Document wqgOV9YZ8k5jZ9O6JzGxR0BnQ

MATERIAL SAFETY DATA SHEET JSIALCO PRODUCT NMJCO 5541 EMULSION BREAKER Emergency Telephone Number Medical (708) 920-1510 (24 hours) GS772 SECTION 1 PRODUCT IDENTIFICATION TRADE NAME: NAICO 5541 EMULSION BREAKER DESCRIPTION: An cocyalkylated resin, an ethylhexanol, and a modified acrylate in a hydrocarbon solvent NFPA 704M/HMIS RATING: 2/2 HEALTH 2/2 FLAMMABrLTIY 0/0 REACTIVITY (^Insignificant l^light 2s=Moderate 3=High 4=Extreme 0 COHH* SECTION 2 HAZARDOUS INGREDIENTS Our hazard evaluation has identified the following chemical ingredient(s) as hazardous under QSHA's Hazard Ccaramication Rule, 29 CFR 1910.1200. Consult Section 14 for the nature of the hazard(s). INEDIENT(S) CAS # APPROX.% Naphthalene Heavy arcanatic distillate Ethylbenzene 2-Ethyhexanol Xylene 91-20-3 68603-08-7 100-41-4 104-76-7 1330-20-7 1-5 20-40 5-10 1-5 5-10 SECTION 3 PRECAUTIONARY IABEL INFORMATION CAUTION: Oarbustible. May cause irritation to skin and eyes. Prolonged inhalation of vapor may be harmful. Avoid contact with skin, eyes, and clothing. Avoid prolonged or repeated breathing of vapor. Use with adequate ventilation. Do not take internally. Keep away from heat and open flame. Keep container closed when not in use. Tfripty containers may contain residual product. Do not reuse container unless properly reconditioned. SECTION 4 FIRST AID INFORMATION EYES: SKIN: INGESTION: INHALATION: Flush with water for 15 minutes. Call a physician. Flush with water for 15 minutes. n a physician. Do not induce vomiting. Give water. Call a physician. Remove to fresh air. Treat syuptcms. Call a physician. NOTE TO HTCSICIAN: No specific antidote is known. Based on the individual reactions of the patient, the physician's judgment should be used to control symptoms and clinical condition. CAUTION: If unconscious, having trouble breathing or in convulsions, PAGE 1 OF 9 SAL 000009964 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAREHVILLE. ILLINOIS 60563-1 19B MATERIAL SAFETY DATA SHEET AJALCO G S772 PRODUCT I NALCO 5541 EMUISICN BREAKER Emergency Telephone Number Medical (706) 920-1510 (24 hours) SECTION 4 FIRST AID INFORMATION do not induce vomiting or give water. SECTION 5 HEALTH EFFECTS INFORMATION ( CONTINUED ) ERIMAKtf RCUIE(S) OF EXPOSURE: Eye, Skin, Inhalation EXE OCNEACT: SKIN CONTACT: INHALA3TCN: Can cause moderate irritation. May cause irritation with prolonged contact. Prolonged inhalation of vapor may be harmful. SYMPTCMS OF EXPOSURE: ACUTE: Inhalation of high concentrations of product can cause nausea, dizziness, vomiting, stupor or unconsciousness. CHRONIC: Prolonged skin contact with product can cause dry skin and defatting resulting in irritation and dermatitis. AGGRAVATION OF EXISTING (XfrJDITTCNS: A review of available data does not identify any worsening of existing conditions. SECTION 6 TOXICOLOGY INFORMATION ACUffi TCKIcriY STUDIES: Acute toxicity studies have not been conducted cn this product, but toxicity studies of the ingredient(s) in Section 2 have been reviewed. The results are shewn belcw. ACUTE ORAL TOXICITY (A3J3INO RATS): 2-Ethylhexanol LD50 = 2.0 - 3.7 g/kg ACUIE DERMAL TOXICITY (ALBINO RABBITS): 2-Ethylbexanol LD50 = 2 g/kg OIHER TOXICITY RESULTS: Male and female rats fed diets containing 1.25% 2-ethylbexanol fear 90 days shewed evidence of kidney and liver effects. Rabbits exposed dermal ly to 2 ml/day fear 12 days shewed evidence of liver, lung, kidney, and heart effects. SECTION 7 PHYSICAL AND CHEMICAL PROPERTIES OOLCR: Hazy aster DENSITY: SOLUBILITY IN WATER: SPECIFIC GRAVITY: pH (NEAT) = PCRi: Liquid 7.8 - 8.2 Ibs/gal. Dispersible 0.97 @ 60 Degrees F 4.5 ODOR: Hydrocarbon PAGE 2 OF 9 SAL 000009965 'i fMALCO CHEMICAL COMPANY ONE NALCO CENTER NAPEOV1LLE. ILLINOIS 0563-1198 *1 MALCO MATERIAL SAFETY DATA SHEET PRODUCT NALCO 5541 EMLJISICN BREAKER Emergency Telephone Number Medical (708) 920-1510 (24 hours) GS772 SECTION 7 PHYSICAL AND CHEMICAL PROPERTIES VISCOSITY: POUR POINT: FLASH POINT: 77 SUS 100 Degrees F less than -35 Degrees F 118 Degrees F (FMCC) ( CONTINUED ) ASTM D-445 ASTM D-97 ASTM D-93 NOTE: These physical properties are typical values far this product. SECTION 8 FIRE AND EXPLOSION INFORMATION FIASH POINT: 118 DegreesF (R4CC) ASTM D-93 EXTINGUISHING MEDIA: Based on the NFPA guide, use dry chemical, foam, carbcn dioxide or other extinguishing agent suitable far Class B fires. Use water to cool containers exposed to fire. For large fires, use water spray or fog, thoroughly drenching the burning material. UNUSUAL FIRE AND EXPLOSION HAZARD: May evolve NQx under fire conditions. Containers exposed in a fire should be cooled with water to prevent vapor pressure buildup leading to a rupture. SECTION 9 REACTIVITY' INFORMATION XNCXI^PATIBILIIY: Avoid contact with strung oxidizers (eg. chlorine, peroxides, chromates, nitric acid, perchlorates, concentrated oxygen, permanganates) which can generate heat, fires, explosions and the release of toxic fumes. Avoid alkaline materials (eg. amrcnia and its solutions, carbonates, sodium hydroxide (caustic), potassium hydroxide, calcium hydroxide (lime), cyanides, sulfides, hypochlorites, chlorites) which can generate heat with splattering or boiling and the release of toxic fumes. THEFMAL DEXXMPOSITICN PRODUCTS: In the event of ccnhusticn CD, 002, 1TCX may be formed. Do not breathe smoke or fumes. Wear suitable protective equipment. SECTION 10 PERSONAL PROTECTION EQUIPMENT RESPIRATORY PROTECTION: If it is possible to generate significant levels of vapors or mists, a NIOSH approved or equivalent respirator is recommended. For large spills, entry into large tanks, vessels or enclosed small spaces with inadequate ventilation, a pressure-demand, self-contained breathing apparatus is recommended. VENTILATION: General ventilation is recommended. Additionally, local exhaust ventilation is recommended where vapors, mists or aerosols may be released. PAGE 3 OF 9 SAL 000009966 NALCO CHEMICAL COMPANY ONE NALCO C1NTER NARERVILLE, ILLINOIS 60563-1198 MATERIAL SAFETY DATA SHEET NALCO G S772 PRODUCT NAIOO 5541 EMJLSICN BREAKER emergency Telephone Number Medical (708) 920-1510(24 hour*) SECTION 10 PERSONAL PROTECTION EQUIPMENT ( CONTINUED ) PROTECTIVE EQUIPMENT: Use inpermeable gloves and chemical splash goggles when attaching feeding equipment or doing