Document wq1em4d8Mw3exmMd8e59rkKw6

ETHYLENE DICHLORIDE UNI184 CAS #107-06-02 RQ FIRE FLAMMABLE. Frsfightnj wearing WOSH/MSHA-approveit Mlf-contewl breithmg apparatus should use dry chemicals foam or carbon dioxide to fight fire. Water spray Stolid be toed to keep fee exposed containers cool Ethylene Ochlonde reacts vigorously MAh nodding moms When in contact with flames, hot glowing siaface or electnc arcs, the formation of toxic and corrosive hydrogen chknde and phosgene is possible EXPOSURE INHALATION: Remove to Iresh air If not breathing, give artificial respiration, preferably mouthto-mouth II breathing is dithcuh. gve oxygen Call a physician EYE/SKIN CONTACT Immediately Hush eyes and slot with plenty ot water (soap and water tor shin) lor at least 15 minutes vdtile removing contaminated dotfvng and shoes Cal a physician Wash contaminated dottung betore reuse or discard Shoes should be discarded SWALLOWING: H conxcioux. dnnk large quanbbes of water DO NOT induce vomibng. Take immediately to a hospital or physician H uncareoaui. or m convulsions, take immediately to a hospital DO NOT induce vomiting or give anything by mouth tu an unconscious person Evacuate the area provide maximum ventilation and remove all sources of ignition Only personnel with proper protective equipment should be permitted m area Dike area to contain spill and pump spilled material into metal containers far disposal or reclaiming 00 NOT allow Elhylene Oidilonde to contaminate nearby water soirees Recover any remaining material on adsoibents. such as sawdust or vermiculite. and place m metal containers for disposal After ell visible traces and all vapors have been removed thoroughly wet vacuum the area of spill Contaminated sawdust vetmiculite, or porous strface must be disposed ot m a permitted hazardous waste management (aalrty Recovered liquids may be reprocessed or inanerated or must be treated in a permitted hazardous waste management faculty If area of spill is porous, remove as much contaminated earth gravel etc as necessary and place in dosed containers for disposal Transportation Incidem Contact CHEMTREC (800* 424-9300 In all other emergencies, contact PPG Industries, Inc. Natnum WV. |304) 843 1300 FLAMMABLE VAPOR HARMFUL WARNING! POSSIBLE CANCER HAZARD BASED ON TESTS WITH LABORATORY ANIMALS- OVEREXPOSURE MAY CREATE CANCER RISK HANDLING AND STORAGE Container and system most be electrically grounded before unloading Oo not use in poorly ventilated or confined areas Ethylene pichloride vapors are heavier than air and will collect m low areas. a Keep container tightly closed when not in use Avoid contact wrth flames, hot surfaces or electric arcs May form toxic and corrosive fumes of hydrogen chloride and possibly phosgene Adequate ventilation must be maintained m storage area to reduce fire hazard in the event of a leak a Store only in closed, properly labeled containers AVOID CONTAMINATION OF WATER SUPPLIES Handling, storage, and use procedures must be carefully monitored to avoid spills or leaks Any spilt or leak has the potential to cause underground water contamination which may if sufficiently severe, render a drinking water source unfit for human consumption Contamination that does occur cannot be easily corrected For additional product information, contact PPG Industries, Inc PPG Industries Inc One PPG Place Pittsburgh, PA 15272 Made in U.S.A. 1989 PPG Industries, Inc. See Reverse Side For Precautions and First Aid L94A-1189F NOTE: READ AND REMOVE TAG BEFORE UNLOADING SL 071206 t'm- ETHYLENE DICHLORIDE UNI184 RQ CAS #107-06-02 FLAMMABLE H VAPOR HARMFUL WARNING! POSSIBLE CANCER HAZARD BASED ON TESTS WITH LABORATORY ANIMALS- OVEREXPOSURE MAY CREATE CANCER RISK PRECAUTIONS KEEP AWAY FROM HEAT, SPARKS. OR FLAME. Ethylene Dichloride vapors are flammable and may be explosive, emitting toxic and corrosive fumes of hydrogen chloride and possibly phosgene. DO NOT BREATHE VAPORS. High vapor concentrations can cause unconsciousness or death a USE WITH ADEQUATE VENTILATION. Ventilation should be sufficient to limit employee exposure to Ethylene Dichloride below permissible exposure limits. OSHA: 1 ppm, 8-hour TWA (Time Weighted Average), 2 ppm, 15-minute STEL (Short-Term