Document wgLRpVQGMM3EdbQgzarJdyrNB

450,000 400,000 350,000 300,000 250,000 200,000 150,000 100,000 50,000 0 Point of discharge Ave. % of WW discharged from TXT processes 1 100 0 100 100 100 100 100 99 100 93 95 100 95 100 90 88 99 100 SPECIFIC AMOUNT OF WASTE WATER DISCHARGED (range 0-450,000 m3/t of textile treated) 99 100 100 98 100 100 99 0 99 100 100 100 100 0.99 99 99 99.5 97 100 0 0 86.3 98 63.3 100 Specific amount of waste water discharged (m3/t of textile treated) CZ015_w {1} FR132_w {1} IT084_w {1} FR132_w {2} IT065_w {1} UK128_w {1} DE024_w {1} UK129_w {1} IT061_w {1} BE013_w {1} BE007_w {1} IT069_w {1} FR135_w {1} IT068_w {1} DE050_w {1} DE029_w {1} BE014_w {1} PT110_w {2} BE009_w {1} IT075_w {1} IT089_w {1} ES058_w {1} FR131_w {1} AT004_w {1} DE046_w {1} DE031_w {1} IT072_w {1} IT071_w {1} IT071_w {2} DE039_w {1} IT059_w {2} DE034_w {1} UK121_w {1} IT079_w {1} IT094_w {1} IT090_w {1} DE049_w {1} UK126_w {1} IT067_w {1} IT074_w {1} IT074_w {2} IT085_w {1} BE008_w {1} UK127_w {1} DE041_w {1} DE030_w {1} PT104_w {1} IT076_w {1} DE051_w {1} BE011_w {1} IT087_w {1} DE022_w {1} IT096_w {1} FR134_w {1} BE010_w {1} DE023_w {1} PT109_w {1} AT003_w {1} IT064_w {1} PT113_w {1} IT078_w {1} AT005_w {1} PT108_w {1} IT092_w {1} PT110_w {1} PT102_w {1} IT077_w {1} IT077_w {2} DE047_w {1} SE119_w {1} IT082_w {1} SE120_w {1} PT099_w {1} IT091_w {1} IT073_w {1} IT083_w {1} PT114_w {1} PT117_w {1} SE118_w {1} CZ017_w {1} DE044_w {1} PT111_w {1} IT070_w {1} IT097_w {1} UK124_w {1} PT098_w {1} CZ020_w {1} IT059_w {1} PT105_w {1} IT088_w {1} DE025_w {1} 100 93 100 95 100 47.1 100 95 99.9 95 90 82.1 100 99 99.2 99 99 90 100 100 80 100 99 100 100 100 95 100 90 100 100 100 16.7 99.1 Ref. Ares(2021)5421579 - 02/09/2021 100 100 2016 Specific amount of WW (m3/t textile treated) 2017 Specific amount of WW (m3/t textile treated) 2018 Specific amount of WW (m3/t textile treated) 1 Point of discharge Ave. % of WW discharged from TXT processes 2 1,000 900 800 700 600 500 400 300 200 100 0 100 0 100 100 100 100 100 99 100 93 95 100 95 100 90 88 99 100 SPECIFIC AMOUNT OF WASTE WATER DISCHARGED (zoom 0-1,000 m3/t of textile treated) 99 100 100 98 100 100 99 0 99 100 100 100 100 0.99 99 99 99.5 97 100 0 0 86.3 98 63.3 100 Specific amount of waste water discharged (m3/t of textile treated) CZ015_w {1} FR132_w {1} IT084_w {1} FR132_w {2} IT065_w {1} UK128_w {1} DE024_w {1} UK129_w {1} IT061_w {1} BE013_w {1} BE007_w {1} IT069_w {1} FR135_w {1} IT068_w {1} DE050_w {1} DE029_w {1} BE014_w {1} PT110_w {2} BE009_w {1} IT075_w {1} IT089_w {1} ES058_w {1} FR131_w {1} AT004_w {1} DE046_w {1} DE031_w {1} IT072_w {1} IT071_w {1} IT071_w {2} DE039_w {1} IT059_w {2} DE034_w {1} UK121_w {1} IT079_w {1} IT094_w {1} IT090_w {1} DE049_w {1} UK126_w {1} IT067_w {1} IT074_w {1} IT074_w {2} IT085_w {1} BE008_w {1} UK127_w {1} DE041_w {1} DE030_w {1} PT104_w {1} IT076_w {1} DE051_w {1} BE011_w {1} IT087_w {1} DE022_w {1} IT096_w {1} FR134_w {1} BE010_w {1} DE023_w {1} PT109_w {1} AT003_w {1} IT064_w {1} PT113_w {1} IT078_w {1} AT005_w {1} PT108_w {1} IT092_w {1} PT110_w {1} PT102_w {1} IT077_w {1} IT077_w {2} DE047_w {1} SE119_w {1} IT082_w {1} SE120_w {1} PT099_w {1} IT091_w {1} IT073_w {1} IT083_w {1} PT114_w {1} PT117_w {1} SE118_w {1} CZ017_w {1} DE044_w {1} PT111_w {1} IT070_w {1} IT097_w {1} UK124_w {1} PT098_w {1} CZ020_w {1} IT059_w {1} PT105_w {1} IT088_w {1} DE025_w {1} 100 93 100 95 100 47.1 100 95 99.9 95 90 82.1 100 99 99.2 99 99 90 100 100 80 100 99 100 100 100 95 100 90 100 100 100 16.7 99.1 100 100 2016 Specific amount of WW (m3/t textile treated) 2017 Specific amount of WW (m3/t textile treated) 2018 Specific amount of WW (m3/t textile treated) 1 100 90 80 70 60 50 40 30 20 10 0 Point of discharge Ave. % of WW discharged from TXT processes 3 100 0 100 100 100 100 100 99 100 93 95 100 95 100 90 88 99 100 SPECIFIC AMOUNT OF WASTE WATER DISCHARGED (zoom 0-100 m3/t of textile treated) 99 100 100 98 100 100 99 0 99 100 100 100 100 0.99 99 99 99.5 97 100 0 0 86.3 98 63.3 100 Specific amount of waste water discharged (m3/t of textile treated) CZ015_w {1} FR132_w {1} IT084_w {1} FR132_w {2} IT065_w {1} UK128_w {1} DE024_w {1} UK129_w {1} IT061_w {1} BE013_w {1} BE007_w {1} IT069_w {1} FR135_w {1} IT068_w {1} DE050_w {1} DE029_w {1} BE014_w {1} PT110_w {2} BE009_w {1} IT075_w {1} IT089_w {1} ES058_w {1} FR131_w {1} AT004_w {1} DE046_w {1} DE031_w {1} IT072_w {1} IT071_w {1} IT071_w {2} DE039_w {1} IT059_w {2} DE034_w {1} UK121_w {1} IT079_w {1} IT094_w {1} IT090_w {1} DE049_w {1} UK126_w {1} IT067_w {1} IT074_w {1} IT074_w {2} IT085_w {1} BE008_w {1} UK127_w {1} DE041_w {1} DE030_w {1} PT104_w {1} IT076_w {1} DE051_w {1} BE011_w {1} IT087_w {1} DE022_w {1} IT096_w {1} FR134_w {1} BE010_w {1} DE023_w {1} PT109_w {1} AT003_w {1} IT064_w {1} PT113_w {1} IT078_w {1} AT005_w {1} PT108_w {1} IT092_w {1} PT110_w {1} PT102_w {1} IT077_w {1} IT077_w {2} DE047_w {1} SE119_w {1} IT082_w {1} SE120_w {1} PT099_w {1} IT091_w {1} IT073_w {1} IT083_w {1} PT114_w {1} PT117_w {1} SE118_w {1} CZ017_w {1} DE044_w {1} PT111_w {1} IT070_w {1} IT097_w {1} UK124_w {1} PT098_w {1} CZ020_w {1} IT059_w {1} PT105_w {1} IT088_w {1} DE025_w {1} 100 93 100 95 100 47.1 100 95 99.9 95 90 82.1 100 99 99.2 99 99 90 100 100 80 100 99 100 100 100 95 100 90 100 100 100 16.7 99.1 100 100 2016 Specific amount of WW (m3/t textile treated) 2017 Specific amount of WW (m3/t textile treated) 2018 Specific amount of WW (m3/t textile treated) 1 EP water name DE042_w {1} PT114_w {2} CZ019_w {1} FR136_w {1} CZ015_w {1} FR132_w {1} IT084_w {1} FR132_w {2} IT065_w {1} UK128_w {1} DE024_w {1} UK129_w {1} IT061_w {1} BE013_w {1} BE007_w {1} IT069_w {1} FR135_w {1} IT068_w {1} DE050_w {1} DE029_w {1} BE014_w {1} PT110_w {2} BE009_w {1} IT075_w {1} IT089_w {1} ES058_w {1} FR131_w {1} AT004_w {1} DE046_w {1} DE031_w {1} IT072_w {1} IT071_w {1} IT071_w {2} Type of discharge DIR = Direct IND = Indirect IND IND DIR IND IND DIR IND DIR IND IND IND IND IND IND DIR IND IND IND IND IND DIR IND DIR IND IND IND DIR IND IND IND IND IND IND SPECIFIC AMOUNT OF WASTE WATER (WW) DISCHARGE: 2016-2018 Associated processes Washing synthetic fibre - Desizing - Bleaching - Dyeing Functional finishing Bleaching - Dyeing - Printing - Functional finishing Desizing Desizing - Scouring - Bleaching - Mercerising - Dyeing Singeing - Fabric production - Functional finishing Dyeing - Functional finishing Bleaching - Dyeing - Thermal treatment (e.g drying, thermofixation, curing) Bleaching - Dyeing Raw wool scouring Desizing - Dyeing - Scouring - Singeing Raw wool scouring Scouring - Wool Carbonising Mercerising Dyeing 2016 Specific amount of WW (m3/t textile treated) 2017 Specific amount of WW (m3/t textile treated) 2018 Specific amount of WW (m3/t textile treated) 2016 Proportion 2017 Proportion 2018 Proportion of WW from of WW from of WW from Origin of other non-textile WW streams textile (%) textile (%) textile (%) 97.0 Waste water energy and water production 0 0 0 Water to boilers 100 100 100 100 100 100 0.01 0.01 0.05 0.05 0.05 100 100 all cooling water is in the second step used in textile finishing processes 0 0 0.11 0.13 0.13 100 100 100 0.14 0.14 0.14 100 100 100 0.12 0.12 0.14 100 100 100 2.70 2.68 2.79 100 100 100 3.90 3.80 3.70 4.43 3.83 3.88 100 100 100 n/a 5.20 6.00 6.30 99.0 99.0 99.0 igienic waste water 9.71 8.59 7.30 100 100 100 distillation process for ammonia recovery 10.73 7.83 93.6 92.3 sanitary waste water - figures based on pile weight Scouring - Bleaching - Mercerising 10.50 11.20 7.10 95.0 95.0 95.0 Steam generator, primary water treatment equipment (e.g. softeners); data referring to the year 2015 Washing synthetic fibre 9.79 10.04 11.48 100 100 100 Washing synthetic fibre - Desizing - Scouring - Bleaching - 14.70 14.30 11.20 95.0 95.0 95.0 Steam generator, primary water treatment equipment Dyeing - Functional finishing - Other (e.g. softeners) Washing synthetic fibre - Desizing - Bleaching 14.60 15.80 12.40 100 100 100 Dyeing 17.50 18.00 14.00 90.0 90.0 90.0 Water/Steam preparation Bleaching - Dyeing - Functional finishing 9.10 11.18 20.86 88.0 88.0 88.0 12% evaporation Dyeing 7.16 21.59 10.14 99.0 99.0 99.0 Bathrooms Printing responsible for 93% of waste water generated, Printing - Coating (also back-coating) and laminating 25.23 23.05 20.78 100 100 100 specific water usage related to weight of printed pile weight Raw wool scouring 23.61 23.38 25.57 specific consuption refered to kg of Tops/Sliver produced Scouring - Dyeing - Thermal treatment (e.g drying, thermofixation, curing) - Other - Bleaching Mercerising - Bleaching - Dyeing - Desizing - Fabric production - Printing - Thermal treatment (e.g drying, thermofixation, curing) Washing synthetic fibre - Bleaching - Dyeing - Printing Functional finishing - Coating (also back-coating) and laminating - Thermal treatment (e.g drying, thermofixation, curing) Washing synthetic fibre Washing synthetic fibre - Dyeing Dyeing Thermal treatment (e.g drying, thermofixation, curing) Scouring - Bleaching - Dyeing - Other Dyeing - Bleaching - Scouring Dyeing - Other - Functional finishing 23.90 25.80 24.70 99.0 99.0 99.0 toilet waste water;toilet waste water;toilet waste water; data related to 2015 27.75 24.70 24.48 100 100 100 27.00 27.10 29.40 100 100 100 30.55 29.73 27.96 98.0 98.0 98.0 2;2;2 25.00 26.00 32.00 100 100 100 25.33 33.68 23.62 100 100 100 25.20 29.20 34.30 99.0 99.0 99.0 igienic waste water 31.00 35.80 30.30 0 0 0 31.00 35.80 30.50 99.0 99.0 99.0 igienic waste water 4 1 EP water name DE039_w {1} IT059_w {2} DE034_w {1} UK121_w {1} IT079_w {1} IT094_w {1} IT090_w {1} DE049_w {1} UK126_w {1} IT067_w {1} IT074_w {1} IT074_w {2} IT085_w {1} BE008_w {1} UK127_w {1} DE041_w {1} DE030_w {1} PT104_w {1} IT076_w {1} DE051_w {1} BE011_w {1} IT087_w {1} DE022_w {1} Type of discharge DIR = Direct IND = Indirect IND IND DIR IND IND IND IND IND IND DIR IND IND IND IND IND IND IND IND IND IND DIR IND IND SPECIFIC AMOUNT OF WASTE WATER (WW) DISCHARGE: 2016-2018 Associated processes Mercerising - Dyeing - Washing synthetic fibre - Bleaching - Desizing Thermal treatment (e.g drying, thermofixation, curing) Functional finishing 2016 Specific amount of WW (m3/t textile treated) 35.00 36.62 2017 Specific amount of WW (m3/t textile treated) 36.00 26.52 2018 Specific amount of WW (m3/t textile treated) 29.00 28.28 2016 Proportion of WW from textile (%) 100 100 2017 Proportion of WW from textile (%) 100 100 2018 Proportion of WW from textile (%) 100 100 Origin of other non-textile WW streams Washing synthetic fibre - Desizing - Bleaching - Dyeing 37.90 38.00 100 100 100 Dyeing 35.38 40.69 100 100 Scouring - Wool Fulling - Functional finishing - Thermal treatment (e.g drying, thermofixation, curing) - Other 30.50 41.90 32.60 0.99 0.99 0.99 toilete waste water 30.82 35.88 41.93 99.0 99.0 99.0 civil wastewater Scouring - Dyeing - Thermal treatment (e.g drying, thermofixation, curing) - Other - Bleaching 26.20 42.30 24.80 99.0 99.0 99.0 toilet waste water;toilet waste water;toilet waste water; data related to 2015 Desizing - Bleaching - Bleaching - Dyeing - Singeing - Printing - Coating (also back-coating) and laminating - 43.40 99.5 99.5 99.5 boiler wastewater Scouring - Functional finishing Dyeing 22.63 31.45 43.45 97.0 97.0 97.0 Compound external unloading area run off Dyeing - Printing - Other - Shrink-proof finishing 43.62 43.69 43.10 100 100 100 specific consuption refered to total material processed (kg on shrink-proof treatment + kg dyed) Washing synthetic fibre - Scouring - Functional finishing - 38.30 41.70 43.70 0 0 0 Steam generator, primary water treatment equipment Dry cleaning - Other (e.g. softeners) (YEAR 2015) Washing synthetic fibre - Scouring 38.30 41.70 43.70 0 0 0 Steam generator, primary water treatment equipment (e.g. softeners) (YEAR 2015) specific consuption refered to dyed tops Dyeing 44.80 37.01 40.38 produced;specific consuption refered to dyed tops produced;specific consuption refered to dyed tops produced Printing - Dyeing 43.10 40.48 45.61 85.0 87.0 87.0 Water treatment (+/-15 %) (de-ironising and de-ionising) and domestic waste water (+/- 5 %) Mercerising - Bleaching - Dyeing - Scouring - Singeing Printing 40.36 44.46 48.05 98.0 98.0 98.0 surface water Desizing - Bleaching - Dyeing 48.00 50.35 37.11 70.0 70.0 50.0 Washing synthetic fibre - Desizing - Mercerising Bleaching - Singeing - Dyeing - Functional finishing Thermal treatment (e.g drying, thermofixation, curing) 46.51 45.60 51.18 100 100 100 Dyeing - Bleaching Raw wool scouring Washing synthetic fibre - Scouring - Bleaching - Dyeing Functional finishing Dyeing Dyeing - Shrink-proof finishing - Shrink-proof finishing Other 53.40 43.96 50.60 47.73 48.80 58.32 specific consuption refered to kg of Tops produced 60.00 60.00 60.00 100 100 100 60.94 56.72 62.87 93.0 93.0 93.0 7% sanitary origin, soil remediation specific consumption refered to dyed yarn 64.00 58.00 55.00 100 100 100 production;specific consumption refered to dyed yarn production;specific consumption refered to dyed yarn production Raw wool scouring - Washing synthetic fibre - Desizing Scouring - Bleaching - Dyeing - Thermal treatment (e.g drying, thermofixation, curing) - Functional finishing Coating (also back-coating) and laminating 55.00 65.00 50.00 95.0 95.0 95.0 generation steam freshwater preparation 5 2 EP water name IT096_w {1} FR134_w {1} BE010_w {1} DE023_w {1} PT109_w {1} AT003_w {1} IT064_w {1} PT113_w {1} IT078_w {1} AT005_w {1} PT108_w {1} IT092_w {1} PT110_w {1} PT102_w {1} IT077_w {1} IT077_w {2} DE047_w {1} SE119_w {1} IT082_w {1} SE120_w {1} PT099_w {1} IT091_w {1} IT073_w {1} IT083_w {1} PT114_w {1} PT117_w {1} SE118_w {1} Type of discharge DIR = Direct IND = Indirect DIR DIR DIR IND IND IND IND IND IND IND IND DIR DIR IND IND IND IND IND DIR IND IND IND IND IND IND IND IND SPECIFIC AMOUNT OF WASTE WATER (WW) DISCHARGE: 2016-2018 Associated processes 2016 Specific amount of WW (m3/t textile treated) 2017 Specific amount of WW (m3/t textile treated) 2018 Specific amount of WW (m3/t textile treated) 2016 Proportion 2017 Proportion 2018 Proportion of WW from of WW from of WW from Origin of other non-textile WW streams textile (%) textile (%) textile (%) Dyeing - Other 61.00 65.00 55.00 100 100 100 specific consumption refered to dyed yarn production Washing synthetic fibre - Desizing - Mercerising Bleaching - Dyeing - Singeing - Functional finishing Bleaching - Dyeing - Bleaching - Scouring - Functional finishing 51.00 65.00 67.00 60.83 53.41 67.71 54.3 49.9 37.0 cleaning of sand filtration, cooling compressors, air conditioning fabric production Washing synthetic fibre - Mercerising - Bleaching - Dyeing 72.00 100 74.00 Mercerising - Dyeing - Desizing - Bleaching 74.10 70.50 Scouring 67.00 79.90 80.40 95.0 95.0 95.0 Steam generator, primary water treatment equipment (e.g. softeners) Dyeing - Washing synthetic fibre - Bleaching - Functional finishing 78.68 81.03 99.9 99.9 laboratory, toilets Wool Fulling - Washing synthetic fibre - Dyeing 74.10 88.70 68.50 95.0 95.0 95.0 Steam generator, primary water treatment equipment (e.g. softeners) 97.20 94.40 95.30 90.6 90.7 88.6 rest rooms, steaming machine Fabric production - Fabric production 99.34 87.71 85.53 86.9 80.5 78.8 13,1;19,5;21,2 Dyeing - Other 99.37 94.18 97.20 100 100 100 specific consumption refered to dyed yarn production Dyeing Scouring - Dyeing - Bleaching 97.06 81.73 101.14 99.0 99.0 99.0 Bathrooms 98.10 89.30 101.60 99.1 99.5 98.9 Domestic and rainwater Desizing - Mercerising - Scouring - Bleaching - Singeing - 103.70 101.40 86.90 99.0 99.0 99.0 igienic service waste water Thermal treatment (e.g drying, thermofixation, curing) Dyeing 103.70 101.40 86.90 99.0 99.0 99.0 igienic service waste water Desizing - Mercerising - Bleaching - Dyeing - Functional finishing 100.00 110.00 90.0 90.0 Rain Washing synthetic fibre - Desizing - Functional finishing - 115.00 101.00 98.00 100 100 100 Dyeing Dyeing - Singeing - Functional finishing - Thermal treatment (e.g drying, thermofixation, curing) - Wool 117.00 116.00 114.00 100 100 100 specific consuption refered to woven textile production Fulling Washing synthetic fibre - Desizing - Bleaching 123.00 122.50 122.00 80.0 80.0 80.0 Dyeing - Printing - Functional finishing 106.00 127.00 116.00 100 100 100 Scouring - Dyeing - Functional finishing - Thermal treatment (e.g drying, thermofixation, curing) - Other 125.80 125.60 127.10 99.0 99.0 99.0 year 2015 Dyeing - Functional finishing 121.20 111.70 129.60 100 100 100 Scouring - Dyeing - Functional finishing 139.16 131.73 136.88 100 100 100 Mercerising - Dyeing - Washing synthetic fibre - Desizing - Scouring - Bleaching - - Thermal treatment (e.g drying, 152.42 143.32 154.04 100 100 100 thermofixation, curing) - Dry cleaning Dyeing - Dyeing - Bleaching - Functional finishing 152.73 161.45 164.28 95.0 95.0 95.0 domestic water Washing synthetic fibre - Scouring - Scouring - Bleaching - Dyeing - Singeing - Printing - Functional finishing - Shrink- proof finishing - Coating (also back-coating) and 113.00 119.00 168.00 100 100 100 laminating - Thermal treatment (e.g drying, thermofixation, curing) 6 3 EP water name CZ017_w {1} DE044_w {1} PT111_w {1} IT070_w {1} IT097_w {1} UK124_w {1} PT098_w {1} CZ020_w {1} IT059_w {1} PT105_w {1} IT088_w {1} DE025_w {1} Type of discharge DIR = Direct IND = Indirect IND IND DIR IND DIR DIR DIR DIR IND IND IND DIR SPECIFIC AMOUNT OF WASTE WATER (WW) DISCHARGE: 2016-2018 Associated processes Spinning - Fabric production - Singeing - Functional finishing - Shrink-proof finishing - Thermal treatment (e.g drying, thermofixation, curing) - Other Desizing - Mercerising - Bleaching - Dyeing 2016 Specific amount of WW (m3/t textile treated) 2017 Specific amount of WW (m3/t textile treated) 2018 Specific amount of WW (m3/t textile treated) 2016 Proportion 2017 Proportion 2018 Proportion of WW from of WW from of WW from Origin of other non-textile WW streams textile (%) textile (%) textile (%) 162.35 143.27 172.76 150.00 180.00 200.00 90.0 90.0 90.0 pretreatment fresh water Desizing - Dyeing - Fabric production - Wool Fulling Functional finishing - Shrink-proof finishing - Dry cleaning Thermal treatment (e.g drying, thermofixation, curing) 199.58 224.63 225.30 Domstic waste - Bathrooms Dyeing - Shrink-proof finishing - Printing - Other 222.00 235.00 100 100 252.06 258.60 240.00 100 100 100 specific consuption refered to dyed yarn production 285.39 249.91 310.78 100 100 100 Wool Fulling - Functional finishing - Dyeing - Thermal treatment (e.g drying, thermofixation, curing) 328.24 276.83 228.59 WC+Canteen;WC;WC Dyeing Scouring - Mercerising - Bleaching - Dyeing - Singeing Dry cleaning 494.20 342.10 372.60 17.0 14.0 19.0 City communal waste water from buildings (Wcs , bathrooms), ballast water 695.84 503.95 537.46 99.1 99.0 99.1 Civil waste water Dyeing - Bleaching 909.23 The installation only started operating in 2017. The annual value of specific amount of waste water is determined by dividing the monthly values of waste water discharged with the monthly values of production. Dyeing - Bleaching Washing synthetic fibre - Dyeing - Printing 98,526.00 90,456.00 98,429.00 100 100 100 none 334,292.00 408,376.00 305,225.00 100 100 100 7 4 8 Other Anaerobic treatment Membrane bioreactor Distillation/rectification Reverse osmosis Chemical reduction Chemical oxidation Flotation Nanofiltration Microfiltration Ultrafiltration Evaporation Adsorption Activated sludge process Nitrification/denitrification Sand filtration Sedimentation Coagulation and flocculation Screening Grit separators Oil separation Neutralisation Equalisation No technique used UK124_w {4} FR132_w {1} IT082_w {1} IT096_w {1} BE010_w {1} DE032_w {1} BE011_w {1} CZ020_w {1} CZ019_w {1} IT092_w {1} IT097_w {1} PT111_w {1} PT098_w {1} BE007_w {1} DE034_w {1} IT067_w {1} FR132_w {2} PT110_w {1} BE009_w {1} BE014_w {1} DE025_w {1} UK124_w {1} FR131_w {1} FR134_w {1} Techniques applied Max. load over 3 years (g/day) Per DIR Type of discharge Type of monitoring Mass load expressed in g/day Concentration expressed in mg/l 1,000 350,000 300,000 250,000 200,000 150,000 100,000 50,000 0 600 400 200 DIR Per UK124_w {4} FR132_w {1} IT082_w {1} IT096_w {1} BE010_w {1} DE032_w {1} BE011_w {1} CZ020_w {1} CZ019_w {1} IT092_w {1} IT097_w {1} PT111_w {1} PT098_w {1} BE007_w {1} DE034_w {1} IT067_w {1} FR132_w {2} PT110_w {1} BE009_w {1} BE014_w {1} DE025_w {1} UK124_w {1} FR131_w {1} FR134_w {1} Freq Freq Per Per Per Per Per Per Freq Freq Per Per Per Per Freq Per Per Per Per Per Per Per DIR DIR DIR DIR DIR DIR DIR DIR DIR DIR DIR DIR DIR DIR DIR DIR DIR DIR DIR DIR DIR DIR UK124_w {4} FR132_w {1} IT082_w {1} IT096_w {1} BE010_w {1} DE032_w {1} BE011_w {1} CZ020_w {1} CZ019_w {1} IT092_w {1} IT097_w {1} PT111_w {1} PT098_w {1} BE007_w {1} DE034_w {1} IT067_w {1} FR132_w {2} PT110_w {1} BE009_w {1} BE014_w {1} DE025_w {1} UK124_w {1} FR131_w {1} FR134_w {1} 0 Point of discharge ELV (mg/l ) over 3 years 800 Average concentration 1,200 COD - Emissions to water 9 Other Anaerobic treatment Membrane bioreactor Distillation/rectification Reverse osmosis Chemical reduction Chemical oxidation Flotation Nanofiltration Microfiltration Ultrafiltration Evaporation Adsorption Activated sludge process Nitrification/denitrification Sand filtration Sedimentation Coagulation and flocculation Screening Grit separators Oil separation Neutralisation Equalisation No technique used UK124_w {4} FR132_w {1} IT082_w {1} IT096_w {1} BE010_w {1} DE032_w {1} BE011_w {1} CZ020_w {1} CZ019_w {1} IT092_w {1} IT097_w {1} PT111_w {1} PT098_w {1} BE007_w {1} DE034_w {1} IT067_w {1} FR132_w {2} PT110_w {1} BE009_w {1} BE014_w {1} DE025_w {1} UK124_w {1} FR131_w {1} FR134_w {1} Techniques applied Max. load over 3 years (g/day) Per DIR Type of discharge Type of monitoring Mass load expressed in g/day Concentration expressed in mg/l 350,000 300,000 250,000 200,000 150,000 100,000 50,000 0 DIR Per UK124_w {4} FR132_w {1} IT082_w {1} IT096_w {1} BE010_w {1} DE032_w {1} BE011_w {1} CZ020_w {1} CZ019_w {1} IT092_w {1} IT097_w {1} PT111_w {1} PT098_w {1} BE007_w {1} DE034_w {1} IT067_w {1} FR132_w {2} PT110_w {1} BE009_w {1} BE014_w {1} DE025_w {1} UK124_w {1} FR131_w {1} FR134_w {1} Freq Freq Per Per Per Per Per Per Freq Freq Per Per Per Per Freq Per Per Per Per Per Per Per DIR DIR DIR DIR DIR DIR DIR DIR DIR DIR DIR DIR DIR DIR DIR DIR DIR DIR DIR DIR DIR DIR UK124_w {4} FR132_w {1} IT082_w {1} IT096_w {1} BE010_w {1} DE032_w {1} BE011_w {1} CZ020_w {1} CZ019_w {1} IT092_w {1} IT097_w {1} PT111_w {1} PT098_w {1} BE007_w {1} DE034_w {1} IT067_w {1} FR132_w {2} PT110_w {1} BE009_w {1} BE014_w {1} DE025_w {1} UK124_w {1} FR131_w {1} FR134_w {1} 200 180 160 140 120 100 80 60 40 20 0 Point of discharge Average concentration over 3 years ELV (mg/l ) COD - Emissions to water (zoom 0-200 mg/l) COD - EMISSIONS TO WATER EP water name Type of discharge DIR = Direct IND = Indirect UK124_w {4} DIR FR132_w {1} DIR IT082_w {1} DIR IT096_w {1} DIR BE010_w {1} DIR IT084_w {1} IND DE032_w {1} DIR BE011_w {1} DIR CZ020_w {1} DIR CZ019_w {1} DIR IT092_w {1} DIR Associated processes No information No information Dyeing - Singeing - Functional finishing - Thermal treatment - Wool Fulling Units for concentration values mg/l mg/l mg/l Dyeing - Other mg/l Bleaching - Dyeing - Bleaching - Scouring - Functional mg/l finishing Bleaching - Dyeing - Thermal treatment mg/l Washing synthetic fibre - Desizing - Bleaching - Dyeing - Printing mg/l Dyeing mg/l Dyeing mg/l Bleaching - Dyeing - Printing - Functional finishing - mg/l Desizing Dyeing - Other mg/l Min. concentration over 3 years Average concentration over 3 years Max. concentration over 3 years Max. load over 3 ELV (mg/l ) years (g/day) Combination of techniques Type of sampling 10 10.00 10 10 27.03 39 12 24.72 43 29 38.67 49 31 45.40 53 24 37.58 54 No information 40 No information Equalisation, Neutralisation, Activated sludge process, 160 Nitrification/denitrification, Sedimentation, Adsorption (e.g. powdered/granular activated carbon, lignite coke, etc.), Other 500 Equalisation, Neutralisation, Activated sludge process, Nitrification/denitrification, Sedimentation, Other 160 EqualisationActivated sludge process, Nitrification/denitrification, Other 160 Equalisation, Neutralisation, Grit separators, Screening, Coagulation and flocculation, Sedimentation No information Grab/spot sample Not applicable No information 24-hour flow proportional composite sample No information 43 51.33 58 Equalisation, Neutralisation, Grit separators, Coagulation and flocculation, Sedimentation, Sand filtration, 24-hour flow proportional composite sample Nitrification/denitrification, Activated sludge process 36 46.07 59 21 34.36 65 71.00 7.6 23.35 73.8 Equalisation, Neutralisation, Coagulation and flocculation, Activated sludge process, Nitrification/denitrification, 160 Sand filtration, Nanofiltration, Chemical oxidation (incl. 24-hour flow proportional composite sample Advanced oxidation) Sedimentation, Nitrification/denitrification, 80 Neutralisation, Coagulation and flocculation, Activated sludge process 100 Equalisation, Neutralisation, Anaerobic treatment, Nitrification/denitrification, Activated sludge process Equalisation, Neutralisation, Activated sludge process, 160 Nitrification/denitrification, Sedimentation, Reverse osmosis No information No information Not applicable IT097_w {1} DIR Dyeing - Shrink-proof finishing - Printing - Other mg/l 28 53.10 80 Equalisation, Neutralisation, Activated sludge process, 160 Nitrification/denitrification, Sedimentation Not applicable PT111_w {1} DIR Desizing - Dyeing - Fabric production - Wool Fulling Functional finishing - Shrink-proof finishing - Dry cleaning -mg/l Thermal treatment 35 56.67 80 150 Equalisation, Neutralisation, Activated sludge process, Sedimentation, Sand filtration, Other No information PT098_w {1} DIR Wool Fulling - Functional finishing - Dyeing - Thermal treatment mg/l 27 58.33 91 Equalisation, Neutralisation, Sedimentation, Sand 150 filtration, Activated sludge process, Other No information BE007_w {1} DIR DE034_w {1} DIR IT067_w {1} DIR FR132_w {2} DIR PT110_w {1} DIR BE009_w {1} DIR PT114_w {2} IND BE014_w {1} DIR DE025_w {1} DIR UK124_w {1} DIR IT076_w {1} IND IT077_w {2} IND Dyeing mg/l Washing synthetic fibre - Desizing - Bleaching - Dyeing mg/l Dyeing - Printing - Other - Shrink-proof finishing mg/l Bleaching - Dyeing mg/l Dyeing mg/l Printing - Coating and laminating No information Bleaching - Dyeing - Functional finishing Washing synthetic fibre - Dyeing - Printing No information Raw wool scouring Dyeing mg/l mg/l mg/l mg/l mg/l mg/l No unit reported 24 52 30 69 19 44 64 20 107.51 88 92.94 59.00 60.18 92.28 74.97 100.75 85.67 87.93 96.76 68.20 96.89 179.33 97 44426 108 116 125 136 140 146 170 174 213324 190 303 Equalisation, Neutralisation, Sand filtration, Activated sludge process, Nitrification/denitrification 100 Activated sludge process, Nitrification/denitrification Flow proportional composite sample, Not applicable, Flow proportional composite sample Flow proportional composite sample 160 Equalisation, Neutralisation, Activated sludge process, Nitrification/denitrification, Sedimentation Not applicable 1000 Other Equalisation, Grit separators, Screening, Coagulation and 125 flocculation, Sedimentation, Activated sludge process, Other Screening, Sedimentation, Equalisation, Activated sludge process, Sand filtration, Coagulation and flocculation, 160 Flotation, Chemical oxidation (incl. Advanced oxidation), Sand filtration, Chemical reduction, Microfiltration, Reverse osmosis 2000 No information 160 Equalisation, Activated sludge process, Nitrification/denitrification Grab/spot sample No information Other, 24-hour flow proportional composite sample, Other No information 24-hour flow proportional composite sample 130 Equalisation, Neutralisation, Coagulation and flocculation, 24-hour flow proportional composite sample Sedimentation, Activated sludge process Neutralisation, Coagulation and flocculation, Flotation, Other Other Equalisation, Flotation, Coagulation and flocculation, 1000 Activated sludge process, Nitrification/denitrification, Sedimentation, Membrane bioreactor Not applicable 3000 No information Other Monitoring frequency Yearly No information 4 times per year Yearly Yearly 4 times per year Twice per year No information Monthly Monthly Monthly Other 4 times per year Twice per year Monthly No information Monthly No information Monthly No information Yearly No information Monthly Weekly Weekly Twice per year IT075_w {1} IND Raw wool scouring mg/l 97 160.16 399 Equalisation, Coagulation and flocculation, Activated 500 sludge process, Nitrification/denitrification, Sedimentation Not applicable Other IT078_w {1} IND IT059_w {1} IND AT006_w {1} IND Wool Fulling - Washing synthetic fibre - Dyeing mg/l Scouring - Mercerising - Bleaching - Dyeing - Singeing - mg/l Dry cleaning Bleaching - Dyeing mg/l 149 352.50 572 201 414.67 672 256 441.00 678 3000 Other 3000 Other Flotation Other Not applicable No information Twice per year Twice per year Other PT099_w {1} IND PT117_w {1} IND IT064_w {1} IND IT072_w {1} IND IT087_w {1} IND Dyeing - Printing - Functional finishing mg/l Dyeing - Dyeing - Bleaching - Functional finishing mg/l Scouring mg/l Thermal treatment - Scouring - Bleaching - Dyeing - mg/l Other Dyeing - Shrink-proof finishing - Shrink-proof finishing - mg/l Other 403 552.33 697 213 539.75 736 485 631.33 752 305 495.67 755 360 583.00 759 1000 Screening, Oil separation, Other 1000 Neutralisation 3000 Other 3000 Other 655 Equalisation No information 24-hour flow proportional composite sample Other Other Not applicable, Grab/spot sample, Not applicable 4 times per year Monthly Twice per year Twice per year Monthly 10 Monitoring standard COD Acid Dichromate Oxidised; determined by spectrometry No information ISO 15705:2002, ISO 15705:2002, IRSA QUAD.11/79 Additional information All values reported as <10 - All values reported as <10 All values reported as <10 ISO 15705:2002 WAC/III/D/020 ISPRA Man 117 2014 Value refered to sampling period - Value refered to sampling period - Value refered to sampling period 3 h medium composite sample - 3 h medium composite sample - 3 h medium composite sample No information WAC/III/D/020 specified in extern laboratory No information ISO 15705:2002 APAT CNR IRSA 5130 Man 29 2003, IRSA Quad.11/79, IRSA Quad.11/79; ISO 15705:2002 SMEWW 5220 D Value refered to sampling period - Value refered to sampling period - Value refered to sampling period Monitoring frequency: once every 4 monthsValue refered to sampling period - Monitoring frequency: once every 4 monthsValue refered to sampling period - Monitoring frequency: once every 4 monthsValue refered to sampling period PNT MA/FQ2-03(2013-04-08), PNT MA/FQ2-03(2013-0408)-MESU.1 and PNT-MA/FQ2-08(2016-07-27) - MESU.2, PNT MA/FQ2-08(2016-07-27) Averaging period for ELVs: Twice per year - Uncertainty: Method PNT MA/FQ2-03(2013-04-08) 11%; PNT-MA/FQ208(2016-07-27) 12% ; Averaging period for ELVs: Twice per year - Averaging period for ELVs: Twice per year WAC/III/D/020 No information under mesurement 1,.. you find the measured values from the authority surveillance APAT CNR IRSA 5130 Man 29 2003, APAT CNR IRSA 5130 Value refered to sampling period - Value refered to Man 29 2003, APAT CNR IRSA 5130 Man 29 2003 sampling period - Value refered to sampling period No information No information 125 in the normal period and 100 in the dry season - 125 in the normal period and 100 in the dry season - 125 in the normal period and 100 in the dry season WAC/III/D/020 Less than 12/year flow proportionate sampling, >12/year are grab sample results. Value 0 means results beneath detection limit of analyses No information WAC/III/D/020 No information SX I COD - acid dichromate oxidised; determined by spectrometry ISO 15705:2002; IRSA Quad.11/79 Value refered to sampling period - Value refered to sampling period - Value refered to sampling period ISO 15705:2002 Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours No information Monitoring end frequency dependent on the operator of the off-site treatment plant - Monitoring end frequency dependent on the operator of the off-site treatment plant - Monitoring end frequency dependent on the operator of the off-site treatment plant ISO 15705:2002 Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours ISO 15705:2002 NORM M 6265:1991 self-monitoring: twice a week (Foto-meter) - selfmonitoring: twice a week (Foto-meter) - self-monitoring: twice a week (Foto-meter) Internal method Laboratory PAQ12 08-01-2018/ Espec Abs Molecular, Internal method Laboratory PAQ12 08-012018/ Espec Abs Molecular, Internal method Laboratory PAQ12 08-01-2018/ Espec Abs Molecular ISO ISO 15705:2002 Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours ISO 15705:2002 No information - Value refered to sampling period - Value refered to sampling period 1 COD - EMISSIONS TO WATER EP water name IT071_w {1} Type of discharge DIR = Direct IND = Indirect IND FR131_w {1} DIR IT073_w {1} IND IT082_w {2} IND IT083_w {1} IND FR134_w {1} DIR PT115_w {1} IND BE013_w {1} IND IT063_w {1} IND IT071_w {2} IND PT102_w {1} IND PT114_w {1} IND PT110_w {2} IND IT094_w {1} IND AT004_w {1} IND BE008_w {1} IND IT074_w {1} IND IT068_w {1} IND IT070_w {1} IND IT077_w {1} IND FR135_w {1} IND PT105_w {1} IND DE051_w {1} IND IT091_w {1} IND IT090_w {1} IND PT113_w {1} IND IT065_w {1} IND CZ017_w {1} IND DE022_w {1} IND Associated processes Units for concentration values Min. concentration over 3 years Average concentration over 3 years Max. concentration over 3 years Max. load over 3 ELV (mg/l ) years (g/day) Combination of techniques Type of sampling Dyeing - Bleaching - Scouring mg/l Washing synthetic fibre - Bleaching - Dyeing - Printing - Functional finishing - Coating and laminating - Thermal mg/l treatment Dyeing - Functional finishing mg/l Dyeing - Singeing - Functional finishing - Thermal mg/l treatment - Wool Fulling Scouring - Dyeing - Functional finishing mg/l Washing synthetic fibre - Desizing - Mercerising - mg/l Bleaching - Dyeing - Singeing - Functional finishing No information mg/l Mercerising mg/l Dyeing - Fabric production - Dry cleaning - Printing - mg/l Printing - Functional finishing Dyeing - Other - Functional finishing mg/l 284 550.83 0 237.00 574 651.50 17 547.33 400 642.67 163 263.92 104 430.17 185 526.00 306 476.44 326 579.33 768 776 329800 779 824 824 837 880 918 947 953 3000 No information Other Other 3000 No technique used No information 2500 Other 250 Equalisation, Neutralisation, Grit separators, Activated sludge process, Anaerobic treatment 2000 Equalisation, Neutralisation, Screening Distillation/rectification, Equalisation, Neutralisation 1000 Equalisation 3000 Other 24-hour flow proportional composite sample Other No information Not applicable No information 24-hour flow proportional composite sample Flow proportional composite sample Other Other Scouring - Dyeing - Bleaching mg/l Mercerising - Dyeing - Washing synthetic fibre - Desizing Scouring - Bleaching - - Thermal treatment - Dry cleaning mg/l Dyeing mg/l No information mg/l Washing synthetic fibre mg/l 160 484.17 590 709.17 85 728.08 372 656.33 617 892.00 980 1000 1059 1077 1090 2000 Other Equalisation, Neutralisation, Screening, Coagulation and 2000 flocculation, Sedimentation, Sand filtration, Adsorption (e.g. powdered/granular activated carbon, lignite coke, etc.) 2000 Equalisation, Grit separators, Screening Other No information 24-hour flow proportional composite sample No information No information No information No information Printing - Dyeing mg/l 550 853.85 1100 Equalisation, Grit separators, Other 24-hour flow proportional composite sample Washing synthetic fibre - Scouring - Functional finishing - mg/l Dry cleaning - Other Washing synthetic fibre - Desizing - Scouring - Bleaching - mg/l Dyeing - Functional finishing - Other No information Desizing - Mercerising - Scouring - Bleaching - Singeing Thermal treatment Washing synthetic fibre mg/l No unit reported mg/l Dyeing - Bleaching mg/l Washing synthetic fibre - Scouring - Bleaching - Dyeing - mg/l Functional finishing Scouring - Dyeing - Functional finishing - Thermal mg/l treatment - Other 650 525 156 155 1111.25 454 910 553 887.67 798.33 501.50 686.00 1219.00 815.75 1155.00 851.33 1126 1140 1150 1236 1329 1340 1400 1470 256497 3000 Other Other 3000 Other Other 3000 No information 3000 No information 1500 Grit separators No information Not applicable Other 24-hour flow proportional composite sample No information Neutralisation, Coagulation and flocculation, Equalisation No information 3000 No information Other Scouring - Dyeing - Thermal treatment - Other - Bleaching mg/l 1026 1231.33 1514 3000 Other 24-hour flow proportional composite sample Dyeing - Washing synthetic fibre - Bleaching - Functional mg/l finishing 617 1005.08 1541 2000 No information Other No information mg/l 400 942.38 1560 Other No information Spinning - Fabric production - Singeing - Functional finishing - Shrink-proof finishing - Thermal treatment - mg/l Other Raw wool scouring - Washing synthetic fibre - Desizing - Scouring - Bleaching - Dyeing - Thermal treatment - mg/l Functional finishing - Coating and laminating 135 853.33 406 1127.17 1600 1675 3000 No information Neutralisation, Oil separation, Evaporation No information Other IT079_w {1} IND Scouring - Wool Fulling - Functional finishing - Thermal treatment - Other mg/l 810 1280.17 1700 3000 Other 24-hour flow proportional composite sample IT085_w {1} IND AT001_w {1} IND AT002_w {1} IND CZ018_w {1} IND IT089_w {1} IND IT088_w {1} IND IT059_w {2} IND IT074_w {2} IND PT104_w {1} IND DE045_w {1} IND PT109_w {1} IND DE039_w {1} IND AT005_w {1} IND IT061_w {1} IND FR136_w {1} IND PT108_w {1} IND IT069_w {1} IND Dyeing mg/l No information mg/l No information mg/l Desizing - Functional finishing - Dyeing - Fabric mg/l production Scouring - Dyeing - Thermal treatment - Other - Bleaching mg/l Dyeing - Bleaching mg/l Thermal treatment - Functional finishing mg/l Washing synthetic fibre - Scouring mg/l Dyeing - Bleaching mg/l Washing synthetic fibre - Desizing - Desizing mg/l No information mg/l Mercerising - Dyeing - Washing synthetic fibre - mg/l Bleaching - Desizing No information mg/l Scouring - Wool Carbonising mg/l Desizing - Scouring - Bleaching - Mercerising - Dyeing - mg/l Singeing - Fabric production - Functional finishing Fabric production - Fabric production mg/l Scouring - Bleaching - Mercerising mg/l 1400 570 290 850 771 388 148 515 400 1660 1000 640 366 2150 650 893 1560.00 1074.62 958.29 1165.83 1252.00 1099.17 620.00 1426.17 1065.83 2200.00 2040.00 1705.00 1454.17 1259.83 2436.28 1479.94 2212.17 1700 1800 1800 1910 1916 1935 2090 2150 2190 2260 2410 2600 2680 2762 2770 2805 Equalisation No information No information 1600 Neutralisation 3000 Other 3000 No information 3000 No technique used 3000 Other No information No information 2000 Oil separation, Neutralisation Equalisation, Neutralisation Neutralisation 3000 Other 4000 Grit separators, Neutralisation 2000 Neutralisation, Sand filtration, Sand filtration 3000 Other Not applicable 24-hour flow proportional composite sample No information 24-hour flow proportional composite sample 24-hour flow proportional composite sample Not applicable Not applicable Other 24-hour flow proportional composite sample 24-hour flow proportional composite sample No information Flow proportional composite sample No information Other No information 24-hour flow proportional composite sample Other DE031_w {1} IND Dyeing mg/l 388 1387.03 3020 No information No information Monitoring frequency Twice per year Daily Twice per year Other Twice per year 4 times per year 4 times per year Yearly 4 times per year Twice per year 4 times per year 4 times per year 4 times per year Twice per year Daily Yearly No information Twice per year Twice per year Twice per year Monthly 4 times per year Monthly No information Twice per year 4 times per year Twice per year Monthly Monthly Twice per year Other Weekly Monthly Other Twice per year Twice per year Twice per year No information 4 times per year Monthly 4 times per year Twice per year Monthly Twice per year No information Monthly Twice per year Other 11 Monitoring standard Additional information ISO 15705:2002 Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours NFT 90 101 unit: mg(O2)/L - unit: mg(O2)/L - unit: mg(O2)/L ISO 15705:2002 ISO 15705:2002 ISPRA Man 117 2014 ISO 15705 SMEWW 5220 D MEIN020 No information ISO 15705:2002 SIDVA - SIDVA - SIDVA sample 22.10.2015-23.10.2015 Authorized in derogation - Authorized in derogation Authorized in derogation Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours SMEWW 5220 D, 21 ed, IT-DLQ-86/V02, IT-DLQ-86/V02 No information No information APAT IRSA 5130 Volume 2:2003 NORM M 6265 (MH) WAC/III/D/020 ISO 15705:2002 ISO 15705:2002 ISO 15705-2002 ISO 15705:2002 No information No information No information ISO 15705:2002 ISO 15705:2002 No information ARPAT CNR IRSA 5130 Man 29 2003 No information Self control and Taxation discharche water - Self control and Taxation discharche water - Self control and Taxation discharche water AVERAGE PERIOD 3 HOURS - AVERAGE PERIOD 3 HOURS AVERAGE PERIOD 3 HOURS (YEAR 2015) Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours (data referring to the year 2015) Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours The installation only started operating in 2017.The value of uncertainty is not refered in the reports. AVERAGE PERIOD 3 HOURS - AVERAGE PERIOD 3 HOURS AVERAGE PERIOD 3 HOURS ELV is referred to 3 hours sampled waste water - ELV is referred to 3 hours sampled waste water - ELV is referred to 3 hours sampled waste water. Data related to 2015. Requested by Italian Law,and other analyses introduced during 2018 to follow the ZDHC Waste Water Guide lines DIN ISO 15705:2002 ISO 15705:2002 DIN 38409 41 DIN 38409-41 No information ISO 15705:2002 iso 15705, iso 15705, iso 15705 ISO 15705:2002 ISO 15705:2002 compound sampling No information No information No information DIN 38409-41 ISO 15705:2002 No information potassium dichromate method ISO 15705:2002 DIN 38409 ELV is referred to 3 hours sampled waste water - ELV is referred to 3 hours sampled waste water - ELV is referred to 3 hours sampled waste water. Data related to 2015. Monitoring end frequency dependent on the operator of the off-site treatment plant monitoring 6 per year - monitoring 6 per year monitoring 6 per year ELV is referred to 3 hours sampled waste water - ELV is referred to 3 hours sampled waste water - ELV is referred to 3 hours sampled waste water. Data related to 2015. Yearly - Yearly - Yearly AVERAGE PERIOD 3 HOURS - AVERAGE PERIOD 3 HOURS AVERAGE PERIOD 3 HOURS (YEAR 2015) AVERAGE PERIOD 3 HOURS - AVERAGE PERIOD 3 HOURS AVERAGE PERIOD 3 HOURS monthly - monthly - monthly Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours (data referring to the year 2015) 23 times/year, almost twice/month - 23 times/year, almost twice/month - 24 times/year, twice/month 2 EP water name Type of discharge DIR = Direct IND = Indirect Associated processes COD - EMISSIONS TO WATER Units for concentration values Min. concentration over 3 years Average concentration over 3 years Max. concentration over 3 years Max. load over 3 ELV (mg/l ) years (g/day) Combination of techniques Type of sampling UK126_w {1} IND Dyeing mg/l 115 1083.60 3320 414266 No information Flow proportional composite sample CZ015_w {1} IND UK121_w {1} IND AT003_w {1} IND SE118_w {1} IND UK127_w {1} IND DE041_w {1} IND DE024_w {1} IND Dyeing - Functional finishing mg/l Dyeing mg/l Mercerising - Dyeing - Desizing - Bleaching mg/l Washing synthetic fibre - Scouring - Scouring - Bleaching - Dyeing - Singeing - Printing - Functional finishing - Shrink- mg/l proof finishing - Coating and laminating - Thermal treatment Mercerising - Bleaching - Dyeing - Scouring - Singeing - mg/l Printing Desizing - Bleaching - Dyeing mg/l Desizing - Dyeing - Scouring - Singeing mg/l 1674 1375 2400 1300 483 452 3328 2586.75 2421.00 3025.00 2322.00 3294.00 3400.00 8284.08 3465 4100 4200 4800 975800 1718400 6330 10400 12360 13129179.6 Grit separators, Equalisation, Sedimentation 4000 Equalisation Other 3000 Sedimentation, Neutralisation 7000 Neutralisation No information Equalisation Flow proportional composite sample 24-hour flow proportional composite sample Other 24-hour flow proportional composite sample 24-hour flow proportional composite sample No information Grab/spot sample UK129_w {1} IND Raw wool scouring Grit separators, Screening, Oil separation, Coagulation mg/l 6790 10766.00 17200 6037200 45000 and flocculation, Ultrafiltration, Flotation 24-hour flow proportional composite sample CZ016_w {1} IND Shrink-proof finishing mg/l 6440 13415.00 27400 No information Flow proportional composite sample Monitoring frequency Other 4 times per year Monthly 4 times per year Weekly Weekly Monthly 4 times per year Daily Monthly UK128_w {1} IND Raw wool scouring mg/l 9530 17957.00 29200 8826600 55000 Coagulation and flocculation 24-hour flow proportional composite sample No information Monitoring standard No information No information 1hr settled. Digestion ISO 6060 DIN 38409-41 No information No information No information No information No information No information No information Additional information Unities Utilities take random samples from the collection unit. It could be once, twice or even three times a month. Unities Utilities take random samples from the collection unit. It could be once, twice or even three times a month. Unities Utilities take random samples from the collection unit. It could be once, twice or even three times a month. Riktvrde: 3000 mg/l Three months averageLimit: 2400 kg/day 7000mg/l in any 24 hour period. Daily max load 10000kg - if COD > 2000, than COD/BOD5 < 4/1 All COD values are Settled COD values and are measured in the effluent after the on-site effluent treatment plant and before the effluent is discharged to public sewer. COD ELV = 45,000mg/litre - Removal efficiencies are based on nominal COD of effluent before on-site treatment generally in the region of 140,000 to 150,000mg/litre. Further treatment in the public sewage works once treated effluent is discharged from site should result in removal e - Results taken from Local sewerage undertakers routine testing as part of compliance permit -results are settled COD - % average removal efficiency for COD & TSS is calculated using an average input to effluent plant of 80000ppm COD and 30000ppm TSS. Remov - Results taken from Local sewerage undertakers routine testing as part of compliance permit -results are settled COD - % average removal efficiency for COD & TSS is calculated using an average input to effluent plant of 80000ppm COD and 30000ppm TSS. Remov - Results taken from Local sewerage undertakers routine testing as part of compliance permit -results are settled COD - % average removal efficiency for COD & TSS is calculated using an average input to effluent plant of 80000ppm COD and 30000ppm TSS. Remov 12 3 13 Other Anaerobic treatment Membrane bioreactor Distillation/rectification Reverse osmosis Chemical reduction Chemical oxidation Flotation Nanofiltration Microfiltration Ultrafiltration Evaporation Adsorption Activated sludge process Nitrification/denitrification Sand filtration Sedimentation Coagulation and flocculation Screening Grit separators Oil separation Neutralisation Equalisation No technique used DE025_w {1} IT082_w {1} BE007_w {1} BE013_w {1} BE011_w {1} BE008_w {1} DE042_w {1} BE014_w {1} DE034_w {1} IT059_w {2} PT098_w {1} DE032_w {1} IT074_w {2} DE044_w {1} IT073_w {1} IT076_w {1} IT069_w {1} IT082_w {2} IT079_w {1} ES058_w {1} PT109_w {1} IT084_w {1} AT006_w {1} DE023_w {1} AT005_w {1} DE046_w {1} IT074_w {1} IT090_w {1} IT061_w {1} IT091_w {1} FR131_w {1} IT089_w {1} BE009_w {1} CZ017_w {1} PT115_w {1} SE118_w {1} IT067_w {1} IT070_w {1} FR135_w {1} IT092_w {1} PT113_w {1} FR136_w {1} IT088_w {1} DE041_w {1} AT001_w {1} IT078_w {1} DE039_w {1} IT063_w {1} DE022_w {1} IT071_w {1} DE049_w {1} PT102_w {1} PT105_w {1} PT110_w {2} PT099_w {1} PT114_w {1} SE119_w {1} IT059_w {1} PT104_w {1} PT111_w {1} IT097_w {1} DE030_w {1} DE026_w {1} DE031_w {1} PT108_w {1} FR134_w {1} AT002_w {1} DE051_w {1} IT065_w {1} AT003_w {1} DE047_w {1} IT094_w {1} DE024_w {1} DE029_w {1} UK127_w {1} IT072_w {1} IT071_w {2} IT064_w {1} IT068_w {1} DE045_w {1} SE120_w {1} UK124_w {1} Techniques applied Max. load over 3 years (g/day) DIR DIR DIR IND DIR IND IND DIR DIR IND DIR DIR IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND DIR IND DIR IND IND IND DIR IND IND DIR IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND DIR DIR IND IND IND IND DIR IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND DIR Per Per Freq Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Freq Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Freq Per Per Freq Per Per Per Per Freq Per Per Per Per Per Per Per Per Per Per Per Per Freq Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Freq Per Per Per Per Freq Freq Per Type of discharge Type of monitoring Mass load expressed in g/day Concentration expressed in mg/l 1,200 1,000 800 600 400 200 0 30 25 20 15 10 5 DE025_w {1} IT082_w {1} BE007_w {1} BE013_w {1} BE011_w {1} BE008_w {1} DE042_w {1} BE014_w {1} DE034_w {1} IT059_w {2} PT098_w {1} DE032_w {1} IT074_w {2} DE044_w {1} IT073_w {1} IT076_w {1} IT069_w {1} IT082_w {2} IT079_w {1} ES058_w {1} PT109_w {1} IT084_w {1} AT006_w {1} DE023_w {1} AT005_w {1} DE046_w {1} IT074_w {1} IT090_w {1} IT061_w {1} IT091_w {1} FR131_w {1} IT089_w {1} BE009_w {1} CZ017_w {1} PT115_w {1} SE118_w {1} IT067_w {1} IT070_w {1} FR135_w {1} IT092_w {1} PT113_w {1} FR136_w {1} IT088_w {1} DE041_w {1} AT001_w {1} IT078_w {1} DE039_w {1} IT063_w {1} DE022_w {1} IT071_w {1} DE049_w {1} PT102_w {1} PT105_w {1} PT110_w {2} PT099_w {1} PT114_w {1} SE119_w {1} IT059_w {1} PT104_w {1} PT111_w {1} IT097_w {1} DE030_w {1} DE026_w {1} DE031_w {1} PT108_w {1} FR134_w {1} AT002_w {1} DE051_w {1} IT065_w {1} AT003_w {1} DE047_w {1} IT094_w {1} DE024_w {1} DE029_w {1} UK127_w {1} IT072_w {1} IT071_w {2} IT064_w {1} IT068_w {1} DE045_w {1} SE120_w {1} UK124_w {1} DE025_w {1} IT082_w {1} BE007_w {1} BE013_w {1} BE011_w {1} BE008_w {1} DE042_w {1} BE014_w {1} DE034_w {1} IT059_w {2} PT098_w {1} DE032_w {1} IT074_w {2} DE044_w {1} IT073_w {1} IT076_w {1} IT069_w {1} IT082_w {2} IT079_w {1} ES058_w {1} PT109_w {1} IT084_w {1} AT006_w {1} DE023_w {1} AT005_w {1} DE046_w {1} IT074_w {1} IT090_w {1} IT061_w {1} IT091_w {1} FR131_w {1} IT089_w {1} BE009_w {1} CZ017_w {1} PT115_w {1} SE118_w {1} IT067_w {1} IT070_w {1} FR135_w {1} IT092_w {1} PT113_w {1} FR136_w {1} IT088_w {1} DE041_w {1} AT001_w {1} IT078_w {1} DE039_w {1} IT063_w {1} DE022_w {1} IT071_w {1} DE049_w {1} PT102_w {1} PT105_w {1} PT110_w {2} PT099_w {1} PT114_w {1} SE119_w {1} IT059_w {1} PT104_w {1} PT111_w {1} IT097_w {1} DE030_w {1} DE026_w {1} DE031_w {1} PT108_w {1} FR134_w {1} AT002_w {1} DE051_w {1} IT065_w {1} AT003_w {1} DE047_w {1} IT094_w {1} DE024_w {1} DE029_w {1} UK127_w {1} IT072_w {1} IT071_w {2} IT064_w {1} IT068_w {1} DE045_w {1} SE120_w {1} UK124_w {1} 0 Point of discharge ELV (mg/l ) over 3 years Average concentration 35 COPPER - Emissions to water 14 Other Anaerobic treatment Membrane bioreactor Distillation/rectification Reverse osmosis Chemical reduction Chemical oxidation Flotation Nanofiltration Microfiltration Ultrafiltration Evaporation Adsorption Activated sludge process Nitrification/denitrification Sand filtration Sedimentation Coagulation and flocculation Screening Grit separators Oil separation Neutralisation Equalisation No technique used DE025_w {1} IT082_w {1} BE007_w {1} BE013_w {1} BE011_w {1} BE008_w {1} DE042_w {1} BE014_w {1} DE034_w {1} IT059_w {2} PT098_w {1} DE032_w {1} IT074_w {2} DE044_w {1} IT073_w {1} IT076_w {1} IT069_w {1} IT082_w {2} IT079_w {1} ES058_w {1} PT109_w {1} IT084_w {1} AT006_w {1} DE023_w {1} AT005_w {1} DE046_w {1} IT074_w {1} IT090_w {1} IT061_w {1} IT091_w {1} FR131_w {1} IT089_w {1} BE009_w {1} CZ017_w {1} PT115_w {1} SE118_w {1} IT067_w {1} IT070_w {1} FR135_w {1} IT092_w {1} PT113_w {1} FR136_w {1} IT088_w {1} DE041_w {1} AT001_w {1} IT078_w {1} DE039_w {1} IT063_w {1} DE022_w {1} IT071_w {1} DE049_w {1} PT102_w {1} PT105_w {1} PT110_w {2} PT099_w {1} PT114_w {1} SE119_w {1} IT059_w {1} PT104_w {1} PT111_w {1} IT097_w {1} DE030_w {1} DE026_w {1} DE031_w {1} PT108_w {1} FR134_w {1} AT002_w {1} DE051_w {1} IT065_w {1} AT003_w {1} DE047_w {1} IT094_w {1} DE024_w {1} DE029_w {1} UK127_w {1} IT072_w {1} IT071_w {2} IT064_w {1} IT068_w {1} DE045_w {1} SE120_w {1} UK124_w {1} Techniques applied Average concentration over 3 years ELV (mg/l ) Max. load over 3 years (g/day) DIR DIR DIR IND DIR IND IND DIR DIR IND DIR DIR IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND DIR IND DIR IND IND IND DIR IND IND DIR IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND DIR DIR IND IND IND IND DIR IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND DIR Per Per Freq Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Freq Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Freq Per Per Freq Per Per Per Per Freq Per Per Per Per Per Per Per Per Per Per Per Per Freq Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Freq Per Per Per Per Freq Freq Per Type of discharge Type of monitoring Mass load expressed in g/day Concentration expressed in mg/l 1,200 1,000 800 600 400 200 0 DE025_w {1} IT082_w {1} BE007_w {1} BE013_w {1} BE011_w {1} BE008_w {1} DE042_w {1} BE014_w {1} DE034_w {1} IT059_w {2} PT098_w {1} DE032_w {1} IT074_w {2} DE044_w {1} IT073_w {1} IT076_w {1} IT069_w {1} IT082_w {2} IT079_w {1} ES058_w {1} PT109_w {1} IT084_w {1} AT006_w {1} DE023_w {1} AT005_w {1} DE046_w {1} IT074_w {1} IT090_w {1} IT061_w {1} IT091_w {1} FR131_w {1} IT089_w {1} BE009_w {1} CZ017_w {1} PT115_w {1} SE118_w {1} IT067_w {1} IT070_w {1} FR135_w {1} IT092_w {1} PT113_w {1} FR136_w {1} IT088_w {1} DE041_w {1} AT001_w {1} IT078_w {1} DE039_w {1} IT063_w {1} DE022_w {1} IT071_w {1} DE049_w {1} PT102_w {1} PT105_w {1} PT110_w {2} PT099_w {1} PT114_w {1} SE119_w {1} IT059_w {1} PT104_w {1} PT111_w {1} IT097_w {1} DE030_w {1} DE026_w {1} DE031_w {1} PT108_w {1} FR134_w {1} AT002_w {1} DE051_w {1} IT065_w {1} AT003_w {1} DE047_w {1} IT094_w {1} DE024_w {1} DE029_w {1} UK127_w {1} IT072_w {1} IT071_w {2} IT064_w {1} IT068_w {1} DE045_w {1} SE120_w {1} UK124_w {1} DE025_w {1} IT082_w {1} BE007_w {1} BE013_w {1} BE011_w {1} BE008_w {1} DE042_w {1} BE014_w {1} DE034_w {1} IT059_w {2} PT098_w {1} DE032_w {1} IT074_w {2} DE044_w {1} IT073_w {1} IT076_w {1} IT069_w {1} IT082_w {2} IT079_w {1} ES058_w {1} PT109_w {1} IT084_w {1} AT006_w {1} DE023_w {1} AT005_w {1} DE046_w {1} IT074_w {1} IT090_w {1} IT061_w {1} IT091_w {1} FR131_w {1} IT089_w {1} BE009_w {1} CZ017_w {1} PT115_w {1} SE118_w {1} IT067_w {1} IT070_w {1} FR135_w {1} IT092_w {1} PT113_w {1} FR136_w {1} IT088_w {1} DE041_w {1} AT001_w {1} IT078_w {1} DE039_w {1} IT063_w {1} DE022_w {1} IT071_w {1} DE049_w {1} PT102_w {1} PT105_w {1} PT110_w {2} PT099_w {1} PT114_w {1} SE119_w {1} IT059_w {1} PT104_w {1} PT111_w {1} IT097_w {1} DE030_w {1} DE026_w {1} DE031_w {1} PT108_w {1} FR134_w {1} AT002_w {1} DE051_w {1} IT065_w {1} AT003_w {1} DE047_w {1} IT094_w {1} DE024_w {1} DE029_w {1} UK127_w {1} IT072_w {1} IT071_w {2} IT064_w {1} IT068_w {1} DE045_w {1} SE120_w {1} UK124_w {1} 1.0 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0.0 Point of discharge COPPER - Emissions to water (zoom 0-1 mg/l) COPPER - EMISSIONS TO WATER EP water name Type of discharge DIR = Direct DE025_w {1} DIR IT082_w {1} DIR BE007_w {1} DIR BE013_w {1} IND BE011_w {1} DIR BE008_w {1} IND DE042_w {1} IND BE014_w {1} DIR DE034_w {1} DIR IT059_w {2} IND Associated processes Washing synthetic fibre - Dyeing - Printing Dyeing - Singeing - Functional finishing - Thermal treatment - Wool Fulling Dyeing Mercerising Dyeing Units for concentration values mg/l mg/l mg/l mg/l mg/l Min. concentration over 3 years Average concentration over 3 years Max. concentration over 3 years Max. load over 3 ELV (mg/l ) years (g/day) 0 0 0 0 0.005 0.005 0 0 0.01 0.01 0.008 0.01 0.011 Combination of techniques Type of sampling 0.3 Equalisation, Neutralisation, Coagulation and flocculation, 24-hour flow proportional composite sample Sedimentation, Activated sludge process Equalisation, Neutralisation, Activated sludge process, 0.1 Nitrification/denitrification, Sedimentation, Adsorption (e.g. powdered/granular activated carbon, lignite coke, etc.), Other Equalisation, Neutralisation, Sand filtration, Activated sludge process, Nitrification/denitrification Distillation/rectification, Equalisation, Neutralisation Not applicable Flow proportional composite sample, Not applicable, Flow proportional composite sample Flow proportional composite sample Equalisation, Neutralisation, Coagulation and flocculation, 0.1 Activated sludge process, Nitrification/denitrification, Sand filtration, Nanofiltration, Chemical oxidation (incl. 24-hour flow proportional composite sample Advanced oxidation) Printing - Dyeing mg/l Washing synthetic fibre - Desizing - Bleaching - Dyeing - mg/l Functional finishing Bleaching - Dyeing - Functional finishing mg/l Washing synthetic fibre - Desizing - Bleaching - Dyeing mg/l Thermal treatment - Functional finishing mg/l 0.013 0.0049 0.01 0.005 0.00386 0.01 0.015 0.01 0.016 0.01 0.016 0.02 0.021 0.01 0.0226 0.05 Equalisation, Grit separators, Other 24-hour flow proportional composite sample 1 Neutralisation, Equalisation 0.2 Equalisation, Activated sludge process, Nitrification/denitrification 0.1 Activated sludge process, Nitrification/denitrification 1 No technique used 24-hour flow proportional composite sample 24-hour flow proportional composite sample Flow proportional composite sample Not applicable Monitoring frequency Monthly Yearly Monthly Yearly No information No information 4 times per year No information Yearly Twice per year PT098_w {1} DIR Wool Fulling - Functional finishing - Dyeing - Thermal mg/l treatment 0.0075 0.02 0.027 Equalisation, Neutralisation, Sedimentation, Sand filtration, Activated sludge process, Other No information Yearly DE032_w {1} DIR IT074_w {2} IND DE044_w {1} IND IT073_w {1} IND IT076_w {1} IND IT069_w {1} IND IT082_w {2} IND IT079_w {1} IND ES058_w {1} IND PT109_w {1} IND IT084_w {1} IND AT006_w {1} IND DE023_w {1} IND AT005_w {1} IND DE046_w {1} IND IT074_w {1} IND IT090_w {1} IND IT061_w {1} IND IT091_w {1} IND FR131_w {1} DIR IT089_w {1} IND BE009_w {1} DIR CZ017_w {1} IND PT115_w {1} IND SE118_w {1} IND IT067_w {1} DIR IT070_w {1} IND FR135_w {1} IND Washing synthetic fibre - Desizing - Bleaching - Dyeing - mg/l Printing Washing synthetic fibre - Scouring mg/l Desizing - Mercerising - Bleaching - Dyeing mg/l Dyeing - Functional finishing mg/l Raw wool scouring mg/l Scouring - Bleaching - Mercerising mg/l Dyeing - Singeing - Functional finishing - Thermal mg/l treatment - Wool Fulling Scouring - Wool Fulling - Functional finishing - Thermal mg/l treatment - Other Mercerising - Bleaching - Dyeing - Desizing - Fabric mg/l production - Printing - Thermal treatment No information mg/l Bleaching - Dyeing - Thermal treatment mg/l Bleaching - Dyeing mg/l Washing synthetic fibre - Mercerising - Bleaching - Dyeing mg/l No information mg/l Washing synthetic fibre - Dyeing mg/l Washing synthetic fibre - Scouring - Functional finishing - mg/l Dry cleaning - Other Scouring - Dyeing - Thermal treatment - Other - mg/l Bleaching Scouring - Wool Carbonising mg/l Scouring - Dyeing - Functional finishing - Thermal mg/l treatment - Other Washing synthetic fibre - Bleaching - Dyeing - Printing Functional finishing - Coating and laminating - Thermal mg/l treatment Scouring - Dyeing - Thermal treatment - Other - mg/l Bleaching Printing - Coating and laminating mg/l Spinning - Fabric production - Singeing - Functional finishing - Shrink-proof finishing - Thermal treatment - mg/l Other No information mg/l Washing synthetic fibre - Scouring - Scouring - Bleaching Dyeing - Singeing - Printing - Functional finishing - Shrink- mg/l proof finishing - Coating and laminating - Thermal treatment Dyeing - Printing - Other - Shrink-proof finishing mg/l No information mg/l Washing synthetic fibre mg/l 0.003 0.02 0.03 0.01 0.03 0.023 0.025 0.01 0.0444 0.001 0.019 0.01 0.01 0.01 0.028 0.016 0.021 0.03 0.012 0.016 0 0.01 0.02 0.032 0.005 0.03 0.009 0.01 0.028 0.03 0.029 0.03 0.03 0.02 0.03 0.03 0.03 0.03 0.031 0.03 0.038 0.02 0.04 0.04 0.04 0.0444 0.01 0.045 0.04 0.048 0.03 0.05 0.02 0.053 0.02 0.055 0.04 0.057 0.03 0.062 0.05 0.065 0.05 0.067 0.03 0.078 0.03 0.081 0.01 0.083 0.04 0.084 0.06 0.0872 0.05 0.0875 31.4125 0.04 0.09 0.07 0.09 0.05 0.098 20.384 Equalisation, Neutralisation, Grit separators, Coagulation and flocculation, Sedimentation, Sand filtration, 24-hour flow proportional composite sample Nitrification/denitrification, Activated sludge process 1 Other No information 1 No technique used Equalisation, Flotation, Coagulation and flocculation, 0.1 Activated sludge process, Nitrification/denitrification, Sedimentation, Membrane bioreactor Other 24-hour flow proportional composite sample Other Not applicable 1 Other Other No information No information 1 Other 24-hour flow proportional composite sample No information 1 Oil separation, Neutralisation 0.1 Equalisation, Neutralisation, Grit separators, Screening, Coagulation and flocculation, Sedimentation 0.5 Flotation 1 No information 0.5 Neutralisation 1 No information 1 Other No information No information No information No information No information No information No information Other 1 Other 24-hour flow proportional composite sample Twice per year No information Twice per year Twice per year Other Twice per year Other Twice per year Yearly Yearly 4 times per year Yearly No information Monthly No information No information Twice per year 1 Other 1 No information Other Other Other 24-hour flow proportional composite sample Twice per year No information Monthly 1 Other 24-hour flow proportional composite sample Screening, Sedimentation, Equalisation, Activated sludge process, Sand filtration, Coagulation and flocculation, 0.05 Flotation, Chemical oxidation (incl. Advanced oxidation), Sand filtration, Chemical reduction, Microfiltration, Reverse osmosis Other, 24-hour flow proportional composite sample, Other No information No information 1 Equalisation, Neutralisation, Screening 24-hour flow proportional composite sample Twice per year No information Yearly Yearly 0.4 Sedimentation, Neutralisation 24-hour flow proportional composite sample 0.1 Equalisation, Neutralisation, Activated sludge process, Nitrification/denitrification, Sedimentation 0.4 No information Grit separators Not applicable Not applicable 24-hour flow proportional composite sample Monthly Other Twice per year Monthly 15 Monitoring standard DIN EN ISO 11885 (E22) Additional information IRSA 3010 + 3020* WAC/III/B011 of WAC/III/B010- WAC/III/B002 MEIN043TAX, MEIN043TAX, MEIN062TAX sample 23.10.2015, <0,005 mg/l - 0,008 mg/l - WAC/III/B011 of WAC/III/B010- WAC/III/B002 5 measurements < DL (0,015 mg/l) WAC/III/B011 of WAC/III/B010- WAC/III/B002 No information Self Control and taxation waste water - Self Control and taxation waste water - Self Control and taxation waste water WAC/III/B011 of WAC/III/B010- WAC/III/B002 4 mesurements < DL (0,025 mg/l) - 3 measurements < DL 0,025 mg/l - 3 measuremenst < DL (0,025 mg/l) No information EPA 6020 B 2014 MESU. 1 - 0,012 mg/l ; There is only VLE for total metals ( As, Cd, Pb, Cu, Cr, Zn, Hg and Ni) - VLE 5mg/l - MESU. 1 - DIN EN ISO 11885 (E22), DIN EN ISO 17294-2(E29), DIN EN 0,027 mg/l ; There is only VLE for total metals ( As, Cd, Pb, ISO 11885 (E22) Cu, Cr, Zn, Hg and Ni) - VLE 5mg/l - MESU. 1 - 0,0075 mg/l ; There is only VLE for total metals ( As, Cd, Pb, Cu, Cr, Zn, Hg and Ni) - VLE 5mg/l No information UNI EN ISO 11885:2009 No information UNI EN ISO 11885:2009 APAT CNR IRSA 3020 Man 29 2003 UNI EN ISO 11885:2009 APAT IRSA -CNR 3010/A + 3020Man 29 2003 UNI EN ISO 11885:2009 No information No information EPA 6020 B 2014 EN ISO 11885 No information DIN EN ISO 11885DIN EN ISO 11885 No information UNI EN ISO 11885:2009 UNI EN ISO 11885:2009 UNI EN ISO 11885:2009 UNI EN ISO 11885:2009 NF EN ISO 11885 UNI EN ISO 11885:2009 WAC/III/BWAC/III/B AVERAGE PERIOD 3 HOURS - AVERAGE PERIOD 3 HOURS AVERAGE PERIOD 3 HOURS (YEAR 2015) Monitoring frequency: spotValue refered to sampling period Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours (data referring to the year 2015) ELV is referred to 3 hours sampled waste water - ELV is referred to 3 hours sampled waste water - ELV is referred to 3 hours sampled waste water. Data related to 2015. 3 h medium composite sample - 3 h medium composite sample - 3 h medium composite sample - qualified sample AVERAGE PERIOD 3 HOURS - AVERAGE PERIOD 3 HOURS AVERAGE PERIOD 3 HOURS (YEAR 2015) ELV is referred to 3 hours sampled waste water - ELV is referred to 3 hours sampled waste water - ELV is referred to 3 hours sampled waste water. Data related to 2015. AVERAGE PERIOD 3 HOURS - AVERAGE PERIOD 3 HOURS Averaging period for ELV: 3 hours; YEAR 2015 AVERAGE PERIOD 3 HOURS - AVERAGE PERIOD 3 HOURS AVERAGE PERIOD 3 HOURS ELV is referred to 3 hours sampled waste water - ELV is referred to 3 hours sampled waste water - ELV is referred to 3 hours sampled waste water. Data related to 2015. Less than 12/year flow proportionate sampling, >12/year are grab sample results. Value 0 means results beneath detection limit of analyses No information SMEWW 3030 K/SMEWW 3111 B, SMEWW 3030 K/SMEWW 3111 B, W- METAXDG1 No information APAT CNR IRSA 3020 Man 29 2003 EPA 6010 C 2007 No information < LQ; LD= 0,02SIDVA - < LQ; LD= 0,07SIDVA - SIDVA Three months average Monitoring frequency: spotValue refered to sampling period 1 COPPER - EMISSIONS TO WATER EP water name Type of discharge DIR = Direct IT092_w {1} DIR PT113_w {1} IND FR136_w {1} IND IT088_w {1} IND DE041_w {1} IND AT001_w {1} IND IT078_w {1} IND DE039_w {1} IND IT063_w {1} IND DE022_w {1} IND IT071_w {1} IND DE049_w {1} IND IT077_w {1} IND PT102_w {1} IND Associated processes Units for concentration values Dyeing - Other mg/l Dyeing - Washing synthetic fibre - Bleaching - Functional mg/l finishing Desizing - Scouring - Bleaching - Mercerising - Dyeing - mg/l Singeing - Fabric production - Functional finishing Dyeing - Bleaching mg/l Desizing - Bleaching - Dyeing mg/l No information mg/l Min. concentration over 3 years Average concentration over 3 years Max. concentration over 3 years Max. load over 3 ELV (mg/l ) years (g/day) 0.01 0.03 0.1 0.1 0.10 0.1 Combination of techniques Equalisation, Neutralisation, Activated sludge process, 0.1 Nitrification/denitrification, Sedimentation, Reverse osmosis 1 No information 0.043 0.03 0.02 0.021 0.07 0.108 0.08 0.12 0.05 0.15 0.09 0.15 15 Grit separators, Neutralisation 1 No information No information 0.5 No information Wool Fulling - Washing synthetic fibre - Dyeing mg/l Mercerising - Dyeing - Washing synthetic fibre - mg/l Bleaching - Desizing Dyeing - Fabric production - Dry cleaning - Printing - mg/l Printing - Functional finishing Raw wool scouring - Washing synthetic fibre - Desizing - Scouring - Bleaching - Dyeing - Thermal treatment - mg/l Functional finishing - Coating and laminating 0.003 0.108 0.01 0.01 0.03 0.152 0.13 0.153 0.04 0.16 0.04 0.17 1 Other Equalisation, Neutralisation 0.4 Equalisation 1 Neutralisation, Oil separation, Evaporation Dyeing - Bleaching - Scouring Desizing - Bleaching - Bleaching - Dyeing - Singeing Printing - Coating and laminating - Scouring - Functional finishing Desizing - Mercerising - Scouring - Bleaching - Singeing Thermal treatment mg/l mg/l No unit reported 0.024 0.02 0 0.06 0.179 0.05 0.18 0.06 0.19 1 No information 0.5 Equalisation, Neutralisation 1 No information Type of sampling Not applicable Other No information Not applicable No information 24-hour flow proportional composite sample Other Flow proportional composite sample Other Other Other 24-hour flow proportional composite sample Other Scouring - Dyeing - Bleaching mg/l 0.0335 0.17 0.2 1 Other 24-hour flow proportional composite sample PT105_w {1} IND PT110_w {2} IND PT099_w {1} IND PT114_w {1} IND SE119_w {1} IND IT059_w {1} IND PT104_w {1} IND PT111_w {1} DIR Dyeing - Bleaching mg/l Dyeing mg/l Dyeing - Printing - Functional finishing mg/l Mercerising - Dyeing - Washing synthetic fibre - Desizing - mg/l Scouring - Bleaching - - Thermal treatment - Dry cleaning Washing synthetic fibre - Desizing - Functional finishing - mg/l Dyeing Scouring - Mercerising - Bleaching - Dyeing - Singeing - mg/l Dry cleaning Dyeing - Bleaching mg/l Desizing - Dyeing - Fabric production - Wool Fulling - Functional finishing - Shrink-proof finishing - Dry cleaning -mg/l Thermal treatment 0.2 0.1 0.03 0.2 0.094 0.0115 0.109 0.0085 0.20 0.2 0.18 0.2 0.16 0.2 0.20 0.2 0.13 0.224 32.256 0.07 0.24 0.20 0.25 0.17 0.25 No information No information 1 Equalisation, Grit separators, Screening 1 Screening, Oil separation, Other Equalisation, Neutralisation, Screening, Coagulation and 1 flocculation, Sedimentation, Sand filtration, Adsorption (e.g. powdered/granular activated carbon, lignite coke, etc.) No information No information No information No technique used 24-hour flow proportional composite sample 1 Other No information 1 Equalisation, Neutralisation, Activated sludge process, Sedimentation, Sand filtration, Other Not applicable 24-hour flow proportional composite sample No information IT097_w {1} DIR Dyeing - Shrink-proof finishing - Printing - Other mg/l 0.005 0.04 0.25 0.1 Equalisation, Neutralisation, Activated sludge process, Nitrification/denitrification, Sedimentation Not applicable DE030_w {1} IND DE026_w {1} IND DE031_w {1} IND PT108_w {1} IND FR134_w {1} DIR AT002_w {1} IND DE051_w {1} IND IT065_w {1} IND AT003_w {1} IND DE047_w {1} IND IT094_w {1} IND DE024_w {1} IND IT077_w {2} IND DE029_w {1} IND UK127_w {1} IND IT072_w {1} IND IT071_w {2} IND IT064_w {1} IND IT068_w {1} IND DE045_w {1} IND SE120_w {1} IND Washing synthetic fibre - Desizing - Mercerising - Bleaching - Singeing - Dyeing - Functional finishing - mg/l Thermal treatment Washing synthetic fibre - Desizing - Dyeing - Bleaching mg/l Dyeing mg/l Fabric production - Fabric production mg/l Washing synthetic fibre - Desizing - Mercerising - mg/l Bleaching - Dyeing - Singeing - Functional finishing No information mg/l Washing synthetic fibre - Scouring - Bleaching - Dyeing - mg/l Functional finishing No information mg/l Mercerising - Dyeing - Desizing - Bleaching mg/l Desizing - Mercerising - Bleaching - Dyeing - Functional mg/l finishing No information mg/l Desizing - Dyeing - Scouring - Singeing Dyeing Dyeing mg/l No unit reported mg/l Mercerising - Bleaching - Dyeing - Scouring - Singeing - mg/l Printing Thermal treatment - Scouring - Bleaching - Dyeing - mg/l Other Dyeing - Other - Functional finishing mg/l Scouring mg/l Washing synthetic fibre - Desizing - Scouring - Bleaching - mg/l Dyeing - Functional finishing - Other Washing synthetic fibre - Desizing - Desizing mg/l Washing synthetic fibre - Desizing - Bleaching mg/l 0.066 0.029 0.005 0.22 0.047 0.055 0.01 0.042 0.12 0.015 0.001 0.03 0.01 0.05 0.0462 0.007 0.028 0.4 0.171 0.22 0.11 0.29 0.10 0.3 0.10 0.316 0.26 0.32 0.12 0.32 148.8 0.15 0.37 0.09 0.39 0.22 0.41 0.27 0.43 0.12 0.453 0.13 0.458 0.22 0.5 0.18 0.5 0.10 0.52 0.16 0.52 1034.1032 0.13 0.563 0.29 0.79 0.62 0.838 0.47 0.898 0.98 0.65 1.5 663 1 Equalisation, Neutralisation, Screening 24-hour flow proportional composite sample 0.5 No information No information Other No information 1 Neutralisation, Sand filtration, Sand filtration 24-hour flow proportional composite sample 0.15 Equalisation, Neutralisation, Grit separators, Activated sludge process, Anaerobic treatment 0.5 No information No information No information 1 Neutralisation, Coagulation and flocculation, Equalisation No information Other 0.5 Other 0.5 Neutralisation No information Other 24-hour flow proportional composite sample Other 1 Equalisation 1 No information 1 No information No information Grab/spot sample Other Flow proportional composite sample 10 Neutralisation 24-hour flow proportional composite sample 1 Other 1 Other 1 Other 1 Other No information 0.5 Neutralisation, Oil separation, Equalisation Other Other Other Other 24-hour flow proportional composite sample 24-hour flow proportional composite sample Monitoring frequency Monthly Yearly No information Twice per year Monthly 4 times per year Twice per year Twice per year 4 times per year Monthly Twice per year 4 times per year Twice per year Twice per year Yearly Twice per year 4 times per year Yearly No information Twice per year Yearly Yearly Twice per year 4 times per year No information Other Yearly 4 times per year Yearly Monthly Twice per year 4 times per year 4 times per year Twice per year 4 times per year Twice per year 4 times per year Weekly Twice per year Twice per year Twice per year Twice per year Twice per year Continuous 16 Monitoring standard Additional information IRSA 3010 + 3030, EPA 3005A 1992 + EPA 6010D 2014, EPA 3005A 1992 + EPA 6010D 2014 No information No information EPA 6010 C 2007 No information DIN EN ISO 11885DIN EN ISO 11885 UNI EN ISO 11885:2009 No information Value refered to sampling period - Value refered to sampling period - Value refered to sampling period detection limit: 0,1 mg/L - detection limit: 0,1 mg/L detection limit: 0,1 mg/L Yearly - Yearly - Yearly 5; one additional control measurement local authority Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours No information DIN UNI EN ISO 11885:2009 DIN UNI EN ISO 11885:2009 IT-DLQ-42/V03;SMEWW3111 B, 21ed No information No information DIN EN ISO 11885/ICP-OES No information Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours In these monitoring the value is below level of quantification - For the second monitoring the value is below level of quantification - In these monitoring the value is below level of quantification The installation only started operating in 2017.The value of uncertainty is not refered in the reports. No information EPA 6020 B 2014 compound sampling W-METAXDG1 APAT CNR IRSA 3020 Man 29 2003, UNI EN ISO 155871:2002+UNI EN ISO 11885:2009, UNI EN ISO 11885:2009 Value refered to sampling periodMeasurement 1 is inferior to detection limit: <0,005 - Value refered to sampling periodMeasurements 1,3 are inferior to detection limit: <0,01 - Measurement 1 is inferior to detection limit: <0,01Measurement 4 is inferior to detection limit: <0,25Value refered to sampling period DIN DIN DIN EN ISO 11885DIN EN ISO 11885 3 times/year - 3 times/year - 3 times/year SMEWW3030 K/SMEWW 3111 B (22 ed), SMEWW3030 annual measurement - annual measurement - annual K/SMEWW 3111 B (22 ed), PT 15 Ed. 12 (2O17-01-12) measurement NF EN ISO 11885 DIN EN ISO 11885DIN EN ISO 11885 No information RSDE regulation - RSDE regulation - RSDE regulation ARPAT CNR IRSA 3010 Man 29 2003 DIN EN ISO 11885DIN EN ISO 11885 No information Requested by Italian Law - Requested by Italian Law Requested by Italian Law,and other analyses introduced during 2018 to follow the ZDHC Waste Water Guide lines APAT CNR IRSA 3020 Volume 1:2003 No information UNI EN ISO 11885:2009 No information No information UNI EN ISO 11885:2009 UNI EN ISO 11885:2009 UNI EN ISO 11885:2009 UNI EN ISO 11885:2009 No information No information - Concentration of mesurement 1 under the detection limit of 0,001 mg/l - In the second determination, the concentration was under the detection limit of 0,001mg/l Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours Toxic metals in excess of 10000ug/l either individually or in total - Toxic metals in excess of 10000ug/l either individually or in total - Toxic metals in excess of 10000ug/l either individually or in total Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours (data referring to the year 2015) Quartely 2 EP water name Type of discharge DIR = Direct UK124_w {1} DIR Associated processes No information UK126_w {1} IND Dyeing COPPER - EMISSIONS TO WATER Units for concentration values mg/l other (please specify in the column "additional information") Min. concentration over 3 years Average concentration over 3 years Max. concentration over 3 years Max. load over 3 ELV (mg/l ) years (g/day) 1 17.35 28.8 10.6 98.30 1740 Combination of techniques Type of sampling Neutralisation, Coagulation and flocculation, Flotation, Other Other No information Flow proportional composite sample Monitoring frequency Twice per year No information Monitoring standard ICPMS Routine- acid digested; determined by ICPMS No information Additional information The unit measurement is in microgrammes/litre - The unit measurement is in microgrammes/litre - The unit measurement is in microgrammes/litre 17 3 18 Other Anaerobic treatment Membrane bioreactor Distillation/rectification Reverse osmosis Chemical reduction Chemical oxidation Flotation Nanofiltration Microfiltration Ultrafiltration Evaporation Adsorption Activated sludge process Nitrification/denitrification Sand filtration Sedimentation Coagulation and flocculation Screening Grit separators Oil separation Neutralisation Equalisation No technique used IT082_w {1} BE011_w {1} CZ019_w {1} IT097_w {1} UK124_w {4} IT096_w {1} BE009_w {1} FR132_w {1} FR132_w {2} BE007_w {1} BE010_w {1} CZ020_w {1} PT110_w {1} PT111_w {1} UK124_w {1} IT092_w {1} PT098_w {1} DE025_w {1} IT067_w {1} UK124_w {2} BE014_w {1} FR131_w {1} FR134_w {1} Techniques applied Max. load over 3 years (g/day) Per DIR Type of discharge Type of monitoring Mass load expressed in g/day Concentration expressed in mg/l 600 500 400 300 200 100 50,000 45,000 40,000 35,000 30,000 25,000 20,000 15,000 10,000 5,000 0 DIR Per IT082_w {1} BE011_w {1} CZ019_w {1} IT097_w {1} UK124_w {4} IT096_w {1} BE009_w {1} FR132_w {1} FR132_w {2} BE007_w {1} BE010_w {1} CZ020_w {1} PT110_w {1} PT111_w {1} UK124_w {1} IT092_w {1} PT098_w {1} DE025_w {1} IT067_w {1} UK124_w {2} BE014_w {1} FR131_w {1} FR134_w {1} Freq Per Per Per Per Per Per Freq Per Per Per Per Freq Per Per Per Per Per Per Freq Per DIR DIR DIR DIR DIR DIR DIR DIR DIR DIR DIR DIR DIR DIR DIR DIR DIR DIR DIR DIR DIR IT082_w {1} BE011_w {1} CZ019_w {1} IT097_w {1} UK124_w {4} IT096_w {1} BE009_w {1} FR132_w {1} FR132_w {2} BE007_w {1} BE010_w {1} CZ020_w {1} PT110_w {1} PT111_w {1} UK124_w {1} IT092_w {1} PT098_w {1} DE025_w {1} IT067_w {1} UK124_w {2} BE014_w {1} FR131_w {1} FR134_w {1} 0 Point of discharge ELV (mg/l ) over 3 years Average concentration 700 TSS - Emissions to water 19 Other Anaerobic treatment Membrane bioreactor Distillation/rectification Reverse osmosis Chemical reduction Chemical oxidation Flotation Nanofiltration Microfiltration Ultrafiltration Evaporation Adsorption Activated sludge process Nitrification/denitrification Sand filtration Sedimentation Coagulation and flocculation Screening Grit separators Oil separation Neutralisation Equalisation No technique used IT082_w {1} BE011_w {1} CZ019_w {1} IT097_w {1} UK124_w {4} IT096_w {1} BE009_w {1} FR132_w {1} FR132_w {2} BE007_w {1} BE010_w {1} CZ020_w {1} PT110_w {1} PT111_w {1} UK124_w {1} IT092_w {1} PT098_w {1} DE025_w {1} IT067_w {1} UK124_w {2} BE014_w {1} FR131_w {1} FR134_w {1} Techniques applied Max. load over 3 years (g/day) Per DIR Type of discharge Type of monitoring Mass load expressed in g/day Concentration expressed in mg/l 50,000 45,000 40,000 35,000 30,000 25,000 20,000 15,000 10,000 5,000 0 DIR Per IT082_w {1} BE011_w {1} CZ019_w {1} IT097_w {1} UK124_w {4} IT096_w {1} BE009_w {1} FR132_w {1} FR132_w {2} BE007_w {1} BE010_w {1} CZ020_w {1} PT110_w {1} PT111_w {1} UK124_w {1} IT092_w {1} PT098_w {1} DE025_w {1} IT067_w {1} UK124_w {2} BE014_w {1} FR131_w {1} FR134_w {1} Freq Per Per Per Per Per Per Freq Per Per Per Per Freq Per Per Per Per Per Per Freq Per DIR DIR DIR DIR DIR DIR DIR DIR DIR DIR DIR DIR DIR DIR DIR DIR DIR DIR DIR DIR DIR IT082_w {1} BE011_w {1} CZ019_w {1} IT097_w {1} UK124_w {4} IT096_w {1} BE009_w {1} FR132_w {1} FR132_w {2} BE007_w {1} BE010_w {1} CZ020_w {1} PT110_w {1} PT111_w {1} UK124_w {1} IT092_w {1} PT098_w {1} DE025_w {1} IT067_w {1} UK124_w {2} BE014_w {1} FR131_w {1} FR134_w {1} 100 90 80 70 60 50 40 30 20 10 0 Point of discharge Average concentration over 3 years ELV (mg/l ) TSS - Emissions to water (zoom 0-100 mg/l) TSS - EMISSIONS TO WATER EP water name Type of discharge DIR = Direct IT082_w {1} DIR DE039_w {1} IND IT079_w {1} IND BE011_w {1} DIR PT102_w {1} IND PT104_w {1} IND PT105_w {1} IND PT108_w {1} IND PT109_w {1} IND CZ019_w {1} DIR PT110_w {2} IND IT097_w {1} DIR PT113_w {1} IND PT114_w {1} IND PT115_w {1} IND UK124_w {4} DIR CZ015_w {1} IND CZ016_w {1} IND CZ017_w {1} IND IT096_w {1} DIR BE009_w {1} DIR FR132_w {1} DIR BE008_w {1} IND FR132_w {2} DIR BE007_w {1} DIR BE010_w {1} DIR PT117_w {1} IND PT099_w {1} IND AT006_w {1} IND AT002_w {1} IND AT004_w {1} IND BE013_w {1} IND CZ020_w {1} DIR SE120_w {1} IND SE118_w {1} IND UK127_w {1} IND Associated processes Dyeing - Singeing - Functional finishing - Thermal treatment - Wool Fulling Mercerising - Dyeing - Washing synthetic fibre Bleaching - Desizing Scouring - Wool Fulling - Functional finishing - Thermal treatment - Other Units for concentration values mg/l mg/l mg/l Min. concentration over 3 years Average concentration over 3 years Max. concentration over 3 years Max. load over 3 ELV (mg/l ) years (g/day) 0 0.33 1 20 20.00 20 Combination of techniques Equalisation, Neutralisation, Activated sludge process, 80 Nitrification/denitrification, Sedimentation, Adsorption (e.g. powdered/granular activated carbon, lignite coke, etc.), Other Equalisation, Neutralisation Type of sampling Not applicable Flow proportional composite sample 133 210.77 283 1200 Other 24-hour flow proportional composite sample Dyeing mg/l Scouring - Dyeing - Bleaching mg/l Dyeing - Bleaching mg/l Dyeing - Bleaching mg/l Fabric production - Fabric production mg/l No information mg/l Bleaching - Dyeing - Printing - Functional finishing - mg/l Desizing Dyeing mg/l Dyeing - Shrink-proof finishing - Printing - Other mg/l Dyeing - Washing synthetic fibre - Bleaching - Functional mg/l finishing Mercerising - Dyeing - Washing synthetic fibre - Desizing Scouring - Bleaching - - Thermal treatment - Dry cleaning mg/l No information mg/l No information mg/l Dyeing - Functional finishing mg/l Shrink-proof finishing mg/l Spinning - Fabric production - Singeing - Functional finishing - Shrink-proof finishing - Thermal treatment - mg/l Other Dyeing - Other mg/l Printing - Coating and laminating mg/l No information mg/l Printing - Dyeing mg/l Bleaching - Dyeing mg/l Dyeing mg/l Bleaching - Dyeing - Bleaching - Scouring - Functional mg/l finishing Dyeing - Dyeing - Bleaching - Functional finishing mg/l Dyeing - Printing - Functional finishing mg/l Bleaching - Dyeing mg/l No information mg/l Washing synthetic fibre mg/l Mercerising mg/l Dyeing mg/l Washing synthetic fibre - Desizing - Bleaching mg/l Washing synthetic fibre - Scouring - Scouring - Bleaching - Dyeing - Singeing - Printing - Functional finishing - Shrink- mg/l proof finishing - Coating and laminating - Thermal treatment Mercerising - Bleaching - Dyeing - Scouring - Singeing - mg/l Printing 2 23 21 30 11 78 10 5 19 0.014 18 3 80 490 19 10 3.90 261.42 71.50 50.80 175.69 139.50 7.50 99.58 8.00 62.72 0.08 39.58 5.99 179.83 16513.06 48.31 12.67 5.9 9.85 2 5.07 118 291.67 2 11.29 22.22 10 14.27 34 90.47 19 63.33 157 224.00 100 315.48 220 331.83 23.3 47.67 2 7.00 12 33.90 130 296.00 70 382.00 6 2500 220 106 390 220 213 11 106 0.21 74 14.2 487 54000 118 15 17 20 570 20 27 169 107 310 880 550 63.3 28 89 900 1810 49128 323100 3599474.6 Equalisation, Neutralisation, Coagulation and flocculation, Activated sludge process, Nitrification/denitrification, 60 Sand filtration, Nanofiltration, Chemical oxidation (incl. 24-hour flow proportional composite sample Advanced oxidation) 1000 Other No information 24-hour flow proportional composite sample 24-hour flow proportional composite sample No information No information 1000 Neutralisation, Sand filtration, Sand filtration 1000 Oil separation, Neutralisation 30 Equalisation, Neutralisation, Anaerobic treatment, Nitrification/denitrification, Activated sludge process 1000 Equalisation, Grit separators, Screening 80 Equalisation, Neutralisation, Activated sludge process, Nitrification/denitrification, Sedimentation 24-hour flow proportional composite sample No information No information No information Not applicable 1000 No information Other Equalisation, Neutralisation, Screening, Coagulation and 1 flocculation, Sedimentation, Sand filtration, Adsorption (e.g. powdered/granular activated carbon, lignite coke, etc.) 1000 Equalisation, Neutralisation, Screening No information 24-hour flow proportional composite sample 60 No information No information Grit separators, Equalisation, Sedimentation No information Flow proportional composite sample Flow proportional composite sample 500 No information No information 200 Equalisation, Neutralisation, Activated sludge process, Nitrification/denitrification, Sedimentation, Other No information Screening, Sedimentation, Equalisation, Activated sludge process, Sand filtration, Coagulation and flocculation, 60 Flotation, Chemical oxidation (incl. Advanced oxidation), Sand filtration, Chemical reduction, Microfiltration, Reverse osmosis 70 No information Other, 24-hour flow proportional composite sample, Other Grab/spot sample 1000 Equalisation, Grit separators, Other 24-hour flow proportional composite sample 600 Other Equalisation, Neutralisation, Sand filtration, Activated sludge process, Nitrification/denitrification 60 EqualisationActivated sludge process, Nitrification/denitrification, Other 1000 Neutralisation 1000 Screening, Oil separation, Other 500 Flotation 500 No information No information 1000 Distillation/rectification, Equalisation, Neutralisation Sedimentation, Nitrification/denitrification, 20 Neutralisation, Coagulation and flocculation, Activated sludge process 50 Neutralisation, Oil separation, Equalisation Grab/spot sample Flow proportional composite sample, Not applicable, Flow proportional composite sample 24-hour flow proportional composite sample 24-hour flow proportional composite sample No information No information No information No information Flow proportional composite sample No information 24-hour flow proportional composite sample Sedimentation, Neutralisation 24-hour flow proportional composite sample Neutralisation 24-hour flow proportional composite sample Monitoring frequency Yearly Twice per year Twice per year No information 4 times per year 4 times per year 4 times per year Monthly 4 times per year Monthly 4 times per year Other 4 times per year 4 times per year 4 times per year Yearly 4 times per year Monthly Monthly Yearly No information No information No information No information Monthly Yearly Monthly 4 times per year Daily Monthly Twice per year Yearly Monthly Continuous Weekly Weekly UK128_w {1} IND Raw wool scouring mg/l 1 1200.00 8370 2368710 10000 Coagulation and flocculation 24-hour flow proportional composite sample No information UK129_w {1} IND PT110_w {1} DIR PT111_w {1} DIR UK124_w {1} DIR Raw wool scouring mg/l Dyeing mg/l Desizing - Dyeing - Fabric production - Wool Fulling Functional finishing - Shrink-proof finishing - Dry cleaning -mg/l Thermal treatment No information mg/l 20 62 348.00 1 10.15 5 12.67 3 8.20 1700 29 29 37.3 596700 45729.8 Grit separators, Screening, Oil separation, Coagulation and flocculation, Ultrafiltration, Flotation 24-hour flow proportional composite sample Equalisation, Grit separators, Screening, Coagulation and 35 flocculation, Sedimentation, Activated sludge process, No information Other 60 Equalisation, Neutralisation, Activated sludge process, Sedimentation, Sand filtration, Other No information 35 Neutralisation, Coagulation and flocculation, Flotation, Other Other Monthly Monthly 4 times per year Weekly Monitoring standard Additional information IRSA 2090-B:2003 No information APAT CNR IRSA 2090 B MAN 29 2003 ELV is referred to 3 hours sampled waste water - ELV is referred to 3 hours sampled waste water - ELV is referred to 3 hours sampled waste water. Data related to 2015. WAC/III/D/002 SMEWW 2540 D, 21ed compound sampling No information Filtration and Gravimetric No information No information No information APAT CNR IRSA 2090B Man 29 2003 Gravimetry 2 measurements < DL (2 mg/l) - 1 measurements < DL (2 mg/l) - 2 measurements < DL (2 mg/l) The installation only started operating in 2017.The value of uncertainty is not refered in the reports. monthly - monthly - monthly Monitoring frequency: spot No information SMEWW 2540 D Suspended Solids - filtered; determined by gravimetry No information No information No information SIDVA - SIDVA - SIDVA APAT CNR IRSA 2090 B Man 29 2003, APAT CNR IRSA Value refered to sampling period - Value refered to 2090 B Man 29 2003, APAT CNR IRSA 2090 B Man 29 2003 sampling period - Value refered to sampling period WAC/III/D/002 No information WAC/III/D/002 No information WAC/III/D/002 WAC/III/D/002 ISO Standard Methods 2540, 23rd Ed./Gavimetria NORM M 6274:1985 DIN 38409 H2 NORM M 6274:1985 (MH) MEIN042 specified in extern laboratory No information Less than 12/year flow proportionate sampling, >12/year are grab sample results. Value 0 means results beneath detection limit of analyses Self Control and taxation waste water - Self Control and taxation waste water - Self Control and taxation waste water self-monitoring daily - self-monitoring daily - selfmonitoring daily sample 22.10.2015-23.10.2015 Quarterly No information No information No information No information No information SMEWW 2540 D Filtered; determined by gravimetry Results taken from Local sewerage undertakers routine testing as part of compliance permit -results are settled COD - % average removal efficiency for COD & TSS is calculated using an average input to effluent plant of 80000ppm COD and 30000ppm TSS. Remov - Results taken from Local sewerage undertakers routine testing as part of compliance permit -results are settled COD - % average removal efficiency for COD & TSS is calculated using an average input to effluent plant of 80000ppm COD and 30000ppm TSS. Remov - Results taken from Local sewerage undertakers routine testing as part of compliance permit -results are settled COD - % average removal efficiency for COD & TSS is calculated using an average input to effluent plant of 80000ppm COD and 30000ppm TSS. Remov Suspended solids are monitored by local water company for sewage charging purposes but no limits or compliance requirements set 35 in the normal period and 30 in the dry season - 35 in the normal period and 30 in the dry season - 35 in the normal period and 30 in the dry season 1 EP water name Type of discharge DIR = Direct Associated processes UK126_w {1} IND Dyeing TSS - EMISSIONS TO WATER Units for concentration values Min. concentration over 3 years Average concentration over 3 years Max. concentration over 3 years Max. load over 3 ELV (mg/l ) years (g/day) Combination of techniques Type of sampling mg/l 32 131.21 688 55494.08 No information Flow proportional composite sample FR135_w {1} IND IT059_w {1} IND IT059_w {2} IND IT092_w {1} DIR PT098_w {1} DIR DE025_w {1} DIR IT061_w {1} IND IT063_w {1} IND IT064_w {1} IND IT065_w {1} IND IT067_w {1} DIR IT068_w {1} IND IT069_w {1} IND IT070_w {1} IND IT071_w {1} IND IT071_w {2} IND IT072_w {1} IND IT073_w {1} IND IT074_w {1} IND IT074_w {2} IND IT075_w {1} IND IT076_w {1} IND Washing synthetic fibre No unit reported Scouring - Mercerising - Bleaching - Dyeing - Singeing - mg/l Dry cleaning Thermal treatment - Functional finishing mg/l Dyeing - Other mg/l Wool Fulling - Functional finishing - Dyeing - Thermal mg/l treatment Washing synthetic fibre - Dyeing - Printing mg/l Scouring - Wool Carbonising mg/l Dyeing - Fabric production - Dry cleaning - Printing - mg/l Printing - Functional finishing Scouring mg/l No information mg/l Dyeing - Printing - Other - Shrink-proof finishing mg/l Washing synthetic fibre - Desizing - Scouring - Bleaching - mg/l Dyeing - Functional finishing - Other Scouring - Bleaching - Mercerising mg/l No information mg/l Dyeing - Bleaching - Scouring mg/l Dyeing - Other - Functional finishing mg/l Thermal treatment - Scouring - Bleaching - Dyeing - mg/l Other Dyeing - Functional finishing mg/l Washing synthetic fibre - Scouring - Functional finishing - mg/l Dry cleaning - Other Washing synthetic fibre - Scouring mg/l Raw wool scouring mg/l 32.5 39.26 7 46.17 11 150.67 2 10.05 10 25.83 0 5.85 73.2 311.85 36 96.91 50.7 75.32 32.8 116.63 5 18.00 57.2 135.37 65.9 484.17 7 81.50 30.9 65.48 23 75.62 28.5 65.73 83.5 110.50 35.4 112.87 114 197.78 5 24.81 55 118 640 39.2 42 45 844 157 122 196 60 335 969.3 225 82.3 113 102 147 230 288 87.5 Raw wool scouring mg/l 14.86 19.49 87 120 Grit separators 1200 Other 24-hour flow proportional composite sample Not applicable 1200 No technique used Equalisation, Neutralisation, Activated sludge process, 80 Nitrification/denitrification, Sedimentation, Reverse osmosis Not applicable Not applicable 60 Equalisation, Neutralisation, Sedimentation, Sand filtration, Activated sludge process, Other No information 35 Equalisation, Neutralisation, Coagulation and flocculation, 24-hour flow proportional composite sample Sedimentation, Activated sludge process 1200 Other Other 400 Equalisation Other 1200 Other Other Other No information 80 Equalisation, Neutralisation, Activated sludge process, Nitrification/denitrification, Sedimentation Not applicable 1200 Other Other 1200 Other 1200 No information 1200 No information 1200 Other 1200 Other 1200 No technique used 1200 Other 1200 Other Other Not applicable Other Other Other Other Other Other Equalisation, Coagulation and flocculation, Activated 200 sludge process, Nitrification/denitrification, Sedimentation Not applicable Equalisation, Flotation, Coagulation and flocculation, 200 Activated sludge process, Nitrification/denitrification, Sedimentation, Membrane bioreactor Not applicable IT077_w {1} IND Desizing - Mercerising - Scouring - Bleaching - Singeing - No unit reported Thermal treatment 61 97.67 177 1200 No information Other Monitoring frequency No information Weekly Twice per year Twice per year Monthly Twice per year Monthly Twice per year 4 times per year Twice per year Twice per year Monthly Twice per year Twice per year Twice per year Twice per year Twice per year Twice per year Twice per year No information No information Other Weekly Twice per year IT077_w {2} IND Dyeing No unit reported 12.2 37.60 55 IT078_w {1} IND ES058_w {1} IND AT001_w {1} IND UK124_w {2} DIR BE014_w {1} DIR IT082_w {2} IND IT083_w {1} IND Wool Fulling - Washing synthetic fibre - Dyeing mg/l Mercerising - Bleaching - Dyeing - Desizing - Fabric mg/l production - Printing - Thermal treatment No information mg/l No information mg/l Bleaching - Dyeing - Functional finishing mg/l Dyeing - Singeing - Functional finishing - Thermal mg/l treatment - Wool Fulling Scouring - Dyeing - Functional finishing mg/l 29.7 59.50 101 42.75 55 153.85 580 3 13.05 80 9 25.57 81 1 79.00 120 60 150.33 226 21 1200 No information 1200 Other No information 300 No information 60 No information 60 Equalisation, Activated sludge process, Nitrification/denitrification No information 400 Other Other Other No information 24-hour flow proportional composite sample No information 24-hour flow proportional composite sample No information Not applicable Twice per year Twice per year 4 times per year 4 times per year Monthly No information Other Twice per year Monitoring standard Additional information No information Unities Utilities take random samples from the collection unit. It could be once, twice or even three times a month. Unities Utilities take random samples from the collection unit. It could be once, twice or even three times a month. Unities Utilities take random samples from the collection unit. It could be once, twice or even three times a month. No information APAT CNR IRSA 2090 B Man 29 2003, APAT CNR IRSA 2090 B Man 29 2003, APAT CNR IRSA 2090 B Man 29 2003 APAT CNR IRSA 2090 B Man 29 2003, APAT CNR IRSA 2090 B Man 29 2003, APAT CNR IRSA 2090 B Man 29 2003 APAT CNR IRSA 2090B Value refered to sampling period - Value refered to sampling period - Value refered to sampling period PNT MA/FQ-17 (2015-09-09), PNT MA/FQ-17 (2015-0909)-MESU.1 and PNT MA/FQ-17 (2016-04-07) MESU.2, PNT MA/FQ-17 (2016-04-07) Averaging period for ELVs: Twice per year - Averaging period for ELVs: Twice per year - Uncertainty: Method PNT MA/FQ-17(2016-04-07)MESU.1 12%; PNT-MA/FQ17(2016-04-07) MESU.2 17% ; Averaging period for ELVs: Twice per year DIN EN 872 (H33) APAT CNR IRSA 2090 B MAN 29 No information APAT CNR IRSA 2090 B MAN 29 2003 ARPAT CNR IRSA 2090B Man 29 2003 AVERAGE PERIOD 3 HOURS - AVERAGE PERIOD 3 HOURS AVERAGE PERIOD 3 HOURS Authorized in derogation - Authorized in derogation Authorized in derogation Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours Requested by Italian Law - Requested by Italian Law Requested by Italian Law,and other analyses introduced during 2018 to follow the ZDHC Waste Water Guide lines APAT CNR IRSA 2090 B Man 29 2003, APAT CNR IRSA Value refered to sampling period - Value refered to 2090 B Man 29 2003, APAT CNR IRSA 2090 B Man 29 2003 sampling period - Value refered to sampling period APAT CNR IRSA 2090 B MAN 29 2003 APAT CNR IRSA 2090 B MAN 29 2003 APAT-IRSA CNR 29-2003 2090B APAT CNR IRSA 2090 B MAN 29 2003 APAT CNR IRSA 2090 B MAN 29 2003 Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours (data referring to the year 2015) Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours (data referring to the year 2015) Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours APAT CNR IRSA 2090 B MAN 29 2003 ARPAT CNR IRSA2090 MAN 29 2003-2004-2005 APAT CNR IRSA 2090 MAN 29 2003 APAT CNR IRSA 2090 MAN 29 2003 AVERAGE PERIOD 3 HOURS - AVERAGE PERIOD 3 HOURS AVERAGE PERIOD 3 HOURS (YEAR 2015) AVERAGE PERIOD 3 HOURS - AVERAGE PERIOD 3 HOURS AVERAGE PERIOD 3 HOURS (YEAR 2015) No information Monitoring end frequency dependent on the operator of the off-site treatment plant - Monitoring end frequency dependent on the operator of the off-site treatment plant - Monitoring end frequency dependent on the operator of the off-site treatment plant APAT CNR IRSA 2090B Man 29 2003 Value refered to sampling period - Value refered to sampling period - Value refered to sampling period APAT CNR IRSA 2090 MAN 29 2003 Averaging period for monitoring: 3 hours; Parameter monitored on indication of the manager of the public sewage - Averaging period for monitoring: 3 hours; Parameter monitored on indication of the manager of the public sewage - Averaging period for monitoring: 3 hours; Parameter monitored on indication of the manager of the public sewage APAT CNR IRSA 2090 MAN 29 2003 APAT CNR IRSA 2090 B MAN 29 2003 No information Averaging period for monitoring: 3 hours; Parameter monitored on indication of the manager of the public sewage - Averaging period for monitoring: 3 hours; Parameter monitored on indication of the manager of the public sewage - Averaging period for