Document wrKeZ9XnvGaNNnxKknEbJDDB4

y Prim Offi. , 3.H filft*? & jit I'M MATERIAL SAFETY DATA SHEET Product Nams , pyp g-pos----------------------- SECTION I - PRODUCT IDENTIFICATION. product NAME and SYNONYMS; Polyvinyl chloride cotin, PVC resin, Chloroetbylene polymer, Chloroetbylene homopolymer, PVC 1095. CAS NAME AND NO.i CHLOROETHYUNE POLYMER 19002-86-21 CHEMICAL FAMILY: Vinyl retin CHEMICAL FORMULA: (Cyl^Cl), MANUFACTURER'S NAME AND ADDRESS Georgia Culf Corporation PVC Division P.O. BOX 629 Plaquemine, Louisiana 70765-0629 EMERGENCY TELEPHONE NO.: (504) 685-2500 or (800) 424-9300 SECTION II - HAZARDOUS INGREDIENTS. COMPONENT * (WT OR VOL) Vinyl Chloride < 0-0002 ACGIH TWA (UNITS) ACGIH STEL (UNITS) OSHA PEL (UNITS) 5 ppm/15M Cl 1 ppm/BH TWA PVC Dust should not exceed IS rag/m3 average per 8 hour day (29 CFR 1919.1000) SECTION TII - PHYSICAL PROPERTIES APPEARANCE AND ODOR; White powder, odorless MOLECULAR WEIGHT: e* 94,000 weight average noted DEC 1886 80ILINC POINT (DECREES FAHRENHEIT): N/A MELTING POINT (DECREES FAHRENHEIT); N/A CAROLE G. MARTIN VAPOR PRESSURE (MM. OP MERCURY): 0.1 SPECIFIC GRAVITY (WATER 1); 1,39 PRIVILEGED AND "CONFIDENTIAL MATERIAL SUBJECT TO PROTECTIVE ORDER" Page 1 of 6 EXHIBIT 5 UCC 080052 *. r r PVC 1095 VAPOK DENSITY (AIR -_Ui H/A PERCENT VOLATILE (BY WEXCHtli 0 pH: Solld-N/A SOLUBILITY IN WATER: Non* EVAPORATION RATE (BUTYL ACETATE 1): Non* PRIVILEGED AND "CONFIDENTIAL MATERIAL SUBJECT TO PROTECTIVE ORDER" SECTION IV - FIRE AND EXPLOSION DATA fLASH POINT: SOO* F (COC) FIRE EXTINGUISHING MEDIA: Carbon dioxide or water FLAMMABLE LIMITS (PERCENT BY VOLUME): LOVER UPPER N/A N/A SPECIAL FIRE FIGHTING PROCEDURES & EQUIPMENT; Wear gt> mask approved for acid vapors. UNUSUAL FIRE AND EXPLOSION HAZARDS: PVC will not continue to burn after Igni tion without an external fire source. Burning liberal** HCl gas. SECTION V - REACTIVITY DATA STABILITY: UNSTABLE ______ STABLE X_ CONDITIONS TO AVOID: Temperature above 300* F - will decompose raw resin and liberate HCl. INCOMPATIBILITY (MATERIALS TO AVOID): Polyvinyl chloride compound* ghould not come Into contact with Acetal or Aoetal copolymers in elevated teroper- ature processing equipment. Th* two materials are not compatible and will react In a violent decomposition when mixed under conditions of heat and .pressure., HAZARDOUS DECOMPOSITION PRODUCTS: Low release of HCl When heated above 300* F. HAZARDOUS POLYMERIZATION: WILL OCCUR ______ WILL NOT OCCUR ___ 5-- CONDITIONS TO AVOID: N/A Page 2 of 6 UCC 080053 o wL v^ oZortjJaSuIF] fr^yi 6i(f K*tOgki fc" Ml*? ,U,iW C/^" AUlf MATERIAL SAFETY DATA SHEET Product Nams --pyc-t^s------- --------------- SECTION VI - HEALTH HAZARD INFORMATION EFFECTS OF OVEREXPOSURE: Polyvinyl chloride as a ratio i more or 1*M lnart at measured by oral L050. Its main hatards. if any, would ba associated with unreacted vinyl chloride monomer (centrally extremely small amounts) and other additives in the plastic. Pneumoconiosis has been described from inhalation of the dust which should be avoided. Combustion