly decomposed by water to give off hydrogen cyanide, a flam mable poison gas. Contact with acids will cause rapid evolution of hy drogen cyanide. It is toxic Oy skin absorption through ooen wounds, by mgestion. and by inhalation of hydrogen cyanide from the decomposition of the material. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use foam, carbon dioxide or dry chemical Do not use water on material itself If large quantities of combustibles are involved, use water in ffooding quantities as spray and fog Use water spray to absorb vapors If material not Involved in fire Keep sparks, flames, and other sources of ignition away Keeo material out of water sources and sewers Use water spray to knock-down vapors Do not use water on material itself Personnel protection Avoid breathing vapors or dusts Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water if contact with the matenai anticipated, wear full protective clothing Environmental consideration* lend spill Dig a pH. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in ram or fire fighting water Environmental coneideratlone water spill Add caustic soda Add calcium hypochlorite Adjust ph to neutral (ph-7) CALCIUM DOOSCYLBENZENESULFONATE 4963309 ORM-E NA9097 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Calcium dodecylbenzenesutfonate is a white to light yellow granular solid. It is used as a detergent. It is soluble in water. It is non-combustible. 98 If materiel Involved In fire Extinguish tire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) IT material not involved in fire Keep matenai out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear poots. protective gloves, ana goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with "copious amounts of water or soap ana water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in ram or fire fighting water Environmental consideration*--water spill If dissofved. apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates CALCIUM HYOROGEN SULFITE SOLUTION (CALCIUM 4932331 BISULPHITE) CORROSIVE MATERIAL. ACIDIC NA2693 Calcium hydrogen sulfite solution is actually the solution of calcium sulfite and sulfur dioxide in water. It is a colorless to yellow liquid with an odor of sulfur dioxide. It is corrosive to metals If material involved in fir* Extinguish fire using agent suitable for type of surrounding fire (Matenai itself does not bum or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If materiel not involved in fire Keep matenai out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the matenai Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the matenai anticipated, wear full protective clothing CALCIUM HYPOCHLORITE MIXTURE (DRY. 4919715 CONTAINING MORE THAN 39 PERCENT AVAILABLE CHLORINE) OXIDIZER UN1749 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100/45.4) Calcium hypochlorite mixture is a whits granular solid or tablets com pressed from the granules with an odor of chlorine, it is used in water purifica purification, as a swimming pool disinfectant, as a bleaching compound, and for many other uses. It is noncombustible but it will accelerate the burning of combustible materials. It is decomposed by water with evolution of chlorine gas and heat. Prolonged exposure to fire or heat may result in the vigorous decomposition of the material and the rupture of its container. Material containing less than 39 percent available chlorine will undergo reactions as described above though it may taka longer to initiate and the resulting reactions may not be as vigorous. April 1981 MCD 000009841 If material on fir* or involved in tiro Flood with water Cool all affected containers with flooding quantities of water Aooiy water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keeo material out of water sources and sewers Personnel protection Avoid breathing ousts Avoid bodily contact with the material Wear boots, protective gloves, and goggles Oo not handle broken oackages without protective equipment Wash away any material which may nave contacted the body with copious amounts ol water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach tire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 5000 feet Environmental considerations--land spill Oig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Add sodium bisulfite Add soda ash Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates CALCIUM HYPOCHLORITE, HYDRATED (MINIMUM 491879$ 5.5% BUT NOT MORE THAN 10% WATER. AND CONTAINING MORE THAN 39% AVAILABLE CHLORINE) OXIDIZER UN2880 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-100/45.4) Calcium hypochlorite, hydrated is a white granular solid or tablets compressed from the granules having an odor of chlorine. It is used for water purification, disinfectant for swimming pools, for bleaching paper and textiles, and for many other uses, it is non-combustible, but it will accelerate the burning of combustible materials. It is decomposed by water with evolution of chlorine gas and heat. Prolonged exposure to fire or heat may result in the vigorous decomposition of the material and rupture of the container. Material containing less than 39% available chionne will undergo reactions as described above though it amy take longed to initiate, and the resulting reactions may not be aa vigorous. If material on fire or involved In fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and net invotvsd in Are Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material if contact with the material anticipated, wear full protective clothing Approach fire with caution April 1981 Evacuation If fire becomes uncontrollable or container is exDosed to direct flame--evacuate for a radius of 5000 feet Environmental conaideratlone--land spill Dig a pit. oond. lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in ram or fire fighting water Environmental considerations--water spill Add sodium bisulfite Add soda ash Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates CALCIUM METAL 4916401 FLAMMABLE SOLID UN1401 WATER REACTIVE Calcium metal is a silvery, soft metal that oxidizes to greyish white on exposure to air. it is used in metallurgy. It is decomposed by water to form calcium hydroxide and hydrogen, a flammable gas The heat of this reaction may be sufficient to ignite the hydrogen and possibly the calcium itseif. If material on fire or involved in fire Do not use water Do not use carbon dioxide Use graphite, soda ash. powdered sodium chloride, or suitable dry powder tf material not on fire and not Involved in fire Do not use water Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Avoid breathing fumes from burning material CALCIUM NITRATE 4918715 OXIDIZER UN14S4 Calcium nitrate is a white to light grey granular solid, it is used in fertilizers, explosives and pyrotechnics. It is soluble in water. It is non combustible but it will accelerate the burning of combustible materials. H large quantities are involved in the fire or the combustible material is finely divided an explosion may result. Prolonged exposure of the ma terial to fire or heat may result in an explosion. Toxic oxides of nitrogen are produced in fires involving this material. If material on Are or Involved In Are Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible H malarial not on Are end not Involved in Are Keep sparks, flames, and other sources of ignition away Keep materiel out of water sources and sewers hereonnet protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet WCD 000o09a42 99 CALCIUM PERMANGANATE 4918718 OXIDIZER UN1456 Calcium permanganate is a purplish colored crystalline soiid. it is used as a disinfectant and deodonzer. in water punfication. and for many other uses. It is soludie in water. The matenal itself is noncompusiible but it will accelerate the burning ol combustible matenal: if the com bustible material is finely divided the mixture may be explosive. Contact with liquid combustible materials may result in spontaneous ignition. Contact with sulfuric acid may cause fires or explosions. If material on fire or Involved In fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involvad in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts Avoid bodily contact with the material Wear boots, protective gloves, and goggles Oo not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius ol 2500 feet CALCIUM PEROXIOE 4918717 OXIDIZER UN1457 Calcium peroxide is a greyish white granular material, it is used in baking, in medicine, in bleaching oils, and for amny other uses, it is insoluble in water and slowly decomposed by water. It is noncombustible but it will accelerate the burning of combustible material: if the com bustible material is finely divided the mixture may be explosive. Mixtures of combustible material and the peroxide can be ignited by friction or contact with moisture. If material on fire or involved In fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involvad in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus whan fighting fires involv ing this matenal Evacuation if fire becomes uncontrollable evacuate for a radius of 2500 feat CALCIUM PHOSPHIDE 4918310 FLAMMABLE SOUD, POISONOUS UNI360 WATER REACTIVE Calcium phosphide appears as red-brown crystals to grey granular lumps. It reacts with water to form calcium hydroxide and phosphine, a flammable poisonous gas. Phosphine wM normally ignite sponta neously in contact with air. If there is an excess of water this lira of phosphine will not normally ignite surrounding combustible material. If material on fire or Involved In fire Do not use water Use dry chemical or carbon dioxide 100 If material not on fire and not Involved in fire Do not use water Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Personnel protection Avoid breathing dusts, and fumes from burning matenal Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the matenal anticipated, wear full protective clothing CALCIUM RESINATE 4916703 FLAMMABLE SOUO UN1313 Calcium resinate is a greyish white to yellow amorphous powder, if it comes in contact with air. spontaneous heating may result. This heat may be sufficient to ignite the matenal itself or surrounding combustible matenal. It is insoluble in water. If material on fire or Involved in fire Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not on fire and not Involved In tire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water CALCIUM RESINATE, FUSED 4916704 FLAMMABLE SOLID UN1314 Calcium resinate. fused is in the form of greyish lumps made by fusing the powdered material. If it comes in contact with air. spontaneous heating may result. This heat may be sufficient to ignite the matenal itself or surrounding combustible material. It is insoluble in water. If material on fire or Involved In fire Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If materiel not on fire end not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sourcss and sewers Personnel protection Avoid breathing dusts, end fumes from burning material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water CALCIUM-MANGANESE-SIUCON ALLOYS, 4918787 (FLAMMABLE SOUD, N.O.S.) FLAMMABLE SOUO UN132S Calcium-manganese-silicon alloys exist as gray lustrous crystalline lumps, it may react with water to give off hydrogen, a flammable gas. The heat of this reaction may be sufficient to ignite the hydrogen. April 198 0000qq 43 If material on fir* or Involved In fire Do not use water Use graphite, soda ash. powdered sodium chloride, or suitable dry powder tf material not on fire and not involved in fire Do not use water Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Personnel protection Wear boots, protective gloves, and goggles Do not handle broken Dackages without protective eguipment Wash away any material which may have contacted the body wiih copious amounts of water or soao and water Avoid breathing fumes Irom burning material Wear self-contained breathing apparatus when lighting tires involv ing this material If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain iiauip or solid material Cover solids with a plastic sheet to prevent dissolving m ram or fire fighting water Environmental considerations--water spill Add caicium hypochlorite Neutralize with agricultural lime tsiaked lime), crushed limestone. or sodium bicarbonate Add feme chloride (fecl3) Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates CALCIUM, METAL CRYSTALLINE 4916402 FLAMMABLE SOLIO NA1401 WATER REACTIVE Calcium, metal, crystalline is a greyish white granular metal, it is used m metallurgy. As it is finely divided it is more reactive with water than non-crystalline metallic calcium. It reacts with water to form hydrogen, a flammable gas. The heat of this reaction may be sufficient to ignite the hydrogen and also the calcium itself. If material on fire or involved in fire Do not use water Do not use carbon dioxide Use graphite, soda ash. powdered sodium chloride, or suitable dry powder If materiel not on fire and not involved in fire Do not use water Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Avoid breathing fumes from burning material CAMPHOR OIL 4913153 COMBUSTIBLE LIQUID UN1130 Camphor oil is a colorless liquid with a characteristic odor It has a flash point of 125 deg. F. It is insoluble in water and it is generally lighter than water. Its vapors are heavier than air. If material on Are or involved in fire Do not extinguish fire unless flow can be stooped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities ot water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fira and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Oo not handle broken packages without protective eouipment Wash away any material which may have contacted the body with copious amounts of water or soap and water CALCIUMARSENITE, SOLID 4923219 POISONS NA1S74 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Calcium arsemte. solid is a white powder. It is insoluble in water. It is toxic by inhalation (dust) and by ingestion. If materiel involved in Are Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved tot Are Keep matenai out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning matenai Keep upwind Avoid bodily contact with the matenai Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenai which may have contacted the body with copious amounts of water or soap and water April 1981 MCD 000009844 CANNON PRIMERS 4903120 CLASS C EXPLOSIVE Cannon primer is a small device containing a small amount of a percussion sensitive explosive which ignites a large charge of defla grating explosive which in turn ignites the gun propellant. H materiel on Are or Involved toi Are Flood with water Apply water from as far e distance as possible tf material not on Are and not involved in Are Keep spaifce. flames, and other sources of ignition away Personnel protection Approach fire with eaution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet 101 CAPRYLYL PEROXIDE SOLUTION 4919517 ORGANIC PEROXIDE NA2129 Capryiyf peroxide solution is a clear colorless to straw colored iiauid with a sharp odor. The peroxide itself is a straw colored liquid. The solution may take some effort to ignite Put once ignited it burns with increasing vigor as the fire progresses. It strongly supports the Burning of comoustipie material. Containers of the solution, if exposed to fire or flame, may explode. If material on fire or involved in fire Use water in flooding Quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to disperse vapors and dilute standing pools of llQUld Personnel protection Avoid breathing vapors or dusts Keep upwind Avoid bodily contact with the matenal Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts ot water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the matenal is on fire or involved in fire evacuate for a radius of 2500 feet CAPTAN (AGRICULTURAL INSECTICIDES. NEC. OTHER THAN LIQUID) 4961164 ORM-E NA9099 ENVIRONMENTALLY HA2AROOUS SUBSTANCE (RQ-10/4.54) Captan is a white solid. It is used as a fungicide. It is a wettabie powder. It can cause illness by inhalation, skin absorption and/or inges tion. In case of damage to. or leaking from containers of this material contact the oesticide safety team network. Telephone: 800-424-9300. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Matenal itself does not burn or burns with difficulty.) If material not Involved In fire Keep matenal out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates CAPTAN (AGRICULTURAL INSECTICIDES, NEC, 4961167 LIQUID) ORM-E NA9099 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-10/4.S4) Captan is a white solid disaoived in a liquid carrier. It is used as a fungicide. It is a water emulsifiable liquid, it can cause illness by inhal ation. skin absorption and/or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team net work. Telephone: 800-424*9300. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Matenal itself does not bum or bums with difficulty.) If material not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental conslderattona land apW Dig a pit. pond, lagoon, holding area to contain liquid or solid matenal Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations water spin If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dradges or lifts to remove immobilized masses of pollutants and precipitates 102 CAPTAN (INSECTICtOES, OTHER THAN 4961110 AGRICULTURAL, NEC) ORM-E NA9099 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-IO/4.54) Captan is a white solid or the solid dissolved in a liquid carrier. It is used as a fungicide. It is a wettabie powder or water emulsifiable liquid. It can cause illness by inhalation, skin absorption and/or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone: 800-424-9300. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) if material not Involved in Are Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and gogglas Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations land spill Dig a pit pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rein or firs fighting water Environmental considerations water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greeter concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobitized masses of pollutants and precipitates April 1961 000009845 MCD CARBAMATE PESTICIDE. LIQUID. N.O.S. 4921625 (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES, NEC. LIQUID) POISON B UN2757 Carbamate pesticide is a liquid or solid dissolved in a liquid earner. The carrier is water emulsifiabie. The earner may burn though it may require some effort to ignite. It fs toxic by inhalation, skin absorption, and/or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone: 800* 424-9300. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities df water Apply water from as far a distance as possible Use "alcohol" foam, caroon dioxide or dry chemical If material not on fire and not invoivad in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the matenai Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water CARBAMATE PESTICIDE. LIQUIO. N.O.S. 4910528 (COMPOUNOS AND PREPARATIONS) - (AGRICULTURAL INSECTICIDES. NEC. LIQUIO) FLAMMABLE LIQUIO UN2756 Carbamate pesticide is a liquid or solid dissolved in a nauid carrier. The earner is water emulsifiabie. The primary hazard of this material is the flammability of the carrier. It has a flash point below 100 deg. F. It can cause illness by inhalation, skin absorption and or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone: 800-424-9300 If material on fire or Involved in fire Do not extinguish fire unless flow can be stooped Use water in flooding quantities as tog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fira and not invoivad In tire Keep sparks, flames, and other sources of ignition away Keep matenai out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wear seif-contained breathing apparatus when fighting fires involv ing this material CARBAMATE PESTICIDE. LIQUID. N.O.S. 4910527 (COMPOUNDS AND PREPARATIONS) (INSECTICIDES. OTHER THAN AGRICULTURAL, NEC) FLAMMABLE LIQUID UN27S8 Carbamate pesticide is a liquid or solid dissolved in a liquid carrier. The earner is water emulsifiabie. The primary hazard of this material is the flammability of the carrier. It has a flash point below 100 deg. F. It can cause illness by inhalation, skin absorption and/or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone: 800-424-9300. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on lira and not involved In Are Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wear self-contained breathing apparatus when fighting fires involv ing this matenai April 1961 CARBAMATE PESTICIDE, LIQUID, N.O.S. 4921624 (COUMPOUNDS AND PREPARATIONS) (INSECTICIDES, OTHER THAN AGRICULTURAL, NEC) POISON B UN2757 Carbamate pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emulsifiabie. The carrier may bum though it may require some effort to ignite. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone; 800- 424-9300. If materiel on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Invoivad In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear seif-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 103 000009S46 tfCt> CARBAMATE PESTICIDE. SOLIO. N.O.S. 4921627 (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIOES. NEC. OTHER THAN LIQUID) POISON B UN2757 Carbamate pesticide is a solid or a liquid absorbed on a dry earner, it is a wettable oowder. It is toxic by inhalation, skin absorption, andor ingestion in case of damage to. or leaking from containers Of this ma terial contact the pesticide safety team network. Telephone: 800-424- 9300. If material on fire or involved in fire Extinguish tire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodrly contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts ol water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing CARBAMATE PESTICIDE, SOLID. N.O.S. 4921626 (COMPOUNDS AND PREPARATIONS) (INSECTICIDES. OTHER THAN AGRICULTURAL, NEC) POISON B UN2757 Carbamate pesticide is a solid or a liquid absorbed on a dry carrier. It is a wettable powder. It is toxic by inhalation, skin absorption, and or ingestion. In case of damage to. or leaking from containers of this ma terial contact the pesticide safety team network. Telephone; 800-424- 9300. If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use alcohol" foam, carbon dioxide or dry chemical If material not on fire end not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing CARBARYL (AGRICULTURAL INSECTICIDES, NSC. 4941121 UQUID) ORM-A NA2757 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RG-100/45.4) Carbaryl is a white crystalline solid dissolved in a liquid carrier. It is used as a pesticide. It is a water emulsifiabte liquid, ft can cause illness by inhalation, skin absorption and/or ingestion. In case of damage to. or leaking from containers ol this material contact the pesticide safety team network. Telephone: 800-424-9300. 104 ff material involved in fire Extinguish fire using agent suitable for type of surrounding fire ' (Material itself does not bum or bums with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental consideration*--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash. cement powder, sawdust, or com mercial sorbents Environmental considerations--water spilt If dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates CARBARYL (AGRICULTURAL INSECTICIDES. NEC. 4941122 OTHER THAN UQUID) ORM-A NA27S7 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100 45.4) Carbaryl is a white cylstalline solid. It is used as a pesticide. It is a wettable powder. It can cause illness by inhalation, skin absorption and or ingestion. In case ol damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424- 9300. ff materiel involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit pond, lagoon, holding areato contain liquid or soiid material Cover solids with a plastic sheet to prevent dissolving in rain or lire fighting water Environmental considerations--water spill It dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates CARBARYL (INSECTICIDES. OTHER THAN 4941120 AGRICULTURAL. NEC) ORM-A NA2757 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-IOO/45.4) Carbaryl is a white crystalline solid or the solid dissolved in a liquid carrier. It is used as a pesticide. It is a wettable powder or water emul- sifiabie liquid. It can cause illness by inhalation, skin absorption and or ingestion. In case of damage to. or leaking from containers of this ma terial contact the pesticide safety team network. Telephone: 800-424- 9300. April 1981 MCD 000009847 ft material involved in fir* Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) If materiel not Involved in fire Keep material out of water sources and sewers Build dikes to contain (low as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may nave contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in ram or lire fighting water Environmental considerations--water spill if dissolved, apply activated carbon at len times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates CARBOFURAN 4921525 POISON B NA2757 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-10/4.54) Carbofuran is a white solid or the solid dissolved in a liquid carrier, it is used as a pesticide. It is a wettabie powder or water emulsifiable liquid. It is toxic by inhalation, skin absorption, and or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone. 800*424-9300. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear lull protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of toppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates April 1981 CARBOFURAN MIXTURE. LIQUID (AGRICULTURAL 4921524 INSECTICIDES. NEC. LIQUID) POISON B NA27S7 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-10/4.54) Carbofuran mixture, liquid is a white solid dissolved m a liquid carrier. It is used as a pesticide. It is a water emulsifiable liquid, it >s toxic by inhalation, skin absorption, and or ingestion In case ol damage to. or leaking from containers of this material contact the pesticide safety team networx Telephone. 800-424-9300. If materiel on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Sond streams of water may be ineffective Cool alt affected containers with flooding quantities of water Aooiy water from as far a distance as possible Use alcohol foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keeo sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keeo upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective eauipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in ram or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at len times the spilled amount m region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates CARBOUC AGIO OR PHENOL 4921220 POISON B, CORROSIVE. COMBUSTIBLE UN1671 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Carbolic add or phenol is a colorless crystalline solid with a charac- tenstic odor. It is used to make plastics, adhesives, and other chemicals. It absorbs moisture from the air and liquefies It is soluble in water and its vapor is heavier than air. It is also combustible. It is corrosive lo the skin and lethal amounts can be absorbed through the skin. It weighs 8.9 pounds per gallon. If materiel on fire or Involved In fire Use water in flooding quantities as fog Sold streams of water may be ineffective Cock all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keeo sparks, flames, and other sources of ignition away Keeo material out of water sources and sewers Build dikes to contain (low as necessary Continued on next pajre 105 MCD 000009848 Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in ram or lire fighting water Environmental considerations--water spill if dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates CARBOLIC ACID. LIQUID OR PHENOL. LIQUID, 4921210 (LIQUfO TAR ACID CONTAINING OVER 50% BENZO-PHENOL) POISON B. CORROSIVE. COMBUSTIBLE NA2621 ENVIRONMENTALLY HAZAROOUS SUBSTANCE (RO-IOOO/454) Carbolic acid, liquid or phenol, liquid is a colorless liquid with a char acteristic odor It is used to make plastics, adhesives, and other chem icals. It is also combustible. Its vapor is heavier than air and it is soluble in water. It is corrosive to the skin. Lethal quantities of the material can be absorbed through the skin, it weighs 8.9 pounds per gallon. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool an affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical ff materiaf not on fire and not involved In fire Keep sparks, dames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the materiel Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--(and spill Dig a p<t. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill if dissolved, apply activated carbon at ten times the spilled amount in region of fOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates 106 MCD 000009849 CARBON BISULROE (OR) CARBON OISULFIDE 4908125 FLAMMABLE LIQUIO UN1131 ENVIRONMENTALLY HAZAROOUS SUBSTANCE (RQ-5000/2270) Carbon bisulfide is a clear colorless to light yellow liquid with a strong disagreeable odor. It is used in the manufacture of rayon and cellophane, m the manufacture of flotation agents and as a solvent. It has a flash point of -22 deg. F. and is flammable over a wide vapor-air concentration range The vapors are readily ignited; the heat of a common light bulb may be sufficient. It is heavier than water and insoluble in water. Its vapors are heavier than a>r It weighs 10.5 pounds per gallon. If material on fire or Involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Use dry chemical or carbon dioxide Do not use water Do not extinguish fire unless flow can be slopped If material not on fire and not involved in fire Keep sparks, dames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Evacuation If fire becomes uncontrollable or container is exposed to direct ffame--evacuate for a radius of 1500 feet if material leaking (not on tire), downwind evacuation must be considered Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Apply fluorocarbon-water foam to diminish vapor and fire hazard Environmental considerations water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate If dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environments! considerations--air spill Apply water spray or mist to knock down vapors Combustion products include corrosive or toxic vapors CARBON BLACK OIL (COMBUSTIBLE LIQUID. N.O.S.) 4915323 COMBUSTIBLE LIQUID NA1993 Carbon black oil is a dark colored liquid with a petroleum-like odor, it has a flash point between 100 and 200 deg. F. it is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with Hooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical April 1961 If material not on fire and not Involved In fire Keep sparks, names, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to Stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If material involved In fire Extinguish tire using agent suitable for type of surrounding fire (Matenal itself does not burn or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Attempt to stop leak if without hazard Personnel protection Wear protective gloves and goggles Do not handle broken packages without protective equipment CARBON BLACK OIL (FLAMMABLE LIQUID, N.O.S.) 4910323 FLAMMABLE LIQUID UN1993 Carbon black oil is a dark colored liquid with a petroleum like odor It has a flash point of less than 100 ceg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water CARBON OIOXIOE--OXYGEN MIXTURE 4904420 NONFLAMMABLE GAS UN1014 Carbon dioxide--oxygen mixture is a colorless odorless gas. Both carbon dioxide ana oxygen are noncombustible; however, oxygen can accelerate the burning of a fire. It may only be shipped in cylinders. If material involved in fire Extinguish fire using agent suitable lor type of surrounding fire (Material itself does not bum or bums with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible tf material not involved In fire Keep sparks, flames, and other sources of ignition away Attempt to stop leak if without hazard Personnel protection Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach lire with caution CARBON OIOXIOE'AIR MIXTURE (COMPRESSEO 4904510 GAS. N.O.S.) NONFLAMMABLE GAS UN1956 Carbon dioxide-air mixture is a colorless odorless gas mixture, it is noncombustible. It may only be shipped m cylinders. April 1981 CARBON DIOXIDE-ETHYLENE OXIDE GAS MIXTURE 4904511 (COMPRESSED GAS, N.O.S.) NONFLAMMABLE GAS UN1956 Carpon dioxide-ethylene oxide mixture is a colorless gas with an ether like odor, it is used as a fumigant. Carbon dioxide is noncombustible. Ethylene oxide is flammable. The mixture can asphyxiate by displace ment oi air. It may only be Shipped m cylinders. If material involved In fire Extinguish fire using agent suitable for type of surrounding lire (Material itself does not bum or burns with difficulty.) Cool all affected containers with flooding Quantities of water Apply water from as far a distance as possible If material not Involved in fire Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water CARBON DIOXIDE-ETHYLENE OXIDE MIXTURE 4905820 (COMPRESSED GAS, N.O.S.) FLAMMABLE GAS UN1954 Carbon dioxide-ethylene oxide is a colorless gas with an ether like odor. It is easily ignitable and may only be shipped in cylinders. Carbon dioxide is noncombustible and ethylene oxide is flammable. Both are heavier than air. A (lame can flash back to the source of leak very easily it can asphyxiate by the displacement of air. Under fire conditions cyl inders may violently rupture and rocket. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to Stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire wtin caution Evacuation If fve becomes uncontrollable or container is exposed to direct flame---evacuate (or a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered 107 MCD 000009850 CARBON DIOXIDE-NITROGEN GAS MIXTURE 4904512 (COMPRESSED GAS, N.O.S.) NONFLAMMABLE GAS UN19S8 Carbon dioxide-nitrogen gas mixture is a colorless odorless gas. Both carbon dioxide and nitrogen are noncombustible. The mixture can as phyxiate by the displacement of air. It may only be shipped in cylinders. It material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Cool all affected containers with Hooding quantities of water Apply water from as far a distance as possible If material not involved in fire Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Oo not handle broken packages without protective equipment CARBON DIOXIDE-NITROUS OXIDE MIXTURE 4904513 NONFLAMMABLE GAS UN1015 Carbon dioxide-nitrous oxide mixture is a colorless sweet tasting gas. Both carbon dioxide and nitrous oxide are noncombustible. The mixture can asphyxiate by the displacement of air. ft may only be shtpped in cylinders If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved In fire Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwmd Wear protective gloves and goggles Oo not handle broken packages without protective equipment CARBON DIOXIOE-PROPYLENE OXIOE GAS MIXTURE 4904514 (COMPRESSED GAS, N.O.S.) NONFLAMMABLE GAS UN1956 Carbon dioxide-propylene oxide gas mixture is a colorless gas with an ether like odor. Carbon dioxide is noncombustible. Propylene oxide is flammable. The mixture can separate with the flammable propylene oxide collecting in low areas. The mixture can asphyxiate by the dis placement of air. It may only be shipped in cylinders. If material Involved In fire Extinguish fire using agent suitable tor type of surrounding fire (Material itself does not bum or bums with difficulty.) Coo> all affected containers with flooding quantities of water App y water from as far a distance as possible If material not Involved in fire Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 108 CARBON DIOXIOE-PROPYLENE OXIDE MIXTURE 4905815 (COMPRESSEO GAS, N.O.S.) FLAMMABLE GAS UN1954 Carbon dioxide propylene oxide mixture is a colorless odorless gas It is easily ignited and may only be shipped in cylinders. Carbon dioxide is noncombustible and propylene oxide is flammable. Both are heavier than air. A flame can flash back to the source of leak very easily. It can asphyxiate by the displacement of air Under fire conditions cylinders may violently rupture and rocket. If material on fire or involved in fire Do not extinguish fire unless How can be stopped Use water in flooding quantities as tog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and noi involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Oo not handle broken packages without protective equipment Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If matenal leaking (not on fire), downwind evacuation must be considered CARBON OIOXIOE. LIQUEFIED 4904509 NONFLAMMABLE GAS UN2187 Carbon dioxide, liquefied is a colorless liquid. It is used as a refrigerant, in fire extinguishers, and in making carbonated beverages. It is non combustible. Contact with the liquid will cause frostbite. The gas is heavier than air and can asphyxiate by the displacement of air. If material involved In fire Extinguish tire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Cool all affected containers with flooding quantities of water Do not use water on material itself . Apply water from as far a distance as possible If material not involved in fire Attempt to stop leak if without hazard Do not use water on material itself Personnel protection Avoid breathing vapors Wear protective gloves and goggles Do not handle broken packages without protective equipment CARBON MONOXIOE 4905709 FLAMMABLE GAS UN1016 Carbon monoxide is a colorless, odortess gas. Prolonged exposure to carbon monoxide rich atmospheres may be fatal. It is easily ignited and may be shipped only in cylinders. It is |ust lighter than air and a flame can flash back to the source of leak very easily. Under fire con ditions the cylinders may violently rupture and rocket. H material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool ail affected containers with flooding quantities of water Apply water from as tat a distance as possible April 1981 ,009851 ttCD 0 ff material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Wear protective gloves and goggles Do not handle broken packages without protecttve equipment Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed 10 direct flame--evacuate for a radius of 1500 feet It material leaking (not on fire), downwind evacuation must be considered CARBON REMOVER. LIQUID 4910130 FLAMMABLE LIQUID UN1132 Carbon remover is a colorless liquid with a petroleum-like odor It has a flash poini of less than 100 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool alt affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water CARBON TETRACHLORIDE 4940320 ORM-A UN1846 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Carbon tetrachloride is a clear colorless heavy liquid with a charac teristic odor. It is used as a solvent, in the manufacture of other chem icals, as an agricultural fumigant, and for many other uses. It is heavier than water and insoluble m water. It is non-combustible. It can cause illness by inhalation, skin absorption and-or ingestion. It weighs 13.2 pounds per gallon. If material involved in fire Extinguish (ire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1981 00o9S52 Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Apply universal" gelling agent to immobilize spill Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom Remove trapped material with suction hoses if dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants ana precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Vaoor knockdown water is corrosive or toxic and should be diked for containment Thermal decomposition to phosgene can occur CARTRIDGE CASES. EMPTY, PRIMED 4903140 CLASS C EXPLOSIVE Cartridge cases, empty, primed consist of small arms cartridge cases, containing no propellant or projectile, with a smaitarms primer attached to the base. It material on fire or Involved in fire Flood with water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when lighting tires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet CARTRIDGE, PRACTICE AMMUNITION 4903150 CLASS C EXPLOSIVE Cartridge, practice ammunition consists of a metal cartridge case, primed with a limited amount of propelling charge and a solid projectile or solid projectile with smoke spotting charge. If material on fire or involved in fire Flood with water Apply water from as far a distance as possible If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear seH-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet CAUSTIC POTASH, DRY. SOUO, FLAKE, BEAO, OR GRANULAR (See POTASSIUM HYDROXIDE, DRY, SOLID, FLAKE, BEAD. OR GRANULAR 493522S) CAUSTIC POTASH. LtQUIO OR SOLUTION (Sea POTASSIUM HYDROXIDE, SOLUTION 4935230) 109 CAUSTIC SODA AND CAUSTIC POTASH. MIXEO, IN SOLUTION (POTASSIUM HYDROXIDE, LIQUIO, 4935244 OR SOLUTION) CDBROSIVP MATERIAL UN1814 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Caustic soda and caustic potash, mixed, in solution is a while solid dissolved in water, it is used in chemical manufacturing, petroleum re fining. cleaning compounds, and for many other uses. It is corrosive to metals ana tissue. It is non-combustible. It weighs 12.6 pounds per gallon. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Apply water fiom as far a distance as possible If material not involved In fire Keep material out of water sources and sewers Personnel protection Avoid breathing vapors or dusts Avoid bodily contact with the material Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Oig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with vinegar or other dilute acid Environmental considerations--water spill Neutralize with dilute acid or removable strong add Environmental considerations--air spill Apply water spray or mist to knock down vapors CAUSTIC SOOA AND CAUSTIC POTASSIUM. MIXED. 493S245 IN SOLUTION (SODIUM HYDROXIDE LIQUIO (OR) SOLUTION) CORROSIVE MATERIAL UN1B24 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Caustic soda and caustic potassium, mixed, in solution is the white solid material dissolved in water. It is non-combustible. It dissolves in water with release of heat. It is corrosive to metals and tissue. It weighs 12.7 pounds per gallon. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Apply water from as far a distance as possible If materiel not involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak H without hazard Personnel protection Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with vinegar or other dilute add Environmental considerations--water spill Neutralize with dilute add or removable strong add Environmental considerations--air spill Apply water spray or mist to knock down vapors no CAUSTIC SOOA SOLUTION SPENT (SODIUM 4935206 HYDROXIDE SOLUTION) CORROSIVE MATERIAL, BASIC UN1824 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Caustic soda solution, spent is a colorless to dark colored liquid. It is at least partially soluble in water with release of heat. It is corrosive to meials and tissue, it weighs 12.7 pounds per gallon. H material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itselt does not burn or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved In fire Keep material out oi water sources and sewers Buiid dikes to contain Mow as necessary Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting (ires involv ing this material If contact with the matenal anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with vinegar or other dilute acid Environmental conaidarations--water spill Neutralize with dilute acid or removable strong acid Environmental conaidarations--air spill Apply water spray or mist to knock down vapors CAUSTIC SODA, DRY, SOLID, FLAKE, BEAD, OR GRANULAR (Sea SODIUM HYDROXIDE. DRY, SOUD. FLAKE, BEAD, OR GRANULAR 4935235) CAUSTIC SOOA, UQUIO OR SOLUTION (Sea SOOIUM HYDROXIOE, SOLUTION 4935240) CELLULOSE FILM, NEC, PRINTED, (FLAMMABLE 4917397 SOLID, N.O.8.) FLAMMABLE SOUD UNI 329 Cellulose film, nec. printed is a flammable solid when made of nitro cellulose. It is then easily ignited and bums with great rapidity. Older film may deteriorate and be liable to spontaneous heating and Ignition. Toxic oxides of nitrogen are produced during combustion. If material on fire or Involved in fire Flood with water If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away CEMENT OR CONCRETE WATER PROOFING 4915462 COMPOUNDS. LIQUID OR PASTE (COMBUSTIBLE LIQUID. N.O.S.) COMBUSTIBLE LIQUIO NA1993 Cement or concrete water proofing compounds, liquid or paste are materials containing a solvent having a closed cup flash point between 100 and 199 deg. F. The hazard of these materials is combustibility. April 1981 mcd 00009853 ff material on fire or involved in fire Do not extinguish fire unless How can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of Ignition away Keep matenai out of water sources and sewers Build dikes to contain flow as necessary Use water spray lo knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water CEMENT OR CONCRETE WATER PROOFING 4910462 COMPOUNDS, LIQUID OR PASTE (FLAMMABLE LIQUIO. N.O.S.) FLAMMABLE LIQUID UN1993 Cement or concrete water proofing compounds, liquid or paste are materials containing a solvent having a closed cup flash point of less than 100 deg. F. The hazard of these materials is flammability. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as log Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use 'alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep matenai out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water CEMENT, ADHESIVE, N.O.S. COMBUSTIBLE UQUIO (See CEMENT, LIQUIO, N.O.S.,COMBUSTIBLE UQUIO 4915114) CEMENT, ADHESIVE, N.O.S., FLAMMABLE LIQUID (See CEMENT, UQUIO, N.O.S., FLAMMABLE UQUIO 4910114) CEMENT, CONTAINER UNOLEUM, TILE, OR WALLBOARO, UQUIO 4910112 FLAMMABLE LIQUID NA1133 Cement, container linoleum, tile, or wallboard. liquid are the solutions of various gums, resins etc. in different solvents. The liquids are generally quite thick and may range from dear colorless to black "tar." me flash point of the cement depends on the solvent used but it will be less than 100 deg. F. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool ail affected containers with flooding quantities of water April 1981 MCD 000009854 Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keeo upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water CEMENT. CORK, INSULATION, LIQUIO (CEMENT, 4910458 LIQUID, N.O.S.) FLAMMABLE LIQUID NA1133 Cement, cork, insulation, liquid is a solution of various gums and resins in various solvents. The liquids are generally quite thick and range from clear colorless to black tar '. The flash point depends on the sol vents used; but it will be below 100 deg. F. The hazard ol these materials is flammability. H material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water CEMENT, CORK. INSULATION. LIQUID (CEMENT. LIQUIO, N.O.S.) 4915456 COMBUSTIBLE LIQUIO NA1133 Cement, cork, insulation, liquid is a solution of various gums and resins in venous solvents. The liquids are generally quite thick and range from clear colorless to black "tar." the flash point depends on the solvents used but it will be between 100 and 199 deg. F. The hazard of these materials is combustibility. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 111 CEMENT, LEATHER FLAMMABLE LIQUID 4910110 NAUM Cement, leather is the solution of various gums and resins in vanous solvents. The liquids are generally quite thick and may range from clear colorless to black ' tar". The flash point of the cement depends on the solvent used but it will be less than 100 deg. F. If material on fire or involved in fire Do not extinguish fire unless How can be stopped Use water m flooding quantities as fog Solid streams of water may be ineffective Cool ail atlected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol' foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and waier CEMENT. LIQUID, N.O.S. 4910114 FLAMMABLE LIQUID NA1133 Cement, liquid, n.o.s. are solutions of various gums and resins in various solvents. The liquids are generally quite thick and may range from clear to black tar". The flash point of the cement depends on the solvent used but it will be less than 100 deg. F. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water CEMENT. LIQUID, N.O.S. 4915114 COMBUSTIBLE LIQUID NA1133 Cement, liquid, n.o.s. are solutions of various gums and resins in various solvents. The liquids are generally quite (hick and may range from clear to black "tar". The (lash point of the cement depends on the solvent used but it will be between 100 and 199 deg. F. If material on fire or involved in fire Do not extinguish fire unless flow can be stopoed Use water m flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical 112 If material not on fire and not involved In fire Keep sparks, (lames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water CEMENT, PYROXYLIN 4910116 FLAMMABLE LIQUID NA1133 Cement pyroxylin is pyroxylin plastic dissolved in a solvent The flash point of the cement depends upon the solvent used but it will be less than 100 deg. F. The film deposited by the evaporation of the solvent is easily ignited and once ignited burns with great rapidity. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If materiat not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water CEMENT, ROOFING, LIQUID 4910118 FLAMMABLE LIQUID NA1133 Cement, roofing, liquid is a solution of various gums and resins in vanous solvents. The liquids are quite thick and are generally black tars'. The flash point of the cement depends on the solvent used but it will be less than 100 deg. F. If material on Are or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool an affected containers with Hooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep soarks. flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1981 MCD 000009855 CEMENT. RUB8ER 4910120 FLAMMABLE LIQUID NA1133 Cement, rubber is a solution of various gums and resins in various solvents. The liquid is quite thick and is generally a milky white color. The flash point of the cement depends upon the solvent used but it will be less than 100 deg F. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cooi all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol'' foam, carbon dioxide or dry chemical H material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water CESIUM METAL 4916405 FLAMMABLE SOLID UNI 407 WATER REACTIVE Cesium metal is a silver white metal readily tarnished greyish white by air. It is used in electronics, as a catalyst m chemical processing, and for many other uses. It melts at 82 deg. F it is violently decomposed by water giving cesium hydroxide and hydrogen, a flammable gas. The heat of this decomposition may be sufficient to ignite the hydrogen. If material on fire or involved in fire Do not use water Do not use carbon dioxide Use graphite, soda ash. powdered sodium chloride, or suitable dry powder If material not on fire and not involved in fire Do not use water Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Do not attempt to sweep up dry material Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with coo'Ous amounts of water or soap and water Avoid breathing fumes from burning material CHAMPAGNE (ALCOHOLIC BEVERAGE) 4910345 FLAMMABLE LIQUIO UN1170 Champange is a variable colored bubbling liquid having the odor char acteristic of fermented liquors. It has a flash point between 73 and 100 deg. F it is soluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water m flooding quantities as fog SoNd streams of water may be ineffective Cooi all affected containers witn flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary April 1981 Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools ol liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken oackages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water CHAMPAGNE (ALCOHOLIC BEVERAGE) 4915312 COMBUSTIBLE LIQUID UN 1170 Champange is a variable colored bubbung liquid having the odor char acteristic of fermented liquors, it has a flash pomt between 100 and 199 deg. F. It is soluble m water. Its vapors are heavier than air If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water m flooding quantities as fog Solid streams of water may be ineffective Cool all aHected containers with Hooding auantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, names, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools ot liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equiomem Wash away any material which may have contacted the body with copious amounts of water or soap and water CHARCOAL BRIQUETTES (CHARCOAL BRIQUETTES 4917311 OR PELLETS. WITH PETROLEUM BINDER) FLAMMABLE SOLID NA1361 Charcoal briquettes are powdered or granular charcoal mixed with a tar or starch and water binder and pressed into regular lumps The hazard is that of spontaneous heating if the charcoal briquettes are not properly cooled after manufacture. H material on fire or involved in fire Remove burning material from load if safe and practicable to do so Use dry chemical or carbon dioxide Use wafer only if flooding quantities are available H material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material dry CHARCOAL BRIQUETTES (CHARCOAL BRIQUETTES 4917312 OR PELLETS, WITHOUT PETROLEUM BINDER) FLAMMABLE SOLID NA1361 Charcoal bnquettes are powdered or granular charcoal mixed with a tar or starch and water binder and pressed into regular lumps The hazard is that of spontaneous heating if the charcoal briquettes are not properly cooled after manufacture. Continued on next pege 113 00009S5 6 If material on fire or involved in fire Remove Burning material from load if safe and practicable to do so Use dry chemical or carbon dioxide Use water only if flooding quantities are available If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material dry CHARCOAL BRIQUETTES (CHARCOAL BRIQUETTES. COMPRESSED. SELF-IGNITING) 4917313 FLAMMABLE SOLID NA1361 Charcoal Briquettes are powdered or granular charcoal mixed with a tar or starch and water omder and pressed into regular lumps. The hazard is lhat of spontaneous healing if the charcoal briQuettes are not properly cooled after manufacture. If material on fire or involved in fire Remove burning material from load if safe and practicable to do so Use dry chemical or carbon dioxide Use water only if flooding quantities are available If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material dry CHARCOAL SCREENINGS, MADE FROM "PINON" 4917320 WOOD FLAMMABLE SOLID NA1361 Charcoal screenings, made from "pinon" wood is a finely divided black solid it is fairly easily ignued. The main hazard is that of spontaneous heating if the charcoal has not been properly ceoled after manufacture. It material on fire or involved in fire Remove burning material from load if safe and practicable to do so Use dry chemical or carbon dioxide Use water only if flooding quantities are available If material not on fire and not Involved in fire Keep material dry CHARCOAL. ACTIVATED 4917310 FLAMMABLE SOLID UN 1362 Charcoal, activated is a black granular material that has been treated to improve its absorptive ability. The hazard is that of spontaneous heating if the charcoal is not properly cooled after manufacture. If material on fire or involved In fire Remove burning material from load if safe and practicable to do so Do not use carbon dioxide If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material dry CHARCOAL. CORN COB OR COTTONSEED OR RICE 4917394 HULL, NOT ACTIVATED (CHARCOAL. SHELL) FLAMMABLE SOLID UN1325 Charcoal, corn cob or cottonseed or rice hull, not activated is a black solid The hazard in transDortauon is that of spontaneous heating if the matenai is not properly cooied after manufacture, or if it should become wet If material on fire or involved In fire Remove burning material from load if safe and practicable to do so Use dry chemical or carbon dioxide Use water only if flooding quantities are available If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material dry 114 CHARCOAL, OTHER THAN ANIMAL OR WOOO, NEC. NOT ACTIVATED, (FLAMMABLE SOLIO, N.O.S ) 4917395 FLAMMABLE SOLID UN1325 Charcoal, other than animal or wood. nec. not activated is a black solid. The hazard in transportation is that of spontaneous heating if the material is not properly cooled after manufacture or if it should become wet if material on fire or involved in fire Remove burning material from load if safe and practicable to do so Use dry chemical or carbon dioxide Use water only if Hooding quantities are available If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material dry CHARCOAL, SHELL 4917314 FLAMMABLE SOLID NA1361 Charcoal, shell is made from coconut shells, walnut shells, fruit pits, or other similar material. The hazard is that of spontaneous heating if the charcoal is not properly cooled after manufacture. If material on fire or involved in fire Remove burning material from load if safe and practicable to do so Use dry chemical or carbon dioxide Use water only if flooding quantities are available If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material dry CHARCOAL, WOOD SCREENINGS. OTHER THAN 4917322 "PtNON" WOOO SCREENINGS FLAMMABLE SOLID NA1361 Charcoal, wood screenings, other than 'pinon' wood screenings is a finely divided black solid, it is fairly easily ignited. The main hazard is that of spontaneous heating if the charcoal has not been properly cooled after manufacture. If material on fire or involved in fire Remove burning material from load if safe and practicable to do so Use dry chemical or carbon dioxide Use water only if flooding quantities are available If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material dry CHARCOAL. WOOO, GROUND, CRUSHED, 4917316 GRANULATEO. (OR) PULVERIZED FLAMMABLE SOLID NA1361 Charcoal, wood, ground, crushed, granulated, or pulverized is a finely divided black solid. It is fairly easily ignited. The main hazard is that of spontaneous heating if the charcoal has not been properly cooled after manufacture. If materiel on fire or involved In fire Remove bumjng material from load if safe and practicable to do so Use dry chemical or carbon dioxide Use water only if flooding quantities are available If material not on fire end not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material dry CHARCOAL, WOOD. LUMP 4917318 FLAMMABLE SOUD NA1361 Charcoal, wood, lump is large pieces of black material. The hazard in transportation is that of spontaneous heating if the charcoal has not been properly cooled after manufacture. April 1981 000009S57 MCD If material on fire or Involved in fire Remove burning material from load if safe and practicable lo do so Use dry chemical or carbon dioxide Use water only if flooding quantities are available If material not on fire and not involved in fire Keep sparks. names, and other sources of ignition away Keep material dry CHEMICAL AMMUNITION. NONEXPLOSIVE 4920925 (CONTAINING A POISON A MATERIAL) POISON A UN2016 Chemical ammuntition. nonexplosive (containing a poison a material) may be any type of projectile, bomb, granade. etc. containing a material classed as poison a. and does not contain any explosive components- the poison a material can cause death by inhalation or skin absorption. Of very small quantities. It may or may not be combustible. If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as tog Cool all affected containers with Hooding quantities of water Apply water from as far a distance as possible Use 'alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Wear full protective clothing Oo not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered CHEMICAL AMMUNITION, NONEXPLOSIVE 4923915 (CONTAINING A POISON 8 MATERIAL) POISON B UN2016 Chemical ammunition, nonexplosive (containing a poison b material) may be any type of proieciile. bomb, grenade, etc. containing a material classed as a poison b and does not contain any explosive components. The poison b material can cause death by inhalation, ingestion or skm absorption. The poison b material may or may not be combustible. If material on fire or Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as tog Cool all affected containers with flooding quantities of water Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the matenal Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with cooious amounts of water or soap and water Wear self-contained breathing apparatus when fighting tires involv ing this material if contact with the material anticipated, wear full protective clothing April 1961 CHEMICAL AMMUNITION. NONEXPLOSIVE 4925640 (CONTAINING AN IRRITATING MATERIAL) IRRITATING MATERIAL UN2017 Chemical ammunition, nonexplosive (containing an irritating matenal) may be any type ol projectile, bomb, grenade, etc. containing a sub stance classed as an irritating material, and does not contain any ex plosive components. The irritating material gives off fumes that are ex tremely irritating to the eyes and mucous membrances when exposed to air or contact with fire. It may or may not be combustible. If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in Hooding quantities as log Cool all affected containers with flooding quantities ol water Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water CHEMICAL KIT 4936546 CORROSIVE MATERIAL NA1760 Chemical kit is a package containing limited quantities of various corrosive matenals. They are generally non-combustible and soluble in water with release of heat. They are corrosive to metals and tissue, tf material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in Hooding quantities as fog tf material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material tf contact with the material anticipated, wear full protective clothing CHEMICAL PLANT WASTE (COMBUSTIBLE LIQUID. 4915560 N.O.S.) COMBUSTIBLE UQUIO NA1993 Chemical plant waste, nec is a dear to variable colored liquid which may have a pleasant or unpleasant odor. It has a flash point of between 100 and 199 deg. F. It may be insoluble, partially soluble, or soluble in water. It may be heavier or lighter than water, its vapors are heavier than air Contact the shipper to determine the specific constituents and properties of this matenal. If material on fire or involved in fire Do not extinguish lire unless How can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantifies of water Apply water from as far a distance as possible Use alcohol" loam, carbon dioxide or dry chemical Continued on next psge 115 MCD 000009858 If material not on fire and not Involved in fire Keep sparks, flames, and other sources ol ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear bools, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts cf water or soap and water Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equ^^em Wash away any material which may have contacted the oody with copious amounts of water or soap and water CHEMICAL PLANT WASTE, NEC (CORROSIVE 4936538 LIQUID, N.O.S.) CORROSIVE MATERIAL UN1760 Chemical plant waste, nec is a clear to variable colored liquid. It is usually soluble in water. It may burn though it may require some effort to ignite. It is corrosive to metals and tissue. Contact the shipper to determine the specific constituents and properties of this material. If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water m flooding quantities as spray and fog Use water spray to absorb vapors Cool ail affected containers with flooding quantities of waier Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain llow as necessary Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have coniacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear fun protective clothing CHEMICAL PLANT WASTE. NEC (FLAMMABLE 4910560 LIQUID, N.O.S.) FLAMMABLE UQUID UN1993 Chemical plant waste, nec is a dear to variable colored liquid and may have a pleasant or unpleasant odor. It has a flash point of less than 100 deg. F. It may be insoluble, partially soluble, or soluble in water. It may be heavier or lighter than water. Its vapors are heavier than air. Contact the shipper to determine the specific constituents and properties of this material. tf material on fire or involved in fire Do not extinguish fire unless llow can be stopoed Use water in flooding quantities as fog Solid streams of water may be ineffective Coot all affected containers with flooding qualities of water Apply water from as far a distance as possible Use "alcohol" (oam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, llames. and other sources of ignition away Keep material out of water sources and sewers 116 CHEMICAL PLANT WASTE. NEC (POISONOUS 4923370 LIQUID, N.O.S.) POISON B NA2810 Chemical plant waste, nec is a variable colored liquid. It may or may not be water soluble. It may burn though it may require some effort to ignite it is toxic by ingestion, inhalation (vapors, mist, etc.) or oy skin absorption. Contact the shipper to determine the specific constituents and properties of (his material. If material on fire or involved in fire Do not extinguish fire unless How can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool alt affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol"' foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear tull protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the bo j / with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered CHLORAL (CORROSIVE LIQUID. N.O.S.) 4935515 CORROSIVE MATERIAL UN1760 Chloral is a colorless oily liquid with a strong pungent odor H s used to ma*e chloral hydrate and ddt it is heavier than water and is soluble m water Its vapors are heavier man air. It is corrosive to tissue tf material involved in fire Extinguish fire using agent suitable for type of surrounc "g fire (Material itself does not burn or burns with difficulty.) Cool all affected containers with flooding quantities of wate- Aopty water from as far a distance as possible Use water spray to absorb vapors If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash or lime April 1981 MCD 000009859 Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the matenai Wear boots, protective gloves, and goggles Oo not handle broken packages without protective eouioment Wash away any matenai which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material II contact with the material anticipated, wear full protective clothing CHLORATE OF POTASH (See POTASSIUM CHLORATE 4918722) CHLORATE OF SODA (See SODIUM CHLORATE 4916723) CHLORATE AND BORATE MIXTURE 4918719 OXIDIZER UN1458 Chlorate and borate mixture is usually a white crystalline solid. It may only be partially soluble in water, ft forms a very flammable mixture with combustible materials and this mixture may be explosive if the com bustible material is very finely divided. The mixture can be ignited by friction. Contact with strong sulfuric acid can cause fires or explosions When mixed with ammonium salts, spontaneous decomposition ana ignition may result. Prolonged exposure of the material to fire or heat can result in an explosion. If material on fire or involved In fire Flood with water Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet CHLORATE. N.O.S. 4918721 OXIDIZER UN1461 Chicate. n.o.s is a crystalline compouna having the following prop erties The material is soluble m water. It torms a very tiammabie mixture with cc-nbustible materials and this mixture may be explosive if the combustible material is finely divided. The mixture can be ignited by fnctior Contact with strong sulfuric acio can cause fires or explosions. When mixed with ammonium salts, spontaneous decomposition and ignition may result. Prolonged exposure to fire or heat can result in an explosion. If material on fire or involved in fire F ood with water Cool all affected containers with Hooding quantities of water Apoiy water irom as far a distance as possible It material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keao material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages witnout protective equipment Wash away any material which may have contacted the body with copious amounts of water or soac and water Wear sell-contained breathing apparatus when fighting fires involv ing this material Evacuation H ; re becomes uncontrollable--evacuate for a radius of 2500 teet CHLORATE ANO MAGNESIUM CHLORIDE MIXTURE 4918720 OXIDIZER UN1459 Chlorate and magnesium chloride mixture is a white crystalline solid. It is soluble in water. It forms a very flammable mixture with combustible materials and this mixture may be explosive if the combustible material is very finely divided. The mixture can be ignited by friction. Contact with strong sulfuric acid can cause fires or explosions. When mixed with ammonium salts, spontaneous decomposition and ignition may result. Prolonged exposure of the material to fire or heat can result in an explosion. If material on fire or involved In fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible tf material not on fire and not involved In fire Keep spares, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenai which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet April 1981 CHLORATE, N.O.S., WET 4918610 OXIDIZER NA1461 Chic'ate. n.o.s.. wet is a slurry or sludge of white crystalline com pounds compounds which have the following properties. The material is soluoie in water. The matenai itself is noncombustible, but It can lorm a very `lammabie mixture with combustioie materials, and this mixture may be explosive if the combustible material is very finely divided. The mixture can be ignited by friction. Contact with strong sulfuric add can cause fires or explosions. When mixed with ammonium salts, sponta neous decomposition and ignition may result. Prolonged exposure of the material to heat or fire can result in an explosion. If material on fire or involved in fire F ood with water Cool an affected containers with flooding quantities of water Aoply water from as far a distance as possible If material not on fire and not involvtd in fire K-?ep sparks flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection '' ear boots, protective gloves, and goggles C : not handle broken packages without protective equipment v. ash away any material which may have contacted the body with copious amounts of water or soap and water v. ear self-contained breathing apparatus when fighting fires involv ing this material Approach fire with caution Evacuation If Hre becomes uncontrollable--evacuate for a radius of 1500 feet 117 MCD 000009860 CHLORDANE, LIQUID 4909320 FLAMMABLE LIQUID NA2762 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-10.4S4) Chiordane. liquid is the solution of chioraane. a clear colorless, odor less liquid m some solvent, it is used as an insecticide it has a Mash point of less than 100 deg. F depending on the solvent and the con centration of chiordane. chiordane itself does not burn. It is generally heavier than water and insoluble in water Its vapors are heavier than air. It weighs *3.3 pouncs per gallon If material on fire or involved in fire Use water m flooding quantities as fog Do not extinguisn tire unless How can De stoppec Solid streams of water may be ineffective Cool an affected containers with flooding Quantities of water Apply waier from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash. cement powder, sawdust, or com mercial sorbents Apply universal'' gelling agent to immobilize spin Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom if dissolved, apply activated carbon at ten times the spilled amount in region of tOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Combustion products include corrosive or toxic vapors CHLOROANE, LIQUIO 4913170 COMBUSTIBLE LIQUIO NA2762 ENVIRONMENTALLY HAZAROOUS SUBSTANCE (RQ-1/0.454) Chiordane. liquid is the solution of chiordane. a dear colorless, odor less liquid in a solvent, it has a flash point between 100 and 199 deg. F. it is generally heavier than water and insoluble in water. Its vapors are heavier than air. It weighs 13.3 pounds per gallon. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors 118 Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the matenat Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area io contain liauid or solid maienai Dike surface flow using soil, sand bags, foamed bolyurethane. or foamed concrete Absorb bulk liquid with fly ash, cement powder, sawdust, or com mercial sorbents Apply universal" gelling agent to immobilize spill Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag Darners to trap material at bottom If dissolved, apply activated carbon at ten times the spitieo amount m region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Aooly water spray or mist to knock down vapors Combustion products include corrosive or toxic vapors CHLORIC ACID 4918206 OXIDIZER. CORROSIVE NA2626 Chloric add is a colorless liquid. It is used as a reagent in chemical analysis and to make other chemicals. It will accelerate the burning of combustible materials and can ignite most on contact. It is corrosive to metals and tissue. If material involved in fire Use water in flooding quantities as log Cool all affected containers with flooding Quantities of water Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled maierial with crushed limestone soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may nave contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear Ml protective clothing Evacuation If tire becomes uncontrollable--evacuate for a radius of 1500 leet CHLORINATED LIME. LIQUID (CORROSIVE LIQUID, 4932332 N.O.S.) CORROSIVE MATERIAL. ACIDIC UN1760 Chlorinated lime, liquid is the water solution of calcium chloride and calcium hypochlorite. It has an odor of chlorine. It is corrosive to metals and to tissue. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire Material itself does not bum or bums with difficulty.> Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible H material not involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled maierial with crushed limestone, soda ash. or lime April 1981 MCD 000009861 E Personnel protection Avoid tyeathing vapors Avoid oodily contact with the material Wear boots, protective gloves, and goggles Do not nandle broken packages without protective eouioment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear set-contained breathing apparatus wnen fighting fires involv ing r s material If coma:: witn the material anticipated, wear full protective clothing CHLORINATED PHENOL PETROLEUM SOLUTION 4921494 (POISONOUS LIQUID, N.O.S.) POISON B NA2810 Chlorinated ohenoi petroleum solution is a coiorless to yellow liquid. It is msoiuoe in water and may or may not be combustible. It is toxic oy inhalatio" and by skin absorption. If material on fire or involved in fire Do noi extinguish fire unless flow can be stooped Use water in flooding quantities as fog Solid sheams of water may be ineffective Cool a affected containers with flooding quantities of water Apply *ater from as far a distance as possible Use foam, carbon dioxide or dry chemical Use water spray to absorb vapors If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build cues to contain flow as necessary Attemo: to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid preathmg vapors Keep upwind Wear self-contained breathing apparatus Avoid codiiy contact with the material Wear full protective clothing Do not nandie broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water CHLORINE 4904120 NONFLAMMABLE GAS, POISONOUS UN1017 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-10/4.54) Chlorine s a greenish yellow gas with a pungent suffocating odor. It is used to punfy water, bleach woodpulp. and to make other chemicals. It is toxic by inhalation It is soluble in water. It reacts explosively or forms explosive compounds, with many common chemicals. It is nor mally shipped as a liquid in cylinders or tank cars. Contact with liquid should be avoided as it can cause frostbite. The liquid does readily vaporize to gas. The vapors are much heavier than air and tend to settle m low areas It weighs 13 0 pounds per gallon. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Maienai itse'f does not bum or bums with difficulty.) Cooi a affected containers with flooding quantities of water Apply *ater from as far a distance as possible Use water sorav to absorb vapors If material not involved in fire Keep material out of water sources and sewers Attempt to slop teak if without hazard Do not apply water to point of leak in tank car or container Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus April 1981 Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation if material leaking mot on firei evacuate for a radius of 2500 feet Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concreie Absorb bulk liquid with fly asn or cement powder Neutralize with caustic soda or soda ash Environmental considerations--water spill Add caustic soda If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment CHLORINE DIOXIDE HYDRATE. FROZEN 4918110 OXIDIZER. POISONOUS AND THERMALLY UNSTABLE NA9191 Chlorine dioxide hydrate, frozen is an orange colored solid, appearing as a block of ice. with a faint odor of chlorine, it is used to bleach wood pulp, fats and oils: in processing hour, and tor water purification. It may only be shipped in the frozen state and then only by private or contract motor carrier. The melting point of the hydrate is around 30 deg F. If it should thaw and lurther warm up. chlorine dioxide gas is given off. The gas is toxic by inhalation The gas and liquid are violently decom posed by organic materials. The gas will decompose explosively at temperatures below the boiling point of water. If material on fire or involved in fire Use water m flooding quantities as fog Cool all affected containers with flooding quantities of water Extinguish fire using agent suitable for type of surrounding lire (Material itself does not burn or burns with difficulty.) If material not on fire and not involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing vapors Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet CHLORINE TRIFLUORIDE 4918210 OXIDIZER. POISONOUS. CORROSIVE UN1749 Chlorine trifiuoride $ a colorless gas or green liquid with a pungent odor. It becomes a gas at 53 deg F. It reacts with water to form chlorine and hydrofluoric add with release of heat. Contact with organic materials may result in spontaneous ignition, ft may only be shipped in cylinders not equipped with safety relief Devices. It is corrosive to metals and (issue. Prolonged exposure of the cylinders to fire can result in their violent rupturing and rocketing Continued on next page *00 o,o0 '9. 119 H material Involved in fire Do not use water on material itself Use dry chemical or carbon dioxide Cool all affected containers with flooding Quantities of water 11 targe quantities of combustibles are involved, use water m flooding quantities as spray and fog Use water spray to absorb vapors If material not involved in fire Keep material out of water sources and sewers Do not use water on material itself Use water spray to knock-down vaoors Neutralize spilled material witn crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear fuli protective clothing Do noi handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet if material leaking (not on fire), downwind evacuation must be considered 4-CHLORO-O-TOLUIDINE HYDROCHLORIDE 4921412 POISON B UN1579 4-chloro-o-toIuidme hydrochloride is a white crystalline solid. It is sol uble in water. It is toxic by skin absorption and inhalation (dust). If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Use water in flooding quantities as fog Use alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keeo sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing vapors or dusts Keep upwind Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material CHLOROACET1C ACID, SOUO 4931416 CORROSIVE MATERIAL ACIDIC UN1751 Chloroacetic acid, solid is a colorless to light-brown crystalline solid. ' absorbs moisture from air and forms a syrup. It is soluble in water, it i corrosive to metals and tissue if material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep material out of water sources and sewers Neutralize spilled material with crushed limestone, soda ash. or lime i 20 Personnel protection Avoid breathing vapors Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when lighting fires involv ing this material if contact with the material anticipated, wear full protective clothing CHLOROACETOPHENONE, GAS, LIQUID OR SOLID 4925220 IRRITATING MATERIAL UN1697 Chloroacetophenone is in the form of colorless to white crystals. The vapor ol the material is very irritating to the eyes and mucous membranes. If material on fire or involved in fire Use water in flooding quantities as fog Use alcohol" foam, carbon dioxide or dry chemical Cool all affected containers with Hooding quantities ol water Use water spray to absorb vapors If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep materiai out of water sources and sewers Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body w<ih copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing CHLOROACETYL CHLORIDE 4931210 CORROSIVE MATERIAL, ACIDIC. POISONOUS UN1752 Chloroacetyl chloride is a colorless to light yellow liquid with a pungent odor. It is decomposed by water to chloroacetic and hydrochloric acics These and the materiai itself are corrosive to metals and tissue. If material involved in fire Use dry chemical or carbon dioxide Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Appiy water from as far a distance as possible If material not involved In fire Keep material out of water sources and sewers Bodd dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash. or time Personnel protection Avo<d breathing vapors Keeo upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body wun copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing April 1981 S63 0009 00 CHLOROBENZOL (OR) CHLOROBENZENE 4909153 FLAMMABLE LIQUID UN1134 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100 45.4) Chlorobenzol is a clear colorless liquid with an almond-like odor It has a flash point of 66 deg. F. It is heavier than water and slightly soluble in water. Its vapors are heavier than air. It weighs 9.2 pounds per gallon. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding Quantities as fog Solid streams of water may spread tire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, names, and other sources of ignition away Keep material out of water sources and sewers Sudd dikes to contain flow as necessary Attempt to stop eak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface How using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash. cement powder, sawdust, or com mercial sorbents Apply universal gelling agent to immobilize spill - Apply fluorocarbon-water foam to diminish vapor and fire hazard Environmental considerations--water spill Use natural deeo water pockets, excavated lagoons, or sand bag barriers to trao material at bottom if dissolved, apoiy activated carbon at ten times the spilled amount m region of iQppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Combustion products include corrosive or toxic vapors P-CHLOROBENZOYL PEROXIDE 4919120 ORGANIC PEROXIDE UN2113 R-chiorobenzoyt peroxide is a white granular solid, ft is easily ignited and bums very rapidly it strongly supports the burning of combustible materials n can form explosive mixtures with finely divided combustible materials Under prolonged exposure to fire or heat containers of the material can explode if material on fire or involved in fire Use water in Hooding quantities as tog Cool an affected containers with flooding quantities of water Aooiy water fro-- as far a distance as possible Use alcohol !oam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, names, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up April i98i Personnel protection Avoid breathing dusts, and tumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages withoul protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing thts material If contact with the maieriai anticipated, wear full protective clothing Approach fire with cauiion Evacuation If the material is on fire or involved m fire evacuate for a radius of 2500 feet P-CHLOROBENZOYL PEROXIDE, (NOT MORE THAN 4919219 52% AS A PASTE) THAN 52% WITH INERT SOLID) ORGANIC PEROXIDE UN2114 3.3.6.6.9.9-hexamethyl-l.2.4.5-tetraoxocyclononane. (not more than 52% solid. It is used to manufacture paints, plastics, and rubber. It is plastics, and rubber. It is insoluble in water. It is easily ignited and as the fire progresses. It can form explosive mixtures with finely divided mixtures with finely divided combustible materials. It supports the burning under prolonged'exposure to fire or heat containers of the material may containers of the material may explode. If material on fire or involved in fire Use water in flooding quantities as <og Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as tar a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning matenal Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting (ires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is or fire or involved in fire evacuate for a radius of 2500 feet P-CHLOROBENZOYL PEROXIDE. (NOT MORE THAN 4919218 75% WITH WATER) ORGANIC PEROXIOE UN2113 P-chlorobenzoyl peroxide, (not more than 75% with wateri is a white solid, it is used to manufacture paints, plastics, and rubber, It is insoluble m water. It is easily ignited and burns with increasing rapidity as the fire progresses. It can form explosive mixtures with finely divided combus tible materials. It supports ihe burning of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. Continued on next pep# 121 MCD 000009864 If material on fire or involved in fire Use water in flooding quantifies as fog Solid streams of water may be ineffective Coot all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol' foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and `umes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective ecuioment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the materia) anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet CHLOROFORM (CHLOROFORM 4940310 (TRICHLORMETHANE). NEC. OTHER THAN TECHNICAL GRADE) ORM-A UN1808 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Chloroform is a clear colorless heavy liquid with a characteristic odor it is used as a solvent, to make other chemicals, as fumigant, and for other uses, tt is heavier than water and slightly soluble in water. It is nonflammable under most conditions, but it will bum under extreme fire conditions, tt can cause illness by inhalation, skin absorption and/or ingestion. It weighs 12.3 pounds per gallon. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spHI Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface How using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Apply universal" gelling agent to immobilize sptll Environmental considerations--water apill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom Remove trapped material with suction hoses If dissolved, apply activated carbon at ten times the spilled amoum in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--sir spill Combustion products include corrosive or toxic vapors Thermal decomposition to phosgene can occur 122 CHLOROFORM (CHLOROFORM. NEC. TECHNICAL 4940311 GRADE (TRICHLOROMETHANE)) ORM-A UNI 838 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000 2270) Chloroform is a dear colorless heavy liquid with a characteristic odor It is used as a solvent, to make other chemicals, as fumigant, and for other uses. It is heavier than water and slightly soluble in water. It is nonflammable under most conditions, but it will bum under extreme fire conditions. It can cause illness by inhalation, skin absorption and/or ingestion. it weighs '2 3 pounds per gallon If material involved in fire Extinguish fire using agent suitable for type ol surrounding fire (Material itself does not burn or bums with difficulty ) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain How as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted me body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or sand material Dike surface flow using soil, sand bags, foamed poiyurethane. or foamed concrete Absorb bulk liquid with fly ash or cement powder Apply "universal" gelling agent to immobilize spill Environmental considerationa--water spill Use natural deep water pockets, excavated lagoons, or sand bag barbers to trap material at bottom Remove trapped material with suction hoses if dissolved, apply activated carbon at ten times the spmed amount m region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations---air spill Combustion products include corrosive or toxic vapors Thermal decomposition to phosgene can occur CHLOROPENTANES (COMBUSTIBLE LIQUID. N.O.S.) 4913136 COMBUSTIBLE LIQUID NA1993 Chioropentanes are clear colorless to pale yellow liquids They have a flash point between 100 and 199 deg. F. They are fighter man water and insoluble in water. Their vapors are heavier than air. H material on fire or involved In fire Do not extinguish fire unless How can be stopped Use water in flooding quantities as fog Solid streams ol water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, llamas, and other sources of ignition away Keep material oui of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material April 1981 MCD 000009865 CHLOROPENTANES (FLAMMABLE LIQUID, N.O.S.) 4909136 FLAMMABLE LIQUID UN1993 Chloropentanes are clear colorless to yellow liquids. Their flash point is in the range of 54 to 99 deg. F. They are lighter than water and nsoluble in water. Their vapors are heavier than air. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affecied containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material CHLOROPHENYL TRICHLOROSILANE 4934220 CORROSIVE MATERIAL. ACIDIC UN1753 Chlorophenyi tnchiorosiiane is a colorless to pale yellow liquid with a pungent odor. The material will bum though it may lake some effort to ignite. It is decomposed by moisture or water to hydrochloric acid with evolution of heat. It is corrosive to metals and tissue If material on fire or involved in fire Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as soray and fog Use water spray to aosoro vaoors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes lo contain How as necessary Use water spray to xnocK-down vapors Do not use water on material rtseif Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vaoors Keep upwind Wear seif-containec breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the matenai anticipated, wear full protective clothing 3-CHLOROPEROXYBENZOIC ACID, (NOT MORE THAN 4919223 66% WITH 3-CHLOROBENZOIC ACIO) ORGANIC PEROXIDE UN2755 3-cbloroperoxybenzoic acid, (not more than 86% with 3-chlorobenzoic acid) is a white solid, ft is used to manufacture paints, plastics, and rubber. It is insoluble in water. It is easily ignited and bums with increas ing rapidity as the lire progresses. It can lorm explosive mixtures with finely divided combustible materials. It supports the burning of combus tible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or involved in fire Use water m flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts o( water or soap and water Wear sell-contained breathing apparatus when fighting fires involv ing this material II contact with the material anticipated, wear full protective clothing Approach lire with caution Evacuation If the material is on fire or invotved in fire evacuate for a radius of 2S00 feet April 1981 CHLOROPICRIN AND METHYL CHLORIOE MIXTURE 4920105 POISON A, FLAMMABLE UN1562 Chloropicnn and methyl chloride mixture is a colorless gas with an intense, penetrating odor. It is shipped as a liquefied gas under its vapor pressure. Methyl chionde is a flammable gas and chloropicrin is non combustible. The mixture can separate with the chloropicrin settling into low areas. Chloropicnn ts very irntatmg to all body surfaces and is toxic by inhalation. It may only be shiooed in cylinders and these may be overpacked in wooden boxes Prolonged exposure to fire or heat mav cause the cylinders to violently rupture and rocket. If material on Art or Invotved in fire Do not extinguish fire unless flow can be stopped Use water m flooding Quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, (lames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keeo upwind Wear self-contained breaming apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body w>n copious amounts of water or soap and water Evacuation If material leaking (not on fire). downwind evacuation must be considered 123 MCD 00009866 CHLOROPICRIN MIXTURE (CONTAINING NO 4921416 COMPRESSEO GAS OR POISON A LIOUIO) POISON 8 UN1583 Chloropicrin mixture is a variable colored liquid usually colorless to yellow. Chloropicrin is non-combustible and the flammability of the mix ture will depend on the other component of the mixture. Chloropicrin vapors are heavier than air and it is toxic by inhalation. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone: 000-424-9300 If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as fog Use alcohol" foam, carbon dioxide or dry chemical Use water spray to absorb vapors If material not on fire and not involved in fire Keep sparks, flames, and other sources o< ignition away Keep material out of water sources and sewers Build dikes to contain 'low as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered CHLOROPICRIN, ABSORBED 4921415 POISON B NA1S63 Chloropicrin, absorbed is a liquid chloropicrin absorbed on a dry car rier. The strong odor of chloropicrin may or may not be present The carrier usually is not soluble in water and is non-combusiible. Chloro- picnn is slightly soluble m water and is non-combustible. Vapors of chloropicrin are heavier than air and it is toxic by inhalation. In case of damage to. or leaking from containers ol this material contact the pes ticide safety team network Telephone: 800-424-9300 If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use alcohol" foam, carbon dioxide or dry chemical If material not involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing vapors or dusts Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts ol water or soap and water If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Use water in flooding quantities as fog Use alcohol'' foam, carbon dioxide or dry chemical If material not involved in fire Keep material out of water sources and sewers Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact wiih the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts ol water or soap and water Evacuation If materia! leaking (not on fire), downwind evacuation must be considered CHLOROPRENE, INHIBITED 4907223 FLAMMABLE LIOUIO POLYMERIZABLE UN1991 Chloroprene is a clear colorless liquid. It is used to make neoprene rubber. It has a Mash point of -4 deg. F II subject to heat it may poly merize. with evolution of additional heat. If the polymenzation takes place in a container, the container is subject to possible rupture. It is heavier than water and slightly soluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep materia) out of water sources and sewers Attempt to stop leak <f without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation if fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet if material leaking (not on fire), downwind evacuation must be considered CHLOROPICRIN. LIOUIO 4921414 POISONS UN1580 Chloropicrin. liquid is a colorless to yellow liquid with a strong odor It is slightly soluble m water and is non-combustible, its vapors are heavier than air and it is toxic by inhalation, in case ol damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone: 800-424-9300 124 MOD 000009867 2-CHLOROPROPENE 4908126 FLAMMABLE UQUID UN2456 2-chioropropene is a clea- colorless volatile liquid. It has a flash point of -4 deg. f. and a boiling point of 73 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. April 1961 K tf material on fire or Involved In fire Do not extinguish fire unless flow can be slopped Use water m flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus wnen fighting fires involv ing this material Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered CHLOHOSULFONIC ACID 4930204 CORROSIVE MATERIAL. ACIDIC UN1754 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/4S4) Chiorosulfomc acid is a colorless to yellow colored fuming liquid with a pungent odor It is decomposed by water to give hydrochloric and sulfuric acids with release of heat. It is corrosive to metals and tissue, it weighs 14.7 pounds per gallon. If material involved in fire Do not use water on material itself Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Keep material out ot water sources and sewers Bu>id dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill D<g a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or 'oamed concrete Absorb bulk liquid with fly ash or cement oowder Neutralize with agricultural lime (slaked i me), crushed limestone. qr sodium bicarbonate Di Jte slowly with water Environmental considerations--water spill Neutralize with agricultural lime (slaked me), crushed limestone, or sodium bicarbonate Environmental considerations--sir spill Aooly water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment April 1981 CHLOROSUNFONIC ACID-SULFUR TRIOXIOE MIXTURE CORROSIVE MATERIAL. ACIDIC ENVIRONMENTALLY HAZARDOUS SUBSTANCE 4930205 UN1754 (RQ-1000 454) Chlorosuilonic acid-sulfur trioxide mixture is a colorless to yellow fum ing liquid with a pungent odor. It is decomposed by water into hydro chloric and sulfuric actd with release of heat. It is corrosive to metais and skin. It weighs '4 7 pounds per gallon. If material involved in tire Do not use water on material itsetl Use water in flooding quantities as log Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limesione. soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Oo not handle broken packages without proiechve equipment Wash away any material which may have contacted the body wnn copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, loomed oolyurethane. or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agricultural lime (slaked lime), crushed limestone or sodium bicarbonate Dilute slowly with water Environmental considerations--water spill Neutralize with agricultural lime istaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment CHLORPICRIN AND NONFLAMMABLE. 4920505 NONLIQUEFIED COMPRESSED GAS MIXTURE POISON A NA1955 Chiorpicnn and nonflammable, nonhquefied compressed gas is a col orless gas with an intense penetrating odor, i; is toxic by inhalation (vapor) and ingestion. It may only be shipped m cylinders. Its vapors are heavier than air. Prolonged exposure of the cylinder to fire or heat may result m the violent ruptunng and rocketing of the cylinder, tf material Involved in fire Extinguish lire using agent suitable tor ivoe of surrounding fire (Material itself does not burn or burns wirn difficulty.) Use water m flooding quantities as tog Cool ail affected contatners with flooding c jantities of wate' Apply water from as far a distance as pos-ole Use alcohol ' foam, carbon dioxide or dry rhermcal If material not involved In fire Keep sparks, flames, and other sources o- ignition away Keep material out of water sources and sewers Attempt to stop <eak if without hazard Use water spray to knock-down vapors Continued on next page 009 00 125 Personnel protection Avoid breaming vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with cooious amounts of water or soap and water Evacuation If material leaking mot on firei. downwind evacuation must be considered Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped matenal with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates CHLORPYRIFOS (AGRICULTURAL INSECTICIDES. 4941123 NEC. LIQUID) ORM-A NA2783 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Chlorpyrifos is a white crystalline solid dissolved m a liquid earner II is used as a herbicide. It is a water emulsifiable liquid. It can cause illness by inhalation, skin absorption and or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone: 800-424-9300. It material involved in tire Extinguish fire using agent suitable for type Of surrounding fire (Material itself does not burn or burns with difficulty.) If material not involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill If dissolved, apo'y activated carbon at ten times the spilled amount m region of lOpDm or greater concentration Remove traoDed material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates CHLORPYRIFOS (AGRICULTURAL INSECTICIDES, 4941124 NEC. OTHER THAN UQUIO) ORM-A NA2763 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RG-1/0.454) Chlorpyrifos is a white crystalline solid, it is used as a herbicide. It is a wettabie powder it can cause illness by inhalation, skin absorption and.or ingestion in case of damage to. or leaking from containers of this material contact tne pesticide safety team network. Telephone: 800- 424-9300 If material involved in fire Extinguish ` -e using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) If material not involved In fire Keep maten-i1 out of water sources and sewers Build dikes 'c contain flow as necessary Personnel protection Keep jpwmc Wear boots o'otective gloves, and goggles Avoid breatning vapors or dusts Wasn away any material which may have contacted the body with copious amounts of water or soap and water 126 CHLORPYRIFOS (INSECTICIOES. OTHER THAN 4941125 AGRICULTURAL, NEC) ORM-A NA2783 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1 0.454) Chlorpyrifos is a white crystalline solid or the solid dissolved m a liquid carrier. It is used as a herbicide. It is a wettabie powder or water emul sifiable liquid, it can cause illness by inhalation, skin absorption and or ingestion. In case of damage to. or leaking from containers of this ma terial contact the pesticide safety team network. Telephone: 800-424- 9300. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty ) If material not involved in fire Keep material out ol water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in ram or tire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates CHROME CHLORIDE SOLUTION (CHROMOUS 4963324 CHLORIDE) ORM-E NA9102 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Chrome chloride solution is the white crystalline solid dissolved m water. It is used to make other chemicals. It is non-combustible If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Matenal itself does not bum or burns with difficulty ) If material not involved In fire Keep material out ol water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1981 000009B69 Environmental consideration*--land spill Dike surface How using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Apply "universal" gelling agent to immobilize spill Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Use mechanical dredges or lifts lo remove immobilized masses of pollutants and precipitates CHROME CHLORIDE SOLUTION (CORROSIVE LIQUID. 4932338 N.O.S.) CORROSIVE MATERIAL. ACIDIC UN1760 Chrome chloride solution is the blue or green colored crystals dis solved m water. The solution is corrosive to metals. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Avoid oodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material ii contact with the material anticipated, wear full protective clothing Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates CHROMIC ACETATE 4963312 ORM-E NA9101 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Chromic acetate is a greyish green to bluish green powder. It is used in tanning and in textile dyeing. It is soluble in water. It is non- combustible. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in ram or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates CHROME SULPHATE SOLUTION (CHROMIC 4963319 SULFATE) ORM-E NA9100 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-IOOO/454) Chrome sulphate solution is the oark green to violet crystalline material dissolved in water It is used in paints and inks, ceramics, and in textile dyemg. it is soluble in water. It is non-combustible. If material involved in fire Extinguish fire using agent suitable lor type of surrounding fire (Material itself does not bum or bums with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or Justs Wash away any material wn>ch may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using son sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash. cement powder, sawdust or com mercial sorbents Apply universal" gelling agent to immobiize spill April 1981 CHROMIC ACID MIXTURE, DRY 4918511 OXIDIZER, CORROSIVE NA1463 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Chromic acid mixture, dry is the mixture of the dark purplish red solid and other solid chemicals. The chromic acid is soluble in water with release of heat. The other materials may or may not be soluble in water. The material itself is noncombustible but it will accelerate the burning of combustible materials, its solution is corrosive to metals and tissue. If material on flra or Involved In fire Flood with water Apply water from as far a distance as possible If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing dusts Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water if contact with the material anticipated, wear full protective clothing Approach lire with caution Continued on next page 127 MCD 000009870 Environmental considerations--land spill Dig a pit pond, lagoon, holding area <0 contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in ram or lire fighting water Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Neutralize with agricultural lime (staked lime), crushed limestone, or sodium bicarbonate Use mechanical dredges or lifts to remove immobilized masses ot pollutants and precipitates CHROMIC ACID SOLUTION 4930206 CORROSIVE MATERIAL. ACIDIC UN1755 ENVIRONMENTALLY HAZAROOUS SUBSTANCE (RQ-1000/454) Chromic acid solution is a dark red colored liquid. It is soluble in water. It is corrosive to metals and tissue. It can react with combustible matenals and the heat of this reaction may be sufficient to result in the ignition of the combustible material. It weighs 13.9 pounds per gallon, if material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water m flooding quantities as fog Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep uowind Avoid bodily contact with the matenal Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land apili Dig a pit. pond, lagoon, holding area to contain liquid or solid matenal Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Adjust ph to neutral (ph*7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental consideration*--air apili Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should ba diked for containment CHROMIC ACID, SOLID 4918S10 OXIDIZER. CORROSIVE NA1463 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-IOOO/454) Chromic aod is a dark purplish red solid, it is soluble m water to form a corrosive solution. The matenal itself is noncombustibfe but it will accelerate the burning of combustible materials. Sufficient heat may be generated from the reaction with combustible materials to ignite the mass. Prolonged exposure to fire or heat can cause containers of the material to explode. If material on fire or Involved In fire Flood with water Apply water from as far a distance as possible 128 tf material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing dusts Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Neutralize with agricultural lime islaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Neutralize with agricultural lime (slaked lime) crushed time^to.n or sodium bicarbonate Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates CHROMIC ANHYDRIOE (See CHROMIC ACID, SOLID 4918510) CHROMIC FLUORIOE SOLUTION 4932340 CORROSIVE MATERIAL, ACIOIC UN17S7 Chromic fluoride solution is the green crystalline solid dissolved m water. It is corrosive to metals and tissue. If material Involved in fire Extinguish fire using agent suitable for type of surrounding lire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with Hooding quantities of water Apply water from as far a distance as possible tf material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Wear boots, protective gloves, ana goggles Do not handle broken packages without protective equipmeni Wash away any material which may have contacted the body with copious amounts of water or soap and water Avoid breathing fumes from burning material if contact with the material anticipated, wear full protective clothing CHROMIC FLUORIDE. SOLID 4932339 CORROSIVE MATERIAL UNI 756 Chromic fluoride, solid is a green crystalline solid. It is soluble in water It is corrosive to tissue. If material involved in fire Extinguish fire using agent suitable for type of surrounding tire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Keep materia) out of water sources and sewers Neutralize spilled material with crusned limestone, soda ash. or hme April 1961 MCD 000009871 I Personnel protection Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing CHROMIC SULFATE 4963314 ORM-E NA9100 ENVIRONMENTALLY HA2AROOUS SUBSTANCE (RQ-1000/454) Chromic sulfate is a dark green to violet solid. It is used in ceramics, as a pigment for paint, and in textile dyeing. It is soluble in water, it is non-combustible. it material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) II material not Involved In lire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates CHROMIC TRIOXIDE (See CHROMIC ACID, SOUO 4916510) CHROMIUM RESINATE (FLAMMABLE SOLID, N.O.S.) 4916765 FLAMMABLE SOLID UN1325 Chromium resinate is a green to violet amorphous powder. It may spontaneously heat in the presence of air or moisture. This heat may be sufficient to ignite surrounding combustible matenals. If material on fire or Involved in fire Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical if material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water CHROMIUM SULPHATE, BASIC, DRY (CHROMIC 4963317 SULFATE) ORM-E NA9100 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Chromium sulphate, basic, dry is a green solid. It is used in leather tanning. It is soluble in water. It is non<ombustible. April 1981 If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty. > If material not Involved in fire Keep matenal out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids witn a plastic sheet to prevent dissolving in ram or `ire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses ol pollutants ana precipitates CHROMOUS CHLORIOE 4963322 ORM-E NA91Q2 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Chromous chloride is a white crystalline solid. It is used to make other chemicals and as an oxygen absorbent. It is soluble in water It is non combustible. If material involved In fire Extinguish fire using agent suitable for type of surrounding lire (Material itself does not burn or burns with difficulty.) If material not involved In fire Keep matenal out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the oody with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheetto prevent dissolving in ram or lire fighting water Environmental considerations--watsr spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates CHROMYL CHLORIDE (OR) CHROMIUM 4930203 OXYCHLORIDE CORROSIVE MATERIAL. ACIDIC UNI 758 Chromyl chloride is a dark red colored fuming liquid with a pungent odor, li is decomposed by water to chromic add. hydrochloric acid, and some chlorine with release of heat. If material Involved in firs Extinguish lire using agent suitable for type of surrounding lire (Material itseif does not bum or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Continued on next peg* 00 129 ff material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on matenal itself Neutralize spilled material with crushed limestone, soda ash. or time Personnel protection Avoid dreaming vapors Keep upwind Wear self-contained Oreathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water It contact with the material anticipated, wear full protective clothing CIGARETTE LIGHTER 4905726 FLAMMABLE GAS UN1057 Cigarette lighter consists of a small device charged with a flammable gas. usually butane and equipped with an ignition device. The lighters continually leak very small amounts of gas and therefore may not be shipped m airtight containers. If material on fire or Involved in fire Use water m flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing vapors Keep upwind Approach fire with caution CIGARETTE LIGHTER 491042S FLAMMABLE LIQUID UNI226 Cigarette lighter is a small device containing a flammable liquid fuel in a reservoir with or without absorbent packing. The fuel has a flash point of less than 100 deg. F. It is lighter than water and insoluble in water The vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless How can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Wear boots, protective gloves, and goggles Do not hanaie broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water CIGARETTE LOADS 4903510 CLASS C EXPLOSIVE Cigarette load consist of wooden pegs to which are affixed a small amount of explosive composition. 130 If material on fire or Involved In fire Flood with water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Approach fire with caution Avoid Oreathing dusts, and fumes from burning matenal Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet CLEANING COMPOUND, IRON OR STEEL, LIQUID 4936516 (COMPOUND, CLEANING, LIQUID) CORROSIVE MATERIAL NA1760 Cleaning comoounds. iron or steel, nec. liquid are various colored liquids. They are water soluble and are corrosive to metals and-or tissue. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water m flooding quantities as fog Apply water from as far a distance as possible If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact wrtn the material anticipated, wear full protective clothing CLEANING COMPOUNDS. IRON OR STEEL, DRY 4936517 (CORROSIVE SOLID, N.O.S.) CORROSIVE MATERIAL UNI 759 Cleaning comoounds. iron or steel, dry are various colored solids. They are water soluble and are corrosive to metals and/or tissue. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Matenal itself does not bum or bums with difficulty.) Use water m flooding quantities as fog Apply water from as far a distance as possible If material not involved in fire Keep matenal out of water sources and sewers Personnel protection Avoid bodily contact with the material Wear boots protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing COAL BRIQUETTE BINDER (COMBUSTIBLE LIQUID, 4915510 N.O.S.) COMBUSTIBLE LIQUID NA1993 Coal briquette binder is a dark colored liquid with a petroleum like odor. It has a flash point between 100 and 199 deg. F. It is generally heavier than water and insoluble in water. Its vapors are heavier than air April 1981 MOD 000009873 It material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks. flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COAL BRIQUETTE BINOER (FLAMMABLE LIQUID, 4910510 N.O.S.) FLAMMABLE LIQUID UN1993 Coal briquette binder is a dark colored liQuid with a petroleum like odor It has a flash point of less than 100 deg. F. it is generally heavier than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COAL SPRAYING OIL, PETROLEUM (PETROLEUM 4910361 OIL, N.O.S.) FLAMMABLE LIQUIO NA1270 Coal spraying oil. petroleum is a dark colored liquid with a charac teristic odor. It has a flash point of less than 100 deg. F. It is generally lighter than water and is insoluble in water, its vapors are heavier than air if material on fire or Involved In fire Do not extinguish fire unless flow can be stooped Use water in flooding quantities as fog Solid streams of water may spread fire Coot all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors April 1981 Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COAL SPRAYING OIL. PETROLEUM (PETROLEUM 4915361 OIL. N.O.S.) COMBUSTIBLE LIQUID NA1993 Coal spraying oil. petroleum is a dark colored liquid with a charac teristic odor. It has a (lash point between 100 and 199 deg. F It is generally lighter than water and is insoluble in water, its vapors are heavier than air. II material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fira and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out ot water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Oo not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COAL TAR OIST1LLATE 4910133 FLAMMABLE LIQUID UN1136 Coal tar distillate is a clear colorless to dark brownish colored liquid with an aromatic odor. It has a flash point of less than 100 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on flra or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical tf material not on fira and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 131 MCD 000009874 COAL TAR DISTILLATE 4915133 COMBUSTIBLE LIQUIO UN1137 Coal tar distillate is a clear colorless to dark brownish colored liquid with an aromatic odor. It has a flash point between 100 and 199 deg. F It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved In fire Oo not extinguish fire unless flow can be stopped Use water m flooding quantities as tog Solid streams of water may spread fire Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use (oam. carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks. Names, and other sources ol ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted ihe body with copious amounts of water or soap and water COAL TAR DYE, LIQUIO 4936510 CORROSIVE MATERIAL NA2801 Coal lar dye. liquid are various colored liquids or solutions of solids. They are combustible though it may require some effort to ignite them. They are corrosive to metals and or tissue. If material on fire or involved in fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Bund dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear bools, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing COAL TAR FIBRE SATURANT LIQUIO (FLAMMABLE 4910511 LIQUID, N O.S.) FLAMMABLE LIQUIO UN1993 Coal tar fiber saturant liquid is a dark colored liquid. It has a flash oomt of less than 100 deg. F. It is generally heavier than water and insoluble m water. Its vapors are heavier than air. if material on fire or Involved in fire Do not extinguish (ire unless flow can be stopped Use water m flooding quantities as log Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical 132 If material not on fire and not involved in fire Keep sparks. Karnes, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COAL TAR FIBRE SATURANT, LIQUID 4915511 (COMBUSTIBLE LIQUID, N.O.S.) COMBUSTIBLE LIQUID NA1993 Coal tar fibre saturant. liquid is a dark colored liquid, it has a flash point between 100 and 199 deg. F. 11 is generally heavier than water and insoluble in water. Its vapors are heavier than air If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in Hooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts ol water or soap and water COAL TAR LIGHT OIL 4910134 FLAMMABLE LIQUID NA1136 Coal tar light oil is a dear colorless to dark brownish colored liquid with an aromatic odor, It has a flash point of less than 100 deg. F It is fighter than water and insoluble in water. Its vapors are heavier than air If material on fire or Involved in fire Oo not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use loam, carbon dioxide or dry chemical tf material not on Are end not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material oui of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Oo not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1981 000009875 MCD COAL TAR LIGHT OIL 4915134 COMBUSTIBLE LIQUIO NA1137 Coal tar light oil is a clear colorless to dark brownish colored liquid with an aromatic odor. It has a flash point between 100 and 199 deg F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or Involved In fire Do not extinguish fire unless flow can be stooped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possipie Use foam, carbon dioxide or dry chemical if material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COAL TAR LIGHT OIL (CRUDE LIGHT OIL OF COAL 4910135 TAR) FLAMMABLE LIQUIO NA1136 Coal tar light oil (crude light oil of coal tar) is a clear colorless to dark brownish colored liquid with an aromatic odor. It has a flash point of less than too deg. F. K is lighter than water and insoluble* in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish lire unless flow can be stopped Use water m flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks. Names, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COAL TAR LIGHT OIL (CRUDE LIGHT OIL OF COAL 4915135 TAR) COMBUSTIBLE LIQUID NA1137 Coal tar light oh (crude light oil of coal tar) is a clear colorless to darn brownish colored liquid with an aromatic odor. It has a flash point be tween 100 and 199 deg F. It is lighter chan water and insoluble in water Its vaoors are heavier than air If material on lire or involved in fire Do not extinguish lire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water April 1981 Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COAL TAR NAPHTHA 4910136 FLAMMABLE LIQUID NA2S53 Coal tar naphtha is a dear coioness to dark brownish colored liquid with an aromatic odor, u has a flash point of less than 100 deg F. It is lighter than water and insoluble in water. Its vapors are heavier than air If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid stream's of water may spread fire Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain (low as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COAL TAR NAPHTHA 4915136 COMBUSTIBLE LIQUIO NA2553 Coal tar naphtha is a clear colorless to dark brownish colored liquid with an aromatic odor. It has a flash point between 100 and 199 deg. F. It is lighter than water and insoluble in water. It vapors are heavier than air. if material on fire or involved in fire Do not extinguish tire unless flow can be slopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical if materiel not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 133 MOD 000009876 COAL TAR NAPHTHA (COAL TAR NAPHTHA, CRUDE) 910137 FLAMMABLE L1QUIO NA25S3 Coal tar naphtha, crude is a clear colorless to dark brownish colored liquid with an aromatic odor, it has a flash point of less than 100 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or Involved in fire Do net extinguish fire unless How can be stopped Use water m flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with Hooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COAL TAR NAPHTHA (COAL TAR NAPHTHA, CRUDE) 4915137 COMBUSTIBLE LIQUID NA2553 Coal tar naphtha, crude is a clear colorless to dark brownish colored liquid with an aromatic odor. It has a flash point between 100 and 199 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COAL TAR NAPHTHA AND LIGHT OIL OF COAL TAR, 4915512 CRUDE (COMBUSTIBLE LIOUIO, N.O.S.) COMBUSTIBLE LIQUID NA1993 Coal tar naphtha and light oil of coal tar, crude is a dear colorless to dark colored liquid with a petroleum like odor. It has a flash point between 100 and 199 deg. F. It is lighter than water and insoluble m water. Its vapors are heavier than air. H material on fire or involved in fire Do not extinguish lire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical 134 If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwmd Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COAL TAR NAPHTHA AND LIGHT OIL OF COAL TAR, 4910512 CRUDE (FLAMMABLE LIQUID, N.O.S.) FLAMMABLE LIQUID UN1993 Coal tar naphtha and light oil of coal tar. crude is a clear colorless to dark colored liquid with a petroleum like odor, it has a flash point of less than 100 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams' of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If materiel not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak it without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COAL TAR OIL 4910138 FLAMMABLE UQUIO NA1136 Coal tar oil is a dear colorless to dark brownish colored liquid with an aromatic odor. It has a Hash point of less than 100 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry cnemical H material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1981 MCD 000009877 COAL TAR OIL 4015138 COMBUSTIBLE LIQUID NA1137 Coal tar oil is a clear colorless to dark brownish colored liquid with an nromatic odor, it has a flash point between i00 and 199 deg. F. it is ighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stooped Use water m Hooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding Quantities of water Apply water from as far a distance as possible Use loam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources Of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COAL TAR OIL (COAL TAR OIL. CRUDE. NEC) 4910139 FLAMMABLE LIQUID NA1136 Coal tar oil. crude, nec is a clear colorless to dark brownish colored liquid with an aromatic odor, tt has a flash point of less than 100 deg. F it is lighter than water and insoluble m water, its vapors are heavier than air. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as tar a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COAL TAR OIL (COAL TAR OIL. CRUDE, NEC) 4915139 COMBUSTIBLE LIQUID NA1137 Coal tar. oil. crude, nec is a clear colorless to dark brownish colored liquid with an aromatic odor It has a flash point between 100 ana 199 aeg F. U is lighter than water and insoluble m water. Its vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical April 1961 MCD 000009878 If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts ol water or soap and water COAL TAR OIL. CRUDE. NEC (CORROSIVE LIQUID. 4931412 N.O.S.) CORROSIVE MATERIAL. ACIDIC UN1760 Coal tar oil. crude, nec. is a dark colored liquid with a creosote odor It is combustible though it may take some effort to ignite, it is lighter than water and is partially soluble in water. It is corrosive to tissue. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams oi water may be ineffective Cool all affected containers with flooding Quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Use water spray to absorb vapors If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matena! which may have contacted the oody with copious amounts of water or soap and water If contact with the maienal anticipated, wear full protective clothing COAL TAR OIL CRUDE, NEC (CORROSIVE SOLID. 4931413 N.O.S.) CORROSIVE MATERIAL ACIDIC UN1759 Coal tar oil. crude, nec. is a dark colored solid with a creosote odor It is combustible. It is heavier than water and is partially soluble in water It is corrosive to tissue. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams ot water may be ineffective Cool all affected containers with flooding quantities of water Aopty water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Use water spray to absorb vapors If materiel not on fire and not involved in fire Keep sparks, flames, and other sources ot ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spitted material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water H contact with the material anticipated, wear full protective clothing 135 COAL TREATING COMPOUNDS, OTHER THAN 4915330 PETROLEUM. NEC. LIQUID (COMBUSTIBLE LIQUID) COMBUSTIBLE LIQUID NA1993 Coal treating compounds, other than petroleum, nec. liquid are vari able colored liquids. They have a flash point between 100 and 199 deg. F They are generally insoluble in water and heavier than water. Their vapors are heavier than air If material on fire or involved in fire Do not extinguish fire unless flow can be slopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry cnermcal If material not on fire and not involved in fire Keep sparks, flames, and other sources o< ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COAL TREATING COMPOUNDS. OTHER THAN 4910330 PETROLEUM, NEC. LIQUID (FLAMMABLE LIQUfO. NOS.) FLAMMABLE LIQUfO UN1993 Coal treating compounds, other than petroleum, nec. liquid are vari able colored liquids. They have a flash point of less than 100 deg. F They are generally insoluble in water and heavier than water. Their vapors are heavier than air. ff material on fire or involved in fire Do not extinguish tire unless Mow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COAL. GROUNO BITUMINOUS. SEA COAL. COAL 4917307 FACINGS. ETC. FLAMMABLE SOLID NA1361 Coal, ground bituminous is powdered coal. M must be stored for si* days after grinding, else it must be shipped in tight metal containers or cars if not stored it is iiapie to spontaneous heating and ignition. If material on fire or involved In fire Use dry chemical or carbon dioxide Use water only if Hooding quantities are available tf material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material dry 136 COATING SOLUTION 4910142 FLAMMA8LE LIQUID UN1139 Coating solution is a solution of vanous gums and resins in various solvents. The liquids are generally quite thick and may range from clear colorless to black "tar". The flash point depends on the solvent used but ft will be less than 100 deg. F. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in Hooding quantities as tog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical if material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts of water or soap and water COBALT RESINATE. PRECIPITATED 4916705 FLAMMABLE SOLID UNI 318 Cobalt resmate, precipitated is a reddish brown powder, it is used a drier m paints. If it comes in contact with air. spontaneous heating may result. This heat may be sufficient to ignite the material itself or sur rounding combustible material. It is insoluble in water. It material on fire or involved in fire Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical if material not on fire and not Involved in fire Keep sparks, flames, and Pther sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COBALTOUS BROMIOE 4963710 ORM-E NA9103 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Cobaitous bromide is a red violet crystalline solid. It is used as a catalyst in the production of other chemicals. It is soluble in water. It is non-combustible, tf material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) tf material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Oig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or lire fighting water April 1981 mod 000009379 Environmental considerations--water spill Neutralize witti agricultural lime (siaked lime), crushed limestone. or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates COBALTOUS FORMATE 4963327 ORM-E NA9104 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000 454) Cobaitous formate is a red crystalline solid. It is used 10 make catalysts for use m chemical manufacture. It is soluble m water It is non combustible. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain hQuid or solid material Cover solids with a plastic sheet to prevent dissolving m ram or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates COBALTOUS SULFAMATE 4963329 ORM-E NA9105 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-IOOO/454) Cobaitous sultamate is a. It is used for electroplating metals. II is soluble m water. It is non-combustible. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) if material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving m ram or tire fighting water Environmental considerations--water spill Add calcium hypochlorite Neutralize with agricultural lime (slaked Ume). crushed limestone. or sodium bicarbonate Ad|ust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates April 1981 COCCULUS. SOLID 4921418 POISON B UN1584 Coccuius. solid is a dried fruit. It is toxic by ingestion. If material on fire or involved in fire Extinguish fire using agent suitable for type o< surrounding (ire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material rot involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear bools, protective gloves, anc goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soao and water Wear self-contained breathing apparatus when fighting tires involv ing this material If contact with the material anticioated. wear full protective clothing COCOA BEAN SHELLS, (FLAMMABLE SOLID, N.O.S.) 4917387 FLAMMABLE SOUO UN132S Cocoa bean shells are in the form of brown leaves'' or "flakes" H the shells are not cooled after processing, or dried too much, or appre ciable oil is left behind in processing, they are liable to spontaneous heat mg and ignition. If material on fire or involved in fire Flood with water If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away COLLIDIENE (COMBUSTIBLE LIQUID, N.O.S.) 4913173 COMBUSTIBLE LIQUID NA1993 Collidiene is a clear colorless liquid, it is used to make other chemicals. It has a flash point of 135 deg. F. It is lighter than water and insoluble m water. Its vapors are heavier than air. Toxic oxides ol nitrogen are produced during combustion of this material. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the maienal Wear boots, protective gloves, ana goggles Do not handle broken packages wunout protective equipment Wash away any maiena' which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when lighting fires involv ing this material If contact with the matenal anticipated, wear full protective clothing 000009880 MOD 137 COLLODION 4910144 FLAMMABLE LIQUID NA2059 Collodion is a solution of nitrocellulose in a mixture of ether and ethyl alcohol. Its flash point may vary but it is well below 100 deg. F. The film deposited by the evaporation of the solvent is easily ignited and once ignited burns with great rapidity. If the fire is confined, and large quantities of material are involved, an explosion may result. If material on fire or involved in fire Oo not extinguish fire unless flow can be stopped Use water m flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep matena! out of water sources and sewers Build dikes to contain flow as necessary Use water soray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Oo not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material COMBUSTIBLE LIQUID, N.O.S. 49151SS COMBUSTIBLE LIQUID NA1993 Combustible liquid, n.o.s. is the proper shipping name lor those ma terials having a closed cup flash point between 100 and 199 deg. F. and not specifically mentioned in the hazardous materials regulations. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with Hooding quantities of water Apply water from as `ar a distance as possible Use `'alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contair flow as necessary Use water spray to knock-down vapors Peraonnal protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Do not handle broken packages without protective equipment Wash away any maienal which may have contacted the body with copious amounts of water or soap and water Wear self-contained oreathing apparatus when fighting tires involv ing this material If contact with the material anticipated, wear lull protective clothing COMBINATION FUZE 4903205 CLASS C EXPLOSIVE Combination fuze is a device used for detonating the bursting charge of a proiectile. It has both a percussion mechanism and a time delay mechanism. If material on fire or involved in fire Flood with water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable---evacuate for a radius of 1500 feet COMBINATION PRIMER 4903210 CLASS C EXPLOSIVE Combination pnmer is a device employing both a percussion element and an electrical element either of which can be used to make the device function. If material on fire or involved in fire Flood wrth water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Apqroach fire with caution Avoid breathing dusts, and tumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If lire becomes uncontrollable--evacuate for a radius of 1500 feet 138 COMMON FIREWORKS 4903S20 CLASS C EXPLOSIVE Common fireworks are Fireworks devices suitable for use by the public and designed primarily to produce visible effects by combustion. Some small devices designed to produce audible effects are also included m this description. If material on fire or involved in fire Flood with water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet COMPOUND, CLEANING. LIQUIO 4936515 CORROSIVE MATERIAL NA1760 Compound, cleaning, liquid is a vanable colored liquid. The compound is generally water soluble. It is corrosive to metals and or tissue H material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as tog Apply water from as far a distance as possible H material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary April 1901 MCD 000009881 Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Oo not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material if contact with the material anticipated, wear full protective clothing COMPOUND, CLEANING. LIQUID 4910147 FLAMMABLE LIQUIO NA1993 Compound, cleaning, liquid is a variable colored liquid with a petro leumlike odor. Its has a flash point of less than 100 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If materiel on fire or involved in fire Do not extinguish fire unless (low can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COMPOUND, CLEANING. LIQUID 4915147 COMBUSTIBLE LIQUID NA1993 Compound, cleaning, liquid is a variable colored liquid with a petro leum like odor. It has a Hash point between 100 and 199 deg. F. ft is lighter than water and insoluble in water, its vapors are heavier than air. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical ff material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1981 MOD 00009882 COMPOUNO, CLEANING, LIQUIO (CONTAINING 4930209 HYDROCHLORIC (MURIATIC) ACID) CORROSIVE MATERIAL, ACIDIC NA1789 Compound, cleaning, liquid (containing hydrochloric (muriatic) acid) are various colored liquids with a pungent odor, it is soluble in water with release of some heat. It is corrosive to metals and/or tissue. If material on fire or Involved In fire Do not use water on material itself Extinguish fire using agent suitable for type of surrounding tire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as log Use foam, carbon dioxide or dry chemical Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with' the material anticipated, wear full protective clothing COMPOUNO, CLEANING, LIQUID (CONTAINING 4930210 HYDROFLUORIC ACID) CORROSIVE MATERIAL, ACIOIC NA1790 Compound, cleaning, liquid (containing hydrofluoric acid) are various colored liquids with a pungent odor. They are soluble in water with the release of some heat. They are corrosive to metals and or tissue. Skin contact with fumes or small quantities of material for short periods of time car cause severe painful bums. If materiel on fire or Involved In fire Do not use water on material itself Extinguish fire using agent suitable for type of surrounding (ire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on ffra and not Involved in fire Keep material out of water sources and sewers Buik) dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective dothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COMPOUND, CLEANING. LIQUIO (CONTAINING 4936520 PHOSPHORIC OR ACETIC ACIDS) CORROSIVE MATERIAL. ACIOIC NA1760 Compound, cleaning, liquid (containing phosphoric or acetic acids) are various colored liquids, generally odorless if containing phosphoric acid and having a vinegar like odor, it containing acetic acid. They are soluble in water with evolution of heat. They are corrosive to metals and tissue. Continued on next page 139 tf material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as tog Apply water from as far a distance as possible If material not fnvofved In fire Keep material out of waJer sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing COMPOUND, CLEANING, LIQUID (CONTAINING 4936521 SODIUM OR POTASSIUM HYDROXIDE) CORROSIVE MATERIAL, BASIC NA1760 Compound, cleaning, liquid (containing sodium or potassium hydrox ide) are various colored liquids. They are soluble in water with evolution of heat. They are corrosive to metals and tissue. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Apply water from as far a distance as possible ff material not involved in fire Keep material out of water sources and sewers Build dikes to contain How as necessary Personnel protection Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the matenal anticipated, wear full protective clothing COMPOUND. ENAMEL 4910150 FLAMMABLE LIQUID NA1263 Compound, enamel is a variable colored 'paint'' like liquid. It has a flash point of less than 100 deg. F. it is usually lighter than water and is insoluble in water. Its vapors are heavrer than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use ' alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 140 COMPOUND, LACQUER, PAINT OR VARNISH REMOVING LIOUIO 4936535 CORROSIVE MATERIAL, BASIC. COMBUSTIBLE NA1760 Compounds, lacquer, paint or varnish removing liquid are various colored materials. They are corrosive to metals and'or tissue. If material on fire or Involved in fire Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use "alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing COMPOUND, LACQUER, PAINT, OR VARNISH. 4915153 REMOVING, REOUCING OR THINNING COMBUSTIBLE LIQUID NA1142 Compound, lacquer, paint, or varnish, removing, reducing or thinning are generally clear colorless liquids Their flash point is between 100 and 199 deg. F. Most of these compounds are lighter than water and insoluble in water. Their vapors are heavier than air. If material on Are or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical tf material not on Are and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts of water or soap and water COMPOUNO. LACQUER. PAINT. OR VARNISH. 49101S3 REMOVING, REOUCING OR THINNING. FLAMMABLE UQUIO NA1142 Compound, lacquer, paint, or varnish, removing, reducing or thinning are generally dear colorless liquids. Their flash point is less than 100 deg. F. Most of these compounds are lighter than water and insoluble in water. Their vapors are heavier than air. April 1981 MOD 000009883 if material on fire or Involved In fire Do not extinguish tire unless flow can be stopoed Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keeo sparks, flames, and other sources of ignition away Keep material out ol water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COMPOUND, POLISHING. LJQUIO 4910155 FLAMMABLE LIQUID NA1142 Compound, polishing, liquid is usually a variable colored liquid con taining an undissolved solid. It has a flash point of less than 100 deg. F. It is lighter than water and generally insoluble in water. Its vapors are heavier than air. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical tf material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COMPOUNO, TREE (OR) WEEO KILLING. UQUID 4936532 CORROSIVE MATERIAL NA1760 Compound, tree (or) weed killing, liquid is a variable colored liquid. It may eiiher be a solution of solid material in a liquid or a simple liquid or mixture of liquids. It may be combustible though requiring some effort to ignite, ft is usually soluble in water. It is corrosive to metals and or tissue. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities ol water Apply water from as far a distance as possible Solid streams of water may be ineffective Use alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticioated. wear full protective clothing COMPOUND. TREE OR WEED KILLING. LIQUID 4910157 FLAMMABLE LIQUIO NA1993 Compound, tree or weed killing, liquid is a variable colored liquid H has a flash point of less than 100 deg. F most of these materials are lighter than water. Its vapors are heavier than air If material on fire or involved in fire Do not extinguish fire unless flow can be stooped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding Quantities of water Apply water from as tar a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain (low as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COMPOUND, TREE OR WEED KILLING. LIQUID 4915157 COMBUSTIBLE UQUID NA1993 Compound, tree or weed killing, liquid is a variable colored liQuid. it has a flash point between 100 and 199 deg. F. Most of these materials are lighter than water. Its vapors are heavier than air. It material on tire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing April 1981 000009884 MCT> 141 COMPOUND. TREE OR WEED KILLINGS. SOLIO 4918405 OXIDIZER NA1479 Compound, tree or weed killing, solid are various solid materials. They may or may not burn. Out it mixed with combustible materials they will accelerate their burning Prolonged exposure of these materials and or (heir containers to fire or heat may result in an explosion. If material on fire or Involved In fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources o< ignition away Keep material oul of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Oo not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Approach fire with caution Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet COMPOUND. VULCANIZING. LIOUIO 4910162 FLAMMABLE LIQUID NA1142 Compound, vulcanizing, liquid is a variable colored liquid, it has a flash point of less than 100 deg. F. The hazard of this material is flammability. If material on fire or Involved in fire Oo not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities ol water Apply water from as far a distance as possible Use alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COMPOUNO, VULCANIZING, LIQUID 4938534 CORROSIVE MATERIAL NA1760 Compound, vulcanizing, liquid are various colored materials. They are corrosive to metals and/or tissue. If material on fire or involved In fire Use water in flooding quantities as fog Cool all aflected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use alcohol ' foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, (fames, and other sources of ignition away Keep matenai out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material 142 Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounis of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing COMPOUNDS CAULKING OR GLAZING 49154S0 (COMBUSTIBLE LIQUID. N.O.S.) COMBUSTIBLE LIQUID NA1993 Compounds caulking or glazing are materials containing a solvent having a closed cup flash point between 100 and 199 deg. F. The hazard of these materials is combustibility. If material on fire or involved in fire Do not extinguish lire unless Mow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as passible Use alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep matenai out of water sources and sewers Build dikes to contain (low as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenai which may have contacted the body with copious amounts of water or soap and water COMPOUNDS CAULKING OR GLAZING (FLAMMABLE 4910450 LIQUIO, N.O.S.) FLAMMABLE LIQUIO UN1993 Compounds caulking or glazing are materials containing a solvent having a closed cup Hash point of less than 100 deg F. The hazard of these materials is flammability. If material on fire or involved in fire Oo not extinguish tire unless Mow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Coof all affected containers with Hooding quantities of water Apply water from as far a distance as possible Use "alcohol" loam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenai which may have contacted the body with copious amounts of water or soap and water COMPOUNDS GAS PURIFYING (FLAMMABLE SOLID, 4917396 N.O.S.) FLAMMABLE SOLID UN1325 Compounds gas purifying are various colored solid materials having the property of being readily ignited by external sparks or flame and when so ignited bums vigorously and persistently. April 1981 MCD 000009885 If material on fire or Involved In fire Flood with water If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Build dikes to contain flow as necessary Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Avoid breathing dusts, and fumes from burning material COMPOUNDS METAL PURIFYING, NEC (POISONOUS 4923390 SOLID, N.O.S.) POISON B NA2B11 Compounds metal purifying are various colored solid materials. They may or may not be water soluble. They are toxic by ingestion, inhalation (dusts), or by skin absorption. If material Involved in fire Extinguish fire using agent suitable For type oi surrounding lire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as tog Use foam, carbon dioxide or dry chemical if material not involved In fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing COMPOUNDS, CASE CARBURIZING OR HARDENING. 4923391 NEC (POISONOUS SOLIO. N.O.S.) POISON B NA2811 Compounds, case.carburizing or hardening, nec are vanous colored solids frequently containing some cyanide. The material is toxic by inges tion. Cyanides are decomposed by acids giving off hydrogen cyanide a flammable poison gas. Cyanides are also toxic by skin absorption through open wounds and by inhalation of the hydrogen cyanide from decomposition. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved In fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid oodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing April 1981 COMPOUNDS, CASE HARDENING OR CARBURIZING. 4923392 CHARCOAL. COAL OR COKE BASE (POISONOUS SOUD, N.O.S.) POISON B NA2811 Compounds, case hardening or carburizing, charcoal, coal or coke base are black solids frequently containing some cyanide. The matenal is toxic by ingestion. Cyanides are decomposed by acids giving off hydrogen cyanide a flammable poison gas. Cyanides are also toxic by skin absorption through ooen wounds, and by inhalation of hydrogen cyanide from the decomposition of the material. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Matenal itself does not burn or burns with difficulty.) Use water m flooding quantities as fog Use foam, carbon oioxide or dry chemical If material not involved In fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning matenal Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the matenal anticipated, wear full protective clothing COMPOUNDS. HECTOGRAPH (COMBUSTIBLE 4915470 LIQUID, N.O.S.) COMBUSTI8LE LIQUID NA1993 Compounds, hectograph are materials containing a solvent having a closed cup flash point between 100 and 199 deg. F. The hazard of these materials is combustibility, if material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COMPOUNDS. HECTOGRAPH (FLAMMABLE LIQUID. 4910470 N.O.S.) FLAMMABLE LIQUID UN1993 Compounds, hectograon are materials containing a solvent having a closed cup flash point of less than 100 deg, F. The hazard of these materials is flammability Continued on next page 143 MCD 000009886 If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use ' alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources ana sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COMPOUNDS, IRON OR STEEL RUST PREVENTING. OTHER THAN PETROLEUM, NEC (RUST 4915184 PREVENTIVE COATING) COMBUSTIBLE LIQUID NA1142 Compounds, iron or steel rust preventing other than petroleum, nec are thick variable colored liquids having an odor ol paint. They have a flash point between 100 and 199 deg. F. They are insoluble in water and are heavier than water. Their vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water m flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out ot water sources and sewers Build dikes to contain (low as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COMPOUNDS. LEATHER FINISHING. NEC 4915472 (COMBUSTIBLE UOUIO, N.O.S.) COMBUSTIBLE LIQUID NA1993 Compounds, leather finishing, nec is a material containing a solvent having a closed cup flash point between 100 and 199 deg. F. The hazard of this material is combustibility. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water m flooding quantities as fog Solid streams of water may be ineffective Cool a affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire end not Involved in fire Keep sparks, dames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors 144 Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathrng apparatus when fighting fires involv ing this material COMPOUNDS, LEATHER FINISHING. NEC 4910472 (FLAMMABLE LIQUID. N.O.S.) FLAMMABLE LIQUIO UN1993 Compounds, leather finishing, nec is a material containing a solvent having a closed cup flash point of less man tOO deg. F. The hazard of this material is flammablility. II material on lire or involved in fire Do not extinguish fire unless How can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain (low as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COMPOUNDS. PETROLEUM TREATING, CRUDE. NEC 4936563 (ACID, LIQUID. N.O.S.) CORROSIVE MATERIAL UN1760 Compounds, petroleum treating, crude, nec are various colored liq uids. They are corrosive to metals and tissue. They may burn though it may require some effort to ignite. K material on fire or involved in fire Use water in flooding quantities as fog Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use alcohol" foam, carbon dioxide or dry chemical tf material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soao and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing April 1961 MCD 000009887 COMPOUNDS. PETROLEUM TREATING, CRUDE, NEC 4910349 (FLAMMABLE UQUIO, N.O.S.) FLAMMABLE LIQUID UNI 993 Compounds, petroleum treating, crude, nec are various colored liq uids. They have a Hash point of less than 100 deg. F. They are generally lighter than water and soluble in water. Their vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use waler in flooding quantities as fog Solid streams ot water may be ineffective Cool all affected containers with Hooding quantities of water Apply water from as far a distance as possible Use alcohol" foam, carbon dioxide or dry chemical ff material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain (low as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COMPOUNDS, RUST PREVENTING (OR) COMPOUND 4936530 RUST REMOVING CORROSIVE MATERIAL NA1760 Compounds rust preventing or compound rust removing are various colored liquids. They are soluble in water with evolution of heat. They are corrosive to metals and tissue. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water m flooding quantities as fog Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Build dikes lo contain flow as necessary Personnel protection Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing COMPOUNDS. STONE STENCIL. IN SHEET FORM 4936571 (CORROSIVE SOLIO. N.O.S.) CORROSIVE MATERIAL UNI 759 Compounds, stone stencil in sheet form are various materials im pregnated m paper or cloth. These compounds have the property of bemg corrosive to tissue They may or may not be water soluble. The sheets may be combustible. If material on fire or involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog April 1961 fiCQ 000o9eee ff material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts ot water or soap and water COMPOUNDS, TREE OR WEED KILLING. LIQUID 4921419 POISON B NA2810 Compound, tree or weed killing. Iiauid are various materials or solu tions that have the property of being toxic by ingestion, inhalation or skin absorption. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol foam, carbon dioxide or dry chemical Use water spray to absorb vapors If material not on fira and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COMPOUNDS. WALL OR WALL PAPER CLEANING 4910414 (COMPOUNO. CLEANING, LIQUID) FLAMMABLE UQUIO NA1993 Compounds, wall or wall paper cleaning contain a flammable liquid. The flash point is less than 100 deg. F. The hazard is flammability. If material on fire or involved in fire Do not extinguish lire unless How can be stopped Use water in flooding quantities as log Solid streams of water may be ineffective Cool all affected containers with Hooding quantities o< water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out ol water sources and sewers Build dikes lo contain How as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 145 COMPOUNDS. WALL OR WALL PAPER CLEANING 4915414 (COMPOUNO. CLEANING. LIQUID) COMBUSTIBLE LIQUID NA1993 Compounds, wall or wall paper cleaning contain a combustible liquid. The Hash point is between 100 and 199 deg. F. The hazard is combustibility. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with Hooding quantities of water Apply water from as far a distance as possible Use alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COMPOUNDS. WATER SYSTEM RUST OR SCALE 4936546 PREVENTING. DRY (CORROSIVE SOLIO, N.O.S.) CORROSIVE MATERIAL UN1759 Compounds, water system rust or scale preventing, dry are various colored solid materials. They are water soluble. They are corrosive to tissue. If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as tog Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing COMPRESSED GAS. N.O.S. 4905710 FLAMMABLE GAS UN1954 Compressed gases, n.o.s. are materials which are shipped in con tainers under pressure. They may be mixtures of flammable and non flammable gases. With the mixture having flammable properties. The gas is easily ignited. The mixture may separate with the flammable gas settling tn low areas, or the nonflammable gas settling in low areas. It may only be shipped m cylinders. A flame may flash back to the source of leak very easily Under fire conditions the cylinders may violently rupture and rocket. If the cylinder is an aerosol it will violently rupture under fire conditions. If material on fire or Involved in fire Oo not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible 146 If materiel not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered COMPRESSED GAS. N.O.S. 4904515 NONFLAMMABLE GAS UN1956 Compressed gases, n.o.s. are materials which are shipped in con tainers under pressure. They may be mixtures consisting of a nonflamm able gas(es) and a flammable gas(es) with the mixture having nonflamm able properties. The mixture may separate with the flammable gas settling in low areas, or the nonflammable gassettling into low areas It may asphyxiate by the displacement of air. It may only be shipped in cylinders. H the cylinder is an aerosol container, it can rupture and rocket under fire conditions. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Do not use water on material itself Use water spray to absorb vapors W material not involved in fire Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered COPPER ACETATE (VERDIGRIS) (CUPRIC ACETATE) 4962310 ORM-E NA9106 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100/45.4) Copper acetate is a blueish greenish crystalline solid, ft is used as an insecticide, in the preparation of other chemicals, as a fungicide, and mildew preventive, it is soluble in water, it is non-combustible. If material Involved In Are Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary April 1981 Oo 09aa9 Personnel protection Keep upwind Wear bools, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agncuitural lime {slaked lime), crushed limestone, or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates COPPER ACETOARSENITE, SOLID 4923220 POISON 8 UN1585 ENVIRONMENTALLY HAZAROOUS SUBSTANCE (RQ-100 45.4) Copper acetoarsemte. solid is an emerald-green powder. It is insoluble in water. It is toxic by inhalation (dust) and by ingestion. If material Involved in fire Extinguish fire using agent suitable for type Of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as log Use foam, carbon dioxide or dry chemical If material not Involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when lighting fires involv ing this material It contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or lire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates COPPER ARSENITE, SOLID 4923221 POISON B UN1S86 Copper arsemte. solid is a light green powder. It is insoluble in water It is toxic by ingestion. If material involved in fire Extinguish tire using agent suitable for type ol surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind April f981 MCD 000009890 Avoid bodily contact with the matenal Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting Fires involv ing this material If contact with the material anticipated, wear lull protective clothing COPPER BASED PESTICIDE. LIQUID. N.O.S. 4923331 (COMPOUNDS AND PREPARATIONS) (INSECTICIDES, OTHER THAN AGRICULTURAL. NEC) POISON B UN2775 Copper based pesticide is a liquid or solid dissolved m a liquid carrier. The earner is water emulsifiable. The carrier may burn though it may require some effon to ignite. It is toxic by inhalation, skin absorption, and or ingestion. In case Of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone; 800- 424-9300. If material Involved in fire Extinguish fire using agent suitable For type of surrounding Fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COPPER BASED PESTICIDE. LIQUID, N.O.S. 4923332 (COMPOUNDS AN0 PREPARATIONS) (AGRICULTURAL INSECTICIDES, NEC, LIQUID) POISON B UN2775 Copper based pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emulsifiable. The carrier may bum though it may require some effort to ignite. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to. or leaking from containers of this matenal contact the pesticide safety team network. Telephone; 000- 424-9300. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use toam, carbon dioxide or dry chemical If material not involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 147 COPPER BASED PESTICIDE. LIQUID, N.O.S. 4910506 (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES, NEC, LIQUID) FLAMMABLE LIQUID UN2776 Cooper based pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emulsifiable. The primary ha2ard of this material is the flammability of the carrier. It has a flash point below 100 deg. F. It can cause illness by inhalation, skin absorption and or ingestion. In case of damage to, or leaking from containers of this maierial contact the pesticide safely team network Telephone: 800-424-9300. If material on fire or involved in fire Do not extinguish fire unless flow can be stooped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use 'alcohol foam, carbon dioxide or dry chemical II material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wear self-contained breathing apparatus when fighting fires involv ing this material COPPER BASED PESTICIDE, SOLID. N.O.S. (COMPOUNDS AND PREPARATIONS) 4923334 (AGRICULTURAL INSECTICIDES, NEC, OTHER THAN L1QUIO) POISON B UN277L Copper based pesticide is a solid or a liquid aDsorbed on a dry earner. It is a wettabie powder. It is toxic by inhalation, skin absorption, and or ingestion. In case of damage to. or leaking from containers of this ma terial contact the pesticide safety team network. Telephone: 800-424- 9300. If material on fire or Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with . copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting tires involv ing this material If contact with the material anticipated, wear full protective clothing COPPER BASED PESTICIDE. LIQUID. N.O.S. 4910505 (COMPOUNDS ANO PREPARATIONS) (INSECTICIDES. OTHER THAN AGRICULTURAL, NEC) FLAMMABLE LIQUID UN2776 Copper based pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emulsifiable. The primary hazard of this material is the flammability of the carrier. It has a flash point below 100 deg. F. tt can cause illness by inhalation, skin absorption and or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone: 800-424-9300. If material on fire or involved In fire Oo not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol ' foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wear self-contained breathing apparatus when fighting fires involv ing this material 148 MCD 000009891 COPPER BASED PESTICIDE. SOLIO. N.O.S. 4923333 (COMPOUNDS AND PREPARATIONS) (INSECTICIOES, OTHER THAN AGRICULTURAL. NEC) POISON B UN277S Copper based pesticide is a solid or a liquid absorbed on a dry came It is a wettabie powder. It is toxic by inhalation, skin absorption, and o> ingestion. In case of damage to. or leaking from containers of this ma terial contact the pesticide safety team network. Telephone: 800-424- 9300. If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gioves. and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective doming COPPER CHLORIDE 4944173 ORM-B UN2802 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-10 4.54) Copper chloride is a yellowish brown powder or a green crystalline it is useto manufacture other chemicals, in dyeing, in printing, in fun gicides. as a wood preservative, and tor many other uses. It is soluble in water, ft is non-combustible. It is corrosive to aluminum. Apnl 1981 H material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap ana water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire lighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates COPPER CYANIDE 4923418 POISON B UN 1587 Copper cyanide is a green powder. It is insoluble in water. It is de composed by acids to give off hydrogen cyanide, a flammable poison gas. It is toxic by skin absorption through open wounds, by ingestion, and by inhalation of hydrogen cyanide from decomposition of the ma terial. Toxic oxides of nitrogen are produced in fires involving this material. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use foam, carbon dioxide or dry chemical Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors If material not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Use water spray to knock-down vapors Do not use water on material itself Personnel protection Avoid breathing vapors or dusts Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this matenal If contact with the material anticipated, wear full protective clothing COPPER NAPHTHANATE PETROLEUM SOLUTION. 4910S16 NOT MORE THAN B% COPPER NAPHTHANATE (FLAMMABLE LIQUID, N.O.S.) FLAMMABLE LIQUID UN1993 Copper naphthanate petroleum solution is a green colored liquid with a petroleum like odor. It has a flash point of less than 100 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air If material on fire or involved In fire Do not extinguish fire unless flow can be slopped Use water in flooding quantities as fog Solid streams of water may spread fire April 1961 CD 0009892 Cool all affected containers with flooding quantities of water Apply water from as tar a distance as possible Use alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid Dreathmg vapors Keep upwind Wear boots, protective gloves, and goggles Oo not handle broken packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts of water or soap and water COPPER NAPHTHANATE SOLUTION. NOT MORE 4915516 THAN 8% COPPER NAPHTHANATE (COMBUSTIBLE LIQUID, N.O.S.) COMBUSTIBLE LIQUID NA1993 Copper naphthanate solution is a green colored liquid with a petroleum like odor, it has a Hash point between 100 and 199 deg. F. It is lighter than water and insoluble m water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol ' foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COPPER NITRATE SOLUTION (CUPRIC NITRATE) 491874S OXIDIZER NAt 479 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100/4S.4) Copper nitrate solution is a blue crystalline solid dissolved >n water. It is used m medicine, as an insecticide, in chemical analysis, in making light sensitive papers, and for many other uses. It is noncombustible, but it will accelerate the burning ol combustible materials. If large quan tities of the material are involved or the material is finely divided, an explosion may result. Prolonged exposure to fire or heat may result m an explosion. Toxic oxices of nitrogen are produced in fires involving this material. If material on fire or involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as tar a distance as possible If matenal not on fire end not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Contlnutd on next page 149 Personnel protection Wear bools, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation if fire oecomes uncontrollable--evacuate for a radius of 2500 feet Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations---water spill Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Ad|ust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates COPPER RESINATE, (FLAMMABLE SOLID, N.O.S.) 4916762 FLAMMABLE SOLID UNI 325 Copper resinate is a green amorphous powder. It may spontaneously heat in the presence of air and moisture. This heat may be sufficient to ignite nearby combustible material. It is insoluble in water, if material on fire or involved in fire Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Wear boots, protective gfoves. and goggles Do not handle broken packages without protective equipment Wash away any material which, may have contacted the body with copious amounts of water or soap and water COPPER SULFATE AND UME COMBINEO, DRY 4961317 (CUPRIC SULFATE) ORM-E NA9109 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-IO/4.54) Pentachlorophenol is a white powder or crystalline solid or. fused in copper sulfate is blue and lime is white, it is used as an agricultural soil is slightly soluble in water, it is non-combustible. Is non-combustible. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) If material not involved in Are Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spilt Dig a pit. pond, lagoon, holding area lo contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water eplll Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of poilutants and precipitates 150 COPPER SULPHATE AND SULPHUR (CUPRIC SULFATE) 4961316 ORM-E NA9109 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-10 4.54) Copper sulphate and sulphur is a solid: copper sulfate is blue and sulfer is yellow. It is used as an agncultural fungicide. The copper sulfate is soluble in water sulphur is not soluble in water. It is non-combustible. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving m ram or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium- bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates COROEAU DETONANT FUSE 4903345 CLASS C EXPLOSIVE Cordeau detonant fuse is a fuse containing a core of pentaerythnte tetranitrate or cydotnmethy/ene-tnnitramine not exceeding 400 grains per linear foot, overspun with tapes, yams, plastics, or waterproofing compounds. tf material on fira or involved in fire Dangerously explosive Flood with water Apply water from as far a distance as possible If material not on fira and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation II lira becomes uncontrollable--evacuate for a radius of 1500 feet CORES OR CORE ASSEMBLIES OR FUEL BLANKET 4926445 ASSEMBUES, NUCLEAR REACTOR, NOT IRRADIATED, WITH NON4RRADIATED FUEL. (RADIOACTIVE MATERIAL, N.O.S.) RADIOACTIVE MATERIAL NA9161 Cores or core assemblies or fuel blanket assemblies, nuclear reactor, not irradiated, with non-irradialed fuel, are sealed metal tubes or tube assemblies containing the fuel. Radioactive materials emit certain rays that may be hazardous. These rays can be detected only by instruments. Exposure of humans to intense radiation may be harmful, whereas film may be damaged by radiation from refatrve/y low concentrations. April 1981 MCD 000009893 ff material on fire or involved In fire Contact the focal, state, or department ot energy radiological re sponse team Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved In fire Contact the local, state, or department of energy radiological re sponse team Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Keep upwind Avoid breathing fumes from burning material Wear full protective clothing Wear self-contained breathing apparatus Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation Keep unnecessary people out of incident area until area declared safe by radiological response team H material on Are or Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear bools, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing CORROSIVE LIQUID. N.O.S. 4936540 CORROSIVE MATERIAL UN1760 Corrosive liquid, n.o.s. is a liquid that can cause visible destruction or irreversible alterations in human skin tissue at the site ot contact, or in the case of leakage from its packaging a liquid that has a severe corrosion rate on steel. It may be combustible though it may require some effort to ignite. It may or may not be water soluble. If material on fire or Involved In fire Extinguish (ire using agent suitable for type ol surrounding fire (Material itself does not burn or bums with difficulty.) Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing CORROSIVE LIQUID. POISONOUS, N.O.S. 4936015 CORROSIVE MATER/AL.POISONOUS UN2922 Corrosive liquid, poisonous, n.o.s. Is a liquid that can cause visible destruction or irreversible alterations in human skin tissue at the site of contact, or in the case of leakage from its packaging a liquid that has a severe corrosion rate on steel, is is also toxic by ingestion, inhalation, or by skin absorption. It may be combustible though it may require some effort (o ignite, it may or may not be water soiubie. CORROSIVE SOLID. N.O.S. 4936S4S CORROSIVE MATERIAL UN17S9 Corrosive solid, n.o.s. is a variable colored material that can cause visible destruction or irreversible alteration in human skin tissue at the site of contact. It may be combustible though requiring some effort to ignite. It may or may not be water soiubie. H material on fire or Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog If material not on Are and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodify contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water A contact with the material anticipated, wear full protective clothing COSMETICS. N.O.S. 4917377 FLAMMABLE SOLID NA1325 Cosmetics, n.o.s. is the proper shipping name of any solid material, other than one classed as an explosive. or specificalfy listed by name in the list of hazardous materials which is liable under conditions incident to transportation to cause fires through fnction. absorption of moisture, spontaneous chemical changes as a result of retained heat from the manufacturing or processing of the solid, or which can be readily ignited by external sparks or flame and when so ignited bums vigorously and per sistently. Try to ascertain the exact name of the material. It material on fire or Involved In Art Extinguish Are using agent suitable for type of fire Continued on next page April 1981 MCD 000009894 151 If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Build dikes to contain How as necessary Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the matenal Wear boots, protective gloves, and goggles Oo not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COSMETICS, N.O.S. 4910411 OXIDIZER NA1479 Cosmetics, n.o.s. are various materials which have the property of accelerating the burning of combustible material. These materials may not burn by themselves. Prolonged exposure of these matenals and or their containers to fire or heat may result in an explosion. These materials may only be shipped in containers of 55 gallon capacity or less If material on fire or involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as tar a distance as possible If material not on fire and not involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts ol water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this matenal Approach fire with caution Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet COSMETICS, N.O.S. 4910192 FLAMMABLE LIQUID NA1993 Cosmetics, n.o.s. is the proper shipping name for those matenals having a closed cup flash point of less than too deg. F. and not spe cifically mentioned in the hazardous materials regulations. The hazard is flammability. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol' foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, names, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 152 COSMETICS. N.O.S. COMBUSTIBLE LIQUID 4915192 NA1993 Cosmetics, n.o.s. is the proper shipping name for those materials having a closed cup flash point between 100 and 199 deg. F. and not specifically mentioned in the hazardous matenals regulations. The haz ard is combustibility. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COSMETICS, N.O.S., LIQUID 4936551 CORROSIVE MATERIAL NA1760 Cosmetics, n.o.s.. liquid is the proper shipping name lor various col ored liquids having the property of being corrosive to steel or tissue. It may either be a simple liquid material or a solid matenal dissolved in a solvent It may be combustible though requiring some effort to ignite. They may or may not be water soluble. If material on fire or involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use alcohol'' loam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting tires involv ing this matenal If contact with the material anticipated, wear full protective clothing COSMETICS. N.O.S., SOLID 4936552 CORROSIVE MATERIAL NA1759 Cosmetics, n.o.s.. solid is the proper shipping name for various colored solids having the property of being corrosive to tissue. They may or may not be water soluble. April 1961 MCD 000009895 If material on fire or Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Use dry chemical, carbon dioxide, or dry sand Oo not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog If material not on fire and not Involved in fire Keep sparks, flames, and other sources o< ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Wear sell-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Oo not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing COTTON WASTE. OILY (WITH MORE THAN 5% 4917415 ANIMAL OR VEGETABLE OIL) FLAMMABLE SOLIO UN1364 Cotton waste, oily is material contaminated, coated or impregnated with animal or vegetable oil. It is liable to spontaneous heating and ignition. If material on fire or involved in fire Flood with water if material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away COUMAPHOS 4921505 POISON B NA2783 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-10/4.54) Coumaphos is white to light brown crystalline solid. II is combustible and is insoluble m water, it is toxic by ingestion, in case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone: 600-424-9300 If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not on fire and not involved in Are Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily coniact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Environmental conslderations--fand spill Dig a pit. pond, lagoon, holding area to contain liquid or solid matenal Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount m region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates COUMAPHOS MIXTURE, LIQUID (AGRICULTURAL INSECTIDES, NEC. LIQUID) 4921506 POISON B NA2783 ENVIRONMENTALLY HAZAROOUS SUBSTANCE (RQ-10/4.54) Coumaphos mixture, liquid is the white io light brown crystalline solid dissolved in a liquid carrier, it is combustible and is insoluble m water, it is toxic by ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone: 000-424-9300 tf material on fire or Involved in fire Extinguish tire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep matenal out o< water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts o( water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in ram or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap matenal at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates CREOSOTE. COAL TAR 4915363 COMBUSTIBLE LIOUIO NA1993 Creosote, coal tar is a yellowish to dark green colored liquid with a characteristic odor. It is used as a wood preservative and as a disin fectant. It has a flash point in the range of 120 to 180 deg. F, ft is heavier than water and insoluble in water. Its vapors are heavier than air. tf material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical if material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing April 1981 153 MCD 000009896 CRESOL 4931417 CORROSIVE MATERIAL. ACIDIC. COMBUSTIBLE UN2076 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RCMOOO'454) Cresylic acid is a colorless to yellow liquid with a tar-like odor, it ts combustible and has a flash point of 178 deg. F. It is insoluble in water. It IS corrosive to tissue. II weighs 8.7 pounds per gallon. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams o! water may be ineffective Cool all affected containers with Hooding quantities of water Apply water from as far a distance as possible Use alcohol' foam, carbon dioxide or dry chemical Use water spray to absorb vapors if material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash. cement powder, sawdust, or com mercial sorbents Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment CROTONALDEHYDE 4909137 FLAMMABLE LIQUID UN1143 POLYMERIZABLE ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100/45.4) Crotonaldehyde is a clear, colorless to straw colored liquid with a penetrating pungent odor. It has a flash point of 55 deg. F. If subject to heat it may polymerize. If polymerization takes place in a container the container may violently rupture, fl is lighter than water and slightly soluble m water, its vapors are heavier than air. It weighs 7.1 pounds per gallon. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing poofs of liquid 154 MCD 000009897 Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of waier or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cemeni powder Apply fluorocarbon-water foam to dimmish vapor and fire hazard Add sodium bisulfite (nahso3) Environmental considerations--water spill Use natural barriers or oil spill control booms to limit spill motion Use surface active agent (e.g. detergent, soaps, alcohols) to com press and thicken spilled material Inject "universal" gelling agent to solidify encircled spill and increase effectiveness of booms Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors CROTONICACID 4931418 CORROSIVE MATERIAL, ACIDIC, COMBUSTIBLE UN2823 Crotonic acid is a white crystalline solid. It is combustible and has a flash point of 190 deg. F. It is soluble in water. It is corrosive to metals and tissue. If material on fire or Involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical II material not on fire and not involved In fire Keep material out of water sources and sewers Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing CROTONYLENE 4909138 FLAMMABLE LIQUID UN1144 Crotonylene is a clear colorless liquid with a petroleum like odor. It has a flash point of less than -4 deg. F. and a boiling point of 51 deg. F. ft is lighter than water and insoluble in water. Its vapors are heavier than air. H material on fire or Involved In fire Do not extinguish lire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fira and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors April 1981 Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water CRUDE NITROGEN FERTILIZER SOLUTION (MORE 4904240 THAN 25.3 PSIG) NONFLAMMABLE GAS, CORROSIVE NA1043 Crude nitrogen fertilizer solution is the aqueous solution of nitrogen fertilizer charged with ammonia gas having an absolute pressure ex ceeding 40 psi at 70 deg. F. in the container, the solution is corrosive. Although ammonia is lighter than air. the vapors from a leak initially hug the ground. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use water spray to absorb vapors If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and gas tight goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Evacuation If material leaking (not on fire), downwind evacuation must be considered CRUDE OIL. PETROLEUM FLAMMABLE LIQUIO 4910165 UNI 267 Crude oil. petroleum is dark viscous liquid. It has a flash point of less than 100 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1981 ,0009898 tfCD 00 CRUDE OIL, PETROLEUM 4915165 COMBUSTIBLE LIQUIO UN1267 Crude oil. petroleum is a dark viscous liquid. It has a flash point between 100 and 199 deg. F. It is lighter than water and insoluble in water. Its vaoors are heavier than air. If material on fire or involved in fire Do nol extinguish lire unless llow can be stopped Use water m flooding quantities as fog Solid streams of water may spread tire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep matenal out ot water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water CUMENE (COMBUSTIBLE LIQUIO, N.O.S.) 4913125 COMBUSTIBLE LIQUIO NA1993 Cumene is a clear colorless liquid with an aromatic odor. It has a flash point of 111 deg. F. It is lighter than water and insoluble in water. Us vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water CUMENE HYDROPEROXIDE 4919525 ORGANIC PEROXIOE UN2116 Cumene hydroperoxide is a colorless to pale yellow colored liquid. It must be shipped as a solution not exceeding 96% in a non-volatile solvent. The solution may take some effort to ignite but once ignited it bums with increasing vigor as the fire progresses. It strongly supports the burning of combustible material. Containers of the solution if exposed to fire or flame may explode. Solutions of 90% peroxide m a non volatile solvent may be shipped in tank cars. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Continued on next page 155 If material not on fire and not involved in fire Keep sparks, (lames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid Oreathing vapors Keep upwind Avoid Dodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material if contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet if material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet lo prevent dissolving in ram or fire fighting water Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates CUPRfC NITRATE 4916744 OXIDIZER NA1479 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100/4S.4) Cupric nitrate is a blue crystalline solid. It is used in medicine, as an insecticide, in chemical analysis, in making light sensitive papers, and for many other uses, it is soluble in water. II is noncombustible, but it will accelerate the burning of combustible materials. If large quantities of the material are involved or the material is finely divided, an explosion may result. Prolonged exposure to fire or heat may result in an explosion. Toxic oxides of nitrogen are produced in fires involving this material, tf material on fire or involved in fire Flood with water Coot all affected containers with flooding quantities of water Apply water from as far a distance as possible tf material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out ot water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material. Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet Environments! considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water split Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates CUPRIC OXALATE 4962610 ORM-E NA2449 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100/45.4) Cupric oxalate is a bluish white powder. It is used as a catalyst in the manufacture of other chemicals. It is insoluble in water. It is non combustible. 156 CUPRIC SULFATE 4961316 ORM-E NA9109 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-10 4.54) Cupric sulfate is a blue crystalline solid. It is used in agriculture, as a fertilizer, pesticide, or feed aditive. to make other copper compounds, as a wood preservative, and for many other uses. It is soluble in water. It is non-combustible. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) tf material not involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spilt Neutralize with agricultural lime (slaked lime!, crushed limestone. or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates CUPRIC SULFATE, AMMONIATED 4962313 ORM-E NA9110 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100'45.4) Cupric sulfate, ammomated is a dark blue crystalline solid with a faint odor of ammonia. It is used as a pesticide, to print fabrics, and lo make other copper compounds. It decomposes on exposure lo air giving off ammonia. It is soluble m water. It is non-combustible. H material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary April 1961 MCD 000009899 Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to coniain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Ad|ust ph to neutral lph-7) Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Adjust ph 10 neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates CUPRIC TARTRATE 4962614 ORM-E NA9111 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100'45.4) Cupric tartrate is a green to blue powder. It is used for electroplating metals. It is insoluble in water. It is non-combustible. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land splil Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates CUPRIETHYLENE-DIAMINE SOLUTION 4935630 CORROSIVE MATERIAL, BASIC UNI 761 Cupriethylene-diamme solution is a purple colored liquid with an am monia like odor it is soluble in water, it is corrosive to metals and tissue. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water m flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain (low as necessary April 1981 Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the matenal Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing aooaratus when fighting fires involv ing this material If contact with the material anticioated. wear full protective clothing CUTCH, CATECHU. OR JAPONICA EXTRACTS. 4915432 LIQUIO (COMBUSTIBLE LIQUID. N.O.S.) COMBUSTIBLE LIQUID NA1993 Cutch. catechu, or japonica extracts, liquid are materials containing a solvent having a closed cup flash point between 100 and 199 deg. F The hazard of these materials is combustibility. II material on fire or involved in fire Do not extinguish fire unless flow can be stooped Use water m flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep uowind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment' Wash away any material which may have contacted the body with copious amounts of water or soap and water CUTCH, CATECHU, OR JAPONICA EXTRACTS, 4910432 LIQUID (FLAMMABLE LIQUIO. N.O.S.) FLAMMABLE LIQUID UN1993 Cutch. catechu, or japonica extracts, liquid are materials containing a solvent having a dosed cup flash point of less than 100 deg. F. The hazard of these materials is flammability. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as log Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use waier spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 157 MCD 000009900 CYANIDE OR CYANIOE MIXTURE, DRY 4923224 POISON B UNI 586 Cyanide or cyanide mixtures, dry are generally white crystalline or powdered material. They are slowly decomposed by water and very rapidly decomposed by acids to give off hydrogen cyanide, a flammable poison gas. It is toxic by skin absorption through open wounds, by ingestion, and inhalation of the hydrogen cyanide from the decompo sition of the material. Toxic oxides of nitrogen are produced in fires involving this material. If material involved In fire Extinguish lire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use foam, carbon dioxide or dry chemical Do not use water on material itself If large quantities of combustibles are involved, use water m flooding quantities as spray and tog Use water spray to absorb vapors If material not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Use water spray to knock-down vapors Do not use water on material Itself Personnel protection Avoid breathing vapors or dusts Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing CYANOGEN BROMIDE 4923229 POISON B UN1869 Cyanogen bromide is a colorless to white crystalline solid with a pen etrating odor, it is used in gold extraction, to make other chemicals, and as a fumigant. It is slightly soluble in water, it is gradually decomposed by water and very rapidly by acids to give off hydrogen bromide, a flammable poison gas. Contamination with many materials can cause rapid decomposition of the material. It is toxic by inhalation of its vapors or by the hydrogen cyanide from decomposition or by ingestion. Toxic oxides of nitrogen are produced in fire involving this material. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use foam, carbon dioxide or dry chemical Cool all affected containers with flooding quantities of water Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors If material not involved in fire Keep material out of water sources and sewers Use water spray to knock-down vapors Do not use water on material itself Personnel protection Avoid breathing vapors or dusts Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear lull protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water CYANIDE SOLUTION. N.O.S. 4923230 POISON B UN1935 Cyanide solution, n.o.s. is the white crystalline material dissolved in water with a stabilizer having the faint odor of bitter almonds. It is slowly decomposed by water and very repidly by acids to give off hydrogen cyanide, a flammable poison gas. It is toxic by skin absorption, by inges tion. and inhalation of the hydrogen cyanide from the decomposition of the material. If material on fire or involved in fire Extinguish fire using agent suitable lor type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Use foam, carbon dioxide or dry chemical Use water spray to absorb vapors If material not on fire and not Involved in Are Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 158 CYANOGEN CHLORIDE (CONTAINING LESS THAN 4920S06 0.9% WATER) POISON A UN1589 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-104.54) Cyanogen chloride is a colorless liquid boiling at 60 deg. F. with a strong odor. In very low concentrations it is irritating to the eyes and mucous membranes while in higher concentrations it is toxic by inhal ation. Its vapor is heavier than air. It may only be shipped in cylinder. Prolonged exposure of the cylinder to lire or heat may cause violently rupturing and rocketing. It weighs 10.0 pounds per gallon. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'' foam, carbon dioxide or dry chemical If material not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Oo not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1961 MCD 00000990^ Evacuation If material leaking (not on fire), downwind evacuation must be considered Environmental considerations--land spill Dig a pit pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill Add caustic soda Add calcium hypochlorite Adjust ph to neutral (ph-7) Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment CYANOGEN GAS 4920115 POISON A, FLAMMABLE UNI 026 Cyanogen gas is a colorless gas with an odor of almonds, it is used to make other chemicals, as a fumigant, and as a rocket propellant. It is shipped as a liquefied gas under its vapor pressure. Its vapor is heavier than air and a flame can travel back to the source of leak very easily. Material is soluble in water and slowty decomposed by water to oxalic acid, a non regulated material, and ammonia. Material may. be only shipped in cylinders and these may have to be overpacked in wooden boxes. Prolonged exposure to lire or heat may cause violent rupturing and rocketing of the cylinders. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams oi water may be ineffective Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the maienal Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on lire), downwind evacuation must be considered CYCLOHEXANE FLAMMABLE LIQUID 4906132 UN1149 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Cyclohexane is a clear colorless liquid with a petroleum-like odor. It is used to make nylon, as a solvent. oaint remover, and to make other chemicals. It has a Hash point of -4 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. It weighs 6.5 pounds per gallon. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread Tire April 1981 MCD 000009902 Cool all affected containers with flooding quantities ol water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash. cement powder, sawdust, or com mercial sorbents Apply "universal" gelling agent to immobilize spill Apply lluorocarbon-water foam to diminish vapor and fire hazard Environmental considerations--water spill Use natural barriers or oil spill control booms to limit spill motion Use surface active agent (e.g. detergent, soaps, alcohols) to com press and thicken spilled material Inject "universal" gelling agent to solidify encircled spill and increase effectiveness of booms Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spilt Apply water spray or mist to knock down vapors CYCLOHEXANONE (COMBUSTIBLE UQUIO. N.O.S.) 4913179 COMBUSTIBLE UOUIO NA1993 Cyclohexanone is a colorless to pale yellow liquid with a pleasant odor. It is used to make nylon, as a chemical reaction medium, and as a solvent. It is lighter than water and is slightly soluble in water. It has a Hash point of 111 deg. F. Its vapors are heavier than air. H material on fire or Involved In fire Do not extinguish lire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'' foam, carbon dioxide or dry chemical If materiel not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 159 CYCLOHEXANONE PEROXIDE (IN SOLUTION WITH 4919527 NOT MORE THAN 9% BY WEIGHT ACTIVE OXYGEN) ORGANIC PEROXIDE UN2118 Cyclohexanone peroxide, (in solution with not more than 9% by weight active oxygen) is a colorless to pale yellow liquid. It is used to manu facture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite: but once ignited, it will burn with increasing rapidity as the fire progresses, if spilled on combustible materials, spontaneous ignition of the matenal may occur. Contamina tion with many chemical substances can cause a violent chemical re action It supports the burning of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with cooious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the matenal is on fire or involved in fire evacuate for a radius of 2500 feet CYCLOHEXANONE PEROXIDE AND BIS(1- 4919537 HYDROXYCYCLOHEXYL) PEROXIDE MIXTURE ORGANIC PEROXIDE UN2119 Cyclohexanone peroxide and bis(t -hydroxycyctohexyf) peroxide mix* ture is a colorless solution of a white crystalline solid in a non-volatile solvent. The solution may take some effort to ignite but once ignited it burns with increasing vigor as the fire progresses. The dried material is easier to ignite. It strongly supports the burning of combustible ma terial. The dried material can form explosive mixtures with finely divided combustible matenals. Under prolonged exposure to heat or fire con tainers of the material can explode. If material on fire or Involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol" foam, cartoon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment 160 MCD 000009903 Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet CYCLOHEXANONE PEROXIDE AND OI-<1- 4919125 HYDROXYCYCLOHEXYL) PEROXIOE MIXTURE ORGANIC PEROXIOE UN2896 Cyclohexanone peroxide and di-(i-hydroxycyclohexyl) peroxide mix ture is a white solid or colorless to white tiauid or paste. It is used to manufacture paints, plastics, and rubber, it is insoluble m water The liquid or solution may require some effort to ignite: but once ignited, it will burn with increasing rapidity as the tire progresses. If spilled on combustible matenals. spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burning of combustible materials Un der prolonged exposure to fire or heat, containers of the materials may explode. If material on fire or Involved In fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol' foam, carbon dioxide or dry chemical Dangerously explosive if material not on firo and not involvad in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in (ire evacuate for a radius of 2500 feet CYCLOHEXANONE PEROXIDE, (AS A PASTE WITH 4919S28 NOT MORE THAN 9% BY WEIGHT ACTIVE OXYGEN) ORGANIC PEROXIDE UN2896 Cyclohexanone peroxide, (as a paste with not more than 9% by weight active oxygen) is a white solid. It is used to manufacture paints, plastics, and rubber, it is insoluble in water. It is easily ignited and bums with increasing rapidity as the fire progresses. It can form explosive mixtures with finely divided combustible materials. It supports the burning of com bustible materials. Under prolonged exposure to fire or heat containers ol the material may explode. If materiel on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol" foam, carbon dioxide or dry chemical Dangerously explosive April 1981 If material not on fire and not Involved In tire Keep sparks, (lames, and other sources o( ignition away Keep material out of water sources and sewers Keep spriled materia) wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact wilh the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet CYCLOHEXANONE PEROXIDE. (NOT OVER 50% 4919530 PEROXIDE) ORGANIC PEROXIDE UN2896 Cyclohexanone peroxide is a colorless solution of a white crystalline solid. The solution may take some effort to ignite but once ignited it burns with increasing vigor as the fire progresses. It strongly supports the burning of combustible material. The dried material is easily ignited. The dried material can form explosive mixtures with combustible ma terials. Under prolonged exposure to fire or heat containers of the ma terial may explode. If material on fire or involved in fire Use water in Hooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities* of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive It material not on fire and not Involved In Are Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet CYCLOHEXANONE PEROXIDE, (50 TO 55% 4919535 PEROXIDE) ORGANIC PEROXIDE UN2119 Cyclohexanone peroxide is a colorless solution of a white crystalline solid. The solution may take some effort to ignite but once ignited H burns with increasing vigor as the fire progresses. It strongly supports the burning of combustible material. The dried material is easily ignited. The dried material can form explosive mixtures with combustible ma terials. if exposed to fire or heat for prolonged periods of time, container of the solution may explode. April 1981 M material on fire or involved In fire Use water in Hooding quantities as fog Solid streams of water may be ineffective Coot all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on lire or involved in fire evacuate for a radius of 2500 feet CYCLOHEXENYL TRICHLOROSILANE 4934217 CORROSIVE MATERIAL, ACIDIC. COMBUSTIBLE UN1762 Cyclohexenyl trichlorosilane is a colorless liquid with a pungent odor, it is used to make various silicon containing compounds, it is combustible and has a flash point of 200 deg. F. It is readily decomposed by moisture or water to hydrochloric acid with evolution of heat. It is corrosive to metals and tissue. If material on fire or involved in fire Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water m Hooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with Hooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body wilh copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing CYCLOHEXYL TRICHLOROSILANE 493421B CORROSIVE MATERIAL, ACIDIC UNI 763 Cyciohexyl trichlorosilane is a colorless to pale yellow liquid with a pungent odor. It is combustible and has a Hash point ol 1B5 deg. F. It is readily decomposed by moisture or water to hydrochloric acid with evolution of heat. It is corrosive to metals and tissue. Continued on next psgo 161 MCD 000009904 If material on Tire or Involved in fire Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water m flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as tar a distance as possible If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts ot water or soap and water If contact with the material anticipated, wear full protective clothing CYCLOHEXYLAMINE 4909139 FLAMMABLE LIQUID UN2357 Cyclohexylamine is a clear colorless to yellow liquid with an ammonia like odor. It has a flash point of 90 deg. F. It is irritating to the eyes and respiratory system. Skin contact may result in burns. It is lighter than water and soluble in water. Its vapors are heavier than air. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical tf material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop teak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material CYCLOPENTANE 4908135 FLAMMABLE LiQUIO UN1146 Cyclopentane is a clear colorless liquid with a petroleum-like odor. It has a flash point of -35 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water 162 MCD 000009905 Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to Stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered CYCLOPENTANE, METHYL 4908137 FLAMMABLE UQUID UN2298 Cyclopentane, methyl is a clear colorless liquid with a petroleum-like odor. It has a flash point of -17 deg. F. it is lighter than water and insoluble in water. Its vapors are heavier than air. If material on Are or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool ail affected containers with flooding quantities of water Apply water from as tar a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered CYCLOPROPANE 4905713 FLAMMABLE GAS UN1027 Cyclopropane is a colorless gas with a petroleum like odor, It is shipped as a liquid under its own vapor pressure. It is easily ignited and may only be shipped in cylinders. It is heavier than air and a flame can * flash back to Ihe source of leak very easily. Contact with the liquid may cause frostbite. It can asphyxiate by the displacement of air. Under fire conditions the cylinders may violently rupture and rocket, tf materiel on fire or involved In fire Do not extinguish fire unless flow can be slopped Use water in flooding quantities as fog Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible April 1981 If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Use water spray to knock-down vapors Keep material dry Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate lor a radius of 1500 feet If material leaking (not on firei. downwind evacuation must be considered i tf material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop teak if without hazard Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear seif-centained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing DDT (OR) DICHLORODIPHENYLTRICHLOROETHANE 4941129 ORM-A NA2761 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1 0.454) Ddt is a colorless to white crystalline solid. It is used as a pesticide. H is a wettable powder or water emulsifiable liquid. It can cause illness by inhalation, skin absorption and or ingestion. In case of damage to. or leaking from containers of this matenal contact the pesticide safety team network. Telephone: 800-424-9300. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Oig a pit. pond, lagoon, holding area to contain liquid or solid material Cover sofids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates DE-JNK1NG COMPOUNDS USED IN RECYCLING 4935278 PAPER (CORROSIVE LIQUID, N.O.S.) CORROSIVE MATERIAL UN1760 De-mking compounds are various colored liquids. They may or may not be soluble in water. They may burn though it may take some effort to ignite. They are corrosive to metals and tissue. If material on fire or Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use "alcohol'' foam, carbon dioxide or dry chemical April 1981 DECABORANE 4916610 FLAMMABLE SOLID, POISONOUS UNI 868 Decaborane is a colorless to white crystalline matenal with a persistent disagreeable odor. It is readily ignited and once ignited burns with a green flame. It may spontaneously ignite on exposure to air. It is toxic by skin absorption. It is slightly soluble in cold water and is slowly hy drolyzed by hot water to give off hydrogen, a flammable gas. It forms shock sensitive compounds when dissolved in oxygenated or halogen- ated solvents. If material on fire or involved in fire Use water in flooding quantities as fog Use dry chemical or carbon dioxide If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep matehaf dry Personnel protection Avoid breathing dusts Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted (he body with copious amounts of water or soap and water DECAHYDRONAPHTHALENE 4913167 COMBUSTIBLE LIQUID UN1147 Oecahydronaphthalene is a clear colorless liquid with an aromatic odor. It has a flash point of 134 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless (low can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts ol water or soap and water 163 MCD 000009906 DECANOYL PEROXIOE. (TECHNICALLY PURE) 4919128 ORGANIC PEROXIDE UN2120 Decanoyi peroxide, (technically pure) is a white solid. If is used to manufacture paints, plastics, and rubber. It is insoluble in water. It is easily ignited and burns with increasing rapidity as the lire progresses, it can form explosive mixtures with finely divided combustible materials, it supports the burning of combustible materials. Under prolonged et- cosure to tire or heat containers of the material may explode. If material on fire or involved in fire Use water m flooding quantities as fog Solid streams of water may be ineffective Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keeo sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning malenal Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective eouipment Wash away any material which may have contactec the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation if the material is on fire or involved in fire evacuate for a radius of 2500 feet DECYL ALCOHOL. OTHER THAN PERFUMERY 4913121 GRADE (ALCOHOL. N.O.S.) COMBUSTIBLE LIQUID UN1987 Decyl alcohol is a clear colorless liquid with a sweet fat-like odor. It has a flash point of 180 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire end not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water DEFOAMING COMPOUND. NEC. LIQUID 4915208 (COMBUSTIBLE LIQUID. N.O.S.) COMBUSTIBLE LIQUID NA1993 Defoaming compound, nec. liquid is a variable colored liquid, it has a flash point between 100 and 199 deg. F. It is generally lighter than water and soluble in water. Its vapors are heavier than air. 164 If material on fire or involved in fire Do not extinguish fire unless flow can t>e stopped Use water in flooding quantities as log Solid streams of water may be ineffective Cool ail affected containers with Hooding quantities of water Apply water from as far a distance as possible Use alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep malenal out of water sources and sewers Build dikes to contain How as necessary Use water spray to disperse vapors and dilute standing pools oi liquid Personnel protection Avoid breathing vapors Keep upwind Wear bools, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water DEFOAMING COMPOUNO. NEC, LIQUID (FLAMMABLE 4910208 LIQUID. N.O.S.) FLAMMABLE LIQUID UNI 993 Defoammg compound, nec. liquid is a variable colored liquid. It has a flash point of less than 100 deg. F. It is generally lighter than water and soluble in water. Its vapors are heavier than air. If material on fire or involved in fire Oo not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with Hooding quantities ol water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical if material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water DEGUMMiNG COMPOUNDS, FABRIC OR FIBER 4915466 (COMBUSTIBLE LIQUID. N.O.S.) COMBUSTIBLE LIQUID NA1993 Degummmg compounds, fabric or fiber are materials containing a solvent having a flash point between 100 and 199 deg. F. The hazard of these materials is combustibility. If material on fire or Involved In fire Do not extinguish fire unless How can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain (low as necessary Use water spray to knock-down vapors April 1981 MCD 000009907 Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts ol water or soap and water DEGUMMING COMPOUNDS. FABRIC OR FIBER 4910466 (FLAMMABLE LIQUID. N.O.S.) FLAMMABLE LIQUID UN1993 Degummmg compounds, fabric or fiber are materials containing a solvent having a flash point of below 100 deg. F. The hazard of these materials s flammability. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water DELAY ELECTRIC IGNITER 4903435 CLASS C EXPLOSIVE Delay electric igniter consists of small metal, fiberboard or paste board tubes containing a wire bridge in contact with a small quantity of an ignition compound in contact to a short piece of igniter cord. If material on fire or involved In fire Flood with water Apply water from as far a distance as possible if material not on fire and not involved in Are Keep sparks, flames, and other sources of ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this matenal Evacuation If lire becomes uncontrollable--evacuate for a radius of 1500 feet DENATURED ALCOHOL 4909141 FLAMMABLE LIQUID NA1966 Denatured alcohol is a dear, colorless liquid with a characteristic odor, it is used as a fuel, solvent, antifreeze, and to make other chemicals. It has a flash point of 58-60 deg. F. It is lighter than water and soluble m water. Its vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool an affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, cartoon dioxide or dry chemical April 1961 If materiel not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water DENATURED ALCOHOL SOLVENT. (ALCOHOL. 4909142 N.O.S.) FLAMMABLE LIQUID UN1967 Denatured alcohol is a clear, colorless liquid with a characteristic odor. It has a flash point of 58*60 deg. F. It is lighter than water and soluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water n flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use 'alcohol'' loam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep matenai out of water sources and sewers Build dikes to contain (low as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water DENATURED ALCOHOL SOLIDIFIED (ALCOHOL 4910403 N.O.S.) FLAMMABLE UQUID UNI 967 Denatured alcohol, solidified is a stemo-like gel. The alcohol can separate out. The hazard is flammability. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 165 MCD 000009908 DENATURING ALCOHOL, NEC (ALCOHOL, N.O.S.) 4909143 FLAMMABLE UQUIO UN1987 Denaturing alcohol is a clear colorless liquid. It has a flash point of too deg. F. It is lighter than water and soluble in water. Its vapors are heavier than air. If material on lire or involved in fire Do not extinguish fire unless flow can be stopped Use water m flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water DENATURING ALCOHOL, NEC (ALCOHOL, N.O.S.) 4913133 COMBUSTIBLE LIQUID UNI 967 Denaturing alcohol, nec is a clear colorless liquid. It has a'flash point between 100 and 199 deg. F. It is lighter than water and slightly soluble in water, its vapors are heavier than air. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with Hooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involvad In fira Keep sparks, flames, and other sources of ignition away Keep material out of watar sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water DETERGENT INTERMEDIATES, OTHER THAN CYCUC 4915371 OR PETROLEUM (COMBUSTIBLE UQUIO. N.O.8.) COMBUSTIBLE UOUID NA1993 Detergent intermediates, other than cyclic or petroleum are clear col orless liquid. They have a flash point between 100 and 199 deg. F. They are generally lighter than water and soluble in water. Their vapors are heavier than air. If material on Are or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical 166 If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts of water or soap and water OETERGENT INTERMEDIATES. OTHER THAN CYCLIC 4910371 OR PETROLEUM (FLAMMABLE LIQUID. N.O.S.) FLAMMABLE LIQUID UN1993 Detergent intermediate, other than cyclic or petroleum are clear col orless liquid. They have a flash point of less than 100 deg. F. They are generally lighter than water and soluble in water. Their vapors are heav ier than air. If material on fire or Involved in fire Do not extinguish tire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fira and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools ol liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water DETONATING FUZE 4901205 CLASS A EXPLOSIVE Detonating fuze is a device consisting of a detonator and may contain several ounces of high explosives encased in a heavy steel envelope. Under fire conditions they wilt explode. If material on fire or involved In fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and lat bum If material not on fire and not involved In fire Keep sparks, names, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this matenal Evacuation If the matenal is on fire or involved in fire evacuate for a radius of 5000 feet DETONATING FUZE, CLASS C EXPLOSIVE 4903215 CLASS C EXPLOSIVE Detonating fu2e, class c explosive is a device containing a limited amount of explosive and is used to detonate the bursting charge of projectiles, bombs, mines, torpedoes, or grenades, or to transmit a det onation between two or more explosive devices. April 1981 MOD 000009909 If material on fire or involved In fire Flood with water Apply water from as far a distance as possible tf material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet DETONATING FUZE. RADIOACTIVE 4901210 CLASS A EXPLOSIVE Detonating fu2e. radioactive is a device consisting of a detonator and may contain several ounces of high explosives and a small amount of a radioactive component encased in a steel envelope. Under fire con ditions they will explode. If material on fire or Involved in fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let burn If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius ol 5000 feet DETONATING PRIMER {CAPS. BLASTING OR 4901260 ELECTRIC BLASTING. EXPLOSIVE) CLASS A EXPLOSIVE Oetonating primer is a device consisting ol a metal or plastic envelope containing a detonator and an additional charge of high explosives. Under fire conditions these devices wifi explode. If material on fire or Involved in fire Dangerously explosive Do not fight tires in a cargo of explosives Evacuate area and let burn If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the matenal is on fire or involved in (ire evacuate for a radius of 5000 feet OETONATING PRIMER (CAPS. BLASTING OR 4901365 ELECTRIC BLASTING, EXPLOSIVE) CLASS C EXPLOSIVE Detonating primer is a device consisting of a metal or plastic envelope containing a detonator and an additional charge of high explosives. Under fire conditions these devices will explode. If material on fire or involved In fire Dangerously explosive Flood with water Apply water from as far a distance as possible April 1981 If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation H lire becomes uncontrollable--evacuate for a radius of 1500 feel DETONATORS (CAPS. BLASTING OR ELECTRIC 4901330 BLASTING. EXPLOSIVE) CLASS C EXPLOSIVE Detonators are small tubes, usually made of an alloy ol either copper or aluminum closed at one end and loaded with one or more charges of initiating or priming explosives Underfire conditions they will explode. If material on fire or involved in fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let burn If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on (ire or involved in fire evacuate for a radius of 5000 feet DETONATORS (CAPS, BLASTING OR ELECTRIC 4903360 BLASTING, EXPLOSIVE) CLASS C EXPLOSIVE Detonators are small tubes, usually made of an alloy of either copper or aluminum closed at one end and loaded with one or more charges of initiating or priming explosives. Under tire conditions they will explode. If material on fire or Involved In fire Dangerously explosive Flood with water Apply water from as far a distance as possible If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If lire becomes uncontrollable--evacuate for a radius of 1500 feet DK2-ETHYLHEXYL) PHOSPHORIC ACID 4931422 CORROSIVE MATERIAL, ACIOIC NAt902 Di(2-ethylhexyi) phosphoric acid is a colorless liquid. It is insoluble in water. It is corrosive to metais and tissue. If material on fire or Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use water spray to absorb vapors Continued on next pego 167 MCD 000009910 If material not on fire and not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, ana goggles Do not handle broken packages without protective equipment Wash away any material which nay have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing 1.1 -DI-(TERT*BUTYLPEROXY)-3.3.5-TRIMETHYL 4919296 CYCLOHEXANE. (TECHNICALLY PURE) ORGANIC PEROXIDE UN2145 1.1 -di-(iert-burylperoxy)'3.3.5-trimeihyl cyclohexane, (technically pure) is a colorless to pale yellow liquid. U is used to manufacture paints. Plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite: but once ignited, it will burn with increasing rapidity as the fire progresses. If spilled on combustible materials, spon taneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burning of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol' foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes Irom burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in tire evacuate for a radius of 2500 feet 1.1 -DHTERT-BUTYLPEROXY).313,5-TRIMETHYL CYCLOHEXANE. (NOT MORE THAN 57% IN 4919297 SOLUTION) ORGANIC PEROXIDE UN2146 f,t-di-(tert-butylperoxy)-3.3.5-lrimethyl cyclohexane, (not more than 57% m solution) is a coloress to pale yellow liouid. It is used to manu facture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite: but once ignited, it will burn with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur. Contamina tion with many chemical substances can cause a violent chemical re action. II supports the burning of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. 168 If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities ot water Apply water from as far a distance as possible Use "alcohol foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius ot 2500 feet . 1.1-DHTERT-BUTYLPEROXY)-3.3.S*TRIMETHYL 4919298 CYCLOHEXANE, (NOT MORE THAN 56% WITH INERT SOLID) ORGANIC PEROXIDE UN2147 i.i-di-(lert-butylperoxy)-3.3.5-tfimethyl cyclohexane, (not more than 58% with inert solid) is a white solid ft is used to manufacture paints, plastics, and rubber. It is insoluble in water. It is easily ignited and burns with increasing rapidity as the fire progresses. It can form explosive mixtures with finely divided combustible materials. It supports the burning of combustible materials. Under prolonged exposure to fire or heat con tainers of the material may explode. If material on fire or involved in fire Use water in Hooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apoaratus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation II the material is on lire or involved in fire evacuate for a radius of 2500 feet April 1981 MCD 000009911 2,2-OMTERT*BUTYLPEROXY)BUTANE, (NOT MORE 4919210 THAN 55% IN SOLUTION) ORGANIC PEROXIDE UN2111 2.2-di-(tert-butylperoxy)butane. (no! more than 55% in solution) ts a colorless to pate yellow liquid. II is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite, but once ignited, it will burn with increasing rapidity as the fire progresses. U spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burn ing of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting (ires involv ing this material if contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on lire or involved in fire evacuate for a radius of 2500 feet 1,1-DI-(TERT-BUTYLPEROXY)CYCLOHEXANE, (NOT 4919229 MORE THAN 40% WITH INERT INORGANIC SOLIO, WITH NOT LESS THAN 13% PHLEGMATIZER) ORGANIC PEROXIDE UN2885 i,i-di-(tert-butylperoxy)cyclohexane. (not more lhan 40% with inert inorganic solid, with not less than 13% phiegmatizer) is a white solid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. It is easily ignited and burns with increasing rapidity as the fire progresses. It can form explosive mixtures with finely divided combus tible materials, it supports the burning of combustible materials. Under prolonged exposure to fire or heat containers of the material may ex plode. The phiegmatizer is a material added to make the peroxide less reaciiive. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not Involved in fire Keep sparks, flames, and other sources ol ignition away Keep matenal out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning matenal Avoid bodily contact with the material Wear boots, protective gloves, and goggles Aphl 1981 Do not handle broken packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved m fire evacuate for a radius of 2500 feet 1.1-DI-(TERT-8UTYLPEROXY)CYCLOHEXANE, (NOT 4919230 MORE THAN 50% WITH PHLEGMITIZER) ORGANIC PEROXIDE UN2897 1. t-di-(tert-butylperoxy)cyclohexane. (not more than 50% with phieg matizer) is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is insoluble <n water. The liquid or solution may require some effort to ignite, but once ignited, it will burn with increasing rapidity as the tire progresses. If spilled on combustible ma terials. spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction it supports the burning of combustible materials. Under prolonged ex posure to fire or heat containers of the material may explode. The phieg matizer is a matenal added to make the peroxide less reacitive if material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Coot all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled matenal before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet 1,1-OI-(TERT-BUTYLPEROXY)CYCLOHEXANE, (NOT 4919227 MORE THAN 77% IN SOLUTION) ORGANIC PEROXIDE UN2180 i. 1 -di-(tert-butylperoxy)cyciohexane. (not more than 77% in solution i is a colorless to pale yellow liquid. It is used to manufacture paints plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort lo ignite: but once ignited, it will burn with increasing rapidity as the fire progresses, if spilled on combustible materials, spon taneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burning of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. Continued on noxt pgo 169 MCD 000009912 If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'' loam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out o4 water sources and sewers Keep spilled materia; wet Wet spilled material oefore picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained oreathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation II the material is on fire or involved in fire evacuate for a radius of 2500 feet 1.2-DMTERT-BUTYLPEROXY)CYCLOHEXANE, (NOT 4919226 MORE THAN 77% IN SOLUTION) ORGANIC PEROXIDE UN2101 l.2-di-(tert-butylperoxylcyciohexane, (not more than 77% in solution) is a colorless to pale yellow liquid, ft is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite; but once ignited, it will bum with increasing rapidity as the fire progresses. II spilled on combustible materials, spon taneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burning of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or Involved in fire Use water in flooding quantities as fog Solid streams of wafer may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fir* and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material Oefore picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Oo not handle broken packages without protective equipment Wash away any matenat which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear fuff protective clothing Approach fire with caution Evacuation II the material is on fire or involved in fire evacuate for a radius of 2500 feet 1.1-OI-(TERT-BUTYLPEROXY)CYCLOHEXANE, (TECHNICALLY PURE) 4919226 ORGANIC PEROXIDE UN2179 1.1 -di-ftert-butylperoxyjcyclohexane. (technically pure) is a colorless to pale yellow liquid- It is used to manufacture paints, plastics, and rubber. It is insoluble in water The liquid or solution may require some effort to ignite; but once ignited, it will bum with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction It supports the burn ing of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or involved In fire Use water in flooding quantities as log Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol'' foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate lor a radius of 2500 feet DI-(TERT-8UTYLPEROXY)PHTHALATE, (NOT MORE 4919268 THAN 55% AS A PASTE) ORGANIC PEROXIDE UN2106 Di-(tert-buty1peroxy)phthalate. (not more than 55% as a paste) is a white solid. II is used to manufacture paints, plastics, and rubber. II is insoluble in water. It is easily ignited and bums with increasing rapidity as the tire progresses. It can form explosive mixtures with finely divided combustible materials. It supports the burning of combustible materials. Under prolonged exposure to lire or heat containers of (he material may explode H material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol" foam, carbon dioxide or dry chemical Dangerously explosive ff material not on fire end not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it <4) 170 mcd 00009g 13 April 1961 Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach tire with caution Evacuation If the material is on fire or involved in fire evacuate tor a radius of 2500 feet DI-(TERT-BUTYLPEROXY)PHTHALATE, (NOT MORE 4919287 THAN 55% IN SOLUTION) ORGANIC PEROXIDE UN2107 Di-(tert-butylperoxy)phthalate. (not more than 55% in solution) is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite: but once ignited, it will burn with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction, tt supports the burn ing of combustible materials. Under prolonged exposure to tire or heat containers of the material may explode. If material on fire or involved In fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use 'alcohol" foam, carbon dioxide or dry chemical Dangerously explosive if material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting (ires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet DI-<TERT-BUTYLPEROXY)PHTHALATE, 4918286 (TECHNICALLY PURE) ORGANIC PEROXIDE UN2106 Di-(tert-butylperoxy)phthalate, (technically pure) is a white solid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. It is easily ignited and bums with increasing rapidity as the fire pro gresses. It can form explosive mixtures with finely divided combustible materials. It supports the burning of combustible materials. Under pro* !<*>nged exposure to fire or heat containers of the material may explode. April 1981 If material on fire or involved In fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as tar a distance as possible Use 'alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not Involved in fire Keep sparks, flames, and other sources of Ignition away Keeo material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and tumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet 2,2*OI*<TERT*8UTYLPEROXY)PROPANE. (NOT MORE 4919291 THAN 40% WITH INERT INORGANIC SOLID WITH NOT LESS THAN 13% PHLEGMAT1ZER) ORGANIC PEROXIOE UN2864 2.2-di-(tert-butylperoxy)propane. (not more than 40% with inert'inor ganic solid with not less than 13% phlegmatizer) is a white solid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. It is easily ignited and bums with increasing rapidity as the fire pro* gresses. It can form explosive mixtures with finely divided combustible materials. It supports the burning of combustible materials. Under pro* longed exposure to fire or heal containers of the material may explode. The phlegmatizer is a material added to make the peroxide less reatitive. H material on fire or involved In fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If materiel not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach (ire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feel 171 MCD 000099i4 2,2-OHTERT-8UTYLPEROXY)PROPANE, (NOT MORE 4919290 THAN 50% WITH PHLEGMATIZER) ORGANIC PEROXIDE UN2883 2.2-di-(<ert-butylperoxy)propane, (not more than 50% with phlegma* tizer) is a colorless to pale yellow liquid- It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite; but once ignited, it will burn with increasing rapidity as the fire progresses. If spilled on combustible materials, spon taneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burning of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. The phlegmatizer is a material added to make the peroxide less reacitive. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol' foam, carbon dioxide or dry chemical Dangerously explosive if material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet DH1-HYDROXYCYCLOHEXYL) PEROXIDE, 4919279 (TECHNICALLY PURE) ORGANIC PEROXIDE UN2149 Di-( i -hydroxycyclohexyl) peroxide, (technically pure) is a white solid, it is used to manufacture paints, plastics, and rubber, ft is insoluble in water, it is easily ignited and bums with increasing rapidity as the fire progresses. It can form explosive mixtures with finely divided combus tible materials. It supports the burning of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or Involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved In fire Keep sparks, flames, and other sources ol ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Peraonnei protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 172 Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet OH2-ETHYLHEXYL) PEROXYDICARBONATE. (NOT 4919281 MORE THAN 67% IN SOLUTION) ORGANIC PEROXIDE UN2123 Di-(2-ethylhexyl) peroxydicarbonate. mot more than 67% in solution! is a colorless to pale yellow liquid, it is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite; but once ignited, it will burn with increasing rapidity as the fire progresses. If spilled on combustible materials, spon taneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burning of combustible materials. Under orolonged exposure to tire or heat containers of the material may explode. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool ail affected containers with flooding quantities of water Appiy water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Oangerously explosive tf material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled matenal wet Wet spilled material before picking it up Peraonnei protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material It contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation tf the material is on fire or involved in fire evacuate for a radius of 2500 feet DH2-ETHYLHEXYL) PEROXYDICARBONATE. (TECHNICALLY PURE) 4919260 ORGANIC PEROXIDE UN2122 Di*(2-ethytttexyl) peroxydicarbonate. (technically pure) is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite; but once ignited. t will bum with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction It supports the burn ing of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode, if material on fire or involved In fire Use water in flooding quantities as tog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive April 1981 MCD 000009915 H material not on fire and not involved In fire Keep sparks. Flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet DH2-METHYLBENZOYL) PEROXIDE, (NOT MORE ` 4919282 THAN 85% WITH WATER) ORGANIC PEROXIDE UN2593 Di-(2-mefhylbenzoyi) peroxide, (not more than 85% with water) is a white solid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. It is easily ignited and burns with increasing rapidity as the fire progresses. It can form explosive mixtures with finely divided combustible materials. It supports the burning of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all aflected containers with ttooding quantities of water Apply water from as far a distance as possible Use "alcohol " foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation if the material is on fire or involved in fire evacuate for a radius of 2500 feet ^ril 1981 MCD 000009916 1.3-DH2-TERT-BUTYLPEROXYISOPROPYL) BENZENE 4919207 ANO 1.4-DM2-TERT- 8UTYLPER0XYIS0PR0PYL) BENZENE MIXTURE. (TECHNICALLY PURE OR MORE THAN 40% WITH INERT SOLID) UN2112 ORGANIC PEROXIDE l.3-di-(2-tert-butylperoxyisapropyl) benzene and i.4-di-(2-tert-butyl- peroxyisopropyl) benzene mixture, (technically pure or more than 40 with inert solid) is a white solid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. It is easily ignited and burns with increasing rapidity as ihe fire progresses. It can form explosive mixtures with finely divided combustible materials. It supports the Burning of com bustible materials. Under prolonged exposure to Fire or heat containers of the material may explode. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as Far a distance as possible Use "alcohol ' foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material It contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet 1.3-DH2-TERT-BUTYLP6ROXYISOPROPYL) 4919206 BENZENE, (TECHNICALLY PURE OR MORE THAN 40% WITH INERT SOLID) ORGANIC PEROXIOE UN2112 1.3-dH2-tert-butylperoxyisopropyl) benzene, (technically pure or more than 40% with inert solid) is a white solid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. It is easily ignited and bums with increasing rapidity as the fire progresses. It can loon explosive mixtures with finely divided combustible materials. It supports the burning of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or involved In fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Continued on next page 173 Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear seif-contained breathing apparatus when fighting fires involv ing this material if contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet 1,4-DI*(2-TERT*BUTYLPEROXYlSOPROPYL) 4919209 QEN2ENE. (TECHNICALLY PURE OR MORE THAN 40% WITH INERT SOLID) ORGANIC PEROXIDE UN2112 t .4-di-(2-tert-butylperoxyisopropyl) benzene, (technically pure or more than 40% with inert solid) is a white solid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. It is easily ignited and burns with increasing rapidity as the lire progresses. It can form explosive mixtures with finely divided combustible materials. It supports the burning of combustible materials. Under prolonged exposure to lire or heat containers of the material may explode. If material on fire or involved in fire Use water in flooding quantities as log Solid streams of water may be ineffective Cool all affected containers with Hooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical. Dangerously explosive If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material if contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in tire evacuate for a radius of 2500 feet OH3.5.S-TRIMETHYL-1.2-OIOXOLANYL-3) PEROXIDE, 4919283 (NOT MORE THAN 50% AS A PASTE, WITH PHLEGMATIZER) ORGANIC PEROXIOE UN2597 Di-(3.5.5-trimethyl-1,2-dioxolanyl-3) peroxide, (not more than 50% as a paste, with phlegmatizer) is a white solid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. It is easily ignited and burns with increasing rapidity as the fire progresses. It can form explosive mixtures with finely divided combustible materials. It supports the burning of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. The phlegmatizer is a material added to make the peroxide less reacitive. 174 MCD 000009917 If material on fire or Involved In fire Use water in Hooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "afcohot" foam, carbon dioxide or dry chemical Dangerously explosive If material not on tire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning matenal Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water o< soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius o' 2500 feet DH4-TERT- 4919284 BUTYLCYCLOHEXYL)PEROXYOICARBONATE. (NOT MORE THAN 42%, STABLE DISPERSION, IN WATER) ORGANIC PEROXIOE UN2894 Di-(4-tert-butylcyclohexyf)peroxydicarbonate. (not more than 42%. stable dispersion, in water) is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. The liquid or solution may require some effort to ignite; but once ignited, it will burn with increasing rapidity as the fire progresses. If spitted on combustible materials, spon taneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burning of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or involved In fire Use water in Hooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use " alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and kxnes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting tires involv ing this material tf contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation (f the material is on fire or involved In fire evacuate for a radius of 2500 feet April 1981 DW4-TERTBUTYLCYCLOHEXYLJPEROXYDICARBONATE, 4919285 (TECHNICALLY PURE) ORGANIC PEROXIDE UN2154 Di-(4-tert-bytylcyctohexyl)peroxydicarbonate, (technically pure) is a white solid. It is used to manufacture paints, plastics, and rubber. It is insoluble m water. It is easily ignited and bums with increasing rapidity as the fire progresses. It can form explosive mixtures with finely divided combustible materials. It supports the burning of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or involved In fire Use water tn flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol" foam, carbon dioxide or dry chemical Dangerously explosive if material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material if contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius ol 2500 feet 2,2-OI-(4,4-DI-TERT-BUTYLPEROXYCYCLOHEXYL) 4919292 PROPANE, (NOT MORE THAN 42% WITH INERT SOLID) ORGANIC PEROXIDE UN2168 2.2-di-(4,4-di-tert*butylperoxycyclohexyl) propane, (not more than 42% with men solid) is a white solid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. It is easily ignited and bums with increasing rapidity as the fire progresses. It can form explosive mixtures with finely divided combustible materials. It supports the burning of combustible materials. Under prolonged exposure to fire or heat con tainers of the material may explode. If material on fire or Involved In fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantifies of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1961 Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach tire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet DI-N-PROPYL PEROXYDICARBONATE, 4919294 (TECHNICALLY PURE) ORGANIC PEROXIDE UN2176 Di-n-propyl peroxydicarbonate. (technically pure) is a white solid. It is used to manufacture paints, plastics, and rubber, it is slightly soluble in water. It is easily ignited and burns with increasing rapidity as the fire progresses. It can form explosive mixtures with finely divided combus tible materials. It supports the burning of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. H materiel on fire or Involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Appfy water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodify contact with the material Wear bools, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet DLN-PROPYLAMINE (FLAMMABLE LIQUID, N.O.S.) 4909157 FLAMMABLE UQUID UNI 993 Di-n-propylamine is a dear colorless liquid with an ammonia-like odor. It has a flash point of 30 deg. F. It is lighter than water and soluble in water. Its vapors are heavier than air. Toxic oxides of nitrogen are produced during combustion of this material. H material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantifies as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Continued on next page 175 MCD 000009918 Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contacl with the material Wear boots, protective gloves, and goggles Oo not handle broken packages without protective equipment Wash away any material which may have contacted the body with cooious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material if contact with the material anticipated, wear full protective clothing DI-SEC-BUTYL PEROXYDICARBONATE, (NOT MORE 4919214 THAN 52% IN SOLUTION) ORGANIC PEROXIDE UN2151 Di-sec-butyl peroxydicarbonate. mot more than 52% in solution) is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite; but once ignited, it will burn with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burn ing of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignitibn away Keep material out of water sources and sewers Keep spilled material wet Wei spilled malenal before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If Ihe material is on fire or involved in fire evacuate for a radius of 2500 feet DI-SEC-BUTYL PEROXYDICARBONATE, 4919215 (TECHNICALLY PURE) ORGANIC PEROXIDE UN2150 Di-sec-butyl peroxydicarbonate. (technically pure) is a colorless lo pale yellow liquid. II is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite, but once ignited, it will bum with increasing rapidity as the tire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction, it supports the burning of com bustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water 176 Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled matehal wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning matehal Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting (ires involv ing this matehal If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet Dt-TERT-BUTYL PEROXIDE, (TECHNICALLY PURE) 4919213 ORGANIC PEROXIDE UN2102 Di-lert-butyl peroxide, (technically pure) is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite: but once ignited, it will bum with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the matenal may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burning of combustible ma terials. Under prolonged exposure to fire or heat containers of the ma tehal may explode. If material on fire or involved in fire Use water in flooding quantities as (og Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use `'alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the matehal Wear boots, protective gloves, and goggies Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this matehal If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the matehal is on fire or involved in fire evacuate for a radius of 2500 feet OIACETONE ALCOHOL 4909149 FLAMMABLE LIOUIO UN1148 Diacetone alcohol is a clear colorless liquid with a pleasant odor. It has a flash point of less than 100 deg. F. It is lighter than water and is soluble in water. Its vapors are heavier than air. April 1981 MCD 000009919 ff material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use 'alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and ofher sources of ignition away Keep material out ol water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vaoors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water DIACETONE ALCOHOL PEROXIDE, (NOT MORE THAN 4919234 57% IN SOLUTION WITH NOT MORE THAN 9% HYDROGEN PEROXIDE, NOT LESS THAN 26% DIACETONE ALCOHOL AND NOT LESS THAN 9% WATER: TOTAL ACTIVE OXYGEN CONTENT NOT MORE THAN 9%) ORGANIC PEROXIDE UN2163 Oiacetone alcohol peroxide, (not more than 57% in solution with not more than 9% hydrogen peroxide, not less than 26% diacetone alcohol and not less than 9% water: total active oxygen content not more than 9%) is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. The liquid or solution may require some effort to ignite: but once ignited, it will burn with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burning of com bustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with Hooding quantities of water Apply water from as far a distance as possible Use "alcohol " foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing aoparatus when fighting fires involv ing this material If contact with the material anticioated. wear full protective clothing Approach fire with caution Evacuation if the material is on fire or involved in fire evacuate for a radius of 2500 feet April 1981 MCD 000009920 DfACETYL 4909144 FLAMMABLE LIQUID UN2346 Diacetyl is a clear colorless liquid with a strong chlorine like odor. It has a flash point of 80 deg. F. It is lighter than water and soluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with Hooding quantities of water Apply water from as far a distance as possible Use alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, fiames. and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if withoui hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water DIAZINON (AGRICULTURAL INSECTTC10ES. NEC. 4941141 UQUIO) ORM-A NA2783 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Diazinon is a colorless to white liquid. It is used as a pesticide. It is a water emulsifiable liquid. It can cause illness by inhalation, skin ab sorption and/or ingestion, in case of damage to. or leaking from con tainers of this material contact the pesticide safety team network. Tele phone: 800-424-9300. tf material Involved in fire Extinguish tire using agent suitable for type of surrounding lire (Material itself does not bum or burns with difficulty.) If materiel not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts ot water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill Use natural barriers or oil spill control booms to limit spill motion If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates 177 DIAZINON (AGRICULTURAL INSECTICIDES, NEC, 4941142 OTHER THAN LIQUID) ORM-A NA2783 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-1/0.454) Diazinon is a colorless to white liquid absorbed on a dry carrier. It is used as a pesticide. It is a wettable powder It can cause illness by inhalation, skin absorption and or ingestion. In case ol damage to. or leaking from containers of this material contact the pesticide safety team network Telephone: 000-424-9300 If material involved in fire Extinguish tire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty ) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or lire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates it dissolved, apply activated carbon at ten times the spilled amount m region of 10ppm or greater concentration DIAZINON (INSECTICIDES, OTHER THAN 4941140 AGRICULTURAL, NEC) ORM-A NA2783 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Diazinon is a colorless to white liquid or the liquid absorbed on a dry carrier. It is used as a pesticide. It is a wettable powder or water emul- sifiable liquid. It can cause illness by inhalation, skin absorption and or ingestion. In case of damage to. or leaking from containers of this ma terial contact the pesticide safety team network. Telephone: 800-424- 9300. If material involved in fire Extinguish fire using agent suitable lor type of surrounding fire (Material itself does not burn or bums with difficulty.) If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear bools, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates If dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration 178 DIBENZYL PEROXYOICARBONATE. (NOT MORE THAN 87% WITH WATER) 4919235 ORGANIC PEROXIDE UN2149 Dibenzyl peroxydicarbonate. (not more than 87% with water) is a white solid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. It is easily ignited and bums with increasing rapidity as the fire progresses. It can form explosive mixtures with finely divided combus tible materials. It supports the burning of combustible materials. Under prolonged exposure to fire or heat containers of the matenal may explode. If material on fire or involved In fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" loam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled matenal before picking it up Personnel protection Avoid breathing dusts, and fumes from burning matenal Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet DIBORANE FLAMMABLE GAS, POISONOUS 4905420 UNI 911 Diborane is a colorless gas with an offensive odor. It is used in elec tronics. It is toxic by inhalation. Diborane is decomposed by water giving off hydrogen, another flammable gas and boric acid non-regulated ma terial. Its vapors are heavier than air. K material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use water spray to absorb vapors If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered April 1981 MCD 000009921 DIBORANE MIXTURES 4905425 FLAMMABLE GAS, POISONOUS UN1911 Diborane mixtures is a colorless gas with an offensive odor. It is used 5 electronics. Diborane is decomposed by water giving off hydrogen, another flammable gas. and boric acid, a non-regulated material. Their vapors are heavier than than air. It material on fire or involved In fire Do not extinguish fire unless flow can be stooped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use water spray to absorb vapors If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct ^ flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered ,2-DIBROMOETHANE (See ETHYLENE OIBROMID6 4940335) Environmental eonslderatfone--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates DICAMBA (AGRICULTURAL INSECTICIDES, NEC. 4963337 OTHER THAN LIQUID) ORM-E NA2769 ENVIRONMENTALLY HAZAROOUS SUBSTANCE (RQ-1000454) Dicamba is a white solid or the solid dissolve in a liquid carrier. It is used as a herbicide. It is a wettable powder. It can cause illness by inhalation, skin absorption and/or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone: 800-424-9300. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill II dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates DICAM8A (AGRICULTURAL INSECTICIOES, NEC, 4963334 LIQUID) ORM-E NA2769 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RCM000/454) Dicamba is a white solid dissolved in a liquid carrier. It is used as a herbicide. It is a water emulsifiable liquid, it can cause illness by inhal ation. skin absorption and/or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team net work. Telephone: 800-424-9300. if material involvad In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) tf material not Involved tit fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--lend spill Dig a. pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder April 1961 DICAMBA (INSECTICIDES, OTHER THAN 4963332 AGRICULTURAL. NEC) ORM-E NA2769 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100Q/454) Dicamba is a white solid or the solid dissolved in a liquid carrier. It is used as a herbicide. It is a wettable powder or water emulsifiable liquid. It can cause illness by inhalation, skin absorption and/or ingestion. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone: 800-424-9300. If material Involved In Are Extinguish lira using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) H material not involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land split Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates 179 MCD 000009922 DICETYL PEROXYDICARBONATE, (NOT MORE THAN 4919237 42%. STABLE DISPERSION. IN WATER) ORGANIC PEROXIDE UN2895 Dicetyl peroxydicarbonate. (not more than 42%. stable dispersion, in water) is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. The liquid or solution may require some effort to ignite; but once ignited, it will burn with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burn ing of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. It material on fire or involved In fire Use water in Hooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires invpiv- ing this material If contact with the material anticipated, wear lull protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet DICETYL PEROXYDICARBONATE. (TECHNICALLY 4919239 PURE) ORGANIC PEROXIDE UN2164 Dicetyl peroxydicarbonate, (technically pure) is a white solid. It ts used to manufacture paints, plastics, and rubber. It is insoluble in water. It is easily ignited and bums with increasing rapidity as the fire progresses, it can form explosive mixtures with finely divided combustible materials. It supports (he burning of combustible materials. Under prolonged ex posure to fire or heat containers of the material may explode. H material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use 'alcohol'' foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking rt up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet OICHLOBENIL (AGRICULTURAL INSECTICIOES, NEC, 4963809 LIQUID) ORM-E NA2769 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Dichlobenil is a white solid dissolved in a liquid carrier. It is used as a herbicide. It is a water emutsifiable liquid. It can cause illness by inhalation, skin absorption and/or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone: 800-424-9300. H material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) If materiel not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any matenal which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spilt If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and preapitates DICHLOBENIL (AGRICULTURAL INSECTICIDES, NEC. 4963814 OTHER THAN UQUIO) ORM-E NA2769 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Dichlobenil is a white sofid. It is used as a herbicide. It is a wettabie powder. It can causa illness by inhalation, skin absorption andor inges tion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone: 800-424-9300. tf material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any matenal which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Covet solids with a plastic sheet to prevent dissolving in rain or fire fighting water 180 April 1981 MCP 000009923 Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--water spill Use natural barriers or oil spill control booms to limit spill motion If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses ot pollutants and precipitates DICHLOBENIL (INSECTICIDES, OTHER THAN 4963805 AGRICULTURAL, NEC) ORM-E NA2769 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-IOOO'454) Dichlobeml is a white solid or the solid dissolved in a liquid earner. It is used as a herbicide. It is a wettabie powder or water emulsifiabie liquid It can cause illness by inhalation, skin absorption and or ingestion. In case of damage to. or leaking from containers of this matenai contact the pesticide safety team network. Telephone; 800-424-9300. 11 material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in ram or fire lighting water Environmental considerations--water spill (f dissolved, apply activated carbon at ten limes the spilled amount m region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates DICHLONE (AGRICULTURAL INSECTICIDES. NEC. 4960617 LIQUID) ORM-E NA2761 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Dichlone is a yellow crystalline solid dissolved in a liquid carrier. It is used as a fungicide. It is a water emuisifiabie liquid. K can cause illness by inhalation, skin absorption and or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone: 800-424-9300. H material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain How as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface (low using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder April 1961 MCD 000009924 DICHLONE (AGRICULTURAL INSECTICIDES, NEC. 4960616 OTHER THAN LIQUID) ORM-E NA2761 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1 0.4S4) Dichlone is a yellow crystalline solid. It is used as a fungicide. It is a wettabie powder. It can cause illness by inhalation, skin absorption and or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone: 800-424- 9300. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spilt Oig a pit. pond, tagoon. holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom if dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates OICHLONE (INSECTICIDES, OTHER THAN 4960618 AGRICULTURAL, NEC) ORM-E NA2761 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Dichlone is a yellow crystalline solid or the solid dissolved in a liquid earner. It is used as a fungicide. It is a wettabie powder or water emui sifiabie liquid. It can cause illness by inhalation, skin absorption material contact the pesticide safety team network. Telephone; 800-424-9300. If material involved In fire Extinguish lire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Continued on next pap* 181 Environmental consideration*--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spilt Use natural deep water pockets, excavated lagoons, or sand bag oarriers to trap material at bottom if dissolved, apply activated carbon at ten times the spilled amount m region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates OICHLOnOACETIC ACIO 4931420 CORROSIVE MATERIAL, ACIDIC UNI 764 Dichioroacetic acid is a colorless crystalline solid melting at 49 deg. F. It is soluble in water. It is corrosive to metals and tissue, if material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire ('Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Aoply water from as far a distance as possible if material not on fire and not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing DICHLOROACETYL CHLORIDE 4931735 CORROSIVE MATERIAL, ACIOIC, COMBUSTIBLE UN1765 Dichloroacetyl chloride is a colorless, fuming liquid with a pungent odor. It is combustible and has a flash point of 151 deg. F. Its vapors are irritating to the eyes and mucous membranes. It is decomposed by water to dichioroacetic acid and hydrochloric acid, corrosive materials, with release of heat. It is corrosive to metals and tissue. If material on fire or involved In fire Use dry chemical or carbon dioxide Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material Itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing 182 OICHLOROANILINE (POISONOUS SOUO, N.O.S.) 4921515 POISON B NA2811 Dichloroamline is an amber to brownish colored crystalline solid. It is used in the manufacture of dyes and pesticides. It is insoiube in water and is combustible. It is toxic by skin absorption and by inhalation (dust, etc.). Toxic oxides of nitrogen are produced during combustion of this material. tf material on fire or Involved in fire Use dry chemical or carbon dioxide Cool all affected containers with flooding quantities of water Use water in flooding quantities as fog tf material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material DICHLOROBENZENE, ORTHO, LIOUIO 4941127 ORM-A UNI 591 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100/45.4) Oichlorobenzene. ortho, liquid dear colorless liquid with a pleasant odor. It is used to make other chemicals, solvent, fumigant and insec ticide. and for many other uses. It is combustible and has a flash point of 150 deg. F. It is heavier than water and is soluble in water If materiel involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty ) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Apply "universal" gelling agent to immobilize spill Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates DICHLOROBENZENE, PARA, SOUO 4941129 ORM-A UN1592 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-100/45.4) Dichlorobenzene, para, solid is a white crystalline volatile solid having the odor of moth balls. It is used as a modi repellent, to make other chemicals, as a fumigant, and for many other uses. It is heavier than water and insoluble in water. It will bum though it may lake some effort to ignite. April 1981 MCD 000009925 If material involved In fire Extinguish fire using agent suitable lor type of surrounding fire (Material itself does not bum or bums with difficulty.) If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid matenal Cover solids with a plastic sheet to prevent dissolving in rain or (ire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates 2,4-OICHLOROBENZOYL PEROXIDE, (NOT MORE ` 4919243 THAN 52% AS A PASTE) ORGANIC PEROXIDE UN2138 2,4-dichlorobenzoyl peroxide, (not more than 52% as a paste) is a white solid, it is used to manufacture paints, plastics, and rubber. It is insoluble in water. It is easily ignited and bums with increasing rapidity as the fire progresses. It can form explosive mixtures with finely divided combustible materials, it supports the burning of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or Involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool ail affected containers with Hooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material if contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet April 1981 MCD 000009926 2,4-DICHLOROBENZOYL PEROXIDE, (NOT MORE THAN 52% IN SOLUTION) 4919244 ORGANIC PEROXIDE UN2139 2.4-dichlorobenzoyl peroxide, (not more than 52% in solution) is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite; but once ignited, it will bum with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burn ing of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode, if material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive ff material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily-contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material Is on fire or involved in fire evacuate for a radius of 2500 feet 2,4-DICHLOROBENZOYL PEROXIDE, (NOT MORE 4919242 THAN 75% WITH WATER) ORGANIC PEROXIDE UN2137 2,4-dichlorobenzoyl peroxide, (not more than 75% with water) is a white solid, ft is used to manufacture paints, plastics, and rubber, it is easily ignited and bums with increasing rapidity as the fire progresses. It can form explosive mixtures with finely divided combustible materials. It supports the burning of combustible materials. Under prolonged ex posure to lire or heat containers of the material may explode. H material on fira or Involved in fire Use water in Hooding quantities as fog Solid streams ol water may be ineHective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive II material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Continued on next page 183 Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when lighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material II contact with the material anticipated, wear full protective clothing DICHLOROBUTENE 4907605 FLAMMABLE LIQUID, CORROSIVE NA2924 Dichlorobutene is a clear colorless to straw colored liquid. It has a flash point of 80 deg. F. It is corrosive to metals and tissue. It is heavier than water and insoluble in water. Its vapors are heavier than air. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities ol water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If materiel not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1S00 feet If material leaking (not on fire), downwind evacuation must be considered DICHLOROBUTENE 4936312 CORROSIVE MATERIAL NA2924 Dichlorobutene is a clear colorless liquid. It is used to make other chemicals. It will burn though it may require some effort to ignite. It is corrosive to tissue. It is heavier than water and insoluble in water. It vapors are heavier than air. If materiel on fire or involved in fire Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use "alcohol" foam, carbon dioxide or dry chemical Use water spray to absorb vapors 184 MCD 000009927 DICHLORODIFLUOROMETHANE 4904516 NONFLAMMABLE GAS UN1Q28 Dichlorodifluoromethane is a colorless gas having a faint ethereal odor. It is shipped, as a liquid under its own vapor pressure. It is non combustible. It is heavier than air and can cause asphyxiation by the displacement of air. Contact with the liquid can cause frostbite. Toxic gases can be produced in fires involving this material. If material involved in fire Extinguish lire using agent suitable for type ol surrounding fire (Material itself does not bum or bums with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible K material not Involved in fire Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment DICHLORODIFLUOROMETHANE AND 4904534 OIFLUOROETHANE MIXTURE (CONSTANT BOIUNG MIXTURE) NONFLAMMABLE GAS UN2602 Dichlorodifluoromethane and difluoroethane mixture is a colorless gas having a faint ethereal odor, it is shipped as a liquefied gas under its own vapor pressure. DichlorodiftuoTomelhane is noncombustible', di fluoroethane is a flammable gas. The vapor of dichlorodifluoromethane is heavier than that of difluoroethane and both are heavier than air. They can asphyxiate by the displacement of air. Contact with the liquid can cause frostbite. Toxic gases can be produced in (ires involving this material. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved in Ere Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment April 1981 DICHLORODIFLUOROMETHANE- 4904S19 DICHLOROTETRAFLUOROETHANE MIXTURE NONFLAMMABLE GAS NA1956 Dichlorodifluoromethane-dichlorotetrafluoroethane mixture is a col* iriess gas having a fainr ethereal odor. It is shipped liquefied as a gas jnder its own vapor pressure. Both dichlofodilluoromethane and dich- lorotetrafluoroethane are noncombustible. The two gases are heavier than air and can asphyxiate by the displacement of air in a closed space. Contact with the liquid can cause frostbite. Toxic gases can be produced in fires involving this material. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible if material not Involved In fire Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment OICHLOROOIFLUOROMETHANE- 4904525 TRICHLOROMONOFLUOROMETHANEMONOCHLORODIFLUORO- METHANE MIXTURE NONFLAMMABLE GAS NA1956 Dichlorodifluoromelhane-trichloromonofluoromethane-monochlorodilluoromethane mixture is a colorless gas. It is shipped as a liquefied gas under its own vapor pressure. Its odor varies from none to faintly ethereal or carbon tetrachloride like odor. All three gases are noncombustible. They can asphyxiate by the displacement of air. Contact with the liquid can cause frostbite. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible if material not involved in fire Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment K DICHLORODIFLUOROMETHANE- 4904522 MONOCHLORODIFLUOROMETHANE MIXTURE NONFLAMMABLE GAS NA1956 Dichlorodifluoromethane-monochlorodiftuoromethane mixture is a col orless gas: odorless to a faint chloroform like odor, it r$ shipped as a liquefied gas under its own vapor pressure. Both gases are noncom bustible. They can asphyxiate by the displacement of air in a closed space. Contact with the liquid can cause frostbite. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment DICHLORODIFLUOROMETHANE- 4904528 TRICHLOROTRIFLUOROETHANE MIXTURE NONFLAMMABLE GAS NA1956 Dichlorodifluoromethane-trichtorotrifluoroethane mixture is a colorless odorless gas It is shipped as a liquefied gas under its own vapor pres sure Both gases are noncombustible. It can asphyxiate by the displace ment of air. Contact with the liquid can cause frostbite. If material involved in Are Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible II material not involved in fire Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment DICHLORODIFLUOROMETHANE- 4904531 MONOCHLOROTRIFLUOROMETHANE MIXTURE NONFLAMMABLE GAS NA19S6 Oichlorodifluoromethane-monochlorotrifluoromelhane mixture is a colorless gas with no odor to a faint ethereal-carbon tetrachloride odor. It is shipped as a liquefied gas under its own vapor pressure. Both gases are noncombustible. They can asphyxiate by the displacement of air. Contact with the liquid can cause frostbite. If material Involved In Are Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved In Are Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment April 1961 DICHLOROETHYL ETHER (POISONOUS 4921550 UQUIO.N.O.S.) POISON B NA2810 Dichlofoethyt ether is a dear colorless liquid with a chloroform-like odor. It is used in deaning compounds, in paints, in textile finishing, and as a general solvent. It is combustible and has a flash point of 131 deg. F. It is heavier than water and is insoluble in water. It is toxic by inhalation and skin absorption. If material on Art or involvad In Are Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities ol water Apply water from as far a distance as possible If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Continued on next pege 185 MCD 000009928 Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Oo not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material DICHLOBOETHYLENE 4909145 FLAMMABLE LIQUID UN1150 Dichtoroethyiene >s a clear colorless liquid with an ether-like odor. It has a flash point of 36-39 deg. F. it is heavier than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water m flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources ol ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body wtth copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material DICHLOROISOCYANURIC ACID (OXIDIZING 4918724 MATERIAL, N.O.S.) OXIDIZER UN1479 Dichloroisocyanuric acid is a white crystalline solid with an odor of chlorine, it is used as a dry bleach in household cleaning compounds and in swimming pool disinfectants. The material itself is noncombustible but if contaminated with combustible matenal ignition can result. It will accelerate the burning of combustible materials. Contact with ammonium compounds or hydrated salts can cause a very vigorous chemical re action. May vigorously react with small quantities of water releasing chlorine gas. Prolonged exposure of the matenal to fire or heat may result in its violent decomposition and rupturing of the container. It material on fire or Involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved In Are Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet 186 OICHLOROISOPROPYL ETHER 4936315 CORROSIVE MATERIAL, COMBUSTIBLE UN2490 Dichloroisopropyl ether is a colorless liquid. It is combustible and has a flash point of 185 deg. F. It is heavier than water and insoluble in water, It is corrosive to metals and tissue. If material on fire or Involved in fire Use water in flooding quantities as fog Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use 'alcohol'' foam, carbon aioxide or dry chemical Use water spray to absorb vaoors If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equioment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing DICHLOROPENTANE 4909147 FLAMMABLE LIQUID UN1152 Dichloropentane is a dear colorless to yellow liquid. It has a flash point of 90 deg. F. It is lighter than water and is insoluble m water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical K material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material 2,4-DICHLOROPHENOXYACETIC ACID 4941126 ORM-A NA2765 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100/45.4) 2,4-dichk>rophenoxyac6tic add & a white to yellow crystalline solid. It is used as a weed killer and defoliant. It is slightly soluble in water. It is non-combustible, if material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) April 1981 MCD 000009929 H material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in ram or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount m region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates tf material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing DICHLOROPROPANE (See PROPYLENE DICHLORIDE 4909269) 2,4-DICHLOROPHENOXYACETIC ACID ESTER 4962130 ORM-E NA276S ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100/45.4) 2.4-dichlorophenoxyacetic acid ester is a while solid. It is used as a herbicide and defoliant. It is slightly soluble in water. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water epill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates DICHLOROPHENYL TFIICHLOROSILANE 493422$ CORROSIVE MATERIAL, ACIDIC UN1766 Dichlorophenyl trichlorositane is a straw colored liquid with a pungent odor. Material will bum though it may require some effort to ignite. It is decomposed by moisture or water to hydrochloric acid with evolution of heat. It is corrosive to metals and tissue. If material on fire or Involved In fire Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible April 1961 DICHLOROPROPENE 4909255 FLAMMABLE LIQUID UN2047 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Dichloropropene is a clear colorless liquid. It is used to make other chemicals and as soil fumigant. It has a Hash point of 95 deg. F. It is heavier than water and insoluble in water. Its vapors are heavier than air. It weighs 10.2 pounds per gallon. If material on Art or involved in fire Use water in flooding quantities as fog Do not extinguish fire unless How can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with Hooding quantities ot water Apply water from as far a distance as possible Use loam, carbon dioxide or dry chemical If material not on Are and not involved in Are Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken paokages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear seif-contained breathing apparatus when fighting fires involv ing this material Environmental considarationa--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or loamed concrete Absorb bulk liquid with fly ash. cement powder, sawdust, or com mercial sorbents Apply fluorocarbon-water foam to diminish vapor and fire hazard Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--sir spill Apply water spray or mist to knock down vapors Combustion products include corrosive or toxic vapors Thermal decomposition to phosgene can occur 187 ,00993 OOO DiCHLOROPROPENE ANO PROPYLENE DICHLORIDE 4907640 MIXTURE FLAMMABLE LIQUIO. CORROSIVE NA2047 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Dichioropropene and propylene dichlonde mixture is a colorless liquid with a chloroform like odor li is flammable and has a flash point below 100 deg. F. (t is heavier than water and insoluble in water It is corrosive to metals and tissue, it weighs 9.9 pounds per gallon. 11 material on fire or involved in fire Use water m flooding Quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use "alcohol ' foam. carbon dioxide or dry chemical Use water spray to absorb vapors If material not on fire and not involved in fire Keep sparks, flames, and other sources ol ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the matenal anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with tty ash. cement powder, sawdust, or com mercial sorbents Apply fluorocarbon-water foam to diminish vapor and fire hazard Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap matenal at bottom Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--sir spill Apply water spray or mist to knock down vapors Combustion products include corrosive or toxic vapors Thermal decomposition to phosgene can occur 2,2-OICHLOROPROPIONIC ACID 49214$$ CORROSIVE MATERIAL NA1790 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-S000/2270) 2.2-dichtoroproptonic acid is a cotoriess liquid, ft is used as a herbicide. It is soluble in water. It is corrosive to metals and tissue. It weighs 11.6 pounds per gallon. If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use water spray to absorb vapors If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash. or lime 186 Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water if contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid wilh fly ash. cement powder, sawdust, or com mercial sorbents Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses o< pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors DICHLORVOS (AGRICULTURAL INSECTICIDES, NEC. 4921534 LIQUID) POISON B NA2783 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-10/4.54) Dichlorvos is a colorless to amber liquid. It is used as a pesticide, it is a water emulsifiable liquid, ft is toxic by inhalation, skin absorption, and or ingestion. In case of damage to. or leaking from containers ot this material contact the pesticide safety team network. Telephone: 800- 424-9300. If material on fire or involved In fire Do not extinguish tire unless flow can be stopped Use water in Hooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as tar a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop teak it without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any materiai which may have contacted the body with copious amounts ol water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface How using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors April 1981 MCD 000009931 DICHLORVOS (AGRICULTURAL INSECT1CIOES, NEC. 4921535 OTHER THAN LIQUID) POISON B NA2783 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-10 4.54) Dichlorvos is a colorless to amber liquid absorbed on a dry carrier. It is used as a pesticide. It is a wettable powder. It is toxic by inhalation, skin absorption, and or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone: 800-424-9300. If material on fire or involved in fire Extinguish tire using agent suitable tor type of surrounding fire (Material itself does not burn or burns with difficulty.