Document wg2mG3pjwynYkqeOMNX2MD4no
STLS E V E R N TREN 1
STL Chicago 2417 Bond Street University Park, IL 60466
Teh 7 0 8 5 3 4 5 2 0 0 Fax; 708 534 5211 IWVW.St/-/nC.CO/77
SEVER TRENT LABORATORIES ANALYTICAL REPORT
JOB NUMBER: 232677
P r e p a r e d F o r : .
Weston- S o l u z i o n 5 , Inc.
l400 Weston
Buil
-2
wesc. C h e s t e r PA 19380-1499
Pro jecu C o n f i d e n t ial D e c a cur - EC Investiga t i o n
A t L e n t ieri : J a i Re s a r i
.... C a te: 1 2 / 2 7 / 2 0 0 4
Tille: Project Manager E - M a i l : r w r ig h t @ s 1 1 - in o .c o m
This Report Contains
Leaders in Environmental Testing
____________ /
Dato.
/ /-
STL Chicago 2417 Rond Street University Park, IL 60466
PHONE: (708) 534 5200 P A X . .: (708) 5 3 4 - 5 2 1 1
) Pages
Severn Trent Laboratories, ins.
WET CHEMISTRY DATA PACKAGE CONFIDENTIAL DECATUR - FC INVESTIGATION
JOB# 232677
Data Summary............................................................... 1 Chain of Custody......................................................... 21 Case Narrative............................................................. 27 Raw Data.................................................... ................ 29
STL Chicago is part of Severn Trent Laboratories, Inc.
S A M P L E I N F O R M A T I 0 N . .Date!. 12/27/2004
Job Number. 232677 Customer... Weston Solutions, Inc. Attn...... Jai (Cesari
Project Number......... : 20004891 Customer Project ID.... : CONFIDENTIAL DECATUR Project Description___ : Confidential Decatur - FC Investigation
. Laboratory . . ... .Sample ID
... .
Customer :....... Sample ID
232677-1
DF06-SB-132R-0-D0D0
232677-2
DF06-SB-132R-0-0005
232677-3
DF06-SB"132R-0-0010
232677-4
DF06-SB-132R-0-0020
232677-5
DF06-SB-132R-0-0050
232677-6
DF06-SB-132R-0-0445
232677-7
DF06-SB-133R-0-0000
232677-8
DF06-SB-133R-0-0005
232677-9
DF06-SB-133R-0-0010
232677-10
DF06-SB-133R-0-0020
232677-11
DF06-SB-133B-0-0000
232677-12
DF06-SB-133B-0-0005
232677-13
DF06-SB-133B-0-0010
232677-14
DF06-SB-133B-0-0020
Sample Matrix Soil soi l soil Soi L Soi l Soil soi l Soi 1 Soil SOI l Soi l Sol 1 soi 1 Soi 1
....Date - .... Time
Date .
.. .Sampled
Sampled " ; Received
12/07/2004
07:40
12/10/2004
12/07/2004
07:45
12/10/2004
12/07/2004
07:55
12/10/2004
12/07/2004
08:10
12/10/2004
12/07/2004
08:19
12/1/24
12/07/2004
11:35
12/10/2004
12/07/2004
12:50
12/10/2004
12/07/2004
13:10
12/10/2004
12/07/2004
13:20
12/10/2004
12/07/2004
13:30
12/10/2004
12/07/2004
14:10
12/10/2004
12/07/2004
14:15
12/10/2004
12/07/2004
14:25
12/10/2004
12/07/2004
14:40
12/10/2004
Time Received
10:00 10:00 10:00 10:00 10:00 10:00 10:00 10:00 10:00 10:00 10:00 10:00 10:00 10:00
Page 1
STL Chicago is part of Severn Trent Laboratories, Inc.
Job Humber: 232677
CUSTOMER: Weston Solutions, Inc.
Customer Sample ID Date Sampled..... Time Sampled..... Sample Matrix....
DF06-SB-132R-D-0000 12/07/2004 07:40 Soi l
TEST METHOD L lo y d Kahn
.PARAMETER/TEST ;DESCRIPTION
Total Organic Carbon fSoiIs} TOC Average Duplicates, Solid
e*
LABORATORY
TEST
RESULTS
PROJECT : :CONFIDE WTI AL: DE CAT UR
Laboratory Sample ID: 232677-1 Date Received....... : 12/10/2004 Time Received....... : 10:00
Date:12/27/2004 ATTN : -Jai Recar i
SAMPLE RESULT QfFLAGS6000
:HDL: 190
RL DILUTION UNITS BATCH 'DT DATE/TIM TECH
730
mg/Kg
13725S
112/15/04 1405 c l s
* In Description = Dry Wgt.
Page 2
STL Oli caga l's pari o"f Severn Treni Laboratories, Ine.
Job Number: 232677
CUSTOMER: Weston Solutions, Inc.
Customer SampLe JD: DFQ-SB- 132R-1>-0005 Date Sampled...... :12/07/2004 Time Sampled...... :07:45 Sample Matrix..... :Soil
TEST METHOD Lloyd Kahn
.PARAMETER/TEST DESCRIPTION
Total Organic Carbon (Soils) TOC Average Dlicates, Soil'd
LABORATORY
TEST
RESULTS
. . PROJECT:LC0*JF I0EMTIAL DECATUR
Laboratory Sample ID 232677-2 Date Received...... 12/10/2004 Time Received...... 10:00
Date:12/27/2004 ATTN : Ja.i!Kesari ;:
SAMPLE RESULT Q FLAGS : 3300
H0L 210
RL: 300
DILUTION UNITE BATCH :0T DATE/TIME TECf
mg/Kg
137253
112/15/04 1422!cls
* Sn Description = Dry Wgt.
Page 3
STL Chicago is part of Severn Trent Laboratories, inc.
STL Chicago is part of Severn Trent Laboratories, ]nc.
O
]n Description = Dry Wgt.
Page 5
STL Chicago is part of Severn Trent Laboratories, Ine.
Job Number: 232677
CUSTOMER: Weston Salut ions, Inc. o
Customer Sample ID: DF06-SE-132R-0-0050 Date Sampled...... :12/07/2004 Time Sampled...... :08:19 Sample Matrix..... :Soil
TEST METHOD Lloyd Kahn
PARAMETER/TEST DESCRIPTION
Total Organic Carbon (Soils) TOC Average Duplicates, Solid
LABORATORY
TEST
RESULTS
PROJECT: CONFIDENTIAL DECATUR
Laboratory Sample ID: 232677-5 Date Received....... : 12/10/2004 Tinse Received....... : 10:00
Date:12/27/2004 . ATTW: Jai Rosari : :
. SAMPLE RESULT Q FLAGS 4700
HDl
:=:= : RL
:0ELOTJON UNITS /BATCH/ or; DATE/TIME TEC11
130
490 1
mg/Kg 137258
12/15/04 1532 els
* In Description = Dry Ugt.
Page 6
STL Chicago is part of Severn Trent Laboratories, Inc-
* In Description = Dry Wat.
Page 7
STL Chicago is part of Severn Trent Laboratories, ine.
* [n Description = Dry Ugt.
Page 8
STL Chicago is part of Severn Trent Laboratories, ]nc.
Job Number: 232677
. CUSTOMER: Weston Solutions, Inc.
Customer Sample ID: DF06-SE3-133R-0-0005 Date Sampled...... :12/07/2004 Time Sampled...... :13:10 Sample Matrix..... :Soi l
TEST METHOD ;
:: PARAMETER/TEST DESCRIPTION
Lloyd Kahn
Total Organic Carbon <SoiLa) TOC Average Duplicates, Solid
<n
LABORATORY
TEST
RESULTS
PROJECT: CONFIDENTIAL DECATUR
Laboratory Sample ID: 232677-3 Date Received........ :12/10/2004 Time Received........ :10:00
Date:12/27/2004 ATTN: Jai Kesari
SAMPLE RESULT 3: FLAGS 28DD
HDL 150
Rl 590
0 1L'JT]ON UNITS BATCH :ET DATE/T1ME TECH
1
mg/Kg 137233
12/16/04 1042 els
* In Descri Pt ion = Dry Ugt.
Rage 9
STL Chicago is part of Severn Trent Laboratories, nc.
Job Number: 232677
.CUSTOMER: Wes ton Solutione , Inc.
Customer Sample ED: D F06-SB-133 R-0-0010 Date Sampled..... : 12/07/2004 Time Sampled..... : 13:20 Sample Matrix.... : Soi L
TEST METHOD Lloyd Kahn
:PARAMETER/TEST DESCRJ-PTION :
Total Organic Carbon [Soils) TOC Average Duplicates, Solid
O
LABORATORY
TEST
RESULTS
PROJECT: CONFIDENTIAL DECATUR
Laboratory Sample ID: 232677-9 Date Received...... : T2/1Q/24 I ime Recei ved...... : 10:00
Date:12/27/2004 ATTN: Jai Kesari
SAMPLE RESULT 1700
FLAGS
IWL 140
RL-: 560
DILUTION
UHITS BATCH BT DATE/TIME TECH:
mg/Kg 13728S : 12/16/04 10 5 6 1cLs
En Desert pti on = Dry Ugt.
Page 10
STL Chicago is part of Severn Trent Laboratories, [nc.
H
* [n Description = Dry Ugt.
Page 11
STL Chicago is part of Severn Trent Laboratories, [nc.
Job Nunber: 232677
CUSTOMER': Weston Solutions, Inc.
Customer Sample ID: DF06-SE-133B-0-000 Date Sampled..... 12/07/2004 Time Sampled..... 14:10 Sample Matrix.... Sei l
TESI KETHCO
:PA RAHE TE R/TE ST DESCR IPM O N
Lloyd Kahn
Total Organic Carbon (Soils) !TOC Average Duplicates, Solid
j
LABORATORY
TEST
RESULTS
PROJECT: CONFIDENT[AL DECATUR
Laboratory Sample ID 232677-11 Date Received...... 12/10/2004 Time Received...... 10:00
Date:12/27/2004 . AT'TH: Jai Kesari .
SAMPLE RESULT 5300
FLAGS
H0L 100
RL
DILUTION
UNITS . BATCH DT DATE/TIME TECh
390
mg/Kg 1372S3
12/16/04 1134 c Is
* In Description = Dry Wgt.
Page 12
STL Chicago is part of Severn Trent Laboratories, Inc.
Job Nimber: 232677
CUSTOMER: Weston Solutions,:Inc.
Customer Sample ID Date Sampled........... Time Sampled..... Sample Matrix....