monitoring: 3 hours; Parameter monitored on indication of the manager of the public sewage Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours DIN 38409 H2 5; one additional control measurement local authority Suspended Solids - filtered; determined by gravimetry WAC/III/D/002 APAT IRSA -CNR 2090/B Man 29 2003 APAT CNR IRSA 2090 B Man 29 2003, APAT CNR IRSA 2090 B Man 29 2003, APAT CNR IRSA 2090 B Man 29 2003 2 TSS - EMISSIONS TO WATER EP water name Type of discharge DIR = Direct IT084_w {1} IND IT085_w {1} IND IT087_w {1} IND IT088_w {1} IND IT089_w {1} IND Associated processes Bleaching - Dyeing - Thermal treatment Units for concentration values mg/l Min. concentration over 3 years Average concentration over 3 years Max. concentration over 3 years Max. load over 3 ELV (mg/l ) years (g/day) 3 10.33 24 Combination of techniques Type of sampling 80 Equalisation, Neutralisation, Grit separators, Screening, No information Coagulation and flocculation, Sedimentation Dyeing mg/l Dyeing - Shrink-proof finishing - Shrink-proof finishing - mg/l Other Dyeing - Bleaching mg/l 18 63.29 224 74 253.59 383 30 200.33 856 Equalisation 340 Equalisation 1200 No information Not applicable Not applicable, Grab/spot sample, Not applicable Not applicable Scouring - Dyeing - Thermal treatment - Other - Bleaching mg/l 36.7 114.98 236 1200 Other 24-hour flow proportional composite sample IT090_w {1} IND IT091_w {1} IND FR131_w {1} DIR IT094_w {1} IND FR134_w {1} DIR AT005_w {1} IND UK121_w {1} IND Scouring - Dyeing - Thermal treatment - Other - Bleaching mg/l Scouring - Dyeing - Functional finishing - Thermal mg/l treatment - Other Washing synthetic fibre - Bleaching - Dyeing - Printing - Functional finishing - Coating and laminating - Thermal mg/l treatment No information mg/l Washing synthetic fibre - Desizing - Mercerising - mg/l Bleaching - Dyeing - Singeing - Functional finishing No information mg/l Dyeing mg/l 42.8 107.4 0 63 22 27 19 87.58 175.23 16.50 89.53 70.42 99.22 68.00 153 332.8 105 141 234 160 180 44625 42840 1200 Other 24-hour flow proportional composite sample 1200 No information Other Other Other 35 Equalisation, Neutralisation, Grit separators, Activated sludge process, Anaerobic treatment 300 Neutralisation 1000 Equalisation 24-hour flow proportional composite sample No information No information No information 24-hour flow proportional composite sample Monitoring frequency 4 times per year Other Monthly Twice per year Twice per year Twice per year No information Daily Twice per year 4 times per year Monthly Monthly Monitoring standard APAT IRSA -CNR 2090/B Man 29 2003 APAT CNR IRSA 2090B Man 29 2003 No information apat irsa cnr 29/2003 2090 APAT CNR IRSA 2090 B MAN 29 2003 APAT CNR IRSA 2090 B MAN 29 2003 APAT CNR IRSA 2090 MAN 29 2003 No information APAT IRSA 2090 B Volume 1:2003 NF EN 872 DIN 38409 H2 ISO 11929 Additional information 3 h medium composite sample - 3 h medium composite sample - 3 h medium composite sample Monitoring end frequency dependent on the operator of the off-site treatment plant Value refered to sampling period - Value refered to sampling period - Value refered to sampling period Yearly - Yearly - Yearly ELV is referred to 3 hours sampled waste water - ELV is referred to 3 hours sampled waste water - ELV is referred to 3 hours sampled waste water. Data related to 2015. ELV is referred to 3 hours sampled waste water - ELV is referred to 3 hours sampled waste water - ELV is referred to 3 hours sampled waste water. Data related to 2015. AVERAGE PERIOD 3 HOURS - AVERAGE PERIOD 3 HOURS AVERAGE PERIOD 3 HOURS 22 3 23 Other Anaerobic treatment Membrane bioreactor Distillation/rectification Reverse osmosis Chemical reduction Chemical oxidation Flotation Nanofiltration Microfiltration Ultrafiltration Evaporation Adsorption Activated sludge process Nitrification/denitrification Sand filtration Sedimentation Coagulation and flocculation Screening Grit separators Oil separation Neutralisation Equalisation No technique used DE025_w {1} BE011_w {1} ES058_w {1} DE045_w {1} PT109_w {1} DE022_w {1} BE007_w {1} PT105_w {1} BE013_w {1} PT115_w {1} DE032_w {1} PT110_w {2} IT082_w {1} DE029_w {1} BE009_w {1} BE010_w {1} SE118_w {1} IT074_w {1} PT102_w {1} PT108_w {1} DE031_w {1} DE046_w {1} PT098_w {1} AT006_w {1} FR136_w {1} DE030_w {1} IT063_w {1} PT099_w {1} FR131_w {1} IT076_w {1} FR134_w {1} IT059_w {2} CZ015_w {1} DE039_w {1} BE008_w {1} SE119_w {1} AT003_w {1} DE026_w {1} IT084_w {1} CZ017_w {1} IT069_w {1} BE014_w {1} IT070_w {1} IT094_w {1} IT092_w {1} PT113_w {1} AT001_w {1} IT078_w {1} DE051_w {1} AT002_w {1} IT067_w {1} IT073_w {1} IT091_w {1} IT071_w {2} IT097_w {1} IT083_w {1} IT071_w {1} IT088_w {1} IT087_w {1} IT082_w {2} IT072_w {1} IT079_w {1} DE049_w {1} DE024_w {1} DE042_w {1} IT085_w {1} IT065_w {1} SE120_w {1} AT004_w {1} IT074_w {2} IT061_w {1} IT059_w {1} IT068_w {1} IT064_w {1} IT089_w {1} IT090_w {1} AT005_w {1} UK127_w {1} FR135_w {1} UK124_w {1} Techniques applied Max. load over 3 years (g/day) DIR DIR IND IND IND IND DIR IND IND IND DIR IND DIR IND DIR DIR IND IND IND IND IND IND DIR IND IND IND IND IND DIR IND DIR IND IND IND IND IND IND IND IND IND IND DIR IND IND DIR IND IND IND IND IND DIR IND IND IND DIR IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND DIR Per Per Freq Freq Per Per Freq Per Per Per Per Per Per Per Per Per Freq Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Freq Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Freq Per Per Per Per Per Per Per Per Per Freq Freq Per Type of discharge Type of monitoring Mass load expressed in g/day Concentration expressed in mg/l 25,000 20,000 15,000 10,000 5,000 60 50 40 30 20 10 0 DE025_w {1} BE011_w {1} ES058_w {1} DE045_w {1} PT109_w {1} DE022_w {1} BE007_w {1} PT105_w {1} BE013_w {1} PT115_w {1} DE032_w {1} PT110_w {2} IT082_w {1} DE029_w {1} BE009_w {1} BE010_w {1} SE118_w {1} IT074_w {1} PT102_w {1} PT108_w {1} DE031_w {1} DE046_w {1} PT098_w {1} AT006_w {1} FR136_w {1} DE030_w {1} IT063_w {1} PT099_w {1} FR131_w {1} IT076_w {1} FR134_w {1} IT059_w {2} CZ015_w {1} DE039_w {1} BE008_w {1} SE119_w {1} AT003_w {1} DE026_w {1} IT084_w {1} CZ017_w {1} IT069_w {1} BE014_w {1} IT070_w {1} IT094_w {1} IT092_w {1} PT113_w {1} AT001_w {1} IT078_w {1} DE051_w {1} AT002_w {1} IT067_w {1} IT073_w {1} IT091_w {1} IT071_w {2} IT097_w {1} IT083_w {1} IT071_w {1} IT088_w {1} IT087_w {1} IT082_w {2} IT072_w {1} IT079_w {1} DE049_w {1} DE024_w {1} DE042_w {1} IT085_w {1} IT065_w {1} SE120_w {1} AT004_w {1} IT074_w {2} IT061_w {1} IT059_w {1} IT068_w {1} IT064_w {1} IT089_w {1} IT090_w {1} AT005_w {1} UK127_w {1} FR135_w {1} UK124_w {1} DE025_w {1} BE011_w {1} ES058_w {1} DE045_w {1} PT109_w {1} DE022_w {1} BE007_w {1} PT105_w {1} BE013_w {1} PT115_w {1} DE032_w {1} PT110_w {2} IT082_w {1} DE029_w {1} BE009_w {1} BE010_w {1} SE118_w {1} IT074_w {1} PT102_w {1} PT108_w {1} DE031_w {1} DE046_w {1} PT098_w {1} AT006_w {1} FR136_w {1} DE030_w {1} IT063_w {1} PT099_w {1} FR131_w {1} IT076_w {1} FR134_w {1} IT059_w {2} CZ015_w {1} DE039_w {1} BE008_w {1} SE119_w {1} AT003_w {1} DE026_w {1} IT084_w {1} CZ017_w {1} IT069_w {1} BE014_w {1} IT070_w {1} IT094_w {1} IT092_w {1} PT113_w {1} AT001_w {1} IT078_w {1} DE051_w {1} AT002_w {1} IT067_w {1} IT073_w {1} IT091_w {1} IT071_w {2} IT097_w {1} IT083_w {1} IT071_w {1} IT088_w {1} IT087_w {1} IT082_w {2} IT072_w {1} IT079_w {1} DE049_w {1} DE024_w {1} DE042_w {1} IT085_w {1} IT065_w {1} SE120_w {1} AT004_w {1} IT074_w {2} IT061_w {1} IT059_w {1} IT068_w {1} IT064_w {1} IT089_w {1} IT090_w {1} AT005_w {1} UK127_w {1} FR135_w {1} UK124_w {1} 0 Point of discharge ELV (mg/l ) over 3 years Average concentration 70 ZINC - Emissions to water 24 Other Anaerobic treatment Membrane bioreactor Distillation/rectification Reverse osmosis Chemical reduction Chemical oxidation Flotation Nanofiltration Microfiltration Ultrafiltration Evaporation Adsorption Activated sludge process Nitrification/denitrification Sand filtration Sedimentation Coagulation and flocculation Screening Grit separators Oil separation Neutralisation Equalisation No technique used DE025_w {1} BE011_w {1} ES058_w {1} DE045_w {1} PT109_w {1} DE022_w {1} BE007_w {1} PT105_w {1} BE013_w {1} PT115_w {1} DE032_w {1} PT110_w {2} IT082_w {1} DE029_w {1} BE009_w {1} BE010_w {1} SE118_w {1} IT074_w {1} PT102_w {1} PT108_w {1} DE031_w {1} DE046_w {1} PT098_w {1} AT006_w {1} FR136_w {1} DE030_w {1} IT063_w {1} PT099_w {1} FR131_w {1} IT076_w {1} FR134_w {1} IT059_w {2} CZ015_w {1} DE039_w {1} BE008_w {1} SE119_w {1} AT003_w {1} DE026_w {1} IT084_w {1} CZ017_w {1} IT069_w {1} BE014_w {1} IT070_w {1} IT094_w {1} IT092_w {1} PT113_w {1} AT001_w {1} IT078_w {1} DE051_w {1} AT002_w {1} IT067_w {1} IT073_w {1} IT091_w {1} IT071_w {2} IT097_w {1} IT083_w {1} IT071_w {1} IT088_w {1} IT087_w {1} IT082_w {2} IT072_w {1} IT079_w {1} DE049_w {1} DE024_w {1} DE042_w {1} IT085_w {1} IT065_w {1} SE120_w {1} AT004_w {1} IT074_w {2} IT061_w {1} IT059_w {1} IT068_w {1} IT064_w {1} IT089_w {1} IT090_w {1} AT005_w {1} UK127_w {1} FR135_w {1} UK124_w {1} Techniques applied Average concentration over 3 years ELV (mg/l ) Max. load over 3 years (g/day) DIR DIR IND IND IND IND DIR IND IND IND DIR IND DIR IND DIR DIR IND IND IND IND IND IND DIR IND IND IND IND IND DIR IND DIR IND IND IND IND IND IND IND IND IND IND DIR IND IND DIR IND IND IND IND IND DIR IND IND IND DIR IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND DIR Per Per Freq Freq Per Per Freq Per Per Per Per Per Per Per Per Per Freq Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Freq Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Freq Per Per Per Per Per Per Per Per Per Freq Freq Per Type of discharge Type of monitoring Mass load expressed in g/day Concentration expressed in mg/l 25,000 20,000 15,000 10,000 5,000 0 DE025_w {1} BE011_w {1} ES058_w {1} DE045_w {1} PT109_w {1} DE022_w {1} BE007_w {1} PT105_w {1} BE013_w {1} PT115_w {1} DE032_w {1} PT110_w {2} IT082_w {1} DE029_w {1} BE009_w {1} BE010_w {1} SE118_w {1} IT074_w {1} PT102_w {1} PT108_w {1} DE031_w {1} DE046_w {1} PT098_w {1} AT006_w {1} FR136_w {1} DE030_w {1} IT063_w {1} PT099_w {1} FR131_w {1} IT076_w {1} FR134_w {1} IT059_w {2} CZ015_w {1} DE039_w {1} BE008_w {1} SE119_w {1} AT003_w {1} DE026_w {1} IT084_w {1} CZ017_w {1} IT069_w {1} BE014_w {1} IT070_w {1} IT094_w {1} IT092_w {1} PT113_w {1} AT001_w {1} IT078_w {1} DE051_w {1} AT002_w {1} IT067_w {1} IT073_w {1} IT091_w {1} IT071_w {2} IT097_w {1} IT083_w {1} IT071_w {1} IT088_w {1} IT087_w {1} IT082_w {2} IT072_w {1} IT079_w {1} DE049_w {1} DE024_w {1} DE042_w {1} IT085_w {1} IT065_w {1} SE120_w {1} AT004_w {1} IT074_w {2} IT061_w {1} IT059_w {1} IT068_w {1} IT064_w {1} IT089_w {1} IT090_w {1} AT005_w {1} UK127_w {1} FR135_w {1} UK124_w {1} DE025_w {1} BE011_w {1} ES058_w {1} DE045_w {1} PT109_w {1} DE022_w {1} BE007_w {1} PT105_w {1} BE013_w {1} PT115_w {1} DE032_w {1} PT110_w {2} IT082_w {1} DE029_w {1} BE009_w {1} BE010_w {1} SE118_w {1} IT074_w {1} PT102_w {1} PT108_w {1} DE031_w {1} DE046_w {1} PT098_w {1} AT006_w {1} FR136_w {1} DE030_w {1} IT063_w {1} PT099_w {1} FR131_w {1} IT076_w {1} FR134_w {1} IT059_w {2} CZ015_w {1} DE039_w {1} BE008_w {1} SE119_w {1} AT003_w {1} DE026_w {1} IT084_w {1} CZ017_w {1} IT069_w {1} BE014_w {1} IT070_w {1} IT094_w {1} IT092_w {1} PT113_w {1} AT001_w {1} IT078_w {1} DE051_w {1} AT002_w {1} IT067_w {1} IT073_w {1} IT091_w {1} IT071_w {2} IT097_w {1} IT083_w {1} IT071_w {1} IT088_w {1} IT087_w {1} IT082_w {2} IT072_w {1} IT079_w {1} DE049_w {1} DE024_w {1} DE042_w {1} IT085_w {1} IT065_w {1} SE120_w {1} AT004_w {1} IT074_w {2} IT061_w {1} IT059_w {1} IT068_w {1} IT064_w {1} IT089_w {1} IT090_w {1} AT005_w {1} UK127_w {1} FR135_w {1} UK124_w {1} 1.5 1.4 1.3 1.2 1.1 1.0 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0.0 Point of discharge ZINC - Emissions to water (zoom 0-1.5 mg/l) ZINC - EMISSIONS TO WATER EP water name Type of discharge DIR = Direct DE025_w {1} DIR BE011_w {1} DIR ES058_w {1} IND DE045_w {1} IND PT109_w {1} IND DE022_w {1} IND BE007_w {1} DIR PT105_w {1} IND BE013_w {1} IND PT115_w {1} IND DE032_w {1} DIR PT110_w {2} IND IT082_w {1} DIR DE029_w {1} IND BE009_w {1} DIR BE010_w {1} DIR SE118_w {1} IND IT074_w {1} IND PT102_w {1} IND Associated processes Washing synthetic fibre - Dyeing - Printing Units for concentration values mg/l Min. concentration over 3 years Average concentration over 3 years Max. concentration over 3 years Max. load over 3 ELV (mg/l ) years (g/day) 0 0 0 Combination of techniques Type of sampling 1.5 Equalisation, Neutralisation, Coagulation and flocculation, 24-hour flow proportional composite sample Sedimentation, Activated sludge process Dyeing mg/l Mercerising - Bleaching - Dyeing - Desizing - Fabric mg/l production - Printing - Thermal treatment Washing synthetic fibre - Desizing - Desizing mg/l No information mg/l Raw wool scouring - Washing synthetic fibre - Desizing - Scouring - Bleaching - Dyeing - Thermal treatment - mg/l Functional finishing - Coating and laminating Dyeing mg/l Dyeing - Bleaching mg/l Mercerising mg/l No information mg/l 0.022 0.0564 0.01 0.08 0.033 0.01 0.03 0.038 0.05 0.06 0.06 0.0564 0.03 0.06 0.07 0.08 0.08 0.06 0.085 0.05 0.0905 Equalisation, Neutralisation, Coagulation and flocculation, 2 Activated sludge process, Nitrification/denitrification, Sand filtration, Nanofiltration, Chemical oxidation (incl. 24-hour flow proportional composite sample Advanced oxidation) No information No information 5 Oil separation, Neutralisation No information 24-hour flow proportional composite sample No information 2 Neutralisation, Oil separation, Evaporation Other Equalisation, Neutralisation, Sand filtration, Activated sludge process, Nitrification/denitrification No information Distillation/rectification, Equalisation, Neutralisation 5 Equalisation, Neutralisation, Screening Flow proportional composite sample, Not applicable, Flow proportional composite sample No information Flow proportional composite sample 24-hour flow proportional composite sample Washing synthetic fibre - Desizing - Bleaching - Dyeing - mg/l Printing Dyeing mg/l Dyeing - Singeing - Functional finishing - Thermal mg/l treatment - Wool Fulling Dyeing mg/l Printing - Coating and laminating mg/l Bleaching - Dyeing - Bleaching - Scouring - Functional mg/l finishing Washing synthetic fibre - Scouring - Scouring - Bleaching Dyeing - Singeing - Printing - Functional finishing - Shrink- mg/l proof finishing - Coating and laminating - Thermal treatment Washing synthetic fibre - Scouring - Functional finishing - mg/l Dry cleaning - Other 0.015 0.05 0 0.02 0 0.025 0.065 0.106 0.04 0.098 0.09 0.1 0.03 0.1 0.06 0.11 0.05 0.116 0.06 0.116 0.08 0.118 41.536 0.12 0.139 Equalisation, Neutralisation, Grit separators, Coagulation and flocculation, Sedimentation, Sand filtration, 24-hour flow proportional composite sample Nitrification/denitrification, Activated sludge process 5 Equalisation, Grit separators, Screening Equalisation, Neutralisation, Activated sludge process, 0.5 Nitrification/denitrification, Sedimentation, Adsorption (e.g. powdered/granular activated carbon, lignite coke, etc.), Other 2 No information Screening, Sedimentation, Equalisation, Activated sludge process, Sand filtration, Coagulation and flocculation, 0.6 Flotation, Chemical oxidation (incl. Advanced oxidation), Sand filtration, Chemical reduction, Microfiltration, Reverse osmosis 0.4 EqualisationActivated sludge process, Nitrification/denitrification, Other No information Not applicable Flow proportional composite sample Other, 24-hour flow proportional composite sample, Other 24-hour flow proportional composite sample 0.3 Sedimentation, Neutralisation 24-hour flow proportional composite sample 2 Other Other Scouring - Dyeing - Bleaching mg/l 0.03 0.06 0.14 5 Other 24-hour flow proportional composite sample Monitoring frequency Monthly No information 4 times per year Twice per year Yearly Monthly Monthly Yearly Yearly Yearly Twice per year Twice per year Yearly 4 times per year No information Yearly Monthly No information Twice per year PT108_w {1} IND Fabric production - Fabric production mg/l DE031_w {1} IND Dyeing mg/l DE046_w {1} IND Washing synthetic fibre - Dyeing mg/l 0.05 0.028 0.033 0.10 0.14 0.09 0.155 0.10 0.16 5 Neutralisation, Sand filtration, Sand filtration No information 2 No information 24-hour flow proportional composite sample No information No information Yearly Other No information PT098_w {1} DIR Wool Fulling - Functional finishing - Dyeing - Thermal mg/l treatment 0.086 0.15 0.18 Equalisation, Neutralisation, Sedimentation, Sand filtration, Activated sludge process, Other No information Yearly AT006_w {1} IND FR136_w {1} IND DE030_w {1} IND IT063_w {1} IND PT099_w {1} IND FR131_w {1} DIR IT076_w {1} IND FR134_w {1} DIR IT059_w {2} IND CZ015_w {1} IND DE039_w {1} IND BE008_w {1} IND SE119_w {1} IND AT003_w {1} IND DE026_w {1} IND IT084_w {1} IND CZ017_w {1} IND IT069_w {1} IND BE014_w {1} DIR IT070_w {1} IND Bleaching - Dyeing mg/l Desizing - Scouring - Bleaching - Mercerising - Dyeing - mg/l Singeing - Fabric production - Functional finishing Washing synthetic fibre - Desizing - Mercerising - Bleaching - Singeing - Dyeing - Functional finishing - mg/l Thermal treatment Dyeing - Fabric production - Dry cleaning - Printing - mg/l Printing - Functional finishing Dyeing - Printing - Functional finishing mg/l Washing synthetic fibre - Bleaching - Dyeing - Printing - Functional finishing - Coating and laminating - Thermal mg/l treatment Raw wool scouring mg/l Washing synthetic fibre - Desizing - Mercerising - mg/l Bleaching - Dyeing - Singeing - Functional finishing Thermal treatment - Functional finishing mg/l Dyeing - Functional finishing mg/l Mercerising - Dyeing - Washing synthetic fibre - mg/l Bleaching - Desizing Printing - Dyeing mg/l Washing synthetic fibre - Desizing - Functional finishing - mg/l Dyeing Mercerising - Dyeing - Desizing - Bleaching mg/l Washing synthetic fibre - Desizing - Dyeing - Bleaching mg/l Bleaching - Dyeing - Thermal treatment mg/l Spinning - Fabric production - Singeing - Functional finishing - Shrink-proof finishing - Thermal treatment - mg/l Other Scouring - Bleaching - Mercerising mg/l Bleaching - Dyeing - Functional finishing mg/l No information mg/l 0.058 0.042 0.055 0.05 0.0898 0.07 0.2 0.022 0.0379 0.05 0.078 0.014 0.061 0.11 0.037 0.005 0.17 0.087 0.03 0.02 0.10 0.18 0.12 0.188 0.10 0.19 0.10 0.19 0.13 0.2 0.13 0.2 0.20 0.2 0.09 0.21 102.9 0.10 0.213 0.09 0.22 0.16 0.232 0.13 0.24 0.11 0.243 43.497 0.15 0.25 0.10 0.26 0.04 0.26 0.24 0.283 0.16 0.288 0.10 0.295 0.11 0.3 2 Flotation 15 Grit separators, Neutralisation No information No information 2 Equalisation, Neutralisation, Screening 24-hour flow proportional composite sample 1 Equalisation 5 Screening, Oil separation, Other Other Other No information 24-hour flow proportional composite sample Equalisation, Flotation, Coagulation and flocculation, 0.5 Activated sludge process, Nitrification/denitrification, Sedimentation, Membrane bioreactor 0.8 Equalisation, Neutralisation, Grit separators, Activated sludge process, Anaerobic treatment 2 No technique used Grit separators, Equalisation, Sedimentation Equalisation, Neutralisation 0.3 Equalisation, Grit separators, Other No technique used 0.5 Other 2 No information Not applicable No information Not applicable Flow proportional composite sample Flow proportional composite sample 24-hour flow proportional composite sample 24-hour flow proportional composite sample Other Other 0.5 Equalisation, Neutralisation, Grit separators, Screening, No information Coagulation and flocculation, Sedimentation No information No information 2 Other 0.9 Equalisation, Activated sludge process, Nitrification/denitrification 1 No information Other 24-hour flow proportional composite sample Not applicable Yearly No information 4 times per year 4 times per year 4 times per year Monthly Other 4 times per year Twice per year 4 times per year Twice per year No information No information 4 times per year No information 4 times per year Yearly Twice per year No information Twice per year 25 Monitoring standard DIN EN ISO 11885 (E22) Additional information WAC/III/B011 of WAC/III/B010- WAC/III/B002 5 measurements < DL (0,066 mg/l) No information No information No information DIN WAC/III/B011 of WAC/III/B010- WAC/III/B002 No information MEIN043TAX, MEIN043TAX, MEIN062TAX SMEWW 3030 K/SMEWW 3111 B, SMEWW 3030 K/SMEWW 3111 B, W- METAXDG1 No information No information IRSA 3010 + 3020* No information WAC/III/BWAC/III/B WAC/III/B011 of WAC/III/B010- WAC/III/B002 The installation only started operating in 2017.The value of uncertainty is not refered in the reports. sample 23.10.2015, 0,033 mg/l - <0,005 mg/l < LQ; LD= 0,01SIDVA - SIDVA - SIDVA Less than 12/year flow proportionate sampling, >12/year are grab sample results. Value 0 means results beneath detection limit of analyses 1 measurement < 0,025 mg/l No information Three months average UNI EN ISO 11885:2009 IT-DLQ-42/V03;SMEWW3111 B, 21ed AVERAGE PERIOD 3 HOURS - AVERAGE PERIOD 3 HOURS AVERAGE PERIOD 3 HOURS (YEAR 2015) For the second monitoring the value is below level of quantification - In these monitoring the value is below level of quantification - SMEWW3030 K/SMEWW 3111 B (22 ed), SMEWW3030 annual measurement - annual measurement - annual K/SMEWW 3111 B (22 ed), PT 15 Ed. 12 (2O17-01-12) measurement DIN EN ISO 11885DIN EN ISO 11885 No information 3 times/year - 3 times/year - 3 times/year - qualified sample - There is only VLE for total metals ( As, Cd, Pb, Cu, Cr, Zn, DIN EN ISO 11885 (E22), DIN EN ISO 17294-2(E29), DIN EN Hg and Ni) - VLE 5mg/l ; - MESU. 1 - 0,086 mg/l ; There is ISO 11885 (E22) only VLE for total metals ( As, Cd, Pb, Cu, Cr, Zn, Hg and Ni) - VLE 5mg/l - There is only VLE for total metals ( As, Cd, Pb, Cu, Cr, Zn, Hg and Ni) - VLE 5mg/l ; EN ISO 11885 No information DIN No information DIN EN ISO 11885/ICP-OES NF EN ISO 11885 APAT CNR IRSA 3020 Man 29 2003 NF EN ISO 11885 EPA 6020 B 2014 No information No information WAC/III/B011 of WAC/III/B010- WAC/III/B002 No information DIN EN ISO 11885DIN EN ISO 11885 DIN EPA 6020 B 2014 No information UNI EN ISO 11885:2009 WAC/III/B011 of WAC/III/B010- WAC/III/B002 EPA 6010 C 2007 Monitoring frequency: spotValue refered to sampling period RSDE regulation - RSDE regulation - RSDE regulation 3 h medium composite sample - 3 h medium composite sample - 3 h medium composite sample Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours (data referring to the year 2015) 1 mesurement < DL (0,025 mg/l)2 measurements < DL (0,025 mg/l) 1 ZINC - EMISSIONS TO WATER EP water name Type of discharge DIR = Direct IT094_w {1} IND IT092_w {1} DIR PT113_w {1} IND AT001_w {1} IND IT078_w {1} IND DE051_w {1} IND AT002_w {1} IND IT067_w {1} DIR IT073_w {1} IND IT091_w {1} IND IT071_w {2} IND Associated processes Units for concentration values Min. concentration over 3 years Average concentration over 3 years Max. concentration over 3 years Max. load over 3 ELV (mg/l ) years (g/day) Combination of techniques Type of sampling No information mg/l 0.001 0.11 0.3 Other No information Dyeing - Other mg/l Dyeing - Washing synthetic fibre - Bleaching - Functional mg/l finishing No information mg/l Wool Fulling - Washing synthetic fibre - Dyeing mg/l Washing synthetic fibre - Scouring - Bleaching - Dyeing - mg/l Functional finishing No information mg/l Dyeing - Printing - Other - Shrink-proof finishing mg/l Dyeing - Functional finishing mg/l Scouring - Dyeing - Functional finishing - Thermal mg/l treatment - Other Dyeing - Other - Functional finishing mg/l 0.31 0.07 0.098 0.068 0.06 0.055 0.18 0.11 0.12 0.27 0.31 0.31 0.18 0.32 0.18 0.33 0.18 0.34 0.21 0.39 0.12 0.39 0.27 0.4 0.21 0.425 0.23 0.475 0.38 0.5 Equalisation, Neutralisation, Activated sludge process, 0.5 Nitrification/denitrification, Sedimentation, Reverse osmosis 5 No information Not applicable Other 1 No information 24-hour flow proportional composite sample 2 Other Other 2 Neutralisation, Coagulation and flocculation, Equalisation No information 0.5 No information 0.5 Equalisation, Neutralisation, Activated sludge process, Nitrification/denitrification, Sedimentation 2 No technique used No information Not applicable Other 2 No information Other 2 Other Other Monitoring frequency Twice per year Other Yearly 4 times per year Twice per year Monthly Yearly Other Twice per year No information Twice per year IT097_w {1} DIR Dyeing - Shrink-proof finishing - Printing - Other mg/l 0.005 0.13 0.5 0.5 Equalisation, Neutralisation, Activated sludge process, Nitrification/denitrification, Sedimentation Not applicable Twice per year IT083_w {1} IND IT071_w {1} IND IT088_w {1} IND IT087_w {1} IND IT077_w {1} IND IT082_w {2} IND IT072_w {1} IND IT079_w {1} IND DE049_w {1} IND DE024_w {1} IND DE042_w {1} IND IT085_w {1} IND IT065_w {1} IND SE120_w {1} IND AT004_w {1} IND IT074_w {2} IND IT061_w {1} IND IT059_w {1} IND IT077_w {2} IND IT068_w {1} IND IT064_w {1} IND IT089_w {1} IND IT090_w {1} IND AT005_w {1} IND UK127_w {1} IND FR135_w {1} IND UK124_w {1} DIR UK126_w {1} IND Scouring - Dyeing - Functional finishing mg/l Dyeing - Bleaching - Scouring Dyeing - Bleaching Dyeing - Shrink-proof finishing - Shrink-proof finishing Other Desizing - Mercerising - Scouring - Bleaching - Singeing Thermal treatment Dyeing - Singeing - Functional finishing - Thermal treatment - Wool Fulling Thermal treatment - Scouring - Bleaching - Dyeing Other mg/l mg/l mg/l No unit reported mg/l mg/l Scouring - Wool Fulling - Functional finishing - Thermal mg/l treatment - Other Desizing - Bleaching - Bleaching - Dyeing - Singeing - Printing - Coating and laminating - Scouring - Functional mg/l finishing Desizing - Dyeing - Scouring - Singeing mg/l Washing synthetic fibre - Desizing - Bleaching - Dyeing - mg/l Functional finishing Dyeing mg/l No information mg/l Washing synthetic fibre - Desizing - Bleaching mg/l Washing synthetic fibre mg/l Washing synthetic fibre - Scouring mg/l Scouring - Wool Carbonising mg/l Scouring - Mercerising - Bleaching - Dyeing - Singeing Dry cleaning Dyeing mg/l No unit reported Washing synthetic fibre - Desizing - Scouring - Bleaching - mg/l Dyeing - Functional finishing - Other Scouring mg/l Scouring - Dyeing - Thermal treatment - Other - mg/l Bleaching Scouring - Dyeing - Thermal treatment - Other - mg/l Bleaching No information mg/l Mercerising - Bleaching - Dyeing - Scouring - Singeing - mg/l Printing Washing synthetic fibre No information Dyeing mg/l mg/l other (please specify in the column "additional information") 0.28 0.40 0.33 0.49 0.05 0.24 0.67 0.67 0.03 0.27 0.065 0.45 0.3 0.47 0.16 0.36 0.088 0.24 0.06 0.37 0.087 0.39 1.1 1.20 0.1 0.34 0.34 0.89 0.52 1.19 0.173 0.74 0.44 1.41 0.0575 0.63 0.074 0.45 0.041 0.90 0.051 0.88 0.08 1.34 1.07 0.38 0.119 0.6 5 96 1.59 0.97 1.65 3.11 28.33 2038.51 0.5 0.58 0.6 0.67 0.69 0.69 0.883 0.94 0.98 1.13 1.2 1.3 1.56 1.7 1.72 1.745 1.835 1.84 1.84 1.863 1.87 1.9 785.6 1.91 2.5 10 14.95 61.6 19886.6 2933.3395 8360 1 Other 2 No information 2 No information 1 Equalisation 2 No information No information 2 Other 2 Other 2 Equalisation, Neutralisation 2 Equalisation 2 Neutralisation, Equalisation Equalisation Other 0.5 Neutralisation, Oil separation, Equalisation 2 No information 2 Other 2 Other 2 Other 2 No information 2 Other 2 Other 2 Other Not applicable Other Not applicable Not applicable, Grab/spot sample, Not applicable Other No information Other 24-hour flow proportional composite sample 24-hour flow proportional composite sample Grab/spot sample 24-hour flow proportional composite sample Not applicable No information 24-hour flow proportional composite sample No information Other Other Not applicable Other Other Other 24-hour flow proportional composite sample Other Twice per year Twice per year Other Twice per year Other Twice per year Twice per year 4 times per year 4 times per year 4 times per year Other Twice per year Continuous Weekly No information Twice per year Twice per year Twice per year Twice per year Twice per year Twice per year 2 Other 2 Neutralisation 24-hour flow proportional composite sample No information 10 Neutralisation 24-hour flow proportional composite sample 1.5 Grit separators Neutralisation, Coagulation and flocculation, Flotation, Other 24-hour flow proportional composite sample Other No information Flow proportional composite sample Twice per year Monthly Weekly Monthly Twice per year No information 26 Monitoring standard Additional information APAT CNR IRSA 3020 Volume 1:2003 APAT CNR IRSA 3020 Man 29 2003 - In the second determination, the concentration was under the detection limit of 0,001mg/l - In the second determination, the concentration was under the detection limit of 0,001mg/l Monitoring frequency: spotValue refered to sampling period No information DIN EN ISO 11885DIN EN ISO 11885 5; one additional control measurement local authority UNI EN ISO 11885:2009 Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours No information DIN EN ISO 11885DIN EN ISO 11885 APAT CNR IRSA 3020 Man 29 2003 UNI EN ISO 11885:2009 UNI EN ISO 11885:2009 UNI EN ISO 11885:2009 Monitoring frequency: spotValue refered to sampling period AVERAGE PERIOD 3 HOURS - AVERAGE PERIOD 3 HOURS AVERAGE PERIOD 3 HOURS Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours APAT CNR IRSA 3020 Man 29 2003, UNI EN ISO 155871:2002+UNI EN ISO 11885:2009, UNI EN ISO 11885:2009 Measurement 2 is inferior to detection limit: <0,005Value refered to sampling period - Measurement 3 is inferior to detection limit: <0,05Value refered to sampling period Measurement 1 is inferior to detection limit: <0,05Measurement 4 is inferior to detection limit: <0,5Value refered to sampling period APAT CNR IRSA 3010 A Man 29 2003+APAT CNR IRSA 3020 Man 29 2003 UNI EN ISO 11885:2009 EPA 6010 C 2007 RANDOM TEST MADE BY THE COMPANY - RANDOM TEST MADE BY THE COMPANY Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours Yearly - Yearly - Yearly No information Monitoring frequency: spot UNI EN ISO 11885:2009 Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours APAT IRSA -CNR 3010/A + 3020Man 29 2003 UNI EN ISO 11885:2009 Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours UNI EN ISO 11885:2009 ELV is referred to 3 hours sampled waste water - ELV is referred to 3 hours sampled waste water - ELV is referred to 3 hours sampled waste water. Data related to 2015. DIN No information No information No information ARPAT CNR IRSA 3010 Man 29 2003 No information EN ISO 11885 (MH) UNI EN ISO 11885:2009 UNI EN ISO 11885:2009 EPA 6020 B 2014 UNI EN ISO 11885:2009 UNI EN ISO 11885:2009 UNI EN ISO 11885:2009 UNI EN ISO 11885:2009 UNI EN ISO 11885:2009 DIN EN ISO 11885DIN EN ISO 11885 No information No information ICPMS Routine- acid digested; determined by ICPMS Monitoring end frequency dependent on the operator of the off-site treatment plant Requested by Italian Law - Requested by Italian Law Requested by Italian Law,and other analyses introduced during 2018 to follow the ZDHC Waste Water Guide lines Quartely AVERAGE PERIOD 3 HOURS - AVERAGE PERIOD 3 HOURS AVERAGE PERIOD 3 HOURS (YEAR 2015) AVERAGE PERIOD 3 HOURS - AVERAGE PERIOD 3 HOURS Averaging period for ELV: 3 hours; YEAR 2015 Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours (data referring to the year 2015) Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours ELV is referred to 3 hours sampled waste water - ELV is referred to 3 hours sampled waste water - ELV is referred to 3 hours sampled waste water. Data related to 2015. ELV is referred to 3 hours sampled waste water - ELV is referred to 3 hours sampled waste water - ELV is referred to 3 hours sampled waste water. Data related to 2015. Toxic metals in excess of 10000ug/l either individually or in total - Toxic metals in excess of 10000ug/l either individually or in total - Toxic metals in excess of 10000ug/l either individually or in total No information The unit measurement is in microgrammes/litre - The unit measurement is in microgrammes/litre - The unit measurement is in microgrammes/litre 2 27 Other Anaerobic treatment Membrane bioreactor Distillation/rectification Reverse osmosis Chemical reduction Chemical oxidation Flotation Nanofiltration Microfiltration Ultrafiltration Evaporation Adsorption Activated sludge process Nitrification/denitrification Sand filtration Sedimentation Coagulation and flocculation Screening Grit separators Oil separation Neutralisation Equalisation No technique used DE025_w {1} ES058_w {1} SE118_w {1} DE031_w {1} IT094_w {1} FR131_w {1} DE042_w {1} DE045_w {1} DE039_w {1} FR134_w {1} IT059_w {2} DE024_w {1} IT059_w {1} FR136_w {1} IT074_w {2} IT076_w {1} DE030_w {1} FR135_w {1} PT109_w {1} IT065_w {1} DE051_w {1} DE029_w {1} CZ015_w {1} DE023_w {1} SE120_w {1} IT082_w {1} AT006_w {1} IT069_w {1} IT097_w {1} BE009_w {1} IT091_w {1} IT064_w {1} IT074_w {1} UK127_w {1} DE026_w {1} AT003_w {1} DE049_w {1} IT092_w {1} BE007_w {1} IT068_w {1} IT084_w {1} AT005_w {1} DE022_w {1} PT098_w {1} PT115_w {1} AT002_w {1} BE014_w {1} IT082_w {2} IT078_w {1} BE008_w {1} AT001_w {1} PT110_w {2} PT113_w {1} IT087_w {1} IT079_w {1} IT071_w {2} CZ017_w {1} IT067_w {1} PT102_w {1} SE119_w {1} PT104_w {1} PT105_w {1} PT111_w {1} IT061_w {1} PT099_w {1} IT088_w {1} IT073_w {1} IT072_w {1} IT070_w {1} IT071_w {1} IT063_w {1} IT089_w {1} IT085_w {1} IT090_w {1} UK121_w {1} UK124_w {1} Techniques applied Max. load over 3 years (g/day) DIR IND IND IND IND DIR IND IND IND DIR IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND DIR IND IND DIR DIR IND IND IND IND IND IND IND DIR DIR IND IND IND IND DIR IND IND DIR IND IND IND IND IND IND IND IND IND IND DIR IND IND IND IND DIR IND IND IND IND IND IND IND IND IND IND IND IND DIR Per Freq Freq Per Per Per Per Freq Per Per Per Per Per Per Per Per Per Freq Per Per Per Per Per Per Freq Per Per Per Per Per Per Per Per Freq Per Per Per Per Freq Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Freq Per Per Per Per Per Per Per Per Per Per Per Per Per Per Freq Per Type of discharge Type of monitoring Mass load expressed in g/day Concentration expressed in mg/l 10 900 800 700 600 500 400 300 200 100 0 6 4 2 DE025_w {1} ES058_w {1} SE118_w {1} DE031_w {1} IT094_w {1} FR131_w {1} DE042_w {1} DE045_w {1} DE039_w {1} FR134_w {1} IT059_w {2} DE024_w {1} IT059_w {1} FR136_w {1} IT074_w {2} IT076_w {1} DE030_w {1} FR135_w {1} PT109_w {1} IT065_w {1} DE051_w {1} DE029_w {1} CZ015_w {1} DE023_w {1} SE120_w {1} IT082_w {1} AT006_w {1} IT069_w {1} IT097_w {1} BE009_w {1} IT091_w {1} IT064_w {1} IT074_w {1} UK127_w {1} DE026_w {1} AT003_w {1} DE049_w {1} IT092_w {1} BE007_w {1} IT068_w {1} IT084_w {1} AT005_w {1} DE022_w {1} PT098_w {1} PT115_w {1} AT002_w {1} BE014_w {1} IT082_w {2} IT078_w {1} BE008_w {1} AT001_w {1} PT110_w {2} PT113_w {1} IT087_w {1} IT079_w {1} IT071_w {2} CZ017_w {1} IT067_w {1} PT102_w {1} SE119_w {1} PT104_w {1} PT105_w {1} PT111_w {1} IT061_w {1} PT099_w {1} IT088_w {1} IT073_w {1} IT072_w {1} IT070_w {1} IT071_w {1} IT063_w {1} IT089_w {1} IT085_w {1} IT090_w {1} UK121_w {1} UK124_w {1} DE025_w {1} ES058_w {1} SE118_w {1} DE031_w {1} IT094_w {1} FR131_w {1} DE042_w {1} DE045_w {1} DE039_w {1} FR134_w {1} IT059_w {2} DE024_w {1} IT059_w {1} FR136_w {1} IT074_w {2} IT076_w {1} DE030_w {1} FR135_w {1} PT109_w {1} IT065_w {1} DE051_w {1} DE029_w {1} CZ015_w {1} DE023_w {1} SE120_w {1} IT082_w {1} AT006_w {1} IT069_w {1} IT097_w {1} BE009_w {1} IT091_w {1} IT064_w {1} IT074_w {1} UK127_w {1} DE026_w {1} AT003_w {1} DE049_w {1} IT092_w {1} BE007_w {1} IT068_w {1} IT084_w {1} AT005_w {1} DE022_w {1} PT098_w {1} PT115_w {1} AT002_w {1} BE014_w {1} IT082_w {2} IT078_w {1} BE008_w {1} AT001_w {1} PT110_w {2} PT113_w {1} IT087_w {1} IT079_w {1} IT071_w {2} CZ017_w {1} IT067_w {1} PT102_w {1} SE119_w {1} PT104_w {1} PT105_w {1} PT111_w {1} IT061_w {1} PT099_w {1} IT088_w {1} IT073_w {1} IT072_w {1} IT070_w {1} IT071_w {1} IT063_w {1} IT089_w {1} IT085_w {1} IT090_w {1} UK121_w {1} UK124_w {1} 0 Point of discharge ELV (mg/l ) over 3 years 8 Average concentration 12 CHROMIUM - Emissions to water 28 Other Anaerobic treatment Membrane bioreactor Distillation/rectification Reverse osmosis Chemical reduction Chemical oxidation Flotation Nanofiltration Microfiltration Ultrafiltration Evaporation Adsorption Activated sludge process Nitrification/denitrification Sand filtration Sedimentation Coagulation and flocculation Screening Grit separators Oil separation Neutralisation Equalisation No technique used DE025_w {1} ES058_w {1} SE118_w {1} DE031_w {1} IT094_w {1} FR131_w {1} DE042_w {1} DE045_w {1} DE039_w {1} FR134_w {1} IT059_w {2} DE024_w {1} IT059_w {1} FR136_w {1} IT074_w {2} IT076_w {1} DE030_w {1} FR135_w {1} PT109_w {1} IT065_w {1} DE051_w {1} DE029_w {1} CZ015_w {1} DE023_w {1} SE120_w {1} IT082_w {1} AT006_w {1} IT069_w {1} IT097_w {1} BE009_w {1} IT091_w {1} IT064_w {1} IT074_w {1} UK127_w {1} DE026_w {1} AT003_w {1} DE049_w {1} IT092_w {1} BE007_w {1} IT068_w {1} IT084_w {1} AT005_w {1} DE022_w {1} PT098_w {1} PT115_w {1} AT002_w {1} BE014_w {1} IT082_w {2} IT078_w {1} BE008_w {1} AT001_w {1} PT110_w {2} PT113_w {1} IT087_w {1} IT079_w {1} IT071_w {2} CZ017_w {1} IT067_w {1} PT102_w {1} SE119_w {1} PT104_w {1} PT105_w {1} PT111_w {1} IT061_w {1} PT099_w {1} IT088_w {1} IT073_w {1} IT072_w {1} IT070_w {1} IT071_w {1} IT063_w {1} IT089_w {1} IT085_w {1} IT090_w {1} UK121_w {1} UK124_w {1} Techniques applied Average concentration over 3 years ELV (mg/l ) Max. load over 3 years (g/day) DIR IND IND IND IND DIR IND IND IND DIR IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND DIR IND IND DIR DIR IND IND IND IND IND IND IND DIR DIR IND IND IND IND DIR IND IND DIR IND IND IND IND IND IND IND IND IND IND DIR IND IND IND IND DIR IND IND IND IND IND IND IND IND IND IND IND IND DIR Per Freq Freq Per Per Per Per Freq Per Per Per Per Per Per Per Per Per Freq Per Per Per Per Per Per Freq Per Per Per Per Per Per Per Per Freq Per Per Per Per Freq Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Freq Per Per Per Per Per Per Per Per Per Per Per Per Per Per Freq Per Type of discharge Type of monitoring Mass load expressed in g/day Concentration expressed in mg/l 900 800 700 600 500 400 300 200 100 0 DE025_w {1} ES058_w {1} SE118_w {1} DE031_w {1} IT094_w {1} FR131_w {1} DE042_w {1} DE045_w {1} DE039_w {1} FR134_w {1} IT059_w {2} DE024_w {1} IT059_w {1} FR136_w {1} IT074_w {2} IT076_w {1} DE030_w {1} FR135_w {1} PT109_w {1} IT065_w {1} DE051_w {1} DE029_w {1} CZ015_w {1} DE023_w {1} SE120_w {1} IT082_w {1} AT006_w {1} IT069_w {1} IT097_w {1} BE009_w {1} IT091_w {1} IT064_w {1} IT074_w {1} UK127_w {1} DE026_w {1} AT003_w {1} DE049_w {1} IT092_w {1} BE007_w {1} IT068_w {1} IT084_w {1} AT005_w {1} DE022_w {1} PT098_w {1} PT115_w {1} AT002_w {1} BE014_w {1} IT082_w {2} IT078_w {1} BE008_w {1} AT001_w {1} PT110_w {2} PT113_w {1} IT087_w {1} IT079_w {1} IT071_w {2} CZ017_w {1} IT067_w {1} PT102_w {1} SE119_w {1} PT104_w {1} PT105_w {1} PT111_w {1} IT061_w {1} PT099_w {1} IT088_w {1} IT073_w {1} IT072_w {1} IT070_w {1} IT071_w {1} IT063_w {1} IT089_w {1} IT085_w {1} IT090_w {1} UK121_w {1} UK124_w {1} DE025_w {1} ES058_w {1} SE118_w {1} DE031_w {1} IT094_w {1} FR131_w {1} DE042_w {1} DE045_w {1} DE039_w {1} FR134_w {1} IT059_w {2} DE024_w {1} IT059_w {1} FR136_w {1} IT074_w {2} IT076_w {1} DE030_w {1} FR135_w {1} PT109_w {1} IT065_w {1} DE051_w {1} DE029_w {1} CZ015_w {1} DE023_w {1} SE120_w {1} IT082_w {1} AT006_w {1} IT069_w {1} IT097_w {1} BE009_w {1} IT091_w {1} IT064_w {1} IT074_w {1} UK127_w {1} DE026_w {1} AT003_w {1} DE049_w {1} IT092_w {1} BE007_w {1} IT068_w {1} IT084_w {1} AT005_w {1} DE022_w {1} PT098_w {1} PT115_w {1} AT002_w {1} BE014_w {1} IT082_w {2} IT078_w {1} BE008_w {1} AT001_w {1} PT110_w {2} PT113_w {1} IT087_w {1} IT079_w {1} IT071_w {2} CZ017_w {1} IT067_w {1} PT102_w {1} SE119_w {1} PT104_w {1} PT105_w {1} PT111_w {1} IT061_w {1} PT099_w {1} IT088_w {1} IT073_w {1} IT072_w {1} IT070_w {1} IT071_w {1} IT063_w {1} IT089_w {1} IT085_w {1} IT090_w {1} UK121_w {1} UK124_w {1} 1.0 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0.0 Point of discharge CHROMIUM - Emissions to water (zoom 0-1 mg/l) CHROMIUM - EMISSIONS TO WATER EP water name Type of discharge DIR = Direct DE025_w {1} DIR ES058_w {1} IND SE118_w {1} IND DE031_w {1} IND IT094_w {1} IND FR131_w {1} DIR DE042_w {1} IND DE045_w {1} IND DE039_w {1} IND FR134_w {1} DIR IT059_w {2} IND DE024_w {1} IND IT059_w {1} IND FR136_w {1} IND IT074_w {2} IND IT076_w {1} IND IT077_w {1} IND DE030_w {1} IND FR135_w {1} IND PT109_w {1} IND IT065_w {1} IND DE051_w {1} IND DE029_w {1} IND CZ015_w {1} IND DE023_w {1} IND SE120_w {1} IND IT082_w {1} DIR AT006_w {1} IND IT069_w {1} IND Associated processes Units for concentration values Washing synthetic fibre - Dyeing - Printing mg/l Mercerising - Bleaching - Dyeing - Desizing - Fabric mg/l production - Printing - Thermal treatment Washing synthetic fibre - Scouring - Scouring - Bleaching - Dyeing - Singeing - Printing - Functional finishing - Shrink- mg/l proof finishing - Coating and laminating - Thermal treatment Dyeing mg/l Min. concentration over 3 years Average concentration over 3 years Max. concentration over 3 years Max. load over 3 ELV (mg/l ) years (g/day) 0 0 0 Combination of techniques Type of sampling 0.2 Equalisation, Neutralisation, Coagulation and flocculation, 24-hour flow proportional composite sample Sedimentation, Activated sludge process 0 No information No information 0.0015 0.005 0.0024 0.01 0.0057 0.007 2.0064 0.0001 Sedimentation, Neutralisation No information 24-hour flow proportional composite sample No information No information mg/l 0.001 0.0022 0.008 Other No information Washing synthetic fibre - Bleaching - Dyeing - Printing - Functional finishing - Coating and laminating - Thermal mg/l treatment Washing synthetic fibre - Desizing - Bleaching - Dyeing - mg/l Functional finishing Washing synthetic fibre - Desizing - Desizing mg/l Mercerising - Dyeing - Washing synthetic fibre - mg/l Bleaching - Desizing Washing synthetic fibre - Desizing - Mercerising - mg/l Bleaching - Dyeing - Singeing - Functional finishing Thermal treatment - Functional finishing mg/l Desizing - Dyeing - Scouring - Singeing mg/l Scouring - Mercerising - Bleaching - Dyeing - Singeing - mg/l Dry cleaning Desizing - Scouring - Bleaching - Mercerising - Dyeing - mg/l Singeing - Fabric production - Functional finishing Washing synthetic fibre - Scouring mg/l Raw wool scouring mg/l Desizing - Mercerising - Scouring - Bleaching - Singeing Thermal treatment Washing synthetic fibre - Desizing - Mercerising Bleaching - Singeing - Dyeing - Functional finishing Thermal treatment Washing synthetic fibre No information No unit reported mg/l mg/l mg/l 0 0.005 0.008 0.0025 0.00127 0.01 0.00127 0.006 0.009 0.03 0.01 0.005 0 0.0335 0.0035 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.02 0.03 0.02 0.01 0.0044 0.03 0.009 0.01 0.013 0.013 0.0144 0.02 0.021 0.021 0.028 0.03 0.03 0.031 0.031 0.0335 6.006 6.448 Other 24-hour flow proportional composite sample 0.5 Neutralisation, Equalisation No information Equalisation, Neutralisation 24-hour flow proportional composite sample 24-hour flow proportional composite sample Flow proportional composite sample 0.005 Equalisation, Neutralisation, Grit separators, Activated sludge process, Anaerobic treatment 4 No technique used 0.5 Equalisation 4 Other No information Not applicable Grab/spot sample Not applicable Grit separators, Neutralisation No information 4 Other Other Equalisation, Flotation, Coagulation and flocculation, 2 Activated sludge process, Nitrification/denitrification, Sedimentation, Membrane bioreactor Not applicable 4 No information Other 0.5 Equalisation, Neutralisation, Screening 0 Grit separators Oil separation, Neutralisation 24-hour flow proportional composite sample 24-hour flow proportional composite sample No information No information mg/l 0.012 0.02 0.04 Other No information Washing synthetic fibre - Scouring - Bleaching - Dyeing - mg/l Functional finishing Dyeing mg/l Dyeing - Functional finishing mg/l Washing synthetic fibre - Mercerising - Bleaching - Dyeing mg/l Washing synthetic fibre - Desizing - Bleaching mg/l Dyeing - Singeing - Functional finishing - Thermal mg/l treatment - Wool Fulling Bleaching - Dyeing mg/l Scouring - Bleaching - Mercerising mg/l 0.01 0.01 0.05 0.05 0.05 0.05 0.007 0.04 0.05 0.01 0.03 0.05 0.0071 0.03 0.051 27.6 0 0.03 0.059 0.019 0.018 0.04 0.062 0.03 0.065 0.5 Neutralisation, Coagulation and flocculation, Equalisation No information 0.5 No information Grit separators, Equalisation, Sedimentation Flow proportional composite sample Flow proportional composite sample 0.5 No information No information 0.2 Neutralisation, Oil separation, Equalisation Equalisation, Neutralisation, Activated sludge process, 2 Nitrification/denitrification, Sedimentation, Adsorption (e.g. powdered/granular activated carbon, lignite coke, etc.), Other 1 Flotation 24-hour flow proportional composite sample Not applicable No information 4 Other Other Monitoring frequency Monthly Yearly Monthly Other Twice per year Monthly 4 times per year Twice per year Twice per year 4 times per year Twice per year 4 times per year Twice per year No information No information Other Twice per year 4 times per year Monthly Yearly Twice per year Monthly 4 times per year 4 times per year No information Continuous Yearly Yearly Twice per year IT097_w {1} DIR BE009_w {1} DIR IT091_w {1} IND IT064_w {1} IND IT074_w {1} IND UK127_w {1} IND DE026_w {1} IND AT003_w {1} IND DE049_w {1} IND IT092_w {1} DIR BE007_w {1} DIR IT068_w {1} IND IT084_w {1} IND Dyeing - Shrink-proof finishing - Printing - Other mg/l Printing - Coating and laminating mg/l Scouring - Dyeing - Functional finishing - Thermal mg/l treatment - Other Scouring mg/l Washing synthetic fibre - Scouring - Functional finishing - mg/l Dry cleaning - Other Mercerising - Bleaching - Dyeing - Scouring - Singeing - mg/l Printing Washing synthetic fibre - Desizing - Dyeing - Bleaching mg/l Mercerising - Dyeing - Desizing - Bleaching mg/l Desizing - Bleaching - Bleaching - Dyeing - Singeing - Printing - Coating and laminating - Scouring - Functional mg/l finishing Dyeing - Other mg/l Dyeing mg/l Washing synthetic fibre - Desizing - Scouring - Bleaching - mg/l Dyeing - Functional finishing - Other Bleaching - Dyeing - Thermal treatment mg/l 0.005 0.039 0.02 0.007 0.018 0.00914 0.005 0.01 0.005 0.05 0.011 0.001 0.04 0.07 0.05 0.073 0.03 0.073 0.04 0.078 0.05 0.083 0.03 0.0859 169.570895 0.01 0.09 0.03 0.09 0.03 0.095 0.08 0.1 0.11 0.04 0.116 0.02 0.13 2 Equalisation, Neutralisation, Activated sludge process, Nitrification/denitrification, Sedimentation Not applicable Screening, Sedimentation, Equalisation, Activated sludge process, Sand filtration, Coagulation and flocculation, 0.2 Flotation, Chemical oxidation (incl. Advanced oxidation), Sand filtration, Chemical reduction, Microfiltration, Reverse osmosis Other, 24-hour flow proportional composite sample, Other 4 No information Other 4 Other Other 4 Other Other Twice per year No information No information Twice per year No information 10 Neutralisation 24-hour flow proportional composite sample Weekly 0.5 No information 0.5 Other 0.5 Equalisation, Neutralisation Equalisation, Neutralisation, Activated sludge process, 2 Nitrification/denitrification, Sedimentation, Reverse osmosis Equalisation, Neutralisation, Sand filtration, Activated sludge process, Nitrification/denitrification 4 Other Other Other 24-hour flow proportional composite sample Not applicable Flow proportional composite sample, Not applicable, Flow proportional composite sample Other No information 4 times per year 4 times per year Monthly Monthly Twice per year 2 Equalisation, Neutralisation, Grit separators, Screening, No information Coagulation and flocculation, Sedimentation 4 times per year 29 Monitoring standard Additional information DIN EN ISO 11885 (E22) No information No information Three months average DIN EN ISO 11885DIN EN ISO 11885 APAT CNR IRSA 3020 Volume 1:2003 NF EN ISO 11885 3 times/year - 3 times/year - 3 times/year Concentration under the detection limit of 0,001 mg/l Concentration of mesurement 1 under the detection limit of 0,001 mg/l - Concentration under the detection limit of 0,001 mg/l No information No information No information NF EN ISO 11885 EPA 6020 B 2014 No information EPA 6020 B 2014 No information UNI EN ISO 11885:2009 APAT CNR IRSA 3020 Man 29 2003 UNI EN ISO 11885:2009 DIN No information No information ARPAT CNR IRSA 3010 Man 29 2003 No information No information No information No information No information mesures for water agency for calculate a fee - mesures for water agency for calculate a fee - mesures for water agency for calculate a fee AVERAGE PERIOD 3 HOURS - AVERAGE PERIOD 3 HOURS AVERAGE PERIOD 3 HOURS (YEAR 2015) Monitoring frequency: spotValue refered to sampling period Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours Requested by Italian Law - Requested by Italian Law Requested by Italian Law,and other analyses introduced during 2018 to follow the ZDHC Waste Water Guide lines Quartely IRSA 3020:2003*, IRSA 3020:2003*, IRSA 3010 + 3020* EN ISO 11885 UNI EN ISO 11885:2009 APAT CNR IRSA 3020 Man 29 2003, calculated, calculated Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours (data referring to the year 2015) Value refered to sampling periodMeasurements 1,2 are inferior to detection limit: <0,005 - Value refered to sampling periodMeasurement 1 is inferior to detection limit - Value refered to sampling periodMeasurement 1 is inferior to detection limit WAC/III/BWAC/III/B Less than 12/year flow proportionate sampling, >12/year