Document wgdXxwpzMxmeGxRq4K2N60xzB
UNION CARBIDE CORPORATION Chemicals & Plastics
To: Mr. T. w. Carmody
Mr. M. E. Eisenhour
Mr. A. W. Lutz
Dr. W. R. Manning Mr. W. C. Quiraby / Mr. R. N. Wheeler`S Mr. J. W. Whittlesey Dr. N. L. Zutty
270 Park Avenue, New York, New York
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e/ *
10017
Date:
September 19, 1974
RECtiVffD
SEP 25 19/4
* N. WHEELS. Jni.
Here is the summary section of the very recently issued Foster D, Snell DRAFT FINAL REPORT - ECONOMIC IMPACT STUDIES OF THE EFFECTS OF PROPOSED OSHA STANDARD FOR VINYL CHLORIDE. This study was contracted by OSHA to rebut the Industry presentation that the Proposed Permanent Standard was simply not feasible with present technology.
A response to the Snell report is now due September 25th.
ABS :ml Attachment
A. B. Steele
ucc 036108
VI. CONCLUSIONS AND RECOMMENDATIONS
I
This chapter addresses the conclusions and recommendations of the report based on the findings and economic analysis of the previous section.
1. ACHIEVING "NO DETECTABLE11 LEVELS OF VCM PRINCIPALLY THROUGH ENGINEERING MEANS IS JUDGED NOT FEASIBLE WITH PRESENT TECHNOLOGY BOTH IN THE VCM AND PVC SECTORS
Based on the industry surveys and Snell's independent assessments of the state-of-the-art of the technology, it is concluded -that achieving "no detectable" (0-1 ppm) VCM levels in the VCM industry is not feasible principally through engineering means. Reasons include the following:
technology, including state-of-the-art developments, is not available to eliminate VCM leaks and fugitive losses
existing plants have not been designed for total VCM containment
there is no design or operating experience in the industry aimed at maintaining very low VCM levels
no direct technology transfer opportunities are known to enable development of designs for "no detectable" levels in new plants.
Based on the industry surveys and Snell's independent assessments of the state-of-the-art of the technology, it is concluded that achieving "no detectable" (.0-1 ppm) VCM levels in the PVC industry is not feasible principally through engineering means. Reasons include the following:
PVC manufacture is a batch operation
Technology, including state-of-the-art developments is not available to eliminate VCM leaks and fugitive losses
VI-l
od
existing plants have not been designed for total VCM containment there is no design or operating experience in the industry aimed at maintaining very low VCM levels no direct technology transfer opportunities are known to enable development of designs for "no detectable" levels in new plants. Up to four years of development is estimated to reduce residual VCM levels below 100 ppm in PVC products on the basis of output volume.
The technology including state-of-the-art developments is not available to reach very low or "no detectable" residual VCM levels on the basis of output volume. 2. T1IE COSTS OF COMPLIANCE INCREASE RAPIDLY WITH DECREASING VCM TARGET LEVELS AND REPRESENT SIGNIFICANT ENGINEERING UNCERTAINTY OR 1NFEASABIL1TY BEYOND 10 PPM CEILING AND 2-5 PPM TWA FOR THE VCM INDUSTRY AND 15 - 25 PPM CEILING AND 10-15 TWA FOR THE PVC INDUSTRY The analysis which follows indicates the cost sensitivity of attempting to reach very low VCM levels in the VCM industry.
VI-2
038110
VCM Target Level (ppm)
Standard Price (d/lb.)
Historical Practice
1.41
SO ceiling
*1.41
25 ceiling
1.59
10 ceiling and 2-5 TWA Extrapolated Attempt to Reach "No Detectable" Levels
7.69 12.11
*
Price Index 1.00 1.01
1,02 1.04
Percent of VCM Industry Capacity Endangered Not Applicable 0% 01o Oft
1.12 *
100^ "No Detectable"
Levels
Time To Reach , Level Via Engineering
Controls (years) Not Applicable 0.5 2.5 3.0
Not Estimated
Source: Exhibits V-15 and V-13
9
The table indicates the rapid rise in costs associated with attempting to reach the technologically infeasible "no detectable" levels beyond the 10 ppm ceiling and 2-5 ppm TWA target level.
