Document wrJZYkwjRzbKpgyYXowo32L34

i ROLES AND REGULATIONS . * 48303^ i . (3) The Administrator shall be notl- (2) The maximum 24-hour period (f) All sludge samples Shall be ana " fled at least 30 days prior to an emission sludge incineration or drying rate shall lyzed for mercury content within 30 days test, so that he may at his option observe be determined by use of a flow rate meas after the sludge sample is collected. Each '' the test. urement device that can measure the determination shall be reported to the. (4) Samples shall be taken over such' mass rate of sludge Charged to the in i ' a period or periods as are necessary to cinerator or dryer with an accuracy of * determine accurately the maximum 5 percent over its operating range. emissions which will occur in a 34-hour Other methods of measuring sludge mass period. No changes shall be made in the charging rates may be.used If they have Administrator by a registered letter dis- ' patched before the close of the next busi ness day following such determination. (g) Records of sludge ""p1lTig. charg ing rate determination and other data operation which would potentially in received prior approval by the Adminis needed to determine mercury content crease emissions above the level deter- trator. of wastewater treatment plant sludges . mined by the most recent stack test, un (3) The handling, preparation, and shall be retained at the source and made til the new emission level has been esti analysis of sludge samples shall be ac available, for inspection by the Admin mated by calculation and the results re complished according to Method 105 in istrator, for a minimum of 2 years. ported to the Administrator. ` (5) All samples shall be analysed, and Appendix B of this part. (d) The mercury emissions .shall be 6 61.55 Emission monitoring. 1 mercury emissions shall be determined determined by use of the following (a) Wastewater treatment plant sludge within 30 days after the stack test Each equation: incineration and drying plants. All such' determination shall be reported to the Administrator by a registered letter dis patched before the close of the next busi ness day following such determination. (6) Records of emission test results and other data needed to determine total emissions shall be retained at the source and shall be made available, for inspec tion by the Administrator, for a mini where Kar=l x 10-* c9 gsi=SIercury emissions, g/day. . e =Mercury concentration of sludge on a dry eollds basis, sg/g (ppm). Q =81udge charging rate, kg/day. (e) No changes in the operation of a plant shall be made after a sludge test has been conducted which would poten sources for which mercury emissions ex ceed 1600 g/day, demonstrated either by stack sampling according to {61.53 or sludge sampling according to (61.54, shall monitor mercury emissions at totervals of at least onoe per year by use of Method 105 of Appendix B, or the proce dures specified in ( 61.64(c) and (d). The results of monitoring shall be reported mum of 2 years. tially increase emissions above the level and retained according to ( 61.53(d) (5) 14. Sections 61.54 and 61.55 are added as follows: 61.54 Sludge sampling. (a) As an alternative means for determined by the most recent sludge test, until the new emission level has been estimated by calculation and the results reported to the Administrator. and (6), or { 61.54(f) and (g). | 15. Appendix A is revised to a new re porting format, and sections (Z) (C) and (I) (D) are added as follows: * demonstrating compliance with { 61.52 Cb), an owner or operator may use .APPENDIX A Method 105 of Appendix B and the proce dures specified in this section. National Emission Standards for Hazardous Air Pollutants (1) A sludge test shall be conducted Compliance Status Information within 90 days of the effective date of these regulations in the case of an exist ing source or a new source which has an initial startup