Document wgvXqepLZGKvp0G58Ey2z9xEB

Where needs take us Safety data sheet According to 1907/2006/EC (REACH), 453/2010/EU, 2015/830/EU Phos-Chek 3% AFFF MS - [AQUAFILM AF-3MS] 1.1 Product identifier: Phos-Chek 3% AFFF MS - [AQUAFILM AF-3MS] 1.2 Relevant identified uses of the substance or mixture and uses advised against: Relevant uses: Fire-extinguishing. For professional use only. Uses advised against: All uses not specified in this section or in section 7.3 1.3 Details of the supplier of the safety data sheet: 1.4 Emergency telephone number: AUXQUIMIA, S.A.U. Poligono Industrial de Baina, parcela 23 33682 Baina (Mieres) - Asturias - Spain Phone.: +34 985 242 945 / +34 985 242 946 Fax: +34 985 253 809 auxquimia@icl-group.com www.auxquimia.com +34 985 242 945 / +34 985 242 946 2.1 Classification of the substance or mixture: NFPA: Health Hazards: 3 Flammability Hazards: 0 Instability Hazards: 0 Special Hazards: Non-applicable CLP Regulation (EC) n 1272/2008: Classification of this product has been carried out in accordance with CLP Regulation (EC) n 1272/2008. Eye Dam. 1: Serious eye damage, Category 1, H318 2.2 Label elements: NFPA: CLP Regulation (EC) n 1272/2008: Danger Hazard statements: Eye Dam. 1: H318 - Causes serious eye damage Precautionary statements: P280: Wear protective gloves/protective clothing/eye protection/face protection P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310: Immediately call a POISON CENTER or doctor/physician Supplementary information: EUH208: Contains Amphoteric hydrocarbon surfactant 6608110000. May produce an allergic reaction Substances that contribute to the classification Non-ionic hydrocarbon surfactant 6607700000; Anionic hydrocarbon surfactant 6201310000; Anionic hydrocarbon surfactant 6608700000 2.3 Other hazards: Non-applicable Date of compilation: 3/9/2015 - CONTINUED ON NEXT PAGE Version: 1 Page 1/12 US00005595 Where needs take us Safety data sheet According to 1907/2006/EC (REACH), 453/2010/EU, 2015/830/EU Phos-Chek 3% AFFF MS - [AQUAFILM AF-3MS] 3.1 3.2 Substance: Non-applicable Mixture: Chemical description: Aqueous solution of tensoactives Components: In accordance with Annex II of Regulation (EC) n1907/2006 (point 3), the product contains: : Identification : Chemical name/Ciassification Concentration CAS: 112-34-5 2-(2-butoxyethoxy)ethanol EC: 203-961-6 Index: 603-096-00-8 Regulation 1272/2008 : Eye Irrlt. 2: H319 - Warning REACH: 01-2119475104^14-XXXX ATP CLPOO A 15 - <20 % CAS: Non-applicable EC: Non-applicable Index: Non-applicable REACH: Non-applicable Mixture of fluorosurfactants Regulation 1272/2008 i Not classified 1 - <3 % CAS: Non-applicable EC: Non-applicable Index: Non-applicable REACH: Non-applicable Non-ionic hydrocarbon surfactant 6607700000 Regulation 1272/2008 ; Eye Dam. 1: H318 - Danger Self-classified 1 - <3 % CAS: Non-applicable EC: Non-applicable Index: Non-applicable REACH: Non-applicable Anionic hydrocarbon surfactant 6201310000 Self-classified Regulation 1272/2008 ^AcuteTx- 4: m u l'<Aquat'c Chronic 3: H412; Eye Dam. 1: H318; Skin Irrit. 2: H315 ' : Danger i ... 1 - <3 % CAS: Non-applicable EC: Non-applicable Index: Non-applicable REACH: Non-applicable Anionic hydrocarbon surfactant 6608700000 Regulation 1272/2008 ; Eye Dam. 1: H318; Skin Irrit. 2: H315 - Danger Self-classified 4% 1 - <3 % CAS: Non-applicable EC: Non-applicable Index: Non-applicable REACH: Non-applicable Amphoteric hydrocarbon surfactant 6608110000 Regulation 1272/2008 : Eye Irrit. 2: H319; Skin Sens. 1: H317 - Warning Self-classified ! 0, 1 - < 1 % CAS: Non-applicable EC: Non-applicable Index: Non-applicable REACH: Non-applicable Anionic hydrocarbon surfactant 6200710000 Regulation 1272/2008 i Eye Irrit. 2: H319; Skin Irrit. 2: H315 - Warning Self-classified ! 0,1- <1% CAS: 111-77-3 2-(2-methoxyethoxy)ethanol EC: 203-906-6 Index: 603-107-00-6 Regulation 1272/2008 ; Repr. 2: H361d - Warning REACH: 01-211947510Q-52-XXXX ATP CLPOO <0,1 % CAS: 67-56-1 EC: 200-659-6 Methanol : Index: 603-0Q1-Q0-X Regulation L272/2008 : Acute Tox. 3: H301+H311+H331; Flam. Llq. 2: H225; STOT SE 1: H370 - Danger REACH: Q1-2119433307H4-XXXX : ATP CLPOO $>#<$> <0,1 % To obtain more information on the risk of the substances consult sections 8, 11, 12, 15 and 16. SECTION 4: FIRST AID M EASURES 4.1 Description of first aid measures: The symptoms resulting from intoxication can appear after exposure, therefore, in case of doubt, seek medical attention