Document wDz4y9grRzDzqBRxJ9b5vze7J
AR226-2686
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AR226-2686
Perfluorinated Surfactants
'Dupont / UvA / RIKZ Meeting, 07-05-200;
"Perfluorinatecr" surfactants
A desk study on the use and environmental effects of perfluorinated
surfactants in the Netherlands
Floris Hekster & Pirn de Voogt
A desk study commissioned by the Dutch Ministry of Transport, Public Works
____ ____ ___and Water Management ____
EID676803
Perfluorinated Surfactants
'Dupont / UvA / RIKZ Meeting, 07-05-2002
Outline of the presentation
-y Goals
ne ble of contents report
/
Methodology
Available knowledge
Remaining questions/ uncertainties
A desk study commissioned by the Dutch Ministry ot Transport, Public Wolks
____
__ and Water Management ______ ___
EID676804
Perfluorinated Surfactants
' Dupont / UvA / RIKZ Meeting, 07-05-20
The study has three major goals
1. Overview of available knowledge
on: the environmental behaviour the ecotoxicology the occurrence
2. Inventory of the use of PFS in NL 3. Estimation of the emissions of
PFS in NL
A desk study commissioned by tte Dutch Ministry of Transport, Public Works
Water Management
______________and
____________
EID676805
Perfluorinated Surfactants
r Dupont / UvA / RIKZ Meeting, 07-05-200;
Table of contents report
1. Introduction 2. Physico-chemical properties 3. Sources and emissions to the aq.
environment 4. Behaviour in the aq. environment 5. Occurrence in the aq.
environment 6. Toxicity in the aq. environment 7. Policy
A desk study commissioned by the Dutch Ministry of Transport, Public Works
__ Water Management
______________and
EID676806
Perfluorinated Surfactants
r Dupont / UvA / RIKZ Meeting, 07-05-2002
baia are obtained from ^sciemmc)
literature... >OECD hazard assessment ()KCI>((|
^3M/ USEPA database on ECF producQM
^USEPA hazard assessment on PFOAf^
>NCEHS, review on PFAS in the UK
> Various publications in: Environmental Science & Technol
Journal of Fluorine Chemistry
Etc.
s-Kissa, Fluorinated surfactants and repellents
Material Safety Data Sheets/Product data sheets
A desk study commissioned by tie Dutch Ministry ol Transport, Public Worts
_____________and Water Management___
___
EID676807
Perfluorinated Surfactants
''Dupont/ UvA / RIKZ Meeting, 07-05-200;
...and from additional sources
> Interviews with:
i^ym
Chemicals manufa
3M, Asahi, AtoFina, Bayer, Clariant, Daildn. Dupont, Miteni, APl^ Users; Ajax fire systems, Lakatex
Representing
organisations: NVTF(capen&y), FNL
(leather, VEBON (fire fighting, VTN (textile), GOT (carpentry
Researchers: ISEGA, universities
(Antwerp, Michigan State, Oregon State,
^nterrTePseaR^e^l Viv 'if\A desk study commisstoned by the Dutch Ministry of Transport. Public Works
__________ and Water Management____ ___
EID676808
Perfluorinated Surfactants
' Dupont / UvA / RIKZ Meeting, 07-05-20
Available knowledge
> Two major production processes: ECF and telomerisation
> Biodegradation of EOF products: PFOS and PFOA
> Environmental fate modelling based on Kg^ is not applicable
> PFOS and to a lesser extend PFOA are globally distributed:
Bioaccumulation Long-range air transport
> PFOS is moderately toxic, PFOA has a low toxicity
> PFOA is weakly carcinogenic > Besides SNUR of USEPA, there is no policy
A deffl&iRRiSn(iyet^dby me Dutch Ministry of Transport, Public Works ______________and Water Management_______________
EID676809
Perfluorinated Surfactants
' Dupont / UvA / RIKZ Meeting, 07-05-200;
PFS can be used in many
plications
> Coatings
I> Electronics
|> Herbicides > Leather > Medical
use > Metal
Finishing > Oil wells > Polymerisa
tion > Wetting
agents
A desk study commissioned by the Dutch MInlstty o( Transport, Public Works
______________and Water Management______________
EID676810
^ ntsJH| Perflu orinated Surfacta
^ybupont/LJvA / RIKZ Meeting, 07-05-2002KU
Ihe re are 4 maj 0 r1tor--ms-ofy
a p Pe;a ranee
Mono)meric
\ poh/men
^;c)-
^Phosphate
^Both telomer awd
ECF products have
various forms of
WtelB)
appearance,
wphate
dependent on the
function
A\deskst udycomm sstoned by Ihe Dutch Ministry ol Trvansportt ,p'ubilc Works and Water Management
EID676811
Perfluorinated Surfactants
''Dupont/ UvA / R1KZ Meeting, 07-05-200;
' The lire-fighting foam for mobile equipment is changing towards socalled Eco-toam. This contains much less or no PFS
" The degradation of polymers might lead to the emission of PFS from polymers. Furthermore impurities can leak from the polymers A desk study commissioned by me Dutch Ministry of Transport, Public Works
_____________and Water Management_____________
EID676812
Perfluorinated Surfactants
' Dupont / UvA / RIKZ Meeting, 07-05-200:
Some important uncertainties are remaining
> Properties of telomer products
> Chemical/ biodegradation and degradation products of fluoropolymers
> Environmental fate/ distribution mechanisms
> Alternative compounds for applications
> Use figures for various applications
A desk study commissioned by the Dutch Ministry of Transport, public Works
Water Management
______________and
_____
___
EID676813