| Use water in flooding quantities as fog Use alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving m ram or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated tagoons. or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten limes the spilled amount in region of tOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates DICHLORVOS (INSECTICIDES. OTHER THAN AGRICULTURAL. NEC) 4921536 POISON B NA2783 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-10 4.54) Dichlorvos is a colorless to amber liquid or the liquid absorded on a dry carrier. It is used as a pesticide. It is a wettable powder or water emulsifiable liquid. It is toxic by inhalation, skin absorption, and or inges tion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone: 800-424-9300. If materiel on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing April 1981 Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount m region of lOppm or greater concentration Use mechanical dredges or >'ts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to <nock down vapors DICHLORVOS MIXTURE, ORY (AGRICULTURAL 4921537 INSECTICIDES, NEC. OTHER THAN LIQUID) POISON B NA2783 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-10 4.54) Dichlorvos mixture, dry is a colorless to amber liquid absorbed on a dry earner It is used as a pesticide It is a wetable powder. It is toxic by inhalation, skin absorption, and or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone: 800-424-9300 If material on fire or Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting tires involv ing this material If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or tire fighting water Environmental considerations--watar spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap materia! at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates OICUMYL PEROXIDE (50% PEROXIOE) 4919545 ORGANIC PEROXIDE NA2121 Dicumyl peroxide (50% peroxide) is a colorless to straw colored liquid. It may take some effort to ignite but once ignited it bums with increasing vigor as the fire progresses. It strongly supports the burning of com bustible materials. If the containers of the peroxide are exposed to fire or heat for prolonged periods, they may explode. Continued on next page 189 MCD 000009932 if material on fire or involved in fire Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Keep spilled material wet Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Oo not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this matenal If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet DICYCLOHEXYL PEROXYDICARBONATE, (NOT MORE 4919248 THAN 91*4 WITH WATER) ORGANIC PEPOXIDE UN2153 Dicyciohexv eroxydicarbonate. (not more than 91% with water) is a white solid, it is used to mahufacture paints, plastics, and rubber, it is insoluble in water. It is easily ignited and bums with increasing rapidity as the fire progresses. It can form explosive mixtures with finely divided combustible materials. It supports the burning of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning matenal Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet OICUMYL PEROXIDE, DRY 4919540 ORGANIC PEROXIDE UN2121 Dicumyl peroxide, dry is a buff colored crystalline or lumpy solid. It is easify ignited and once ignited it bums with increasing vigor as the fire progresses. It strongly supports the burning of combustible material. If the containers of the peroxide are exposed to fire or heat for prolonged periods, they may explode. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Coot all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in Are Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Personnel protection Avoid breathing vapors or dusts Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the matenal is on fire or involved in fire evacuate for a radius of 2500 feet DICYCLOHEXYL PEROXYDfCARBONATE, 4919247 (TECHNICALLY PURE) ORGANIC PEROXIDE UN2152 Dicyclohexyl peroxydcarbonate, (technically pure) is a white solid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water, ft is easily ignited and bums with increasing rapidity as the fire progresses, it can form explosive mixtures with finely divided combus tible materials, it supports the burning of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or involved in Are Use water in flooding quantities as tog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive tf material not on Are and not Involved In Are Keep sparks, flames, and other sources of ignition away Keep material out of water sources end sewers Keep spilled material wet Wet spilled material before picking it up 190 MCD 000009933 April 1981 Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate 'or a radius o! 2500 feet DIELDRIN (AGRICULTURAL INSECTICIDES, NEC, 4941134 LIQUID) ORM-A NA2761 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Dieldnn is a light tan solid dissolved in a liquid carrier, it is used as a pesticide. It is a water emulsitiable liquid. It can cause illness by inhalation, skin absorption and/or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone: 800-424-9300. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spiil Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill Use natural barriers or oil spiil control booms to limit spill motion If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates DiELORIN (AGRICULTURAL INSECTICIDES, NEC, 4941135 OTHER THAN LIQUID) ORM-A NA2761 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-I/O.454) Dieldnn is a light tan solid. It is used as a pesticide. It is a wettable powder. It can cause illness by inhalation, skin absorption and.or inges tion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone: 800-424-9300. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vaoors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1961 MCD 000009934 Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates DIELDRIN (INSECTICIDES, OTHER THAN 4941133 AGRICULTURAL. NEC) ORM-A NA2761 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Dteldrin is a light tan solid or the solid dissolved in a liquid carrier. It is used as a pesticide. It is a wettable powder or water emulsifiable liquid. It can cause illness by inhalation, skin absorption and. or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone: 800-424-9300. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) If material not Involvad In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--^water spilt Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates DIESEL FUEL (See FUEL OIL 4915113) DIETHYL BENZENE (COMBUSTIBLE LIQUID, N.O.S.) 4913135 COMBUSTIBLE LIQUID NA1993 Dietheylbenzene is a dear colorless liquid with an aromatic odor. It has a flash point of 140 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on firs or Involved in Are Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical ContkuMd on next pogo 191 if material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Build dikes to contain flow as necessary Attempt to stop teak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soao and water DIETHYL DICHLOROSILANE 4907609 FLAMMABLE LIQUIO. CORROSIVE UN1767 Diethyl dichlorosilane is a colorless liquid with a pungent odor. It has a flash point of 77 deg. F. It is readily decomposed by water to hydro chloric acid with evolution of heat. It is corrosive to metals and tissue, its vapors are heavier than air. If material on fira or involved in fire Do not extinguish fire unless flow can be stopped Use "alcohol" foam, carbon dioxide or dry chemical Do not use water on material itself Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feel If material leaking (not on fire), downwind evacuation must be considered DIETHYL PEROXYDICARBONATE, (NOT MORE THAN 4919251 27% IN SOLUTION) ORGANIC PEROXIDE UN2175 Diethyl peroxydicarbonate. (not more than 27% in solution) is a col orless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effon to ignite; but once ignited, it will burn with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burn ing of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use '"alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet DIETHYL KETONE FLAMMABLE UQUID 4909150 UN1156 Diethyl ketone is a clear colorless liquid with an acetone-like odor. It has a flash point of 55 deg. F. It is lighter than water and slightly soluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Soiid streams of water may spread fire Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers 192 DIETHYL SULFATE (CORROSIVE LIQUID. N.O.S.) 4933320 CORROSIVE MATERIAL, ACIDIC UN1760 Diethyl sutlate is a clear colorless liquid with a peppermint odor. It will bum though it may require some effort to ignite. It is heavier than water and is slowly decomposed by water to ethyl alcohol, a flammable liquid, and ethyl sulfate. It is corrosive to metals and tissue. If material on fire or Involved in fira Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with Hooding quantities of water Apply water Irom as far a distance as possible April 1961 MOD 000009935 N material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing OIETHYLAMINE 4907815 FLAMMABLE LIQUID, CORROSIVE, BASIC UN1154 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Diethylamme is a clear colorless liquid with an ammonia like odor. It has a flash point of *15 deg. F. It is a respiratory irritant and is corrosive to the eyes and skin. It is lighter than water and soluble in water. Its vapors are heavier than air. Toxic oxides of nitrogen are produced during combustion of this material, ft weighs 5.9 pounds per gallon. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply wafer from as far a distance as possible Use "alcohol'' foam, carbon dioxide or dry chemical Use water spray to absorb vapors If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fees involv ing this material Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash. cement powder, sawdust, or com mercial sorbents Neutralize with sodium bisulfate (nahso4) Environmental considerations--water spill Add sodium bisulfate If dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration April 1981 Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--sir spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment DIETHYLAMINOETHANOL (COMBUSTIBLE LIQUID, 4913186 N.O.S.) COMBUSTIBLE LIQUID NA1993 Diethylamrnoethanol is a clear colorless liquid. <t is used to make other chemicals. i( has a flash point of 140 deg. F. It is lighter than water and is soluble in water, its vapors are heavier than air. Toxic oxides of nitrogen are produced dunng combustion of this material. If material involved In fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool ail affected containers with flooding quantities o< water Apply water from as far a distance as possible For scattered burning fusees, smother in dirt If material not on fire and not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Keep upwind Avoid breathing vapors Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the materia! anticipated, wear full protective clothing DIETHYLENETRIAMINE (CORROSIVE LIQUID. N.O.S.) 4935631 CORROSIVE MATERIAL. BASIC UNI 760 Diethyienetriamine is a yellow colored liquid with an ammonia-like odor. It is used as a solvent for plastics and dyes and in chemical synthesis. It is lighter than water and soluble in water. It will bum though it may take some effort to ignite, t is corrosive to metals and tissue. Its vapors are heavier than air. Toxic oxides ol nitrogen are produced during combustion of this material. If material on fire or Involved in fire Do not extinguish lire unless Ifow can be stopped Use water in flooding quantities as tog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, llamas, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain (low as necessary Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing 193 mcd 0009936 DIETHYLHYDROXYLAMINE (COMBUSTIBLE UOUIO. 4913185 N.O.S.) COMBUSTIBLE LIQUID NA1993 Diethylhydroxylamine is a dear colorless liquid. It is used in photog- rapny and as a corrosion inhibitor. It has a (lash point o! 113 deg. F, it is lighter than water and is soluble in water, its vapors are heavier than air. Toxic oxides o( nitrogen are produced during combustion of this material. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water m flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol' foam. cart>on dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Avoid breathing vapors Avoid bodily contact with the material Wear bools, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing 1.1 OIFLUORO-1-CHLOROETHANE (See DIFLUOROMONOCHLOROETHANE 4904552) DIFLUOROETHANE 4905716 FLAMMABLE GAS UNI 030 Difluoroethane is colorless, odorless gas shipped as a liquefied gas under its vapor pressure. Contact with the liquid can cause frostbite, ft is easily ignited, its vapors are heavier than air and a flame can travel back to the source of leak very easily. This leak can be either a liquid or vapor leak. It can asphyxiate by the displacement of air. Under fire conditions the cylinders or tank cars may violently rupture and rocket, If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire end not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment Wear self-contained breathing apparatus when fighting fires involv ing this material Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet If material leaking (not on fire), downwind evacuation must be considered 194 DIFLUOROMONOCHLOROETHANE FLAMMABLE GAS 4905719 UN2517 Difluoromonochloroethane is a colorless gas shipped as a liquefied gas under its vapor pressure. Contact with the liquid can cause frostbite. It is easily ignited. Its vapor is heavier than air and a flame can travel back to the source of leak very easily. The leak can either be a liquid or vapor leak. It can asphyxiate by the displacement of air. Under fire conditions the cylinders or tank cars may violently rupture or rocket. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as log Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible ft material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Oo not handle broken packages without protective equipment Wear self-contained breathing apparatus when fighting fires involv ing this material Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet If material leaking (not on fire), downwind evacuation must be considered DIFLUOROPHOSPHORIC ACID. ANYDROUS 4930214 CORROSIVE MATERIAL, ACIDIC UN1768 Difluorophospboric acid is a colorless fuming liquid. It is soluble m water. It is corrosive to metals and tissue. If material involved in firm Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible if material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water if contact with the material anticipated, wear fufl protective clothing 2.2-OiHYDROPEROXY PROPANE. (NOT MORE THAN 4919253 25% WITH INERT ORGANIC SOLID) ORGANIC PEROXIDE UN2178 2.2-dihydroperoxy propane, (not more than 25% with inert organic solid) is a white solid. It is used to manufacture paints, plastics, and rubber. It is slightly soluble in water. It is easily ignited and bums with increasing rapidity as the fire progresses. It can form explosive mixtures with finely divided combustible materials. It supports the burning of com bustible materials. Under prolonged exposure to tire or heat containers of the material may explode. April 1981 MCD 000009937 If material on fire or Involved In fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feel DIHYDROPYRAN 4908240 FLAMMABLE LIQUID UN2376 Dihydropyran is a clear colorless liquid with an ethereal odor. It has a flash point of 0 deg. F. It is lighter than water and slightly soluble in water. Its vapors are heavier than air. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers Build dikes to contain (low as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered DIISOBUTYL KETONE 4913140 COMBUSTIBLE LIQUI0 UN1157 Diisobutyl ketone is a clear colorless liquid. It has a flash point of 140 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If materiel on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog April 19S1 Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water DHSOBUTYLAMINE (FLAMMABLE LIQUID, N.O.S.) 4909177 FLAMMABLE LIQUID UNI 993 Diisobutylamine is a clear colorless liquid with a fish like odor, it has a flash point of 85 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. Toxic oxides of nitrogen are produced during combustion. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as tog Solid streams of water may spread fire Cool all affected containers with Hooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes lo contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material DIISOBUTYLCARBINOL (COMBUSTIBLE UQUID, 4913119 N.O.S.) COMBUSTIBLE UQUID UNI 987 Diisobutyicarbinoi is a odorless liquid, it has a flash point of 162 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in Hooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" loam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Continued on next page 195 MCD 000009938 Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet DIISOBUTYLENE (FLAMMABLE LIQUID, N.O.S.) 4909209 FLAMMABLE LIQUID UNI 993 Diisobutylene is a clear colorless liquid with a petroleum-like odor is used m the manufacture of other chemicals. It has a flash point of 10 deg. F it is lighter than water and insoluble in water. Its vapors are heavier than air If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water DIIS08UTYRYL PEROXIDE, (NOT MORE THAN 52% IN 4919255 SOLUTION) ORGANIC PEROXIDE UN21B2 Diisobutyryl peroxide, (not more than 52% in solution) is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite; but once ignited, it will bum with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction, ft supports the burn ing of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol" foam, carbon dioxide or dry chemical Dangerously explosive if material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 196 DIISOOCTYL ACID PHOSPHATE 4933325 CORROSIVE MATERIAL, ACIDIC, COMBUSTIBLE UN1902 Diisooctyl acid phosphate is a colorless liquid. It will burn though it may require some effort to ignite. It is corrosive to metals and tissue If material on fire or involved in fire Use dry chemical, carbon dioxide, or dry sand Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors If material not on fira and not involved in fire Keep sparks, (lames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting (ires involv ing this material If contact with the material anticipated, wear full protective clothing DtlSOPROPYL ETHER 4900195 FLAMMABLE UQUIO UN1159 Diisopropyf ether is a dear colorless liquid with an ethereal odor. It has a flash point of -18 deg. F. On prolonged standing in contact with air peroxides may form which may explode spontaneously or if heated. It is lighter than water and slightly soluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as log Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If materiel not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1981 MCD 000009939 Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius ol 1500 feet If material leaking (not on fire), downwind evacuation must be considered DIISOPROPYLAMINE 4909148 FLAMMABLE LIQUID UN1158 Diisopropylamine is a clear colorless liquid with an ammonia-like odor, it is used to make other chemicals, it has a flash point of 30 deg. F. It is lighter than water and is soluble m water. Its vapors are heavier than air Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as tog Solid streams of water may be ineffective Cool all affected containers with flooding quantities ol water Apply water from as far a distance as possible Use "alcohol" loam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain fk>w as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing OIISOPROPYLBENZENE HYDROPEROXIDE SOLUTION 4919130 (NOT OVER 60% PEROXIDE) ORGANIC PEROXIDE UN2171 Diisopropylbenzene hydroperoxide is a colorless to pale yellow liquid. It must be shipped in a non-volatile solvent not exceeding 60% con centration. It may take some effort to ignite but once ignited it bums with increasing vigor as the fire progresses. It strongly supports the burning of combustible materials. Under prolonged exposure to heat or fire con tainers of material can explode. Chemical substances can cause a vi olent chemical reaction. It supports the burning of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or Involved in Are Use water in Hooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles April 1981 Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate tor a radius of 2500 feet DIISOTRIDECYL PEROXYDICARBONATE. 4919257 (TECHNICALLY PURE) ORGANIC PEROXIDE UN2869 Diisotndecyl peroxydicarbonate, (technically pure) is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite; but once ignited, it will burn with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burning of com bustible materials. Under prolonged exposure to fire or heat containers of the material may explode. It material ori fire or Involved In fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive if material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet DIMETHYL CARBONATE 49091S4 FLAMMABLE LIQUID UN1161 Oimethyl carbonate is a clear, colorless liquid with a pleasant odor. H is used to make other chemicals and as a special purpose solvent. It has a Hash point of 66 deg. F. It is heavier than water and slightly soluble in water. Its vapors are heavier than air. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Continued on next page 197 MCD 00009940 if material not on fire and not Involved in fire Keep sparks, (lames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet If material leaking (not on fire), downwind evacuation must be considered DIMETHYL CHLOROTHIOPHOSPHATE 4933319 CORROSIVE MATERIAL. POISONOUS NA2922 Dimethyl chlorothiophosphate is a colorless to light amber liquid. It is used to make other chemicals, as a corrosion inhibitor, as a fuel and lubricant additive, and for may other uses. It is slightly soluble in water. It is corrosive to metals and tissue. It is toxic by inhalation, skin ab sorption, and/or ingestion. If material involved in fire Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with Hooding quantities of water Apply water from as far a distance as possible If material not involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water or material itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material - If contact with the material anticipated, wear full protective dothing DIMETHYL ETHER 4905725 FLAMMABLE GAS UN1033 Dimethyl ether is a colorless gas with a faint ethereal odor. It is shipped as a liquefied gas under its vapor pressure. Contact with the liquid can cause frostbite. It is easily ignited, its vapors are heavier than air and a flame can flash back to the source of leak very easily. The leak can either be liquid or vapor leak. It can asphyxiata by lha displacement of air. Under fire conditions the cylinder or tank car may violently rupture. If material on fire or Involved in fire Do not extinguish fire unless fk7w can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on Are and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors 198 DIMETHYL HYDRAZINE. UNSYMMETRICAL 4906210 FLAMMABLE LIQUIO, POISONOUS, CORROSIVE THERMALLY UNSTABLE UN1163 Unsymmetrical dimethylhydrazine is a clear colorless liquid with an ammonia like odor. It is used as a rocket propellant, to make other chemicals, and for many other uses. It has a flash point of 0. deg. F. It is flammable over a wide range of vapor-air concentrations. It may ignite spontaneously in contact with oxidizers. The vapors are toxic and attack the eyes and respiratory system. The liquid is corrosive to the skin. It is lighter than water and soluble in water. The vapors are heavier than air. Prolonged exposure of containers of the material to fire or heat may result in their violent rupturing and rocketing due to the decom position of the material. Toxic oxides of nitrogen are produced during combustion of this material. H material on fire or Involved In fire Do not extinguish tire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical H material not on fire and not Invofvad in fira Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective dothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If firs becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 5000 feet If material leaking (not on fire), downwind evacuation must be considered DIMETHYL PHOSPHOROCHLORIDOTHIOATE (See OIMETHLYL CHLOROTHIOPHOSPHATE 4933319) DIMETHYL SULFATE 4933322 CORROSIVE MATERIAL, ACIDIC, COMBUSTIBLE UN1595 Dimethyl sulfate is a colorless oily liquid, odorless to a faint onionlike odor It is a combustible liquid and has a flash point of 182 deg. F. It is slightly soluble in water and decomposed by water to give sulfuric add with evolution of heat. It Is corrosive to metals and tissue. April 1981 MCD 000009941 tf material on fire or Involved In fire Use dry chemical, carbon dioxide, or dry sand Do noi use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing 2,5-0<METHYL2,5-0{-<BENZ0YLPER0XY) HEXANE, (NOT MORE THAN 82% WITH INERT SOLID) 4919260 ORGANIC PEROXIDE UN2173 2,5-dimethy1-2,5-di-(benzoylperoxy) hexane, (not more than 82% with inert solid) is a white solid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. K is easily ignited and bums with increasing rapidity as the fire progresses. It can form explosive mixtures with finely divided combustiblematerials. it supports the burning of com bustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If materiel on fire or Involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this matehal If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet DIMETHYL SULFIDE 4908151 FLAMMABLE LIQUID UN1154 Dimethyl sulfide is a clear colorless to straw colored liquid with a disagreeable odor. It has a flash point of less than 0. deg. F. It is lighter than water and slightly soluble in water. Its vapors are heavier than air. If material on fire or involved In fire Do not extinguish lire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with fkxxfing quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered April 1981 2,5-DIMETHYL-2,5-DI-(BENZOYLPEROXY) HEXANE, 4919259 (TECHNICALLY PURE) ORGANIC PEROXIDE UN2172 2,5-dimethy1-2,5-di-(benzoy1peroxy) hexane, (technically pure) is a white solid. It is used to manufacture paints, plastics, and rubber, it is insoluble in water. It is easily ignited and bums with increasing rapidity as the fire progresses. It can form explosive mixtures with finely divided combustible materials. It supports the burning of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or Involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Continued on next pago 199 MCD 000009942 Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Oo not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear sell-contained breathing apparatus when fighting fires involv ing this material if contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet 2.5-OIMETHYL-2,$-DI-(TERT-BUTYLPEROXY) HEXANE, 4919263 (NOT MORE THAN 52% WITH INERT SOLID) ORGANIC PEROXIDE UN2156 2.5-dimeihyl-2,5-di-(tert-butylperoxy) hexane, (not more than 52% with inert solid) is a white solid, it is used to manufacture paints, plastics, and rubber. It is insoluble in water. It is easily ignited and burns with increasing rapidity as the lire progresses. It can form explosive mixtures with finely divided combustible materials. It supports (he burning of com bustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or Involved In fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use ' alcohol" foam, carbon dioxide or dry chemicai Dangerously explosive If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material < Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting Ikes involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet 2,5-OIMETHYL-2.5*OI-(TERT8UTYLPEROXY) HEXANE, 4919262 (TECHNICALLY PURE) ORGANIC PEROXIDE UN2155 2.5-dimethyl-2.5-di-(teri-butylperoxy) hexane, (technically pure) is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite; but once ignited. H will bum with Increasing rapidity as the fire progresses, if spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burn ing of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. 200 If material on fire or Involved In fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" loam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Oo not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet 2,5-OIMETHYL-2,$-DI-(TERT-BUTYLPEROXY)HEXYNE* 4919265 3, (NOT MORE THAN 52% WITH INERT SOLID) ORGANIC PEROXIDE UN2159 2,S-dimethy1-2.5di-(tert-buty!peroxy)hexyne-3. (not more than 52% with inert solid) is a white solid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. It is easily ignited and bums with increasing rapidity as the fire progresses. It can form explosive mixtures with finely divided combustible materials. It supports the burning of com bustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or involved in fire Use water in Hooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Appiy water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire end not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet April 198, MCD 000009943 2t5-OIMETHYL-2,5-OHTERT-BUTYLPEROXY)HEXYNE* 4919264 3. (TECHNICALLY PURE) ORGANIC PEROXIOE UN2156 2,5-dimethyl-2,5-di-(tert-butylperoxy)he)cyne-3, (technically pure) is a colorless to pale yellow liquid. It is used lo manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite: but once ignited, it will burn with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burn ing of combustible materials. Under prolonged exposure to tire or heal containers of the material may explode. if material on fire or Involved In fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'' loam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation II the material is on fire or involved in fire evacuate for a radius of 2500 feet 2,S>D(METHYL*2,5*OI{2-ETHYLHEXANOYLPEROXY) 4919258 HEXANE, (TECHNICALLY PURE) ORGANIC PEROXIDE UN21S7 2.5-dimethyl-2,5-di-{2-ethy1hexanoylperoxy| hexane, (technically pure) is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite; but once ignited, it will bum with increasing rapidity as the fire progresses. If spilled on combustible materials, spon taneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burning of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. K material on fire or Involved In fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not Involved in fire Keep sparks, (lames, and other sources of ignition away Keep material out ol water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1981 mcd OOOOO9944 Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet 2.5-OIMETHYL.2.5-OIHYDROPEROXY HEXANE. (NOT MORE THAN 82% WITH WATER) 4919261 ORGANIC PEROXIDE UN2174 2.5-dimethyl-2.5-dihydroperoxy hexane, (not more than 82% with water' is a white solid. It is used to manufacture paints, plastics, and rubber. It is insoluble m water. It is easily ignited and burns with increas ing rapidity as the fire progresses. It can form explosive mixtures with finely divded combustible materials. It supports the burning of combus tible materials. Under prolonged exposure to fire or heat containers of the matenal may explode. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol" foam, carbon dioxide or dry chemical Dangerously explosive tf material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in Tire evacuate for a radius ot 2500 feet DIMETHYLAMINE, ANHYDROUS 4905510 FLAMMABLE GAS, CORROSIVE UN1032 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Dimethylamine anhydrous is a colorless gas with a fish-like odor at low concentrations changing to ammonia-like odor at higher concentra tions. it is used to make other chemicals, as a solvent, as a solvent, and for many other uses. It is shipped as liquefied gas under its vapor pressure. Contact with the liquid can cause frostbite or chemical type bums. The gas itself is corrosive and it is soluble in water to form flammable corrosive solutions. It is easily ignited. Its vapor is heavier than air and a flame can flash back to the source of leak very easily It can asphyxiate by the displacement of air. Under fire conditions the cylinders or tank cars may rupture and rocket. Toxic oxides of nitrogen are produced during combustion of this material. It weighs 5.5 pounds per gallon. If malarial on lire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as log Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Continued on next page 201 It material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Wear fuli protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet If material leaking (not on fire), downwind evacuation must be considered Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid matenal Dike surface How using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash. cement powder, sawdust, or com mercial sorbents Neutralize with sodium bisulfate (nahso4) Environmental considerations--water spill Use natural barriers or oil spill control booms to limit spill motion Use surface active agent (e.g. detergent, soaps, alcohols) to com press and thicken spilled material Inject "universal" gelling agent to solidify encircled spill and increase effectiveness of booms if dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Add sodium bisulfate Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations---air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment DIMETHYLAMINE, AQUEOUS SOLUTION 4907820 FLAMMABLE LIQUID, CORROSIVE, BASIC UN1160 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Dimethylamine, aqueous solution is the solution of dimethylamine. a gas. in water and has an odor ranging from a fish-like to ammonia-like as the vapor concentration increases. A 25% solution has a flash point of 54 deg. F. It is corrosive to the skin and eyes. The solution is lighter than water and soluble in water. Its vapors are heavier than air. Toxic oxides of nitrogen are produced during combustion of this material. It weighs 7.3 pounds per gallon. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as log Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Use water spray to absorb vapors If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts ol water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking {not on tire), downwind evacuation must be considered Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash, cement powder, sawdust, or com mercial sorbents Apply "universal" gelling agent to immobilize spill Neutralize with sodium bisulfate (nahso4) Environmental considerations--water spill Add sodium bisuifate If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment DIMETHYLAMINIOETHYL METHACRYLATE 4912218 (COMBUSTIBLE LIQUID, N.O.S.) COMBUSTIBLE LIQUID NA1993 POLYMERIZABLE Dimethylaminioethyl methacrylate is a clear colorless liquid. It is used to make plastics, in textiles, and for many other uses, its vapors are irritating to eyes and mucous membranes. It has a flash point of 165 deg. F. It is lighter than water and is insoluble in water, its vapor are heavier than air. If it becomes contaminated or is subject to heat, it may polymerize, if this polymerization takes place inside a container, the container may violently rupture, toxic oxides of nitrogen are produced during combustion of this material. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical H material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water OIMETHYLAMINOETHANOL (COMBUSTIBLE LIQUID, 4913184 N.O.S.) COMBUSTIBLE UOUIO NA1993 Dimethylaminoethanol is a dear colorless liquid having a fish-like odor, it is used to make other chemicals. If has a flash point of 105 deg. F. It is lighter than water and is soluble in water, its vapors are heavier than air. Toxic oxides of nitrogen are produced during combustion of this material. 202 April 1981 MOD 000009945 If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool ail affected containers with Hooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matehal which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the matehal anticipated, wear full protective clothing 2.3- OIMETHYLBUTANE 4908275 FLAMMABLE LIQUID UN2457 2, 3-dimethylbutane is a clear colorless liquid with a petroleum odor. It has a flash point of -20 deg. F. It is lighter than water and insoluble in water, its vapors are heavier than air. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep matehal out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matehal which may have contacted the body with copious amounts of water or soap and water Evacuation if fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If matehal leaking (not on fire), downwind evacuation must be considered 1.4-DIMETHYLCYCLOHEXANE 4909156 FLAMMABLE LIQUID UN2263 1,4-dimethylcyclohexane is a dear, colorless liquid with a petroleum like odor. It has a flash point of 51 to 61 deg. F. It is lighter than water and is insoluble in water, its vapors are heavier than air. ff material on Ore or involved in Ore Do not extinguish fire unless flow can be slopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If materiel not on fire and not Involved In Ore Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers April 1981 Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water DIMETHYLDICHLOROSILANE 4907610 FLAMMABLE LIQUID, CORROSIVE, ACIDIC UN1162 Oimethyldichlorosilane is a colorless fuming liquid with a pungent odor. It has a flash point of 16 deg. F. Vapor and liquid can cause bums. It is heavier than water and is decomposed by water to form hydrochloric acid, a corrosive material. Its vapors are heavier than air. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use "alcohol" foam, carbon dioxide or dry chemical Cool all affected containers with flooding quantities of water Apply water from as tar a distance as possible Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors It material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep matehal out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Do not use water on matehal itself Neutralize spilled matehal with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct Hamo evacuate tor a radius of 1500 feet If matehal leaking (not on fire), downwind evacuation must be considered DIMETHYLETHYLAMINE (FLAMMABLE LIQUIO, 4907625 N.O.S.) FLAMMABLE UQUID UNI 993 Dimethylethylamine is a dear colorless liquid with a strong odor that can vary from ammonia to lish-like. It is used in the manufacture of other chemicals. It has a flash point of 10 deg.f. Its vapors are irritating to the eyes and mucous membranes. It is lighter than water and soluble in water. Its vapors are heavier than air. Toxic oxides of nitrogen are produced during combustion of this material, ff material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'' foam, carbon dioxide or dry chemical Use water spray to absorb vapors Continued on next page 203 MCD 000009946 If material not on fire and not involved In Are Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered D1METHYLHEXANE DIHYDROPEROXIDE, (WITH 18% 4919140 OR MORE WATER) ORGANIC PEROXIOE UN2174 Dimethythexane dihydroperoxide solution is a slurry or sludge of white crystals. Wet. the material requires some effort to ignite, but once ignited it bums very rapidly. Dry, the material is very easily ignited. In either condition it strongly supports the burning of combustible materials. Under prolonged exposure to heat or fire containers of the material can explode. If material on fire or involved In fire Use water in Hooding quantities as log Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out ol water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and lumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation II the material is on fire or involved in fire evacuate for a radius of 2500 feet DIMYRISTYL PEROXYOICARBONATE, (NOT MORE 4919270 THAN 22%, STABLE DISPERSION, IN WATER) ORGANIC PEROXIDE UN2892 Dimyristyl peroxydicarbonate. (not more than 22%. stable dispersion, in water) is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. The liquid or solution may require some effort to ignite; but once ignited, it will bumwith increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burn ing of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. 204 H material on fire or involved In fire Use water in flooding quantities as log Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive It material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the matenai Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach lire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet . DIMYRISTYL PEROXYDICARBONATE, (TECHNICALLY 4919269 PURE) ORGANIC PEROXIDE UN2S9S Dimyristyl peroxydicarbonate, (technically pure) is a white solid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. It is easily ignited and bums with increasing rapidity as the fire pro gresses. It can form explosive mixtures with finely divided combustible materials. It supports the burning of combustible materials. Under pro longed exposure to fire or heat containers of the material may explode. H material on fire or Involved in fire Use water in flooding quantities as log Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use ``alcohol'' loam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not Involved In fire Keep spaifcs, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the matenai Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting (ires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet April 1961 MCD 000009947 DINITROBENZENE, SOUD OR DINITROBENZOL SOLID POISON B "NVIRONMENTALLY HAZARDOUS SUBSTANCE 4921421 UN 1597 (RQ-1000/454) Dinitrobenzene, solid is a white or yellow crystalline solid. It is slightly soluble in water. It is toxic by skin absorption and by inhalation (dust,etc). It is combustible. Prolonged exposure ol the material to fire or heat may result in the spontaneous decomposition of the material with a resultant explosion. Toxic oxides of nitrogen are produced during combustion of this material. H material on fire or involved in fire Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use 'alcohol'' loam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning matenal Keep upwind Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting tires involv ing this material Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fiqhting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap matenal at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates DINITROBENZOL. SOLUTION 4921422 POISON B UNI 597 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Dinitrobenzol. solution is the colorless or yellow solution of dinitro benzene in a suitable solvent. The flammability of die solution depends on (he nature of the solvent. The material itself is combustible. It is toxic by skin absorption and inhalation. Prolonged exposure to fire or heat may result in spontaneous decomposition with a resultant explosion. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources ol ignition away Keep matenal out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodity contact with the material Wear full protective clothing Do not handle broken packages without protective equipment April 1981 MCD 000009948 Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation II material leaking (not on fire), downwind evacuation must be considered Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash, cement powder, sawdust, or com mercial sorbents Environmental considerations--water spill Use natural barriers or oil spill control booms to limit spill motion Use surface active agent (e g. detergent, soaps, alcohols) to com press and thicken spilled material Infect "universal" gelling agent to solidify encircled spill and increase effectiveness of booms If dissolved, apply activated carbon at ten times the spilled amount m region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates DtNITROCHLOROBENZOL, SOLID OR 4921424 DINITROCHLOROBENZENE POISON B UN1577 Dinitrochtorobenzot. solid is a colorless to yellow crystalline solid with an almond like odor. It is insoluble in water. It is combustible though it may require some effort to ignite. It is toxic by skin absorption or in halation (dust, etc.). Prolonged exposure to tire or heat may result in spontaneous decomposition with a resultant explosion. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or involved in fire Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire end not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing DINITROPHENOL (FLAMMABLE SOUD, POISONOUS, 4916526 N.O.S.) FLAMMABLE SOUO,POISONOUS UN1992 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Dinrirophenol is a yellow crystalline solid, shipped water wet with at least 15 % water. It is used to make dyes, as a lumber preservative, and to make explosives. When not water wet it is a high explosive. Dry, the material is easily ignited and it will bum very vigorously. The wet material can bum though it may require some effort to ignite, it is slightly soluble in water. Toxic oxides of nitrogen are produced in fires involving this material. If material on fire or Involved in fire Dangerously explosive Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Continued on next page 205 H material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Do not attempt to sweep up dry material Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable--evacuate for a radius of 5000 feet Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates DINITROPHENOL SOLUTION 4921425 POISON B UN1599 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Dinitrophenol solution is a yellow colored liquid of the yellow crystalline material dissolved in a suitable solvent. The material itself is very slightly soluble in water. The flammability of the solution depends on the nature of the solvent. Dinitrophenol itself is combustible though it may require some effort to ignite, it is toxic by skin absorption and inhalation. Pro longed exposure to fire or heat may result in the spontaneous decom position and heating with a resultant explosion. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear seif-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation if material leaking (not on fire), downwind evacuation must be considered Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with ffy ash or cement powder 206 MCD 000009949 Environmental considerations--water spill Use natural barriers or oil spill control booms to limit spill motion Use surface active agent (e.g. detergent, soaps, alcohols) to com press and thicken spilled material Inject "universal'' gelling agent to solidify encircled spill and increase effectiveness of booms If dissolved, apply activated carbon at ten times the spilled amount in region of tOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates DINITROTOLUENE, LIQUID 4963120 ORM-E UN1600 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Dinitrotoluene. liquid is yellow colored liquid, it is used to make dyes, explosives, and other chemicals, it is insoluble In water, it is combustible though it may take some effort to ignite. Toxic oxides of nitrogen are produced during combustion of this material. It weighs 10-6 pounds per gallon. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use loam, carbon dioxide or dry chemical if material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors or dusts Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Apply "universal" gelling agent to immobilize spill Environmental considerations--water spill Use natural barriers or oil spill control booms to limit spill motion Use surface active agent (e.g. detergent, soaps, alcohols) to com press and thicken spilled material Inject "universal" gelling agent to solidify encircled spill and increase effectiveness of booms Remove trapped material with suction hoses ft dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates DINITROTOLUENE, SOLID 4963115 ORM-E UNI 600 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Dinitrotoluene is a yellow crystalline solid. It is used to make dyes, explosives, and other chemicals. It is insoluble in water. It is combustible though it may take some effort to ignite. Toxic oxides of nitrogen are produced during the combustion of this material, tf material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use foam, carbon dioxide or dry chemical April 1981 If material not on fir* and not invotved in fir* Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors or dusts Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in ram or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom Remove trapped material with suction hoses If dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates DIOXANE 4909155 FLAMMABLE LIQUIO UN1165 Dioxane is a clear colorless liquid with a faint ethereal odor, it has a flash point of 55 deg. F. It is slightly heavier than water and is soluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dHute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts oi water or soap and water OIOXOLANE 4909158 FLAMMABLE UQUIO UN1188 Dioxolane is a clear colorless liquid. H has a flash point of 35 deg. F. It is lighter than water and is soluble in water, tts vapors are heavier than air. If material on fire or invotved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use `alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers April 1981 Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water DIPHENYL DICHLOROSILANE 4934235 CORROSIVE MATERIAL. ACIOIC UN1769 Diphenyl dichiorosilane is a colorless liquid with a pungent odor. Ma terial will burn though it may require some effort to ignite. It is decom posed by water to hydrochloric acid with evolution of heat. It is corrosive to metals and tissue. If material on fire or involved in fire Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective dothing DIPHENYL METHYL BROMIDE, SOUD 4936220 CORROSIVE MATERIAL UNI 770 Diphenyl methyl bromide, solid is a white crystalline solid, it is insoluble in cold water and is decomposed by hot water producing hydrobromic add, a corrosive material. It is corrosive to tissue. If material on fire or invotved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing vapors Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective dothing 207 MCD 000009950 OIFHENVL METHYL BROMIDE, SOLUTION 4936225 CORROSIVE MATERIAL UN1770 Diphenyl methyl bromide, solution is the white crystalline solid dis solved m some solvent. The combustibility of the solution depends on the solvent used. Diphenyl methyl bromide is insoluble in cold water and is decomposed by hot water producing hydrobromic acid, a corrosive material. The solution is corrosive to metals and tissue. If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing OIPHENYLAMiNECHLOROARSINE IRRITATING MATERIAL 4925230 UN1698 Diphenylaminechloroarsine is in the form of yellow crystals. The va pors of this material are very irritating 10 Ihe eyes and mucous mem branes and are also nauseating. If material on fire or involved in fire Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical Cool all affected containers with flooding quantities of water Use water spray to absorb vapors If material not on fire and not involved in fire Keep sparks. Names, and other sources of ignition away Keep material out of water sources and sewers Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing DIPHENYLCHLORARSINE (IRRITATING AGENT, 925240 N.O.S.) IRRITATING MATERIAL NA1693 Diphenylchloroarsine is in the form of colorless crystals if pure oth erwise a brown oily liquid. The vapors of the material are extremely irritating to the eyes and mucous membranes. If material on fire or involved In fire Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical Cool all affected containers with flooding quantities of water Use water spray to absorb vapors 208 If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Evacuation If material leaking (not on tire), downwind evacuation must be considered DtQUAT (AGRICULTURAL INSECTICIOES, NEC, 4963342 LiQUIO) ORM-E NA2761 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Oiquat is a yellow crystalline sollid dissolved in a liquid carrier. It is used as a herbicide. It is a water emulsifiable liquid. It can cause illness by inhalation, skin absorption and/or ingestion. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone: 800-424-9300. If material Involved In fire Extinguish tire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface Now using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental consideration*---water spill tf dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates DtQUAT (AGRICULTURAL INSECTICIOES, NEC, 4963344 OTHER THAN UQUID) ORM-E NA27S1 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Diquat is a yellow crystalline solid. It is used as a herbicide. It is a wettable powder. It can cause illness by inhalation, skin absorption and/ or ingestion. In case of damage to. or leaking from containers ol this material contact the pesticide safety team network. Telephone; 800-424- 9300. tf material Involved in fire Extinguish fire using agent suitable lor type of surrounding fire (Material itself does not bum or bums with difficulty.) If materiel not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary April 1981 MCD 000009951 Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates DIQUAT (INSECTICIDES, OTHER THAN 4969339 AGRICULTURAL, NEC) ORM-E NA2781 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Diquat is a yellow crystalline solid or the solid dissolved in a liquid earner. It is used as a herbicide. It is a wettable powder or water emui* sifiable liquid. It can cause illness by inhalation, skin absorption and/or ingestion. In case of damage to. or leaking from containers of this ma terial contact the pesticide safety team network. Telephone; 800*424- 9300. ft materiel involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) If material not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land split Dig a pit. pond, lagoon, holding area to contain tiqukj or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates DISINFECTANT. UQUIO 4923910 POISON B UNI 601 Disinfectant, liquid Is a variable colored liquid. N is generally soluble in water. It is toxic by ingestion, inhalation (vapors, mists, etc.), or by skin absorption. If material on fire or involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Use foam, carbon dioxide or dry chemical If materiel not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material April 1981 Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting (ires involv ing this material If contact with the material anticipated, wear full protective clothing DISINFECTANT, LIQUID 4936561 CORROSIVE MATERIAL UNI 903 Disinfectant, liquid is a variable colored liquid. It is generally soluble in water. It may be combustible though it may require some effort to ignite. It may be toxic by ingestion, inhalation (vapors, mists, etc.) or by skin absorption. It is corrosive to metals and/or tissue. If material on fire or involved in fire Extinguish lire using agent suitable for type of surrounding fire (Material itself ooes not bum or burns with difficulty.) Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing DISINFECTANT, LIQUID, N.O.S. 491511$ COMBUSTIBLE UQUID NA1993 Disinfectant, liquid, n.o.s. is a variable colored liquid. It has a flash point between 100 and 199 deg. F. Although the material is not classed as a poison b. breathing of the vapors or skin contact with the liquid should be avoided. It is lighter than water and soluble in water, its vapors are heavier than air. H material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as log Solid streams of water may be ineffective Cod all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "ataoboT foam, carbon dioxide or dry chemical If material not on fira and not Invotved in Are Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear bools, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing 209 MOD 000009952 DISINFECTANT, SOLID 4923911 POISON B UNI SOI Disinfectant, solid is a variable colored solid. It is generally soluble in water. It is toxic by ingestion, inhalation (dusts), or by skin absorption. If material on fire or involved in Are Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical Cool all affected containers with Hooding quantities of water If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing DISPERSANT GASES, NEC (COMPRESSED GAS, N.O.S.) 4904536 NONFLAMMABLE GAS UN1956 Dispersant gases, nec are materials which are shipped in containers under pressure. They may be mixtures consisting of nonflammable gas(es) (and flammable gas(es)) with the mixture being nonflammable. The mixture may separate with the flammable gas setting into low areas, or the nonflammable gas setting into low areas. It may asphyxiate by the displacement of air. It may only be shipped in cylinders. Toxic gases can be produced in fires involving this material. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved In fire Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment DISPERSANT GASES, NEC. FLAMMABLE 4905727 (COMPRESSED GAS, N.O.S.) FLAMMABLE GAS UN1954 Dispersant gases are colorless gases shipped as liquefied gases un der its vapor pressure. Contact with the liquid can cause frostbite. It is easily ignited. Its vapors are heavier than air and a flame can flash back to the source of leak very easily. This leak may either be a liquid or vapor leak. It can asphyxiate by the displacement of air. Under fire conditions the cylinder or tank car may violently rupture and rocket. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped :e water in flooding quantities as fog Jool all affected containers with flooding quantities of water Apply water from as far a distance as possible tf materiel not on fire end not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors 210 Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered DISULFOTON (AGRICULTURAL INSECTICIDES, NEC, 4921511 LIQUID) POISON B NA2783 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Disulfoton is a pale yellow liquid, it is used as a pesticide. It is a water emulsifiable liquid. It is toxic by inhalation, skin absorption, and/or inges tion. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone: 800-424-9300. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors DISULFOTON (AGRICULTURAL INSECTICIDES, NEC, 4921512 OTHER THAN UQUID) POISON B NA2763 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) DisuHoion is a pale yellow liquid absorbed on a dry carrier. It is used as a pesticide. It is a wettabie powder. It is toxic by inhalation, skin absorption, and/or ingestion. In case ol damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone; 600-424-9300. Aphi 1981 MCD 000009953 If material on fire or Involved in fire Extinguish fire using agent suitable lor type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use "alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keeo upwind Avoid bodiiy contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this matenal If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental consideratione--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount m region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates DISULFOTON (INSECTICIDES. OTHER THAN 4921513 AGRICULTURAL. NEC) 'OISON B NA2783 NVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Oisulfoton is a pale yeliow liquid or the liquid absorbed on a dry carrier, ft is used as a pesticide. It is a wettable powder or water emulsifiable liquid. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone; 600-424-9300. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Coot all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical H material not on fire and not Involved In fire Keep sparks, flames, and other sources of Ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avcmj bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area lo contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder April 1961 Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses ot pollutants and precipitates OISULFOTON MIXTURE. DRY (AGRICULTURAL 4921508 INSECTICIDES, NEC. OTHER THAN LIQUIO) POISON B NA2783 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Oisulfoton mixture, dry is the pale yellow liquid absorbed on a dry carrier. It is used as a pesticide. It is a wetable powder. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone: 800-424-9300. If material on fire or Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as fog Use "alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Environmental consideration*--land pill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cwer solids with a plastic sheet to prevent dissolving in rain or lire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom if dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates OISULFOTON MIXTURE. LIQUID (AGRICULTURAL 4921509 INSECTICIDES, NEC. LIQUIO) POISON B NA2783 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Oisulfoton mixture, liquid Is a pale yellow liquid, it is used as a pes ticide. It i9 a water emulstfiable liquid, it is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone: 800-424-9300. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Continued on next page 211 Hod 000099s4 If material not on fire and not involved in fir* Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the matenal Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors DITHIOCARBAMATE PESTICIDE. UQUIO, N.O.S. (COMPOUNDS AND PREPARATIONS) 4921631 (INSECTICIDES, OTHER THAN AGRICULTURAL. NEC) POISON B UN2771 Dithiocarbamate pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emulsitiable, The carrier may bum though it may require some effort to ignite. It is toxic by inhalation, skin ab sorption. and/or ingestion. In case of damage to. or leaking from con tainers of this material contact the pesticide safety team network. Tele phone; 800-424-9300. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water DITHIOCARBAMATE PESTICIDE, UQUIO, N.O.S. 4921632 (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES, NEC. LIQUID) POISON B UN2771 Dithiocarbamate pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emulsiUabte- The carrier may bum though It may require some effort to ignite. It is toxic by inhalation, skin ab sorption, and/or ingestion. In case of damage to. or leaking from con tainers gf this matenal contact the pesticide safety team network. Tele phone; 600-424-9300 If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possfcte Use "alcohol" foam, carbon dioxide or dry chemical ff material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 212 DITHIOCARBAMATE PESTICIDE, UQUID, N.O.S. 4910532 (COMPOUNDS ANO PREPARATIONS) (AGRICULTURAL INSECTICIDES, NEC, UQUID) FLAMMABLE UQUID UN2772 Dithiocarbamate pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emuisifiable. The primary hazard of this material is the flammability of the carrier, ft has a flash point below 100 deg. F. It can cause iHness by inhalation, skin absorption and/or inges tion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in (tooting quantifies as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical It material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wear self-contained breathing apparatus when fighting fires involv ing this material April 1981 000009955 tfCD DITHIOCARBAMATE PESTICIDE, UQUID, N.O.S. 4910531 (COMPOUNDS AND PREPARATIONS) (INSECTICIDES, OTHER THAN AGRICULTURAL NEC) LAMMABLE LIQUID UN2772 Dithiocarbamate pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emulsiliable. The primary hazard of this material is the flammability of the carrier. It has a flash point below 100 deg. F. it can cause illness by inhalation, skin absorption and/or inges tion. In case of damage to, or leaking from containers of this material coniact the pesticide safety team network. Telephone; 800-424-9300. If material on fire or Involved In fire Oo not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wear self-contained breathing apparatus when fighting fires involv ing this material DITHIOCARBAMATE PESTICIDE. SOLID, N.O.S. 4921633 (COMPOUNDS AND PREPARATIONS) (INSECTICIDES, OTHER THAN AGRICULTURAL. NEC) POISON B UN2771 Dithiocarbamate pesticide is a solid or a liquid absorbed on a dry carrier. It is a wettable powder. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone: 800- 424-9300. If material on fire or Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing DfTHIOCARBAMATE PESTICIDE. SOUO. N.O.S. 4921634 (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES. NEC. OTHER THAN UQUID) POISON B UN2771 Dithiocarbamate pesticide is a solid or a Ikjted absorbed on a dry earner. Ii is a wettable powder. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone: 800- 424-9300 If materiel on fire or Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use ' alcohol'* foam, carbon dioxide or dry chemical H material not on fire end not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear seif-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing April 1981 DIURON (AGRICULTURAL INSECTICIDES, NEC, 4962620 LIQUID) ORM-E NA2767 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RG-100/45.4) Diuron is a white crystalline solid dissolved in a liquid carrier. It is used as a herbicide. It is a water emulsifiable liquid. It can cause illness by inhalation, skin absorption and/or ingestion. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300. H materiel Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) If materiel not involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--lend spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates 213 MCD 0009956 DIURON (AGRICULTURAL INSECTICIDES, NEC, 4962621 OTHER THAN LIQUID) ORM-E NA2767 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-100/45.4) Diuron is a while crystalline solid. It is used as a herbicide. It is a wettable powder. It can cause illness by inhalation, skin absorption and/ or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone: 800-424- 9300. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear pools, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill If dissolved, apply activated carbon at ten limes the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates DIURON (INSECTICIDES, OTHER THAN 4962622 AGRICULTURAL, NEC) ORM-E NA2767 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-IOO/45.4) Diuron is a white crystalline solid or the solid dissolved in a liquid carrier. It is used as a herbicide. It is a wettable powder or water emul- sifiable liquid- It can cause illness by inhalation, skin absorption and/or ingestion. In case of damage to. or leaking from containers of this ma terial contact the pesticide safety team network. Telephone: 800-424- 9300. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) If material not Involved in Are Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental eonsideratlone--lend spIN Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill If dissolved, apply activated cartoon at ten times the spilled amount in region of 10ppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates If material on Are or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain (low as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered DODECYL TRICHLOROSILANE 4934240 CORROSIVE MATERIAL, ACIDIC UN1771 Dodecyl trichlorosilane is a colorless to yellow liquid with a pungent odor. Material will bum though it may take some effort to ignite. It is decomposed by moisture or water to hydrochloric acid wilh evolution of heat, it is corrosive to metals and tissue. If material on fire or Involved In fire Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and tog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing OIVINYL ETHER 4906165 FLAMMABLE LIQUID UN1167 Oivinyt ether is a clear colorless liquid. It has a flash point of less than -22 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. 214 DODECYLBENZENESULFONIC ACID 4931426 CORROSIVE MATERIAL NA2584 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Dodecylbenzenesulfonic add is a colorless liquid. It is used to make detergents. It is soluble in water. It is corrosive to metals and tissue. April 1961 MCD 000009957 H material on fire or Involved In fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Use water spray to absorb vapors If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate If dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates DRUGS OR MEDICINES, N.O.S. 4917376 rLAMMABLE SOUD NA1325 Drugs or medicines, n.o.s. is (he proper shipping name of any solid material, other than one classed as an explosive, or specifically listed by name in the list of hazardous materials which is liable under conditions incident to transportation to cause Ares through friction, absorption of moisture, spontaneous chemical changes as a result of retained heat from the manufacturing or processing of the solid, or which can be readily ignited by external sparks or flame and when so ignited bums vigorously and persistently. Try to ascertain the exact name of the material, if material on fire or Involved in fire Extinguish fire using agent suitable for type of fire II meterlet not on fire end not Involved in fire Keep sparks, flames, and other sources of ignition away Build dikes to contain flow as necessary Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water DRUGS OR MEDICINES, N.O.S. 4916410 OXIOIZER NA1479 Drugs or medicines, n.o.s. are various materials which have the prop erty of accelerating the burning of combustible material. These materials may not bum by themselves. Prolonged exposure of these materials and/or their containers to fire or heat may result in an explosion. These materials may only be shipped in containers of 55 gallon capacity or less. April 1961 If materiel on fire or Involved In fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Approach fire with caution Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet DRUGS OR MEDICINES, N.O.S. (LIQUID) 4921427 POISON B NA2610 Drugs or medicines, n.o.s. (liquid) are liquid or solution of solids ma terials which have the property of being toxic by ingestion, inhalation, or skin absorption. The liquid or solution may or may not burn depending on (he nature of the material and/or the solvent of the solution. If material on fire or Involved In lira Do not extinguish Are unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical H material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak If without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation H material leaking (not on Are), downwind evacuation must be considered DRUGS OR MEDICINES, N.O.S. (SOUD) 4921496 POISON B NA2811 Onjgs or medicines, n.o.s. (solid) are pure materials or mixtures of two or more solids or liquids absorbed on a dry carrier. It has the property of being toxic by ingestion, inhalation (vapor dust, etc) or skin absorption. If material on fire or Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical H material not on fire and not involved In fire Keep sparks, flames, and other souroes of ignition away Keep material out of water sources and sewers Continued on next page 215 MOD 0000995s Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when lighting fires involv ing this material If contact with the material anticipated, wear full protective clothing DRUGS. N.O.S. 4915191 COMBUSTIBLE LIQUID NA1993 Drugs, n.o.s. are those drugs with the property of having a flash point between 100 and 199 deg. F. They are generally lighter than water and soluble in water. Their vapors are heavier than air. If material on fire or Involved in fire Do not extinguish fire unless flow can be slopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, (lames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing DRUGS, N.O.S. 4910191 FLAMMABLE LIQUID NA1993 Drugs, n.o.s. are those drugs with the property of having a flash point of less than 100 deg. F. They are generally lighter than water and soluble in water. Their vapors are heavier than air. If material on lira or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any malarial which may have contacted the body with copious amounts of water or soap and water 216 DRUGS, N.O.S., LIQUID 4936SS1 CORROSIVE MATERIAL NA1760 Drugs, n.o.s.. liquid is the proper shipping name (or various liquids having the property of being corrosive to steel or tissue. It may either be a simple liquid material or a solid material dissolved in a solvent. It may be combustible though requiring some effort to ignite. They may or may not be water soluble. If material on fire or involved in fire Extinguish lire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities ol water Apply water from as far a distance as possible Solid streams of water may be ineffective Use ` alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, (tames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain (low as necessary Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing DRUGS, N.O.S., SOUO 4936582 CORROSIVE MATERIAL NA1759 Drugs, n.o.s., solid is the proper shipping name for various colored solids having the property of being corrosive to tissue. They may or may not be water soluble. If material on fire or Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material rtsetf does not bum or bums with difficulty.) Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing DRY CLEANER, LIQUID, OR LIQUID CLEANSER 4910146 (COMPOUND, CLEANING, UQUID) FLAMMABLE UQUID NA1993 Dry deaner. liquid, or liquid deanser is a variable colored liquid with a petroleum like odor. It has a flash point of less than 100 deg. F. It is lighter than water and generally insoluble in water. Its vapors are heavier than air. 000009959 rtCD April 1981 If material on Are or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol " foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water DRY CLEANER, LIQUID, OR L1QU10 CLEANSER 4915146 (COMPOUND, CLEANING, LIQUID) COMBUSTIBLE LIQUID NA1993 Dry clearer, liquid, or liquid cleanser is a variable colored liquid with a petroleum like odor. It has a flash point between 100 and 199 deg. P. it is lighter than water and generally insoluble in water. Its vapors are heavier than air. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical W material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water DYE INTERMEDIATE, UQUID 4930555 CORROSIVE MATERIAL UN2801 Dye intermediate, liquid is a variable colored material. It may be com bustible though requiring some effort to ignite. It is corrosive to metals and/or tissue. It may or may not be water soluble. If materiel on fire or Involved in fire Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles April 1981 Do not handle broken packages without protective equipment Wash away ary material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing (his material If contact with the material anticipated, wear full protective clothing ELECTRIC SQUIB 4903440 CLASS C EXPLOSIVE Electnc squib consists of a small tube or clock containing a small amount of an ignition compound in contact with a bridge wire. The device may or may not have long lead wires attached to it. H material on fire or Involved in fire Flood with water Apply water from as far a distance as possible If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet ELECTRIC WIRE SATURATING OR FINISHING 491S46S COMPOUND, ASPHALT OR PITCH BASE (COMBUSTIBLE UQUID, N.O.S.) COMBUSTIBLE LIQUID NA1993 Electric wire saturating or finishing compound asphalt or pitch base is a material containing a solvent having a dosed cup flash point between 100 and 199 deg. F. The hazard of this material is combustibility, ff material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ELECTRIC WIRE SATURATING OR FINISHING 4910456 COMPOUND, ASPHALT OR PITCH BASE (FLAMMABLE UQUID, N.O.S.) FLAMMABLE UQUID UNI 993 Electric wire saturating or finishing compound asphalt or pitch base is a material containing a solvent having a closed cup flash point of less than 100 deg. F. The hazard of this material is flammability. Continued on next pep* 217 000 996q If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Buiio dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ELECTRIC WIRE SATURATING OR FINISHING 4915418 COMPOUND, PARAFFINE BASE (COMBUSTIBLE LIQUID, N.O.S.) COMBUSTIBLE LIQUID NA1993 Electric wire saturating or finishing compound is a material containing a solvent having a closed cup flash point between 100 and 199 deg. F. The hazard is combustibility. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ELECTRIC WIRE SATURATING OR FINISHING 4910418 COMPOUND, PARAFFINE BASE (FLAMMABLE LIQUID, N.O.S.) FLAMMABLE LIQUID UN1993 Electric wire saturating or finish compound is a material containing a solvent having a closed cup flash point of less than 100 deg. F. The hazard is flammability. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out o< water sources and sewers Build dikes to contain flow as necessary Use water spray lo knock-down vapors 218 Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ELECTROLYTE (ACID) BATTERY, FLUID 4930216 CORROSIVE MATERIAL, ACIDIC UN2796 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Electrolyte (acid), battery fluid is a sulfuric acid-water solution. It is a clear colorless odorless liquid. It is soluble in water with release of heat. It is corrosive to metals and to tissue. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash. or lime Personnel projection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--lend spill Oig a pit pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--sir spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment ELECTROLYTE (ACIO) PACKED WITH BATTERY 4939564 CHARGER, RADIO CURRENT SUPPLY DEVICE OR ELECTRONIC EQUIPMENT AND ACTUATING DEVICE) CORROSIVE MATERIAL, ACIDIC NA2797 Electrolyte (acid) packed with battery charger, radio current supply device or electronic equipment and actuating devices consist of con tainers of electrolyte (acid) packed in the same outside shipping con tainer with battery charger, radio current supply device or electronic equipment and actuating devices. The electrolyte (acid) is soluble in water with evolution of heat. It is corrosive to metals and tissue. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Apply water from as far a distance as possible If material not involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash, or lime April 1981 mod 000009961 Personnel protection Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing ELECTROLYTE (ACID) PACKED WITH DRY STORAGE 4930217 BATTERY CORROSIVE MATERIAL NA2797 Electrolyte (acid) packed with dry storage battery is the dry (empty) storage battery and the electrolyte (acid) in a container packaged to gether in the same outside container. The electrolyte (acid) is a sulfuric acid-water solution. It is a clear colorless liquid. II is soluble in water with release of heat. It is corrosive to metals and tissue. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved in Are Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing EMBEDDING CEMENT, NEC (CEMENT, UQUID, N.O.S.) 4910448 FLAMMABLE UQUID NA1133 Embedding cement nec is a solution of various gums or resins in various solvents. The liquids are generally quite thick and may range from clear colorless to black "tars". The flash point of the cement de pends on the solvents used but it will be (ess than 100 deg. F. The hazard is flammability. If material on Are or involved In Are Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on Are and not involved in Are Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1961 EMBEDDING CEMENT, NEC (CEMENT, LIQUID, N.O.S.) 4915448 COMBUSTIBLE UQUID NA1133 Embedding cement nec is a solution of various gums or resins in various solvents. The liquids are generally quite thick and may range from clear colorless to black "tars." the flash point of the cement depends on the solvents used but it will be between 100 and 199 deg. F. The hazard is combustibility. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ENAMEL (ENAMEL OTHER THAN WATCH DIAL) 4910176 FLAMMABLE UQUID UN1263 Enamel or watch dial may contain a flammable solvent. Its flash point is 100 deg. F. or lower. The hazard is that of flammablility. K material on Are or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In Are Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ENAMEL (ENAMEL OTHER THAN WATCH DIAL) 4915176 COMBUSTIBLE UQUID UN1263 Enamel is a variable colored liquid which may contain a combustible solvent. Its flash point is between 100 and 199 deg. F. The hazard is that of combustibility. H material on Are or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as tog Solid streams of water may be ineffective Cod all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" loam, carbon dioxide or dry chemical Continued on next page 219 MCD 000009962 ft material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ENAMEL WHITENING COMPOUNDS (COMBUSTIBLE 491S177 LIQUID, N.O.S.) COMBUSTIBLE LIQUID NA1993 Enamel whitening compounds are dear colorless to white liquids. They have a flash point between 100 and 199 deg. F. They are generally lighter than water and insoluble in water. Their vapors are heavier than air. If material on fira or fnvolvad In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities ol water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ENAMEL WHITENING COMPOUNDS (FLAMMABLE 4910177 LIQUID, N.O.S.) FLAMMABLE LIQUID UN1999 Enamel whitening compounds are dear colorless to white liquids. They have a flash point of less than 100 deg. F. They are generally lighter than water and insoluble in water. Their vapors are heavier than air. If material on Are or Involved in fire Do not extinguish Are unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical H material not on fire and not involved In Are Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 220 ENDOSULFAN (AGRICULTURAL INSECTICIDES, NEC, 4921516 LIQUID) POISON B NA2761 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-VO.454) Endosulfan is a white solid dissolved in a liquid carrier. It is used as a pesticide. It is a water emuisifiable liquid. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300. If material on Are or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors ENDOSULFAN (AGRICULTURAL INSECTICIDES, NEC, 4921517 OTHER THAN UOUIO) POISON B NA2761 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Endosulfan is a white solid H is used as a pesticide, fungicide, or herbicide, it is a wettabie powder. It is toxic by inhalation, skin containers of this material contact the pesticide safety team network. Telephone; 800-424-9300. If material on fire or involved In fire Extinguish tire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use "alcohol'' foam, carbon dioxide or dry chemical if material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers April 1981 MOD 000009963 Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear bools, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates ENDOSULFAN (INSECTICIDES, OTHER THAN 492151S AGRICULTURAL, NEC) POISON B NA2761 ENVIRONMENTALLY HAZARDOUS SU8STANCE (RQ-1/0.454) Endosuifan is a white solid or (he solid dissolved in a liquid earner. It is used as a pesticide, fungicide, or herbicide. It is a wettable powder or water emulsifiable liquid, it is toxic by inhalation, skin absorption, and; or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424- 9300. H material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use `alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear fuK protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental conalderationa- land split Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental conaldaratlona--water spill It dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors April 1981 ENDOSULFAN MIXTURE, LIQUID (AGRICULTURAL 4921519 INSECTICIDES, NEC. LIQUID) POISON S NA2761 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Endosuifan mixture, liquid is the white solid dissolved in a liquid carrier. It is used as a pesticide. It is a water emulsifiable liquid, ft is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerationa--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors ENDRIN (AGRICULTURAL INSECTICIDES. NEC, 4921521 LIQUID) POISON B NA2761 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Endrin is a white solid dissolved in a liquid carrier. It is used as a pesticide. It is a water emulsifiable liquid. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300. If material on Are or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "aicohoi" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Continued on next page mcd 000009964 221 Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts ol water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors ENORIN (AGRICULTURAL INSECTICIOES, NEC, 4921522 OTHER THAN LIQUID) POISON B NA2761 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Endrin is a white solid. It is used as a pesticide. It is we(table powder. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to, or leaking from containers of this material contact the pes ticide safety team network. Telephone; 600-424-9300. If material on fire or Involved In fire - Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as tog Use "alcohol'" foam, carbon dioxide or dry chemical If materiel not on fire end not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighfog fires involv ing this material If contact with the material anticipated, wear full protective clothing Environmental considerations--lend spin Oig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates 222 ENORIN (INSECTICIOES, OTHER THAN AGRICULTURAL, NEC) 4921523 POISON B NA2761 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Endrin is a white solid or the solid dissolved in a liquid carrier. It is used as a pesticide, it is a wettable powder or water emulsifiable liquid. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to, or leaking from containers of this material contact the pes ticide safety team network. Telephone: 600-424-9300. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, (lames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, iagoon, holding area to contain liquid or solid material Oike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with tty ash or cement powder Environmental considerations--water spill if dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors ENORIN MIXTURE, LIQUID (AGRICULTURAL 4921520 INSECTICIDE, NEC, LIQUID) POISON B NA2761 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Endrin mixture, liquid is a white solid dissolved in a liquid carrier. It is used as a pesticide. It is a water emulsifiable liquid. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300. ft material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as tog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical H materiel not on fire end not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors 9g65 oooo 0 April 1961 Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not hanoie broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface How using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill ff dissolved, acply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors ENGINE STARTING FLUID 4905728 FLAMMABLE GAS UN1960 Engine starting fluid is a flammable liquid in a container mixed with a flammable or nonflammable compressed gas as a propellant. It is easily ignited and may only be shipped in cylinders. It is heavier than air and a flame can flash back to the source of leak very easily. Under fire conditions the cylinders may violently rupture and rocket. If the cylinders are aerosols they will violently rupture and rocket under fire conditions. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding Quantities as tog Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible ff material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sawers Personnel protection Avoid breathing vapors Keep upwind Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet EPICHLOROHYDRIN 4907420 FLAMMABLE LIQUID, POISONOUS UN2023 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-1000/454) Epichlorohydrin is a dear, colorless liquid with an irritating chloroform like odor, it is used to make plastics, and as a solvent It has a flash point of 87 deg. F. if contaminated, the material is subject to polymer ization with evolution of heat. If the polymerization takas place inside a container, the container is subject to rupture. It is Irritating to the skin and respiratory system and is toxic by ingestion. It is heavier than water and soluble in water. Its vapors are heavier than air. It weighs 9.8 pounds per gallon. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in Hooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical April 1981 tt material not on fire and not involved In fire Keep sparks, Names, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear bools, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts ol water or soap and water If contact with the material anticipated, wear full protective clothing Evacuation if fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered Environmental considerations--lend spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface How using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash. cement powder, sawdust, or com mercial sorbents Apply "universal" gelling agent to immobilize spill Apply fluorocarbon-water foam to diminish vapor and fire hazard Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--sir spill Apply water spray or mist to knock down vapors Combustion products include corrosive or toxic vapors Thermal decomposition to phosgene can occur ERADICATOR, PAINT OR GREASE, LIQUID 4910178 FLAMMABLE UOUIO UNI 850 Eradicator, paint or grease, liquid is variable colored liquid generally having a petroleum odor. It has a flash point of less than 100 deg. F. It is generally lighter than water and insoluble in water. Its vapors are heavier than air. If material on Are or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from aa far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If materiel not on fire end not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 223 MCD 000009966 ETCHING ACID, LIQUID, N.O.S. 4930005 CORROSIVE MATERIALS, ACIDIC, POISONOUS NA1790 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-IOOO/454) Etching acid, liquid, n.o.s. is a colorless to pale yellow liquid composed of nitric acid, hydrofluoric acid, water and possibly acetic acid. It is soluble in water with release of heat, It is corrosive to metals and tissue. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental consideratlona--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental consideratlona--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment ETHANE FLAMMABLE GAS 4905731 UN1035 Ethane is a colorless odorless gas. It is easily Ignited and may only be shipped in cylinders. It is heavier than air but a flame can aasily flash back to the source of the leak very easily. It can asphyxiate by the displacement of air. Under fire conditions the cylinders may violently rupture and rocket. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet 224 ETHER (DIETHYL ETHER, ANESTHESIA GRADE) 4908157 FLAMMABLE LIQUID UN1155 Ethyl ether is a clear colorless liquid with a characteristic anesthetic odor, it is used as an anesthetic, as a solvent, and to make other chem icals. It has a (lash point ol -49 deg. F. It is lighter than water and insoluble in water, its vapors are heavier than air. II material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities ol water Apply water from as tar a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-dowr vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered ETHER (DIETHYL ETHER, OTHER THAN ANESTHESIA 4908156 GRAOE) FLAMMABLE LIQUIO UN1155 Ether is a clear colorless liquid with a characteristic anesthetic odor. It has a flash point of *49 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or Involved In fire Do not extinguish fire unless fiow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cod all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "aicohd" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered 0 00 ?1 April 1981 ETHION (AGRICULTURAL INSECTICIDES, NEC, 4921565 LIQUID) POISON B NA2783 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-IO/4.54) Ethion is a colorless liquid. It is used as a pesticide. It is awater emulsifiable liquid. It is toxic by inhalation, skin absorption, and/or inges tion. in case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water m flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep matenai out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and wafer Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors ETHION (AGRICULTURAL INSECT1CIOES, NEC, 4921566 OTHER THAN LIQUID) POISON B NA27S3 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-10/4.54) Ethion is a colorless liquid absorbed on a dry carrier. It is used as a pesticide. It is a wettable powder. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone: 600- 424-9300. If material on fire or Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material April 1981 Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid matenai Cover solids with a plastic sheet to prevent dissolving in ram or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates ETHION (INSECTICIDES, OTHER THAN 4921567 AGRICULTURAL, NEC) POISON B NA2763 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-10/4.54) Ethion is a colorless liquid or the liquid absorbed on a dry carrier. It is used as a pesticide. It is a wettable powder or water emulsifiable liquid, it is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" loam, carbon dioxide or dry chemical If material not on fire end not involved in fire Keep sparks, llamas, and other sources of ignition away Keep material out ol water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--lend epill Dig a pH, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--sir spill Apply water spray or mist to knock down vapors 225 MCD 000009968 ETHION MIXTURE, DRY (AGRICULTURAL INSECTICIDES, NEC, OTHER THAN DRY UQUIO) 4921568 POISON B NA2783 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-10/4.54) Ethion mixture, dry is a colorless liquid absorbed on a dry carrier. It is used as a pesticide. It is a wetable powder. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300. If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical If material net on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts ot water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Environmental considerations--land split Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates ETHYL ACRYLATE, INHIBITED 4907215 FLAMMABLE UQUIO POLYMERIZABLE UN1917 Ethyl acrylate is a dear colorless liquid with an acrid odor. It is used to make paints and plastics. It has a flash point of 60 deg. F. If the material is subjected to heat for prolonged periods or becomes contam inated it is subject to polymerization with evolution of heat. If the poly merization takes place inside a container the container may violently rupture. The material is lighter than water and slightly soluble in water. The vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread tire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak it without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gtoves. and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet If material leaking (not on fire), downwind evacuation must be considered ETHYL ACETATE 4909160 FLAMMABLE LIQUID UN1173 Ethyl acetate is a clear colorless liquid with a fruity odor. It has a flash point of 24 deg. F. It is lighter than water and siighdy soluble in water. Its vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Coot all affected containers with hooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 226 ETHYL ALCOHOL (COLOGNE SPIRITS) 4909159 FLAMMABLE LIQUID NA1170 Ethyl alcohol is a dear colorless liquid with a characteristic odor. It has a flash point of 62 deg. F. It is lighter than water and soluble in water. Its vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water In flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material noton fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1981 MCD 000009969 ETHYL ALCOHOL, ANHYDROUS, DENATURED IN 4909110 PART WITH GASOLINE, GASOUNE CONTENT NOT TO EXCEEO S PERCENT (ALCOHOL, N.O.S.) FLAMMBLE LIQUID UN1987 Ethyl alcohol, anhydrous, denatured in part with gasoline is a colorless liquid with a charactenstic alcohol odor. It is used for blending with gasoline to make gasohol. It has a flash point of 58-60 deg. F. It is lighter than water and soluble in water. Its vapors are heavier than air. If material on fire or Involved in fire Do not extinguish fire unless flow can be slopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved <n fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ETHYL ALDEHYOE (See ACETALDEHYDE 4907210) ETHYL BENZENE 4909163 FLAMMABLE UQUIO UN1175 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Ethyl benzene is a clear colorless liquid with an aromatic odor. It is used as a solvent and to make other chemicals. It has a flash point of 59 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. It weighs 7.2 pounds per gallon. H material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--(and spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Oike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash, cement powder, sawdust, or com mercial sorbents Apply "universal" gelling agent to immobilize spill Apply fluorocarbon-water loam to diminish vapor and (ire hazard Environmental considerations--water spill Use natural barriers or oil spill control booms to limit spill motion Use surface active agent (e.g. detergent, soaps, alcohols) to com press and thicken spilled material Inject "universal" gelling agent to solidify encircled spill and increase effectiveness of booms If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses ol pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors ETHYL BORATE 4909161 FLAMMABLE LIQUID UN1176 Ethyl borate is a clear colorless liquid, it has a flash point of 52 deg. F. It is lighter than water and is decomposed by water giving ethyl alcohol, another flammable liquid. Its vapors are heavier than air. K materiel on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantises of water Apply water from as far a distance as possible Use "alcohol'1 foam, carbon dioxide or dry chemical If material not on fira and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ETHYL BUTYL ACETATE 4913113 COMBUSTIBLE LIQUID UN1177 Ethyl butyl acetate is a clear colorless liquid. It has a flash point of 130 deg. F. It is heavier than water and insoluble in water. Its vapors are heavier than air. If material on fira or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical if material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1961 0099^ tfCB o 22 7 ETHYL BUTYL ETHER 4909164 FLAMMABLE L1QUIO UN1179 Ethyl butyl ether is a clear, colorless liquid with an ethereal odor. It has a flash point of 40 deg. F. It is lighter than water and is slightly soluble in water. Its vapors are heavier than air. II material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as tog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ETHYL BUTYRALDEHYDE 4909168 FLAMMABLE LIQUID UN1178 Ethyl butyraldehyde is a dear, colorless liquid- It has a flash point of 70 deg. F. It is lighter than water and is insoluble in water. Its vapors are heavier than air. If material on fire or Involved In Are Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ETHYL BUTYRATE 4909132 FLAMMABLE LIQUID UN1180 Ethyl butyrate is a clear colorless liquid with a pineapple-like odor. It has a flash point of 78 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Coot all affected containers with flooding quantities of water Appty water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical 228 If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts of water or soap and water ETHYL CHLOROACETATE 4913114 COMBUSTIBLE LIQUID UN1181 Ethyl chloroacetate is a clear colorless liquid with a pungent odor. It has a flash point of 100 deg. F. it is heavier than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this matenal ETHYL CHLOROFORMATE 4907617 FLAMMABLE LIQUID, CORROSIVE UN1182 Ethyl chloroformata is a colorless liquid with a pungent odor. It has a flash point of 66 deg. F. Its vapor is irritating to the eyes and mucous membranes. If is corrosive to metals and tissue. It is decomposed by water to give hydrochloric acid,a corrosive material.with evolution of heat. Its vapors are heavier than air. H material on fin or involved In fire Do not extinguish fire unless flow can be stopped Use "alcohol" foam, carbon dioxide or dry chemical Cool all affected containers with flooding quantities of water Apply water from as far a distance aa possible H material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear sett-contained breathing apparatus Avoid bodily contact with the material Wear full protective dotting Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1981 000009971 MCD Evacuation If fire becomes uncontrollable or container is exposed to direct f/ame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered ETHYL CHLOROTHIOFORMATE CORROSIVE MATERIAL 4933327 UN2626 Elhyl ch/orothioformate fs an amber colored liquid with a pungent penetrating odor. It is combustible and has a flash point of 125 deg. F. The vapors are irritating to the eyes and respiratory system. It is corrosive to metals and tissue. It is heavier than water and reacts with water forming hydrochloric acid, another corrosive material, with evolution of heat. Its vapors are heavier than air. If material on fire or Involved In fire Use "alcohol" foam, carbon dioxide or dry chemical Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved In Are Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed iimestone. soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with (he material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ETHYL CROTONATE 4909162 FLAMMABLE LIQUID UN1662 Ethyl crotonate is a clear colorless liquid with a pungent odor. It has a flash point of 36 deg. F. It is lighter than water and is insoluble in water. Its vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooring quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire end not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do riot handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1981 MCD 000009972 ETHYL DICHLOROSILANE 4907615 FLAMMABLE LIQUIO, CORROSIVE, ACIDIC UN1163 Ethyldichlorosilane js a colorless fuming liquid with a pungent odor. It has a flash point of 30 deg. F. Vapor and liquid can cause burns. It is heavier than water and is decomposed by water to form hydrochloric acid, a corrosive material. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless (low can be stopped Use "alcohol" foam, carbon dioxide or dry chemical Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out ol water sources and sewers Build dikes to contain (low as necessary Attempt to stop leak il without hazard Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Oo not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on tire), downwind evacuation must be considered ETHYL FORMATE 4908167 FLAMMA8LE LIQUID UN1190 Ethyl formate is a dear colorless liquid with a pleasant odor. It has a flash point of -4 deg. F. It is lighter than water and soluble in water. It is slowly decomposed by water to formic acid, a corrosive material and ethyl alcohol, another flammable liquid, its vapors are heavier than air. if material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use "alcohol" foam, carbon dioxide or dry chemical Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Do not use water on material itself If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Do not use water on material itself Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Continued on next pege 229 Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered ETHYL HEXALDEHYDE COMBUSTIBLE LIQUID 4913164 UN1191 Ethyl hexaldehyde is a clear colorless liquid with a mild odor. It has a flash point of 125 deg. F. It is lighter than water and slightly soluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use ' alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water if material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered ETHYL LACTATE 4913165 COMBUSTIBLE UQUID UN1192 Ethyl lactate is a clear colorless liquid with a mild odor. It has a flash point of 115 deg. F. It is heavier than water and soluble in water, its vapors are heavier than air. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" loam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ETHYL MERCAPTAN 4906169 FLAMMABLE UQUID UN2363 Ethyl mercaptan Is a dear colorless liquid with an overpowering garlic like odor. It has a flash point of -55 deg. F. and a boiling point of 97 deg. F. It is lighter than water and very slightly soluble in water, its vapors are heavier than air. 230 ETHYL METHYL ETHER 4908171 FLAMMABLE UQUID UN1039 Ethyl methyl ether is a dear colorless liquid with a medicinal like odor. It has a flash point of -35 deg. F. and a boiling point of 52 deg. F. Upon prolonged standing, or exposure to sunlight or oxygen; peroxides may form which may explode spontaneously or when heated. It is lighter than water and soluble in water. Its vapors are heavier than air. if material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cod all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohd" foam, carbon dioxide or dry chemical If material not on fire end not Involved In Are Keep sparks, flames, and other sources of Ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrdiade or container is exposed to direct flame--evacuate for a radius of 1500 feet if material leaking (not on tire), downwind evacuation must be considered April 1981 oo'& O',o ETHYL NITRATE 4907010 FLAMMABLE LIQUID NA1993 THERMALLY UNSTABLE Ethyl nitrate is a clear, colorless liquid with a pleasant odor. It has flash point of 50 deg. F. Prolonged exposure of the material to heat may result in the spontaneous decomposition of the material and this de composition may reach explosive violence. Prolonged exposure of the containers of the material to fire or heat may result in the violent rupturing of the containers due to the decomposition of the material. It is heavier than water and insoluble in water. Its vapors are heavier than air. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or involved in fire Do not extinguish lire unless (low can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet If material leaking (not on fire), downwind evacuation must be considered ETHYL NITRITE 4907020 FLAMMABLE LIQUID UN1194 THERMALLY UNSTABLE Ethyl nitrite is a clear colorless to yellow liquid. It has a flash point of- 31 deg. f, and a boiling point of 63. deg. F. It is flammable over a wide range of vapor-air concentrations. The vapors may ignite spontaneously at 194 deg. f. and its decomposition may reach explosive violence. H is decomposed by heat and light. Prolonged exposure to heat or fire by the containers of the material may result in their violently rupturing due to the decomposition of the material. It is lighter than water and insoluble in water. Its vapors are heavier than air. Toxic oxides of nitrogen are produced during combustion of this material, tf material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical tf material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out ol water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet If material leaking (not on fire), downwind evacuation must be considered ETHYL PHENYL OICHLOROSILANE 4934245 CORROSIVE MATERIAL, ACIDIC UN2435 Ethyl phenyl dichlorosilane is a colorless liquid with a pungent odor. It is decomposed by water to hydrochloric acid with evolution of heat. It is corrosive to metals and tissue. If material on fire or Involved in fire Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing ETHYL PHOSPHONOTHIOIC DICHLOR1DE, 4933355 ANHYDROUS CORROSIVE MATERIAL NA1760 Ethyl phosphonothioic dichloride, anhydrous is a dear colorless liquid with a pungent odor, ft win bum though it may require some effort to ignite, ft is heavier than water and reacts with water forming hydrochloric acid, a corrosive material, with release of heat ft is corrosive to metals and tissue. tf material on fire or involved In fire Use "alcohol" foam, carbon dioxide or dry chemical Do not use water on material ttsetf If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Do not use water on meterial itself Neutralize spilled material with crushed limestone, soda ash, or time Continued on next pogo April 1981 ttCD 0009974 231 Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap ana water ETHYL PHOSPHONOUS DICHLORIDE, ANHYOROUS 4933332 CORROSIVE MATERIAL, ACIDIC NA2645 PYROFORIC Ethyl phosphorous dichloride, anhydrous is a colorless liquid with a pungent odor. It is pyroforic and will spontaneously ignite on contact with moist air or water. It is heavier than water and besides igniting on contact with water hydrochloric acid, a corrosive material, is produced. It is corrosive to metals and tissue. If material on fire or Involved in fire Use "alcohol" foam, carbon dioxide or dry chemical Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and 'water ETHYL PHOSPHOROOICHLORIDATE 4933333 CORROSIVE MATERIAL, ACIDIC NA1760 Ehtyl phosphorodichloridate Is a dear colorless liquid with a pungent odor. It reacts with water giving hydrochloric and phosphoric adds, which are also corrosive materials. It is corrosive to metals and tissue. If material on fire or Involved In fire Use "alcohol" foam, carbon dioxide or dry chemical Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and log Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire end not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind 232 Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ETHYL PROPIONATE 4909170 FLAMMABLE LIQUID UN1195 Ethyl propionate i$ a clear colorless liquid with a pineapple like odor. It has a flash point of 54 deg. F. It is lighter than water and is insoluble in water. Its vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use 'alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ETHYL SILICATE 4913166 COMBUSTIBLE LIQUID UN1292 Ethyl silicate is a clear colorless liquid with a faint odor. It has a flash point of 125 deg. F. It is lighter than water and reacts with water forming a silicone adhesive, a milky white mass. Its vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Coot aN affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ETHYL-N-BUTYLAMINE (FLAMMABLE LIQUID, N.O.S.) 4909173 FLAMMABLE LIQUID UN1993 Ethyl-n-butylamine is a clear colorless liquid with a fish like odor. It has a flash point of 65 deg. F. It is lighter than water and slightly soluble in water. Its vapors are heavier than air. Toxic oxides of nitrogen are produced during combustion of this material. April 1981 MCD 000009975 ff material on fire or involved in fire Do not extinguish tire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire end not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing ETHYL-N-CYCLOHEXYLAMINE (FLAMMABLE LIQUID, 4909165 N.O.S.) FLAMMABLE LIQUID UN19S3 Ethyi-n-cyciohexylamine is a dear colorless liquid with an ammonia like odor. It has a flash point of 86 deg. F. It is lighter than water and is slightly soluble in water. Its vapors are heavier than air. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or involved in fire Do not extinguish fire unless flow can be slopped Use water in flooding quantities as tog Solid streams of water may spread fire Cool ati affected containers with Hooding quantities of water Apply water from as far a distance as possible Use "aicohoT foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing April 1981 ETHYL-3-3,DHTERT-8UTYLPER0XY)BUTYRATE, (TECHNICALLY PURE) 4919275 ORGANIC PEROXIOE UN21S4 Ethyl-3-3.di-(tert-butylperoxy)butyrate, (technically pure) is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite; but once ignited, it will bum with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burn ing of combustible materials. Under prolonged exposure to tire or heat containers of the matenal may explode If material on fire or involved in fire Use water in flooding quantities as log Solid streams ol water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as oossibie Use "alcohol" foam, carbon dioxide or ary chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material v.'hich may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing tiiis material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet ETHYL-3,3-DKTERT-BUTYLPEROXY)BUTYRATEf 4919273 (NOT MORE THAN 50% WITH INERT INORGANIC SOLID) ORGANIC PEROXIDE UN2596 Ethyl-3,3-dh(tert-butylperoxy)butyrate, (not more than 50% with inert inorganic solid) ia a white solid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. It is easily ignited and bums with increasing rapidity as the fire progresses, ft can form explosive mixtures with finely divided combustible materials. It supports the burning of com bustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or Involved in fire Use water in Hooding quantities as fog Solid streams of water may be ineffective Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive H material not on fire end not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Continued on next page 233 Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet ETHYL-3,3-DI-(TERT-BUTYLPEROXY)BUTYRATE, 4919274 (NOT MORE THAN 77% IN SOLUTION) ORGANIC PEROXIDE UN21B5 Ethyl-3.3-di-(tert-butylperoxy)butyrate. (not more than 77% in solution) is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite; but once ignited, it will bum with increasing rapidity as the fire progresses. If spilled on combustible materials, spon taneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burning of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or involved In fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear fid protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet ETHYLCHLORIOE 4908162 FLAMMABLE LIQUIO UN1037 Ethyl chloride is a clear colorless liquid with a pungent odor. It has a flash point of -56 deg. F. and a boiling point of 54 deg. F. ft is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical 234 if material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without ha2ard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered ETHYLENE 4905734 FLAMMABLE GAS UN1962 Ethylene is a colorless gas with a sweet odor and taste. It is easily ignited. The gas is. lighter than air but a flame can flash back to the source of the leak very easily. Under fire conditions cylinder of the gas may violently rupture and rocket. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered ETHYLENE CHLOROHYORIN 4921420 POISON B, COMBUSTIBLE UN1135 Ethylene chtorohydrin is a colorless liquid with an ether-like odor. H is soluble in water and Is also a combustible liquid. Its vapors are heavier than air and it is toxic by inhalation and skin absorption. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Use water spray to absorb vapors If material not on fire and not Involved in fire Keep sparks, flames, and other sources of Ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid April 1981 MCD 000009977 Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered ETHYLENE DIBROMIOE (OR) 1,2-DIBROMOETHANE 4940335 ORM-A UN16Q5 ENVIRONMENTALLY HAZAROOUS SUBSTANCE (RQ-1000/454) Ethylene dibromide is a dear colorless liquid with a sweetish odor. It is used as a solvent, as a grain fumigant, in the manufacture of other chemicals, and for many other uses. It is heavier than water and slightly soluble in water. It is non-combustible. It can cause illness by inhalation, skin absorption and/or ingestion. It weighs 18.1 pounds per gallon. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) If material not involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles - Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Apply "universal" gelling agent to immobilize spill Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated cart>on at ten times the spilled amount in region ol lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates ETHYLENE BICHLORIDE 4909166 FLAMMABLE LIQUID UN1164 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-S000/2270) Ethylene dichloride is a dear colorless liquid with a chloroform-like odor. It has a flash point of 56 deg. F. it is heavier than water and insoluble in water. Its vapors are heavier than air. It weighs 10.4 pounds per gallon. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, earbon dioxide or dry chemical April 1981 tf material not on fire and not involved In fire Keep sparks, flames, and other sources ol ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash, cement powder, sawdust, or com mercial sorbents Apply "universal" gelling agent to immobilize spill Apply fluorocarbon-water foam to diminish vapor and fire hazard Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom if dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Thermal decomposition to phosgene can occur ETHYLENE GLYCOL DIETHYL ETHER 4913115 COMBUSTIBLE LIQUID UN11S3 Ethylene glycol diethyl ether is a dear colorless liquid with a faint ether-like odor. It has a flash point of 100 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cod all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohd" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ETHYLENE GLYCOL MONOETHYL ETHER 4913116 COMBUSTIBLE LIQUID UN1171 Ethylene glycd monoethyl ether is a dear colorless liquid. It has a (lash point of 120 deg. F. It is lighter than water and soluble in water. Its vapors are heavier than air. Continued on no* page MCD 000009978 235 If material on fire or Involved In fire Oo not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of wafer or soap and water ETHYLENE GLYCOL MONOETHYL ETHER ACETATE 4913117 COMBUSTIBLE LIQUID UN1172 Ethylene glycol monoethyt ether acetate is a dear colorless liquid with a pleasant odor. It has a flash point of 120 deg. F. It is lighter than water and slightly soluble in water. Its vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical tf material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ETHYLENE GLYCOL MONOMETHYL ETHER 4913162 COMBUSTIBLE UQUIO UN1186 Ethylene glycol monomethyl ether is a dear colorless liquid with a pleasant odor. It has a flash point of 110 deg. F. It is lighter than water and soluble in water, its vapors are heavier than air. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to disperse vapors and dilute standing pools of liquid 236 000009979 MCD Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ETHYLENE GLYCOL MONOMETHYL ETHER ACETATE 4913163 COMBUSTIBLE LIQUID UN1189 Ethylene glycol monomethyl ether acetate is a clear colorless liquid with a pleasant odor. It has a flash point of 135 deg. F. It is heavier than water and soluble in water. Its vapors are heavier than air. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread tire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ETHYLENE (MINE. INHIBITED 4906220 FLAMMABLE LIQUID, POISONOUS UN1185 THERMALLY UNSTABLE Ethylene imine is a dear, colorless liquid with an ammonia-like odor. It has a flash point of 12 deg. F. It is flammable over a wide range of vapor-air concentrations. The vapors are initially irritating to the skin, eyes. nose, and throat Prolonged exposure may result in death due to inhalation, skin absorption, or ingestion. It is lighter than water and soluble in water. The vapors are heavier than air. Prolonged exposure of containers of the material to fire or heat may result in its polymerization and a violent rupturing of the container. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers Build dikes to contain (low as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and (flute standing pools of liquid April 1981 I Personnel protection Keep upwind Wear boots, protective gloves. ar>d goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts ot water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in ram or fire fighting water Environmental considerations--water spill Adjust ph to neutral <ph-7) Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates CUPRIC TARTRATE ORM-E 4962614 NA9111 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-IOQ/45.4) Cupric tartrate is a green to blue powder. It is used for electroplating metals. It is insoluble in water. It is non-combustible. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) If material not involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates CUPRIETHYLENE-DtAMINE SOLUTION 4935630 CORROSIVE MATERIAL. BASIC UN1761 Cupnethylene-diamine solution is a purple colored liquid with an am monia like odor, it is soluble in water, it is corrosive to metals and tissue. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with Hooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use alcohol" foam, carbon dioxide or dry chemical H material not on Are and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain How as necessary April 1981 Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material if contact with the material anticipated, wear full protective ctolhing CUTCH, CATECHU, OR JAPONICA EXTRACTS. 4915432 LIQUIO (COMBUSTIBLE LIQUID. N.O.S.) COMBUSTIBLE LIQUID NA1993 Cutch. catechu, or japonica extracts, liquid are materials containing a solvent having a closed cup flash point between 100 and 199 deg. F. The hazard of these materials Is combustibility. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in Hooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical H material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water CUTCH. CATECHU. OR JAPONICA EXTRACTS, 4910432 UQUIO (FLAMMABLE LIQUIO, N.O.S.) FLAMMABLE LIQUID UN1993 Cutch. catechu, or japonica extracts, liquid are materials containing a solvent having a closed cup flash point of less than 100 deg. F. The hazard of these materials is flammability. If material on Are or involved In Are Do not extinguish fire unless How can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with Hooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on Art and not involved in Are Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 157 MCD 000009980 If material not on Are and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Guild dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material if contact with the matenal anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fty ash or cement powder Neutralize with sodium bisuttate (nah$o4) Environmental considerations--water spill Use natural barriers or oil spill control booms to limit spill motion Use surface active agent (e.g. detergent, soaps, alcohols) to com press and thicken spilled material iniect "universal" gelling agent to solidify encircled spill and increase effectiveness of booms Add sodium bisulfate If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air epill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment ETHYLENEDIAMINETETRAACET1C AGIO (OR) EDTA ORM-E 4966910 NA9117 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) ' Ethyienediaminetetraacetic add is colorless crystalline solid. It is used in chemical analysis, to make detergents and cleaning compounds, and for many other uses. It is slightly soluble in water. It is non-combustible. H materiel Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material Itself does not bum or bums with difficulty.) If material not involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet lo prevent dissolving in rain or fire fighting water Environmental considerations--water spill Add caustic soda Adjust ph to neutral (pb-7) Use mechanical dredges or lifts to remove immobilized messes of pollutants and precipitates 238 ETHYLHEXYLACRYLATE (COMBUSTIBLE LIQUID. 4912220 N.O.S.) COMBUSTIBLE LIQUID NA1993 Ethythexylacrylate is a clear colorless liquid with a pleasant odor. It is used in making of paints and plastics. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or Involved In fire Do not extinguish fire unless How can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate (or a radius of 1500 feet ETHYLTRICHLOROSILANE 4907620 FLAMMABLE LIQUID, CORROSIVE ACIDIC UN1196 Ethyttrichlorosilane is a colorless fuming liquid with a pungent odor. It has a flash point of 57 deg. F. Vapor and liquid can cause bums. It is heavier than water and is decomposed by water to form hydrochloric acid, a corrosive material. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use "alcohol" foam, carbon dioxide or dry chemical Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Do not use water on material itseK Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered April 1981 Mod 0000998l ETIOLOGIC AGENT, N.O.S. (OR) INFECTIOUS 4925999 SU8STANCE, HUMAN, N.O.S. ETIOLOGIC AGENT NA2814 Etiologic agent or infectious substance, human is a viable microo- ganism or its toxin which causes or may cause human disease- In case of damage to. or leaking of the package contact- Director. center for disease control Atlanta, georgia its toxin which causes or may cause human disease. In case of damage to, or leaking of the package contact- corrosive material. Its vapors are heavier than air. EXPLOSIVE AUTO ALARM 4903420 CLASS C EXPLOSIVE Explosive auto alarm is a tubular device containing a small amount of explosive composition and igniting compound which is ignited by an electric spark. If material on fire or involved in fire Dangerously explosive Flood with water Apply water from as far a distance as possible If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet EXPLOSIVE BOMB 4901230 CLASS A EXPLOSIVE Explosive bomb is a metal or other type of container filled with a high explosive- It may be shipped either fuzed or unfuzed. The fuzed bomb may be sensitive to shock or mechanical impact Under prolonged ex posure to heat or fire it can explode. If material on fire or involved In fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let bum If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 5000 feet EXPLOSIVE CABLE CUTTER 4903310 CLASS C EXPLOSIVE Explosive cable cutter is a device containing an explosive charge used to propel a knife-edged component into an anvil. If material on fire or Involved In fire Flood with water Apply water from as far a distance as possible If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away April 1981 Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet EXPLOSIVE MINE 4901235 CLASS A EXPLOSIVE Explosive mine is a metal or composition container filled with a high explosive. It may be shipped either fuzed or unfuzed. The fuzed mine may be sensitive to shock or mecnamcai impact. Under prolonged ex posure to heat or fire it can explode. If material on fire or involved in fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let bum If material not on fire and not involved In fire Keep sparks, flames, and otrer sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 5000 feet EXPLOSIVE POWER DEVICE, CLASS B 4902570 CLASS B EXPLOSIVE Explosive power device, class o is a device designed to drive a gen erator or mechanical apparatus by means of a propellant explosive, class b. The device has a housing containing the propellant explosive and an electric igniter or squib. The explosive power device class b differs from an explosive power device, class c by the amount of (he propellant explosive. If material on fire or involved In fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let bum If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fwnes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet EXPLOSIVE POWER DEVICE, CLASS C 4903480 CLASS C EXPLOSIVES Explosive power device, class c is a device designed to drive a gen erator or mechanical apparatus by means of a propellant explosive class b. The device has a housing containing the propellant explosive and an electric igniter or squib. The explosive power device, class c differs from an explosive power device, class b by the amount of propellant explosive or the power of the propellant explosive. If material on fire or involved in fire Flood with water Apply water from as far a distance as possible Continued on next page 239 MCI) 00009982 If material not on fire and not Involved in fire Keep sparks, flames, and other sources oi ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feel EXPLOSIVE PROJECTILE 4901240 CLASS A EXPLOSIVE -xplosive projectile is a shell, projectile, warhead, or rocket head loaded with explosives or bursting charges with or without other mate* rials. It may be shipped either fuzed or unfuzed. The fuzed projectile may be sensitive to shock or mechanical impact. Under prolonged ex posure to heat or fire it can explode. If material on fire or involved in fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let bum If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 5000 feet EXPLOSIVE TORPEDO 4901245 CLASS A EXPLOSIVE Explosive topedo is a metal device containing a propulsion device and a quantity of high explosives. It may be shipped either fuzed or untuzed. It may be sensitive to shock or mechanical impact. Under prolonged exposure to heat or fire it can explode. If material on fire or involved in fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let bum If material not on fire and not involved in fire Keep sparks, flames, and other sources ol ignition away Personnel protection Avoid breaking dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 5000 feet EXPLOSIVE RELEASE DEVICE 490331$ CLASS C EXPLOSIVE Explosive release device consists of a rod or link fitted with a means for mechanical attachment to other apparatus or equipment and con taining a small electrically initiated explosive charge which will break the rod or link upon functioning. If material on fire or involved In fire Flood with water Apply water from as far a distance as possible If material not on fire and not Involved In fire Keep sparks, flames-, and other sources of ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable ovacuate for a radius of 1S00 feet EXPLOSIVE RIVET 4903425 CLASS C EXPLOSIVE Explosive rivet is an ordinary rivet having a cavity in the end opposite to the rivet head. The cavity is filled with an explosive composition. It functions on application of heat or impact by expanding. If material on fire or Involved In fire Dangerously explosive Flood with water Apply water from as far a distance as possible If materiel not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away EXTRACT, LIQUID, FLAVORING 4910161 FLAMMABLE LIQUID UN1197 Extract, liquid, flavoring is generally an alcoholic extract of various vegetable products used for flavoring food. It has a flash point of less than 100 deg. F. It is lighter than water and soluble in water. Its vapors are heavier than air. H material on fire or involved In fire Do not extinguish tire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to disperse vapors and dilute standing pools of Squid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water EXTRACTS, CHESTNUT OR QUEBRACHO, UQUIO 4915430 (COMBUSTIBLE LIQUID, N.O.S.) COMBUSTIBLE UQUIO NA1993 Extracts, chestnut or quebracho, liquid are materials containing a solvent having a closed cup flash point between 100 and 199 deg. F. The hazard is combustibility. 240 April 1981 000009983 tf material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use 'alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep soarks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Oo not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water EXTRACTS. CHESTNUT OR QUEBRACHO. LIQUID 4910430 (FLAMMABLE LIQUIDS. N.O.S.) FLAMMABLE LIQUID UN1993 Extracts, chestnut or quebracho, liquid are materials containing a solvent having a closed cup flash point of less than 100 deg. F. The hazard is flammability. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water EXTRACTS. FUSTIC OR LOGWOOD. UQUID OR 4915434 PASTE (COMBUSTIBLE UQUID, N.O.S.) COMBUSTIBLE UQUID NA1993 Extracts, fustic or logwood liquid or paste are materials containing a solvent having a closed cup flash point between 100 and 199 deg. F. The hazard of these materials is combustibility, tf material on fire or involved In fire Do not extinguish fire unless (low can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical tf material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors April 1961 Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water EXTRACTS, FUSTIC OR LOGWOOD, LIQUID OR 4910434 PASTE (FLAMMABLE LIQUID, N.O.S.) FLAMMABLE LIQUID UN1993 Extracts, fustic or log wood liquid or paste are materials containing a solvent having a closed cup flash point of less than 100 deg. F. The hazard of these matenals is flammability, tf material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water EXTRACTS, HYPERNIC UQUID OR PASTE 4915438 (COMBUSTIBLE UQUIO, N.O.S.) COMBUSTIBLE UQUID NA1993 Extracts, hypemic. liquid or paste are materials containing a solvent having a closed cup flash point between 100 and 199 deg. F. The hazard of these materials is combustibility, tf material on lira or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 241 0o EXTRACTS. HYPERNIC LIQUID OR PASTE 4910438 (FLAMMABLE LIQUID, N.O.S.) FLAMMABLE LIQUID UN1993 Extracts, hypemic. liquid or paste are materials containing a solvent having a dosed cup flash point of less than 100 deg. F. The hazard of these materials is flammability. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water m flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use 'alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep material out of water sources and sewers Keep sparks, flames, and other sources of ignition away Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do nol handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water EXTRACTS, TANNING. NEC UQUID OR PASTE 4915440 (COMBUSTIBLE LIQUID, N.O.S.) COMBUSTIBLE UQUID NA1993 Extracts, tanning, nec liquid or paste are materials containing a solvent having a closed cup flash point between 100 and 199 deg. F. The hazard of these materials is combustibility. If materiel on fire or involved In fire Do not extinguish lire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water EXTRACTS, TANNING, NEC UQUID OR 4910440 PASTE(FLAMMABLE UQUID, M.O.S.) FLAMMABLE LIQUIO UNI993 Extracts, tanning, nec liquid or paste are materials containing a solvent having a closed cup flash point of less than 100 deg. F. The hazard of these materials is flammability. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Appty water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical 242 MCD 000009985 If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain (low as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water FATTY ALCOHOLS, ALIPHATIC OR CYCLIC, 4935223 CYANOETHYLATED AND HYDROGENATED, AND DERIVATIVES THEREOF SUCH AS SALTS OIAMINES, OXYALKYLATES AND QUANTERNARY AMMONIUM COMPOUNDS (ALKALINE CORROSIVE LIQUID, N.O.S.) CORROSIVE MATERIAL, BASIC NA1719 Fatty alcohols, aliphatic or cyclic, cyanoethylated or hydrogenated and derivatives thereof such as salts, diamines, oxyalkylates and quaternary ammonium compounds are colorless to milky or amber colored liquid. They will bum though they may require some effort to ignite. They are lighter than water and may or may not be soluble in water. They are corrosive to metals and/or tissue. If materiel on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Appty water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing FATTY ALCOHOLS, ANIMAL FAT OR ANIMAL, FISH, 4915548 PETROLEUM, SEA-ANIMAL OR VEGETABLE OILS, NEC, WHEN BLENOEO WITH EACH OTHER. UQUID (ALCOHOL, N.O-S.) COMBUSTIBLE UQUID UN1987 Fatty alcohols are dear colorless to light colored liquids. They have a flash point between 100 and 200 deg. F. They are ighter than water and insoluble in water. Their vapors are heavier than air. If materiel on fire or involved in fire Do not extinguish fire unless now can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical H material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors April 1981 Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water FEEDING TANKAGE. NEC (FLAMMABLE SOLID, 4917412 N.O.S.) FLAMMABLE SOLID NA1325 Feeding tankage, nec is various scrap food products. If it has not been properly cooled or is too dry it is liable to spontaneous heating and ignition. If material on fire or Involved In fire Flood with water If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away FELT, WASTE, WET (See WASTE WOOL, WET 4917372) FERRIC AMMONIUM CITRATE 4963349 ORM-E NA9118 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-IOOO/454) Ferric ammonium citrate is a yellowish brown to red solid with a taint odor of ammonia. It is used in medicine, in making blueprints, and as a leed additive. It is soluble in water. It is non-combustible. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) If material not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--wtter spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates FERRIC AMMONIUM OXALATE 4963352 ORM-E NA9119 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100QM54) Ferric ammonium oxalate is a green crystalline solid. H t$ used in making blueprints. It is soluble in water. It is non-combustible. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary April 1961 Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic Sheet to prevent dissolving in ram or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or 'ifts to remove immobilized masses of pollutants and precipitates FERRIC ARSENATE, SOLID 4923231 POISON B UN1606 Ferric arsenate, solid is a green or brown powder. It is insoluble in water. It is toxic by ingestion. H material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved In fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material if contact with the material anticipated, wear full protective clothing FERRIC ARSENITE, SOLID 4923232 POISON B UN1607 Ferric arsenke is a yellow-brown powder. It is insoluble in water. It is toxic by ingestion, tf material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water In flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved In fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing 0o^ae 243 FERRIC CHLORIDE SOLID ORM-8 4944138 UNI 773 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/4S4) Ferric chloride is an orange to brown black solid. It is used to treat sewage, industrial waste, to purify water, as an etching agent for en graving circuit boards, and in the manufacture of other chemicals. It is soluble in water. It is non-combustible. It is corrosive to aluminum. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not involved in fire Keep matenal out of water sources and sewers Build dikes to contain ftow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or tire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates FERRIC CHLORIOE SOLUTION (IRON CHLORIDE 4932343 (IRON MURIATE), OTHER THAN CRUDE, LIQUID) CORROSIVE MATERIAL UN2582 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Ferric chloride solution is the water solution of the yellow orange crystalline solid having a faint hydrochloric add odor, it is corrosive to metals and tissue, it weighs 12.6 pounds per gallon. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible H material not involved in fire Keep material out ot water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water if contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash. cement powder, sawdust, or com mercial sorbents Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate 244 000009987 Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Adjust ph to neutrai (ph-7) Environmental considerations--air spill Apply water spray or mist to knock down vapors FERRIC CHLORIDE SOLUTION (IRON CHLORIDE, 4932342 CRUDE, LIQUID NOT LESS THAN 50% WATER) CORROSIVE MATERIAL UN2562 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/4S4) Ferric chloride solution is the water solution of the yellow orange crystalline solid having a faint hydrochloric acid odor. It is corrosive to metals and tissue. It weighs 12.6 pounds per gallon. It material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pH, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash, cement powder, sawdust, or com mercial sorbents Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Adjust ph to neutrai (ph-7) Environmental considerations--air spiH Apply water spray or mist to knock down vapors FERRIC FLUORIDE 4962626 ORM-E NA9120 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-100/45.4) Ferric fluoride is a green crystalline solid. It is used in ceramics. It is soluble in water. It is non-combustible. H material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) If material not Involved in fire Keep material out ot water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1981 Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Add soda ash Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates FERRIC NITRATE 4918725 OXIDIZER UNI 466 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Ferric nitrate is a violet crystalline solid. It is used for dyeing and tanning, in chemical analysis, and in medicine. It is soluble in water. It is non-combustible but it will accelerate the burning of combustible ma terials. If large quantities are involved in the fire or the combustible material is finely divided an explosion may result. Prolonged exposure of the material to fire or heat may result in an explosion. Toxic oxides of nitrogen are produced in fires involving this material. If material on fire or Involved In fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing (his material Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates FERRIC SULPHATE SOLUTION (FERRIC SULFATE) 4963827 ORM-E NA9121 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Ferric sulphate solution is the yellow crystalline solid dissolved in water. It is used in water purification, as a disenfectanL in textile proc essing, and for many other uses. It is non-combusbbie. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) If material not involved In fire Keep material out oi water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1981 Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash, cement powder, sawdust, or com mercial sorbents Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Adjust ph to neutrai tph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates FERROUS AMMONIUM SULFATE 4963354 ORM-E NA9122 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Ferrous ammonium sulfate is a light green crystalline solid. It is used in medicine, in chemical analysis, and in metallurgy. It is soluble in water. It is non-combustible. If material involved In fire Extinguish fire using agent suitable lor type of surrounding fire (Matenal itself does not bum or bums with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Allow to aerate Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates FERROUS AMMONIUM SULPHATE, FERTILIZER 4963357 GRADE (IRON AMMONIUM SULPHATE) (FERROUS AMONMJM SULFATE) ORM-E NA9122 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Ferrous ammonium sulphate, fertilizer grade is a light green crystalline solid. It is used as an ingredient to mixed fertilizers or as a soil additive by itself. It is soluble in water, it is non-combustible. If material involved In fire Extinguish fire using agent suftable for type of surrounding fire (Material itself does not bum or bums with difficulty.) If material not Involved In fire Keep material out of water sources and sewers Build dikes to contain How as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Conttnuod on noxt paga 245 Environmental consideration*--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Allow to aerate Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Adjust ptj to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates FERROUS ARSENATE, SOLID 4923233 POISON B UN160S Ferrous arsenate, solid is a green powder. It is insoluble in water. It is toxic by ingestion. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not Involved In fira Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear tuit protective clothing FERROUS CHLORIDE, SOUO 4941131 ORM-A NA17S9 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100/45.4) Ferrous chloride is a greenish white crystalline solid, it is used in sewage treatment, in dyeing of fabrics, and for many other uses. It is soluble in water. It is non-combustible. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) If materiel not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Adjust ph to neutral (ph-7) Allow to aerate Neutralize with agricultural lime (slaked time), crushed limestone. or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates FERROUS CHLORIDE, SOLUTION 4932329 CORROSIVE MATERIAL NA1760 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100/45.4) Ferrous chloride, solution is the greenish-white crystalline solid dis solved in water. It is used in dyeing, in medicine, and sewage treatment. It is corrosive to metals and tissue. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing fumes from burning material Avoid bodity contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash. cement powder, sawdust, or com mercial sorbents Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Adjust ph to neutral (ph-7) Environmental considerations--air spill Apply water spray or mist to knock down vapors FERROUS SULFATE 4963832 ORM-E NA9125 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Ferrous sulfate is a greenish to yellow brown crystalline solid. It is used used to make other iron compounds, in water and sewage treat- mem, as a fertilizer, feed additive, and tor many other uses. It is slightly soluble in water. It is non-combust&>ie. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material Itself does not bum or bums with difficulty.) tf materiel not Involved kt fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental consideration*--land apill Dig a pit pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water 246 MCD 000009989 April 1961 Environmental consideration*--watar spill Adjust ph to neutral (ph-7) Allow to aerate Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates FERROUS SULPHATE, LESS THAN 40% WATER 4963636 (FERROUS SULFATE) ORM-E NA9125 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RG-1000/454) Ferrous sulphate, less than 40% water is a greenish to yellowish brown crystalline solid. It is used for sewage and water treatment, as a fertilizer, feed additive, and for many other uses. It is slightly soluble in water. It is non-combustible. It weighs 15.0 pounds per gallon. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) If material not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental consideration#--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sard bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fty ash, cement powder, sawdust, or com mercial sorbents Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Adjust ph to neutral (ph-7) Allow to aerate Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates FERROUS SULPHATE, NOT LESS THAN 40% WATER 4963841 (FERROUS SULFATE) ORM*E NAdi 25 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Ferrous sulphate, not less than 40% water is either a greenish to yellow brown crystalline or a dark green to brown liquid. It is used for water or sewage treatment as a fertilizer ingredient and for other uses, tt is non-combustible. It weighs 15.0 pounds per gallon. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) If materiel not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1981 Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash, cement powder, sawdust, or com mercial sorbents Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Adjust ph to neutral (ph-7) Allow to aerate Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates FERTILIZER AMMONIAT1NG SOLUTION (CONTAINING 4904250 FREE AMMONIA) NONFLAMMABLE GAS, CORROSIVE UNI 043 Fertilizer ammoniating solution is the solution of ammonium com pounds charged with ammonia gas and having a absolute pressure exceeding 40 psi at 70 deg. F. in the container. It has the characteristic odor of ammonia. The solution may be corrosive. Although ammonia is lighter than air, the vapors initially tend to hug the ground. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use water spray to absorb vapors If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak rf without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and gas tight goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Evacuation if material leaking (not on fire), downwind evacuation must be considered FERTILIZER SOLUTION, CONSISTING OF WATER, 4935272 FREE AMMONIA AND SULPHUR, TOTAL AMMONIA CONTENT NOT TO EXCEED 30 PERCENT BY WEIGHT (CORROSIVE LIQUID, N.O.S.) CORROSIVE MATERIAL UN1760 Fertilizer solution, consisting of water, free ammonia and sulphur, total ammonia content not to exceed 30 percent by weight is a colorless to yellow colored liquid having the odor characteristic of ammonia. It is corrosive to metals and tissue, its vapors are heavier than air. If material on fire or Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material Itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Apply water from as far a distance as possible Use water spray to absorb vapors ContUuMd on n*xt p*g* 247 mod 000009990 If material not Involved In fire Keep material out of water sources and sewers Build dikes lo contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing FILM (NITROCELLULOSE) (CELLULOSE FILM SCRAP 4917383 OR WASTE) FLAMMABLE SOUD NA1324 Film (nitrocellulose) is a photographic film made from nitrocellulose. It is easily ignited and bums with great rapidity. Older film may deteriorate and be liable to spontaneous heating and ignition. Toxic oxides of ni trogen are produced during combustion. II material on fire or involved in fire Flood with water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Wear self-contained breathing apparatus when fighting fires involv ing this material Approach fire with caution FERTILIZING COMPOUNDS, NEC DRY (OXIDIZING 4918920 MATERIAL. N.O.S.) OXIDIZER UNI 479 Fertilizing compounds, nec, dry are various materials which have the property of accelerating the burning of combustible material. These materials may not bum by themselves. Prolonged exposure to fire or heat by these materials anchor their containers may result in an explo sion. These materials may only be packaged in containers of 55-gallon capacity or smaller. If material on fire or Involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved In fire Keep sparks, flames, and other sources of Ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate lor a radius of 2500 feet FIBERS OR FABRIC, CONTAINING NOT MORE THAN 4917327 S% ANIMAL OR VEGETABLE OIL. FLAMMABLE SOUD NA1373 Fibers or fabric, containing not more than 5% animal or vegetable oil are materials that have been contaminated, impregnated or coated with animal or vegetable oil. It is liable to spontaneous heating and ignition. If material on fire or Involved In fire Flood with water If material not on lira and not involved in fire Keep sparks, flames, and other sources of ignition away FILM (NITROCELLULOSE) (MOVING PICTURE FILM 4917340 SCRAP) FLAMMABLE SOLIO NA1324 Film (nitrocellulose) Is a photographic Him made of nitrocellulose. It is easily ignited and bums with great rapidity. Older film may deteriorate and be liable to spontaneous heating and ignition. Toxic oxides of ni trogen are produced during combustion. If material on fire or involved In fire Flood with water Apply water from as far a distance as possible tf material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Wear self-contained breathing apparatus when fighting fires involv ing this material Approach fire with caution FILM (NITROCELLULOSE) (MOVING PICTURE FILM, 4917337 EXPOSED, NEC) FLAMMABLE SOUD NA1324 Film (nitrocellulose) is a photographic film made of nitrocellulose. It is easily ignited and bums with great rapidity. Older film may deteriorate and be liable to spontaneous heating and ignition. Toxic oxides of ni trogen are produced during combustion, fl material on fire or involved In fire Flood with water Apply water from as far a distance as possible If material not on fire end not Involved In fire Keep sparks, flames, and other sources of ignition away Personnel protection Wear self-contained breathing apparatus when fighting fires involv ing this material Approach fire with caution FIBERS, BURNT 491732S FLAMMABLE SOLID NA1372 Burnt fiber is fiber that has been on fire and the burned parts have not been removed. The hazard is that once the liber has been on fire the tire may persist for a long time in the interior of the bale or bag. H material on fire or involved In Art Flood with water H material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away FILM (NITROCELLULOSE) (PHOTOGRAPHIC FILM, 4917382 NEC, UNEXPOSED) FLAMMABLE SOUD NA1324 Rim (nitrocellulose) is a photographic film made from nitrocellulose. It is easily ignited and bums with great rapidity. Olderfilm may deteriorate and be liable to spontaneous heating and ignition. Toxic oxides of ni trogen are produced during combustion. If material on fire or Involved In fire Flood with water Apply water from as tar a distance as possible 248 009"^ 00 April 1981 H material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Personnel protection Wear self-contained breathing apparatus when fighting fires involv ing this material Approach fire with caution FIRE EXTINGUISHER 4904820 NONFLAMMABLE GAS UN1044 Fire extinguisher is a device containing a nonflammable gas under pressure, it has a mechanism to spray the contained gas or expel a liquid, through some type of nozzle. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Wear protective gloves and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water FIRE EXTINGUISHER CHARGES CONTAINING 4930219 SULFURIC ACID CORROSIVE MATERIAL, ACIDIC UN1774 Fire extinguisher charges consist of two chemicals packed in the same outside container. One is sodium bicarbonate, white water soluble solid that is non hazardous. The other is sulfuric add, in limited quantities, i colorless odorless liquid. Sulfuric add is soluble in water with release of heat. It is corrosive to metals and tissue. If material involved in fire Extinguish tire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as tog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved in fire Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear ful protective clothing If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing FIRECRACKERS OR TORPEDOES (COMMON 4903525 FIREWORKS) CLASS C EXPLOSIVE Firecrackers or torpedoes are tubular devices, made of paper with external dimensions not exceeding 1 1/2 inches in length and V4 inch in diameter. They are filled with a pyrotechnic composition not exceeding two grains in weight designed to produce an audible effect. If material on fire or Involved in fire Flood with water Apply water from as far a distance as possible If material not on fire end not involved In fire Keep sparks, flames, and other sources of ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate lor a radius of 1500 feet FISH MEAL CONTAINING LESS THEN 6% OR MORE 4917320 THAN 12% WATER (FISH MEAL, GROUND, PULVERIZED OR SCREENED) FLAMMABLE SOUO NA1374 Fish meal that is too dry is liable to spontaneous heating and Ignition. Fish meal that is too wet is liable to decay, spontaneous heating and ignition. It must be shipped in air tight metal containers. If material on fire or Involved in fire Flood with water If material not on Are and not Involved in Are Keep sparks, flames, and other sources of ignition away FIRE PROOFING COMPOUNDS, LIQUID, NEC 4936536 (CORROSIVE LIQUID, N.O.S.) CORROSIVE MATERIAL UN176Q Fireproofing compounds, liquid, nec are various colored materials. They are corrosive to metals and/or tissue. If material involved in fire Extinguish (ire using agent suitable tor type of surrounding (ire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Apply water from as far a distance as possible April 1961 RSH OIL RESIDUUM, DEHYDRATED (GARBAGE 4917460 TANKAGE (CONTAINING LESS THAN 6% MOISTURE) FLAMMABLE SOUO NA1325 Fish oil residuum, dehydrated is liable to spontaneous heating and ignition if not properly cooled after manufacture or is too dry. H materiel on Are or involved In Are Flood with water 249 WC.D 00009992 FISH SCRAP CONTAINING LESS THAN 6% OR MORE 4917329 THAN 12% WATER (FISH SCRAP, GROUND, PULVERIZED OR SCREENED) FLAMMABLE SOUD NA1374 Fish scrap that is too dry is liable to spontaneous heating and ignition. Fish scrap that is too wet is liable to decay, spontaneous heating and ignition. It must be shipped in airtight metal containers. If material on fire or involved In fire Flood with water If material not on fire and not Involved In fire Keep sparks, flames, and other sources ol ignition away FISH SCRAP CONTAINING LESS THAN 6% OR MORE 4917330 THAN 12% WATER (FISH SCRAP, NEC, DRY NOT GROUND, PULVERIZED NOR SCREENED) FLAMMABLE SOUD NA1374 Fish scrap that is too dry is liable to spontaneous heating and ignition Fish scrap that is too wet is liable to decay, spontaneous heating and ignition, It must be shipped in airtight metal containers. If material on fire or involved In fire Flood with water If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away FISH SCRAP OR FISH MEAL CONTAINING LESS 4917331 THAN 6% OR MORE THAN 12% WATER (FISH TANKAGE, NEC, DRY, NOT GROUND, PULVERIZED. OR SCREENED) FLAMMABLE SOUO NA1374 Fish scrap or fish meal that is too dry is liable to spontaneous heating and ignition. Fish scrap or fish meal that is too wet is liable to decay, spontaneous heating and ignition, it must be shipped in airtight metal containers. If material on fire or involved in fire Flood with water If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away FISH SCRAP, NEC, GREEN (FISH SCRAP 4917462 (CONTAINING LESS THAN 6% OR MORE THAN 12% MOISTURE}) FLAMMABLE SOUD NA1374 Fish scrap, nec, green that is too dry Is liable to spontaneous heating and ignition; or too wet is liable to decay, spontaneous heating and ignition. If material on fire or Involved In fire Flood with water if material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away FLAME COLORING COMPOUNDS (OXIOtZING 4918905 MATERIALS, N.O.S.) OXIDIZER UNI 479 Flame coloring compounds are various materials which have the prop erty of accelerating the burning of combustible material. These materials may not bum by themselves. Prolonged exposure to tire or heat by these ma (erials and/or their containers may result in an explosion. These materials may only be found in containers of 55-gaiton capacity or smaller. If material on fire or involved In fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible 250 If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out ol water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting tires involv ing this matenal Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet FLAME RETARDANT COMPOUNO, LIQUID 4936570 CORROSIVE MATERIAL NA1760 Flame retardant compound liquid is a variable colored material having the property of being corrosive to metals and/or tissue. It may or may not be water soluble. If material involved in fire Extinguish fire using agent suitablo for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical If material not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective dothing FLAMMABLE GAS, N.O.S. (See COMPRESSED GAS, N.O.S., FLAMMABLE GAS 4905710) FLAMMABLE LIQUID, CORROSIVE, N.O.S. 4907829 FLAMMABLE UQUID, CORROSIVE UN2924 Flammable liquid, corrosive, n.o.s. is the proper shipping name for those liquids having a closed cup flash piont of less than 100 deg. F., being corrosive to steel and/or tissue, and not being specifically men tioned in the hazardous materials regulations. Try to ascertain the exact name of the material from the shipping papers. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use "aicohor foam, carbon dioxide or dry chemical Cod all affected containers with flooding quantities of water Apply water from as tar a distance as possible Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash. or lime April 1981 0009993 Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the matenal Wear full protective clothing Do not handle broken packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts of water or soap and water FLAMMABLE LIQUID, N O S. 4910185 FLAMMABLE LIQUID UN1993 Flammable liquid, n.o.s. is the proper shipping name lor those ma- tbiiats having a closed cup flash point of less than 100 deg. F. and not specifically mentioned in the hazardous materials regulations, if material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts of water or soap and water FLAMMABLE LIQUID, POISONOUS. N.O.S. 4907422 FLAMMABLE LIQUID UN1992 Flammable liquid, poisonous, n.o.s. is the proper shipping name for those liquids having a closed cup flash point of less than 100 deg. F.. being toxic by ingestion, inhalation, or skin absorption, and not specif ically mentioned in the hazardous materials regulations. Try to ascertain the exact name of this material from the shipping papers. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams ol water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on lira and not Involved in lira Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water if contact with the material anticipated, wear full protective doming April 1981 Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered FLAMMABLE SOLID, CORROSIVE, N.O.S. 49167S5 FLAMMABLE SOLIO UN2925 Flammable solid, corrosive, n.o.s. is the proper shipping name of any solid material other than one classed as an explosive which is liable under conditions incident to transportation to cause fires through friction, absorption of moisture, spontaneous chemical changes as a result of retained heat from the manufacturing or processing of the material, or which can be easily ignited by external sparks or flame and when so ignited bums vigorously and persistently. Also, the material is corrosive to metals and/or tissue. Try to ascertain the exact name of the material from the shipping papers. If material on fire or involved in fire Extinguish fire using agent suitable for type of fire If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily, contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water tf contact with the material anticipated, wear full protective clothing FLAMMABLE SOLID, N.O.S. 4917332 FLAMMABLE SOLID UN132S Flammable solid, n.o.s. is the proper shipping name of any solid ma terial other than one classed as an explosive, or specifically listed by name in the list of hazardous materials which Is liable under conditions incident to transportation to cause fires through friction, absorption of moisture, spontaneous chemical changes as a result of retained heat from the manufacturing or processing of the solid, or which can be readily ignited by external sparks or flame and when so ignited bums vigorously and persistently. Try to ascertain the exact name of the material. If material on fire or involved In fire Extinguish fire using agent suitable for type of fire K material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Build dikes to contain flow as necessary Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water FLAMMABLE SOLID, POISONOUS, N.O.S. 4916815 FLAMMABLE SOUD, POISONOUS UN2926 Flammable solid, poisonous, n.o.s. is the proper shipping name ol any solid material other than one classed as an explosive which is liable under conditions incident to transportation to cause fires through friction, absorption of moisture, spontaneous chemical changes as a result of retained heat from the manufacturing or processing of the material, or which can be easily Ignited by external sparks or flame and when so ignited bums vigorously and persistently. Also, the material is toxic by ingestion, inhalation, or skin absorption. Try to ascertain the exact name of the material from the shipping papers. Continued on next page 251 000009994 MCD H material on fire or involved in fire Extinguish fire using agent suitable for type of fire If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Build dikes to contain flow as necessary Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water tf material not on fire and not involved in fire Keep sparks, flames, and other sources ol ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts ot water or soap and water FLARES, HIGHWAY SAFETY, SOLIDIFIED FUEL, 4917445 OTHER THAN EXPLOSIVES OR FIREWORKS. (FLAMMABLE SOLID, N.O.S.) FLAMMABLE SOLID UN1325 Flares, highway safety, solidified fuel are pasteboard or fiber tubes containing a solid fuel that bum with an intense red. green, or yellow flame. Once ignited they can bum under water. If material on fire or Involved in fire If fire is massive, back off. protect surroundings, and let bum For scattered burning fusees, smother in dirt If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing fumes from burning material FLEXIBLE LINEAR SHAPED CHARGE. METAL CLAD 4903320 CLASS C EXPLOSIVE Flexible linear shaped charge, metal dad consists of a core containing not more than 15 grains ot high explosive composition per foot and not exceeding 26 feet in length or containing not more than 2 1/2 grains of high explosive composition per foot covered with metal. It may be cov ered with tapes, yams, plastics or waterproofing compounds. If material on fire or involved in fire Dangerously explosive Flood with water Apply water from as far a distance as possible If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation it fire becomes uncontrollable--evacuate for a radfos of 1500 feet FLOOR COVERING UNDER LAYMENT COMPOUNDS, 4910456 NEC (FLAMMABLE UQUIO, N.O.S.) FLAMMABLE UOUID UNI 993 Floor covering undertayment compounds, nec are various colored thick liquids. They have a flash point of less than 100 deg. F. They are generally heavier than water and insoluble in water. The vapors are heavier than air. If material on fire or Involved In Are Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'' foam, cartoon dioxide or dry chemical 252 FLOOR COVERING UNDERLAYMENT COMPOUNDS, 491S456 NEC (COMBUSTIBLE LIQUIDS, N.O.S COMBUSTIBLE LIQUID NAt 993 Floor covering undertayment compounds, nec are various colored thick liquids. They have a flash point between 100 and 199 deg. F. They are generally heavier than water and insoluble in water. Their vapors are heavier than air. If materiel on fire or Involved In fire Do not extinguish tire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water FLOOR POLISH OR WAX (POLISH, WOOO, UQUIO) 4910271 FLAMMABLE UQUIO NA1142 Floor polish or wax is a dear colorless to milky white or cream colored thick liquid. It has a flash point ol less than 100 deg. F. It is generally heavier than water and insoluble in water, its vapors are heavier than air. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical K material not on fire end not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out ot water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1981 MCD 000009995 FLOOR ROUSH OR WAX (ROUSH, WOOD, LIQUID) 4915271 COMBUSTIBLE LIQUID NAll42 Floor polish or wax is a clear colorless lo milky white or cream colored thick liquid, ft has a flash point between 100 and 199 deg. F. It is generally heavier than water and insoluble in water. Its vapors are heavier than air. It material on fire or Involved In fire Do not extinguish fire unless (tow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water FLOUR BLEACHING COMPOUNDS, NEC (OXIOtZINO 4918910 MATERIAL, N.O.S.) OXIDIZER UNI 479 Flour bleaching compounds, nec are various materials which have the property of accelerating the burning of combustible material. These materials may not bum by themselves. Prolonged exposure to fire or heal by these materials and/or their containers may result in an explo sion. These materials may be only packaged in containers of 55-gallon capacity or smaller, tf material on fire or Involved ki fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible tf material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet FLU060RIC ACID 4930222 CORROSIVE MATERIAL, ACIDIC UN1775 Fluoboric acid is a colorless odorless liquid. It is soluble in water with release of heat. It is corrosive to metals and tissue. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible H material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind April 1981 000009996 MCD Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the matenal anticipated, wear full protective clothing FLUORIC ACID (See HYDROFLUORIC ACID SOLUTION 4930022) FLUORINE 4904030 NONFLAMMABLE GAS, OXIDIZING, POISONOUS. UN1045 CORROSIVE Fluorine is a pale yellow gas with a pungent odor. It is toxic by in halation. Contact with skin in lower than lethal concentration causes bums. It reacts with water to form hydrofluoric acid and oxygen. It is corrosive to most common materials. It reacts with most combustible matenais to the point that ignition often occurs. It must be shipped in cylinders, not equipped with a safety relief device and in quantities not exceeding 6 pounds of gas per cylinder. Under fire conditions the cyl inders are subject to violent rupturing and rocketing. It material Involved In fire Do not extinguish fire unless flow can be stopped Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Do not use water on material itself Use water spray to absorb vapors If material not Involved In fire Keep sparks, flames, and other sources of ignition away Attempt to stop leak if without hazard Use water spray to knock-down vapors Do not use water on material itself Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered FLUOROETHANE GASES, NONFLAMMABLE 4904538 (COMPRESSED GAS, N.O.S.) NONFLAMMABLE GAS UN1956 Fluoroethane gases are colorless odorless gases. They are noncom- bustibie. They can cause asphyxiation by the displacement of air. It may only be shipped in cylinders. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible H material not involved in fire Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment 253 FLUOROPHOSPHOfifC ACIO, ANHYDROUS (Sm MONOPLUOROPHOSPHORIC ACIO, ANHYDROUS 4930240) FLUOROSILICIC ACID (See HYDROFLUOROSIUCIC ACID 4930226) FLUOSULFONIC ACIO (OR) FLUOROSULFONiC ACID 4930010 CORROSIVE MATERIAL, ACIDIC, POISONOUS UNI 777 Fluosulfonic acid is an odorless fuming liquid. It is soluble in water and is decomposed by water to hydrofluoric acid and sulfuric acid with release of neat, it is corrosive to metals and to tissue. The fumes and very short contact with small quantities of the acid can cause severe painful burns. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material FOOT WARMER OR HOT BOTTLE CHARGES, 4915476 CHEMICAL (COMBUSTIBLE LIQUID, N.O.S.) COMBUSTIBLE LIQUID NA1993 Foot warmer or hot bottle charges, chemical are materials containing a solvent having a closed cup flash point between 100 and 199 deg. F. The hazard of these materials is combustibility. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water FOOT WARMER OR HOT BOTTLE CHARGES, 4910476 CHEMICAL (FLAMMABLE LIQUID, N.O.S.) FLAMMABLE UQUID UNI993 Foot warmer or hot bottle charges, chemical are materials containing a solvent having a closed cup flash point of less then 100 deg. F. The hazard of these materials is flammabiRty. 254 If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water FORMALDEHYDE (OR) FORMAUN SOLUTION (IN CONTAINERS OF 110 GALLONS OR LESS) 4940341 (FORMALDEHYDE. LIQUID) ORM-A UN1196 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Formaldehyde is the colorless solution of formaldehyde gas in water. It is used to make plastics, other chemicals and fertilizers, as a pre servative, as a corrosion inhibitor, and for many other uses, tt is com bustible and has a flash point varying from 122 to 185 deg. F. The gas readily vaporizes from the solution and is flammable over a wide vapor- air concentration range. It is heavier than water and is soluble in water. Its vapors are heavier than air. It weighs 9.4 pounds per gallon. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors or dusts Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Apply ''universal" gelling agent to immobilize spill Environmental considerations--water spill Use natural barriers or oil spill control booms to Hmit spill motion Use surface active agent (e.g. detergent, soaps, alcohols) to com press and thicken spilled material Inject "universal" gelling agent to solidify encircled spill and increase effectiveness of booms If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--sir spill Apply water spray or mist to knock down vapors April 1981 MCD 000009997 FORMALDEHYDE (OR) FORMALIN SOLUTION (IN 4940342 CONTAINERS OF 110 GALLONS OR LESS) (FORMALDEHYDE, PASTE) ORM-A UN1198 iNVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Formaldehyde is the colorless solution of formaldehyde gas in water. It is used to make plastics, other chemicals and fertilizers, as a pre servative. as a corrosion inhibitor, and for many other uses. It is com bustible and has a flash point varying from 122 to 185 deg. F. The gas readily vaporizes from the solution and is flammable over a wide vapor- air concentration range. It is heavier than water and is soluble in water. Its vapors are heavier than air. ft weighs 9.4 pounds per gailon. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors or dusts Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface How using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fty ash or cement powder Apply "universal" gelling agent to immobilize'spill Environmental considerations--water spill Use natural barriers or oil spill control booms to limit spill motion Use surface active agent (e.g. detergent soaps, alcohols) to com press and thicken spilled material Inject "universal" gelling agent to solidify encircled spill and increase effectiveness of booms If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental consideration!--air spill Apply water spray or mist to knock down vapors FORMALOEHYDE, LIQUID (FORMALOEHYDE OR 4913144 FORMAUN SOLUTION) COMBUSTIBLE UQUID UN1199 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Formaldehyde liquid is the colorless solution of formaldehyde gas in water. It is used to make plastics, other chemicals, and fertilizers, as a preservative, as a corrosion inhibitor, and for many other uses. It has a flash point varying from 122 to 185 deg. F. The gas readily vaporizes from solution and is flammable over a wide vapor air concentration range. The liquid is heavier than water and soluble in water. Its vapors are heavier than air. It weighs 9.4 pounds per gallon. If material on fire or involved In firs Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use l,alcohoi,' foam, carbon dioxide or dry chemical April 1981 -Vqo Oo If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or loamed concrete Absorb bulk liquid with fly ash or cement powder Add sodium bisulfite (nahso3) Environmental considerations--water spill Use natural barriers or oil spill control booms to limit spill motion Use surface active agent (e.g. detergent, soaps, alcohols) to com press and thicken spilled material Inject "universal" gelling agent to solidify encircled spill and increase effectiveness of booms Add sodium bisulfite If dissolved, apply activated carbon at ten times the spilled amount in regionof lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses ol pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Combustion products include corrosive or toxic vapors FORMALDEHYDE, PASTE (FORMALDEHYDE OR FORMAUN SOLUTION) 4913145 COMBUSTIBLE UQUID UN1198 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Formaldehyde, paste is the thick mixture of paraformaldehyde the polymer of formaldehyde, formaldehyde and water having an irritating odor. Formaldehyde, itself, is a gas which readily vaporizes from the paste and is flammable over a wide vapor air concentration range. The paste has a flash point range of 122 to 165 deg. F. It is heavier than water and soluble in water. Its vapors are heavier than air. tt weighs 9.4 pounds per gallon. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool alt affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protactive equipment Wash sway any material which may have contacted the body with copious amounts of water or soap and water Continued on next pegs 255 Environmental consideration*--land spill Oig a prt, pond, lagoon, holding area to contain liquid or solid material Oiks surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Add sodium bisulfite (nahsod) Environmental considerations--water spill Use natural barriers or oil spill control booms to limit spill motion Use surface active agent (e.g. detergent, soaps, alcohols) to com press and thicken spilled material Inject "universal" gelling agent to solidify encircled spill and increase effectiveness of booms Add sodium bisulfite If dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Combustion products include corrosive or toxic vapors FORMIC ACID 4931320 CORROSIVE MATERIAL, ACIDIC, COMBUSTIBLE UN1779 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Formic acid is a colorless liquid with a pungent odor. It is combustible over a wide range of vapor air mixtures and has a flash point of 156 deg. F. it is soluble in water with release of heat, tt is corrosive to metals and tissue. It weighs 10.2 pounds per gallon. If material on fire or Involved In fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Use water spray to absorb vapors If materiel not on fire and not Involved in firs Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material Anticipated, wear Ml protective clothing Environmental considerations land spin Dig a pit, pond, lagoon, holding area to contain Squid or solid material Dike surface flow using soft. sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist lo knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment 256 wen oooss FORMIC ACID SOLUTION CORROSIVE MATERIAL, ACIDIC 4931431 UN1779 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Formic add solution is me liquid material dissolved in water. It has a pungent odor. It is corrosive to metals and tissue. It weighs 10.2 pounds per gallon. If material on fire or Involved In fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Use water spray to absorb vapors H material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear Kill protective clothing Environmental considerations--land spill Oig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment FREIGHT FORWARDER TRAFFIC 4950130 Consult the shipping papers for the exact contents of the car, con tainer. or trailer. FUELOIL 4915113 COMBUSTIBLE LIQUID NA1993 Fuel oil is a straw ysNow to dark colored liquid with s petroleum like odor. It has s flash point between 100 and 199 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or Involved In fire Oo not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of Ignition sway Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors April 1981 Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water FUEL OIL TREATING COMPOUNDS (CORROSIVE 4936537 LIQUID, N.O.S.) CORROSIVE MATERIAL UN1760 Fuel oil treating compounds are various colored liquids. They are corrosive to metals and tissue. They may bum though it may require some effort to ignite. If material on fire or Involved In fire Extinguish fire using agent suitable for type of surrounding lire (Material itself does not bum or bums with difficulty.) Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Wear sell-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing FUEL OIL, DIESEL (See FUEL OIL 491S113) FUEL OIL, NO. 1,2,4, OR S 4915112 COMBUSTIBLE UQUID NA1993 Fuel oil, no. 1,2.4, or 5 are straw yellow to dark colored liquids with a petroleum like odor. They have a flash point between 100 and 199 deg. F. They are lighter than water and insoluble in water. Their vapors are heavier than air. If material on fire or Involved In Are Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possibit Use foam, carbon dioxide or dry chemical if material not on Are and not Involved In Are Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1981 FUEL, AVIATION, TURBINE ENGINE 4909215 FLAMMABLE UQUID UN1B63 Fuel, aviation, turbine engine is a clear colorless to variable colored liquid with a petroleum like odor. It has a flash point in the range of -10 deg. f to 100 deg. F. It is lighter than water and insoluble in water, its vapors are heavier than air. if material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water FUEL, AVIATION, TURBINE, ENGINE 4915167 COMBUSTIBLE UQUID UN1863 Fuel, aviation, turbine, engine is a clear colorless to vanabie colored liquid with a faint petroleum like odor. It has a flash point of between 100 and 199 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. A material on Are or involved in fire Do not extinguish Tire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical H material not on fire end not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water FUMARIC ACID 4966352 ORM-E NA9126 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Fumaric add is a colorless crystalline solid. It is used to make paints and plastics, in food processing and preservation, and for other uses. It is slightly soluble in water. It is combustible though it may take some effort to Ignite. Continued on next page 257 ooooio000 MCD tf material on fire or involved In fire Do not extinuish tire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use "alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors or dusts Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any malenal which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Neutralize with agricultural lime {slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates FUNGICIDES, AGRICULTURAL, NEC, LIQUID 4915198 (COMBUSTIBLE LIQUID, N.O.S.) COMBUSTIBLE LIQUID NA1993 Fungicides, agricultural, nec. liquid, are various colored liquids. They consist of either a mixture of liquid materials or a solid dissolved in some solvent. They are generally lighter than water and are soluble in water. Prolonged exposure to the vapors or contact with liquid may result in poisoning by inhalation or skin absorption. Their flash point is between 100 and 200 deg. F. Their vapors are heavier than air. In case of damage to or leakage from containers of this material, contact the pesticide safety team network. Telephone 800-424-9300. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind. Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material FUMARYL CHLORIDE 4931740 CORROSIVE MATERIAL, ACIDIC, COMBUSTIBLE UN1780 Fumaryl chloride is a straw colored fuming liquid with a pungent odor. It is combustible and has a flash point of 165 deg. F. Its fumes are irritating to the eyes and mucous membranes, it is decomposed by water to hydrochloric acid, a corrosive material, and water insoluble fumaric add with release of heat. It is corrosive to metals and tissue. If material on fire or involved In fire Use dry chemical or carbon dioxide Do not use water on material Itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knockdown vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with toe material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted toe body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing 258 FUNGICIDES, AGRICULTURAL NEC, UQUID 4910198 (FLAMMABLE UQUID, N.O.S.) FLAMMABLE UQUID UN1993 Fungicides, agricultural, nec, liquid are various colored liquids. They consist of either a mixture of liquid materials or a solid dissolved in some solvent. They are generally Tighter than water and are soluble in water. Prolonged exposure to the vapors or contact with toe liquid may result in poisoning by inhalation or skin absorption. Their flash point is below 100 deg. F. Their vapors are heavier than air. In case of damage to or leakage from containers of this material, contact toe pesticide safety team network. Telephone 800-424-9300. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool alt affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted toe body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material April 1981 MCD 000010001 FUNGICIDES, AGRICULTURAL. NEC, LIQUIO 49214S4 (POISONOUS LIQUID, N.O.S.) POISON 9 NA2810 Fungicides, agricultural, nec. liquid, are various colored liquids. They consist of either a mixture o< liquid materials or a solid dissolved in some solvent. They are generally lighter than water and are soluble in water. They are toxic by ingestion, skin absorption and inhalation. In case of damage to or leaking from containers of this material, contact the pes ticide safety team network. Telephone 800-424-9300. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical if material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water FUNGICIDES, AGRICULTURAL. NEC. OTHER THAN 4921456 LIQUID (POISONOUS SOLID, N.O.S.) POISON B NA2811 Fungicides, agricultural, nec. other than liquid, are either a mixture of dry materials or a liquid adsorbed on some solid carrier. They are toxic by ingestion, inhalation (dust, etc) or skin absorption. In case of damage to or leaking from containers of this material, contact tha pesticide safety team network. Telephone 800-424-9300. If material on fire or Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooring quantities as fog Use "alcohol'* foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective dothing FURAN 4909175 FLAMMABLE LIQUID UN2369 Furan is a clear cokxfess liquid. It has a flash point of less than 32 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. April 1981 .0^ .0,vo'O' O & tf material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities a$ fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water FURFURAL 4913146 COMBUSTIBLE LIQUIO UN1199 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RG-1000/454) Furfural is a clear colorless liquid turning reddish brown on exposure to light and air having a penetrating odor of aimonds. It has a flash point of 140 deg. F. it is heavier than water and is soluble in water. Its vapors are heavier than air. It weighs 9.7 pounds per gallon. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Coot all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical H material not on fire end not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Add sodium bisulfite (nahsoS) Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom Inject "universal" gelling agent to solidify encircled spill and increase effectiveness of booms If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Combustion products include corrosive or toxic vapors 259 FURFURYL ALCOHOL (ALCOHOL, N.O.S.) 4913124 CUMBUSTtBLE LIQUID UN19S7 Furfuryl alcohol is a clear colorless liquid turning brown to dark red on exposure to light. It has a Hash point of 167 Peg. F. It reacts vigorously with most acids forming a black solid. It is heavier than water and soluble m water Its vapors are heavier than air. If material on fire or Involved In fire Do not extinguish tire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding Quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water FUSE IGNITER 4903445 CLASS C EXPLOSIVE Fuse igniters are small cylindrical pasteboard or metal tubes contain ing an igniting composition in one end with the other end open to permit it to be placed on safety fuse. If material on fire or involved in Are Flood with water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet FUSE, SAFETY CLASS C EXPLOSIVE. 4903323 Safety fuse consists of a core of fine grained black powder encased in a fabric covering of yam, tape, and a waterproofing compound. Under fire conditions it will only bum and not explode. If material on fire or involved In Are Flood with water Apply water from as far a distance as possible If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material FUSEE (RAILWAY AND HIGHWAY) 4917333 FLAMMABLE SOLID NA1325 Fusees (railway and highway) are pasteboard or fiber tubes containing a pyrotechnic composition that bums with an intense red, green or yellow flame. Once ignited the fusee may bum under water, if material on fire or involved In fire If fire is massive, back off, protect surroundings, and let burn For scattered burning fusees, smother in dirt If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing fumes from burning material FUSEE (TRUCK FLARES, STEEL, 24 GAUGE OR 4917366 THICKER) FLAMMABLE SOLID NAt 325 Fusees (truck flares, steel, 24 gauge or thicker) are metal devices containing a pyrotechnic composition. These devices are easily ignited and bum with an intense flame. If material on fire or involved In fire If fire is massive, back off, protect surroundings, and let bum For scattered burning fusees, smother in dirt If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing fumes from burning material FUSE LIGHTER 4903450 CLASS C EXPLOSIVE Fuse lighters are small cylindrical pasteboard or metal tubes contain ing an igniting composition in one end with the other end open to permit it to be placed on safety fuse. H material on fire or Involved In fire Flood with water Apply water from as far a distance as possible If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes Irom burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable evacuate for a radius of 1500 feet 260 O0' 0,0No.00' & FUSEL OIL 4915169 COMBUSTIBLE LIQUID UN1201 Fusel oil is a dear colorless liquid with a mild odor. It has a flash point of 123 deg. F. It is lighter than water and soluble in water. Its vapors are heavier than air. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to disperse vapors and dilute standing pools of liquid April 1961 Personnel protection Avoid breaking vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water GALENA ORE. CRUDE (LEAD SULFIDE) 4966994 ORM-E NA2291 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Galena ore. crude is stone with grey crystalline solid. It is used as the source mineral for lead. It is insoluble in water. If material Involved in fire Extinguish fire using agent suitable for type of surrounding tire (Material itself does not bum or bums with difficulty.) H material not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spin Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates GAMBIER EXTRACTS, UQUID (FLAMMABLE UQUID, N.O.S.) 4910436 FLAMMABLE UQUID UN1993 Gambier extracts, liquid are materials containing a solvent having a closed cup flash point of less than 100 deg. F. The hazard of these materials is flammability. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'' foam, carbon dioxide or dry chemical H material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers 8uiid dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water GARBAGE TANKAGE (CONTAINING LESS THAN 8% 4917346 MOISTURE) FLAMMABLE SOLID NA1325 Garbage tankage is dried waste food products. If it has not been property cooled or is too dry. it is liable to spontaneous heating and ignition. If material on fire or Involved In fire Flood with water H material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away GAMBIER EXTRACTS, UQUID (COMBUSTIBLE 4915436 LIQUID, N.O.S.) COMBUSTIBLE LIQUID NA1993 Gambier extracts, liquid are materials containing a solvent having a closed cup flash point between too and 199 deg. F. The hazard of these materials is combustibility. H materiel on fire or involved in fire Do not extinguish fire unless flow can be slopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool ail affected containers with flooring quantities of water Apply water from as far a distance as possible Use "ataohoT foam, carbon dioxide or dry chemical If materiel not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Buikj dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1981 GARBAGE TANKAGE (CONTAINING LESS THAN 8% 4917364 WATER) FLAMMABLE SOUD NA1325 Garbage tankage is dried waste food products. If it has not been properly cooled or is too dry, it is liable to spontaneous heating and ignition. If material on fire or involved in Are Flood with water H material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away GAS DRIPS, HYDROCARBON 4915166 COMBUSTIBLE UQUID UNI 664 Gas drips, hydrocarbon are dear colorless to variable colored liquids. Their flash point is between 100 and 199 deg. F. They are lighter than water and insoluble in water. Their vapors are heavier than air. H material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical ConttnuMt on nxt p$g9 oO' Ooov r.t> 261 If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenai which may have contacted the body with copious amounts of water or soap and water GAS DRIPS, HYDROCARBON 4910188 FLAMMABLE LIQUID UN1864 Gas drips, hydrocarbon are clear colorless to variable colored liquids. Their flash point is below 100 deg. F. and is generally much lower. They are lighter than water and insoluble in water. Their vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread lire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of Ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenai which may have contacted the body with copious amounts of water or soap and water GAS IDENTIFICATION SET 4920910 POISON A NA9039 Gas identification set is a collection of small quantities of poisonous liquids and gases, poison a and possibly irritating materials and chlorine, it is used to familiarize people with the smell of the various materials. The outside container must be either a wooden box or a specially con structed flanged steel cylinder. If materiel on fire or Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of Ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Wear full protective dothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 262 GAS IDENTIFICATION SET 4925835 IRRITATING MATERIAL NA9035 Gas identification set is a collection of small containers of irritating materials absorbed on an inert material. It is used to familiarize people with the smell of the various materials. The outside container must be either a wooden box or a specially constructed flanged steel cylinder. If material on fire or Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Materia) itself does not burn or burns with difficulty.) Use water in flooding quantities as log Cool all affected containers with flooding quantities of water Use foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water GAS MIXTURE, NEC, COMPRESSED, OTHER THAN 4904580 POISON (COMPRESSEO GAS. N.O.S.) NONFLAMMABLE GAS UN19S6 Gas mixtures, nec are two or more gases shipped in the same con tainer under pressure. The mixture may consist of both nonflammable and flammable gases with the mixture having nonflammable properties. The mixture can separate after leaking with either the flammable or nonflammable gas settling in low areas, it may asphyxiate by the dis placement of air. It may only be shipped in cylinders. If the cylinder is an aerosol container, it can rupture and rocket under lire conditions, if material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Do not use water on material itself Use water spray to absorb vapors if material not involved In fire Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water GAS ODORANTS, NOT COMPRESSEO GAS 4915474 (COMBUSTIBLE UQUIO, N.O.S.) COMBUSTIBLE LIQUID NA1993 Gas odorants, not compressed gas are materials containing a solvent having a dosed cup flash point between 100 and 199 deg. F. The hazard of these materials is combustibility. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance ea possible Use "aJcohoT foam, carbon dioxide or dry chemical April 1981 0 if material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water GAS ODORANTS, NOT COMPRESSED GAS 4910474 (FLAMMABLE LIQUID, N.O.S.) FLAMMABLE LIQUID UN1993 Gas odorants, not compressed gas are materials containing a solvent having a closed cup flash point of less than 100 deg. F. The hazard of these materials is flammability. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire end not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water GASOHOL 4907827 FLAMMABLE LIQUID NA1257 Gasohol is a blend of gasoline and ethyl alcohol having an odor more of alcohol than gasoline. It is used as a motor fuel. It has a flash point of less than 0 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involvad in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnat protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1981 Evacuation II fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered GASOLINE 4908178 FLAMMABLE LIQUID UNI 203 Gasoline is a clear colorless to amber colored volatile liquid with a petroleum like odor. It has a flash point of less than 0 deg. F. it is lighter than water and insoluble in water. The vapors are heavier than air. If material on fire or involved in fire Do not extinguish tire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet H material leaking (not on tire), downwind evacuation must be considered GASOUNE (GASOLINE NATURAL (CASING HEAD)) 4908176 FLAMMABLE LIQUID UN1203 Gasoline is a clear colorless to amber colored volatile liquid with a petroleum Hke odor. It has a flash point of less than 0 deg. F. It is lighter than water and insoluble in water. The vapors are heavier than air. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a tfstance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involvad In fire Keep sparks, flames, and other sources of Ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered 263 Q.'0'.0^ o GASOLINE {GASOLINE, BLENDED) 4906177 Cool all affected containers with flooding quantities of water FLAMMABLE LIQUID UNI 203 Apply water from as far a distance as possible Gasoline is a clear colorless lo amber colored volatile liquid with a Use "alcohol" foam, carbon dioxide or dry chemical petroleum like odor. It has a flash point of less than 0 deg. F. it is lighter If material not on fire and not involved in fire than water and insoluble in water. The vapors are heavier than air. Keep sparks, flames, and other sources of ignition away If material on fire or Involved in fire Keep material out of water sources and sewers Do not extinguish fire unless flow can be stopped Build dikes to contain flow as necessary Use water in flooding quantities as fog Use water spray to knock-down vapors Solid streams of water may spread fire Personnel protection Cool all affected containers with flooding quantities of water Avoid breathing vapors Apply water from as far a distance as possible Keep upwind Use foam, carbon dioxide or dry chemical Wear boots, protective gloves, and goggles If material not on fire and not involved in fire Do not handle broken packages without protective equipment Keep sparks, flames, and other sources of ignition away Wash away any material which may have contacted the body with Keep material out of water sources and sewers copious amounts of water or soap and water Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered GERANIOL-NEROL MIXTURE (COMBUSTIBLE LIQUIO, 4913182 N.O.S.) COMBUSTIBLE LIQUID NA1993 Geranioi-nerol mixture is a colorless to pale yellow liquid having a pleasant flowery odor, it is used in perfumery and as a flavoring, it has a flash point of 176 deg. F. it is lighter than water and insoluble in water. Its vapors are heavier than air. if material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical GASOLINE PRESERVATIVE, NEC, LIQUID 4915476 (COMBUSTIBLE LIQUID, N.O.S.) COMBUSTIBLE LIQUID NA1993 Gasoline preservative nec, liquid is a material containing a solvent having a closed cup flash point between 100 and 199 deg. F. The hazard of this material is combustiblity. If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to disperse vapors and diiute standing pools of liquid tf material on fire or involved in fire Personnel protection Do not extinguish fire unless flow can be stopped Avoid breathing vapors Use water in flooding quantities as fog Keep upwind Solid streams of water may be ineffective Wear boots, protective gloves, and goggles Cool all affected containers with flooding quantities of water Do not handle broken packages without protective equipment Apply water from as far a distance as possible Wash away any material which may have contacted the body with Use "alcohol'* foam, carbon dioxide or dry chemical copious amounts of water or soap and water If material not on (Ire and not Involved in Are Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use wafer spray to knock-down vapors Personnel protection Avoid breathing vapors Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water GERMANE 4920120 POISON A UN2192 Germane is a colorless gas with a pungent odor, it is used in making electronics. It is flammable. The gas is heavier than air and a flame can flash back to the source of leak very easily, ft is toxic by inhalation. It may only be shipped in cylinders which may have to be overpacked in wooden or metal containers. Prolonged exposure of toe cylinders to fire or heat may result In the cylinders violent rupturing and rocketing. if material on Are or Involved in Are Do not extinguish fire unless flow can be stopped GASOLINE PRESERVATIVE, NEC, LIQUID (FLAMMABLE LIQUID, N.O.S.) 4910476 Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water FLAMMABLE LIQUID UN1993 Apply water from as far a distance as possible Gasoline preservative nec, liquid is a material containing a solvent having a closed cup flash point of less than 100 deg. F. The hazard of this material is flammability, ff material on fire or involved In Are Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Use "alcohol" foam, carbon dioxide or dry chemical If material not on Are and not Involved In Are Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak H without hazard Solid streams of water may be ineffective Use water spray to knock-down vapors 264 0^ oO CA 0o April 1981 Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet GRENADE, HAND, EXPLOSIVE 4901250 CLASS A EXPLOSIVE Hand grenade is a small metal device tilled with explosives with or without other material such as toxic gas or tear gas. smoke or incendiary charge and a burster. Under fire conditions they will explode, fragmenting in the process. ff material on fire or Involved in fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let bum If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on tire or involved in fire evacuate for a radius of 5000 feet GUANIDINE NITRATE 4918415 OXIDIZER, THERMALLY UNSTABLE UN1467 Guanidine nitrate is a white crystalline solid that is soluble in water. It takes some effort to ignite but once ignited it will bum with increasing vigor as the fire progresses. If contaminated with combustible materials vill accelerate their burning. Prolonged exposure of guanidine nitrate Sor its containers to fire or heat may result in an explosion. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or Involved In fire Flood with water Coot all affected containers with flooding quantities of water Apply water from as far a distance as possible H material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Approach fire with caution Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet HAFNIUM METAL, DRY 4918711 FLAMMABLE SOLIO UN2545 Hafnium metal, dry, is a greyish metallic colored powder. Dust from dry powder may be ignited by static electricity. The dry powder reacts with moisture to produce hydrogen, a flammable gas. The heat from this reaction may be sufficient to ignite the hydrogen. It does not appreciably react with large quantities of water. If material on fire or Involved Hi fira Use suitable dry powder Use dry chemical or carbon dioxide Use water only if flooding quantities are available 466 If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water HAFNIUM, METAL, WET 4916712 FLAMMABLE SOLID UN1326 Hafnium metal, wet is a greyish metallic colored sludge. Dust from dry powder may be ignited by static electricity. The dry powder reacts with moisture to produce hydrogen, a flammable gas. The heat from this reaction may be sufficient to ignite the hydrogen. It does not appreciably react with large quantities of water. H material on fire or Involved In fire Use suitable dry powder Use dry chemical or carbon dioxide Use water only if flooding quantities are available If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water HAIR, WET 4917435 FLAMMABLE SOLID NA1372 Hair, wet is hair wet with water. It is liable to spontaneous heating and ignition. ff material on fira or Involved In fire Flood with water If material not on fire and not involved Hi fire Keep sparks, flames, and other sources of ignition away HAND SIGNAL OEVtCE 4903610* CLASS C EXPLOSIVE Hand signal devices are a metal, cardboard or plastic tube containing a pyrotechnic composition which produces either a flare or smoke upon functioning. tl material on fire or involved In fira Flood with water Apply water from as far a distance as possible N material net on fira and not involved In fire Keep sparks, flames, and other sources of Ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation H fire becomes uncontrollable--evacuate for a radius of 1500 feet April 1981 MOD 000010009 Personnel protection Avoid breathing vapors Keep upwind Wear seif-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts ot water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered GLUE CATALYST, NEC (COMBUSTIBLE LIQUIO, 49154S4 N.O.S.) COMBUSTIBLE LIQUIO NA1993 Glue catalyst, nec is a material containing a solvent having a closed cup flash point between 100 and 199 deg. F. The hazard of this material is combustibility. K material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in Hooding quantities as fog Solid streams of water may be ineffective Cool ail affected containers with flooding quantities of wafer Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water GLUE CATALYST, NEC (FLAMMABLE LIQUIO, N.O.S.) 4910454 FLAMMABLE LIQUID UN1993 Glue catalyst, nec is a material containing a solvent having a dosed cup Hash point of less than 100 deg. F. The hazard of this material is flammability. If material on Are or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep matehal out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matehal which may have contacted the body with copious amounts of water or soap and water Aprit 1961 GLYCERINE. CRUOE, (SPENT LYE). CONCENTRATED 4936541 (CORROSIVE LIQUIO. N.O.S.) CORROSIVE MATERIAL, BASIC UN1760 Glycerine, crude, (spent lye), concentrated is a colorless to browr. colored liquid. It is soluble in water. It is combustible though it may require some effort to ignite. The residual sodium hydroxide (lye) is what cause this matehal to be corrosive to metals and/or tissue. If material on tire or involved in fire Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the matehal anticipated, wear full protective clothing GLYCOL ETHERS (COMBUSTIBLE LIQUID, N.O.S.) 4913194 COMBUSTIBLE LIQUIO NA1993 Glycol ethers are dear colorless liquids, with odors varying from none to mildly pleasant. They are used as a solvent for paints and plastics, and as a reaction medium for chemical synthesis. They have flash points between 100 and 200 deg. F. They are lighter than water and are soluble in water. Their vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other.sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water GRENADE, EMPTY, PRIMED 4903245 CLASS C EXPLOSIVE Grenade, empty, primed is a grenade shell devoid of any bursting charge but which has the primer installed. If material on fire or involved In fire Flood with water Apply water from as tar a distance as possible N material not on fire end not Involved In fire Keep sparks, flames, and other sources of ignition away Continued on next page O.0.0 c# O' 265 HAZARDOUS SUBSTANCE UQUIO (OR) SOUD, NO.S. 4960132 ORM-E NA9188 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Hazardous substance, liquid (or) solid, n.o.s. Specifically named in 'ie hazardous materials regulations that has been determined to be .ia2ardous to the environment if released. Consult the shipping papers for the exact contents of the car. trailer, or container. HAZARDOUS WASTE, LIQUID (OR) SOLID, N.O.S. 4960131 ORM-E NA9189 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1 0.454) Hazardous waste, liquid (or) solid, n.o.s. Specifically named in the hazardous materials regulations that is being shipped to an epa des ignated disposal facility. Consult the shipping papers for the exact contents of the car. trailer, or container. HEUUM--ARGON GAS MIXTURE (COMPRESSED 4904542 GAS, N.O.S.) NONFLAMMABLE GAS UNI 956 Helium--argon gas mixture is a colorless odorless gas. Both helium and argon are noncombustible. Helium is lighter than air and argon is heavier than air. tt can cause asphyxiation by the displacement of air. It may only be shipped in cylinders. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved In fire Attempt to stop leak if without hazard Personnel protection Avoid breathing vapo<3 Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment HEATER FOR REFRIGERATOR CAR, UQUID FUEL 4910195 TYPE FLAMMABLE UQUID NA1993 Heater for refrigerator car, liquid fuel types are mechanical devices for heating refrigerator cars. They may only be shipped containing fuel if shipped in carload or truckload quantities. The hazard is flammability which will depend upon the specific fuel. If material on Are or Involved In fire Do not extinguish fire unless flow can be slopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, ffames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water HEUUM 4904540 NONFLAMMABLE GAS UN1040 Helium is a colorless odorless gas. it is lighter than air and la noncombustible. If malarial involved In fire Extinguish lire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible H material not Involved In fire Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment pcfi 1961 HEUUM--OXYGEN MIXTURE 4904430 NONFLAMMABLE GAS NA1980 Helium-oxygen mixture is a colorless odorless gas. Both helium and oxygen are noncombustible; however, oxygen will accelerate the com bustion of a fire. It may only be shipped in cylinders. H material Involved In firs Extinguish lire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved In fire Keep sparks, flames, and other sources of ignition away Attempt to stop leak if without hazard Personnel protection Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution HEUUM-BUTANE GAS MIXTURE (COMPRESSED GAS, 4904543 N.O.S.) NONFLAMMABLE GAS UN1956 Helium-butane gaa mixture is a colorless odorless gas. While helium is non-combustible and butane is flammable, the mixture is nonflamm able. The mixture can separate with the butane settling into low areas. H may only be shipped in cylinders. If material Involved In firs Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved In fire Attempt to stop leak if without hazard Personnel protection Avoid breathing vapora Keep upwind Wear protective gloves and goggles Do not handle broke** **ckagee without protective equipment O.Oo' o\o0,vo 267 & HELIUM-BUTANE GAS, MIXTURE (COMPRESSED 4905840 GAS, N.O.S.) FLAMMABLE GAS UN1954 Helium butane gas mixture is a colorless gas with a faint odor of petroleum. It is easily ignited and may only be shipped in cylinders. Helium is lighter than air and noncombustible, butane is flammable and heavier than air. A flame may flash back to the source of leak very easily. Under fire conditions cylinders may violently rupture and rocket, tf material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak If without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered HELIUM-CARBON DIOXIDE-NITROGEN MIXTURE 4904547 (COMPRESSED GAS, N.O.S.) NONFLAMMABLE GAS UN1956 Helium-carbon dioxide-nitrogen is a colorless, odorless gas. Helium, carbon dioxide, and nitrogen are each noncombustible. It can asphyxiate by the displacement of air. I( may only be shipped in cylinders, tf material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved In fire Attempt (o stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment HEUUM-4SOBUTANE GAS MIXTURE (COMPRESSED 4905542 GAS, N.O.S.) FLAMMABLE GAS UN1954 Helium-isobutane gas mixture is e colorless gas with a faint petroleum like odor. It is easily ignited and may only be shipped in cylinders. HeNum is lighter than air and noncombustible. isobutane ia heavier then air and flammable. A flame may flash back to the source of leek very easily. Under fire conditions cylinders may violently rupture and rocket, tf materiel on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If materiel not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leek if without hazard Use water spray to knock-down vapors 266 0i 000 Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered HEUUM4SOBUTANE GAS MIXTURE (COMPRESSED 4904544 GAS, N.O.S.) NONFLAMMABLE GAS UNI 956 Helium-isobutane gas mixture is a colorless odorless gas. While he lium is noncombustible and isobutane is flammable. The mixture is non flammable. The mixture can separate with the isobutane settling into low areas. It may only be shipped in cylinders. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved In fire Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment HEUUM-NTTROGEN MIXTURE (COMPRESSED GAS, 4904545 N.O.S.) NONFLAMMABLE GAS UNI 956 Helium-nitrogen mixture is colorless odorless gas. Both helium and nitrogen are noncombustible. It may only be shipped in cylinders. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved In fire Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment HEPTACHLOR 4960630 ORM-E NA2761 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Heptachior is a white to light tan waxy looking solid. It is used as an insectide. It is non-combustible. It is insoluble in water, ft can cause illness by inhalation, skin absorption and/or ingestion. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone- 800-424-9300. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in Hooding quantities as log Use foam, carbon dioxide or dry chemical tf large quantities of combustibles are involved, use water in flooding quantities as spray and fog April 1981 H (tutorial not Involved in lira Keep material out of water sources and sewers Build dikes to contain llow as necessary Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted hie body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire lighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the matehal anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or lire fighting water Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap matehal at bottom Remove trapped matehal with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors HEPTANE 4909190 FLAMMABLE UQUID UNI 206 Heptane is a clear colorless liquid with a petroleum-like odor. It has a flash point of 25 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. ft material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical K material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep matehal out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matehal which may have contacted the body with copious amounts of water or soap and water HEXACHLOROCYCIOPENTACMENE 4933015 CORROSIVE MATERIAL POISONOUS UN2646 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Hexachlorocydopentadiene a pale yellow liquid with a pungent odor. It ts noncombustible and solidifies at 50 deg. F. It is insoluble in water, it is toxic by skin absorption and inhalation. It is oorrosive to tissue. It weighs 14.3 pounds per gallon, if material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water spray to absorb vapors If material not Involved In fire Keep matehal out of water sources and sewers Build dikes to contain flow as necessary HEXAOECYL TRICHLOROSILANE 4934250 CORROSIVE MATERIAL, ACIDIC UN17S1 Hexadecyl trichkxosilane is a colorless to yellow liquid with a pungent odor. Material will bum though it may require some effort to ignite. It is decomposed by moisture or water to hydrochloric add with evolution of heat. It is corrosive to metals and tissue, if materiel on fire or Involved In fire Use dry chemical, carbon dioxide, or dry sand Do not usa water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible If materiel not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodky contact with the material Wear boots, protective gloves, and goggles Do not hands broken packages without protective equipment Wash away, any material which may have contacted the body with copious amounts of water or soap and water tf contact with the material anticipated, wear full protective clothing HEXADIENE 4908194 FLAMMABLE UQUID UN2458 Hexadiene is a dear, colorless liquid with a petroleum tike odor, ft has a flash point of less than 0 deg. F. it is tighter than water and insoluble in water. Its vapors art heavier than air. Continued on ftsjtf pa0 April 1981 000010012 MCD 269 If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If materiel not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered HEXAETHYL TETRAPHOSPHATE MIXTURE, ORY 4921423 (CONTAING NOT MORE THAN 2% HEXAETHYL TETRAPHOSPHATE) POISON B NA2783 Hexaethyl tetraphosphate mixture, dry is a liquid absorbed on a dry earner. Hexaethyl tetraphosphate itself is soluble in water and is difficult to bum. It is toxic by skin absorption and inhalation (dust, etc.). In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300 If material on fire or involved In fire Extinguish lire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical M material not on fire and not involved In Are Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material if contact with the material anticipated, wear ful protective clothing H material on fire or involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bum9 with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material if contact with the material anticipated, wear full protective clothing HEXAETHYL TETRAPHOSPHATE MIXTURE, LIQUID 4921432 (CONTAINING MORE THAN 2S% HEXAETHYL TETRAPHOSPHATE) POISON B NA2783 Hexaethyl tetraphosphate mixture, liquid is the yellow liquid dissolved in a solvent. The mixture is soluble in water. The combustibility of the mixture will depend on the solvent used. It is toxic by inhalation and by skin absorption. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424- 9300 If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If materiel leaking (not on fire), downwind evacuation must be considered HEXAETHYL TETRAPHOSPHATE MIXTURE, ORY 4921431 (CONTAINING MORE THAN 2% HEXAETHYL TETRAPHOSPHATE) POISON B NA2783 Hexaethyl tetraphosphate mixture, dry is a liquid absorbed on a dry carrier. Hexaethyl tetraphosphate itself is soluble in water and is difficult lo bum. It is toxic by skin absorption and inhalation (dust, etc.). In ease of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300 HEXAETHYL TETRAPHOSPHATE MIXTURE, LIQUID 4921441 (CONTAINING NOT MORE THAN 25% HEXAETHYL TETRAPHOSPHATE) POISON B NA2783 Hexaethyl tetraphosphate mixture, liquid is the yellow liquid dissolved In a solvent. The mixture is soluble in water. The combustibility of the mixture will depend on the solvent used. It is toxic by inhalation and by skin absorption. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424- 9300 270 April 19b MCD 000010013 If materiel on fir* or Involved in fir* Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered HEXAETHYL TETRAPHOSPHATE, UQUID 4921430 POISON B UNI 611 Hexaethyi tetraphosphate, liquid is a yellow liquid. It is soluble in water and difficult to bum. It is toxic by skin absorption and inhalation. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone; 600-424-9300 If material on Are or Involved in fir* Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Use foam, carbon dioxide or dry chemical If material not on fir* and not involved in fir* Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear seff-containsd breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered HEXAETHYLTETRAPHOSPHATE AMO COMPRESSED 4920515 GAS MIXTURE POISON A UNI 612 Hexaethyttetraphosphate and compressed gas mixture is a liquid material charged with a gas. Hexaethyttetraphosphate is a yellow liquid and is lethal by skin absorption and inhalation. The material may only be shipped in cylinders, and these must be over packed in either a wooden box or a fiberboard box. Prolonged exposure of the cylinders to fire or heat may result In the violent rupturing and rocketing of the cylinders. In case of damage to, or leaking from containers of this ma terial contact the pesticide safety team network. Telephone; 800-424- 9300 April 1961 N material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical if material not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation if material leaking (not on fire), downwind evacuation must be considered HEXAFLUOROPHOSPHORIC ACID 4930015 CORROSIVE MATERIAL, ACIDIC, POISONOUS UN1782 Hexafluorophosphoric add is a colorless fuming liquid. It is soluble in water with release of heat. It is corrosive to metals and tissue. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If materiel not involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing HEXAFLUOROPROPYLENE 4904546 NONFLAMMABLE GAS UNI 6S6 Hexafluoropropylene is an odorless, colorless gas. It is noncombus tible. it can asphyxiate by the displacement of air. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible H material not Involved in fire Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment 271 o0 Oz Oo HEXAFLUOROPROPYLENE OXIDE 4904548 NONFLAMMABLE GAS NA1956 Hexafiuoropropylene oxide is a colorless odorless gas. U is shipped as a liquefied gas under its vapor pressure. Contact with the liquid can cause frostbite. Its vapors are heavier than air. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible tf material not Involved in fire Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment HEXALDEHYDE 4909185 FLAMMABLE LIQUID UN1207 Hexaldehyde is a clear colorless liquid with a pungent odor. It has a flash point of 90 deg. F. It is lighter than water and is insoluble in water. Its vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol*' foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 3,3,6,6.9.9-HEXAMETHYL-1.2.4,5- 4919277 TETRAOXOCYCLONONANE, (TECHNICALLY PURE) ORGANIC PEROXIOE UN2165 3.3.6.6,9,9-hexamethyM ,2.4,5-tetraoxocyctononane, (tecnhicaly pure) is a white solid, it is used to manufacture painta. plastics, and rubber. It is insoluble in water. It is easily ignited and bums with increasing rapidity as the fire progresses. It can form explosive mixtures with finely divided combustible materials. It supports the burning of combustible materials. Under prolonged exposure to fire or heet containers of the material may explode. If material on fire or Involved In fire Use water in flooding quantities aa tog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive tf material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up 272 Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach tire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet 3,3,6,6,9,9-HEXAMETHYL-1,2,4,5- 4919169 TETRAOXOCYCLONONANE, (NOT MORE THAN 52% WITH INERT SOLID) ORGANIC PEROXIDE UN2166 3.3,6.6.9.9-hexamethyl-l,2,4,5-tetraoxocyciononane, (not more than 52% with inert solid) is a white solid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite; but once ignited, it will bum with increasing rapidity as the fire progresses. If spilled on combustible materials, spon taneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burning of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or Involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use ' alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep materiel out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this materia! If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate tor a radius of 2500 feet 3,3,6,6,9,9-HEXAMETHYL-l ,2,4,5- 4919188 TETRAOXOCYCLONONANE, (NOT MORE THAN 52% IN SOLUTION) ORGANIC PEROXIDE UN2167 3.3,6.6,9,9-hexamethyt-l,2.4,$-tetraoxocyciononane. (not more than 52% in solution) is a colorless to pale yellow liquid. It is used to man ufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite; but once ignited, it will bum with increasing rapidity as the fire progresses. II spiHed on combustible materials, spontaneous ignition of the material may occur. Contamina tion with many chemical substances can cause a violent chemical re action. It supports the burning of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. April 1961 MCD 000010015 Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts ot water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If matenal leaking (not on fire), downwind evacuation must be considered HEXANOIC ACID 4931434 CORROSIVE MATERIAL, ACIDIC NA1760 Hexanoic acid is a colorless to light yellow liquid with an odor of limburger cheese, it will bum though it may take some effort to ignite. It is slightly soluble in water. It is corrosive to metals and tissue. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Use water spray to absorb vapors If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing HEXYL ALCOHOL, OTHER THAN PERFUMERY 4913129 GRAOE (ALCOHOL, N.O.S.) COMBUSTIBLE LIQUID UN1987 Hexyl alcohol is a clear colorless liquid. It has a flash point of 149 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved In fire Do not extinguish tire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as posable Use "alcohol" foam, carbon dioxide or dry chemical if material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes (o contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water (A HEXYL TRtCHLOROSILANE 49342S5 CORROSIVE MATERIAL, ACIDIC UNI 794 Hexyl trichlorosilane is a colorless liquid with a pungent odor. It is decomposed by moist air or water to hydrochloric acid with evolution of heat, it is corrosive to metals and tissue. H material on fire or Involved In fire Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible H material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear bools, protective gioves. and goggles Do not handle- broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing HIGH EXPLOSIVE 4901502 CLASS A EXPLOSIVE High explosive is the proper shipping name for those solid materials having the property of detonating when initiated by a commercial number 8 electric blasting cap. It is a variable colored solid. It does not function by burning. Most high explosives will bum once ignited by a flame and many will bum quietly if the quantity is small or the material is thinly spread over a large area. If large quantities are involved in the fire, or if the material is confined, or is packaged for shipment the material can explode en masse without warning. If material on fire or Involved In fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let bum If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep spilled material wet Wet spilled material before picking it up Do not attempt to sweep up dry material Personnel protection Avoid breathing dusts, and fumes from burning material Wear protective gioves and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in tire evacuate for a radius of 5000 feet April 1961 MCI) 000010017 If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use `alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material if contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet HEXAMETHYLENE DIAMINE SOLUTION 4935645 CORROSIVE MATERIAL, BASIC UNI 783 Hexamethylene diamine solution is a dear colorless liquid. It is used to make nylon. It will bum though it may require some effort to ignite. It is soluble in water, ft is corrosive to metals and tissue. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear futi protective clothing HEXAMETHYLENE DIAMINE. SOLID 4935540 CORROSIVE MATERIAL, 8ASIC UN2280 Hexamethylene diamine, solid Is a colorless crystalline solid. It is soluble in water. It is corrosive to metals and tissue. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or Involved in fire Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use "alcohol" foam, carbon dioxide or dry chemical April 1961 tf materiel not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when lighting fires involv ing this material If contact with the material anticipated, wear full protective clothing HEXAMETHYLENE IMINE 4935650 CORROSIVE MATERIAL, BASIC, FLAMMABLE, UN2493 POISONOUS Hexamethylene imine is a colorless liquid with an ammonia like odor. It is flammable and has a flash point of 65 deg. F. It is toxic by ingestion. It is soluble in water. It is corrosive to metals and tissue. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water- in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use "alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when lighting fires involv ing this material If contact with the material anticipated, wear full protective clothing HEXANE 4906163 FLAMMABLE LIQUID UN1206 Hexane is a dear colorless iquid with a petroleum like odor. It is used as a solvent, paint thinner, and chemical reaction medium. It has a flash point of -9 deg. F. ft t$ fighter than water and insoluble in water. Its vapors are heavier than air. If material on lire or involved In fire Oo not extinguish fire unlees flow can be stopped Use water in footing quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire end not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak H without hazard Use water spray to knock-down vapors Continued on next pego 273 HCD 000010016 H material not on fire and not involved In fire Keep sparks, (lames, and other sources of ignition away Keep spilled material wet Wet spilled material before picking it up Do not attempt to sweep up dry material Personnel protection Avoid breathing dusts, and fumes from burning material Wear protective gloves and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 5000 feet HYDRAZINE, ANHYDROUS 4906225 FLAMMABLE LIQUID, POISONOUS, CORROSIVE UN2029 THERMALLY UNSTABLE Hydrazine, anhydrous is a colorless, turning oily liquid with an am* monia like odor. It has a (fash point of 99 deg. F. ft can ignite sponta neously on contact with oxidizers, and may ignite spontaneously on contact with porous materials such as earth, wood, and doth. It is toxic by inhalation and by skin absorption. It is corrosive to tissue. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical. If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective dothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation H fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet If material leaking (not on fire), downwind evacuation must bo considered HYDRAZINE. AQUEOUS SOLUTION 4935030 CORROSIVE MATERIAL. BASIC, POISONOUS UN2030 Hydrazine, aqueous solution is a colorless liquid with an ammonia like odor. It is combustible though it may require some effort to ignite. Contact with oxidizing materials may result in spontaneous ignition. It is toxic by inhalation and by skin absorption. It is corrosive to tissue. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water 76 Apply water from as far a distance as possible Solid streams of water may be ineffective Use ''alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to slop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation It fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet KYDRIODIC ACID 4930226 CORROSIVE MATERIAL UN1787 Hydriodic acid is a colorless to yellow liquid with a pungent odor, tts fumes are irritating to the eyes and mucous membranes. It is soluble in water with release of heat. It is corrosive to metals and to tissue. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog . Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved In fire Keep materiel out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water H contact with the material anticipated, wear full protective dothing HYDROBROMIC AOD (MORE THAN 49% STRENGTH) 4930227 CORROSIVE MATERIAL, ACIDIC UN1788 Hydrobromic add is a colorless to yellow liquid with a pungent odor. Its fumes are irritating to the eyes and mucous membranes. It is soluble in water with release of heat. It is corrosive to metals and tissue. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use wafer spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash, or lime April 1961 MCD 000010019 HIGH EXPLOSIVE (NITROCELLULOSE, DRY) 4901520 CLASS A EXPLOSIVE Nitrocellulose, dry is a white fibrous to amorphous powder, or a com pressed block or stick. It can be detonated with a commercial number 8 electric blasting cap. It will bum once ignited with a flame and wilt continue to bum vigorously if the quantity is small or the material is thinly spread over a large area. If large quantities are involved in the fire, or if the material is confined, or is packaged for shipment, the material can explode en masse without warning. If material on fire or involved in fire Dangerously explosive Do not fight (ires in a cargo of explosives Evacuate area and let burn If material not on fire and not involved in fire Keep sparks, (lames, and other sources of ignition away Keep spilled material wet Wet spilled material before picking it up Do not attempt to sweep up dry material Personnel protection Avoid breathing dusts, and fumes from burning material Wear protective gloves and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 5000 feel HIGH EXPLOSIVE (NITROSTARCH, DRY) 4901530 CLASS A EXPLOSIVE Nitrostarch, dry is a white solid. It can be detonated with a commercial number 6 electric blasting cap. It will bum once ignited with a flame and will continue to bum vigorously if the quantity is small or the material is thinly spread over a large area. If large quantities are involved in the fire, or if the material is confined, or is packaged for shipment, the material can explode en masse without warning. If material on fire or involved in fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let bum If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep spilled material wet Wet spilled material before picking it up Do not attempt to sweep up dry material Personnel protection Avoid breathing dusts, and fumes from burning material Wear protective gloves and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting firee involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 5000 feet HIGH EXPLOSIVE (PICRIC ACID, DRY) 4901510 CLASS A EXPLOSIVE Picric acid is a yellow crystalline solid. It can be detonated with a commercial number 8 electric blasting cap. II will bum onc8 ignited by a flame and will continue to bum quietly if the quantity is small or the material is thinly spread over a large area. If large quantifies are involved in the fire, or if the material is confined, or is packaged for shipment the material can explode en masse without warning. H material on fire or Involved in fire Dangerously explosive Do not light fires in a cargo of explosives Evacuate area and let bum If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep spilled material wet Wet spilled material before picking it up Do not attempt to sweep up dry material Personnel protection Avoid breathing dusts, and fumes from burning material Wear protective gloves and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts ot water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 5000 feet HIGH EXPLOSIVE (TRINITROTOLUOL, DRY) 4901540 CLASS EXPLOSIVE Trinitrotoluol, dry is a yellow crystalline solid. It can be detonated with a commercial number 8 electric blasting cap. It will bum once ignited by a flame and will continue to bum quietly if the quantity is small or the material is thinly spread over a large area. If large quantities are involved, or the material is confined, or is packaged for shipment, the material can explode en masse without warning. If material on fira or involved In fire Oangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let bum If material not on fire and not involved In fire Keep sparks, flames, and other sources of Ignition away Keep spilled material wet Wet spilled material before picking it up Do not attempt to sweep up dry material Personnel protection Avoid breathing dusts, and fumes from burning matenal Wear protective gloves and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 5000 feet HIGH EXPLOSIVE, LIQUID 4901504 CLASS A EXPLOSIVE High explosive, liquid is the proper shipping name for those liquid materials having the property of detonating when initiated by a number 8 electric blasting cap. They are vanous colored liquids and slumes. They do not function by burning. They are sensitive to shock or impact. Most high explosives, liquid will bum once ignited by a flame and many will bum quietly if the quantity is small or the material is thinly spread over a large area. If large quantities are involved in the fire, or if the material is confined, or is packaged for shipment, the material can ex plode en masse without warning. If material on fire or involved In fire Dangerously explosive Do not light fires in a cargo of explosives Evacuate area and let bum ContlniMd on next page April 1981 00001001S MCD 275 Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with Ihe material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach lire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet If material leaking (not on fire), downwind evacuation must be considered HYDROBROMIC ACID, ANHYDROUS (See HYDROGEN BROMIDE 4904260) HYDROBROMIC ACID, NOT MORE THAN 49% 4930232 STRENGTH CORROSIVE MATERIAL UN1788 Hydrobromic acid is a colorless to yellow liquid with a pungent odor. Its fumes are irritating to the eyes and mucous membranes. It is soluble in water with release of heat. It is corrosive to metals and tissue. If material involved m fire Extinguish fire using agent suitable for type of surrounding lire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing HYDROCARBON GAS. UQUEFIEO 4905749 FLAMMABLE GAS UNI 965 Hydrocarbon gas, liquefied is a colorless gas with a faint petroleum like odor shipped as a liquefied gas under its vapor pressure. For trans port ation it may be stenched. Contact with the Squid can cause frostbite. It is easily ignited. Its vapor is heavier than air and a flame can flash back to source of leak very easily. The leak can be either a liquid or vapor leak. It can asphyxiate by the displacement of air. Under fire conditions the cylinders or tank cars may violently rupture and rocket If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as log Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak If without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind HYDROCARBON GAS, NONLIQUEFIED 4905779 FLAMMABLE GAS UN1964 Hydrocarbon gas. nonliquefied is a colorless gas with a faint petroleum like odor. It is easily ignited and may only be shipped in cylinders. A flame may flash back to the source of leak very easily. Under fire con ditions the cylinders may violently rupture and rocket. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out oi water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Keep upwind Wear self-contained breathing apparatus Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered HYDROCARBON GAS, NONLIQUEFIED (COAL GAS) 4905708 FLAMMABLE GAS UN1964 Coal gas is a colorless gas. It has a faint petroleum odor unless there are impurities to give it the characteristic odor of the impurity; commonly hydrogen sulfide, rotten eggs; or benzene, aromatic. It is easily ignited and may only be shipped in cylinders. A flame may Hash back to the source of leak very easily. Under fire conditions the cylinders may vi olently rupture and rocket. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as log Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible H material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop teak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered April 1981 MCD 000010020 277 HYDROCHLORIC ACID 4930226 CORROSIVE MATERIAL, ACIDIC UN1769 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Hydrochloric acid is a colorless to yellow liquid with a pungent odor, it is used for cleaning masonary and metals, manufacturing chemicals, in petroleum production, and for many other uses. Its fumes are irritating to the eyes and mucous membranes. It is soluble in water with release of heat. It is corrosive to metals and tissue. It weighs 10.1 pounds per gallon. If material involved in fire Extinguish fire using agent suitable for type of surrounding tire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--Isnd spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agricultural lime (slaked lime), grushed limestone, or sodium bicarbonate Environmental consideratlona--water eplll Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment HYDROCHLORIC ACIO (MURIATIC ACID, SPENT) 4930231 CORROSIVE MATERIAL UNI 789 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Muriatic acid, spent is a dark colored liquid with a pungent odor. Its fumes are irritating to the eyes and mucous membranes. H is soluble in water with release of heat. It is corrosive to metals and tissue. It weighs 10.1 pounds per gaHon. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment 278 Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--lend eplll Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment HYDROCHLORIC ACID MIXTURE 4930229 CORROSIVE MATERIAL, ACIDIC NA1769 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Hydrochloric acid mixtures are colorless to yellow liquids. Its fumes are irritating to the eyes and mucous membranes. It is soluble in water with release of heat. It is corrosive to metals and tissue. It weighs 10.1 pounds per gallon. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear bools, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental confidentiona--land spill Dig a pit, pond, iagoon. holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agricultural time (slaked lime), crushed limestone, or sodium bicarbonate Environmental consideratlona--water spill Neutralize with agrictdtural lime (slaked lime), crushed limestone,* or sodium bicarbonate Environmental conalderstfons--air spilt Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment HYDROCHLORIC ACID SOLUTION, INHIBITED 4930230 CORROSIVE MATERIAL, ACIDIC NA1789 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Hydrochloric acid solution, inhibited is a colorless to yellow liquid. Its fumes are irritating to the eyes and mucous membranes. It is soluble in water with release of heat It contains some material which cuts its rate of corrosivity to metals compared to the uninhibited acid. It is cor rosive to metals and tissue. It weighs 10.1 pounds per gallon. April 1981 mcd 00l002i If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apoly water from as far a distance as possible If material not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment HYDROCHLORIC ACID, ANHYDROUS (See HYDROGEN CHLORIDE 4904270) HYDROCYANIC ACID, LIQUEFIED 4920125 POISON A, FLAMMABLE NA1051 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-10/4.54) Hydrocyanic acid, liquefied is a colorless gas with a faint aromatic odor. It is shipped as a liquefied gas under its vapor pressure end it must be stabilized to avoid polymerization. It it easily ignited. The vapor is just lighter than air but a flame can travel back to the source of leak very easily. It can polymerize from contact with afcaM. Lethal amounts may be absorbed through the skin, aa weN as by inhalation. It may be shipped in cylinders or tank cars. Prolonged exposure to Are or heel may cause the cylinder or tank car to violently rupture and rocket It weighs 5.7 pounds per gaHon. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors April 1981 MCI) 00010022 Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear kill protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet If material leaking (not on fire) evacuate for a radius of 2500 feet Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill Use natural barriers or oil spill control booms to limit spill motion Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment HYDROCYANIC ACID. SOLUTION 4920130 POISON A. FLAMMABLE UN1613 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-10/4.54) Hydrocyanic add, solution is hydrocyanic add, a gas dissolved in water. It is a dear colorless liquid with a faint aromatic odor. It is flam mable though the lower concentrations may require some effort to ignite. The vapor is lighter than air. but a flame can flash back to the source of the leak very easily. Lethal amounts may be absorbed through the skin as well as by inhalation. n materiel on fire or Involved in fire Do not extinguish Are unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far e distance as possible Solid streams of water may be ineffective Use "alcohol" foam, carbon dioxide or dry chemical K material not on lire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers BuHd dikes to contain flow as necessary Attempt to stop leak If without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation H fire becomes uncontrollable or container is exposed to direct flame evacuate for a radius of 2500 feet If material Making (not on tire) evacuate for a radius of 2500 feet ContUwd on noxt pog* 279 Environmental considerations--land spill Dig a pit pond, lagoon, holding area to contain liquid or solid material Dike surface (low using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment HYDROCYANIC ACID, SOLUTION, LESS THAN 5% 4921417 HYDROCYANIC ACID POISON 8 UN1613 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-10/4.S4) Hydrocyanic acid solution is water containing up to 5% dissolved hydrocyanic acid with the faint odor of almonds. It is toxic by inhalation and skin absorption. If materiel on fire or involved In fire Do not extinguish fire unless flow can be stopped Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away arty material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations water spill Neutralize with agricultural lime (slaked Hme), crushed limestone, or sodium bicarbonate Environmental considerations--air aplH Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment HYOROFLUORIC ACID SOLUTION 4930022 CORROSIVE MATERIAL, ACIDIC, POISONOUS UNI 790 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Hydrofluoric add solution is a colorless fuming liquid with a pungent odor. It is soluble in water with release of heat It Is corrosive to metals and tissue. The fumes and very short contact with small quantities of the liquid can cause severe painful bums. It weighs 9.6 pounds per gallon. 280 If material involved in fire Extinguish fire using agent suitable for type of sunounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Add soda ash Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment HYDROFLUORIC AGIO, ANHYDROUS (OR) 4930024 HYDROGEN FLUORIDE CORROSIVE MATERIAL, ACIDIC, POISONOUS UN1052 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Hydrofluoric add, anhydrous is a colorless fuming liquid boiling at 67 deg. F. It is used as a catalyst and raw material in chemical manufacture. It is shipped as a liquid or liquefied gas under Its vapor pressure. It is soluble in water with release of heat, ft is corrosive to metals and tissue. The fumes and vary short contact with small quantities of the liquid can cause severe painful bums, it weighs 8.2 pounds per gallon. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If materiel not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash, or lime April 1961 MOD 000010023 Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire) evacuate for a radius of 2500 feet Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface (low using soil, sand bags, foamed polyurethane, or foamed corcrete Absorb bulk liquid with fty ash or cement powder Neutralize with agricultural lime {slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water split Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Add soda ash Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment HYDROFLUORIC AND SULFURIC ACID MIXTURES 4930020 CORROSIVE MATERIAL, ACIDIC, POISONOUS UN1796 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Hydrofluoric and sulfuric add, mixture is a dear colorless liquid with a pungent odor. It is soluble in water with release of heat it is corrosive to metals and tissue. The fumes and very short contact with small quan tities of me add can cause severe, painful bums. It weighs 15.3 pounds per gallon. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in Hooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible if material not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain Hquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water apUf Neutralize with agricultural lime (slaked time), crushed Imestone, or sodium bicarbonate Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment HYDROFLUOSILICIC, AGIO 4930026 CORROSIVE MATERIAL ACIDIC, POISONOUS NA1778 Hydrofluosilicic acid is a colorless fuming liquid with a penetrating pungent odor, it is used m water fluoridation, in hardening cement and ceramics, as a wood preservative, and for many other uses. It is soluble in water with release of heat, it is corrosive to metals and tissue. The fumes and very short contact with small quantities of the liquid can cause severe painful bums. If material Involved in fire Extinguish lire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing HYDROGEN 4905746 FLAMMABLE GAS UN1049 Hydrogen is a colorless, odorless gas. It is easily ignited. It is lighter than air. but a flame can flash back to the source of the leak very easily. It is flammable over a wide range of vapor air concentrations. It may be shipped in cylinders and spatial tank cars. Under fire conditions the cylinders may violently rupture and rocket. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as tar a dfetance as posstole If material not on firs and net involved hi fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame evacuate tor a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered April 1981 010024 tfCD 000 281 HYDROGEN BROMIOE 4904260 NONFLAMMABLE GAS, CORROSIVE UN1048 Hydrogen bromide is a colorless gas with a pungent irritating odor. It is used to make other chemicals and as a calalyst in the manufacture of chemicals. The gas is corrosive. It dissolves in water to form hy- drobromic acid, a corrosive material. The vapor is heavier than air. It may only be shipped in cylinders. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or Burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use water spray to absorb vapors ft material not involved In fire Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash, or lime Do not use water on material itself Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered HYOROGEN CHLORIDE 4904270 NONFLAMMABLE GAS, CORROSIVE UN1050 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Hydrogen chloride is a colorless gas with a pungent odor. The gas is corrosive to metals and tissue and irritating to the eyes and respiratory system. It dissolves in water to form hydrochloric acid, a corrosive ma terial. The vapor is heavier than air. It weighs 9.9 pounds per gation. If materiel involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itsett does not bum or bums with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use water spray to absorb vapors If material not involved in fire Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash, or lime Do not use water on material itself Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any materia) which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered Environmental considerations--land spin Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete 282 Absorb bulk liquid with fly ash or cement powder Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment HYDROGEN IODIDE SOLUTION (See HYDRIOOIC ACID 4930226) HYDROGEN PEROXIDE SOLUTION (OVER 52% 4918335 PEROXIDE) OXIDIZER, CORROSIVE. THERMALLY UNSTABLE UN201S Hydrogen peroxide solution is a colorless liquid dissolved in water. It is used to bleach textiles and wood pulp, in chemical manufacturing and food processing, and in water purification. Its vapors are irritating to the eyes and mucous membranes. The material can violently decom pose on contact with most common metals and their compounds Con tact with combustible material can result in spontaneous ignition. It is corrosive to tissue. Under exposure to fire or heal containers of the material can violently rupture due to decomposition of the material. If material involved in fire Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible H material not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear respiratory protection If material is misting Wear boots, protective gloves, and goggles Avoid bodily contact with the material If contact with the material anticipated, wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct name--evacuate for a radius of 2500 feet HYDROGEN PEROXIDE SOLUTION (40% TO 52% 4916776 PEROXIDE) OXIDIZER, CORROSIVE UN2014 Hydrogen peroxide solution is the colorless liquid dissolved in water, its vapors are irritating to the eyes and mucous membranes. It is cor rosive to tissue. The material can violently decompose on metals and their compounds. Contact with combustible material can result in spon taneous ignition. Under exposure to fire or heat containers of the material can violently rupture due to the decomposition of the material. If material Involved In fire Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If msterial not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary April 1961 tfCD Personnel protection Avoid breathing vapors Keep upwind Wear respiratory protection if material i$ misting Wear boots, protective gloves, and goggles Avoid bodily contact with the material If contact with the material anticipated, wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If matehal leaking (not on fire), downwind evacuation must be considered HYDROGEN SULFATE (See SULFURIC ACID 4930040) HYDROGEN PEROXIDE SOLUTION (6% TO 40% 4918775 PEROXIDE) OXIDIZER, CORROSIVE UN2014 Hydrogen peroxide solution is the colorless liquid dissolved in water. Its vapors are irritating to the eyes and mucous membranes. The ma terial, especially the higher concentrations, can violently decompose in contact with most common metals and their compounds. Contact with combustible materials can result in spontaneous ignition. Under pro longed exposure to fire or heat containers of the matehal may violently rupture due to decomposition of the material, tf material involved In fire Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible ft material not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Wear respiratory protection if material is misting Wear boots, protective gloves, and goggles Avoid bodily contact with the material II contact with the material anticipated, wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water HYDROGEN SELENIDE 4909415 FLAMMABLE GAS, POISONOUS UN2202 Hydrogen seienide is a cofortesa gas with an offensive odor. It is soluble in water. It is irritating to the eyes and mucous membranes. It is heavier than air. It may only be shipped in cylinders. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as tog Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use water spray to absorb vapors If material not on fire end not Involved in Are Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors April 1961 HYDROGEN SULFIDE 4905410 FLAMMABLE GAS, POISONOUS UN10S3 ENVIRONMENTALLY HAZARDOUS SU8STANCE (RCM00/45.4) Hydrogen sulfide is a colorless gas having the odor of rotten eggs. It is shipped as a liquefied gas under its own vapor pressure. One's sense of smell becomes rapidly fatigued in atmospheres containing hydrogen sulfide and hence cannot be counted on to wam of the con tinued presence of the gas. Contact with the liquid can cause frostbite. The gas is heavier than air and a flame can flash back to the source of leak very easily. Under fire conditions cylinders and tank cars may vi olently rupture and rocket. It is soluble in water. It weighs 8.3 pounds per gallon, tf material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use water spray to absorb vapors If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Approach fire with caution Evacuation tf fire becomes uncontrollable or container is exposed to dkect flame--evacuate for a radius of 2500 feet If material leaking (not on fire) evacuate tor a radius of 2500 feet Environmental considerations--land spill Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considaratlons--watar spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment 283 MCD 000010026 HYDROGEN, LIQUEFIED 4905745 FLAMMABLE GAS UNI 966 Hydrogen, liquefied is hydrogen gas which has been compressed and condensed as a liquid at very low temperatures, boiling point >442 deg. F. It is a colorless liquid and may be shipped only in special very heavily insulated cylinders and tank cars. Contact with the liquid will cause frostbite. Hydrogen gas at normal temperatures is lighter than air but until vapors Irom the liquid warms up it will be heavier than air. It is very easily ignited and a flame will flash back to the source of the leak very easily. The leak could either be a liquid or vapor leak. -the tank car or cylinder is required to vent the vapor as it is normally given off). Under fire conditions the tank car or cylinder may violently rupture and rocket. If material on ftre or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as (og Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Oo not use water on material itself If material not on fire and not Involved in fire Keep sparks, (lames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Do not use water on material itself Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water HYDROXY ALDEHYDE WASTES (FLAMMABLE 4910466 LIQUIO, N.O.S.) FLAMMABLE LIQUID UN1993 Hydroxy aldehyde wastes is a material containing a solvent having a closed cup Hash point of less than 100 deg. F. The hazard of this material is flammability. K material on tire or involved In fire Do not extinguish fire unless flow can be stopped Use water in Hooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use ''alcohol'' foam, carbon dioxide or dry chemical tf material not on firs and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water HYDROStUCOFLUORIC ACID (See HYDROFLUOROSIUCIC ACtO 4930026) HYDROXY ALDEHYDE WASTES (COMBUSTIBLE 4915466 LIQUID, N.O.S.) COMBUSTIBLE LIQUID NA1993 Hydroxy aldehyde wastes is s material containing a sotvant having a dosed cup flash point batwasn 100 and 199 dag. F. The hazard of this material is combustibility, tf material on fire or Involved toi fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If materiel not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind HYDROXYETHYLACRYLATE (CORROSIVE 4935675 LIQUID,N.O.S.) CORROSIVE MATERIAL UN1760 Hydroxyethyiacryiate is a dear colorless liquid, ft is used to make plastics. It is corrosive to tissue. H is also combustible and has a flash point of 120 deg. F. If the material Is subject to heat or becomes con taminated, it is liable to polymerize with release of heat. If the poly merization takes place inside a container, the container is subject to voiient rupture. It Is lighter than water and is slightly soluble in water, its vapors are heavier than air. If material on firs or involved In fire Use water in flooding quantities as log Solid streams of water may be ineffective Coot alt affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Use water spray to absorb vapors If material not on firs and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Oo not use water on material itself Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap end water If contact with the material anticipated, wear full protective cfothing 264 April 1961 -n 00001002^ HYDROXYPROPYL ACRYLATE (CORROSIVE LIQUID, 4935510 N.O.S.) CORROSIVE MATERIAL, POISONOUS UNI 760 POLYMERIZABLE Hydroxypropyl acrylate is a dear colorless liquid. It is used to make plastics. It is toxic by inhalation and skin absorption, and is corrosive to tissue. It is also combustible and has a flash point of 136 deg. F. If the material is subject to heat or becomes contaminated, it is liable to po lymerize with release of heat. If the polymerization takes place inside a container, the container is subject to violent rupture. It is lighter than water and is slightly soluble in water. Its vapors are heavier than air. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use ' alcohol'' foam, carbon dioxide or dry chemical Use water spray to absorb vapors If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing HYPOCHLORITE SOLUTION (CONTAINING MORE 4936335 THAN 7% AVAILABLE CHLORINE BY WEIGHT) CORROSIVE MATERIAL UNI 791 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100/45.4) Hypochlorite solutions are colorless to light yellow liquids having a chlorine like odor. They consist of a hypochlorite compound dissolved in water. They are corrosive to metals and tissue. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty,) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in Are Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Avoid bodily contact with tha material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective dothing Environmental conskferatione--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate April 1961 Environmental considerations--water spill Neutralize with agricultural lime (slaked time), crushed limestone, or sodium bicarbonate If dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors HYPOCHLORITE SOLUTION CONTAINING NOT MORE 4944145 THAN 7% AVAILABLE CHLORINE (BY WEIGHT) ORM-A NA1791 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100/45.4) Hypochlorite solution containing not more than 7% available chlorine (by weight) is the white crystalline solid dissolved in water having a faint odor of chlorine. It is used as a bleach for textiles and paper pulp, for water purification, to make other chemicals, and for many other uses. It is corrosive to aluminum. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) If material not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Oike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations air spill Apply water spray or mist to knock down vapors IGNITER 4903465 CLASS C EXPLOSIVE Igniter consists of a fiberboard. plastic, paper, or metal tube containing a small quantity of igniting compound which is ignited by the action of a primer, pull wire or scratch composition. H material on fire or involved in fire Flood with water Apply water from as far a distance as possible If materiel not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material 285 MCD 000010028 IGNITER CORO 4903455 CLASS C EXPLOSIVE Igniter cord consists of textile yams and/or a wire uniformly covered with a combustible chemical mixture, with or without additional textile or wire counterings waterproofing or finishing coatings which, when ig nited bums externally at various rates according to design. If material on fire or involved In fire Flood with water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting tires involv ing this material IGNITER FUSE-METAL CLAD 4903450 CLASS C EXPLOSIVE Igniter fuse-metal clad is an explosive igniter composition encased in a metal tube. If material on fire or involved In fire Flood with water Apply water from as far a distance as possible If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius Of 1500 feet IGNITER, JET THRUST (JATO) 4901360 CLASS A EXPLOSIVE Igniter, jet thrust (jato) is a device consisting of an electrically or remotely controlled ignition element and a charge of deflagrating type explosive. They are used to ignite the propelling charge of jet thrust units. If material on fire or Involved in fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let bum If material not on fire and not Involved In fire Keep sparks, (lamas, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting flies involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 5000 feat IGNITER, JET THRUST (JATO) 4902540 CLASS B EXPLOSIVE Ignitef, jet thrust (jato) are devices consisting of an electrically or remotely controlled ignition element and a charge of deflagrating type explosive. They are used to ignite the propelling charge of jet thrust units. If material on firs or involved in fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let bum 266 If material not on fire and not involved in fire Keep sparks, (lames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation if the material is on fire or involved in lire evacuate for a radius of 2500 feet IGNITER, ROCKET MOTOR 4902550 CLASS B EXPLOSIVE Igniters, rocket motor are devices consisting of electrically or remotely controlled ignition elements and a deflagrating type of explosive. They are used to ignite the prooulsion charge of rocket motors. If material on fire or Involved In fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let bum If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet IGNITER, ROCKET MOTOR 4901362 CLASS A EXPLOSIVE Igniter, rocket motor is a device consisting of an electrically or remotely controlled ignition element and a deflagrating type of explosive. They are used to ignite the propelling charge of rocket motors. If material on fire or involved In fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let bum If material not on fire and not involved in fire Keep sparks, flames, end other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 5000 feet IMINOBISPROPYLAMINE 4935659 CORROSIVE MATERIAL, BASIC, COMBUSTIBLE UN2269 Iminobispropyiamine is s colorless liquid, with an ammonia-like odor. It is combustible and has s flash point of 175 deg. F. It is soluble in water. It it corrosive to metals and tissue. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or Involved in fire Do not extinguish firs unless flow can be stopped Use water in flooding quantities as fog Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Uaa "aicohor foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and eewara Build dikes to contain flow as necessary April 1981 0000X00^ Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing INITIATING EXPLOSIVE (OIAZODINITROPHENOL) 4901430 CLASS A EXPLOSIVE Diazodinitrophenol is a yellow crystalline solid that darkens on ex posure to sunlight. It must be shipped wet with at least 40% water or water and denatured alcohol mixture, if it should dry out it can explode due to shock, heat, flame or friction. Upon prolonged exposure to fire or heal containers of the wet material will explode. If material on fire or Involved In fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let bum if material not on fire end not Involved in fire Keep sparks, flames, and other sources of ignition away Keep spilled material wet Wet spilled material before picking it up Do not attempt to sweep up dry material Personnel protection Avoid breathing dusts, and fumes from burning material Wear protective gloves and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 5000 feet INITIATING EXPLOSIVE (FULMINATE OF MERCURY, 4901420 WET) CLASS A EXPLOSIVE Fulminate of mercury, wet is shipped as a slurry or wet mass of white crystals, it must be shipped wet with at least 25% water or water-ethyl alcohol mixture, if it should dry out, it can explode due to shock, heat flame, or friction. Upon prolonged exposure to fire or heat containers of the wet material will explode. If material on fire or involved in lira Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let bum If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep spilled material wet Wet spilled material before picking it up Oo not attempt to sweep up dry material Personnel protection Avoid breathing dusts, and fumes from burning material Wear boots, protective gloves, and goggles Oo not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear seif-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 5000 feet April 1961 INITIATING EXPLOSIVE (GUANYL NITROSAMINO 4901435 GUANYLIDENE HYDRAZINE) CLASS A EXPLOSIVE Guanyi nitrosamino guanylidene hydrazine is a colorless to pale yellow fluffy crystalline solid. It must be shipped wet with at least 30% water or water and denatured ethyl alcohol mixture. Dry it will detonate due to shock, heat, flame, or friction. Containers of the wet material can explode on prolonged exposure to fire or heat. If material on fire or involved in fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let bum if material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep spilled material wet Wet spilled material before picking it up Do not attempt to sweep up dry material Personnel protection Avoid breathing dusts, and fumes from burning material Wear protective gloves and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation if the material is on fire or involved in fire evacuate for a radius of 5000 feet INITIATING EXPLOSIVE (LEAD AZIDE, DEXTRINATED 4901440 TYPE ONLY) CLASS A EXPLOSIVE Lead azide is shipped as a wet slurry or mass of colorless crystals. It must be shipped wet with at least 20% water or water and denatured ethyl alcohol mixture. If it should dry out, it may explode or detonate due to shock, heat, flame or friction, under prolonged exposure to fire or heat containers of the wet material wiH explode, if material on fire or involved In fire Dangerously explosive Do not fight fires In a cargo of explosives Evacuate area and let bum If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep spilled material wet Wet spilled material before picking It up Do not attempt to sweep up dry material Personnel protection Avoid breathing dusts, and fumes from burning material Wear protective gloves and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on Are or involved in Are evacuate for a radius of 5000 feet INITIATING EXPLOSIVE (LEAD 4901445 MONONITRORESORCINATE) CLASS A EXPLOSIVE Lead mononitroresorcinate is shipped as a slurry or wet mass of reddish-brown crystals. It must be shipped wet with at least 40% water or water and denatured alcohol mixture. If it should dry oul it can explode due to shock, heat, flame, or friction. Upon prolonged exposure to fire or heat containers of the wet material wUI explode. Coatinutd on mxtpsg* 287 MOD 000010030 ff material on fire or Involved In fire Dangerously explosive Do not light tires in a cargo of explosives Evacuate area and let bum If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep spilled material wet Wet spilled material before picking it up Do not attempt to sweep up dry material Personnel protection Avoid breathing dusts, and fumes from burning material Wear protective gloves and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 5000 feet INITIATING EXPLOSIVE (LEAD STYPHNATEMLEAD 4901450 TRINITRORESORCINATE) CLASS A EXPLOSIVE Lead styphnate is shipped as slurry or wet mass of orange-yellow crystals. It must be shipped wet with at least 20% water or water and denatured ethyl alcohol mixture. If it should dry out, it can explode due to shock, heat, flame or friction. Upon prolonged exposure to fire or heat containers of the wet material will explode. If material on fire or involved In fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let bum If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep spilled material wet Wet spilled material before picking it up Do not attempt to sweep up dry material Personnel protection Avoid breathing dusts, and fumes from burning material Wear protective gloves and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus whan fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 5000 feet INITIATING EXPLOSIVE (NITROSOGUANIDINE) 4901460 CLASS A EXPLOSIVE Nitrosoguanidine is shipped as a slurry or wet mast of pale yellow crystals. It must be shipped wet with at least 10% water, if it should dry out it can explode due to shock, heat flame, or friction. Upon prolonged exposure to fire or heat containers of the wet material will explode. If material on fire or involved In fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let bum If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep spilled material wet Wet spilled material before picking it up Do not attempt to sweep up dry material Personnel protection Avoid breathing dusts, and fumes from burning material Wear protective gloves and goggles Do not handle broken packages without protective equipment 286 Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 5000 feet INITIATING EXPLOSIVE (PENTAERYTHRITE 4901465 TETRANITRATE) CLASS A EXPLOSIVE Pentaerythrite letranitrate is shipped as a slurry or wet mass of white crystals. It must be shipped wet with at least 40% water or water and denatured alcohol mixture. If it should dry out. it can explode due to shock, heat, flame or friction. Upon prolonged exposure to fire or heat containers of the wet material will explode. If material on fire or Involved In fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let bum If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep spilled material wet Wet spilled material before picking it up Oo not attempt to sweep up dry material Personnel protection Avoid breathing dusts, and fumes from burning material Wear protective gloves and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation if the material is on fire or involved in fire evacuate for a radius of 5000 feet INITIATING EXPLOSIVE (TETRAZENE) (GUANYL NITROSOAMINO GUANYL TETRAZENE 4901470 CLASS A EXPLOSIVE Tetrazene is shipped as a slurry or wet mass of light yellow fluffy solid. It must be shipped wet with at least 30% water or water and denatured alcohol mixture, tf it should dry out it can explode due to shock heat flame, or friction. Upon prolonged exposure to fire or heat containers of the wet material will explode. If material on fire or Involved In fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let bum If material not on fire and not Involved m fire Keep sparks, names, and other sources of ignition away Keep spilled material wet Wet spilled material before picking it up Do not attempt to sweep up dry materiel Personnel protection Avoid breathing dusts, and fumes from burning material Wear protective gloves and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 5000 feet Hoc 0ooioo April 1981 INITIATING EXPLOSIVES {NITRO MANNITE) 4901455 CLASS A EXPLOSIVE Nitro mannite is shipped as a slurry or wet mass of colorless crystals, t must be shipped wet with at least 40% water or water and denatured alcohol mixture. If it should dry ouL it can explode due to shock, heat, flame, or friction. Upon prolonged exposure to fire or heat containers of the wet material will explode. If material on fire or Involved in fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let bum If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep spilled material wet Wet spilled material before picking it up Do not attempt to sweep up dry material Personnel protection Avoid breathing dusts, and fumes from burning material Wear protective gloves and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 5000 feet INK (INK MATERIALS, NEC) 4915206 COMBUSTIBLE LIQUID NA1993 Ink materials, nec may contain a flammable solvent Its flash point is between 100 and 199 deg. F. The hazard is combustibility. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water INK (INK, PRINTING, NEC) 4910205 FLAMMABLE LIQUID UN1210 Ink. printing, nec is various colored liquids or fluid pastes. It has a flash point of less than 100 deg. F. It is generally lighter than water and insoluble in water. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as tog Solid streams of water may be ineffective Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use `alcohol" foam, carbon dtoxide or dry chemical April 1981 MCD 000010032 If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water INK MATERIALS, NEC (FLAMMABLE LIQUID, N.O.S.) 4910206 FLAMMABLE LIQUID UN1993 Ink materials, nec may contain a flammable solvent. Its flash point is less than 100 deg. F. The hazard is flammability. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on firs and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Buikj dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water INK, PRINTING, NEC (INK) 4915205 COMBUSTIBLE UQUIO UN2867 Ink, printing, nec is various colored liquids, fluids, or pastes. It has a flash point between 100 and 199 deg. F. It is generally lighter than water and insoluble to water. Its vapors are heavier than air. N material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical ff materiel not on fire end not involved In fire Keep sparks, flames, end other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 289 INSECTICIDE ADHESIVES, LIQUID (ADHESIVE, N.O.S.) 4915502 COMBUSTIBLE LIQUID NA1133 Insecticide adhesives, liquid are the solutions of various gums and resins in vanous solvents. The liquids are generally quite thick and range from a clear colorless to a black "tar". The flash point depends on the solvent used, but it will be between 100 and 199 deg. F. The hazard of ihis material is combustibility. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water INSECTICIDE ADHESIVES, LIQUID (ADHESIVES, 4910502 N.O.S.) FLAMMABLE LIQUID NA1133 Insecticide adhesives, liquid are the solutions of various gums and resins in various solvents. The liquids are generally quite thick and range from a clear colorless to a black "tar". The flash point depends on the solvent used. But it will be below 100 deg. F. The hazard ot this material is flammability. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water INSECTICIDE ADHESIVES, SPREADERS OR 4936594 SUCKERS, LIQUIO (CORROSIVE UOUIO, N.O.S.) CORROSIVE MATERIAL UN1760 Insecticide adhesives, spreaders or stickers, liquid are various colored liquids having the property of being corrosive to metals and/or tissue. It may be combustible though requiring some effort to ignite, ft may or may not be water soluble. H material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in Hooding quantities as fog Use '`alcohol" loam, carbon dioxide or dry chemical 290 If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapops Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this materia' If contact with the material anticipated, wear full protective clothing INSECTICIDE, DRV. N.O.S. (AGRICULTURAL 4921435 INSECTICIDES OR FUNGICIDES. NEC, OTHER THAN LIQUID) POISON B NA2S86 Insecticide, dry is a material which have the property of being toxic by ingestion, inhalation or skin absorption. Contact the pesticide safety team network. Telephone; 800-424-9300 If material on fire or involved in fire Extinguish fire using agent suitable tor type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires Involv ing this material If contact with the material anticipated, wear full protective clothing INSECTICIDE, DRY, N.O.S. (INSECTICIDES, INSECT 4921434 OR ANIMAL REPELLENTS OR VERMIN EXTERMINATORS, NEC, OTHER THAN AGRICULTURAL) POISON B NA2586 Insecticide, dry, n.o.s. is e material which have the property of being toxic by ingestion, inhalation or skin absorption. M material on fire or Involved In fire Extinguish fire using agent suitable tor type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical H material not on fire and not Involved In fire Keep sparks, flames, and other sources ol ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material April 1981 mod 00010033 INSECTICIDE, UQUEF1E0 GAS 4904830 NONFLAMMABLE GAS NA1968 Insecticide, liquefied gas are nonflammable formulations using a liq uefied nonflammable gas as a propellant to disperse the material. While the material doesn't meet dot poison definitions prolonged breathing ot the fumes should be avoided. It may only be shipped in cylinders or aerosol containers. Exposure of the aerosol containers to fire or heat can result in their rupturing and rocketing. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use water spray to absorb vapors If material not involved in fire Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water INSECTICIDE, LIQUID, N.O.S. 4910210 FLAMMABLE LIQUID NA1993 Insecticide, liquid is the proper shipping name lor those materials having closed cup flash point of less than 100 deg. F. and not specifically mentionned in the hazardous materials regulations. Prolonged exposure to the vapors or contact with the liquid may result in death through inhalation or skin absorption, though the main hazard is flammability. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus whan fighting fires involv ing this material INSECTICIDE, LIQUID, N.O.S. 4915210 COMBUSTIBLE UQUIO NA1993 Insecticide, liquid is the proper shipping name lor those materials having a closed cup flash point between 100 and 199 deg. F. and not specifically mentioned in the hazardous materials regulations. Prolonged exposure to the vapors or contact with the liquid may result in death through inhalation or skin absorption, though the main hazard is combustibility. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog April 1981 0oO:oVoO' Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use '`alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain (low as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water INSECTICIDE, LIQUID, N.O.S. (AGRICULTURAL 4921436 INSECTICIDES OR FUNGICIDES, NEC, LIQUID) POISON B NA2902 Insecticide, liquid, n.o.s. is a liquid material which has the property of being toxic by ingestion, inhalation, or skin absorption. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300 If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical H material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water INSECTICIDE, LIQUID, N.O.S. (INSECTICIDES OR 4910197 FUNGICIDES, AGRICULTURAL, NEC, LIQUID) FLAMMABLE LIQUID NA1993 Insecticide liquid, n.o.s. is the proper name for those materials having a dosed cup flash point of less than 100 deg. F. and not specifically mentioned in the hazardous materials regulations. Although the main hazard is flammabiiity, prolonged exposure to the vapors or contact with the liquid may result in death thruogh inhalation or skin absorption, in case of damage to or leaking from containers of this material, contact the pesticide safety team network. Telephone 800-424-9300. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as log Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Continued on noxt pogo 291 If material not on fire and not Involved In Are Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Oo not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material INSECTICIDE, LIQUID, N.O.S. (INSECTICIDES OR 4915197 FUNGICIDES, AGRICULTURAL, NEC, UQUJO) COMBUSTIBLE LIQUID NA1993 Insecticide liquid n.o.s., is the proper shipping name (or those ma terials having a closed cup flash point between 100 and 200 deg.f and not specifically mentioned in the hazardous materials regulations. Pro longed exposure to the vapors or contact with the liquid may result in illness or death through inhalation or skin absorption though the main hazard is combustibility. In case of damage to or leakage from containers of this material, contact the pesticide safety team network. Telephone 800-424-9300. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol'' foam, carbon dioxide or dry chemical If material not on fire end not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material INSECTICIDE, LIQUIEF1ED GAS. CONTAINING POISON 4920550 A MATERIAL OR POISON B MATERIAL POISON A NA1957 insecticide, liquefied gas. containing poison a material or poison b material are formulations using a liquefied gas as a propellent to disperse the poison a or b material. It may only be shipped in eyinders which may have to be overpacked in wooden or metal containers. Prolonged exposure of the cylinders to fire or heat may result in the violent rupturing and rocketing of the cylinders. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone; 600-424-9300 If materiel involved in fire Do not extinguish fire unless flow can be stopped Extinguish fire using agent suitable tor type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Cool alt affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical 292 ff material not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered INSTANTANEOUS FUSE 4903470 CLASS C EXPLOSIVE Instantaneous fuse is cotton yam impregnated with a finely-powdered deflagrating composition. It is overspun with tape and yam. and is used to ignite multiple lengths of safety fuse from a common point. If material on fire or Involved to fire Flood with water Apply water from as far a distance as possible If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material IOCMNE MONOCHLORIDE 4932345 CORROSIVE MATERIAL UN1792 Iodine monochloride is a reddish brown oily liquid becoming a solid at 81 deg. F. It has a pungent odor. It is decomposed by water into iodine, iodic add and hydrochloric add with release of heat. It is corrosive to metals and tissue, if material involved In fire Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself if large quantities of combustibles are involved, use water in flooding quantities as spray and tog Use water spray to absorb vapors Cool an affected containers with floodtog quantities of water Apply water from as far a distance as possible If material not Involved to fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing April 1961 MOD 000010035 tOOINE PENTAFLUORIDE 4918215 OXIOIZER, POISONOUS, CORROSIVE UN2495 Iodine pentafluoride is a colorless fuming liquid. It is decomposed by water to iodine and hydrofluoric acid. Contact with organic materials may result in spontaneous ignition. It is corrosive to metals and tissue. It may only be shipped in cylinders not equipped with safety relief de vices. Prolonged exposure of the cylinder to fire may result in their violent rupturing and rocketing. It material Involved In fire Do not use water on material itself Use dry chemical or carbon dioxide Cool all affected containers with flooding quantities of water If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors If material not Involved In fire Keep material out of water sources and sewers Do not use water on material itself Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective dothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered IRON CHLORIOE, SOUD (See FERRIC CHLORIDE, SOLID 4944138} IRON SESQUICHLORIDE. SOUD (See FERRIC CHLORIDE, SOUP 4944138) IRON SULPHATE (FERRIC), DRY, CRUDE (FERRIC 4963823 SULFATE) ORM-E NA9121 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Iron sulphate (ferric), dry. crude is a yellow crystalline lo greyish white powder. It is used in water purification, as a soil conditioner, and for many other uses. It is slightly soluble in water. It is non-combustible. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) If material not involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates IRON MASS OR SPONGE (NOT PROPERLY OXIOIZED) 4916717 FLAMMABLE SOUD NA1383 Iron mass or sponge (not property oxidized) is finely divided iron oxide on a wood shavings base, if the iron is not completely oxidized the iron sponge is liable to spontaneous heating as the remaining iron is oxidized. The heat from the oxidation may be sufficient to ignite the material. Iron sponge is fairly easily ignited by sparks or heat from external sources, tf material on fire or involved in fire Flood with water If material not on fire and not involved In Are Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning materiel Wear boots, protective gloves, and goggles IRON MASS, (OR) SPONGE, SPENT (IRON SPONGE, 4916718 SPENT, OR SPENT OXIDE) FLAMMABLE SOUD UN1376 Iron mass (or) sponge, spent is iron sponge saturated with sulfur from gas purification. It is quite liable to spontaneous heating. This heat may be sufficient to ignite the iron mass. It is also fairty easily ignited by sparks or heat from external sources. If material on fire or involved in fire Flood with water tf material not on fire and not involved In fire Keep, sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear boots, protective gloves, and goggles April 1981 MCD 000010036 IRON SULPHATE (FERRIC), DRY, OTHER THAN 4963818 CRUDE (FERRIC SULFATE) ORM-E NA9121 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/4S4) Ferric sulphate Is a yeflow crystalline or greyish white powder. II is used in water purification, as a soil conditioner, as a disenfectant and for many other uses. It is soluble in water. It is non-combustible. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) If material not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations water spill Neutralize with agricultural time (slaked lime), crushed limestone, or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove Immobilized masses of pollutants and precipitates 293 IRON, POWDERED, NEC (FLAMMABLE SOLID, N.O.S.) 4916769 FLAMMABLE SOLID UN132S Iron, powdered, nec is a grey lustrous powder, it is used in powder metallurgy, and as a catalyst in chemical manufacture. It may react with water to give off hydrogen, a flammable gas. The heat from this reaction may be sufficient to ignite the hydrogen. If materiel on fire or involved in fire Use water only if flooding quantities are available Use graphite, soda ash. powdered sodium chloride, or suitable dry powder If material not on fire and not involved in fire Do not use water Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Personnel protection Avoid breathing dusts, and fumes from burning material Wear boots, protective gloves, and goggles IRRITATING AGENT, N.O.S. 4925830 IRRITATING MATERIAL NA1693 Irritating agent, n.o.s. is the proper shipping name for those materials not specifically mentioned in the regulations having the property of giving fumes that are extremely irritating to the eyes and mucous membranes when exposed to air, or contact with fire. Try to ascertain the .exact material. If material on fire or Involved in fire Extinguish fire using agent suitable lor type of surrounding fire (Material itself does not burn or bums with difficulty.) Use water in flooding quantities as fog Use "alcohol" loam, carbon dioxide or dry chemical Cool all affected containers with flooding quantities of water Use water spray to absorb vapors If material not on fire and not involved In Are Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing ISO HEPTYL ALCOHOL (ALCOHOL, K.O.S.) 4913122 COMBUSTIBLE UOUID UN1997 Iso heptyl alcohol is a clear colorless liquid with a pleasant odor, h is used to make other chemicals, as a solvent, and in cosmetic for mulations. it has a flash point of 106 dag. F. K Is Hqhter than water and insoluble in water. Its vapors are heavier than air. It materiel on Are or involved In Are Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition ewey Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors 294 Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ISOAMYL ALCOHOL (ALCOHOL, N.O.S.) 4913127 COMBUSTIBLE LIQUID UN1987 Isoamyl alcohol is a clear colorless liquid with a disagreeable odor. It has a flash point of 114 deg. F. It is lighter than water and slightly soluble in water. Its vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If materiel not on Are and not Involved In Are Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ISOBUTANE 4906747 FLAMMABLE GAS UN107S Isobutane is a colorless gas with a faint petroleum like odor. It is shipped as a liquefied gas under its Vapor pressure. Contact with the liquid can causa frostbite. It is sasily ignited. Its vapor is heavier than air and a flame can flash back to the source of leak very easily. The leak can either be a liquid or vapor leak. It can asphyxiate by the dis placement of air. Under fire conditions the cylinders or tank car may violently rupture and rocket If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as tar e distance as possible If material not on fire end not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak If without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution Evacuation If fire becomes uncontrollable or container Is exposed to direct flame--evacuate for a radius of 2500 feet If material leaking (not on fire), downwind evacuation must be considered MOD 000010037 AprH 1981 ISOBUTANE (ISOBUTANE FOR FURTHER REFINERY 4905750 PROCESSING) FLAMMABLE GAS UN1075 'sobutane is a colorless gas with a faint petroleum like odor. It is used in aerosol propellant, to make other chemicals, and for many other uoss it is shipped as a liquefied gas under its vapor pressure. Contact with the liquid can cause frostbite. It is easily ignited. Its vapors are heavier than air and a flame can flash back to the source of leak very easily. The leak can be either a liquid or vapor leak. It can asphyxiate by the displacement of air. Under fire conditions the cylinders or tank cars may rupture and rocket. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed -to direct flame--evacuate for a radius of 2500 feet If material leaking (not on fire), downwind evacuation must be considered ISOBUTYL ACETATE 4909207 FLAMMABLE LIQUID UNI 213 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) 'sobutyl acetate is a dear colorless liquid with a fruity odor. It has a .1 point of 64 deg.f. It is lighter than water and insoluble in water, its vapors are heavier than air. It weighs 7.2 pounds per gallon. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as log Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If materiel not on fire and not Involved In fire Keep sparks, names, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Apply fluorocarbon-water foam to diminish vapor and fire hazard Environmental consideration*--water spill Use natural barriers or oil spill control booms to limit spil motion Use surface active agent (e.g. detergent soaps, alcohols) to com press and thicken spilled material Apm 1981 Inject "universal" gelling agent to solidify encircled spill and increase effectiveness of booms If dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors ISOBUTYL ALCOHOL (BUTYL ALCOHOL) 4909131 FLAMMABLE LIQUID NA1120 Isobutyl alcohol is a clear colorless liquid. It has a flash point of 82 deg. F. tt is lighter than water and soluble in water. Its vapors are heavier than air. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use 'alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, (lames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ISOBUTYLACRYLATE (FLAMMABLE LIQUID, N.O.S.) 4907263 FLAMMABLE LIQUID UN1993 POLYMERIZABLE Isobutyl acrylate is a clear colorless liquid with an acrid odor. It has a flash point of 86 deg. F. The vapors are irritating to the eyes and respiratory system. If the material Is subjected to heat for prolonged periods or becomes contaminated, it is subject to polymerization. If the polymerization takes place inside a container, the container may violently rupture. The material is lighter than, water and slightly soluble in water. If materiel on fire or involved in fire Do not extinguish fire unless How can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cod all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical H material not on fire and not Involved In fire Keep sparks, flames, and other sources of Ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop Isak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire beoomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered 295 3S ISOBUTYLAMINE 4908186 FLAMMABLE LIQUID UN1214 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-1000/454) Isobutylamine is a dear colorless liquid with a fish like odor. It has a flash point of 15 deg. F. It is lighter than water and soluble in water, Its vapors are heavier than air. Toxic oxides of nitrogen are produced during combustion of this material. It weighs 6.1 pounds per gallon. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, (lames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash, cement powder, sawdust or com* merdal sorbents Apply fluorocarbon-water foam to diminish vapor and fire hazard Neutralize with sodium bisulfate (nahso4) Environmental eoneideratlone--water split Add sodium bisutfats if dissolved, apply activated carton at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air apIN Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible if material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame---evacuate for a radius of 2500 feet If material leaking (not on fire), downwind evacuation must be considered ISOBUTYRALOEHYDE (FLAMMABLE LIQUID, N.O.S.) 4908185 FLAMMABLE UQUIO UN1993 Isobutyraldehyde is a dear cotoriess liquid having a pungent odor. It is used to make other chemicals. H has a flash point of -40 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or Involved in fire Do not extinguish Are unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread Are Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If Are becomes uncontrollable or container is exposed to direct flame evacuate for a radius of 1500 feet If material leaking (not on Are), downwind evacuation must be considered ISOBUTYLENE 4905748 FLAMMABLE GAS UN1075 Isobutylene is a colorless gas with a faint petroleum like odor. For transportation it may be stenched. ft is shipped as a liquefied gas under its vapor pressure. Contact with the liquid can cause frostbite. It is easily ignited. Its vapors are heavier than air and a flame can flash back to the source of leak very easily. The leak can either be in liquid or vapor leak. It can asphyxiate by the displacement of air. Under Are conditions the cylinder or tank car may violently rupture and rocket 296 ISOBUTYRIC ACID 4931438 CORROSIVE MATERIAL, ACIOIC, COMBUSTIBLE UN2529 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Isobutyric add is a colorless liquid with a light odor of rancid butter. A is combustible and has a flash point of 132 dag. F. It is soluble in water. It 1$ corrosive to metals and tissue. A weighs 7.9 pounds per gation. April 1981 MCD 000010039 If material on fire or Involved In fire Use water in flooding quantities as log Solid streams of water may be ineffective Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Use water spray to absorb vapors If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate if dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment ISOBUTYRIC ANHYDRIDE CORROSIVE MATERIAL, ACIDIC. COMBUSTIBLE 4931439 UN2530 Isobutyric anhydride is a colorless liquid. It is combustible and has a flash point of 139 deg. F. It is decomposed by water to isobutyric add, which is water soluble with release of heat. It is corrosive to metals and skin. If material on fire or Involved In fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use ``alcohol'' foam, carbon dioxide or dry chemical If material not on lira and not Involved In lire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear fuff protective clothing xt< 1981 Qano Jo. o. ISOBUTYRONITRILE (FLAMMABLE LIQUID, N.O.S.) 4909206 FLAMMABLE UQUID UN1993 isobutyronitrile is a clear colorless liquid. It has a flash point of 47 deg. F. It is lighter than water and slightly soluble in water. Its vapors are heavier than air. Toxic oxides of nitrogen are produced during combustion. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing ISONONANYL PEROXIDE, (TECHNICALLY PUREXOR) 4919174 ISONONANYL PEROXIDE, (IN SOLUTION) ORGANIC PEROXIDE UN2128 isononanyt peroxide, (technically pure or) isononanyl peroxide, (in solution) is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite; but once ignited, it will bum with increasing rapidity as the fire progresses. If spilled on combustible ma terials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burning of combustible materials. Under prolonged ex posure to fire or heat containers of the material may explode. If material on fire or Involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire end not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spiffed material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2S00 feet 297 ISOOCTANE FLAMMABLE LIQUIO 490818ft UN1262 Isooctane is a clear colorless liquid having a petroleum like odor. It has a flash point of 10 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless (low can be stopped Use water in flooding quantities as tog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Butld dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet if material leaking (not on fire), downwind evacuation must be considered ISOOCTENE 4908189 FLAMMABLE LIQUID UN121S Isooctene is a dear colorless liquid having a petroleum-like odor. It has a flash point of less than 20 deg. F. It is lighter than water and insoluble in water. Its vapors are lighter than air. It material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fin Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on Are and not Involved In fire Keep sparks, flames, and other sources of Ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak If without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for e radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered ISOOCTYL ALCOHOL, OTHER THAN PERFUMERY 491312S GRADE (ALCOHOL, N.O.S.) COMBUSTIBLE LIQUIO UN19S7 Isooctyl alcohol, other than perfumery grade, is a clear colorless liquid with a faint pleasant odor. It is used as a solvent, in the making of cutting and lubricating oils, in hydraulic fluids, and in the production of other chemicals. It has a flash point of 180 deg.f. it is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ISOOCTYL ALCOHOL, PERFUMERY GRADE 4913129 (ALCOHOL, N.O.S.) COMBUSTIBLE LIQUID UN1967 Isooctyl alcohol, perfumery grade is a dear colorless liquid with a faint pleasant odor. It is used as an ingredient of cosmetics. It has flash point of 180 deg.f. It is lighter than water and in soluble in water. Its vapors are heavier than air tf material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ISOPENTANE 4908192 FLAMMABLE UQUID UNI 265 Isopentane is a clear colorless liquid having a petroleum like odor. It has a flash point ot -70 deg. F. a boiling point of 82 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved In fire Do not extinguish lire unless flow can be stopped Use water in flooding quantities as log Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical 298 MOD 000010041 April 1981 tf material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered ISOPENTANOIC ACID 4931440 CORROSIVE MATERIAL NA1760 Isopentanoic acid is a colorless liquid with a penetrating odor. It is slightly soluble in water. It is corrosive to metals and to tissue. If material on fire or involved In fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Use water spray to absorb vapors If material not on fire and not Involved In fira Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind AvokJ bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing ISOPRENE 4907230 FLAMMABLE LIQUID UN1218 POLYMERIZABLE ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Isoprene is a dear coloriess liquid with a petroleum-like odor. It has a flash point of -65 deg. F. and a boiling point of 93 deg. F. If It becomes contaminated or is subjected to heat, isoprene may polymerize. If the polymerization take place in a container, the container Is subject to violent rupture. It is lighter than water and insoluble in water. Its vapors are heavier than air. It weighs 5.7 pounds per gailon. ft material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread lira Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical <1 1981 If material not on fire and not involved In fire Keep sparks, Names, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain Now as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet If material leaking (not on fire), downwind evacuation must be considered Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface Now using soil, sand bags, foamed polyurethane, or loamed concrete Absorb bulk liquid with fly ash. cement powder, sawdust, or com mercial sorbents Apply "universal" gelling agent to immobilize spill Environmental considerations--water spill Use natural barriers or oil spill control booms to limit spill motion Use surface active agent (e.g. detergent, soaps, alcohols) to com press and thicken spilled material Inject "universal" gelling agent to solidify encircled spill and increase effectiveness of booms Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors ISOPROPANOL 4909205 FLAMMABLE LIQUID UN1219 Isopropanol is a dear colorless liquid with a medicinal odor, it it used to make other chemicals, as a solvent, in pharmaceuticals (rubbing alcohol), and for many other uses, ft has a flash point of 53 deg. F. It is lighter than water and soluble in water. Its vapors are heavier than air. If material on fira or Involved in fire Do not extinguish fira unless flow can be stopped Use water in flooding quantities as fog Sold streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohoT foam, carbon dioxide or diy chemical If material not on fira and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 299 o,Oq 'Jo,o ISOPROPANOL AND METHANOL MIXTURE 4909206 (ALCOHOL, N.O.S.) FLAMMABLE LIQUID UN1987 Isopropanol and methanol mixture is a dear colorless liquid. It has a flash point of 52*55 deg. F. It is lighter than water and soluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical H material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes'to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ISOPROPANOLAMINE 4963359 DOOECYLBENZENESULFONATE ORM-E NA9127 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Isopropanolamine dodecylbenzenesulfonate is a white to light yellow granular solid. It is used as a detergent, it is soluble in water, it will bum though it may require some effort to ignite. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental coneiderations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerationa--water spill If dissolved, apply activated carbon at tan times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates ISOPROPY NITRATE 4907035 FLAMMABLE LIQUID UN1222 THERMALLY UNSTABLE Isopropyl nitrate is a clear colorless liquid with a pleasant odor. It has a flash point between 32 and 73 deg. F. Prolonged exposure of the material to heat may result in the spontaneous decomposition of the material and this decomposition may reach explosive violence. Pro* longed exposure of the containers of the material to fire or heat may result in the violent rupturing of the containers due to the decomposition of the material. It is heavier than water and insoluble in water. Its vapors are heavier than air. Toxic oxides of nitrogen are produced during com bustion of this material. 300 H material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the matenal Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation if fire becomes uncontrollable or container is exposed to direct flame evacuate for a radius of 2500 feet If material leaking (not on fire), downwind evacuation must be considered ISOPROPYL ACETATE 4909210 FLAMMABLE LIQUID UN1220 Isopropyl acetate is a dear colorless liquid. It has a flash point of 40 deg. F. It is lighter than water and slightly soluble in water. Its vapors are heavier than air. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool aH affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, llamas, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop teak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ISOPROPYL ACtO PHOSPHATE, SOUD 4933335 CORROSIVE MATERIAL, ACIDIC UNI 793 Isopropyl add phosphate is a white crystalline solid. It is corrosive to metals and tissue. N materiel on fire or Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible If materiel not on fire end not Involved In fire Keep sparks, flames, and other sources of ignition away Keep materiel out of water sources and sewers Neutralize spilled material with crushed limestone, soda ash, or lime April 1981 000010043 MOD Personnel protection Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with (he material anticipated, wear full protective clothing ISOPROPYL MERCAPTAN 4908205 FLAMMABLE LIQUID UN2703 Isopropyl mercaptan is a colorless liquid having a very strong disa greeable odor. It has a flash point of-30 deg. F. it is lighter than water and slightly soluble in water, its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as tar a distance as possible Use ' alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Oo not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on (ire), downwind evacuation must be considered ISOPROPYL PERCARBONATE. STABILIZED 4919SS0 ORGANIC PEROXIDE NA2134 Isopropyl percarbonate is a white granular softd. It must be shipped in refrigerated containers by private or contract motor carriage. It is insoluble in water. Spontaneous decomposition at room temperature releases flammable and corrosive products. It wB accelerate the burning of combustible materials. If material on fire or Involved in fire Use water in flooding quantities as log Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Appfy water from as far a distance as possfeie Use ''alcohol'' foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts Keep upwind Avoid bodily contact with the material yril 1981 Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet ISOPROPYL PERCARBONATE, UNSTABILIZED 4919551 ORGANIC PEROXI0E NA2133 Isopropyf percarbonate. unstabilized is a white crystalline or granular solid. It must be shipped in refrigerated containers by private or contract motor carriage. It is insoluble in water. Spontaneous decomposition at room temperature releases flammable and corrosive products. It will accelerate the burning of combustible materials, ff material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously-explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet ISOPROPYL PEROXYDICARBONATE, (NOT MORE 4919176 THAN 52% IN SOLUTION) ORGANIC PEROXIDE UN2134 Isopropyf peroxydicarbonate, (not more than 52% in solution) is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite; but once ignited, it will bum with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition ol the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burn ing of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or Involved In fire Use water in flooding quantities as fog Solid streams ol water may be ineffective Cod all affected containers with flooding quantities of water Appfy water from as far a distance as possible Use "atcohor foam, carbon dioxide or dry chemical Dangerously explosive Continued on next pege 301 WQD OOo 10o4< If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet ISOPROPYL PEROXYOICARBONATE, (TECHNICALLY 4919175 PURE) ORGANIC PEROXIDE UN2133 isopropyl peroxydicarbonate, (technically pure) is a white solid. It is used to manufacture paints, plastics, and rubber, it is insoluble in water. It is easily ignited and bums with increasing rapidity as the fire pro* grasses. It can form explosive mixtures with finely divided combustible materials. It supports the burning of combustible materials. Under pro* longed exposure to fire or heat containers of the material may explode. If material on fire or Involved In fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire end not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires Involv ing this material If contact with the material anticipated, wear fuR protective clothing Approach fire with caution Evacuation If tiie material is on fire or involved in fire evacuate for a radius of 2500 feet ISOPROPYLAMINE 4908194 FLAMMABLE LIQUIDS UN1221 Isopropyiamine is a clear colorless liquid with an ammonia-tike odor. It is used as a solvent and to make other chemicals. It has a flash point of -35 deg. F. and a boiling point of 90 deg. F. It is lighter than water and soluble in water. Its vapors are heavier than air. Toxic oxides of nitrogen are produced during the combustion of the material. If material on lira or Involved In Are Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective 302 Cool all affected containers with Hooding quantities of water Apply water from as far a distance as pdssible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without pro.ectrve equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear setf-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 leet If material leaking (not on fire), downwind evacuation must be considered ISOPROPYLTOLUENE (COMBUSTIBLE LIQUID, 4913147 N.O.S.) COMBUSTIBLE LIQUID NA1993 Isopropyltoluene is a clear colorless liquid with an aromatic odor. It has a flash point of 117 deg. F. It is lighter than water and insoluble in water, Its vapors are heavier than air. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread lire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire end not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water JET THRUST UNIT (JATO) 4902510 CLASS B EXPLOSIVE Jet thrust unit (jato) is a metal cylinder containing a mixture of chem icals capable of burning rapidly. They are used to furnish auxiliary thrust in the launching of aircraft, missiles etc. The usual (jato) units contain solid propellant although units based on liquid propellants are also used. Under prolonged exposure to heat or fire these units may explode. If material on fire or Involved In fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let bum If material not on fire end not Involved In fire Keep sparks, flames, and other sources of ignition away April 1991 MCD 000010045 Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet JET THRUST UNIT (JATO) 4901340 CLASS A EXPLOSIVE Jet thrust unit (jato) consists of a metal cylinder containing propellant explosive capable of burning rapidly and producing considerable pres sure. These units are designed to be ignited by an electric igniter. If material on fire or involved in fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let bum If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 5000 feet KELTHANE (AGRICULTURAL INSECTICIDES, NEC, 4966940 OTHER THAN LIQUIO) ORM-E NA2761 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Kelthane is a white crystalline solid, it is used as a pesticide. H is a wettable powder. It can cause illness by inhalation, skin absorption and/ or ingestion. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424- 9300. If material Involved In fire Extinguish fire using agent suitable for type of surrounding lire (Material itself does not bum or bums with difficulty.) If material not involved in fire Keep material out ol water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental consideration!--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental consideration*--water spill II dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates KELTHANE (AGRICULTURAL INSECTICIDES, NEC, 4966930 UQUIO) ORM-E NA2761 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Kelthane is a white crystalline solid dissolved in a liquid carrier. It is used as a pesticide. The carrier is water emuisifiabie. It can cause illness by inhalation, skin absorption and/or ingestion, in case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone; 600-424-9300. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) H material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spiH Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or loamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill if dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates April 1981 KELTHANE (INSECTICIDES, OTHER THAN 4966920 AGRICULTURAL, NEC) ORM-E NA2761 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Kelthane is a white crystalline solid or the solid dissolved on a liquid carrier. It is used as a pesticide. It is a wettable powder or water emui sifiabie liquid. It can cause illness by inhalation, skin absorption and/or ingestion. In case of damage to, or leaking from containers of this ma terial contact the pesticide safety team network. Telephone; 800-424- 9300. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) If material not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates 303 ttCZ) 0qq *46 KEPONE 4960140 ORM-E NA2761 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Kepone is a white solid. It is used as a pesticide. It is a wettabie powder or water emulsifiable liquid. It car cause illness by inhalation, skin absorption and/or mqestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone: 800-424-9300. if material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental consideration*--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates KEROSENE 4915171 COMBUSTIBLE UQUIO UN1223 Kerosene is a clear colorless to tight amber liquid with a petroleum odor. It has a flash point of 100 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out ol water sources and sewers Build dikes to contain (low as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water KITS, PNEUMATIC TIRE CLEANING, AUTO 4915464 (COMBUSTIBLE LIQUIO, N.O.S.) COMBUSTIBLE LIQUIO NA1993 Kits, pneumatic tire cleaning, auto is a material containing a solvent having a closed cup flash point between 100 and 199 deg. F. The hazard of this material is combustibility, if material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as log Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water 304 Apply water from as far a distance as possible Use `alcohol" foam, carbon dioxide or dry chemical If materiel not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Oo not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water KITS. PNEUMATIC TIRE CLEANING, AUTO 4910484 (FLAMMABLE UQUIO, N.O.S.) FLAMMABLE UQUID UN1993 Kits, pneumatic tire cleaning, auto is a material containing a solvent having a closed cup flash point of less than 100 deg. F. The hazard oi this material is flammability. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with Hooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical tf material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water LACQUER BASE DRY 4917323 FLAMMABLE SOUD NA2557 Lacquer base dry is the solid material used in making lacquers (paint). Because the material contains nirocelluiose, it is very flammable and easily ignited. Toxic oxides of nitrogen are produced during combustion. If material on Are or Involved in fire Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical Cool all affected containers with flooding quantities of water tf material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Personnel protection Wear self-contained breathing apparatus when fighting fires involv ing this material LACQUER BASE OR LACQUER CHIPS, PLASTIC 4910217 (WET WITH ALCOHOL OR SOLVENT) FLAMMABLE UQUIO NA1263 Lacquer base or lacquer chips, plastic contain a flammable solvent. Its flash point is 100 deg. F. or lower. The hazard is flammability. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as log Solid streams of water may be ineffective Coot all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical April 1981 MCD 000010047 H materia) not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water LACQUER CHIPS. DRY 4917324 FLAMMABLE SOLID NA2557 Lacquer chips, dry is the solid material used in making lacquers (paint). Because the material contains nitrocellulose it is very flammable and easily ignited. Toxic oxides of nitrogen are produced during combustion. If material on fire or involved in fire Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical Cool all affected containers with flooding quantities of water If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Personnel protection Wear self-contained breathing apparatus when fighting fires involv ing this material LACQUER THINNING COMPOUNDS. USED 4910486 (COMPOUND, LACQUER, THINNING) FLAMMABLE UQUID NA1142 Lacquer thinning compounds used are generally clear colorless liq uids. The flash point is below 100 deg. F. Most of these compounds are lighter than water and only partially soluble in water. Their vapors are heavier than air. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak If without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water LACQUER THINNING COMPOUNDS, USED 491 $466 (COMPOUND, LACQUER, THINNING) COMBUSTIBLE UQUID NA1142 Lacquer thinning compounds used are generally dear colorless liq uids. The flash point is between 100 and 199 deg. F. Most of these compounds are lighter than water and only partially soluble in water. Their vapors are heavier than air. it material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers 8uiid dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water LACTIC ACIO (HYDROXYPROPIONIC ACID) (ACID, 4931757 UQUID, N.O.S.) CORROSIVE MATERIAL, ACIDIC, COMBUSTIBLE NA1760 Lactic acid is a colorless to yellow syrupy liquid and is odoriess. It is used to make cultured dairy products, as a food preservative, and to make chemicals, it is soluble in water, it is corrosive to metals and tissue. H material on fire or Involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Use water spray to absorb vapors H material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled material with erushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodity contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water if contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit. pond, lagoon, holding area lo contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--sir spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment April 1981 000010** HCD 305 LAUROYL PEROXIDE 4919560 ORGANIC PEROXIDE UN2124 lauroyl peroxide is a coarse white powder. It is shipped either dry or 30 percent water wet. Dry, the material is easily ignited and bums with increasing rapidity as the fire progresses, though not as vigorously as some other peroxides. Dry or wet it supports the burning of combustible materials. Under prolonged exposure to heat or fire containers of the material may explode. If material on fire or involved in fire Use water in flooding quantities as fog Cool all affected containers witn Hooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing vapors or dusts Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is or fire or involved in fire evacuate for a radius of 2500 feet LAUROYL PEROXIDE, (NOT MORE THAN 4919167 42%,STABLE DISPERSION, IN WATER) ORGANIC PEROXIDE UN2893 Lauroyl peroxide, (not more than 42%.stable dispersion, in water) is a colorless to pale yellow liquid, it is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite: but once ignited, it will bum with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burn ing of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fir# or involved In fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive if material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away ary material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach tire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet LEAD ACETATE 4966640 ORM-E UN1616 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Lead acetate is a white crystalline solid. It is used to make other lead compounds, in chemical analysis, as an insecticide, and for many other uses. It is soluble in water, it is non-combustible. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental consideration*--water spill Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates LEAD ARSENATE AND SULPHUR, DRY (LEAD 4923318 ARSENATE, SOLID) POISON S UN1617 ENVIRONMENTALLY HAZAROOUS SUBSTANCE (RQ-500Q/227Q) Lead arsenate and sulphur, dry is a yellow white to yellow powder. It Is insoluble In water. It is toxic by inhalation and ingestion. Lead arsenate and sulphur, dry (lead arsenate, solid) na2020 If material involved In fire Extinguish fire using agent suitable lor type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or lire fighting water 306 tfCD 00l0oio49 April 1981 Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Add ferric chloride (fecl3) Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates LEAD ARSENATE, SOLIO 4923235 POISON B UN1617 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Lead arsenate, solid is a white powder, it is insoluble in water. It is toxic by skin absorption, inhalation (dust) and by ingestion. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical tf material not involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Add ferric chloride (fed3) Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates LEAD ARSENATE, SOLID (LEAD ARSENATE, PASTE) 4923234 POISON B UNI 617 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Lead arsenate, paste is the white powder mixed with water to form a thick slurry. It is insoluble in water. The dried material is toxic by skin absorption, inhalation (powder) and by ingestion, if material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical tf material not Involved In fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear ful protective clothing April 1981 Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental conslderatlone--water tplll Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Add ferric chloride (fecl3) Adiust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates LEAD ARSENITE, SOLID 4923236 POISON B UN1618 Lead arsenite. solid is a white powder. It is insoluble in water. It r$ toxic by inhalation (dust) and by ingestion. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved In fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material tf contact with the material anticipated, wear full protective clothing LEAD BAQHOU8E FLUE DUST (FLUE DUST, 4923361 POISONOUS) POISON B NA2811 Lead baghouse Hue dust is a greyish black powder. It is insoluble in water. It is toxic by inhalation (dust, etc.) and by ingestion, tf material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical tf material not involved In fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing LEAD CHLORIDE 4944130 ORM-B NA2291 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Lead chloride is a white crystaiine solid. It is used to make other lead compounds and In analytical chemistry. It is insoluble in cold water and is soluble in hot water. It is non-combustible. It is corrosive to aluminum. Continued on next paga MCD 000010050 307 ft material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upw<nd Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates LEAD CYANIDE 4923447 POISON B UN1620 Lead cyanide is a white to yellowish powder. It is slightly soluble in water and is gradually decomposed by water and very rapidly decom posed by acids to give off hydrogen cyanide, a flammable poison gas. It is toxic by skin absorption through open wounds, by ingestion, and by inhalation of dusts or hydrogen cyanide decomposition of the material. Toxic oxides of nitrogen are produced in fires involving this material. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use foam, carbon dioxide or dry chemical Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors H material not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Use water spray to knock-down vapors Keep material dry Personnel protection Avoid breathing vapors or dusts Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away ary material which may have contacted the body with copious amounts of water or soap and water Wear salt-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing LEAD FLUE DUST (FLUE DUST, POISONOUS) 4923360 POISON B NA2811 Lead flue dust is a greyish black powder. It is insoluble in water. It is loxic by inhalation (dust, etc.) and by ingestion. H material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical H material not Involved in fire Keep material out of water sources and sewers 308 Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material if contact with the material anticipated, wear full protective clothing LEAD FLUOBORATE 4944133 ORM-8 NA2291 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Lead fluoborate is a colorless crystalline solid. H is used in mate! plating and finishing, it is corrosive to aluminum. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use foam, carbon dioxide or dry chemical Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog If material not Involved in Are Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental conaideretlons--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates LEAD FLUORIDE 4944140 ORM-B NA2S11 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/4S4) Lead fluoride is a white crystalline solid. It is used in electronics and to make optical glasses. It is insoluble in water. It is non-combustible. It is corrosive to aluminum. H material Involved In Are Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) If material not Involved In Are Keep material out of water sources and sewers Build dikes lo contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1961 MCD 000010051 Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agricuftural lime (slaked lime), crushed limestone, or sodium bicarbonate Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates LEAD IODIDE 4966950 ORM-E NA2811 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Lead iodide is a yellow crystalline solid. It is used in printing and photography, to seed clouds and other uses, it is insoluble in water. It is non-combustible. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) If material not involved In fire Keep material out of water sources and sewers Build dikes to contain (low as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate If dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates LEAD NITRATE 4918726 OXIDIZER UN1469 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Lead nitrate is a white crystalline solid. The material is soluble in water. It is non-combustible but it will accelerate the burning of com bustible materials. If large quantities of the material are involved in the fire an explosion may result. Prolonged exposure of the material to fire or heat may result in an explosion. Toxic oxides of nitrogen are produced in fires involving this material. If material on fire or involved In fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible if material not on fire and not Invotved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material April 1981 Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates LEAD PEROXIDE, GROUND, DRY (LEAD PEROXIDE 4918779 OXIDIZER UN1872 Lead peroxide, ground, dry is a brown granular or powdered material. It is insoluble in water. It is non-combustible but it will accelerate the burning of combustible material. If material involved In fire Flood with water If material not Involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts Wear boots,- protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water LEAD PEROXIDE, PASTE (LEAD PEROXIDE) 4918780 OXIDIZER UNI 872 Lead peroxide, paste is a brown dough-like material. The usual liquid in the paste is water or acetic acid. It is insoluble in water. Lead peroxide itself is non combustible but it will accelerate the burning of combustible materials. If material Involved in fire Flood with water H material not involved In fire Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water LEAD STEARATE 4966960 ORM-E NA2811 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Lead stearate is a white powder. It is used as a corrosion inhibitor, as a dryer for paints, and for many other uses- it is slightly soluble in water. It will bum though it may take some effort to ignite. If material involved in fire Extinguish fire using agent suitable for type of surrounding lire (Material itself does not bum or bums with difficulty.) H material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Continued on next pape 309 MOD 000010052 Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire lighting water Environmental considerations'--water spill Neutralize with agricultural iime (slaked lime), crushed limestone, or sodium bicarbonate If dissolved, apply activated carbon at ten limes the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates LEAD SULFATE, SOLID (CONTAINING MORE THAN 4930237 3% FREE ACIO) CORROSIVE MATERIAL, ACIDIC UN1794 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Lead sulfate, solid (containing more than 3% free acid is a white wet- looking solid. The lead sulfate itself is insoluble in water. The sulfuric acid is soluble in water. The material is corrosive to metals and tissue. If material involved in fire Extinguish fire using agent suitable lor type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved in fire Keep material out of water sources and sewers Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear fun protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, loamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash, cement powder, sawdust or com mercial sorbents Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--sir spill Apply water spray or mist to knock down vapors LEAO SULFIDE 4966987 ORM-E NA2291 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Lead sulfide is a silvery metalic crystalline solid or black powder. It is used to make ceramics, in the electronic industry, and for other uses, it is insoluble in water, it is non-combustible. If material Involvad In fira Extinguish fire using agent suitable for type of surrounding lire (Material itself does not bum or bums with difficulty.) If material not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary 310 Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates LEAD SULPHATE, CRUDE (LEAD SULFATE) 4966970 ORM-E UNI 794 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Lead sulphate, crude is a white to grey crystalline solid. Refined it is used to make storage batteries, and as in certain paints as a pigment. It is slightly soluble in water. It is non-combustible. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) If material not Involved in fira Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or lire fighting water Environmental considerations--wtter spilt Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates LEAO SULPHATE, REFINED (LEAO SULFATE) 4966960 ORM-E UN1794 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Lead sulphate, refined is a white crystalline solid. It is used to make storage batteries and as a pigment in specialized paints. It is slightly soluble in water. H is non-combustible. If material involved in fire Extinguish fire using agent suitable lor type of surrounding fire (Material itself does not bum or bums with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1961 Men oo0l S3 Environmental consideration*--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate II dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped matenal with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates LEAD THIOCYANATE 4966256 ORM-E NA2291 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Lead thiocyanate is a white to yellow crystalline solid. It is used to make explosives, safety matches, and in dyeing. It is slightly soluble in water. It is non-combustible. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) If material not involved In fire Keep matenal out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental consideration*--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considaratlons--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates LEATHER BLEACH 4910222 FLAMMABLE LIQUID NA1142 Leather bleach is a commercial preparation which may contain a flammable solvent which has a flash point of lesa than 100 deg. F. The hazard is flammability. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of watsr may be ineffective Cool all affected container* with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical H material not on fir* end not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts of water or soap and water LEATHER BLEACH 4915222 COMBUSTIBLE LIQUID NA1142 Leather bleach is a commercial preparation which may contain a solvent having a flash point between 100 and 199 deg. F. The hazard is combustibility. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water LEATHER DRESSING 4910223 FLAMMABLE LIQUID NA1142 Leather dressing is a commercial preparation which may contain a flammable solvent. In this case the hazard is the flammability of the solvent. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical ft material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water LEATHER DRESSING 491S223 COMBUSTIBLE LIQUID NA1142 Leather dressing is a commercial preparation which may contain a solvent having a flash point between 100 and 199 deg. F. The hazard is combustibility. If material on fire or Involved In fire Do not extinguish fire unless flow can ba stopped Use water in flooding quantities as fog Solid str$am$ of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Continued on next page April 1981 HCD 000100S4 311 Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water LEWISITE (POISONOUS LIQUID, N.O.S.) 4920517 POISON A NA9035 Lewisite is a colorless liquid with a geranium-like oddr. It is colorless when pure but impurities will have the color ranging from brown to violet. It is toxic by inhalation and skin absorption. Contact with the skin will also cause severe burns. At concentrations below that at which one can detect the material by smell, it is irritating to the eyes and mucous membranes. It is slowly decomposed by water. It may only be shipped in cylinders. Prolonged exposure o< the cylinders to fire or heat may result in the violent rupturing and rocketing of the cylinders. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered LIGHTER FLUID 4910125 FLAMMABLE LIQUID UN1226 Lighter fluid is a clear colorless liquid with a petroleum like odor. It has a flash point o< less than 100 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved In fire Do not extinguish lire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 312 LIGNITE ASH. URANIUM BEARING (RADIOACTIVE 4926438 MATERIAL. LOW SPECIFIC ACTIVITY, (OR), LSA, N.O.S.) RADIOACTIVE MATERIAL UN2912 Lignite ash. uranium bearing, is a greyish to light tan colored solid. Radioactive materials emit certain rays that may be hazardous. These rays can be detected only by instruments. Exposure of humans to intense radiation may be harmful, whereas film may be damaged by radiation from relatively low concentrations. If material involved in fire Contact the local, state, or department of energy radiological re sponse team Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Cool all affected containers with flooding Quantities of water Apply water from as far a distance as possible If material not involved in fire Contact the local, state, or department of energy radiological re sponse team Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Keep upwind Avoid breathing fumes from burning material Wear full protective clothing Wear self-contained breathing apparatus Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water LIME SALTS, NEC (CORROSIVE SOUO, N.O.S.) 4935255 CORROSIVE MATERIAL. BASIC UN1759 Lime salts, nec are various calcium containing compounds having the property of being corrosive to either metals and/or tissue. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as log Apply water from as far a distance as possible If material not Involved In fire Keep material out of water sources and sewers Personnel protection Avoid bodily contact with foe material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted foe body with copious amounts of water or soap and water LINDANE (AGRICULTURAL INSECTICIDES, NEC, 4941151 LIQUID) ORM-A NA2761 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Lindane is a white to yellow liquid dissolved in a liquid carrier. It is used as a pesticide. It is a water emulsifiabie liquid. It can cause illness by inhalation, skin absorption and/or ingestion. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone: 900-424-9300. H material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary April 1981 MCD 000010055 Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb butk liquid with fly ash or cement powder Environmental considerations--water spill Use natural barriers or oil spill control booms to limit spril motion If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates LINDANE (AGRICULTURAL INSECTICIDES, NEC, OTHER THAN LIQUID) 4941152 ORM-A NA2761 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Lindane is a white to yellow solid. It is used as a pesticide. It is a wettable powder. It can cause illness by inhalation, skin absorption and/ or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424* 9300. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration LINDANE (INSECTICIDES, OTHER THAN 4941150 AGRICULTURAL, NEC) ORM-A NA2761 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-1/0.454) Lindane is a white to yellow solid or the solid dissolved in a liquid carrier. It is used as a pesticide. It is a wettable powder or water emul- sifiable liquid. It can cause illness by inhalation, skin absorption and/or ingestion. In case of damage to, or leaking from containers of this ma terial contact the pesticide safety team network. Telephone; 900-424- 9300. If materiel involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) H material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in ram or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom Use mechanical dredges or lifts to remove immobilized masses o( pollutants and precipitates if dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration LIQUEFIED NONFLAMMABLE GASES (CHARGED 4904840 WITH NITROGEN, CARBON DIOXIDE, OR AIR) NONFLAMMABLE GAS NA1058 Liquefied nonflammable gases are liquids other than those classified as flammable, corrosive or poisonous which are charged with nitrogen, carbon dioxide, or air for the purpose of expelling the liquid from the container. In the case of aerosols the violent rupture and rocketing ol the container is possible if the container is exposed to fire or heat, if material Involved in fire Extinguish fire using agent suitable for type of surrounding (ire (Material itself does not bum or bums with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible if material not involved in fire Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Wear protective gloves and goggles Do not handle broken packages without protective equipment LIQUEFIED PETROLEUM GAS 4905752 FLAMMABLE GAS UN1075 Liquefied petroleum gas is a colorless gas with a faint petroleum like odor shipped as a liquid under its vapor pressure. For transportation it may be stenched. Contact with the liquid can cause frostbite. It Is easily ignited, its vapor is heavier than air and a Name can flash back to the source of leak very easily. This leak may be either a liquid or vapor leak. It can asphyxiate by the displacement oi air. Under fire conditions the cylinders can rupture and rocket. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with Hooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, dames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Continued on noxt pogo April 1981 MCD 000010056 313 Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet If material leaking (not on fire), downwind evacuation must be considered LIQUEFIED PETROLEUM GAS (PINTSCH GAS) 4905780 FLAMMABLE GAS UN1075 Pintsch gas is a colorless gas with a petroleum*like odor. It is shipped as a liquefied gas under its vapor pressure. For transportation it may be stenched- Contact with the liquid can cause frostbite. It is easily ignited. Its vapor is heavier than air and a flame can flash back to the source of leak very easily. This leak can be either a liquid or vapor leak. It can asphyxiate by the displacement of air. Under fire conditions the cylinders or tank cars may violently rupture and rocket. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt (o stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution Evacuation if fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet If material leaking (not on fire), downwind evacuation must be considered LIQUORS, ALCOHOUC, NEC (ALCOHOLIC 4910225 BEVERAGE) FLAMMABLE LIQUID UN1170 Alcoholic liquors are beverages containing alcohol. They have suffi cient alcohol in them for the flash point to ba below 100 deg. F. They are about the same density as water and soluble in water. The alcohol vapors are heavier than air. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If materiel not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to disperse vapors and dilute standing pools of liquid 314 Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water LIQUORS, ALCOHOLIC, NEC (ALCOHOLIC 4915225 BEVERAGE) COMBUSTIBLE UQUIO UN1170 Alcoholic liquors are beverages containing alcohol. They have suffi cient alcohol in them for the flash point to be between 100 and 199 deg. F. They are about the same density as water and soluble in water. The alcohol vapors are heavier than air. If material on fire or involved In fire Do not extinguish tire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If materiel not on fire end not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which, may have contacted the body with copious amounts of water or soap and water LITHIUM ACETYUOE-ETHYLENE DIAMINE COMPLEX 4916415 FLAMMABLE SOLID NA2813 WATER REACTIVE Lithium acetytide-ethylene diamine complex is a crystalline solid. It can absorb moisture from the air and spontaneously heat and ignite. It reacts with water to form lithium hydroxide, a corrosive material, and acetylene, a flammable gas. The heat of this reaction may be sufficient to ignite the acetylene. If material on fire or involved In fire Do not use water Use graphite, soda ash. powdered sodium chloride, or suitable dry powder If material not on fire and not Involved in fire Do not use water Keep sparks, flames, aid other sources of ignition away Keep material out of water sources and sewers Keep material dry Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Approach fire with caution Wear self-contained breathing apparatus when fighting fires involv ing this material April 1961 MCD 000010057 LITHIUM ALUMINUM HYDRIDE 4916420 FLAMMABLE SOLID UN1410 WATER REACTIVE Lithium aluminum hydride is a light greyish white powder, it is used 3 make other chemicals, as a polymerization catalyst, as a hydrogen source, and as a propellant. If spread out over a large flat combustible surface friction may be sufficient to cause ignition. It reacts with water to form lithium hydroxide, a corrosive material, aluminum hydroxide and hydrogen, a flammable gas. The heat of this reaction may be sufficient to ignite the hydrogen. The lithium and aluminum hydroxides are cor rosive. It may react violently with heat or oxidizing materials. If material on fire or Involved in fire Do not use water Use graphite, soda ash. powdered sodium chloride, or suitable dry powder It material not on fire and not Involved In fire Do not use water Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Do not attempt to sweep up dry material Personnel protection Avoid breathing dusts, and fumes from burning material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water LITHIUM ALUMINUM HYDRIDE, ETHEREAL 4908216 FLAMMABLE LIQUID UN1411 Lithium aluminum hydride, ethereal is the solution of lithium aluminum fydride in an ether solvent, it is used lo make other chemicals, and as a catalyst in making plastics. It has a flash point of less than 20 deg. F. It reacts with water giving off hydrogen, a flammable gas. The heat of this reaction may be sufficient to ignite the hydrogen. It can react violently if in contact with oxidizers. If the solvent evaporates the 90lid remaining is a white powder. If subject to very light friction, a fire is very likely to result. The solvent vapors are heavier than air. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Do not use water Use "alcohol'' foam, carbon dioxide or dry chemical Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible H material not on Are and not Involved In fire Keep sparks, flames, and other sources of Ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Do not use water Do not attempt to sweep up dry material Personnel protection Avoid breathing fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered April 1981 LITHIUM AMIDE, POWDERED 4916722 FLAMMABLE SOLID UN1412 Lithium amide is a white to greyish crystalline solid with an ammonia like odor, it is used to make other chemicals. It reacts with water to form lithium hydroxide a corrosive material, and ammonia, a nonflammable gas. the heat from this decomposition may be sufficient to ignite sur rounding combustible materials. If material on fire or involved In fire Do not use water Use graphite, soda ash or powdered sodium chloride If material not on fire and not Involved in fire Do not use water Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing LITHIUM BOROHYDRIOE 4916421 FLAMMABLE SOLID UNI 413 WATER REACTIVE Lithium borohydride is a white to greyish crystalline powder. It is de composed by water to form lithium hydroxide, a corrosive material, and hydrogen, a flammable gas. The heat of this reaction may be sufficient to ignite the hydrogen. The material itself is easily Ignited and bums vigorously once ignited, tf material on fire or Involved in fire Do not use water Use graphite, soda ash, powdered sodium chloride, or suitable dry powder If material not on fire and not involved in fire Do not use water Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Do not attempt to sweep up dry material Personnel protection Avoid breathing dusts, and fumes from burning material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water LITHIUM CHROMATE 4963720 ORM-E NA9134 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Lithium chromate is a yellow crystalline solid. It is used as a corrosion inhibtor and in the manufacture of other chemicals. It is soluble in water. It is non-combustible. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itseH does not bum or bums with difficulty.) If material not Involved tn fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Continued on next page 315 MCD 000010058 Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Add soda ash Adjust ph to neutral (ph*7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates LITHIUM FERRO SILICON 4916422 FLAMMABLE SOLID UN2630 WATER REACTIVE Lithium ferro silicon is in the form of crystalline metallic lumps or powder It reacts with water to form lithium hydroxide, a corrosive ma terial and hydrogen, a flammable gas. The heat of the reaction may be sufficient to ignite the hydrogen. If material on fire or involved In fire Do not use water Do not use carbon dioxide Use suitable dry powder Use dry chemical or carbon dioxide If material not on fire and not Involved in fire Do not use water Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Personnel protection Avoid breathing dusts, and fumes from burning material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water LITHIUM HYDRIDE 4916424 FLAMMABLE SOUD UN1414 WATER REACTIVE Lithium hydride is a greyish white granular powder. It reacts with water to form lithium hydroxide, a corrosive material, and hydrogen, a flam* mable gas. The heat of this reaction may be sufficient to ignite the hydrogen. It may react violently with heat or oxidizing materials. K material on fire or Involved In fire Do not use water Do not use dry chemical or carbon dioxide Use graphite, soda ash or powdered sodium chloride If material not on fire and not Involved In fire Do not use water Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Personnel protection Avoid breathing dusts, and fumes from burning material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 316 LITHIUM HYDRIDE IN FUSED SOLID FORM 4916425 FLAMMABLE SOLID UN2805 WATER REACTIVE Lithium hydride in fused solid form exists as greyish white lumps, it is used to make other chemicals, as a hydrogen source, and for other uses. It reacts with water to form lithium hydroxide, a corrosive material and hydrogen a flammable gas. The heat from this decomposition may be sufficient to ignite the hydrogen. It may react violently with heat or oxidizing materials. If material on fire or involved In fire Do not use water Do not use dry chemical or carbon dioxide Use graphite, soda ash or powdered sodium chloride If material not on fire and not involved in fire Do not use water Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Personnel protection Avoid breathing dusts, and fumes from burning material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water LITHIUM HYPOCHLORITE COMPOUND. DRY 4916727 CONTAINING MORE THAN 39 PERCENT AVAILABLE CHLORINE OXIDIZER UN1471 Lithium hypochlorite compound, dry is a white granular solid or tab lets compressed from the granules with an odor of chlorine, it is used as a dry bleach, tt is noncombustible but it will accelerate the burning of combustible material. It is decomposed by water with the evolution of chlorine gas and heat. Prolonged exposure of the material to fire or heat may result in the vigorous decomposition of the material and the rupture of its container. Material containing less than 39 percent available chlorine will undergo reactions described above though it may take longer to initiate and the resulting reactions may not be as vigorous. If material on fire or involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet LITHIUM METAL 4916426 FLAMMABLE SOUD UN1415 WATER REACTIVE Lithium metal is a soft silvery metal though normally greyish white due to oxide formation. It reacts with water to form lithium hydroxide a cor rosive material, and hydrogen a flammable gas. The heat of this reaction may be sufficient to ignite the hydrogen. If fithium metal is heated to its melting point spontaneous ignition is likely. April 1981 mcd 00loo59 If material on fire or Involved In fire Do not use water Do not use carton dioxide Use graphite, soda ash. powdered sodium chloride, or suitable dry powder If material not on fire and not Involved in fire Do not use water Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Personnel protection Avoid breathing dusts, and fumes from burning material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water LITHIUM METAL. IN CARTRIDGES 4916429 FLAMMABLE SOLID UN1415 WATER REACTIVE Lithium metal in cartridges is a very limited quantity of the soft silvery metal sealed in a copper tube overpacked in a wooden box. Lithium reacts with water to form lithium hydroxide, a corrosive material and hydrogen a flammable gas. The heat of this reaction may be sufficient to ignite the hydrogen. If material on fire or involved in fire Do not use water Do not use carbon dioxide Use graphite, soda ash, powdered sodium chloride, or suitable dry powder tf material not on fire and not Involved In fire Oo not use water Keep sparks, (lames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Personnel protection Avoid breathing dusts, and fumes from burning material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water LITHIUM NITRIOE . 4916432 FLAMMABLE SOUD UN2806 WATER REACTIVE Lithium nitride is a reddish brown powder, it is used in metallurgy, and to make other chemicals. H is easily ignited and bums slowly with intense heat. Moisture intensifies the fire. It reacts with water to form lithium hydroxide, a corrosive material and ammonia, a nonflammable gas. The heat of the reaction may be sufficient to ignite nearby combustible ma terials or the material itself. If materiel on fire or involved in Are Do not use water Do not use dry chemical or carbon dioxide Use graphite, soda ash or powdered sodium chloride If material not on fire and not involved in fire Do not use water Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers Keep material dry Personnel protection Avoid breathing dusts, and fumes from burning material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water LITHIUM PEROXIDE 4918520 OXIDIZER, CORROSIVE UN1472 Lithium peroxide is a white to light yellow granular solid. It is soluble in water. Contaminants can cause the solution to decompose to a lithium hydroxide solution which is corrosive. The material itself ic -in-com bustible but It accelerates the burning of combustible material, rolonged exposure of the material and/or its containers to fire or heal may result in a vigorous chemical reaction and the resulting rupture of the containers. If material on fire or involved in fire Use suitable dry powder If material not on fire and not Involved In fire Keep sparks, flames, and other sources o< ignition away Keep matenal out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Approach lire with caution Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet LITHIUM SILICON 4916431 FLAMMABLE SOUD UN1417 WATER REACTIVE Lithium silicon is a black, lustrous powder to lump material with a sharp irritating odor, it reacts with water to form lithium hydroxide a corrosive material and hydrogen, a flammable gas. The heat of this reaction may be sufficient to ignite the hydrogen. If material on fire or involved in fire Do not use water Do not use carbon dioxide Use graphite, soda ash, powdered sodium chloride, or suitable dry powder tf material not on fire and not Involved In fire Do not use water Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Personnel protection Avoid breathing dusts, and fumes from burning material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water LONDON PURPLE, SOUO 4923237 POISON B UNI 621 London purple, solid consists of a mixture of arsenic trioxide, anaine. lime and ferrous oxide. It is insoluble in water. It is toxic by inhalation (dust, etc.) and by ingestion. If material on fire or Involved In fire Extinguish fire using agent suitable lor type ol surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical tf material not on fire and not Involved In fir# Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Continued on next peg* April 1981 MCD 00010060 317 Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing LOW EXPLOSIVE 4901705 CLASS A EXPLOSIVE Low explosive is a solid material which can be made lo bum very vigorously by means of a spark or flame. Upon prolonged exposure to fire containers of the material can explode. If material on fire or Involved in fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let bum If material not on fire and not involved in fire Keep sparks, (lames, and other sources of ignition away Keep spilled material wet Wet spilled material before picking it up Do not attempt to sweep up dry material Personnel protection Avoid breathing dusts, and fumes from burning material Wear protective gloves and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 5000 feet LUBRICATING OIL, NEC (COMBUSTIBLE UQUIO, 4915229 N.O.S.) COMBUSTIBLE LIQUID NA1993 Lubricating oil, nec, is a variable colored liquid with a petroleum-like odor. It has a flash point between 100 and 200 deg. F. It is lighter than water and insoluble in water, its vapors are heavier than air. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical H material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 316 LUBRICATING SYSTEM SIGHT FEED FLUID 4915228 (COMBUSTIBLE UQUIO, N.O.S.) COMBUSTIBLE LIQUID NA1993 Lubricating system sight feed fluid is a variable colored liquid with a petroleum-like odor. It has a flash point between 100 and 200 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as log Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water LUTiDENE (FLAMMABLE UQUID,N.O.S.) 4909181 FLAMMABLE LIQUID UNI 993 Lutidene is a colorless liquid having a peppermint odor. If is used to make other chemicals. It has a flash point of 92 deg. F. It is lighter than water and soluble in water. Its vapors are heavier than air. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as log Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical K material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak H without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material if contact with the material anticipated, wear full protective clothing LYE, CONCENTRATED. NEC (SODIUM HYDROXIDE, 4935262 DRY, SOLID, FLAKE, BEAD OR GRANULAR) CORROSIVE MATERIAL, BASIC UN1823 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Lye. concentrated, nec is a white solid. It is soluble in water with release of heat It absorbs moisture from the air and dissolves in it. It is corrosive to metals and tissue. April 1981 MCD 000010061 tf material involved in fire Extinguish fire using agent suitable (or type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Apply water from as far a distance as possible If material not Involved in fire Keep material out of water sources and sewers Personnel protection Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle proken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with dilute acid or removable strong aod MAGNESIUM ALUMINUM PHOSPHIDE 4916440 FLAMMABLE SOLID UN1419 WATER REACTIVE Magnesium aluminum phosphide is a crystalline or a grey lump solid. It reacts with water to form magnesium and aluminum hydroxides and phosphine a flammable poisonous gas. Phosphine will normally ignite spontaneously in contact with air. ff material on fire or Involved In fire Do not use water Use dry chemical or carbon dioxide K material not on fire and not Involved In Are Do not use water Keep sparks, flames, and other sources of igrfition away Keep material out of water sources and sewers Keep material dry Personnel protection Avoid breathing dusts, and fumes from burning material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material MAGNESIUM ARSENATE, SOLID 4923238 POISON B UN1622 Magnesium arsenate, solid is a white powder. It is insoluble in water. It is toxic by inhalation (dust, etc.) and by ingestion. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material Itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical ff material not Involved In fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear ful protective clothing April 1981 MAGNESIUM NITRATE 4918728 OXIDIZER UNI 474 Magnesium nitrate is a white crystalline solid, it is used in pyrotechnics, it absorbs moisture from the air and dissolves in it. The material is soluble in water. It is noncombustible but it will accelerate the burning of com bustible materials. If large quantities of the material are involved in the fire or the combustible material is finely divided an explosion may result. Prolonged exposure of the material to lire or heat may result in an explosion. Toxic oxides of nitrogen are produced in fires involving this matenal. If material on fire or Involved In fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggies Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting tires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet MAGNESIUM PERCHLORATE 4918729 OXIOIZER UNI 475 Magnesium perchlorate is a white crystalline solid, it is used as a drying agent and as an oxidizing agent. It strongly absorbs water from air and dissolves in it. The material is soluble in water. It is noncom- bustible but It will accelerate the burning of combustible materials. If targe quantities of the material are involved in the fire or the combustible material is finely divided an explosion may result. Prolonged exposure of the material to fire or heat may result in an explosion. H material on fire or involved In fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible H material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable evacuate for a radius of 2500 feet MAGNESIUM PEROXIDE. SOLID 4918730 OXIDIZER UN1476 Magnesium peroxide is a whits powder, it is used in medicine, and as a bleaching agent. It is insoluble in water and slowly decomposed by water. It is noncombustible but it will accelerate the burning of com bustible material, if the combustible material is finely divided the mixture may be explosive. Mixtures of combustibls material and the peroxide can be ignited by friction or contact with moisture. H material on fire or Involved In fire Flood with water Cool ail affected containers with flooding quantities of water Apply water from as tar a distance as possible Continued on next page Hc:> OQox 00B2 319 It material not on Are and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation It tire becomes uncontrollable--evacuate for a radius ot 2500 feet MAGNESIUM SCRAP (BORINGS, CLIPPINGS, 4916436 SHAVINGS. SHEET, TURNINGS, OR SCALPINGS) FLAMMABLE SOUD NA1S69 WATER REACTIVE Magnesium scrap is a silvery colored metal. The more finely divided forms react with water to liberate hydrogen, a flammable gas. though not as vigorously as lithium or sodium. The thinner pieces are easily ignited and bum with an intense white flame. If material on fire or Involved In fire Do not use water Use graphite, soda ash, powdered sodium chloride, or suitable dry powder If material not on fire and not Involved In fire Do not use water Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Personnel protection Wear boots, protective gloves, and goggles MAGNESIUM, METAL (POWDERED, PELLETS, 4916435 TURNINGS OR RIBBONS) FLAMMABLE SOUD UN1669 WATER REACTIVE Magnesium, metal (powdered, pellets, turnings, or ribbons) is a light silvery colored metal. The more finely divided material reacts with water to liberate hydrogen, a flammable gas. though this reaction is not as vigorous as that of sodium or lithium with water. In finely divided forms it is easily ignited and bums with an intense white flame. If material on fire or Involved In fire Do not use water Use graphite, soda ash, powdered sodium chloride, or suitable dry powder If materiel notion fire and not Involvad In flra Do not use water Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Do not attempt to sweep up dry material Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 320 MALATHION 4941156 ORM-A NA2763 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-10/4.54) Malathion is a yellow liquid. It is used as an insecticide. It is com bustible though it may take some effort to ignite. It is slightly soluble in water. It can cause illness by inhalation, skin absorption and/or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone. 800-424-9300. It weighs 10.3 pounds per gallon. If material involved In fire Extinguish fire using agent suitable lor type of surrounding fire (Material itself does not burn or bums with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface how using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of toppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates MALEIC ACID ORM-A 4941155 NA2215 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Maleic add is a coiortess crystaline solid having a faint odor. It is used to make other chemicals and tor dyeing and finishing naturally occurring fibers. It is combustible though it may take some effort to ignite. lt soluble in water. If materiel on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use MatoohoT foam, carbon dioxide or dry chemical If materiel not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors or dusts Wear boots, protective gloves, and goggles Oo not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill if dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of poflutants and precipitates April 1961 Mcd 00100S3 MALEIC ANHYDRIDE 4941161 ORM-A UN2215 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RD-5000/2270) Maleic anhydride is a colorless crystaline solid. It is used to make paints and plastics and other chemicals. It is combustible though it may take some effort to ignite. It is slowly decomposed by water to give maleic acid, another orm-a. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in Hooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors or dusts Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spHI If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates MANGANESE RESINATE, (FLAMMABLE SOLID, 4916766 N.O.S.) FLAMMABLE SOLID UN1325 Manganese resinate ranges from a dark brown-black solid mass to a fight tan powder, it may spontaneously heat in the presence of air or moisture. This heat may be sufficient to ignite surrounding combustible materials. It is insoluble in water. If material on fire or involved in fire Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not on fir# and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Wear boots, protective gloves, and goggles Oo not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water MATCHES, SAFETY (BOOK, CARD OR STRIKE ON 4917356 BOX) FLAMMABLE SOLID UN1944 Matches, safety are strips of cardboard held together as an assembly, or wooden sticks having their ends dipped with a pyrotechnic mixture and requiring a specially treated surface for striking to cause ignition. If material on fire or involved in fire Flood with water If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing fumes from burning material April 1981 MATCHES, STRIKE ANYWHERE 4917336 FLAMMABLE SOLID UN1331 Matches, strike anywhere are wooden sticks with an end coated with a pyrotechnic composition that may be ignited by friction with almost any dry surface. Fires occurring in packages of these matches caused by internal friction between the matches or impact are usually contained in the package if it is not broken. If the matches have gotten wet and dried out they are more readily ignited. If material on fire or involved in fire Flood with water II material not on fir* and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing fumes from burning material MEDICINES, N.O.S. 4917378 FLAMMABLE SOLID NA132S Medicines, n.o.s. is the proper shipping name of any solid material, other than one classed as an explosive, or specifically listed by name in the list of hazardous materials which is liable under conditions incident to transportation to cause fires through friction, absorption of moisture, spontaneous chemical changes as a result of retained heat from the manufacturing or processing of the solid, or which can be readily ignited by external sparks or flame and when so ignited bums vigorously and persistently. Try to ascertain the exact name of the material. It material on fire or involved In fire Extinguish fire using agent suitable for type of fire If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Build dikes to contain Row as necessary Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water MEDICINES, N.O.S. 4918412 OXIDIZER NA1479 Medicines, n.o.s. are various materials which have the property of accelerating the burning of combustible material. These materials may not bum by themselves. Prolonged exposure of these materials and/or their containers to fire orheat may result in an explosion. These materials may only be shipped in containers of 55 gallon capacity or less, tf material on fire or involved in fire Flood with water Cool aK affected containers with flooding quantities of water Apply water from as far a distance as possible tf material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Approach fire with caution Evacuation If fire becomes uncontroiabie evacuate for a radius of 1500 feet 321 0 Oo^o,6< MEDICINES, N.O.S. 4910193 FLAMMABLE UQUIO NA1993 Medicines, n.o.a. are those medicines with the property of having a flash point of less than 100 deg. F. They are generally lighter than water and soluble in water. Their vapors are heavier than air If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool alt affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain How as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water MEDICINES, N.O.S. 4915193 COMBUSTIBLE LIQUID UN1851 Medicines, n.o.s. are those medicines with the property of having a flash point between 100 and 199 deg. F. They are generally lighter than water and soluble in water. Their vapors are heavier than air. H material on Are or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires Involv ing this material If contact with the material anticipated, wear full protective clothing MEDICINES. N.O.S. (LIQUID) 4921426 POISON B NA2810 Medicines, n.o.s. (liquid) are liquids or a solid dissolved in a liquid having the property of being toxic by Ingestion, inhalation, or skin ab sorption. The liquid or solution may or may not bum depending on the nature of the material and/or the solvent of the solution. If material on fire or involved In fire Do not extinguish tire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool alt affected containers with flooding quantities of water Appfy water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical tf material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation if material leaking (not on tire), downwind evacuation must be considered MEDICINES, N.O.S. (SOUD) 4921491 POISON B NA2811 Medicines, n.o.s. (solid) are pure materials or mixtures of two or more solids or a liquid absorbed on a dry carrier. It has the property of being toxic by ingestion, inhalation (vapor dust, etc) or skin absorption. If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fira Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing MEDICINES, N.O.