are grab sample results. Value 0 means results beneath detection limit of analyses UNI EN ISO 11885:2009 UNI EN ISO 11885:2009 UNI EN ISO 11885:2009 No information AVERAGE PERIOD 3 HOURS - AVERAGE PERIOD 3 HOURS AVERAGE PERIOD 3 HOURS Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours AVERAGE PERIOD 3 HOURS - AVERAGE PERIOD 3 HOURS AVERAGE PERIOD 3 HOURS (YEAR 2015) Toxic metals in excess of 10000ug/l either individually or in total - Toxic metals in excess of 10000ug/l either individually or in total - Toxic metals in excess of 10000ug/l either individually or in total DIN DIN EN ISO 11885DIN EN ISO 11885 DIN IRSA 3010 + 3030, EPA 3005A 1992 + EPA 6010D 2014, EPA 3005A 1992 + EPA 6010D 2014 Value refered to sampling period - Value refered to sampling period - Value refered to sampling period WAC/III/B011 of WAC/III/B010- WAC/III/B002 UNI EN ISO 11885:2009 EPA 6020 B 2014 Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours (data referring to the year 2015) 3 h medium composite sample - 3 h medium composite sample - 3 h medium composite sample 1 CHROMIUM - EMISSIONS TO WATER EP water name AT005_w {1} Type of discharge DIR = Direct IND DE022_w {1} IND Associated processes No information Raw wool scouring - Washing synthetic fibre - Desizing Scouring - Bleaching - Dyeing - Thermal treatment Functional finishing - Coating and laminating Units for concentration values mg/l mg/l Min. concentration over 3 years Average concentration over 3 years Max. concentration over 3 years Max. load over 3 ELV (mg/l ) years (g/day) 0.01 0.04 0.14 Combination of techniques 0.5 Neutralisation 0.01 0.02 0.15 0.5 Neutralisation, Oil separation, Evaporation Type of sampling No information Other PT098_w {1} DIR PT115_w {1} IND AT002_w {1} IND BE014_w {1} DIR IT082_w {2} IND IT078_w {1} IND BE008_w {1} IND AT001_w {1} IND PT110_w {2} IND PT113_w {1} IND IT087_w {1} IND IT079_w {1} IND IT071_w {2} IND CZ017_w {1} IND IT067_w {1} DIR PT102_w {1} IND SE119_w {1} IND PT104_w {1} IND PT105_w {1} IND PT111_w {1} DIR IT061_w {1} IND PT099_w {1} IND IT077_w {2} IND IT088_w {1} IND IT073_w {1} IND IT072_w {1} IND IT070_w {1} IND IT071_w {1} IND IT063_w {1} IND IT089_w {1} IND IT085_w {1} IND IT090_w {1} IND UK121_w {1} IND UK124_w {1} DIR UK126_w {1} IND Wool Fulling - Functional finishing - Dyeing - Thermal mg/l treatment No information mg/l No information mg/l Bleaching - Dyeing - Functional finishing mg/l Dyeing - Singeing - Functional finishing - Thermal mg/l treatment - Wool Fulling Wool Fulling - Washing synthetic fibre - Dyeing mg/l Printing - Dyeing mg/l No information mg/l Dyeing mg/l Dyeing - Washing synthetic fibre - Bleaching - Functional mg/l finishing Dyeing - Shrink-proof finishing - Shrink-proof finishing - mg/l Other Scouring - Wool Fulling - Functional finishing - Thermal mg/l treatment - Other Dyeing - Other - Functional finishing mg/l Spinning - Fabric production - Singeing - Functional finishing - Shrink-proof finishing - Thermal treatment - mg/l Other Dyeing - Printing - Other - Shrink-proof finishing mg/l Scouring - Dyeing - Bleaching mg/l Washing synthetic fibre - Desizing - Functional finishing - mg/l Dyeing Dyeing - Bleaching mg/l Dyeing - Bleaching mg/l Desizing - Dyeing - Fabric production - Wool Fulling Functional finishing - Shrink-proof finishing - Dry cleaning -mg/l Thermal treatment Scouring - Wool Carbonising mg/l Dyeing - Printing - Functional finishing Dyeing Dyeing - Bleaching Dyeing - Functional finishing Thermal treatment - Scouring - Bleaching - Dyeing Other No information Dyeing - Bleaching - Scouring Dyeing - Fabric production - Dry cleaning - Printing Printing - Functional finishing mg/l No unit reported mg/l mg/l mg/l mg/l mg/l mg/l Scouring - Dyeing - Thermal treatment - Other - mg/l Bleaching Dyeing mg/l Scouring - Dyeing - Thermal treatment - Other Bleaching Dyeing No information Dyeing mg/l mg/l mg/l other (please specify in the column "additional information") 0.028 0.0239 0.019 0.017 0.019 0.046 0.061 0.029 0.01 0.2 0.25 0.07 0.024 0.126 0.03 0.0084 0.152 0.002 0.5 0.077 0.015 0.08 0.03 0.02 0.025 0.09 0.01 0.028 0.16 0.11 0.42 0.063 0.036 0.5 4.5 0.08 0.08 0.07 0.06 0.09 0.12 0.10 0.11 0.17 0.20 0.25 0.13 0.18 0.22 0.08 0.33 0.27 0.33 0.50 0.36 0.16 0.24 0.19 0.16 0.24 0.35 0.31 0.49 0.54 0.73 1.11 1.16 1.51 2.62 261.80 0.15 0.15 0.15 0.152 0.17 0.18 0.19 0.19 0.2 0.2 0.25 0.26 0.27 0.303 0.33 0.4 0.474 0.5 0.5 0.5 0.51 0.57 0.57 0.6 0.67 0.69 0.9 1.2 1.22 1.58 1.8 2.185 3.9 8.2 3140 76.612 772.2 Equalisation, Neutralisation, Sedimentation, Sand filtration, Activated sludge process, Other No information Equalisation, Neutralisation, Screening 0.5 No information 0.5 Equalisation, Activated sludge process, Nitrification/denitrification No information 4 Other 0.5 Equalisation, Grit separators, Other No information 2 Equalisation, Grit separators, Screening No information 4 Equalisation 24-hour flow proportional composite sample No information 24-hour flow proportional composite sample No information Other 24-hour flow proportional composite sample 24-hour flow proportional composite sample No information Other Not applicable, Grab/spot sample, Not applicable 4 Other 24-hour flow proportional composite sample 4 Other Other No information 2 Equalisation, Neutralisation, Activated sludge process, Nitrification/denitrification, Sedimentation No information Not applicable Other 24-hour flow proportional composite sample No technique used No information No information 24-hour flow proportional composite sample 24-hour flow proportional composite sample No information 2 Equalisation, Neutralisation, Activated sludge process, Sedimentation, Sand filtration, Other No information 0.2 Other Screening, Oil separation, Other 4 No information 4 No information 4 No technique used 4 Other 4 No information 4 No information 4 Equalisation Other No information Other Not applicable Other Other Not applicable Other Other 4 Other 24-hour flow proportional composite sample Equalisation Not applicable 4 Other 24-hour flow proportional composite sample 5 Equalisation Neutralisation, Coagulation and flocculation, Flotation, Other 24-hour flow proportional composite sample Other No information Flow proportional composite sample Monitoring frequency Monthly Monthly Yearly Yearly Yearly No information Other Twice per year No information No information Twice per year Yearly Other Twice per year Twice per year Yearly Monthly Twice per year No information Yearly Yearly Yearly Twice per year 4 times per year Twice per year Twice per year Twice per year Twice per year Twice per year Twice per year 4 times per year Twice per year Other Twice per year Monthly Twice per year No information Monitoring standard DIN EN ISO 11885DIN EN ISO 11885 Additional information DIN There is only VLE for total metals ( As, Cd, Pb, Cu, Cr, Zn, Hg and Ni) - VLE 5mg/l - MESU. 1 - 0,052 mg/l ; There is DIN EN ISO 11885 (E22), DIN EN ISO 17294-2(E29), DIN EN only VLE for total metals ( As, Cd, Pb, Cu, Cr, Zn, Hg and ISO 11885 (E22) Ni) - VLE 5mg/l - MESU. 1 - 0,028 mg/l ; There is only VLE for total metals ( As, Cd, Pb, Cu, Cr, Zn, Hg and Ni) - VLE 5mg/l PA 45, PA 45, W- METAXDG1 < LQ; LD= 0,08SIDVA - < LQ; LD= 0,15SIDVA - SIDVA DIN EN ISO 11885DIN EN ISO 11885 WAC/III/B011 of WAC/III/B010- WAC/III/B002 3 measurements < DL 0,01 mg/l APAT IRSA -CNR 3010/A + 3020Man 29 2003 UNI EN ISO 11885:2009 WAC/III/B011 of WAC/III/B010- WAC/III/B002 EN ISO 11885 No information No information No information Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours Self Control and taxation waste water - Self Control and taxation waste water - Self Control and taxation waste water control measurement local authority detection limit: 0,2 mg/L - detection limit: 0,2 mg/L detection limit: 0,2 mg/L Monitoring frequency: spot UNI EN ISO 11885:2009 UNI EN ISO 11885:2009 ELV is referred to 3 hours sampled waste water - ELV is referred to 3 hours sampled waste water - ELV is referred to 3 hours sampled waste water. Data related to 2015. Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours No information APAT CNR IRSA 3010 Man 29 2003 IT-DLQ-42/V03;SMEWW3111 B, 21ed No information compound sampling No information Value refered to sampling period - Value refered to sampling period - Value refered to sampling period In these monitoring the value is below level of quantification - For the second monitoring the value is below level of quantification - In these monitoring the value is below level of quantification The installation only started operating in 2017.Measurement value : < 0.5 mg/L (below level of quantification). The value of uncertainty is not refered in the reports. W-METAXDG1 UNI EN ISO 11885:2009 DIN EN ISO 11885/ICP-OES UNI EN ISO 11885:2009 EPA 6010 C 2007 UNI EN ISO 11885:2009 UNI EN ISO 11885:2009 EPA 6010 C 2007 UNI EN ISO 11885:2009 No information UNI EN ISO 11885:2009 No information UNI EN ISO 11885:2009 BS 6068 Section 2.6 ICPMS Routine- acid digested; determined by ICPMS AVERAGE PERIOD 3 HOURS - AVERAGE PERIOD 3 HOURS Averaging period for ELV: 3 hours; YEAR 2015 Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours Yearly - Yearly - Yearly Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours ELV is referred to 3 hours sampled waste water. Cr was quantified as Cr VI - ELV is referred to 3 hours sampled waste water. Cr was quantified as Cr VI - ELV is referred to 3 hours sampled waste water. Cr was quantified as CrVI. Data related to 2015. Monitoring end frequency dependent on the operator of the off-site treatment plant ELV is referred to 3 hours sampled waste water. Cr was quantified as Cr VI - ELV is referred to 3 hours sampled waste water. Cr was quantified as Cr VI - ELV is referred to 3 hours sampled waste water. Cr was quantified as CrVI. Data related to 2015. No information The unit measurement is in microgrammes/litre - The unit measurement is in microgrammes/litre - The unit measurement is in microgrammes/litre 30 2 31 Other Anaerobic treatment Membrane bioreactor Distillation/rectification Reverse osmosis Chemical reduction Chemical oxidation Flotation Nanofiltration Microfiltration Ultrafiltration Evaporation Adsorption Activated sludge process Nitrification/denitrification Sand filtration Sedimentation Coagulation and flocculation Screening Grit separators Oil separation Neutralisation Equalisation No technique used FR131_w {1} PT098_w {1} IT059_w {1} IT067_w {1} IT076_w {1} IT084_w {1} DE034_w {1} BE014_w {1} IT059_w {2} IT091_w {1} DE031_w {1} DE042_w {1} DE025_w {1} DE045_w {1} SE120_w {1} SE119_w {1} IT073_w {1} IT082_w {2} AT005_w {1} IT074_w {1} IT074_w {2} DE026_w {1} BE011_w {1} IT078_w {1} IT065_w {1} DE039_w {1} AT002_w {1} BE008_w {1} FR135_w {1} DE051_w {1} IT079_w {1} BE009_w {1} IT071_w {2} DE049_w {1} DE024_w {1} DE030_w {1} DE032_w {1} ES058_w {1} IT061_w {1} DE029_w {1} AT003_w {1} IT097_w {1} IT087_w {1} AT001_w {1} PT109_w {1} IT070_w {1} IT088_w {1} PT110_w {2} PT099_w {1} IT063_w {1} PT113_w {1} PT115_w {1} FR134_w {1} PT102_w {1} PT105_w {1} BE007_w {1} PT111_w {1} UK127_w {1} IT092_w {1} IT071_w {1} UK124_w {1} Techniques applied Max. load over 3 years (g/day) DIR DIR IND DIR IND IND DIR DIR IND IND IND IND DIR IND IND IND IND IND IND IND IND IND DIR IND IND IND IND IND IND IND IND DIR IND IND IND IND DIR IND IND IND IND DIR IND IND IND IND IND IND IND IND IND IND DIR IND IND DIR DIR IND DIR IND DIR Per Per Per Per Per Per Per Per Per Per Per Per Per Freq Freq Freq Per Per Per Per Per Per Per Per Per Per Per Per Freq Per Per Per Per Per Per Per Per Freq Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Freq Per Freq Per Per Per Type of discharge Type of monitoring Mass load expressed in g/day Concentration expressed in mg/l 2,000 1,800 1,600 1,400 1,200 1,000 800 600 400 200 0 10 6 4 2 FR131_w {1} PT098_w {1} IT059_w {1} IT067_w {1} IT076_w {1} IT084_w {1} DE034_w {1} BE014_w {1} IT059_w {2} IT091_w {1} DE031_w {1} DE042_w {1} DE025_w {1} DE045_w {1} SE120_w {1} SE119_w {1} IT073_w {1} IT082_w {2} AT005_w {1} IT074_w {1} IT074_w {2} DE026_w {1} BE011_w {1} IT078_w {1} IT065_w {1} DE039_w {1} AT002_w {1} BE008_w {1} FR135_w {1} DE051_w {1} IT079_w {1} BE009_w {1} IT071_w {2} DE049_w {1} DE024_w {1} DE030_w {1} DE032_w {1} ES058_w {1} IT061_w {1} DE029_w {1} AT003_w {1} IT097_w {1} IT087_w {1} AT001_w {1} PT109_w {1} IT070_w {1} IT088_w {1} PT110_w {2} PT099_w {1} IT063_w {1} PT113_w {1} PT115_w {1} FR134_w {1} PT102_w {1} PT105_w {1} BE007_w {1} PT111_w {1} UK127_w {1} IT092_w {1} IT071_w {1} UK124_w {1} FR131_w {1} PT098_w {1} IT059_w {1} IT067_w {1} IT076_w {1} IT084_w {1} DE034_w {1} BE014_w {1} IT059_w {2} IT091_w {1} DE031_w {1} DE042_w {1} DE025_w {1} DE045_w {1} SE120_w {1} SE119_w {1} IT073_w {1} IT082_w {2} AT005_w {1} IT074_w {1} IT074_w {2} DE026_w {1} BE011_w {1} IT078_w {1} IT065_w {1} DE039_w {1} AT002_w {1} BE008_w {1} FR135_w {1} DE051_w {1} IT079_w {1} BE009_w {1} IT071_w {2} DE049_w {1} DE024_w {1} DE030_w {1} DE032_w {1} ES058_w {1} IT061_w {1} DE029_w {1} AT003_w {1} IT097_w {1} IT087_w {1} AT001_w {1} PT109_w {1} IT070_w {1} IT088_w {1} PT110_w {2} PT099_w {1} IT063_w {1} PT113_w {1} PT115_w {1} FR134_w {1} PT102_w {1} PT105_w {1} BE007_w {1} PT111_w {1} UK127_w {1} IT092_w {1} IT071_w {1} UK124_w {1} 0 Point of discharge ELV (mg/l ) over 3 years 8 Average concentration 12 NICKEL - Emissions to water 32 Other Anaerobic treatment Membrane bioreactor Distillation/rectification Reverse osmosis Chemical reduction Chemical oxidation Flotation Nanofiltration Microfiltration Ultrafiltration Evaporation Adsorption Activated sludge process Nitrification/denitrification Sand filtration Sedimentation Coagulation and flocculation Screening Grit separators Oil separation Neutralisation Equalisation No technique used FR131_w {1} PT098_w {1} IT059_w {1} IT067_w {1} IT076_w {1} IT084_w {1} DE034_w {1} BE014_w {1} IT059_w {2} IT091_w {1} DE031_w {1} DE042_w {1} DE025_w {1} DE045_w {1} SE120_w {1} SE119_w {1} IT073_w {1} IT082_w {2} AT005_w {1} IT074_w {1} IT074_w {2} DE026_w {1} BE011_w {1} IT078_w {1} IT065_w {1} DE039_w {1} AT002_w {1} BE008_w {1} FR135_w {1} DE051_w {1} IT079_w {1} BE009_w {1} IT071_w {2} DE049_w {1} DE024_w {1} DE030_w {1} DE032_w {1} ES058_w {1} IT061_w {1} DE029_w {1} AT003_w {1} IT097_w {1} IT087_w {1} AT001_w {1} PT109_w {1} IT070_w {1} IT088_w {1} PT110_w {2} PT099_w {1} IT063_w {1} PT113_w {1} PT115_w {1} FR134_w {1} PT102_w {1} PT105_w {1} BE007_w {1} PT111_w {1} UK127_w {1} IT092_w {1} IT071_w {1} UK124_w {1} Techniques applied Average concentration over 3 years ELV (mg/l ) Max. load over 3 years (g/day) DIR DIR IND DIR IND IND DIR DIR IND IND IND IND DIR IND IND IND IND IND IND IND IND IND DIR IND IND IND IND IND IND IND IND DIR IND IND IND IND DIR IND IND IND IND DIR IND IND IND IND IND IND IND IND IND IND DIR IND IND DIR DIR IND DIR IND DIR Per Per Per Per Per Per Per Per Per Per Per Per Per Freq Freq Freq Per Per Per Per Per Per Per Per Per Per Per Per Freq Per Per Per Per Per Per Per Per Freq Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Freq Per Freq Per Per Per Type of discharge Type of monitoring Mass load expressed in g/day Concentration expressed in mg/l 2,000 1,800 1,600 1,400 1,200 1,000 800 600 400 200 0 FR131_w {1} PT098_w {1} IT059_w {1} IT067_w {1} IT076_w {1} IT084_w {1} DE034_w {1} BE014_w {1} IT059_w {2} IT091_w {1} DE031_w {1} DE042_w {1} DE025_w {1} DE045_w {1} SE120_w {1} SE119_w {1} IT073_w {1} IT082_w {2} AT005_w {1} IT074_w {1} IT074_w {2} DE026_w {1} BE011_w {1} IT078_w {1} IT065_w {1} DE039_w {1} AT002_w {1} BE008_w {1} FR135_w {1} DE051_w {1} IT079_w {1} BE009_w {1} IT071_w {2} DE049_w {1} DE024_w {1} DE030_w {1} DE032_w {1} ES058_w {1} IT061_w {1} DE029_w {1} AT003_w {1} IT097_w {1} IT087_w {1} AT001_w {1} PT109_w {1} IT070_w {1} IT088_w {1} PT110_w {2} PT099_w {1} IT063_w {1} PT113_w {1} PT115_w {1} FR134_w {1} PT102_w {1} PT105_w {1} BE007_w {1} PT111_w {1} UK127_w {1} IT092_w {1} IT071_w {1} UK124_w {1} FR131_w {1} PT098_w {1} IT059_w {1} IT067_w {1} IT076_w {1} IT084_w {1} DE034_w {1} BE014_w {1} IT059_w {2} IT091_w {1} DE031_w {1} DE042_w {1} DE025_w {1} DE045_w {1} SE120_w {1} SE119_w {1} IT073_w {1} IT082_w {2} AT005_w {1} IT074_w {1} IT074_w {2} DE026_w {1} BE011_w {1} IT078_w {1} IT065_w {1} DE039_w {1} AT002_w {1} BE008_w {1} FR135_w {1} DE051_w {1} IT079_w {1} BE009_w {1} IT071_w {2} DE049_w {1} DE024_w {1} DE030_w {1} DE032_w {1} ES058_w {1} IT061_w {1} DE029_w {1} AT003_w {1} IT097_w {1} IT087_w {1} AT001_w {1} PT109_w {1} IT070_w {1} IT088_w {1} PT110_w {2} PT099_w {1} IT063_w {1} PT113_w {1} PT115_w {1} FR134_w {1} PT102_w {1} PT105_w {1} BE007_w {1} PT111_w {1} UK127_w {1} IT092_w {1} IT071_w {1} UK124_w {1} 0.10 0.09 0.08 0.07 0.06 0.05 0.04 0.03 0.02 0.01 0.00 Point of discharge NICKEL - Emissions to water (zoom 0-0.1 mg/l) NICKEL - EMISSIONS TO WATER EP water name Type of discharge DIR = Direct FR131_w {1} DIR Associated processes Washing synthetic fibre - Bleaching - Dyeing - Printing Functional finishing - Coating and laminating - Thermal treatment Units for concentration values mg/l Min. concentration over 3 years Average concentration over 3 years Max. concentration over 3 years Max. load over 3 ELV (mg/l ) years (g/day) 0 0 0 Combination of techniques Other Type of sampling 24-hour flow proportional composite sample PT098_w {1} DIR Wool Fulling - Functional finishing - Dyeing - Thermal mg/l treatment 0.0003 0.0014 0.0032 Equalisation, Neutralisation, Sedimentation, Sand filtration, Activated sludge process, Other No information IT059_w {1} IND IT067_w {1} DIR IT076_w {1} IND IT084_w {1} IND Scouring - Mercerising - Bleaching - Dyeing - Singeing - mg/l Dry cleaning Dyeing - Printing - Other - Shrink-proof finishing mg/l Raw wool scouring mg/l Bleaching - Dyeing - Thermal treatment mg/l 0.00089 0.005 0.005 0.005 0.0027 0.01 0.01 0.01 0.00442 0.005 0.005 0.005 4 Other 2 Equalisation, Neutralisation, Activated sludge process, Nitrification/denitrification, Sedimentation Equalisation, Flotation, Coagulation and flocculation, 2 Activated sludge process, Nitrification/denitrification, Sedimentation, Membrane bioreactor Not applicable Not applicable Not applicable 2 Equalisation, Neutralisation, Grit separators, Screening, No information Coagulation and flocculation, Sedimentation Monitoring frequency Monthly Yearly Twice per year Other Other 4 times per year DE034_w {1} DIR BE014_w {1} DIR IT059_w {2} IND IT091_w {1} IND DE031_w {1} IND DE042_w {1} IND DE025_w {1} DIR DE045_w {1} IND SE120_w {1} IND SE119_w {1} IND IT073_w {1} IND IT082_w {2} IND AT005_w {1} IND IT074_w {1} IND IT074_w {2} IND DE026_w {1} IND BE011_w {1} DIR IT078_w {1} IND IT065_w {1} IND DE039_w {1} IND AT002_w {1} IND BE008_w {1} IND FR135_w {1} IND DE051_w {1} IND IT079_w {1} IND BE009_w {1} DIR IT071_w {2} IND DE049_w {1} IND DE024_w {1} IND DE030_w {1} IND DE032_w {1} DIR ES058_w {1} IND IT061_w {1} IND DE029_w {1} IND AT003_w {1} IND Washing synthetic fibre - Desizing - Bleaching - Dyeing mg/l Bleaching - Dyeing - Functional finishing mg/l Thermal treatment - Functional finishing mg/l Scouring - Dyeing - Functional finishing - Thermal mg/l treatment - Other Dyeing mg/l Washing synthetic fibre - Desizing - Bleaching - Dyeing - mg/l Functional finishing Washing synthetic fibre - Dyeing - Printing mg/l Washing synthetic fibre - Desizing - Desizing mg/l Washing synthetic fibre - Desizing - Bleaching mg/l Washing synthetic fibre - Desizing - Functional finishing - mg/l Dyeing Dyeing - Functional finishing mg/l Dyeing - Singeing - Functional finishing - Thermal mg/l treatment - Wool Fulling No information mg/l Washing synthetic fibre - Scouring - Functional finishing - mg/l Dry cleaning - Other Washing synthetic fibre - Scouring mg/l Washing synthetic fibre - Desizing - Dyeing - Bleaching mg/l Dyeing mg/l Wool Fulling - Washing synthetic fibre - Dyeing mg/l No information mg/l Mercerising - Dyeing - Washing synthetic fibre - mg/l Bleaching - Desizing No information mg/l Printing - Dyeing mg/l Washing synthetic fibre mg/l Washing synthetic fibre - Scouring - Bleaching - Dyeing - mg/l Functional finishing Scouring - Wool Fulling - Functional finishing - Thermal mg/l treatment - Other Printing - Coating and laminating mg/l Dyeing - Other - Functional finishing mg/l Desizing - Bleaching - Bleaching - Dyeing - Singeing - Printing - Coating and laminating - Scouring - Functional mg/l finishing Desizing - Dyeing - Scouring - Singeing mg/l Washing synthetic fibre - Desizing - Mercerising - Bleaching - Singeing - Dyeing - Functional finishing - mg/l Thermal treatment Washing synthetic fibre - Desizing - Bleaching - Dyeing - mg/l Printing Mercerising - Bleaching - Dyeing - Desizing - Fabric mg/l production - Printing - Thermal treatment Scouring - Wool Carbonising mg/l Dyeing mg/l Mercerising - Dyeing - Desizing - Bleaching mg/l 0.005 0.0056 0.0032 0.004 0.01 0.005 0 0 0.01 0.01 0.004 0.005 0.005 0.01 0.004 0.0112 0.012 0 0 0 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.0003 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.0009 0.01 0.01 0.01 0.01 0.006 0.0064 0.0089 0.009 0.01 0.01 0.01 0.01 0.01 0.01 0.011 0.011 0.012 0.012 0.012 0.0129 0.013 0.013 0.015 0.016 0.02 0.02 0 0 0.005 0.01 0.005 0.005 0.005 0.02 0 0.01 0.02 0.01 0.02 0.01 0.024 0.01 0.03 0.01 0.032 0.02 0.033 0.03 0.02 0.035 0.02 0.04 0.02 0.05 3.088 0.05 Activated sludge process, Nitrification/denitrification Flow proportional composite sample Yearly 0.5 Equalisation, Activated sludge process, Nitrification/denitrification 4 No technique used 4 No information No information 0.5 Neutralisation, Equalisation 24-hour flow proportional composite sample Not applicable Other No information 24-hour flow proportional composite sample 0.2 Equalisation, Neutralisation, Coagulation and flocculation, 24-hour flow proportional composite sample Sedimentation, Activated sludge process No information Neutralisation, Oil separation, Equalisation 24-hour flow proportional composite sample 24-hour flow proportional composite sample No technique used 24-hour flow proportional composite sample 4 No technique used Other No information No information 0.5 Neutralisation No information 4 Other Other 4 Other Other 0.5 No information Other Equalisation, Neutralisation, Coagulation and flocculation, 0.1 Activated sludge process, Nitrification/denitrification, Sand filtration, Nanofiltration, Chemical oxidation (incl. 24-hour flow proportional composite sample Advanced oxidation) 4 Other Other Other No information Equalisation, Neutralisation Flow proportional composite sample 0.5 No information 0.5 Equalisation, Grit separators, Other Grit separators No information 24-hour flow proportional composite sample 24-hour flow proportional composite sample 0.5 Neutralisation, Coagulation and flocculation, Equalisation No information No information Twice per year No information Other 4 times per year Monthly Twice per year No information No information Twice per year Other Monthly No information No information No information No information Twice per year Twice per year Twice per year Yearly No information Monthly Monthly 4 Other 24-hour flow proportional composite sample Screening, Sedimentation, Equalisation, Activated sludge process, Sand filtration, Coagulation and flocculation, 0.2 Flotation, Chemical oxidation (incl. Advanced oxidation), Sand filtration, Chemical reduction, Microfiltration, Reverse osmosis Other, 24-hour flow proportional composite sample, Other 4 Other Other 0.5 Equalisation, Neutralisation 0.5 Equalisation 0.5 Equalisation, Neutralisation, Screening 24-hour flow proportional composite sample Grab/spot sample 24-hour flow proportional composite sample Equalisation, Neutralisation, Grit separators, Coagulation and flocculation, Sedimentation, Sand filtration, 24-hour flow proportional composite sample Nitrification/denitrification, Activated sludge process No information No information 4 Other 0.5 No information 0.5 Other Other Flow proportional composite sample Other Twice per year No information Twice per year 4 times per year 4 times per year 4 times per year Twice per year Yearly Twice per year 4 times per year 4 times per year 33 Monitoring standard Additional information NF EN ISO 11885 detection limit of the lab 5g/L MESU. 1 - 0,0032 mg/l ; There is only VLE for total metals ( As, Cd, Pb, Cu, Cr, Zn, Hg and Ni) - VLE 5mg/l - MESU. 1 - DIN EN ISO 11885 (E22), DIN EN ISO 17294-2(E29), DIN EN <0,0010 mg/l ; There is only VLE for total metals ( As, Cd, ISO 11885 (E22) Pb, Cu, Cr, Zn, Hg and Ni) - VLE 5mg/l ; < LD - MESU. 1 - <0,0020 mg/l ; There is only VLE for total metals ( As, Cd, Pb, Cu, Cr, Zn, Hg and Ni) - VLE 5mg/l ; < LD EPA 6020 B 2014 APAT CNR IRSA 3020 Man 29 2003 APAT CNR IRSA 3020 Man 29 2003 Monitoring frequency: spotValue refered to sampling period Monitoring frequency: spotMeasurement is inferior to detection limit: <0,005 mg/lValue refered to sampling period EPA 6020 B 2014 No information WAC/III/B011 of WAC/III/B010- WAC/III/B002 EPA 6020 B 2014 UNI EN ISO 11885:2009 DIN EN ISO 11885DIN EN ISO 11885 No information 3 h medium composite sample - 3 h medium composite sample - 3 h medium composite sample under mesurement 2 and following,.. you find the measured values from the authority surveillance - under mesurement 2 and following,.. you find the measured values from the authority surveillance - under mesurement 2 and following,.. you find the measured values from the authority surveillance 6 measurements < DL (0,01 mg/l) - 3 measurements < DL (0,01 mg/l) - 3 measurements < DL (0,01 mg/l) AVERAGE PERIOD 3 HOURS - AVERAGE PERIOD 3 HOURS AVERAGE PERIOD 3 HOURS 3 times/year - 3 times/year - 3 times/year DIN EN ISO 11885 (E22) No information No information No information UNI EN ISO 11885:2009 APAT IRSA -CNR 3010/A + 3020Man 29 2003 DIN EN ISO 11885DIN EN ISO 11885 UNI EN ISO 11885:2009 UNI EN ISO 11885:2009 DIN AVERAGE PERIOD 3 HOURS - AVERAGE PERIOD 3 HOURS AVERAGE PERIOD 3 HOURS (YEAR 2015) AVERAGE PERIOD 3 HOURS - AVERAGE PERIOD 3 HOURS AVERAGE PERIOD 3 HOURS (YEAR 2015) WAC/III/B011 of WAC/III/B010- WAC/III/B002 UNI EN ISO 11885:2009 EPA 6020B :2014 EPA 200,8 rev.5,4 No information DIN EN ISO 11885DIN EN ISO 11885 WAC/III/B011 of WAC/III/B010- WAC/III/B002 No information No information UNI EN ISO 11885:2009 WAC/III/BWAC/III/B UNI EN ISO 11885:2009 DIN No information DIN 5 measurements < DL (0,01 mg/l)2 measurements < DL (0,009 mg/l) Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours analyses introduced during 2018 to follow the ZDHC Waste Water Guide lines ELV is referred to 3 hours sampled waste water - ELV is referred to 3 hours sampled waste water - ELV is referred to 3 hours sampled waste water. Data related to 2015. Less than 12/year flow proportionate sampling, >12/year are grab sample results. Value 0 means results beneath detection limit of analyses Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours No information No information UNI EN ISO 11885:2009 No information DIN EN ISO 11885DIN EN ISO 11885 AVERAGE PERIOD 3 HOURS - AVERAGE PERIOD 3 HOURS Averaging period for ELV: 3 hours; YEAR 2015 1 EP water name Type of discharge DIR = Direct Associated processes NICKEL - EMISSIONS TO WATER Units for concentration values Min. concentration over 3 years Average concentration over 3 years Max. concentration over 3 years Max. load over 3 ELV (mg/l ) years (g/day) Combination of techniques Type of sampling IT097_w {1} DIR Dyeing - Shrink-proof finishing - Printing - Other mg/l 0.005 0.04 0.05 2 Equalisation, Neutralisation, Activated sludge process, Nitrification/denitrification, Sedimentation Not applicable IT087_w {1} IND AT001_w {1} IND PT109_w {1} IND IT070_w {1} IND IT088_w {1} IND PT110_w {2} IND PT099_w {1} IND IT063_w {1} IND PT113_w {1} IND PT115_w {1} IND FR134_w {1} DIR PT102_w {1} IND Dyeing - Shrink-proof finishing - Shrink-proof finishing - mg/l Other No information mg/l No information mg/l No information mg/l Dyeing - Bleaching mg/l Dyeing mg/l Dyeing - Printing - Functional finishing mg/l Dyeing - Fabric production - Dry cleaning - Printing - mg/l Printing - Functional finishing Dyeing - Washing synthetic fibre - Bleaching - Functional mg/l finishing No information mg/l Washing synthetic fibre - Desizing - Mercerising - mg/l Bleaching - Dyeing - Singeing - Functional finishing Scouring - Dyeing - Bleaching mg/l 0.053 0 0.0654 0.01 0.01 0.01 0.005 0.02 0.1 0.005 0.002 0.002 0.05 0.0048 0.07 0.04 0.03 0.07 0.07 0.04 0.10 0.07 0.03 0.17 0.053 0.062 0.0654 0.07 0.07 0.1 0.1 0.1 0.1 0.15 0.19 0.2 93.67 0.3 Equalisation Not applicable, Grab/spot sample, Not applicable 0.5 No information 2 Oil separation, Neutralisation 4 No information 4 No information 2 Equalisation, Grit separators, Screening 2 Screening, Oil separation, Other 24-hour flow proportional composite sample No information Not applicable Not applicable No information No information 4 Equalisation Other 2 No information Other 2 Equalisation, Neutralisation, Screening 24-hour flow proportional composite sample 0.01 Equalisation, Neutralisation, Grit separators, Activated sludge process, Anaerobic treatment No information 2 Other 24-hour flow proportional composite sample Monitoring frequency Twice per year Other 4 times per year Yearly Twice per year Twice per year Twice per year 4 times per year 4 times per year Yearly Yearly 4 times per year Twice per year PT105_w {1} IND BE007_w {1} DIR PT111_w {1} DIR UK127_w {1} IND IT092_w {1} DIR IT071_w {1} IND UK124_w {1} DIR UK126_w {1} IND Dyeing - Bleaching mg/l Dyeing mg/l Desizing - Dyeing - Fabric production - Wool Fulling Functional finishing - Shrink-proof finishing - Dry cleaning -mg/l Thermal treatment Mercerising - Bleaching - Dyeing - Scouring - Singeing - mg/l Printing Dyeing - Other Dyeing - Bleaching - Scouring No information Dyeing mg/l mg/l mg/l other (please specify in the column "additional information") 0.3 0.005 0.00914 0.05 0.004 1.74 5.61 0.30 0.49 0.34 0.05 0.11 0.35 3.18 30.90 0.3 0.5 0.917 1823.60122 1 2 5.62 352 No information No information Yearly Equalisation, Neutralisation, Sand filtration, Activated sludge process, Nitrification/denitrification 2 Equalisation, Neutralisation, Activated sludge process, Sedimentation, Sand filtration, Other Flow proportional composite sample, Not applicable, Flow proportional composite sample No information Monthly Yearly 10 Neutralisation 24-hour flow proportional composite sample Equalisation, Neutralisation, Activated sludge process, 2 Nitrification/denitrification, Sedimentation, Reverse osmosis 4 No information Neutralisation, Coagulation and flocculation, Flotation, Other Not applicable Other Other No information Flow proportional composite sample Weekly Monthly Twice per year Twice per year No information Monitoring standard Additional information APAT CNR IRSA 3020 Man 29 2003, UNI EN ISO 155871:2002+UNI EN ISO 11885:2009, UNI EN ISO 11885:2009 Measurements 1 is inferior to detection limit: <0,005Measurements 3 is inferior to detection limit: <0,005Value refered to sampling period - Measurements 1,3 are inferior to detection limit: <0,05Value refered to sampling period - Measurement 1,3 are inferior to detection limit: <0,05Value refered to sampling period No information Monitoring frequency: spot DIN EN ISO 11885DIN EN ISO 11885 No information EPA 6010 C 2007 EPA 6010 C 2007 No information DIN EN ISO 11885/ICP-OES No information No information SMEWW 3030 K/SMEWW 3111 B, SMEWW 3030 K/SMEWW 3111 B, W- METAXDG1 NF EN ISO 11885 IT-DLQ-42/V03;SMEWW3111 B, 21ed No information WAC/III/B011 of WAC/III/B010- WAC/III/B002 5; one additional control measurement local authority Yearly - Yearly - Yearly below level of quantification - below level of quantification - below level of quantification detection limit: 0,1 mg/L - detection limit: 0,1 mg/L detection limit: 0,1 mg/L < LQ; LD= 0,04SIDVA - < LQ; LD= 0,15SIDVA - < LQ; LD= Does not exist. SIDVA mesures for water agency for calculate a fee - mesures for water agency for calculate a fee - mesures for water agency for calculate a fee In these monitoring the value is below level of quantification - In these monitoring the value is below level of quantification - In these monitoring the value is below level of quantification The installation only started operating in 2017.Measurement value: < 0.3 mg/L (below level of quantification). The value of uncertainty is not refered in the reports. W-METAXDG1 No information Toxic metals in excess of 10000ug/l either individually or in total - Toxic metals in excess of 10000ug/l either individually or in total - Toxic metals in excess of 10000ug/l either individually or in total IRSA 3010 + 3030, EPA 3005A 1992 + EPA 6010D 2014, EPA 3005A 1992 + EPA 6010D 2014 UNI EN ISO 11885:2009 ICPMS Routine- acid digested; determined by ICPMS Value refered to sampling period - Value refered to sampling period - Value refered to sampling period Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours No information The unit measurement is in microgrammes/litre - The unit measurement is in microgrammes/litre - The unit measurement is in microgrammes/litre 34 2 TOTAL N - Emissions to water Concentration expressed in mg/l 50 45 40 35 30 25 20 15 10 5 0 Point of discharge Average concentration over 3 years ELV (mg/l ) DE034_w {1} PT098_w {1} BE007_w {1} DE025_w {1} CZ019_w {1} BE009_w {1} BE011_w {1} PT110_w {1} IT092_w {1} IT097_w {1} PT111_w {1} BE010_w {1} CZ020_w {1} FR134_w {1} BE014_w {1} IT067_w {1} FR131_w {1} Type of discharge DIR DIR DIR DIR DIR DIR DIR DIR DIR DIR DIR DIR DIR DIR DIR DIR DIR Type of monitoring Per Per Freq Per Freq Per Per Per Per Per Per Per Per Per Per Per Per 1.0 Mass load expressed in g/day 0.8 0.6 Max. load over 3 0.4 years (g/day) 0.2 0.0 DE034_w {1} PT098_w {1} BE007_w {1} DE025_w {1} CZ019_w {1} BE009_w {1} BE011_w {1} PT110_w {1} IT092_w {1} IT097_w {1} PT111_w {1} BE010_w {1} CZ020_w {1} FR134_w {1} BE014_w {1} IT067_w {1} FR131_w {1} Techniques applied Other Anaerobic treatment Membrane bioreactor Distillation/rectification Reverse osmosis Chemical reduction Chemical oxidation Flotation Nanofiltration Microfiltration Ultrafiltration Evaporation Adsorption Activated sludge process Nitrification/denitrification Sand filtration Sedimentation Coagulation and flocculation Screening Grit separators Oil separation Neutralisation Equalisation No technique used DE034_w {1} PT098_w {1} BE007_w {1} DE025_w {1} CZ019_w {1} BE009_w {1} BE011_w {1} PT110_w {1} IT092_w {1} IT097_w {1} PT111_w {1} BE010_w {1} CZ020_w {1} FR134_w {1} BE014_w {1} IT067_w {1} FR131_w {1} 35 TOTAL N - EMISSIONS TO WATER EP water name Type of discharge DIR = Direct DE034_w {1} DIR ES058_w {1} IND PT098_w {1} DIR IT059_w {1} IND BE007_w {1} DIR DE025_w {1} DIR CZ019_w {1} DIR BE009_w {1} DIR BE011_w {1} DIR IT094_w {1} IND IT074_w {1} IND IT059_w {2} IND IT079_w {1} IND PT110_w {1} DIR SE119_w {1} IND IT092_w {1} DIR IT097_w {1} DIR PT111_w {1} DIR BE010_w {1} DIR IT073_w {1} IND IT091_w {1} IND IT083_w {1} IND DE039_w {1} IND CZ020_w {1} DIR IT090_w {1} IND FR134_w {1} DIR Associated processes Washing synthetic fibre - Desizing - Bleaching - Dyeing Mercerising - Bleaching - Dyeing - Desizing - Fabric production - Printing - Thermal treatment Wool Fulling - Functional finishing - Dyeing - Thermal treatment Scouring - Mercerising - Bleaching - Dyeing - Singeing Dry cleaning Dyeing Washing synthetic fibre - Dyeing - Printing Bleaching - Dyeing - Printing - Functional finishing Desizing Printing - Coating and laminating Dyeing Units for concentration values mg/l mg/l mg/l mg/l mg/l mg/l mg/l mg/l mg/l Min. concentration over 3 years Average concentration over 3 years Max. concentration over 3 years Max. load over 3 ELV (mg/l ) years (g/day) 1.89 2.06 2.22 3.70 1 2.20 4.6 1.85 3.68 5.5 5.70 0.39 2.52 6.42 7.60 3 4.11 7.7 2 4.85 9.7 Combination of techniques Type of sampling 6 Activated sludge process, Nitrification/denitrification Flow proportional composite sample No information No information 15 Equalisation, Neutralisation, Sedimentation, Sand filtration, Activated sludge process, Other No information Other Not applicable Equalisation, Neutralisation, Sand filtration, Activated sludge process, Nitrification/denitrification Flow proportional composite sample, Not applicable, Flow proportional composite sample 12 Equalisation, Neutralisation, Coagulation and flocculation, 24-hour flow proportional composite sample Sedimentation, Activated sludge process 11 Equalisation, Neutralisation, Anaerobic treatment, Nitrification/denitrification, Activated sludge process Screening, Sedimentation, Equalisation, Activated sludge process, Sand filtration, Coagulation and flocculation, 15 Flotation, Chemical oxidation (incl. Advanced oxidation), Sand filtration, Chemical reduction, Microfiltration, Reverse osmosis No information Other, 24-hour flow proportional composite sample, Other Equalisation, Neutralisation, Coagulation and flocculation, 15 Activated sludge process, Nitrification/denitrification, Sand filtration, Nanofiltration, Chemical oxidation (incl. 24-hour flow proportional composite sample Advanced oxidation) No information mg/l Washing synthetic fibre - Scouring - Functional finishing - mg/l Dry cleaning - Other Thermal treatment - Functional finishing mg/l 1.67 5.57 10.3 8.2 9.92 12.3 7.76 10.38 13 Other Other No technique used No information Other Not applicable Scouring - Wool Fulling - Functional finishing - Thermal mg/l treatment - Other 8 10.48 13.1 Other 24-hour flow proportional composite sample Dyeing mg/l Washing synthetic fibre - Desizing - Functional finishing - mg/l Dyeing Dyeing - Other mg/l Dyeing - Shrink-proof finishing - Printing - Other mg/l Desizing - Dyeing - Fabric production - Wool Fulling - Functional finishing - Shrink-proof finishing - Dry cleaning -mg/l Thermal treatment Bleaching - Dyeing - Bleaching - Scouring - Functional mg/l finishing Dyeing - Functional finishing mg/l Scouring - Dyeing - Functional finishing - Thermal mg/l treatment - Other Scouring - Dyeing - Functional finishing mg/l Mercerising - Dyeing - Washing synthetic fibre - mg/l Bleaching - Desizing Dyeing mg/l 4 7.38 6.6 10.40 17.1 17.10 6 12.25 6 9.48 3 8.24 12.3 15.52 12.4 15.25 3.2 10.12 15 18.00 2.5 6.23 15 16 2896 17.1 18.5 18.7 19.9 19.9 20.7 20.8 21 24 Equalisation, Grit separators, Screening, Coagulation and 15 flocculation, Sedimentation, Activated sludge process, No information Other No technique used 24-hour flow proportional composite sample Equalisation, Neutralisation, Activated sludge process, Nitrification/denitrification, Sedimentation, Reverse osmosis Equalisation, Neutralisation, Activated sludge process, Nitrification/denitrification, Sedimentation Not applicable Not applicable 15 Equalisation, Neutralisation, Activated sludge process, Sedimentation, Sand filtration, Other No information 15 EqualisationActivated sludge process, Nitrification/denitrification, Other No technique used 24-hour flow proportional composite sample Other No information Other 100 Other Not applicable Equalisation, Neutralisation Sedimentation, Nitrification/denitrification, 25 Neutralisation, Coagulation and flocculation, Activated sludge process Flow proportional composite sample No information Scouring - Dyeing - Thermal treatment - Other - mg/l Bleaching 16.6 20.65 25 Other 24-hour flow proportional composite sample Washing synthetic fibre - Desizing - Mercerising - mg/l Bleaching - Dyeing - Singeing - Functional finishing 4.1 12.08 26.6 30 Equalisation, Neutralisation, Grit separators, Activated sludge process, Anaerobic treatment No information Monitoring frequency No information Yearly Yearly Twice per year Monthly Monthly Monthly No information No information Twice per year No information Twice per year Twice per year Monthly No information Other No information 4 times per year Yearly Twice per year No information Twice per year Twice per year Monthly Twice per year 4 times per year IT072_w {1} IND Thermal treatment - Scouring - Bleaching - Dyeing - mg/l Other 7.7 14.28 27.7 Other Other Twice per year BE014_w {1} DIR BE008_w {1} IND IT067_w {1} DIR DE042_w {1} IND IT074_w {2} IND IT089_w {1} IND IT063_w {1} IND Bleaching - Dyeing - Functional finishing mg/l Printing - Dyeing mg/l Dyeing - Printing - Other - Shrink-proof finishing mg/l Washing synthetic fibre - Desizing - Bleaching - Dyeing - mg/l Functional finishing Washing synthetic fibre - Scouring mg/l Scouring - Dyeing - Thermal treatment - Other - mg/l Bleaching Dyeing - Fabric production - Dry cleaning - Printing - mg/l Printing - Functional finishing 5.2 13.01 29 0.7 19.55 30.8 19.7 24.83 34.8 14 21.61 36 6.9 13.72 36.8 19.7 27.88 39.6 9 19.96 40 36 Equalisation, Activated sludge process, Nitrification/denitrification 60 Equalisation, Grit separators, Other Equalisation, Neutralisation, Activated sludge process, Nitrification/denitrification, Sedimentation Neutralisation, Equalisation Other 24-hour flow proportional composite sample 24-hour flow proportional composite sample Not applicable 24-hour flow proportional composite sample Other Other 24-hour flow proportional composite sample 54 Equalisation Other No information No information No information 4 times per year No information Twice per year 4 times per year IT071_w {2} IND Dyeing - Other - Functional finishing mg/l 6 23.02 42.4 Other Other Twice per year BE013_w {1} IND PT115_w {1} IND SE120_w {1} IND AT004_w {1} IND Mercerising mg/l No information mg/l Washing synthetic fibre - Desizing - Bleaching mg/l Washing synthetic fibre mg/l 12.8 25.93 9 21.33 3.8 18.90 22 32.55 43.6 45 45 22080 45.3 Distillation/rectification, Equalisation, Neutralisation Equalisation, Neutralisation, Screening Neutralisation, Oil separation, Equalisation No information Flow proportional composite sample 24-hour flow proportional composite sample 24-hour flow proportional composite sample No information Yearly Yearly Continuous Twice per year 36 Monitoring standard Additional information No information No information POQ 14 Edio 11, PNT MA/FQ2-07(2015-09-09), PNT MA/FQ2-07(2015-09-09) APAT CNR IRSA 5030 Man 29 2003 WAC/III/D/033 qualified sample - qualified sample - qualified sample - < LD - < LD CALCULATED No information WAC/III/D/033 Less than 12/year flow proportionate sampling, >12/year are grab sample results. Value 0 means results beneath detection limit of analyses WAC/III/D/033 Determined as the sum of NH4-N, NO2-N and NO3-N INTERNAL MHETOD APAT CNR IRSA 5030 Man 29 2003 Marconcini SRL internal method n. 34 ELV is referred to 3 hours sampled waste water - ELV is referred to 3 hours sampled waste water - ELV is referred to 3 hours sampled waste water. Data related to 2015. No information No information LCK 238 Monitoring frequency: spot LCK 238; UNI EN 12260:2004 Monitoring frequency: spot SMEWW 4500 N WAC/III/D/033 Metodo interno n34 INTERNAL MHETOD AVERAGE PERIOD 3 HOURS - AVERAGE PERIOD 3 HOURS AVERAGE PERIOD 3 HOURS apat cnr irsa 4030 a1-a2/c-4050+5030-4020 Man 29 2003 No information specified in extern laboratory Marconcini SRL internal method n. 34 NF EN 25663 INTERNAL METHOD WAC/III/D/033 WAC/III/D/033 LCK 238 No information INTERNAL MHETOD Marconcini SRL internal method n. 34 No information INTERNAL METHOD MEIN040 SMEWW 4500 N No information EN 25663 (MH) ELV is referred to 3 hours sampled waste water - ELV is referred to 3 hours sampled waste water - ELV is referred to 3 hours sampled waste water. Data related to 2015. Averaging period for monitoring: 3 hours; Parameter monitored on indication of the manager of the public sewage - Averaging period for monitoring: 3 hours; Parameter monitored on indication of the manager of the public sewage - Averaging period for monitoring: 3 hours; Parameter monitored on indication of the manager of the public sewage ELV is referred to 3 hours sampled waste water - ELV is referred to 3 hours sampled waste water - ELV is referred to 3 hours sampled waste water. Data related to 2015. Authorized in derogation - Authorized in derogation Authorized in derogation Averaging period for monitoring: 3 hours; Parameter monitored on indication of the manager of the public sewage - Averaging period for monitoring: 3 hours; Parameter monitored on indication of the manager of the public sewage - Averaging period for monitoring: 3 hours; Parameter monitored on indication of the manager of the public sewage sample 22.10.2015-23.10.2015 Environmetal Permit - Environmetal Permit Environmetal Permit TKN; no ELV in the permit - TKN; no ELV in the permit TKN; no ELV in the permit 1 EP water name Type of discharge DIR = Direct Associated processes TOTAL N - EMISSIONS TO WATER Units for concentration values Min. concentration over 3 years Average concentration over 3 years Max. concentration over 3 years Max. load over 3 ELV (mg/l ) years (g/day) Combination of techniques Type of sampling Monitoring frequency IT071_w {1} IND Dyeing - Bleaching - Scouring mg/l 27.9 37.38 46.1 No information Other Twice per year FR131_w {1} DIR AT005_w {1} IND IT065_w {1} IND DE045_w {1} IND SE118_w {1} IND IT088_w {1} IND DE031_w {1} IND Washing synthetic fibre - Bleaching - Dyeing - Printing - Functional finishing - Coating and laminating - Thermal mg/l treatment No information mg/l No information mg/l Washing synthetic fibre - Desizing - Desizing mg/l Washing synthetic fibre - Scouring - Scouring - Bleaching - Dyeing - Singeing - Printing - Functional finishing - Shrink- mg/l proof finishing - Coating and laminating - Thermal treatment Dyeing - Bleaching mg/l Dyeing mg/l 4.2 17.80 38 44.33 0.1 12.85 52.00 13 25.00 0.5 14.98 18 40.72 47 49 51 56 19712 60 91 10 Other 50 Neutralisation Other No information 25 Sedimentation, Neutralisation No information No information 24-hour flow proportional composite sample No information No information 24-hour flow proportional composite sample 24-hour flow proportional composite sample Not applicable No information Monthly Twice per year Twice per year Twice per year Weekly Twice per year Other IT064_w {1} IND Scouring mg/l 16.8 53.52 91 Other Other Twice per year DE030_w {1} IND IT087_w {1} IND DE049_w {1} IND CZ017_w {1} IND IT085_w {1} IND AT002_w {1} IND FR135_w {1} IND DE051_w {1} IND FR136_w {1} IND UK127_w {1} IND Washing synthetic fibre - Desizing - Mercerising Bleaching - Singeing - Dyeing - Functional finishing Thermal treatment Dyeing - Shrink-proof finishing - Shrink-proof finishing Other Desizing - Bleaching - Bleaching - Dyeing - Singeing Printing - Coating and laminating - Scouring - Functional finishing Spinning - Fabric production - Singeing - Functional finishing - Shrink-proof finishing - Thermal treatment Other mg/l No unit reported mg/l mg/l Dyeing mg/l No information mg/l Washing synthetic fibre mg/l Washing synthetic fibre - Scouring - Bleaching - Dyeing - mg/l Functional finishing Desizing - Scouring - Bleaching - Mercerising - Dyeing - mg/l Singeing - Fabric production - Functional finishing Mercerising - Bleaching - Dyeing - Scouring - Singeing - mg/l Printing 18.9 33.59 38 73.40 47.3 79.00 70 85.53 69 93.00 34 61.07 5.9 29.77 23 42.32 80 143.56 3 88.00 93.1 95 96 107 110 120 215 44720 225 233 252 497460.6 Equalisation, Neutralisation, Screening Equalisation Equalisation, Neutralisation 24-hour flow proportional composite sample Not applicable, Grab/spot sample, Not applicable 24-hour flow proportional composite sample No information No information Equalisation Not applicable No information 50 Grit separators No information 24-hour flow proportional composite sample Neutralisation, Coagulation and flocculation, Equalisation No information 400 Grit separators, Neutralisation No information Neutralisation 24-hour flow proportional composite sample 4 times per year No information Yearly Yearly Other No information Monthly Monthly No information Weekly IT068_w {1} IND Washing synthetic fibre - Desizing - Scouring - Bleaching - mg/l Dyeing - Functional finishing - Other 13.5 74.40 309 Other Other Twice per year CZ015_w {1} IND CZ016_w {1} IND Dyeing - Functional finishing Shrink-proof finishing mg/l 206 303.50 474 mg/l 211.1 998.41 2791 Grit separators, Equalisation, Sedimentation No information Flow proportional composite sample Flow proportional composite sample 4 times per year Monthly Monitoring standard INTERNAL METHOD NF EN 25663 DIN EN 25663DIN EN 25663DIN EN 25663 ARPAT CNR IRSA4060 Man 29 2003 No information No information apat irsa cnr 28/2003 4060 No information INTERNAL METHOD DIN No information DIN No information No information DIN EN 25663 No information No information No information No information INTERNAL METHOD No information No information Additional information Averaging period for monitoring: 3 hours; Parameter monitored on indication of the manager of the public sewage - Averaging period for monitoring: 3 hours; Parameter monitored on indication of the manager of the public sewage - Averaging period for monitoring: 3 hours; Parameter monitored on indication of the manager of the public sewage Requested by Italian Law - Requested by Italian Law Requested by Italian Law,and other analyses introduced during 2018 to follow the ZDHC Waste Water Guide lines Three months average Yearly - Yearly - Yearly Averaging period for monitoring: 3 hours; Parameter monitored on indication of the manager of the public sewage - Averaging period for monitoring: 3 hours; Parameter monitored on indication of the manager of the public sewage - Averaging period for monitoring: 3 hours; Parameter monitored on indication of the manager of the public sewage Monitoring end frequency dependent on the operator of the off-site treatment plant Ammonia values as nitrogen - Ammonia values as nitrogen - Ammonia values as nitrogen Averaging period for monitoring: 3 hours; Parameter monitored