date preceding the effec tive date; or I. SOURCE REPORT . (2) A sludge test shall be conducted within 90 days of startup In the case of a new source which did not have an initial startup date preceding the effective date. INSTRUCTIONS: Owners or operators of.sources of hazardous pollutants subject to the National Emission Standards for Hazardous Air Pollutants are required to submit the information contained (b) The Administrator shall be notified In Section I to the appropriate U.S. Environmental at least 30 days prior to a sludge sampling test, so that he may at his option observe the test (c) Sludge shall be sampled according Protection Agency Regional Office prior to 90 days after the effective date of any standards or amend ments which require the submission of such Information. to paragraph (c) Cl) of this section, A list of regional offices Is provided In 161.04, sludge charging rate for the plant shall be determined according to paragraph A. SOURCE INFORMATION (c) (2) of this section, and the sludge analysis shall be performed according to 1, Identification/Location - Indicate the aim and address of each source. paragraph' (c) (3) of this section. (1) -The sludge shall be sampled after 1 2 3 4 5___ -8 - 913 0 0 0 0 fr 1 Region State county Source Number IT IS 17 IS IT, dewatering and before incineration or drying, at a location that provides a representative sample of the sludge that 20____ 22 AqCR f 23____26 City Code ' 27 Source Name TS 1 is charged to the incinerator or dryer. Eight consecutive grab samples shall be 4/ street Address (Location of Plant) 66 W * obtained at Intervals of between 45 and 60 minutes and thoroughly mixed into one sample. Each of the eight grab sam Dup 1-18 TT 21T---------- City HSwf:---------34 Stale 35-----39 ples shall have a volume of at least 200 ml but not more than 400 ml. A total of three composite samples shall be ob tained within an operating period of 24 hours. When the 24-hour operating pe riod Is not continuous, the total sam 6558 40 state Regis. Number 54 NEDS X Ref. . 8 5IC 53 TF VP 64 65 77 79 SUTT SIT - pling period shall not exceed 72 hours after the first grab sample is obtained. Samples shall not be exposed to any con Dup 1-38 5 TT " . t? . SIP TC 30 31 49 jAw HT , , v dition that may result In mercury con tamination or loss. 2. Contact Indicate the name and telephone msnber of the owner or operator or other responsible official whom EPA may contact concerning this report. FEDERAL REGISTER, VOL 40, NO. 199--TUESDAY, OCTOBER 14, 1975 :&! n PLAINTIFF'S EXHIBIT C 003213 A MON-2534 LAM022863 RULES AND REGULATIONS Pup 1-18 4 1 ino 2T T3 44_____ 46 ' -______ ,, " Ari Code 47 Humber54 W 3. Source Description - 8r1efly state the nature of the source (e.g...'Chlor alnail Plant'or "Machine Shop*}. Dup 1'18 19^25 21---------:-----------Oescrlptton-------------------------- W 51 Continued T9 BT 4. Alternative Hailing Address - Indicate an alternative nailing address if correspondence Is to be directed to a location different than that specified above. Pup 1-18 43 ino 2T" (lustier Street of box nutter 49 . W Dup 1-18 4 4 21--------- rniy------------------ 35 8Itale? 41 'Zip' 44 55 1 19 20 S. Cotollance Status - The emissions from this source _ can __ cannot meet the emission limitations contained In the Motional Emission Standards on or prior to 90 days after the effective date of any standards or amendments which require the submission of such Information. signature of owner. Operator of'Qtner Responsible official VOTfe: if the emissions from the source will exceed those limits set by the National Emission Standards for Hazardous Air Pollutants, the source will be In violation and subject to Federal enforcement actions unless granted a waiver of compliance.by the Administrator of the U.S. Environmental Protection Agency. The information needed for , such waivers Is listed In Sectton II of this form. 8. PROCESS 1HFORHATIOH. Part 8 should be completed separately for each point of emission for each hazardous pollutant. [Sources subject to 61.22(1} may omit number 4. below.] Dud 1-13 005 14--16 17--ft 1? 