D F06-SB-133B-0-0005 12/07/2004 14:15 Soi l
TEST METHOD:
PARAMETER/TEST DESCRIPTION
Lloyd Kahn
Total Organic Carbon (Soils) TOC Average Duplicates, Solid
LABORATORY
TEST
RESULTS
PROJ EOT : !CON FIDENT [AL OE CATUR
Laboratory Sample ID 232677-12 Date Received....... 12/10/2004 Time Received....... 10:00
Date :12/27/2004 ATTN; Ja i Kesari
SAMPLE RESULT !0 FLAGS 3400
MOL 140
RL '0 ELUT10N UNITS BATCH DT DATE/T ]ME TECH
550
mg/Kg 1372BB
i2/16/04 1157 els
In Description = Dry Wgt.
Page 13
STL Chicago is part of Severn Trent Laboratories, Inc.
Joh Niflifoer: 32677
CUSTOMER: Weston Solutions, Inc.
Customer Sarrple ED Date Sampled..... Time Sampled..... Sample Matrix....
D f06-SB-133 B-0-0010 12/07/2004 14:25 Soi l
TEST METHOD Lloyd Kahn
PARAMETER/TEST;DESCRIPT ION
Total Organic Carbon ISoils) TOC Average Duplicates, Solid
H
LABORATORY
TEST
RESULTS
PROTECT : CONFIDENTIAL DECATUR
Laboratory Sample ID 232677-13 Date Received...... 12/1D/2004 Time Received...... 10 :D0
Date :12/27/2C-04 ATTN: Jai Rosari
SAMPLE: RESULT 2400
ELAGS:
MOL 13D
RL DILUTION ; ;:OMITS j:BATCH DT DATE/T3ME TECH
520
mg/Kg 13728S
12/16/04 1218 els
* In Description = Dry Wgt.
Page 14
STL Chicago is pari of Severn Treni Laboratories, Ine,
Job Number: 232677
:CUSTOMER::Weston SolutIons r Inc.
Customer Sample ID: D F06-SB-133B-0-0020 Date Sampled..... : 12/07/2004 Time Sampled..... : 14:40 Sample Matrix.... : Soi L
TEST METHOD Lloyd Kahn
PARAMETER/TEST DESCRIPTION
Total Organic Carbon [Soils! TOC Average Duplicates, Solid
\ft
vi
LABORATORY
TEST
RESULTS
PROJECT: CONFIDENTEALDECATUR :-=
Laboratory Sample ID: 232677-14 Date Received...... : 12/10/2004 Time Received...... : 10:00
Date:12/27/2004 ATTN: . Jai Kesari
s a m p l e RESULT Q FLAGS 1500
MDL no
RL DILUTION UNITS BATCH -DT' DATE/TIME TECH
430 1
mg/Kg
1372SS !! 12/16/04 1329 c ls
* In Description = Dry Ugt.
Page 15
' _________________________
STL Chicago is part of Severn Trent Laboratories, Inc.
Job Number: 232677
LABORATORY
CHRONICLE
Date: 12/27/2004
CUSTOMER : Weston Solution?, Inc. !.. '
"PROJECT; CONFIDENTIAL DECATUR
ATTN: Jai K'esari
Lab ID: 232677-1 METHOD
EDD Lloyd Kahn
Client ID: DF06-SE-132R-O-G0Q DESCRIPTION Electronic Data Deliverable Total Organic Carbon (Soils)
Lab ID: 232677-2 Client ID: DF6-SE-132R-0-0005
METHOD
DESCRIPTION
Lloyd Kahn
Total Organic Carbon (Soils)
Lab ID: 232677-3 METHOD
Lloyd Kahn
Client ID: DF06-SB-132R-0-0010 DESCRIPTION Total Organic Carbon (Soils)
Lab ID: 232677-4 METHOD
Lloyd Kahn
Client ID: DF06-SB-132R--02
DESCRIPTION Total Organic Carbon (Soi La)
Lab ID: 232677-5 METHOD
Lloyd Kahn
Client ID: DF06-SB-132R-0-005D
DESCRIPTION Total Organic Carbon (Soils)
Lab ID: 232677-6 Client ID: DF6-SB-132R-0-0445
METHOD
DESCRIPTION
Lloyd Kahn
Total Organic Carbon (Soils)
Lab ID: 232677-7 Client ID: DF06-SB-133R-O-OOOO
METHOD
DESCRIPTION
Lloyd Kahh
Total Organic Carbon (Soils)
Lab ID: 232677-8 Client ID: DF6-SB-133R-0-0005
METHOD
DESCRIPTION
Lloyd Kahn
Total Organic Carbon (Soils)
Lab ID: 232677-9 Client ID: DFO6-SB-133R-O-O01O
METHOD
DESCRIPTION
Lloyd Kahn
Total Organic Carbon (Soils)
Lab ID: 232677-10 client ID: DF06-SB-133R-0-0020
METHOD
DESCRIPTION
Lloyd Kahn
Total Organic Carbon (Soils)
Lab ID: 232677-11 Client ID: DF06-SB-133B-0-0000
METHOD
DESCRIPTION
Lloyd Kahn
Total Organic Carbon (Soils)
Lab ID: 232677-12 Client ID: DF06-SB-133B-0-0005
METHOD
DESCRIPTION
Lloyd Kahn
Total Organic Carbon (Soils)
Lab ID: 232677-13 Client ID: DF06-5B-133B-0-0010
METHOD
DESCRIPTION
Lloyd Kahn
Total Organic Carbon (Soils)
Lab ID: 232677-14 Client ID: DF06-SB-133B-0-0020
METHOD
DESCRIPTION
Lloyd Kahn
Total Organic Carbon (Soils)
Date Recvd: 12/10/2004 Sample Date: 12/07/2004
RUN# BATCH# PREP BT #($)
DATE/TIME ANALYZED
1
1 137258 137258
12/15/2004 1405
DILUTION
Date Recvd: 12/10/2004 Sample Date: 12/07/2004
RUN# BATCH# PREP BT #S)
DATE/TIME ANALYZED
1 137258 137258
12/15/2004 1422
DILUTION
Date Recvd: 12/10/2004 Sample Date: 12/07/2004
RUN# BATCH# PREP BT #(S>
DATE/TIME ANALYZED
1 137258 137258
12/15/2004 1443
DILUTION
Date Recvd: 12/10/2004 Sample Date: 12/07/2004
RUN# BATCH# PREP BT #<S)
DATE/TIME ANALYZED
1 137258 137258
12/15/2004 1513
DILUTION
Date Recvd: 12/10/2004 Sample Date: 12/07/2004
RUN# BATCH# PREP BT #(S)
DATE/TIME ANALYZED
1 137258 137258
12/15/2004 1532
DILUTION
Date Recvd: 12/10/2004 Sample Date: 12/07/2004
RUN# BATCH# PREP BT #(S)
DATE/TIME ANALYZED
1 137258 137258
12/15/2004 1557
DILUTION
Date Recvd: 12/10/2004 Sample Date: 12/07/2004
RUN# BATCH# PREP BT #(S)
DATE/TIME ANALYZED
1 137288 137288
12/16/2004 1007
DILUTION
Date Recvd: 12/10/2004 Sample Date: 12/07/2004
RUN# BATCH# PREP BT #(S)
DATE/TIME ANALYZED
1 137288 137288
12/16/2004 1042
DILUTION
Date Recvd: 12/10/2004 Sample Date: 12/07/2004
RUN# BATCH# PREP BT #(S>
DATE/TIME ANALYZED
1 137288 137288
12/16/2004 1056
DILUTION
Date Recvd: 12/10/2004 Sample Date: 12/07/2004
RUN# BATCH# PREP BT #(S)
DATE/TIME ANALYZED
1 137288 137288
12/16/2004 1119
DILUTION
Date Recvd: 12/10/2004 Sample Date: 12/07/2004
RUN# BATCH# PREP BT #(S)
DATE/TIME ANALYZED
1 137288 137288
12/16/2004 1134
DILUTION
Date Retvd: 12/10/2004 Sample Date: 12/07/2004
RUN# BATCH# PREP BT #(S)
DATE/TIME ANALYZED
1 137288 137288
12/16/2004 1157
DILUTION
Date Recvd: 12/10/2004 Sample Date: 12/07/2004
RUN# BATCH# PREP BT #(S)
DATE/TIME ANALYZED
1 137288 137288
12/16/2004 1218
DILUTION
Date Recvd: 12/10/2004 Sample Date: 12/07/2004
RUN# BATCH# PREP BT #{S)
DATE/TIME ANALYZED
1 137288 137288
12/16/2004 1329
DILUTION
Page 16
iS
Jab Number.: 232677 Cu s t o m e r : Ueston Solutions, lnc.
QUAL 17 Y CONTROL RESUL T S PROJECT : CON FIDENT 1AL DECATUR
Report Date.: 12/27/2004 ATTN:'Jai Kesari
Test Method.... .:. Method Description-.
Parameter___ ......
Lloyd Kahn . .
Total 'Organic- Carbon (Sci Is)
'
Organic.Carbon, Tot. TTocr^ii:^./':
QC Lab ID
Reagent
Units
ICV 137258-002 I4LSTTC2
MB 137258-003 LCS 137258-004 I0FSTLK3 LCD 137258-005 I00FSTLK3
mg/Kg me/Kg
mg/Kg mg/Kg
QC Result
QC Result
2155.26
32.00 U
4127.36
4745.15
4127.36
CCV 137258-015 I04LSTTC2 CCB 137258-016
CCV 137258-015 I4LSTTC2 CCB 137258-016
mg/Kg mg/Kg
mg/Kg mg/Kg
2208.49 32.00
1927.07 32, DO
U U
Batch ..;
.....: 137258 .
Equipment Code... .: TC4
Analyst.,.: els Test Code.; T O C .
