Document wepBym15KYjJeNGBay1Q4n5d
TO:
Distribution
Af
FROM: DATE:
Interoffice
SUBJ:
Communication
T. G. Grumbles April 8, 1987
CALIFORNIA PROPOSITION 65
The attached describes recent regulatory action in California which could, or will, impact some of our products sold or toll processed in that state. The actual impact is not clear because the law's wording is vague and can be interpreted quite broadly.
The law requires that a list of known carcinogens and reproductive toxins be published by the Governor. Chemicals on the list will be regulated to prohibit any "significant" discharge of those chemicals into drinking water sources and to require "clear and reasonable" warning to prevent individual exposures. The act defines significant to be any detectable amount.
The primary list published on March 1 includes benzene, mineral oils, vinyl chloride, lead and ethylene oxide. We have already received an inquiry regarding the mineral oil listing and it's applicability to ODC. Specific to that issue we feel our LPA solvents are not covered
I by the mineral oil listing.
Please let us know if you get questions regarding the above Ue can assist in answering customer inquiries regarding this rulemaking.
T. G. Grumbles
ajo .9
L. McClain
J. A. Hall R. E. Swantkowski B. E. A. Larsen S. K. Saborsky R. T. Means
VVV 000023381
rnuoiWl 1914
CHEMICAL SPECIALTIES MANUFACTURERS ASSOCIATION
March 26, 1987
TO:
CSMA Membership
FROM:
George G. Mrsko / 7// Regulatory Counsel '
RE:
California Preposition 65: Lists of Covered Chemicals
Suite 1120
f
1001 Connecticut Avenue. NW
Washington. DC 20036
/h\ ' j 'j
202/872-8110
*
..
Proposition 65, enacted in California by referendum in November, 1986, prohibits the contamination of drinking water with chemicals known to cause cancer or reproductive toxicity, and require warnings prior to exposing any individuals to chemicals known to cause cancer or reproductive toxicity. The law requires the Governor of California to publish a list of those chemicals "known to the State to cause cancer or reproductive toxicity" by March 1, 1987. The chemicals on that list are those to which the drinking water prohibitions and warning requirements apply.
On February 27, 1987, Governor Deukmejian published two lists of toxic chemicals. The first list of 29 chemicals
are those which have been determined to cause cancer or reproductive toxicity. The second list of approximately 250 chemicals will be reviewed by a Scientific Advisory Panel established by the Governor. The decision to include these chemicals on the list of covered chemicals will be based upon the Scientific Panel's review. Copies of these two lists of chemicals are attached.
Following publications of the two lists by the Governor, a number of environmental groups, among others, filed suit against the Governor. The suit generally alleges that the Governor did not include enough chemicals on the first list.
CSMA also has available interpretive guidelines and procedures promulgated by the California Department of Health and Welfare. The interpretive guidelines provide definitions to many of the terms used in the Act. The procedures review the steps the Department of Health will take to make safe use determinations. If you desire copies of these documents, please contact Marlene Copeland, (202) 872-8110, at CSMA.
We will keep you advised of other steps taken to
implement Proposition 65. : me
vvv O00023382
CHEMICALS KNOWN TO CAUSE CANCER OR REPRODUCTIVE TOXICITY
The Safe Drinking Water and Toxic Enforcement Act of 1986 requires the Governor to publish by March 1, 19S7 a list of those chemicals known to the State to cause cancer or reproductive toxicity. Health and Safety Code Section 25249.8(a). The attached list includes all those chemicals which are known to cause cancer in humans as determined by World Health Organization's International Agency for Research on Cancer (IARC) or the United States Public Health Service's National Toxicology Program (NTP). in audition, the list includes the three chemicals currently regulated by the United States Department of Labor's Occupational Safety and Health. Administration (OSHA) as reproductive toxicants. The Safe Drinking Water and Toxic Enforcement Act of 1936 requires that the attached list be revised and republished at least once per year. Therefore, new chemicals may be added to the list based on the recommendations of the Safe Drinking Water and Toxic Enforcement Act Scientific Advisory Panel, changes to determinations of IARC cr NTP, or changes to federal OSHA regulations. Questions about the list or requests for copies of the current list should be addressed to the State's lead agency for implementation of the Safe Drinking Water and Toxic Enforcement Act:
State of California Health and Welfare Agency 1600 Ninth Street, Room 450 Sacramento, CA 95814
)
VVV 000023383
LIST OF CANDIDATE CHEMICALS
The Safe Drinking Water and Enforcement Act of 1986 (the Act) requires the Governor to publish a list of chemicals known to the State to cause cancer or reproductive toxicity and to revise and republish the list in light of additional knowledge. A primary list of chemicals known to the State to cause cancer or reproductive toxicity has been published as required by the Act. However, it is also necessary to begin the process of considering additions oo r.his primary list. What follows is a list of candidate chemicals which is being referred to as the Safe Drinking Water and Toxic Enforcement Act Scientific Advisory Panel for its consideration and opinion.