for direct exposure to the chemical product or persistent discomfort, showing the SDS of this product. By inhalation: This product is not classified as dangerous through inhalation,however, it Is recommended In case of intoxication symptoms to remove the person affected from the area of exposure, provide clean air and keep at rest. Request medical attention if symptoms persist. By skin contact: This product is not classified as dangerous when in contact with the skin. However, in case of skin contact it is recommended to remove contaminated clothes and shoes, rinse the skin or shower the person affected if necessary thoroughly with cold water and neutral soap. In case of serious reaction consult a doctor. By eye contact: Rinse eyes thoroughly with lukewarm water for at least 15 minutes. Do not allow the person affected to rub or close their eyes. If the injured person uses contact lenses, these should be removed unless they are stuck to the eyes, as this could cause further damage. In all cases, after cleaning, a doctor should be consulted as quickly as possible with the SDS of the product. Date of compilation: 3/9/2015 - CONTINUED ON NEXT PAGE Version: 1 Page 2/12 US00005596 ICL Where needs take us Safety data sheet According to 1907/2006/EC (REACH), 453/2010/EU, 2015/830/EU Phos-Chek 3% AFFF MS - [AQUAFILM AF-3MS] By ingestion/aspiration: Do not induce vomiting, but if it does happen keep the head up to avoid inhalation. Keep the person affected at rest. Rinse out the mouth and throat, as they may have been affected during ingestion. 4.2 Most important symptoms and effects, both acute and delayed: Acute and delayed effects are indicated in sections 2 and 11. 4.3 Indication of any immediate medical attention and special treatment needed: Non-applicable 5.1 Extinguishing media: Product is non-flammable under normal conditions of storage, manipulation and use, containing flammable substances. In the case of inflammation as a result of improper manipulation, storage or use preferably use polyvalent powder extinguishers (ABC powder), in accordance with the Regulation on fire protection systems. IT IS NOT RECOMMENDED to use tap water as an extinguishing agent. 5.2 Special hazards arising from the substance or mixture: As a result of combustion or thermal decomposition reactive sub-products are created that can become highly toxic and, consequently, can present a serious health risk. 5.3 Advice for firefighters: Depending on the magnitude of the fire it may be necessary to use full protective clothing and individual respiratory equipment. Minimum emergency facilities and equipment should be available (fire blankets, portable first aid kit,...) in accordance with Directive 89/654/EC. Additional provisions: Act in accordance with the Internal Emergency Plan and the Information Sheets on actions to take after an accident or other emergencies. Destroy any source of ignition. In case of fire, refrigerate the storage containers and tanks for products susceptible to inflammation, explosion or BLEVE as a result of high temperatures. Avoid spillage of the products used to extinguish the fire into an aqueous medium. SECTIO N 6: A C C ID E N T A L RELEA S E M EASU RES 6.1 Personal precautions, protective equipment and emergency procedures: Isolate leaks provided that there is no additional risk for the people performing this task. Evacuate the area and keep out those without protection. Personal protection equipment must be used against potential contact with the spilt product (See section 8). Above all prevent the formation of any vapour-air flammable mixtures, through either ventilation or the use of an inertization agent. Destroy any source of ignition. Eliminate electrostatic charges by interconnecting all the conductive surfaces on which static electricity could form, and also ensuring that all surfaces are connected to the ground. 6.2 Environmental precautions: Avoid spillage into an aqueous medium as it contains substances potentially dangerous for this. Contain the product absorbed in hermetically sealed containers. In the case of serious spillage into an aqueous medium notify the relevant authority. 6.3 Methods and material for containment and cleaning up: It is recommended: Absorb the spillage using sand or inert absorbents. For any concern related to 6.4 Reference to other sections: and move it to a safe place. Do not absorb in sawdust or other combustible il consult section 13. See sections 8 and 13. 