on indication of the manager of the public sewage - Averaging period for monitoring: 3 hours; Parameter monitored on indication of the manager of the public sewage - Averaging period for monitoring: 3 hours; Parameter monitored on indication of the manager of the public sewage (data referring to the year 2015) 37 2 38 Other Anaerobic treatment Membrane bioreactor Distillation/rectification Reverse osmosis Chemical reduction Chemical oxidation Flotation Nanofiltration Microfiltration Ultrafiltration Evaporation Adsorption Activated sludge process Nitrification/denitrification Sand filtration Sedimentation Coagulation and flocculation Screening Grit separators Oil separation Neutralisation Equalisation No technique used DE046_w {1} IT063_w {1} IT063_w {3} DE034_w {1} DE023_w {1} DE050_w {1} DE044_w {1} IT069_w {1} AT006_w {1} IT090_w {1} DE032_w {1} BE010_w {1} BE007_w {1} IT064_w {1} IT079_w {1} IT073_w {1} ES058_w {1} DE025_w {1} IT068_w {1} SE118_w {1} BE009_w {1} DE031_w {1} IT078_w {1} BE008_w {1} CZ017_w {1} DE029_w {1} IT074_w {1} IT097_w {1} AT004_w {1} DE022_w {1} FR131_w {1} DE047_w {1} DE051_w {1} DE045_w {1} IT089_w {1} DE024_w {1} DE049_w {1} AT002_w {1} DE026_w {1} FR132_w {2} DE041_w {1} DE030_w {1} FR136_w {1} FR134_w {1} DE039_w {1} CZ020_w {1} AT001_w {1} DE042_w {1} PT099_w {1} AT003_w {1} SE120_w {1} IT063_w {2} CZ018_w {1} AT005_w {1} CZ016_w {1} Techniques applied Max. load over 3 years (g/day) IND IND IND DIR IND IND IND IND IND IND DIR DIR DIR IND IND IND IND DIR IND IND DIR IND IND IND IND IND IND DIR IND IND DIR IND IND IND IND IND IND IND IND DIR IND IND IND DIR IND DIR IND IND IND IND IND IND IND IND IND Per Per Per Per Per Per Per Per Per Per Per Per Freq Per Per Per Freq Per Per Freq Per Per Per Per Per Per Per Per Per Per Per Per Per Freq Per Per Per Per Per Per Freq Per Per Per Per Per Per Per Per Per Freq Per Per Per Per Type of discharge Type of monitoring Mass load expressed in g/day Concentration expressed in mg/l 500 300 200 100 70 60 50 40 30 20 10 0 DE046_w {1} IT063_w {1} IT063_w {3} DE034_w {1} DE023_w {1} DE050_w {1} DE044_w {1} IT069_w {1} AT006_w {1} IT090_w {1} DE032_w {1} BE010_w {1} BE007_w {1} IT064_w {1} IT079_w {1} IT073_w {1} ES058_w {1} DE025_w {1} IT068_w {1} SE118_w {1} BE009_w {1} DE031_w {1} IT078_w {1} BE008_w {1} CZ017_w {1} DE029_w {1} IT074_w {1} IT097_w {1} AT004_w {1} DE022_w {1} FR131_w {1} DE047_w {1} DE051_w {1} DE045_w {1} IT089_w {1} DE024_w {1} DE049_w {1} AT002_w {1} DE026_w {1} FR132_w {2} DE041_w {1} DE030_w {1} FR136_w {1} FR134_w {1} DE039_w {1} CZ020_w {1} AT001_w {1} DE042_w {1} PT099_w {1} AT003_w {1} SE120_w {1} IT063_w {2} CZ018_w {1} AT005_w {1} CZ016_w {1} DE046_w {1} IT063_w {1} IT063_w {3} DE034_w {1} DE023_w {1} DE050_w {1} DE044_w {1} IT069_w {1} AT006_w {1} IT090_w {1} DE032_w {1} BE010_w {1} BE007_w {1} IT064_w {1} IT079_w {1} IT073_w {1} ES058_w {1} DE025_w {1} IT068_w {1} SE118_w {1} BE009_w {1} DE031_w {1} IT078_w {1} BE008_w {1} CZ017_w {1} DE029_w {1} IT074_w {1} IT097_w {1} AT004_w {1} DE022_w {1} FR131_w {1} DE047_w {1} DE051_w {1} DE045_w {1} IT089_w {1} DE024_w {1} DE049_w {1} AT002_w {1} DE026_w {1} FR132_w {2} DE041_w {1} DE030_w {1} FR136_w {1} FR134_w {1} DE039_w {1} CZ020_w {1} AT001_w {1} DE042_w {1} PT099_w {1} AT003_w {1} SE120_w {1} IT063_w {2} CZ018_w {1} AT005_w {1} CZ016_w {1} 0 Point of discharge ELV (mg/l ) over 3 years 400 Average concentration 600 AOX - Emissions to water 39 Other Anaerobic treatment Membrane bioreactor Distillation/rectification Reverse osmosis Chemical reduction Chemical oxidation Flotation Nanofiltration Microfiltration Ultrafiltration Evaporation Adsorption Activated sludge process Nitrification/denitrification Sand filtration Sedimentation Coagulation and flocculation Screening Grit separators Oil separation Neutralisation Equalisation No technique used DE046_w {1} IT063_w {1} IT063_w {3} DE034_w {1} DE023_w {1} DE050_w {1} DE044_w {1} IT069_w {1} AT006_w {1} IT090_w {1} DE032_w {1} BE010_w {1} BE007_w {1} IT064_w {1} IT079_w {1} IT073_w {1} ES058_w {1} DE025_w {1} IT068_w {1} SE118_w {1} BE009_w {1} DE031_w {1} IT078_w {1} BE008_w {1} CZ017_w {1} DE029_w {1} IT074_w {1} IT097_w {1} AT004_w {1} DE022_w {1} FR131_w {1} DE047_w {1} DE051_w {1} DE045_w {1} IT089_w {1} DE024_w {1} DE049_w {1} AT002_w {1} DE026_w {1} FR132_w {2} DE041_w {1} DE030_w {1} FR136_w {1} FR134_w {1} DE039_w {1} CZ020_w {1} AT001_w {1} DE042_w {1} PT099_w {1} AT003_w {1} SE120_w {1} IT063_w {2} CZ018_w {1} AT005_w {1} CZ016_w {1} Techniques applied Average concentration over 3 years ELV (mg/l ) Max. load over 3 years (g/day) IND IND IND DIR IND IND IND IND IND IND DIR DIR DIR IND IND IND IND DIR IND IND DIR IND IND IND IND IND IND DIR IND IND DIR IND IND IND IND IND IND IND IND DIR IND IND IND DIR IND DIR IND IND IND IND IND IND IND IND IND Per Per Per Per Per Per Per Per Per Per Per Per Freq Per Per Per Freq Per Per Freq Per Per Per Per Per Per Per Per Per Per Per Per Per Freq Per Per Per Per Per Per Freq Per Per Per Per Per Per Per Per Per Freq Per Per Per Per Type of discharge Type of monitoring Mass load expressed in g/day Concentration expressed in mg/l 70 60 50 40 30 20 10 0 DE046_w {1} IT063_w {1} IT063_w {3} DE034_w {1} DE023_w {1} DE050_w {1} DE044_w {1} IT069_w {1} AT006_w {1} IT090_w {1} DE032_w {1} BE010_w {1} BE007_w {1} IT064_w {1} IT079_w {1} IT073_w {1} ES058_w {1} DE025_w {1} IT068_w {1} SE118_w {1} BE009_w {1} DE031_w {1} IT078_w {1} BE008_w {1} CZ017_w {1} DE029_w {1} IT074_w {1} IT097_w {1} AT004_w {1} DE022_w {1} FR131_w {1} DE047_w {1} DE051_w {1} DE045_w {1} IT089_w {1} DE024_w {1} DE049_w {1} AT002_w {1} DE026_w {1} FR132_w {2} DE041_w {1} DE030_w {1} FR136_w {1} FR134_w {1} DE039_w {1} CZ020_w {1} AT001_w {1} DE042_w {1} PT099_w {1} AT003_w {1} SE120_w {1} IT063_w {2} CZ018_w {1} AT005_w {1} CZ016_w {1} DE046_w {1} IT063_w {1} IT063_w {3} DE034_w {1} DE023_w {1} DE050_w {1} DE044_w {1} IT069_w {1} AT006_w {1} IT090_w {1} DE032_w {1} BE010_w {1} BE007_w {1} IT064_w {1} IT079_w {1} IT073_w {1} ES058_w {1} DE025_w {1} IT068_w {1} SE118_w {1} BE009_w {1} DE031_w {1} IT078_w {1} BE008_w {1} CZ017_w {1} DE029_w {1} IT074_w {1} IT097_w {1} AT004_w {1} DE022_w {1} FR131_w {1} DE047_w {1} DE051_w {1} DE045_w {1} IT089_w {1} DE024_w {1} DE049_w {1} AT002_w {1} DE026_w {1} FR132_w {2} DE041_w {1} DE030_w {1} FR136_w {1} FR134_w {1} DE039_w {1} CZ020_w {1} AT001_w {1} DE042_w {1} PT099_w {1} AT003_w {1} SE120_w {1} IT063_w {2} CZ018_w {1} AT005_w {1} CZ016_w {1} 1.0 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0.0 Point of discharge AOX - Emissions to water (zoom 0-1 mg/l) AOX - EMISSIONS TO WATER EP water name DE046_w {1} IT063_w {1} IT063_w {3} Type of discharge DIR = Direct IND = Indirect IND IND IND Associated processes Washing synthetic fibre - Dyeing Dyeing - Fabric production - Dry cleaning - Printing Printing - Functional finishing Dry cleaning Units for concentration values mg/l mg/l mg/l Min. concentration over 3 years Average concentration over 3 years Max. concentration over 3 years Max. load over 3 ELV (mg/l ) years (g/day) 0.015 0.015 0.015 0.01 0.01 0.02 0.01 0.02 0.03 Combination of techniques 1 No information Equalisation 2 No information Type of sampling No information Other No information DE034_w {1} DIR Washing synthetic fibre - Desizing - Bleaching - Dyeing mg/l 0.015 0.03 0.05 0.1 Activated sludge process, Nitrification/denitrification Flow proportional composite sample Monitoring frequency No information 4 times per year 4 times per year Yearly DE023_w {1} IND DE050_w {1} IND DE044_w {1} IND IT069_w {1} IND AT006_w {1} IND IT090_w {1} IND DE032_w {1} DIR BE010_w {1} DIR BE007_w {1} DIR IT064_w {1} IND Washing synthetic fibre - Mercerising - Bleaching - Dyeing mg/l Washing synthetic fibre - Desizing - Bleaching mg/l Desizing - Mercerising - Bleaching - Dyeing mg/l Scouring - Bleaching - Mercerising mg/l Bleaching - Dyeing mg/l Scouring - Dyeing - Thermal treatment - Other - Bleaching mg/l Washing synthetic fibre - Desizing - Bleaching - Dyeing - Printing mg/l Bleaching - Dyeing - Bleaching - Scouring - Functional mg/l finishing Dyeing mg/l Scouring mg/l 0.01 0.051 0.06 0.016 0.023 0.036 0.035 0.08 0.077 0.02 0.051 0.06 0.05 0.05 0.06 0.06 0.10 0.13 0.10 0.05 0.051 0.06 0.089 0.09 0.091 0.12 0.12 0.134 1 No information 1 No information No information No information No information 24-hour flow proportional composite sample No information Once every 3 years Twice per year 2 Other Other Twice per year 0.5 Flotation Other No information 24-hour flow proportional composite sample Yearly Twice per year Equalisation, Neutralisation, Grit separators, Coagulation and flocculation, Sedimentation, Sand filtration, 24-hour flow proportional composite sample Nitrification/denitrification, Activated sludge process 0.55 EqualisationActivated sludge process, Nitrification/denitrification, Other Equalisation, Neutralisation, Sand filtration, Activated sludge process, Nitrification/denitrification 24-hour flow proportional composite sample Flow proportional composite sample, Not applicable, Flow proportional composite sample Twice per year Other Monthly 2 Other Other Twice per year IT079_w {1} IND IT073_w {1} IND ES058_w {1} IND BE014_w {1} DIR DE025_w {1} DIR IT068_w {1} IND SE118_w {1} IND BE009_w {1} DIR DE031_w {1} IND IT078_w {1} IND BE008_w {1} IND CZ017_w {1} IND DE029_w {1} IND IT074_w {1} IND IT097_w {1} DIR BE011_w {1} DIR AT004_w {1} IND DE022_w {1} IND FR131_w {1} DIR DE047_w {1} IND Scouring - Wool Fulling - Functional finishing - Thermal treatment - Other Dyeing - Functional finishing Mercerising - Bleaching - Dyeing - Desizing - Fabric production - Printing - Thermal treatment Bleaching - Dyeing - Functional finishing mg/l mg/l mg/l No unit reported Washing synthetic fibre - Dyeing - Printing mg/l Washing synthetic fibre - Desizing - Scouring - Bleaching - mg/l Dyeing - Functional finishing - Other Washing synthetic fibre - Scouring - Scouring - Bleaching Dyeing - Singeing - Printing - Functional finishing - Shrink- mg/l proof finishing - Coating and laminating - Thermal treatment Printing - Coating and laminating mg/l Dyeing mg/l Wool Fulling - Washing synthetic fibre - Dyeing mg/l Printing - Dyeing mg/l Spinning - Fabric production - Singeing - Functional finishing - Shrink-proof finishing - Thermal treatment - mg/l Other Dyeing mg/l Washing synthetic fibre - Scouring - Functional finishing - mg/l Dry cleaning - Other Dyeing - Shrink-proof finishing - Printing - Other mg/l Dyeing No unit reported Washing synthetic fibre mg/l Raw wool scouring - Washing synthetic fibre - Desizing - Scouring - Bleaching - Dyeing - Thermal treatment - mg/l Functional finishing - Coating and laminating Washing synthetic fibre - Bleaching - Dyeing - Printing Functional finishing - Coating and laminating - Thermal mg/l treatment Desizing - Mercerising - Bleaching - Dyeing - Functional mg/l finishing 0.07 0.045 0.033 0 0.082 0.06 0.085 0.023 0.075 0.16 0.19 0.01 0.092 0.28 0.08 0 0.01 0.019 0 0.11 0.14 0.10 0.15 0.15 0.06 0.158 0.02 0.16 0.12 0.163 2 Other 24-hour flow proportional composite sample No technique used Other No information No information 1 Equalisation, Activated sludge process, Nitrification/denitrification 24-hour flow proportional composite sample 0.3 Equalisation, Neutralisation, Coagulation and flocculation, 24-hour flow proportional composite sample Sedimentation, Activated sludge process 2 Other Other Twice per year Twice per year 4 times per year No information Monthly Twice per year 0.11 0.17 61.03 0.12 0.175 0.08 0.19 0.15 0.211 0.19 0.22 0.23 0.258 0.07 0.26 Sedimentation, Neutralisation 24-hour flow proportional composite sample Screening, Sedimentation, Equalisation, Activated sludge process, Sand filtration, Coagulation and flocculation, 1 Flotation, Chemical oxidation (incl. Advanced oxidation), Sand filtration, Chemical reduction, Microfiltration, Reverse osmosis No information Other, 24-hour flow proportional composite sample, Other No information 4 times per year No information Other 2 Other Other Twice per year 1 Equalisation, Grit separators, Other No information 1 No information 24-hour flow proportional composite sample No information Flow proportional composite sample No information Yearly 4 times per year 0.18 0.312 2 Other Other No information 0.32 0.35 0.17 0.38 0.17 0.38 0.10 0.391 Equalisation, Neutralisation, Activated sludge process, Nitrification/denitrification, Sedimentation Not applicable Equalisation, Neutralisation, Coagulation and flocculation, Activated sludge process, Nitrification/denitrification, 1 Sand filtration, Nanofiltration, Chemical oxidation (incl. 24-hour flow proportional composite sample Advanced oxidation) 1 No information No information 1 Neutralisation, Oil separation, Evaporation Other No information No information Twice per year Monthly 0.13 0.41 0.19 0.451 0.001 Other 0.5 Neutralisation 24-hour flow proportional composite sample 24-hour flow proportional composite sample Monthly 4 times per year 40 Monitoring standard No information No information No information No information No information No information No information APAT CNR IRSA 5150 MAN 29 2003 EN ISO 9562:2004 APAT CNR IRSA 5150 MAN 29 2003 No information No information No information APAT CNR IRSA 5150 MAN 29 2003 APAT CNR IRSA 5150 MAN 29 2003 ARPAT CNR IRSA 5150 MAN 29 2003 No information WAC/IV/B/11 DIN EN ISO 9562 (H14) APAT CNR IRSA 5150 MAN 29 2003 No information WAC/IV/B/011 DIN EN ISO9562 APAT CNR IRSA 5150 MAN 29 2003 WAC/IV/B/011 No information No information APAT CNR IRSA 5150 MAN 29 2003 ISO 9562:2004 WAC/IV/B/011 EN ISO 9562:2004 (MH) DIN NF EN ISO 9562 No information Additional information - qualified sample - under mesurement 2,3,.. you find the measured values from the authority surveillance - under mesurement 2,3,.. you find the measured values from the authority surveillance - under mesurement 2,3,.. you find the measured values from the authority surveillance Averaging period for ELV: 3 hours; (researched parameter: chlorinated solvents) - Averaging period for ELV: 3 hours; (researched parameter: chlorinated solvents) - Averaging period for ELV: 3 hours; (researched parameter: chlorinated solvents, data referring to the year 2015) ELV is referred to 3 hours sampled waste water - ELV is referred to 3 hours sampled waste water - ELV is referred to 3 hours sampled waste water. Data related to 2015. Averaging period for ELV: 3 hours (researched parameter: chlorinated solvents) - Averaging period for ELV: 3 hours (researched parameter: chlorinated solvents) - Averaging period for ELV: 3 hours (researched parameter: chlorinated solvents) ELV is referred to 3 hours sampled waste water - ELV is referred to 3 hours sampled waste water - ELV is referred to 3 hours sampled waste water. Data related to 2015. Averaging period for ELV: 3 hours (researched parameter: chlorinated solvents) - Averaging period for ELV: 3 hours (researched parameter: chlorinated solvents) - Averaging period for ELV: 3 hours (researched parameter: chlorinated solvents data referring to the year 2015) 3 times/year - 3 times/year - 3 times/year Averaging period for ELV: 3 hours (researched parameter: chlorinated solvents) - Averaging period for ELV: 3 hours (researched parameter: chlorinated solvents) - Averaging period for ELV: 3 hours (researched parameter: chlorinated solvents) Averaging period for ELV: 3 hours (researched parameter: chlorinated solvents) - Averaging period for ELV: 3 hours (researched parameter: chlorinated solvents) - Averaging period for ELV: 3 hours (researched parameter: chlorinated solvents) (YEAR 2015) most measurements result with matrix interference 1 AOX - EMISSIONS TO WATER EP water name DE051_w {1} DE045_w {1} IT065_w {1} Type of discharge DIR = Direct IND = Indirect IND IND IND Associated processes Units for concentration values Min. concentration over 3 years Average concentration over 3 years Max. concentration over 3 years Max. load over 3 ELV (mg/l ) years (g/day) Washing synthetic fibre - Scouring - Bleaching - Dyeing - mg/l Functional finishing Washing synthetic fibre - Desizing - Desizing mg/l 0.04 0.14 0.47 0.49 No information No unit reported 0.19 0.34 0.49 Combination of techniques Type of sampling 1 Neutralisation, Coagulation and flocculation, Equalisation No information No information 24-hour flow proportional composite sample Other No information IT089_w {1} IND DE024_w {1} IND DE049_w {1} IND AT002_w {1} IND DE026_w {1} IND FR132_w {2} DIR DE041_w {1} IND DE030_w {1} IND FR136_w {1} IND FR134_w {1} DIR DE039_w {1} IND CZ020_w {1} DIR AT001_w {1} IND DE042_w {1} IND PT099_w {1} IND AT003_w {1} IND SE120_w {1} IND IT063_w {2} IND CZ018_w {1} IND AT005_w {1} IND BE013_w {1} IND CZ016_w {1} IND Scouring - Dyeing - Thermal treatment - Other - Bleaching mg/l Desizing - Dyeing - Scouring - Singeing mg/l Desizing - Bleaching - Bleaching - Dyeing - Singeing - Printing - Coating and laminating - Scouring - Functional mg/l finishing No information mg/l Washing synthetic fibre - Desizing - Dyeing - Bleaching mg/l Bleaching - Dyeing mg/l Desizing - Bleaching - Dyeing mg/l Washing synthetic fibre - Desizing - Mercerising - Bleaching - Singeing - Dyeing - Functional finishing - mg/l Thermal treatment Desizing - Scouring - Bleaching - Mercerising - Dyeing - mg/l Singeing - Fabric production - Functional finishing Washing synthetic fibre - Desizing - Mercerising - mg/l Bleaching - Dyeing - Singeing - Functional finishing Mercerising - Dyeing - Washing synthetic fibre - mg/l Bleaching - Desizing Dyeing mg/l No information Washing synthetic fibre - Desizing - Bleaching - Dyeing Functional finishing Dyeing - Printing - Functional finishing Mercerising - Dyeing - Desizing - Bleaching Washing synthetic fibre - Desizing - Bleaching Dry cleaning Desizing - Functional finishing - Dyeing - Fabric production No information Mercerising Shrink-proof finishing mg/l mg/l mg/l mg/l mg/l mg/l mg/l mg/l No unit reported mg/l 0.045 0.1 0.05 0 0.081 0.02 0.15 0.05 0.509 0.06 0.5 0.03 0 0 0.01 0 0.01 0.357 0.26 20 26 0.14 0.32 0.16 0.25 0.22 0.21 0.16 0.34 0.71 0.30 0.69 0.14 0.35 0.49 0.17 0.36 1.00 0.23 1.22 1.88 20.00 158.12 0.49 0.5 0.5 0.52 0.57 0.661 0.8 0.81 0.853 0.86 0.88 0.95 0.95 1 1 1 1.64 1.85 7.4 20 530 Other 24-hour flow proportional composite sample 1 Equalisation 0.5 Equalisation, Neutralisation Grab/spot sample 24-hour flow proportional composite sample 0.5 No information 0.5 No information 1 Other No information 1 Equalisation, Neutralisation, Screening No information Other Grab/spot sample No information 24-hour flow proportional composite sample Grit separators, Neutralisation No information Equalisation, Neutralisation, Grit separators, Activated sludge process, Anaerobic treatment No information Equalisation, Neutralisation Sedimentation, Nitrification/denitrification, 0.2 Neutralisation, Coagulation and flocculation, Activated sludge process 1 No information Flow proportional composite sample No information 24-hour flow proportional composite sample 1 Neutralisation, Equalisation 1 Screening, Oil separation, Other 1 Other Neutralisation, Oil separation, Equalisation 2 No information 1.5 Neutralisation 2.5 Neutralisation Distillation/rectification, Equalisation, Neutralisation No information 24-hour flow proportional composite sample No information Other 24-hour flow proportional composite sample No information 24-hour flow proportional composite sample No information Flow proportional composite sample Flow proportional composite sample Monitoring frequency Monthly Twice per year Twice per year Twice per year 4 times per year 4 times per year Yearly No information No information Monthly 4 times per year No information 4 times per year Twice per year Monthly 4 times per year 4 times per year 4 times per year 4 times per year No information 4 times per year Other Monthly Yearly Monthly Monitoring standard No information No information ISO 9562:2004 APAT CNR IRSA 5150 MAN 29 2003 No information DIN NORM EN ISO 9562 DIN No information No information DIN No information NF EN ISO 9562 No information specified in extern laboratory NORM EN ISO 9562 No information EN ISO 9562/MORM EN ISO 9562 No information No information No information NORM EN ISO 9562 No information No information Additional information analyses introduced during 2018 to follow the ZDHC Waste Water Guide lines ELV is referred to 3 hours sampled waste water - ELV is referred to 3 hours sampled waste water - ELV is referred to 3 hours sampled waste water. Data related to 2015. - compliance and selfmonitoring - compliance and selfmonitoring acc. To our permit mesures for water agency for calculate a fee - mesures for water agency for calculate a fee - mesures for water agency for calculate a fee 5; one additional control measurement local authority monitoring 6 per year - monitoring 6 per year monitoring 6 per year 41 2 42 Other Anaerobic treatment Membrane bioreactor Distillation/rectification Reverse osmosis Chemical reduction Chemical oxidation Flotation Nanofiltration Microfiltration Ultrafiltration Evaporation Adsorption Activated sludge process Nitrification/denitrification Sand filtration Sedimentation Coagulation and flocculation Screening Grit separators Oil separation Neutralisation Equalisation No technique used BE007_w {1} IT059_w {2} IT084_w {1} DE025_w {1} CZ020_w {1} IT065_w {1} BE010_w {1} BE013_w {1} IT082_w {1} CZ019_w {1} DE032_w {1} IT087_w {1} DE039_w {1} BE009_w {1} BE011_w {1} ES058_w {1} IT063_w {1} BE014_w {1} PT098_w {1} PT111_w {1} IT085_w {1} IT059_w {1} AT005_w {1} DE034_w {1} IT083_w {1} IT092_w {1} BE008_w {1} IT097_w {1} PT115_w {1} CZ017_w {1} IT070_w {1} IT088_w {1} AT003_w {1} IT076_w {1} SE120_w {1} IT096_w {1} PT110_w {1} DE049_w {1} IT067_w {1} DE031_w {1} AT002_w {1} IT091_w {1} UK127_w {1} IT073_w {1} DE042_w {1} AT001_w {1} FR135_w {1} DE022_w {1} DE030_w {1} FR131_w {1} FR136_w {1} FR134_w {1} DE051_w {1} SE118_w {1} Techniques applied Average concentration over 3 years ELV (mg/l ) Max. load over 3 years (g/day) DIR IND IND DIR DIR IND DIR IND DIR DIR DIR IND IND DIR DIR IND IND DIR DIR DIR IND IND IND DIR IND DIR IND DIR IND IND IND IND IND IND IND DIR DIR IND DIR IND IND IND IND IND IND IND IND IND IND DIR IND DIR IND IND Freq Per Per Per Per Per Per Per Per Freq Per Per Per Per Per Freq Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Freq Freq Per Per Per Per Per Per Per Per Per Per Per Freq Per Per Per Per Per Per Freq Type of discharge Type of monitoring Mass load expressed in g/day Concentration expressed in mg/l 30,000 25,000 20,000 15,000 10,000 5,000 0 BE007_w {1} IT059_w {2} IT084_w {1} DE025_w {1} CZ020_w {1} IT065_w {1} BE010_w {1} BE013_w {1} IT082_w {1} CZ019_w {1} DE032_w {1} IT087_w {1} DE039_w {1} BE009_w {1} BE011_w {1} ES058_w {1} IT063_w {1} BE014_w {1} PT098_w {1} PT111_w {1} IT085_w {1} IT059_w {1} AT005_w {1} DE034_w {1} IT083_w {1} IT092_w {1} BE008_w {1} IT097_w {1} PT115_w {1} CZ017_w {1} IT070_w {1} IT088_w {1} AT003_w {1} IT076_w {1} SE120_w {1} IT096_w {1} PT110_w {1} DE049_w {1} IT067_w {1} DE031_w {1} AT002_w {1} IT091_w {1} UK127_w {1} IT073_w {1} DE042_w {1} AT001_w {1} FR135_w {1} DE022_w {1} DE030_w {1} FR131_w {1} FR136_w {1} FR134_w {1} DE051_w {1} SE118_w {1} BE007_w {1} IT059_w {2} IT084_w {1} DE025_w {1} CZ020_w {1} IT065_w {1} BE010_w {1} BE013_w {1} IT082_w {1} CZ019_w {1} DE032_w {1} IT087_w {1} DE039_w {1} BE009_w {1} BE011_w {1} ES058_w {1} IT063_w {1} BE014_w {1} PT098_w {1} PT111_w {1} IT085_w {1} IT059_w {1} AT005_w {1} DE034_w {1} IT083_w {1} IT092_w {1} BE008_w {1} IT097_w {1} PT115_w {1} CZ017_w {1} IT070_w {1} IT088_w {1} AT003_w {1} IT076_w {1} SE120_w {1} IT096_w {1} PT110_w {1} DE049_w {1} IT067_w {1} DE031_w {1} AT002_w {1} IT091_w {1} UK127_w {1} IT073_w {1} DE042_w {1} AT001_w {1} FR135_w {1} DE022_w {1} DE030_w {1} FR131_w {1} FR136_w {1} FR134_w {1} DE051_w {1} SE118_w {1} 180 160 140 120 100 80 60 40 20 0 Point of discharge TOTAL P - Emissions to water 43 Other Anaerobic treatment Membrane bioreactor Distillation/rectification Reverse osmosis Chemical reduction Chemical oxidation Flotation Nanofiltration Microfiltration Ultrafiltration Evaporation Adsorption Activated sludge process Nitrification/denitrification Sand filtration Sedimentation Coagulation and flocculation Screening Grit separators Oil separation Neutralisation Equalisation No technique used BE007_w {1} IT059_w {2} IT084_w {1} DE025_w {1} CZ020_w {1} IT065_w {1} BE010_w {1} BE013_w {1} IT082_w {1} CZ019_w {1} DE032_w {1} IT087_w {1} DE039_w {1} BE009_w {1} BE011_w {1} ES058_w {1} IT063_w {1} BE014_w {1} PT098_w {1} PT111_w {1} IT085_w {1} IT059_w {1} AT005_w {1} DE034_w {1} IT083_w {1} IT092_w {1} BE008_w {1} IT097_w {1} PT115_w {1} CZ017_w {1} IT070_w {1} IT088_w {1} AT003_w {1} IT076_w {1} SE120_w {1} IT096_w {1} PT110_w {1} DE049_w {1} IT067_w {1} DE031_w {1} AT002_w {1} IT091_w {1} UK127_w {1} IT073_w {1} DE042_w {1} AT001_w {1} FR135_w {1} DE022_w {1} DE030_w {1} FR131_w {1} FR136_w {1} FR134_w {1} DE051_w {1} SE118_w {1} Techniques applied Average concentration over 3 years ELV (mg/l ) Max. load over 3 years (g/day) DIR IND IND DIR DIR IND DIR IND DIR DIR DIR IND IND DIR DIR IND IND DIR DIR DIR IND IND IND DIR IND DIR IND DIR IND IND IND IND IND IND IND DIR DIR IND DIR IND IND IND IND IND IND IND IND IND IND DIR IND DIR IND IND Freq Per Per Per Per Per Per Per Per Freq Per Per Per Per Per Freq Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Freq Freq Per Per Per Per Per Per Per Per Per Per Per Freq Per Per Per Per Per Per Freq Type of discharge Type of monitoring Mass load expressed in g/day Concentration expressed in mg/l 30,000 25,000 20,000 15,000 10,000 5,000 0 BE007_w {1} IT059_w {2} IT084_w {1} DE025_w {1} CZ020_w {1} IT065_w {1} BE010_w {1} BE013_w {1} IT082_w {1} CZ019_w {1} DE032_w {1} IT087_w {1} DE039_w {1} BE009_w {1} BE011_w {1} ES058_w {1} IT063_w {1} BE014_w {1} PT098_w {1} PT111_w {1} IT085_w {1} IT059_w {1} AT005_w {1} DE034_w {1} IT083_w {1} IT092_w {1} BE008_w {1} IT097_w {1} PT115_w {1} CZ017_w {1} IT070_w {1} IT088_w {1} AT003_w {1} IT076_w {1} SE120_w {1} IT096_w {1} PT110_w {1} DE049_w {1} IT067_w {1} DE031_w {1} AT002_w {1} IT091_w {1} UK127_w {1} IT073_w {1} DE042_w {1} AT001_w {1} FR135_w {1} DE022_w {1} DE030_w {1} FR131_w {1} FR136_w {1} FR134_w {1} DE051_w {1} SE118_w {1} BE007_w {1} IT059_w {2} IT084_w {1} DE025_w {1} CZ020_w {1} IT065_w {1} BE010_w {1} BE013_w {1} IT082_w {1} CZ019_w {1} DE032_w {1} IT087_w {1} DE039_w {1} BE009_w {1} BE011_w {1} ES058_w {1} IT063_w {1} BE014_w {1} PT098_w {1} PT111_w {1} IT085_w {1} IT059_w {1} AT005_w {1} DE034_w {1} IT083_w {1} IT092_w {1} BE008_w {1} IT097_w {1} PT115_w {1} CZ017_w {1} IT070_w {1} IT088_w {1} AT003_w {1} IT076_w {1} SE120_w {1} IT096_w {1} PT110_w {1} DE049_w {1} IT067_w {1} DE031_w {1} AT002_w {1} IT091_w {1} UK127_w {1} IT073_w {1} DE042_w {1} AT001_w {1} FR135_w {1} DE022_w {1} DE030_w {1} FR131_w {1} FR136_w {1} FR134_w {1} DE051_w {1} SE118_w {1} 20 18 16 14 12 10 8 6 4 2 0 Point of discharge TOTAL P - Emissions to water (zoom 0-20 mg/l) TOTAL P - EMISSIONS TO WATER EP water name BE007_w {1} IT059_w {2} Type of discharge DIR = Direct DIR IND IT084_w {1} IND DE025_w {1} DIR CZ020_w {1} DIR IT065_w {1} IND BE010_w {1} DIR BE013_w {1} IND IT082_w {1} DIR CZ019_w {1} DIR DE032_w {1} DIR IT087_w {1} IND DE039_w {1} IND BE009_w {1} DIR BE011_w {1} DIR ES058_w {1} IND IT063_w {1} IND BE014_w {1} DIR PT098_w {1} DIR PT111_w {1} DIR IT085_w {1} IND IT059_w {1} IND AT005_w {1} IND Associated processes Dyeing Thermal treatment - Functional finishing Bleaching - Dyeing - Thermal treatment Units for concentration values mg/l mg/l mg/l Min. concentration over 3 years Average concentration over 3 years Max. concentration over 3 years Max. load over 3 ELV (mg/l ) years (g/day) 0.14 0.219 0.23 0.239 0.1 0.13 0.4 Combination of techniques Type of sampling Equalisation, Neutralisation, Sand filtration, Activated sludge process, Nitrification/denitrification 20 No technique used 10 Equalisation, Neutralisation, Grit separators, Screening, Coagulation and flocculation, Sedimentation Flow proportional composite sample, Not applicable, Flow proportional composite sample Not applicable No information Washing synthetic fibre - Dyeing - Printing mg/l Dyeing mg/l 0 0.13 0.47 0.08 0.21 0.65 1 Equalisation, Neutralisation, Coagulation and flocculation, 24-hour flow proportional composite sample Sedimentation, Activated sludge process Sedimentation, Nitrification/denitrification, 2.5 Neutralisation, Coagulation and flocculation, Activated sludge process No information No information mg/l 0.75 0.78 0.8 Other No information Bleaching - Dyeing - Bleaching - Scouring - Functional mg/l finishing Mercerising mg/l Dyeing - Singeing - Functional finishing - Thermal mg/l treatment - Wool Fulling Bleaching - Dyeing - Printing - Functional finishing - mg/l Desizing Washing synthetic fibre - Desizing - Bleaching - Dyeing - mg/l Printing Dyeing - Shrink-proof finishing - Shrink-proof finishing - mg/l Other Mercerising - Dyeing - Washing synthetic fibre - mg/l Bleaching - Desizing Printing - Coating and laminating mg/l Dyeing mg/l Mercerising - Bleaching - Dyeing - Desizing - Fabric mg/l production - Printing - Thermal treatment Dyeing - Fabric production - Dry cleaning - Printing - mg/l Printing - Functional finishing Bleaching - Dyeing - Functional finishing mg/l Wool Fulling - Functional finishing - Dyeing - Thermal mg/l treatment Desizing - Dyeing - Fabric production - Wool Fulling Functional finishing - Shrink-proof finishing - Dry cleaning -mg/l Thermal treatment Dyeing mg/l Scouring - Mercerising - Bleaching - Dyeing - Singeing - mg/l Dry cleaning No information mg/l 0.2 0.57 0.91 0.3 0.60 1 0.198 0.53 1 1.20 0.35 0.81 1.4 0.62 1.01 1.4 0.47 1.07 1.66 0 0.56 1.67 0.33 0.77 1.7 2.09 0.66 1.20 2.1 0.18 1.24 2.2 0.15 1.05 2.4 0.33 1.20 2.4 2.1 2.27 2.4 0.68 1.64 2.59 0.37 1.17 2.6 4 EqualisationActivated sludge process, Nitrification/denitrification, Other Distillation/rectification, Equalisation, Neutralisation Equalisation, Neutralisation, Activated sludge process, 10 Nitrification/denitrification, Sedimentation, Adsorption (e.g. powdered/granular activated carbon, lignite coke, etc.), Other 2 Equalisation, Neutralisation, Anaerobic treatment, Nitrification/denitrification, Activated sludge process 24-hour flow proportional composite sample Flow proportional composite sample Not applicable No information Equalisation, Neutralisation, Grit separators, Coagulation and flocculation, Sedimentation, Sand filtration, 24-hour flow proportional composite sample Nitrification/denitrification, Activated sludge process 30 Equalisation Not applicable, Grab/spot sample, Not applicable Equalisation, Neutralisation Flow proportional composite sample Screening, Sedimentation, Equalisation, Activated sludge process, Sand filtration, Coagulation and flocculation, 2 Flotation, Chemical oxidation (incl. Advanced oxidation), Sand filtration, Chemical reduction, Microfiltration, Reverse osmosis Other, 24-hour flow proportional composite sample, Other Equalisation, Neutralisation, Coagulation and flocculation, 2 Activated sludge process, Nitrification/denitrification, Sand filtration, Nanofiltration, Chemical oxidation (incl. 24-hour flow proportional composite sample Advanced oxidation) No information No information 15 Equalisation 2 Equalisation, Activated sludge process, Nitrification/denitrification 10 Equalisation, Neutralisation, Sedimentation, Sand filtration, Activated sludge process, Other 10 Equalisation, Neutralisation, Activated sludge process, Sedimentation, Sand filtration, Other Other 24-hour flow proportional composite sample No information No information Equalisation Not applicable 20 Other 2 Neutralisation Not applicable No information Monitoring frequency Monthly Twice per year 4 times per year Monthly Monthly Twice per year Yearly Yearly Yearly Monthly Twice per year Other Twice per year No information No information 4 times per year 4 times per year No information Yearly 4 times per year Other Twice per year Twice per year DE034_w {1} DIR Washing synthetic fibre - Desizing - Bleaching - Dyeing mg/l 0.76 1.33 2.8 2 Activated sludge process, Nitrification/denitrification Flow proportional composite sample No information IT083_w {1} IND IT092_w {1} DIR BE008_w {1} IND IT097_w {1} DIR PT115_w {1} IND CZ017_w {1} IND IT070_w {1} IND IT088_w {1} IND AT003_w {1} IND IT076_w {1} IND SE120_w {1} IND IT096_w {1} DIR PT110_w {1} DIR DE049_w {1} IND IT067_w {1} DIR DE031_w {1} IND Scouring - Dyeing - Functional finishing mg/l Dyeing - Other mg/l Printing - Dyeing mg/l Dyeing - Shrink-proof finishing - Printing - Other mg/l No information mg/l Spinning - Fabric production - Singeing - Functional finishing - Shrink-proof finishing - Thermal treatment - mg/l Other No information mg/l Dyeing - Bleaching mg/l Mercerising - Dyeing - Desizing - Bleaching mg/l Raw wool scouring mg/l Washing synthetic fibre - Desizing - Bleaching mg/l Dyeing - Other mg/l Dyeing mg/l Desizing - Bleaching - Bleaching - Dyeing - Singeing Printing - Coating and laminating - Scouring - Functional mg/l finishing Dyeing - Printing - Other - Shrink-proof finishing mg/l Dyeing mg/l 1.6 2.23 2.85 0.3 1.24 2.9 1.6 2.09 3.1 0.1 1.99 3.32 2.2 3.80 4.7 1.95 3.29 4.93 0.03 2.26 5.7 0.03 1.13 5.7 3.1 4.39 6.7 0.38 2.81 6.85 1.4 3.80 2.3 4.67 6.9 3808.8 7 1.1 4.50 7.1 3.8 5.37 8 0.1 1.70 8 0.47 3.87 9.32 10 Other Equalisation, Neutralisation, Activated sludge process, 10 Nitrification/denitrification, Sedimentation, Reverse osmosis 6 Equalisation, Grit separators, Other Not applicable Not applicable 24-hour flow proportional composite sample 10 Equalisation, Neutralisation, Activated sludge process, Nitrification/denitrification, Sedimentation Not applicable Equalisation, Neutralisation, Screening 24-hour flow proportional composite sample No information No information 20 No information 20 No information 10 Other Not applicable Not applicable Other Equalisation, Flotation, Coagulation and flocculation, 10 Activated sludge process, Nitrification/denitrification, Sedimentation, Membrane bioreactor Not applicable 6 Neutralisation, Oil separation, Equalisation 24-hour flow proportional composite sample 10 Equalisation, Neutralisation, Activated sludge process, Nitrification/denitrification, Sedimentation, Other No information Equalisation, Grit separators, Screening, Coagulation and 10 flocculation, Sedimentation, Activated sludge process, No information Other Equalisation, Neutralisation 24-hour flow proportional composite sample 10 Equalisation, Neutralisation, Activated sludge process, Nitrification/denitrification, Sedimentation No information Not applicable No information Twice per year Monthly No information Other Yearly Yearly Twice per year Twice per year 4 times per year Weekly Continuous Yearly Monthly Yearly Monthly Other 44 Monitoring standard WAC/III/B011 of WAC/III/B010- WAC/III/B002 APAT CNR IRSA 5030 Man 29 2003 ALPHA St. Mth. For the Examination of water snd wastewater ed 23 rd 2017, 4500-P B + 4500 P E DIN EN ISO 6878 (D11):2004-2005-2006 specified in extern laboratory ISO 6878:2004 WAC/III/B011 of WAC/III/B010- WAC/III/B002 MEIN039 IRSA 4110-A2:2003, IRSA 4110-A2:2003, IRSA 3010 +3020* No information No information No information No information WAC/III/C/010 Additional information 3 h medium composite sample - 3 h medium composite sample - 3 h medium composite sample Requested by Italian Law,and other analyses introduced during 2018 to follow the ZDHC Waste Water Guide lines sample 22.10.2015-23.10.2015 Monitoring frequency: spot Less than 12/year flow proportionate sampling, >12/year are grab sample results. Value 0 means results beneath detection limit of analyses WAC/III/B011 of WAC/III/B010- WAC/III/B002 No information No information WAC/III/B011 of WAC/III/B010- WAC/III/B002 POQ 15 Edio 10, W-PTOT-SPC, PNT-MA/FQ2-09(201703-20) - MESU.1 - 0,601 mg/l - < LD SMEWW 4500 P No information Monitoring end frequency dependent on the operator of the off-site treatment plant APAT CNR IRSA 5030 Man 29 2003 DIN EN ISO 11885DIN EN ISO 11885 No information under mesurement 1,.. you find the measured values from the authority surveillance - under mesurement 1,.. you find the measured values from the authority surveillance - under mesurement 1,.. you find the measured values from the authority surveillance APAT CNR IRSA 3010 Man 29 2003+APAT CNR IRSA 3020 Man 29 2003 IRSA 3010+3020:2003, EPA 3005A 1992 + EPA 6010D 2014, EPA 3005A 1992 + EPA 6010D 2014 Value refered to sampling period - Value refered to sampling period - Value refered to sampling period WAC/III/B011 of WAC/III/B010- WAC/III/B002 APAT CNR IRSA 3020 Man 29 2003, IRSA 4110/A2, IRSA 4110/A2 SMEWW 4500 P Monitoring frequency: once every 4 monthsValue refered to sampling periodMeasurement 2 is inferior to detection limit: <0,1 - Monitoring frequency: once every 4 monthsValue refered to sampling period - Monitoring frequency: once every 4 monthsValue refered to sampling period Environmetal Permit - Environmetal Permit Environmetal Permit No information APAT-IRSA CNR 29-2003 4110 apat irsa cnr 29/2003 4110 DIN EN ISO 11885DIN EN ISO 11885 Yearly - Yearly - Yearly EPA 3005A 1992 + EPA 6010D 2014; IRSA 4110/A2 Value refered to sampling period - Value refered to sampling period - Value refered to sampling period No information Quartely APAT CNR IRSA 4110/A2 Man 29 2003, APAT CNR IRSA Value refered to sampling period - Value refered to 4110/A2 Man 29 2003, APAT CNR IRSA 3020 Man 29 2003 sampling period - Value refered to sampling period No information DIN APAT CNR IRSA 3020 Man 29 2003 DIN EN ISO 6878 Value refered to sampling period - Value refered to sampling period - Value refered to sampling period 3 tests/year - 3 tests/year - 3 tests/year 1 TOTAL P - EMISSIONS TO WATER EP water name AT002_w {1} Type of discharge DIR = Direct IND IT091_w {1} IND UK127_w {1} IND IT073_w {1} IND DE042_w {1} IND SE119_w {1} IND AT001_w {1} IND FR135_w {1} IND DE022_w {1} IND DE030_w {1} IND FR131_w {1} DIR FR136_w {1} IND FR134_w {1} DIR DE051_w {1} IND SE118_w {1} IND Associated processes No information Scouring - Dyeing - Functional finishing - Thermal treatment - Other Mercerising - Bleaching - Dyeing - Scouring - Singeing Printing Dyeing - Functional finishing Washing synthetic fibre - Desizing - Bleaching - Dyeing Functional finishing Washing synthetic fibre - Desizing - Functional finishing Dyeing Units for concentration values mg/l mg/l Min. concentration over 3 years Average concentration over 3 years Max. concentration over 3 years Max. load over 3 ELV (mg/l ) years (g/day) 3.9 5.91 10 2.5 5.60 11 mg/l 5.71 8.46 11.2 mg/l 3.1 8.15 13.7 mg/l 2.2 6.56 16 No unit reported 3.2 5.40 17 Combination of techniques No information 20 No information Neutralisation 20 No technique used Neutralisation, Equalisation No technique used Type of sampling No information Other 24-hour flow proportional composite sample Other 24-hour flow proportional composite sample 24-hour flow proportional composite sample No information mg/l 2.4 8.98 17 20 No information 24-hour flow proportional composite sample Washing synthetic fibre mg/l 7.5 11.76 17.6 3660.8 10 Grit separators 24-hour flow proportional composite sample Raw wool scouring - Washing synthetic fibre - Desizing - Scouring - Bleaching - Dyeing - Thermal treatment - mg/l Functional finishing - Coating and laminating 0.31 6.51 20 15 Neutralisation, Oil separation, Evaporation Other Washing synthetic fibre - Desizing - Mercerising - Bleaching - Singeing - Dyeing - Functional finishing - mg/l Thermal treatment Washing synthetic fibre - Bleaching - Dyeing - Printing - Functional finishing - Coating and laminating - Thermal mg/l treatment Desizing - Scouring - Bleaching - Mercerising - Dyeing - mg/l Singeing - Fabric production - Functional finishing Washing synthetic fibre - Desizing - Mercerising - mg/l Bleaching - Dyeing - Singeing - Functional finishing Washing synthetic fibre - Scouring - Bleaching - Dyeing - mg/l Functional finishing Washing synthetic fibre - Scouring - Scouring - Bleaching - Dyeing - Singeing - Printing - Functional finishing - Shrink- mg/l proof finishing - Coating and laminating - Thermal treatment 5.4 11.14 6.4 12.12 5 20.17 14 28.50 3.3 7.68 3.7 14.30 25 26 45 46 60 77 27104 Equalisation, Neutralisation, Screening 24-hour flow proportional composite sample 10 Other 24-hour flow proportional composite sample 160 Grit separators, Neutralisation No information 10 Equalisation, Neutralisation, Grit separators, Activated sludge process, Anaerobic treatment No information Neutralisation, Coagulation and flocculation, Equalisation No information 8 Sedimentation, Neutralisation 24-hour flow proportional composite sample Monitoring frequency No information No information No information Twice per year 4 times per year No information 4 times per year Monthly Monthly 4 times per year Monthly No information 4 times per year Monthly Weekly Monitoring standard DIN EN ISO 11885 INTERNAL MHETOD No information Metodo interno n33 No information No information DIN EN ISO 11885DIN EN ISO 11885 No information DIN DIN NF EN ISO 11885 No information No information No information No information Additional information AVERAGE PERIOD 3 HOURS - AVERAGE PERIOD 3 HOURS AVERAGE PERIOD 3 HOURS 5; one additional control measurement local authority Limit on yearly basis: 6 kg/dayriktvrde: 8 mg/l three months average 45 2 NH4-N - Emissions to water 30 Concentration expressed in mg/l 25 20 Average concentration over 3 years 15 ELV (mg/l ) 10 5 IT096_w {1} BE010_w {1} IT082_w {1} UK124_w {2} UK124_w {4} CZ019_w {1} DE032_w {1} DE034_w {1} BE014_w {1} IT097_w {1} DE025_w {1} IT092_w {1} IT067_w {1} CZ020_w {1} BE009_w {1} 0 Point of discharge Type of discharge DIR DIR DIR DIR DIR DIR DIR DIR DIR DIR DIR DIR DIR DIR DIR Type of monitoring Per Per Per Per Per Freq Per Freq Per Per Per Per Per Per Freq Mass load expressed in g/day 8,000 7,000 6,000 5,000 4,000 3,000 2,000 1,000 0 Max. load over 3 years (g/day) IT096_w {1} BE010_w {1} IT082_w {1} UK124_w {2} UK124_w {4} CZ019_w {1} DE032_w {1} DE034_w {1} BE014_w {1} IT097_w {1} DE025_w {1} IT092_w {1} IT067_w {1} CZ020_w {1} BE009_w {1} Techniques applied Other Anaerobic treatment Membrane bioreactor Distillation/rectification Reverse osmosis Chemical reduction Chemical oxidation Flotation Nanofiltration Microfiltration Ultrafiltration Evaporation Adsorption Activated sludge process Nitrification/denitrification Sand filtration Sedimentation Coagulation and flocculation Screening Grit separators Oil separation Neutralisation Equalisation No technique used IT096_w {1} BE010_w {1} IT082_w {1} UK124_w {2} UK124_w {4} CZ019_w {1} DE032_w {1} DE034_w {1} BE014_w {1} IT097_w {1} DE025_w {1} IT092_w {1} IT067_w {1} CZ020_w {1} BE009_w {1} 46 NH4-N - Emissions to water (zoom 0-3 mg/l) 3.0 Concentration expressed in mg/l 2.5 2.0 Average concentration over 3 years 1.5 ELV (mg/l ) 1.0 0.5 IT096_w {1} BE010_w {1} IT082_w {1} UK124_w {2} UK124_w {4} CZ019_w {1} DE032_w {1} DE034_w {1} BE014_w {1} IT097_w {1} DE025_w {1} IT092_w {1} IT067_w {1} CZ020_w {1} BE009_w {1} 0.0 Point of discharge Type of discharge DIR DIR DIR DIR DIR DIR DIR DIR DIR DIR DIR DIR DIR DIR DIR Type of monitoring Per Per Per Per Per Freq Per Freq Per Per Per Per Per Per Freq Mass load expressed in g/day 8,000 7,000 6,000 5,000 4,000 3,000 2,000 1,000 0 Max. load over 3 years (g/day) IT096_w {1} BE010_w {1} IT082_w {1} UK124_w {2} UK124_w {4} CZ019_w {1} DE032_w {1} DE034_w {1} BE014_w {1} IT097_w {1} DE025_w {1} IT092_w {1} IT067_w {1} CZ020_w {1} BE009_w {1} Techniques applied Other Anaerobic treatment Membrane bioreactor Distillation/rectification Reverse osmosis Chemical reduction Chemical oxidation Flotation Nanofiltration Microfiltration Ultrafiltration Evaporation Adsorption Activated sludge process Nitrification/denitrification Sand filtration Sedimentation Coagulation and flocculation Screening Grit separators Oil separation Neutralisation Equalisation No technique used IT096_w {1} BE010_w {1} IT082_w {1} UK124_w {2} UK124_w {4} CZ019_w {1} DE032_w {1} DE034_w {1} BE014_w {1} IT097_w {1} DE025_w {1} IT092_w {1} IT067_w {1} CZ020_w {1} BE009_w {1} 47 NH4-N - EMISSIONS TO WATER EP water name IT059_w {1} Type of discharge DIR = Direct IND IT096_w {1} DIR PT114_w {1} IND BE010_w {1} DIR IT082_w {1} DIR UK124_w {2} DIR UK124_w {4} DIR CZ019_w {1} DIR IT074_w {1} IND IT079_w {1} IND Associated processes Scouring - Mercerising - Bleaching - Dyeing - Singeing Dry cleaning Units for concentration values mg/l Dyeing - Other mg/l Mercerising - Dyeing - Washing synthetic fibre - Desizing - mg/l Scouring - Bleaching - - Thermal treatment - Dry cleaning Bleaching - Dyeing - Bleaching - Scouring - Functional mg/l finishing Dyeing - Singeing - Functional finishing - Thermal mg/l treatment - Wool Fulling No information mg/l Min. concentration over 3 years Average concentration over 3 years Max. concentration over 3 years Max. load over 3 ELV (mg/l ) years (g/day) Combination of techniques 0.1 0.10 0.1 100 Other Type of sampling Not applicable 0.1 0.10 0.1 0.04 0.09 0.19 0.06 0.15 0.25 0 0.17 0.33 0.5 0.50 0.5 15 Equalisation, Neutralisation, Activated sludge process, Nitrification/denitrification, Sedimentation, Other No information Equalisation, Neutralisation, Screening, Coagulation and 100 flocculation, Sedimentation, Sand filtration, Adsorption (e.g. powdered/granular activated carbon, lignite coke, etc.) EqualisationActivated sludge process, Nitrification/denitrification, Other Equalisation, Neutralisation, Activated sludge process, 15 Nitrification/denitrification, Sedimentation, Adsorption (e.g. powdered/granular activated carbon, lignite coke, etc.), Other No information 24-hour flow proportional composite sample Not applicable No information No information No information mg/l Bleaching - Dyeing - Printing - Functional finishing - mg/l Desizing Washing synthetic fibre - Scouring - Functional finishing - mg/l Dry cleaning - Other 0.5 0.50 0.5 0.60 0.2 0.50 0.9 No information 2 Equalisation, Neutralisation, Anaerobic treatment, Nitrification/denitrification, Activated sludge process 100 Other No information No information Other Scouring - Wool Fulling - Functional finishing - Thermal mg/l treatment - Other 0.1 0.58 1.4 100 Other 24-hour flow proportional composite sample IT069_w {1} IND DE032_w {1} DIR IT094_w {1} IND DE034_w {1} DIR IT070_w {1} IND IT091_w {1} IND DE042_w {1} IND DE045_w {1} IND IT059_w {2} IND BE014_w {1} DIR IT073_w {1} IND Scouring - Bleaching - Mercerising mg/l Washing synthetic fibre - Desizing - Bleaching - Dyeing - mg/l Printing No information mg/l Washing synthetic fibre - Desizing - Bleaching - Dyeing mg/l No information mg/l Scouring - Dyeing - Functional finishing - Thermal mg/l treatment - Other Washing synthetic fibre - Desizing - Bleaching - Dyeing - mg/l Functional finishing Washing synthetic fibre - Desizing - Desizing mg/l Thermal treatment - Functional finishing mg/l Bleaching - Dyeing - Functional finishing mg/l Dyeing - Functional finishing mg/l 0.1 0.60 1.5 0.19 0.96 1.9 0.27 0.91 0.2 0.70 0.06 1.81 0.8 1.88 2 2.2 939.4 3.1 3.3 0.39 1.59 3.7 3.90 0.1 2.05 4 3.06 3.77 4.51 1.4 2.83 4.8 100 Other Other Equalisation, Neutralisation, Grit separators, Coagulation and flocculation, Sedimentation, Sand filtration, 24-hour flow proportional composite sample Nitrification/denitrification, Activated sludge process Other No information Activated sludge process, Nitrification/denitrification Flow proportional composite sample 100 No information Not applicable 100 No information Other Neutralisation, Equalisation No information 100 No technique used Equalisation, Activated sludge process, Nitrification/denitrification 100 No technique used 24-hour flow proportional composite sample 24-hour flow proportional composite sample Not applicable 24-hour flow proportional composite sample Other IT097_w {1} DIR Dyeing - Shrink-proof finishing - Printing - Other mg/l 0.1 1.08 5.2 15 Equalisation, Neutralisation, Activated sludge process, Nitrification/denitrification, Sedimentation Not applicable IT083_w {1} IND PT105_w {1} IND IT077_w {1} IND DE025_w {1} DIR PT109_w {1} IND IT092_w {1} DIR PT113_w {1} IND IT068_w {1} IND IT074_w {2} IND ES058_w {1} IND IT072_w {1} IND IT077_w {2} IND IT063_w {1} IND IT084_w {1} IND IT090_w {1} IND IT088_w {1} IND IT067_w {1} DIR CZ020_w {1} DIR IT089_w {1} IND Scouring - Dyeing - Functional finishing Dyeing - Bleaching Desizing - Mercerising - Scouring - Bleaching - Singeing Thermal treatment mg/l mg/l No unit reported Washing synthetic fibre - Dyeing - Printing mg/l No information mg/l Dyeing - Other mg/l Dyeing - Washing synthetic fibre - Bleaching - Functional mg/l finishing Washing synthetic fibre - Desizing - Scouring - Bleaching - mg/l Dyeing - Functional finishing - Other Washing synthetic fibre - Scouring Mercerising - Bleaching - Dyeing - Desizing - Fabric production - Printing - Thermal treatment Thermal treatment - Scouring - Bleaching - Dyeing Other Dyeing Dyeing - Fabric production - Dry cleaning - Printing Printing - Functional finishing mg/l mg/l mg/l No unit reported mg/l Bleaching - Dyeing - Thermal treatment mg/l Scouring - Dyeing - Thermal treatment - Other - mg/l Bleaching Dyeing - Bleaching mg/l Dyeing - Printing - Other - Shrink-proof finishing mg/l Dyeing mg/l Scouring - Dyeing - Thermal treatment - Other - mg/l Bleaching 0.5 2.37 5.2 5.8 5.80 5.8 0.5 2.37 5.8 0.34 2.08 6 6 6.00 6 0.03 1.28 6.5 4.49 5.39 6.76 0.1 2.92 6.8 0.1 1.62 7 7.13 2.2 4.65 9.1 0.1 2.43 9.3 1 5.92 11 0.06 3.16 12 1.1 3.38 12.7 0.1 2.95 13.2 0.1 3.46 14.6 0.03 1.77 19 1.6 11.32 23.5 30 Other No information Not applicable No information 100 No information Other 5 Equalisation, Neutralisation, Coagulation and flocculation, 24-hour flow proportional composite sample Sedimentation, Activated sludge process 100 Oil separation, Neutralisation Equalisation, Neutralisation, Activated sludge process, 15 Nitrification/denitrification, Sedimentation, Reverse osmosis No information Not applicable 100 No information Other 100 Other Other 100 Other Other No information No information 100 Other Other 100 No information Other 30 Equalisation Other 15 Equalisation, Neutralisation, Grit separators, Screening, No information Coagulation and flocculation, Sedimentation 100 Other 24-hour flow proportional composite sample 100 No information 15 Equalisation, Neutralisation, Activated sludge process, Nitrification/denitrification, Sedimentation Sedimentation, Nitrification/denitrification, 10 Neutralisation, Coagulation and flocculation, Activated sludge process Not applicable Not applicable No information 100 Other 24-hour flow proportional composite sample Monitoring frequency Twice per year Yearly Yearly Other 4 times per year Monthly Yearly Monthly No information Twice per year Twice per year Twice per year Twice per year No information Twice per year No information 4 times per year Twice per year Twice per year No information Twice per year Other Twice per year Yearly Twice per year Monthly Yearly Monthly Yearly Twice per year No information 4 times per year Twice per year Twice per year 4 times per year 4 times per year Twice per year Twice per year Monthly Monthly Twice per year 48 Monitoring standard APAT CNR IRSA 5030 Man 29 2003 APAT CNR IRSA 3030 Man 29 2003 Additional information Value refered to sampling period - Value refered to sampling period - Value refered to sampling period No information No information IRSA 4030-A1:2003 nutrients - determined colourimetrically by autoanalyser Each of the values reported as <0.5 nutrients - determined colourimetrically by autoanalyser All values reported as <0.5 - All values reported as <0.5 All values reported as <0.5 No information APAT CNR IRSA 4030 MAN 29 2003 AVERAGE PERIOD 3 HOURS - AVERAGE PERIOD 3 HOURS AVERAGE PERIOD 3 HOURS (YEAR 2015) APAT CNR IRSA 4030 MAN 29 2003 ELV is referred to 3 hours sampled waste water - ELV is referred to 3 hours sampled waste water - ELV is referred to 3 hours sampled waste water. Data related to 2015. APAT CNR IRSA 4030 MAN 29 2003 Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours (data referring to the year 2015) No information APAT IRSA 5030 Volume 2:2003 No information APAT-IRSA CNR 29-2003 4030 APAT CNR IRSA 4030 MAN 29 2003 No information No information APAT CNR IRSA 5030 Man 29 2003 No information ARPAT CNR IRSA 4030 MAN 29 2003 APAT CNR IRSA 3030 Man 29 2003, IRSA 4030/C, IRSA 4030/C APAT CNR IRSA 4030 A2/C Man 29 2003 No information APAT CNR IRSA 4030 MAN 29 2003 DIN EN ISO 11732 (E23) No information EPA 350.1 1993 No information APAT CNR IRSA 4030 MAN 29 2003 APAT CNR IRSA 4030 MAN 29 2003 No information APAT CNR IRSA 4030 MAN 29 2003 APAT CNR IRSA 4030 MAN 29 2003 No information APAT CNR IRSA 4030 A2 Man. 29 2003 APAT CNR IRSA 4030 MAN 29 2003 apat irsa cnr 29/2003 4030 APAT CNR IRSA 3030 Man 29 2003 specified in extern laboratory - qualified sample - AVERAGE PERIOD 3 HOURS - AVERAGE PERIOD 3 HOURS AVERAGE PERIOD 3 HOURS Monitoring frequency: once every 4 monthsValue refered to sampling period - Monitoring frequency: once every 4 monthsValue refered to sampling periodMeasurements 1,2,3 are inferior to detection limit: <0,5 - Monitoring frequency: once every 4 monthsValue refered to sampling periodMeasurements 2,3 are inferior to detection limit: <0,5 The installation only started operating in 2017.The value of uncertainty is not refered in the reports. Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours Value refered to sampling period - Value refered to sampling period - Value refered to sampling period Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours (data referring to the year 2015) AVERAGE PERIOD 3 HOURS - AVERAGE PERIOD 3 HOURS AVERAGE PERIOD 3 HOURS (YEAR 2015) Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours 3 h medium composite sample - 3 h medium composite sample - 3 h medium composite sample ELV is referred to 3 hours sampled waste water - ELV is referred to 3 hours sampled waste water - ELV is referred to 3 hours sampled waste water. Data related to 2015. Yearly - Yearly - Yearly Value refered to sampling period - Value refered to sampling period - Value refered to sampling period APAT CNR IRSA 4030 MAN 29 2003 ELV is referred to 3 hours sampled waste water - ELV is referred to 3 hours sampled waste water - ELV is referred to 3 hours sampled waste water. Data related to 2015. 1 NH4-N - EMISSIONS TO WATER EP water name Type of discharge DIR = Direct BE009_w {1} DIR IT064_w {1} IND IT076_w {1} IND IT071_w {2} IND IT071_w {1} IND PT110_w {2} IND SE118_w {1} IND IT065_w {1} IND IT087_w {1} IND IT075_w {1} IND IT085_w {1} IND SE120_w {1} IND Associated processes Printing - Coating and laminating Scouring Units for concentration values mg/l mg/l Min. concentration over 3 years Average concentration over 3 years Max. concentration over 3 years Max. load over 3 ELV (mg/l ) years (g/day) 0.16 10.59 27.2 6816.4016 Combination of techniques Type of sampling Screening, Sedimentation, Equalisation, Activated sludge process, Sand filtration, Coagulation and flocculation, Flotation, Chemical oxidation (incl. Advanced oxidation), Sand filtration, Chemical reduction, Microfiltration, Reverse osmosis Other, 24-hour flow proportional composite sample, Other 6.8 12.68 28.5 100 Other Other Raw wool scouring mg/l 1.2 4.70 32.6 Equalisation, Flotation, Coagulation and flocculation, 200 Activated sludge process, Nitrification/denitrification, Sedimentation, Membrane bioreactor Not applicable Dyeing - Other - Functional finishing mg/l 1.1 12.37 33.7 100 Other Other Dyeing - Bleaching - Scouring mg/l Dyeing mg/l Washing synthetic fibre - Scouring - Scouring - Bleaching - Dyeing - Singeing - Printing - Functional finishing - Shrink- mg/l proof finishing - Coating and laminating - Thermal treatment 17 23.83 0.15 4.26 0.82 10.40 35 38 42 14784 100 No information 100 Equalisation, Grit separators, Screening Sedimentation, Neutralisation Other No information 24-hour flow proportional composite sample No information mg/l 0.1 8.88 52 Other No information Dyeing - Shrink-proof finishing - Shrink-proof finishing - mg/l Other 32 56.25 82.6 70.9 Equalisation Not applicable, Grab/spot sample, Not applicable Raw wool scouring mg/l 0.09 23.84 106 Equalisation, Coagulation and flocculation, Activated 80 sludge process, Nitrification/denitrification, Sedimentation Not applicable Dyeing mg/l Washing synthetic fibre - Desizing - Bleaching mg/l 82 91.45 0.2 925.00 115 25 12275 Equalisation Neutralisation, Oil separation, Equalisation Not applicable 24-hour flow proportional composite sample Monitoring frequency No information Twice per year Weekly Twice per year Twice per year 4 times per year Weekly Twice per year Monthly Other Other Continuous Monitoring standard No information APAT CNR IRSA 4030 MAN 29 2003 ARPAT CNR IRSA 4030 MAN 29 2003 APAT CNR IRSA 4030 MAN 29 2003 APAT CNR IRSA 4030 MAN 29 2003 No information No information ARPAT CNR IRSA 4030 a2 Man 29 2003 No information No information EPA 350,1 1993 No information Additional information Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours Value refered to sampling period - Value refered to sampling period - Value refered to sampling period Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours Requested by Italian Law - Requested by Italian Law Requested by Italian Law,and other analyses introduced during 2018 to follow the ZDHC Waste Water Guide lines Value refered to sampling period - Value refered to sampling period - Value refered to sampling period Monitoring end frequency dependent on the operator of the off-site treatment plant - Monitoring end frequency dependent on the operator of the off-site treatment plant - Monitoring end frequency dependent on the operator of the off-site treatment plant 49 2 50 Other Anaerobic treatment Membrane bioreactor Distillation/rectification Reverse osmosis Chemical reduction Chemical oxidation Flotation Nanofiltration Microfiltration Ultrafiltration Evaporation Adsorption Activated sludge process Nitrification/denitrification Sand filtration Sedimentation Coagulation and flocculation Screening Grit separators Oil separation Neutralisation Equalisation No technique used DE025_w {1} IT097_w {1} IT092_w {1} ES058_w {1} BE007_w {1} PT115_w {1} PT108_w {1} PT099_w {1} IT063_w {1} IT059_w {1} PT104_w {1} PT113_w {1} PT114_w {2} IT065_w {1} AT002_w {1} PT114_w {1} IT088_w {1} AT005_w {1} AT004_w {1} AT006_w {1} IT070_w {1} IT071_w {2} IT091_w {1} IT078_w {1} IT064_w {1} IT059_w {2} IT071_w {1} IT068_w {1} IT074_w {1} IT069_w {1} IT074_w {2} AT001_w {1} FR135_w {1} Techniques applied Max. load over 3 years (g/day) Per Type of discharge Type of monitoring IND Mass load expressed in g/day Concentration expressed in mg/l 50 1.0 0.8 0.6 0.4 0.2 0.0 DIR Per DE025_w {1} IT097_w {1} IT092_w {1} ES058_w {1} BE007_w {1} PT115_w {1} PT108_w {1} PT099_w {1} IT063_w {1} IT059_w {1} PT104_w {1} PT113_w {1} PT114_w {2} IT065_w {1} AT002_w {1} PT114_w {1} IT088_w {1} AT005_w {1} AT004_w {1} AT006_w {1} IT070_w {1} IT071_w {2} IT091_w {1} IT078_w {1} IT064_w {1} IT059_w {2} IT071_w {1} IT068_w {1} IT074_w {1} IT069_w {1} IT074_w {2} AT001_w {1} FR135_w {1} Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Freq Freq Per Per IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND DIR IND DIR DIR DE025_w {1} IT097_w {1} IT092_w {1} ES058_w {1} BE007_w {1} PT115_w {1} PT108_w {1} PT099_w {1} IT063_w {1} IT059_w {1} PT104_w {1} PT113_w {1} PT114_w {2} IT065_w {1} AT002_w {1} PT114_w {1} IT088_w {1} AT005_w {1} AT004_w {1} AT006_w {1} IT070_w {1} IT071_w {2} IT091_w {1} IT078_w {1} IT064_w {1} IT059_w {2} IT071_w {1} IT068_w {1} IT074_w {1} IT069_w {1} IT074_w {2} AT001_w {1} FR135_w {1} 0 Point of discharge 200 Average concentration 150 over 3 years ELV (mg/l ) 100 250 HYDROCARBON OIL INDEX - Emissions to water 51 Other Anaerobic treatment Membrane bioreactor Distillation/rectification Reverse osmosis Chemical reduction Chemical oxidation Flotation Nanofiltration Microfiltration Ultrafiltration Evaporation Adsorption Activated sludge process Nitrification/denitrification Sand filtration Sedimentation Coagulation and flocculation Screening Grit separators Oil separation Neutralisation Equalisation No technique used DE025_w {1} IT097_w {1} IT092_w {1} ES058_w {1} BE007_w {1} PT115_w {1} PT108_w {1} PT099_w {1} IT063_w {1} IT059_w {1} PT104_w {1} PT113_w {1} PT114_w {2} IT065_w {1} AT002_w {1} PT114_w {1} IT088_w {1} AT005_w {1} AT004_w {1} AT006_w {1} IT070_w {1} IT071_w {2} IT091_w {1} IT078_w {1} IT064_w {1} IT059_w {2} IT071_w {1} IT068_w {1} IT074_w {1} IT069_w {1} IT074_w {2} AT001_w {1} FR135_w {1} Techniques applied Average concentration over 3 years ELV (mg/l ) Max. load over 3 years (g/day) Per Type of discharge Type of monitoring IND Mass load expressed in g/day Concentration expressed in mg/l 1.0 0.8 0.6 0.4 0.2 0.0 DIR Per DE025_w {1} IT097_w {1} IT092_w {1} ES058_w {1} BE007_w {1} PT115_w {1} PT108_w {1} PT099_w {1} IT063_w {1} IT059_w {1} PT104_w {1} PT113_w {1} PT114_w {2} IT065_w {1} AT002_w {1} PT114_w {1} IT088_w {1} AT005_w {1} AT004_w {1} AT006_w {1} IT070_w {1} IT071_w {2} IT091_w {1} IT078_w {1} IT064_w {1} IT059_w {2} IT071_w {1} IT068_w {1} IT074_w {1} IT069_w {1} IT074_w {2} AT001_w {1} FR135_w {1} Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Freq Freq Per Per IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND DIR IND DIR DIR DE025_w {1} IT097_w {1} IT092_w {1} ES058_w {1} BE007_w {1} PT115_w {1} PT108_w {1} PT099_w {1} IT063_w {1} IT059_w {1} PT104_w {1} PT113_w {1} PT114_w {2} IT065_w {1} AT002_w {1} PT114_w {1} IT088_w {1} AT005_w {1} AT004_w {1} AT006_w {1} IT070_w {1} IT071_w {2} IT091_w {1} IT078_w {1} IT064_w {1} IT059_w {2} IT071_w {1} IT068_w {1} IT074_w {1} IT069_w {1} IT074_w {2} AT001_w {1} FR135_w {1} 50 45 40 35 30 25 20 15 10 5 0 Point of discharge HYDROCARBON OIL INDEX - Emissions to water (zoom 0-50 mg/l) HYDROCARBON OIL INDEX - EMISSIONS TO WATER EP water name Type of discharge DIR = Direct DE025_w {1} DIR IT097_w {1} DIR IT092_w {1} DIR ES058_w {1} IND BE007_w {1} DIR PT115_w {1} IND PT108_w {1} IND PT099_w {1} IND IT063_w {1} IND IT059_w {1} IND PT104_w {1} IND PT113_w {1} IND PT114_w {2} IND IT065_w {1} IND Associated processes Washing synthetic fibre - Dyeing - Printing Dyeing - Shrink-proof finishing - Printing - Other Dyeing - Other Mercerising - Bleaching - Dyeing - Desizing - Fabric production - Printing - Thermal treatment Dyeing No information Fabric production - Fabric production Units for concentration values mg/l mg/l mg/l mg/l mg/l mg/l Min. concentration over 3 years Average concentration over 3 years Max. concentration over 3 years Max. load over 3 ELV (mg/l ) years (g/day) 0 0 0 0.03 0.03 0.03 0.03 0.03 0.03 0.32 0.93 0.04 1.41 2.48 Combination of techniques Type of sampling 2 Equalisation, Neutralisation, Coagulation and flocculation, 24-hour flow proportional composite sample Sedimentation, Activated sludge process Equalisation, Neutralisation, Activated sludge process, Nitrification/denitrification, Sedimentation Equalisation, Neutralisation, Activated sludge process, Nitrification/denitrification, Sedimentation, Reverse osmosis Not applicable Not applicable No information No information Equalisation, Neutralisation, Sand filtration, Activated sludge process, Nitrification/denitrification 50 Equalisation, Neutralisation, Screening Flow proportional composite sample, Not applicable, Flow proportional composite sample 24-hour flow proportional composite sample mg/l 0.3 2.58 4 50 Neutralisation, Sand filtration, Sand filtration 24-hour flow proportional composite sample Dyeing - Printing - Functional finishing mg/l Dyeing - Fabric production - Dry cleaning - Printing - mg/l Printing - Functional finishing Scouring - Mercerising - Bleaching - Dyeing - Singeing - mg/l Dry cleaning Dyeing - Bleaching mg/l Dyeing - Washing synthetic fibre - Bleaching - Functional mg/l finishing No information mg/l 1 1.64 5.7 0.5 1.69 5.7 3.2 4.37 6 0.23 2.51 7 2 3.67 7 5 5.67 7 15 Screening, Oil separation, Other Equalisation 200 Other No information 50 No information 50 No information No information Other Not applicable 24-hour flow proportional composite sample Other No information No information mg/l 2.5 5.53 9.4 Other No information Monitoring frequency Other Other Other 4 times per year Monthly Yearly Yearly 4 times per year 4 times per year Twice per year Yearly Yearly Yearly Twice per year AT002_w {1} IND PT114_w {1} IND IT088_w {1} IND AT005_w {1} IND DE022_w {1} IND AT004_w {1} IND AT006_w {1} IND IT070_w {1} IND IT071_w {2} IND IT091_w {1} IND IT078_w {1} IND IT064_w {1} IND IT059_w {2} IND IT071_w {1} IND IT068_w {1} IND IT074_w {1} IND IT069_w {1} IND IT074_w {2} IND AT001_w {1} IND FR135_w {1} IND No information mg/l Mercerising - Dyeing - Washing synthetic fibre - Desizing Scouring - Bleaching - - Thermal treatment - Dry cleaning mg/l Dyeing - Bleaching No information Raw wool scouring - Washing synthetic fibre - Desizing Scouring - Bleaching - Dyeing - Thermal treatment Functional finishing - Coating and laminating mg/l mg/l No unit reported Washing synthetic fibre mg/l Bleaching - Dyeing mg/l No information mg/l Dyeing - Other - Functional finishing mg/l Scouring - Dyeing - Functional finishing - Thermal mg/l treatment - Other Wool Fulling - Washing synthetic fibre - Dyeing mg/l Scouring mg/l Thermal treatment - Functional finishing mg/l Dyeing - Bleaching - Scouring mg/l Washing synthetic fibre - Desizing - Scouring - Bleaching - mg/l Dyeing - Functional finishing - Other Washing synthetic fibre - Scouring - Functional finishing - mg/l Dry cleaning - Other Scouring - Bleaching - Mercerising mg/l Washing synthetic fibre - Scouring mg/l No information mg/l Washing synthetic fibre mg/l 0 1.56 9.8 5 6.67 10 0.1 6.02 10 1 3.13 10 0.05 2.85 18 0.05 11.08 18 0.05 11.12 20.3 0.1 8.72 22.2 13.1 16.92 25.5 3.7 13.43 25.8 6.6 13.47 28.7 7.6 15.35 29.3 0.6 8.93 30 3.9 13.62 30.7 4.2 15.73 32.5 13.5 32.18 45.5 11.4 29.47 66 1.9 21.93 73.5 8 30.86 100 0.3 51.37 147.5 20 No information Equalisation, Neutralisation, Screening, Coagulation and 50 flocculation, Sedimentation, Sand filtration, Adsorption (e.g. powdered/granular activated carbon, lignite coke, etc.) 200 No information 10 Neutralisation No information No information Not applicable No information 20 Neutralisation, Oil separation, Evaporation Other 15 No information 15 Flotation 200 No information 200 Other 200 No information 200 Other 200 Other 200 No technique used 200 No information 200 Other 200 Other 200 Other 200 Other 20 No information 5 Grit separators No information No information Not applicable Other Other Other Other Not applicable Other Other Other Other Other 24-hour flow proportional composite sample 24-hour flow proportional composite sample Twice per year Yearly Twice per year Monthly Monthly Twice per year Yearly Twice per year Twice per year No information Twice per year Twice per year Twice per year Twice per year Twice per year No information Twice per year No information 4 times per year 4 times per year Monitoring standard Additional information DO-H53-1 UNI EN ISO 9377-2:2002 UNI EN ISO 9377-2:2002 measured by regulating authority as required - measured by regulating authority as required - measured by regulating authority as required Monitoring frequency: spotValue measured inferior to detection limit: < 0,030mg/l Monitoring frequency: spotMeasurement 1 is inferior to detection limit: <0,030 mg/l No information No information PA 69 Non-infrared spectrometry after extraction with suitable solvents; Gravimetry after extraction with suitable solvents Standard Methods 5520F, 23rd Ed./FT-IR SIDVA - < LQ; LD= 0,04SIDVA - SIDVA annual measurement - annual measurement - annual measurement below level of quantification - below level of quantification - below level of quantification No information APAT CNR IRSA 5160 A1/A2 Man 29 2003 compound sampling No information No information UNI EN ISO 9377-2:2002 NORM EN ISO 9377-2 total hydrocarbons without oil - total hydrocarbons without oil - total hydrocarbons without oil - detection limit: 2 mg/L - detection limit: 2 mg/L Requested by Italian Law - Requested by Italian Law Requested by Italian Law,and other analyses introduced during 2018 to follow the ZDHC Waste Water Guide lines ELV: sum of hydrocarbons - ELV: sum of hydrocarbons ELV: sum of hydrocarbons No information UNI EN ISO 9377-2:2002 NORM EN ISO 9377-2 Yearly - Yearly - Yearly DIN DIN 38409-18:1981 EN ISO 9377-2:2000 (MH) EN ISO 9377-2:2000 UNI EN ISO 9377-2:2002 APAT CNR IRSA 5160 MAN 29 2003 APAT CNR IRSA 5160 MAN 29 2003 APAT CNR IRSA 5160 MAN 29 2003 APAT CNR IRSA 5160 MAN 29 2003 APAT CNR IRSA 5160 A1/A2 Man 29 2003 APAT CNR IRSA 5160 MAN 29 2003 APAT CNR IRSA 5160 MAN 29 2003 APAT CNR IRSA 5160 MAN 29 2003 APAT CNR IRSA 5160 MAN 29 2003 APAT CNR IRSA 5160 MAN 29 2003 NORM EN ISO 9377-2 No information sum of hydrocarbons - sum of hydrocarbons - 1st measurement: sum of hydrocarbons measurement and ELV: sum of hydrocarbons measurement and ELV: sum of hydrocarbons - ELV: sum of hydrocarbons Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours AVERAGE PERIOD 3 HOURS - AVERAGE PERIOD 3 HOURS AVERAGE PERIOD 3 HOURS Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours (data referring to the year 2015) AVERAGE PERIOD 3 HOURS - AVERAGE PERIOD 3 HOURS AVERAGE PERIOD 3 HOURS (YEAR 2015) Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours (data referring to the year 2015) AVERAGE PERIOD 3 HOURS - AVERAGE PERIOD 3 HOURS AVERAGE PERIOD 3 HOURS (YEAR 2015) 5; one additional control measurement local authority 52 1 TOC - Emissions to water Concentration expressed in mg/l 50 45 40 35 30 25 20 15 10 5 0 Point of discharge Average concentration over 3 years ELV (mg/l ) BE009_w {1} DE025_w {1} BE014_w {1} BE007_w {1} DE032_w {1} BE010_w {1} IT097_w {1} IT092_w {1} Type of discharge DIR DIR DIR DIR DIR DIR DIR DIR Type of monitoring Per Per Per Per Freq Per Per Per 1.0 Mass load expressed in g/day 0.8 0.6 Max. load over 3 0.4 years (g/day) 0.2 0.0 BE009_w {1} DE025_w {1} BE014_w {1} BE007_w {1} DE032_w {1} BE010_w {1} IT097_w {1} IT092_w {1} Other Anaerobic treatment Membrane bioreactor Distillation/rectification Reverse osmosis Chemical reduction Chemical oxidation Flotation Nanofiltration Microfiltration Ultrafiltration Evaporation Adsorption Activated sludge process Nitrification/denitrification Sand filtration Sedimentation Coagulation and flocculation Screening Grit separators Oil separation Neutralisation Equalisation No technique used Techniques applied IT092_w {1} IT097_w {1} BE010_w {1} DE032_w {1} BE007_w {1} BE014_w {1} DE025_w {1} BE009_w {1} 53 TOC - EMISSIONS TO WATER EP water name Type of discharge DIR = Direct IT092_w {1} DIR IT097_w {1} DIR BE010_w {1} DIR DE032_w {1} DIR DE034_w {1} DIR BE007_w {1} DIR BE014_w {1} DIR DE025_w {1} DIR BE009_w {1} DIR ES058_w {1} IND PT115_w {1} IND BE008_w {1} IND SE120_w {1} IND AT002_w {1} IND CZ015_w {1} IND SE119_w {1} IND DE031_w {1} IND DE042_w {1} IND SE118_w {1} IND DE049_w {1} IND DE030_w {1} IND Associated processes Dyeing - Other Units for concentration values Min. concentration over 3 years Average concentration over 3 years Max. concentration over 3 years Max. load over 3 ELV (mg/l ) years (g/day) mg/l 10.4 10.40 10.4 Dyeing - Shrink-proof finishing - Printing - Other mg/l Bleaching - Dyeing - Bleaching - Scouring - Functional mg/l finishing Washing synthetic fibre - Desizing - Bleaching - Dyeing - mg/l Printing 10.5 10.50 10.5 10 13.17 19 12.5 16.82 22 Combination of techniques Type of sampling Equalisation, Neutralisation, Activated sludge process, Nitrification/denitrification, Sedimentation, Reverse osmosis Equalisation, Neutralisation, Activated sludge process, Nitrification/denitrification, Sedimentation EqualisationActivated sludge process, Nitrification/denitrification, Other Not applicable Not applicable 24-hour flow proportional composite sample Equalisation, Neutralisation, Grit separators, Coagulation and flocculation, Sedimentation, Sand filtration, 24-hour flow proportional composite sample Nitrification/denitrification, Activated sludge process Washing synthetic fibre - Desizing - Bleaching - Dyeing Dyeing Bleaching - Dyeing - Functional finishing No unit reported mg/l mg/l Washing synthetic fibre - Dyeing - Printing mg/l Printing - Coating and laminating mg/l Mercerising - Bleaching - Dyeing - Desizing - Fabric mg/l production - Printing - Thermal treatment No information mg/l Printing - Dyeing mg/l Washing synthetic fibre - Desizing - Bleaching mg/l No information mg/l Dyeing - Functional finishing mg/l Washing synthetic fibre - Desizing - Functional finishing - mg/l Dyeing Dyeing mg/l Washing synthetic fibre - Desizing - Bleaching - Dyeing - mg/l Functional finishing Washing synthetic fibre - Scouring - Scouring - Bleaching - Dyeing - Singeing - Printing - Functional finishing - Shrink- mg/l proof finishing - Coating and laminating - Thermal treatment Desizing - Bleaching - Bleaching - Dyeing - Singeing - Printing - Coating and laminating - Scouring - Functional mg/l finishing Washing synthetic fibre - Desizing - Mercerising - Bleaching - Singeing - Dyeing - Functional finishing - mg/l Thermal treatment 9.6 16.53 24.36 20 25.80 22 30.06 15 30.80 51.00 64 194.00 11 166.83 61 170.00 52 235.40 150 256.75 210 399.00 24 351.56 410 660.00 220 535.00 430 823.33 730 1211.67 23 31 42 44 269 290 300 410 443 560 870 870 1000 1400 1600 143520 100240 352000 Activated sludge process, Nitrification/denitrification Flow proportional composite sample Equalisation, Neutralisation, Sand filtration, Activated sludge process, Nitrification/denitrification Equalisation, Activated sludge process, Nitrification/denitrification Flow proportional composite sample, Not applicable, Flow proportional composite sample 24-hour flow proportional composite sample Equalisation, Neutralisation, Coagulation and flocculation, 24-hour flow proportional composite sample Sedimentation, Activated sludge process Screening, Sedimentation, Equalisation, Activated sludge process, Sand filtration, Coagulation and flocculation, Flotation, Chemical oxidation (incl. Advanced oxidation), Sand filtration, Chemical reduction, Microfiltration, Reverse osmosis Other, 24-hour flow proportional composite sample, Other No information No information Equalisation, Neutralisation, Screening Equalisation, Grit separators, Other 165 Neutralisation, Oil separation, Equalisation No information Grit separators, Equalisation, Sedimentation No technique used No information Neutralisation, Equalisation 24-hour flow proportional composite sample 24-hour flow proportional composite sample 24-hour flow proportional composite sample No information Flow proportional composite sample 24-hour flow proportional composite sample No information 24-hour flow proportional composite sample Sedimentation, Neutralisation 24-hour flow proportional composite sample Equalisation, Neutralisation Equalisation, Neutralisation, Screening 24-hour flow proportional composite sample 24-hour flow proportional composite sample Monitoring frequency Other Other Other Other No information Monthly No information Monthly No information 4 times per year Yearly Other Continuous No information 4 times per year No information Other 4 times per year Weekly Yearly 4 times per year Monitoring standard UNI EN 1484:1999 UNI EN 1484:1999 No information No information No information WAC/III/D No information DIN EN 1484 (H3) WAC/III/D/050 No information SMEWW 5310 B No information No information DIN EN 1484 No information No information DIN EN 1484 No information No information DIN DIN Additional information Monitoring frequency: spot Monitoring frequency: spot Occasional - Occasional - Occasional Environmetal Permit - Environmetal Permit Environmetal Permit - Monitoring 2 yearly measurement IPPC control Quarterly 3 times/year - 3 times/year - 3 times/year 54 1 SULPHIDE - Emissions to water 70 Concentration expressed in mg/l 60 50 Average concentration 40 over 3 years ELV (mg/l ) 30 20 10 DE025_w {1} BE007_w {1} AT006_w {1} PT115_w {1} DE039_w {1} DE024_w {1} IT067_w {1} IT076_w {1} IT092_w {1} ES058_w {1} DE022_w {1} PT105_w {1} DE030_w {1} IT097_w {1} IT065_w {1} AT005_w {1} PT102_w {1} IT070_w {1} 0 Point of discharge Type of discharge DIR DIR IND IND IND IND DIR IND DIR IND IND IND IND DIR IND IND IND IND Type of monitoring Per Freq Per Per Per Per Per Per Per Freq Per Per Per Per Per Per Per Per 1.0 Mass load expressed in g/day 0.8 0.6 Max. load over 3 0.4 years (g/day) 0.2 0.0 DE025_w {1} BE007_w {1} AT006_w {1} PT115_w {1} DE039_w {1} DE024_w {1} IT067_w {1} IT076_w {1} IT092_w {1} ES058_w {1} DE022_w {1} PT105_w {1} DE030_w {1} IT097_w {1} IT065_w {1} AT005_w {1} PT102_w {1} IT070_w {1} Techniques applied Other Anaerobic treatment Membrane bioreactor Distillation/rectification Reverse osmosis Chemical reduction Chemical oxidation Flotation Nanofiltration Microfiltration Ultrafiltration Evaporation Adsorption Activated sludge process Nitrification/denitrification Sand filtration Sedimentation Coagulation and flocculation Screening Grit separators Oil separation Neutralisation Equalisation No technique used DE025_w {1} BE007_w {1} AT006_w {1} PT115_w {1} DE039_w {1} DE024_w {1} IT067_w {1} IT076_w {1} IT092_w {1} ES058_w {1} DE022_w {1} PT105_w {1} DE030_w {1} IT097_w {1} IT065_w {1} AT005_w {1} PT102_w {1} IT070_w {1} 55 SULPHIDE - Emissions to water (zoom 0-1.5 mg/l) Concentration expressed in mg/l 1.5 1.4 1.3 1.2 1.1 1.0 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0.0 Point of discharge Average concentration over 3 years ELV (mg/l ) DE025_w {1} BE007_w {1} AT006_w {1} PT115_w {1} DE039_w {1} DE024_w {1} IT067_w {1} IT076_w {1} IT092_w {1} ES058_w {1} DE022_w {1} PT105_w {1} DE030_w {1} IT097_w {1} IT065_w {1} AT005_w {1} PT102_w {1} IT070_w {1} Type of discharge DIR DIR IND IND IND IND DIR IND DIR IND IND IND IND DIR IND IND IND IND Type of monitoring Per Freq Per Per Per Per Per Per Per Freq Per Per Per Per Per Per Per Per 1.0 Mass load expressed in g/day 0.8 0.6 Max. load over 3 0.4 years (g/day) 0.2 0.0 DE025_w {1} BE007_w {1} AT006_w {1} PT115_w {1} DE039_w {1} DE024_w {1} IT067_w {1} IT076_w {1} IT092_w {1} ES058_w {1} DE022_w {1} PT105_w {1} DE030_w {1} IT097_w {1} IT065_w {1} AT005_w {1} PT102_w {1} IT070_w {1} Techniques applied Other Anaerobic treatment Membrane bioreactor Distillation/rectification Reverse osmosis Chemical reduction Chemical oxidation Flotation Nanofiltration Microfiltration Ultrafiltration Evaporation Adsorption Activated sludge process Nitrification/denitrification Sand filtration Sedimentation Coagulation and flocculation Screening Grit separators Oil separation Neutralisation Equalisation No technique used DE025_w {1} BE007_w {1} AT006_w {1} PT115_w {1} DE039_w {1} DE024_w {1} IT067_w {1} IT076_w {1} IT092_w {1} ES058_w {1} DE022_w {1} PT105_w {1} DE030_w {1} IT097_w {1} IT065_w {1} AT005_w {1} PT102_w {1} IT070_w {1} 56 SULPHIDE - EMISSIONS TO WATER EP water name Type of discharge DIR = Direct DE025_w {1} DIR BE007_w {1} DIR AT006_w {1} IND PT115_w {1} IND DE039_w {1} IND DE024_w {1} IND IT067_w {1} DIR IT076_w {1} IND IT092_w {1} DIR ES058_w {1} IND DE022_w {1} IND PT105_w {1} IND DE030_w {1} IND PT108_w {1} IND IT097_w {1} DIR IT065_w {1} IND AT005_w {1} IND PT102_w {1} IND IT070_w {1} IND Associated processes Washing synthetic fibre - Dyeing - Printing Dyeing Bleaching - Dyeing No information Mercerising - Dyeing - Washing synthetic fibre Bleaching - Desizing Desizing - Dyeing - Scouring - Singeing Dyeing - Printing - Other - Shrink-proof finishing Raw wool scouring Units for concentration values Min. concentration over 3 years Average concentration over 3 years Max. concentration over 3 years Max. load over 3 ELV (mg/l ) years (g/day) mg/l 0 0 0 mg/l 0 mg/l 0 0 0 mg/l 0.02 0.02 0.02 mg/l 0.03 0.04 0.04 mg/l 0.1 0.10 0.1 mg/l 0.1 0.10 0.1 mg/l 0.1 0.10 0.1 Dyeing - Other mg/l Mercerising - Bleaching - Dyeing - Desizing - Fabric mg/l production - Printing - Thermal treatment Raw wool scouring - Washing synthetic fibre - Desizing - Scouring - Bleaching - Dyeing - Thermal treatment - mg/l Functional finishing - Coating and laminating 0.1 0.10 0.1 0.14 0.006 0.03 0.34 Combination of techniques Type of sampling 1 Equalisation, Neutralisation, Coagulation and flocculation, 24-hour flow proportional composite sample Sedimentation, Activated sludge process Equalisation, Neutralisation, Sand filtration, Activated sludge process, Nitrification/denitrification 1 Flotation Flow proportional composite sample, Not applicable, Flow proportional composite sample No information 2 Equalisation, Neutralisation, Screening 24-hour flow proportional composite sample Equalisation, Neutralisation 1 Equalisation 1 Equalisation, Neutralisation, Activated sludge process, Nitrification/denitrification, Sedimentation Equalisation, Flotation, Coagulation and flocculation, 1 Activated sludge process, Nitrification/denitrification, Sedimentation, Membrane bioreactor Equalisation, Neutralisation, Activated sludge process, 1 Nitrification/denitrification, Sedimentation, Reverse osmosis No information Flow proportional composite sample Grab/spot sample Not applicable Not applicable Not applicable No information 1 Neutralisation, Oil separation, Evaporation Other Dyeing - Bleaching mg/l 0.4 0.40 0.4 Washing synthetic fibre - Desizing - Mercerising - Bleaching - Singeing - Dyeing - Functional finishing - mg/l Thermal treatment 0.04 0.18 0.58 Fabric production - Fabric production No unit reported 0.05 0.36 0.97 Dyeing - Shrink-proof finishing - Printing - Other mg/l 1 1.00 1 No information No information 1 Equalisation, Neutralisation, Screening 24-hour flow proportional composite sample 2 Neutralisation, Sand filtration, Sand filtration Equalisation, Neutralisation, Activated sludge process, Nitrification/denitrification, Sedimentation 24-hour flow proportional composite sample Not applicable No information mg/l 0.6 2.00 3.4 Other No information No information mg/l 0.2 1.48 3.4 10 Neutralisation No information Scouring - Dyeing - Bleaching mg/l 1 4.52 17 2 Other 24-hour flow proportional composite sample No information mg/l 0.02 4.05 23.2 60 No information Not applicable Monitoring frequency Monthly Monthly Yearly Yearly Twice per year 4 times per year Other Other Other 4 times per year Monthly Yearly 4 times per year Yearly Other Twice per year Twice per year Twice per year Twice per year Monitoring standard Additional information DIN 38405-27:1992-07 No information NORM M 6615:1994 PA 17 No information No information LCK 653 LCK 652 APAT CNR IRSA 4160 Man 29 2003 No information < LQ; LD= 0,02SIDVA - < LQ; LD= 0,02SIDVA - < LQ; LD= 0,02SIDVA Monitoring frequency: spotValue refered to sampling period Monitoring frequency: spotValue refered to sampling period Monitoring frequency: spotMeasurement 1 is inferior to limit value: <0,1 mg/lValue refered to sampling period DIN No information The installation only started operating in 2017.The value of uncertainty is not refered in the reports. DIN Molecular Absorption Spectrometry (EAM) - Methylene Blue APAT CNR IRSA 4160 Man 29 2003 ISO 10530:1992 No information SMEWW 4500 S2-F ISO 10530-1992 annual measurement - annual measurement - annual measurement Monitoring frequency: spotMeasurement 1 is inferior to detection limit: <1 We do not use Sulphur dyes; This Analysis has been introduced during 2018 to follow the ZDHC Waste Water Guide lines For the third monitoring the value is below level of quantificationFor the last two monitoring the value is below level of quantification 57 1 ANTIMONY - Emissions to water 1.2 Concentration expressed in mg/l 1.0 0.8 Average concentration over 3 years 0.6 ELV (mg/l ) 0.4 0.2 IT067_w {1} IT092_w {1} BE008_w {1} DE031_w {1} IT065_w {1} BE010_w {1} SE118_w {1} IT084_w {1} BE014_w {1} SE119_w {1} DE051_w {1} IT097_w {1} DE022_w {1} SE120_w {1} 0.0 Point of discharge Type of discharge DIR DIR IND IND IND DIR IND IND DIR IND IND DIR IND IND Type of monitoring Per Per Per Per Per Per Freq Per Per Freq Per Per Per Freq Mass load expressed in g/day 600 500 400 300 Max. load over 3 200 years (g/day) 100 0 IT067_w {1} IT092_w {1} BE008_w {1} DE031_w {1} IT065_w {1} BE010_w {1} SE118_w {1} IT084_w {1} BE014_w {1} SE119_w {1} DE051_w {1} IT097_w {1} DE022_w {1} SE120_w {1} Techniques applied Other Anaerobic treatment Membrane bioreactor Distillation/rectification Reverse osmosis Chemical reduction Chemical oxidation Flotation Nanofiltration Microfiltration Ultrafiltration Evaporation Adsorption Activated sludge process Nitrification/denitrification Sand filtration Sedimentation Coagulation and flocculation Screening Grit separators Oil separation Neutralisation Equalisation No technique used IT067_w {1} IT092_w {1} BE008_w {1} DE031_w {1} IT065_w {1} BE010_w {1} SE118_w {1} IT084_w {1} BE014_w {1} SE119_w {1} DE051_w {1} IT097_w {1} DE022_w {1} SE120_w {1} 58 ANTIMONY - Emissions to water (zoom 0-0.08 mg/l) 0.08 Concentration expressed in mg/l 0.07 0.06 0.05 Average concentration over 3 years 0.04 ELV (mg/l ) 0.03 0.02 0.01 IT067_w {1} IT092_w {1} BE008_w {1} DE031_w {1} IT065_w {1} BE010_w {1} SE118_w {1} IT084_w {1} BE014_w {1} SE119_w {1} DE051_w {1} IT097_w {1} DE022_w {1} SE120_w {1} 0.00 Point of discharge Type of discharge DIR DIR IND IND IND DIR IND IND DIR IND IND DIR IND IND Type of monitoring Per Per Per Per Per Per Freq Per Per Freq Per Per Per Freq Mass load expressed in g/day 600 500 400 300 Max. load over 3 200 years (g/day) 100 0 IT067_w {1} IT092_w {1} BE008_w {1} DE031_w {1} IT065_w {1} BE010_w {1} SE118_w {1} IT084_w {1} BE014_w {1} SE119_w {1} DE051_w {1} IT097_w {1} DE022_w {1} SE120_w {1} Techniques applied Other Anaerobic treatment Membrane bioreactor Distillation/rectification Reverse osmosis Chemical reduction Chemical oxidation Flotation Nanofiltration Microfiltration Ultrafiltration Evaporation Adsorption Activated sludge process Nitrification/denitrification Sand filtration Sedimentation Coagulation and flocculation Screening Grit separators Oil separation Neutralisation Equalisation No technique used IT067_w {1} IT092_w {1} BE008_w {1} DE031_w {1} IT065_w {1} BE010_w {1} SE118_w {1} IT084_w {1} BE014_w {1} SE119_w {1} DE051_w {1} IT097_w {1} DE022_w {1} SE120_w {1} 59 ANTIMONY - EMISSIONS TO WATER EP water name IT067_w {1} Type of discharge DIR = Direct DIR IT092_w {1} DIR BE008_w {1} IND DE031_w {1} IND BE011_w {1} DIR IT065_w {1} IND BE010_w {1} DIR SE118_w {1} IND IT084_w {1} IND BE014_w {1} DIR SE119_w {1} IND DE051_w {1} IND IT097_w {1} DIR DE022_w {1} IND SE120_w {1} IND Associated processes Dyeing - Printing - Other - Shrink-proof finishing Dyeing - Other Printing - Dyeing Dyeing Units for concentration values mg/l Min. concentration over 3 years Average concentration over 3 years Max. concentration over 3 years Max. load over 3 ELV (mg/l ) years (g/day) 0.0005 0.0005 0.0005 mg/l 0.0005 0.0005 0.0005 mg/l 0.0033 0.0033 0.0033 mg/l 0 0.01 0.014 Combination of techniques Equalisation, Neutralisation, Activated sludge process, Nitrification/denitrification, Sedimentation Equalisation, Neutralisation, Activated sludge process, Nitrification/denitrification, Sedimentation, Reverse osmosis 1 Equalisation, Grit separators, Other No information Type of sampling Not applicable Not applicable 24-hour flow proportional composite sample No information Dyeing No unit reported 0.01 0.01 0.02 Equalisation, Neutralisation, Coagulation and flocculation, 0.2 Activated sludge process, Nitrification/denitrification, Sand filtration, Nanofiltration, Chemical oxidation (incl. 24-hour flow proportional composite sample Advanced oxidation) No information mg/l Bleaching - Dyeing - Bleaching - Scouring - Functional mg/l finishing Washing synthetic fibre - Scouring - Scouring - Bleaching Dyeing - Singeing - Printing - Functional finishing - Shrink- mg/l proof finishing - Coating and laminating - Thermal treatment Bleaching - Dyeing - Thermal treatment mg/l Bleaching - Dyeing - Functional finishing mg/l Washing synthetic fibre - Desizing - Functional finishing - mg/l Dyeing Washing synthetic fibre - Scouring - Bleaching - Dyeing - mg/l Functional finishing Dyeing - Shrink-proof finishing - Printing - Other mg/l 0.00974 0.0202 0.062 0.001 0.033 0.138 0.03 0.01 0.02 0.0275 0.02 0.031 0.08 0.11 38.72 0.03 0.12 0.06 0.158 0.20 0.354 50.976 0.15 0.44 0.26 0.5 Other 1 EqualisationActivated sludge process, Nitrification/denitrification, Other 0.1 Sedimentation, Neutralisation No information 24-hour flow proportional composite sample 24-hour flow proportional composite sample Equalisation, Neutralisation, Grit separators, Screening, Coagulation and flocculation, Sedimentation 1 Equalisation, Activated sludge process, Nitrification/denitrification No technique used No information 24-hour flow proportional composite sample 24-hour flow proportional composite sample Neutralisation, Coagulation and flocculation, Equalisation No information Equalisation, Neutralisation, Activated sludge process, Nitrification/denitrification, Sedimentation Not applicable Raw wool scouring - Washing synthetic fibre - Desizing - Scouring - Bleaching - Dyeing - Thermal treatment - mg/l Functional finishing - Coating and laminating Washing synthetic fibre - Desizing - Bleaching mg/l 0.16 0.36 0.48 0.77 0.7 1.1 540.1 0.5 Neutralisation, Oil separation, Evaporation 0.4 Neutralisation, Oil separation, Equalisation Other 24-hour flow proportional composite sample Monitoring frequency Other Other No information Yearly No information Twice per year Other Monthly 4 times per year No information No information Monthly Other Monthly Continuous Monitoring standard APAT CNR IRSA 3020 Man 29 2003 APAT CNR IRSA 3020 Man 29 2003 WAC/II/B U.S. EPA 3015A +U.S. EPA 6020A WAC/III/B EPA 6020B :2014 EPA 200,8 rev.5,4 No information No information EPA 6020 B 2014 WAC/III/B No information No information APAT CNR IRSA 3020 Man 29 2003 DIN No information Additional information Monitoring frequency: spotValue refered to sampling period Monitoring frequency: spot Inspection, 0,0033 mg/l Detection limit: 1 g/L; result was lower as detection limit - 1 measurement < 0,03 mg/l (DL) - 4 measurments < 0,03 mg/l (result with matrix interference) analyses introduced during 2018 to follow the ZDHC Waste Water Guide lines Three months average 3 h medium composite sample - 3 h medium composite sample - 3 h medium composite sample Monitoring frequency: spotMeasurement 1 is inferior to detection limit: <0,5 mg/lMeasurement 2 is inferior to detection limit: <0,01 mg/l Quartely 60 1 TOTAL DISSOLVED SOLIDS - Emissions to water 3,500 Concentration expressed in mg/l 3,000 2,500 Average concentration 2,000 over 3 years ELV (mg/l ) 1,500 1,000 500 CZ017_w {1} CZ018_w {1} CZ019_w {1} IT097_w {1} IT092_w {1} FR136_w {1} SE119_w {1} IT083_w {1} 0 Point of discharge Type of discharge IND IND IND DIR DIR DIR IND IND Type of monitoring Per Freq Per Per Per Freq Per Per Mass load expressed in g/day 8,000 7,000 6,000 5,000 4,000 3,000 2,000 1,000 0 Max. load over 3 years (g/day) CZ017_w {1} CZ018_w {1} CZ019_w {1} IT097_w {1} IT092_w {1} FR136_w {1} SE119_w {1} IT083_w {1} Other Anaerobic treatment Membrane bioreactor Distillation/rectification Reverse osmosis Chemical reduction Chemical oxidation Flotation Nanofiltration Microfiltration Ultrafiltration Evaporation Adsorption Activated sludge process Nitrification/denitrification Sand filtration Sedimentation Coagulation and flocculation Screening Grit separators Oil separation Neutralisation Equalisation No technique used Techniques applied IT083_w {1} SE119_w {1} FR136_w {1} IT092_w {1} IT097_w {1} CZ019_w {1} CZ018_w {1} CZ017_w {1} 61 Techniques applied IT083_w {1} SE119_w {1} FR136_w {1} IT092_w {1} IT097_w {1} CZ019_w {1} CZ018_w {1} CZ017_w {1} Concentration expressed in mg/l 500 450 400 350 300 250 200 150 100 50 0 Point of discharge IT083_w {1} Type of discharge IND Type of monitoring Per Mass load expressed in g/day 8,000 7,000 6,000 5,000 4,000 3,000 2,000 1,000 0 IT083_w {1} 62 SE119_w {1} FR136_w {1} IT092_w {1} TOTAL DISSOLVED SOLIDS - Emissions to water (zoom 0-500 mg/l) CZ018_w {1} CZ019_w {1} IT097_w {1} IT092_w {1} FR136_w {1} SE119_w {1} IND IND DIR DIR DIR IND Freq Per Per Per Freq Per IT097_w {1} CZ019_w {1} CZ018_w {1} CZ017_w {1} CZ017_w {1} Average concentration over 3 years ELV (mg/l ) IND Per Max. load over 3 years (g/day) Other Anaerobic treatment Membrane bioreactor Distillation/rectification Reverse osmosis Chemical reduction Chemical oxidation Flotation Nanofiltration Microfiltration Ultrafiltration Evaporation Adsorption Activated sludge process Nitrification/denitrification Sand filtration Sedimentation Coagulation and flocculation Screening Grit separators Oil separation Neutralisation Equalisation No technique used TOTAL DISSOLVED SOLIDS - EMISSIONS TO WATER EP water name IT083_w {1} SE119_w {1} Type of discharge DIR = Direct IND IND FR136_w {1} IND IT092_w {1} DIR IT097_w {1} DIR CZ019_w {1} DIR CZ018_w {1} IND CZ017_w {1} IND Associated processes Scouring - Dyeing - Functional finishing Washing synthetic fibre - Desizing - Functional finishing Dyeing Desizing - Scouring - Bleaching - Mercerising - Dyeing Singeing - Fabric production - Functional finishing Units for concentration values mg/l mg/l mg/l Dyeing - Other mg/l Dyeing - Shrink-proof finishing - Printing - Other mg/l Bleaching - Dyeing - Printing - Functional finishing - mg/l Desizing Desizing - Functional finishing - Dyeing - Fabric mg/l production Spinning - Fabric production - Singeing - Functional finishing - Shrink-proof finishing - Thermal treatment - mg/l Other Min. concentration over 3 years Average concentration over 3 years Max. concentration over 3 years Max. load over 3 ELV (mg/l ) years (g/day) 0.1 0.30 0.8 13 26.00 42 7518 Combination of techniques Other No technique used 83 190.53 360 360.00 904 904.00 1054.00 120 1481.11 243 360 904 2010 Grit separators, Neutralisation Equalisation, Neutralisation, Activated sludge process, Nitrification/denitrification, Sedimentation, Reverse osmosis Equalisation, Neutralisation, Activated sludge process, Nitrification/denitrification, Sedimentation 1800 Equalisation, Neutralisation, Anaerobic treatment, Nitrification/denitrification, Activated sludge process 2300 Neutralisation 488 1330.50 2530 3000 No information Type of sampling Not applicable 24-hour flow proportional composite sample No information Not applicable Not applicable No information 24-hour flow proportional composite sample No information Monitoring frequency Twice per year No information No information Other Other Monthly Other Monthly Monitoring standard APAT CNR IRSA 2090 MAN 29 2003 No information No information APAT CNR IRSA 2090 A Man 29 2003 APAT CNR IRSA 2090 Man 29 2003 No information No information No information Additional information Monitoring frequency: spot Monitoring frequency: spot monitoring 6 per year - monitoring 6 per year monitoring 6 per year 63 1 64 Other Anaerobic treatment Membrane bioreactor Distillation/rectification Reverse osmosis Chemical reduction Chemical oxidation Flotation Nanofiltration Microfiltration Ultrafiltration Evaporation Adsorption Activated sludge process Nitrification/denitrification Sand filtration Sedimentation Coagulation and flocculation Screening Grit separators Oil separation Neutralisation Equalisation No technique used DE031_w {1} FR134_w {1} FR134_w {1} FR134_w {1} IT065_w {1} IT065_w {1} IT092_w {1} BE014_w {1} FR131_w {1} IT092_w {1} IT064_w {1} IT071_w {1} IT089_w {1} IT090_w {1} IT097_w {1} AT002_w {1} BE010_w {1} AT002_w {1} BE014_w {1} SE120_w {1} FR131_w {1} BE007_w {1} SE120_w {1} FR134_w {1} IT097_w {1} IT078_w {1} SE119_w {1} UK127_w {1} UK127_w {1} AT004_w {1} AT004_w {1} BE011_w {1} BE011_w {1} BE011_w {1} Techniques applied years (g/day) 80 Max. load over 3 Parameter Type of discharge Type of monitoring Mass load expressed in g/day Concentration expressed in mg/l 0.30 0.25 0.20 0.15 0.10 0.05 160 140 120 100 60 40 20 0 IND Per DE031_w {1} FR134_w {1} FR134_w {1} FR134_w {1} IT065_w {1} IT065_w {1} IT092_w {1} BE014_w {1} FR131_w {1} IT092_w {1} IT064_w {1} IT071_w {1} IT089_w {1} IT090_w {1} IT097_w {1} AT002_w {1} BE010_w {1} AT002_w {1} BE014_w {1} SE120_w {1} FR131_w {1} BE007_w {1} SE120_w {1} FR134_w {1} IT097_w {1} IT078_w {1} SE119_w {1} UK127_w {1} UK127_w {1} AT004_w {1} AT004_w {1} BE011_w {1} BE011_w {1} BE011_w {1} OP, OP1EO;NP, NPEO 4-n-nolylphnol 4-nonylphnol ditoxylate 4-nonylphnols monoethoxylate AP APEO APEO OP APEO NPEO NP NP NP NP NPEO OP NP NP NP NPEO AP NP NP NP APEO NP APEO OP NP OP NP APEO C16 APEO C15 APEO C17 Per Per Per Per Per Per Per Freq Per Per Per Freq Per Per Freq Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per DIR DIR DIR IND IND IND IND IND IND DIR DIR IND DIR DIR IND DIR IND DIR IND DIR IND IND IND IND DIR DIR DIR DIR IND IND DIR DIR DIR DE031_w {1} FR134_w {1} FR134_w {1} FR134_w {1} IT065_w {1} IT065_w {1} IT092_w {1} BE014_w {1} FR131_w {1} IT092_w {1} IT064_w {1} IT071_w {1} IT089_w {1} IT090_w {1} IT097_w {1} AT002_w {1} BE010_w {1} AT002_w {1} BE014_w {1} SE120_w {1} FR131_w {1} BE007_w {1} SE120_w {1} FR134_w {1} IT097_w {1} IT078_w {1} SE119_w {1} UK127_w {1} UK127_w {1} AT004_w {1} AT004_w {1} BE011_w {1} BE011_w {1} BE011_w {1} 0.00 Point of discharge Average concentration over 3 years ELV (mg/l ) 0.35 APs and APEOs - Emissions to water 65 Other Anaerobic treatment Membrane bioreactor Distillation/rectification Reverse osmosis Chemical reduction Chemical oxidation Flotation Nanofiltration Microfiltration Ultrafiltration Evaporation Adsorption Activated sludge process Nitrification/denitrification Sand filtration Sedimentation Coagulation and flocculation Screening Grit separators Oil separation Neutralisation Equalisation No technique used DE031_w {1} FR134_w {1} FR134_w {1} FR134_w {1} IT065_w {1} IT065_w {1} IT092_w {1} BE014_w {1} FR131_w {1} IT092_w {1} IT064_w {1} IT071_w {1} IT089_w {1} IT090_w {1} IT097_w {1} AT002_w {1} BE010_w {1} AT002_w {1} BE014_w {1} SE120_w {1} FR131_w {1} BE007_w {1} SE120_w {1} FR134_w {1} IT097_w {1} IT078_w {1} SE119_w {1} UK127_w {1} UK127_w {1} AT004_w {1} AT004_w {1} BE011_w {1} BE011_w {1} BE011_w {1} Techniques applied years (g/day) 80 Max. load over 3 Parameter Type of discharge Type of monitoring Mass load expressed in g/day Concentration expressed in mg/l 0.008 0.006 0.004 0.002 160 140 120 100 60 40 20 0 IND Per DE031_w {1} FR134_w {1} FR134_w {1} FR134_w {1} IT065_w {1} IT065_w {1} IT092_w {1} BE014_w {1} FR131_w {1} IT092_w {1} IT064_w {1} IT071_w {1} IT089_w {1} IT090_w {1} IT097_w {1} AT002_w {1} BE010_w {1} AT002_w {1} BE014_w {1} SE120_w {1} FR131_w {1} BE007_w {1} SE120_w {1} FR134_w {1} IT097_w {1} IT078_w {1} SE119_w {1} UK127_w {1} UK127_w {1} AT004_w {1} AT004_w {1} BE011_w {1} BE011_w {1} BE011_w {1} OP, OP1EO;NP, NPEO 4-n-nolylphnol 4-nonylphnol ditoxylate 4-nonylphnols monoethoxylate AP APEO APEO OP APEO NPEO NP NP NP NP NPEO OP NP NP NP NPEO AP NP NP NP APEO NP APEO OP NP OP NP APEO C16 APEO C15 APEO C17 Per Per Per Per Per Per Per Freq Per Per Per Freq Per Per Freq Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per DIR DIR DIR IND IND IND IND IND IND DIR DIR IND DIR DIR IND DIR IND DIR IND DIR IND IND IND