This list of candidate chemicals includes chemicals for which there is limited evidence of carcinogenicity in humans or sufficient evidence of carcinogenicity in experimental animals as identified by the World Health Organization's International Agency for Research on Cancer (IARC) or by the United States Public Health Service's National Toxicology Program (NTP). Under the terms of the Act, the Scientific Advisory Panel
Jis responsible for reviewing the available data concerning these chemicals and any other chemicals which are suspected carcinogens or reproductive toxicants and forming an opinion on whether such chemicals have been clearly shown through scientifically valid testing according to generally accepted principles to cause cancer or reproductive toxicity.
Any questions about this list of candidate chemicals or suggestions for additional chemicals to be considered by the Scientific Advisory Panel should be addressed to the lead agency for implementation of the Act:
State of California Health and Welfare Agency 1600 Ninth Street, Room 450 Sacramento, CA 95814
)
vvv 000023384
Note: (1) An asterisk (*) indicates Chat the corapound(s) responsible for the carcinogenic effect in humans cannot be specified.
(2) The identification number is the Chemical Abstracts Service (CAS) Registry Number. No CAS number is given when several substances are presented as a single listing.
CARCINOGENS
Chemical
CAS Number
4-Aminobiphenyl
92671
Analgesic mixtures containing phenacetin*
Arsenic and arsenic compounds*
--
Asbestos
1332214
Azathioprine
446866
'snzene
J
Benzidine [and its salts}
71432 92875
N,N-Bis(2- chlo roe thy1) - 2 - naphthylamine ( Chlo mapaz ine )
494031
Bis(chloromethyl)ether
542881
1,4-Butanediol dimethanesufonate (Myleran)
55981
Certain combined chemotherapy for lymphomas*
Chlorambucil
305033
Chloromethyl methyl ether (technical grade)
107302
Chromium and certain chromium compounds* Coke oven emissions*
...
Conjugated estrogens*
Cyclophosphamide
50180
Diechylstilbestrol
_^lphalan Hethoxsalen. with ultraviolet A therapy (PUVA)
VVV 000023385
56531 148823 298817
Mustard Gas
505602
2- -
2-Naphythylaraine Soocs, cars and mineral oils* (mineral oils
may vary in composition, particularly in relation to their content of carcinogenic polycyclic aromatic hydrocarbons) Thorium dioxide Treosulfan Vinyl chloride
REPRODUCTIVE TOXICANTS 1,2,Dibromo-3-chloropropane Ethylene oxide Lead
91598 -----
1314201 299752 75014
96128 75218 7439921
VVV 000023386
Candidate Chemical Carcinogens (Chemicals showing limited evidence for carcinogenicity in
people and/or sufficient evidence in animals)
Note: '
The identification number is the Chemical Abstracts Service (CAS) Registry Number. No CAS number is given when several substances are presented as a single listing.