25~`--S5C-------27 2ST9 35 3T NEDS X Ref LS SIP , 1 KDERAl REGISTER, VOL 40, NO. 199--TUESDAY, OCTOBER 14, 197S C 003214 l LAM022864 . RULES AND REGULATIONS 1. Pollutant Emitted - Indicate the type of hazardous pollutant emitted by the process. Indicate *AB" for asbestos, "BE* for beryl Ilia, or "HQ* for mercury, 32 33 4 Pollutant 34 Regulation. 48 EC 2. Process Description - Provide a brief description of each process (e.g., Hydrogen end box" in a mercury chlor-alkall plant, "grinding machine" In . a beryllium machine shop}. Use additional sheets If necessary. 148305 SD------------- Process `Description DUP 1-18 6 1 19 Tb 21 -------- 74 nr so SI 75 80 . * Dup 1-18 62 is a 21 so SI- 75 nr 3. Amount of Pollutant - Indicate the average weight of the hazardous material named in Item 1 which enters the process in pounds per month (based on the previous twelve months of operation). Dup 1-18 6 3 19--2b 2T lbs./mo. ~7r w "36 4. Control Devices . - T. indicate the type of pollution control devices. If any, used to reduce the emissions from the process (e.g., venturi scrubber, baghouse, wet cyclone) and the estimated percent of the-pollutant which the device removes from the process gas stream. Dup 1-18 6 4 llTTO 21 PRIMARY CONTROL DEVICE: * 4'3 45 Primary Device Name 86 70 64 "Percent Removal 72 75 i ' i ` '..V or f I$ . I \V fOEKAL REGISTER, VOL 40, MO. 199^-TUESOAY, OCTOBE1 14, 19TS C 003215 LAM022865 -$.k : v7' .48306 RULES AND REGULATIONS Duo 1-18 6 5 SECONDARY CONTROL DEVICES: 19 20 21----------------------------------------------------------------XS 47 Secondary Device Name 64 66 70 72 * HTIC* rn9 n|mri Percent Removal Efficiency b. Asbestos Emission Control Devices Only I. If a baghouse is specified in Item 4a, give the following Information: i The air flow permeability in cubic feet' per minute per square foot of fabric area, Air flow permeability * cfa/ft2 The pressure drop in Inches water gauge acrqss.the filter at which the baghouse is operated. Operating pressure drop inches w.g. If the baghouse material contains synthetic fill yam, check whether this material is / / spun / / or not spun. If the baghouse utilizes.a felted fabric, give the minimum thickness in inches and the density in ounces per square yard. 2 Thickness =Inches Density .. oz/yd II. If a wet collection device is specified in Item 4a, give the designed unit contacting energy in Inches water gauge. , Unit contacting energy'*Inches w.g. C. DISPOSAL OF ASBESTOS-CONTAINING HASTES. Part C should be completed separately for each asbestos-containing waste generation operation arising from sources subject to 161.22(a), (c), (e), and (h). Duo 1-13 14------ T6 00 17 fa 5 T9 20 see 27 2ST9 w 3T NEDS X Ref cs SIP AB 32 3*3 34 Pollutant Regulation 48 49 EC i \* \ FEDERAL REGISTER, VOL. 40, NO. 199--TUESDAY, OCTOBER 14, 1975 c LAM022866 RULES AND REGULATIONS 1. Waste generation - Provide a brief description of each process that generates asbestos-containing waste (e.g. disposal of control device wastes}.. 60 ' Process Description 79 ; W 2. Asbestos Concentration - Indicate the average percentage asbestos content of tnese materials. Dup MB ^ 2[ ASBESTOS COHCBp*nON:^ ; ' OT W 3. Amount of Wastes - indicate the average weight of asbestos-containing wastes disposed of. measured In kg/da/. Dup 1-18 6 2 im> 2T ' tg/<fay TT 21 14 4. Control Hethods - Indicate the mission control methods used la all stages of waste disposal, fron collection, processing, and packaging to transporting and deposition. r Dup 1-18 6 3 Prlaarv Control Hethod 13 ZD 2T 13 41 Dup 1-18 64 13^TD 2T 73 10 W- 5T 73 / OT 5; Waste Disposal - Indicate the type of disposal site (sanitary landfill, open, covered/ or Incineration site (municipal, private) where the