True Value 2000.00
4780.00 4780.00
2000.00
2000.00
Orig, Value
QC C a U . F * 108 1
196.92 187.55
U 86 U 99
14 110
% %
%
96 %
Limits 85-115
53-140 53-140
85-115
85-115
Date Time
12/15/2004 0908 12/15/2004 0915 12/15/2004 1016 12/15/2004 1024
12/15/2004 1501 12/15/2004 1508 12/15/2004 1621 12/15/2004 1623
Test Method.. ..... ; Lloyd Kahn Method Descri pt 1 O H .: Total Organic- Carbon (Soils) .Parameter... ..... : Organic Carbon, Tot. (TOC) ::
:B a t c h . .... ,...: 137288 "Equipment Code .... : TOC4
Analyst. * : els Test Code : TOC
QC Lab ID
Reagent
Units
ICV 137288-002 I04LSTTC2 MB 137288-003 LCS 137288-004 I00FSTLK3 LCD 137288-005 I00FSTLK3
mg/Kg mg/Kg mg/Kg mg/Kg
CCV 137288-016 I04LSTTC2
CCB 137288-017 CCV 137288-016 IQ4LSTTC2 CCB 137288-017
mg/Kg mg/Kg
mg/Kg mg/Kg
QC Result
QC Result
1990.99
32.00 U
4550.88
4890.69
4550.88
2054.40 32.00
2000.34 32.00
U U
True Value 2000.00
4780.00 4780.00
2000.00
2000.00
Orig. Value QC Calc. F * Limits
Date Time
100
200.00 171.24
U 95 U 102
7 103
100
% 85-115
% 53-140 % 53-140 R 30 % 85-115
% 85-115
12/16/2004 0813 12/16/2004 0820 12/16/2004 0839 12/16/2004 0849
12/16/2004 1246 12/16/2004 1254 12/16/2004 1624 12/16/2004 1629
Ragt 17
%=% REC, R=RPD, A=AES Diff., D=% Dlff_
17
0 U A L I O'""" A 5 S U R A N C E M E T H O D S. E R E N C E S A N D .;N. T .EjjSj ; '/-, .Report Date: 12/27/2004
REPORT COMMENTS 1) M l pages of this report are integral parts of the analytical data. Therefore, this report should
be reproduced only in its entirety. 2) Soil, sedimeht and sludge sample results are reported on a "dry weight" basis except when analyzed for
landfill disposal or incineration parameters. All other solid matrix samples are reported on an "as received" basis unless noted differently. 3) Reporting Limits are adjusted for sample size used, dilutions and moisture content if applicable. 4) The test results for the noted analytical method(S) meet the requirements of NELAC. Lab Cert. ID# 100201 5) According to 40CFR Part 136.3, pH, Chlorine Residual and Dissolved Oxygen analyses are to be performed immediately after aqueous sample collection. When these parameters are not indicated as field (e.g. pH Field) they were not analyzed immediately, but as soon as possible on laboratory receipt.
Glossary of flags, qualifiers and abbreviations (any number of which may appear in the report) Inorganic Qualifiers (Q-Column) U Analyte was not detected at. or above the statedlimit, < Not detected at or above the reporting limit. J Result is less than the RL, but greater than or equal to the method detection limit. B Result is less than the CRDL/RL, but greater than or equal tothe IDL/MDL. S Result was determined by the Method of standard Additions. F AFCEE: Result is less than the RL, but greater than or equal to the methoddetection limit. Inorganic Flags (Flag Column)
ICV,CCV,ICB,CCB,ISA,ISB,CRI,CRA,MRLi Instrument related QC exceed the upper or Lower control Limits. * LCS, LCD, MD: Batch QC exceeds the upper or lower control Limits. + MSA correlation coefficient is less than D.995. 4 MS, M5D: The analyte present in the original sample is 4 times greater than the matrix spike concentration; therefore, control limits are not applicable, E SD: Serial dilution exceeds the control Limits. H MB, EB1, EB2, EB3: Batch QC is greater thah reporting Limit or had a negative instrument reading lower than the absolute value of the reporting limit. N MS, MSD: Spike recovery exceeds the upper or lower control Limits. W AS(GFAA) Post-digestion spike was outside 85-115% control Limits. Organic Qualifiers (Q * column) U Analyte was not detected at or above the stated limit. ND Compound not detected, J Result is an estimated value below the reporting limit or a tentatively identified compound (TIC). Q Result was qualitatively confirmed, but not quantified. C Pesticide identification was confirmed by GC/MS. V The chromatographic response resembles a typical fuel pattern. Z The chromatographic response does not resemble a typical fuel pattern, E Result exceeded calibration range, secondary dilution required. F AFCEEResult is an estimated value below the reporting limit ora tentativelyidentified compound (TIC) Organic Flags (Flags Column) MB: Batch QC is greater than reporting limit. * LCS, LCD, ELC, ELD, CV, MS, MSD, Surrogate: Batch QC exceeds the upper or Lowercontrol limits. EB1, EB2, EB3, MLE: Batch QC is greater than reporting Limit A Concentration exceeds the instrument calibration range a Concentration is below the method Reporting Limit (RL) B Compound was found in the blank and sample. D Surrogate or matrix spike recoveries were not obtained because the extract was diluted for analysis; also compounds analyzed at a dilution will be flagged with a D. H Alternate peak selection upon analytical review 1 Indicates the presence of an interfence, recovery is not calculated. M Manually integrated compound. P The lower of the two values is reported when the % difference between the results of two GC columns is
Page IS
18
Q U A L I T Y ASS U R
METHODS
F E R. E N C E .S
OTES
Report ;;pat e: 12/27/ 2004
greater than 25%.
Abbreviations
AS Post Digestion Spiko (GFAA Samples - See Note 1 below)
Batch Designation given to identify a specific extraction, digestion, preparation set. or analysis set
CAP Capillary Column CCB Continuing Calibration Blank
ccv Continuing Calibration Verification
CF Confirmation analysis of original
Cl Confirmation analysis of A1 or 01
C2 Confirmation analysis of AZ or D2
C3 Confirmation analysis of A3 or D3
CRA Low Level Standard Check - GFAA; Mercury
CRI Low Level Standard Check - ICP
cv Calibration Verification Standard
Dii Fac Dilution Factor - Secondary dilution analysis
D1 Dilution 1
02 Dilution 2
03 Dilution 3
DLFac Detection Limit Factor
DSH Distilled Standard - High Level
OSL Distilled Standard - Low Level
OSM DistiLled Standard - Medium Level
EBl Extraction Blank 1
EB2 Extraction Blank 2
EB3 DI Blank
ELC Method Extracted LCS
ELD Method Extracted LCD
ICAL
Initial calibration
ICB Initial Calibration Blank
icv Initial Calibration Verification
I0L Instrument Detection Limit
ISA interference Check Sample A ICAF3
ISB Interference Check Sample B - ICAP
Job No. The first six digits of the sample ID which refers to a specific client, project and sample group
Lab ID An 8 number unique Laboratory identification
LCD Laboratory Control Standard Duplicate
LCS Laboratory Control Standard with reagent grade water or a matrix free from the analyte of interest
MB Method Blank or (PB) Preparation Blank
MD Method Duplicate
MDL Method Detection Limit
MLE Medium Level Extraction Blank
MRL Method Reporting Limit Standard
MSA Method of Standard Additions
MS Matrix Spike
MSO Matrix Spike Duplicate
ND Not Detected
PRPF Preparation factor used by the Laboratory's Information Management System CLIMS)
PDS Post Digestion Spike (ICAP)
RA Re-analysis of original
Al Re-analysis of DI
A2 Re-analysis of D2
A3 Re-anaLysis of D3
RD Re^extraction of dilution
RE Re-extract ion of original
RC Re-extract ion Confirmation
RL Reporting Limit
RPD Relative Percent Difference of duplicate (unrounded) analyses
RRF Relative Response Factor
RT Retention Time
Page 19
.. ..... Q U A L I T Y A S S U R A N C E M E T H 0 d s
R E F E R E N C E S A N D N O T E' S Report Date: 12/27/2004
RTW Retention Time Window Sample ID A 9 digit number unique for each sample, the first
six digits are referred as the job number
5CB Seeded Control Blahk
SD Serial Dilution (Calculated when sample concentration exceeds 50 times the MDL)
UCB Unseeded Control Blank
SSV Second Source Verification Standard
SLCS
Solid Laboratory Control Standard(LCS)
PHC pH Calibration Check LC5P pH Laboratory Control Sample
LCDP
pH Laboratory Control Sample Duplicate
MDPH
pH Sample Duplicate
MDFP
Flashpoint Sample Duplicate
LCFP
Flashpoint LC5
G1 Gelex Check Standard Range 0-1
G2 Gelex Check Standard Range 1'10
G3 Gelex Check Standard Range 10-100
G4 Gelex Check Standard Range 100-1000
Note 1: The Post Spike Designation on Batch QC for GFAA is designated with an MSM added to the current
abbreviation used. EX. LCS S-LCS Post Spike (GFAA); MSS=M5 Post Spike (GFAA)
Note 2: The MD calculates an absolute difference (A) when the sample concentration is less than 5 times the
reporting limit. The control limit is represented as +/- the RL.
Pago 20
CHAIN OF CUSTODY
9 .3 2 ^ 1
CHAIN OF CUSTODY / ANALYSIS REQUEST FORM
Severn Trent Laboratories
T: 706-534-5200
F: 708-534-5211
2417 Bond Street
University Park, IL 60466
PAGE ( of ^2
PROJECT INFORMATION Client: Weston Solutions, Inc.
1400 Weston Way, Bldg. 5-2 West Chester, PA 19380 T: 610-701-3761 F: 610-701-7401
Project Manager: Jai Kesari em ail: i.kes3ri@westonsolutions.com
Project Name: Reference No:
Decatur, Alabama 02181-129-081-0001
ANALYSES REQUESTED
r?
"
I
Sampler:
T Frinakr A Murphy
P.O. #: Quotation #:
Grab Sample Composite No. of Containers
SAMPLE ANALYSIS
ExyLIMS # Client Sample Identification
t DF06 SB 132R 0 0000 3L DF06 SB 132R 0 0005
3 DF06 SB 132R 0 0010 + DF06 SB 132R 0 0020
DF06 SB 132R 0 0050
<9 DF06 SB 132R 0 0445 1 DF06 SB 133R 0, 0000 K DF06 SB 133R 0 0005
DF06 SB 133R 0 0010
___________: DFQ6 SB 133R 0 0020
Collection Date
7-Dec-04 7-Dec-04 7-Dec-04 7-Dec-04 7-Dec-04 7-Dec-04 7-Dee-04 7-Dec-04 7-Dec-04 7-Dec-04
Collection
Time
7:40 X
7:45 X
7:55 X
8:10 X
8:19 X
11:35
X
12:50
X
13:10
X
13:20
X
13:30 __ ! X
1 1 1 1 1 1 1 1 1 1
Sampie Matrix SOIL SOIL SOIL SOIL SOIL SOIL SOIL SOIL SOIL SOIL
CHAIN OF CUSTODY
Cooler ID No.: |
Rei inq uish e jC y ^ C ' , Date Time 1___ 1
--> k
-- "V --
/
y
Y fW
i
Received By: Fed Ex
' * '
Cooler Temp. (C): j
Date Time
1{
\0O O
Comments 0-3 INCHES 0.5-1.0 FEET 1.0-1.5 FEET 2.0-2.5 FEET 5.0-5.5 FEET
44.5-46.0 0-3 INCHES 0.5-1.0 FEET 1.0-1.5 FEET 2.0-2.5 FEET
U O 1X X X X X X X X X X
PROJECT REQUIREMENTS
\ Results Deadline:
Laboratory Report Options:
Sample Results Only Add Case Narrative Add Quality Control Summary Add Calibration Summary
Add Raw Data Other:
CHAIN OF CUSTODY / ANALYSIS REQUEST FORM
Severn Trent Laboratories
T: 706-534-5200
F: 708-534-5211
2417 Bond Street
University Park, IL 60466
PAGE 2 . of^Z
PROJECT INFORMATION Client: Weston Solutions, Inc.