CAS Number
2-Acetylaminofluorene
53963
Acrylonitrile
107131
Actinomycins
Adriamycin
23214928
AF-2;[2-(2-furyl)-3-(5-nitro-2-furyl]acrylamide
3688537
Aflatoxins
^-Aminoanthraquinone
117793
ortho-Aminoazotoluene
97563
1-Amino- 2-me thylanthraquinone
82280
2 Amino-5-(5-nitro-2-furyl)-1,3,4-thiadiazole
712685
Amitrole
61825
ortho-Anisidine and ortho-Anisidine hydrochloride
90040
Aramite
140578
Auramine
492808
Azaserine
115026
Benz[a]anthracene Benzo[b]fluoranthene Benzo(j j fluoranthene Lzo[k] fluoranthene
Benzo{a]pyrene
000023387
56553 205992 205823 207089
50323
2- -
Benzocrichloride Benzyl violet 4B Beryl ore Beryllium Beryllium compounds:
Beryllium aluminum alloy Beryllium chloride Beryllium fluoride Beryllium hydroxide Beryllium oxide Beryllium phosphate Beryllium sulfate Zinc beryllium silicate 2-(p-tert-Butylphenoxy)isopropyl-2-chloroechyl sulfite beta-Butyrolactone
98077 1694093
----7440417
12770502 7787475 7787497
13327327 1304569
13598157 13510491 15191852
140578 3068880
Cadmium
Cadmium compounds:
Cadmium chloride
Cadmium oxide
Cadmium sulfate
Cadmium sulfide
Carbon tetrachloride
Carrageenan (degraded) Chlordecone (Kepone)
A* >000^ N'1
1-(2-Chloroethyl)- 3-cyclohexyl-1-nitrosourea (CCNTJ)
7440439
10108642 1306190
10124364 1306236 56235
143500 13010474
Chloroforra 4-Chloro-ortho-phenylenediamine Citrus Red No. 2 para-Cresidine Cupferron Cycasin
-3-
Dacarbazine
Daunomycin
DDT (1,1, l-Trichloro-2,2-bis(p-chlorophenyl)ethane N,N'-Diacetylbenzidine
2,4-Diaminoanisole sulfate
4,4'-Diaminodiphenyl ether 2,4'Diaminotoluene
Dibenz[a,h)acridine
Dibenz(a,j]acridine
Dibenz [a,h Janthracene
7H`Dibenzo[c,g]carbazole
Dibenzofa,e1pyrene
Dibenzo[a,h)pyrene Dibenzo[a,i)pyrene Dibenzo[a,1]pyrene 1,2-Dibromo-3-chloropropane
vvw OOOOZ3309
3,3'-Dichlorobenzidine [and its salts)
3,3'-Dichloro-4,4'-diaminodiphenyl ether
Diepoxybutane
67663 95830 6358538 120718 135206 14901087
4342034 20830813
50293 613354 39156417 101814
95807 226368 224420
53703 194592 192654 189640 189559 191300 96128 91941 28434868 1464535
-4-
Di(2-ethylhexyl)phthalate 1,2-Diethylhydrazine Diethyl sulfate Dihydrosafrole Dihydroxymethylfuratrizine (Panfuran S) 3- 3' -Diraethoxybenzidine (ortho-Dianiasidine) 4- Diniethylarainoazobenzene trans-2-[(Dimethylamino)methylimino)-5-[2-5-nitro-2-furyl)vinyl)-
1,3,4-oxadiazole 3,3'Dimethylbenzidine (ortho-Tolidine) Dimethylcarbamoyl chloride 1T1 Dimethylhydrazine 1,2 Dimethylhydrazine Dimethyl sulfate 1,4-Dioxane Direct Black 38 (technical grade) Direct Blue 6.(technical grade)
117817 1615801
64675 94586 556127 119904 60117 55738540
119937 79447 57147
540738 77781
123911 1937377 2602462
Epichlorohydrin Estradiol 17B Estrone Ethinylestradiol Ethylene dibroinide Ethylene dichloride Ethyleneimine Echylene oxide
106898 50282 53167 57636
106934 107062 151564
75218
Echylene thiourea Ethyl methanesulfonate
-5-
96457 62500
Formaldehyde Formylhydrazino) -4 - (5-tiitro-2-furyl)thiazole
50000 2570750
Glycialdehyde Gyromitrin (acetaldehyde methylformylhydrazone)
765 344 16568028
Hexachlorobenzene Hexamethylphosphoramide
^drazine and hydrazine sulfate Hydrazobenzene
118741 680319 302012 122667
Indeno[1,2,3-cd]pyrene Iron dextran complex Isosafrole
193395 9004664
120581
Lasiocarpine
Lead
Lead compounds:
Lead acetate
Lead phosphate
Lead subacetate
j
Lindane and ocher hexachlorocyclohexane isomers
303344 7439921
301042 7446277 1335326
58899
VVV 000023391
6- -
Merphalan Mestranol 5-Methyl chrysene 2-Methylazlridine (piropyleneimine) Methylazoxymethanol; methylozaoxyreethyl acetate 4,4'-Methylene bis(2-chloroaniline) (MBOCA) 4,4'-Methylene bis(2-methylaniline) 4,4'-Methylenedianiline and its dihydrochloride Methyl iodide Methyl methanesulfonate 2-Methyl-l-nitroanthraquinone (of uncertain purity) N-Kethyl-N'-Nitro-N-nitrosoguanidine Methylthiouracil Metronidazole Michler's ketone Mirex Mitomycin C Monocrotaline 5-(Morpholinomethyl)-3-[(5-nitro-furfurylidene)-amino]-