Exposure Limit). AVOID CONTACT WITH EYES. May cause pain, irritation and watering. AVOID PROLONGED OR REPEATED CONTACT WfTH SKIN. May cause irritation and dermatitis WASH THOROUGHLY AFTER HANDLING. DO NOT SWALLOW Swallowing may cause injury or death DO NOT EAT. DRINK OR SMOKE IN WORK AREAS. + FIRST AID + * INHALATION' Remove to fresh air If not breathing, give artificial respiration, preferably mouth to-mouth If breathing is difficult, give oxygen Call a physician a EYE/SKIN CONTACT Immediately flush eyes and skin with plenty of water (soap and water for skm) or at least 15 minutes, while removing contaminated clothing and shoes Call a physician Wash contaminated clothing before reuse or discard Discard shoes SWALLOWING If conscious, drink targe quantities of water DO NOT induce vomiting Take immediately to a hospital or physician If unconscious, or n convulsions take immediately to a hospital DO NOT induce vomiting or give anything by mouth to an unconscious person NOTE TO PHYSICIAN: NEVER administer adrenaline tor swallowing or inhalation overexposure. Increased sensitivity of the heed to adrenaline may be caused by overexposure to Ethylene Dichloride. Saline cathartics should be considered following high dose ingestion. PPG Industries Inc One PPG Place Pittsburgh PA 15272 L94A-1189F See Reverse Side Eor Handling and Storage NOTE. READ ANO REMOVE TAG BEFORE UNLOADING SL 071207 ETHYLENE DICHLORIDE UNI184 RQ CAS #107-06-02 I FLAMMABLE Firefighters wearing NKJSH/MSHA-apprqvad, self-contained breathing apparatus l EXPOSURE INHALATION Remove to fresh air if not breathing, give artificial respiration, preferably mouth to-mouth ft breathing is difficult, give oxygen Call a physician EYE/SPUN CONTACT Immediately flush eyes and skin with plenty of water (soap and water for skin) for at least 15 mmotes while removing contaminated clothing and shoes Call a physician. Wash contaminated dothmg before reuse or discard Shoes should be discarded SWALLOWING' tf cqrsoous. dnnk large quantities of water 00 NOT induce vomiting Take immediately to a hospital or physician H unconscious, oi tn convulsions, take immediately to a ho^wtal DO NOT induce smiting or grve anything by mouth to an unconscious person SPILL OR LEAK Evacuate the area provide maximum ventilation and remove all sources of ignrtion Only personnel wrth proper protective equipment should be permitted m area Dike area to contain spilt and pump spilled material into metal containers for disposal or reclaiming DO NOT allow Ethylene OicWonde to contaminate nearby water sources Recover any remaining material on adsorbents, such as sawdust or venmculite. and place tn metal containers for disposal After all visible traces and all vapors have been removed thoroughly wet vacuum the area of spill Contaminated sawdust vermicuiite, or porous surface must be disposed of m a permitted hazardous waste management facility Recovered liquids may be reprocessed or incinerated or must be treated m a permitted hazardous waste management facility If area of sptll is porous remove as much contaminated earth, gravel, etc as necessary and place m closed containers for disposal EMERGENCY Transportation toadeirt Contact CHEMTREC (800' 424-9300 In all other emergencies contact PPG Industries Inc Natnum WV 1304) 843'1300 i FLAMMABLE VAPOR HARMFUL WARNING! POSSIBLE CANCER HAZARD BASED ON TESTS WITH LABORATORY ANIMALS- OVEREXPOSURE MAY CREATE CANCER RISK HANDLING AND STORAGE Container and system must be electrically grounded before unloading Do not use in poorly ventilated or confined areas Ethylene Dtchlonde vapors are heavier than air and will collect in low areas Keep container tightly dosed when not >n use Avoid contact wrth flames, hot surfaces or electric arcs May form toxic and corrosive fumes of hydrogen chloride and possibly phosgene Adequate ventilation must be maintained <n storage area to reduce fire hazard m the event of a leak. a Store only in closed, properly labeled containers AVOID CONTAMINATION OF WATER SUPPLIES Handling, storaqe and use procedures must be carefully monitored to avoid spills or leaks Any spill of leak has the potential to cause underground water contamination which may f sufficiently severe, render a drinking