&, UOUID 4936583 CORROSIVE MATERIAL UN1851 Medicines, n.o.s., liquid is the proper shipping name for various liquids having the property of being corrosive to steel or tissue, it may either be a simpie liquid material or a soM dissolved in a solvent, it may be combustible though requiring some effort to ignite. They may or may not be water soluble. tf material on fire or Involved in Are Extinguish lire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with Hooding quantities of water Appfy water from as far a distance as possible SoM streams of water may be ineffective Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other souroes of ignition away Keep material out of water sources and sewers Buid dikes to contain flow as necessary 322 MCD 000010065 April 1981 Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing MEDICINES, N.O.S., SOLID 4936584 CORROSIVE MATERIAL UN1651 Medicines, n.o.s., solid is the proper shipping name forvarious colored solids having the property of being corrosive to tissue. They may or may not be water soluble. If material on fire or Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing MEMTETRAHYDROPHTHALIC ANHYDRIDE 4931441 CORROSIVE MATERIAL NA1760 Memtetrahydrophthalic anhydride is a colorless to light yellow liquid. It is used to make plastics. It is soluble in water and decomposed by water to tetrahydrophthaiic add, which is also water soluble, with release of heat, it is corrosive to skin. If material on fire or Involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as posstte Use "alcohol" foam, carbon dioxide or dry chemical Use water spray to absorb vapors H material not on fire end not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water if contact with the material anticipated, wear full protective clothing April 1981 MERCAPTAN MIXTURE, ALIPHATIC 4913120 COMBUSTIBLE LIQUID NA1228 Mercaptan mixture, aliphatic is a dear colorless to light yellow liquid with a very offensive odor. It has a flash point between 100 and 199 deg. F. It is lighter than water and very slightly soluble in water. Its vapors are heavier than air. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical H material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material MERCAPTAN MIXTURE, ALIPHATIC 4909220 FLAMMABLE LIQUID NA1228 Mercaptan mixture, aliphatic is a clear colorless to light yellow liquid with a very offensive odor. It has a flash point of less than 100 deg.f. It is lighter than water and very slightly soluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cod ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out ol water sources and sewers Buikf dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear seif-contained breathing apparatus when fighting fires involv ing this material MERCAPTOOIMETHUR 4962145 ORM-E NA2757 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100/45.4) Mercaptodimethur is a white crystalline powder. It is used as a pes ticide. It is a wettable powder or water emulsifiable liquid. It can cause illness by inhalation, skin absorption and/or ingestion. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300. Continued on next page 323 Oo 0'*o0. % If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) If material not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates MERCURIC ACETATE 4923241 POISON B UN1629 Mercuric acetate is a white crystalline solid with a vinegar like odor. It is soluble in water and is decomposed by water to form 9 white insoluble precipitate. It is toxic by inhalation (dust, etc.) and by ingestion. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and Fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing MERCURIC BENZOATE, SOUD 4923243 POISON B UNI 631 Mercuric benzoate, solid is a white crystalline solid. It is slightly soluble in water. It is toxic by inhalation (dust, etc.) and by ingestion. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not Involved In fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material ff contact with the material anticipated, wear full protective clothing 324 MERCURIC BROMIDE, SOLID 4923244 POISON B UN1634 Mercuric bromide, solid is a white crystalline solid. It is very slightly soluble in water. It is toxic by inhalation (dust, etc.) and by ingestion. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material U contact with the material anticipated, wear lull protective clothing MERCURIC CHLORIOE 4923245 POISON B UN1624 Mercuric chloride is a white crystalline solid. It is soluble in water. It is corrosive to the mucous membranes. It is toxic by inhalation (dust etc.) and ingestion. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itsalf does not bum or bums with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical H material not Involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when lighting fires involv ing this material If contact with the material anticipated, wear full protective clothing MERCURIC CHLORIDE (MERCURIC CHLORIDE AND 4923271 CHARCOAL CATALYST, SPENT) POISON B UN 1624 Mercuric chloride and charcoal catalyst, spent is mercuric chloride deposited on a charcoal carrier base. The mercuric chloride is soluble in water. It is corrosive to the mucous membranes. It is toxic by ingestion, and inhalation (dusts, etc). If material on fire or involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itsell does not bum or bums with difficulty.) Use water in flooding quantities as fog Usa foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Apr* 1961 \00^ 000 Personnel protection Avoid breathing dusts, and fumes from burring material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing MERCURIC CYANIDE. SOLID 4923246 POISON B UNI 636 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Mercuric cyanide solid is a white crystalline solid. It is slightly soluble in water. It is gradually decomposed by water and rapidly decomposed by acids to give off hydrogen cyanide, a flammable poison gas. It is toxic by inhalation (dust, and the hydrogen cyanide from decomposition) and by ingestion. Toxic oxides Of nitrogen are produced in fires involving this material. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved In fire Keep material out of water sources and sewers Personnel protection Avoid breathing vapors or dusts Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Add caustic soda If dissolved, apply sodium sulfide solution to precipitate heavy metals Add calcium hypochlorite If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates MERCURIC IODIOE, SOUD 4923247 POISON B UNI 638 Mercuric iodide, solid is a red crystalline solid. It is very slightly soluble in water. It is toxic by inhalation (dusts, etc) and by ingestion. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved In fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind April 1981 Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material if contact with the material anticipated, wear full protective clothing MERCURIC IODIDE, SOLUTION 4923249 POISON B UN1636 Mercuric iodide, solution is a red liquid, it is slightly soluble in water. It is toxic by ingestion. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as tog Use loam, carbon dioxide or dry chemical If material not involved In fire Keep matenal out of water sources and sewers Personnel protection Avoid breathing vapors or dusts Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing MERCURIC NITRATE 4918769 OXIDIZER UN162S ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-10/4.54) Mercuric nitrate is a while crystalline solid. It is used to make other chemicals and in medicine, it is soluble in water, it is non-combustible, but it will accelerate the burning of combustible materials. If large quan tities are involved in a fire or the combustible material is finely divided, an explosion may result Prolonged exposure to lire or heat may result in an explosion. Toxic oxides ol nitrogen are produced in fires involving this material. If material on fira or involved In Are Rood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable---evacuate for a radius of 2500 feet Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Continued on next page MCD 000010068 325 Environmental considerations--water spill Add caustic soda If dissolved, apply sodium sulfide solution to precipitate heavy metals If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Allow to aerate MERCURIC OLEATE, SOLID 4923250 POISON B UNI640 Mercuric oleate, solid is a yellowish-brown grease-like solid. It is in soluble in water. It is toxic by ingestion. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not Involved In fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing MERCURIC OXIDE, SOLID 4923251 POISON B UN1641 Mercuric oxide, solid is a red-orange powder. It is Insoluble in water. It is toxic by inhalation (dust etc.) and by ingestion, if material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities, as fog Use foam, carbon dioxide or dry chemical If material not involved in Are Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus whan fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing MERCURIC OXYCYANIDE, SOUD (DESENSITIZED) 4923253 POISON B UN1642 Mercuric oxycyanide, solid is a white crystalline solid, it is used in medicine. It is soluble in water. It can explode on prolonged exposure to fire or heat, it decomposes on contact with acid to give off hydrogen cyanide, a flammable poison gas. It is toxic by inhalation (dust and hydrogen cyanide from decomposition) and by ingestion. 326 If metertei Involved In Are Extinguish fire using agent suitable lor type of surrounding fire (Material itself does not burn or bums with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved In fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing MERCURIC SALICYLATE, SOUD 49232S5 POISON B UNI 644 Mercuric salicylate, solid is a white powder with a yellow or pink tint. It is insoluble in water. It is toxic by inhalation (dust, etc.) and by ingestion. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not Involved In fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing MERCURIC SUBSULFATE, SOUD 4923256 POISON B NA2025 Mercuric subsulfate, solid is a lemon yellow powder or a yellow scaley material. It is insoluble in water. It is toxic by inhalation (dust, etc.) and by ingestion. If material Involved In fire Extinguish fire using agent suitable for type of surrounding (ire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved In fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing April 1961 MCD 000010069 MERCURIC SULFATE, SOLID 4923257 POISON B UN1845 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-10/4.54) Mercuric sulfate, solid is a white crystalline powder, it is used in med icine, for gold and silver extraction, and to make other mercury com pounds. It is decomposed by water to yellow mercuric subsulfate and free sulfuric acid, a corrosive material. It is toxic by inhalation (dust) and by ingestion. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical It material not involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Oig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Add caustic soda If dissolved, apply sodium sulfide solution to precipitate heavy metals If dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Allow to aerate Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--water split Add caustic soda if dissolved, apply sodium sulfide solution to precipitate heavy metals If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Allow to aerate Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates MERCURIC-AMMONIUM CHLORIDE, SOLIO 4923242 POISON B UN1630 Mercuric-ammonium chloride is a white crystalline solid. It is soluble in water. It is corrosive to the mucous membranes. It is toxic by inhalation (dust, etc.) and by ingestion. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water in Hooding quantities as fog Use foam, carbon dioxide or dry chemical If material not Involved In fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing MERCURIC SULFO CYANATE, SOUD (OR) MERCURIC 4923258 THIOCYANATE POISON B UN1848 ENVIRONMENTALLY HAZAROOUS SUBSTANCE (RQ-10/4.54) Mercuric sulfo cyanate is a white crystalline powder. It is very slightly soluble in water. When heated or burned tt expands to many times in volume. It is toxic by inhalation (dust) and by ingestion. If material involved in fire Extinguish fire using agent suitable for type of surrounding (ire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical if materiel not Involved in Are Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodify contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted (he body with copious amounts of water or soap and water Wear self-contained breathing apparatus when lighting fires involv ing this material It contact with the material anticipated, wear fun protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water April 1981 MCI) 000010070 MERCURIC-POTASSIUM CYANIDE, SOUD 4923254 POISON B UN1526 Mercuric--potassium cyanide solid is a colorless crystalline solid. It is soluble in water. It is rapidly decomposed by adds to give off hydrogen cyanide, a flammable poison gas. It is toxic by inhalation (dust, and the hydrogen cyanide from decomposition) and by ingestion. Toxic oxides of nitrogen are produced in fires involving this material, tf material Involved In Are Extinguish fire using agent suitable for type of surrounding fire (Material Kseif does not bum or bums with difficulty.) Use foam, carbon dioxide or dry chemical Do not use water on material itself if large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors If material not Involved In Are Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Do not use water on material itself Personnel protection Avoid breathing vapors or dusts Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing 327 MERCURIC-POTASSIUM IODIOE, SOLIO 4923272 POISON B UN1643 Mecuric-potassium iodide, solid is a yellow crystalline solid. It absorbs water from the air and dissolves in it. It is soluble in water. It is toxic by ingestion. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved in fire Keep material out oi water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting tires involv ing this material If contact with the material anticipated, wear full protective clothing MERCUROL OR MERCURY NUCLEATE, SOLID 4923259 POISON B UNI 639 Mercurol is a brown powder containing a mercury compound. It is soluble m water. It is toxic by inhalation (vapor, dust, etc) and by skin absorption. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved In fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective dothing MERCUROUS ACETATE, SOLID 4923266 POISON B UN1629 Mercurous acetate, solid is a white crystalline solid with a vinegar Nke odor. It is soluble in water and is decomposed to white insoluble pre cipitate. it is toxic by ingestion and by inhalation (dusts, etc), tf material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved In fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear lull protective clothing MERCUROUS BROMIDE. SOLID 4923260 POISON B UN1634 Mercurous bromide, solid is a white powder darkening on exposure to light. It is insoluble In water, it is toxic by inhalation (dust, etc) and by ingestion. If malarial involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not Involved In fire Keep material out ol water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material tf contact with the material anticipated, wear full protective clothing MERCUROUS GLUCONATE, SOUD 4923261 POISON B UN1637 Mercurous gluconate, solid is a white powder. It is slightly soluble in water. It is toxic by inhalation (dust, etc.) and by ingestion, tf material Involved In fire Extinguish fire using agent suitable lor type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not Involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material tf contact with the material anticipated, wear full protective clothing MERCUROUS IODIDE, SOLID 4923262 POISON B UNI636 Mercurous iodide, solid is a tight yellow powder. It is insoluble in water. It is toxic by inhalation (dust, etc.) and by ingestion. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical tf material not Involved In fire Keep material out of water sources and sewers 326 April 1961 MCD 000010071 Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this matenal II contact with the matenal anticipated, wear full protective clothing Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing MERCUROUS NITRATE. SOLID 4918752 OXIDIZER, POISONOUS UN1627 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-10/4.S4) Mercurous nitrate, solid is a colorless crystalline material with a faint odor of nitric acid, it is used in medicine and in chemical analysis. It darkens on exposure to light. It is slightly soluble in water and decom poses to a white insoluble precipitate, It wilt accelerate the burning of combustible material. It is toxic by ingestion or inhalation of dusts, toxic oxides of nitrogen are produced in fires involving this material. If material on fire or Involved In fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Approach fire with caution Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or lire fighting water Environmental considerations--water spill Add caustic soda If dissolved, apply sodium sutfide solution to precipitate heavy metals Allow to aerate If dissolved, apply activated cartoon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates MERCUROUS OXIOE. BLACK, SOLID 4923264 POISON B UN1641 Mercurous oxide, black, solid is a black powder. It is decomposed by light to free mercury and mercuric oxide. It is insoluble in water. It is toxic by inhalation (dust, etc) and by ingestion. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved in fire Keep material out of water sources and sewers April 1981 MCD 000010072 MERCUROUS SULFATE, SOLID 4923265 POISON B UN1628 Mercurous sulfate, solid is a white to yellow crystalline powder. It is insoluble in water. It is toxic by inhalation (dust, etc) and by ingestion. If material involved In fire Extinguish fire using agent suitable lor type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use loam, carbon dioxide or dry chemical If material not Involved In fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing MERCURY BASEO PESTICIOE, LIQUID, N.O.S. 4921651 (COMPOUNDS AND PREPARATIONS) (INSECTICIDES, OTHER THAN AGRICULTURAL. NEC) POISON B UN2777 Mercury based pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emulsrtiabte. The carrier may bum though it may take some effort to ignite. It is toxic by inhalation, skin absorption, and/ or ingestion. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424- 9300. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as tog Solid streams of water may be ineffective Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 329 MERCURY BASED PESTICIDE, LIQUID, N.O.S. 4921652 (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES, NEC, LIQUID) POISON B UN2777 Mercury based pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emulsifiable. The carrier may bum though it may take some effort to ignite. It is toxic by inhalation, skin absorption, and/ or ingestion. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424- 9300. If material on fire or involved In fire Do not extinguish fire unless How can be stopped Use water in flooding quantities as tog Solid streams of water may be ineffective Cool all affected containers with Hooding quantities of water Apply water from as far a distance as possible Use 'alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water MERCURY BASED PESTICIDE, LIQUID, N.O.S. (COMPOUNDS AND PREPARATIONS) 4910537 (INSECTICIDES, OTHER THAN AGRICULTURAL, NEC) FLAMMABLE LIQUID UN2778 Mercury based pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emulsifiable. The primary hazard of this material is the flammability of the carrier, it has a flash point below 100 deg. F. It can cause illness by inhalation, skin absorption and/or ingestion. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as tog Solid streams of water may be ineffective Cooi all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breaming vapors Keep upwind. Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wear self-contained breaming apparatus when fighting fires involv ing this material MERCURY BASED PESTICIDE, UQUID, N.O.S. 4910538 (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES, NEC, UQUIO) FLAMMABLE UOUIO UN2778 Mercury based pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emulsifiable. The primary hazard of this material is the flammability of the carrier. It has a flash point below 100 deg. F. It can cause illness by inhalation, skin absorption and/or ingestion. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300. If material on fire or Involved in fire Do not extinguish fire unless flow can ba stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance aa possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wear self-contained breathing apparatus when fighting fires involv ing this material MERCURY BASEO PESTICIDE, SOLID, N.O.S. 4921653 (COMPOUNDS AND PREPARATIONS) (INSECTICIDES, OTHER THAN AGRICULTURAL, NEC) POISON B UN2777 Mercury based pesticide is a solid or a liquid absorbed on a dry carrier. It is a wettable powder. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to, or leaking from containers of this ma terial contact the pesticide safety team network. Telephone; 800-424- 9300. H material on lira or involved in fire Extinguish lira using agent suitable for type ol surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing 330 000010073 MOD April 1981 MERCURY BASED PESTICIDE, SOLID, N.O.S. 49216S4 (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES, NEC, OTHER THAN LIQUID) POISON B UN2777 Mercury based pesticide is a solid or a liquid absorbed on a dry carrier. II is a wettable powder. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to. or leaking from containers of this ma terial contact the pesticide safety team network. Telephone; 800-424- 9300. It material on tire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use ' alcohol'' foam, carbon dioxide or dry chemical If material not on tire and not involved In fire Keep sparks, flames, and other sources ot ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matehal which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing MERCURY COMPOUND, SOLID, N.O.S. 4923269 POISON B UN2025 Mercury compound, solid, n.o.s. is a various colored crystalline ma terial containing mercury. It may or may not be water soluble. It is toxic by inhalation (dust) or by ingestion. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not Involved In fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing MESITYL OXIDE 4909223 FLAMMABLE UQUIO UN1229 Mesityl oxide is a colorless, oily liquid witft a pungent honey-like odor, it is used in paint removers, as a solvent lor plastics, and as an insect repellent. It has a flash point of 87 deg. F. It is lighter than water and is slightly soluble in water. Its vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in Hooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use '`alcohol" foam, carbon dioxide or dry chemical jri\ 1981 ^00 G 0'Jo O^ If material not on tire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water METAL ALKYL, SOLUTION, N.O.S. 4906030 FLAMMABLE LIQUID NA919S PYROFORIC Metal alkyl, solution, n.o.s. is a material whose principal property is that of igniting spontaneously in contact with moist air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Do not use water Use graphite, soda ash or powdered sodium chloride If material not on fire and not involved in fire Do not use water Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered METAL ALLOY BILLETS. BLOOMS, INGOTS, PIGS. 4926488 SPONGE OR SHOT. NEC, NOT IRRAOIATED NOR REQUIRING PROTECTIVE SHIELDING (RADIOACTIVE MATERIAL* N.O.S.) RADIOACTIVE MATERIAL UN2912 Metal alloy billets, blooms, ingots, pigs, sponge or shot are greyish to silvery colored materials. Radioactive materials emit certain rays that may be hazardous. These rays can be detected only by instruments. Exposure of humans to intense radiation may be harmful, whereas film may be damaged by radiation from relatively low concentrations, tf material on fire or Involved In fire Contact the local, state, or department of energy radiological re sponse team Extinguish (ire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use graphite, soda ash, powdered sodium chloride, or suitable dry powder Continued on next pago 331 If material not on fire and not involved in fire Contact the local, state, or department of energy radiological re sponse team Do not use water Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Do not attempt to sweep up dry material Personnel protection Keep upwind Avoid breathing dusts, and fumes from burning material Wear full protective clothing Wear self-contained breathing apparatus Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation Keep unnecessary people out of incident area until area declared safe by radiological response team METAL OR METAL ALLOY BILLETS, BLOOMS. 4926489 INGOTS, PIGS, SPONGE, OR SHOT, NOT IRRIDATEO NOR REQUIRING PROTECTIVE SHIELOING (RADIOACTIVE MATERIAL, LOW SPECIFIC ACTIVITY OR LSA, N.O.S.) RADIOACTIVE MATERIAL UN2912 Metal or metal alloy billets, blooms, ingots, pigs, sponge, or shot is greyish to silvery colored material. Radioactive materials emit certain rays that may be hazardous. These rays can be detected only by instruments. Exposure of humans lo intense radiation may be harmful whereas films may be damaged by radiation from relatively tow concentrations. If material on fire or involved in fire Contact the focal, state, or department of energy radiological re sponse team Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use graphite, soda ash, powdered sodium chloride, or suitable dry powder If material not on fire and not Involved In fire Contact the local, state, or department of energy radiological re sponse team Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Keep upwind Avoid breathing dusts, and fumes from burning material Wear full protective clothing Wear self-contained breathing apparatus Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation Keep unnecessary people out of incident area until area declared safe by radiological response team METHACRYLIC ACID, GLACIAL (CORROSIVE UQUID, 4931402 N.O.S.) CORROSIVE MATERIAL, ACIOIC, COMBUSTIBLE UN1760 Methacrylic acid, glacial is a dear colorless liquid having a pungent odor. It is used to make plastics, it is corrosive to metals and tissue, it is also combustible and has a flash point of 154 deg. f, and a melting point of 61 deg. F. If the material becomes contaminated or is subject to heat, it may polymerize. If the polymerization takes place inside a container, the container may violently rupture. It is lighter than water and is soluble in water, its vapors are heavier than air. 332 If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Use water spray to absorb vapors If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1 500 feet METHALLYL CHLORIDE (FLAMMABLE UQUID, 4906223 N.O.S.) FLAMMABLE LIQUID UNI 993 Methatlyl chloride is a colorless to straw colored liquid with a sharp penetrating odor. It has a flash point of 11 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool alt affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol*' foam, carbon dioxide or dry chemical tf material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation tf fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered mcd 0010075 April 1981 METHANE 4905755 FLAMMABLE GAS UN1971 Methane is a colorless odorless gas. It is easily ignited. It may only be shipped in cylinders. The gas is lighter than air but a flame may flash back to the source of a leak very easily. Under fire conditions the cyl inders may violently rupture and rocket. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray t*'1 knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered METHANOL (METHYL ALCOHOL, COLUMBIAN 4909230 SPIRITS) FLAMMABLE UQUIO UN1230 Methanol is a clear colorless liquid. It is used to make other chemicals, to remove water from automotive and aviation fuels, as an antifreeze, and as a solvent for various paints and plastics. It has a flash point of 52 deg. F. It is lighter than water and soluble in water, its vapors are heavier than air. tf material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical tf material not on fire and not involved in fire Keep sparks, flames, and other sources ot ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop teak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts o( water or soap and water METHANOL. CONTAMINATED, VALUE ONLY FOR 4909237 REFINING (ALCOHOL. N.O.S.) FLAMMABLE LIQUID UN1987 Methanol, contaminated is a clear colorless to variable colored liquid. It-has a flash point of 52 deg. F. which may vary depending on contam ination. It is fighter than water and may not be completely water soluble, methanol itself is water soluble.) its vapors are heavier than air. priI 1981 ^QD 00 IOq ?8 If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in Hooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water METHANOL, SOLIDIFIED (ALCOHOL N.O.S.) 4910404 FLAMMABLE LIQUID UNI 967 Methanol, solidified is a sterno-like gel. The alcohol can separate out. The hazard is flammability. If material on lira or involvad in fira Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance possible Use "alcohol" foam, carbon dioxide or dry chemical tf material not on fira and not involved in fire Keep sparks, flames, and other sources of ignition away Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water METHYL CHLOROCARBONATE (tee METHYL CHLOROFORMATE 4907429) METHYLETHANOLAMINE (COMBUSTIBLE UQUIO, 4913183 N.O.S.) COMBUSTIBLE UQUIO NA1933 Methylethanoiamine is a dear colorless liquid, it is used to make other chemicals. It has a flash point of 165 deg. F. It is lighter than water and is soluble in water. Its vapors are heavier than air. Toxic oxides d nitrogen are produced during combustion of this material. It material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as tar a distance as possible Solid streams of water may be ineffective Use "alcohol" foam, carbon dioxide or dry chemical Continued on next peg# 333 If material not on fire and not Involved In Are Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material METHOXYCHLOR (AGRICULTURAL INSECTICIDES, 4960646 NEC, LIQUID) ORM-E NA2761 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Methoxychlor is a white crystalline solid dissolved in a liquid carrier. It is used as a pesticide. It is a water emulsifiable liquid. It can cause illness by inhalation, skin absorption and/or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental consideration*--water spill Use natural barriers or oil spill control booms to limit spill motion If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates METHOXYCHLOR (AGRICULTURAL INSECTICIDES, 4960647 NEC, OTHER THAN LIQUID) ORM-E NA2761 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Methoxychlor is a white crystalline solid. It is used as a pesticide. It is a wettable powder. H can cause illness by inhalation, akin absorption and/or ingestion. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone; 800- 424-9300. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) If material not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental consideration*--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water 334 Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates METHOXYCHLOR (INSECTICIDES, OTHER THAN 4960648 AGRICULTURAL. NEC) ORM-E NA2761 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Methoxychlor is a white crystalline solid or the solid dissolved in a liquid carrier. It is used as a pesticide. It is a wettable powder or water emulsifiable liquid. It can cause illness by inhalation, skin absorption and/or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone; 800- 424-9300. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates METHYL ACETATE 4908220 FLAMMABLE LIQUID UN1231 Methyl acetate is a dear colorless liquid with a fragrant odor. It has a flash point of 14 deg. F. It is fighter than water and soluble in water. Its vapors are heavier than air. If material on fir* or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If materiel not on fir* end not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use watef spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1981 HCD 000010077 Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered METHYL ACETOACETATE (COMBUSTIBLE LIQUID, 4913150 N.O.S.) COMBUSTIBLE LIQUID NA1993 Methyl acetoacetate is a clear colorless liquid. It has a flash point of 158 deg. F. It is heavier than water and slightly soluble in water. Its vapors are heavier than air. tf material on tire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water METHYL ACETONE 4909238 FLAMMABLE LIQUID UN1232 Methyl acetone is a clear colortess liquid composed of acetone, methyi acetate and methanol, it has a flash point of less than 52 deg. F. It is lighter than water and soluble in water, its vapors are heavier than air. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in hooding quantities as fog Solid streams of water may be ineffective Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical tf material not on Are and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water METHYL AMYL ACETATE 4909235 FLAMMABLE UQUIO UN1233 Methyl amyl acetate is a dear colorless liquid. It has a flash point of 95 deg. F. It is lighter than water and is insoluble in water. Its vapors are heavier than air. April 1981 Hcr> 00010078 if material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with Hooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water METHYL AMYL KETONE 4913132 COMBUSTIBLE LIQUID UN1110 Methyl amyl ketone is a clear colorless liquid. It has a flash point of 126 deg. F. It is lighter than water and slightly soluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish lire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread tire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain How as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water METHYL BROMIDE AND ETHYLENE DIBROMIDE 4921438 MIXTURE, LIQUID POISON B UN1647 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Methyl bromide and ethylene dibromkJe mixture, liquid is the mixture of two liquids having a chloroform like odor. Neither material is com bustible. Both are very slightly soluble in water. The mixture ia toxic by inhalation and skin absorption. It weighs 18.0 pounds per gallon. If material involved In fire Extinguish tire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Use foam, carbon dioxide or dry chemical If material not on fire end not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Continued on next page 335 Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten limes the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors METHYL BROMIOE AND MORE THAN 2% 4921437 CHLOROPICRIN MIXTURE, LIQUID POISON B NA1591 Methyl bromide and more than 2% chloropicrin mixture, liquid is a mixture of two liquids. Neither is combustible or water soluble. They are toxic by inhalation. Prolonged or repeated skin contact can cause severe bums and possible absorption of toxic quantities of the material. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Use foam, carbon dioxide or dry chemical If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of watar or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered METHYL BROMIOE AND NONFLAMMABLE 4921439 NONLIQUEFIEO COMPRESSED GAS MIXTURE, LIQUID POISON B NA1955 Methyl bromide and nonflammable nonliquefied compressed gas mix ture, liquid is a liquid charged with a gas. It is non-combustible and has a chloroform-like odor. It is very slightly soluble in water. It is toxic by inhalation. 336 MCD 000010079 If material Involved In fire Extinguish lire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered METHYL BROMIDE. LIQUID (INCLUDING UP TO 2% 4921440 CHLOROPICRIN) POISON B UN1062 Methyl bromide is colorless liquid with a chloroform-like odor. Under most circumstances it is non-combustible. It is very slightly soluble in water. It is toxic by inhalation. Prolonged or repeated skin contact can cause severe burns and possible absorption of toxic quantities of the material. If materiel Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as log Cool all affected containers with flooding quantities of water Use foam, carbon dioxide or dry chemical ff material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt lo stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered METHYL BUTENE 4909225 FLAMMABLE UOUID UN2460 Methyl butene is a clear colorless liquid with a petroleum like odor. It has a flash point of less than 20 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. H material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool ail affected containers with flooding quantities of water Apply water from as tar a distance as possible Use foam, carbon dioxide or dry chemical April 1961 It material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out ol water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water METHYL BUTYL KETONE (FLAMMABLE LIQUID. 4909242 N.O.S.) FLAMMABLE LIQUIO UN1993 Methyl butyl ketone is a clear colorless liquid. It has a flash point of 95 deg. F. It is lighter than water and slightly soluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use `alcohol" foam, carbon dioxide or dry chemical H material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water METHYL BUTYRATE 4909226 FLAMMABLE LIQUID UN1237 Methyl butyrate is a clear colorless liquid. It has a flash point of 37 deg. F. It is lighter than water and slightly soluble in water. Its vapors are heavier than air. H material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If materiel not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1981 Oq 10a0 METHYL CHLORIDE 4905761 FLAMMABLE GAS UN1063 Methyl chloride is a colorless gas with a faint sweet odor, it is used to make other chemicals and as a herbicide. It is shipped as a liquefied gas under its vapor pressure. Contact with me liquid can cause frostbite. It is easily ignited. Its vapors are heavier than air. and a flame can flash back to the source of leak very easily. The leak can be either a liquid or vapor leak. It can asphyxiate by the displacement of air. Under fire conditions the cylinder or tank car may vioientty rupture and rocket. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved In fire Keep sparks, (lames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet If material leaking (not on fire), downwind evacuation must be considered METHYL CHLORIDE-METHYLENE CHLORIDE 4905764 MIXTURE FLAMMABLE GAS UN1912 Methyl chloride-methylenechloride is a colorless gas with a faint sweet odor. It is shipped as a liquefied gas under its vapor pressure. Contact with the liquid can cause frostbite. It is easily ignited. Its vapors are heavier than air and a flame can flash back to the source of leak very easily. It can asphyxiate by the displacement of air. Under fire conditions the cylinders or tank cars may violently rupture or rocket. If materiel on fire or Involved In fire Do not extinguish fire unless How can be stopped Use water in flooding quantities as fog Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet If material leaking (not on fire), downwind evacuation must be considered 337 METHYL CHLOROFORMATE 4907429 FLAMMABLE LIQUID, CORROSIVE UNI 238 Methyl chtorotormate is a colorless liquid with a pungent odor. It has a flash point of 54 deg. F. It is slightly soluble in water and decomposed by water to hydrochloric acid with evolution ol heat. It is corrosive to metals and tissue. Its vapors are heavier than air. If materiel on fire or involved in fire Do not extinguish fire unless flow can be stopped Use "alcohol" foam, carbon dioxide or dry chemical Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knockdown vapors Do not use water on material itseif Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is -exposed to direct flame--evacuate for a radius of i500 feet If material leaking (not on fire), downwind evacuation must be considered METHYL DICHLOROACETATE 49333S0 CORROSIVE MATERIAL, ACIDIC, COMBUSTIBLE UN2299 Methyl dichloroacetate is a colorless liquid with an ethereal odor. It is used to make other chemicals, it is combustible and has a flash point of 176 deg. F. It is decomposed by water to dichloroacetic add. a cor rosive material with evolution of heat. It is corrosive to metals and tissue. H material on fire or involved In fire Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool aH affected containers with flooding quantities of water Apply water from as far a distance as possible M material not on firs and not Involved in fire Keep sparks, flames, and other sources erf ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts ol water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing 338 METHYL ETHYL KETONE (ETHYL METHYL KETONE) 4909243 FLAMMABLE LIQUID UN1193 Methyl ethyl ketone is a clear colorless liquid with an acetone-like odor. It is used as a solvent for paints, plastics, and adhesives. It has a flash point of 21 deg. F. It is lighter than water and soluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless (low can be stopped Use water in flooding quantities as tog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, (lames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain (low as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water METHYL ETHYL KETONE PEROXIDE, (IN SOLUTION 4919178 WITH NOT MORE THAN 9% BY WEIGHT ACTIVE OXYGEN) ORGANIC PEROXIDE UN25S0 Methyl ethyl ketone peroxide, (in solution with not more than 9% by weight active oxygen) is a coloress to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite; but once ignited, it will bum with increasing rapidity as the fire progresses, if spilled on combustible materials, spontaneous ignition ol the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burning of combustible materials. Un der prolonged exposure to fire or heat containers of the material may explode. ff material on fire or Involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in lira Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation ff the material is on fire or involved in fire evacuate tor a radius of 2500 feet HOP 000010081 April 1981 METHYL ETHYL PYRIDINE 4935660 CORROSIVE MATERIAL, BASIC, COMBUSTIBLE UN2300 Methyl ethyl pyridine is a colorless liquid with a sharp penetrating 'dor. It is combustible and has a flash point of 165 deg. F. It is slightly oluble in water. It is corrosive to metals and tissue. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing METHYL FORMATE FLAMMABLE UQUID 4908225 UN1243 Methyl formate is a dear colorless liquid with an agreeable odor. It has a flash point of -27 deg. F. It is lighter than water and reacts with water to give formic acid, a corrosive material and methyl alcohol, an other flammable liquid. Both of these materials are soluble in water. Its vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use "alcohol" foam, carbon dioxide or dry chemical Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Do not use water on material itself If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate lor a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered April 1981 *Tn On. o,'O o.o>. 9r<? METHYL HYDRAZINE 4906230 FLAMMABLE UQUID, POISONOUS, CORROSIVE THERMALLY UNSTABLE UN1244 Methyl hydrazine is a colorless liquid with an ammonia-like odor, it is used to make other chemicals, as a solvent, and as a rocket propellant, it has a flash point of 17 deg. F. It is flammable over a wide range of vapor air concentrations. It may ignite spontaneously in contact with porous materials such as earth, wood, cloth, etc., and with oxidizing materials. It is toxic and the vapors attack the eyes and respiratory system, It is also corrosive to the skin. It is lighter than water and slightly soluble in water. The vapors are heavier than air. Prolonged exposure of the containers of the material to fire or heat may result in the spon taneous decomposition of the material and violent rupture of the con tainer. Toxic oxides of nitrogen are produced during combustion of this material. K material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodfly contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 5000 feet If material leaking (not on fire), downwind evacuation must be considered METHYL ISOBUTYL CARBINOL (COMBUSTIBLE 4913143 LIQUID, N.O.S.) COMBUSTIBLE UQUID UN1987 Methyl isobutyt carbind is a dear colorless liquid. It has a flash point of 120 deg. F. it is lighter than water and soluble in water. Its vapors are heavier than mt. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to disperse vapors and dilute standing pools of liquid ConUmm/on nmxt paga 339 Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water METHYL ISOBUTYL KETONE (FLAMMABLE LIQUIO. 4909245 N.O.S.) FLAMMABLE LIQUID UN1993 Methyl isobutyl ketone is a clear colorless liquid with a pleasant odor. It has a (lash point of 73 deg. F. It is lighter than water and slightly soluble in water. Its vapors are heavier than air. H material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use '`alcohol'1 foam, carbon dioxide or dry chemical If material not on fire and not involved in fira Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water METHYL ISOBUTYL KETONE PEROXIDE, (IN 4919180 SOLUTION WITH NOT MORE THAN 9% BY WEIGHT ACTIVE OXYGEN) ORGANIC PEROXIOE UN2126 Methyl isobutyl ketone peroxide, (in solution with not more than 9% by weight active oxygen) is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is slightly soluble in water. The liquid or solution may require some effort to ignite; but once ignited, it will bum with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause e violent chemical reaction. It supports the burning of combustible materials. Un der prolonged exposure to fire or heat containers of the material may explode. H material on fire or involved In fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cod all affected containers with Hooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive (f material not on fira and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment 340 Wash away any material which may have contacted (he body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet METHYL ISOPROPENYL KETONE, INHIBITED 4907240 FLAMMABLE UQUID UN1246 POLYMERIZATION Methyl isopropenyl ketone is a dear colorless liquid. It has a flash point of 52 deg. F. If contaminated or subjected to heat it may polymerize if methyl isopropenyl ketone is confined in a container when polymeri zation takes place the container may violently rupture. It is heavier than water and insoluble in water. Its vapors are heavier than air. H material on fira or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fira and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak If without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fira becomes uncontrollable or container is exposed to direct flamo evacuate tor a radius of 2500 feet If material leaking (not on fire), downwind evacuation must be considered METHYL MAGNESIUM BROMIDE IN ETHYL ETHER 4909230 FLAMMABLE UQUID UN 1928 This is the solution of methyl magnesium bromide in ethyl ether. Ethyl ether has a flash point of -49 deg. F. The solution reacts with water to give methane, a flammable gas. The heat of this reaction may be suf ficient to ignite the methane. The vapors of ethyl ether are heavier than air. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use "alcohol" foam, carbon cfioxide or dry chemical Coot all affected containers with flooding quantities of water Apply water from aa far a distance as possible Do not use water on material itself If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself April 1981 MOD 000010083 Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered METHYL MERCAPTAN 4905520 FLAMMABLE GAS, CORROSIVE UN1064 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100/45.4) Methyl mercaptan is a colorless gas with a very strong disagreeable odor of rotten cabbage. It is shipped as a liquefied gas under its vapor pressure. Contact with the liquid can cause frostbite or chemical type burn. It is slightly soluble in water. It is easily ignited. Its vapor is heavier than air and a flame can flash back to the source of leak very easily. It can asphyxiate by the displacement of air. Under fire conditions the cylinders or tank cars may violently rupture and rocket. It weighs 7.3 pounds per gallon. If material on fire or involved in fire Do not extinguish (ire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible H material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet If material leaking (not on fire), downwind evacuation must be considered Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Oike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill Use natural barriers or oil spill control booms to limit spill motion If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses ol pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors April 1981 0 qQ 6^ METHYL METHACRYLATE MONOMER, INHIBITED 4907250 FLAMMABLE LIQUIO POLYMERIZABLE UN1247 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Methyl methacrylate monomer <s a clear colorless liquid. It is used to make plastics. It has a flash point of 50 deg. F. The vapors are irritating to the eyes and respiratory system. If contaminated or subjected to heat, it may polymerize. If the polymerization takes place in a container, the container is subject to violent rupture. It is lighter than water and slightly soluble in water. Its vapors are heavier than air. It weighs 7.8 pounds per gallon. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet If material leaking (not on fire), downwind evacuation must be considered Environmental considerationa--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash, cement powder, sawdust, or com mercial sorbents Apply `universal'' gelling agent to immobilize spill Apply fluorocarbon-water foam to diminish vapor and fire hazard Environmental considerations--water spill Use natural barriers or oil spill control booms to limit spill motion Use surface active agent (e.g. detergent, soaps, alcohols) to com press and thicken spilled material Inject "universal" gelling agent to solidify encircled spill and increase effectiveness of booms If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors METHYL METHOXY PENTANONE (COMBUSTIBLE 4913138 LIQUID, N.O.S.) COMBUSTIBLE LIQUID NA1993 Methyl methoxy pentanone is a clear colorless liquid. It is used as a solvent. It has a flash point of 141 deg. F. II is liqhter man water and insoluble in water. Its vapors are heavier than air. Continued on next page 341 If material on fir* or involved in firs Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water METHYL NORBORNENE DICARBOXYUC ANHYDRIOE (See MEMTETRAHYORO PHTHALIC ANHYDRIDE 4931441) METHYL PARATHION MIXTURE, DRY 4921443 POISON B NA2783 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-IOO/45.4) Methyl parathion mixture, dry is the liquid material absorbed on a dry carrier. Methyl parathion is very slightly soluble in water. Methyl para* thion is a combustible liquid but the combustibility depends on the nature of the carrier and quantity of methyl parathion. It is toxic by skin ab sorption and inhalation (vapor, dust, etc.) in case of damage to, or leaking from containers of this material contact the pesticide safety team net work. Telephone; 800-424-9300 If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from bunting material Keep upwind Avoid bodily contact with the material Wear fun protective dotting Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom if dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Remove (rapped material with suction hoses Use mechanical dredges or lifts to remve immobilized masses of pollutants and precipitates 342 METHYL PARATHION MIXTURE, LIQUID (CONTAINING 4921444 25% OR LESS METHYL PARATHION) POISON B NA2783 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100/45.4) Methyl parathion mixture, liquid is the solution of methyl parathion and a liquid or solid dissolved in it. Methyl parathion is slightly soluble in water and is itself a combustible liquid, The combustibility of the mixture depends upon the nature of the other material dissolved in the solution, it is toxic by inhalation and by skin absorption. In case of damage to. or leaking from containers of this matenal contact the pesticide safety team network. Telephone; 800-424-9300 If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clotting Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered Environmental consideration#--land spill Dig a prt, pond, lagoon, holding area to contain liquid or solid materia Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerationa--water spill Use natural barriers or oil spill control booms to limit spill motion Use surface active agent (e.g. detergent, soaps, alcohols) to com press and thicken spilled material Inject "universal" gelling agent to solidify encircled spill and increase effectiveness of booms If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with auction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors METHYL PARATHION MIXTURE, LIQUID (CONTAINING 4921447 OVER 25% METHYL PARATHION) POISON B NA2783 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100/45.4) Methyl parathion mixture, liquid is the solution of methyl parathion and a liquid or solid dissolved in it. Methyl parathion is slightly soluble in water and is itself a combustible liquid. The combustibility of the mixture depends upon the nature of the otter material dissolved in the solution. It is toxic by inhalation and by skin absorption. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300 MCD 000010035 April 1981 N material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain llow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill Use natural barriers or oil spill control booms to limit spill motion Use surface active agent (e.g. detergent, soaps, alcohols) to com press and thicken spilled material Inject "universal" gelling agent to solidify encircled spill and increase effectiveness of booms ll dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered METHYL PENTANE 4906191 FLAMMABLE LIQUID UN2462 Methyl pentane is a clear colorless liquid with a petroleum like odor. It has a flash point of -10 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to slop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered METHYL PENTADIENE 4909173 FLAMMABLE UQUID UN2461 Methyl pentadiene is a clear colorless liquid with a petroleum like odor. It has a flash point of -30 deg. F. It is Kghter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as posafcle Use foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1981 METHYL PHOSPHONOTHIOIC BICHLORIDE, 4933336 ANHYDROUS CORROSIVE MATERIAL, POISONOUS NA1760 Methyl phosphonothioic dichloride, anhydrous is a colorless liquid with a pungent odor. It is noncombustible. It is toxic by inhalation. It is heavier than water and reacts with water to give hydrochloric acid,a corrosive material, with relaasa of heat It is corrosive to metals and tissue. H material on fire or Involved In fire Us# "alcohol" foam, carbon dioxide or dry chemical Cool aH affected containers with flooding quantities of water Apply water from as far a distance as possible Do not use water on material Itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Do not use water on material Itself Neutralize spilled material with crushed limestone, soda ash. or lime Continued on next pogo 343 MCD 000010086 Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Oo not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water METHYL PHOSPHONOUS DICHLORIDE 4933337 CORROSIVE MATERIAL NA2845 PYROFORIC Methyl phosphonous dichloride is a colorless liquid with a pungent odor. It is pyroforic and will spontaneously ignite on contact with moist air or water. It is heavier than water and besides igniting on contact with water hydrochlonc acid, a corrosive material, is produced. It is corrosive to metals and tissue. If material on fire or involved In fire Use "alcohol" foam, carbon dioxide or dry chemical Do not use water on material itself If large quantities of combustibles are involved, use water in Hooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain How as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do rot handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water METHYL PROPIONATE 4909240 FLAMMABLE UOUID UNI 249 Methyl propionate is a dear colortess liquid, it ia used as a flavoring and as a solvent. It has a Hash point of 28 deg. F. It is lifter than water and is slightly soluble in water. Its vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire end not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear bools, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts oi water or soap and water METHYL PROPYL KETONE 4909216 FLAMMABLE LIQUID UN1249 Methyl propyl ketone is a clear colorless liquid with an odor of fingernail polish, ft has a flash point of 45 deg. F. It is lighter than water and slightly soluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as log Solid streams ot water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of fiquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water METHYL SULFATE (Sea DIMETHYL SULFATE 4933322) METHYL SULFIDE (See DIMETHYL SULFIOE 4906122) METHYL VINYL KETONE, INHIBITED 4907260 FLAMMABLE LIQUIO UNI 251 POLYMERIZABLE Methyl vinyl ketone is a dear colorless liquid. It has a flash point of 20 deg. F. If contaminated or subjected to heat it may polymerize. If the polymerization takes place in a container, the container may violently rupture. It is lighter than water and soluble in water. Its vapors are heavier than air. Its vapors are heavier than air. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical K material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 344 0000^ os'1 lC*> April 1981 Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet If material leaking (not on fire), downwind evacuation must be considered N-METHYL-N'-NITRO-N-NITROSOGUANIDINE 4916723 FLAMMABLE SOLID NA1325 N-methyl-n -mtro-nitrosoguanidine If material on fire or involved In fire Flood with water If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material METHYLACETYLENE-PROPADIENE, STABILIZED 490S7S8 FLAMMABLE GAS UN1060 Methylacetylene-propadiene stabilized is a colorless gas with an acetylene like odor. It is shipped as a liquefied gas under its vapor pressure. Contact with the liquid can cause frostbite. It is easily ignited. Its vapors are heavier than air and a flame can flash back to the source of leak very easily. This leak may be either a liquid or a vapor leak. It can asphyxiate by the displacement of air. Under fire conditions the cylinders or tank cars may violently rupture and rocket. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved In Are Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet If material leaking (not on fire), downwind evacuation must be considered METHYLACRYLATE, INHIBITED 4907245 FLAMMABLE UQUID UN1919 POLYMERIZABLE Methyl acrylate is a clear colorless liquid with an acrid odor. It has a flash point of 27 deg. F. The vapors are irritating to the eyes and res piratory system. If the material is subjected to heat for prolonged periods or becomes contaminated, it is subject to polymerization with evolution ol heat. If the polymerization takes place inside a container, the container may violently rupture. The material is lighter than water and is slightly soluble in water. Its vapors are heavier than air. April 1981 **C, o.o.o*0,'o. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Appty water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet If material leaking (not on fire), downwind evacuation must be considered METHYLAL 4908222 FLAMMABLE LIQUID UN1234 Methylal is a dear colorless liquid with a chloroform-like odor. It has a flash point of 0 deg. F. It is lighter than water and soluble in water. Its vapors are heavier than air. tf material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carton dioxide or dry chemical It material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontroMable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered METHYLCHLOROMETHYL ETHER, ANHYDROUS 4907430 FLAMMABLE UQUID, POISONOUS UN1239 Methylchloromethyt ether is a dear colorless liquid, it has a flash point of -4 deg. F. It is irritating to the eyes and respiratory system. Prolonged exposure to its vapors may result in death. It is heavier than water and is decomposed by water to form hydrochloric add, a corrosive material. Its vapors are heavier than air. Continual on noxt paga 345 tf material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as tog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol ' foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered METHYLCYCLOHEXANE 4909330 FLAMMABLE LIQUID UN2296 Methyl cyclohexane is a dear colorless liquid with a petroleum like odor. It has a Hash point of 25 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any malarial which may hava contacted the body with copious amounts of water or soap and water METHYLDICHLOROARSINE 4920520 POISON A NA1556 Methyidichloroarsine is a colorless liquid with a strong burning odor, in low concentrations it is very irritating to the respiratory system and in higher concentrations or prolonged exposure to low concentrations it is toxic by inhalation. Contact with the liquid will causa very painful bums. The material may only be shipped in cylinders and these must be overpacked In wooden boxes. Prolonged exposure to fire or heat may cause the cylinders to violently rupture and rocket 346 If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical tf material not involved In fire Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered METHYLDICHLOROSILANE 4907625 FLAMMABLE UQUIO, CORROSIVE, ACIDIC UN1242 Methyldichkxosilane is a colorless fuming liquid with a pungent odor. It has a flash point of -26 deg. F. Vapor and liquid can cause bums. It is heavier than water and is decomposed by water to form hydrochlohc add, a corrosive material. Its vapors are heavier than air. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use "alcohol'' foam, carbon dioxide or dry chemical Cod all affected containers with flooding quantities of water Apply water from as far a distance as possible Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors If material not on fire and not Involved In fire Keep spaiks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodty contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation tf fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered METHYLFURAN 4908210 FLAMMABLE LIQUID UN2301 Methytfuran is a dear colorless liquid with an ether like odor. It has a flash point of -22 dag. F. It is lighter than water and Insoluble in water. Its vapors are heavier than air. April 1981 00 If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use 'alcohol" foam, carbon dioxide or dry chemicaf tf material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct (lame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered METHYLMETHACRYLATE MONOMER. UNINHIBITED 4907255 FLAMMABLE LIQUID NA1247 POLYMERIZABLE ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Methyl methacrylate monomer, uninhibited is a clear colorless liquid. It is used to make plastics. It has a flash point of 50 deg. F. The vapors are irritating to the eyes and respiratory system. Containers of the ma terial must be shipped under refrigeration, or the chilled material may be shipped in heavily insulated containers. If the materia) becomes con taminated or the chilled material warms up, it may polymerize, tf the jiymenzation lakes place inside a container, the container is subject to violent rupture. It is lighter than water and slightly soluble in water. Its vapors are heavier than air. It weighs 7.8 pounds per gallon, tf material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical tf material not on fire end not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered Environmental considerations--land spill Dig a pH, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete April 1981 000^ 09 Absorb bulk liquid with fly ash, cement powder, sawdust, or com mercial sorbents Apply "universal1' gelling agent to immobilize spill Apply fluorocarbon-water foam to diminish vapor and fire hazard Environmental consideration*--water apiil Use natural barriers or oil spill control booms to limit spill motion Use surface active agent (e.g. detergent, soaps, alcohols) to com press and thicken spilled material Inject "universal" gelling agent to solidify encircled spill and increase effectiveness of booms If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors METHYLTRICHLOROSILANE 4907630 FLAMMABLE LIQUID, CORROSIVE, ACIDIC UNI 250 Methyltrichlorosilane is a colorless fuming liquid with a pungent odor. It has a flash point of 8 deg. F. Vapor and liquid can cause bums. It is heavier than water and is decomposed by water to form hydrochloric acid, a corrosive material. Its vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use "alcohol" foam, carbon dioxide or dry chemical Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak rf without hazard Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct llama--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered METHYL PARATHION, LIQUID 4921442 POISON B. COMBUSTIBLE NA2783 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-IOO/45.4) Methyl parathion, liquid is a dear colorless liquid, it is used as a pesticide. It is slightly soluble in water and it is a combustible liquid. It is toxic by inhalation and skin absorption. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300 It weighs 11.3 pounds per gallon. Continued on next pope 347 rt material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool aJI affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical H material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered Environmental consideration*--land spill Dig a pit pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerationa--water spill Use natural barriers or oil spill control booms to limit spill motion Use surface active agent (e.g. detergent soaps, alcohols) to com press and thicken spilled material Inject "universal" gelling agent to solidify encircled spill and increase effectiveness of booms If dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors MEVINPHOS (AGRICULTURAL INSECTICIDES, NEC* 4921531 LIQUID) POISON B NA2753 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/1U54) Mevinphos is a yellow to orange liquid. It is used as a pesticide. It is a water emuistfiable liquid. It is toxic by inhalation, skin absorption, and/ or ingestion. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone; 000-424- 9300. tf material on fira or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as tar a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of wafer sources and sewers Build dikes to contain flow as necessary Attempt to stop teak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind 348 Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill if dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors MEVINPHOS (AGRICULTURAL INSECTICIDES, NEC, 4921532 OTHER THAN LIOUIO) POISON 8 NA27B3 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1 0.454) Mevinphos is a.yellow to orange liquid absorbed on a dry carrier. It is used as a pesticide. It is a wettable powder. It is toxic by inhalation, skin absorption, and/or ingestion, in case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300. If material on fire or involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical tf material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or sotid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates MEVINPHOS (INSECTICIDES, OTHER THAN 4921S33 AGRICULTURAL, NEC) POISON B NA2783 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Mevinphos is a yellow to orange liquid or the liquid absorbed on a dry carder. K is used as a pesticide. It is a wettable powder or water emul- siftabie liquid. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300. April 1981 MCD 000010091 If material on fire or involved in Are Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dtoxtde or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray lo knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--lend apill Oig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors MEVINPHOS MIXTURE, DRY (AGRICULTURAL 4921533 INSECTICIDES, NEC, OTHER THAN LIQUID) POISON 8 NA2783 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Mevinphos mixture, dry is a yellow to orange liquid absorbed on a dry carrier. It is used as a pesticide, it is a wettable powder. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300. If material on fire or involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical tf materiel not on fire end not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Environmental considerations--land apill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water April 1981 Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates MEVINPHOS MIXTURE. LIQUID (AGRICULTURAL 4921539 INSECTC1DES, NEC, LIQUID) POISON 8 NA2783 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Mevinphos mixture, liquid is a ye:iow to orange liquid. It is used as a pesticide. It is a water emulsifiable liquid. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone; 800*424-9300. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes lo contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water apill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors MEXACARBATE (AGRICULTURAL INSECTICIDES, 4921541 NEC, LIQUID) POISON B NA2757 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Mexacarbate is a white solid dissolved in a liquid carrier. It is used as a pesticide. It is awater emulsifiable liquid. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Continued on next page 349 MCD 000010092 tf material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out Of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface Mow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors MEXACARBATE (AGRICULTURAL INSECUCIOES, 4921S42 NEC. OTHER THAN LIQUID) POISON B NA2757 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Mexacarbate is a white solid. It is used as a pesticide. It is a wettable powder, it is toxic by inhalation, skin absorption, and/or ingestion, in case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300. If material on fire or Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use `alcohol" foam, carbon dioxide or dry chemical If materiel not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom II dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates 350 MEXACARBATE (INSECTICIDES, OTHER THAN AGRICULTURAL, NEC) 4921540 POISON B NA2757 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Mexacarbate is a white solid or the solid dissolved in a liquid carrier. It is used as a pesticide. It is a wettable powder or water emulsitiabie liquid. It is toxic by inhalation, skin absorption, and/or ingestion. In case oi damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300. if material on fire or Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Environmental considerationa--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill It dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental consideraUona--air spill Apply water spray or mist to knock down vapors MILD DETONATING FUSE, METAL CLAD 4903355 CLASS C EXPLOSIVE Mild detonating fuse, metal dad consists of a core containing not more than 15 grains of high explosive composition per foot and not exceeding 26 feet in length or containing not more than 21/2 grains of high explosive composition per foot covered with metal. It may or may not be covered with tapes, yams, plastics or waterproofing compounds. Under fire con ditions they will explode, tf material on fire or Involved In Are Dangerously explosive Flood with water Apply water from as far a distance as possible If material not on firs and not Involved In fire Keep sparks, flames, and other sources of Ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this materiel Evacuation if fire becomes uncontrollable evacuate for a radius of 1500 feet April 1981 bcr> ooo2 093 MINE RESCUE EQUIPMENT CONTAINING CARBON 4904645 DIOXIDE NONFLAMMABLE GAS NA1956 Mine rescue equipment containing carbon dioxide consists of various apparatus and a cylinder of carbon dioxide. Carbon dioxide is nonflamm able and is heavier than air. It can asphyxiate by the displacement of air If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved In fire Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Wear protective gloves and goggles Do not handle broken packages without protective equipment Anempt to stop leak i without hazard Use water spray to knock-down vapors Oo not use water on material itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact wrth the material Wear full protective oothing Do not handle broken oackages without protective equipment Wash away any matenal which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered MINING REAGENT, LIQUID (CONTAINING 20% OR 4931442 MORE CRESYLIC ACID) CORROSIVE MATERIAL, ACIOIC NA2022 Mining reagent, liquid (containing 20% or more cresyfic add) is a variable colored liquid with a phenol-like odor. It is insoluble in water. It is corrosive to tissue. H material on Ore or Involved In fire Use water in flooding quantities as fog Solid streams ol water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Use water spray to absorb vapors H material not on tire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing MIXED CHLOROSfLANES (FLAMMABLE LIQUID, 4907636 CORROSIVE, N.O.S.) FLAMMABLE LIQUID, CORROSIVE UN2924 Mixed chiorosilanes are a dear colorless liquid having a pungent odor. It has a flash point of less than 100 deg. F. Both the liquid and vapor are corrosive, it is decomposed by water to give hydrochloric add. Its vapors are heavier than air. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use 'alcohol" foam, carbon dioxide or dry chemical Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Do not use water on material itself If large quantities of combustibles are Involved, use water in flooding quantities as spray and fog Use water 9pray to absorb vapors If materiel not on fire and not Involved in Are Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary April 1981 0000l094 HCD MIXED LOAD OF GROCERIES AND GROCERS 4950160 SUPPLIES Consult shipping paper for exact contents of the car. container or trailer MONOKTRICHLORO) TETRA-(MONOPOTASSIUM 4916420 OICHLORO) PENTA-S-TRIAZINETRIONE (ORY CONTAINING MORE THAN 39% AVAILABLE CHLORINE) OXIOIZER NA2468 Mono-(trichioro)tetra-(monopotassium dichloro) penta-s-triazinetrione is a white crystalline soSd with an odor of chlorine, it is used as a dry bleach in household clearing compounds and swimming pool disinfec tants. The material itself is rtoncombustibls but if contaminated with combustible material ignition can result. It will also accelerate the burning of combustible material. Contact with ammonium compounds or hy drated salts can cause a very vigorous chemical reaction. May vigorously react with small quantities of water releasing chlorine gas. Prolonged exposure of the material to fire or heat may result in the vigorous de composition of the material and the rupturing of its containers. Material containing less than 39% available chlorine will undergo reactions as described above though it may take longer to initiate and the resulting reaction may not be as vigorous. H material on Are or Involved In fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far s distance as possible If material not on fire and net Involved In fire Keep sparics, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If (Ire becomes uncontrollable--evacuate for a radius of 2500 feet 3S1 MONO-TERT-0UTYL-META-CRESOL (COMBUSTIBLE 4913172 LIQUID, N.O.S.) COMBUSTIBLE LIQUID NA1993 Mono-tert-butyl-meta-cresol is a clear colorless liquid. It is used as a disinfectant, to make rubber, as a lubricating oil additive, and for many other uses It has a flash point of 116 deg. I. and a melting point of 74 deg. F It is lighter than water and insoluble in water. If material on fire or Involved in fire Use water m flooding quantities as fog Solid streams of water may be ineffective Coot all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol" foam, carbon dioxide or dry chemical Use water spray to absorb vapors If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water MONOBROMOTRIFLUOROMETHANE 4904549 NONFLAMMABLE GAS UN1Q09 Monobromotrifluorornethane is a colorless, odorless gas. It is shipped as a liquefied gas under its own vapor pressure. It is noncombustible. It can asphyxiate by the displacement of air. Contact with the liquid can cause frostbite. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved in fire Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment MONOCHLOROACET1C ACID, LIQUID 4931444 CORROSIVE MATERIAL, ACIDIC UN1750 Monochloroacetic acid, liquid is a colorless solution of the white crys talline solid, it is corrosive to metals and tissue. If materiel on fire or involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use water spray to absorb vapors If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material 352 Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing MONOCHLOROACETONE, STABILIZED OR INHIBITED 4925250 IRRITATING MATERIAL UN1695 Monochloroacetone. stabilized or inhibited is a colorless liquid with the pungent odor characteristic of hydrochloric acid. Its vapors are ex tremely irritating to the eyes and mucous membranes. If material on fire or involved In fire Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical Cool ail affected containers with flooding quantities of water Use water spray to absorb vapors If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Evacuation If material leaking (not on fire), downwind evacuation must be considered MONOCHLOROOIFLUOROMETHANE 4904552 NONFLAMMABLE GAS UN1018 Monochlorodifluoromethane is a colorless gas with an ethereal odor. It is shipped as a liquefied gas under its own vapor pressure. It is noncombustible. it can asphyxiate by the displacement of air. Contact with the liquid can cause frostbite. Toxic gases can be produced in fires involving this material. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If materiel not Involved In fire Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment MONOCHLOROETHYLENE (See VINYL CHLORIDE, MONOMER 4905792) MONOCHLOROPENTAFLUOROETHANE 4904555 NONFLAMMABLE GAS UN1020 Monochioropentafluoroethane is a colorless odorless gas with an ether tike odor. It is shipped as a liquefied gas under its own vapor pressure. H is noncombustible. It can asphyxiate by the displacement of air. Contact with the liquid can cause frostbite. April 1981 MCD 000010095 K material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved In fire Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment MONOCHLOROTETRAFLUOROETHANE 4904556 NONFLAMMABLE GAS UN1021 Monochiorotetrafluoroethane is a colorless odorless gas. It is shipped as a liquefied gas under its own vapor pressure. It can asphyxiate by the displacement of air. Contact with the liquid can cause frostbite. It may only be shipped in cylinders. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved in fire Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment MONOCHLOROTRIFLUOROMETHANE 4904560 NONFLAMMABLE GAS UN1022 Monochlorotrifluoromethane is a colorless odorless gas. it is shipped as a liquefied gas under its own vapor pressure. It is noncombustible. It can asphyxiate by the displacement of air. Contact with the liquid can cause frostbite. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment MONOETHANOLAMINE 4935665 CORROSIVE MATERIAL, BASIC, COMBUSTIBLE UN2491 Monoethanolamine is a dear colorless liquid with an ammonia like odor. It is combustible and has a flash point of 165 deg. F. It is soluble in water with release of heat. It is corrosive to metals and tissue. Toxic oxides of nitrogen are produced during combustion of this material. If material on fira or Involved In fire Do not extinguish fire unless flow can be stopped Use water in Hooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use `alcohol" foam, carbon dioxide or dry chemical April 1981 MCD 000010096 If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing MONOETHYLAMINE 4907835 FLAMMABLE LIQUID, BASIC UN1036 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Monoethylamine is a clear colorless liquid with an ammonia-like odor. It has a flash point of less than 0 deg. F. and boils at 62 deg. F. It is corrosive to the skin and eyes. It is lighter than water and soluble in water. Its vapors are heavier than air. Toxic oxides of nitrogen are produced during combustion of this material. It weighs 5.7 pounds per gallon. If material on fire or involved In fire Do not extinguish fire unless (low can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Use water spray to absorb vapors If material not on fire and not Involved In fire Keep sparks, (lames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Avoid bodiiy contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash, cement powder, sawdust, or com mercial sorbents Apply "universal" gelling agent to immobilize spill Neutralize with sodium bisulfate (nahso4) Continued on next page 353 Environmental conaldaratlona--water aplll Add sodium bisulfate if dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment MONOFLUOROPHOSPHORIC ACID, ANHYDROUS 4930240 CORROSIVE MATERIAL, ACIOIC UN1776 Monofluorophosphoric acid, anhydrous is a colorless odorless liquid. It is soluble in water with release of heat. It is corrosive to metals and tissue. If material involved In fire Extinguish fire using agent suitable for type of surrounding tire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible tf material not involved In fir* Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing MONOISOPROPANOLAMINE (CORROSIVE LIQUID. 4935626 N.O.S.) CORROSIVE MATERIAL, BASIC UN1760 Monoisopropanalamine is a colorless liquid with a slight ammonia like odor. It is used In plastics, paints, cutting oils, and specialized cleaning compounds. It is lighter than water and is insolubie in water. It is com* bustible and has a flash point of 165 deg. F. It is corrosive to metals and tissue. Its vapors are heavier than air. toxic oxides of nitrogen are produced during combustion of this material tf material on fire or involved in fire Do not extinguish tire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material 354 Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing MONOMETHYLAMINE, ANHYDROUS 4905530 FLAMMABLE GAS UN1061 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Methylamine, anhydrous is a colorless gas with a fish-lik odor at low concentration having ammonia-like odor at higher concentrations, it is used to make other chemicals, as a solvent, in paint removers, and for many other uses. It is shipped as a liquefied gas under its vapor pressure. Contact with the liquid can cause frostbite or chemical type bums. The gas itself is corrosive and it is soluble in water to form flammable cor rosive solutions. It is easily ignited. Its vapors are heavier than air and a flame can flash back to the source of leak very easily. It can asphyxiate by the displacement of air. Under fire conditions the cylinders or tank cars may violently rupture and rocket. Toxic oxides of nitrogen are pro duced during combustion of this material. It weighs 5.5 pounds per gallon. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as log Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear seif-contained breathing apparatus Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet If material leaking (not on fire), downwind evacuation must be considered Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Oike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash, cement powder, sawdust, or com mercial sorbents Neutralize with sodium bisulfate (nahso4) Environmental considerations--water aplll Use natural barriers or oil spill control booms to limit spill motion Use surface active agent (e.g. detergent, soaps, alcohols) to com press and thicken spilled material Inject "universal" gelling agent to solidity encircled spill and increase effectiveness of booms If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Add sodium bisulfate Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment April 1981 MOD 000010097 MONOMETHYLAMINE, AQUEOUS SOLUTION 4907840 FLAMMABLE UQUIO, CORROSIVE, BASIC UN1235 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Monorneihytamine, aqueous solution is the solution of monomethy- lamine, a gas. in water and has an odor ranging from fish-like to am monia-like as the vapor concentration increases. It has a flash point less than 100 deg. F. It is corrosive to skin and eyes. The solution is lighter than water and soluble in water. Its vapors are heavier than air. Toxic oxides of nitrogen are produced during combustion of this material. It weighs 7.4 pounds per gallon. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as tog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol" foam, carbon dioxide or dry chemical Use water spray to absorb vapors It material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear full protective clothing Do not handle broker packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear seif-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash. cement powder, sawdust or com mercial sorbents Apply "universal" gelling agent to immobilize spill Neutralize with sodium bisulfate (nahso4) Environmental considerations--water spill Add sodium bisulfate If dissolved, apply activated carbon at tan times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerationa--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment MORPHOLINE 4907846 FLAMMABLE UQUIO, CORROSIVE UN20S4 Morpholine is a colorless liquid with a fish-like odor. It is used to make other chemicals, as a corrosion inhibitor, and in detergents. It has s flash point of 100 deg. F. It is corrosive to metals and tissue. It is lighter than water and is soluble in water. Its vapors are heavier than air. If matarlal on flra or Invoivad In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective April 1981 MOD 000010098 Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical tf material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet tf material leaking (not on fire), downwind evacuation must be considered MORPHOLINE, AEQUOUS MIXTURE 4935666 CORROSIVE MATERIAL NA1760 Morpholine, aequous mixture is a colorless liquid with a fish-like odor dissolved in water. It is used to make other chemicals, as a corrosion inhibitor, and in detergents. It is corrosive to metals and tissue. It will bum though it may require some effort to ignite. Its vapors are heavier than air. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use "alcohol" foam, carbon dioxide or dry chemical If material not on flra and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting Ikes involv ing this material If contact with the material anticipated, wear full protective clothing MORPHOLINE, AEQUOUS MIXTURE 4907647 FLAMMABLE LIQUID, CORROSIVE NA2054 Morpholine, aequous mixture is a colorless liquid with a fish-like odor dissolved in water. It is used to make other chemicals, as a corrosion inhibitor, and in detergents. It is corrosive to metals and tissue, ft has a flash point of 100 deg. F. Its vapors are heavier than air. Continued on next pege 355 ff material on Are or involved in fire Use water in Hooding quantities as fog Do not extinguish fire unless flow can be stopped Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use 'alcohol" foam, carbon dioxide or dry chemical ff material not on fire and not Involved In Are Keep sparks, flames, and other sources of Ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered MORTAR STAIN, LIQUID 4915230 COMBUSTIBLE LIQUID UN1263 Mortar stain, liquid may be formulated with a flammable solvent which has a flash point between 100 and 199 deg. F. The hazard is combustibility. ff material on Are or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical ff material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water MORTAR STAIN, LIQUIO 4910230 FLAMMABLE LIQUID UNI 263 Mortar stain, liquid may be formulated with a flammable solvent which has a flash point below 100 deg. F. The hazard is flammability. H material on firs or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective 356 Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep matenai out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water MOTOR FUEL ANTIKNOCK COMPOUND (OR) 4921445 ANTIKNOCK COMPOUND (THESE MATERIALS MAY CONTAIN VARIOUS HAZARDOUS SUBSTANCE FOR WHICH THE APPROPRIATE RQ APPLIES) POISON B UN1649 ENVIRONMENTALLY HAZARDOUS SUBSTANCE Motor fuel antiknock compound is a variable colored liquid with a mildly pungent sweet odor. It is also a flammable or combustible liquid. It is heavier than water and insoluble in water. It is toxic by inhalation and by skin absorption, Prolonged exposure of the material to fire or heat can result in the spontaneous decomposition of the material. If the decomposition takes place inside a container, the container may violently rupture and rocket. It weighs 13.6 pounds per gallon. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use loam, carbon dioxide or dry chemical If material not on Art and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation ff Are becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feel ff material leaking (not on fire), downwind evacuation must be considered Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Oike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk Squid with fly ash, cement powder, sawdust, or com mercial sorbents April 1981 MOD 000010099