products of Polyvinyl Chloride may result In an asthma syndrome. Check OSKA VCM Regulation 29 CFR, Title 29, Chapter XVII, Part 1910. * PROBABLE ROUTES OF EXPOSURE; Inhalation (of dust) EMERGENCY AND FIRST AID PROCEDURES INGESTION; Practically inert. INHALATION: Remove victim to fresh air. Get medical attention If necessary. EYE CONTACT: Flush with water. Do not bub. See physician if residual foreign body is suspected. SKIN CONTACT: N/A SECTION VII - TOXICITY DATA OML: N/A DERMAL: N/A INHALATION: Mouse LC5> - 140 mg/m3/10M CARCINOCENICITY: This material contains vinyl chloride which is a cancer suspect agent, PVC meets ETECS criteria as an equivocal tumorigenic agent - tumors of the lungs, thorsx or respiratory system; tumors of the skin (rat --- oral). This material may contain trace amounta of vinyl chloride which is a cancer-suspect agent. Polyvinyl chloride is listed by IARC. as of 1983, as an indefinite suspect in humans. There is no polyvinyl chloride listing in MTP Fourth Annual Report on Carclnoteni. 1985. OSHA. as of 1/30/86, does not list polyvinyl chloride per se but requires label ing that it may contain vinyl chloride monomer which Is listed as a cancer suspect agent. PRIVILEGED AND gT.HER PERTINENT QATA: N/A "CONFIDENTIAL MATERIAL SUBJECT TO PROTECTIVE ORDER" Page 3 of 6 UCC 080054 A OOv PVC 1095 SECTION VIII - SPECIAL PROTECTION INFORMATION PERSONAL PROTECTIVE EQUIPMENT PROTECTIVE CLOVES; N/A ETE PROTECTION: Safety Glasses (fop dust) RESPIRATORY PROTECTION (SPECIFY TYPE): Any MSHA-approved dust respirator OTHER; N/A VENTILATION . LOCAL EXHAUST; As required for general work areas. MECHANICAL (GENERAL); N/A SPECIAL; N/A OTHER; N/A PRIVILEGED AND "CONFIDENTIAL MATERIAL SUBJECT TO PROTECTIVE ORDER" SECTION II - SPILL. LEAK. AND DISPOSAL PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Vacuum, sweep, or shovel Up. WASTE DISPOSAL METHODS: Landfill, high temperature s\odern incineration under controlled conditions due to formation of HCl. CLEAN WATER ACT REQUIREMENTS: N/A RESOURCE CONSERVATION AND RECOVERY ACT (KCRA) REQUIREMENTS: N/A SECTION X - REGULATORY INFORMATION FDA: - Approved for use In film wrap under prior sanction provided that POA'Speelfled quality assurance tests are met. (See ASTM standards 1243-66 and 3030-22.) Also approved for use In cellophane (177.1200). Regulated under 21 CFE 176.180 for safe use as compo nent of the uaeoated or coated food-contact surface of paper and pa perboard intended for use In producing, manufacturing, packing, pro cessing. preparing, treating, packaging, transporting, or holding any f od of the typ Identified In $176.170(c), table 1, under type Page 4 of 6 UCC 080055 i ** : 'J tn Z *ri <4i0 V n b D J ti t fc ^ w *o <Sn*fM> cc - F>*Ofi,r*t Mf)*' Gff*W J#!M* MATERIAL SAFETY DATA SHEET Product Nsms rvvec 109s VIII. Alto liittd undtr $175,105 tc t subatenee for ut at component of adheiives. Ittulittd undtr J17S.300O)(tv) tod 5175.320(b)(3) Resinous and polymeric coatings for food-eontaet surfaces, and for polyolefin films, respectively. USDAt