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minute. In very recent experiments on the effect of the thickness of dust lay| was found that, in the equipment used, the lowest ignition temperatures reached with layers Vs inch thick. In nearly all cases, 90 per cent or more off powder was finer than 74 p. Selected results are given for metal powders6 ini. 2, for dusts in the plastics industry6 in Table 3, and for agricultural andS dusts11'16 in Table 4. Data for coal dust clouds in air and in .oxygen and of coal dusts of various volatile contents8 are shown in Figure 1.
Powder
Aluminum, atomized Aluminum, stamped Antimony Cadmium Chromium Copper Dowmetal Iron, hydrogon reduced Iron, carbon reduced Iron carbonyl Lead, atomized Lead, stamped Magnesium, atomized Magnesiumrmilled Magnesium, stamped
TABLE 2 Ignition Temperatures of Metal Powders
,,SU
' '*{
Ignition
Ignlfijoj
temperature
tempera!
r C.)
Dust Dust
( DuBt
cloud 640
layer 750
Powder Manganese
cloud 1 &
550 470
Silicon
415 330 570 250 900 -- 700 --
Tin Thorium Thorium hydride (ThHi)" Titanium
030 270!*$ 260 ft .130
430 480
Titanium hydride (Tills)
440" .
315 290
Uranium*
20;
425 390
Uranium hydride (UH.)"*
20
320 230
Vanadium
500;
710 270 5SO 300
Zinc Zirconium*
600' 20
600 490
Zirconium hydride (ZrHO
350.
540- . 475-.... ......Ferrosilicon-(88%-Si).....-- _____-Ml
520 480
Ferrotitanium, low-carbon
370
Magnesium-aluminum (50-50 ) 535
"On exposure in air for several minutes at normal laboratory temperature, layers
and UHi ignited spontaneously.
^
"During dispersion through furnace at room temperature, dust clouds of U, UHi;
ignited.
TABLE.3
Ignition Temperatures of Dusts in Plastics Industry
""Powder
Ignition tempera
ture of dust cloud
rc.j
Powder
Resins Shellac, rosin, gum
...Vinylbutyral.. Cellulose acetate Pine-rosin base Polyethylene
390 ,390 370 440
410
Molding compositions Ethyl cellulose
.. ;Rubb.er,.synthetic,... CelEQoso acetate Kutyrate"^?' Cellulose acetate Methyl methacrylate.....
H I. Hartmann, in L. S. Marks, Mechanical Engineers' Handbook, 5th ed 1951, pp. 795-800.
111. Hartmann, Ind. Eng. Chem., 40, 752 (1948).
560
-vMMr-prp,1
TABLE 3 (conltnued)
Ignition tempera ture of
dust cloud CC.)
Powder
450 Uroa 460 Phenolic 460 Polystyrene 470 Vinyl chloride-vinyl ace 490 tate 500 520 520 840
Fillers for molding composi 350 tions
Ground alpha pulp 410 Ground cotton flock 450 Ground wood flour
Ignition tempera
ture of dust cloud (C.) 450 490 560 690
480 470 430
Ignition temperature of dust cloud
( C.)