maintenance. If clothing is contaminated, remove clothing and thoroughly wash the affected area. launder contaminated clothing before reuse. SECTION 11 SPILL AND DISPOSAL INFORMATION IN CASE OF aSANSPORTKTICN ACCIDENTS, CALL THE POUOWINS 24-HXR TELEFTCNE NUMBER (708-920-1510) SPHL OCNTRDL AND RECOVER*: Small liquid spills: Contain with absorbent material, such as clay, soil or any ccaanercially available absorbent. Shovel reclaimed liquid and absorbent into recovery or salvage drums for disposal. Refer to CERdA in Section 14. large liquid spills: Dike to prevent further movement and reclaim into recovery or salvage drums or tank truck far disposal. Refer to CFRTTA in Secticn 14. DISPOSAL: If this product berrariRs a waste, it meets the criteria of a hazardous waste as defined under the Resource Conservation and Recovery Act (PCRA) 40CFR261. Hazardous Waste D001. In addition, this product may contain trace levels of benzene. Before disposal, the product should be analyzed to determine if it meets the hazardous waste classification of D018 (Toxicity Characteristic leaching Procedure (TCLP) Test). As a hazardous liquid waste, it mist be solidified with stabilizing agents (such as sand, fly ash, or cement) so that no free liquid remains before disposed, to a licensed industrial waste landfill (Hazardous Waste Treatment, Storage and Disposal facility) A hazardous liquid waste can also be incinerated in accordance with local, state, and federal regulations. SECTION 12 ENVIRONMENTAL INFORMATION If released into the environment, see CERCLA in Secticn 14. SECTION 13 TRANSPORTATION INFORMATION DOT PROPER SHIPPING NAME/HAZARD COCE - COMBUSTIBLE LIQUID, N.O.S. CXMBU5TTBIE LIQUID NA 1993 CONTAINS - ARCMATIC HfEKXARBCNS, PAGE 4 OF 000009967 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1190 MATERIAL SAFETY DATA SHEET JSIALCO 03 PRODUCT NALOO 5541 EMULSION BREAKER Emergency Telephone Number Medical (706) 920-1510 (24 hour*) G S772 SECTION 13 TRANSPORTATION INFORMATION ( CONTINUED NAFHTHALENE SECTION 14 REGULATORY INFORMATION The following regulations apply to this product. FEDERAL REGULATIONS: OSHA'S HAZARD CXM4UNIGA3TCN RULE, 29 CFR 1910.1200: Fas*** on our hazard evaluation, the following ingredients in this product are hazardous and the reasons are shewn belcw. Heavy aromatic distillate - Skin irritant Ethylbenzene - Eye irritant 2-Ethylhexanol - Ocotoustible, irritant Xylene - Eye irritant Naphthalene - Eye irritant Naphthalene = TYiA 10 ppm, STEL 15 ppm ADGIH/TIA/ 52 mq/m3, 79 mg/m3 ACGIH/TLV Ethylbenzene = TWA 100 ppm, STEL 125 ppm AOGIH/TLV 434 mg/n>3, 543 mg/m3 ACGIH/nV Xylene = TWA 100 ppm, SEEL 150 ppm ACGTH/TLV 434 mg/m3, 651 mg/to3 PCGm/TD/ Naphthalene -- TWA 10 ppm, STEL 15 ppm OSHA/PEL 50 mg/m3, 75 iog/m3 OSHA/PEL Ethylbenzene = TWA 100 ppm, STEL 125 ppm OSHA/PEL 435 TEQ/elS, 545 ng/m3 OGHA/PEL Xylene = TWA 100 ppm, STEX. 150 ppm OSHA/EEL 435 mg/m3, 655 tecj/eB QSHA/FEL 1 Heavy aromatic naphtha = 100 ppm T1V Manufacturer's reoemmendation CTROA/SUFERFUND, 40 CFR 117, 302: This product contains naphthalene, a Reportable Quantity (RQ) substaree and if 3,800 pounds of product are released, it requires notification