7.1 Precautions for safe handling: A. - Precautions for safe manipulation Comply with the current legislation concerning the prevention of industrial risks. Keep containers hermetically sealed. Control spills and residues, destroying them with safe methods (section 6). Avoid leakages from the container. Maintain order and cleanliness where dangerous products are used. B. - Technical recommendations for the prevention of fires and explosions Date of compilation: 3/9/2015 CONTINUED ON NEXT PAGE Version: 1 Page 3/12 US00005597 Where needs take us Safety data sheet According to 1907/2006/EC (REACH), 453/2010/EU, 2015/830/EU Phos-Chek 3% AFFF MS - [AQUAFILM AF-3MS] Avoid the evaporation of the product as it contains flammable substances, which could form flammable vapour/air mixtures in the presence of sources of ignition. Control sources of ignition (mobile phones, sparks,...) and transfer at slow speeds to avoid the creation of electrostatic charges. Avoid projections and pulverizations. Consult section 10 for conditions and materials that should be avoided. C. - Technical recommendations to prevent ergonomic and toxicological risks Do not eat or drink during the process, washing hands afterwards with suitable cleaning products. D. - Technical recommendations to prevent environmental risks It is recommended to have absorbent material available at close proximity to the product (See subsection 6.3) 7.2 Conditions for safe storage, including any incompatibilities: A. - Technical measures for storage Minimum Temp.: 0 C Maximun Temp.: 50 C B. - General conditions for storage Avoid sources of heat, radiation, static electricity and contact with food. For additional information see subsection 10.5 7.3 Specific end use(s): Except for the instructions already specified it is not necessary to provide any special recommendation regarding the uses of this product. SECTION 8: EXPO SURE CO N TRO LS/PERSO N AL PROTECTION 8.1 Control parameters: Substances whose occupational exposure limits have to be monitored in the work environment i 2-(2-butoxyethoxy)ethanol CAS: 112-34-5 EC: 203-961-6 2-(2-methoxyethoxy)ethanoi CAS: 111-77-3 EC: 203-906-6 Methanol CAS: 67-56-1 EC: 200-659-6 DNEL (Workers): Identification IOELV (8h) IOELV (STEL) Year IOELV (Sh) IOELV (STEL) Year IOELV (Sh) IOELV (STEL) Year Environmental limits 10 ppm 15 ppm 2014 10 ppm 67,5 mg/m3 101,2 mg/m3 50,1 mg/m3 2014 200 ppm 260 mg/m3 2014 Short exposure Long exposure ; : Identification :2 -(2 -b u t o x y e t h o x y ) e t h a n o l ;CAS: 112-34-5 :EC: 203-961-6 :Non-ionic hydrocarbon surfactant 6607700000 :CAS: Non-applicable :EC: Non-applicable Anionic hydrocarbon surfactant 6201310000 iCAS: Non-appiicable .CU, NUII dppilLdUlc Anionic hydrocarbon surfactant 6608700000 CAS: Non-applicable EC: Non-applicable 2-(2-methoxyethoxy)ethanol CAS: 111-77-3 EC: 203-906-6 Methanol CAS: 67-56-1 EC: 200-659-6 : Oral Dermal Inhalation Oral Dermal Inhalation Oral Dermal Inhalation Oral Dermal Inhalation Oral Dermal Inhalation Oral Dermal Inhalation Systemic Non-applicable Non-applicable Non-applicable N o n -a p p lic a b le N o n -a p p lic a b le Non -a pplica ble N o n -a p p iic a b ie M1VUnInl- aa pn prvillierda uh lloc N o n -a p p iic a b ie Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable 40 mg/kg 260 mg/m3 ! Local Non-applicable Non-applicable 101,2 mg/m3 Non-applicable Non-applicable Ml ynu nii aapnpniliiLr aa ku Ui c Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable 260 mg/m3 S yste m ic Non-applicable 20 mg/kg 67,5 mg/m3 Non-applicable 595000 mg/kg 420 mg/m3 Non-applicable 4060 mg/kg 285 mg/m3 Non-applicable 4060 mg/kg 285 mg/m3 Non-applicable 0,53 mg/kg 50,1 mg/m3 Non-applicable 40 mg/kg 260 mg/m3 Local Non-applicable Non-applicable 67,5 mg/m3 Non-applicable Non-applicable Non -a pplica ble Non-appiicabie MIMnUnI1- aa np rpvlllVirda uh lloc Non-appiicabie Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable 260 mg/m3 Date of compilation: 3/9/2015 CONTINUED ON NEXT PAGE Version:! Page 4/12 US00005598 Where needs take us Safety data sheet According to 1907/2006/EC (REACH), 453/2010/EU, 2015/830/EU Phos-Chek 3% AFFF MS - [AQUAFILM AF-3MS] 8.2 DNEL (General population): Short exposure Long exposure i Identification 2-(2-butoxyethoxy)ethanol CAS: 112-34-5 EC: 203-961-6 Non-ionic hydrocarbon surfactant 6607700000 CAS: Non-applicable EC: Non-applicable Anionic hydrocarbon surfactant 6201310000 