1400 Weston Way, Bldg. 5-2 West Chester, PA 19380 T: 610-701-3761 F: 610-701-7401
Project Manager: Jai Kesari email: i.ke sa ri westo nso Iution s.com
Project Name: Reference No:
Decatur, Alabama 02181-129-081-0001
ANALYSES REQUESTED
Sampler:
T Frinakf A Murphy
P.O. #: Quotation #:
SAMPLE ANALYSIS
ExyLIMS#
HJ3
t4-
Client Sample Identification
DF06 SB 133B 0 0000
DF06 SB 133B 0 0005
DF06 SB 133B
0010
DF06 SB 133B
0020
Collection
Date
7-Dec-04 7-Dec-04 7-Dec-04 7-Dec-04
Collection
Time
14:10 14:15 14:25 14:40
'S. 2c
oz.
o o
X X
Sam ple
M atrix
SOIL SOJL SOIL SOIL
Comments 0-3 INCHES 0.5-1.0 FEET
CHAIN OF CUSTODY
Cooler ID No.:
. RelinqujjstpBd^^j
D?te. Time / ? / ? / * '{ 1fC i0 '
Received By: Fed Ex
*/
Cooler Temp. (C):
Date Time
t
n- .te [&
PROJECT REQUIREMENTS
Results Deadline:
Laboratory Report Options: Sample Results Only Add Case Narrative Add Quality Control Summary Add Calibration Summary Add Raw Data Other:
Sample Lot#:
2 ^>3-
Sample No.
Analysis
I'L if
LV '
STL Chicago Internal Sample Custody Transfer Record
____
Client:
Relinquished by; Received by:
Date
Time
Comments
- Y A--
ytmL _
0
O V IV
0 1 'U i
t1
CHI-22-11-001/C-1/99
rpjsckl
Job Sample Receipt Checklist Report
Job Number.: 232677
Location.: 57222 Check List Number.: 1
Description.:
Customer Job ID.___ :
Job Check List Date,: 12/10/2004
Project Number.: 20004891 Project Description.: Confidential Decatur - FC Investigation
Customer...... : Weston Solutions, Inc.
Contact,: Jai kesgri
Questions 7
(Y/N) Comments
V2
Date of the Report..: 12/27/2004 Project Manager.... : row
Chain-of-custody Present?.,....................... Y
Were samples dropped off at or picked up by STL?.. N
Custody seal on shipping container?..r............ Y
-.,If "yes", custody seal intact?..,.............. Y
Custody seals on sample containers?............... N
...If "yes", custody seal intact?.................
Samples ioed?....................................
Y
Temperature of cooler acceptable? <4 deg C +/- 2). Y 3.8
Samples received int3ct (good condition)?........ Y
Volatile samples acceptable? (no headspace).... .
Correct containers used?......................
Y
Adequate sample volume provided?.................. Y
Samples preserved correctly?...................... Y
Samples received within holding-time?............. Y
Agreement between COC and sample labels?......... Y
Radioactivity at or below background levels?___ _ Y
A Sample Discrepancy Report (SDR) was needed?...,, N
If samples were shipped was there an air bill #?.. Y
Sample Custodian Signature/Date.............,,.... Y
Page 1
1 Ram Data
Express US Airbill / . sg fl4
Sander's
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9aridsiajgrtrMeejiIrdoundeeufTtirwitipaaenuds1h9d ft-- ton^VU4ourWafa3
frr E ll 1j90tyG4MdL IJXI.-H E U -., fe r.C n V ,41!- Pat r n * C " W -S W FccL>* f f * . ^ n H U.5 A. Kr^.V H 1 *
CASE NARRATIVE
Client: Job #:
STL Chicago Wet Chemistry Case Narrative
Weston Solutions, Inc. 232677
Date Rec'd: 12/10/04
1. This narrative covers the analysis of the samples in the above Job # for TOC by the Lloyd Kahn Method.
The samples were analyzed for TOC in duplicate by furnace combustion and nondispersive infrared detection on a Dohrmann Phoenix 8000 TOC analyzer, after acidification to remove inorganic carbon, and drying. No correction was made, therefore, for moisture content. The average o f the sample bums is reported.
2. fhe method-recommended holding time o f 2 weeks was met. Refer to the Laboratory Chronicle Page for dates of sampling, receipt, and analysis.
3. The TOC calibration curve and the initial and continuing verification standards and blanks met acceptance criteria, except that the final CCV in batch 137258 was initially high, at 144% recovery. It was re-injected and within limits, at 96% recovery.
4. The method blanks were less than the reporting limit.
5. The LCSs were within acceptance limits.
6. The matrix QC in these analytical batches was done on samples from other Job #s,
7. The second analysis o f sample 232677-6 was an outlier and not reported. Sec the raw data.
-
Diane L Harper
Wet Chemistry Section Manager
Date
RAW DATA
TOC
RUN LOG
y>Xt, 17
12/16/0 14:37
T otal O rganic Carbon (S o ils ) Method C o d e ..: TOCS Batch C o d e ...: 137258
S t a t u s .............. , : RPT Batch D a te ,,, 12/16/04 Batch T im e.., 1330
U ser Name... QC C o d e .. . , , C alc C o d e ... . . . : TOCS
L ocation C ode,, Equipment code, Import C o d e,,,,
TEST CODE
TTTTTTTTTTTTT
DOOO0 0 OCCC I 1 I
CCCc c c c S S S CCC
2 3 4 AAA 2 AS s S
VVV
V 2A
234 2 2
SAMPLE: Grp Pos Sam ple ID
D ilution
TEST POS D ate / Time
123 4 5 6 7 1 1 12 2 2 78 90 12
11
___ ICALJ04LSTTC1_
0
12
___ ICV_I04LSTTC2_
12/15/04 0908 0
13
MB
12/15/04 0915 0
14
___ LCSJ00F5TLK3_
12/15/04 1016 0
15
LCD 10QFSTLK3 _
12/1 5 /0 4 1024 0
16
232676 5 S
12/15/04 1032
0
17
232676_6_S____
12/15/04 1109
0
18
232676 7 S___
12/15/04 1123
0
19
2 3 2 6 7 6 _ 8 _ S ___
12/15/04 1139
0
1 10 232676m8_SJ1SJ04CSTTC2_9
1 2 /15/04 1155
0
1 11 232676_8_S_M SDJ 04LSTTC2_9
0
1 2 /15/04 1350
M
1 12 2 3 2 6 7 7 J _ S ___
1 2 /1 5 /0 4 1405
0
1 13 232677 2 S
12/15/04 1422
0
1 14 232677_3_S___
12/1 5 /0 4 1443
0
1 15 1 16
___ CCV_104LSTTC2_ ___ CCB__
1 2 /1 5 /0 4 1501 0 12/15/04 1508 0
"11
1 17 232677 4 S
12/15/04 1513
0
1 18 232677_5_S___
12/15/04 1532
0
1 19 252677 6 S
12/15/04 1557
0
1 20 ___ CCV_I04LSTTC2_
1 2 /1 5 /0 4 1621 0
1 21 ___ CCB__
12/1 5 /0 4 1623 0
Page 1
TT
oc s m n a r y
***
<V2 )
T otal O rganic Carbon (S o ils )
Method C o d e ..: TQCS Batch c o d e ...: 137258 S t a t u s . . . . . . . : RPT
Batch D a t e ...: 12/16/04 Batch T im e ...: 1330 U ser Name------; e l s
QC Code................. : TOCS C a lc Code............ : TOCS L o catio n C o d e ..: 57Z22
Grp Smp Sam ple ID
Pos Test R esult
Known
orig in al
1 2 ___ 1CVJ04LSTTC2_
1 TOC 2 1 5 5 .2 6 2000
1 3 ___ MB__
1 TOC -2 .3 8
1 4 ___ LCS_I0QFSTLK3_
1 TOC 4 1 2 7 .3 6 4780
1 5 ___ LCDJOOFSTLK3_
1 TOC 474 5 .1 5 4780
1 10 Z32676i_8_S_MS_104LSTTC2_9
5 TOCAV2 5 7 2 8 .2 6 2000
1731.20
1 11 Z32676_i8_S_MSD_ 104L STTC2_9
5 TOCAV2 6 9 9 9 .0 0 2000
1731,20
1 15 ___ CCV_I04LSTTC2_
1 TOC 2 2 0 8 .4 9 2000
1 16 ___ CCB__
1 TOC -1 .8 9
1 20 ___ CCVJ04LSTTC2_
1 TOC 192 7 .0 7 2000
1 21
CCB
1 TOC '2 . 2 8
R eport D ate: 12/16/04 14:37
E quipm ent C o d e .: T0C4 I n p o r t Code____ :
A l t e r n a t e QC Res 108
F QC Res
F
5728.26
86 99 100.3 147,5 110
_ 1_4
N
96
Page 1
*** RAW TEST DATA
***
V2 )
Total Organic carbon (S o ils )
Method Code, Batch :o d e .. S tatus
TOCS 137258
Batch D a te ...: 12/16/04 Batch T im e ...: 1330 U ser Name.. . . : e ls
SAMPLE
Grp Pos Sam ple ID
11
ICAL I04LSTTC1
12
ICV IQ4LSTC2
13
MB
14
ICS I00FSTLIC3
15
LCD I00FSTLK3
1 6 232676 5 S
17
1e
232676 6 S 232676 7 S
1 9 232676 8 S
1 10 232676 8 S MS I04LSTTC2 9
1 11 232676 8 S MSD I04LSTTC2 9
1 12 232677 1 S
1 13 232677 2 S
1 14 232677 3 S
1 15
CCV I4LSTTC2
1 16
CCB
1 17 232677 4 S
1 18 232677 5 S
1 19 232677 6 S
1 20
CCV I04LSTC2
1 21
CCB
QC C o d e ... . . . + * : TOCS C a lc Code. ___ i TOCS L ocation C o d e..: 57222
D ilution
TOC mg/Kg
TQC2 mg/Kg
R eport D ate: 12/16/04 14:37
E quipm ent C o d e .: T0C4 Im port Code *** i
T0C3 mg/Kg
TQC4 mg/Kg
T0CAV2 mg/Kg
2155.26
-2 .3 8
4127.36
4745.15
14151.93 16628.09
4641.14 7437.13
2214.31
2423.65
1526.24 1936.16
5728.26
0 6999.00
7361.04 8603.97
2675.91
3732.21
1273.08 1738.95
2208.49
-1 .8 9
997.27
1224.27
4311.65 5023.62
536.36
323.33
1927.07
-2.2B
15390.01 6039.14 2318.98 1731.20 5728.26 6999.00 7982.50 3304.06 1506.02
1110.77 4667.64 429.85
Pegs 1
RAW TEST DATA
V2 )
Total Organic Carbon (SoiLs)
Method C ode.. B atch Codo S t a t u s ------
TOCS
137Z58 RPT
Batch D a te ..: 12/16/04 Batch T im e ...: 1330 u s e r Name___ : e l$
SAMPLE:
Grp Pos Sam ple ID
11
I CAL 104LSTTC1
12
ICV I04LSTC2
13
MB
14
LCS I0FSTUC3
15
LCD I0FSTLK3
1 6 232676 5 S
1 7 232676 6 S
1 8 232676 7 S
1 9 232676 8 S
1 10 232676 8 S MS I04LSTTC2 9
1 11 ZS 2 6 7 (f S S MSD I04LSTTC2 9
1 12 232677 1 S
1 13 232677 2 S
1 14 232677 3 S
1 15
CCV I04LSTTC2
1 16
CCB
1 17 232677 4 S
1 IS 232677 5 S
1 19 232677 6 S
1 20
CCV I04LSTTC2
1 21
CCB
QC c o d e . . .