water source unfit for human consumption Contamination that does occur cannot be easily corrected For additional product information, contact PPG Industries. Inc PPG Industries Ini, One PPG Place Pittsburgh PA 15272 Mads in U.S.A. 1988 PPG Industries, Inc. See Reverse Side For Precautions and First Aid L94A-788E NOTE: READ AND REMOVE TAG BEFORE UNLOADING SL 071208 r gp* % ETHYLENE DICHLORIDE UNI184 CAS #107-06-02 RQ _______________ _____ FLAMMABLE VAPOR HARMFUL 1 lAf A R III 1 III 1.1 POSSIBLE CANCER HAZARD BASED ON TESTS WITH 1 V VrtmtlIIVU: LABORATORY ANIMALS- OVEREXPOSURE MAY CREATE 1 CANCER RISK _______________________ PRECAUTIONS KEEP AWAY FROM HEAT. SPARKS. OR FLAME. Ethylene Dichloride vapors are flammable and may be explosive, emitting toxic and corrosive fumes of hydrogen chloride and possibly phosgene DO NOT BREATHE VAPORS. High vapor concentrations can cause unconsciousness or death, a USE WITH ADEQUATE VENTILATION. Ventilation should be sufficient to limit employee exposure to Ethylene Dichlonde below permissible exposure limits. OSHA: 50 ppm, 8-hour TWA (time weighted average); Ceiling 100 ppm; maximum peak-200 ppm (5 minutes in any 3 hours). ACGIH: 10 ppm, 8-hour TWA PPG Internal Permissible Exposure Limit: 5 ppm, 8-hour TWA; 15 ppm, STEL (short term exposure limit). a AVOID CONTACT WITH EYES. May cause pain, irritation and watering. a AVOID PROLONGED OR REPEATED CONTACT WITH SKIN. May cause irritation and dermatitis a WASH THOROUGHLY AFTER HANDLING. DO NOT SWALLOW Swallowing may cause injury or death a DO NOT EAT. DRINK OR SMOKE IN WORK AREAS + FIRST AID 4* INHALATION Remove to fresh sir II not breathing, give artificial respiration, preferably mouth-to-moutb If breathing /s difficult, give oxygen Call a physician EYE/SKIN CONTACT: Immediately flush eyes and skin with plenty of water (soap and water for skm) or at least 15 minutes, while removing contaminated clothing and shoes Call a physician Wash contaminated clothing before reuse or discard Discard shoes SWALLOWING If conscious, drink large quantities of water DO NOT induce vomiting Take immediately to a hospital or physician If unconscious, or in convulsions take immediately to a hospital DO NOT induce vomiting or give anything by mouth to an unconscious person NOTE TO PHYSICIAN: NEVER administer adrenaline for swallowing or inhalation overexposure Increased sensitivity of the heart to adrenaline may be caused by overexposure to Ethylene Oichloride. Saline cathartics should be considered following high dose ingestion. PPG Industries inc One PPG Place Pittsburgh PA 15272 L94A-788E See Reverse Side For Handling and Storage NOTE: READ AND REMOVE TAG BEFORE UNLOADING SL 071209 # ETHYLENE DICHLORIDE CAS #107-06-02 UN1184 FLAMMABLE. Firefighters wearing NIOSH/MSHA-appnwnt self-contained breathing apparatus should use dry chemicals, loam or carbon dioxide to Fight fire Water spray should be used to keep fire esposed containers cool Ethylene Oichlonde reacts vigorously with oxidcmg agents Vlflien in contact with flames, hot glowing staFace or electric acts, the formation of tone and corrosive hyihogen chlonde and phosgene is possible EXPOSURE INHALATION: fompve to fresh air If not breathing, give artificial respiration, preferably mouthto-mouth If breathing is difficult, give orygen Call a physician EYE/SKIN CONTACT: tmmediately flush eyes and skin with plenty of water (soap and water for skin| lor at least 15 minutes while removing contaminated dotting and shoes. Cal a physician Wash contaminated dothmg before reuse or discard. Shoes should be discarded SWALLOWING: N censdgiB. dm* large quantities of water. DO NOT induce vomiting. Take immediately to a hospital or physician ft uncondous. m corniisons, taka immediately tp a hospital DO NOT induce vomiting pi give anything by mouth to an incpnsaous person. Evacuate the area provide maximum ventilation and remove all sources of ignition. Only personnel with proper protective equqtment shtadd be permitted m area Dike area te contain spill and pump spdled material into metal containers for disposal or reclaiming DO NOT allow Ethylene Oichlonde to contaminate nearby water soirees Recover any remaining material on adsorbents, such as sawdust or