CAS: Non-applicable EC: Non-applicable Anionic hydrocarbon surfactant 6608700000 CAS: Non-applicable EC: Non-applicable 2-(2-methoxyethoxy)ethanol CAS: 111-77-3 EC: 203-906-6 Methanol CAS: 67-56-1 EC: 200-659-6 j Oral Dermal Inhalation Oral Dermal Inhalation Oral Dermal Inhalation Oral Dermal Inhalation Oral Dermal Inhalation Oral Dermal Inhalation Systemic Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable N o n -a p p lic a b le N o n -a p p lic a b le N o n -a p p lic a b le MIHUn nI1- aa pn prvlIlLirua uh lloc M1HUn!n1. au rpvrptilliUr au UKIlCo MIHUn nI1- aa pn prviltiuraa uh lloc 8 mg/kg 8 mg/kg 50 mg/m3 Local Non-applicable Non-applicable 50,6 m g/m 3 Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable 50 mg/m3 Systemic 1,25 mg/kg 10 mg/kg 34 mg/m3 35,7 mg/kg 357000 mg/kg 124 mg/m 3 24 mg/kg 2440 mg/kg 85 mg/m3 24 mg/kg 2440 mg/kg 85 mg/m3 1,5 mg/kg 0,27 mg/kg 25 mg/m3 8 mg/kg 8 mg/kg 50 m g/m 3 Local Non-applicable Non-applicable 34 mg/m3 Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable 50 mg/m3 PNEC: 1 Identification 2-(2-butoxyethoxy)ethanol CAS: 112-34-5 EC: 203-961-6 ; Non-ionic hydrocarbon surfactant 6607700000 CAS: Non-applicable EC: Non-applicable Anionic hydrocarbon surfactant 6201310000 CAS: Non-applicable EC: Non-applicable Anionic hydrocarbon surfactant 6608700000 :CAS: Non-applicable EC: Non-applicable :2- (2 -methoxyet hoxy)etha no1 iCAS: 111-77-3 :EC: 203-906-6 :M e th a n o l ;CAS: 67-56-1 EC: 200-659-6 Exposure controls: STP Soil In te rm itte n t Oral STP Soil In te rm itte n t Oral STP Soil In te rm itte n t Oral STP Soil In te rm itte n t Oral STP Soil In te rm itte n t Oral STP Soil In te rm itte n t Oral 200 mg/L 0,4 mg/kg 3,9 mg/L 56 g/kg 560 mg/L 0,654 mg/kg 0,27 mg/L 111,11 g/kg 1,35 mg/L 0,2445 mg/kg 0,086 mg/L Non-applicable 1,35 mg/L 0,22 mg/kg Non-applicable Non-applicable 10000 mg/L 2,44 mg/kg 12 mg/L 90 g/kg 100 mg/L 23,5 mg/kg 1540 mg/L Non-applicable Fresh water Marine water Sediment (Fresh water) Sediment (Marine water) Fresh water Marine water Sediment (Fresh water) Sediment (Marine water) Fresh water Marine water Sediment (Fresh water) Sediment (Marine water) Fresh water Marine water Sediment (Fresh water) Sediment (Marine water) Fresh water Marine water Sediment (Fresh water) Sediment (Marine water) Fresh water Marine water Sediment (Fresh water) Sediment (Marine water) 1 mg/L 0,1 mg/L 4 mg/kg 0,4 mg/kg 0,176 mg/L 0,0176 mg/L 1,516 mg/kg 0,152 mg/kg 0,095 mg/L 0,0095 mg/L 1,5 mg/kg 0,15 mg/kg 0,1357 mg/L 0,01357 mg/L 1,5 mg/kg 0,15 mg/kg 12 mg/L 1,2 mg/L 44,4 mg/kg 0,44 mg/kg 154 mg/L 15,4 mg/L 570,4 mg/kg Non-applicable A.- General security and hygiene measures in the work place If product is used at the concentration dosing conditions specified in the relevant instructions for use (section 15), personal protective equipment described in section 8.2 for UNDILUTED products will not be required. Safe handling recommendations for undiluted product: I Date of compilation: 3/9/2015 - CONTINUED ON NEXT PAGE Version: 1 Page 5/12 US00005599 A icl Where needs take us Safety data sheet According to 1907/2006/EC (REACH), 453/2010/EU, 2015/830/EU Phos-Chek 3% AFFF MS - [AQUAFILM AF-3MS] As a preventative measure it is recommended to use basic Personal Protection Equipment, with the corresponding <<CE marking>> in accordance with Directive 89/686/EC. For more information on Personal Protection Equipment (storage, use, cleaning, maintenance, class of protection,...) consult the information leaflet provided by the manufacturer. For more information see subsection 7.1. All information contained herein is a recommendation which needs some specification from the labour risk prevention services as it is not known whether the company has additional measures at its disposal. B. - Respiratory protection The use of protection equipment will be necessary if a mist forms or if the professional exposure limits are exceeded. C. - Specific protection for the hands Pictogram Labelling CEN Standard Remarks Chemical protective gloves Mandatory hand protection D.- Ocular and facial protection Pictogram PPE Panoramic glasses against liquid splash Mandatory face protection E.