TOCS
C a lc Code. ..........: TOCS
L ocation C o d e..: 57222
Di l u t io n
TOCAV3 mg/Ka
TCAV4 mg/Kg
Report Date*. 12/16/04 14:37
Equipm ent C o d e .: TOC4 Im port Code
TOCR1 ug
TOCR2 ug
TCR3 ug
107.7632
-0 .3 8 0 7
107.3113
129.5426
284.4537 237.7817
69.6171
132.3810
31.0003 67,8622
34.0351 45.6934
143.7793
0 195.9721
208.3173 230.5863
60.1065
108.2342
42.0115 60.8631 110.4244
-Q.302
36.0016 54.3576
193.5930 182.8598
44.2498 29.2286
96.3537
-0.3644
Page 2
3
*** RAW TEST DATA
(V2 )
TotaL Organic Carbon (SoiLs)
Method C ode.. B atch Code S t a t u s ___
TOCS 137258
RPT
Batch D ate. 12/16/4 Batch T i r . . . : 1330
U ser Name___ : c l s
SAMPLE:
rp Pos Sam ple ID
11
ICAL I04LSTTC1
12
ICV I04L5TTC2
13
MB
14
LCS I00FSTU 3
15
LCD I0GFSTLK3
1 6 232676 5 S
1 7 232676 6 S
1 S 232676 7 S
1 9 232676 8 S
1 10 232676 8 S MS I04L5TTC2 9
1 11 232676 8 S HSD I04LSTTC2 9
1 12 232677 1 S
1 13 232677 2 S
1 14 232677 3 S
1 15
CCV I4LSTTC2
1 16
CCB
1 17 232677 4 S
1 18 232677 5 S
1 19 232677 6 S
1 20
CCV I4LSTTC2
1 21
CCB
QC C o d e .. . T a lc Code
TOCS Tnrs
L ocation C ode..: 57222
Di l u t io n
TOCR4 us
UT1 9
Report Date: 12/16/04 14:37
E quipm ent C o d e .: T0C4 Iirm ort E nde__ _ :
WT2 WT3 UT4 9S9
0.05
0*16
0.0260
0.0273
0.0201
0.0143
0.0150
0.0178
0.0140
0.0280
0.0223
0.0236
0.0251
0 0,0280
0.0283
0.0268
0.0209
0.0290
0.0330
0.0350
0.05
0.16
0.0361
0.0444
0.0449
0.0364
0.0825
.Q904
0.05
0 .1 6
*** RAW TST DATA
Total Organic Carbon (Soils)
Method c o d e , . : TOCS Batch C ode-.. : 137258 S t a t u s ............... : RPT
Batch D a te .. : 12/16/04 Batch T im e.. : 1330 U ser M arne... : c 1$
SAMPLE:
Grp Pos Sam ple ID
11
JCAL I4LSTTC1
12
1CV I04LSTTC2
13
MB
14
LCS IO0FSTLK3
15
LCD lOOfSTLK3
1 6 232676 5 S
1 7 232676 S
1 8 232676 7 S
1 9 232676 8 S
1 10 232676 8 S MS I04LSTTC2 9
1 11 232676 8 S MSD I04LSTTC2 9
1 12 232677 1 S
1 13 232677 2 S
1 14 232677 3 S
1 15
CCV I04LSTTC2
1 16
CCB
1 17 232677 4 S
1 18 232677 5 S
1 19 232677 6 S
1 20
CCV I04LSTTC2
1 21
CCB
oc Code.............. . : TOCS C a lc Code.......... . TOCS L ocation Code. . : 57222
D ilution
DLFAC N/A
ICS mg/Kg
3.2000 1.0000 6.1538 5.8606 9.3023 9.7561 7.6190 6.9717
6.3745 0 5.7143
5.8076 6.4128 4.7059 3.2000 1.0000 3.9752 3.9360 1.8508 3.2000 1.0000
CVS )
Report Date: 12/16/04 14:37
E quipm ent C o d e .: OC4 Im port Code___ :
CS2 mg/Kg
TCSAV2 mg/Kg
TICS mg/Kg
Page 4
Calibration Report Print Date/Time: 2004/12/16 7:35:41
Cal. Curve ID:
SOILCURVE
Created:
12/13/2004 13:36
Calibration Factor (m); 9.841e+04
Y Intercept (b): -250134
r-squared:
0.99935
Standard ID Y X Expected Measured Message Date &
Raw Data ug C ug C
Time
0 ugram C
-8891 0.000 2.451 No Sample Det 12/13/200411:24
10ugramC
911065 10.000 11.800
12/13/200411:42
20 ugram C 1853385 20.000 21.375
12/13/2004 11:48
40 ugram C 3745719 40.000 40.605
12/13/2004 12:04
120 ugram C 11194916 120.000 116.302 Endpoint Time 12/13/200412:28
200 ugram C 18654032 200.000 192.099
12/13/2004 12:46
300 ugram C 29462156 300.000 301.928
12/13/200412:59
400 ugram C 39451668 400.000 403.439 Endpoint Time 12/13/200413:19
IV;V
TUf./tw*.
TC
ICB-MB
-0,3807
TC
ICS
107.3113
TC
LCD......... .......... ........ 129.5426............ ...TC .
232676-5
284.4537
TC
232676-5
-0.2819
TC
232676-5............ ........... 237.7817... ......... TC
232676-6
69.6171
TC
232676-6
132.3810
TC
232676-7............ ........... 31,0003... ......... TC
232676-7
67.8622
TC
232676-8
34.0351
TC
232676-8............ ........... 45,6934... ......... TC
232676-8ms 232676-8ms
143.7793 195.9721
TC TC
232677-1........................ 2083173... ......... TC
232677-1
230,5863
TC
232677-2
60.1065
TC
232677-2........................ 108.2342... .. ...TC
232677-3
42.0115
TC
232677-3
60,8631
TC
CCV.................... ........ 110.4241............ ...TC ,
CCB
-0.3020
TC
232677-4
36.0016
TC
232677-4........................ 543576... ......... TC
232677-5
193.5930
TC
232677-5
182.8598
TC
232677-6........................ 14.8402... ......... TC
232677-6
44.2498
TC
232677-6
29.2286
TC
CCV.................... ........ 143.5157............ ,,TC .
CCV
96.3537
TC
CCB
-0.3647
TC
Detailed Analysis Report Print Date/Time: 2004/12/16 7:53:18
Sample ID: ICV Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12150902
Timestamp: 12/15/201 Sample Type: Cal. Veriffc
09:(f/ '
IVI I
Rep# ppmC ugC Raw Data Beginning Ending Integration Baseline Baseline Time
1 107.7632 107.7632 10354667 1.459 2.459 323
Sample ID: ICB-MB Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC
Filename: 12150911
Timestamp: 12/15/2004 09:15
Sample Type: Sample l
/
Rep# ppmC ugC Raw Data Beginning Ending Integration Baseline Baseline Time
1 -0.3807 *0,3807 -11702 1.805 1,697 120
Last Message: No Sample Detected
Sample ID: LCS Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode. TC Filename: 12151010
Timestamp: 12/15/2 Sample Type: Sample
Rep# ppmC ugC Raw Data Beginning Ending Integration Baseline Baseline Time
1 107.3113 107.3113 10586095 0.759 1.759 305
Sample ID: LCD Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode. TC Filename: 12151019
Timestamp: 12/15/2 Sample Type: Sample
Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time
1 129.5426 129,5426 12773842 2.063 3,062 290
Sample ID: 232676-5 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode. TC mame: 12151026
[Imestamp: 12/15/200^10:32 Sampl^Type: Sample
Rep # ppm C ug C Raw Data Beginning XEnding
Baseline Baseline Tim%
Integration
y ,r
r
1 195.9721 195.9721 1^11056
7/tY
2.477 3.475 391
Sample ID: 232677-1 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC
Filename: 12151358
f
Timestamp: 12/15/2004 14:05
Sample Type: Sample \
y
Rep# ppmC ugC Raw Data Beginning Ending Integration Baseline Baseline Time
1 208.3173 208.3173 20525928 1.624 2,624 357
Sample ID: 232677-1 Method: boat
08 Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 121514
Timestamp: 12/15/2004 14:15 Sample Type: Sample
Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time
1 230.5863 230.5863 22717388 2,151 3.151 350
Sample ID: 232677-2 Method: boat Cal, Curve: SOILCURVE Operator ID: CAROL
Mode: TC
^
Filename: 12151417
f
Timestamp: 12/15/200414:22
Sample Type: Sample l
^
Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time
1 60.1065 60.1065 5940749 1.980 2.980 257 =?==?============================ti3=Esgs=======3==z===
Sample ID: 232677-2 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12151428
Timestamp: 12/15/2004 14:34 Sample Type: Sample
Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time
1 108.2342 108.2342 10676918 1.663 2,660 325
Sample ID: 232677-3
Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC
Filename: 12151436 Timestamp: 12/15/20I
Sample Type: Sample
U14:43
Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time
J
/
as:
1 42.0115 ^42.0115 4160050 2.057 3.055 243
Sample ID: 232677-3 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode. TO Filename: 12151445
Timestamp: 12/15/2004 14:51 Sample Type: Sample
Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time
1 60.8631 60.8631 6015201 1.970 2.968 276
Sample ID: CCV Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12151456
Timestamp: 12/15/2 Sample Type: Cal. Verifi
Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time
1 110.4241 110.4241 10616519 2.494 3.492 287
Sample ID: CCB Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12151505
Timestamp: 12/15/2004 15:08 Sample Type: Sample
Rep# ppmC ug C Raw Data Beginning Ending Integration Baseline Baseline Time
1 -0.3020 -0.3020 -3957 1.693 1.635 120
Last Message: No Sample Detected
1:=======================;^:^^"= = --========================;^~
Sample ID: 232677-4 Method: boat
Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC
Filename: 12151509
/
Timestamp: 12/15/2QCW 15:13 /
Sample Type: Sample y
x7
Rep# ppmC ugC Raw Data Beginning Ending Integration Baseline Baseline Time
1 36.0016 36.0016 3568627 1.661 2.658 250
Sample ID: 232677-4 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12151515