USDA self-certification (9 CFR 317.20); is Approved. CPSC; Nob listed-In Hazardous Substaneat Labeling Guides. TSCA: CAS #9002-86-2 DOT PROPER SHIPPING NAME: Polyvinyl ehlorlda HAZARD CUSS: N/A LABEL REQUIRED: H/A IDEHTIFICATIOH NO.: H/A OTHER PERTINENT INFORMATION; H/A OSHA: PVC may contain a vary low. level of VCH- Therefore, under normal working conditions with adequate ventilation, OSKA's PEL (1 ppm) should not be exceeded. The workplace should be monitored, and if the level exceeds the PEL. refer to 29 CFR 1910.1017. In addition, containers of PVC shall be legibly labeled: POLYVINYL CHLORIDE COHTAlNS VIHYL CHLORIDE VINYL CHLORIDE IS A CANCER-SUSPECT AGENT SECTION XI - SPECIAL PRECAUTIONS AND COMMENTS PRECAUTIONS-TO BE TAKEN IN HANDLING AND STORING: 100" F. OTHER PRECAUTIONS: H/A REOISTRATIOH/CERTIFICATION: H/A Store In dry area below PRIVILEGED AND "CONFIDENTIAL MATERIAL SUBJECT TO PROTECTIVE ORDER" EFFECTIVE DAT?; 11/24/86 SUPERSEDES: 8/18/86 PREPARER: C.J.Koch PHONE HUMBER: <404) 395-4585 Page $ of 6 ucc 080056 4k * V v Y PVC 1095 IMPOSTANT; Tbt Information and data htraln ara believed to ba accurata and bava baan compilad from aoureat believed to ba reliable. It la offarad for four consideration. Investigation and varlfleatlon. Buyer assume* all risk of uta,.storage and handling of tha product In compllanca with appllcabla fadoral, atata and local laws and regulation*. CEORGIA-CULF HAKES NO WARRANTY OF ANY KINO, EXPRESS OK IHPLIED, CONCERNING THE ACCURACY OK COMPLETENESS OF THE INFORMATION AND DATA HEREIN. Gaortla-Culf will not ba llabla for claim* relating to any party'i uta of or rallance on Information and data contained herein reg*rdl**#of whather It 1* claimed that tha information and data are inaceurata, incomplete or otherwise misleading. This Information relates to the material designated and may not ba valid for such material' used in combi nation with any other materials or in any process. MAJOR SOURCES USED FOR MSPS PREPARATION 1) nTh* Condensed Chemical Dictionary," Tenth Edition, 1981 2) "Threshold Limit Values for Chemical Substances in the Work Environment Adopted by ACGIH for 1966-87," American Confer ence of Governmental Industrial Hygienists 3) "OSHA Safety and Health Standards <29 CFR 1910) OSKA 2206," Revised March 11, 1983, U. S. Department of Labor, Occupa tional Safety and Health Administration 4) "Occupational Health Guidelines for Chemical Hazards," Pre pared for National Institute for Occupational safety end Health, January 1981, U. S. Department of Commerce National Technical Information Service 5) "NIOSH Pocket Culde to Chemical Hazards," September 1985. V. S. Department of Health & Human Services 6) "Registry of Toxic Effects of Chemical Substances," 1983 Supplement to the 1981-82 Edition, U. S. Department of Health & Human Services, Public Health Service, NIOSH 7) "Fourth Annual Beport on Carelnogeni1985, National Toxi cology Program (NIP), U. S. Public Health Service. Page 6 of 6 PRIVILEGED AND "CONFIDENTIAL MATERIAL SUBJECT TO PROTECTIVE ORDER" UCC 080057