- idily protection PPE Labelling f f A T II Labelling EN 374-1:2003 EN 374-3:2003/AC:2006 EN 4 2 0 :2 0 0 3 A l: 2009 Replace the gloves at any sign of deterioration. CEN Standard i EN 166:2001 EN 172:1994/A1:2000 EN 172:1994/A2:2001 EN ISO 4007:2012 Remarks Clean daily and disinfect periodically according to the m an u factu rer's instructions. Use if there is a risk of splashing. CEN Standard Remarks W ork clothing EN ISO 13688:2013 For professional use only. Anti-slip work shoes EN ISO 20347:2012 EN ISO 20344:2011 None F.- Additional emergency measures Emergency measure Standards Emergency measure Standards Emergency shower ANSI Z358-1 ISO 3864-1:2002 Eyewash stations DIN 12 899 ISO 3864-1:2002 Environmental exposure controls: In accordance with the community legislation for the protection of the environment it is recommended to avoid environmental spillage of both the product and its container. For additional information see subsection 7.1.D PROPERTIES 9.1 Information on basic physical and chemical properties: For complete information see the product datasheet. Appearance: Physical state at 20 C: Liquid Appearance: Transparent Color: Yellowish Odor: Characteristic Volatility: *Not relevant due to the nature of the product, not providing information property of its hazards. - CONTINUED ON NEXT PAGE - Date of compilation: 3/9/2015 Version: 1 Page 6/12 US00005600 Where needs take us Safety data sheet According to 1907/2006/EC (REACH), 453/2010/EU, 2015/830/EU Phos-Chek 3% AFFF MS - [AQUAFILM AF-3MS] Boiling point at atmospheric pressure: Vapour pressure at 20 C: Non-applicable * Non-applicable * Vapour pressure at 50 C: Evaporation rate at 20 C: Product description: Non-applicable * Non-applicable * Density at 20 C: Relative density at 20 C: Dynamic viscosity at 20 C: Kinematic viscosity at 20 C: Kinematic viscosity at 40 C: Concentration: pH: Vapour density at 20 C: Partition coefficient n-octanol/water 20 C: Solubility in water at 20 C: Solubility properties: Decomposition temperature: 1000 - 1040 kg/m3 Non-applicable * 4 cP Non-applicable * Non-applicable * Non-applicable * 7-8,5 Non-applicable * Non-applicable * Non-applicable * Highly water-soluble Non-applicable * Melting point/freezing point: Flammability: Flash Point: Autoignition temperature: Lower flammability limit: Non-applicable * Non Flammable (>60 C) Non-applicable * Non-applicable * Upper flammability limit: Non-applicable * Other information: Surface tension at 20 C: Refraction index: Non-applicable * 1,367 *Not relevant due to the nature o f the product, not providing information property of its hazards. SECTIO N 10: S T A B ILITY A N D REA C TIV ITY 10.1 Reactivity: No hazardous reactions are expected if the following technical instructions storage of chemicals. See section 7. 10.2 Chemical stability: Chemically stable under the conditions of storage, handling and use. 10.3 Possibility of hazardous reactions: Under the specified conditions, hazardous reactions that lead to excessive temperatures or pressure are not expected. 10.4 Conditions to avoid: Applicable for handling and storage at room temperature: : Shock and friction ; Not applicable Contact with air Not applicable Increase in tem perature Precaution : Sunlight Precaution Humidity : Not applicable 10.5 Incompatible materials: : Acids ; Not applicable Water Not applicable Co mbu stive materia is Avoid direct impact ^Combustible mate riais Not applicable Others j Not applicable 10.6 Hazardous decomposition products: See subsection 10.3, 10.4 and 10.5 to find out the specific decomposition products. Depending on the decomposition conditions, complex mixtures of chemical substances can be released: carbon dioxide (C02), carbon monoxide and other organic compounds. Date of compilation: 3/9/2015 - CONTINUED ON NEXT PAGE Version: 1 Page 7/12 US00005601 Where needs take us Safety data sheet According to 1907/2006/EC (REACH), 453/2010/EU, 2015/830/EU Phos-Chek 3% AFFF MS - [AQUAFILM AF-3MS] 11.1 Information on toxicological effects: The experimental information related to the toxicological properties of the product itself is not available Contains glycols. With possibility of effects that are hazardous to the health, it is recommended not to breathe the vapours for long periods of time. Dangerous health implications: In case of exposure that is repetitive, prolonged or at concentrations higher than recommended by the occupational exposure limits, it may result in adverse effects on health depending on the means of exposure: A.