venrearlite. and place et metal containers for disposal After all viable traces and all vapors have been removed thoroughly wet vacuum the area of spill. Contaminated sawdust, vtnrvculne. or porous suface must be disposed of m a permitted hazardous waste management facility Recovered bqmds may be reprocessed or incinerated or must be treated in a permitted hazardous waste management facility If area o( spilt is parous, remove as much contaminated earth, gravel etc as necessary and place m dosed containers tor disposal EMERGENCY TfOTsportrion heifteflt Contact CHEMTREC (BOO) 424-9300. bi all other emergencies, contact PPG Industries, Inc. Natrium WV, (304) 843-1300 FLAMMABLE VAPOR HARMFUL WARNING! POSSIBLE CANCER HAZARD BASED ON TESTS WrTH `:-V LABORATORY ANIMALS- OVEREXPOSURE MAY CREATE CANCER RISK HANDLING AND STORAGE Container and system must be electrically grounded before unloading. Do not use in poorly ventilated or confined areas. a Ethylene Dichlonde vapors are heavier than air and will collect in low areas Keep container tightly closed when not in use. Avoid contact wrth flames, hot surfaces or electnc arcs. May form toxic and corrosive fumes of hydrogen chlonde and possibly phosgene e Adequate ventilation must be maintained in storage area to reduce fire hazard in the event of a leak Store only in closed, property labeled containers AVOID CONTAMINATION OF WATER SUPPLIES. Handling, storage, and use procedures must be carefully monitored to avoid spills or leaks. Any spill or leak has the potential to cause underground water contamination which may, if sufficiently severe, render a dnnking water source unfit for human consumption. Contamination that does occur cannot be easily corrected e For additional product information, contact PPG Industries, Inc PPG Industries. Inc One PPG Place Pittsburgh, PA 15272 Made *r U S.A Cl985 PPG Industries. Inc L55A-1A-1185D See Reverse Side For Precautions and First Aid NOTE: READ AND REMOVE TAG BEFORE UNLOADING SL 071210 ETHYLENE DICHLORIDE CAS #107-06-02 UN1184 FLAMMABLE VAPOR HARMFUL WARNING! M POSSIBLE CANCER HAZARD BASED ON TESTS WITH LABORATORY ANIMALS- OVEREXPOSURE MAY CREATE CANCER RISK PRECAUTIONS KEEP AWAY FROM HEAT. SPARKS. OR FLAME. Ethylene Dichlor.de vapors are flammable and may be explosive. emitting toxic and corrosive fumes of hydrogen chloride and possibly phosgene. a DO NOT BREATHE VAPORS. High vapor concentrations can cause unconsciousness or death USE WITH ADEQUATE VENTILATION. Ventilation should be sufficient to limit employee exposure to Ethylene Dichloride below permissible exposure limits. OSHA, SO ppm. 8-hour TWA Ceiling 100 ppm, maximum peak-200 ppm (5 minutes in any 3 hours). ACGIH 10 ppm, 8-hour TWA 15 ppm. STEL (15-minute short-term exposure limit). PPG Internal Permissible Exposure Limit: 5 ppm, 8-hour TWA. 15 ppm. STEL. AVOID CONTACT WITH EYES. May cause pain, irritation and watermc a AVOID PROLONGED OR REPEATED CONTACT WITH SKIN. Ma and dermatitis ause irritation a WASH THOROUGHLY AFTER HANDLING. DO NOT SWALLOW. Swallowing may cause injury or death a DO NOT EAT, DRINK OR SMOKE IN WORK AREAS. + FIRST AID + INHALATION. Remove to fresh air If not breathing, give artificial respiration, preferably mouth-to-mouth W breathing is difficult, give oxygen Call a physician EYE/SKIN CONTACT: Immediately flush eyes and skin with plenty of water (soap and water for skin) or at least 15 minutes, while removing contaminated clothing and shoes Call a physician Wash contaminated clothing before reuse or discard Discard shoes. SWALLOWING: II conscious, drmk large quantities of water DO NOT induce vomiting Take immediately to a hospital or physician If unconscious, or m convulsions, take immediately to a hospital DO NOT induce vomiting or give enythmg by mouth to an unconscious person NOTE TO PHYSICIAN' NEVER administer adrenalin for swallowing or inhalation overexposure increased sensitivity of the heart to adrenalin may be caused by overexposure to Ethylene Dichionde. Saline cathartics should be considered folkwvtng high dose ingestion PPG Industries Inc One PPG Place Pittsburgh, PA 15272 L55A-1A-1185D See Reverse Side For Handling and Storage NOTE. READ AND REMOVE TAG BEFORE UNLOADING 1 SL 071211