IND DIR DIR DIR DIR IND IND DIR DIR DIR DE031_w {1} FR134_w {1} FR134_w {1} FR134_w {1} IT065_w {1} IT065_w {1} IT092_w {1} BE014_w {1} FR131_w {1} IT092_w {1} IT064_w {1} IT071_w {1} IT089_w {1} IT090_w {1} IT097_w {1} AT002_w {1} BE010_w {1} AT002_w {1} BE014_w {1} SE120_w {1} FR131_w {1} BE007_w {1} SE120_w {1} FR134_w {1} IT097_w {1} IT078_w {1} SE119_w {1} UK127_w {1} UK127_w {1} AT004_w {1} AT004_w {1} BE011_w {1} BE011_w {1} BE011_w {1} Point of discharge 0.000 Average concentration over 3 years ELV (mg/l ) 0.010 APs and APEOs - Emissions to water (zoom 0-0.01 mg/l) 66 Other Anaerobic treatment Membrane bioreactor Distillation/rectification Reverse osmosis Chemical reduction Chemical oxidation Flotation Nanofiltration Microfiltration Ultrafiltration Evaporation Adsorption Activated sludge process Nitrification/denitrification Sand filtration Sedimentation Coagulation and flocculation Screening Grit separators Oil separation Neutralisation Equalisation No technique used DE031_w {1} FR134_w {1} FR134_w {1} FR134_w {1} IT065_w {1} IT065_w {1} IT092_w {1} BE014_w {1} FR131_w {1} IT092_w {1} IT064_w {1} IT071_w {1} IT089_w {1} IT090_w {1} IT097_w {1} AT002_w {1} BE010_w {1} AT002_w {1} BE014_w {1} SE120_w {1} FR131_w {1} BE007_w {1} SE120_w {1} FR134_w {1} IT097_w {1} IT078_w {1} SE119_w {1} UK127_w {1} UK127_w {1} AT004_w {1} AT004_w {1} BE011_w {1} BE011_w {1} BE011_w {1} Techniques applied years (g/day) 80 Max. load over 3 Parameter Type of discharge Type of monitoring Mass load expressed in g/day Concentration expressed in mg/l 0.004 0.003 0.002 0.001 160 140 120 100 60 40 20 0 IND Per DE031_w {1} FR134_w {1} FR134_w {1} FR134_w {1} IT065_w {1} IT065_w {1} IT092_w {1} BE014_w {1} FR131_w {1} IT092_w {1} IT064_w {1} IT071_w {1} IT089_w {1} IT090_w {1} IT097_w {1} AT002_w {1} BE010_w {1} AT002_w {1} BE014_w {1} SE120_w {1} FR131_w {1} BE007_w {1} SE120_w {1} FR134_w {1} IT097_w {1} IT078_w {1} SE119_w {1} UK127_w {1} UK127_w {1} AT004_w {1} AT004_w {1} BE011_w {1} BE011_w {1} BE011_w {1} OP, OP1EO;NP, NPEO 4-n-nolylphnol 4-nonylphnol ditoxylate 4-nonylphnols monoethoxylate AP APEO APEO OP APEO NPEO NP NP NP NP NPEO OP NP NP NP NPEO AP NP NP NP APEO NP APEO OP NP OP NP APEO C16 APEO C15 APEO C17 Per Per Per Per Per Per Per Freq Per Per Per Freq Per Per Freq Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per DIR DIR DIR IND IND IND IND IND IND DIR DIR IND DIR DIR IND DIR IND DIR IND DIR IND IND IND IND DIR DIR DIR DIR IND IND DIR DIR DIR DE031_w {1} FR134_w {1} FR134_w {1} FR134_w {1} IT065_w {1} IT065_w {1} IT092_w {1} BE014_w {1} FR131_w {1} IT092_w {1} IT064_w {1} IT071_w {1} IT089_w {1} IT090_w {1} IT097_w {1} AT002_w {1} BE010_w {1} AT002_w {1} BE014_w {1} SE120_w {1} FR131_w {1} BE007_w {1} SE120_w {1} FR134_w {1} IT097_w {1} IT078_w {1} SE119_w {1} UK127_w {1} UK127_w {1} AT004_w {1} AT004_w {1} BE011_w {1} BE011_w {1} BE011_w {1} Point of discharge 0.000 Average concentration over 3 years ELV (mg/l ) 0.005 APs and APEOs - Emissions to water (zoom 0-0.005 mg/l) APs and APEOs - EMISSIONS TO WATER EP water name Type of discharge DIR = Direct IND = Indirect DE031_w {1} IND FR134_w {1} DIR FR134_w {1} DIR FR134_w {1} DIR IT065_w {1} IND IT065_w {1} IND Associated processes Units for KEI concentration values Dyeing OP, OP1EO;NP, mg/l NPEO Washing synthetic fibre - Desizing - Mercerising - Bleaching 4-n-nolylphnol mg/l - Dyeing - Singeing - Functional finishing Washing synthetic fibre - Desizing - Mercerising - Bleaching 4-nonylphnol mg/l - Dyeing - Singeing - Functional finishing ditoxylate Washing synthetic fibre - Desizing - Mercerising - Bleaching 4-nonylphnols mg/l - Dyeing - Singeing - Functional finishing monoethoxylate No information AP mg/l No information APEO mg/l Min. concentration over 3 years Average concentration over 3 years Max. concentration over 3 years Max. load over 3 ELV (mg/l ) years (g/day) 0 0 0 0 0 0 0.00001 0.00001 0 0 0 0.00001 0.00001 0 0 0 0.00001 0.00001 0 0.025 0 0.025 0 0.025 IT092_w {1} DIR Dyeing - Other APEO mg/l 0.00001 0.00001 0.00001 BE014_w {1} DIR FR131_w {1} DIR IT092_w {1} DIR Bleaching - Dyeing - Functional finishing OP mg/l Washing synthetic fibre - Bleaching - Dyeing - Printing - Functional finishing - Coating and laminating - Thermal APEO mg/l treatment Dyeing - Other NPEO mg/l 0.00003 0 0.0002 0.00003 0.00002 0.0002 0.00003 0.0001 0.00018 0.00303 0.00008 Combination of techniques Type of sampling No information Equalisation, Neutralisation, Grit separators, Activated sludge process, Anaerobic treatment Equalisation, Neutralisation, Grit separators, Activated sludge process, Anaerobic treatment Equalisation, Neutralisation, Grit separators, Activated sludge process, Anaerobic treatment Other Other Equalisation, Neutralisation, Activated sludge process, Nitrification/denitrification, Sedimentation, Reverse osmosis Equalisation, Activated sludge process, Nitrification/denitrification No information No information No information No information No information No information Not applicable 24-hour flow proportional composite sample Other Equalisation, Neutralisation, Activated sludge process, Nitrification/denitrification, Sedimentation, Reverse osmosis 24-hour flow proportional composite sample Not applicable IT064_w {1} IND Scouring NP mg/l 0.0002 0.0002 0.0002 Other Other Monitoring frequency Yearly 4 times per year 4 times per year 4 times per year Twice per year Twice per year Other No information 4 times per year Other Twice per year IT071_w {1} IND IT089_w {1} IND IT090_w {1} IND IT097_w {1} DIR AT002_w {1} IND BE010_w {1} DIR AT002_w {1} IND BE014_w {1} DIR SE120_w {1} IND FR131_w {1} DIR BE007_w {1} DIR SE120_w {1} IND FR134_w {1} DIR IT097_w {1} DIR IT078_w {1} IND SE119_w {1} IND UK127_w {1} IND UK127_w {1} IND AT004_w {1} IND AT004_w {1} IND BE011_w {1} DIR BE011_w {1} DIR BE011_w {1} DIR Dyeing - Bleaching - Scouring NP mg/l Scouring - Dyeing - Thermal treatment - Other - Bleaching NP mg/l Scouring - Dyeing - Thermal treatment - Other - Bleaching NP mg/l Dyeing - Shrink-proof finishing - Printing - Other NPEO mg/l No information OP mg/l Bleaching - Dyeing - Bleaching - Scouring - Functional NP mg/l finishing No information NP mg/l Bleaching - Dyeing - Functional finishing NP mg/l Washing synthetic fibre - Desizing - Bleaching NPEO mg/l Washing synthetic fibre - Bleaching - Dyeing - Printing - Functional finishing - Coating and laminating - Thermal AP mg/l treatment Dyeing NP mg/l Washing synthetic fibre - Desizing - Bleaching NP mg/l Washing synthetic fibre - Desizing - Mercerising - Bleaching NP mg/l - Dyeing - Singeing - Functional finishing Dyeing - Shrink-proof finishing - Printing - Other APEO mg/l Wool Fulling - Washing synthetic fibre - Dyeing NP mg/l Washing synthetic fibre - Desizing - Functional finishing - APEO mg/l Dyeing Mercerising - Bleaching - Dyeing - Scouring - Singeing - OP mg/l Printing Mercerising - Bleaching - Dyeing - Scouring - Singeing - NP mg/l Printing Washing synthetic fibre OP mg/l Washing synthetic fibre NP mg/l Dyeing APEO C16 mg/l Dyeing APEO C15 mg/l Dyeing APEO C17 mg/l 0.0002 0.0002 0.0002 0.00036 0 0.00017 0.0 0.00014 0.0 0.00013 0.0 0.005 0.0002 0.0002 0.0002 0.0004 0.0002 0.0004 0.0006 0.0006 0.002 0.0005 0.0008 0.005 0.0014 0.005 0.0002 0.0002 0.0002 0.00036 0.00092 0.00113 0.0013 0.00145 4.0398 0.4094 1.2306 0.6992 0.0003 0.988 0.143086 0.00008 0.0023 0.0036 0.0049 0.005 2.4157 0.025 No information Other Yearly Other 24-hour flow proportional composite sample Yearly Other Equalisation, Neutralisation, Activated sludge process, Nitrification/denitrification, Sedimentation No information EqualisationActivated sludge process, Nitrification/denitrification, Other No information Equalisation, Activated sludge process, Nitrification/denitrification Neutralisation, Oil separation, Equalisation Other Equalisation, Neutralisation, Sand filtration, Activated sludge process, Nitrification/denitrification Neutralisation, Oil separation, Equalisation Equalisation, Neutralisation, Grit separators, Activated sludge process, Anaerobic treatment Equalisation, Neutralisation, Activated sludge process, Nitrification/denitrification, Sedimentation 24-hour flow proportional composite sample Yearly Not applicable No information 24-hour flow proportional composite sample No information 24-hour flow proportional composite sample 24-hour flow proportional composite sample Other No information Other No information No information Other 24-hour flow proportional composite sample 4 times per year Flow proportional composite sample, Not applicable, Flow No information proportional composite sample 24-hour flow proportional composite sample Other No information 4 times per year Not applicable Other 0.0002 0.002 0.0053 Other Other Twice per year 0.001 0.002 0 0 0.024 0.1 0.19 0.009 0.006 0.011 0.006 0.007 0.024 0.16 0.23 0.01 0.02 0.02 0.02 0.024 0.126 2.1 10.1832 0.001 0.27 116.532 0.001 0.31 133.796 0.001 No technique used 24-hour flow proportional composite sample Neutralisation 24-hour flow proportional composite sample Neutralisation 24-hour flow proportional composite sample No information No information No information No information Equalisation, Neutralisation, Coagulation and flocculation, Activated sludge process, Nitrification/denitrification, Sand 24-hour flow proportional composite sample filtration, Nanofiltration, Chemical oxidation (incl. Advanced oxidation) Equalisation, Neutralisation, Coagulation and flocculation, Activated sludge process, Nitrification/denitrification, Sand 24-hour flow proportional composite sample filtration, Nanofiltration, Chemical oxidation (incl. Advanced oxidation) Equalisation, Neutralisation, Coagulation and flocculation, Activated sludge process, Nitrification/denitrification, Sand 24-hour flow proportional composite sample filtration, Nanofiltration, Chemical oxidation (incl. Advanced oxidation) No information Yearly Yearly Other Other No information No information No information Monitoring standard ASTM D7065 No information No information No information ISO 18857-1 2005 ISO 18857-2:2009 ISO 18857-1:2005 WAC/IV/A/01-05 ISO 18857-1/-2 ISO 18857-1:2005 UNI EN ISO 18857-2:2012 UNI EN ISO 18857-2:2012 UNI EN ISO 18857-2:2012 UNI EN ISO 18857-2:2012 ISO 18857-1:2005 DIN EN ISO 18857-1 No information DIN EN ISO 18857-1 WAC/IV/A/01-05 No information ISO 18857-1/-2 No information No information No information No information UNI EN ISO 18857-2:2012 No information No information No information DIN EN ISO 18857-2 DIN EN ISO 18857-2 WAC/IV/A/001-WAC/IV/A/005 WAC/IV/A/001-WAC/IV/A/005 WAC/IV/A/001-WAC/IV/A/005 Additional information Detection limit: 1 g/L; result was lower as detection limit Detection limit: 1 g/L; result was lower as detection limit Detection limit: 1 g/L; result was lower as detection limit - RSDE regulation - RSDE regulation - RSDE regulation - RSDE regulation - RSDE regulation - RSDE regulation Not detected, LOD 0.01 ; introduced during 2018 to follow the ZDHC Waste Water Guide lines Not detected, LOD 0.01 ; introduced during 2018 to follow the ZDHC Waste Water Guide lines Monitoring frequency: spotMeasurement is inferior to limit value: <0,01 g/l 4-ter octylphenol: 6 measurements < DL (0,10 ug/l), sum phenols (limit value)4 n-octylphenol: 5 measurements < DL (0,01 ug/l), 1 mesurement 0,03 ug/l RSDE detection limit of the lab 0,1g/L - RSDE detection limit of the lab 0,1g/L - RSDE detection limit of the lab 0,1g/L Monitoring frequency: spot Averaging period for monitoring: 3 hours; Parameter monitored on indication of the manager of the public sewage - Averaging period for monitoring: 3 hours; Parameter monitored on indication of the manager of the public sewage - Averaging period for monitoring: 3 hours; Parameter monitored on indication of the manager of the public sewage - Averaging period for monitoring: 3 hours; Parameter monitored on indication of the manager of the public sewage - Averaging period of monitoring: 3 hours. Parameter monitored on basis of manager of the public waste water plant - Averaging period of monitoring: 3 hours. Parameter monitored on basis of manager of the public waste water plant - Monitoring frequency:spot measurement to calculate loads for EMREG reporting; date of sampling: 2015 alle measurements < DL - alle measurements < DL - 1 measurement < 0,01 ug/l measurement to calculate loads for EMREG reporting; date of : 2015 sum phenols (limit value) One week every two years, See appendix 2One week every two years, See Appendix 1 RSDE detection limit of the lab 0,1g/L - RSDE detection limit of the lab 0,1g/L - RSDE detection limit of the lab 0,1g/L - 3 Measuring result < 0,1 ug/l (DL) One week every two years, see Appendix 2One week every two years, see Appendix 1 Monitoring frequency:spotMeasurement is inferior to detection limit: <5 g/l Averaging period for monitoring: 3 hours; Parameter monitored on indication of the manager of the public sewage - Averaging period for monitoring: 3 hours; Parameter monitored on indication of the manager of the public sewage - Averaging period for monitoring: 3 hours; Parameter monitored on indication of the manager of the public sewage Appendix 2Appendix 1 less than. Whole site APEO free - less than. Whole site APEO free less than. Whole site APEO free - less than. Whole site APEO free Reference year: 2015; once every 6 years Reference year: 2015; once every 6 years Permit: Sum APEO2 measurements < DL (3 ug/l) Permit: Sum APEO Permit: Sum APEO 67 1 Techniques applied DE031_w {1} IT065_w {1} BE011_w {1} DE026_w {1} BE010_w {1} DE026_w {1} IT097_w {1} AT004_w {1} 0.06 Concentration expressed in mg/l 0.05 0.04 0.03 0.02 0.01 DE031_w {1} 0.00 Point of discharge Type of discharge IND Type of monitoring Per Parameter Mass load expressed in g/day 10 9 8 7 6 5 4 3 2 1 0 68 DE031_w {1} IT065_w {1} Brominated and chlorinated flame retardants Flame retardants: TRIS;TEPA;TCEP;PBB;BD BPT;BBP;PBDE;OctaBDE; DecaBDE;HBCDD;TSCPP; TCPP; TBB; TBPH; TPP; TMP; TBBPA; BBMP: TetraBDE; HexaBDE; HeptaBDE; NonaBDE BE011_w {1} DecaBDE DE026_w {1} NonaBDE Brominated and brominated flame retardants - Emissions to water IT097_w {1} DE026_w {1} BE010_w {1} DE026_w {1} BE011_w {1} IT065_w {1} IND DIR IND DIR IND DIR Per Per Per Per Per Per BE010_w {1} DecaBDE DE026_w {1} IT097_w {1} AT004_w {1} DecaBDE 13 substances DecaBDE AT004_w {1} Average concentration over 3 years ELV (mg/l ) IND Per Max. load over 3 years (g/day) Other Anaerobic treatment Membrane bioreactor Distillation/rectification Reverse osmosis Chemical reduction Chemical oxidation Flotation Nanofiltration Microfiltration Ultrafiltration Evaporation Adsorption Activated sludge process Nitrification/denitrification Sand filtration Sedimentation Coagulation and flocculation Screening Grit separators Oil separation Neutralisation Equalisation No technique used Techniques applied DE031_w {1} IT065_w {1} BE011_w {1} DE026_w {1} BE010_w {1} DE026_w {1} IT097_w {1} AT004_w {1} 0.006 Concentration expressed in mg/l 0.005 0.004 0.003 0.002 0.001 DE031_w {1} Point of discharge 0.000 Type of discharge IND Type of monitoring Per Parameter Mass load expressed in g/day 10 9 8 7 6 5 4 3 2 1 0 69 DE031_w {1} IT065_w {1} Brominated and chlorinated flame retardants Flame retardants: TRIS;TEPA;TCEP;PBB;BD BPT;BBP;PBDE;OctaBDE; DecaBDE;HBCDD;TSCPP; TCPP; TBB; TBPH; TPP; TMP; TBBPA; BBMP: TetraBDE; HexaBDE; HeptaBDE; NonaBDE BE011_w {1} DecaBDE DE026_w {1} NonaBDE Brominated and brominated flame retardants - Emissions to water (zoom 0-0.006 mg/l) IT097_w {1} DE026_w {1} BE010_w {1} DE026_w {1} BE011_w {1} IT065_w {1} IND DIR IND DIR IND DIR Per Per Per Per Per Per BE010_w {1} DecaBDE DE026_w {1} IT097_w {1} AT004_w {1} DecaBDE 13 substances DecaBDE AT004_w {1} Average concentration over 3 years ELV (mg/l ) IND Per Max. load over 3 years (g/day) Other Anaerobic treatment Membrane bioreactor Distillation/rectification Reverse osmosis Chemical reduction Chemical oxidation Flotation Nanofiltration Microfiltration Ultrafiltration Evaporation Adsorption Activated sludge process Nitrification/denitrification Sand filtration Sedimentation Coagulation and flocculation Screening Grit separators Oil separation Neutralisation Equalisation No technique used Brominated and brominated flame retardants - EMISSIONS TO WATER EP water name Type of discharge DIR = Direct IND = Indirect Associated processes DE031_w {1} IND Dyeing IT065_w {1} IND No information SE120_w {1} IND BE011_w {1} DIR Washing synthetic fibre - Desizing - Bleaching Dyeing Units for KEI concentration values Brominated and chlorinated flame mg/l retardants Min. concentration over 3 years Average concentration over 3 years Max. concentration over 3 years Max. load over 3 ELV (mg/l ) years (g/day) 0 0 0 Flame retardants: TRIS;TEPA;TCEP;P BB;BDBPT;BBP;P BDE;OctaBDE;De caBDE;HBCDD;TS CPP; TCPP; TBB; mg/l TBPH; TPP; TMP; TBBPA; BBMP: TetraBDE; HexaBDE; HeptaBDE; NonaBDE HpBDe other (please specify in the column "additional information") 0.00001 0.00001 0.00001 0.00005 DecaBDE mg/l 0.00018 0.0002 0.00018 0.126171 0.001 DE026_w {1} IND BE010_w {1} DIR DE026_w {1} IND IT097_w {1} DIR SE120_w {1} IND AT004_w {1} IND Washing synthetic fibre - Desizing - Dyeing - Bleaching Bleaching - Dyeing - Bleaching - Scouring - Functional finishing Washing synthetic fibre - Desizing - Dyeing - Bleaching Dyeing - Shrink-proof finishing - Printing - Other Washing synthetic fibre - Desizing - Bleaching Washing synthetic fibre NonaBDE DecaBDE DecaBDE 13 substances DecaBDE DecaBDE mg/l mg/l mg/l mg/l No unit reported mg/l 0.00032 0.00016 0.0014 0.005 0.0005 0.0003 0.0004 0.0014 0.005 0.005 0.017 0.00032 0.00064 0.0014 0.005 0.052 0.05248 0.09792 0.02 0.2296 8.684 Combination of techniques No information Other Type of sampling No information No information Neutralisation, Oil separation, Equalisation 24-hour flow proportional composite sample Equalisation, Neutralisation, Coagulation and flocculation, Activated sludge process, Nitrification/denitrification, Sand 24-hour flow proportional composite sample filtration, Nanofiltration, Chemical oxidation (incl. Advanced oxidation) No information EqualisationActivated sludge process, Nitrification/denitrification, Other No information Equalisation, Neutralisation, Activated sludge process, Nitrification/denitrification, Sedimentation Neutralisation, Oil separation, Equalisation No information Other 24-hour flow proportional composite sample Other Not applicable 24-hour flow proportional composite sample No information Monitoring frequency Yearly Twice per year No information No information No information Other No information No information No information Other Monitoring standard U.S. EPA 527+ U.S. EPA 8321 B No information No information WAC/IV/A/030 No information No information No information No information No information EPA 8270 Additional information Detection limit: 1 g/L; result was lower as detection limit Detection limit: 1 g/L; result was lower as detection limit Detection limit: 1 g/L; result was lower as detection limit Not detected, LOD 0.01 ; introduced during 2018 to follow the ZDHC Waste Water Guide lines - 1 measurement 0,18 - 2 measurements <0,40 and <0,0038 < 0,079 ug/l all the substances analysed are inferior to detection limit: <5 g/l See Appendix 1 Reference year: 2015; once every 6 years 70 1 71 Other Anaerobic treatment Membrane bioreactor Distillation/rectification Reverse osmosis Chemical reduction Chemical oxidation Flotation Nanofiltration Microfiltration Ultrafiltration Evaporation Adsorption Activated sludge process Nitrification/denitrification Sand filtration Sedimentation Coagulation and flocculation Screening Grit separators Oil separation Neutralisation Equalisation No technique used IT082_w {1} IT082_w {1} IT082_w {1} IT096_w {1} IT067_w {1} IT096_w {1} IT082_w {2} BE011_w {1} IT097_w {1} IT069_w {1} IT067_w {1} IT092_w {1} IT094_w {1} IT074_w {1} IT097_w {1} IT092_w {1} IT077_w {2} IT064_w {1} IT071_w {1} IT091_w {1} IT096_w {1} IT097_w {1} UK124_w {1} IT072_w {1} IT096_w {1} IT072_w {1} IT092_w {1} IT061_w {1} IT075_w {1} IT076_w {1} IT071_w {2} IT078_w {1} IT092_w {1} IT074_w {2} IT064_w {1} IT067_w {1} IT067_w {1} IT078_w {1} IT084_w {1} IT077_w {2} IT068_w {1} IT069_w {1} IT090_w {1} IT071_w {1} IT077_w {1} IT089_w {1} IT091_w {1} IT073_w {1} IT077_w {1} IT068_w {1} IT073_w {1} IT097_w {1} IT082_w {2} IT079_w {1} IT087_w {1} IT079_w {1} IT074_w {2} IT089_w {1} IT094_w {1} IT074_w {1} IT065_w {1} IT090_w {1} BE009_w {1} IT061_w {1} IT087_w {1} IT065_w {1} IT071_w {2} IT087_w {1} IT063_w {1} IT087_w {1} IT070_w {1} PT113_w {1} IT063_w {1} IT082_w {2} IT070_w {1} IT082_w {2} IT077_w {2} IT072_w {1} IT065_w {1} IT078_w {1} IT074_w {2} IT068_w {1} IT094_w {1} IT074_w {1} IT061_w {1} IT091_w {1} IT071_w {2} IT071_w {1} UK127_w {1} IT077_w {1} IT064_w {1} IT073_w {1} IT089_w {1} IT070_w {1} IT090_w {1} IT070_w {1} IT085_w {1} IT079_w {1} IT069_w {1} Techniques applied Max. load over 3 years (g/day) Parameter DIR DIR DIR DIR DIR DIR IND DIR DIR IND DIR DIR IND IND DIR DIR IND IND IND IND DIR DIR DIR IND DIR IND DIR IND IND IND IND IND DIR IND IND DIR DIR IND IND IND IND IND IND IND IND IND IND IND IND IND IND DIR IND IND IND IND IND IND IND IND IND IND DIR IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Freq Per Per Per Per Per Per Freq Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Freq Per Per Per Per Per Per Per Freq Per Per Type of discharge Type of monitoring Mass load expressed in g/day 120,000 100,000 80,000 60,000 40,000 20,000 0 IT082_w {1} IT082_w {1} IT082_w {1} IT096_w {1} IT067_w {1} IT096_w {1} IT082_w {2} BE011_w {1} IT097_w {1} IT069_w {1} IT067_w {1} IT092_w {1} IT094_w {1} IT074_w {1} IT097_w {1} IT092_w {1} IT077_w {2} IT064_w {1} IT071_w {1} IT091_w {1} IT096_w {1} IT097_w {1} UK124_w {1} IT072_w {1} IT096_w {1} IT072_w {1} IT092_w {1} IT061_w {1} IT075_w {1} IT076_w {1} IT071_w {2} IT078_w {1} IT092_w {1} IT074_w {2} IT064_w {1} IT067_w {1} IT067_w {1} IT078_w {1} IT084_w {1} IT077_w {2} IT068_w {1} IT069_w {1} IT090_w {1} IT071_w {1} IT077_w {1} IT089_w {1} IT091_w {1} IT073_w {1} IT077_w {1} IT068_w {1} IT073_w {1} IT097_w {1} IT082_w {2} IT079_w {1} IT087_w {1} IT079_w {1} IT074_w {2} IT089_w {1} IT094_w {1} IT074_w {1} IT065_w {1} IT090_w {1} BE009_w {1} IT061_w {1} IT087_w {1} IT065_w {1} IT071_w {2} IT087_w {1} IT063_w {1} IT087_w {1} IT070_w {1} PT113_w {1} IT063_w {1} IT082_w {2} IT070_w {1} IT082_w {2} IT077_w {2} IT072_w {1} IT065_w {1} IT078_w {1} IT074_w {2} IT068_w {1} IT094_w {1} IT074_w {1} IT061_w {1} IT091_w {1} IT071_w {2} IT071_w {1} UK127_w {1} IT077_w {1} IT064_w {1} IT073_w {1} IT089_w {1} IT070_w {1} IT090_w {1} IT070_w {1} IT085_w {1} IT079_w {1} IT069_w {1} Anionic surfactants... Non-ionic surfactants CTAB Anionic surfactants Cationic surfactants Cationic surfactants CBAS Anionic surfactants... Anionic surfactants Cationic surfactants Anionic surfactants Anionic surfactants Cationic surfactants... Anionic surfactants Non-ionic surfactants Cationic surfactants Cationic surfactants Cationic surfactants Anionic surfactants Cationic surfactants Non-ionic surfactants Total surfactants Anionic and Non-ionic... Cationic surfactants Total surfactants Anionic surfactants Non-ionic surfactants Cationic surfactants Total surfactants Total surfactants Cationic surfactants Anionic surfactants Total surfactants Anionic surfactants Anionic surfactants Non-ionic surfactants Total surfactants Cationic surfactants Total surfactants Anionic surfactants Anionic surfactants Anionic surfactants Anionic surfactants Cationic surfactants Anionic surfactants Anionic surfactants Anionic surfactants Cationic surfactants Cationic surfactants Cationic surfactants Anionic surfactants... Cationic surfactants Anionic surfactants... Anionic surfactants Anionic surfactants Cationic surfactants Cationic surfactants Cationic surfactants Anionic surfactants... Cationic surfactants Cationic surfactants Cationic surfactants Total surfactants Anionic surfactants Cationic surfactants Anionic surfactants... Anionic surfactants Non-ionic surfactants Anionic surfactants... Total surfactants Anionic surfactants... Anionic surfactants... Non-ionic surfactants... Non-ionic surfactants CTAB Total surfactants Non-ionic surfactants Non-ionic surfactants Non-ionic surfactants... Non-ionic surfactants Non-ionic surfactants Non-ionic surfactants Non-ionic surfactants... Non-ionic surfactants Non-ionic surfactants Non-ionic surfactants Non-ionic surfactants Non-ionic surfactants Anionic surfactants Non-ionic surfactants Non-ionic surfactants Non-ionic surfactants... Non-ionic surfactants Non-ionic surfactants Non-ionic surfactants Total surfactants Total surfactants Non-ionic surfactants Non-ionic surfactants IT082_w {1} IT082_w {1} IT082_w {1} IT096_w {1} IT067_w {1} IT096_w {1} IT082_w {2} BE011_w {1} IT097_w {1} IT069_w {1} IT067_w {1} IT092_w {1} IT094_w {1} IT074_w {1} IT097_w {1} IT092_w {1} IT077_w {2} IT064_w {1} IT071_w {1} IT091_w {1} IT096_w {1} IT097_w {1} UK124_w {1} IT072_w {1} IT096_w {1} IT072_w {1} IT092_w {1} IT061_w {1} IT075_w {1} IT076_w {1} IT071_w {2} IT078_w {1} IT092_w {1} IT074_w {2} IT064_w {1} IT067_w {1} IT067_w {1} IT078_w {1} IT084_w {1} IT077_w {2} IT068_w {1} IT069_w {1} IT090_w {1} IT071_w {1} IT077_w {1} IT089_w {1} IT091_w {1} IT073_w {1} IT077_w {1} IT068_w {1} IT073_w {1} IT097_w {1} IT082_w {2} IT079_w {1} IT087_w {1} IT079_w {1} IT074_w {2} IT089_w {1} IT094_w {1} IT074_w {1} IT065_w {1} IT090_w {1} BE009_w {1} IT061_w {1} IT087_w {1} IT065_w {1} IT071_w {2} IT087_w {1} IT063_w {1} IT087_w {1} IT070_w {1} PT113_w {1} IT063_w {1} IT082_w {2} IT070_w {1} IT082_w {2} IT077_w {2} IT072_w {1} IT065_w {1} IT078_w {1} IT074_w {2} IT068_w {1} IT094_w {1} IT074_w {1} IT061_w {1} IT091_w {1} IT071_w {2} IT071_w {1} UK127_w {1} IT077_w {1} IT064_w {1} IT073_w {1} IT089_w {1} IT070_w {1} IT090_w {1} IT070_w {1} IT085_w {1} IT079_w {1} IT069_w {1} 50 100 150 200 Concentration expressed in mg/l 250 300 0 Point of discharge Average concentration over 3 years ELV (mg/l ) 350 Surfactants - Emissions to water 72 Other Anaerobic treatment Membrane bioreactor Distillation/rectification Reverse osmosis Chemical reduction Chemical oxidation Flotation Nanofiltration Microfiltration Ultrafiltration Evaporation Adsorption Activated sludge process Nitrification/denitrification Sand filtration Sedimentation Coagulation and flocculation Screening Grit separators Oil separation Neutralisation Equalisation No technique used IT082_w {1} IT082_w {1} IT082_w {1} IT096_w {1} IT067_w {1} IT096_w {1} IT082_w {2} BE011_w {1} IT097_w {1} IT069_w {1} IT067_w {1} IT092_w {1} IT094_w {1} IT074_w {1} IT097_w {1} IT092_w {1} IT077_w {2} IT064_w {1} IT071_w {1} IT091_w {1} IT096_w {1} IT097_w {1} UK124_w {1} IT072_w {1} IT096_w {1} IT072_w {1} IT092_w {1} IT061_w {1} IT075_w {1} IT076_w {1} IT071_w {2} IT078_w {1} IT092_w {1} IT074_w {2} IT064_w {1} IT067_w {1} IT067_w {1} IT078_w {1} IT084_w {1} IT077_w {2} IT068_w {1} IT069_w {1} IT090_w {1} IT071_w {1} IT077_w {1} IT089_w {1} IT091_w {1} IT073_w {1} IT077_w {1} IT068_w {1} IT073_w {1} IT097_w {1} IT082_w {2} IT079_w {1} IT087_w {1} IT079_w {1} IT074_w {2} IT089_w {1} IT094_w {1} IT074_w {1} IT065_w {1} IT090_w {1} BE009_w {1} IT061_w {1} IT087_w {1} IT065_w {1} IT071_w {2} IT087_w {1} IT063_w {1} IT087_w {1} IT070_w {1} PT113_w {1} IT063_w {1} IT082_w {2} IT070_w {1} IT082_w {2} IT077_w {2} IT072_w {1} IT065_w {1} IT078_w {1} IT074_w {2} IT068_w {1} IT094_w {1} IT074_w {1} IT061_w {1} IT091_w {1} IT071_w {2} IT071_w {1} UK127_w {1} IT077_w {1} IT064_w {1} IT073_w {1} IT089_w {1} IT070_w {1} IT090_w {1} IT070_w {1} IT085_w {1} IT079_w {1} IT069_w {1} Techniques applied Max. load over 3 years (g/day) Parameter DIR DIR DIR DIR DIR DIR IND DIR DIR IND DIR DIR IND IND DIR DIR IND IND IND IND DIR DIR DIR IND DIR IND DIR IND IND IND IND IND DIR IND IND DIR DIR IND IND IND IND IND IND IND IND IND IND IND IND IND IND DIR IND IND IND IND IND IND IND IND IND IND DIR IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Freq Per Per Per Per Per Per Freq Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Freq Per Per Per Per Per Per Per Freq Per Per Type of discharge Type of monitoring Mass load expressed in g/day 120,000 100,000 80,000 60,000 40,000 20,000 0 IT082_w {1} IT082_w {1} IT082_w {1} IT096_w {1} IT067_w {1} IT096_w {1} IT082_w {2} BE011_w {1} IT097_w {1} IT069_w {1} IT067_w {1} IT092_w {1} IT094_w {1} IT074_w {1} IT097_w {1} IT092_w {1} IT077_w {2} IT064_w {1} IT071_w {1} IT091_w {1} IT096_w {1} IT097_w {1} UK124_w {1} IT072_w {1} IT096_w {1} IT072_w {1} IT092_w {1} IT061_w {1} IT075_w {1} IT076_w {1} IT071_w {2} IT078_w {1} IT092_w {1} IT074_w {2} IT064_w {1} IT067_w {1} IT067_w {1} IT078_w {1} IT084_w {1} IT077_w {2} IT068_w {1} IT069_w {1} IT090_w {1} IT071_w {1} IT077_w {1} IT089_w {1} IT091_w {1} IT073_w {1} IT077_w {1} IT068_w {1} IT073_w {1} IT097_w {1} IT082_w {2} IT079_w {1} IT087_w {1} IT079_w {1} IT074_w {2} IT089_w {1} IT094_w {1} IT074_w {1} IT065_w {1} IT090_w {1} BE009_w {1} IT061_w {1} IT087_w {1} IT065_w {1} IT071_w {2} IT087_w {1} IT063_w {1} IT087_w {1} IT070_w {1} PT113_w {1} IT063_w {1} IT082_w {2} IT070_w {1} IT082_w {2} IT077_w {2} IT072_w {1} IT065_w {1} IT078_w {1} IT074_w {2} IT068_w {1} IT094_w {1} IT074_w {1} IT061_w {1} IT091_w {1} IT071_w {2} IT071_w {1} UK127_w {1} IT077_w {1} IT064_w {1} IT073_w {1} IT089_w {1} IT070_w {1} IT090_w {1} IT070_w {1} IT085_w {1} IT079_w {1} IT069_w {1} Anionic surfactants... Non-ionic surfactants CTAB Anionic surfactants Cationic surfactants Cationic surfactants CBAS Anionic surfactants... Anionic surfactants Cationic surfactants Anionic surfactants Anionic surfactants Cationic surfactants... Anionic surfactants Non-ionic surfactants Cationic surfactants Cationic surfactants Cationic surfactants Anionic surfactants Cationic surfactants Non-ionic surfactants Total surfactants Anionic and Non-ionic... Cationic surfactants Total surfactants Anionic surfactants Non-ionic surfactants Cationic surfactants Total surfactants Total surfactants Cationic surfactants Anionic surfactants Total surfactants Anionic surfactants Anionic surfactants Non-ionic surfactants Total surfactants Cationic surfactants Total surfactants Anionic surfactants Anionic surfactants Anionic surfactants Anionic surfactants Cationic surfactants Anionic surfactants Anionic surfactants Anionic surfactants Cationic surfactants Cationic surfactants Cationic surfactants Anionic surfactants... Cationic surfactants Anionic surfactants... Anionic surfactants Anionic surfactants Cationic surfactants Cationic surfactants Cationic surfactants Anionic surfactants... Cationic surfactants Cationic surfactants Cationic surfactants Total surfactants Anionic surfactants Cationic surfactants Anionic surfactants... Anionic surfactants Non-ionic surfactants Anionic surfactants... Total surfactants Anionic surfactants... Anionic surfactants... Non-ionic surfactants... Non-ionic surfactants CTAB Total surfactants Non-ionic surfactants Non-ionic surfactants Non-ionic surfactants... Non-ionic surfactants Non-ionic surfactants Non-ionic surfactants Non-ionic surfactants... Non-ionic surfactants Non-ionic surfactants Non-ionic surfactants Non-ionic surfactants Non-ionic surfactants Anionic surfactants Non-ionic surfactants Non-ionic surfactants Non-ionic surfactants... Non-ionic surfactants Non-ionic surfactants Non-ionic surfactants Total surfactants Total surfactants Non-ionic surfactants Non-ionic surfactants IT082_w {1} IT082_w {1} IT082_w {1} IT096_w {1} IT067_w {1} IT096_w {1} IT082_w {2} BE011_w {1} IT097_w {1} IT069_w {1} IT067_w {1} IT092_w {1} IT094_w {1} IT074_w {1} IT097_w {1} IT092_w {1} IT077_w {2} IT064_w {1} IT071_w {1} IT091_w {1} IT096_w {1} IT097_w {1} UK124_w {1} IT072_w {1} IT096_w {1} IT072_w {1} IT092_w {1} IT061_w {1} IT075_w {1} IT076_w {1} IT071_w {2} IT078_w {1} IT092_w {1} IT074_w {2} IT064_w {1} IT067_w {1} IT067_w {1} IT078_w {1} IT084_w {1} IT077_w {2} IT068_w {1} IT069_w {1} IT090_w {1} IT071_w {1} IT077_w {1} IT089_w {1} IT091_w {1} IT073_w {1} IT077_w {1} IT068_w {1} IT073_w {1} IT097_w {1} IT082_w {2} IT079_w {1} IT087_w {1} IT079_w {1} IT074_w {2} IT089_w {1} IT094_w {1} IT074_w {1} IT065_w {1} IT090_w {1} BE009_w {1} IT061_w {1} IT087_w {1} IT065_w {1} IT071_w {2} IT087_w {1} IT063_w {1} IT087_w {1} IT070_w {1} PT113_w {1} IT063_w {1} IT082_w {2} IT070_w {1} IT082_w {2} IT077_w {2} IT072_w {1} IT065_w {1} IT078_w {1} IT074_w {2} IT068_w {1} IT094_w {1} IT074_w {1} IT061_w {1} IT091_w {1} IT071_w {2} IT071_w {1} UK127_w {1} IT077_w {1} IT064_w {1} IT073_w {1} IT089_w {1} IT070_w {1} IT090_w {1} IT070_w {1} IT085_w {1} IT079_w {1} IT069_w {1} Concentration expressed in mg/l 50 45 40 35 30 25 20 15 10 5 0 Point of discharge Average concentration over 3 years ELV (mg/l ) Surfactants - Emissions to water (zoom 0-50 mg/l) 73 Other Anaerobic treatment Membrane bioreactor Distillation/rectification Reverse osmosis Chemical reduction Chemical oxidation Flotation Nanofiltration Microfiltration Ultrafiltration Evaporation Adsorption Activated sludge process Nitrification/denitrification Sand filtration Sedimentation Coagulation and flocculation Screening Grit separators Oil separation Neutralisation Equalisation No technique used IT082_w {1} IT082_w {1} IT082_w {1} IT096_w {1} IT067_w {1} IT096_w {1} IT082_w {2} BE011_w {1} IT097_w {1} IT069_w {1} IT067_w {1} IT092_w {1} IT094_w {1} IT074_w {1} IT097_w {1} IT092_w {1} IT077_w {2} IT064_w {1} IT071_w {1} IT091_w {1} IT096_w {1} IT097_w {1} UK124_w {1} IT072_w {1} IT096_w {1} IT072_w {1} IT092_w {1} IT061_w {1} IT075_w {1} IT076_w {1} IT071_w {2} IT078_w {1} IT092_w {1} IT074_w {2} IT064_w {1} IT067_w {1} IT067_w {1} IT078_w {1} IT084_w {1} IT077_w {2} IT068_w {1} IT069_w {1} IT090_w {1} IT071_w {1} IT077_w {1} IT089_w {1} IT091_w {1} IT073_w {1} IT077_w {1} IT068_w {1} IT073_w {1} IT097_w {1} IT082_w {2} IT079_w {1} IT087_w {1} IT079_w {1} IT074_w {2} IT089_w {1} IT094_w {1} IT074_w {1} IT065_w {1} IT090_w {1} BE009_w {1} IT061_w {1} IT087_w {1} IT065_w {1} IT071_w {2} IT087_w {1} IT063_w {1} IT087_w {1} IT070_w {1} PT113_w {1} IT063_w {1} IT082_w {2} IT070_w {1} IT082_w {2} IT077_w {2} IT072_w {1} IT065_w {1} IT078_w {1} IT074_w {2} IT068_w {1} IT094_w {1} IT074_w {1} IT061_w {1} IT091_w {1} IT071_w {2} IT071_w {1} UK127_w {1} IT077_w {1} IT064_w {1} IT073_w {1} IT089_w {1} IT070_w {1} IT090_w {1} IT070_w {1} IT085_w {1} IT079_w {1} IT069_w {1} Techniques applied Max. load over 3 years (g/day) Parameter DIR DIR DIR DIR DIR DIR IND DIR DIR IND DIR DIR IND IND DIR DIR IND IND IND IND DIR DIR DIR IND DIR IND DIR IND IND IND IND IND DIR IND IND DIR DIR IND IND IND IND IND IND IND IND IND IND IND IND IND IND DIR IND IND IND IND IND IND IND IND IND IND DIR IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND IND Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Freq Per Per Per Per Per Per Freq Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Per Freq Per Per Per Per Per Per Per Freq Per Per Type of discharge Type of monitoring Mass load expressed in g/day 120,000 100,000 80,000 60,000 40,000 20,000 0 IT082_w {1} IT082_w {1} IT082_w {1} IT096_w {1} IT067_w {1} IT096_w {1} IT082_w {2} BE011_w {1} IT097_w {1} IT069_w {1} IT067_w {1} IT092_w {1} IT094_w {1} IT074_w {1} IT097_w {1} IT092_w {1} IT077_w {2} IT064_w {1} IT071_w {1} IT091_w {1} IT096_w {1} IT097_w {1} UK124_w {1} IT072_w {1} IT096_w {1} IT072_w {1} IT092_w {1} IT061_w {1} IT075_w {1} IT076_w {1} IT071_w {2} IT078_w {1} IT092_w {1} IT074_w {2} IT064_w {1} IT067_w {1} IT067_w {1} IT078_w {1} IT084_w {1} IT077_w {2} IT068_w {1} IT069_w {1} IT090_w {1} IT071_w {1} IT077_w {1} IT089_w {1} IT091_w {1} IT073_w {1} IT077_w {1} IT068_w {1} IT073_w {1} IT097_w {1} IT082_w {2} IT079_w {1} IT087_w {1} IT079_w {1} IT074_w {2} IT089_w {1} IT094_w {1} IT074_w {1} IT065_w {1} IT090_w {1} BE009_w {1} IT061_w {1} IT087_w {1} IT065_w {1} IT071_w {2} IT087_w {1} IT063_w {1} IT087_w {1} IT070_w {1} PT113_w {1} IT063_w {1} IT082_w {2} IT070_w {1} IT082_w {2} IT077_w {2} IT072_w {1} IT065_w {1} IT078_w {1} IT074_w {2} IT068_w {1} IT094_w {1} IT074_w {1} IT061_w {1} IT091_w {1} IT071_w {2} IT071_w {1} UK127_w {1} IT077_w {1} IT064_w {1} IT073_w {1} IT089_w {1} IT070_w {1} IT090_w {1} IT070_w {1} IT085_w {1} IT079_w {1} IT069_w {1} Anionic surfactants... Non-ionic surfactants CTAB Anionic surfactants Cationic surfactants Cationic surfactants CBAS Anionic surfactants... Anionic surfactants Cationic surfactants Anionic surfactants Anionic surfactants Cationic surfactants... Anionic surfactants Non-ionic surfactants Cationic surfactants Cationic surfactants Cationic surfactants Anionic surfactants Cationic surfactants Non-ionic surfactants Total surfactants Anionic and Non-ionic... Cationic surfactants Total surfactants Anionic surfactants Non-ionic surfactants Cationic surfactants Total surfactants Total surfactants Cationic surfactants Anionic surfactants Total surfactants Anionic surfactants Anionic surfactants Non-ionic surfactants Total surfactants Cationic surfactants Total surfactants Anionic surfactants Anionic surfactants Anionic surfactants Anionic surfactants Cationic surfactants Anionic surfactants Anionic surfactants Anionic surfactants Cationic surfactants Cationic surfactants Cationic surfactants Anionic surfactants... Cationic surfactants Anionic surfactants... Anionic surfactants Anionic surfactants Cationic surfactants Cationic surfactants Cationic surfactants Anionic surfactants... Cationic surfactants Cationic surfactants Cationic surfactants Total surfactants Anionic surfactants Cationic surfactants Anionic surfactants... Anionic surfactants Non-ionic surfactants Anionic surfactants... Total surfactants Anionic surfactants... Anionic surfactants... Non-ionic surfactants... Non-ionic surfactants CTAB Total surfactants Non-ionic surfactants Non-ionic surfactants Non-ionic surfactants... Non-ionic surfactants Non-ionic surfactants Non-ionic surfactants Non-ionic surfactants... Non-ionic surfactants Non-ionic surfactants Non-ionic surfactants Non-ionic surfactants Non-ionic surfactants Anionic surfactants Non-ionic surfactants Non-ionic surfactants Non-ionic surfactants... Non-ionic surfactants Non-ionic surfactants Non-ionic surfactants Total surfactants Total surfactants Non-ionic surfactants Non-ionic surfactants IT082_w {1} IT082_w {1} IT082_w {1} IT096_w {1} IT067_w {1} IT096_w {1} IT082_w {2} BE011_w {1} IT097_w {1} IT069_w {1} IT067_w {1} IT092_w {1} IT094_w {1} IT074_w {1} IT097_w {1} IT092_w {1} IT077_w {2} IT064_w {1} IT071_w {1} IT091_w {1} IT096_w {1} IT097_w {1} UK124_w {1} IT072_w {1} IT096_w {1} IT072_w {1} IT092_w {1} IT061_w {1} IT075_w {1} IT076_w {1} IT071_w {2} IT078_w {1} IT092_w {1} IT074_w {2} IT064_w {1} IT067_w {1} IT067_w {1} IT078_w {1} IT084_w {1} IT077_w {2} IT068_w {1} IT069_w {1} IT090_w {1} IT071_w {1} IT077_w {1} IT089_w {1} IT091_w {1} IT073_w {1} IT077_w {1} IT068_w {1} IT073_w {1} IT097_w {1} IT082_w {2} IT079_w {1} IT087_w {1} IT079_w {1} IT074_w {2} IT089_w {1} IT094_w {1} IT074_w {1} IT065_w {1} IT090_w {1} BE009_w {1} IT061_w {1} IT087_w {1} IT065_w {1} IT071_w {2} IT087_w {1} IT063_w {1} IT087_w {1} IT070_w {1} PT113_w {1} IT063_w {1} IT082_w {2} IT070_w {1} IT082_w {2} IT077_w {2} IT072_w {1} IT065_w {1} IT078_w {1} IT074_w {2} IT068_w {1} IT094_w {1} IT074_w {1} IT061_w {1} IT091_w {1} IT071_w {2} IT071_w {1} UK127_w {1} IT077_w {1} IT064_w {1} IT073_w {1} IT089_w {1} IT070_w {1} IT090_w {1} IT070_w {1} IT085_w {1} IT079_w {1} IT069_w {1} Concentration expressed in mg/l 5.0 4.5 4.0 3.5 3.0 2.5 2.0 1.5 1.0 0.5 0.0 Point of discharge Average concentration over 3 years ELV (mg/l ) Surfactants - Emissions to water (zoom 0-5 mg/l) Surfactants - EMISSIONS TO WATER EP water name Type of discharge DIR = Direct IND = Indirect IT082_w {1} DIR Associated processes Dyeing - Singeing - Functional finishing - Thermal treatment - Wool Fulling IT082_w {1} DIR Dyeing - Singeing - Functional finishing - Thermal treatment - Wool Fulling KEI Anionic surfactants (MBAS) Non-ionic surfactants IT082_w {1} DIR IT096_w {1} DIR IT067_w {1} DIR IT096_w {1} DIR IT082_w {2} IND BE011_w {1} DIR IT097_w {1} DIR IT069_w {1} IND IT067_w {1} DIR IT092_w {1} DIR IT094_w {1} IND IT074_w {1} IND IT097_w {1} DIR IT092_w {1} DIR IT077_w {2} IND IT064_w {1} IND IT071_w {1} IND IT091_w {1} IND IT096_w {1} DIR Dyeing - Singeing - Functional finishing - Thermal treatment - Wool Fulling CTAB Dyeing - Other Dyeing - Printing - Other - Shrink-proof finishing Dyeing - Other Dyeing - Singeing - Functional finishing - Thermal treatment - Wool Fulling Dyeing Anionic surfactants Cationic surfactants Cationic surfactants CBAS Anionic surfactants (MBAS) Dyeing - Shrink-proof finishing - Printing - Other Anionic surfactants Scouring - Bleaching - Mercerising Cationic surfactants Dyeing - Printing - Other - Shrink-proof finishing Anionic surfactants Dyeing - Other No information Washing synthetic fibre - Scouring - Functional finishing Dry cleaning - Other Anionic surfactants Cationic surfactants (DBAS) Anionic surfactants Dyeing - Shrink-proof finishing - Printing - Other Non-ionic surfactants Dyeing - Other Dyeing Scouring Dyeing - Bleaching - Scouring Scouring - Dyeing - Functional finishing - Thermal treatment - Other Dyeing - Other Cationic surfactants Cationic surfactants Cationic surfactants Anionic surfactants Cationic surfactants Non-ionic surfactants Units for concentration values Min. concentration over 3 years Average concentration over 3 years Max. concentration over 3 years Max. load over 3 ELV (mg/l ) years (g/day) mg/l 0 0 0 mg/l 0 0 0 mg/l 0 0 0 mg/l 0.1 0.13 0.2 mg/l 0.1 0.15 0.2 mg/l 0.1 0.17 0.2 mg/l 0.2 0.20 0.2 mg/l 0.24 0.24 0.24 3 mg/l 0.1 0.21 0.3 mg/l 0.2 0.30 0.5 mg/l 0.1 0.18 0.5 mg/l 0.07 0.39 0.5 mg/l 0.5 0.50 0.5 mg/l 0.5 0.52 0.6 mg/l 0.2 0.39 0.62 mg/l 0.05 0.22 0.64 mg/l 0.20 0.48 0.7 mg/l 0.20 0.60 0.9 mg/l 0.50 0.65 0.9 mg/l 0.40 0.70 1 mg/l 0.40 0.67 1.1 IT097_w {1} DIR Dyeing - Shrink-proof finishing - Printing - Other Total surfactants mg/l 0.10 0.59 1.13 2 UK124_w {1} DIR IT072_w {1} IND IT096_w {1} DIR IT072_w {1} IND IT092_w {1} DIR IT061_w {1} IND IT075_w {1} IND No information Anionic and Non- mg/l ionic surfactants Thermal treatment - Scouring - Bleaching - Dyeing - Other Cationic mg/l surfactants Dyeing - Other Total surfactants mg/l Thermal treatment - Scouring - Bleaching - Dyeing - Other Anionic mg/l surfactants Dyeing - Other Non-ionic mg/l surfactants Scouring - Wool Carbonising Cationic mg/l surfactants Raw wool scouring Total surfactants mg/l 0.06 0.33 0.40 0.70 0.60 0.80 0.50 0.80 0.02 0.31 0.30 0.68 0.50 0.61 1.2 1471.2 5 1.2 1.2 2 1.2 1.2 1.3 1.3 4 IT076_w {1} IND IT071_w {2} IND IT078_w {1} IND IT092_w {1} DIR IT074_w {2} IND Raw wool scouring Dyeing - Other - Functional finishing Wool Fulling - Washing synthetic fibre - Dyeing Dyeing - Other Washing synthetic fibre - Scouring Total surfactants mg/l Cationic mg/l surfactants Anionic mg/l surfactants Total surfactants mg/l Anionic mg/l surfactants 0.34 0.50 1.48 10 0.40 0.93 1.5 0.80 1.10 1.5 0.23 0.58 1.6 2 0.50 0.85 1.6 Combination of techniques Type of sampling Equalisation, Neutralisation, Activated sludge process, Nitrification/denitrification, Sedimentation, Adsorption (e.g. powdered/granular activated carbon, lignite coke, etc.), Other Equalisation, Neutralisation, Activated sludge process, Nitrification/denitrification, Sedimentation, Adsorption (e.g. powdered/granular activated carbon, lignite coke, etc.), Other Equalisation, Neutralisation, Activated sludge process, Nitrification/denitrification, Sedimentation, Adsorption (e.g. powdered/granular activated carbon, lignite coke, etc.), Other Equalisation, Neutralisation, Activated sludge process, Nitrification/denitrification, Sedimentation, Other Equalisation, Neutralisation, Activated sludge process, Nitrification/denitrification, Sedimentation Equalisation, Neutralisation, Activated sludge process, Nitrification/denitrification, Sedimentation, Other Not applicable Not applicable Not applicable No information Not applicable No information No information No information Equalisation, Neutralisation, Coagulation and flocculation, Activated sludge process, Nitrification/denitrification, Sand 24-hour flow proportional composite sample filtration, Nanofiltration, Chemical oxidation (incl. Advanced oxidation) Equalisation, Neutralisation, Activated sludge process, Nitrification/denitrification, Sedimentation Not applicable Other Other Equalisation, Neutralisation, Activated sludge process, Nitrification/denitrification, Sedimentation Equalisation, Neutralisation, Activated sludge process, Nitrification/denitrification, Sedimentation, Reverse osmosis Other Not applicable Not applicable No information Other Other Equalisation, Neutralisation, Activated sludge process, Nitrification/denitrification, Sedimentation Equalisation, Neutralisation, Activated sludge process, Nitrification/denitrification, Sedimentation, Reverse osmosis No information Not applicable Not applicable Other Other Other No information Other No information Equalisation, Neutralisation, Activated sludge process, Nitrification/denitrification, Sedimentation, Other Other No information Equalisation, Neutralisation, Activated sludge process, Nitrification/denitrification, Sedimentation Not applicable Neutralisation, Coagulation and flocculation, Flotation, Other Other Equalisation, Neutralisation, Activated sludge process, Nitrification/denitrification, Sedimentation, Other Other Equalisation, Neutralisation, Activated sludge process, Nitrification/denitrification, Sedimentation, Reverse osmosis Other Other Other No information Other Not applicable Other Equalisation, Coagulation and flocculation, Activated Not applicable sludge process, Nitrification/denitrification, Sedimentation Equalisation, Flotation, Coagulation and flocculation, Activated sludge process, Nitrification/denitrification, Sedimentation, Membrane bioreactor Not applicable Other Other Other Equalisation, Neutralisation, Activated sludge process, Nitrification/denitrification, Sedimentation, Reverse osmosis Other Other Not applicable Other 74 Monitoring frequency 4 times per year 4 times per year 4 times per year Yearly Monthly Yearly No information No information Other Twice per year Monthly Monthly Twice per year Twice per year Other Monthly Twice per year Twice per year Twice per year Twice per year Yearly Other Monthly Twice per year Yearly Twice per year Monthly Twice per year Other Weekly Twice per year Twice per year Monthly Twice per year Monitoring standard Additional information IRSA 5170:2003* IRSA 5180:2003* DIN 38409-20:1989* APAT CNR IRSA 5170 Man 29 2003, APAT CNR IRSA 5170 Man 29 2003, APAT CNR IRSA 5170 Man 29 2003 M008:2005 Rev.0 M008:2005 Rev.0 Kit colorimetrico Tensiattivi cationici Limit value MBAS + MBAS + CTAB is 2mg/l - Limit value MBAS + MBAS + CTAB is 2mg/l - Limit value MBAS + MBAS + CTAB is 2mg/l Limit value MBAS + MBAS + CTAB is 2mg/l - Limit value MBAS + MBAS + CTAB is 2mg/l - Limit value MBAS + MBAS + CTAB is 2mg/l Limit value MBAS + MBAS + CTAB is 2mg/l - Limit value MBAS + MBAS + CTAB is 2mg/l - Limit value MBAS + MBAS + CTAB is 2mg/l Value refered to sampling period - Value refered to sampling period - Value refered to sampling period Value refered to sampling period - Value refered to sampling period - Value refered to sampling period WAC/IV/A/22 Permit: Sum anion, non ion and kation2 measurements <DL (0,20 mg/l) APAT CNR IRSA 5170 5170 Man 29 2003, IRSA 5170, IRSA 5170 INTERNAL METHOD APAT CNR IRSA 5170 Man 29 2003, APAT CNR IRSA 5170 Man 29 2003, APAT CNR IRSA 5170 Man 29 2003 Monitoring frequency: once every 4 months - Monitoring frequency: once every 4 months - Monitoring frequency: once every 4 months Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours (data referring to the year 2015) EPA 425.1, ISO 16265:2009, ISO 16265:2009 Internal method, Internal method, Internal method APAT CNR IRSA 5170 MAN 29 2003 APAT CNR IRSA 5180 Man 29 2003, IRSA 5180, IRSA 5180 DIN 38409-20:1989, Bromophenol blue (Dr Lange LCK 331), Bromophenol blue (Dr Lange LCK 331) Value refered to sampling period - Value refered to sampling period - Value refered to sampling period Concentration under the detection limit of 0,5mg/l Concentration under the detection limit of 0,5mg/l Concentration under the detection limit of 0,5mg/l Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours (YEAR 2015) Monitoring frequency: once every 4 monthsMeasurement 2 is inerior to detection limit: <0,3 - Monitoring frequency: once every 4 months - Monitoring frequency: once every 4 months Value refered to sampling period - Value refered to sampling period - Value refered to sampling period MARCONCINI SRL INTERNAL METHOD 22 Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours INTERNAL METHOD Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours APAT CNR IRSA 5170 MAN 29 2003 Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours INTERNAL METHOD Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours APAT CNR IRSA 5180 Man 29 2003 M008:2005 Rev.0 Value refered to sampling period - Value refered to sampling period - Value refered to sampling period Monitoring frequency: once every 4 monthsValue refered to sampling period - Monitoring frequency: once every 4 monthsValue refered to sampling period - Monitoring frequency: once every 4 monthsValue refered to sampling period OPPE / BAC Detergents INTERNAL METHOD Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours M009:2013 Rev.0 Value refered to sampling period - Value refered to sampling period - Value refered to sampling period APAT CNR IRSA 5170 MAN 29 2003 Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours Specroquant Merck 01787, UNI 10511/1:1996 + A1 2000, UNI 10511/1:1996 + A1 2000 INTERNAL METHOD No information Value refered to sampling period - Value refered to sampling period - Value refered to sampling period Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours; YEAR 2015 Monitoring end frequency dependent on the operator of the off-site treatment plant - Monitoring end frequency dependent on the operator of the off-site treatment plant - No information Value refered to sampling period - Value refered to sampling period - Value refered to sampling period INTERNAL METHOD APAT CNR IRSA 5170 MAN 29 2003 Calculated, Calculated, Calculated APAT CNR IRSA 5170 MAN 29 2003 Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours Value refered to sampling period - Value refered to sampling period - Value refered to sampling period Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours (YEAR 2015) 1 Surfactants - EMISSIONS TO WATER EP water name Type of discharge DIR = Direct IND = Indirect IT064_w {1} IND Associated processes Scouring IT067_w {1} DIR IT067_w {1} DIR Dyeing - Printing - Other - Shrink-proof finishing Dyeing - Printing - Other - Shrink-proof finishing IT078_w {1} IND Wool Fulling - Washing synthetic fibre - Dyeing Units for KEI concentration values Anionic mg/l surfactants Non-ionic mg/l surfactants Total surfactants mg/l Cationic mg/l surfactants Min. concentration over 3 years Average concentration over 3 years Max. concentration over 3 years Max. load over 3 ELV (mg/l ) years (g/day) 0.50 1.04 1.7 0.10 0.75 1.7 0.30 0.94 1.8 2 0.30 0.92 1.8 IT084_w {1} IND Bleaching - Dyeing - Thermal treatment Total surfactants mg/l 0.10 0.88 1.8 2 IT077_w {2} IND IT068_w {1} IND IT069_w {1} IND IT090_w {1} IND IT071_w {1} IND IT077_w {1} IND IT089_w {1} IND IT091_w {1} IND IT073_w {1} IND IT077_w {1} IND IT068_w {1} IND IT073_w {1} IND Dyeing Anionic mg/l surfactants Washing synthetic fibre - Desizing - Scouring - Bleaching - Anionic mg/l Dyeing - Functional finishing - Other surfactants Scouring - Bleaching - Mercerising Anionic mg/l surfactants Scouring - Dyeing - Thermal treatment - Other - Bleaching Anionic mg/l surfactants Dyeing - Bleaching - Scouring Cationic mg/l surfactants Desizing - Mercerising - Scouring - Bleaching - Singeing - Anionic mg/l Thermal treatment surfactants Scouring - Dyeing - Thermal treatment - Other - Bleaching Anionic mg/l surfactants Scouring - Dyeing - Functional finishing - Thermal treatment - Other Anionic mg/l surfactants Dyeing - Functional finishing Cationic mg/l surfactants Desizing - Mercerising - Scouring - Bleaching - Singeing - Cationic mg/l Thermal treatment surfactants Washing synthetic fibre - Desizing - Scouring - Bleaching - Cationic mg/l Dyeing - Functional finishing - Other surfactants Dyeing - Functional finishing Anionic surfactants mg/l (MBAS) 0.37 0.79 1.8 0.50 1.15 2 0.80 1.54 2.1 1.00 1.56 2.2 0.40 1.20 2.5 0.47 0.93 2.6 0.60 1.75 2.8 0.80 1.41 2.87 0.90 1.43 2.9 300 0.20 1.18 2.9 0.40 1.83 3 0.60 1.55 3 300 Combination of techniques Type of sampling Other Equalisation, Neutralisation, Activated sludge process, Nitrification/denitrification, Sedimentation Equalisation, Neutralisation, Activated sludge process, Nitrification/denitrification, Sedimentation Other Other Not applicable Not applicable Other Equalisation, Neutralisation, Grit separators, Screening, Coagulation and flocculation, Sedimentation No information No information Other Other Other Other Other Other 24-hour flow proportional composite sample No information Other No information Other Other 24-hour flow proportional composite sample No information No technique used No information Other Other Other Other Other No technique used Other Monitoring frequency Twice per year Monthly Monthly Twice per year 4 times per year Twice per year Twice per year Twice per year Twice per year Twice per year Twice per year Twice per year Twice per year Twice per year Twice per year Twice per year Twice per year IT097_w {1} DIR Dyeing - Shrink-proof finishing - Printing - Other Cationic mg/l surfactants 0.10 0.42 3 Equalisation, Neutralisation, Activated sludge process, Nitrification/denitrification, Sedimentation Not applicable Other IT082_w {2} IND IT079_w {1} IND IT087_w {1} IND IT079_w {1} IND IT074_w {2} IND IT089_w {1} IND IT094_w {1} IND IT074_w {1} IND IT065_w {1} IND IT090_w {1} IND BE009_w {1} DIR IT061_w {1} IND IT087_w {1} IND IT065_w {1} IND IT071_w {2} IND IT087_w {1} IND IT063_w {1} IND IT087_w {1} IND Dyeing - Singeing - Functional finishing - Thermal treatment - Wool Fulling Anionic surfactants mg/l (MBAS) Scouring - Wool Fulling - Functional finishing - Thermal Anionic mg/l treatment - Other surfactants Dyeing - Shrink-proof finishing - Shrink-proof finishing - Anionic mg/l Other surfactants Scouring - Wool Fulling - Functional finishing - Thermal Cationic mg/l treatment - Other surfactants Washing synthetic fibre - Scouring Cationic mg/l surfactants Scouring - Dyeing - Thermal treatment - Other - Bleaching Cationic mg/l surfactants No information Anionic surfactants mg/l (MBAS) Washing synthetic fibre - Scouring - Functional finishing - Cationic mg/l Dry cleaning - Other surfactants No information Cationic mg/l surfactants Scouring - Dyeing - Thermal treatment - Other - Bleaching Cationic mg/l surfactants Printing - Coating and laminating Total surfactants mg/l Scouring - Wool Carbonising Dyeing - Shrink-proof finishing - Shrink-proof finishing Other No information Dyeing - Other - Functional finishing Dyeing - Shrink-proof finishing - Shrink-proof finishing Other Dyeing - Fabric production - Dry cleaning - Printing Printing - Functional finishing Dyeing - Shrink-proof finishing - Shrink-proof finishing Other Anionic mg/l surfactants Cationic mg/l surfactants Anionic surfactants mg/l (MBAS) Anionic mg/l surfactants Non-ionic mg/l surfactants Anionic surfactants mg/l (MBAS) Total surfactants mg/l 0.10 1.18 3.34 0.50 1.57 3.4 0.18 1.20 3.5 0.20 1.50 3.9 0.20 1.60 4.1 0.40 1.63 4.1 0.71 2.04 4.5 0.20 2.85 5 0.20 2.48 5 1.00 2.63 5.5 7.21 7.21 7.21 1.20 2.90 7.6 0.07 3.15 8.2 0.20 4.18 8.3 0.70 3.50 11.2 0.62 4.31 11.6 0.10 3.33 11.9 2.70 7.97 17.1 3 20.72 No information Other Equalisation Other No information 24-hour flow proportional composite sample Not applicable, Grab/spot sample, Not applicable 24-hour flow proportional composite sample No information Twice per year Monthly Twice per year Other Other Twice per year Other 24-hour flow proportional composite sample Twice per year Other No information Twice per year Other Other Other No information Twice per year No information Other 24-hour flow proportional composite sample Twice per year Screening, Sedimentation, Equalisation, Activated sludge process, Sand filtration, Coagulation and flocculation, Flotation, Chemical oxidation (incl. Advanced oxidation), Sand filtration, Chemical reduction, Microfiltration, Reverse osmosis Other, 24-hour flow proportional composite sample, Other No information Other Other Twice per year Equalisation Not applicable, Grab/spot sample, Not applicable Monthly Other No information No information Other Equalisation Equalisation Equalisation Other Not applicable, Grab/spot sample, Not applicable Other Not applicable, Grab/spot sample, Not applicable Twice per year Monthly 4 times per year Monthly 75 Monitoring standard Additional information APAT CNR IRSA 5170 MAN 29 2003 Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours APAT CNR IRSA 5180 Man 29 2003 M009:2013 Rev.0 INTERNAL METHOD Value refered to sampling period - Value refered to sampling period - Value refered to sampling period Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours APAT CNR IRSA 5170 + APAT CNR IRSA 5180 Man. 29 2003 3 h medium composite sample - 3 h medium composite + MPI sample - APAT IRSA CNR 5170 MAN 29 2003 APAT CNR IRSA 5170 MAN 29 2003 APAT CNR IRSA 5170 MAN 29 2003 APAT CNR IRSA 5170 MAN 29 2003 INTERNAL METHOD Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours (data referring to the year 2015) Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours (data referring to the year 2015) AVERAGED PERIOD FOR ELV 3 HOURS - AVERAGED PERIOD FOR ELV 3 HOURS - DATA RELATED TO 2015. AVERAGED PERIOD FOR ELV 3 HOURS Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours APAT IRSA CNR 5170 MAN 29 2003 APAT CNR IRSA 5170 MAN 29 2003 APAT CNR IRSA 5170 MAN 29 2003 Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours AVERAGED PERIOD FOR ELV 3 HOURS - AVERAGED PERIOD FOR ELV 3 HOURS - DATA RELATED TO 2015. AVERAGED PERIOD FOR ELV 3 HOURS Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours Metedo interno n22 MARCONCINI SRL INTERNAL METHOD 22 INTERNAL METHOD Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours (data referring to the year 2015) ARPAT CNR IRSA 5170 MAN 29 2003 M008:2005 Rev.0, M.I. (d), M.I. (d) Monitoring frequency: once every 4 monthsMeasurements 1,2,3 are inferior to detection limit: 0,1 - Monitoring frequency: once every 4 monthsMeasurements 2,3 are inferior to detection limit: 0,1 - Monitoring frequency: once every 4 monthsMeasurements 1,2,3 are inferior to detection limit: 0,1 APAT IRSA -CNR 5170 Man 29 2003 APAT CNR IRSA 5170 MAN 29 2003 No information MARCONCINI SRL INTERNALMETHOD 22 INTERNAL METHOD MARCONCINI SRL INTERNALMETHOD 22 APAT IRSA 5180 Volume 2:2003 INTERNAL METHOD MIESO06/11 REV 0 MARCONCINI SRL INTERNALMETHOD 22 AVERAGED PERIOD FOR ELV 3 HOURS - AVERAGED PERIOD FOR ELV 3 HOURS - DATA RELATED TO 2015. AVERAGED PERIOD FOR ELV 3 HOURS Value refered to sampling period - Value refered to sampling period - Value refered to sampling period AVERAGED PERIOD FOR ELV 3 HOURS - AVERAGED PERIOD FOR ELV 3 HOURS - DATA RELATED TO 2015. MEASUREMENT 1 VALUE <0,2 mg/l. AVERAGED PERIOD FOR ELV 3 HOURS Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours (YEAR 2015) AVERAGED PERIOD FOR ELV 3 HOURS - AVERAGED PERIOD FOR ELV 3 HOURS - DATA RELATED TO 2015. MEASUREMENT 1 VALUE <0,2 mg/l. AVERAGED PERIOD FOR ELV 3 HOURS Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours (YEAR 2015) Requested by Italian Law - Requested by Italian Law Requested by Italian Law AVERAGED PERIOD FOR ELV 3 HOURS - AVERAGED PERIOD FOR ELV 3 HOURS - DATA RELATED TO 2015. MEASUREMENT 1 VALUE <0,2 mg/l. AVERAGED PERIOD FOR ELV 3 HOURS No information APAT CNR IRSA 5170 MAN 29 2003 No information MIESC01/09 rev 4/2011 APAT CNR IRSA 5170 MAN 29 2003 No information No information No information Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours; YEAR 2015 Value refered to sampling period - Value refered to sampling period - Value refered to sampling period Requested by Italian Law - Requested by Italian Law Requested by Italian Law Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours Value refered to sampling period - Value refered to sampling period - Value refered to sampling period Authorized in derogation - Authorized in derogation Authorized in derogation Value refered to sampling period - Value refered to sampling period - Value refered to sampling period 2 Surfactants - EMISSIONS TO WATER EP water name Type of discharge DIR = Direct IND = Indirect IT070_w {1} IND PT113_w {1} IND IT063_w {1} IND IT082_w {2} IND IT070_w {1} IND IT082_w {2} IND IT077_w {2} IND IT072_w {1} IND IT065_w {1} IND IT078_w {1} IND IT074_w {2} IND IT068_w {1} IND IT094_w {1} IND IT074_w {1} IND IT061_w {1} IND IT091_w {1} IND IT071_w {2} IND IT071_w {1} IND UK127_w {1} IND IT077_w {1} IND IT064_w {1} IND IT073_w {1} IND IT089_w {1} IND IT070_w {1} IND IT090_w {1} IND IT070_w {1} IND IT085_w {1} IND IT079_w {1} IND IT069_w {1} IND Associated processes No information Dyeing - Washing synthetic fibre - Bleaching - Functional finishing Dyeing - Fabric production - Dry cleaning - Printing Printing - Functional finishing Dyeing - Singeing - Functional finishing - Thermal treatment - Wool Fulling No information Dyeing - Singeing - Functional finishing - Thermal treatment - Wool Fulling Dyeing Units for KEI concentration values Anionic surfactants mg/l (MBAS) Anionic surfactants mg/l (MBAS) Non-ionic mg/l surfactants (TAS) Non-ionic mg/l surfactants CTAB mg/l Total surfactants mg/l Non-ionic mg/l surfactants Thermal treatment - Scouring - Bleaching - Dyeing - Other Non-ionic mg/l surfactants No information Non-ionic mg/l surfactants (BIAS) Wool Fulling - Washing synthetic fibre - Dyeing Non-ionic mg/l surfactants Washing synthetic fibre - Scouring Non-ionic mg/l surfactants Washing synthetic fibre - Desizing - Scouring - Bleaching - Non-ionic mg/l Dyeing - Functional finishing - Other surfactants No information Non-ionic mg/l surfactants (BIAS) Washing synthetic fibre - Scouring - Functional finishing - Non-ionic mg/l Dry cleaning - Other surfactants Scouring - Wool Carbonising Non-ionic mg/l surfactants Scouring - Dyeing - Functional finishing - Thermal treatment - Other Non-ionic mg/l surfactants Dyeing - Other - Functional finishing Non-ionic mg/l surfactants Dyeing - Bleaching - Scouring Non-ionic mg/l surfactants Mercerising - Bleaching - Dyeing - Scouring - Singeing - Anionic mg/l Printing surfactants Desizing - Mercerising - Scouring - Bleaching - Singeing - Non-ionic mg/l Thermal treatment surfactants Scouring Non-ionic mg/l surfactants Dyeing - Functional finishing Non-ionic mg/l surfactants (TAS) Scouring - Dyeing - Thermal treatment - Other - Bleaching Non-ionic mg/l surfactants No information Non-ionic mg/l surfactants Scouring - Dyeing - Thermal treatment - Other - Bleaching Non-ionic mg/l surfactants No information Total surfactants mg/l Dyeing Total surfactants mg/l Scouring - Wool Fulling - Functional finishing - Thermal Non-ionic mg/l treatment - Other surfactants Scouring - Bleaching - Mercerising Non-ionic mg/l surfactants Min. concentration over 3 years Average concentration over 3 years Max. concentration over 3 years Max. load over 3 ELV (mg/l ) years (g/day) 0.70 7.53 22.3 3.00 10.00 23 50 1.00 10.62 26.1 0.20 10.50 31.1 0.20 11.13 34.2 0.20 11.61 34.44 0.17 9.36 36 6.50 18.87 37 9.50 25.32 40 2.80 17.70 40 19.40 33.33 42 22.60 35.90 45 14.90 27.47 45.2 13.00 28.78 46 15.00 32.80 47 20.00 31.67 51 22.00 33.98 55 20.00 0.27 0.14 37.67 3.50 31.19 56 56.4 111336.42 57 34.80 49.63 60 16.00 33.67 65 300 21.00 50.08 88 1.80 18.88 89.1 18.00 68.00 110 2.50 37.45 145.6 300 80.00 88.30 157 27.20 99.73 174 39.00 110.45 176.7 Combination of techniques No information No information Equalisation No information No information No information No information Other Other Other Other Other Other Other Other No information Other No information Neutralisation No information Other No technique used Other No information Other No information Equalisation Other Other Type of sampling Not applicable Other Other No information Not applicable No information Other Other No information Other Other Other No information Other Other Other Other Other 24-hour flow proportional composite sample Other Other Other 24-hour flow proportional composite sample Not applicable 24-hour flow proportional composite sample Not applicable Not applicable 24-hour flow proportional composite sample Other Monitoring frequency Twice per year Yearly 4 times per year No information Twice per year No information Twice per year Twice per year No information Twice per year Twice per year Twice per year Twice per year Twice per year Twice per year Twice per year Twice per year Twice per year Weekly Twice per year Twice per year Twice per year Twice per year Twice per year Twice per year Twice per year Other Twice per year Twice per year Monitoring standard APAT-IRSA CNR 29-2003 5170 No information No information APAT IRSA -CNR 5180 Man 29 2003 con variazione DIN 38409 Calcolo UNI 10511-1:1996/A1:2000 UNI 10511-1:1996/A1:2000 MIES001/10 rev3/2011 UNI 10511-1:1996/A1:2000 UNI 10511-1:1996/A1:2000 UNI 10511-1:1996/A1:2000 APAT IRSA 5180 Volume 2:2003 UNI 10511-1:1996/A1:2000 UNI 10511-1:1996/A1:2000 UNI 10511-1:1996/A1:2000 UNI 10511-1:1996/A1:2000 UNI 10511-1:1996/A1:2000 No information UNI 10511-1:1996/A1:2000 UNI 10511-1:1996/A1:2000 UNI 10511-1:1996/A1:2000 UNI 10511-1:1996a1:2000 APAT-IRSA CNR 29-2003 5180 UNI 10511-1:1996a1:2000 SUMMATION MBAS+BIAS+CTAB No information UNI 10511-1:1996a1:2000 UNI 10511-1:1996/A1:2000 Additional information detection limit: 4 mg/Ldetection limit: 3 mg/L (since 2018) Authorized in derogation - Authorized in derogation Authorized in derogation Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours Requested by Italian Law - Requested by Italian Law Requested by Italian Law Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours (YEAR 2015) Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours (data referring to the year 2015) Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours (YEAR 2015) Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours; YEAR 2015 Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours AVERAGED PERIOD FOR ELV 3 HOURS - AVERAGED PERIOD FOR ELV 3 HOURS - DATA RELATED TO 2015. AVERAGED PERIOD FOR ELV 3 HOURS AVERAGED PERIOD FOR ELV 3 HOURS - AVERAGED PERIOD FOR ELV 3 HOURS - DATA RELATED TO 2015. AVERAGED PERIOD FOR ELV 3 HOURS Monitoring end frequency dependent on the operator of the off-site treatment plant AVERAGED PERIOD FOR ELV 3 HOURS - AVERAGED PERIOD FOR ELV 3 HOURS - DATA RELATED TO 2015. AVERAGED PERIOD FOR ELV 3 HOURS Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours - Averaging period for ELV: 3 hours (data referring to the year 2015) 76 3 77 Other Anaerobic treatment Membrane bioreactor Distillation/rectification Reverse osmosis Chemical reduction Chemical oxidation Flotation Nanofiltration Microfiltration Ultrafiltration Evaporation Adsorption Activated sludge process Nitrification/denitrification Sand filtration Sedimentation Coagulation and flocculation Screening Grit separators Oil separation Neutralisation Equalisation No technique used DE031_w {1} SE120_w {1} DE039_w {1} PT105_w {1} SE120_w {1} IT097_w {1} IT065_w {1} DE026_w {1} DE026_w {1} IT092_w {1} PT105_w {1} BE010_w {1} IT092_w {1} BE010_w {1} DE034_w {1} IT092_w {1} BE010_w {1} DE039_w {1} IT092_w {1} BE011_w {1} DE034_w {1} BE014_w {1} BE014_w {1} BE014_w {1} DE034_w {1} IT097_w {1} DE032_w {1} SE119_w {1} BE014_w {1} Techniques applied years (g/day) 15 Max. load over 3 Parameter Type of discharge Type of monitoring Mass load expressed in g/day Concentration expressed in mg/l 0.3 0.3 0.2 0.2 0.1 0.1 30 25 20 10 5 0 IND Per DE031_w {1} SE120_w {1} DE039_w {1} PT105_w {1} SE120_w {1} IT097_w {1} IT065_w {1} DE026_w {1} DE026_w {1} IT092_w {1} PT105_w {1} BE010_w {1} IT092_w {1} BE010_w {1} DE034_w {1} IT092_w {1} BE010_w {1} DE039_w {1} IT092_w {1} BE011_w {1} DE034_w {1} BE014_w {1} BE014_w {1} BE014_w {1} DE034_w {1} IT097_w {1} DE032_w {1} SE119_w {1} BE014_w {1} PFOS; PFOA DE031_w {1} IND Freq PFOS SE120_w {1} IND Per PFOS DE039_w {1} IND Per PFOS PT105_w {1} IND Freq PFOA SE120_w {1} DIR Per PFOA PFC: PFBA; PFPeA; PFHxA; PFHpA; PFOA; PFNA; PFDA; PFUnA; PFDoA; PFTrA; PFTA; PFBS; PFHxS;... PFOS Per IND IT097_w {1} IT065_w {1} DE026_w {1} IND Per IND Per PFOA DE026_w {1} DIR Per PFHxA IT092_w {1} IND Per PFOA PT105_w {1} DIR Per PFOS BE010_w {1} DIR Per PFPeA IT092_w {1} DIR Per PFHxS BE010_w {1} DIR Per PFOA DE034_w {1} DIR Per PFOA IT092_w {1} DIR Per PFOA BE010_w {1} IND Per PFOA DE039_w {1} DIR Per PFHpA IT092_w {1} DIR Per PFOA BE011_w {1} DIR Per PFHxA DE034_w {1} DIR Per PFOS BE014_w {1} DIR Per PFHxA BE014_w {1} DIR Per PFHpA BE014_w {1} DIR Per PFPeH DE034_w {1} DIR Per 6 substances IT097_w {1} DIR Per Sum10PFT DE032_w {1} IND Freq PFAS SE119_w {1} DIR Per PFOA BE014_w {1} 0.0 Point of discharge Average concentration over 3 years ELV (mg/l ) 0.4 0.4 Perfluorocarbons - Emissions to water 78 Other Anaerobic treatment Membrane bioreactor Distillation/rectification Reverse osmosis Chemical reduction Chemical oxidation Flotation Nanofiltration Microfiltration Ultrafiltration Evaporation Adsorption Activated sludge process Nitrification/denitrification Sand filtration Sedimentation Coagulation and flocculation Screening Grit separators Oil separation Neutralisation Equalisation No technique used DE031_w {1} SE120_w {1} DE039_w {1} PT105_w {1} SE120_w {1} IT097_w {1} IT065_w {1} DE026_w {1} DE026_w {1} IT092_w {1} PT105_w {1} BE010_w {1} IT092_w {1} BE010_w {1} DE034_w {1} IT092_w {1} BE010_w {1} DE039_w {1} IT092_w {1} BE011_w {1} DE034_w {1} BE014_w {1} BE014_w {1} BE014_w {1} DE034_w {1} IT097_w {1} DE032_w {1} SE119_w {1} BE014_w {1} Techniques applied years (g/day) 15 Max. load over 3 Parameter Type of discharge Type of monitoring Mass load expressed in g/day Concentration expressed in mg/l 0.0008 0.0006 0.0004 0.0002 30 25 20 10 5 0 IND Per DE031_w {1} SE120_w {1} DE039_w {1} PT105_w {1} SE120_w {1} IT097_w {1} IT065_w {1} DE026_w {1} DE026_w {1} IT092_w {1} PT105_w {1} BE010_w {1} IT092_w {1} BE010_w {1} DE034_w {1} IT092_w {1} BE010_w {1} DE039_w {1} IT092_w {1} BE011_w {1} DE034_w {1} BE014_w {1} BE014_w {1} BE014_w {1} DE034_w {1} IT097_w {1} DE032_w {1} SE119_w {1} BE014_w {1} PFOS; PFOA DE031_w {1} IND Freq PFOS SE120_w {1} IND Per PFOS DE039_w {1} IND Per PFOS PT105_w {1} IND Freq PFOA SE120_w {1} DIR Per PFOA PFC: PFBA; PFPeA; PFHxA; PFHpA; PFOA; PFNA; PFDA; PFUnA; PFDoA; PFTrA; PFTA; PFBS; PFHxS;... PFOS Per IND IT097_w {1} IT065_w {1} DE026_w {1} IND Per IND Per PFOA DE026_w {1} DIR Per PFHxA IT092_w {1} IND Per PFOA PT105_w {1} DIR Per PFOS BE010_w {1} DIR Per PFPeA IT092_w {1} DIR Per PFHxS BE010_w {1} DIR Per PFOA DE034_w {1} DIR Per PFOA IT092_w {1} DIR Per PFOA BE010_w {1} IND Per PFOA DE039_w {1} DIR Per PFHpA IT092_w {1} DIR Per PFOA BE011_w {1} DIR Per PFHxA DE034_w {1} DIR Per PFOS BE014_w {1} DIR Per PFHxA BE014_w {1} DIR Per PFHpA BE014_w {1} DIR Per PFPeH DE034_w {1} DIR Per 6 substances IT097_w {1} DIR Per Sum10PFT DE032_w {1} IND Freq PFAS SE119_w {1} DIR Per PFOA BE014_w {1} 0.0000 Point of discharge Average concentration over 3 years ELV (mg/l ) 0.0010 Perfluorocarbons - Emissions to water (zoom 0-0.001 mg/l) EP water name Type of discharge DIR = Direct IND = Indirect Associated processes DE031_w {1} IND Dyeing Perfluorocarbons - EMISSIONS TO WATER Units for Min. Average Max. Max. load over 3 KEI concentration concentration concentration concentration years (g/day) ELV (mg/l ) Combination of techniques values over 3 years over 3 years over 3 years PFOS; PFOA mg/l 0 0 0 No information Type of sampling No information SE120_w {1} IND DE039_w {1} IND PT105_w {1} IND SE120_w {1} IND IT097_w {1} DIR IT065_w {1} IND DE026_w {1} IND DE026_w {1} IND IT092_w {1} DIR PT105_w {1} IND BE010_w {1} DIR IT092_w {1} DIR BE010_w {1} DIR DE034_w {1} DIR IT092_w {1} DIR BE010_w {1} DIR DE039_w {1} IND IT092_w {1} DIR BE011_w {1} DIR DE034_w {1} DIR BE014_w {1} DIR BE014_w {1} DIR BE014_w {1} DIR DE034_w {1} DIR IT097_w {1} DIR DE032_w {1} DIR SE119_w {1} IND DE032_w {1} DIR BE014_w {1} DIR Washing synthetic fibre - Desizing - Bleaching PFOS mg/l Mercerising - Dyeing - Washing synthetic fibre - Bleaching - PFOS mg/l Desizing Dyeing - Bleaching PFOS mg/l Washing synthetic fibre - Desizing - Bleaching PFOA mg/l Dyeing - Shrink-proof finishing - Printing - Other PFOA mg/l No information PFC: PFBA; PFPeA; PFHxA; PFHpA; PFOA; PFNA; PFDA; PFUnA; PFDoA; PFTrA; PFTA; PFBS; PFHxS; PFHpS; PFOS; PFDS; PFOSA; PFHxO; mg/l PFOcO; PFDeO; PFOcAc; FTOH 102; PFHxS; NMeFOSE; NEtFOSE; NMeFOSA; NEtFOSA; FTA 102; H2PFDA; HPFHpA; HPFUnA; H4PFO Washing synthetic fibre - Desizing - Dyeing - Bleaching PFOS mg/l Washing synthetic fibre - Desizing - Dyeing - Bleaching PFOA mg/l Dyeing - Other PFHxA mg/l Dyeing - Bleaching PFOA mg/l Bleaching - Dyeing - Bleaching - Scouring - Functional PFOS mg/l finishing Dyeing - Other PFPeA mg/l Bleaching - Dyeing - Bleaching - Scouring - Functional PFHxS mg/l finishing Washing synthetic fibre - Desizing - Bleaching - Dyeing PFOA mg/l Dyeing - Other PFOA mg/l Bleaching - Dyeing - Bleaching - Scouring - Functional PFOA mg/l finishing Mercerising - Dyeing - Washing synthetic fibre - Bleaching - PFOA mg/l Desizing Dyeing - Other PFHpA mg/l 0.000009 0.00001 0.000013 0.0000042 0.0000090 0.0000100 0.0000120 0.0000130 0.000009 0.00001 0.000013 0.00001 0.0000140 0.000018 0.000019 0.00001 0.00003 0.000037 0.000002 0.00005 0.00001 0.000078 0.000096 0.000009 0.00016 0.000175 0.0000216 0.0000190 0.0000310 0.0000373 0.0000217 0.00005 0.0000200 0.00008 0.00010 0.00007 0.0002 0.0002 0.0000246 0.0000305 0.000031 0.0000373 0.00004 0.000052 0.00006 0.000078 0.000096 0.0001 0.00016 0.000175 0.0038868 0.004819 0.01 0.041184 0.05 Dyeing PFOA mg/l Washing synthetic fibre - Desizing - Bleaching - Dyeing Bleaching - Dyeing - Functional finishing Bleaching - Dyeing - Functional finishing Bleaching - Dyeing - Functional finishing Washing synthetic fibre - Desizing - Bleaching - Dyeing Dyeing - Shrink-proof finishing - Printing - Other PFHxA mg/l PFOS mg/l PFHxA mg/l PFHpA mg/l PFPeH mg/l 6 substances mg/l Washing synthetic fibre - Desizing - Bleaching - Dyeing Printing Washing synthetic fibre - Desizing - Functional finishing Dyeing Washing synthetic fibre - Desizing - Bleaching - Dyeing Printing Sum10PFT PFAS Sum2PFT Bleaching - Dyeing - Functional finishing PFOA mg/l mg/l No unit reported mg/l 0.0000004 0.0005 0.0005 0.0001 0.0002 0.0010 0.0010 0.0006 0.04 0.006 0.00012 0.0005 0.0005 0.0002 0.0005 0.0010 0.0010 0.0008 0.0011 0.088 0.084 0.0002 0.000496 0.0005 0.0005 0.00073 0.000984 0.001 0.0011 0.15 0.3756 0.10147 0.05 0.261888 0.0282 0.01 0.046873 0.177624 0.519552 26.292 0.05 Neutralisation, Oil separation, Equalisation Equalisation, Neutralisation No information Neutralisation, Oil separation, Equalisation Equalisation, Neutralisation, Activated sludge process, Nitrification/denitrification, Sedimentation 24-hour flow proportional composite sample Flow proportional composite sample No information 24-hour flow proportional composite sample Not applicable Other No information No information Other No information Other Equalisation, Neutralisation, Activated sludge process, Nitrification/denitrification, Sedimentation, Reverse osmosis No information EqualisationActivated sludge process, Nitrification/denitrification, Other Equalisation, Neutralisation, Activated sludge process, Nitrification/denitrification, Sedimentation, Reverse osmosis EqualisationActivated sludge process, Nitrification/denitrification, Other Not applicable No information 24-hour flow proportional composite sample Not applicable 24-hour flow proportional composite sample Activated sludge process, Nitrification/denitrification Flow proportional composite sample Equalisation, Neutralisation, Activated sludge process, Nitrification/denitrification, Sedimentation, Reverse osmosis EqualisationActivated sludge process, Nitrification/denitrification, Other Not applicable 24-hour flow proportional composite sample Equalisation, Neutralisation Flow proportional composite sample Equalisation, Neutralisation, Activated sludge process, Nitrification/denitrification, Sedimentation, Reverse osmosis Not applicable Equalisation, Neutralisation, Coagulation and flocculation, Activated sludge process, Nitrification/denitrification, Sand 24-hour flow proportional composite sample filtration, Nanofiltration, Chemical oxidation (incl. Advanced oxidation) Activated sludge process, Nitrification/denitrification Equalisation, Activated sludge process, Nitrification/denitrification Equalisation, Activated sludge process, Nitrification/denitrification Equalisation, Activated sludge process, Nitrification/denitrification Activated sludge process, Nitrification/denitrification Flow proportional composite sample 24-hour flow proportional composite sample 24-hour flow proportional composite sample 24-hour flow proportional composite sample Flow proportional composite sample Equalisation, Neutralisation, Activated sludge process, Nitrification/denitrification, Sedimentation Not applicable Equalisation, Neutralisation, Grit separators, Coagulation and flocculation, Sedimentation, Sand filtration, Nitrification/denitrification, Activated sludge process 24-hour flow proportional composite sample No technique used 24-hour flow proportional composite sample Equalisation, Neutralisation, Grit separators, Coagulation and flocculation, Sedimentation, Sand filtration, Nitrification/denitrification, Activated sludge process Equalisation, Activated sludge process, Nitrification/denitrification 24-hour flow proportional composite sample 24-hour flow proportional composite sample Monitoring frequency Yearly Other No information Yearly Other Other Twice per year No information No information Other Yearly Other Other Other No information Other Other No information Other No information No information No information No information No information No information Other Other No information Other No information Monitoring standard Liquid Chromatograph Mass Spectrometer No information No information No information No information MI1207 Rev.2:2018 Additional information detection limit: PFOA&PFOS: 0,01, Other 0,5: result was lower as detection limit - detection limit: PFOA&PFOS: 0,01, Other 0,5: result was lower as detection limit detection limit: PFOA&PFOS: 0,01, Other 0,5: result was lower as detection limit One week every two years, See appendix 2One week every two years, See Appendix 1 Type of sampling not specified. Measurement value: < 0.01 (below level of quantification) One week every two years, See Appendix 2One week every two years, See Appendix 1 Monitoring frequency: spot MIP_CW1207_rev2:2018 No information No information MI1207 rev2:2018 No information No information MI1207 rev2:2018 No information No information MI1207 rev2:2018 No information No information MI1207 rev2:2018 WAC/IV/A/025, No information WAC/IV/A/025 WAC/IV/A/025 WAC/IV/A/025 No information With reference to DIN38407-42 or CEN/TS15968 and followed by LCMS or LC/MS/MS analysis No information No information No information WAC/IV/A/025 Not detected, LOD 0.01 ; introduced during 2018 to follow the ZDHC Waste Water Guide lines Monitoring frequency: spot Type of sampling not specified. Monitoring frequency: spot 2 measurements < 0,01 ug/l measured values from the authority surveillance Monitoring frequency: spot Monitoring frequency: spot - 1 measurement <0,10 ug/l measured values from the authority surveillance 5 measurements < DL (0,03 ug/l) Limit value 200 ug/l (sum PFT excl. PFOA, PFOS) Limit value 200 ug/l (sum PFT excl. PFOA, PFOS) measured values from the authority surveillance Monitoring frequency: spotall the substance analysed are inferior to detection limit: <1 or < 0,01 g/l Occasional - Occasional - Occasional - See appendix about PFAS-analysis. - See appendix about PFAS-analysis. Occasional - Occasional - Occasional 79 1 80 Other Anaerobic treatment Membrane bioreactor Distillation/rectification Reverse osmosis Chemical reduction Chemical oxidation Flotation Nanofiltration Microfiltration Ultrafiltration Evaporation Adsorption Activated sludge process Nitrification/denitrification Sand filtration Sedimentation Coagulation and flocculation Screening Grit separators Oil separation Neutralisation Equalisation No technique used IT092_w {1} IT097_w {1} IT097_w {1} IT076_w {1} IT092_w {1} IT076_w {1} IT076_w {1} IT076_w {1} UK128_w {1} UK129_w {1} UK129_w {1} UK129_w {1} UK129_w {1} UK128_w {1} UK128_w {1} Techniques applied years (g/day) Max. load over 3 Parameter Type of monitoring Mass load expressed in g/day Concentration expressed in mg/l 1.0 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0.0 DIR Per IT092_w {1} IT097_w {1} IT097_w {1} IT076_w {1} IT092_w {1} IT076_w {1} IT076_w {1} IT076_w {1} UK128_w {1} UK129_w {1} UK129_w {1} UK129_w {1} UK129_w {1} UK128_w {1} UK128_w {1} 63 substances IT092_w {1} DIR Per 277 substances IT097_w {1} DIR Per Imidacloprid IT097_w {1} IND Per Desetilatrazina IT076_w {1} DIR Per Imidacloprid IT092_w {1} IND Per Atrazina IT076_w {1} IND Per Simazina IT076_w {1} IND Per Total pesticides IT076_w {1} IND Per Organochlorine UK128_w {1} Organochlorine pesticides Per IND UK129_w {1} IND Per Phenylurea pesticides UK129_w {1} Synthetic pyrethroid pesticides Per IND UK129_w {1} Organophosphorus pesticides Per IND UK129_w {1} Per Organophosphate UK128_w {1} IND Per Synthetic Pyrethroid UK128_w {1} IND Type of discharge 1.8 1.6 1.4 1.2 1.0 0.8 0.6 0.4 0.2 0.0 Point of discharge Average concentration over 3 years ELV (mg/l ) Pesticides - Emissions to water 81 Other Anaerobic treatment Membrane bioreactor Distillation/rectification Reverse osmosis Chemical reduction Chemical oxidation Flotation Nanofiltration Microfiltration Ultrafiltration Evaporation Adsorption Activated sludge process Nitrification/denitrification Sand filtration Sedimentation Coagulation and flocculation Screening Grit separators Oil separation Neutralisation Equalisation No technique used IT092_w {1} IT097_w {1} IT097_w {1} IT076_w {1} IT092_w {1} IT076_w {1} IT076_w {1} IT076_w {1} UK128_w {1} UK129_w {1} UK129_w {1} UK129_w {1} UK129_w {1} UK128_w {1} UK128_w {1} Techniques applied years (g/day) Max. load over 3 Parameter Type of monitoring Mass load expressed in g/day Concentration expressed in mg/l 0.002 1.0 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0.0 DIR Per IT092_w {1} IT097_w {1} IT097_w {1} IT076_w {1} IT092_w {1} IT076_w {1} IT076_w {1} IT076_w {1} UK128_w {1} UK129_w {1} UK129_w {1} UK129_w {1} UK129_w {1} UK128_w {1} UK128_w {1} 63 substances IT092_w {1} DIR Per 277 substances IT097_w {1} DIR Per Imidacloprid IT097_w {1} IND Per Desetilatrazina IT076_w {1} DIR Per Imidacloprid IT092_w {1} IND Per Atrazina IT076_w {1} IND Per Simazina IT076_w {1} IND Per Total pesticides IT076_w {1} IND Per Organochlorine UK128_w {1} Organochlorine pesticides Per IND UK129_w {1} IND Per Phenylurea pesticides UK129_w {1} Synthetic pyrethroid pesticides Per IND UK129_w {1} Organophosphorus pesticides Per IND UK129_w {1} Per Organophosphate UK128_w {1} IND Per Synthetic Pyrethroid UK128_w {1} IND Type of discharge Point of discharge 0.000 0.008 Average concentration 0.006 over 3 years ELV (mg/l ) 0.004 0.010 Pesticides - Emissions to water (zoom 0-0.01 mg/l) EP water name Type of discharge DIR = Direct IND = Indirect IT092_w {1} DIR Associated processes Dyeing - Other IT097_w {1} DIR IT097_w {1} DIR Dyeing - Shrink-proof finishing - Printing - Other Dyeing - Shrink-proof finishing - Printing - Other IT076_w {1} IND Raw wool scouring IT092_w {1} DIR Dyeing - Other IT076_w {1} IND Raw wool scouring IT076_w {1} IND Raw wool scouring IT076_w {1} IND Raw wool scouring Pesticides - EMISSIONS TO WATER Units for Min. Average Max. Max. load over 3 KEI concentration concentration concentration concentration years (g/day) ELV (mg/l ) values over 3 years over 3 years over 3 years 63 substances mg/l 0.00001 0.00001 0.00001 277 substances mg/l Imidacloprid mg/l 0.00003 0.00005 0.00003 0.00005 0.00003 0.000053 Desetilatrazina mg/l 0.00007 0.00007 0.00007 Imidacloprid mg/l 0.00017 0.0002 0.000165 Atrazina mg/l 0.0005 0.0005 0.0005 Simazina mg/l 0.0007 0.0007 0.0007 Total pesticides mg/l 0.0013 0.0013 0.0013 Combination of techniques Equalisation, Neutralisation, Activated sludge process, Nitrification/denitrification, Sedimentation, Reverse osmosis Equalisation, Neutralisation, Activated sludge process, Nitrification/denitrification, Sedimentation Equalisation, Neutralisation, Activated sludge process, Nitrification/denitrification, Sedimentation Equalisation, Flotation, Coagulation and flocculation, Activated sludge process, Nitrification/denitrification, Sedimentation, Membrane bioreactor Equalisation, Neutralisation, Activated sludge process, Nitrification/denitrification, Sedimentation, Reverse osmosis Equalisation, Flotation, Coagulation and flocculation, Activated sludge process, Nitrification/denitrification, Sedimentation, Membrane bioreactor Equalisation, Flotation, Coagulation and flocculation, Activated sludge process, Nitrification/denitrification, Sedimentation, Membrane bioreactor Equalisation, Flotation, Coagulation and flocculation, Activated sludge process, Nitrification/denitrification, Sedimentation, Membrane bioreactor Type of sampling Not applicable Not applicable Not applicable Not applicable Not applicable Not applicable Not applicable Not applicable Monitoring frequency Other Other Other Other Other Other Other Other UK128_w {1} IND Raw wool scouring Organochlorine mg/l 0 0.0002 0.001685 0.025 Coagulation and flocculation 24-hour flow proportional composite sample 4 times per year UK129_w {1} IND Raw wool scouring UK129_w {1} IND Raw wool scouring UK129_w {1} IND Raw wool scouring UK129_w {1} IND Raw wool scouring UK128_w {1} IND Raw wool scouring UK128_w {1} IND Raw wool scouring Organochlorine mg/l pesticides Phenylurea mg/l pesticides Synthetic pyrethroid mg/l pesticides Organophosphor mg/l us pesticides Organophosphat mg/l e Synthetic mg/l Pyrethroid 0.000035 0.0010 0.003958 0.05 0.050 0.05 0.0002 0.008 0.08165 0.0003 0.020 0.09447 0.0025 0.070 0.21586 0.013 Grit separators, Screening, Oil separation, Coagulation and 24-hour flow proportional composite sample flocculation, Ultrafiltration, Flotation 0.35 Grit separators, Screening, Oil separation, Coagulation and 24-hour flow proportional composite sample flocculation, Ultrafiltration, Flotation 0.1145 Grit separators, Screening, Oil separation, Coagulation and 24-hour flow proportional composite sample flocculation, Ultrafiltration, Flotation 0.985 Grit separators, Screening, Oil separation, Coagulation and 24-hour flow proportional composite sample flocculation, Ultrafiltration, Flotation 4 times per year 4 times per year 4 times per year 4 times per year 1.7 Coagulation and flocculation 24-hour flow proportional composite sample 4 times per year 0 0.077 0.35476 0.537 Coagulation and flocculation 24-hour flow proportional composite sample 4 times per year Monitoring standard Additional information APAT CNR IRSA 5060 Man 29 2003 APAT CNR IRSA 5060 Man 29 2003 APAT CNR IRSA 5060 Man 29 2003 APAT CNR IRSA 5060 Man 29 2003 APAT CNR IRSA 5060 Man 29 2003 APAT CNR IRSA 5060 Man 29 2003 APAT CNR IRSA 5060 Man 29 2003 APAT CNR IRSA 5060 Man 29 2003 Monitoring frequency: spotAll the substances analysed are inferior to detection limit: <0,01 g/l Monitoring frequency: spotall the substance analysed are inferior to detection limit:until < 0,03 g/l Monitoring frequency: spot Monitoring frequency: spot Monitoring frequency: spot Monitoring frequency: spot Monitoring frequency: spot Monitoring frequency: spot No information OC individual ELV - all values are Microgram/litre - HCB & Isomers 1.0 - HCH & Isomers 1.0 - Aldrin 1.0 - Dieldrin 1.0 Endrin 1.0 - Endosulphan 1.0 - DDT & Isomers 10.0. - OC individual ELV - all values are Microgram/litre - HCB & Isomers 1.0 - HCH & Isomers 1.0 - Aldrin 1.0 - Dieldrin 1.0 Endrin 1.0 - Endosulphan 1.0 - DDT & Isomers 10.0. - OC individual ELV - all values are Microgram/litre - HCB & Isomers 1.0 - HCH & Isomers 1.0 - Aldrin 1.0 - Dieldrin 1.0 Endrin 1.0 - Endosulphan 1.0 - DDT & Isomers 10.0. liquid/liquid extraction, GPC/SPE cleanup, GC-MS analysis 7 different OC pesticides are separately limited and analysed for - values given are for combined OC pesticides. Individual ELV for each pesticide are: HCH = 5ug/litre, HCB = 1ug/litre; Aldrin = 1ug/litre; Dieldrin = 1ug/litre; Endrin = 1ug/litre; Endosu - as above - as above liquid/liquid extraction, GPC/SPE cleanup, GC-MS analysis 2 different PU pesticides are separately limited and analysed for - values are given for combined PU pesticides. Individual ELV for each pesticide are: Flucofuron = 100ug/litre; Sulcofuron = 250ug/litre. These pesticides are no longer used in UK for tex - as above - as above liquid/liquid extraction, GPC/SPE cleanup, GC-MS analysis 3 different SP pesticides are separately limited and analysed for - values given are for combined SP pesticides. Individual ELV for each pesticide are: Cyfluthrin =1ug/litre; Cypermethrin = 110ug/litre; Permethrin = 3.5ug/litre. All pesticide removal e - as above - as above liquid/liquid extraction, GPC/SPE cleanup, GC-MS analysis 3 different OP pesticides are separately limited and analysed for - values given are for combined OP pesticides. Individual ELV for each pesticide are: Propetamphos = 150ug/litre; Diazinon = 800ug/litre; Chlorfenvinphos = 35ug/litre. All pesticide remov - as above - as above No information OP individual ELV - all values are Microgram/litre Propetamphos 800 - Diazinon 800 - Chlorfenvinphos 100. OP individual ELV - all values are Microgram/litre Propetamphos 800 - Diazinon 800 - Chlorfenvinphos 100. OP individual ELV - all values are Microgram/litre Propetamphos 800 - Diazinon 800 - Chlorfenvinphos 100. No information SP individual ELV - all values are Microgram/litre Cypermethrin 500 - Cyfluthrin 10.0 - Permethrin 17.0 Deltamethrin 10.0 - SP individual ELV - all values are Microgram/litre - Cypermethrin 500 - Cyfluthrin 10.0 Permethrin 17.0 - Deltamethrin 10.0 - SP individual ELV all values are Microgram/litre - Cypermethrin 500 Cyfluthrin 10.0 - Permethrin 17.0 - Deltamethrin 10.0 82 1 EP water name Parameter Monitoring frequency DE025 w{1} BE007 w{1} BE009 w{1} BE011 w{1} FR134 w{1} SE120 w{1} SE119 w{1} FR131 w{1} IT063 w{1} IT067 w{1} ES058 w{1} IT097 w{1} IT092 w{1} IT096 w{1} BE009 w{1} SE119 w{1} IT067 w{1} IT097 w{1} IT092 w{1} SE119 w{1} IT067 w{1} IT097 w{1} IT092 w{1} SE120 w{1} SE119 w{1} Toxicity 1 Toxicity 1 4 times per year Yearly Toxicity 1 No information Toxicity 1 Toxicity 1 No information Twice per year Toxicity 1 No information Toxicity 1 No information Toxicity 1 Toxicity 1 Toxicity 1 Toxicity 1 Toxicity 1 Toxicity 1 Toxicity 1 4 times per year Yearly No information 4 times per year Yearly Other (please specify in "additional information") Yearly Toxicity 2 No information Toxicity 2 No information Toxicity 2 No information Toxicity 2 Toxicity 2 Toxicity 3 Yearly Other (please specify in "additional information") No information Toxicity 3 No information Toxicity 3 Yearly Toxicity 3 Other (please specify in "additional information") Biodeg/elim No information Biodeg/elim No information PT110 w{1} Colour Monthly AT006 w{1} Colour Daily;Daily;Daily AT002 w{1} Colour Monthly AT004 w{1} BE013 w{1} Colour Colour Twice per year Yearly WASTE WATER CHARACTERISTICS: TOXICITY, BIODEGRADABILITY/ELIMINABILITY AND COLOUR Type of sampling Unit Grab/spot sample Grab/spot sample;Not applicable GEI LC50 (96h) Grab/spot sample % Grab/spot sample Grab/spot sample OECD203 No information Flow proportional composite sample 24-hour flow proportional composite sample 24-hour flow proportional composite sample Other or more than one type Grab/spot sample Grab/spot sample Grab/spot sample % No information No information No information %I 30' Equitox % Grab/spot sample % Grab/spot sample % Grab/spot sample 24-hour flow proportional composite sample Grab/spot sample % % %-24h Grab/spot sample % Grab/spot sample 24-hour flow proportional composite sample Grab/spot sample % % %-72h Grab/spot sample % Individual measurements (unless mentioned ELV otherwise) Report 11 measurements: six 2 times 1, five times 2 0.431 7.9-10-8.9 11.1-11-42-41.7 Report 6 measurements, all equal to 0 5-5 50 not detected 5.1-5.5 1,3 % (15 min exp) Report 12 measurements, all none equal to 0 17-3 11 50 2.45-0-0 0-16-31 50 3 50 Report 3 measurements, all 50 equal to 0 45-12.5-78.4-0 100-5 Not toxic 3 50 0-0-3 50 0 50 1.6-2 Not toxic 53 50 11-7-14 50 Standard monitoring method DIN EN ISO 15088 WAC/V/B/004 OECD201;OECD202;ISO 11348-3:1996E OECD203 NF EN ISO 6341 NF EN ISO 6341 UNI EN ISO 11348-3:2009 UNI EN ISO 8692:2005 rev.2012 UNI EN ISO 11348-1:2009 APAT CNR IRSA 8020B Man 29 2003 OECD203 APAT CNR IRSA 8020B Man 29 2003 APAT CNR IRSA 8020B Man 29 2003 APAT CNR IRSA 8020B Man 29 2003 UNI EN ISO 8692:2012 UNI EN ISO 11348-3:2009 Grab/spot sample % 26 50 UNI EN ISO 8692:2012 Flow proportional composite sample 24-hour flow proportional composite sample % DOC % 24-hour flow proportional composite mg/l Pt sample 24-hour flow proportional composite sample 24-hour flow proportional composite sample;24-hour flow proportional composite sample; 24-hour flow proportional composite sample Grab/spot sample [m-1] (SAC:436nm; 525; 620nm) [m-1] (SAC:436nm; 525; 620nm) [m-1] (SAC:436nm; 525; 620nm) Pt-Co scale 52 61-57 40% after 28 days Report 36 measurement in the range of 2-8.4, except 2 measurements of 24 and 32 not visible 1:20 // 28/24/20;28/24/20;28/24/2 EN ISO 7887;EN ISO 7887;EN ISO 7887 0 // 28/24/20;; DIN EN ISO 7887;; // 16-56-187 28/24/20;28/24/20;28/24/2 0 - EN ISO 7887 (MH);EN ISO 7887 (MH);EN ISO 7887 (MH) MEIN001 Additional information (Giftigkeit gegenber Fischeiern )Toxicity to fish-spawn One time measurement (2012) P. Subcapitata;One time measurement (2012) Daphnia Magna;One time measurement 2012 (Virbrio Fischeri) 2 measurements < 10%, expressed in %effect One week every two years, See appendix 2;;One week every two years, See appendix 1 micro tox, period of one week. See appendix 3.;;Ec50 (15 min exp) measurements carried out for water agencies to calculate a fee Average sample of 3 hours Value refered to sampling period - test on Vibrio fischeri value refered to sampling period - Test on Pseudokirchrneriella Subcapitata Monitoring frequency: spotValue refered to sampling period - Test on Vibrio Fischeri Value refered to sampling period 4 measurement (Oncorhynchus Mykiss) to determine if further actions were needed EN ISO 9509:2006, period of one week. See appendix 3.;;40 vol% sample (% inhibition) Value refered to sampling period - test n Daphnea Magna value refered to sampling period - Test on Daphnea Magna Monitoring frequency: spotValue refered to sampling period - Test on Daphnia EN 8192-1995B, period of one week. See appendix 3. ;;40 vol% sample speed 30 and 180 minutes) Value refered to sampling period - test on Pseudokirchrneriella Subcapitata value refered to sampling period - Test on vibrio fischeri Monitoring frequency: spotValue refered to sampling period - Test on Pseudokirchneriella subcapitata One week sample, see appendix 3 OECD 301A, period of one week . See appendix 3.;;52% after 10 days, 57 %after 28 days 3,4/2/1,2; self-monitoring daily;3,6/1,7/1,3; selfmonitoring daily;2,4/0,8/0,5; self-monitoring daily M1: 43/43/28; M2: 27/27/19; M3: 49/44/28; M4: 24/25/13; M6: 23/20/22; M7: 33/30/18; M8: 26/23/17; M9: 28/23/25; M10: 33/34/38; M11: 33/28/29; M12: 48/47/43;M1: 24/22/19; ; M1: 8,2/5/3,2; M2: 8,1/6,2/4,4;M1: 2,1/1,6/0,81; M2: 10/5,5/3,8;M1: 8,8/6,1/4,6; M2: 4,5/2,8/3,5 sample 23.10.2015 83 1 EP water name Parameter UK124 w{1} Colour IT065 w{1} Colour IT076 w{1} ES058 w{1} AT001 w{1} Colour Colour Colour IT097 w{1} Colour IT085 w{1} Colour IT087 w{1} IT092 w{1} IT096 w{1} AT005 w{1} Colour Colour Colour Colour Monitoring frequency Monthly Twice per year Other (please specify in "additional information") 4 times per year No information Other (please specify in "additional information") Other (please specify in "additional information") Other (please specify in "additional information") Monthly Yearly Twice per year WASTE WATER CHARACTERISTICS: TOXICITY, BIODEGRADABILITY/ELIMINABILITY AND COLOUR Type of sampling Unit No information Flow proportional composite sample [m-1] (SAC:436nm; 525; 620nm) Grab/spot sample No information Grab/spot sample 24-hour flow proportional composite sample No information [m-1] (SAC:436nm; 525; 620nm) Other or more than one type No information Grab/spot sample No information Grab/spot sample No information Grab/spot sample No information Grab/spot sample No information 24-hour flow proportional composite [m-1] (SAC:436nm; 525; sample 620nm) Individual measurements (unless mentioned ELV otherwise) Measurements reported as frequent sampling. Min=0.01- 0.1nm Ave=0.02-Max=0.04 Standard monitoring method Additional information Absorbance Scan - determined by scanning UV/ visible spectrometry Measured in absorbance units nm 0.01-0.01 20 N.P. 1:20 Report 3 measurements, all equal to 0 // Report 8 measurements, all N.P. 1:20 equal to 20 100-100-80-40-100-100 ISO 7887:2001 APAT CNR IRSA 2020 Man 29 2003 not detected ; LOD 1 m-1 ISO 7887-2001 introduced during 2018 to follow the ZDHC Waste Water Guide lines Monitoring frequency: spotMeasurement is N.P. 1:20: not percepible with diluition 1:20Value refered to sampling period APAT CNR IRSA 2020 Man 29 2003;IRSA 2020/A;IRSA 2020/A APAT CNR IRSA 2020 ;;M3: 148/129/105; control measurement local authority Monitoring frequency: spotMeasurements (N.P. 1:20) non percepition with diluition 1:20Value refered to sampling period;Monitoring frequency: once every 4 monthsMeasurements (N.P. 1:20) non percepition with diluition 1:20Value refered to sampling period;Monitoring frequency: once every 4 monthsMeasurements (N.P. 1:20) non percepition with diluition 1:20Value refered to sampling period Measurements are N.P. 1:100: not percepible with diluition 1:100Monitoring frequency: spot;Measurement is N.P. 1:80: not percepible with diluition 1:80Monitoring frequency: spot;Measurements are N.P. 1:40 and N.P. 1:100: not percepible with diluition 1:40 and 1:100Monitoring frequency: spot 50-20-20-39-9-40 Report 34 measurements, twenty-three times 10, eleven times 20 Report 3 measurements, all equal to 20 // 80 20 N.P. 1:20 20/ 28 / 24 1/m;20/ 28 / 24 1/m;20/ 28 / 24 1/m IRSA 2020-A:2003;APAT CNR IRSA 2020A ;APAT CNR IRSA 2020A APAT CNR IRSA 2020 Man 29 2003 DIN EN ISO 7887;DIN EN ISO 7887;DIN EN ISO 7887 Monitoring frequency: spot not perceptible in dilution 1:10 - 1:20Value refered to sampling period Measurement is N.P. 1:20: not percepible with diluition 1:20Value refered to sampling period M1: 32/30/35; M2: 32/29/33;M1: 46/15/8; M2: 39/52/61;M1: 35/32/36; M2: 33/21/16 84 2