- Ingestion: - Acute toxicity: Based on available data, the classification criteria are not met, however, it contains substances classified as dangerous for consumption. For more information see section 3. - Corrosivity/Irritability: Based on available data, the classification criteria are not met, however, it contains substances classified as dangerous for consumption. For more information see section 3. B- Inhalation: - Acute toxicity: Based on available data, the classification criteria are not met, however, it contains substances classified as dangerous for inhalation. For more information see section 3. - Corrosivity/Irritability: Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for this effect. For more information see section 3. C- Contact with the skin and the eyes: - Contact with the skin: Based on available data, the classification criteria are not met, however, it contains substances classified as dangerous for skin contact. For more information see section 3. - Contact with the eyes: Produces serious eye damage after contact. D- CMR effects (carcinogenicity, mutagenicity and toxicity to reproduction): - Carcinogenicity: Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for the effects mentioned. For more information see section 3. - Mutagenicity: Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for this effect. For more information see section 3. - Reproductive toxicity: Based on available data, the classification criteria are not met, however it does contain substances classified as dangerous for this effect. For more information see section 3. E- Sensitizing effects: - Respiratory: Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous with sensibilizising effects. For more information see section 3. - Cutaneous: Based on available data, the classification criteria are not met, however, it contains substances classified as dangerous with sensibilizising effects. For more information see section 3. F- Specific target organ toxicity (STOT)-time exposure: Based on available data, the classification criteria are not met, however, it does contain substances which are classified as dangerous as a result of a single exposure. For more information see section 3. G- Specific target organ toxicity (STOT)-repeated exposure: - Specific target organ toxicity (STOT)-repeated exposure: Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for this effect. For more information see section 3. - Skin: Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for this effect. For more information see section 3. H- Aspiration hazard: Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for this effect. For more information see section 3. Other information: Non-applicable Specific toxicology information on the substances: : Identification 2-(2-methoxyethoxy)ethanol CAS: 111-77-3 EC: 203-906-6 Anionic hydrocarbon surfactant 6201310000 CAS: Non-applicable EC: Non-applicable Methanol CAS: 67-56-1 Acute toxicity LD5Q oral 7128 mg/kg LD50 dermal 9404 mg/kg LC50 inhalation Non-applicable LD50 oral 580 mg/kg LD50 dermal Non-applicable LC50 inhalation Non-applicable LD50 oral LD50 dermal 100 mg/kg 300 mg/kg - CONTINUED ON NEXT PAGE - Genus Rat Rabbit Rat Rat Rabbit Date of compilation: 3/9/2015 Version:! Page 8/12 US00005602 Where needs take us EC: 200-659-6 Safety data sheet According to 1907/2006/EC (REACH), 453/2010/EU, 2015/830/EU Phos-Chek 3% AFFF MS - [AQUAFILM AF-3MS] Identification LC50 inhalation Acute toxicity 3m g/L(4h) Genus Rat The experimental information related to the eco-toxicological properties of the product itself is not available 12.1 Toxicity: i Identification j 2-(2-butoxyethoxy)ethanol CAS: 112-34-5 EC: 203-961-6 Non-ionic hydrocarbon surfactant 6607700000 CAS: Non-applicable EC: Non-applicable Anionic hydrocarbon surfactant 6201310000 CAS: Non-applicable EC: Non-applicable 2-(2-methoxyethoxy)ethanol CAS: 111-77-3 EC: 203-906-6 Methanol CAS: 67-56-1 EC: 200-659-6 12.2 Persistence and degradability: LC50 EC50 EC50 LC50 EC50 EC50 LC5Q EC50 EC50 LC50 EC50 EC50 LC50 EC50 EC50 Acute toxicity 1300 mg/L (96 h) 2850 m g/L (24 h) 53 m g/L (192 h) 126 mg/L (96 h) 151 mg/L (48 h) 27 mg/L (72 h) 177 mg/L (96 h) Non-applicable 21,5 mg/L (72 h) 5741 mg/L (96 h) 1192 m g /L (48 h) MiMn onn-aanpnplni cr aakml ea 15400 mg/L (96 h) 12000 mg/L (96 h) 530 m g/L(168 h) ; Specie Lepomis macrochirus Daphnia magna Microcystis aeruginosa Brachydanio rerio Acartia tonsa Scenedesmus subspicatus Brachydanio rerio Genus Fish Crustacean Algae Fish Crustacean Algae Fish Pseudokirchneriella subcapitata Pimephales promelas Daphnia magna Algae Fish Crustacean Lepomis macrochirus