waste Is disposed of and who operates the site (company, private,municipal). State the name and location of the site (closest city or town, county, state}. Dup 1-18 6 5 13 ZD 21 TYPE OF SITE: 13 ; 31 3D 5T 73 . W 48307. i SEDESAl SEGISTH, VOL 40, NO. |*_TUESDAY, OCTOBB 14, 1079 C 003217 * LAM022867 RULES AND REGULATIONS Dug 1-18 8 8 IS 2D OPERATOR: T9 3l 61---------------- :-- Dup 1-18 67 IS 2b LOCATION: 21 ------- 29 sr 7T T9 TO TO D. WASTE DISPOSAL SITES. Part S should be csnpleted separately for each asbestos waste disposal site subject to section 61.22(1), . Dup 1-13 ______ 00 S IS------T6 17--19 IT 2ff--29 35 3T NEDS X Ref CS SIP 32*^33 53 39 Pollutant Regulation T9 59 EC WASTE DISPOSAL SITE 60----------------------------------------- T9 -55 1. Description - Provide a brief description of the site. Including Its size and configuration, and the distance to the closest city or town, closest residence) and closest primary road, Dup 1-18 6 1 19 70 2T SITE DESCRIPTION "37 3T "50 51------------------------------------------------ "79 55 Dup 1-18 6 2 DISTANCE: TOWN: - lrri) 21------------------ T9 30 54 35" TO 42TT3 RESIDENCE: 43" T9 ST" K N ROAD: TO 62 53 65 T9 rr "75 KM 77--78 55 F' f is, U K FEDERAL REGISTER, VOL 40, HO 199--TUESDAY, OCTOBER 14. I97S C 003218^ LAM022868 RULES AND REGULATIONS' 2. Inactivation - After the site is tnactivated, Indicate the Method or Methods used to comply with the standard end said a- list of the actions that Mill be undertaken to maintain the inactivated site. Dup 1-18 6 8 15 20 ZT HETHSSffiMsiTE: "52 ':t-v ST 79 ar 48309 P li .'.i- II. WAIVER REQUESTS ? I . "rj-Cjt I' - V'*, 1t ' .ttfl H. I A. WAIVER OF COMPLIANCE. Owners or operators of'sources unMabbiltet_o__o,perate In - ^ *1$** ^ conpllance with the National Emission Standards for Hazardous Air Pollutants prior to 90 days after the effective date of any standards or'amendments which require the submission of such ' from the Administrator of the U. time period necessary to install '"..y - - modifications to achieve'compliance' of compliance with the standard for the effective date of the hazardous pollutant standards, if he finds .that such period is necessary for. the installation of controls and that steps will be taken during the period of the waiver to assure that the health .* Wire's* toil of persons will be protected from imminent endangerment. ' `vv-' The report information provided in Section I must accompany this application. , S V l.' : - ' Applications should be sent to the appropriate EPA regional office. - ., ..- 1. Processes Involved - Indicate the process or processes emitting hazardou*K^.i%fe,,v''{[it,^r, ' pollutants to which emission controls are to be applied. 2. Controls Describe the proposed type of control device tb be added or modification to be made to the process to' reduce the emissions of hazardous pollutants'to an acceptable level. (Use additional sheets if necessary.) -t-- V b. Describe the measures that will be taken during the waiver period to assure that the health of persons will be protected from iiuninent endangerment. (Use additional sheets if necessary.) 3. Increments of Progress - Specify the dates by which the following increments of progress will be met. . .-Wr& ',,Y. i V ,, *ii- aVll ** ' /3 Date by which contracts for emission control systems or process modifications will be awarded; or date by which orders will be issued for the purchase of the component parts to accoeplish emission control or process modification. -r.*; ' i. ] ? * ii ;/ FEDERAL REGISTER, VOL 40, NO. 199--TUESDAY, OCTOBER 14, 1975 J i . iTi*'- . - / !;. C 003219 LAM022869 .M BOISS AND RBOULATIONS * . h -r>, " Dup 1-16 01 7 it--rs r sr bled as shown In Figure 106-1. in place of too? nr magnesium perchlorate drying tube, small i leading lamp with MW bulb may Mod to' Oat* of Initiation of on-sit* oattmettfe or taitaliatloo of Mission control oqulpant or process prevent condensation of molsturo tnslde tbs' cell. The lamp Is positioned eoas not to Inter-a ten with the measurement and to shine onj the absorption cell maintaining the air tern- i Dup 1-16 0*7 17-------T9 soi ar - omm-- w peratun about 6'C above ambient. 