Exhibit VI-1, on the following page^presents a similar discussion for the PVC industry.
VI-3
I
IMM IM
me iMou>Tr cuauo annual com to
I ACHltVC VCM TAHCT LCVCU AhO SUSTAIN IIK CA/ACirV ii|
ECONOMIC IMPACT CRITERIA PLANTS LIKELY TO BE MOST "ENDANGERED''*2*
Highest compliance costs Plant located in cold climate Old plant Small plant Small reactors Copolymer, emulsion or latex resin production
(High free monomer) Small company Merchant sales Slackening demand
PLANTS LIKELY TO BE LEAST "ENDANGERED"*2*
Lowest compliance costs
Plant located in warm climate
Modern plant with automation
Large reactors
Bulk or suspension resin production
Large company
Large plant
Captive use of PVC
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. Highly disciplined plant personnel
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ai toftWGfKlhllMimHIlf ILL NWMT CD--UNA AMI SMUTBONN
Ui fUflTONI PMviMDCatr imuiKHUTfl TO -NO M1ICT*M"VCHtlU WMATIftfl
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SIN lit INHIATifMA
For the VCM industry, the engineering control steps for OSHA compliance are significantly the same as those potentially used for air pollution control. Therefore, appreciable air pollution control costs are automatically accounted for by OSHA compliance.
For the PVC industry, engineering control steps from the 50 ppm VCM ceiling level to the 15-25 ppm ceiling with 10-15 ppm TWA primarily address OSHA compliance, but significant air pollution control benefits are gained, especially at lower levels.
3. AREA MONITORING. PARTICULARLY IN PVC PLANTS IS RECOMMENDED TO OSHA AS A COMPLIANCE REQUIREMENT REGARDLESS OF THE TARGET; LEVEL SELECTED BY OSHA
4
Automatic Sequential Monitoring Systems (ASMS] can serve as a long term data collection system for an entire plant.
The ASMS can analyze an air sample from a particular point in the plant in 1 to 3 minutes with potential for at least 10 point monitoring.
The ASMS can be used to provide correlation with personnel monitoring data of actual worker exposure. In addition, it can be used to provide a permanent record of VCM levels, provide alarms in case of exceeding ceiling values, serve as a means to initially identify the general sources of VCM releases, and to monitor progress in complying with OSHA requirements.
A system installed in the polymerization building can provide warning to work personnel in that area if VCM levels have gone above ceiling levels.
Response to alarm can be standardized. These steps could include donning of personal protective equipment, investigation using leak detectors, isolating the point of VCM release and corrective maintenance.
CJ c So
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VI-4
4. IT IS RECOMMENDED THAT OSHA ESTABLISH PHASED REQUIREMENTS FOR REACHING VCM TARGET LEVELS TO ALLOW THE COLLECTION OF ADDITIONAL VCM MONITORING DATA TO FULLY ASSESS THE EFFICIENCY OF THE CORRECTIVE STEPS. SUBJECT TO REVIEW IN LIGHT OF CURRENT MEDICAL FINDINGS. AND AS THEY BECOME AVAILABLE
. The currently available data base particularly for VCM monitoring, is relatively small. In addition, the technology required for compliance with the lower VCM levels is not yet proven. Consequently, considerable risks exist as to the efficacy of engineering controls even for levels other than "no detectable", which is not technologically feasible. A phased compliance plan would allow for the assessment of the efficiency of corrective steps already taken by industry. In any event, significant lead times exist for hardware required for engineering controls.
The phased compliance plan should be reviewed in light of current and emerging medical findings.
A possible result of a phased compliance plan would be to spread the costs of compliance over periods of time. This may be desirable considering that the VCM and PVC price impacts may be of the same order of magnitude as the price results of the "energy crisis".
Developmental efforts should be encouraged to improve techniques in personal protective devices, monitoring systems, and residual monomer reductions.
*****
The Appendices supporting the report follow in a separate volume.
VI-5
036114