2-oxalolidinone
531760 72333
3697243 75558
592621 101144 838880 101779
74884 66273 129157 70257 56042 443481 90948 2385855 50077 315220 139913
Nafenopin Nickel Nickel compounds:
Nickel carbonyl Nickel carbonate
VWV OOOOZ33'2
3771195 7440020
13463393 3333673
-7-
Nickel hydroxide Nickel subsulfide Niridazole Nitrilotriacetic acid 4-Nitrobipheuyl 5-Nitroacenaphthene 5-Nitro-o-anisidine Nicrofen (technical grade) 1- ( (5-Nitrofurfurylidene)-amino]-2-iraidazolidinone N- [4-(5 >Nitro-2-furyl)- 2-thiazolyl]acetamide Nitrogen mustard and its hydrochloride ^.trogen mustard N-oxide and its hydrochloride 2-Nitropropane N-Nitrosodi-n-butylaraine N-Nitrosodiethanolamine N-Nitrosodiethylamine N-Nitrosodimethylamine p-Nitrosodiphenylamine N-Nitrosodi-n-propylamine N-Nitroso-N-ethylurea N-Nitrosomethylethylamine N-Nitroso-N-raethylurea N-Nitroso-N-methylurethane N-Nitrosomethylvinylaraine .^-Nitrosomorpholine
N-Nitrosonornicocine
VVV 000023393
12054487 12035722
61574 139139
92933 602879
99592 1836755
555840 531828
51752 302705 108032 924163 116547
55185 62759 156105 621647 759739 10595956 684935 615532 4549400 59892 16543558
N-Nitrosopiperidine N-Nitrosopyrrolidine N-Nitrososarcosine
8- -
Orange Oil SS Oxyme tho lone
Phenacetin Phena2opyridine and its hydrochloride Phenoxybenzamine and its hydrochloride Phenytoin and sodium salt of phenytoin Polybrominated biphenyls Polychlorinated biphenyls Ponceau MX Ponceau 3R Procarbazine and its hydrochloride Progesterone 1,3-Propane sultone beta-Propiolactone Propylthiouracil
Reserpine
Saccharin;sodium saccharin Safrole Selenium sulfide
VVV 000023394
100754 930552 13256229
2646175 434071
62442 136403
59861 57410
3761533 3564098
366701 57830
1120714 57578 51525
50555
81072; 128449 94597
7488564
Sterigmatocystin Streptozotocin Sulfallate
-9-
Testosterone and its esters 2,3,7,8-Tetrachlorodibenzo-para-dioxin (TCDD) Thioacetamide 4,4'-Thiodianiline Thiourea Toluene diisocyanate ortho-Toluidine and its hydrochloride ^oxaphene (polychorinated camphenes)
2,4,6-Trichlorophenol Tris(l-aziridinyl)phosphine sulfide (thlotepa) Tris(2,3-dibromopropyl)phosphate Trp-P-1 (Tryptophan-P-1) Trp-F-2 (Tryptophan-P-2) Trypan Blue (commercial grade)
Uracil mustard Urechane
10048132 1SBB3664
95067
58220 1746016
62555 139651
62566 584849 636215 8001352
88062 52244 126727 62450060 62450071 72571
66751 51796
tI i
l
I
TO: D. A. Kuhn
FROM: DATE:
Interoffice
SUBJ:
Communication
T. G. Grumbles April 3, 1987
PROGRESS REPORT FOR THE WEEK ENDING APRIL 3, 1987
VIST/
1. A review of Blane hazardous waste management practices was completed and recommendations made.
2. A presentation was made to PVC TSR's and Business Area regarding environmental impacts on the PVC business.
3. BFG settled an EPA/DOJ lawsuit on VCM emissions from its Calvert City Plant for $123M plus projects to prevent recurrence.
4. T. G. Grumbles attended The Management Process training, March 30 - April 3.
5. EPA was notified under TSCA 8(e) that groundwater contamination may have migrated beyond the fence line at LCVCM.
6. The EPA proposed new reportable quantities for several
substances under Superfund.
The materials manufactured,
processed or used by Vista affected by this ruling include vinyl
chloride, methyl chloride and benzene. A memo was sent to the
Plant Environmental Coordinators.
T. G. Grumbles
ajo .5
yVV 0000233*?6
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I