to the NATIONAL RESPONSE CENTER, WASHLNGTTCN, D. C. (1-800-424-8802). SARA/SUPERFOND AMENDMENTS AND REAUMCRIZATICN ACT OF 1986 (TITLE IH) - SECTIONS 302, 311, 312 AND 313: SECTION 302 - EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355): PAGE 5 OF 9 SAL 000009968 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1190 MATERIAL SAFETY DATA SHEET NALCO G S772 PRODUCT NALCO 5541 EFUIJSICN BREAKER Emergency Telephone Number Medical (708) 920*1510 (24 hour*) SECTION 14 REGULATORY INFORMATION ( CONTINUED ) This product ck^es not contain ingredients listed in Appendix A and B as an Extremely Hazardous Substance. SBCITOhB 311 ard 312 - MATERIAL SAFETY DATA SHEET REQUIREMENTS (40 CFR 370): Our hazard evaluation has found this product to be hazardous. The product should be reported under the following EPA hazard categories: XX ^mediate (acute) health hazard -- Delayed (chronic) health hazard XX Fire hazard -- Sudden release of pressure hazard -- Reactive hazard SECTION 313 - LIST OF TOXIC CHEMICALS (40 CFR 372): This product contains the following ingredient(s), (with CAS # and % range) which appear(s) on the hist of TteocLc Chemicals. Naphthalene Ethylbenzene Xylene 91-20-3 100-41-4 1330-20-7 1-5 5-10 5-10 TOXIC SUBSTANCES. CONTROL ACT (TSCA) : The chemical ingredients in this product are on the 8(b) Inventory List (40 CFR 710). RESOURCE CONSERVATION AND RECOVERY ACT (RCRA), 40 CFR 261 SUBPAKT C & D: Consult Section 11 for RCRA classification. FEDERAL WAUR POUUIICN CCNIHDL ACT, CLEAN WATER ACT, 40 CFR 401.15 (formerly Sec. 307), 40 CR 116 (formerly Sec. 311): This product contains the following ingredients covered by the Clean Water Act: Naphthalene - Section 307, 311 Ethylbenzene - Section 307, 311 Xylene - Section 311 CLEAN AIR ACT, 40 CFR 60, SECTION 111, 40 CFR 61, SECTION 112: This product contains the following ingredients covered by the Clean Air Art: Ethylbenzene - Section 111 Xylene - Section 111 2-Ethylhexanol - Section 111 STATE REGULATIONS: PAGE 6 OF 9 SAL 000009969 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1 19B MALCO MATERIAL SAFETY DATA SHEET PRODUCT NALCO 5541 EMULSION BREAKER Emergency Telephone Number S 7 7 2Mftdlcal (70S) 920-1510 <24 hour*) U SECTION 14 REGULATORY INFORMATION ( CONTINUED ) CALIFORNIA PROPOSITION 65: None of the chemicals cn the current Proposition 65 list are known to be present in this product. MICHIGAN CRITICAL MATERIALS: This product contains the following substance(s) identified on the Michigan Critical Materials Register: Naphthalene, Xylene SLATE RIGHT TO KNOW LAWS: The following ingredient(s) are disclosed for compliance with State Right To Knew laws: Ethylbenzene 2-Ethylbexanol Heavy aromatic distillateNaphthalene Qxyalkylated resin Polyol ester Xylene 100-41-4 104-76-7 68603-08-7 91-20-3 Trade secret Trade secret 1330-20-7 INIERNATICNAL REGULATIONS: This is a WHMIS controlled product under The House of Ocsnucns of Canada Rin C-70 (Class B3 and Class D2B). The product contains the following substance(s), from the Ingredient Disclosure List or has been evaluated based cn its toxicological properties/ to contain the following hazardous ingredierrt(s): Chemical