8. Reagents. 3.1 Analysts. Data fey which on-site construction or.Installation of Mission control equlpaent or process notification Is to he conpleted. 8.1.1 Aqua Regia--Prepare Immediately^ before use by carefully adding three volumes: - of concentrated HC1 to one volume of eon-j tup M6 i70JLZt5 jam s?--* a fl ho/bvtw a r centrated HNO,. 3.12 Sulfuric Add, 02N--Dilute 142 ml . of concentrated sulfuric acid to 12 liter. Date by which final cenpliance Is to be achieved. 342 Stannous Sulfate--Add 26 g etan-, nous sulfate to 280 ml of 02N sulfuric acid. Dup 1-16 047 17------ 17 sra sr Til 61 W/DY/YR------- BIT This mixture Is a suspension and Should be ' stimd continuously during use. Stannous chloride may be used In place of tbe stannous : D. UMVER OF mission TESTS. A waiver of Mission testing nay be granted to . owners or curators efTources of berylllun or oareww Pollutants If, In the judMtntof the Administrator of the Envlromental Protection Agency the Missions from the source eonply with the appropriate standard or If the owners or operators of the source have requested a waiver of eoepllance or have been granted a waiver of compliance. sulfate. 3.1.4 Sodium Chloride--Hydroxylamlne Sulfate Solution--Dissolve 12 grams of so dium chloride and 12 grams of hydroxylamlne ; sulfate In distilled water and dilute to 100 ml. Hydroxylamlne hydrochloride may be used in place of the hydroxylamlne sulfate. i This application should accompany the report Information provided In 3.1.5 Potassium Permanganate--5% solu tion, w/v. Dissolve 6 grams of potassium per Section I. manganate in 100 ml ofdistilled water. 1. Reason - State the reasons for requesting a waiver of Mission testing. TTTKe reason stated Is that the emissions from the source are within V the prescribed limits, documentation of this condition must be attached. 3.1.0 Stock Mercury Solution--Dissolve 0.1354 grains of reagent grade mercuric chlo ride (Assay >85%) In 76 ml of distilled water. Add 10 ml of concentrated nitric arid and adjust the volume to 100.0 ml. 1 ml=l mg Hg,. 8.1.7 Working Mercury Solution--Make successive dilutions of the stook mercury solution tq obtain a working standard con taining 0.1 pg per ml. This working standard and the dilutions of the stock mercury solu Date * Signature of tlie owner or operator tion should be prepared fresh dally. Acidity of the working standard should be main Appendix B--Test Methods 2.12 Mercury Hollow Cathode Lamp-- IS. Method 10S la added to Appendix B aa ' follows: Weatinghouse WL-22847, argon filled, or equivalent. 2.1.3 Recorder--Any multirange, variable- speed recorder that Is compatible with the METHOD 103. METHOD POX DETERMINATION OP UV detection system la suitable. MEECURT IN WASTEWATER TREATMENT PLANT 2.1.4 Absorption Cell--Standard spectro i SEWAGE SLUDGES photometer cells 10 cm long, having quarts i l. Principle and applicability. 1.1 Prin ciple--A weighed portion of the sewage aludge sample Is digested In aqua regia for a minutes at PS*0, followed by oxidation with potassium permanganate. Mercury In the digested sample 1s then measured by the conventional spectrophotometer cold vapor technique. An alternative digestion Involving the use of an autoclave Is described In para graph 422 of this method. 