Nitrocra spinipes Microcystis aeruginosa Fish Crustacean Algae : Identification 2-(2-butoxyethoxy)ethanol CAS: 112-34-5 EC: 203-961-6 Non-ionic hydrocarbon surfactant 6607700000 CAS: Non-applicable EC: Non-applicable Anionic hydrocarbon surfactant 6201310000 CAS: Non-applicable EC: Non-applicable 2- (2 -methoxyet hoxy)eth a noi :CAS: 111-77-3 :EC: 203-906-6 12.3 Methanol :CAS: 67-56-1 ;EC: 200-659-6 Bioaccumulative potential: Degradability BOD5 COD 0.25 g 02/g 2.08 g 02/g BOD5/COD 0.12 BODS COD Non-applicable Non-applicable BOD5/COD Non-applicable BOD5 COD Non-applicable Non-applicable BOD5/COD Non-applicable BOD5 Non-applicable COD BOD5/COD Non-applicable 0.07 BOD5 COD Non-applicable 1.42 g 02/g BOD5/COD Non-applicable Concentration Period % Biodegradable Concentration Period % Biodegradable Concentration Period % Biodegradable Concentration Period % Biodegradable Concentration Period % Biodegradable Biodegradability 100 mg/L 28 days 92 % Non-applicable 28 days 100 % 2 mg/L 30 days 98 % Non-applicable 28 days 100 % 100 mg/L 14 days 92 % :2 -(2 -b u t o x y e t h o x y ) e t h a n o l :CAS: 112-34-5 EC: 203-961-6 2-(2-methoxyethoxy)ethanol CAS: 111-77-3 EC: 203-906-6 12.4 Methanol CAS: 67-56-1 EC: 200-659-6 Mobility in soil: Identification BCF Row Log Potential BCF Row Log Potential BCF Pow Log Potential Bioaccumulation potential 0,46 0,56 Low 3 -1,18 Low 3 -0,77 Low Date of compilation: 3/9/2015 - CONTINUED ON NEXT PAGE Version: 1 Page 9/12 US00005603 Where needs take us Safety data sheet According to 1907/2006/EC (REACH), 453/2010/EU, 2015/830/EU Phos-Chek 3% AFFF MS - [AQUAFILM AF-3MS] Identification 2-(2-butoxyethoxy)ethanol CAS: 112-34-5 EC: 203-961-6 Non-ionic hydrocarbon surfactant 6607700000 CAS: Non-applicable EC: Non-applicable Anionic hydrocarbon surfactant 6201310000 CAS: Non-applicable EC: Non-applicable 2-(2-methoxyethoxy)ethanol CAS: 111-77-3 EC: 203-906-6 Methanol 12.5 CAS: 67-56-1 EC: 200-659-6 Results of PBT and vPvB assessment: Non-applicable 12.6 Other adverse effects: Not described Absorption/desorption KOC Conclusion 48 Very High Surface tension 33950 N/m (25 C) Koc Conclusion 50 Very High Surface tension Non-applicable Koc Conclusion Surface tension 150 V ery High 33200 N/m (24 C) Koc 1 Conclusion Surface tension Very High 35900 N/m (25 C) Koc Conclusion Non-applicable Non-applicable Surface tension 23550 N/m (25 <T) Henry Dry soil Moist soil Henry Dry soil Moist soil Henry Dry soil Moist soil Henry Dry soil Moist soil Henry Dry soil Moist soil Volatility 7,2E-9 PaTnVm ol No No l,2E-8 PaTnVm ol No No l,06 E -2 PaTT^/mol Non-applicable Non-applicable l,621E-6 Pa-m Vm ol Non-applicable No Non-applicable Non-applicable Non-applicable SECTIO N 13: D ISP O SA L C O N SID E R A T IO N S 13.1 Waste treatment methods: ; Code 16 05 08* ; Description Discarded organic chemicals consisting of or containing hazardous substances Waste class (Regulation (E ll) No 1357/2014) : Dangerous Type of waste (Regulation (EU) No 1357/2014): HP4 Irritant -- skin irritation and eye damage Waste management (disposal and evaluation): Consult the authorized waste service manager on the assessment and disposal operations in accordance with Annex 1 and Annex 2 (Directive 2008/98/EC). As under 15 01 (2014/955/EC) of the code and in case the container has been in direct contact with the product, it will be processed the same way as the actual product. Otherwise, it will be processed as non-dangerous residue. We do not recommended disposal down the drain. See paragraph 6.2. Regulations related to waste management: In accordance with Annex II of Regulation (EC) n1907/2006 (REACH) the community or state provisions related to waste management are stated Community legislation: Directive 2008/98/EC, 2014/955/EU, Regulation (EU) No 1357/2014 SECTIO N 14: T R A N S P O R T IN FO R M ATIO N This product is not regulated for transport (ADR/RID,IMDG,IATA) SECTIO N 15: R EG U LA T O R Y IN FO R M ATIO N 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture: Candidate substances for authorisation under the Regulation (EC) 1907/2006 (REACH): Non-applicable Substances included in Annex XIV of REACH ("Authorisation List") and sunset date: Non-applicable Regulation (EC) 1005/2009, about substances that deplete the ozone layer: Non-applicable Active substances for which a decision of non-inclusion onto Annex I (Regulation (EU) No 528/2012): Non-applicable REGULATION (EU) No 649/2012, in