Name CAS # % Concentration Range Naphthalene Heavy aromatic distillate Ethylbenzene 2-Ethyhexanol Xylene 91-20-3 68603-08-7 100-41-4 104-76-7 1330-20-7 1-5 20-40 5-10 1-5 5-10 SECTION 15 ADDITIONAL INFORMATION F 302640 PACE 7 OF 9 000009970 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1 19B NALCO G S772 MATERIAL SAFETY DATA SHEET PRODUCT NALCO 5541 MJLSICN BREAKER C/nergency Telephone Number Medical (708) 920*1510 (24 hours) SECTION 16 USER'S RESPONSIBILITY This product material safety data sheet provides health and safety information. The product1 is to be used in applications consistent with our product literature. Individuals handling this product should be informed of tte recommended safety precautions and should have access to this information. For any other uses, exposures should be evaluated so that appropriate handling practices and training programs can be established to ensure safe workplace operations. Please consult your local sales representative for any further information. SECTION 17 BIBLIOGRAPHY ANNUAL REPORT CN CARCINOGENS, U.S. Department of Health and Human Services, Public Health Service, PB 33-135855, 1983. CASARETT AND DOULL'S TOXICOLOGY, THE BASIC SCIENCE OF POISONS, Doull, J. , KLaassen, C. D., and Adraur, M. O., eds., MacaniIlian Publishing Company, Inc. N. Y., 2nd edition, 1980. CHEMICAL HAZARDS OF THE WCKKPIACE, Proctor, N. H., and Hughes, J. P., eds., J. P. Lipincott Ocmparry, N.Y., 1981. DANGEROUS LROPERTTES OF INDUSIRIAL MATERIALS, Sax, N. Irving, ed., Van Nostrand Rairihold Company, N.Y., 6th edition, 1984. IARC MHOGRAPHS CN THE EVALUATION OF THE CARCINOGENIC RISK OF CHEMICAIS TO MAN, Gereva: World Health Organization, International Agency for Research cn Cancer, 1972-1977. PATTY'S INDUSTRIAL HYGIENE AND TOXICOLOGY, Clayton, G. D., Clayton, F. E., eds., John Wiley and Sons, N. Y., 3rd edition, Vol. 2 A-C, 1981. REGISTRY CF TOXIC EFFECTS CN CHEMICAL SUBSTANCES, U.S. Department of Health and Human Services, Public Health Service, Center for Disease Control, National Institute far Occupational Safety and Health, 1983 supplement of 1981-1982 edition, Vol. 1-3, CH, 1984. Title 29 Code of Federal Regulations Part 1910, Subpart Z, Ttodc and Hazardous Substances, Occupational Safety and Health Administration (OSHA). THRESHOLD LIMIT VALDES FOR CHEMICAL SUBSTANCES AND PHYSICAL AONTS IN THE W3RKRQCM ENVIRONMENT WITH INTENDED CHANGES, American Conference of Governmental Industrial Hygienists, CH. PAGE 8 OF 9 SAL 000009971 NALCO CHEMICAL COMPANY JNE NALCO CENTER NAPERVILLE. ILLINOIS BO5B3-1190 MALGO SECTION 17 BIBLIOGRAPHY MATERIAL SAFETY DATA SHEET PRODUCT NALCO 5541 EMULSION BREAKER Emergency Telephone Number Medical (70S) 920-1510(24 hours) * U 772 ( CONTINUED ) PREPARED BY: Ricky A. Stackhouse PhD., Toxicologist DATE CHANGED: 10/01/90 DATE PRINTED: 12/12/90 PAGE 9 OF 9 SAL 000009972 NAl ZO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE, ILLINOIS 60563-1198 IMALCO G S772 MATERIAL SAFETY DATA SHEET PRODUCT Emergency Telephone Number Medical (708) 920-1510(24 hour*) tr \ SAL OOOOO9973 NALCO CHEMICAL COMPANY OKIE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1 19S :hi