Document wgdadkRq16dZpqknz4Dr4pG2Q
MS 'B 2 .
INTERNAL CORRESPONDENCE
UNION CARBIDE CORPORATION
PLAINTIFFS j x EXHIBIT
* UC-1004
RLoti v c.L
SCP l 4-1983
W. P. Miller
17625 EL CAMINO REAL. HOUSTON TX 770:
TofNamei Division location
Copy to
A. S. Amatangelo H. M. Bartlett B. F. Dole J. L. Davidson H. V. Hooper Felix LaFontaine L. 0. Martin N*H. Mayfield G. L. Miller W. P. Miller K. G. Morlock W. 3. Ooms H. Ortiz A. V. Parikh D. H. Reed G. W. Sanders 3. Sipos
J. H. Barrett D. H. Glenn, M.D. A. 3. Hart
o,,, September 9, 1983
Originating Dapl Answering letter date
Subject Update-Exposure Standards/ Guidelines
BUSINESS CONFIDENTIAL
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Here are updated lists of Latex chemicals which have\(lj) personnel
exposure standards established by UCC, UCC Divisions, or OSHA and (2) personnel exposure guidelines recommended bv the American Conferenced Governmental Industrial-Hygienists. We will continue to distinguish betwe the two lists as follows:
Exposure Standards are not to be exceeded
-&S-&TH
Exposure Guidelines provide program guidance.
The lists have been expanded to include materials which may be of importance at only 1 plant, laboratory chemicals, refrigerants and which may have implications for your Fertile Female protection programs. Several information sources were used in developing the updated lists.
Please let me know if you have questions.
Very truly yours,
VDD:jl
Attachments 2907L
Ui
V. D. Dutcher
^2298?
BUSINESS CONFIDENTIAL
LATEX CHEMICALS WITH EXPOSURE STANDARDS
Chemical
Acetic Acid Acrylamide Acrylic Acid Acrylonitrile
Ammonia Asbestos
Butyl Acrylate Butyl CELLOSOLVE Butyl Mercaptan Carbon Tetrachloride
Chloroform
Dibutyl Phthalate t Dodecyl Mercaptan Ethyl Acrylate 2 Ethylhexyl /jcrylate Fluorocarbon 22 Formaldehyde Hydrogen Chloride Hydrogen Peroxide 90 pet Itaconic Acid
8 Hour Exposure Standard
Sourc
10 ppm 0.3 mg/M3 Skin
OSHA OSHA
2 ppm
UCC
2 ppm (Teratogen/Carcinogen)
OSHA
10 ppm Ceiling (15 Minute)
OSHA
50 ppm
OSHA
2 Fibers/cc (Carcinogen)
OSHA
10 Fibers/cc Ceiling
>5 uM Long
5 ppm
UCC
50 ppm (Skin)
OSHA
10 ppm
OSHA
2 ppm (Embryotoxic)
UCC
4 ppm Ceiling
(Suspect Cancer Agent)
10 ppm (Teratogen)
UCC
25 ppm Ceiling (15 minute)
(Suspect Cancer Agent) 5 mg/M3
OSHA
0.5 ppm 5 ppm Skin 5 ppm
UCC UCC UCC
1000 ppm (Teratogen) 2 ppm (Suspect Cancer Agent)
UCC UCC
5 ppm Ceiling
1 ppm 5 mg/M3
OSHA OSHA ^229^5
LATEX CHEMICALS WITH EXPOSURE STANDARDS (Cont)
Mercury-All Compounds Except Alkyl
Methyl Methacrylate Monoethanolamine Neopentyl Glycol Diacrylate
Propylene Imine Sodium Hydroxide Styrene
Sulfuric Acid Vinyl Acetate Vinyl Chloride
0.05 mg/M3
UCC
100 ppm 3 ppm No Skin or Oral Contact (Suspect Cancer Agent) 2 ppm Skin 2 mg/M3
100 ppm 200 ppm Ceiling 600 ppm 5 Minutes Peak Any 3 Hours 1 mg/M3
10 ppm 1 ppm (Teratogen/Carcinogen) 5 ppm Ceiling (15 Minutes)
OSHA OSHA UCC
OSHA 09HA OSHA OSHA OSHA OSHA UCC OSHA OSHA
NOTE:
Although UCC has not been requested to evaluate the need for an in ternal exposure standard forlpropyleneimine) it should be_handled as
a suspect cancer agent (ana aiscussed with female emoloveeslas a
chemical ot"concern. Ethyleneimine, a similar chemical, is embryotoxic.
Revised 9/9/83
A22983
BUSINESS CONFIDENTIAL
LATEX CHEMICALS WITH ACGIH EXPOSURE GUIDELINES
Acetic Acid Acrylamide Acrylic Acid Acrylonitrile Ammonia Asbestos Butyl Acrylate Butyl CELLOSCLVE n Butyl Mercaptan Carbon Tetrachloride Chloroform Di butyl Phthalate yn <v Ethyl Acrylate Ethylene Glycol Fluorocarbon 12 Fluorocarbon 22 Formaldehyde Hydrogen Chloride Hydrogen Peroxide Mercury-Aryl Compounds Methacrylic Acid Methyl Methacrylate Monoethanolamine Propylene Imine Sodium Bisulfite Sodium Hydroxide Styrene
TLV Ceiling
10 15
0.3*
0.6*
Skin
10
2 Skin
25 35
Complex Guideline, Refer to ACG
10
25 75 Skin
0.5
5 30
10 50
5* 10*
5 25 Skin
1000 1000
1 5 1 0.1* 20 100 3 2 5*
50
1250 1250
2
2
125 6
2* 100
-
Skin
A2299C
LATEX CHEMICALS WITH ACGIH EXPOSURE GUIDELINES (Cont)
Sulfuric Acid
yy\
Tetrasodium Pyrophosphate
Vinyl Acetate
Vinyl Chloride
1* 5* 10 20 5 10
Units are mg/M5 For other entries, units are ppm.
9/9/83
A22991
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