relation to the import and export of hazardous chemical products: Non-applicable Date of compilation: 3/9/2015 - CONTINUED ON NEXT PAGE Version: 1 Page 10/12 US00005604 Where needs take us Safety data sheet According to 1907/2006/EC (REACH), 453/2010/EU, 2015/830/EU Phos-Chek 3% AFFF MS - [AQUAFILM AF-3MS] Limitations to commercialisation and the use of certain dangerous substances and mixtures (Annex XVII, REACH): Non-applicable Specific provisions in terms of protecting people or the environment: It is recommended to use the information included in this safety data sheet as data used in a risk evaluation of the local circumstances in order to establish the necessary risk prevention measures for the manipulation, use, storage and disposal of this product. Relevant instructions for use: This product is intended for the production of foam for fire extinguishing purposes. It should be diluted at 3% in water and used with appropriate foam-generating equipment. Other legislation: The product could be affected by sectorial legislation 15.2 Chemical safety assessment: The supplier has not carried out evaluation of chemical safety. Legislation related to safety data sheets: This safety data sheet has been designed in accordance with ANNEX II-Guide to the compilation of safety data sheets of Regulation (EC) N 1907/2006 (Regulation (EU) N 453/2010, Regulation (EC) N 2015/830) Modifications related to the previous security card which concerns the ways of managing risks. : Non-applicable Texts of the legislative phrases mentioned in section 2: H318: Causes serious eye damage Texts of the legislative phrases mentioned in section 3: The phrases indicated do not refer to the product itself; they are present merely for informative purposes and refer to the individual components which appear in section 3 CLP Regulation (EC) n 1272/2008: Acute Tox. 3: H301+H311+H331 - Toxic if swallowed, in contact with skin or if inhaled Acute Tox. 4: H302 - Harmful if swallowed Aquatic Chronic 3: H412 - Harmful to aquatic life with long lasting effects Eye Dam. 1: H318 - Causes serious eye damage Eye Irrit. 2: H319 - Causes serious eye irritation Flam. Liq. 2: H225 - Highly flammable liquid and vapour Repr. 2: H361d - Suspected of damaging the unborn child. Skin Irrit. 2: H315 - Causes skin irritation Skin Sens. 1: H317 - May cause an allergic skin reaction STOT SE 1: H370 - Causes damage to organs Classification procedure: Eye Dam. 1; Calculation method Advice related to training: Minimal training is recommended to prevent industrial risks for staff using this product, in order to facilitate their comprehension and interpretation of this safety data sheet, as well as the label on the product. Principal bibliographical sources: http://esis.jrc.ec.europa.eu http://echa.europa.eu http://eur-lex.europa.eu Abbreviations and acronyms: Date of compilation: 3/9/2015 - CONTINUED ON NEXT PAGE Version: 1 Page 11/12 US00005605 Where needs take us Safety data sheet According to 1907/2006/EC (REACH), 453/2010/EU, 2015/830/EU Phos-Chek 3% AFFF MS - [AQUAFILM AF-3MS] - ADR: European agreement concerning the international carriage of dangerous goods by road -IMDG: International maritime dangerous goods code -IATA: International Air Transport Association -ICAO: International Civil Aviation Organisation -COD: Chemical Oxygen Demand -BOD5: 5-day biochemical oxygen demand -BCF: Bioconcentration factor -LD50: Lethal Dose 50 -CL50: Lethal Concentration 50 -EC50: Effective concentration 50 -Log-POW: Octanol-water partition coefficient -Koc: Partition coefficient of organic carbon The information contained in this security data sheet is based on sources, technical knowledge and current legislation at European and state level, without being able to guarantee its accuracy. This information cannot be considered a guarantee of the properties of the product, it is simply a description of the security requirements. The occupational methodology and conditions for users of this product are not within our awareness or control, and it is ultimately the responsibility of the user to take the necessary measures to obtain the legal requirements concerning the manipulation, storage, use and disposal of chemical products. The information on this security data sheet only refers to this product, which should not be used for needs other than those specified. - END OF SAFETY DATA SHEET - Date of compilation: 3/9/2015 Version:! Page 12/12 US00005606