Timestamp: 12/15/2004 15:20 Sample Type; Sample
Rep # ppm C ug C Raw Data Beginning Ending Integration
V* Baseline Baseline Time 1 54.3576 54.3576 5375008 2.062 3.061 278
Sample ID: 232677-5 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12151523
Timestamp: 12/15/2 Sample Type: Sample
Rep # ppm C ug C Raw Data Beginning Ending Baseline Baseline Time
1 103.5930 193.5930 19076934 1.695 2.694
ss====ss:s=s
Inte 350
Sample ID: 232677-5 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12151533
Timestamp: 12/15/200415:40 Sample Type: Sample
Rep # ppm C ug C Raw Data Beginning Ending integration Baseline Baseline Time
1 182.8598 182.8598 18020700 2.126 3.124 344
Sample ID: 232677-6
i0 Mode: TC
Method: boat \ ^ ,y- Filename: 12151544
Cal. Curve: SOILCURVE
Timestamp: 12/15/200415:49
Operator ID: CAROL \ ' / ,y ' Sample Type: Sample
rV f
Rep # ppm C ug C \Raw Data Beginning Ending Integration
baseline Baseline Time
1 14.8402 14.8402 1466164 2.434 3.434 231
s j y kU - L . /
Sample ID: 232677-6 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12151551
Timestamp: 12/15/2004/15:57 Sample Type: Sample l
Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time
1 44.2498 44.2498 4380313 1.564 2.550 324
SamplelD: 232677-6 Method: boat Cai. Curve: SOILCURVE Operatorio: CAROL
Mode: TC Filename: 12151559
Timestamp: 12/15/2004 16:04 Sample Type: Sample
Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time
&
1 .2286 2902108 2.587 3.586 245
Sample ID: CCV Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
^ Mode: TC
Filename: 12151606 Timestamp: 12/15/2 ample Type: CalrVerifi
Rep# ppmC ugC Raw Data Begin! Baseline Baseline
1 143.5157 143.5157 13873017 1.774
Integration 350
Last Message: Out of Calibration
Sample ID: CCV Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12151615
Timestamp: 12/15/201 Sample Type: Cal. Verifies
Rep# ppmC ugC Raw Data Beginning Ending Integration Baseline Baseline Time
1 96.3537 96,3537 9231873 1.976 2.967 294
====?^=====~=======^s====s^=======t===========s==:=======sc;
Sample ID: CCB Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12151621
Timestamp: 12/15/20 Sample Type: Sample
16:23 .X
Rep# ppmC ugC Raw Data Beginning Ending Integration
Baseline Baseline Time 1 -0.3647 -0.3647 -10128 2.537 1.759 120
Last Message: No Sample Detected
STL Chicago
Page No.:
105
TOC in Soils
Book No.
Method; Lloyd Kahn
Instrument Phoenix 8000 (Tqca
LabNet Batch: 7 ^ 7 2 r e
calculations;
Date of Standard Curve: S & .- d 'j/Z r y ' ,
TOC(mg/kg) =* ug C / grams sample
Book# *7 7 ^ 7 Face#
MS, MSb Known Cone, (mg/kg) 3 100 ug C / grams sample
MS, MSD Observed (mg/kg) = ug C / grams sample
MS, MSD Ree, * iobsarved mo/ko - avo, sample result fma/Vai] x 100
known concentration in mg/kg
Standard Traceability: (Note: Working Standards are prepared daily from the noted Stock Solutions.)
Stock I fCutval Q c I C ? r7 C -1
stock II (ICV/CCW T - Lf ( - S r y < r \
ICS Soure ID J ^ fS Z L O -C S Tru Valu 7 7 Y ^ / k Acceptance Range
Sample ID;
Sample Weight (g)
ugC
Comments;
o rc o
LO ^ LP n 0 2 1 /7 C n
______________
0 .0 % O- { 6 O .n o -L O C /O 9 -1 2 k L O . O 1.0/ -&=-o * f y 0- C /H 3 .o / r o, o n < ?
_ fn7r7 W . - 0 .3 o l
t e n . 7// 3 /o ft, s m 'z? H .v < y ? ' 2-X I f --
CS7. 7 7 / ? 4 9 C /7 / f.3 2 n /O '
*
.H l
n . o /^ /o
31 a?3
1- n _ o, n zz*
I 1 .M 2
.............. I - r I -- t*.*?
< f .6 2 /Z -2 . n o ' s c . . P 0 !J
7 C (fJY t ' a . 719?
y oi+fHy jfW V-
11Ori
1^? YiHfil
\(m * * '
n . H o
'? r,f7 p / T
'r
iva-
H Lei7 - 1
'.ftH 'b
v o f^ m
1
____ ____- 1 L
O .O H P s t . <3 <Z& 7
n o , 9U 1 Go. jog r
-7 > -3 CS/ _______ CU
n .n H o
(? ~ U n o .o3 r o
n a*r
/0 r , T ) n 976u<
GO. /
ft o?M
ivc0-i<;o>
Prep Analyst A
ta
________________ Date: n /lJ iQ
Analyst
_________________ Date: / `2 / / i / a c/
Reviewed bv: S 4 A ^ Q U --*, _____________Date: V iT n /iH ______ _ ^
STL C h ica g o
Pag* No.:________ 1 C f i
TOC in S o ils
Book No.: ^ 7 V 7
M e th o d: L lo y d K ahn
instrument Phoenix 8000 rro c 4 i
LabNet Batch: / V 7 2 C X
C a lcu la tio n *:
Date of Standard C urve:/ / - / / ?
:
TOC (mg/kg) * ug C / grama sample
Book#
7 Pane# / o f _____
MS, MSD Known Cone, (mg/kg) * 100 ug C / grams sample
MS, MSD Observed (mg/kg) = ug C / grams sample MS, MSD Rec. * fobserved mo/ko - avo. sample result (mo/koH x 100
known concentration in mg/kg
Standard Traceability: (Not*: Working Standards are prepared daily from the noted Stock Solutions.)
Stock I (Curve) f C H U ^ T O . ( Stock II (ICV/CCV) C ~ 5 t T<?-
LCS Source ID
/x T L liX frCS True Value 1 /7 f X ifct Acceptance Range K % ~ / V fr *5'
S a m p le 10;
4 3 2 /7 7 X .
\ -4
S a m p le W e ig h t (g )
a tu , n 'c 1 n u '-f'J
ugC
~ 3 0 10
X 0 0 j(, t w l
C om m enta:
*- _________________
-SW * /*
-< -r
L. - x
^Cco~ e e .C ' cerb \ \
a o v tl. O, 0 ^ 0 1 - .o 'n x - -- .o r -'f n. o io 't
n .o ^
0 .^ X /rA
iY i. ? r? p ~ h / . r y * * r - - i'S /
yy, Q jf -i2 Jtff
r i 3^3? ~.
X
X
X X
-
X
\
_\
X
N\
Prep Ana Ivst:
/< 0 ;^
Reviewed by:. -- ( h - iU J j-Joe.H/p
Date:
W *
Date: IJ X //< / Y
Date:
/ Jxf
CHI-Z2-12-OBS/B-OS/01
* * * RUN LOG
lie
{M2 )
Page 1
RUN LOG
***
CVE ) 12/20/04 13:35
Page 2
*** QC Limary
CV2 )
Total Organic Carbon (Soils)
Method Code..: TOCS Batch Code,..: 137288 Status.....,.: RVWD
Grp Smp Sample ID
12
ICV I04LSTTC2
13 14
___MB__ ___LCSJDDFSLK3_3
1 5 ___LCD_I00FSTLK3_3
1 16 ___CCV_I04LSTTC2_
1 17 ___CCB__
1 28 ___CCV_I04LSTTC2_
1 29
CCB
Batch Date__ : 12/16/04 Batch Time...: 1516 User Name___ : els
q c Code.........: TOCS Calc Code...... : TOCS Location Code..: 57222
Pos Test Result
Known
Original
1 TOC 1990.99 2000
1 TOC 12.89
1 TOC 4550.8$ 4780
12.89
1 TOC 4890.69 4780
12.89
1 TOC 2054.40 2000
1 TOC -1.84
1 TOC 2000.34 2000
1 TOC -2.40
Report Date: 12/20/04 13:35
Equipment Code.: TOC4 Import Code,...:
Alternate QC Res 100
F QC Res
F
4550.88
95 102 103
7
100
---- Page 1
j
*** RAU TEST PATA
<V2 )
Total Organic Carbon (Soils)
Method Code.. TOCS Batch Code... 137288 Status....... RVWD
Batch Pate...: 12/16/04 Batch Time.,.: 1516
User Name.... : eis
SAMPLE:
Grp Pos Sample ID
11
ICAL I04LSTTC1
12
ICV IQ4LSTTC2
13
MB
14
LCS IQQFSTLK3 3
15
LCD ID0FSTLK3 3
1 6 232577 11 S
1 7 232577 11 S MS I04LSTTC2 6
1 8 232577 11 S MSD I04LSTTC2 6-
1 9 232677 7 5
1 10 232677 8 S
1 11 232677 9 S
1 12 232677 10 S
1 13 232677 11 S
1 14 232677 12 S
1 15 232677 13 S
1 16
CCV I04LSTTC2
1 17
DCB
1 18 232677 14 $
1 19 232679 1 S
1 20 232679 2 S
1 21 232679 3 S
1 22 232679 4 S
1 23 232679 5 S
1 24 232679 S
1 25 232679 7 S
1 26 232679 8 S
1 27 232746 9 S
1 28
CCV 104LSTTC2
1 29
CCB
QC Code... .... : TCS CaLc Code. Location Code,.: 57222
Di lut ion
TOC mg/Kg
T0C2 mg/Kg
Report Date: 12/20/04 13:35
Equipment Code.: T0C4 Import Code....:
TOC3 mg/Kg
TOC4 mg/Kg
TCAV2 mg/Kg
1990.99
12.89 4550.88 4890.69 1379.46 2882.69 3007.39 9275.47 2939.25 1794.66 1199.75 5027.33 3665.60 2640.71 2054.40
-1.84 1440.55 1589.83 7100.85 1054.59
1021.71 401.47 402,46 631.27 631.42 133019*80 2000.34 -2.40
1230.22
4707.10 2675.00 1544,31 638.83 5665,06 3168.78 2087.93
1501.31 2008.47 7999.75 614.39 888.92 348.14 336.02 613,67 452.44 145772.70
1304.84 2882.69 3007,39 6991.28 2807.12 1669.48 919.29 5346.19 3417.19 2364.32
1470.93 1799.15 7550.30 834.49 955.32 374.81 369.24 622.47 541.93 139396.25
f*age 1
i:.8
*** RAW TEST DATA
<V2 }
Total Organic Carbon (Soils)
Method Code, : TOCS Batch Code : 13/206 Status___
Batch Date,..; 12/16/04 Batch Time,..: 1516 User Hame___ : els
SAMPLE:
Grp Pos Sample [0
11
ICAL I04LSTTC1
12
ICV 104LSTTC2
13
MB
14
LCS I00FSTLK3 3
15
LCD IDQFSTLK3 3
1 6 232577 11 S
1 7 232577 11 S MS I04LSTTC2 6
1 8 232577 11 S MSB I04LSTTC2 6-
1 9 232677 7 S
1 10 232677 S S
1 11 232677 9 S
1 12 232677 10 S
1 13 232677 11 S
1 14 232677 12 S
1 15 232677 13 S
1 16
CCV I04LSTTC2
1 17
CCB
1 IS 232677 14 5
1 19 232679 1 S
1 20 232679 2 S
1 21 232679 3 S
1 22 232679 4 S
1 23 232679 5 S
1 24 232679 6 S
1 25 232679 7 S
1 26 232679 8 S
1 27 232746 9 S
1 28
CCV I04LSTC2
1 29 ___CCB__
QC Code...