12 Applicability--This method Is appli cable for the determination of total organic and Inorganic mercury content In sewage sludges, soils, sediments, and bottom-type materials. The normal range of this method Is 02 to 6 Ag/g. The range may be extended above or below the normal range by Increas end windows may be used. Suitable cells may be constructed from plexiglass tubing, 2.5 cm O.D. x 11.4 cm (ca. 1" OJ3. x 4*4"). The ends are ground perpendicular to the longi tudinal axis, and quartz windows |2.5 cm diameter x 0.16 cm thickness (ea. 1" diameter x vju" thickness)] an cemented in place. (3as inlet and outlet ports (also of plexiglass but 0.6 cm OJD. (ca. %" OH.) ] an attached approximately 12 cm (%") from each end. The cell Is stropped to a burner for support and aligned In the light beam to give the maximum transmittance. NOTE: Two 6.1 cm x 6.1 cm (ca. 2" x 2") cards with 2.6 cm (ca. 1") diameter holes may he placed over each end of the oell to assist In positioning the cell for maximum transmittance. ing or decreasing sample size and through In 2.1.6 Air. Pump--Any peristaltic pump strument and recorder control. capable of delivering 1 liter of air per minute 2. Apparatus. 2.1 Analysis--The conven may be used. A Maaterfiex pump with elec tional cold-vapor technlquc(S) la used to tronic speed control has been found to be analyze the sample. satisfactory. (Regulated compressed air can 2.1.1 Atomic Absorption Spectrophoto meter1--Any atomic absorption unit having an open sample presentation area In which to mount the absorption cell Is suitable. In be used In an open one-pass system.) 2.1.0 Flowmeter--Capable of measuring . an air flow of 1 liter per minute. 2.1.7 Aeration Tubing--Tygon tubing Is used for passage of the mercury vapor from strument settings recommended by tbe par the sample bottle to the absorption cell and tained at 0.16% nitric acid. This acid Should be added to the flask as needed before the addition of the aliquot. Mercuric solutions should not be prepared in plastic containers. 4. Procedures. Samples for mercury analy sis an subject to contamination from a variety of sources. Extreme care must be taken to prevent contamination. Certain In terferences may occur during the analysis procedures. Extreme caution must be taken to avoid Inhalation of mercury. 4.1 Sample Handling and Preservation. 44.1 Because of the extreme sensitivity of the analytical procedure and the om nipresence of mercury, can must he taken to avoid extraneous contamination. Sam pling devices, sample containers, and re agents should be ascertained to be free of significant amounts of mercury; the sample . should not be exjx>sed' to any condition In the laboratory that may result In contact or .,i airborne mercury contamination. Sample % containers to be used for collection and ship- ment of mercury samples should be properly ' cleaned before use. These should be rinsed with at least 20% v/v HNO. followed by- distlUed water. .1 4.12 While the sample may be analyzed i without drying. It has been found to be more f convenient to analyze a dry sample. Moisture may bq driven on In a drying oven at a tem- 'jij peratun of 00*C. No significant mercury j losses have been observed by using this dry--5 lng step. The dry sample should be pulver% lzed and thoroughly mixed before the aliquot Is welgbed. 42 Interferences. ,,a.- - ticular manufacturer should be followed. return, straight glass tubing terminating In 42.1 Interferences that may occur lh j a coarse porous tilt Is used for Bparglng air sludge samples an sulfides, high copper, high * 1 Instruments designed specifically for the Into the sample. chlorides, etc. A discussion of possible ln-J measurement of mercury using the cold 2.1.8 Drying Tube--16 cm long x 12 cm terfennees and suggested preventative mess-3 vapor technique an commercially available diameter (ca. 6" long x 14" diameter) tube ures to be taken Is given In Reference (0) (7).2 and may be substituted for the atomic containing 20 grama of the desiccant mag 4.22 Volatile materials which absorb at'f absorption spectrophotometer. nesium perchlorate. The apparatus Is assem- the 253.7 an will cause a positive lnterfer- *A Xl b 61 6 Ol tl Vt 111 tl w b( XI) ri di di 11: ai at Is ag Pr pe lie Ei Y FEDERAL REGISTER, VOL. 40, NO. 199--TUESDAY, OCTOBER 14, 1975 C 003220M LAM022870 LAM022862