. TOCS
Calc code.
TOCS
Location Code.*: 57222
Dfluti on
T0CAV3 mg/icg
QCAV4 mg/Kg
Report Date: 12/20/04 13:35
Equipment Code.: TOC4 Import code
TOCR1 ug
TOCR2 ug
TOCR3 ug
99.5494 2.0625 116.5025 146*2316 95.8727 174.9791 190.0672 213.3358 85.2383 58.5059
55*1$86 278.0111 140.7590 1OB.2690 102.7198 -0.2950 60.7911 80.2864 291.8449 43.5546 47.1010
36.6142
33.1221 52.9636 55.8174 133.0198 100.0171 -0.3848
77.5036
118*6188 104.3250 60.8457 36.2218 262.2923 109.0061 74.9566
75.2155 118.2986 319.1901 35.5731 39.8237 32.3418 26*0417 46.7615 41.6243 145.7727
Page 2
RAW TEST PATA
<V2 )
Total O rg a n ic Carbon (Soils)
Method Code . . : TOCS
Batch Code.
137288
s t a t u s .......... RVWD
Batch D a te .. : 12/16/04 Batch T im e.. : 1516 User N am e... : e ls
SAMPLE :
Grp Pos Sam ple ID
11
ICAL 104LSTTC1
12
ICV I04LSTTC2
13
MB
14
LCS 10DP5LK3 3
15
LCD I00FSTLK3 3
1 6 232577 11 S
1 7 232577 11 S MS I04LSTTC2 6
1 8 232577 11 S MSD I04LSTTC2 6
1 9 232677 7 S
1 10 232677 B S
1 11 232677 9 S
1 12 232677 10 S
1 13 232677 11 S
1 14 232677 12 S
1 15 232677 13 S
1 16
CCV IQ4LSTTC2
1 17
CCB
1 18 232677 H S
1 19 232679 1 S
1 20 232679 2 S
1 21 232679 3 S
1 22 232679 4 S
1 23 232679 5 S
1 24 232679 6 S
1 25 232679 7 S
1 26 232679 8 S
1 27 232746 9 S
1 28
CCV I4LSTTC2
1 29
CCB
OC Code.................: TOCS C a lc Code___ _. : TOCS L ocation C o d e..; 57222
D ilu tio n
TOCR4 ug
UT1 9
Report Date: 12/20/04 13:35
Equipm ent C o d e .; TQC4 im port Code------:
UT2 WT3 WT4 SS9
0.05 0.16
.Q256 0*0299 0.0695 0.0607 0,0632 0.0230 0.0290 0.0326 0.0460 0.0553 0.0384 0.0410 0.05 0.16 0.0422 0.0505 0.0411 0*0413 0*0461 0.0912 0.0823 0.0839 0.0884 0.0010 0.05 0.16
0.0630
0.0252 0.0390 0.0394 0.0567 0*0463 0.0344 0.0359
0.0501 0.0589 0*0399 0.0579 0.0448 0.0929 0*0775 0.0762 0.0920 0.0010
Page 3
SO
*** RAU TEST DATA
Total. Organic Carbon (SoiLsl
Method Code.r: TOCS Batch Code...: 137288 Status.______: RVUD
Batch Date...: 12/16/04 Batch Time...: 1516 User Name___ : cls
SAMPLE:
Grp Pos Sample ID
11
ICAL I04LSTTC1
12
ICV I04LSTTC2
13
MB
14
LCS I0FSTLK3 3
15
LCD IQ0FSTLK3 3
1 6 232577 11 S
1 7 232577 11 S MS I4LSTTC2 6
1 8 232577 11 S MSD I4LSTTC2 6-
1 9 232677 7
1 10 232677 8 S
1 11 232677 9 S
1 12 232677 10 S
1 13 232677 11 S
1 U 232677 12 S
1 15 232677 13 S
1 16
CCV I04LSTTC2
1 17
CCB
1 18 232677 14 S
1 19 232679 1 S
1 20 232679 2 S
1 21 232679 3 S
1 22 232679 4 S
1 23 232679 5 S
1 24 232679 6 S
1 25 232679 7 5
1 26 232679 8 5
1 27 232746 9 S
1 28
CCV I04LSTTC2
1 29 ___CCB__
QC Code... Cale Code. .... : TOCS Location Code..: 57222
Di lut ion
DL FAC N/A
TCS mg/Kg
3.2000 1.0000 6.2500 5.3512
2.4151 2.6359 2.5316 6.6390 4.7059 4.4444 3.1159 3.1496 4.3956 4.1612 3.2000 1.0000 3.4670 2.9250 3.9506 3.2258 3.5204 1.7382 2.0025 1.9988
1.7738 160.0000 3.2000 1.0000
V2 )
Report Date: 12/20/04 13:35
Equipment Code.: OC4 Import Code **, ;
TCS2 mg/Kg
TCSAV2 mg/Kg
TICS mg/ Kg
Page 4
Si
Calibration Report Print Date/Time: 2004/12/20 8:20:27
Cal. Curve ID:
SOILCURVE
Created:
12/13/2004 13:36
Calibration Factor (m): 9.841 e+04
Y Intercept (b); -250134
r-squared:
0.99935
Standard ID Y X Expected Measured Message Date &
Raw Data ug C ug C
Time
0 ugram C
-8891 0,000 2.451 No Sample Det 12/13/200411:24
10ugramC
911065 10.000 11.800
12/13/2004 11:42
20 ugram C 1853385 20.000 21.375
12/13/2004 11:48
40 ugram C 3745719 40.000 40.605
12/13/2004 12:04
120 ugram C 11194916 120.000 116.302 Endpoint Time 12/13/200412:28
200 ugram C 18654032 200.000 192.099
12/13/2004 12:46
300 ugram C 29462156 300.000 301.928
12/13/2004 12:59
400 ugram C 39451668 400.000 403.439 Endpoint Time 12/13/200413:19
Multiple Analysis Report Print Date/Time: 2004/12/16 16:35:47
Sample ID
Result Std. Dev. RSD Mode ALT
1CV
99.5494
TC
ICB-MB
2.0625
TC
LCS
116.5025
TC
LCD...................... ...... 146.2316............ ...TC ..
232572-11
22.8143
TC
232572-11
95.8727
TC
232572-11...,......... .......... 77.5036... ......... TC
232572-11ms
174.9791
TC
232572-11msd
190.0672
TC
232677-7........................ 213.3358... ......... TC ,
232677-7
118.6188
TC
232677-8
85.2383
TC
232677-8........................ 104.3250... ......... TC .
232677-9
58.5059
TC
232677-9
60.8457
TC
232677-10................... . 55.1886... ......... TC
232677-10
36.2218
TC
232677-11
278.0111
TC
232677-11....................... 262.2923... ......... TC
232677-12
140.7590
TC
232677-12
109.0061
TC
232677-13....................... 108.2690... ......... TC
232677-13
74.9566
TC
ccv
102.7198
TC
CCB...................... .......-0.2950............ ...TC ..
232677-14
60.7911
TC
232677-14
75.2155
TC
232677-15............ .......... 80.2864... ......... TC
232677-15
118.2986
TC
232679-2
291,8449
TC
232679-2.............. ......... 319.1901... ......... TC
232679-3
43.5546
TC
232679-3
35.5731
TC
232679-4.............. ......... 47.1010...
......... TC .
232679-4
39.8237
TC
232679-5
15.6963
TC
232679-5.............. ......... 36,6142...
......... TC
232679-5
32.3418
TC
232679-6
33.1221
TC
232679-6.............. ......... 26.0417...
......... TC .
232679-7
52,9636
TC
232679-7
46.7615
TC
232679-8.............. ..........55.8179...
......... TC .
232679-8
41.6243
TC
232746-9
133.0198
TC
232746-9.............. ......... 145.7727... ......... TC
CCV
100.0171
TC
CCB
-0.3848
TC
S3
Detailed Analysis Report Print Date/Time: 2004/12/16 16:36:63
Sample ID: ICV Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC
^
Filename: 12160806
\
Timestamp: 12/16/200408:13,
Sample Type: Cal. Verificaltieo^
Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time
1 99.5494 99.6494 9546364 1.160 2.159 316
Sample ID: ICB-MB Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12160814
Timestamp: 12/16/20(^4 08:20 Sample Type: Cat. Verification^
Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time
1 2.0625 2.0625 -47164 1.656 1.249 120
Last Message: Out oTDsiifcration
Sample ID: LCS
Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12160833
Timestamp: 12/16/20) Sample Type: Sample
08:39
Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time
1 116.5025 116.5025 11490585 1.744 2.743 275
Sample ID: LCD Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12160843
timestamp: 12/16/20 Sample Type: Sample
Rep# ppmC ugC Raw Data Beginning Ending Integration Baseline Baseline Time
1 146.2316 146,2316 14416174 1.900 2.898 287
Sample ID: 232572-11 Method: boat \ Cal. Curve: SOILCURVE Operator ID: CAROL \
Mode: TC Filename: 12160859
Timestamp: 12/16/2004 09:04 Sample Type: Sample
Rep # ppm C ug C ' aw Data Beginning Ending Integration seline Baseline Time
1 22,8143
22708V ^ 1.336 2.336 239
Sample ID: 232572-11 Method: boar Cal. Curve: SOILCURVE Operator ID: CAR(
Mode: TC Filename: 12160908
Timestamp: 12/16/2004 0 ^ 1 4 ^ ' Sample Type: Sample
Rep # ppm C ug' Raw Data Beginning Ending Integration Baseline Baseline Time
1 95.8727 95.8727 X9460444 1.461 2.459 349
Sample ID: 232572-11 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12160918
Timestamp: 12/16/2004 09:23 Sample Type: Sample
Rep # ppm C ug C Raw Data \ Beginning Ending Integration Baseline Baseline Time
1 77.5036 77.5036 7652767 V899 2.896 269
Sample ID: 232572-11 ms Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mod& TC
Filename: T2160932 Timestamp: 12/16/2004 09:38
Sample Type: Sample ^
Rep# ppmC ugC Raw Data Beginning Bpding Integration Baseline Baseline Timt
1 174,9791 174.9791 17245170 2.976 3.97 350
Sample ID: 232572-11msd Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12160943
Timestamp: 12/16/200^09:49 Sample Type: Sample
Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time
1 190.0672 190.0672 18729966 3.073 4.072 294
Sample ID: 232677-7 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC
Filename: 12161000
X
Timestamp: 12/16/200410:07
Sample Type: Sample ^
y
Rep # ppm C ug C Raw Data Beginning Ending Integration
Baseline Baseline Time
1 213.3358 213.3358 21019790
1.485 2.484 375
iS;
Sample ID: 232677-7 Method: boat CaL Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12161019
Timestamp: 12/16/200410:24 Sample Type: Sample
Rep# ppmC ugC Raw Data Beginning Ending Integration Baseline Baseline Time
1 118.6188 118.6188 11698848 1.859 2.857 268
Sample ID: 232677-8 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC
Filename: 12161035
Timestamp: 12/16/2004 10:42
Sample Type: Sample l
,
Rep# ppmC ugC Raw Data Beginning Ending Integration Baseline Baseline Time
1 85.2383 85.2383 8413926 1.373 2.371 369
Sample ID: 232677-8
Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC
Filename: 12161043 Timestamp: 12/16/200410:50
Sample Type: Sample
Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time
1 104.3250 104.3250 10292214 1.552 2.552 291
Sample ID: 232677-9 Method: boat CaL Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12161051
Timestamp: 12/16/2004 10:: Sample Type: Sample ( y
Rep# ppmC ugC Raw Data Beginning Ending Integration Baseline Baseline Time
1 58.5059 58.5059 5783236 4.175 5.171 230
Sample ID: 232677-9 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12161100
Timestamp: 12/16/200411:05 Sample Type: Sample
Rep # ppm C ug C Raw Data Beginning Ending Integration
Baseline Baseline Time
1 60.8457 60.8457 6013491
1.455 2.453 274
T2SSK
Sample ID: 232677-10 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC
Filename: 12161113 Timestamp: 12/16/200*11:19 }
Sample Type: Sample V_
Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time
1 55,1886 55.1886 5456784 1.768 2.767 278
Sample ID: 232677-10 Method: boat Cal. Curve: SOILCURVE Operator I D, CAROL
Mode: TC Filename: 12161119
Timestamp: 12/16/2004 11:24
Sample Type: Sample
Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time
1 36.2218 36.2218 3590297 2,256 3.254 224
Sample ID: 232677-11 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12161126
Timestamp: 12/16/2 Sample Type: Sample
Rep# ppmC ugC Raw Data Beginning Ending Integration Baseline Baseline Time
1 278.0111 278.0111 27384382 1.789 2.787 417
Sample ID: 232677-11 Method: boat Cal. Curve; SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12161135
Timestamp: 12/16/2004 11:40 Sample Type: Sample
Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time
1 262.2923 262.2923 25837524 5.528 6.523 262
Sample ID: 232677-12 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC
Filename: 12161151
/
Timestamp: 12/16/2004 11:57
Sample Type: Sample V
Rep # ppm C ug C Raw Data Beginning Ending Integration
Baseline Baseline Time
1 140.7590 140.7590 13877630
1.717 2.716 361
Sample ID: 232677-12
Method: boat Cal. Curve: SOJLCURVE Operator ID: CAROL
Mode: TC Filename: 12161168
Timestamp: 12/16/2004 12:03 Sample Type: Sample
Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time
1 109.0061 109.0061 10752874 2.016 3.013 277
Sample ID: 232677-13 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC
-
Filename: 12101212
}
Timestamp: 12/16/2004 12:18 /
Sample Type: Sample
Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time
1 108.2690 108.2690 10680344 1.682 2.680 293
Sample ID: 232677-13 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12161220
Timestamp: 12/16/2004 12:27 Sample Type: Sample
Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time
1 74.9566 74.9566 7402125 2.298 3.295 302
Sample ID: CCV Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12161240
Timestamp: 12/16/200412:46 . Sample Type: Cal. Verification y
Rep# ppmC ugC Raw Data Beginning Ending Integration Baseline Baseline Time
1 102.7198 102.7198 9858350 1.368 2.368 323
Sample ID: CCB Method: boat
Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12161252
Timestamp: 12/16/2004 12:54 Sample Type: Sample ^ ^
Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time
1 -0,2950 -0.2950 -3264 1.535 1.501 120
Last Message: No Sample Detected
Sample ID: 232677-14 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC
Filename: 12161325
/
Timestamp: 12/16/2004 13:29
Sample Type: Sample ^
1
Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time
1 60.7911 60.7911 6008115 4.037 5.031 198
Sample ID: 232677-14 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12161337
Timestamp: 12/16/2004 13:43 Sample Type: Sample
Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time
1 75.2155 75.2155 7427599 1.603 2.602 294
Sample ID: 232677'f&i v lt
Method, boat
& J1"
Cal. Curve: SOILCURV^
Operator ID: CAROL
Mode: TC
...
Filename: 12161344
Timestamp: 12/16/2004 13:49
Sample Type: Sample
Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time
1 80.2864 80.2864 7926619 2.227 3.226 249
Sample ID: 21 7- x y Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
i/Wt
Mode: TC Filename: 12161358
Timestamp: 12/16/2004 14:03 Sample Type: Sample
Rep# ppmC ugC Raw Data Beginning Ending Integration Baseline Baseline Time
1 118.2966 118.2986 11667337 1.529 2.529 310
Sample ID: 232679-2 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC
Filename: 12161406
^mestamp: 12/16/2004 14:12
Sample Type: Sample
i
Rep # ppm C ug C Raw Data Beginning Ending Integration
Baseline Baseline
e
1 291.8449 291.8449 28745744 2.108 3X06 324
Sample ID: 232746-9
Method: boat
\
CaL Curve: SOILCURVE \
Operator ID: CAROL
Mode: TC Filename: 12161603
Timestamp: 12/16/2004 16:09 Sample Type: Sample
Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time
1 145,7727 145.7727 14371019 2.059 3,056 346
Sample ID: CCV Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC
--,
Filename: 12161618
/
Timestamp: 12/16/200416:24
Sample Type: Cal. Verification
Rep# ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time
1 100.0171 100.0171 9592382 1.422 2.421 291
Sample ID: CCB Method: boat
Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12161626
Timestamp: 12/16/2 Sample Type: Sample
Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time
1 -0.3848 -0,3848 -12100 1.660 1.514 120
Last Message: No Sample Detected
STL Chicago
107
Page No.:______
TOC in Soils
Book No.:
7 _____
Method: Lloyd Kahn
Instrument: Phoenix 8000 fTOC4i
LabNet Batch: 1 7 7 ^ - 9 ^ '
regulation*:
Date of Standard Curve: / 2 . / s j s 9 ^
TOC (mg/kg) = ug C / grams sample
Book# 7 7 ^ 7 paoe# / d s
MS, MSD Known Cona (mg/kg) = 100 ug C / grams sample
,,
MS, MSD Observed (mg/kg) * ug C / grams sample
Q d f\< -
_-
MS, MSD Rec. * robserved mo/ka - avo, sample result (mo/koll x 100
known concentration in mg/kg
standard Traceability: (Note; Working Standards are prepared daily from the noted Stock Solutions.)
Stock I (Curve)
( stock II (ICV/CCV) T P O Y i 9 ? 7 ~ C X
LCS Source ID f
True Value V
Acceptance Range 7 7 ^
Sample ID:
Sample Weight (g)
ug C
Comments:
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Date: Date:
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STL Chicago
108
TOC in Soil
PBao9o*kNNo0.\__
^2 _Hl
7L
7
l
Method: Lloyd Kahn
Instrument Phoenix 8000 (TQC4)
LabNet Batch: /3 7 -2 -& -F
Calculation:
Date of Standard Curve: X __________;
TOC (mg/kg) * ug C / grama ample
Book#
9 4 oe#
MS, MSD Known Cone (mg/kg) * 100 ugC/ grams sample
MS, MSD Observed (mg/kg) = ug C / grams sample
MS, MSD Rec. [observed mg/kg - avo. sample result fmo/kq^l x 1
known concentration in mg/kj
Standard TraceablUtv: (Note; Wbrklng
are prepared daily from the noted Stock Solutions.)
Stock I (Curve)
lock II (ICV/CCV)
LCS Source ID
;$ True Value
Acceptance Range
Sample ID: Sample Weight (g> ugC
o 3 2 77- /? . O ^ K
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Prep Analyst: w
Analyst
UkReviewed by:.
-7 7
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Date:. Date:. Date:
,
CH1>22>12-41sm-os/81
STL Chicago
Page
109
TOC in So ils Method: Lloyd Kahn
800K N O - ----- --^ Instrument Phoenix 8000 [TO4)
labNet B a tc n X 2 _ J Z 3
r-ilculatiom:
Date of Standard Curve: S L________-
TOC (mg/kg) ug C / grams sample
Book#
. 7 rPafle#________
MS, MSD Known Cone, (mg/kg) = 100 ugC/ grams sample
MS, M$D Observed (mg/kg) = ug C / grams sample
MS, MSORec, fobserved mg/kg - avg. sample result fma/koj]
known concentration in mg/kg
^
standard Traceability: (Note: Wor) jj Standards are prepared dally from the noted Stock Solutions,)
stock I (Curve)________ kC _______ Stock II (ICV/CCV),
LCS Source ID
LCS True Value
Acceptance Range.
^ Sample ID:
co u
V
Sample Weight (g) r ugC
O .O O fO
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Comments:
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Prep Analyst Analyst Reviewed by:
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Date: / Q-///v u/
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Date: / ^-//o-So ^
Date;
2 ffl CHt>Z2-12MS/B-OS/fH
